Perceptions of patients about poor attitudes and behaviours of midwives in the maternity sections in a public hospital of East London South Africa
- Authors: Lawrence, N W
- Date: 2019-11
- Subjects: Midwives , Maternity nursing
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23521 , vital:58085
- Description: Midwives are largely responsible for maternity care in hospitals. As such, they play a significant role in ensuring the health and well-being of pregnant women and newborn babies. To perform that duty effectively, midwives need to be professional in their conduct. However, there are reports that midwives have displayed poor attitudes and behaviour in South Africa. The main research question was “what are the perceptions of patients about attitudes and behaviours of midwives in the maternity section in a public hospital in East London, South Africa?” The aim of the study was to explore the reasons behind poor attitudes and behaviour of midwives in midwifery practice and suggest interventions that can be introduced to promote professional attitudes and behaviour by midwives in a public hospital in East London. This study used a qualitative approach to collect data. The research instrument that was used for this study was semi-structured interviews. The sample of 20 participants which was purposively selected consisted of women that have used the East London public hospital maternity section. Data was collected using coding and themes emanating from the data generated. Midwives are valued and play a very significant role in providing maternal care. Be that as it may, midwives exhibit poor attitudes and behaviours such as being rude, lack sympathy, and lack of empathy. On the other hand, midwives act professionally and are supportive of patients. There is, therefore, a need for the provision of professional etiquette training services, stress counseling, use of work development strategies and performance management systems, technical training, linkage system of traditional and modern midwives, and the use of internet platforms to increase interaction between midwives and those that need maternity care services. , Thesis (MPH) -- Faculty of Health Sciences, 2019
- Full Text:
- Authors: Lawrence, N W
- Date: 2019-11
- Subjects: Midwives , Maternity nursing
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23521 , vital:58085
- Description: Midwives are largely responsible for maternity care in hospitals. As such, they play a significant role in ensuring the health and well-being of pregnant women and newborn babies. To perform that duty effectively, midwives need to be professional in their conduct. However, there are reports that midwives have displayed poor attitudes and behaviour in South Africa. The main research question was “what are the perceptions of patients about attitudes and behaviours of midwives in the maternity section in a public hospital in East London, South Africa?” The aim of the study was to explore the reasons behind poor attitudes and behaviour of midwives in midwifery practice and suggest interventions that can be introduced to promote professional attitudes and behaviour by midwives in a public hospital in East London. This study used a qualitative approach to collect data. The research instrument that was used for this study was semi-structured interviews. The sample of 20 participants which was purposively selected consisted of women that have used the East London public hospital maternity section. Data was collected using coding and themes emanating from the data generated. Midwives are valued and play a very significant role in providing maternal care. Be that as it may, midwives exhibit poor attitudes and behaviours such as being rude, lack sympathy, and lack of empathy. On the other hand, midwives act professionally and are supportive of patients. There is, therefore, a need for the provision of professional etiquette training services, stress counseling, use of work development strategies and performance management systems, technical training, linkage system of traditional and modern midwives, and the use of internet platforms to increase interaction between midwives and those that need maternity care services. , Thesis (MPH) -- Faculty of Health Sciences, 2019
- Full Text:
Retrospective analysis of factors contributing to parasuicide among youth in Buffalo City Metropolitan Municipality, Eastern Cape, South Africa
- Authors: Nganto, Yanga
- Date: 2021-11
- Subjects: Parasuicide -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/22897 , vital:53181
- Description: Parasuicide is a problem that affects the youth locally and globally. Parasuicide has negative psychological impacts on youth. This study was designed to assess elements of parasuicide in the Buffalo City Metropolitan Municipality of South Africa, using records of patients admitted to Frere and Cecilia Makiwane hospitals between 2016 and 2020. The purpose of the study was to conduct a descriptive retrospective review of parasuicide among youth to determine trends, causes, and contributing factors of committing parasuicide. Methods A retrospective, quantitative and descriptive study was conducted with 200 files of patients aged between 18 and 35 years conveniently sampled. These patients diagnosed as committed parasuicide and were admitted at Frere and Cecilia Makiwane hospitals over a period of four years from 1 April 2016 to 31 March 202. Only record files of patients’ residing in East London and Mdantsane catchment area were selected. Raw data was collected for a period of twelve weeks using a developed data collection tool developed in Ms Excel spreadsheet. Results In this sample, the large number of the patients were under 26 years (60.5%), female (57%), single (92.5%), and Black (99.5%). Furthermore, majority of the patients had attained secondary education (89.5%), were unemployed (83%) and living with their families (59%). There were different methods and agents used by participants to commit parasuicide and reasons differed from person to person. Among patients who reported a suicide attempt, organophosphates were most commonly used agent for self-poisoning (47%, n=94), followed by substances such as use of drugs and alcohol (n=57, 28.5%), violence (n=27, 13.5%), corrosive agents including bleach and Jik (n=11, 5.5%), and hydrogen peroxide including acidic sub-stances like battery acid (n=11, 5.5%). The common reason found in the study and indicates participants had psychiatric disorder (34.5%). Conclusion Limiting access to organophosphate agents and other lethal means is an effective strategy that should be adopted to prevent parasuicide among youth. Timely identification of risks or warning signs, social prevention and immediate intervention at the state level will play an important role in controlling parasuicide among youth. Moreover, improving health care services with psychotherapy support would empower youth with skills that would enhance their self-confidence, self-worth and resilience. Consequently, attainment of these attributes would result in the prevention and control of parasuicide amongst youth. , Thesis (MPH) -- Faculty of Health Sciences, 2021
- Full Text:
- Authors: Nganto, Yanga
- Date: 2021-11
- Subjects: Parasuicide -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/22897 , vital:53181
- Description: Parasuicide is a problem that affects the youth locally and globally. Parasuicide has negative psychological impacts on youth. This study was designed to assess elements of parasuicide in the Buffalo City Metropolitan Municipality of South Africa, using records of patients admitted to Frere and Cecilia Makiwane hospitals between 2016 and 2020. The purpose of the study was to conduct a descriptive retrospective review of parasuicide among youth to determine trends, causes, and contributing factors of committing parasuicide. Methods A retrospective, quantitative and descriptive study was conducted with 200 files of patients aged between 18 and 35 years conveniently sampled. These patients diagnosed as committed parasuicide and were admitted at Frere and Cecilia Makiwane hospitals over a period of four years from 1 April 2016 to 31 March 202. Only record files of patients’ residing in East London and Mdantsane catchment area were selected. Raw data was collected for a period of twelve weeks using a developed data collection tool developed in Ms Excel spreadsheet. Results In this sample, the large number of the patients were under 26 years (60.5%), female (57%), single (92.5%), and Black (99.5%). Furthermore, majority of the patients had attained secondary education (89.5%), were unemployed (83%) and living with their families (59%). There were different methods and agents used by participants to commit parasuicide and reasons differed from person to person. Among patients who reported a suicide attempt, organophosphates were most commonly used agent for self-poisoning (47%, n=94), followed by substances such as use of drugs and alcohol (n=57, 28.5%), violence (n=27, 13.5%), corrosive agents including bleach and Jik (n=11, 5.5%), and hydrogen peroxide including acidic sub-stances like battery acid (n=11, 5.5%). The common reason found in the study and indicates participants had psychiatric disorder (34.5%). Conclusion Limiting access to organophosphate agents and other lethal means is an effective strategy that should be adopted to prevent parasuicide among youth. Timely identification of risks or warning signs, social prevention and immediate intervention at the state level will play an important role in controlling parasuicide among youth. Moreover, improving health care services with psychotherapy support would empower youth with skills that would enhance their self-confidence, self-worth and resilience. Consequently, attainment of these attributes would result in the prevention and control of parasuicide amongst youth. , Thesis (MPH) -- Faculty of Health Sciences, 2021
- Full Text:
Perceptions of patients about poor attitudes and behaviours of midwives in the maternity sections in a public hospital of East London South Africa
- Authors: Lawrence, N W
- Date: 2019-11
- Subjects: Midwifery , Nursing ethics , Nurse and patient
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26918 , vital:66099
- Description: Midwives are largely responsible for maternity care in hospitals. As such, they play a significant role in ensuring the health and well-being of pregnant women and newborn babies. To perform that duty effectively, midwives need to be professional in their conduct. However, there are reports that midwives have displayed poor attitudes and behaviour in South Africa. The main research question was “what are the perceptions of patients about attitudes and behaviours of midwives in the maternity section in a public hospital in East London, South Africa?” The aim of the study was to explore the reasons behind poor attitudes and behaviour of midwives in midwifery practice and suggest interventions that can be introduced to promote professional attitudes and behaviour by midwives in a public hospital in East London. This study used a qualitative approach to collect data. The research instrument that was used for this study was semi-structured interviews. The sample of 20 participants which was purposively selected consisted of women that have used the East London public hospital maternity section. Data was collected using coding and themes emanating from the data generated. Midwives are valued and play a very significant role in providing maternal care. Be that as it may, midwives exhibit poor attitudes and behaviours such as being rude, lack sympathy, and lack of empathy. On the other hand, midwives act professionally and are supportive of patients. There is, therefore, a need for the provision of professional etiquette training services, stress counseling, use of work development strategies and performance management systems, technical training, linkage system of traditional and modern midwives, and the use of internet platforms to increase interaction between midwives and those that need maternity care services. , Thesis (MPA) -- Faculty of Health Sciences, 2019
- Full Text:
- Authors: Lawrence, N W
- Date: 2019-11
- Subjects: Midwifery , Nursing ethics , Nurse and patient
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26918 , vital:66099
- Description: Midwives are largely responsible for maternity care in hospitals. As such, they play a significant role in ensuring the health and well-being of pregnant women and newborn babies. To perform that duty effectively, midwives need to be professional in their conduct. However, there are reports that midwives have displayed poor attitudes and behaviour in South Africa. The main research question was “what are the perceptions of patients about attitudes and behaviours of midwives in the maternity section in a public hospital in East London, South Africa?” The aim of the study was to explore the reasons behind poor attitudes and behaviour of midwives in midwifery practice and suggest interventions that can be introduced to promote professional attitudes and behaviour by midwives in a public hospital in East London. This study used a qualitative approach to collect data. The research instrument that was used for this study was semi-structured interviews. The sample of 20 participants which was purposively selected consisted of women that have used the East London public hospital maternity section. Data was collected using coding and themes emanating from the data generated. Midwives are valued and play a very significant role in providing maternal care. Be that as it may, midwives exhibit poor attitudes and behaviours such as being rude, lack sympathy, and lack of empathy. On the other hand, midwives act professionally and are supportive of patients. There is, therefore, a need for the provision of professional etiquette training services, stress counseling, use of work development strategies and performance management systems, technical training, linkage system of traditional and modern midwives, and the use of internet platforms to increase interaction between midwives and those that need maternity care services. , Thesis (MPA) -- Faculty of Health Sciences, 2019
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Teachers’ views on grade 7 reading comprehension skills amongst English first additional language learners: a case study
- Authors: Ruiters, Benedictor
- Date: 2019
- Subjects: Reading comprehension English language -- Study and teaching -- Foreign speakers
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10353/16307 , vital:40707
- Description: The purpose of this study was to investigate the views of Teachers about reading comprehension skills in grade 7 English Additional Language classrooms in Buffalo City Metropolitan, Eastern Cape. Objectives are to instil the love for reading and enabling learners to successfully learn to read and attain their full potential. The researcher was interested in exploring broader trends in reading comprehension skills, with the intention of contributing possible strategies to address the literacy level in English First Additional Language. The study was framed as qualitative in inquiry; a face-to-face semi-structured interview was used to collect data. The participants comprised of 24 learners and 4 educators. The theoretical framework utilised was Lev Vygotsky’s (1979) constructivist theory to analyse data using a qualitative analysis approach. Different tools to verify data, which comprised of semi- structured interview of open-ended questions and document analysis to obtain data from English First Additional Language teachers in four primary schools in the Buffalo City Metropolitan District, were used. Findings indicate English First Additional Language learners are not proficient in the language of teaching and learning because in other public schools mother tongue is additive language, while in other schools it does not exist. The recommendation was that the Department of education needs to introduce a reading module for English First Additional teachers who need training in this area of learning. Another recommendation highlighted by teachers is the revisiting of child development theories that will help teachers have a better understanding about the learners and which strategies to utilise during reading.
