Hom!awab go !Khub Kristuba
- Workshop Participants, Composer not specified, Goamub, Bernardus, Dargie, Dave
- Authors: Workshop Participants , Composer not specified , Goamub, Bernardus , Dargie, Dave
- Date: 1988
- Subjects: Folk music , Field recordings , Africa, Sub-Saharan , Africa Namibia Gobabis f-sx
- Language: Mbukushu
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/308216 , vital:58894 , International Library of African Music, Rhodes University, Makhanda, South Africa , Dave Dargie Field Tapes, Rhodes University, Makhanda, South Africa , DD116-46
- Description: Composition training session of religious song with clapping accompaniment.
- Full Text: false
- Date Issued: 1988
- Authors: Workshop Participants , Composer not specified , Goamub, Bernardus , Dargie, Dave
- Date: 1988
- Subjects: Folk music , Field recordings , Africa, Sub-Saharan , Africa Namibia Gobabis f-sx
- Language: Mbukushu
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/308216 , vital:58894 , International Library of African Music, Rhodes University, Makhanda, South Africa , Dave Dargie Field Tapes, Rhodes University, Makhanda, South Africa , DD116-46
- Description: Composition training session of religious song with clapping accompaniment.
- Full Text: false
- Date Issued: 1988
First house (prison) built in Grahamstown
- Subjects: Grahamstown (South Africa) -- Pictorial works , Historic buildings -- Grahamstown
- Type: Image
- Identifier: vital:14009 , http://hdl.handle.net/10962/d1017576 , CD 55 , MS 10 542 , PIC/SL 4804 , Grahamstown (South Africa) -- Pictorial works , Historic buildings -- Grahamstown
- Description: Photograph depicting first house in Grahamstown. Coral tree planted by Arnoldus Bernardus Dietz , High Street, Grahamstown.
- Full Text: false
- Subjects: Grahamstown (South Africa) -- Pictorial works , Historic buildings -- Grahamstown
- Type: Image
- Identifier: vital:14009 , http://hdl.handle.net/10962/d1017576 , CD 55 , MS 10 542 , PIC/SL 4804 , Grahamstown (South Africa) -- Pictorial works , Historic buildings -- Grahamstown
- Description: Photograph depicting first house in Grahamstown. Coral tree planted by Arnoldus Bernardus Dietz , High Street, Grahamstown.
- Full Text: false
Hom!awab go !Khub Kristuba
- Workshop Participants, Composer not specified, Goamub, Bernardus, Dargie, Dave
- Authors: Workshop Participants , Composer not specified , Goamub, Bernardus , Dargie, Dave
- Date: 1988
- Subjects: Folk music , Field recordings , Africa, Sub-Saharan , Africa Namibia Gobabis f-sx
- Language: Mbukushu
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/308221 , vital:58895 , International Library of African Music, Rhodes University, Makhanda, South Africa , Dave Dargie Field Tapes, Rhodes University, Makhanda, South Africa , DD116-47
- Description: Composition training session of religious song with clapping accompaniment.
- Full Text: false
- Date Issued: 1988
- Authors: Workshop Participants , Composer not specified , Goamub, Bernardus , Dargie, Dave
- Date: 1988
- Subjects: Folk music , Field recordings , Africa, Sub-Saharan , Africa Namibia Gobabis f-sx
- Language: Mbukushu
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/308221 , vital:58895 , International Library of African Music, Rhodes University, Makhanda, South Africa , Dave Dargie Field Tapes, Rhodes University, Makhanda, South Africa , DD116-47
- Description: Composition training session of religious song with clapping accompaniment.
- Full Text: false
- Date Issued: 1988
The law of culpable homicide in South Africa : with reference to the law of manslaughter in English law and the law related to negligent killing in German law
- Authors: du Plessis, J R
- Date: 1987
- Subjects: Homicide -- Law and legislation -- South Africa Homicide -- Law and legislation -- England Homicide -- Law and legislation -- Germany (West)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3670 , http://hdl.handle.net/10962/d1003185
- Description: Culpable homicide is the unlawful negligent killing of a fellow human being. As such it is in many respects a 'residual' crime being the verdict prosecutors may expect when they are unable to prove the intention to kill when prosecuting for murder. A feature of this was that in the past when defences such as, for instance, intoxication or provocation were raised at murder trials, convictions of culpable homicide were almost automatic. In recent years, under the influence of the 'purist' current in our Criminal law, intoxication has become a defence to culpable homicide and provocation resulting in loss of self-control has also become a defence to culpable homicide. These developments are unacceptable to some writers on criminal law and a move away from the purist approach to the 'traditional' or pragmatic approach is to be expected. Greater emphasis will be placed on practical results than on the achievement of logical consistency. This could result in the law of culpable homicide becoming more socially effective than it is at present.
- Full Text:
- Date Issued: 1987
- Authors: du Plessis, J R
- Date: 1987
- Subjects: Homicide -- Law and legislation -- South Africa Homicide -- Law and legislation -- England Homicide -- Law and legislation -- Germany (West)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3670 , http://hdl.handle.net/10962/d1003185
- Description: Culpable homicide is the unlawful negligent killing of a fellow human being. As such it is in many respects a 'residual' crime being the verdict prosecutors may expect when they are unable to prove the intention to kill when prosecuting for murder. A feature of this was that in the past when defences such as, for instance, intoxication or provocation were raised at murder trials, convictions of culpable homicide were almost automatic. In recent years, under the influence of the 'purist' current in our Criminal law, intoxication has become a defence to culpable homicide and provocation resulting in loss of self-control has also become a defence to culpable homicide. These developments are unacceptable to some writers on criminal law and a move away from the purist approach to the 'traditional' or pragmatic approach is to be expected. Greater emphasis will be placed on practical results than on the achievement of logical consistency. This could result in the law of culpable homicide becoming more socially effective than it is at present.
