Osasimba>
- Minjolo Dulana and Co, not specified, composer not specified, Tracey, Hugh
- Authors: Minjolo Dulana and Co , not specified , composer not specified , Tracey, Hugh
- Date: 0000-00-00
- Subjects: Popular music--Africa , Field recordings , Africa, Sub-Saharan , Africa Zambia city not specified f-za
- Language: Nyanja
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/235075 , vital:50264 , International Library of African Music, Rhodes University, Makhanda, South Africa , Hugh Tracey Commercial Records, Rhodes University, Makhanda, South Africa , CR2847 , ABC12736
- Description: A song accompanied by banjo
- Full Text: false
- Date Issued: 0000-00-00
- Authors: Minjolo Dulana and Co , not specified , composer not specified , Tracey, Hugh
- Date: 0000-00-00
- Subjects: Popular music--Africa , Field recordings , Africa, Sub-Saharan , Africa Zambia city not specified f-za
- Language: Nyanja
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/235075 , vital:50264 , International Library of African Music, Rhodes University, Makhanda, South Africa , Hugh Tracey Commercial Records, Rhodes University, Makhanda, South Africa , CR2847 , ABC12736
- Description: A song accompanied by banjo
- Full Text: false
- Date Issued: 0000-00-00
Osasimba>
- Minjolo Dulana and Co, not specified, composer not specified, Tracey, Hugh
- Authors: Minjolo Dulana and Co , not specified , composer not specified , Tracey, Hugh
- Date: 0000-00-00
- Subjects: Popular music--Africa , Field recordings , Africa, Sub-Saharan , Africa Zambia city not specified f-za
- Language: Nyanja
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/235093 , vital:50266 , International Library of African Music, Rhodes University, Makhanda, South Africa , Hugh Tracey Commercial Records, Rhodes University, Makhanda, South Africa , CR2848 , ABC12736
- Description: A song accompanied by banjo
- Full Text: false
- Date Issued: 0000-00-00
- Authors: Minjolo Dulana and Co , not specified , composer not specified , Tracey, Hugh
- Date: 0000-00-00
- Subjects: Popular music--Africa , Field recordings , Africa, Sub-Saharan , Africa Zambia city not specified f-za
- Language: Nyanja
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/235093 , vital:50266 , International Library of African Music, Rhodes University, Makhanda, South Africa , Hugh Tracey Commercial Records, Rhodes University, Makhanda, South Africa , CR2848 , ABC12736
- Description: A song accompanied by banjo
- Full Text: false
- Date Issued: 0000-00-00
A nalichowa>
- Minjolo Dulana and Co, not specified, composer not specified, Tracey, Hugh
- Authors: Minjolo Dulana and Co , not specified , composer not specified , Tracey, Hugh
- Date: 0000-00-00
- Subjects: Popular music--Africa , Field recordings , Africa, Sub-Saharan , Africa Zambia city not specified f-za
- Language: Nyanja
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/235102 , vital:50267 , International Library of African Music, Rhodes University, Makhanda, South Africa , Hugh Tracey Commercial Records, Rhodes University, Makhanda, South Africa , CR2848 , ABC12741
- Description: A song accompanied by banjo and guitar
- Full Text: false
- Date Issued: 0000-00-00
- Authors: Minjolo Dulana and Co , not specified , composer not specified , Tracey, Hugh
- Date: 0000-00-00
- Subjects: Popular music--Africa , Field recordings , Africa, Sub-Saharan , Africa Zambia city not specified f-za
- Language: Nyanja
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/235102 , vital:50267 , International Library of African Music, Rhodes University, Makhanda, South Africa , Hugh Tracey Commercial Records, Rhodes University, Makhanda, South Africa , CR2848 , ABC12741
- Description: A song accompanied by banjo and guitar
- Full Text: false
- Date Issued: 0000-00-00
A nalichowa>
- Minjolo Dulana and Co, not specified, composer not specified, Tracey, Hugh
- Authors: Minjolo Dulana and Co , not specified , composer not specified , Tracey, Hugh
- Date: 0000-00-00
- Subjects: Popular music--Africa , Field recordings , Africa, Sub-Saharan , Africa Zambia city not specified f-za
- Language: Nyanja
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/235084 , vital:50265 , International Library of African Music, Rhodes University, Makhanda, South Africa , Hugh Tracey Commercial Records, Rhodes University, Makhanda, South Africa , CR2847 , ABC12741
- Description: A song accompanied by banjo and guitar
- Full Text: false
- Date Issued: 0000-00-00
- Authors: Minjolo Dulana and Co , not specified , composer not specified , Tracey, Hugh
- Date: 0000-00-00
- Subjects: Popular music--Africa , Field recordings , Africa, Sub-Saharan , Africa Zambia city not specified f-za
- Language: Nyanja
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/235084 , vital:50265 , International Library of African Music, Rhodes University, Makhanda, South Africa , Hugh Tracey Commercial Records, Rhodes University, Makhanda, South Africa , CR2847 , ABC12741
- Description: A song accompanied by banjo and guitar
- Full Text: false
- Date Issued: 0000-00-00
Osasimba
- Minjolo Dulana, Composer not specified, Tracey, Hugh
- Authors: Minjolo Dulana , Composer not specified , Tracey, Hugh
- Date: 0000 00 00
- Subjects: Popular music--Africa , Field recordings , Africa, Sub-Saharan , Africa Malawi city not specified f-mw
- Language: Nyanja
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/266110 , vital:53920 , International Library of African Music, Rhodes University, Makhanda, South Africa , Hugh Tracey Commercial Records, Rhodes University, Makhanda, South Africa , TP0499-ABC12736
- Description: Indigenous music
- Full Text: false
- Date Issued: 0000 00 00
- Authors: Minjolo Dulana , Composer not specified , Tracey, Hugh
- Date: 0000 00 00
- Subjects: Popular music--Africa , Field recordings , Africa, Sub-Saharan , Africa Malawi city not specified f-mw
- Language: Nyanja
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/266110 , vital:53920 , International Library of African Music, Rhodes University, Makhanda, South Africa , Hugh Tracey Commercial Records, Rhodes University, Makhanda, South Africa , TP0499-ABC12736
- Description: Indigenous music
- Full Text: false
- Date Issued: 0000 00 00
Agreement and coordination in XiTsonga, SeSotho and IsiXhosa: an optimality theoretic perspective
- Authors: Mitchley, Hazel
- Date: 2016
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/3423 , vital:20491
- Description: This thesis provides a unified Optimality Theoretic analysis of subject-verb agreement with coordinated preverbal subjects in three Southern Bantu languages: Xitsonga (S53), Sesotho (S33), and isiXhosa (S41). This analysis is then used to formulate a typology of agreement resolution strategies and the contexts which trigger them. Although some accounts in the Bantu literature suggest that agreement with coordinate structures is avoided by speakers (e.g. Schadeberg 1992, Voeltz 1971) especially when conjuncts are from different noun classes, I show that there is ample evidence to the contrary, and that the subject marker used is dependent on several factors, including (i) the [-HUMAN] specification on the conjuncts, (ii) whether the conjuncts are singular or plural, (iii) whether or not the conjuncts both carry the same noun class feature, and (iv) the order of the conjuncts. This thesis shows that there are various agreement resolution strategies which can beused: 1) agreement with the [+HUMAN] feature on the conjuncts, 2) agreement with the[-HUMAN] feature on the conjuncts, 3) agreement with the noun class feature on both conjuncts, 4) agreement with the noun class feature on the conjunct closest to the verb, and 5) agreement with the noun class feature on the conjunct furthest from the verb. Not all of these strategies are used by all languages, nor are these strategies interchangeable in the languages which do use them – instead, multiple factors conspire to trigger the use of a specific agreement strategy within a specific agreement featural context. I show that these effects can be captured using Optimality Theory (Prince and Smolensky 2004). The analysis makes use of seven constraints: RES#, MAX[+H], MAX[-H], DEP[-H], MAXNC, DEPNC, and AGREECLOSEST. The hierarchical ranking of these constraints not only accounts for the confinement of particular strategies to specific agreement featural contexts within a language, but also accounts for the cross-linguistic differences in the use of these strategies. I end off by examining the typological implications which follow from the OT analysis provided in this thesis.