- Full Text:
- Authors: Ruiters, Benedictor
- Date: 2019
- Subjects: Reading comprehension English language -- Study and teaching -- Foreign speakers
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10353/16307 , vital:40707
- Description: The purpose of this study was to investigate the views of Teachers about reading comprehension skills in grade 7 English Additional Language classrooms in Buffalo City Metropolitan, Eastern Cape. Objectives are to instil the love for reading and enabling learners to successfully learn to read and attain their full potential. The researcher was interested in exploring broader trends in reading comprehension skills, with the intention of contributing possible strategies to address the literacy level in English First Additional Language. The study was framed as qualitative in inquiry; a face-to-face semi-structured interview was used to collect data. The participants comprised of 24 learners and 4 educators. The theoretical framework utilised was Lev Vygotsky’s (1979) constructivist theory to analyse data using a qualitative analysis approach. Different tools to verify data, which comprised of semi- structured interview of open-ended questions and document analysis to obtain data from English First Additional Language teachers in four primary schools in the Buffalo City Metropolitan District, were used. Findings indicate English First Additional Language learners are not proficient in the language of teaching and learning because in other public schools mother tongue is additive language, while in other schools it does not exist. The recommendation was that the Department of education needs to introduce a reading module for English First Additional teachers who need training in this area of learning. Another recommendation highlighted by teachers is the revisiting of child development theories that will help teachers have a better understanding about the learners and which strategies to utilise during reading.
- Full Text:
Fabrication of a photocatalytic PAN supported C-TiO2-CFA nanocomposite for use in water treatment
- Authors: Mpelane, Amkelwa
- Date: 2020
- Subjects: Photocatalysis
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: http://hdl.handle.net/10353/18744 , vital:42729
- Description: The goal of this study was to fabricate a visible light responsive composite of C-TiO2-CFA. The prepared nanocomposite (C-TiO2-CFA) was immobilized on poly(acrylonitrile) membrane to address the drawback of recovering the nanosized photocatalyst from water after photodegradation experiments. The C-TiO2-CFA nanocomposites were fabricated using a modified sol-gel method, while the C-TiO2-CFA/PAN membranes were prepared via the phase inversion technique. The nanocomposites were fully characterized using FTIR, XRD, SEM-EDX, TEM, DRS, and BET surface area analysis. The prepared C-TiO2-CFA/PAN membranes were evaluated in the photodegradation of methyl orange and the golden yellow dyes, as well as the photoreduction of lead and cadmium heavy metals in synthetic wastewater. UV-Visible spectroscopy was used to follow the changes in the concentration of organic dyes, while inductively coupled plasma optical emission spectroscopy was used to follow changes in the concentration of the heavy metals. FTIR analysis confirmed the presence of functional groups expected on the prepared C-TiO2- CFA/PAN membranes and EDX analysis accounted for the elements expected. The prepared membranes all exhibited an asymmetric structure as depicted by cross-sectional view study via SEM analysis. TEM and SEM analyses revealed that the prepared C-TiO2-CFA nanocomposite was roughly spherical in shape with an estimate particle size of 10.94 nm according to TEM and 11.62 nm according to XRD using Scherrer equation. The incorporation of carbon into the lattice structure of titanium dioxide resulted in a reduction in bandgap from 3.19 eV to 2.78 eV through introduction of mid-band states, allowing visible light utilization. The best nanocomposite was obtained by doping TiO2 with 4% carbon and having a C-TiO2 to CFA ratio of 4:1 respectively. The C-TiO2-CFA nanocomposite exhibits a crystalline structure with a mixture of rutile and anatase phases. The parameters investigated in the evaluation of photocatalytic performance of C-TiO2- CFA/PAN were effect of photocatalyst load on PAN membrane, initial dye concentration, pH and light source in the activation of photocatalyst. For both dyes (methyl arrange and golden yellow), it was observed that photodegradation efficiencies increased with an increase in catalyst load. In the photodegradation of MO and GY using the membrane with 1% C-TiO2- CFA, removal efficiencies of 73.3% and 59.99% were attained respectively, while the membrane with 2% C-TiO2-CFA achieved MO and GY photodegradation efficiencies of 99.8% and 99.2% respectively. Photodegradation efficiencies of MO and GY were observed to decrease with an increase in dye concentration. Low pH (3) was observed to favour the photodegradation of MO and GY azo dyes. Photodegradation efficiencies of 99.8% and 99.2% were attained where obtained at lower MO and GY initial concentration. The modified photocatalyst (C-TiO2-CFA/PAN) exhibited better photoactivity under sunlight irradiation compared to strict UV light irradiation. Evidently, the C-TiO2-CFA/PAN membranes can be 4 Final Submission of Thesis, Dissertation or Research Report/Project, Conference or Exam Paper utilized as a sustainable and stable photocatalyst to efficiently eliminate methyl orange and golden yellow dyes. A PAN membrane with 2 wt% C-TiO2-CFA revealed enhanced cadmium and lead removal efficiencies in comparison to PAN membranes with 1 wt% and 1.5% C-TiO2-CFA. A Cd2+ removal efficiency of 95% was obtained using 2 wt% C-TiO2-CFA/PAN nanocomposite membranes. Cadmium removal efficiencies of 92.5% and 91% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. A lead removal efficiency of 97% was obtained using PAN membrane with 2 wt% C-TiO2-CFA. Pb2+ removal efficiencies of 90.9% and 94.6% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. The photoreduction activity was observed to decrease with an increase in cadmium and lead initial concentrations. A cadmium and lead removal efficiencies of 95% and 97% were observed at lower Cd2+ and Pb2+ initial concentrations (20 ppm), respectively. The removal efficiencies varied marginally with changes in pH values. The fouling activity of the C-TiO2 modified PAN asymmetric membranes and pure PAN was investigated by carrying out pure water filtration tests as well as bovine serum albumin (BSA) filtration tests. A bovine serum albumin rejection of 98% was obtained utilizing the 2 wt% CTiO2-CFA/PAN membrane.
- Full Text:
- Authors: Mpelane, Amkelwa
- Date: 2020
- Subjects: Photocatalysis
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: http://hdl.handle.net/10353/18744 , vital:42729
- Description: The goal of this study was to fabricate a visible light responsive composite of C-TiO2-CFA. The prepared nanocomposite (C-TiO2-CFA) was immobilized on poly(acrylonitrile) membrane to address the drawback of recovering the nanosized photocatalyst from water after photodegradation experiments. The C-TiO2-CFA nanocomposites were fabricated using a modified sol-gel method, while the C-TiO2-CFA/PAN membranes were prepared via the phase inversion technique. The nanocomposites were fully characterized using FTIR, XRD, SEM-EDX, TEM, DRS, and BET surface area analysis. The prepared C-TiO2-CFA/PAN membranes were evaluated in the photodegradation of methyl orange and the golden yellow dyes, as well as the photoreduction of lead and cadmium heavy metals in synthetic wastewater. UV-Visible spectroscopy was used to follow the changes in the concentration of organic dyes, while inductively coupled plasma optical emission spectroscopy was used to follow changes in the concentration of the heavy metals. FTIR analysis confirmed the presence of functional groups expected on the prepared C-TiO2- CFA/PAN membranes and EDX analysis accounted for the elements expected. The prepared membranes all exhibited an asymmetric structure as depicted by cross-sectional view study via SEM analysis. TEM and SEM analyses revealed that the prepared C-TiO2-CFA nanocomposite was roughly spherical in shape with an estimate particle size of 10.94 nm according to TEM and 11.62 nm according to XRD using Scherrer equation. The incorporation of carbon into the lattice structure of titanium dioxide resulted in a reduction in bandgap from 3.19 eV to 2.78 eV through introduction of mid-band states, allowing visible light utilization. The best nanocomposite was obtained by doping TiO2 with 4% carbon and having a C-TiO2 to CFA ratio of 4:1 respectively. The C-TiO2-CFA nanocomposite exhibits a crystalline structure with a mixture of rutile and anatase phases. The parameters investigated in the evaluation of photocatalytic performance of C-TiO2- CFA/PAN were effect of photocatalyst load on PAN membrane, initial dye concentration, pH and light source in the activation of photocatalyst. For both dyes (methyl arrange and golden yellow), it was observed that photodegradation efficiencies increased with an increase in catalyst load. In the photodegradation of MO and GY using the membrane with 1% C-TiO2- CFA, removal efficiencies of 73.3% and 59.99% were attained respectively, while the membrane with 2% C-TiO2-CFA achieved MO and GY photodegradation efficiencies of 99.8% and 99.2% respectively. Photodegradation efficiencies of MO and GY were observed to decrease with an increase in dye concentration. Low pH (3) was observed to favour the photodegradation of MO and GY azo dyes. Photodegradation efficiencies of 99.8% and 99.2% were attained where obtained at lower MO and GY initial concentration. The modified photocatalyst (C-TiO2-CFA/PAN) exhibited better photoactivity under sunlight irradiation compared to strict UV light irradiation. Evidently, the C-TiO2-CFA/PAN membranes can be 4 Final Submission of Thesis, Dissertation or Research Report/Project, Conference or Exam Paper utilized as a sustainable and stable photocatalyst to efficiently eliminate methyl orange and golden yellow dyes. A PAN membrane with 2 wt% C-TiO2-CFA revealed enhanced cadmium and lead removal efficiencies in comparison to PAN membranes with 1 wt% and 1.5% C-TiO2-CFA. A Cd2+ removal efficiency of 95% was obtained using 2 wt% C-TiO2-CFA/PAN nanocomposite membranes. Cadmium removal efficiencies of 92.5% and 91% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. A lead removal efficiency of 97% was obtained using PAN membrane with 2 wt% C-TiO2-CFA. Pb2+ removal efficiencies of 90.9% and 94.6% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. The photoreduction activity was observed to decrease with an increase in cadmium and lead initial concentrations. A cadmium and lead removal efficiencies of 95% and 97% were observed at lower Cd2+ and Pb2+ initial concentrations (20 ppm), respectively. The removal efficiencies varied marginally with changes in pH values. The fouling activity of the C-TiO2 modified PAN asymmetric membranes and pure PAN was investigated by carrying out pure water filtration tests as well as bovine serum albumin (BSA) filtration tests. A bovine serum albumin rejection of 98% was obtained utilizing the 2 wt% CTiO2-CFA/PAN membrane.
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Diet of the yellow mongoose (Cynictis penicillata) in the Albany Thicket Biome of South Africa
- Authors: Bizani, Mfundo
- Date: 2014
- Language: English
- Type: Thesis , Masters , MSc (Zoology)
- Identifier: vital:11796 , http://hdl.handle.net/10353/d1019840
- Description: The dietary habits of the yellow mongoose Cynictis penicillata were studied in the Albany Thicket Biome of South Africa (Great Fish River Reserve, Eastern Cape). The diet was investigated through the analysis of 1,056 scats that were sampled over a period of 7 years (2005−2009 and 2011−2012) mainly in three similar sites (Kelarny, Grasslands and Junction 10) that were used by at least three families or groups of yellow mongooses. Scats were collected near latrine sites, labelled and stored in a freezer. In the laboratory, scats were oven dried for a period of 24 hours at 50 C. Diet was determined by identifying undigested food remains in the scats. Hair samples were examined under the compound microscope to identify which mammals were ingested. In the field, both arthropod and small mammal abundance were determined in order to evaluate whether yellow mongooses are opportunistic or specialist feeders. Furthermore, inter-annual (2006–2008) and inter-group/inter-site variations in the diet were assessed. Based on faecal analysis, arthropods were the principal prey, while small mammals acted as supplementary food item. Other food categories like vegetation, reptiles and birds were only ingested or preyed upon infrequently. Intermediate dietary diversity, and low standardised diet breadth indices were obtained for all seasons, as well as for the whole sampling period. The diet overlaps calculated for pairs of seasons were very high and did not differ substantially. However, the diet of the yellow mongoose varied seasonally, yearly and between groups (sites), mostly due to variations in arthropod and small mammal consumption. Food availability displayed an increase in biomass of both small mammals and arthropods in summer and autumn. Results obtained in this study could suggest that the yellow mongoose at the GFRR is insectivorous by preferring to feed on insects (and arthropods in general) when both insects and rodents are abundant. However the fact that its diet varies both seasonally, yearly and locally, as well as the presence of remains of other food categories in the scats, indicates that this species is rather an opportunistic, generalist feeder than an insect specialist.