- Full Text:
- Date Issued: 1987
Rhodes University Graduation Ceremony 1976
- Authors: Rhodes University
- Date: 1976
- Language: English
- Type: text
- Identifier: vital:8110 , http://hdl.handle.net/10962/d1004565
- Description: Rhodes University Graduation Ceremonies on Friday 9th April 1976 at 8 p.m. [and] on Saturday 10th April 1976 at 10:30 a.m.in the University Great Hall.
- Full Text:
- Date Issued: 1976
- Authors: Rhodes University
- Date: 1976
- Language: English
- Type: text
- Identifier: vital:8110 , http://hdl.handle.net/10962/d1004565
- Description: Rhodes University Graduation Ceremonies on Friday 9th April 1976 at 8 p.m. [and] on Saturday 10th April 1976 at 10:30 a.m.in the University Great Hall.
- Full Text:
- Date Issued: 1976
Rhodes University Graduation Ceremony 1990
- Authors: Rhodes University
- Date: 1990
- Language: English
- Type: text
- Identifier: vital:8124 , http://hdl.handle.net/10962/d1005707
- Description: Rhodes University Graduation Ceremonies on Friday, 6 April 1990 at 8 p.m. [and] on Saturday, 7 April 1990 at 10 a.m. in the 1820 Settlers National Monument. , Rhodes University East London Graduation Ceremony Saturday; 12 May 1990 at 11.30 a.m. in the Guild Theatre.
- Full Text:
- Date Issued: 1990
- Authors: Rhodes University
- Date: 1990
- Language: English
- Type: text
- Identifier: vital:8124 , http://hdl.handle.net/10962/d1005707
- Description: Rhodes University Graduation Ceremonies on Friday, 6 April 1990 at 8 p.m. [and] on Saturday, 7 April 1990 at 10 a.m. in the 1820 Settlers National Monument. , Rhodes University East London Graduation Ceremony Saturday; 12 May 1990 at 11.30 a.m. in the Guild Theatre.
- Full Text:
- Date Issued: 1990
The legal protection of foreign direct investment in the new millennium :a critical assessment with a focus on South Africa and Zimbabwe
- Authors: Chidede, Talkmore
- Date: 2016
- Subjects: Investments, Foreign -- Law and legislation Economic policy
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: http://hdl.handle.net/10353/7919 , vital:30814
- Description: The increasing investment gap and reduction in foreign aid has made several developing countries to turn to foreign investment as a mechanism to circumvent their financial constraints among other things. There is substantial empirical evidence that foreign direct investment enhances economic development, employment creation, national competitiveness and diffusion of technology from foreign firms to local firms and workers of the host states. As a result, this study firstly argues that foreign investment is much needed in South Africa and Zimbabwe to improve economic growth and development, create employment and increase their competitiveness in the global market. However, these benefits do not accrue automatically but the host states need to create an enabling environment to exploit such benefits. The legal protection of foreign investment has become a fundamental issue in both international and national law. Efforts have been and are still being made in law as well as in practice to implement national investment legal regimes which are in line with international norms or standards. This study undertakes a contemporary assessment of the legal protection of foreign investment in South Africa and Zimbabwe with a view of examining their compliance with international minimum norms, standards and/or best practices. More recently, both South Africa and Zimbabwe have crafted and implemented investment laws and related policies which are perceived to be somewhat hostile towards foreign investment. To achieve this, selected investment laws and related policies in both jurisdictions are critically analysed. This study puts forward an argument and recommendations for policy makers in both South Africa and Zimbabwe for strategic refinements of investment laws and related policies such that they become flexible, friendly and certain to foreign investors while at the same time advancing their respective national policies aimed at the economic empowerment of local citizens.
- Full Text:
- Date Issued: 2016
- Authors: Chidede, Talkmore
- Date: 2016
- Subjects: Investments, Foreign -- Law and legislation Economic policy
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: http://hdl.handle.net/10353/7919 , vital:30814
- Description: The increasing investment gap and reduction in foreign aid has made several developing countries to turn to foreign investment as a mechanism to circumvent their financial constraints among other things. There is substantial empirical evidence that foreign direct investment enhances economic development, employment creation, national competitiveness and diffusion of technology from foreign firms to local firms and workers of the host states. As a result, this study firstly argues that foreign investment is much needed in South Africa and Zimbabwe to improve economic growth and development, create employment and increase their competitiveness in the global market. However, these benefits do not accrue automatically but the host states need to create an enabling environment to exploit such benefits. The legal protection of foreign investment has become a fundamental issue in both international and national law. Efforts have been and are still being made in law as well as in practice to implement national investment legal regimes which are in line with international norms or standards. This study undertakes a contemporary assessment of the legal protection of foreign investment in South Africa and Zimbabwe with a view of examining their compliance with international minimum norms, standards and/or best practices. More recently, both South Africa and Zimbabwe have crafted and implemented investment laws and related policies which are perceived to be somewhat hostile towards foreign investment. To achieve this, selected investment laws and related policies in both jurisdictions are critically analysed. This study puts forward an argument and recommendations for policy makers in both South Africa and Zimbabwe for strategic refinements of investment laws and related policies such that they become flexible, friendly and certain to foreign investors while at the same time advancing their respective national policies aimed at the economic empowerment of local citizens.
- Full Text:
- Date Issued: 2016
Byvoeding van skape op aangeplante weiding in 'n mediterreense klimaat
- Authors: Aucamp, Barend Bernadus
- Date: 2001
- Subjects: Sheep -- Feeding and feeds
- Language: Afrikaans
- Type: Thesis , Masters , MTech (Agriculture)
- Identifier: vital:10949 , http://hdl.handle.net/10948/44 , Sheep -- Feeding and feeds
- Description: Tydens embrio ontwikkeling groei weefsel deur selvermeedering, maar soos wat soogdiere volwassendheid nader vind groei net plaas deur sel vergroting. Volwassenheid word beskou as wanneer spiergroei ‘n maksimum bereik. Groei sluit die neerlegging van vet in, maar spiermassa is van primêre belang. Die groeikurwe (Fig 1) waarin massatoename teenoor ouderdom vergelyk word, volg ‘n sigmoidale kurwe (Owens et al, 1993). Onder ideale toestande is die groeitempo van lammers relatief konstant van kort na geboorte totdat die helfte van volwassemassa bereik word, waarna dit geleidelik afneem tot volwassenheid (Black, 1983). Die afname in groeitempo begin gewoonlik met die bereiking van puberteit (Owens et al, 1993).