- Full Text:
- Date Issued: 2016
- Authors: Mitchley, Hazel
- Date: 2016
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/3423 , vital:20491
- Description: This thesis provides a unified Optimality Theoretic analysis of subject-verb agreement with coordinated preverbal subjects in three Southern Bantu languages: Xitsonga (S53), Sesotho (S33), and isiXhosa (S41). This analysis is then used to formulate a typology of agreement resolution strategies and the contexts which trigger them. Although some accounts in the Bantu literature suggest that agreement with coordinate structures is avoided by speakers (e.g. Schadeberg 1992, Voeltz 1971) especially when conjuncts are from different noun classes, I show that there is ample evidence to the contrary, and that the subject marker used is dependent on several factors, including (i) the [-HUMAN] specification on the conjuncts, (ii) whether the conjuncts are singular or plural, (iii) whether or not the conjuncts both carry the same noun class feature, and (iv) the order of the conjuncts. This thesis shows that there are various agreement resolution strategies which can beused: 1) agreement with the [+HUMAN] feature on the conjuncts, 2) agreement with the[-HUMAN] feature on the conjuncts, 3) agreement with the noun class feature on both conjuncts, 4) agreement with the noun class feature on the conjunct closest to the verb, and 5) agreement with the noun class feature on the conjunct furthest from the verb. Not all of these strategies are used by all languages, nor are these strategies interchangeable in the languages which do use them – instead, multiple factors conspire to trigger the use of a specific agreement strategy within a specific agreement featural context. I show that these effects can be captured using Optimality Theory (Prince and Smolensky 2004). The analysis makes use of seven constraints: RES#, MAX[+H], MAX[-H], DEP[-H], MAXNC, DEPNC, and AGREECLOSEST. The hierarchical ranking of these constraints not only accounts for the confinement of particular strategies to specific agreement featural contexts within a language, but also accounts for the cross-linguistic differences in the use of these strategies. I end off by examining the typological implications which follow from the OT analysis provided in this thesis.
- Full Text:
- Date Issued: 2016
Petrographic and geochemical characterisation of the hangingwall and the footwall rocks (the Dipeta and R.A.T. stratigraphic units) to the Kinsevere and Nambulwa copper ore deposits of the Lufilian Arc, southern Democratic Republic of Congo
- Authors: Nkulu, Robert Kankomba
- Date: 2020
- Subjects: Petrogenesis -- Congo (Democratic Republic) , Analytical geochemistry -- Congo (Democratic Republic) , Copper ores -- Congo (Democratic Republic) , Ore deposits -- Congo (Democratic Republic) , Katangan Sequence , Geological mapping -- Congo (Democratic Republic) , Central African Copperbelt (Congo and Zambia) , Lufilian Arc , Neoproterozoic Katangan R.A.T. (Roches Argilo Talqueuse) Subgroup , Dipeta Subgroup
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/142772 , vital:38115
- Description: The Kinsevere and Nambulwa copper deposits in the Democratic Republic of Congo (D.R.C.) are set in the eastern side of the Neoproterozoic Katanga Supergroup, forming the Lufilian Arc, resulting from a cratonic collision between the Congo and the Kalahari Cratons (ca.620-570_Ma). The Katanga Supergroup was deposited in an extensional rift setting with a sedimentary thickness succession ranging between 7 to 10 km, sub-divided into: − the Roan, the Nguba and the Kundelungu Groups. The stratigraphic column of the Roan Group consists of the R.A.T. (Roche Argilo Talqueuse), the Mines, the Dipeta and the Mwashya Subgroups. Three major deformation phases have been described characterised by complex multiphase tectonics related to a curved superposition of folded, thrust and sheared blocks. The rocks of the R.A.T., Mines and Dipeta Subgroups are recognised as blocks that occur within a stratiform to discordant and diapiritic megabreccia. The blocks were rafted upward with salt tectonics, resulting in the juxtaposition with the hangingwall and the footwall terranes. Therefore, in that context it has been found that the Dipeta may appear overlying the R.A.T. Subgroup through the unconformity decollement surface of heterogeneous breccia. The petrographic observations made of the R.A.T. and Dipeta samples indicates in both units the presence of detrital quartz and feldspar that have been altered and replaced by sericite and muscovite minerals. Gypsum is intimately associated with magnesite, showing an evaporitic environment domain, while magnesite is common as alteration phase both in the R.A.T. and Dipeta Subgroups. Pyrophyllite has been observed in the Dipeta, resulting from reaction of silica with the Kaolinite at low temperature. Accessory detrital minerals include zircon, as well as xenotime intergrown with altered Fe-Ti-oxide hematite, forming complex textures with disseminated Ti-oxides both in R.A.T. and Dipeta units. Major and trace element geochemistry indicates that the Dipeta is more dolomitic and magnesite while the R.A.T. is clay-rich. The Ti2O value of Dipeta and R.A.T samples is relatively low, ranging between 0.36 and 0.69 wt.% respectively, which suggest highly evolved felsic material in the protolith. This is consistent with interpretation based on the Al2O3/TiO2 ratio, which ranges between 18 and 23 for the R.A.T. and Dipeta respectively, indicating an intermediate to felsic granitoids as the protolith of R.A.T. and Dipeta siltstones. The Ti/Zr ratio of R.A.T. and Dipeta samples of less than 10, while, the higher La/Sc ratio of between 2.6 and 5.5 (for the R.A.T. and Dipeta respectively) indicate that both the R.A.T. and Dipeta are active continental and passive margin tectonic setting. Based on the geochemical variation with depth across the R.A.T. and Dipeta and their contact zone, a geochemical fingerprinting suggests that the ratio TiO2/Al2O3 appears to be useful and could be considered as a stratigraphic geochemical maker able to discriminate the R.A.T. and the Dipeta Subgroups during the geological mapping.