- Full Text:
- Authors: Bizani, Mfundo
- Date: 2014
- Language: English
- Type: Thesis , Masters , MSc (Zoology)
- Identifier: vital:11796 , http://hdl.handle.net/10353/d1019840
- Description: The dietary habits of the yellow mongoose Cynictis penicillata were studied in the Albany Thicket Biome of South Africa (Great Fish River Reserve, Eastern Cape). The diet was investigated through the analysis of 1,056 scats that were sampled over a period of 7 years (2005−2009 and 2011−2012) mainly in three similar sites (Kelarny, Grasslands and Junction 10) that were used by at least three families or groups of yellow mongooses. Scats were collected near latrine sites, labelled and stored in a freezer. In the laboratory, scats were oven dried for a period of 24 hours at 50 C. Diet was determined by identifying undigested food remains in the scats. Hair samples were examined under the compound microscope to identify which mammals were ingested. In the field, both arthropod and small mammal abundance were determined in order to evaluate whether yellow mongooses are opportunistic or specialist feeders. Furthermore, inter-annual (2006–2008) and inter-group/inter-site variations in the diet were assessed. Based on faecal analysis, arthropods were the principal prey, while small mammals acted as supplementary food item. Other food categories like vegetation, reptiles and birds were only ingested or preyed upon infrequently. Intermediate dietary diversity, and low standardised diet breadth indices were obtained for all seasons, as well as for the whole sampling period. The diet overlaps calculated for pairs of seasons were very high and did not differ substantially. However, the diet of the yellow mongoose varied seasonally, yearly and between groups (sites), mostly due to variations in arthropod and small mammal consumption. Food availability displayed an increase in biomass of both small mammals and arthropods in summer and autumn. Results obtained in this study could suggest that the yellow mongoose at the GFRR is insectivorous by preferring to feed on insects (and arthropods in general) when both insects and rodents are abundant. However the fact that its diet varies both seasonally, yearly and locally, as well as the presence of remains of other food categories in the scats, indicates that this species is rather an opportunistic, generalist feeder than an insect specialist.
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Effects of loading time and lairage duration on pig behaviour, sex and lairage time on pork physio-chemical characteristics
- Authors: Ntlatywa, Bongiswa
- Date: 2017
- Subjects: Pork -- Quality Meat -- Quality Loading and unloading
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12270 , vital:39225
- Description: The objectives of the study were to determine the effect of loading time, transportation unloading and lairage period, their subsequent effect on responses behaviour and the effect of sex and lairage period on the meat quality of cross breeds reared in commercial farm. The first part of the study assessed the behaviour of pigs during loading at the farm, offloading and in the lairages. A total of 900 pigs from 5 trips (180 per trip) were monitored on behaviour from farm to slaughter plant. The pigs were transported to a commercial abattoir which is 120 km distance, travelling for 2 hours from the farm. The results revealed that time spent in loading pigs was more than when offloading pigs. The frequency of slipping or falling-off in pigs was high (18percent) than voluntary movement (8percent) during loading times (χ2 >0.05) that when off-loading. A significant difference was determined on the avoidance (χ2=0.03), mounting behaviour (χ2 =0.01) and vocal sound (χ2 =0.02) during loading time on each observation day. Furthermore there was no significant difference determined on the time and day of observation in the lairages. These results also reveal that the avoidance behaviour was the highest (47percent) while fighting (34percent) and vocalizing were the least compared to other behaviour during the first 30 minutes after arrival at the abattoir. Moreover, the lying behaviour was found to have highest frequency (15percent) on day 6 compared to other sampling days. These results reveal that time of loading pigs had an influence on pigs’ behaviour before slaughter and consequently that affected physiological features and meat quality. The second section of the study assessed sex and the different lairage time effects on the pork quality attributes. A total of fifty four pigs, 22 weeks old of different sex (26 boars x 28 gilts) reared on a commercial farm and transported to the abattoir on the same day was used in this study. At the abattoir, pigs were grouped according to lairage periods of 17 hours (Group1; 13 gilts and 14 boars) and 36 hours (Group 2; 15 gilts and 12 boars). Results showed no significant difference on the sex of pigs (P >0.05) and meat pH. However, lairage time influenced the thawing loss (P= 0.02) of meat and also the interactions of sex by lairage had a significant difference (P= 0.04) on meat tenderness. There was a positive significant correlation found between sex and meat attributes values were high in boars (r= 0.61) than in gilts (r = 0.49). A negative correlation between a*and WBSF on lairage group1 (r= -0.52) was determined while on group 2 there was a positive correlation between a* and b* (r=0.49). This study suggest that a proper timing on farm feed withdrawal in combination with a sufficient lairage at the slaughter plant may result in better carcass and meat quality traits. Communication among producers and abattoirs is critical when planning the fasting and lairage times in order to elude carcass and technological pork quality complications. To conclude, there is influence caused by time of loading in stressing pigs before transportation and slaughter as aggressive behaviour showed and also lairage time affected meat quality.
- Full Text:
- Authors: Ntlatywa, Bongiswa
- Date: 2017
- Subjects: Pork -- Quality Meat -- Quality Loading and unloading
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12270 , vital:39225
- Description: The objectives of the study were to determine the effect of loading time, transportation unloading and lairage period, their subsequent effect on responses behaviour and the effect of sex and lairage period on the meat quality of cross breeds reared in commercial farm. The first part of the study assessed the behaviour of pigs during loading at the farm, offloading and in the lairages. A total of 900 pigs from 5 trips (180 per trip) were monitored on behaviour from farm to slaughter plant. The pigs were transported to a commercial abattoir which is 120 km distance, travelling for 2 hours from the farm. The results revealed that time spent in loading pigs was more than when offloading pigs. The frequency of slipping or falling-off in pigs was high (18percent) than voluntary movement (8percent) during loading times (χ2 >0.05) that when off-loading. A significant difference was determined on the avoidance (χ2=0.03), mounting behaviour (χ2 =0.01) and vocal sound (χ2 =0.02) during loading time on each observation day. Furthermore there was no significant difference determined on the time and day of observation in the lairages. These results also reveal that the avoidance behaviour was the highest (47percent) while fighting (34percent) and vocalizing were the least compared to other behaviour during the first 30 minutes after arrival at the abattoir. Moreover, the lying behaviour was found to have highest frequency (15percent) on day 6 compared to other sampling days. These results reveal that time of loading pigs had an influence on pigs’ behaviour before slaughter and consequently that affected physiological features and meat quality. The second section of the study assessed sex and the different lairage time effects on the pork quality attributes. A total of fifty four pigs, 22 weeks old of different sex (26 boars x 28 gilts) reared on a commercial farm and transported to the abattoir on the same day was used in this study. At the abattoir, pigs were grouped according to lairage periods of 17 hours (Group1; 13 gilts and 14 boars) and 36 hours (Group 2; 15 gilts and 12 boars). Results showed no significant difference on the sex of pigs (P >0.05) and meat pH. However, lairage time influenced the thawing loss (P= 0.02) of meat and also the interactions of sex by lairage had a significant difference (P= 0.04) on meat tenderness. There was a positive significant correlation found between sex and meat attributes values were high in boars (r= 0.61) than in gilts (r = 0.49). A negative correlation between a*and WBSF on lairage group1 (r= -0.52) was determined while on group 2 there was a positive correlation between a* and b* (r=0.49). This study suggest that a proper timing on farm feed withdrawal in combination with a sufficient lairage at the slaughter plant may result in better carcass and meat quality traits. Communication among producers and abattoirs is critical when planning the fasting and lairage times in order to elude carcass and technological pork quality complications. To conclude, there is influence caused by time of loading in stressing pigs before transportation and slaughter as aggressive behaviour showed and also lairage time affected meat quality.
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Molecular study of mycobacterium tuberculosis complex (MTBC) DNA from Port Elizabeth
- Authors: Londiwe, Bhembe Nolwazi
- Date: 2014
- Subjects: Mycobacterium tuberculosis
- Language: English
- Type: Thesis , Masters , MSc (Microbiology)
- Identifier: vital:11281 , http://hdl.handle.net/10353/d1016163 , Mycobacterium tuberculosis
- Description: Mycobacterium tuberculosis complex (MTBC) is a causative agent of tuberculosis (TB) in humans and animals. The burden of tuberculosis in South Africa is worsened by the concurrent epidemic of HIV. The dynamic of TB epidemics has been investigated and yet little data has been given about the Eastern Cape, particularly Port Elizabeth. The study aimed to investigate the prevalence of drug resistant MTBC and to determine the mutations causing resistance in Port Elizabeth. One hundred and ninety (190) DNA samples isolated from sputum specimen in humans suspected of having TB were amplified using the Seeplex® MTB Nested ACE detection assay. To differentiate Mycobacterium tuberculosis complex (MTBC) members for surveillance purposes a multiplex polymerase chain reaction (PCR) method was done based on genomic regions of differences such as RD1, RD1mic, RD2seal, RD4, RD9 and RD12. Target genes known to confer resistance to first and second-line drugs were amplified and the amplicons sequenced using Big Dye Terminator DNA sequencing kit v3.1 (Applied Biosystems, UK). The patient’s demographic profiles were obtained from the National Health Laboratory Service (NHLS). All hundred and ninety DNA samples tested positive for MTBC using the Seeplex® MTB Nested ACE assay. Results show a high prevalence of extensive drug resistant TB in Port Elizabeth, Eastern Cape Province. One hundred and eighty four (184) DNA isolates were used in the identification of different MTBC species. We ended up working with 184 DNA isolates because we ran out of DNA, and we could not go back to isolate DNA from the affected individuals due to the fact that some patients died, while some have been released to go to their homes. From the 184 DNA isolates 45 (24.5%) isolates were identified to be M. tuberculosis, 94 isolates (51.1%) to be M. bovis BCG and 3 isolates (1.6%) to be M. cannetti. Sequencing results show the position of mutation in each DNA isolate; however in the study we got resistance to MDR to be 100% and 42% pre-XDR while 58% was XDR. These results raise an alarm for the prevalence MDR in MTBC from Port Elizabeth. This is a serious health concern which calls for a need to strategise on the identification of extensive drug resistant TB patients from multi-drug resistant TB patients and ensure monitoring of their treatment.
- Full Text:
- Authors: Londiwe, Bhembe Nolwazi
- Date: 2014
- Subjects: Mycobacterium tuberculosis
- Language: English
- Type: Thesis , Masters , MSc (Microbiology)
- Identifier: vital:11281 , http://hdl.handle.net/10353/d1016163 , Mycobacterium tuberculosis
- Description: Mycobacterium tuberculosis complex (MTBC) is a causative agent of tuberculosis (TB) in humans and animals. The burden of tuberculosis in South Africa is worsened by the concurrent epidemic of HIV. The dynamic of TB epidemics has been investigated and yet little data has been given about the Eastern Cape, particularly Port Elizabeth. The study aimed to investigate the prevalence of drug resistant MTBC and to determine the mutations causing resistance in Port Elizabeth. One hundred and ninety (190) DNA samples isolated from sputum specimen in humans suspected of having TB were amplified using the Seeplex® MTB Nested ACE detection assay. To differentiate Mycobacterium tuberculosis complex (MTBC) members for surveillance purposes a multiplex polymerase chain reaction (PCR) method was done based on genomic regions of differences such as RD1, RD1mic, RD2seal, RD4, RD9 and RD12. Target genes known to confer resistance to first and second-line drugs were amplified and the amplicons sequenced using Big Dye Terminator DNA sequencing kit v3.1 (Applied Biosystems, UK). The patient’s demographic profiles were obtained from the National Health Laboratory Service (NHLS). All hundred and ninety DNA samples tested positive for MTBC using the Seeplex® MTB Nested ACE assay. Results show a high prevalence of extensive drug resistant TB in Port Elizabeth, Eastern Cape Province. One hundred and eighty four (184) DNA isolates were used in the identification of different MTBC species. We ended up working with 184 DNA isolates because we ran out of DNA, and we could not go back to isolate DNA from the affected individuals due to the fact that some patients died, while some have been released to go to their homes. From the 184 DNA isolates 45 (24.5%) isolates were identified to be M. tuberculosis, 94 isolates (51.1%) to be M. bovis BCG and 3 isolates (1.6%) to be M. cannetti. Sequencing results show the position of mutation in each DNA isolate; however in the study we got resistance to MDR to be 100% and 42% pre-XDR while 58% was XDR. These results raise an alarm for the prevalence MDR in MTBC from Port Elizabeth. This is a serious health concern which calls for a need to strategise on the identification of extensive drug resistant TB patients from multi-drug resistant TB patients and ensure monitoring of their treatment.
