Glasnost and glaciers, yurts and yaks : a scientist in Soviet Central Asia
- Authors: Lewis, Colin A
- Date: 1991
- Language: English
- Type: Article
- Identifier: vital:6707 , http://hdl.handle.net/10962/d1006744
- Description: Why are glaciers retreating, and are all glaciers retreating? There is much evidence to suggest that, globally, mean annual air temperatures are rising. Yet not all areas of the world have experienced temperature increases. In 1989 a Joint UNESCO/IGCP research project, Project 297, was initiated in order to identify and correlate geocryological features in mountain areas. A visit to the Alpine Geocryology station of the Academy of Sciences of the USSR to study rock glaciers afforded the author a glimpse of Soviet Asian evidence of climatic change and caused him to revise his interpretation of rock glacier and other geocryological remains in the eastern Cape Drakensberg.
- Full Text: false
- Date Issued: 1991
- Authors: Lewis, Colin A
- Date: 1991
- Language: English
- Type: Article
- Identifier: vital:6707 , http://hdl.handle.net/10962/d1006744
- Description: Why are glaciers retreating, and are all glaciers retreating? There is much evidence to suggest that, globally, mean annual air temperatures are rising. Yet not all areas of the world have experienced temperature increases. In 1989 a Joint UNESCO/IGCP research project, Project 297, was initiated in order to identify and correlate geocryological features in mountain areas. A visit to the Alpine Geocryology station of the Academy of Sciences of the USSR to study rock glaciers afforded the author a glimpse of Soviet Asian evidence of climatic change and caused him to revise his interpretation of rock glacier and other geocryological remains in the eastern Cape Drakensberg.
- Full Text: false
- Date Issued: 1991
Looking at landscapes
- Authors: Lewis, Colin A
- Date: 1991
- Language: English
- Type: Text
- Identifier: vital:576 , http://hdl.handle.net/10962/d1006731
- Description: [From text] Landscape, for me, is Geography, for landscape is the focus of the four great traditions of my subject: spatial; area studies; man-land relationships; earth science (Pattison, 1964,1990). Hedd Wyn and Thomas Roberts, each in his own way, was a Geographer, for each was obviously a student of landscape. My own interest in Geography originated in the view from my bedroom window. I was lucky, Dad was a clergyman, and when he came bade from the army he accepted the parish of St. Peter's Glasbury, in the Wye valley of Wales. From my bedroom window I looked out across The Vicarage lawn, beyond the yew hedge and the orchard, to a series of mounds set in parkland. They were orderly, forming the outline of a rectangle, and when a group of archaeologists excavated the site they discovered that the mounds were the remains of the walls of an Iron Age fort (Savoury, 1955). Although I did not know it at the time, the landscape was already talking to me. , Inaugural Lecture delivered at Rhodes University, Grahamstown, 17 April 1991
- Full Text:
- Date Issued: 1991
- Authors: Lewis, Colin A
- Date: 1991
- Language: English
- Type: Text
- Identifier: vital:576 , http://hdl.handle.net/10962/d1006731
- Description: [From text] Landscape, for me, is Geography, for landscape is the focus of the four great traditions of my subject: spatial; area studies; man-land relationships; earth science (Pattison, 1964,1990). Hedd Wyn and Thomas Roberts, each in his own way, was a Geographer, for each was obviously a student of landscape. My own interest in Geography originated in the view from my bedroom window. I was lucky, Dad was a clergyman, and when he came bade from the army he accepted the parish of St. Peter's Glasbury, in the Wye valley of Wales. From my bedroom window I looked out across The Vicarage lawn, beyond the yew hedge and the orchard, to a series of mounds set in parkland. They were orderly, forming the outline of a rectangle, and when a group of archaeologists excavated the site they discovered that the mounds were the remains of the walls of an Iron Age fort (Savoury, 1955). Although I did not know it at the time, the landscape was already talking to me. , Inaugural Lecture delivered at Rhodes University, Grahamstown, 17 April 1991
- Full Text:
- Date Issued: 1991
Peter Warlock: a study of the composer through the letters to Colin Taylor between 1911 and 1929
- Authors: Smith, Barry, 1939-
- Date: 1991
- Subjects: Warlock, Peter, 1894-1930 -- Correspondence Taylor, Colin, 1881-1973 -- Correspondence Composers -- Great Britain -- Correspondence
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2657 , http://hdl.handle.net/10962/d1002323
- Description: This thesis involves a comprehensive study of the letters written by Philip Heseltine (Peter Warlock) to Colin Taylor from 1911 to 1929. Warlock first came into contact with Taylor at Eton in 1908 when he studied the piano with him as a schoolboy. Through Taylor's imaginative teaching during the next four years Warlock's interest in and understanding of music, particularly modern music, grew and matured. At the same time a strong bond of friendship developed between the two men and continued until Warlock's early death in 1930. This is clearly illustrated in the surviving 87 letters. Warlock was a great letter writer and over a thousand of them have been preserved, mostly in the British Library. His letters to Taylor have a special significance in that they were written during the entire period of his adult life, most of them during the early formative and creative years. They cover a wide range of topics including the influential friendships with the composers Frederick Delius and Bernard van Dieren, contemporary British and foreign music and his own work as a composer, writer, and scholar. They also give us many important insights into his life and personality, written as they are with rare candour and humour. In this thesis each letter has been carefully and systematically studied and the resulting information used to augment and expand the existing knowledge of Warlock's life and personality, his friendship with Taylor, his music and writings. Because of the wide field which the life and works of Peter Warlock cover, this study has been limited to subjects arising out of the correspondence with Taylor. Where necessary, additional information has been interpolated from other sources, mainly to give a sense of continuity and to explain references which might otherwise seem obscure. For a detailed study of Warlock's music readers are referred to Ian Copley's book, The Music of Peter Warlock, (Dennis Dobson, London, 1979). A definitive biography has yet to be written.
- Full Text:
- Date Issued: 1991
- Authors: Smith, Barry, 1939-
- Date: 1991
- Subjects: Warlock, Peter, 1894-1930 -- Correspondence Taylor, Colin, 1881-1973 -- Correspondence Composers -- Great Britain -- Correspondence
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2657 , http://hdl.handle.net/10962/d1002323
- Description: This thesis involves a comprehensive study of the letters written by Philip Heseltine (Peter Warlock) to Colin Taylor from 1911 to 1929. Warlock first came into contact with Taylor at Eton in 1908 when he studied the piano with him as a schoolboy. Through Taylor's imaginative teaching during the next four years Warlock's interest in and understanding of music, particularly modern music, grew and matured. At the same time a strong bond of friendship developed between the two men and continued until Warlock's early death in 1930. This is clearly illustrated in the surviving 87 letters. Warlock was a great letter writer and over a thousand of them have been preserved, mostly in the British Library. His letters to Taylor have a special significance in that they were written during the entire period of his adult life, most of them during the early formative and creative years. They cover a wide range of topics including the influential friendships with the composers Frederick Delius and Bernard van Dieren, contemporary British and foreign music and his own work as a composer, writer, and scholar. They also give us many important insights into his life and personality, written as they are with rare candour and humour. In this thesis each letter has been carefully and systematically studied and the resulting information used to augment and expand the existing knowledge of Warlock's life and personality, his friendship with Taylor, his music and writings. Because of the wide field which the life and works of Peter Warlock cover, this study has been limited to subjects arising out of the correspondence with Taylor. Where necessary, additional information has been interpolated from other sources, mainly to give a sense of continuity and to explain references which might otherwise seem obscure. For a detailed study of Warlock's music readers are referred to Ian Copley's book, The Music of Peter Warlock, (Dennis Dobson, London, 1979). A definitive biography has yet to be written.