- Full Text:
- Date Issued: 2020
- Authors: Nkulu, Robert Kankomba
- Date: 2020
- Subjects: Petrogenesis -- Congo (Democratic Republic) , Analytical geochemistry -- Congo (Democratic Republic) , Copper ores -- Congo (Democratic Republic) , Ore deposits -- Congo (Democratic Republic) , Katangan Sequence , Geological mapping -- Congo (Democratic Republic) , Central African Copperbelt (Congo and Zambia) , Lufilian Arc , Neoproterozoic Katangan R.A.T. (Roches Argilo Talqueuse) Subgroup , Dipeta Subgroup
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/142772 , vital:38115
- Description: The Kinsevere and Nambulwa copper deposits in the Democratic Republic of Congo (D.R.C.) are set in the eastern side of the Neoproterozoic Katanga Supergroup, forming the Lufilian Arc, resulting from a cratonic collision between the Congo and the Kalahari Cratons (ca.620-570_Ma). The Katanga Supergroup was deposited in an extensional rift setting with a sedimentary thickness succession ranging between 7 to 10 km, sub-divided into: − the Roan, the Nguba and the Kundelungu Groups. The stratigraphic column of the Roan Group consists of the R.A.T. (Roche Argilo Talqueuse), the Mines, the Dipeta and the Mwashya Subgroups. Three major deformation phases have been described characterised by complex multiphase tectonics related to a curved superposition of folded, thrust and sheared blocks. The rocks of the R.A.T., Mines and Dipeta Subgroups are recognised as blocks that occur within a stratiform to discordant and diapiritic megabreccia. The blocks were rafted upward with salt tectonics, resulting in the juxtaposition with the hangingwall and the footwall terranes. Therefore, in that context it has been found that the Dipeta may appear overlying the R.A.T. Subgroup through the unconformity decollement surface of heterogeneous breccia. The petrographic observations made of the R.A.T. and Dipeta samples indicates in both units the presence of detrital quartz and feldspar that have been altered and replaced by sericite and muscovite minerals. Gypsum is intimately associated with magnesite, showing an evaporitic environment domain, while magnesite is common as alteration phase both in the R.A.T. and Dipeta Subgroups. Pyrophyllite has been observed in the Dipeta, resulting from reaction of silica with the Kaolinite at low temperature. Accessory detrital minerals include zircon, as well as xenotime intergrown with altered Fe-Ti-oxide hematite, forming complex textures with disseminated Ti-oxides both in R.A.T. and Dipeta units. Major and trace element geochemistry indicates that the Dipeta is more dolomitic and magnesite while the R.A.T. is clay-rich. The Ti2O value of Dipeta and R.A.T samples is relatively low, ranging between 0.36 and 0.69 wt.% respectively, which suggest highly evolved felsic material in the protolith. This is consistent with interpretation based on the Al2O3/TiO2 ratio, which ranges between 18 and 23 for the R.A.T. and Dipeta respectively, indicating an intermediate to felsic granitoids as the protolith of R.A.T. and Dipeta siltstones. The Ti/Zr ratio of R.A.T. and Dipeta samples of less than 10, while, the higher La/Sc ratio of between 2.6 and 5.5 (for the R.A.T. and Dipeta respectively) indicate that both the R.A.T. and Dipeta are active continental and passive margin tectonic setting. Based on the geochemical variation with depth across the R.A.T. and Dipeta and their contact zone, a geochemical fingerprinting suggests that the ratio TiO2/Al2O3 appears to be useful and could be considered as a stratigraphic geochemical maker able to discriminate the R.A.T. and the Dipeta Subgroups during the geological mapping.
- Full Text:
- Date Issued: 2020
An assessment of the performance appraisal system utilised for junior and middle level management within the South African National Defence Force
- Authors: Terblanche, Graham Martin
- Date: 2004
- Subjects: Middle managers -- Rating of -- South Africa , South Africa. National Defence Force Officials and employees Rating of
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:10884 , http://hdl.handle.net/10948/148 , Middle managers -- Rating of -- South Africa , South Africa. National Defence Force Officials and employees Rating of
- Description: The research problem of this study was to assess the extent to which the appraisal system for junior and middle level managers in the South African National Defence Force (SANDF) met the requirements and guidelines for performance appraisal as stipulated in the literature. To achieve this objective, the following procedure was followed: · A survey of existing literature, related to performance appraisal, was conducted. The literature study focused on the requirements for an effective performance appraisal system, appraisal methods and appraisal errors. Attention was also focused on who should take responsibility for performance appraisal and the importance of regularly evaluating the performance appraisal system to meet the demands of a changing environment. The second part of the literature study dealt with the guidelines for establishing an effective appraisal system as well as performance management processes and cycles that are critical for the effectiveness of an appraisal system. The theoretical study formed the basis for the development of a survey questionnaire to establish the extent to which junior and middle level managers in the SANDF agreed with the theoretical guidelines. The survey was administered to a randomly selected group of junior and middle level managers who were representative of the South African Army, Airforce and Medical Services. The empirical results indicated that there was concurrence with many of the guidelines in the literature, but that there were areas that could be improved. It became evident that many respondents felt that the current system was not entirely fair and was not adapted to meet the needs of the integrated SANDF. Specifically, results indicated that the system should be re-evaluated to eliminate bias and to enhance the development of clear standards, both on a quantitative and qualitative level. It became clear that training and communication were important to the successful development and utilisation of a performance appraisal system. An effective performance appraisal system that is integrated with the overall performance management system of an organisation will enhance productivity, satisfaction and the attainment of goals.
- Full Text:
- Date Issued: 2004
- Authors: Terblanche, Graham Martin
- Date: 2004
- Subjects: Middle managers -- Rating of -- South Africa , South Africa. National Defence Force Officials and employees Rating of
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:10884 , http://hdl.handle.net/10948/148 , Middle managers -- Rating of -- South Africa , South Africa. National Defence Force Officials and employees Rating of
- Description: The research problem of this study was to assess the extent to which the appraisal system for junior and middle level managers in the South African National Defence Force (SANDF) met the requirements and guidelines for performance appraisal as stipulated in the literature. To achieve this objective, the following procedure was followed: · A survey of existing literature, related to performance appraisal, was conducted. The literature study focused on the requirements for an effective performance appraisal system, appraisal methods and appraisal errors. Attention was also focused on who should take responsibility for performance appraisal and the importance of regularly evaluating the performance appraisal system to meet the demands of a changing environment. The second part of the literature study dealt with the guidelines for establishing an effective appraisal system as well as performance management processes and cycles that are critical for the effectiveness of an appraisal system. The theoretical study formed the basis for the development of a survey questionnaire to establish the extent to which junior and middle level managers in the SANDF agreed with the theoretical guidelines. The survey was administered to a randomly selected group of junior and middle level managers who were representative of the South African Army, Airforce and Medical Services. The empirical results indicated that there was concurrence with many of the guidelines in the literature, but that there were areas that could be improved. It became evident that many respondents felt that the current system was not entirely fair and was not adapted to meet the needs of the integrated SANDF. Specifically, results indicated that the system should be re-evaluated to eliminate bias and to enhance the development of clear standards, both on a quantitative and qualitative level. It became clear that training and communication were important to the successful development and utilisation of a performance appraisal system. An effective performance appraisal system that is integrated with the overall performance management system of an organisation will enhance productivity, satisfaction and the attainment of goals.
- Full Text:
- Date Issued: 2004
UV-Visible and Electrochemical Monitoring of Carbon Monoxide Release by Donor Complexes to Myoglobin Solutions and to Electrodes Modified with Films Containing Hemin
- Obirai, Joseph C, Hamadi, Sara, Ithurbide, Aurélie, Wartelle, Corinne, Nyokong, Tebello, Zagal, José, Top, Siden, Bedioui, Fethi
- Authors: Obirai, Joseph C , Hamadi, Sara , Ithurbide, Aurélie , Wartelle, Corinne , Nyokong, Tebello , Zagal, José , Top, Siden , Bedioui, Fethi
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283906 , vital:56001 , xlink:href="https://doi.org/10.1002/elan.200603571"
- Description: This study reports on the evaluation of the CO donating behavior of tricarbonyl dichloro ruthenium(II) dimer ([Ru(CO)3Cl2]2) and 1,3-dimethoxyphenyl tricarbonyl chromium (C6H3(MeO)2Cr(CO)3) complex by UV-visible technique and electrochemical technique. The CO release was monitored by following the modifications of the UV-visible features of MbFe(II) in phosphate buffer solution and the redox features of reduced Hemin, HmFe(II), confined at the surface of a vitreous carbon electrode. In the latter case, the interaction between the hemin-modified electrode and the released CO was seen through the observation of an increase of the reduction current related to the FeIII/FeII redox process of the immobilized porphyrin. While the ruthenium-based complex, ([Ru(CO)3Cl2]2), depended on the presence of Fe(II) species to release CO, it was found that the chromium-based complex released spontaneously CO. This was facilitated by illuminating and/or simple stirring of the solution containing the complex.