- Full Text:
Ruthenium (II) complexes of mixed bipyridyl and dithiolate/thiourea ligands :|bsynthesis, characterization, photophysical and electrochemical studies
- Authors: Nkombi, Pelokazi
- Date: 2018
- Subjects: Ruthenium Ruthenium compounds Ligands
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/10134 , vital:35358
- Description: Energy is one of the most important factor to influence human lives. The increased in energy demand as well as the detrimental effects posed by emission of greenhouse gases due to continue use of fossil fuels for electricity generation has led to a renewed focus on energy production using renewable energy sources which are relatively cheap, clean and environmentally sustainable. Among the various renewable energy sources used so far, the Dye Synthesized Solar Cells (DSSCs), a form of photovoltaic device is reported for their better efficiencies despite their low cost of production and ability to work relatively under low light conditions. A recent report on the solar-to-electricity conversion efficiency of a typical DSSC sensitizer made from zinc based porphyrin dye coupled with sintered titanium(IV) oxide as semiconductor was 13 percent. In this study, 2,2-bipyridyl-4,4-dicarboxylic acid (bpydc) was used as mixed ligand and four dithiolate ligands; L1 = dipotassium ethoxycarbonyl-1-cyanoethylene-2,2-dithiolate, L2 = dipotassium bis(ethoxycarbonyl)ethane-2,2-dithiolate, L3 = dipotassium cyanodithio imidocarbonate and L4 = dipotassium 2,2-dicyanoethylene-2,2-dithiolate were synthesized while four alkyl thiourea ligands, L5 = 1,3-dimethyl thiourea, L6 = 1,3-diethyl thiourea, L7 = 1,3-diisopropyl thiourea and L8 = 1-methyl thiourea were purchased and used as supplied without further purification. These ligands were used to prepare eight ruthenium(II) complexes of mixed bipyridyl/dithiolate/thiourea. The compounds were characterised by elemental analysis and spectroscopic techniques, namely: Fourier transform infrared (FTIR), Nuclear Magnetic Resonance (NMR), ultraviolet-visible and photoluminescence (PL). Cyclic voltammetry (CV) and square wave voltammetry (SWV) were used for the electrochemical studies. Photoluminescence and UV-Vis spectroscopies were used for geometric and photophysical studies of the complexes respectively. FTIR spectra confirmed presence of functional groups in ligands and coordination of these ligands to ruthenium(II) ions to form complexes. The UV-Vis confirmed that the Ru(II) dithiolene complexes exhibited square planar geometries while the Ru(II) thiourea complexes gave octahedral geometries, this was deduced from the transitions assigned to the complexes. All the ruthenium(II) complexes synthesized showed photoluminescence properties that are suitable for light harvesting and application for dye-sensitized solar cells. Cyclic and square wave voltammetry show Ru(II) thiourea complexes have better redox properties when compared to Ru(II) dithiolate complexes which is ascribed to ligand strength field possibly due to contribution from the two bonded NCS groups.
- Full Text:
- Authors: Nkombi, Pelokazi
- Date: 2018
- Subjects: Ruthenium Ruthenium compounds Ligands
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/10134 , vital:35358
- Description: Energy is one of the most important factor to influence human lives. The increased in energy demand as well as the detrimental effects posed by emission of greenhouse gases due to continue use of fossil fuels for electricity generation has led to a renewed focus on energy production using renewable energy sources which are relatively cheap, clean and environmentally sustainable. Among the various renewable energy sources used so far, the Dye Synthesized Solar Cells (DSSCs), a form of photovoltaic device is reported for their better efficiencies despite their low cost of production and ability to work relatively under low light conditions. A recent report on the solar-to-electricity conversion efficiency of a typical DSSC sensitizer made from zinc based porphyrin dye coupled with sintered titanium(IV) oxide as semiconductor was 13 percent. In this study, 2,2-bipyridyl-4,4-dicarboxylic acid (bpydc) was used as mixed ligand and four dithiolate ligands; L1 = dipotassium ethoxycarbonyl-1-cyanoethylene-2,2-dithiolate, L2 = dipotassium bis(ethoxycarbonyl)ethane-2,2-dithiolate, L3 = dipotassium cyanodithio imidocarbonate and L4 = dipotassium 2,2-dicyanoethylene-2,2-dithiolate were synthesized while four alkyl thiourea ligands, L5 = 1,3-dimethyl thiourea, L6 = 1,3-diethyl thiourea, L7 = 1,3-diisopropyl thiourea and L8 = 1-methyl thiourea were purchased and used as supplied without further purification. These ligands were used to prepare eight ruthenium(II) complexes of mixed bipyridyl/dithiolate/thiourea. The compounds were characterised by elemental analysis and spectroscopic techniques, namely: Fourier transform infrared (FTIR), Nuclear Magnetic Resonance (NMR), ultraviolet-visible and photoluminescence (PL). Cyclic voltammetry (CV) and square wave voltammetry (SWV) were used for the electrochemical studies. Photoluminescence and UV-Vis spectroscopies were used for geometric and photophysical studies of the complexes respectively. FTIR spectra confirmed presence of functional groups in ligands and coordination of these ligands to ruthenium(II) ions to form complexes. The UV-Vis confirmed that the Ru(II) dithiolene complexes exhibited square planar geometries while the Ru(II) thiourea complexes gave octahedral geometries, this was deduced from the transitions assigned to the complexes. All the ruthenium(II) complexes synthesized showed photoluminescence properties that are suitable for light harvesting and application for dye-sensitized solar cells. Cyclic and square wave voltammetry show Ru(II) thiourea complexes have better redox properties when compared to Ru(II) dithiolate complexes which is ascribed to ligand strength field possibly due to contribution from the two bonded NCS groups.
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Evaluating the contributions of selected drug rehabilitation centres in Gauteng : towards ameliorating the drug problem in South Africa
- Authors: Makuyana, Abigail
- Date: 2017
- Subjects: Rehabilitation centers -- South Africa -- Gauteng Substance abuse -- Rehabilitation Addicts -- Rehabilitation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/8876 , vital:33703
- Description: This study aimed at evaluating the contributions of two (2) selected rehabilitation centres to the goal of ameliorating the substance abuse problem in Gauteng. The study utilized a methodological triangulation approach for data collection, but with greater emphasis on qualitative methods. The study collected its qualitative data from four focus groups conducted with 32 participants and six key informants who were subjected to in-depth interviews. The quantitative aspect of the study made use of a mini-survey in which one hundred (100) questionnaires were distributed amongst the primary caregivers of recovering drug and substance abusers. The major findings of the study pointed out that rehabilitation centres were unequivocally contributing to the goal of ameliorating substance abuse in Gauteng and, by extension, South Africa. Among some of the outstanding contributions of the rehabilitation centres was the provision of a non-judgmental and supportive therapeutic environment for clients to recover. It was also observed that rehabilitation centres were acting as character reformatories for substance abusers, and, thus, aiding their easy reintegration back into their families, societies and work places. The study also found out that the selected rehabilitation centres were providing ample admission periods and competent counselling services for their clients to navigate their way to recovery. The study unearthed new trends in the substance abuse landscape of Gauteng. Firstly, it was established that more educated people were falling into substance abuse usage. Secondly, the drugs which were rendering users more amenable to rehabilitation were noted to be highly potent. The high potency was noted to be responsible for extreme difficulties in withdrawal and rehabilitation. This was, therefore, noted to accentuate the imperativeness of the role and contributions of rehabilitation centres in helping drug users to achieve recovery in an environment that was supportive, nurturing and safe. It is, therefore, on the basis of these fundamental findings that this study concluded that the contributions of rehabilitation centres were not only important in the fight against drug and substance abuse, but were also a necessary precondition in this endeavour. Conversely, it was established that the contributions of the rehabilitation centres were being thwarted by exorbitant and extortionate treatment fees charged by the rehabilitation centres. More so, rehabilitation centres faced the dire challenge of poor visibility due to the poor marketing of services, as well as their location in affluent or remote areas which are mainly accessible only through private transport. This means that some people, especially the rural and the urban poor, were not equitably benefiting from the services of the rehabilitation centres. The study observed that women, girls and children in general were largely excluded from benefiting from the services of the rehabilitation centres. The research closed off by recommending to rehabilitation centres that they ought to address administrative gaps such as embracing and practising social, linguistic, dietary and gender sensitivity in their programmes to ensure that they remain relevant to their clients while also reflecting the diversity in South Africa. Recommendations were also made to the government to intervene and moderate the pricing of substance abuse treatment services, by making them reflect the country’s socioeconomic inequalities.
- Full Text:
- Authors: Makuyana, Abigail
- Date: 2017
- Subjects: Rehabilitation centers -- South Africa -- Gauteng Substance abuse -- Rehabilitation Addicts -- Rehabilitation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/8876 , vital:33703
- Description: This study aimed at evaluating the contributions of two (2) selected rehabilitation centres to the goal of ameliorating the substance abuse problem in Gauteng. The study utilized a methodological triangulation approach for data collection, but with greater emphasis on qualitative methods. The study collected its qualitative data from four focus groups conducted with 32 participants and six key informants who were subjected to in-depth interviews. The quantitative aspect of the study made use of a mini-survey in which one hundred (100) questionnaires were distributed amongst the primary caregivers of recovering drug and substance abusers. The major findings of the study pointed out that rehabilitation centres were unequivocally contributing to the goal of ameliorating substance abuse in Gauteng and, by extension, South Africa. Among some of the outstanding contributions of the rehabilitation centres was the provision of a non-judgmental and supportive therapeutic environment for clients to recover. It was also observed that rehabilitation centres were acting as character reformatories for substance abusers, and, thus, aiding their easy reintegration back into their families, societies and work places. The study also found out that the selected rehabilitation centres were providing ample admission periods and competent counselling services for their clients to navigate their way to recovery. The study unearthed new trends in the substance abuse landscape of Gauteng. Firstly, it was established that more educated people were falling into substance abuse usage. Secondly, the drugs which were rendering users more amenable to rehabilitation were noted to be highly potent. The high potency was noted to be responsible for extreme difficulties in withdrawal and rehabilitation. This was, therefore, noted to accentuate the imperativeness of the role and contributions of rehabilitation centres in helping drug users to achieve recovery in an environment that was supportive, nurturing and safe. It is, therefore, on the basis of these fundamental findings that this study concluded that the contributions of rehabilitation centres were not only important in the fight against drug and substance abuse, but were also a necessary precondition in this endeavour. Conversely, it was established that the contributions of the rehabilitation centres were being thwarted by exorbitant and extortionate treatment fees charged by the rehabilitation centres. More so, rehabilitation centres faced the dire challenge of poor visibility due to the poor marketing of services, as well as their location in affluent or remote areas which are mainly accessible only through private transport. This means that some people, especially the rural and the urban poor, were not equitably benefiting from the services of the rehabilitation centres. The study observed that women, girls and children in general were largely excluded from benefiting from the services of the rehabilitation centres. The research closed off by recommending to rehabilitation centres that they ought to address administrative gaps such as embracing and practising social, linguistic, dietary and gender sensitivity in their programmes to ensure that they remain relevant to their clients while also reflecting the diversity in South Africa. Recommendations were also made to the government to intervene and moderate the pricing of substance abuse treatment services, by making them reflect the country’s socioeconomic inequalities.