- Full Text:
- Date Issued: 2001
- Authors: Aucamp, Barend Bernadus
- Date: 2001
- Subjects: Sheep -- Feeding and feeds
- Language: Afrikaans
- Type: Thesis , Masters , MTech (Agriculture)
- Identifier: vital:10949 , http://hdl.handle.net/10948/44 , Sheep -- Feeding and feeds
- Description: Tydens embrio ontwikkeling groei weefsel deur selvermeedering, maar soos wat soogdiere volwassendheid nader vind groei net plaas deur sel vergroting. Volwassenheid word beskou as wanneer spiergroei ‘n maksimum bereik. Groei sluit die neerlegging van vet in, maar spiermassa is van primêre belang. Die groeikurwe (Fig 1) waarin massatoename teenoor ouderdom vergelyk word, volg ‘n sigmoidale kurwe (Owens et al, 1993). Onder ideale toestande is die groeitempo van lammers relatief konstant van kort na geboorte totdat die helfte van volwassemassa bereik word, waarna dit geleidelik afneem tot volwassenheid (Black, 1983). Die afname in groeitempo begin gewoonlik met die bereiking van puberteit (Owens et al, 1993).
- Full Text:
- Date Issued: 2001
Search algorithms on structured and unstructured data in a large database
- Du Plessis, Mathys Cornelius
- Authors: Du Plessis, Mathys Cornelius
- Date: 2004
- Subjects: Online algorithms , Database searching -- South Africa -- Port Elizabeth , Information retrieval -- South Africa -- Port Elizabeth
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:11094 , http://hdl.handle.net/10948/d1019681
- Description: This project is concerned with the development of a search algorithm for a large archival database. The Port Elizabeth Genealogical Information System (PEGIS) contains a database consisting of almost 600000 individuals. The standard search algorithms are no longer sufficient to locate individuals in the database. A new algorithm was required that allows searches on any of the words or dates in the database, as well as a means to specify where in the desired record a word should occur. A ranking function of retrieved records was also required. A literature study on the field of Information Retrieval and on algorithms designed specifically for the PEGIS was done. These algorithms were adapted and hybridized to yield a search algorithm that allows for the boolean formulation of queries and the specification of the structure of search words in the desired records. The algorithm ranks retrieved records in assumed relevance to the user. The new algorithms were evaluated with regards to retrieval speed and accuracy and were found to be very effective.
- Full Text:
- Date Issued: 2004
- Authors: Du Plessis, Mathys Cornelius
- Date: 2004
- Subjects: Online algorithms , Database searching -- South Africa -- Port Elizabeth , Information retrieval -- South Africa -- Port Elizabeth
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:11094 , http://hdl.handle.net/10948/d1019681
- Description: This project is concerned with the development of a search algorithm for a large archival database. The Port Elizabeth Genealogical Information System (PEGIS) contains a database consisting of almost 600000 individuals. The standard search algorithms are no longer sufficient to locate individuals in the database. A new algorithm was required that allows searches on any of the words or dates in the database, as well as a means to specify where in the desired record a word should occur. A ranking function of retrieved records was also required. A literature study on the field of Information Retrieval and on algorithms designed specifically for the PEGIS was done. These algorithms were adapted and hybridized to yield a search algorithm that allows for the boolean formulation of queries and the specification of the structure of search words in the desired records. The algorithm ranks retrieved records in assumed relevance to the user. The new algorithms were evaluated with regards to retrieval speed and accuracy and were found to be very effective.
- Full Text:
- Date Issued: 2004
Rhodes University Graduation Ceremony 1959
- Authors: Rhodes University
- Date: 1959
- Language: English
- Type: text
- Identifier: vital:8093 , http://hdl.handle.net/10962/d1004403
- Description: Rhodes University Graduation Ceremony in the University Great Hall on Friday , 3rd April, 1959, at 8 p.m. [and] Graduation Ceremony held in April 1959: University College of Fort Hare. Graduation Ceremony at Fort Hare on Friday, April 17th, 1959.
- Full Text:
- Date Issued: 1959
- Authors: Rhodes University
- Date: 1959
- Language: English
- Type: text
- Identifier: vital:8093 , http://hdl.handle.net/10962/d1004403
- Description: Rhodes University Graduation Ceremony in the University Great Hall on Friday , 3rd April, 1959, at 8 p.m. [and] Graduation Ceremony held in April 1959: University College of Fort Hare. Graduation Ceremony at Fort Hare on Friday, April 17th, 1959.
- Full Text:
- Date Issued: 1959
Rhodes University Graduation Ceremony 2001
- Authors: Rhodes University
- Date: 2001
- Language: English
- Type: text
- Identifier: vital:8146 , http://hdl.handle.net/10962/d1007296
- Description: Rhodes University Graduation Ceremonies 1820 Settlers National Monument Friday, 6 April 2001 at 10:30; 18:00 [and] Saturday, 7 April 2001 at 10:30 , Graduation Ceremony Christian Centre, Wyse Street, East London Friday, 1 May 2001 at 18:00
- Full Text:
- Date Issued: 2001
- Authors: Rhodes University
- Date: 2001
- Language: English
- Type: text
- Identifier: vital:8146 , http://hdl.handle.net/10962/d1007296
- Description: Rhodes University Graduation Ceremonies 1820 Settlers National Monument Friday, 6 April 2001 at 10:30; 18:00 [and] Saturday, 7 April 2001 at 10:30 , Graduation Ceremony Christian Centre, Wyse Street, East London Friday, 1 May 2001 at 18:00
- Full Text:
- Date Issued: 2001
Fraction-specific geochemistry across the Asbestos Hills BIF of the Transvaal Supergroup, South Africa: implications for the origin of BIF and the history of atmospheric oxygen
- Oonk, Paul Bernardus Hendrikus
- Authors: Oonk, Paul Bernardus Hendrikus
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/50721 , vital:26021
- Description: Banded iron formations (BIF), deposited prior to and concurrent with the Great Oxidation Event (GOE) at ca. 2.4 Ga, record changes in oceanic and atmospheric chemistry during this critical time interval. Four previously unstudied drill-cores from the Griqualand West Basin, South Africa, capturing the rhythmically mesobanded, deep-water Kuruman BIF and the overlying granular, shallower Griquatown BIF, were sampled every ca. 10 m along core depth. Mineralogically, these BIFs consist of three iron-bearing fractions: (1) Fe-Ca-Mg-Mn carbonates, (2) magnetite with/without minor hematite and (3) Fe-silicates. These fractions are typically fine-grained on a sub-μm scale and their co-occurrence in varying amounts means that bulk-rock or microanalytical geochemical and stable isotope data are influenced by mineralogy.