- Full Text:
- Date Issued: 1991
Rhodes University Annual Report 1991
- Authors: Rhodes University
- Date: 1991
- Subjects: Rhodes University -- history Rhodes University -- employees Rhodes University -- students
- Language: English
- Identifier: vital:20039
- Full Text:
- Date Issued: 1991
- Authors: Rhodes University
- Date: 1991
- Subjects: Rhodes University -- history Rhodes University -- employees Rhodes University -- students
- Language: English
- Identifier: vital:20039
- Full Text:
- Date Issued: 1991
Aspects of the biology, ecology and population dynamics of Galeichthys feliceps (Valenciennes) and G. ater (Castelnau) (Pisces: Ariidae) off the south-east coast of South Africa
- Authors: Tilney, Robin Lewis
- Date: 1991
- Subjects: Catfishes -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5221 , http://hdl.handle.net/10962/d1005064
- Description: This thesis represents a detailed investigation into aspects of the biology, ecology and population dynamics of two endemic ariid species, Galeichthys feliceps and G. ater, off the southeast coast of South Africa. The two species are exploited as a by-catch in the commercial ski-boat fishery off Port Alfred, a fishery dominated by highly fecund sparid and sciaenid species. They collectively constitute approximately 10% of the total annual catch in terms of landed mass G. feliceps outnumber G. ater in the catches by a ratio of 3:1. The investigation was designed to provide the biological data required for stock assessment and to determine optimum management strategies for the two populations. The implications of their K-selected life-history styles for exploitation received particular attention. While the two species were sympatric and had similar depth distributions they were found to be allopatric with respect to their foraging habitats. G. feliceps foraged over sandy and muddy substrata in marine and estuarine environments. G. ater fed only on reef-associated species and did not utilise estuaries. Their feeding-associated morphologies were identical and both species preyed primarily on crustaceans (brachyuran crabs and isopods), echiurids, molluscs and polychaetes. The diet of G. ater was broader in terms of the number of species consumed. The two species are mouth-brooders with low fecundity. G. feliceps and G. ater produced a mean of 49 and 32 eggs each, per annum. The buccal incubation period was determined to be in the region of 140 days for G. feliceps. Embryos hatched after approximately 75-80 days and the young began exogenous feeding thereafter. The young fed intra-buccally on detritus provided by the parent. Adult buccal mucus may also have been used as a food source. Young were released at a total length of ± 55mm. Adult males ceased feeding whilst mouth-brooding. Body musculature, abdominal fat and liver reserves provided energy for basal metabolism and males lost approximately 28% of their body mass during buccal incubation. Females expended less reproductive energy than males. Catches were dominated by mature fish (76% in G. feliceps and 97% in G. ater). Females were significantly more abundant in catches during the spawning and mouth-brooding period. The female to male sex ratios were 1.65:1 and 2.23:1 for G. feliceps and G. ater respectively. Age and growth studies revealed that the two species mature at advanced ages (10 and 9 years for G. feliceps and 9 and 7 years for G. ater males and females respectively). They are long-lived, reaching ages in excess of 18 years in G. feliceps and in excess of 15 years in G. ater. Females live longer than males and grow larger. Yield-per-recruit and spawner biomass-per-recruit analyses demonstrated that G. ater were exploited below FO.1 at a level where spawner biomass-per-recruit was reduced to between 45% and 65% of the unexploited level. The G. ater stock was not adversely affected by current levels of fishing effort. For G. feliceps, both sexes were exploited beyond F₀.₁ where spawner biomass-per-recruit was reduced to between 30% and 22% of the unexploited level. G. feliceps were shown to be sensitive to relatively low levels of exploitation, a phenomenon attributed to their highly Kselected life-history style. Should the species become targeted for in the future, effort restrictions in the form of a closed season during the spawning and mouth-brooding period would prove effective in reducing effort and conserving the population sex ratio.
- Full Text:
- Date Issued: 1991
- Authors: Tilney, Robin Lewis
- Date: 1991
- Subjects: Catfishes -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5221 , http://hdl.handle.net/10962/d1005064
- Description: This thesis represents a detailed investigation into aspects of the biology, ecology and population dynamics of two endemic ariid species, Galeichthys feliceps and G. ater, off the southeast coast of South Africa. The two species are exploited as a by-catch in the commercial ski-boat fishery off Port Alfred, a fishery dominated by highly fecund sparid and sciaenid species. They collectively constitute approximately 10% of the total annual catch in terms of landed mass G. feliceps outnumber G. ater in the catches by a ratio of 3:1. The investigation was designed to provide the biological data required for stock assessment and to determine optimum management strategies for the two populations. The implications of their K-selected life-history styles for exploitation received particular attention. While the two species were sympatric and had similar depth distributions they were found to be allopatric with respect to their foraging habitats. G. feliceps foraged over sandy and muddy substrata in marine and estuarine environments. G. ater fed only on reef-associated species and did not utilise estuaries. Their feeding-associated morphologies were identical and both species preyed primarily on crustaceans (brachyuran crabs and isopods), echiurids, molluscs and polychaetes. The diet of G. ater was broader in terms of the number of species consumed. The two species are mouth-brooders with low fecundity. G. feliceps and G. ater produced a mean of 49 and 32 eggs each, per annum. The buccal incubation period was determined to be in the region of 140 days for G. feliceps. Embryos hatched after approximately 75-80 days and the young began exogenous feeding thereafter. The young fed intra-buccally on detritus provided by the parent. Adult buccal mucus may also have been used as a food source. Young were released at a total length of ± 55mm. Adult males ceased feeding whilst mouth-brooding. Body musculature, abdominal fat and liver reserves provided energy for basal metabolism and males lost approximately 28% of their body mass during buccal incubation. Females expended less reproductive energy than males. Catches were dominated by mature fish (76% in G. feliceps and 97% in G. ater). Females were significantly more abundant in catches during the spawning and mouth-brooding period. The female to male sex ratios were 1.65:1 and 2.23:1 for G. feliceps and G. ater respectively. Age and growth studies revealed that the two species mature at advanced ages (10 and 9 years for G. feliceps and 9 and 7 years for G. ater males and females respectively). They are long-lived, reaching ages in excess of 18 years in G. feliceps and in excess of 15 years in G. ater. Females live longer than males and grow larger. Yield-per-recruit and spawner biomass-per-recruit analyses demonstrated that G. ater were exploited below FO.1 at a level where spawner biomass-per-recruit was reduced to between 45% and 65% of the unexploited level. The G. ater stock was not adversely affected by current levels of fishing effort. For G. feliceps, both sexes were exploited beyond F₀.₁ where spawner biomass-per-recruit was reduced to between 30% and 22% of the unexploited level. G. feliceps were shown to be sensitive to relatively low levels of exploitation, a phenomenon attributed to their highly Kselected life-history style. Should the species become targeted for in the future, effort restrictions in the form of a closed season during the spawning and mouth-brooding period would prove effective in reducing effort and conserving the population sex ratio.
- Full Text:
- Date Issued: 1991
The geology, petrology and geochemistry of the mineralization and hydrothermal alteration at Ongeama, Ongombo and Matchless West Extension, Namibia
- Authors: Moroni, Marilena
- Date: 1991
- Subjects: Geology -- Namibia , Petrology -- Namibia , Geochemistry -- Namibia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5045 , http://hdl.handle.net/10962/d1007693 , Geology -- Namibia , Petrology -- Namibia , Geochemistry -- Namibia
- Description: The Matchless Amphibolite Belt (Damara Orogen, Namibia) hosts several volcanogenic-exhalative, sediment-hosted stratiform cupriferous pyrite deposits. These are thought to be related to submarine volcanism during the early evolutionary stages of a narrow Damaran ocean, the Matchless Trough. The mineralized bodies examined (Ongeama, Ongombo and Matchless West Extension) are deformed and metamorphosed to low-medium grade (greenschist-amphibolite facies). They are associated with metapelite and amphibolite country rocks, and crop out as prominent limonite-rich gossans. The elongated shape of the sulphide bodies suggests a structural control. The mineralization normally consists of a variably developed massive sulphide portion, either quartz-, talc- or amphibole-bearing, and a stratigraphically overlying, extensive horizon of sulphide- and baryte-bearing exhalite (magnetite quartzite and less common talc- and actinolite-bearing schists). Lateral and vertical mineralogical changes within the mineralization match with significant variations in the element distribution. A metamorphosed and deformed alteration pipe, indicating the position of the fluid conduit, can be recognized in association with some ore bodies. The formation of quartz-muscovite and chlorite alteration envelopes (Ongeama, Matchless West Extension) and the presence of subtle mineralogical changes (Ongombo) in the immediate wallrocks, accompanied by extensive redistribution, leaching and introduction of elements from outside, suggest the hydrothermal metasomatic origin of the alteration zones. Element zoning within the mineralized bodies can be related to the original position of the vent, possibly coinciding with the intersection of the axis of the alteration pipe with the sulphide body. Cu, Zn, Au (pro parte) and Mo are enriched proximal to the vent, whereas Pb, Ba, Mn, Ag, Au, Sn, Bi and W enrichment characterizes the distal facies of the mineralization. In spite of the obliterating and disrupting effects of the regional dynamo-metamorphism, the element distribution within the mineralization and alteration zones examined is comparable with the geochemical trends observed in present-day mineralizing systems in early- stage oceanic environments (e.g. Guaymas Basin). During exploration for blind volcanogenic mineralization, the detection of hydrothermally altered rocks is fundamental in indicating the proximity to the mineralization. The localization of the alteration zone is also important in the interpretation of the regional geology of the explored area: in deformed terrains the assessment of the stratigraphic position of the alteration zone, relative to the mineralization, helps in establishing the polarity of the sequence.
- Full Text:
- Date Issued: 1991
- Authors: Moroni, Marilena
- Date: 1991
- Subjects: Geology -- Namibia , Petrology -- Namibia , Geochemistry -- Namibia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5045 , http://hdl.handle.net/10962/d1007693 , Geology -- Namibia , Petrology -- Namibia , Geochemistry -- Namibia
- Description: The Matchless Amphibolite Belt (Damara Orogen, Namibia) hosts several volcanogenic-exhalative, sediment-hosted stratiform cupriferous pyrite deposits. These are thought to be related to submarine volcanism during the early evolutionary stages of a narrow Damaran ocean, the Matchless Trough. The mineralized bodies examined (Ongeama, Ongombo and Matchless West Extension) are deformed and metamorphosed to low-medium grade (greenschist-amphibolite facies). They are associated with metapelite and amphibolite country rocks, and crop out as prominent limonite-rich gossans. The elongated shape of the sulphide bodies suggests a structural control. The mineralization normally consists of a variably developed massive sulphide portion, either quartz-, talc- or amphibole-bearing, and a stratigraphically overlying, extensive horizon of sulphide- and baryte-bearing exhalite (magnetite quartzite and less common talc- and actinolite-bearing schists). Lateral and vertical mineralogical changes within the mineralization match with significant variations in the element distribution. A metamorphosed and deformed alteration pipe, indicating the position of the fluid conduit, can be recognized in association with some ore bodies. The formation of quartz-muscovite and chlorite alteration envelopes (Ongeama, Matchless West Extension) and the presence of subtle mineralogical changes (Ongombo) in the immediate wallrocks, accompanied by extensive redistribution, leaching and introduction of elements from outside, suggest the hydrothermal metasomatic origin of the alteration zones. Element zoning within the mineralized bodies can be related to the original position of the vent, possibly coinciding with the intersection of the axis of the alteration pipe with the sulphide body. Cu, Zn, Au (pro parte) and Mo are enriched proximal to the vent, whereas Pb, Ba, Mn, Ag, Au, Sn, Bi and W enrichment characterizes the distal facies of the mineralization. In spite of the obliterating and disrupting effects of the regional dynamo-metamorphism, the element distribution within the mineralization and alteration zones examined is comparable with the geochemical trends observed in present-day mineralizing systems in early- stage oceanic environments (e.g. Guaymas Basin). During exploration for blind volcanogenic mineralization, the detection of hydrothermally altered rocks is fundamental in indicating the proximity to the mineralization. The localization of the alteration zone is also important in the interpretation of the regional geology of the explored area: in deformed terrains the assessment of the stratigraphic position of the alteration zone, relative to the mineralization, helps in establishing the polarity of the sequence.
- Full Text:
- Date Issued: 1991
Studies in asymmetric synthesis
- Authors: Learmonth, Robin Alec
- Date: 1991
- Subjects: Organic compounds -- Synthesis Stereochemistry Organosilicon compounds Chirality Chemical tests and reagents
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4353 , http://hdl.handle.net/10962/d1005018
- Description: The concept of combining two well established areas of organic chemistry, viz., organosilicon chemistry and the use of chiral auxiliaries, into a viable, alternative method of asymmetric synthesis has only very recently begun to receive attention. At the outset of this investigation, no asymmetric reactions of silyl enol ethers, chiral by virtue of optically active substituents on the silicon, had been reported. A range of novel chiral silyl enol ethers have thus been prepared from a variety of ketones, including pinacolone, cyclohexanone, and α-tetralone, and employing menthol, borneol, and cholesterol as chiral auxiliaries. These preparations have been achieved via several distinct routes, including a novel convergent approach involving the isolation of either the chloro(menthyloxy)dimethylsilane or the (bornyloxy)chlorodimethylsilane. The MS and NMR spectra of these silyl enol ethers were examined in detail and, in the case of the crystalline cholesteryloxy silyl enol ether, the X-ray structure has been determined. The potential of chloroalkoxysilanes to act as general, chiral derivatizing agents has been established by the preparation of diastereomeric silyl acetal mixtures of racemic secondary alcohols (e.g. I-phenylethanol and 2-octanol). The experimental diastereomeric ratios, obtained by GLC and ¹H NMR spectroscopy, approached the expected value of unity, confirming the potential of the alkoxychlorosilanes as chiral probes. The chiral silyl enol ethers have been successfully oxidized to the corresponding α-siloxy ketones employing MCPBA, MMPP, and 2-(phenylsulphonyl)-3-phenyloxaziridine as oxidizing agents and the diastereomeric excesses obtained, which varied from 0 to 16%, indicated some potential for stereochemical control. Alkylation and hydroxyalkylation reactions of the silyl enol ethers have yielded the expected α-iert-butyl and β-hydroxy ketones in good to excellent material yields, with the enantiomeric excesses, as determined by chiral shift reagent studies, reaching 14%. To improve the stereo control in these reactions, attempts have been made to prepare chiral silyl enol ethers with auxiliaries possessing the potential for transition state complex co-ordination in the reactions under consideration. The preparation of such silyl enol ethers, incorporating the proline-derived auxiliaries, N-methyl-2-hydroxymethylpyrrolidine and 2-methoxymethylpyrrolidine met with only limited success. In an alternative approach, three derivatives of 2,3-dihydroxybornane have been prepared. However, two of these auxiliaries, viz., 3-exo-benzyloxy-2-exo-hydroxybornane and 3-exo-(1-methoxyethoxy)-2-exo-hydroxybornane failed to form silyl enol ethers, even under considerably more vigorous conditions than normally employed. The third derivative, 3,3-ethylenedioxy-2-hydroxybornane has been successfully utilized in the preparation of a pinacolone-derived chiral silyl enol ether. Hydroxyalkylation of this compound with benzaldehyde has yielded the β-hydroxyketone with significantly improved enantiomeric excess (26%) and a transition state complex has been proposed to rationalize this improvement.
- Full Text:
- Date Issued: 1991
- Authors: Learmonth, Robin Alec
- Date: 1991
- Subjects: Organic compounds -- Synthesis Stereochemistry Organosilicon compounds Chirality Chemical tests and reagents
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4353 , http://hdl.handle.net/10962/d1005018
- Description: The concept of combining two well established areas of organic chemistry, viz., organosilicon chemistry and the use of chiral auxiliaries, into a viable, alternative method of asymmetric synthesis has only very recently begun to receive attention. At the outset of this investigation, no asymmetric reactions of silyl enol ethers, chiral by virtue of optically active substituents on the silicon, had been reported. A range of novel chiral silyl enol ethers have thus been prepared from a variety of ketones, including pinacolone, cyclohexanone, and α-tetralone, and employing menthol, borneol, and cholesterol as chiral auxiliaries. These preparations have been achieved via several distinct routes, including a novel convergent approach involving the isolation of either the chloro(menthyloxy)dimethylsilane or the (bornyloxy)chlorodimethylsilane. The MS and NMR spectra of these silyl enol ethers were examined in detail and, in the case of the crystalline cholesteryloxy silyl enol ether, the X-ray structure has been determined. The potential of chloroalkoxysilanes to act as general, chiral derivatizing agents has been established by the preparation of diastereomeric silyl acetal mixtures of racemic secondary alcohols (e.g. I-phenylethanol and 2-octanol). The experimental diastereomeric ratios, obtained by GLC and ¹H NMR spectroscopy, approached the expected value of unity, confirming the potential of the alkoxychlorosilanes as chiral probes. The chiral silyl enol ethers have been successfully oxidized to the corresponding α-siloxy ketones employing MCPBA, MMPP, and 2-(phenylsulphonyl)-3-phenyloxaziridine as oxidizing agents and the diastereomeric excesses obtained, which varied from 0 to 16%, indicated some potential for stereochemical control. Alkylation and hydroxyalkylation reactions of the silyl enol ethers have yielded the expected α-iert-butyl and β-hydroxy ketones in good to excellent material yields, with the enantiomeric excesses, as determined by chiral shift reagent studies, reaching 14%. To improve the stereo control in these reactions, attempts have been made to prepare chiral silyl enol ethers with auxiliaries possessing the potential for transition state complex co-ordination in the reactions under consideration. The preparation of such silyl enol ethers, incorporating the proline-derived auxiliaries, N-methyl-2-hydroxymethylpyrrolidine and 2-methoxymethylpyrrolidine met with only limited success. In an alternative approach, three derivatives of 2,3-dihydroxybornane have been prepared. However, two of these auxiliaries, viz., 3-exo-benzyloxy-2-exo-hydroxybornane and 3-exo-(1-methoxyethoxy)-2-exo-hydroxybornane failed to form silyl enol ethers, even under considerably more vigorous conditions than normally employed. The third derivative, 3,3-ethylenedioxy-2-hydroxybornane has been successfully utilized in the preparation of a pinacolone-derived chiral silyl enol ether. Hydroxyalkylation of this compound with benzaldehyde has yielded the β-hydroxyketone with significantly improved enantiomeric excess (26%) and a transition state complex has been proposed to rationalize this improvement.
- Full Text:
- Date Issued: 1991
Rhodes University Graduation Ceremony 1991
- Authors: Rhodes University
- Date: 1991
- Subjects: Relly, Gavin Walter Hamilton
- Language: English
- Type: text
- Identifier: vital:8125 , http://hdl.handle.net/10962/d1006750 , Relly, Gavin Walter Hamilton
- Description: Rhodes University Graduation Ceremonies Friday, 12 April 1991 at 8 p.m. [and] Saturday, 13 April 1991 at 10 a.m. in the 1820 Settlers National Monument. , Rhodes University East London Graduation Ceremony Saturday, 18 May 1991 at 10.00 a.m. in the Guild Theatre. , The Installation of Gavin Walter Hamilton Relly as Chancellor of Rhodes University to be followed by a Graduation Ceremony Friday, 12 April 1991 at 10 a.m. in the 1820 Settlers National Monument.
- Full Text:
- Date Issued: 1991
- Authors: Rhodes University
- Date: 1991
- Subjects: Relly, Gavin Walter Hamilton
- Language: English
- Type: text
- Identifier: vital:8125 , http://hdl.handle.net/10962/d1006750 , Relly, Gavin Walter Hamilton
- Description: Rhodes University Graduation Ceremonies Friday, 12 April 1991 at 8 p.m. [and] Saturday, 13 April 1991 at 10 a.m. in the 1820 Settlers National Monument. , Rhodes University East London Graduation Ceremony Saturday, 18 May 1991 at 10.00 a.m. in the Guild Theatre. , The Installation of Gavin Walter Hamilton Relly as Chancellor of Rhodes University to be followed by a Graduation Ceremony Friday, 12 April 1991 at 10 a.m. in the 1820 Settlers National Monument.
- Full Text:
- Date Issued: 1991
The distribution patterns and community structure of the Tsitsikamma rocky littoral ichthyofauna
- Authors: Burger, Lynton Francois
- Date: 1991
- Subjects: Fishes -- South Africa -- Geographical distribution , Tripterygiidae -- South Africa -- Geographical distribution , Littoral plants -- South Africa -- Tsitsikamma , Littoral plants
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5260 , http://hdl.handle.net/10962/d1005104 , Fishes -- South Africa -- Geographical distribution , Tripterygiidae -- South Africa -- Geographical distribution , Littoral plants -- South Africa -- Tsitsikamma , Littoral plants
- Description: The results of a community survey of the rocky intertidal and subtidal reef ichthyofauna of the Tsitsikamma National Park and adjacent areas are presented. An updated species checklist is given, comprising 116 species of 46 families, including a new genus and species of Tripterygiid. Single species are shown to dominate, in terms of numbers, both the cryptic and subtidal components for all the areas sampled down the vertical profile. Species richness, evenness and diversity are found to increase with depth for both the cryptic and suprabenthic components. A community level feeding study shows an increase in trophic specialisation with depth and food availability is found to be an important factor delimiting littoral fish vertical distribution. The nursery function of the Tsitsikamma rocky littoral area is assessed and it is shown that shallow littoral areas as a whole are more important than intertidal pools alone in functioning as nurseries. The results of the study are found to fit into the existing trend of an increase in species richness and diversity, from west to east, along the South African coast. A significant difference is shown between the observed frequencies of species on exploited reefs outside the Park and unexploited reefs inside the Park. The density of the key reef predator Petrus rupestris is shown to be nine times more abundant on deep reef inside the park compared to deep reef outside the park (0.0045 fish/m² and 0.0005 fish/m² respectively) and a paucity of larger individuals of this species on exploited reefs is noted. Marked differences in the relative abundance of other species between exploited and unexploited reefs are evident and it is hypothesised that community disruption has occurred on exploited reefs, either directly or indirectly because of the removal of P. rupestris. These results are discussed in the context of marine reserves as a conservation strategy and a recommendation is made to extend the 5.6km seaward boundary of the Tsitsikamma National Park westwards to include the large concentration of presently exploited rocky reefs between the Blaaukrans river mouth and Natures Valley.
- Full Text:
- Date Issued: 1991
- Authors: Burger, Lynton Francois
- Date: 1991
- Subjects: Fishes -- South Africa -- Geographical distribution , Tripterygiidae -- South Africa -- Geographical distribution , Littoral plants -- South Africa -- Tsitsikamma , Littoral plants
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5260 , http://hdl.handle.net/10962/d1005104 , Fishes -- South Africa -- Geographical distribution , Tripterygiidae -- South Africa -- Geographical distribution , Littoral plants -- South Africa -- Tsitsikamma , Littoral plants
- Description: The results of a community survey of the rocky intertidal and subtidal reef ichthyofauna of the Tsitsikamma National Park and adjacent areas are presented. An updated species checklist is given, comprising 116 species of 46 families, including a new genus and species of Tripterygiid. Single species are shown to dominate, in terms of numbers, both the cryptic and subtidal components for all the areas sampled down the vertical profile. Species richness, evenness and diversity are found to increase with depth for both the cryptic and suprabenthic components. A community level feeding study shows an increase in trophic specialisation with depth and food availability is found to be an important factor delimiting littoral fish vertical distribution. The nursery function of the Tsitsikamma rocky littoral area is assessed and it is shown that shallow littoral areas as a whole are more important than intertidal pools alone in functioning as nurseries. The results of the study are found to fit into the existing trend of an increase in species richness and diversity, from west to east, along the South African coast. A significant difference is shown between the observed frequencies of species on exploited reefs outside the Park and unexploited reefs inside the Park. The density of the key reef predator Petrus rupestris is shown to be nine times more abundant on deep reef inside the park compared to deep reef outside the park (0.0045 fish/m² and 0.0005 fish/m² respectively) and a paucity of larger individuals of this species on exploited reefs is noted. Marked differences in the relative abundance of other species between exploited and unexploited reefs are evident and it is hypothesised that community disruption has occurred on exploited reefs, either directly or indirectly because of the removal of P. rupestris. These results are discussed in the context of marine reserves as a conservation strategy and a recommendation is made to extend the 5.6km seaward boundary of the Tsitsikamma National Park westwards to include the large concentration of presently exploited rocky reefs between the Blaaukrans river mouth and Natures Valley.
- Full Text:
- Date Issued: 1991
Chemical studies of 1,5-benzodioxepanones
- Authors: Gelebe, Aifheli Carlson
- Date: 1991
- Subjects: Biochemistry , Pigments (Biology) , Benzopyrans
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4423 , http://hdl.handle.net/10962/d1006895 , Biochemistry , Pigments (Biology) , Benzopyrans
- Description: Chromone and flavanone derivatives were prepared by condensation of the corresponding 2-hydroxyacetophenones (with diethyl oxalate or the appropriate aromatic aldehyde respectively) and cyclisation of the condensation products. Saeyer-Villiger rearrangement of these flavanones, with MCPBA, resulted in expansion of the C-ring. Spectroscopic techniques have been used to establish the regioselectivity of the rearrangement and hence, the identity of the rearranged products as 1,5-benzodioxepan-4-ones. The 1,5-benzodioxepan-4-ones were subjected to detailed ¹H and ¹³C n.m.r. analysis and a combination of low and high resolution mass spectrometry has been used to study the mass fragmentation pathways of these ring-expanded products.