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Resilience towards adverse childhood experiences among public secondary school students in Alice, South Africa
- Authors: Obisesan , Matthew Tobiloba
- Date: 2019
- Subjects: Child development Child psychology
- Language: English
- Type: Thesis , Masters , MPH
- Identifier: http://hdl.handle.net/10353/16769 , vital:40772
- Description: Adverse childhood experiences (ACEs) are of great concerns in public health. They are traumatic experiences that occur during childhood. ACEs include various forms of abuse and maltreatment which can be emotional, physical, verbal and sexual, different degrees of household dysfunction such as growing up with substance abuse like drugs and alcohol, witnessing domestic violence, mental illnesses, crime in the home and parental disharmony. Although childhood adversities and traumatic experiences occur before the individual is 18 years of age, the effects of such experiences can last a lifetime causing mental and chronic medical illnesses. Resilience is perceived as an antidote to the detrimental effect of ACEs. It is a situation in which an individual displays a high level of effectiveness after a significant misfortune or adversity. This study was conducted to assess the level of resilience towards adverse childhood experiences among public secondary school children in Alice. Data were collected with the aid of a wellstructured questionnaire from 418 public high school students using Convenience sampling method. Factors influencing resilience among the learners were examined. Consequently, the data collected were analyzed using descriptive statistics and ordered logit regression model. From the results, it is observed that the majority of the learners live with their grandparents and the most prevalent form of ACEs is emotional abuse, followed by sexual abuse while community violence is the least common childhood adversity. This study further reveals that some of the respondents experienced more than one form of adverse childhood experience. In addition, irrespective of what the students have been through, they are largely observed to be resilient. Analysis from the ordered logit regression model shows that age, class in school, gender, religion, race and who the student lives with are significantly related to resilience. The study, therefore, recommends a functional counseling unit in the schools while student-teacher relationship must be encouraged
- Full Text:
- Authors: Obisesan , Matthew Tobiloba
- Date: 2019
- Subjects: Child development Child psychology
- Language: English
- Type: Thesis , Masters , MPH
- Identifier: http://hdl.handle.net/10353/16769 , vital:40772
- Description: Adverse childhood experiences (ACEs) are of great concerns in public health. They are traumatic experiences that occur during childhood. ACEs include various forms of abuse and maltreatment which can be emotional, physical, verbal and sexual, different degrees of household dysfunction such as growing up with substance abuse like drugs and alcohol, witnessing domestic violence, mental illnesses, crime in the home and parental disharmony. Although childhood adversities and traumatic experiences occur before the individual is 18 years of age, the effects of such experiences can last a lifetime causing mental and chronic medical illnesses. Resilience is perceived as an antidote to the detrimental effect of ACEs. It is a situation in which an individual displays a high level of effectiveness after a significant misfortune or adversity. This study was conducted to assess the level of resilience towards adverse childhood experiences among public secondary school children in Alice. Data were collected with the aid of a wellstructured questionnaire from 418 public high school students using Convenience sampling method. Factors influencing resilience among the learners were examined. Consequently, the data collected were analyzed using descriptive statistics and ordered logit regression model. From the results, it is observed that the majority of the learners live with their grandparents and the most prevalent form of ACEs is emotional abuse, followed by sexual abuse while community violence is the least common childhood adversity. This study further reveals that some of the respondents experienced more than one form of adverse childhood experience. In addition, irrespective of what the students have been through, they are largely observed to be resilient. Analysis from the ordered logit regression model shows that age, class in school, gender, religion, race and who the student lives with are significantly related to resilience. The study, therefore, recommends a functional counseling unit in the schools while student-teacher relationship must be encouraged
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Physiological traits, anthropometric characteristics and motor development of rural children in Nkonkobe Municipality, South Africa
- Authors: Idamokoro, Mere
- Date: 2018
- Subjects: Motor learning Children -- Physiology Children -- Anthropometry -- South Africa
- Language: English
- Type: Thesis , Masters , Human Movement Science
- Identifier: http://hdl.handle.net/10353/10061 , vital:35314
- Description: Aim: The purpose of this study was to examine the physiological, anthropometric and motor development characteristics of rural children between the ages of 5 – 7 years old. Methods: The study involved 305 school children (159 boys and 146 girls) randomly selected from primary schools in Alice sub-district, Nkonkobe Municipality. Body weight, height, skinfold thickness and girth measurements were measured using standard procedures. Overweight and obesity were defined using body mass index (BMI) for age and gender. Derived variables were: fat mass, fat-free mass, fat mass index, fat-free mass index, waist-to-hip ratio, waist-to-height ratio and subscapular-to-triceps ratio. Motor development levels were measured and assessed using Test of Gross Motor Development –Second Edition (TGMD-2). Blood pressure was measured using aneroid sphygmomanometer. Results: Boys had higher mean values of blood pressure (69.19 ± 7.30 and 38.15 ± 5.91) compared to girls (68.39 ± 7.97 and 37.11 ± 7.53). The proportion of overweight among girls (15.75 percent) was higher compared to boys (10.69 percent). Likewise, the percentage of obesity among boys (16.35 percent) was higher compared to girls (10.27 percent). The motor development results showed that girls (40.9 ± 6.54) performed better than boys (39.7 ± 6.64) in locomotor skills test. Conversely, boys (39.8 ± 7.62) performed better than girls (38.6 ± 7.29) in object control. Conclusion: The prevalence of overweight and obesity among the children is alarmingly high and concerning for the health. At all ages, girls had higher body fat percentage and fat mass than the boys. However, FFMI and WHR were higher in boys compared to the girls. There is no gender difference in the waist-to-height ratio and STR of both boys and girls. The locomotor raw score is higher in girls than in boys; however, the object control raw score is higher in boys compared to girls. The non-correlation of BMI with TGMD-2 tests suggests an equal potential of motor development among the children, regardless of their body fatness. There is need for obesity prevention programme in schools, which should involve all the stakeholders (teachers, parents/guardians, government, NGOs). The programme should focus on creating awareness concerning child body weight, healthy dietary intake and regular BMI screening in schools.
- Full Text:
- Authors: Idamokoro, Mere
- Date: 2018
- Subjects: Motor learning Children -- Physiology Children -- Anthropometry -- South Africa
- Language: English
- Type: Thesis , Masters , Human Movement Science
- Identifier: http://hdl.handle.net/10353/10061 , vital:35314
- Description: Aim: The purpose of this study was to examine the physiological, anthropometric and motor development characteristics of rural children between the ages of 5 – 7 years old. Methods: The study involved 305 school children (159 boys and 146 girls) randomly selected from primary schools in Alice sub-district, Nkonkobe Municipality. Body weight, height, skinfold thickness and girth measurements were measured using standard procedures. Overweight and obesity were defined using body mass index (BMI) for age and gender. Derived variables were: fat mass, fat-free mass, fat mass index, fat-free mass index, waist-to-hip ratio, waist-to-height ratio and subscapular-to-triceps ratio. Motor development levels were measured and assessed using Test of Gross Motor Development –Second Edition (TGMD-2). Blood pressure was measured using aneroid sphygmomanometer. Results: Boys had higher mean values of blood pressure (69.19 ± 7.30 and 38.15 ± 5.91) compared to girls (68.39 ± 7.97 and 37.11 ± 7.53). The proportion of overweight among girls (15.75 percent) was higher compared to boys (10.69 percent). Likewise, the percentage of obesity among boys (16.35 percent) was higher compared to girls (10.27 percent). The motor development results showed that girls (40.9 ± 6.54) performed better than boys (39.7 ± 6.64) in locomotor skills test. Conversely, boys (39.8 ± 7.62) performed better than girls (38.6 ± 7.29) in object control. Conclusion: The prevalence of overweight and obesity among the children is alarmingly high and concerning for the health. At all ages, girls had higher body fat percentage and fat mass than the boys. However, FFMI and WHR were higher in boys compared to the girls. There is no gender difference in the waist-to-height ratio and STR of both boys and girls. The locomotor raw score is higher in girls than in boys; however, the object control raw score is higher in boys compared to girls. The non-correlation of BMI with TGMD-2 tests suggests an equal potential of motor development among the children, regardless of their body fatness. There is need for obesity prevention programme in schools, which should involve all the stakeholders (teachers, parents/guardians, government, NGOs). The programme should focus on creating awareness concerning child body weight, healthy dietary intake and regular BMI screening in schools.
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The approaches of traditional healers in the treatment of HIV/ AIDS: the case of Chris Hani District Municipality, Cala, Tsengiwe, Eastern cape, South Africa
- Authors: Mati, Similo
- Date: 2017
- Subjects: People with HIV and AIDS disease -- healers -- South Africa --Eastern Cape Traditional medicine -- South Africa -- Eastern Cape Healers -- South Africa -- Eastern Cape HIV infections -- Treatment -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/5249 , vital:29171
- Description: In South Africa, just like in any other country within the African continent, traditional healing remains an integral part of many communities and this is not just restricted to the rural communities only, as is sometimes assumed. The main aim of this research was to explore the approaches of traditional healers in the treatment of HIV/AIDS in the Chris Hani District Municipality, Eastern Cape. The following research objectives were followed regarding the approaches of traditional healers in the treatment of HIV/AIDS: (i) to assess how traditional healers and people living with HIV/AIDS in Tsengiwe village understand HIV/AIDS, (ii) to investigate the reasons people living with HIV/AIDS consult traditional healers in Tsengiwe village, (iii) to assess Tsengiwe village traditional healers’ treatment strategies for HIV/AIDS, (iv) to establish how traditional healers view their role in the treatment of HIV/AIDS in Tsengiwe village. A qualitative research design was utilized, using in-depth interviews with traditional healers and focus group discussions with caregivers and people living with HIV/AIDS respectively. A type of non-probability sampling known as purposive sampling was used. A total of sixteen (16) participants were interviewed. The findings in this research revealed the following themes: (i) HIV/AIDS is incurable and it is understood by symptoms, (ii) belief system entrenched in traditional healing, (iii) cleansing rituals and traditional medicinal remedies and, (iv) strengthening relations between stakeholders. While traditional healers expressed a willingness to work with biomedical professionals in the management of HIV/AIDS, caregivers and people living with HIV/AIDS preferred going to clinics and hospitals for treatment. Furthermore, people living with HIV/AIDS in this research never admitted to consulting traditional healers for their ailments, only saying that they choose to self-medicate.
- Full Text:
- Authors: Mati, Similo
- Date: 2017
- Subjects: People with HIV and AIDS disease -- healers -- South Africa --Eastern Cape Traditional medicine -- South Africa -- Eastern Cape Healers -- South Africa -- Eastern Cape HIV infections -- Treatment -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/5249 , vital:29171
- Description: In South Africa, just like in any other country within the African continent, traditional healing remains an integral part of many communities and this is not just restricted to the rural communities only, as is sometimes assumed. The main aim of this research was to explore the approaches of traditional healers in the treatment of HIV/AIDS in the Chris Hani District Municipality, Eastern Cape. The following research objectives were followed regarding the approaches of traditional healers in the treatment of HIV/AIDS: (i) to assess how traditional healers and people living with HIV/AIDS in Tsengiwe village understand HIV/AIDS, (ii) to investigate the reasons people living with HIV/AIDS consult traditional healers in Tsengiwe village, (iii) to assess Tsengiwe village traditional healers’ treatment strategies for HIV/AIDS, (iv) to establish how traditional healers view their role in the treatment of HIV/AIDS in Tsengiwe village. A qualitative research design was utilized, using in-depth interviews with traditional healers and focus group discussions with caregivers and people living with HIV/AIDS respectively. A type of non-probability sampling known as purposive sampling was used. A total of sixteen (16) participants were interviewed. The findings in this research revealed the following themes: (i) HIV/AIDS is incurable and it is understood by symptoms, (ii) belief system entrenched in traditional healing, (iii) cleansing rituals and traditional medicinal remedies and, (iv) strengthening relations between stakeholders. While traditional healers expressed a willingness to work with biomedical professionals in the management of HIV/AIDS, caregivers and people living with HIV/AIDS preferred going to clinics and hospitals for treatment. Furthermore, people living with HIV/AIDS in this research never admitted to consulting traditional healers for their ailments, only saying that they choose to self-medicate.