- Full Text:
- Date Issued: 2006
- Authors: Obirai, Joseph C , Hamadi, Sara , Ithurbide, Aurélie , Wartelle, Corinne , Nyokong, Tebello , Zagal, José , Top, Siden , Bedioui, Fethi
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283906 , vital:56001 , xlink:href="https://doi.org/10.1002/elan.200603571"
- Description: This study reports on the evaluation of the CO donating behavior of tricarbonyl dichloro ruthenium(II) dimer ([Ru(CO)3Cl2]2) and 1,3-dimethoxyphenyl tricarbonyl chromium (C6H3(MeO)2Cr(CO)3) complex by UV-visible technique and electrochemical technique. The CO release was monitored by following the modifications of the UV-visible features of MbFe(II) in phosphate buffer solution and the redox features of reduced Hemin, HmFe(II), confined at the surface of a vitreous carbon electrode. In the latter case, the interaction between the hemin-modified electrode and the released CO was seen through the observation of an increase of the reduction current related to the FeIII/FeII redox process of the immobilized porphyrin. While the ruthenium-based complex, ([Ru(CO)3Cl2]2), depended on the presence of Fe(II) species to release CO, it was found that the chromium-based complex released spontaneously CO. This was facilitated by illuminating and/or simple stirring of the solution containing the complex.
- Full Text:
- Date Issued: 2006
Critical factors for business success in co-operatives
- Authors: Mpongoshe, Lukhanyiso
- Date: 2013
- Subjects: Cooperative societies -- South Africa -- Nelson Mandela Bay Municipality , Success in business -- South Africa -- Nelson Mandela Bay Municipality
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8842 , http://hdl.handle.net/10948/d1020041
- Description: Many countries that have achieved economic development have a dynamic co-operative sector which contributes substantially to the development of these economies. From a global perspective, co-operatives have been proven to be flexible in meeting a wide variety of social and economic human needs such as job creation, alleviation of poverty and building of communities. With the drive to decrease poverty in South Africa, there has been an increased interest to support co-operatives with the intention to provide employment, social development and building communities/ community care. It seems, however, that South Africa has not yet reached the same momentum in the co-operatives movement as elsewhere in the world and the economy is still characterized by a high unemployment rate and a low growth rate (Van der Walt, 2002). This study is an attempt to determine the factors for business success in co-operatives by assessing the strengths and weaknesses of co-operative businesses within the Nelson Mandela Metropolitan Municipality in the Eastern Cape. The study includes an extensive literature review on the nature and prevalence of co-operatives in South Africa where challenges faced by South African co-operatives and particularly those in the Eastern Cape Province, are indicated. It also highlights international best practice and reveals that for co-operative success, apart for functioning by the International Seven Cooperative Principles, knowledge and expertise in business management are absolutely necessary so that co-operatives can be profitable and sustainable. With this knowledge, an adapted form of the Small Enterprise Development Agency (SEDA) Small Business Assessment Tool was used to formulate the questionnaire and to review business management literature. A survey conducted involved fifty-one co-operative members on the database of the Nelson Mandela Metropolitan University Business Unit. The opinions of the respondents were compared with the guidelines provided by the literature in the study in order to identify the strengths and weaknesses of these co-operatives, which then determine the critical success factors for business success in co-operatives. The empirical results show that the co-operative members understand co-operative principles and function through them. They have a fairly general knowledge of business management. The results also show significantly positive correlations between Marketing Management, Financial Management, Operations Management, Human Resources Management and General Management, on the one hand, and the business success of co-operatives, on the other hand. This indicates that these respondents recognize the importance of these business functions in the success of their businesses. However, failures and weaknesses experienced in these areas lead to the recommendations that they need to be mentored as they cannot put this knowledge into application, and secondly, they need financial assistance and support to sustain the co-operative businesses.
- Full Text:
- Date Issued: 2013
- Authors: Mpongoshe, Lukhanyiso
- Date: 2013
- Subjects: Cooperative societies -- South Africa -- Nelson Mandela Bay Municipality , Success in business -- South Africa -- Nelson Mandela Bay Municipality
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8842 , http://hdl.handle.net/10948/d1020041
- Description: Many countries that have achieved economic development have a dynamic co-operative sector which contributes substantially to the development of these economies. From a global perspective, co-operatives have been proven to be flexible in meeting a wide variety of social and economic human needs such as job creation, alleviation of poverty and building of communities. With the drive to decrease poverty in South Africa, there has been an increased interest to support co-operatives with the intention to provide employment, social development and building communities/ community care. It seems, however, that South Africa has not yet reached the same momentum in the co-operatives movement as elsewhere in the world and the economy is still characterized by a high unemployment rate and a low growth rate (Van der Walt, 2002). This study is an attempt to determine the factors for business success in co-operatives by assessing the strengths and weaknesses of co-operative businesses within the Nelson Mandela Metropolitan Municipality in the Eastern Cape. The study includes an extensive literature review on the nature and prevalence of co-operatives in South Africa where challenges faced by South African co-operatives and particularly those in the Eastern Cape Province, are indicated. It also highlights international best practice and reveals that for co-operative success, apart for functioning by the International Seven Cooperative Principles, knowledge and expertise in business management are absolutely necessary so that co-operatives can be profitable and sustainable. With this knowledge, an adapted form of the Small Enterprise Development Agency (SEDA) Small Business Assessment Tool was used to formulate the questionnaire and to review business management literature. A survey conducted involved fifty-one co-operative members on the database of the Nelson Mandela Metropolitan University Business Unit. The opinions of the respondents were compared with the guidelines provided by the literature in the study in order to identify the strengths and weaknesses of these co-operatives, which then determine the critical success factors for business success in co-operatives. The empirical results show that the co-operative members understand co-operative principles and function through them. They have a fairly general knowledge of business management. The results also show significantly positive correlations between Marketing Management, Financial Management, Operations Management, Human Resources Management and General Management, on the one hand, and the business success of co-operatives, on the other hand. This indicates that these respondents recognize the importance of these business functions in the success of their businesses. However, failures and weaknesses experienced in these areas lead to the recommendations that they need to be mentored as they cannot put this knowledge into application, and secondly, they need financial assistance and support to sustain the co-operative businesses.
- Full Text:
- Date Issued: 2013
What is a co-operative?