- Full Text:
- Date Issued: 2017
- Authors: Oonk, Paul Bernardus Hendrikus
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/50721 , vital:26021
- Description: Banded iron formations (BIF), deposited prior to and concurrent with the Great Oxidation Event (GOE) at ca. 2.4 Ga, record changes in oceanic and atmospheric chemistry during this critical time interval. Four previously unstudied drill-cores from the Griqualand West Basin, South Africa, capturing the rhythmically mesobanded, deep-water Kuruman BIF and the overlying granular, shallower Griquatown BIF, were sampled every ca. 10 m along core depth. Mineralogically, these BIFs consist of three iron-bearing fractions: (1) Fe-Ca-Mg-Mn carbonates, (2) magnetite with/without minor hematite and (3) Fe-silicates. These fractions are typically fine-grained on a sub-μm scale and their co-occurrence in varying amounts means that bulk-rock or microanalytical geochemical and stable isotope data are influenced by mineralogy.
- Full Text:
- Date Issued: 2017
Synthesis, characterisation and biological activity of 2-(methylthiomethyl)anilines, 2-(methylthio)anilines, their Schiff-base derivatives and metal(II) (Co, Ni, Cu) complexes
- Olalekan, Temitope Elizabeth
- Authors: Olalekan, Temitope Elizabeth
- Date: 2013
- Subjects: Aniline , Schiff bases , Ligands , Nuclear magnetic resonance spectroscopy , Chelates , X-ray crystallography , Antimalarials
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4562 , http://hdl.handle.net/10962/d1020868
- Description: A series of 31 sulfur-nitrogen donor ligands and 64 metal(II) complexes have been investigated. The thiomethylated aniline ligands 2–(methylthiomethyl)aniline 2MT and 2–(methylthio)aniline 2MA were synthesized with their substituted derivatives (-Me, -MeO, -Cl, -Br, -NO2) to serve as chelating agents. These ligands behave as bidentate ligands with SN donor group with Co(II), Ni(II) and Cu(II). The Co(II) and Ni(II) complexes have the ML2Cl2 molecular formula while the Cu(II) complexes formed with MLCl2 stoichiometry where L is the bidentate ligand. The ligands and their metal(II) complexes have been characterized by elemental analysis and with spectroscopic techniques. The trend observed in the NMR spectra and IR frequencies of the thiomethylated compounds shows there is a significant difference between the 2MT and 2MA series as a result of sulfur lone pairs extending the conjugation of the aromatic ring in the case of the latter. The effect of the position and electronic nature of ring substituent on the NMR shifts of the amine protons is discussed. The 6- and 5-membered chelate complexes formed by the 2MT and 2MA ligands respectively do not show significant diversity in their spectroscopic properties. From the elemental analysis for the Co(II) and Ni(II) complexes, their compositions reveal 1:2 M:L stoichiometry with 2 chlorine atoms from the respective metal salts. In addition, the spectroscopic data are largely indicative of tetragonally distorted structures for these solid complexes. The X-ray crystallography data reveal the Cu(II) complexes exist as square pyramidal dimers and with long Cu–Cl equitorial bonds fit into the tetragonally distorted octahedral structure. The electrolytic nature of Co(II) and Cu(II) complexes in DMF were found to be similar, they behave as non electrolytes in contrast to Ni(II) complexes which are 1:1 electrolytes. The electronic spectra of these metal(II) complexes were found to be different for both their solid forms and in solutions of DMF and DMSO and this has been discussed. The thiomethylated aniline ligands possess the amine and thioether groups which are present in many known biologically active compounds, hence the biological activity of the ligands and their metal complexes were tested against three strains of bacteria and one fungus. The methoxy-substituted derivatives were found to possess better inhibitory activity and this was similarly reflected in the metal(II) complexes. The activity of the complexes can be said to be in the order, Cu(II) > Co(II) > Ni(II). The Schiff-base derivatives were prepared from the ligands and para-methoxysalicylaldehyde and their Cu(II) complexes were synthesized in order to determine their biological activity. The Schiff-base ligands were found to be less active than their parent ligands. The Cu(II) complexes are not soluble in water, DMSO or DMF, as a result and could not be evaluated for their biological activity. Based on the good results from the antimicrobial evaluation, the antiplasmodial activity of some of the Co(II), Ni(II) and Cu(II) complexes of the thiomethylated ligands against Plasmodium falciparum (FCR-3) was determined. At 50 μM concentration level, the Cu(II) complexes show activity equal or better than the prophylactic chloroquine. The Cu(II) complexes with the methoxy-substituted demonstrated exceptional activity but their Co(II) and Ni(II) analogues did not show any activity. The cytotoxicity of the active Cu(II) complexes at 50 μM concentration was determined against the breast cancer cell line (MDA-MB-231). The compounds destroyed the cancer cell in the range of 28–40%, thus showing their preferred activity against the parasitic cell instead of the cancer cell. The selectivity demonstrated by these compounds have shown them to be potential antimalarial agents and this could be further investigated.