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3-Methyl-1-phenyl-4-[(phenyl)(2-phenylhydrazin-1-yl)methylidene]-1H-pyrazol-5(4H)-one
- Identifier: http://vital.seals.ac.za8080/10353/7489 , http://hdl.handle.net/10353/5328 , vital:29192
- Full Text:
- Identifier: http://vital.seals.ac.za8080/10353/7489 , http://hdl.handle.net/10353/5328 , vital:29192
- Full Text:
Synthesis, characterization and evaluation of photophysical and electrochemical properties of ruthenium(II) complexes for dye-sensitized solar cells
- Authors: Adjogri, Shadrack John
- Date: 2018
- Subjects: Ruthenium Ruthenium compounds
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/17828 , vital:41363
- Description: Eight series of thirty (30) novel heteroleptic ruthenium(II) complexes were designed, synthesized and spectroscopically characterized, with the following general molecular formulae as [Ru(bdmpmar)(H2dcbpy)(NCS)]+, [Ru(bdmpmar)(vpdiinp)(H2dcbpy)]2,+, [Ru(bdmpmar)(vpbpp)(H2dcbpy)]2+,[Ru(H2dcbpy)2(N^)(NCS)]+, [Ru(H2dcbpy)2(N^)2]2+, [Ru(H2dcbpy)(N^)2(NCS)2], [Ru(H2dcbpy)(N^)(NCS)3]– and [Ru(vptpy)(H2dcbpy)(N^^^)]2+ where bdmpmar is a tridentate ligand of N,N-bis(3, 5-dimethylpyrazol-1-yl-methyl) aromatic organic compound (such aromatic organic compounds(Ar) are anthranilic acid, 4-methoxy-2-nitroaniline, aniline, toluidine, cyclohexylamine and anisidine), vpdiinp represents a monodentate ligand of 11-(4-vinylphenyl)diindeno[1,2-b:2’,1’-e]pyridine, vpbpp represents a monodentate ligand of 4-(4-vinylphenyl)-2.6-bis(phenyl)pyridine and vptpy represents a tridentate ligand of 4’-(4-vinyl)-2,2’:6’,2’’-terpyridine. Meanwhile, N^ represents any of the monodentate ligands of either vpdiinp or vpbpp and (N^^^) represents any of the monodentate ligands either of vpdiinp or vpbpp or NCS as disclosed in series VIII. The complexes were characterized by conductivity measurement, solubility, melting point, UV-Vis, PL, FTIR (ATR), NMR, Cyclic and square wave voltammetry. Nine chelating ligands, comprising of six (6) tripodal chelating ligands, two (2) vinyl monodentate ligands and one (1) vinyl tridentate ligand, were used for the synthesis of ruthenium(II) complexes ATR-FTIR spectra of all the ruthenium(II) complexes measured as solid samples, exhibited fine resolution IR bands in region between 3473-3438 cm-1 of carboxylic group in H2dcbpy. The bands in the range 3040-2950 cm-1 were ascribed to C-H bond stretching for the CH3 groups. The coordination of NCS group in the sphere of ruthenium(II) complexes related to series I, IV, VI VII and one compound of series VIII was investigated by ATR-FTIR spectroscopy. Bands in the range of 2116-2106 cm-1 and 777-770 cm-1 are ascribed to the respective N=C and the C=S bond stretching vibration which confirms the N-coordination of the SCN group. For all the complexes, the stretching vibration of Ru-N bonding was between 466 and 411 cm-1 due to coordination of the nitrogen atoms of the ligands to ruthenium central metal atom. The introduction of the two vinyl monodentate ligands (vpdiinp and vpbpp) in the coordination sphere of [Ru(bdmpmar)(vpdiinp)(H2dcbpy)]2+, [Ru(bdmpmar) (vpbpp)(H2dcbpy)]2+, [Ru(H2dcbpy)2(N^)(NCS)]+, [Ru(H2dcbpy)2(N^)2]2+, [Ru(H2dcbpy)(N^)2(NCS)2], [Ru(H2dcbpy)(N^)(NCS)3]– and [Ru(vptpy)(H2dcbpy)(N^^^)]2+ respectively, all related to series II, III, IV, V, VI, VII and two compounds of series VIII ruthenium(II) complexes, has been studied using the 1H and 13C NMR spectroscopy techniques. The 1H NMR spectra of series II-VII and the two compounds of series VIII of the ruthenium(II) complexes show multiplets in the aromatic region above 6 ppm due to the presence of either vpdiinp or vpbpp ligand, situated in different magnetic environment. However, no splitting pattern was observed in series I and part of VIII complexes possibly due to the absence vinyl monodentate subunits (vpdiinp and vpbpp) in series I and one of compound in series VIII ruthenium(II) complexes show no signals of complex splitting patterns. Carbon-13 NMR spectra data of series I to VIII ruthenium(II) complexes show most resonance signals range in the aromatic region of (δ 116.54-199.63ppm) corresponding to the molecular formulation of ruthenium(II) complexes incorporating 4,4-dicarboxy-2,2’-bipyridine, bdmpmar, vptpy, vpdiinp or vpbpp and NCS ligands respectively, depending on the intrinsic ligand variations. Carbon-13 NMR spectra data of series I, IV, VI VII and one compound in VIII show resonance peaks within the range 130-135 ppm are ascribed to NCS ligand confirming the presence of N-coordinated thiocyanate. Cyclic voltammograms of series I-IV and VI-VIII complexes display ruthenium-based oxidative peaks and the pyridines ligand-based reductive peaks. The redox behavior of complexes 4-12, 14-16, 18-20, 24-26 and 30 is dominated by the Ru(II)/R(III) redox couple in region (E1/2 between 0.53 and 1.18) and the pyridines ligand-based redox couples in the region between (E1/2 between −0.25 and −1.45). The photophysical property studies of the Ru(II) complexes are determined through the acquisitions of the absorption spectra, which tends to have profound effect on the short circuit current of DSSC. The absorption maxima were tuned by the introduction and variation of six (6) tripodal chelating ligands, two (2) vinyl monodentate ligands and one (1) vinyl tridentate ligand. From the studies, the results show that series IV, V, VI, VII and VIII complexes of molecular formula [Ru(H2dcbpy)2(N^)(NCS)]2+, [Ru(H2dcbpy)2(N^)2]2+, [Ru(H2dcbpy)(N^)2(NCS)2]2+, [Ru(H2dcbpy)(N^)(NCS)3]2+ and [Ru(vptpy)(H2dcbpy)(N^^^)]2+ respectively, have higher and multiple local absorption maxima near-IR region than the complexes of series I, II and III of molecular [Ru(bdmpmar)(H2dcbpy)(NCS)]2,+, [Ru(bdmpmar)(vpdiinp)(H2dcbpy)]2,+, [Ru(bdmpmar)(vpbpp)(H2dcbpy)]2,+respectively.
- Full Text:
- Authors: Adjogri, Shadrack John
- Date: 2018
- Subjects: Ruthenium Ruthenium compounds
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/17828 , vital:41363
- Description: Eight series of thirty (30) novel heteroleptic ruthenium(II) complexes were designed, synthesized and spectroscopically characterized, with the following general molecular formulae as [Ru(bdmpmar)(H2dcbpy)(NCS)]+, [Ru(bdmpmar)(vpdiinp)(H2dcbpy)]2,+, [Ru(bdmpmar)(vpbpp)(H2dcbpy)]2+,[Ru(H2dcbpy)2(N^)(NCS)]+, [Ru(H2dcbpy)2(N^)2]2+, [Ru(H2dcbpy)(N^)2(NCS)2], [Ru(H2dcbpy)(N^)(NCS)3]– and [Ru(vptpy)(H2dcbpy)(N^^^)]2+ where bdmpmar is a tridentate ligand of N,N-bis(3, 5-dimethylpyrazol-1-yl-methyl) aromatic organic compound (such aromatic organic compounds(Ar) are anthranilic acid, 4-methoxy-2-nitroaniline, aniline, toluidine, cyclohexylamine and anisidine), vpdiinp represents a monodentate ligand of 11-(4-vinylphenyl)diindeno[1,2-b:2’,1’-e]pyridine, vpbpp represents a monodentate ligand of 4-(4-vinylphenyl)-2.6-bis(phenyl)pyridine and vptpy represents a tridentate ligand of 4’-(4-vinyl)-2,2’:6’,2’’-terpyridine. Meanwhile, N^ represents any of the monodentate ligands of either vpdiinp or vpbpp and (N^^^) represents any of the monodentate ligands either of vpdiinp or vpbpp or NCS as disclosed in series VIII. The complexes were characterized by conductivity measurement, solubility, melting point, UV-Vis, PL, FTIR (ATR), NMR, Cyclic and square wave voltammetry. Nine chelating ligands, comprising of six (6) tripodal chelating ligands, two (2) vinyl monodentate ligands and one (1) vinyl tridentate ligand, were used for the synthesis of ruthenium(II) complexes ATR-FTIR spectra of all the ruthenium(II) complexes measured as solid samples, exhibited fine resolution IR bands in region between 3473-3438 cm-1 of carboxylic group in H2dcbpy. The bands in the range 3040-2950 cm-1 were ascribed to C-H bond stretching for the CH3 groups. The coordination of NCS group in the sphere of ruthenium(II) complexes related to series I, IV, VI VII and one compound of series VIII was investigated by ATR-FTIR spectroscopy. Bands in the range of 2116-2106 cm-1 and 777-770 cm-1 are ascribed to the respective N=C and the C=S bond stretching vibration which confirms the N-coordination of the SCN group. For all the complexes, the stretching vibration of Ru-N bonding was between 466 and 411 cm-1 due to coordination of the nitrogen atoms of the ligands to ruthenium central metal atom. The introduction of the two vinyl monodentate ligands (vpdiinp and vpbpp) in the coordination sphere of [Ru(bdmpmar)(vpdiinp)(H2dcbpy)]2+, [Ru(bdmpmar) (vpbpp)(H2dcbpy)]2+, [Ru(H2dcbpy)2(N^)(NCS)]+, [Ru(H2dcbpy)2(N^)2]2+, [Ru(H2dcbpy)(N^)2(NCS)2], [Ru(H2dcbpy)(N^)(NCS)3]– and [Ru(vptpy)(H2dcbpy)(N^^^)]2+ respectively, all related to series II, III, IV, V, VI, VII and two compounds of series VIII ruthenium(II) complexes, has been studied using the 1H and 13C NMR spectroscopy techniques. The 1H NMR spectra of series II-VII and the two compounds of series VIII of the ruthenium(II) complexes show multiplets in the aromatic region above 6 ppm due to the presence of either vpdiinp or vpbpp ligand, situated in different magnetic environment. However, no splitting pattern was observed in series I and part of VIII complexes possibly due to the absence vinyl monodentate subunits (vpdiinp and vpbpp) in series I and one of compound in series VIII ruthenium(II) complexes show no signals of complex splitting patterns. Carbon-13 NMR spectra data of series I to VIII ruthenium(II) complexes show most resonance signals range in the aromatic region of (δ 116.54-199.63ppm) corresponding to the molecular formulation of ruthenium(II) complexes incorporating 4,4-dicarboxy-2,2’-bipyridine, bdmpmar, vptpy, vpdiinp or vpbpp and NCS ligands respectively, depending on the intrinsic ligand variations. Carbon-13 NMR spectra data of series I, IV, VI VII and one compound in VIII show resonance peaks within the range 130-135 ppm are ascribed to NCS ligand confirming the presence of N-coordinated thiocyanate. Cyclic voltammograms of series I-IV and VI-VIII complexes display ruthenium-based oxidative peaks and the pyridines ligand-based reductive peaks. The redox behavior of complexes 4-12, 14-16, 18-20, 24-26 and 30 is dominated by the Ru(II)/R(III) redox couple in region (E1/2 between 0.53 and 1.18) and the pyridines ligand-based redox couples in the region between (E1/2 between −0.25 and −1.45). The photophysical property studies of the Ru(II) complexes are determined through the acquisitions of the absorption spectra, which tends to have profound effect on the short circuit current of DSSC. The absorption maxima were tuned by the introduction and variation of six (6) tripodal chelating ligands, two (2) vinyl monodentate ligands and one (1) vinyl tridentate ligand. From the studies, the results show that series IV, V, VI, VII and VIII complexes of molecular formula [Ru(H2dcbpy)2(N^)(NCS)]2+, [Ru(H2dcbpy)2(N^)2]2+, [Ru(H2dcbpy)(N^)2(NCS)2]2+, [Ru(H2dcbpy)(N^)(NCS)3]2+ and [Ru(vptpy)(H2dcbpy)(N^^^)]2+ respectively, have higher and multiple local absorption maxima near-IR region than the complexes of series I, II and III of molecular [Ru(bdmpmar)(H2dcbpy)(NCS)]2,+, [Ru(bdmpmar)(vpdiinp)(H2dcbpy)]2,+, [Ru(bdmpmar)(vpbpp)(H2dcbpy)]2,+respectively.
- Full Text:
Synthesis, characterization, and biological studies of pyrazolone Schiff bases and their transition metal complexes
- Authors: Idemudia, Omoruyi Gold
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11340 , http://hdl.handle.net/10353/d1016068
- Description: Some new acylpyrazolone Schiff bases have been synthesized from the condensation reaction of two acylpyrazolone diketone precursors with phenylhydrazine, 2,4-dinitrophenylhydrazine and sulfanilamide. They have been fully characterized by elemental analysis and spectroscopic techniques (IR,1H and 13C NMR, and mass-spectra). The single crystal structure of the benzoyl derivative acylpyrazolone Schiff bases have been obtained and analyzed by X-ray crystallography technique. Solid state X-ray diffraction revealed a keto tautomer Schiff base in solid state. Mn(II), Co(II), Ni(II) and Cu(II) complexes with the Schiff bases have been synthesized and characterized by elemental analysis, IR and UV-VIS spectroscopy, magnetic susceptibility measurements, and thermal studies (TGA and DTG). An octahedral geometry around the transition metal ion, consisting of two bidentate Schiff base ligands bonding through the azometine nitrogen and ketonic oxygen have been proposed based on careful interpretation of available analytical and spectroscopic characterization results. Two water molecules as ligands complete the octahedral geometry in all cases. Using the invitro disc diffusion method for screening synthesized compounds against selected gram positive and gram negative bacterial at 40 mg/mL, and the DPPH free radical scavenging methods at 0.50, 0.25 and 0.13 mg/mL, the synthesized Schiff base and metal complexes showed varying biological activities. 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one sul29 fanilamide showed more activity generally, exhibiting a broad spectrum activity against all selected bacterial in some cases. Mn(II), Co(II) and Ni(II) complexes of sulfanilamide Schiff base with the acetylpyrazolone derivative 4-acetyl-3-methyl-1-phenyl-2-pyrazolin-5-one sulfanilamide, exhibited a stronger and very good DPPH radical scavenging activity as good as ascorbic acid on comparing, but not with Cu(II). As such they could be important antitumour candidates.