- Full Text:
- Date Issued: 1991
- Authors: Gelebe, Aifheli Carlson
- Date: 1991
- Subjects: Biochemistry , Pigments (Biology) , Benzopyrans
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4423 , http://hdl.handle.net/10962/d1006895 , Biochemistry , Pigments (Biology) , Benzopyrans
- Description: Chromone and flavanone derivatives were prepared by condensation of the corresponding 2-hydroxyacetophenones (with diethyl oxalate or the appropriate aromatic aldehyde respectively) and cyclisation of the condensation products. Saeyer-Villiger rearrangement of these flavanones, with MCPBA, resulted in expansion of the C-ring. Spectroscopic techniques have been used to establish the regioselectivity of the rearrangement and hence, the identity of the rearranged products as 1,5-benzodioxepan-4-ones. The 1,5-benzodioxepan-4-ones were subjected to detailed ¹H and ¹³C n.m.r. analysis and a combination of low and high resolution mass spectrometry has been used to study the mass fragmentation pathways of these ring-expanded products.
- Full Text:
- Date Issued: 1991
Structural studies on the capsular antigens of Escherichia coli serotypes K102 and K47
- Authors: De Bruin, Aletta Hester
- Date: 1991
- Subjects: Escherichia -- Research , Klebsiella -- Research , Enterobacteriaceae -- Research , Antigens -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3754 , http://hdl.handle.net/10962/d1003232 , Escherichia -- Research , Klebsiella -- Research , Enterobacteriaceae -- Research , Antigens -- Research
- Description: The work presented in this thesis forms part of a continuing programme concerned with the structural determination of capsular polysaccharides of some Enterobacteriaceae. Since bacteria of this family are pathogenic to Man, work in this laboratory has focused on the structural elucidation of Klebsiella and, more recently, Escherichia coli ( E. coli) capsular polysaccharides ( K-antigens ). To date, some 74 K-antigens have been distinguished serologically within the genus E. coli and the structures of approximately 70% are known. In general, the K-antigens of the E. coli are characterized by a wide variety of constituent monosaccharides arranged in repeating units. In this thesis the structural elucidation of the capsular polysaccharides of E. coli serotypes 08: KI02: H- and 08: K47: H2 is presented. A variety of chemical techniques has been employed in the structural analysis, and are discussed. The thesis also includes extensive two-dimensional n.m.r. studies on the E. coli KI02 and K47 polysaccharides, as well as on a modified KI02 polymer produced after a lithium-ethylenediamine degradation of the native polysaccharide.
- Full Text:
- Date Issued: 1991
- Authors: De Bruin, Aletta Hester
- Date: 1991
- Subjects: Escherichia -- Research , Klebsiella -- Research , Enterobacteriaceae -- Research , Antigens -- Research
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3754 , http://hdl.handle.net/10962/d1003232 , Escherichia -- Research , Klebsiella -- Research , Enterobacteriaceae -- Research , Antigens -- Research
- Description: The work presented in this thesis forms part of a continuing programme concerned with the structural determination of capsular polysaccharides of some Enterobacteriaceae. Since bacteria of this family are pathogenic to Man, work in this laboratory has focused on the structural elucidation of Klebsiella and, more recently, Escherichia coli ( E. coli) capsular polysaccharides ( K-antigens ). To date, some 74 K-antigens have been distinguished serologically within the genus E. coli and the structures of approximately 70% are known. In general, the K-antigens of the E. coli are characterized by a wide variety of constituent monosaccharides arranged in repeating units. In this thesis the structural elucidation of the capsular polysaccharides of E. coli serotypes 08: KI02: H- and 08: K47: H2 is presented. A variety of chemical techniques has been employed in the structural analysis, and are discussed. The thesis also includes extensive two-dimensional n.m.r. studies on the E. coli KI02 and K47 polysaccharides, as well as on a modified KI02 polymer produced after a lithium-ethylenediamine degradation of the native polysaccharide.
- Full Text:
- Date Issued: 1991
Environmental and socio-economic effects associated with the planting of Atriplex nummularia Lindl. (Oldman saltbush) in the Karoo
- Authors: Hobson, Colin Desmond
- Date: 1991
- Subjects: Botany, Economic Plant introduction -- South Africa -- Karoo Plants, Cultivated
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: vital:4794 , http://hdl.handle.net/10962/d1001894
- Description: This study examines the environmental and socio-economic effects associated with the planting of Atriplex nummularia Lindl. (Oldman saltbush) in the karoo. This is the first study of its kind on oldman saltbush and serves as an important scoping exercise in assessing the impact of saltbush on its surrounds and in identifying additional aspects which require investigation. The environmental parameters investigated include microclimatic effects, soil induced changes, salinity effects on the germination of selected karoo species and compositional changes in the indigenous plant community within a saltbush plantation. When compared to indigenous karoo plant species oldman saltbush is found to ameliorate soil temperatures and increase surface soil salinity (specifically sodium chloride), on an individual plant basis. Salinity is shown to have a differential effect on the germination of selected karoo shrubs. The indigenous plant community within a forty year old saltbush plantation is impoverished with both density of individuals and species richness being markedly reduced. Saltbush is identified as an unsuitable nurse plant for the majority of karoo shrubs. Farm size in relation to both actual and intended area established to saltbush is considered. The area of saltbush already established in the karoo is considered too insignificant to have any wide socio-economic impact. Farmers who intend planting large areas of their farms to saltbush are in the minority. It is those farmers who already have some saltbush planted, who intend planting more. Ecologically based management guidelines are presented, suggesting practices which minimize the detrimental effects of saltbush on soil salinity and the indigenous plant community. These guidelines are practical and in keeping with the overall objectives of optimum resource utilisation and the national grazing strategy for South Africa.
- Full Text:
- Date Issued: 1991
- Authors: Hobson, Colin Desmond
- Date: 1991
- Subjects: Botany, Economic Plant introduction -- South Africa -- Karoo Plants, Cultivated
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: vital:4794 , http://hdl.handle.net/10962/d1001894
- Description: This study examines the environmental and socio-economic effects associated with the planting of Atriplex nummularia Lindl. (Oldman saltbush) in the karoo. This is the first study of its kind on oldman saltbush and serves as an important scoping exercise in assessing the impact of saltbush on its surrounds and in identifying additional aspects which require investigation. The environmental parameters investigated include microclimatic effects, soil induced changes, salinity effects on the germination of selected karoo species and compositional changes in the indigenous plant community within a saltbush plantation. When compared to indigenous karoo plant species oldman saltbush is found to ameliorate soil temperatures and increase surface soil salinity (specifically sodium chloride), on an individual plant basis. Salinity is shown to have a differential effect on the germination of selected karoo shrubs. The indigenous plant community within a forty year old saltbush plantation is impoverished with both density of individuals and species richness being markedly reduced. Saltbush is identified as an unsuitable nurse plant for the majority of karoo shrubs. Farm size in relation to both actual and intended area established to saltbush is considered. The area of saltbush already established in the karoo is considered too insignificant to have any wide socio-economic impact. Farmers who intend planting large areas of their farms to saltbush are in the minority. It is those farmers who already have some saltbush planted, who intend planting more. Ecologically based management guidelines are presented, suggesting practices which minimize the detrimental effects of saltbush on soil salinity and the indigenous plant community. These guidelines are practical and in keeping with the overall objectives of optimum resource utilisation and the national grazing strategy for South Africa.
- Full Text:
- Date Issued: 1991
Environmental and socio-economic effects associated with the planting of Atriplex nummularia Lindl. (Oldman saltbush) in the Karoo
- Authors: Hobson, Colin Desmond
- Date: 1991
- Subjects: Botany, Economic Plant introduction -- South Africa -- Karoo Plants, Cultivated
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: vital:4175 , http://hdl.handle.net/10962/d1002023
- Description: This study examines the environmental and socio-economic effects associated with the planting of Atriplex nummularia Lindl. (Oldman saltbush) in the karoo. This is the first study of its kind on oldman saltbush and serves as an important scoping exercise in assessing the impact of saltbush on its surrounds and in identifying additional aspects which require investigation. The environmental parameters investigated include microclimatic effects, soil induced changes, salinity effects on the germination of selected karoo species and compositional changes in the indigenous plant community within a saltbush plantation. When compared to indigenous karoo plant species oldman saltbush is found to ameliorate soil temperatures and increase surface soil salinity (specifically sodium chloride), on an individual plant basis. Salinity is shown to have a differential effect on the germination of selected karoo shrubs. The indigenous plant community within a forty year old saltbush plantation is impoverished with both density of individuals and species richness being markedly reduced. Saltbush is identified as an unsuitable nurse plant for the majority of karoo shrubs. Farm size in relation to both actual and intended area established to saltbush is considered. The area of saltbush already established in the karoo is considered too insignificant to have any wide socio-economic impact. Farmers who intend planting large areas of their farms to saltbush are in the minority. It is those farmers who already have some saltbush planted, who intend planting more. Ecologically based management guidelines are presented, suggesting practices which minimize the detrimental effects of saltbush on soil salinity and the indigenous plant community. These guidelines are practical and in keeping with the overall objectives of optimum resource utilisation and the national grazing strategy for South Africa.
- Full Text:
- Date Issued: 1991
- Authors: Hobson, Colin Desmond
- Date: 1991
- Subjects: Botany, Economic Plant introduction -- South Africa -- Karoo Plants, Cultivated
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: vital:4175 , http://hdl.handle.net/10962/d1002023
- Description: This study examines the environmental and socio-economic effects associated with the planting of Atriplex nummularia Lindl. (Oldman saltbush) in the karoo. This is the first study of its kind on oldman saltbush and serves as an important scoping exercise in assessing the impact of saltbush on its surrounds and in identifying additional aspects which require investigation. The environmental parameters investigated include microclimatic effects, soil induced changes, salinity effects on the germination of selected karoo species and compositional changes in the indigenous plant community within a saltbush plantation. When compared to indigenous karoo plant species oldman saltbush is found to ameliorate soil temperatures and increase surface soil salinity (specifically sodium chloride), on an individual plant basis. Salinity is shown to have a differential effect on the germination of selected karoo shrubs. The indigenous plant community within a forty year old saltbush plantation is impoverished with both density of individuals and species richness being markedly reduced. Saltbush is identified as an unsuitable nurse plant for the majority of karoo shrubs. Farm size in relation to both actual and intended area established to saltbush is considered. The area of saltbush already established in the karoo is considered too insignificant to have any wide socio-economic impact. Farmers who intend planting large areas of their farms to saltbush are in the minority. It is those farmers who already have some saltbush planted, who intend planting more. Ecologically based management guidelines are presented, suggesting practices which minimize the detrimental effects of saltbush on soil salinity and the indigenous plant community. These guidelines are practical and in keeping with the overall objectives of optimum resource utilisation and the national grazing strategy for South Africa.
- Full Text:
- Date Issued: 1991
Synthesis and interaction of secondary N-nitrosamines with acetylcholinesterase
- Authors: Mmutle, Tsietso Bernard
- Date: 1991
- Subjects: Chemistry, Physical and theoretical , Enzyme kinetics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4058 , http://hdl.handle.net/10962/d1004119 , Chemistry, Physical and theoretical , Enzyme kinetics
- Description: Secondary N-nitrosamines: diphenylnitrosamine (DPhNA), dimethylnitrosamine (DMNA), diethylnitrosamine (DENA), dipropylnitrosamine (DPNA), dibutylnitrosamine (DBNA), diethanolnitrosamine (DEtNA), methylnitrosoglycine (MNGly), nitrosopyrrolidine (NPyr), nitrosomorpholine (NMor) and nitrosopiperidine (NPip) were synthesised and their interaction with acetylcholinesterase (AChE) was investigated. Analyses of kinetic results show that DMNA (Ki=34.78 μM); DENA (Ki=54.24 μM); DPNA(Ki=60.36 μM); DBNA(Ki=95.54 μM); DEtNA(Ki=43.68 μM)MNGly (Ki=30.18 μM); NPip (Ki=123 μM); NPyr (Ki=66.07 μM), NMor (Ki=73.93 μM) and DPhNA (Ki=20.32 μM) are competitive and reversible inhibitors of acetylcholinesterase, with respect to the substrate, acetylthiocholine chloride, ATChCl. With time they act as irreversible covalent inhibitors with dipropy1nitrosamine producing 72% inactivation after 60 minutes. Scatchard analyses of f1uorometric titrations, (Kd=0.75mM-4.09mM); gel chromatography (Kd=O. 80mM-4. 60mM) and equilibrium dia1ysis (Kd=O. 71mM- 4.21mM) for MNG1y, DMNA, DEtNA, DENA, DPNA, NPyr, DSNA, NMor and NPip show that these compounds have weaker affinity for the enzyme, as compared to the much tightly binding aromatic DPhNA, Kd values (0.65mM, 0.68mM and 0.68mM) for fluorometric experiments, gel chromatography and equilibrium dialysis respectively. In all cases, the number of binding sites of acetylcholinesterase averaged to four.
- Full Text:
- Date Issued: 1991
- Authors: Mmutle, Tsietso Bernard
- Date: 1991
- Subjects: Chemistry, Physical and theoretical , Enzyme kinetics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4058 , http://hdl.handle.net/10962/d1004119 , Chemistry, Physical and theoretical , Enzyme kinetics
- Description: Secondary N-nitrosamines: diphenylnitrosamine (DPhNA), dimethylnitrosamine (DMNA), diethylnitrosamine (DENA), dipropylnitrosamine (DPNA), dibutylnitrosamine (DBNA), diethanolnitrosamine (DEtNA), methylnitrosoglycine (MNGly), nitrosopyrrolidine (NPyr), nitrosomorpholine (NMor) and nitrosopiperidine (NPip) were synthesised and their interaction with acetylcholinesterase (AChE) was investigated. Analyses of kinetic results show that DMNA (Ki=34.78 μM); DENA (Ki=54.24 μM); DPNA(Ki=60.36 μM); DBNA(Ki=95.54 μM); DEtNA(Ki=43.68 μM)MNGly (Ki=30.18 μM); NPip (Ki=123 μM); NPyr (Ki=66.07 μM), NMor (Ki=73.93 μM) and DPhNA (Ki=20.32 μM) are competitive and reversible inhibitors of acetylcholinesterase, with respect to the substrate, acetylthiocholine chloride, ATChCl. With time they act as irreversible covalent inhibitors with dipropy1nitrosamine producing 72% inactivation after 60 minutes. Scatchard analyses of f1uorometric titrations, (Kd=0.75mM-4.09mM); gel chromatography (Kd=O. 80mM-4. 60mM) and equilibrium dia1ysis (Kd=O. 71mM- 4.21mM) for MNG1y, DMNA, DEtNA, DENA, DPNA, NPyr, DSNA, NMor and NPip show that these compounds have weaker affinity for the enzyme, as compared to the much tightly binding aromatic DPhNA, Kd values (0.65mM, 0.68mM and 0.68mM) for fluorometric experiments, gel chromatography and equilibrium dialysis respectively. In all cases, the number of binding sites of acetylcholinesterase averaged to four.
- Full Text:
- Date Issued: 1991
An investigation of the interrelationship between group commitment, religiosity, marital adjustment and attitude to divorce in the Jewish ethnic group
- Authors: Miller, Bernice
- Date: 1991
- Subjects: Jews -- Psychology , Judaism , Jews -- Attitudes , Ethnicity , Marriage (Jewish law) , Divorce (Jewish law)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3019 , http://hdl.handle.net/10962/d1002528 , Jews -- Psychology , Judaism , Jews -- Attitudes , Ethnicity , Marriage (Jewish law) , Divorce (Jewish law)
- Description: The purpose of this research was to investigate the interrelationships between marital adjustment, group commitment, religiosity and attitude to divorce in the Jewish group. It amounted to a within group empirical study of the Jewish community of Cape Town. Research, to date, has focused on marital stability where researchers have found that Jews have lower divorce rates than the general population. The present study attempted to assess the psycho-social outcomes of group commitment in the form of marital adjustment, thus bridging the gap between marital quality and marital stability in the Jewish group. On a wider level, the purpose of this research was to assess whether a social structural framework, utilizing the concept of social integration, is a perspective that can be used in explaining variations in marital adjustment. The following were the findings of the research : Religiosity was correlated to group commitment but not to marital adjustment; group commitment was correlated to marital adjustment; a negative attitude to divorce was not correlated to marital adjustment, group commitment or religiosity.
- Full Text:
- Date Issued: 1991
- Authors: Miller, Bernice
- Date: 1991
- Subjects: Jews -- Psychology , Judaism , Jews -- Attitudes , Ethnicity , Marriage (Jewish law) , Divorce (Jewish law)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3019 , http://hdl.handle.net/10962/d1002528 , Jews -- Psychology , Judaism , Jews -- Attitudes , Ethnicity , Marriage (Jewish law) , Divorce (Jewish law)
- Description: The purpose of this research was to investigate the interrelationships between marital adjustment, group commitment, religiosity and attitude to divorce in the Jewish group. It amounted to a within group empirical study of the Jewish community of Cape Town. Research, to date, has focused on marital stability where researchers have found that Jews have lower divorce rates than the general population. The present study attempted to assess the psycho-social outcomes of group commitment in the form of marital adjustment, thus bridging the gap between marital quality and marital stability in the Jewish group. On a wider level, the purpose of this research was to assess whether a social structural framework, utilizing the concept of social integration, is a perspective that can be used in explaining variations in marital adjustment. The following were the findings of the research : Religiosity was correlated to group commitment but not to marital adjustment; group commitment was correlated to marital adjustment; a negative attitude to divorce was not correlated to marital adjustment, group commitment or religiosity.