- Full Text:
- Date Issued: 2013
- Authors: Olalekan, Temitope Elizabeth
- Date: 2013
- Subjects: Aniline , Schiff bases , Ligands , Nuclear magnetic resonance spectroscopy , Chelates , X-ray crystallography , Antimalarials
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4562 , http://hdl.handle.net/10962/d1020868
- Description: A series of 31 sulfur-nitrogen donor ligands and 64 metal(II) complexes have been investigated. The thiomethylated aniline ligands 2–(methylthiomethyl)aniline 2MT and 2–(methylthio)aniline 2MA were synthesized with their substituted derivatives (-Me, -MeO, -Cl, -Br, -NO2) to serve as chelating agents. These ligands behave as bidentate ligands with SN donor group with Co(II), Ni(II) and Cu(II). The Co(II) and Ni(II) complexes have the ML2Cl2 molecular formula while the Cu(II) complexes formed with MLCl2 stoichiometry where L is the bidentate ligand. The ligands and their metal(II) complexes have been characterized by elemental analysis and with spectroscopic techniques. The trend observed in the NMR spectra and IR frequencies of the thiomethylated compounds shows there is a significant difference between the 2MT and 2MA series as a result of sulfur lone pairs extending the conjugation of the aromatic ring in the case of the latter. The effect of the position and electronic nature of ring substituent on the NMR shifts of the amine protons is discussed. The 6- and 5-membered chelate complexes formed by the 2MT and 2MA ligands respectively do not show significant diversity in their spectroscopic properties. From the elemental analysis for the Co(II) and Ni(II) complexes, their compositions reveal 1:2 M:L stoichiometry with 2 chlorine atoms from the respective metal salts. In addition, the spectroscopic data are largely indicative of tetragonally distorted structures for these solid complexes. The X-ray crystallography data reveal the Cu(II) complexes exist as square pyramidal dimers and with long Cu–Cl equitorial bonds fit into the tetragonally distorted octahedral structure. The electrolytic nature of Co(II) and Cu(II) complexes in DMF were found to be similar, they behave as non electrolytes in contrast to Ni(II) complexes which are 1:1 electrolytes. The electronic spectra of these metal(II) complexes were found to be different for both their solid forms and in solutions of DMF and DMSO and this has been discussed. The thiomethylated aniline ligands possess the amine and thioether groups which are present in many known biologically active compounds, hence the biological activity of the ligands and their metal complexes were tested against three strains of bacteria and one fungus. The methoxy-substituted derivatives were found to possess better inhibitory activity and this was similarly reflected in the metal(II) complexes. The activity of the complexes can be said to be in the order, Cu(II) > Co(II) > Ni(II). The Schiff-base derivatives were prepared from the ligands and para-methoxysalicylaldehyde and their Cu(II) complexes were synthesized in order to determine their biological activity. The Schiff-base ligands were found to be less active than their parent ligands. The Cu(II) complexes are not soluble in water, DMSO or DMF, as a result and could not be evaluated for their biological activity. Based on the good results from the antimicrobial evaluation, the antiplasmodial activity of some of the Co(II), Ni(II) and Cu(II) complexes of the thiomethylated ligands against Plasmodium falciparum (FCR-3) was determined. At 50 μM concentration level, the Cu(II) complexes show activity equal or better than the prophylactic chloroquine. The Cu(II) complexes with the methoxy-substituted demonstrated exceptional activity but their Co(II) and Ni(II) analogues did not show any activity. The cytotoxicity of the active Cu(II) complexes at 50 μM concentration was determined against the breast cancer cell line (MDA-MB-231). The compounds destroyed the cancer cell in the range of 28–40%, thus showing their preferred activity against the parasitic cell instead of the cancer cell. The selectivity demonstrated by these compounds have shown them to be potential antimalarial agents and this could be further investigated.
- Full Text:
- Date Issued: 2013
Rhodeo, Vol. 22, No. 16
- Date: 1968-08-22
- Subjects: Grahamstown -- Newspapers , Journalism, Students -- South Africa , Rhodes University -- Activate , Rhodes University -- Students , Student newspapers and periodicals -- South Africa
- Language: English
- Type: Text
- Identifier: vital:14590 , http://hdl.handle.net/10962/d1019462
- Description: Rhodeo is the Independent Student Newspaper of Rhodes University. Located in Grahamstown, Rhodeo was established in 1947, and renamed in 1994 as Activate. During apartheid Rhodeo became an active part of the struggle for freedom of expression as part of the now defunct South African Student Press Union. Currently Activate is committed to informing Rhodes University students, staff and community members about relevant issues, mainly on campus. These issues range from hard news to more creative journalism. While Activate acts as a news source, one of its main objectives it to be accessible as a training ground for student journalists. The newspaper is run entirely by the students and is published twice a term. Activate is a free newspaper which receives an annual grant from the Rhodes University Student Representative Council, however, majority of its revenue is generated through advertising.
- Full Text:
- Date Issued: 1968-08-22
- Date: 1968-08-22
- Subjects: Grahamstown -- Newspapers , Journalism, Students -- South Africa , Rhodes University -- Activate , Rhodes University -- Students , Student newspapers and periodicals -- South Africa
- Language: English
- Type: Text
- Identifier: vital:14590 , http://hdl.handle.net/10962/d1019462
- Description: Rhodeo is the Independent Student Newspaper of Rhodes University. Located in Grahamstown, Rhodeo was established in 1947, and renamed in 1994 as Activate. During apartheid Rhodeo became an active part of the struggle for freedom of expression as part of the now defunct South African Student Press Union. Currently Activate is committed to informing Rhodes University students, staff and community members about relevant issues, mainly on campus. These issues range from hard news to more creative journalism. While Activate acts as a news source, one of its main objectives it to be accessible as a training ground for student journalists. The newspaper is run entirely by the students and is published twice a term. Activate is a free newspaper which receives an annual grant from the Rhodes University Student Representative Council, however, majority of its revenue is generated through advertising.