- Full Text:
- Authors: Idemudia, Omoruyi Gold
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11340 , http://hdl.handle.net/10353/d1016068
- Description: Some new acylpyrazolone Schiff bases have been synthesized from the condensation reaction of two acylpyrazolone diketone precursors with phenylhydrazine, 2,4-dinitrophenylhydrazine and sulfanilamide. They have been fully characterized by elemental analysis and spectroscopic techniques (IR,1H and 13C NMR, and mass-spectra). The single crystal structure of the benzoyl derivative acylpyrazolone Schiff bases have been obtained and analyzed by X-ray crystallography technique. Solid state X-ray diffraction revealed a keto tautomer Schiff base in solid state. Mn(II), Co(II), Ni(II) and Cu(II) complexes with the Schiff bases have been synthesized and characterized by elemental analysis, IR and UV-VIS spectroscopy, magnetic susceptibility measurements, and thermal studies (TGA and DTG). An octahedral geometry around the transition metal ion, consisting of two bidentate Schiff base ligands bonding through the azometine nitrogen and ketonic oxygen have been proposed based on careful interpretation of available analytical and spectroscopic characterization results. Two water molecules as ligands complete the octahedral geometry in all cases. Using the invitro disc diffusion method for screening synthesized compounds against selected gram positive and gram negative bacterial at 40 mg/mL, and the DPPH free radical scavenging methods at 0.50, 0.25 and 0.13 mg/mL, the synthesized Schiff base and metal complexes showed varying biological activities. 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one sul29 fanilamide showed more activity generally, exhibiting a broad spectrum activity against all selected bacterial in some cases. Mn(II), Co(II) and Ni(II) complexes of sulfanilamide Schiff base with the acetylpyrazolone derivative 4-acetyl-3-methyl-1-phenyl-2-pyrazolin-5-one sulfanilamide, exhibited a stronger and very good DPPH radical scavenging activity as good as ascorbic acid on comparing, but not with Cu(II). As such they could be important antitumour candidates.
- Full Text:
Effect of pre-slaughter stress of pigs on the levels of cortisol, creatine kinase and their subsequent relationship with pork quality
- Authors: Nzolo, Jama
- Date: 2014
- Subjects: Slaughtering and slaughter-houses , Pork -- Quality , Swine -- Handling , Livestock -- Handling , Creatine kinase
- Language: English
- Type: Thesis , Masters , MSc Agric (Animal Science)
- Identifier: vital:11837 , http://hdl.handle.net/10353/d1021287 , Slaughtering and slaughter-houses , Pork -- Quality , Swine -- Handling , Livestock -- Handling , Creatine kinase
- Description: The study was conducted to determine the effect of pre-slaughter stress of pigs on the levels of cortisol, creatine kinase (CK) and their subsequent relationship with pork quality. From our knowledge, there is paucity of information on transportation, lairage duration and sex effects on saliva cortisol and its relation with serum cortisol, urine cortisol and other meat quality traits. Stage one of the study assessed the effect of sex and time to slaughter (transport and lairage duration) on the levels of cortisol and CK in crossbred pigs. The second stage of the study evaluated the effect of sex and lairage duration on pork quality. The trials comprised of 60 22-weeks old commercial crossbred pigs [(30 boars vs. 30 gilts) with an average body weight of 76.9kg for gilts and 78.3kg for boars. Thirty pigs (15 Boars vs. 15 Gilts) were slaughtered on arrival after a 120km road journey and the other 30, after travelling the same road and distance, were slaughtered after having been in the lairage for 20 hours. Saliva samples were obtained during three time periods: between 07:00-10:00 on the day before the journey, on arrival at the abattoir and after lairage. Levels of cortisol in serum and urine and CK in serum samples collected at slaughter were determined. The samples (saliva and serum) were centrifuged at 20oC for 10 min at 3550 x g and stored at -20oC in separate vials until analysis. Pork quality was assessed using muscle pH, colour, thawing and cooking losses and Warner-Bratzler Shear Force. Correlations between cortisol levels in saliva, serum and urine and meat quality were assessed. The effect of sex and time to slaughter on saliva cortisol was significant. Statistical analysis showed significant interaction of sex by time to slaughter on serum cortisol. It was only the effect of sex that demonstrated higher (P <0.05) serum creatine kinase levels in gilts. Likewise, urine cortisol was influenced (P <0.05) only by time to slaughter. Saliva cortisol after transportation (r = 0.52) was correlated (P <0.05) with urine cortisol. The study suggests that there are greater responses of the Hypothalamic-pituitary-adrenal axis following time to slaughter (transport and lairage duration) between gilts and boars. This can be used in measuring cortisol in saliva, serum and urine, and serum creatine kinase to determine stress levels in pigs. Besides the lightness (L*) colour value which was significantly lower (P <0.05) in meat from gilts than from boars, the results of this study showed no interaction or individual effect (sex or lairage duration) on pH and other colour measurements. Meat cooking loss was affected (P <0.05) by gender x lairage interaction. Effect of lairage duration (as an individual effect) on the measured meat quality traits was not significant (P <0.05). Correlation analysis showed significant (P <0.05) negative relation between baseline saliva cortisol (r = -0.40) and the pork L* value. Saliva cortisol after lairage duration (r = -0.38 and r = 0.38) was correlated (P <0.05) with pH45 and pork a* value, respectively. Serum cortisol (r = -0.35) was negatively correlated (P <0.05) with pH45. Moreover, there were negative correlations (P <0.05) between saliva cortisol after transportation (r = -0.35), saliva cortisol after lairage duration (r = -0.44), serum cortisol (r = -0.40) and meat cooking loss. The study suggests that cortisol in saliva and serum can be used to determine effect of time to slaughter (transport and lairage duration) on meat quality traits from gilts and boars. Keywords: Boars; gilts; saliva cortisol; serum cortisol; serum creatine kinase; urine cortisol.
- Full Text:
- Authors: Nzolo, Jama
- Date: 2014
- Subjects: Slaughtering and slaughter-houses , Pork -- Quality , Swine -- Handling , Livestock -- Handling , Creatine kinase
- Language: English
- Type: Thesis , Masters , MSc Agric (Animal Science)
- Identifier: vital:11837 , http://hdl.handle.net/10353/d1021287 , Slaughtering and slaughter-houses , Pork -- Quality , Swine -- Handling , Livestock -- Handling , Creatine kinase
- Description: The study was conducted to determine the effect of pre-slaughter stress of pigs on the levels of cortisol, creatine kinase (CK) and their subsequent relationship with pork quality. From our knowledge, there is paucity of information on transportation, lairage duration and sex effects on saliva cortisol and its relation with serum cortisol, urine cortisol and other meat quality traits. Stage one of the study assessed the effect of sex and time to slaughter (transport and lairage duration) on the levels of cortisol and CK in crossbred pigs. The second stage of the study evaluated the effect of sex and lairage duration on pork quality. The trials comprised of 60 22-weeks old commercial crossbred pigs [(30 boars vs. 30 gilts) with an average body weight of 76.9kg for gilts and 78.3kg for boars. Thirty pigs (15 Boars vs. 15 Gilts) were slaughtered on arrival after a 120km road journey and the other 30, after travelling the same road and distance, were slaughtered after having been in the lairage for 20 hours. Saliva samples were obtained during three time periods: between 07:00-10:00 on the day before the journey, on arrival at the abattoir and after lairage. Levels of cortisol in serum and urine and CK in serum samples collected at slaughter were determined. The samples (saliva and serum) were centrifuged at 20oC for 10 min at 3550 x g and stored at -20oC in separate vials until analysis. Pork quality was assessed using muscle pH, colour, thawing and cooking losses and Warner-Bratzler Shear Force. Correlations between cortisol levels in saliva, serum and urine and meat quality were assessed. The effect of sex and time to slaughter on saliva cortisol was significant. Statistical analysis showed significant interaction of sex by time to slaughter on serum cortisol. It was only the effect of sex that demonstrated higher (P <0.05) serum creatine kinase levels in gilts. Likewise, urine cortisol was influenced (P <0.05) only by time to slaughter. Saliva cortisol after transportation (r = 0.52) was correlated (P <0.05) with urine cortisol. The study suggests that there are greater responses of the Hypothalamic-pituitary-adrenal axis following time to slaughter (transport and lairage duration) between gilts and boars. This can be used in measuring cortisol in saliva, serum and urine, and serum creatine kinase to determine stress levels in pigs. Besides the lightness (L*) colour value which was significantly lower (P <0.05) in meat from gilts than from boars, the results of this study showed no interaction or individual effect (sex or lairage duration) on pH and other colour measurements. Meat cooking loss was affected (P <0.05) by gender x lairage interaction. Effect of lairage duration (as an individual effect) on the measured meat quality traits was not significant (P <0.05). Correlation analysis showed significant (P <0.05) negative relation between baseline saliva cortisol (r = -0.40) and the pork L* value. Saliva cortisol after lairage duration (r = -0.38 and r = 0.38) was correlated (P <0.05) with pH45 and pork a* value, respectively. Serum cortisol (r = -0.35) was negatively correlated (P <0.05) with pH45. Moreover, there were negative correlations (P <0.05) between saliva cortisol after transportation (r = -0.35), saliva cortisol after lairage duration (r = -0.44), serum cortisol (r = -0.40) and meat cooking loss. The study suggests that cortisol in saliva and serum can be used to determine effect of time to slaughter (transport and lairage duration) on meat quality traits from gilts and boars. Keywords: Boars; gilts; saliva cortisol; serum cortisol; serum creatine kinase; urine cortisol.