- Authors: Crankshaw, Paul
- Date: [Date of publication not identified]
- Subjects: Cooperative societies -- South Africa , Producer cooperatives -- South Africa , Consumer cooperatives -- South Africa
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/75688 , vital:30448
- Description: The word ‘co-operative’ means to work together for a common goal. A co-operative is a group of people who together own and control an organisation or a business for the benefit of its members. A co-operative is democratic, and so the members of the co-operative are responsible to each other. They work for themselves; and together they decide how to run the co-operative and how to share the profits. , This booklet was put together by members of Cope, with the help of Paul Crankshaw (editing and layout), Leslie Lawson (photographs and interviews) and Sue Beattie (drawings)
- Full Text:
- Date Issued: [Date of publication not identified]
- Authors: Crankshaw, Paul
- Date: [Date of publication not identified]
- Subjects: Cooperative societies -- South Africa , Producer cooperatives -- South Africa , Consumer cooperatives -- South Africa
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/75688 , vital:30448
- Description: The word ‘co-operative’ means to work together for a common goal. A co-operative is a group of people who together own and control an organisation or a business for the benefit of its members. A co-operative is democratic, and so the members of the co-operative are responsible to each other. They work for themselves; and together they decide how to run the co-operative and how to share the profits. , This booklet was put together by members of Cope, with the help of Paul Crankshaw (editing and layout), Leslie Lawson (photographs and interviews) and Sue Beattie (drawings)
- Full Text:
- Date Issued: [Date of publication not identified]
Ligand isotope vibrational spectroscopic and DFT studies of Pt(II) and Cu(I) complexes
- Authors: Medina, Gerardo Juan
- Date: 2005
- Subjects: Ligands Spectrum analysis Vibrational spectra Infrared spectroscopy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4324 , http://hdl.handle.net/10962/d1004982
- Description: Ligand-isotope labelling studies were performed on Zeise’s salt derivatives with pyridine N-oxide and quinoline N-oxide, their perdeuterated and O-18 isotopomers, C₂D₄ and ¹³CO, and the results of the vibrational analyses are reported. The isotopomers are modelled utilizing DFT calculations at the B3LYP level with the 6-31 G** basis set, and a pseudopotential level for the Pt atom. The calculated and observed structure and vibrational spectra correlate well. The crystal structures of [Pt(C₂2H₄)(pyO)Cl₂] and [Pt(CO)(quinO)Br₂] are reported. The frequency for the νPt-O vibration, ambiguously assigned in the literature, is here assigned unequivocally at 400 cm⁻¹. Previously observed, but inadequately described phenomena are addressed: the νN-O vibration in substituted quinoline N-oxides has been assigned previously at significantly different frequencies, depending on the nature of the substituent. This suggests that there is no specific mid-ir band associated with a high N-O character. A suitable explanation is presented for this phenomenon, showing that in low symmetry systems (eg. quinO) the N-O stretch is dispersed among several modes, whereas in high symmetry systems (eg. pyO) only a few limited modes have a high N-O character. A theoretical study of Cu(I) carbonyl compounds with macrocyclic ligands is presented. Local and global HSAB parameters applied to the donor and Cu atoms are used to explain the observed reactivities and the available spectroscopic data. Extended to [Cu(CO){H₂N(CH₂)[subscript n]NH(CH₂)[subscript m] NH₂}] BPh₄ (where n = 2, m = 2, 3 and n =3, m = 3, 4) and their -d₅ and ¹³CO isotopomers, subtle differences obtained experimentally for the CO stretching frequency in this series have been reproduced in the DFT calculations at the B3LYP level, using the 6-31 G* and 6-31 G** basis sets. Several properties (ligand pK[subscript a] values, νCO frequencies, etc.) correlate with some HSAB descriptors. Vibrational analyses are presented of Cu(I) carbonyl Schiff-base derivatives of N-Benzylidene-N’-[2-(benzyilidene-amino)-ethyl]-ethane-1,2-diamine, {2,2N3(C₆H₄R)₂}, and their -d₅ and ¹³CO isotopomers. The crystal structure of [Cu(CO){2,2N3(C₆H₅)₂}]BPh₄ is reported. From geometry optimizations and the HSAB descriptors, spectroscopic trends ([n]Cu-N and [nu]CO) are related to calculated global hardness and the Hammett substituent parameters, and are discussed in terms of σ-donation and π-backbonding of Cu- CO.
- Full Text:
- Date Issued: 2005
- Authors: Medina, Gerardo Juan
- Date: 2005
- Subjects: Ligands Spectrum analysis Vibrational spectra Infrared spectroscopy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4324 , http://hdl.handle.net/10962/d1004982
- Description: Ligand-isotope labelling studies were performed on Zeise’s salt derivatives with pyridine N-oxide and quinoline N-oxide, their perdeuterated and O-18 isotopomers, C₂D₄ and ¹³CO, and the results of the vibrational analyses are reported. The isotopomers are modelled utilizing DFT calculations at the B3LYP level with the 6-31 G** basis set, and a pseudopotential level for the Pt atom. The calculated and observed structure and vibrational spectra correlate well. The crystal structures of [Pt(C₂2H₄)(pyO)Cl₂] and [Pt(CO)(quinO)Br₂] are reported. The frequency for the νPt-O vibration, ambiguously assigned in the literature, is here assigned unequivocally at 400 cm⁻¹. Previously observed, but inadequately described phenomena are addressed: the νN-O vibration in substituted quinoline N-oxides has been assigned previously at significantly different frequencies, depending on the nature of the substituent. This suggests that there is no specific mid-ir band associated with a high N-O character. A suitable explanation is presented for this phenomenon, showing that in low symmetry systems (eg. quinO) the N-O stretch is dispersed among several modes, whereas in high symmetry systems (eg. pyO) only a few limited modes have a high N-O character. A theoretical study of Cu(I) carbonyl compounds with macrocyclic ligands is presented. Local and global HSAB parameters applied to the donor and Cu atoms are used to explain the observed reactivities and the available spectroscopic data. Extended to [Cu(CO){H₂N(CH₂)[subscript n]NH(CH₂)[subscript m] NH₂}] BPh₄ (where n = 2, m = 2, 3 and n =3, m = 3, 4) and their -d₅ and ¹³CO isotopomers, subtle differences obtained experimentally for the CO stretching frequency in this series have been reproduced in the DFT calculations at the B3LYP level, using the 6-31 G* and 6-31 G** basis sets. Several properties (ligand pK[subscript a] values, νCO frequencies, etc.) correlate with some HSAB descriptors. Vibrational analyses are presented of Cu(I) carbonyl Schiff-base derivatives of N-Benzylidene-N’-[2-(benzyilidene-amino)-ethyl]-ethane-1,2-diamine, {2,2N3(C₆H₄R)₂}, and their -d₅ and ¹³CO isotopomers. The crystal structure of [Cu(CO){2,2N3(C₆H₅)₂}]BPh₄ is reported. From geometry optimizations and the HSAB descriptors, spectroscopic trends ([n]Cu-N and [nu]CO) are related to calculated global hardness and the Hammett substituent parameters, and are discussed in terms of σ-donation and π-backbonding of Cu- CO.
- Full Text:
- Date Issued: 2005
Electrocatalytic activity of bimetallic Au–Pd nanoparticles in the presence of cobalt tetraaminophthalocyanine
- Maringa, Audacity, Mashazi, Philani N, Nyokong, Tebello
- Authors: Maringa, Audacity , Mashazi, Philani N , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189719 , vital:44925 , xlink:href="https://doi.org/10.1016/j.jcis.2014.10.056"
- Description: Au and Pd nanoparticles were individually or together electrodeposited on top of polymerized cobalt tetraaminophthalocyanine (poly-CoTAPc). When Pd and Au nanoparticles are co-deposited together, the electrode is denoted as Au–Pd (co-deposited)/poly-CoTAPc-GCE. X-ray photoelectron spectroscopy (XPS) was used to show the successful deposition of AuNPs, PdNPs and Au–Pd (co-deposited). The scanning electrochemical microscopy showed that Au–Pd (co-deposited)/poly-CoTAPc-GCE (with current range of 9.5–13.5 lA) was more conducting than Au–Pd (co-deposited)-GCE (with current range of 8–12 lA). Electrochemical impedance spectroscopy (EIS) showed that there was less resistance to charge transfer for Au–Pd (co-deposited)/poly-CoTAPc-GCE compared to the rest of the electrodes. Au–Pd (co-deposited)/poly-CoTAPc-GCE showed the best activity for the electrooxidation of hydrazine in terms of limit of detection (0.5 lM), hence shows promise as an electrocatalyst for electrooxidation of hydrazine.
- Full Text:
- Date Issued: 2015
- Authors: Maringa, Audacity , Mashazi, Philani N , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189719 , vital:44925 , xlink:href="https://doi.org/10.1016/j.jcis.2014.10.056"
- Description: Au and Pd nanoparticles were individually or together electrodeposited on top of polymerized cobalt tetraaminophthalocyanine (poly-CoTAPc). When Pd and Au nanoparticles are co-deposited together, the electrode is denoted as Au–Pd (co-deposited)/poly-CoTAPc-GCE. X-ray photoelectron spectroscopy (XPS) was used to show the successful deposition of AuNPs, PdNPs and Au–Pd (co-deposited). The scanning electrochemical microscopy showed that Au–Pd (co-deposited)/poly-CoTAPc-GCE (with current range of 9.5–13.5 lA) was more conducting than Au–Pd (co-deposited)-GCE (with current range of 8–12 lA). Electrochemical impedance spectroscopy (EIS) showed that there was less resistance to charge transfer for Au–Pd (co-deposited)/poly-CoTAPc-GCE compared to the rest of the electrodes. Au–Pd (co-deposited)/poly-CoTAPc-GCE showed the best activity for the electrooxidation of hydrazine in terms of limit of detection (0.5 lM), hence shows promise as an electrocatalyst for electrooxidation of hydrazine.
- Full Text:
- Date Issued: 2015
Azigbo
- Gnaore Djimi (vocals, creator), Gnaore Djimi The Best (album title), Showbiz
- Authors: Gnaore Djimi (vocals, creator) , Gnaore Djimi The Best (album title) , Showbiz
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Cote d'Ivoire Abidjan f-iv
- Language: French
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/128902 , vital:36189 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC17-03
- Description: Ivorian popular song in the Polihet style that is based on the traditional sounds, gestures and heritage of Niamboua people who live in the southwest reagion of Cote d'Ivoire. Polihet is performed at funerals, baptisms,weddings with the themes of love, hate, death and peace
- Full Text: false
- Date Issued: 2000
- Authors: Gnaore Djimi (vocals, creator) , Gnaore Djimi The Best (album title) , Showbiz
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Cote d'Ivoire Abidjan f-iv
- Language: French
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/128902 , vital:36189 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC17-03
- Description: Ivorian popular song in the Polihet style that is based on the traditional sounds, gestures and heritage of Niamboua people who live in the southwest reagion of Cote d'Ivoire. Polihet is performed at funerals, baptisms,weddings with the themes of love, hate, death and peace
- Full Text: false
- Date Issued: 2000
Bidi Djehoua
- Gnaore Djimi (vocals, creator), Gnaore Djimi The Best (album title), Showbiz
- Authors: Gnaore Djimi (vocals, creator) , Gnaore Djimi The Best (album title) , Showbiz
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Cote d'Ivoire Abidjan f-iv
- Language: French
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129014 , vital:36204 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC17-09
- Description: Ivorian popular song in the Polihet style that is based on the traditional sounds, gestures and heritage of Niamboua people who live in the southwest reagion of Cote d'Ivoire. Polihet is performed at funerals, baptisms,weddings with the themes of love, hate, death and peace
- Full Text: false
- Date Issued: 2000
- Authors: Gnaore Djimi (vocals, creator) , Gnaore Djimi The Best (album title) , Showbiz
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Cote d'Ivoire Abidjan f-iv
- Language: French
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129014 , vital:36204 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC17-09
- Description: Ivorian popular song in the Polihet style that is based on the traditional sounds, gestures and heritage of Niamboua people who live in the southwest reagion of Cote d'Ivoire. Polihet is performed at funerals, baptisms,weddings with the themes of love, hate, death and peace
- Full Text: false
- Date Issued: 2000
Agricultural co-operative societies and challenges of sustainability: The case of vegetable cooperative societies in King Sabata Dalindyebo Local Municipality, Eastern Cape Province
- Sohuma, Anathi https://orcid.org/0000-0001-6260-6428
- Authors: Sohuma, Anathi https://orcid.org/0000-0001-6260-6428
- Date: 2020-06
- Subjects: Agriculture, Cooperative , Sustainable development
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/21422 , vital:48601
- Description: The government has initiated various support programmes to assist agricultural co-operative societies to remain viable; however, many cooperatives continue to flounder while some have collapsed. This dissertation assesses the challenges of sustainability facing agricultural co-operative societies gushing vegetable co-operative societies in King Sabata Dalindyebo Local Municipality, Eastern Cape Province as a point of departure. The study used the corporate sustainability theory to investigate the extent to which co-operative societies are able to operate sustainably. The data for this study were collected through document reviews and non-scheduled structured interviews which were conducted through a questionnaire. The board of directors were sampled purposively. The research adopted stratified sampling to select co-operative members that participated in the study. This research made use of the Statistical Package for the Social Sciences (SPSS) version 24 software to analyse data. The outcomes provide an understanding of the sustainability challenges that face vegetable co-operative societies. The results show that most of the co-operative societies rely on members for daily farm management. With regards to management, co-operative societies reveal that they keep sales, production and meeting record books. Furthermore, most co-operatives specified that they received training for financial and production record-keeping. It was found that some cooperatives have had training only once since their establishment. However, fewer co-operatives reported that keeping records is still challenging for them due to lack of training and little profit made from sales. The findings suggest that co-operative societies can function well and become sustainable when there is good management and cooperation amongst members. Based on the findings of this research, it is recommended that the government and co-operative stakeholders should play a greater part in ensuring co-operative societies are developed and managed in a way that will make them sustainable without relying solely on government support. For example, the government and stakeholders can establish and enforce policies that encourage co-operatives to invest in member capability programmes that would equip farmers understanding, adoption and use of co-operative values and principles. This would help in reducing challenges that occur within co-operatives and promote cohesion and commitment within co-operatives. The role of extension services towards the sustainability of the co-operatives is crucial. The majority of the co-operatives indicated that there is some level of interaction between the co-operatives and extension personnel albeit, there is a need to improve the frequency of extension visits, training and follow-up appointments. , Thesis (MSc) -- Faculty of Science and Agriculture, 2020
- Full Text:
- Date Issued: 2020-06
- Authors: Sohuma, Anathi https://orcid.org/0000-0001-6260-6428
- Date: 2020-06
- Subjects: Agriculture, Cooperative , Sustainable development
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/21422 , vital:48601
- Description: The government has initiated various support programmes to assist agricultural co-operative societies to remain viable; however, many cooperatives continue to flounder while some have collapsed. This dissertation assesses the challenges of sustainability facing agricultural co-operative societies gushing vegetable co-operative societies in King Sabata Dalindyebo Local Municipality, Eastern Cape Province as a point of departure. The study used the corporate sustainability theory to investigate the extent to which co-operative societies are able to operate sustainably. The data for this study were collected through document reviews and non-scheduled structured interviews which were conducted through a questionnaire. The board of directors were sampled purposively. The research adopted stratified sampling to select co-operative members that participated in the study. This research made use of the Statistical Package for the Social Sciences (SPSS) version 24 software to analyse data. The outcomes provide an understanding of the sustainability challenges that face vegetable co-operative societies. The results show that most of the co-operative societies rely on members for daily farm management. With regards to management, co-operative societies reveal that they keep sales, production and meeting record books. Furthermore, most co-operatives specified that they received training for financial and production record-keeping. It was found that some cooperatives have had training only once since their establishment. However, fewer co-operatives reported that keeping records is still challenging for them due to lack of training and little profit made from sales. The findings suggest that co-operative societies can function well and become sustainable when there is good management and cooperation amongst members. Based on the findings of this research, it is recommended that the government and co-operative stakeholders should play a greater part in ensuring co-operative societies are developed and managed in a way that will make them sustainable without relying solely on government support. For example, the government and stakeholders can establish and enforce policies that encourage co-operatives to invest in member capability programmes that would equip farmers understanding, adoption and use of co-operative values and principles. This would help in reducing challenges that occur within co-operatives and promote cohesion and commitment within co-operatives. The role of extension services towards the sustainability of the co-operatives is crucial. The majority of the co-operatives indicated that there is some level of interaction between the co-operatives and extension personnel albeit, there is a need to improve the frequency of extension visits, training and follow-up appointments. , Thesis (MSc) -- Faculty of Science and Agriculture, 2020
- Full Text:
- Date Issued: 2020-06
The morphotactic constraints of verbal extensions in isiXhosa
- Authors: Mkabile, Hlumela
- Date: 2019
- Subjects: Xhosa language -- Grammar
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/92849 , vital:30749
- Description: Bantu verbal suffixes, also known as extensions, follow a rather rigid pattern when they attach to the verb. Studies (e.g. Hyman 2002, Good 2005, 2007, among others) have shown that the order followed by these extensions is: Causative, Applicative, Reciprocal, Passive (CARP). Although this pattern is widespread across Bantu, some variations in the ordering of these extensions have been observed in some languages (Kathupa 1991, Simango 1995, Sibanda 2004, among others), which suggests that the template is not as rigid as one might think. This study investigated the morphotactic constraints between four verbal extensions in isiXhosa, the Causative, Applicative, Reciprocal and Passive. It focused on the morphotactics of the transitivising extensions (Causative and Applicative) in the first instance, and morphotactics of the detransitivising extensions (Reciprocal and Passive) in the second instance. The study found that although the co-occurrence of causatives and applicatives is a regular feature in Bantu languages, isiXhosa has restrictions on the co-occurrence of these extensions on some verbs. The study also found that although Causative-Applicative is the expected order the language permits Applicative-Causative in certain contexts. With respect to the detransitivising extensions, the study revealed that there are limited contexts in which these extensions co-occur and, crucially, that these extensions are freely ordered in the language.
- Full Text:
- Date Issued: 2019
- Authors: Mkabile, Hlumela
- Date: 2019
- Subjects: Xhosa language -- Grammar
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/92849 , vital:30749
- Description: Bantu verbal suffixes, also known as extensions, follow a rather rigid pattern when they attach to the verb. Studies (e.g. Hyman 2002, Good 2005, 2007, among others) have shown that the order followed by these extensions is: Causative, Applicative, Reciprocal, Passive (CARP). Although this pattern is widespread across Bantu, some variations in the ordering of these extensions have been observed in some languages (Kathupa 1991, Simango 1995, Sibanda 2004, among others), which suggests that the template is not as rigid as one might think. This study investigated the morphotactic constraints between four verbal extensions in isiXhosa, the Causative, Applicative, Reciprocal and Passive. It focused on the morphotactics of the transitivising extensions (Causative and Applicative) in the first instance, and morphotactics of the detransitivising extensions (Reciprocal and Passive) in the second instance. The study found that although the co-occurrence of causatives and applicatives is a regular feature in Bantu languages, isiXhosa has restrictions on the co-occurrence of these extensions on some verbs. The study also found that although Causative-Applicative is the expected order the language permits Applicative-Causative in certain contexts. With respect to the detransitivising extensions, the study revealed that there are limited contexts in which these extensions co-occur and, crucially, that these extensions are freely ordered in the language.
- Full Text:
- Date Issued: 2019
Asymmetrical zinc (II) phthalocyanines conjugated to metal tungstate nanoparticles for photoinactivation of Staphylococcus aureus
- Mgidlana, Sithi, Managa, Muthumuni, Nyokong, Tebello
- Authors: Mgidlana, Sithi , Managa, Muthumuni , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295718 , vital:57372 , xlink:href="https://doi.org/10.1080/00958972.2022.2090837"
- Description: In this study, we report for the first time on the photodynamic antimicrobial chemotherapy (PACT) of asymmetrical zinc(II) phthalocyanines and their conjugates with nickel tungstate (NiWO4), cobalt tungstate (CoWO4) and bismuth tungstate (Bi2WO6) nanoparticles. CoWO4, NiWO4 and Bi2WO6 were capped with glutathione and covalently linked to three asymmetrical zinc(II) phthalocyanines for PACT. The plate count method was used to investigate the effect of covalently linking asymmetrical zinc(II) phthalocyanines to nanoparticles under light (for PACT against Staphylococcus aureus) and in the dark. Both Pc complexes and the conjugates indicated minimum dark-toxicity. The conjugates showed greater antimicrobial activity against a gram-positive and drug resistant bacteria, Staphylococcus aureus, than Pc complexes alone.
- Full Text:
- Date Issued: 2022
- Authors: Mgidlana, Sithi , Managa, Muthumuni , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/295718 , vital:57372 , xlink:href="https://doi.org/10.1080/00958972.2022.2090837"
- Description: In this study, we report for the first time on the photodynamic antimicrobial chemotherapy (PACT) of asymmetrical zinc(II) phthalocyanines and their conjugates with nickel tungstate (NiWO4), cobalt tungstate (CoWO4) and bismuth tungstate (Bi2WO6) nanoparticles. CoWO4, NiWO4 and Bi2WO6 were capped with glutathione and covalently linked to three asymmetrical zinc(II) phthalocyanines for PACT. The plate count method was used to investigate the effect of covalently linking asymmetrical zinc(II) phthalocyanines to nanoparticles under light (for PACT against Staphylococcus aureus) and in the dark. Both Pc complexes and the conjugates indicated minimum dark-toxicity. The conjugates showed greater antimicrobial activity against a gram-positive and drug resistant bacteria, Staphylococcus aureus, than Pc complexes alone.