- Full Text:
- Date Issued: 1991
Sir Godfrey Lagden : colonial administrator
- Authors: Burton, David Raymond
- Date: 1991
- Subjects: Lagden, Godfrey Yeatman, Sir, 1851-1934 South Africa -- History -- 1836-1909
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2519 , http://hdl.handle.net/10962/d1001848
- Description: The thesis attempts to provide a chronological analysis of Lagden's colonial career between 1877 and 1907. The youngest son of a parish priest, Lagden received limited formal education and no military training. By a fortuitous set of circumstances, he was able, as a man on the spot, to attain high ranking posts in colonial administration. As a young man, he acquired considerable experience in the Transvaal, Egypt and the Gold Coast. However, blatant disobedience led to his dismissal from Colonial service. Fortunately for Lagden, Marshal Clarke, newly appointed Resident Commissioner of Basutoland, insisted on Lagden being appointed to his staff. Except for a brief stint in Swaziland, Lagden remained in Basutoland until 1900. With Clarke, Lagden played a prominent role in the implementation of the Imperial policy of securing the support of the Koena chiefs by allowing them to retain and consolidate their power and influence. Lagden became Resident Commissioner in Basutoland when Clarke was transferred to Zululand. He continued established policies and championed the Basotho cause by opposing the opening of Basutoland to prospectors and by stressing the industrious habits of the Basotho. His tactful and energetic handling of the rinderpest crisis reduced dramatic repercussions amongst the Basotho and enabled cooperative Koena chiefs to increase their economic and political leverage. Despite his reservations over Basotho loyalty, Lagden emerged from the South African War with an enhanced reputation as the Basotho remained loyal and energetically participated in the Imperial war effort. Largely because of his Basutoland experience, Lagden was appointed the Transvaal Commissioner of Native Affairs in 1901. He was responsible for regulating African labour supplies for the mines and delineation of African locations. His failure to procure sufficient labour and his defence of African rights earned Lagden much abusive settler condemnation. As chairman of the South African Native Affairs Commission, Lagden produced an uninspiring report conditioned by the labour shortage and his personal distaste for decisive action. Nevertheless, its advocacy of political and territorial segregation influenced successive Union governments.
- Full Text:
- Date Issued: 1991
- Authors: Burton, David Raymond
- Date: 1991
- Subjects: Lagden, Godfrey Yeatman, Sir, 1851-1934 South Africa -- History -- 1836-1909
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2519 , http://hdl.handle.net/10962/d1001848
- Description: The thesis attempts to provide a chronological analysis of Lagden's colonial career between 1877 and 1907. The youngest son of a parish priest, Lagden received limited formal education and no military training. By a fortuitous set of circumstances, he was able, as a man on the spot, to attain high ranking posts in colonial administration. As a young man, he acquired considerable experience in the Transvaal, Egypt and the Gold Coast. However, blatant disobedience led to his dismissal from Colonial service. Fortunately for Lagden, Marshal Clarke, newly appointed Resident Commissioner of Basutoland, insisted on Lagden being appointed to his staff. Except for a brief stint in Swaziland, Lagden remained in Basutoland until 1900. With Clarke, Lagden played a prominent role in the implementation of the Imperial policy of securing the support of the Koena chiefs by allowing them to retain and consolidate their power and influence. Lagden became Resident Commissioner in Basutoland when Clarke was transferred to Zululand. He continued established policies and championed the Basotho cause by opposing the opening of Basutoland to prospectors and by stressing the industrious habits of the Basotho. His tactful and energetic handling of the rinderpest crisis reduced dramatic repercussions amongst the Basotho and enabled cooperative Koena chiefs to increase their economic and political leverage. Despite his reservations over Basotho loyalty, Lagden emerged from the South African War with an enhanced reputation as the Basotho remained loyal and energetically participated in the Imperial war effort. Largely because of his Basutoland experience, Lagden was appointed the Transvaal Commissioner of Native Affairs in 1901. He was responsible for regulating African labour supplies for the mines and delineation of African locations. His failure to procure sufficient labour and his defence of African rights earned Lagden much abusive settler condemnation. As chairman of the South African Native Affairs Commission, Lagden produced an uninspiring report conditioned by the labour shortage and his personal distaste for decisive action. Nevertheless, its advocacy of political and territorial segregation influenced successive Union governments.
- Full Text:
- Date Issued: 1991
Environmental education : a quest for the future : inaugural lecture delivered at Rhodes University
- Irwin, P.R. (Patrick Roger), 1944-
- Authors: Irwin, P.R. (Patrick Roger), 1944-
- Date: 1991
- Subjects: Environmental education
- Language: English
- Type: Text
- Identifier: vital:640 , http://hdl.handle.net/10962/d1020709 , ISBN 0686102148
- Description: Inaugural lecture delivered at Rhodes University , Rhodes University Libraries (Digitisation)
- Full Text:
- Date Issued: 1991
- Authors: Irwin, P.R. (Patrick Roger), 1944-
- Date: 1991
- Subjects: Environmental education
- Language: English
- Type: Text
- Identifier: vital:640 , http://hdl.handle.net/10962/d1020709 , ISBN 0686102148
- Description: Inaugural lecture delivered at Rhodes University , Rhodes University Libraries (Digitisation)
- Full Text:
- Date Issued: 1991
An investigation of the romantic ballet in its sociocultural context in Paris and London, 1830 to 1850
- Authors: Osborne, Jane
- Date: 1991
- Subjects: Ballet -- France -- Paris , Ballet -- England -- London , Ballet -- History -- 19th century , Ballet -- Sociological aspects
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:2126 , http://hdl.handle.net/10962/d1002028
- Description: Historians have made a considerable contribution to the study of the Romantic ballet in terms of chronological development, the Romantic movement in the arts and the contribution of specific dancers and choreographers; very little research has been attempted to date on the interrelationship between the dance form and the wide range of human experience of the period. This holistic approach provides insight into form, content and stagecraft; political, economic and social influences; the prevailing artistic aesthetic and cultural climate; sex, gender and class issues; and the priorities, value system and nuances of the times. Recent work by historians and social scientists (eg Brinson 1981, Adshead 1983, Spencer 1985, Hanna 1988, Garafola 1989) advocates a recognition of the role of social and cultural systems in the evaluation of dance. This approach further ackowledges the equal status of all cultures, and has opened up areas of African performing dance in cultural systems outside the west. My parallel investigation of the gumboot dance in its South African context, which appears in Appendix B, provides an example. The first half of the nineteenth century was characterized by the disruptive beginnings of the emergent industrial world, centred in Paris and London; and the Romantic ballet tradition reached its greatest heights at this time. Chapter one establishes the political, economic, social and artistic environment, and identifies middle class dominance as a key factor. Chapters two and three focus primarily on the three great ballets of the age, La Sylphide, 1832, Giselie, 1841, and Pas de Quatre, 1845, as expressions of the essential duality of the times, and of Romantic synaesthesia in the arts, which enabled them to transcend the pedestrian bourgeois materialism of faciliatators and audience. Chapter four examines the images of the idealized ballerina and the 'Victorian' middle class woman in relation to bourgeois male attitudes to female sexuality, gender and class. The conclusion sums up the themes of duality, middle class influence, and the Romantic aesthetic, and discusses the prevalent notion that this period was identified as a 'golden age' of the Romantic ballet.