- Full Text:
- Date Issued: 1968-08-22
Rhodes University Graduation Ceremony 1977
- Authors: Rhodes University
- Date: 1977
- Subjects: MacKenzie, Ian
- Language: English
- Type: text
- Identifier: vital:8111 , http://hdl.handle.net/10962/d1004567 , MacKenzie, Ian
- Description: Rhodes University Graduation Ceremonies on Friday, 1st April, 1977 at 8 p.m. [and] on Saturday, 2nd April, 1977 at 10:30 a.m.in the 1820 Settlers National Monument. , The Order for the Installation of Ian MacKenzie as Chancellor of Rhodes University within the Great Hall on Thursday 31 March 1977 at 8:15 p.m.
- Full Text:
- Date Issued: 1977
- Authors: Rhodes University
- Date: 1977
- Subjects: MacKenzie, Ian
- Language: English
- Type: text
- Identifier: vital:8111 , http://hdl.handle.net/10962/d1004567 , MacKenzie, Ian
- Description: Rhodes University Graduation Ceremonies on Friday, 1st April, 1977 at 8 p.m. [and] on Saturday, 2nd April, 1977 at 10:30 a.m.in the 1820 Settlers National Monument. , The Order for the Installation of Ian MacKenzie as Chancellor of Rhodes University within the Great Hall on Thursday 31 March 1977 at 8:15 p.m.
- Full Text:
- Date Issued: 1977
Rhodes University Graduation Ceremony 1978
- Authors: Rhodes University
- Date: 1978
- Language: English
- Type: text
- Identifier: vital:8112 , http://hdl.handle.net/10962/d1004568
- Description: Rhodes University Graduation Ceremonies on Friday, 7th April, 1978 at 8 p.m. [and] on Saturday, 8th April, 1978 at 10:30 a.m. in the 1820 Settlers National Monument.
- Full Text:
- Date Issued: 1978
- Authors: Rhodes University
- Date: 1978
- Language: English
- Type: text
- Identifier: vital:8112 , http://hdl.handle.net/10962/d1004568
- Description: Rhodes University Graduation Ceremonies on Friday, 7th April, 1978 at 8 p.m. [and] on Saturday, 8th April, 1978 at 10:30 a.m. in the 1820 Settlers National Monument.
- Full Text:
- Date Issued: 1978
Synthesis, characterisation and antitumour activities of lanthanide complexes with hydrazones and carboxylic acid ligands
- Authors: Madanhire, Tatenda
- Date: 2020
- Subjects: Organic acids
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/48456 , vital:40878
- Description: The tridentate hydrazone ligands, (E)-N'-(2-hydroxybenzylidene)benzohydrazide (H2phen) and (E)-N'-(2-hydroxybenzylidene)nicotinohydrazide (H2Nic), were synthesised and complexed to Ln(III) acetates. The centrosymmetric, acetato-bridged dinuclear coordination compounds with the formulae, [La2(Hphen)2(OAc)4(H2O)2]·DMF·H2O (1), [Ln2(HNic)2(OAc)4(H2O)2]·DMF·H2O (Ln = La (2) and Nd (3)) and [Ln2(HNic)2(OAc)4(H2O)2]·DMF (Ln = Er (4) and Yb (5)) were isolated and characterised by elemental analyses, IR spectroscopy, UV-Vis spectroscopy, X-ray diffraction studies and SHAPE 2.1. The nine-coordinate complexes 1–3 crystallise in the triclinic space group P-1, with the metal centres having the distorted spherical capped square antiprism geometry (C4v), while the eight-coordinate Er(III) and Yb(III) complexes (monoclinic system, space group P21/c) display the geometry of distorted triangular dodecahedron (D2d). Geometry optimisation of the monoanionic forms of the hydrazone ligands (Hphen– and HNic– ) were performed using Density Functional Theory (DFT) with Becke’s three parameter hybrid method and correlation functional of Lee, Yang and Parr (B3LYP) with augcc-pVTZ basis set. Natural population analysis (NPA) and molecular electrostatic potential (MEP) maps indicated that the most preferred sites for electrophilic attack in the anionic ligands are the phenolate and carbonyl oxygens, and the azomethine nitrogens. The evaluation of the cytotoxic activity of the compounds on breast cancer (MCF-7), the endometrial carcinoma (HEC-1A) and the human monocytic (THP-1) cell lines using the 3-(4,5-dimethyl-2-thiazolyl)-2,5-diphenyl tetrazolium bromide (MTT) assay revealed that the hydrazone ligands and complexes 1–4 are partially cytotoxic against MCF-7 cells, while the Schiff bases and complexes 3–5 significantly inhibit cell growth in HEC-1A cells. The complexation reactions of Ce(III), Nd(III), Gd(III) and Er(III) with the chelating/ bridging monoanionic ligand N-(2,6-dimethylphenyl)oxamate (Hpma– ) in basic media were performed in view of the potential applications of oxamate derivatives as cytotoxic agents. The coordination compounds were characterised by different Abstract T. Madanhire Nelson Mandela University xxvi physico-chemical techniques: elemental analysis, conductivity measurements, IR, 1 H NMR and UV-Vis-NIR spectroscopy. The anionic Hpma– was obtained through conversion of the proligand ethyl (2,6-dimethylphenylcarbamoyl)formate (Hdmp). The reactions afforded lanthanide(III)–oxamate coordination polymers of formulae: {[Ln(Hpma)3(MeOH)(H2O)]∙2MeOH}n (Ln = Ce (1) and Nd (2)), {[Gd2(Hpma)6(MeOH)4]∙6MeOH}n (3), {[Er2(Hpma)6(MeOH)(H2O)3]∙2MeOH}n (4) and [Ln2Na2(Hpma)8(EtOH)(H2O)6]n (Ln = Nd (5) and Gd (6)). The polymeric complexes feature Ln-Hpma moieties bridged by μ2-η 1 :η 1 :η 1 Hpma– , giving onedimensional zig-zag chains of the –Ln–O–C–O–Ln– type. Atomic charge analysis and the MEP map of the Hpma– moiety done using the DFT/B3LYP method were found to be consistent with the chelating and bridging modes of the anionic ligand through all the oxygen atoms. The evaluation of the cytotoxic activities of the metal salts, the proligand and the novel lanthanide complexes on MCF-7, HEC-1A and THP-1 cell lines revealed that only the rare-earth metal salts [Ce(NO3)3∙6H2O] and [Nd(NO3)3∙6H2O] showed modest cytotoxicity against MCF-7 and HEC-1A cells, respectively.
- Full Text:
- Date Issued: 2020
- Authors: Madanhire, Tatenda
- Date: 2020
- Subjects: Organic acids
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/48456 , vital:40878
- Description: The tridentate hydrazone ligands, (E)-N'-(2-hydroxybenzylidene)benzohydrazide (H2phen) and (E)-N'-(2-hydroxybenzylidene)nicotinohydrazide (H2Nic), were synthesised and complexed to Ln(III) acetates. The centrosymmetric, acetato-bridged dinuclear coordination compounds with the formulae, [La2(Hphen)2(OAc)4(H2O)2]·DMF·H2O (1), [Ln2(HNic)2(OAc)4(H2O)2]·DMF·H2O (Ln = La (2) and Nd (3)) and [Ln2(HNic)2(OAc)4(H2O)2]·DMF (Ln = Er (4) and Yb (5)) were isolated and characterised by elemental analyses, IR spectroscopy, UV-Vis spectroscopy, X-ray diffraction studies and SHAPE 2.1. The nine-coordinate complexes 1–3 crystallise in the triclinic space group P-1, with the metal centres having the distorted spherical capped square antiprism geometry (C4v), while the eight-coordinate Er(III) and Yb(III) complexes (monoclinic system, space group P21/c) display the geometry of distorted triangular dodecahedron (D2d). Geometry optimisation of the monoanionic forms of the hydrazone ligands (Hphen– and HNic– ) were performed using Density Functional Theory (DFT) with Becke’s three parameter hybrid method and correlation functional of Lee, Yang and Parr (B3LYP) with augcc-pVTZ basis set. Natural population analysis (NPA) and molecular electrostatic potential (MEP) maps indicated that the most preferred sites for electrophilic attack in the anionic ligands are the phenolate and carbonyl oxygens, and the azomethine nitrogens. The evaluation of the cytotoxic activity of the compounds on breast cancer (MCF-7), the endometrial carcinoma (HEC-1A) and the human monocytic (THP-1) cell lines using the 3-(4,5-dimethyl-2-thiazolyl)-2,5-diphenyl tetrazolium bromide (MTT) assay revealed that the hydrazone ligands and complexes 1–4 are partially cytotoxic against MCF-7 cells, while the Schiff bases and complexes 3–5 significantly inhibit cell growth in HEC-1A cells. The complexation reactions of Ce(III), Nd(III), Gd(III) and Er(III) with the chelating/ bridging monoanionic ligand N-(2,6-dimethylphenyl)oxamate (Hpma– ) in basic media were performed in view of the potential applications of oxamate derivatives as cytotoxic agents. The coordination compounds were characterised by different Abstract T. Madanhire Nelson Mandela University xxvi physico-chemical techniques: elemental analysis, conductivity measurements, IR, 1 H NMR and UV-Vis-NIR spectroscopy. The anionic Hpma– was obtained through conversion of the proligand ethyl (2,6-dimethylphenylcarbamoyl)formate (Hdmp). The reactions afforded lanthanide(III)–oxamate coordination polymers of formulae: {[Ln(Hpma)3(MeOH)(H2O)]∙2MeOH}n (Ln = Ce (1) and Nd (2)), {[Gd2(Hpma)6(MeOH)4]∙6MeOH}n (3), {[Er2(Hpma)6(MeOH)(H2O)3]∙2MeOH}n (4) and [Ln2Na2(Hpma)8(EtOH)(H2O)6]n (Ln = Nd (5) and Gd (6)). The polymeric complexes feature Ln-Hpma moieties bridged by μ2-η 1 :η 1 :η 1 Hpma– , giving onedimensional zig-zag chains of the –Ln–O–C–O–Ln– type. Atomic charge analysis and the MEP map of the Hpma– moiety done using the DFT/B3LYP method were found to be consistent with the chelating and bridging modes of the anionic ligand through all the oxygen atoms. The evaluation of the cytotoxic activities of the metal salts, the proligand and the novel lanthanide complexes on MCF-7, HEC-1A and THP-1 cell lines revealed that only the rare-earth metal salts [Ce(NO3)3∙6H2O] and [Nd(NO3)3∙6H2O] showed modest cytotoxicity against MCF-7 and HEC-1A cells, respectively.
- Full Text:
- Date Issued: 2020
Variables affecting family employee remuneration in South African family businesses
- Authors: Pitsiladi, Lesvokli N
- Date: 2016
- Subjects: Family-owned business enterprises -- South Africa , Human capital -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/3449 , vital:20431
- Description: The purpose of this multi-case study research was to determine variables that affect The Perceived Success of Fair Family Employee Compensation in South African family businesses. Five propositions: Human Capital, Outside Advice, Succession Planning, Fairness and Family Harmony were tested and as a result, Human Capital, Fairness and Family Harmony were deduced to have a positive influence, while Outside Advice and Succession Planning had a non-significant influence. The present research effort begun with an in-depth literature review on family business and the variables: Human Capital, Outside Advice, Succession Planning, Fairness, Family Harmony and Fair Family Employee Compensation, followed by a qualitative explanatory multi-case study research design using embedded units of analysis and provided a valuable insight into compensation issues regarding family businesses in South Africa. Replication logic was used to generalise the results and it was recommended that the preliminary theory regarding Outside Advice and Succession Planning be revised and tested with another set of cases, while the results indicated that Human Capital, Fairness and Family Harmony could be generalised to the broader theory.