- Full Text:
- Date Issued: 2022
An investigation of parameter relationships in a high-speed digital multimedia environment
- Authors: Chigwamba, Nyasha
- Date: 2014
- Subjects: Multimedia communications , Digital communications , Local area networks (Computer networks) , Computer network architectures , Computer network protocols , Computer sound processing , Sound -- Recording and reproducing -- Digital techniques
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4725 , http://hdl.handle.net/10962/d1021153
- Description: With the rapid adoption of multimedia network technologies, a number of companies and standards bodies are introducing technologies that enhance user experience in networked multimedia environments. These technologies focus on device discovery, connection management, control, and monitoring. This study focused on control and monitoring. Multimedia networks make it possible for devices that are part of the same network to reside in different physical locations. These devices contain parameters that are used to control particular features, such as speaker volume, bass, amplifier gain, and video resolution. It is often necessary for changes in one parameter to affect other parameters, such as a synchronised change between volume and bass parameters, or collective control of multiple parameters. Thus, relationships are required between the parameters. In addition, some devices contain parameters, such as voltage, temperature, and audio level, that require constant monitoring to enable corrective action when thresholds are exceeded. Therefore, a mechanism for monitoring networked devices is required. This thesis proposes relationships that are essential for the proper functioning of a multimedia network and that should, therefore, be incorporated in standard form into a protocol, such that all devices can depend on them. Implementation mechanisms for these relationships were created. Parameter grouping and monitoring capabilities within mixing console implementations and existing control protocols were reviewed. A number of requirements for parameter grouping and monitoring were derived from this review. These requirements include a formal classification of relationship types, the ability to create relationships between parameters with different underlying value units, the ability to create relationships between parameters residing on different devices on a network, and the use of an event-driven mechanism for parameter monitoring. These requirements were the criteria used to govern the implementation mechanisms that were created as part of this study. Parameter grouping and monitoring mechanisms were implemented for the XFN protocol. The mechanisms implemented fulfil the requirements derived from the review of capabilities of mixing consoles and existing control protocols. The formal classification of relationship types was implemented within XFN parameters using lists that keep track of the relationships between each XFN parameter and other XFN parameters that reside on the same device or on other devices on the network. A common value unit, known as the global unit, was defined for use as the value format within value update messages between XFN parameters that have relationships. Mapping tables were used to translate the global unit values to application-specific (universal) units, such as decibels (dB). A mechanism for bulk parameter retrieval within the XFN protocol was augmented to produce an event-driven mechanism for parameter monitoring. These implementation mechanisms were applied to an XFN-protocol-compliant graphical control application to demonstrate their usage within an end user context. At the time of this study, the XFN protocol was undergoing standardisation within the Audio Engineering Society. The AES-64 standard has now been approved. Most of the implementation mechanisms resulting from this study have been incorporated into this standard.
- Full Text:
- Date Issued: 2014
- Authors: Chigwamba, Nyasha
- Date: 2014
- Subjects: Multimedia communications , Digital communications , Local area networks (Computer networks) , Computer network architectures , Computer network protocols , Computer sound processing , Sound -- Recording and reproducing -- Digital techniques
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4725 , http://hdl.handle.net/10962/d1021153
- Description: With the rapid adoption of multimedia network technologies, a number of companies and standards bodies are introducing technologies that enhance user experience in networked multimedia environments. These technologies focus on device discovery, connection management, control, and monitoring. This study focused on control and monitoring. Multimedia networks make it possible for devices that are part of the same network to reside in different physical locations. These devices contain parameters that are used to control particular features, such as speaker volume, bass, amplifier gain, and video resolution. It is often necessary for changes in one parameter to affect other parameters, such as a synchronised change between volume and bass parameters, or collective control of multiple parameters. Thus, relationships are required between the parameters. In addition, some devices contain parameters, such as voltage, temperature, and audio level, that require constant monitoring to enable corrective action when thresholds are exceeded. Therefore, a mechanism for monitoring networked devices is required. This thesis proposes relationships that are essential for the proper functioning of a multimedia network and that should, therefore, be incorporated in standard form into a protocol, such that all devices can depend on them. Implementation mechanisms for these relationships were created. Parameter grouping and monitoring capabilities within mixing console implementations and existing control protocols were reviewed. A number of requirements for parameter grouping and monitoring were derived from this review. These requirements include a formal classification of relationship types, the ability to create relationships between parameters with different underlying value units, the ability to create relationships between parameters residing on different devices on a network, and the use of an event-driven mechanism for parameter monitoring. These requirements were the criteria used to govern the implementation mechanisms that were created as part of this study. Parameter grouping and monitoring mechanisms were implemented for the XFN protocol. The mechanisms implemented fulfil the requirements derived from the review of capabilities of mixing consoles and existing control protocols. The formal classification of relationship types was implemented within XFN parameters using lists that keep track of the relationships between each XFN parameter and other XFN parameters that reside on the same device or on other devices on the network. A common value unit, known as the global unit, was defined for use as the value format within value update messages between XFN parameters that have relationships. Mapping tables were used to translate the global unit values to application-specific (universal) units, such as decibels (dB). A mechanism for bulk parameter retrieval within the XFN protocol was augmented to produce an event-driven mechanism for parameter monitoring. These implementation mechanisms were applied to an XFN-protocol-compliant graphical control application to demonstrate their usage within an end user context. At the time of this study, the XFN protocol was undergoing standardisation within the Audio Engineering Society. The AES-64 standard has now been approved. Most of the implementation mechanisms resulting from this study have been incorporated into this standard.
- Full Text:
- Date Issued: 2014
An assessment of the roles of co-operatives as agents of development in rural areas: a case study of Inkwanca Local Municipality
- Authors: Mtshwelo, Linda Hombisa
- Date: 2014
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: vital:11680 , http://hdl.handle.net/10353/d1013542
- Description: The study assesses the role of co-operative societies in economic development. The study was undertaken to investigate the extent to which co-operatives can act as agents towards sustainable community development. Expectations were that cooperative members can perform better than individuals in terms of working together as a group, sharing responsibilities, contributing larger capital, bringing their skills together, incur lower expenses, generate higher income and therefore earn higher profits to be shared amongst themselves. This would enable members to be able to pay for their families’ basic needs and therefore enhance the standard of living of all members. The overall purpose of the study therefore is to investigate whether cooperatives are the best tools for rural development and poverty alleviation in Inkwanca Local Municipality. The research involves the collection of data from co-operative members in Molteno and Sterkstrooom. The data was analysed in order to establish the performance of cooperatives in terms of their leadership and management structures. The research further looks into the challenges and gaps in the co-operative sector in terms of performance by the members and support by the government and government agencies. The research also investigated the best model that can be used to improve co-operatives so that they can enhance the lives of community members in rural areas. In order to gather information, three different approaches were used in the action research which involved different instruments, such as questionnaires, interviews and observations. In spite of all the challenges facing co-operatives, they have been playing an increasingly important role in facilitating job creation, economic growth and social development. The study concludes by emphasising that for co-operatives to be continuously effective and successful, they must improve their ability to service their members. The study commends government for financial and non-financial support programmes although there is still a room for improvement. In addition, further research is needed o the role played by co-operatives as agents of development in rural areas.
- Full Text:
- Date Issued: 2014
- Authors: Mtshwelo, Linda Hombisa
- Date: 2014
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: vital:11680 , http://hdl.handle.net/10353/d1013542
- Description: The study assesses the role of co-operative societies in economic development. The study was undertaken to investigate the extent to which co-operatives can act as agents towards sustainable community development. Expectations were that cooperative members can perform better than individuals in terms of working together as a group, sharing responsibilities, contributing larger capital, bringing their skills together, incur lower expenses, generate higher income and therefore earn higher profits to be shared amongst themselves. This would enable members to be able to pay for their families’ basic needs and therefore enhance the standard of living of all members. The overall purpose of the study therefore is to investigate whether cooperatives are the best tools for rural development and poverty alleviation in Inkwanca Local Municipality. The research involves the collection of data from co-operative members in Molteno and Sterkstrooom. The data was analysed in order to establish the performance of cooperatives in terms of their leadership and management structures. The research further looks into the challenges and gaps in the co-operative sector in terms of performance by the members and support by the government and government agencies. The research also investigated the best model that can be used to improve co-operatives so that they can enhance the lives of community members in rural areas. In order to gather information, three different approaches were used in the action research which involved different instruments, such as questionnaires, interviews and observations. In spite of all the challenges facing co-operatives, they have been playing an increasingly important role in facilitating job creation, economic growth and social development. The study concludes by emphasising that for co-operatives to be continuously effective and successful, they must improve their ability to service their members. The study commends government for financial and non-financial support programmes although there is still a room for improvement. In addition, further research is needed o the role played by co-operatives as agents of development in rural areas.
- Full Text:
- Date Issued: 2014