- Full Text:
- Date Issued: 1991
- Authors: Osborne, Jane
- Date: 1991
- Subjects: Ballet -- France -- Paris , Ballet -- England -- London , Ballet -- History -- 19th century , Ballet -- Sociological aspects
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:2126 , http://hdl.handle.net/10962/d1002028
- Description: Historians have made a considerable contribution to the study of the Romantic ballet in terms of chronological development, the Romantic movement in the arts and the contribution of specific dancers and choreographers; very little research has been attempted to date on the interrelationship between the dance form and the wide range of human experience of the period. This holistic approach provides insight into form, content and stagecraft; political, economic and social influences; the prevailing artistic aesthetic and cultural climate; sex, gender and class issues; and the priorities, value system and nuances of the times. Recent work by historians and social scientists (eg Brinson 1981, Adshead 1983, Spencer 1985, Hanna 1988, Garafola 1989) advocates a recognition of the role of social and cultural systems in the evaluation of dance. This approach further ackowledges the equal status of all cultures, and has opened up areas of African performing dance in cultural systems outside the west. My parallel investigation of the gumboot dance in its South African context, which appears in Appendix B, provides an example. The first half of the nineteenth century was characterized by the disruptive beginnings of the emergent industrial world, centred in Paris and London; and the Romantic ballet tradition reached its greatest heights at this time. Chapter one establishes the political, economic, social and artistic environment, and identifies middle class dominance as a key factor. Chapters two and three focus primarily on the three great ballets of the age, La Sylphide, 1832, Giselie, 1841, and Pas de Quatre, 1845, as expressions of the essential duality of the times, and of Romantic synaesthesia in the arts, which enabled them to transcend the pedestrian bourgeois materialism of faciliatators and audience. Chapter four examines the images of the idealized ballerina and the 'Victorian' middle class woman in relation to bourgeois male attitudes to female sexuality, gender and class. The conclusion sums up the themes of duality, middle class influence, and the Romantic aesthetic, and discusses the prevalent notion that this period was identified as a 'golden age' of the Romantic ballet.
- Full Text:
- Date Issued: 1991
Cecil Rhodes, the Glen Grey Act, and the labour question in the politics of the Cape Colony
- Authors: Thompson, Richard James
- Date: 1991
- Subjects: Rhodes, Cecil, 1853-1902 Labor policy -- South Africa -- History Labor supply -- South Africa -- History Black people -- Employment -- South Africa -- History Cape of Good Hope (South Africa) -- History -- 1872-1910 Cape of Good Hope (South Africa) -- Politics and government -- 1872-1910
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2562 , http://hdl.handle.net/10962/d1002415
- Description: Chapter One: The provisions of the Glen Grey Act of 1894 are summarised. The memoirs of contemporaries are discussed and the historical literature on the Act from 1913 to the present is surveyed. The likelihood of the land tenure provisions of the Act forcing the people of Glen Grey (or the people of other districts that came under the operation of the Act) to seek employment is noted. It is evident that there is an increasing emphasis in the literature on labour concerns rather than on the disenfranchising effects and local government provisions of the Act. It is often assumed that the labour force generated by the Act was meant for the Transvaal gold mines. Chapter Two: The relevance of the labour needs of the Indwe collieries is investigated. These mines lay adjacent to Glen Grey and might have been expected to draw their labour thence if the Act had been effective. Rhodes, the author of the Act and prime minister of the Cape, had bought shares in the collieries for De Beers shortly before the Act was passed, which made a possible connection more intriguing. No causal link between De Beers' interests and the Act could be demonstrated; nor do the collieries seem to have employed many people from Glen Grey. Chapter Three: Examines the Cape colonists' complaints about shortage of labour from 1807 to the eve of the Glen Grey Act, and investigates various official measures to promote the labour supply. The Glen Grey Act was not the first labour measure passed at the Cape, and it seems likely, therefore, that the labour needs of the Cape, rather than the Transvaal, were uppermost in the minds of those responsible for the Act. Chapter Four examines Rhodes's political position in the 1890s and shows him to be increasingly dependent on the parliamentary support of the Afrikaner Bond to stay in office. Since the Bond was an agricultural interest group it seems likely that labour for Cape farms, rather than Transvaal gold mines, was what the Act was supposed to provide. With that Rhodes could readily agree, since he wanted to promote the agricultural development of the Cape. However, the Bond wanted to be able to buy land in Glen Grey (and other district in which the Act was proclaimed). Rhodes wanted to keep such districts as 'reservoirs of labour' so he could not give the Bond all of what they wanted, i.e. Glen Grey titles to be alienable. His manoeuvring to keep the Bond supporting the Bill while not making the land readily salable is described. (In the end the land was alienable with the consent of the government -- consent that a Rhodes ministry would not give, but that another might.) Rhodes's desire to obtain the administration of Bechuanaland for his Chartered Company, and his need therefore to reassure the Colonial Office and humanitarian opinion that he could be trusted to rule over blacks, are pointed out as other possible motivations for the Act, which Rhodes tried hard to present as an enlightened piece of legislation. The course of the Act through the Cape parliament, and the opposition of Cape liberals to the Act, is described. Chapter Five: The mentalité of the Cape colonists as regards race, liquor, land tenure and other political issues is described. Chapter Six: The reaction to the Act of Cape blacks and sympathetic whites, British humanitarians and the Colonial Office is described. The contemporary concern with reserving land for blacks is noted, as well as concern over the morality of economically coerced labour. This is in contrast to the modern concentration on labour almost to the exclusion of other issues in regard to the Glen Grey Act. The unsuccessful efforts of Cape blacks and British humanitarians to have the imperial government veto the Act are described. Rhodes's influence over the Colonial Office is described.
- Full Text:
- Date Issued: 1991
- Authors: Thompson, Richard James
- Date: 1991
- Subjects: Rhodes, Cecil, 1853-1902 Labor policy -- South Africa -- History Labor supply -- South Africa -- History Black people -- Employment -- South Africa -- History Cape of Good Hope (South Africa) -- History -- 1872-1910 Cape of Good Hope (South Africa) -- Politics and government -- 1872-1910
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2562 , http://hdl.handle.net/10962/d1002415
- Description: Chapter One: The provisions of the Glen Grey Act of 1894 are summarised. The memoirs of contemporaries are discussed and the historical literature on the Act from 1913 to the present is surveyed. The likelihood of the land tenure provisions of the Act forcing the people of Glen Grey (or the people of other districts that came under the operation of the Act) to seek employment is noted. It is evident that there is an increasing emphasis in the literature on labour concerns rather than on the disenfranchising effects and local government provisions of the Act. It is often assumed that the labour force generated by the Act was meant for the Transvaal gold mines. Chapter Two: The relevance of the labour needs of the Indwe collieries is investigated. These mines lay adjacent to Glen Grey and might have been expected to draw their labour thence if the Act had been effective. Rhodes, the author of the Act and prime minister of the Cape, had bought shares in the collieries for De Beers shortly before the Act was passed, which made a possible connection more intriguing. No causal link between De Beers' interests and the Act could be demonstrated; nor do the collieries seem to have employed many people from Glen Grey. Chapter Three: Examines the Cape colonists' complaints about shortage of labour from 1807 to the eve of the Glen Grey Act, and investigates various official measures to promote the labour supply. The Glen Grey Act was not the first labour measure passed at the Cape, and it seems likely, therefore, that the labour needs of the Cape, rather than the Transvaal, were uppermost in the minds of those responsible for the Act. Chapter Four examines Rhodes's political position in the 1890s and shows him to be increasingly dependent on the parliamentary support of the Afrikaner Bond to stay in office. Since the Bond was an agricultural interest group it seems likely that labour for Cape farms, rather than Transvaal gold mines, was what the Act was supposed to provide. With that Rhodes could readily agree, since he wanted to promote the agricultural development of the Cape. However, the Bond wanted to be able to buy land in Glen Grey (and other district in which the Act was proclaimed). Rhodes wanted to keep such districts as 'reservoirs of labour' so he could not give the Bond all of what they wanted, i.e. Glen Grey titles to be alienable. His manoeuvring to keep the Bond supporting the Bill while not making the land readily salable is described. (In the end the land was alienable with the consent of the government -- consent that a Rhodes ministry would not give, but that another might.) Rhodes's desire to obtain the administration of Bechuanaland for his Chartered Company, and his need therefore to reassure the Colonial Office and humanitarian opinion that he could be trusted to rule over blacks, are pointed out as other possible motivations for the Act, which Rhodes tried hard to present as an enlightened piece of legislation. The course of the Act through the Cape parliament, and the opposition of Cape liberals to the Act, is described. Chapter Five: The mentalité of the Cape colonists as regards race, liquor, land tenure and other political issues is described. Chapter Six: The reaction to the Act of Cape blacks and sympathetic whites, British humanitarians and the Colonial Office is described. The contemporary concern with reserving land for blacks is noted, as well as concern over the morality of economically coerced labour. This is in contrast to the modern concentration on labour almost to the exclusion of other issues in regard to the Glen Grey Act. The unsuccessful efforts of Cape blacks and British humanitarians to have the imperial government veto the Act are described. Rhodes's influence over the Colonial Office is described.
- Full Text:
- Date Issued: 1991