- Full Text:
- Date Issued: 2016
- Authors: Pitsiladi, Lesvokli N
- Date: 2016
- Subjects: Family-owned business enterprises -- South Africa , Human capital -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/3449 , vital:20431
- Description: The purpose of this multi-case study research was to determine variables that affect The Perceived Success of Fair Family Employee Compensation in South African family businesses. Five propositions: Human Capital, Outside Advice, Succession Planning, Fairness and Family Harmony were tested and as a result, Human Capital, Fairness and Family Harmony were deduced to have a positive influence, while Outside Advice and Succession Planning had a non-significant influence. The present research effort begun with an in-depth literature review on family business and the variables: Human Capital, Outside Advice, Succession Planning, Fairness, Family Harmony and Fair Family Employee Compensation, followed by a qualitative explanatory multi-case study research design using embedded units of analysis and provided a valuable insight into compensation issues regarding family businesses in South Africa. Replication logic was used to generalise the results and it was recommended that the preliminary theory regarding Outside Advice and Succession Planning be revised and tested with another set of cases, while the results indicated that Human Capital, Fairness and Family Harmony could be generalised to the broader theory.
- Full Text:
- Date Issued: 2016
Apartheid South Africa's foreign relations with African states, 1961-1994
- Authors: Pfister, Roger
- Date: 2004
- Subjects: Apartheid -- South Africa -- History -- 20th century Government, Resistance to -- South Africa Democracy -- South Africa South Africa -- Politics and government -- 20th century South Africa -- History -- 1961-1994 South Africa -- Foreign relations -- Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2863 , http://hdl.handle.net/10962/d1007632
- Description: This thesis examines South Africa's foreign relations, viewed from a South African perspective, with the black African countries beyond southern Africa from 1961 to 1994. These relations were determined by the conflict between Pretoria's apartheid ideology on the one hand, and African continental rejection of South Africa's race discrimination policies and its exclusion from the community of African states on the other. The documentary material used primarily stems from the Department of Foreign Affairs archive in Pretoria, supplemented by research conducted in other archives. Furthermore, we conducted interviews and correspondence, and consulted the relevant primary and secondary literature. Given the main source of information, we chose to make this work a case study in Diplomatic History. In consequence, and constituting the core of the study, Chapters 3 to 6 explore the interaction between South Africa and the black African states in a chronological order. At the same time, we draw on the analytical concepts from the academic disciplines of Political Science and its derivative, International Relations, to comprehend developments more fully. We discuss the significance of the approaches from these two disciplines in both the Introduction and Chapter 2. In particular, we emphasise that this study is about Pretoria's foreign policy, involving state and non-state actors, and we suggest that the unequal status between South Africa and the other African states constitutes an inherent factor in the relationship between them. The Conclusion examines the role of the state and non-state actors in determining Pretoria's foreign relations and the relevance of the structural imbalance between South Africa and the black African states in this context.
- Full Text:
- Date Issued: 2004
- Authors: Pfister, Roger
- Date: 2004
- Subjects: Apartheid -- South Africa -- History -- 20th century Government, Resistance to -- South Africa Democracy -- South Africa South Africa -- Politics and government -- 20th century South Africa -- History -- 1961-1994 South Africa -- Foreign relations -- Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2863 , http://hdl.handle.net/10962/d1007632
- Description: This thesis examines South Africa's foreign relations, viewed from a South African perspective, with the black African countries beyond southern Africa from 1961 to 1994. These relations were determined by the conflict between Pretoria's apartheid ideology on the one hand, and African continental rejection of South Africa's race discrimination policies and its exclusion from the community of African states on the other. The documentary material used primarily stems from the Department of Foreign Affairs archive in Pretoria, supplemented by research conducted in other archives. Furthermore, we conducted interviews and correspondence, and consulted the relevant primary and secondary literature. Given the main source of information, we chose to make this work a case study in Diplomatic History. In consequence, and constituting the core of the study, Chapters 3 to 6 explore the interaction between South Africa and the black African states in a chronological order. At the same time, we draw on the analytical concepts from the academic disciplines of Political Science and its derivative, International Relations, to comprehend developments more fully. We discuss the significance of the approaches from these two disciplines in both the Introduction and Chapter 2. In particular, we emphasise that this study is about Pretoria's foreign policy, involving state and non-state actors, and we suggest that the unequal status between South Africa and the other African states constitutes an inherent factor in the relationship between them. The Conclusion examines the role of the state and non-state actors in determining Pretoria's foreign relations and the relevance of the structural imbalance between South Africa and the black African states in this context.
- Full Text:
- Date Issued: 2004
Records of the inquest into the murder of Matthew Goniwe, Sparrow Mkonto, Fort Calata and Sicelo Mhlauli near Port Elizabeth on 21 June 1985
- Date: between 1987 and 1989 , 1987 , 1989 , 2020
- Subjects: Goniwe, Matthew 1946-1985 , Calata, Fort -1985 , Mkonto, Sparrow -1985 , Mhlauli, Sicelo -1985 , South Africa South African Defence Force , South African Police , Violent deaths South Africa , Inquests South Africa
- Language: English , Afrikaans
- Type: legal case and case notes , text
- Identifier: http://hdl.handle.net/10962/164749 , vital:41161 , Rhodes University, Cory Library for Humanities Research Cory Library Manuscript Collection MS 18 898
- Description: Inquest no. 626/87, heard in the Regional Court at New Brighton, Port Elizabeth. Record of proceedings and finding by Mr E de Beer.
- Full Text:
- Date Issued: between 1987 and 1989
- Date Issued: 1987
- Date Issued: 1989
- Date: between 1987 and 1989 , 1987 , 1989 , 2020
- Subjects: Goniwe, Matthew 1946-1985 , Calata, Fort -1985 , Mkonto, Sparrow -1985 , Mhlauli, Sicelo -1985 , South Africa South African Defence Force , South African Police , Violent deaths South Africa , Inquests South Africa
- Language: English , Afrikaans
- Type: legal case and case notes , text
- Identifier: http://hdl.handle.net/10962/164749 , vital:41161 , Rhodes University, Cory Library for Humanities Research Cory Library Manuscript Collection MS 18 898
- Description: Inquest no. 626/87, heard in the Regional Court at New Brighton, Port Elizabeth. Record of proceedings and finding by Mr E de Beer.
- Full Text:
- Date Issued: between 1987 and 1989
- Date Issued: 1987
- Date Issued: 1989