- Full Text:
Psychosocial experiences of caregivers of mentally challenged children in Alice, Eastern Cape
- Authors: Mmangaliso, Azola
- Date: 2021-08
- Subjects: Caregivers , Children with disabilities--Psychology , Children with mental disabilities
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/21025 , vital:46904
- Description: There is dearth of information in South Africa about the psychosocial challenges experienced by caregivers of mentally challenged children. This study addresses psychosocial experiences of caregivers, such as, scorning, isolation and anxiety, which affect their well-being in adverse ways, and that continues to be overlooked by professionals dealing with mental health. This study sought to explore psychosocial experiences of caregivers of mentally challenged children in Alice in the Eastern Cape in South Africa. The study intended to uncover the psychosocial wellbeing of caregivers of mentally challenged children. Secondly, it set out to highlight the coping mechanisms employed by caregivers of mentally challenged children to deal with their psychosocial experiences. Lastly, the study sought to examine policies, legislation and support services in place for psychosocial care of caregivers of mentally challenged children. The researcher adopted qualitative research methods. Snowball sampling was employed to recruit 15 caregivers of mentally challenged children in Alice. The age of the caregivers ranged between the ages of 20 and 65. In addition, purposive sampling was adopted to recruit six professionals working with mental health in Alice. All the participants were black Africans. The gender comprised of thirteen females and two males. Data was collected through the use of face-to-face, semi-structured individual interviews, one interview per research participant, with the caregivers of mentally challenged children, and through the use of one focus group discussion with professionals dealing with mental health. The researcher analysed data through thematic content analysis. The study findings indicate that caregivers of mentally challenged children experience the caregiving process negatively, with a lot of burden. It also appears that they do not cope positively with such experiences despite professionally-trained personnel that are obliged by the Social Assistance Act and other government policies to ensure that caregivers receive sufficient psychosocial services. Findings also indicate that there is very little that is done by the relevant professionals in ensuring that they render sufficient professional support services to caregivers, such as needs assessment and therapeutic services. In light of the findings, the study concludes that there is a need for continuous rendering of comprehensive psychosocial support services to the caregivers of mentally challenged children. It is also recommended that social workers empower caregivers for mentally challenged children so that they can function effectively in their communities. Further, the government needs to reinforce existing policies that afford these psychosocial services, such as Integrated National Strategy on Support Services to Children with Disabilities. Meaning, the government should take an oversite role of these policies and monitor whether they get implemented or not, especially at grassroots level. , Thesis (MSoc Sci) (Social Work) -- University of Fort Hare, 2021
- Full Text:
- Authors: Mmangaliso, Azola
- Date: 2021-08
- Subjects: Caregivers , Children with disabilities--Psychology , Children with mental disabilities
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/21025 , vital:46904
- Description: There is dearth of information in South Africa about the psychosocial challenges experienced by caregivers of mentally challenged children. This study addresses psychosocial experiences of caregivers, such as, scorning, isolation and anxiety, which affect their well-being in adverse ways, and that continues to be overlooked by professionals dealing with mental health. This study sought to explore psychosocial experiences of caregivers of mentally challenged children in Alice in the Eastern Cape in South Africa. The study intended to uncover the psychosocial wellbeing of caregivers of mentally challenged children. Secondly, it set out to highlight the coping mechanisms employed by caregivers of mentally challenged children to deal with their psychosocial experiences. Lastly, the study sought to examine policies, legislation and support services in place for psychosocial care of caregivers of mentally challenged children. The researcher adopted qualitative research methods. Snowball sampling was employed to recruit 15 caregivers of mentally challenged children in Alice. The age of the caregivers ranged between the ages of 20 and 65. In addition, purposive sampling was adopted to recruit six professionals working with mental health in Alice. All the participants were black Africans. The gender comprised of thirteen females and two males. Data was collected through the use of face-to-face, semi-structured individual interviews, one interview per research participant, with the caregivers of mentally challenged children, and through the use of one focus group discussion with professionals dealing with mental health. The researcher analysed data through thematic content analysis. The study findings indicate that caregivers of mentally challenged children experience the caregiving process negatively, with a lot of burden. It also appears that they do not cope positively with such experiences despite professionally-trained personnel that are obliged by the Social Assistance Act and other government policies to ensure that caregivers receive sufficient psychosocial services. Findings also indicate that there is very little that is done by the relevant professionals in ensuring that they render sufficient professional support services to caregivers, such as needs assessment and therapeutic services. In light of the findings, the study concludes that there is a need for continuous rendering of comprehensive psychosocial support services to the caregivers of mentally challenged children. It is also recommended that social workers empower caregivers for mentally challenged children so that they can function effectively in their communities. Further, the government needs to reinforce existing policies that afford these psychosocial services, such as Integrated National Strategy on Support Services to Children with Disabilities. Meaning, the government should take an oversite role of these policies and monitor whether they get implemented or not, especially at grassroots level. , Thesis (MSoc Sci) (Social Work) -- University of Fort Hare, 2021
- Full Text:
Critical assessment of leadership skills in developmental local government: a case study of Buffalo City Municipality in the Eastern Cape
- Mnyatheli, Mbeko Bandla Sizasomzi
- Authors: Mnyatheli, Mbeko Bandla Sizasomzi
- Date: 2011-01
- Subjects: Leadership , Municipal government , Buffalo City (South Africa)
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26175 , vital:64950
- Description: This study seeks to examine the nature and role of leadership, in pursuit of a suitable leadership for a Developmental Local Government environment. The aim of this study is to describe the nature of leadership, particularly in local government, and in public organization in general. The study begins by teasing out the various concepts and terminology attendant with leadership in this environment. The study further reviews relevant literature as basis for understanding and goes on to interrogate the general theories on leadership with a view to choose the best practice in leadership of a developmental local government. Central to its quest for answers, is the drive from the constitutional mandate, a developmental local government imposed to municipality by the constitution of the Republic of South Africa, (1996) arising out of the need to transform the South African local government from an erstwhile policy of racial segregation to a new democratic political dispensation fostering equity and access to services and resources for all citizens. The challenge for the new leadership therefore is how to deal, speedily with the huge disparities and socio-economic backlogs? What kind of leadership and what level of knowledge, skills and competencies are required and how soon can public goods and services be delivered to the satisfaction of the communities it serves? ‘Analysis of variance’ was used to analyse and interpret data collected. Literature on the difference between transactional and transformational leadership formed the basis of the findings. Finally, findings and conclusions were drawn. On the bases of these, recommendations for Buffalo City Municipality were presented. , Thesis (MPA) -- Faculty of Management and Commerce, 2011
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- Authors: Mnyatheli, Mbeko Bandla Sizasomzi
- Date: 2011-01
- Subjects: Leadership , Municipal government , Buffalo City (South Africa)
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26175 , vital:64950
- Description: This study seeks to examine the nature and role of leadership, in pursuit of a suitable leadership for a Developmental Local Government environment. The aim of this study is to describe the nature of leadership, particularly in local government, and in public organization in general. The study begins by teasing out the various concepts and terminology attendant with leadership in this environment. The study further reviews relevant literature as basis for understanding and goes on to interrogate the general theories on leadership with a view to choose the best practice in leadership of a developmental local government. Central to its quest for answers, is the drive from the constitutional mandate, a developmental local government imposed to municipality by the constitution of the Republic of South Africa, (1996) arising out of the need to transform the South African local government from an erstwhile policy of racial segregation to a new democratic political dispensation fostering equity and access to services and resources for all citizens. The challenge for the new leadership therefore is how to deal, speedily with the huge disparities and socio-economic backlogs? What kind of leadership and what level of knowledge, skills and competencies are required and how soon can public goods and services be delivered to the satisfaction of the communities it serves? ‘Analysis of variance’ was used to analyse and interpret data collected. Literature on the difference between transactional and transformational leadership formed the basis of the findings. Finally, findings and conclusions were drawn. On the bases of these, recommendations for Buffalo City Municipality were presented. , Thesis (MPA) -- Faculty of Management and Commerce, 2011
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Strategies employed by teachers to assist Grade 4 learners transition from mother tongue instruction to English as a medium of instruction
- Authors: Butler, Cynthia Desiree
- Date: 2021-01
- Subjects: English language -- Grammar -- Study and teaching , English language -- Study and teaching -- Foreign speakers
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/20035 , vital:45029
- Description: In most South African schools, there is a transition period, where lower primary learners receive instruction in their mother tongue from grades 1-3 and from grade 4 onwards, English becomes the medium of instruction. This study explored how learners in primary schools in Grade 4 learn through the medium of English, since IsiXhosa is their home language and they come from a community of pre-dominantly IsiXhosa speakers where English is seldom heard or spoken. The study is concerned with the language and literacy practices at this crucial transition, and investigated to what extent learners in the Grade 4 have learnt / been taught / have developed sufficient basic inter-personal communication skills, BICS, (Cummins, 2000), in isiXhosa to make the switch to learning all subjects in English. The theoretical frameworks adopted for this study was Cummins Language theories. Within this study an interpretive paradigm aligned with the qualitative approach and the case study design for understanding the phenomena, were adopted. The study covered three primary schools which were purposively selected. The participants comprised of six female teachers teaching Life Skills in Grade 4 from five mainstream schools were also purposively selected. Semi structured interviews, observation and document analyses were used as data collection instruments. A qualitative thematic approach was used for data analyses and the emerging results were organised into different themes reflecting participant’s responses. The findings revealed that teachers did not use lesson plans as they have indicated. Even though literature emphasises the importance of lesson planning, teachers find it tedious to plan. It was established that no assessment tasks were done when the lesson was concluded. Effective teaching without valid and reliable assessment tasks would result in meaningless teaching and learning interactions. It was revealed that teachers used teaching aids, but only a few. The information demonstrated that teachers did not code switch to assist with learner understanding. Instead, they presented their lessons in English which hampered learning. The study discovered that teachers used the old traditional style of teaching, instead of learner-centred instruction, which is interactive and participatory. The study exposed that the biggest challenges learners encountered, was the language of teaching and learning, English. However, the findings established that learners where unable to understand and express themselves in English. English lessons had minimal learner participation, because learners did not have the necessary competence and English was not their home language. The study further revealed that the English language leads to a barrier of effective learning and placed learners at a disadvantage. The findings further suggested that a lack of resources had an impact on teaching and learning which affected learners’ acquisition and understanding of the medium of instruction. The findings claimed that slow and progressed learners exist in classrooms and need individualised and specialised teaching. It was found that parental involvement, translation, learner participation, group work and teaching aids assisted with the challenges teachers encounter during transitioning in the subject Life Skills. It is recommended that the school develop a structured programme to provide support and assistance for teachers with lesson planning. Assessment task should be included in each lesson and should be viewed as an essential part of teaching and learning. Teachers should make use of multiple and a variety of teaching aids. Code switching and translation should be used, as it assists with understanding, accuracy and clarity. An appropriate mix of teaching styles should be used, to reach all leaners in a classroom. Teachers can improve learners English, by incorporating learners’ home language, code-switching and teaching aids in class. Slow and progressed learners could be assisted by using a variety of teaching materials, individual attention, remedial education, peer tutoring, differentiated teaching and curriculum adaptation. A structured learning support programme providing learning support for learners with barriers to learning, can be utilised. It is recommended that parents be involved in their children’s learning. The schools should set up effective monitoring and support mechanism for teachers in order to ensure that quality teaching and learning takes place in schools. Regular monitoring and evaluation by the DoE might assist to support teachers. A suggested framework of strategies in Life Skills, based on the findings of the study and extensive literature review, should contribute and assist with transitioning in Grade 4 in schools. , Thesis (DPhil) -- Faculty of Education, 2021
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- Authors: Butler, Cynthia Desiree
- Date: 2021-01
- Subjects: English language -- Grammar -- Study and teaching , English language -- Study and teaching -- Foreign speakers
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/20035 , vital:45029
- Description: In most South African schools, there is a transition period, where lower primary learners receive instruction in their mother tongue from grades 1-3 and from grade 4 onwards, English becomes the medium of instruction. This study explored how learners in primary schools in Grade 4 learn through the medium of English, since IsiXhosa is their home language and they come from a community of pre-dominantly IsiXhosa speakers where English is seldom heard or spoken. The study is concerned with the language and literacy practices at this crucial transition, and investigated to what extent learners in the Grade 4 have learnt / been taught / have developed sufficient basic inter-personal communication skills, BICS, (Cummins, 2000), in isiXhosa to make the switch to learning all subjects in English. The theoretical frameworks adopted for this study was Cummins Language theories. Within this study an interpretive paradigm aligned with the qualitative approach and the case study design for understanding the phenomena, were adopted. The study covered three primary schools which were purposively selected. The participants comprised of six female teachers teaching Life Skills in Grade 4 from five mainstream schools were also purposively selected. Semi structured interviews, observation and document analyses were used as data collection instruments. A qualitative thematic approach was used for data analyses and the emerging results were organised into different themes reflecting participant’s responses. The findings revealed that teachers did not use lesson plans as they have indicated. Even though literature emphasises the importance of lesson planning, teachers find it tedious to plan. It was established that no assessment tasks were done when the lesson was concluded. Effective teaching without valid and reliable assessment tasks would result in meaningless teaching and learning interactions. It was revealed that teachers used teaching aids, but only a few. The information demonstrated that teachers did not code switch to assist with learner understanding. Instead, they presented their lessons in English which hampered learning. The study discovered that teachers used the old traditional style of teaching, instead of learner-centred instruction, which is interactive and participatory. The study exposed that the biggest challenges learners encountered, was the language of teaching and learning, English. However, the findings established that learners where unable to understand and express themselves in English. English lessons had minimal learner participation, because learners did not have the necessary competence and English was not their home language. The study further revealed that the English language leads to a barrier of effective learning and placed learners at a disadvantage. The findings further suggested that a lack of resources had an impact on teaching and learning which affected learners’ acquisition and understanding of the medium of instruction. The findings claimed that slow and progressed learners exist in classrooms and need individualised and specialised teaching. It was found that parental involvement, translation, learner participation, group work and teaching aids assisted with the challenges teachers encounter during transitioning in the subject Life Skills. It is recommended that the school develop a structured programme to provide support and assistance for teachers with lesson planning. Assessment task should be included in each lesson and should be viewed as an essential part of teaching and learning. Teachers should make use of multiple and a variety of teaching aids. Code switching and translation should be used, as it assists with understanding, accuracy and clarity. An appropriate mix of teaching styles should be used, to reach all leaners in a classroom. Teachers can improve learners English, by incorporating learners’ home language, code-switching and teaching aids in class. Slow and progressed learners could be assisted by using a variety of teaching materials, individual attention, remedial education, peer tutoring, differentiated teaching and curriculum adaptation. A structured learning support programme providing learning support for learners with barriers to learning, can be utilised. It is recommended that parents be involved in their children’s learning. The schools should set up effective monitoring and support mechanism for teachers in order to ensure that quality teaching and learning takes place in schools. Regular monitoring and evaluation by the DoE might assist to support teachers. A suggested framework of strategies in Life Skills, based on the findings of the study and extensive literature review, should contribute and assist with transitioning in Grade 4 in schools. , Thesis (DPhil) -- Faculty of Education, 2021
- Full Text: