Spirit possession and social panic: Amakhosi possession and behaviour among learners in selected schools in Mdantsane Township
- Authors: Meveni, Siphiwo Douglas
- Date: 2014
- Subjects: Spirit possession -- South Africa -- Eastern Cape , Cults -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Soc Sc (Anthropology)
- Identifier: vital:11775 , http://hdl.handle.net/10353/d1018564 , Spirit possession -- South Africa -- Eastern Cape , Cults -- South Africa -- Eastern Cape
- Description: This research sought to investigate the phenomenon of strange behaviour related to spirit possession called amakhosi in Mdantsane Township in East London in the Eastern Cape Province of South Africa. This spirit phenomenon has recently been prevalent in Township schools in the Eastern and Western Cape Provinces where school children were said to be possessed by a spirit which caused them to demonstrate a strange kind of destructive behaviour. These occurrences were also reported in the newspapers and community radio stations. All these media communications reported that teachers, parents and community leaders were increasingly concerned over a growing trend wherein children purchase muti called amakhosi which makes them to behave mysteriously and at times climbed school walls with their bear hands and at time becoming violent to the extent of threatening other learners and educators. The informants included community members, learners and educators. In a mainly qualitative research method, empirical data was collected from five selected high schools by means of observations, individual interviews and group discussions. The main aim of this study was to better understand this amakhosi phenomenon and to determine whether it is a spiritual, drug related or a social phenomenon. The findings of the study suggested that amakhosi possession is partly a spiritual phenomenon and should not be overlooked as it can result into serious crimes leading to death just like in the recent cases of satanic killing reported among the youth in South Africa. Secondly, there is also a strong element of drug abuse among the youth associated with amakhosi rituals. Lastly, amakhosi is more than just a spiritual issue. It is a socio-economic problem which mostly involves the youth who are struggling in identifying their roles and positions in the post apartheid South Africa. The main recommendation is that the amakhosi phenomenon needs a „wholistic‟ approach and not to just intervention by involvement of prayers and traditional healers.
- Full Text:
- Authors: Meveni, Siphiwo Douglas
- Date: 2014
- Subjects: Spirit possession -- South Africa -- Eastern Cape , Cults -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Soc Sc (Anthropology)
- Identifier: vital:11775 , http://hdl.handle.net/10353/d1018564 , Spirit possession -- South Africa -- Eastern Cape , Cults -- South Africa -- Eastern Cape
- Description: This research sought to investigate the phenomenon of strange behaviour related to spirit possession called amakhosi in Mdantsane Township in East London in the Eastern Cape Province of South Africa. This spirit phenomenon has recently been prevalent in Township schools in the Eastern and Western Cape Provinces where school children were said to be possessed by a spirit which caused them to demonstrate a strange kind of destructive behaviour. These occurrences were also reported in the newspapers and community radio stations. All these media communications reported that teachers, parents and community leaders were increasingly concerned over a growing trend wherein children purchase muti called amakhosi which makes them to behave mysteriously and at times climbed school walls with their bear hands and at time becoming violent to the extent of threatening other learners and educators. The informants included community members, learners and educators. In a mainly qualitative research method, empirical data was collected from five selected high schools by means of observations, individual interviews and group discussions. The main aim of this study was to better understand this amakhosi phenomenon and to determine whether it is a spiritual, drug related or a social phenomenon. The findings of the study suggested that amakhosi possession is partly a spiritual phenomenon and should not be overlooked as it can result into serious crimes leading to death just like in the recent cases of satanic killing reported among the youth in South Africa. Secondly, there is also a strong element of drug abuse among the youth associated with amakhosi rituals. Lastly, amakhosi is more than just a spiritual issue. It is a socio-economic problem which mostly involves the youth who are struggling in identifying their roles and positions in the post apartheid South Africa. The main recommendation is that the amakhosi phenomenon needs a „wholistic‟ approach and not to just intervention by involvement of prayers and traditional healers.
- Full Text:
Stakeholders' participation in curriculum development in four secondary schools in Fort Beaufort education district, Eastern cape province: towards a participatory curriculum model
- Authors: Obi, Uloma Nkpurunma
- Date: 2014
- Subjects: Curriculum planning Educational planning -- South Africa -- Eastern Cape Education -- Curricula -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5840 , vital:29401
- Description: The new democratic government came to power in 1994 and one of its major missions was to change the system of education inherited from the apartheid regime by laying a foundation for a single national core syllabus to replace the erstwhile multi-tier system, which discriminated among racial groups. Under the apartheid regime, the curriculum was flawed by ‘racially, offensive and outdated content’ and the government embarked on a bold programme to cleanse it of these elements. The democratic government went about this through curriculum reforms. In 1997, it introduced Curriculum 2005 fondly called “C2005”, with the Outcome-based Education (OBE) principles. Despite the initial overwhelming support for C2005, it soon ran into trouble. In 2000, the Minister appointed a committee that reviewed the curriculum and in 2002, the Revised National Curriculum Statement (RNCS) was born. These curriculum reforms have been met with a lot of criticism and the government felt it was not serving its purpose. Some key stakeholders still felt that their non-involvement, non-participation and the lack of proper consultation in the curriculum process were partly responsible for teachers and subject advisers misinterpreting the curriculum and implementing it from their own perspectives. Subsequently, another review was done and the National Curriculum Statement (NCS) was launched in 2002. But the complaints did not cease, probably due to continuing poor performance at the Matric Examination which continues to feature low pass rates for many provinces, especially the Eastern Cape. Against this backdrop, the government streamlined the NCS curriculum yield, and an amended Curriculum and Assessment Policy Statement (CAPS) emerged. The key issue raised by critics is the lack of sufficient involvement of stakeholders in the curriculum review processes. At the same time, government continues to insist that it has been consulting adequately with all relevant stakeholders. There are iii obviously different interpretations of stakeholder involvement and participation and there is urgent need to reconcile whatever differences of opinion and definition exist, in order to gain common understanding, which is the first step in reaching a solution. For instance, how are the stakeholders involved? More importantly, what is meant by “involvement”? Even if there is no disagreement about the meaning of “involvement”, is the stage in the process at which the stakeholders are involved an important element in whether or not the process is an inclusive and participatory one?.
- Full Text:
- Authors: Obi, Uloma Nkpurunma
- Date: 2014
- Subjects: Curriculum planning Educational planning -- South Africa -- Eastern Cape Education -- Curricula -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5840 , vital:29401
- Description: The new democratic government came to power in 1994 and one of its major missions was to change the system of education inherited from the apartheid regime by laying a foundation for a single national core syllabus to replace the erstwhile multi-tier system, which discriminated among racial groups. Under the apartheid regime, the curriculum was flawed by ‘racially, offensive and outdated content’ and the government embarked on a bold programme to cleanse it of these elements. The democratic government went about this through curriculum reforms. In 1997, it introduced Curriculum 2005 fondly called “C2005”, with the Outcome-based Education (OBE) principles. Despite the initial overwhelming support for C2005, it soon ran into trouble. In 2000, the Minister appointed a committee that reviewed the curriculum and in 2002, the Revised National Curriculum Statement (RNCS) was born. These curriculum reforms have been met with a lot of criticism and the government felt it was not serving its purpose. Some key stakeholders still felt that their non-involvement, non-participation and the lack of proper consultation in the curriculum process were partly responsible for teachers and subject advisers misinterpreting the curriculum and implementing it from their own perspectives. Subsequently, another review was done and the National Curriculum Statement (NCS) was launched in 2002. But the complaints did not cease, probably due to continuing poor performance at the Matric Examination which continues to feature low pass rates for many provinces, especially the Eastern Cape. Against this backdrop, the government streamlined the NCS curriculum yield, and an amended Curriculum and Assessment Policy Statement (CAPS) emerged. The key issue raised by critics is the lack of sufficient involvement of stakeholders in the curriculum review processes. At the same time, government continues to insist that it has been consulting adequately with all relevant stakeholders. There are iii obviously different interpretations of stakeholder involvement and participation and there is urgent need to reconcile whatever differences of opinion and definition exist, in order to gain common understanding, which is the first step in reaching a solution. For instance, how are the stakeholders involved? More importantly, what is meant by “involvement”? Even if there is no disagreement about the meaning of “involvement”, is the stage in the process at which the stakeholders are involved an important element in whether or not the process is an inclusive and participatory one?.
- Full Text:
Stratigraphy and sedimentology of the Mzamba formation in the Eastern Cape, South Africa
- Authors: Susela, Zamampondo
- Date: 2014
- Language: English
- Type: Thesis , Masters , MSc (Geology)
- Identifier: vital:11529 , http://hdl.handle.net/10353/d1019807
- Description: This research project is aimed at providing new information to the stratigraphy, sedimentology, palaeontology and diagenesis of the Mzamba Formation. The study area is located at the south of Port Edward, Eastern Cape. The methodologies employed in this study include field geological investigation and sampling, stratigraphic measurement and logging, thin-section microscope study, powder samples of XRD analysis, and SEM-EDX analysis of rock textures and mineral compositions. The stratigraphy of the Mzamba Formation can be divided into three newly established members, i.e. the Lower Conglomerate Member, Middle Silt/Mudstone-Shell Bed Member and Upper Mudstone-Shell Bed Member with a total thickness of 31.26m in an inland borehole and 30.05m in the field measurement. The Lower Conglomerate Member is 2.65m thick and consists of pebbly conglomerate with coarse sandstone, shell fragments and silicified wood trunks, representing shallow marine nearshore deposits. The Middle Silt/Mudstone and Shell Bed Member is 9.5 m thick and consists of black mudstone and fine-grained siltstone alternated with medium grained pecten beds, which was deposited in a storm influenced deeper marine environment. The Upper Mudstone-Shell Bed Member is 17.9m thick and is made up of fine-mudstones with articulated pecten layers which were deposited in a deep and quiet marine environment. Petrology studies showed that the Mzamba Formation consists of mixed sediments of carbonate and siliciclastic rocks. Siliciclastic rocks include pebbly conglomerates, medium to coarse sandstones and fine-grained mudstones, whereas carbonate rocks include packstone, wackstone and grainstone (pecten beds). The formation shows cyclical pattern of a series fining-upward cyclicities, changing from bottom conglomerate to sandstone, then upward repeated series of cyclotherms from pecten bed to mudstone. Mineralogy of the Mzamba Formation consists of terrigenous minerals of quartz, orthoclase, plagioclase, muscovite and various igneous and metamorphic rock-lithics, clay minerals of smectite, illite and sericite, and carbonate minerals of calcite and dolomite; with minor diagenetic minerals of pyrite, glauconite, hematite, gypsum, albite and organic maceral of vitrinite. Heavy minerals of garnet, zircon and rutile are minor minerals in the strata, which were detrital in origin. Mzamba Formation is a fossiliferous sequence, and contains both fauna and flora fossils in the strata. The pecten beds host well-preserved bivalve, gastropod, brachiopoda, ammonite, and echinoderm; whereas trace fossils of coprolites, burrows and tracks, as well as plant fossils of silicified wood trunks were also found in the formation. Some new fossil species were collected and studied, which include Bivalve: Pteriaceae, Pinnacea and Ostreacea; Gastropod: Cerithiacea and Mesogastopoda; Echinoderm: Echinocystoidea and Crinoidea. The benthonic species predominate in the lower part in the succession, whilst the planktonic species are abundant in the upper part of the sequence, which points to increase in water depths of the depositional environment. Based on lithology, sedimentary structures, and stratum architecture, seven different facies have been distinguished. Facies A (Flat bedded pebbly conglomerate), Facie B (Cross-bedded coarse calcareous sandstone facies), Facies C (Burrowed sandstone facies), Facies D (Shell-fragmental fine-grained calcareous sandstone facies), Facies E (Horizontal bedded calcareous mudstone facies), Facies F (Calcareous patch reef), Facies G (Wash out reef facies). Wash out reef facies is rich in algae, bivalve shells, broken oysters, coral fragments and small pebbles. Four types of cements were found in the Mzamba Formation, including calcite, smectite, illite and quartz. Calcite cement can be further classified into two types, micrite calcite cement and sparite calcite cement. The clay cement consists of smectite and illite and mainly occurs as matrix. The isopachous rim calcite and bright isopachous rim of silica cements indicate diagenesis in a marine phreatic zone. Authigenic minerals which formed in early diagenetic stage include quartz, plagioclase, glauconite and organic maceral of vitrinite. Three stages of diagenesis have been recognised in the sequence, i.e. syndiagenesis, early and late diagenesis. Glauconite pellets and worm faecal pellets were formed in syndiagenetic stage; cementation and authigenic minerals were formed in early diagenetic stage; whereas clay mineral conversion of smectite to illite, quartz overgrowth, bioclast recrystallization and calcite replacement took place during late diagenetic stage. The pebbly conglomerate at the bottom of the Mzamba Formation represents high energy deposits in a shallow marine environment; the grain-size gradually becomes finer in the middle succession and finest mudstone facies at the top of the succession, which represents deep marine deposits. Meanwhile, benthonic fossils are dominant in the bottom succession while plankton fossils are more abundant in the top succession. These features indicate that the Mzamba Formation constitutes a perfect transgression sequence, and the depositional environments started from shallow marine near shore environment, and gradually shifted to a deep marine quiet water environment.
- Full Text:
- Authors: Susela, Zamampondo
- Date: 2014
- Language: English
- Type: Thesis , Masters , MSc (Geology)
- Identifier: vital:11529 , http://hdl.handle.net/10353/d1019807
- Description: This research project is aimed at providing new information to the stratigraphy, sedimentology, palaeontology and diagenesis of the Mzamba Formation. The study area is located at the south of Port Edward, Eastern Cape. The methodologies employed in this study include field geological investigation and sampling, stratigraphic measurement and logging, thin-section microscope study, powder samples of XRD analysis, and SEM-EDX analysis of rock textures and mineral compositions. The stratigraphy of the Mzamba Formation can be divided into three newly established members, i.e. the Lower Conglomerate Member, Middle Silt/Mudstone-Shell Bed Member and Upper Mudstone-Shell Bed Member with a total thickness of 31.26m in an inland borehole and 30.05m in the field measurement. The Lower Conglomerate Member is 2.65m thick and consists of pebbly conglomerate with coarse sandstone, shell fragments and silicified wood trunks, representing shallow marine nearshore deposits. The Middle Silt/Mudstone and Shell Bed Member is 9.5 m thick and consists of black mudstone and fine-grained siltstone alternated with medium grained pecten beds, which was deposited in a storm influenced deeper marine environment. The Upper Mudstone-Shell Bed Member is 17.9m thick and is made up of fine-mudstones with articulated pecten layers which were deposited in a deep and quiet marine environment. Petrology studies showed that the Mzamba Formation consists of mixed sediments of carbonate and siliciclastic rocks. Siliciclastic rocks include pebbly conglomerates, medium to coarse sandstones and fine-grained mudstones, whereas carbonate rocks include packstone, wackstone and grainstone (pecten beds). The formation shows cyclical pattern of a series fining-upward cyclicities, changing from bottom conglomerate to sandstone, then upward repeated series of cyclotherms from pecten bed to mudstone. Mineralogy of the Mzamba Formation consists of terrigenous minerals of quartz, orthoclase, plagioclase, muscovite and various igneous and metamorphic rock-lithics, clay minerals of smectite, illite and sericite, and carbonate minerals of calcite and dolomite; with minor diagenetic minerals of pyrite, glauconite, hematite, gypsum, albite and organic maceral of vitrinite. Heavy minerals of garnet, zircon and rutile are minor minerals in the strata, which were detrital in origin. Mzamba Formation is a fossiliferous sequence, and contains both fauna and flora fossils in the strata. The pecten beds host well-preserved bivalve, gastropod, brachiopoda, ammonite, and echinoderm; whereas trace fossils of coprolites, burrows and tracks, as well as plant fossils of silicified wood trunks were also found in the formation. Some new fossil species were collected and studied, which include Bivalve: Pteriaceae, Pinnacea and Ostreacea; Gastropod: Cerithiacea and Mesogastopoda; Echinoderm: Echinocystoidea and Crinoidea. The benthonic species predominate in the lower part in the succession, whilst the planktonic species are abundant in the upper part of the sequence, which points to increase in water depths of the depositional environment. Based on lithology, sedimentary structures, and stratum architecture, seven different facies have been distinguished. Facies A (Flat bedded pebbly conglomerate), Facie B (Cross-bedded coarse calcareous sandstone facies), Facies C (Burrowed sandstone facies), Facies D (Shell-fragmental fine-grained calcareous sandstone facies), Facies E (Horizontal bedded calcareous mudstone facies), Facies F (Calcareous patch reef), Facies G (Wash out reef facies). Wash out reef facies is rich in algae, bivalve shells, broken oysters, coral fragments and small pebbles. Four types of cements were found in the Mzamba Formation, including calcite, smectite, illite and quartz. Calcite cement can be further classified into two types, micrite calcite cement and sparite calcite cement. The clay cement consists of smectite and illite and mainly occurs as matrix. The isopachous rim calcite and bright isopachous rim of silica cements indicate diagenesis in a marine phreatic zone. Authigenic minerals which formed in early diagenetic stage include quartz, plagioclase, glauconite and organic maceral of vitrinite. Three stages of diagenesis have been recognised in the sequence, i.e. syndiagenesis, early and late diagenesis. Glauconite pellets and worm faecal pellets were formed in syndiagenetic stage; cementation and authigenic minerals were formed in early diagenetic stage; whereas clay mineral conversion of smectite to illite, quartz overgrowth, bioclast recrystallization and calcite replacement took place during late diagenetic stage. The pebbly conglomerate at the bottom of the Mzamba Formation represents high energy deposits in a shallow marine environment; the grain-size gradually becomes finer in the middle succession and finest mudstone facies at the top of the succession, which represents deep marine deposits. Meanwhile, benthonic fossils are dominant in the bottom succession while plankton fossils are more abundant in the top succession. These features indicate that the Mzamba Formation constitutes a perfect transgression sequence, and the depositional environments started from shallow marine near shore environment, and gradually shifted to a deep marine quiet water environment.
- Full Text:
Stratigraphy, sedimentary facies and diagenesis of the ECCA group, Karoo supergroup in the Eastern Cape, South Africa
- Authors: Nyathi, Nonhlanhla
- Date: 2014
- Language: English
- Type: Thesis , Masters , MSc (Geology)
- Identifier: vital:11528 , http://hdl.handle.net/10353/d1019776
- Description: This is a MSc research project, and is aimed at the new insight on the stratigraphy, sedimentary facies, diagenesis and depositional environments of the Ecca Group, Karoo Supergroup in the Eastern Cape Province. Methodologies used in this research include field investigation, stratigraphic logging, thin-section microscope study, X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) analyses. The stratigraphy of the Ecca Group is divided into five formations, namely the Prince Albert Formation, Whitehill Formation, Collingham Formation, Rippon Formation and the Fort Brown Formation from bottom upward. Based on the field investigation and laboratory correlation, the Prince Albert, Whitehill, Collingham, and Fort Brown Formations can each be subdivided into two new members, i.e. lower member and upper member; whereas three new members have been proposed for the Rippon Formation, i.e. lower, middle and upper members. The Ecca Group sediments were accumulated in various depositional environments, from bottom of deep marine environment, passed through the middle of deltaic environment, and ended in a lacustrine environment. The Prince Albert Formation, Whitehill Formation and the Collingham Formation were all deposited in a deep marine basin, whilst the Rippon Formation was laid down in a deltaic environment. As the climate gradually became warmer and drier, the top Fort Brown Formation was lastly deposited in a lacustrine environment. The stratigraphic succession of the Ecca Group constitutes a perfect regression sequence, indicating that the marine water gradually retreated and the sea-level gradually dropped. The rocks in the Ecca Group are mainly terrigenous sandstone and mudstone with some coarse grain-sized siliciclastic rock of conglomerate. The sandstones are dominated by feldspathic graywackes with minor quartz-wackes, and there are no arenites in the Ecca Group. Whereas the mudstones are dominated by grayish mudrocks and black shales, purer claystone was found in the turbidite facies of the Collingham Formation, which probably has economic significance for the future since the reserve is quite large. Optical microscope, XRD and SEM analyses demonstrated that the minerals in the Ecca Group include detrital minerals of quartz, orthoclase, microcline, plagioclase, biotite, muscovite; and clay minerals (smectite, kaolinite, illite and sericite). These minerals constitute the rock framework grains and cements whereas; the authigenic minerals of calcite and hematite were formed during diagenesis. Accessory minerals such as rutile and zircon are the heavy minerals present in the strata, and occur only in a small amount. Based on the lithologies, sedimentary structures and sequence stacking patterns, ten sedimentary facies have been recognised, namely 1) Grayish laminated and thin bedded shale facies, 2) Grayish laminated shale and intercalated chert facies, 3) Grayish rhythmite facies (all the three facies above were deposited in deep marine water); 4) Flat and lenticular bedded graywacke facies, 5) Grayish alternating mudstone and sandstone facies, 6) Dark organic rich mudstone facies, 7) Fossil bearing mudstone facies, 8) Laminated and thin bedded black mudstone with lenticular siltstone facies, 9) Interbedded grayish sandstone and mudstone facies (above Facies 4-9 were deposited in deltaic environment and appeared in the Rippon Formation); and 10) Varved rhythmic mudstone facies, which occurs only in the Fort Brown Formation and represents lacustrine sediments. Four types of cements have been identified in the rocks of the Ecca Group, including quartz, smectite, calcite and feldspar cements. The first three cement types are the major cement types, whilst the feldspar cement is minor and occurs only locally. Recrystallisation in Ecca sediments includes quartz, feldspar, clay mineral recrystallisation and conversion from smectite and kaolinite to illite and then to sericite. Replacement involves calcite replacing quartz, feldspar and clay matrix; accompanied by albitization, i.e. albite replacing other feldspar minerals in a deep burial environment. Dissolution in the Ecca Group involved calcite and kaolinite dissolving and leaching, which created more pore-space and increased porosity. The sediments of the Ecca Group went through three stages of digenesis, namely the early stage, the late stage and the up lift stage which led the rocks being exposed on the Earth’s surface and being weathered. In each stage, some minerals became unstable, then replaced by a more stable mineral suitable for the new diagenetic environment. Precipitation of cements and formation of authigenic minerals mostly occurred in the early diagenetic stage, which led the soft sediments becoming a hard rock; whilst recrystallisation, replacement, and dissolution took place mostly in the later diageneti
- Full Text:
- Authors: Nyathi, Nonhlanhla
- Date: 2014
- Language: English
- Type: Thesis , Masters , MSc (Geology)
- Identifier: vital:11528 , http://hdl.handle.net/10353/d1019776
- Description: This is a MSc research project, and is aimed at the new insight on the stratigraphy, sedimentary facies, diagenesis and depositional environments of the Ecca Group, Karoo Supergroup in the Eastern Cape Province. Methodologies used in this research include field investigation, stratigraphic logging, thin-section microscope study, X-Ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) analyses. The stratigraphy of the Ecca Group is divided into five formations, namely the Prince Albert Formation, Whitehill Formation, Collingham Formation, Rippon Formation and the Fort Brown Formation from bottom upward. Based on the field investigation and laboratory correlation, the Prince Albert, Whitehill, Collingham, and Fort Brown Formations can each be subdivided into two new members, i.e. lower member and upper member; whereas three new members have been proposed for the Rippon Formation, i.e. lower, middle and upper members. The Ecca Group sediments were accumulated in various depositional environments, from bottom of deep marine environment, passed through the middle of deltaic environment, and ended in a lacustrine environment. The Prince Albert Formation, Whitehill Formation and the Collingham Formation were all deposited in a deep marine basin, whilst the Rippon Formation was laid down in a deltaic environment. As the climate gradually became warmer and drier, the top Fort Brown Formation was lastly deposited in a lacustrine environment. The stratigraphic succession of the Ecca Group constitutes a perfect regression sequence, indicating that the marine water gradually retreated and the sea-level gradually dropped. The rocks in the Ecca Group are mainly terrigenous sandstone and mudstone with some coarse grain-sized siliciclastic rock of conglomerate. The sandstones are dominated by feldspathic graywackes with minor quartz-wackes, and there are no arenites in the Ecca Group. Whereas the mudstones are dominated by grayish mudrocks and black shales, purer claystone was found in the turbidite facies of the Collingham Formation, which probably has economic significance for the future since the reserve is quite large. Optical microscope, XRD and SEM analyses demonstrated that the minerals in the Ecca Group include detrital minerals of quartz, orthoclase, microcline, plagioclase, biotite, muscovite; and clay minerals (smectite, kaolinite, illite and sericite). These minerals constitute the rock framework grains and cements whereas; the authigenic minerals of calcite and hematite were formed during diagenesis. Accessory minerals such as rutile and zircon are the heavy minerals present in the strata, and occur only in a small amount. Based on the lithologies, sedimentary structures and sequence stacking patterns, ten sedimentary facies have been recognised, namely 1) Grayish laminated and thin bedded shale facies, 2) Grayish laminated shale and intercalated chert facies, 3) Grayish rhythmite facies (all the three facies above were deposited in deep marine water); 4) Flat and lenticular bedded graywacke facies, 5) Grayish alternating mudstone and sandstone facies, 6) Dark organic rich mudstone facies, 7) Fossil bearing mudstone facies, 8) Laminated and thin bedded black mudstone with lenticular siltstone facies, 9) Interbedded grayish sandstone and mudstone facies (above Facies 4-9 were deposited in deltaic environment and appeared in the Rippon Formation); and 10) Varved rhythmic mudstone facies, which occurs only in the Fort Brown Formation and represents lacustrine sediments. Four types of cements have been identified in the rocks of the Ecca Group, including quartz, smectite, calcite and feldspar cements. The first three cement types are the major cement types, whilst the feldspar cement is minor and occurs only locally. Recrystallisation in Ecca sediments includes quartz, feldspar, clay mineral recrystallisation and conversion from smectite and kaolinite to illite and then to sericite. Replacement involves calcite replacing quartz, feldspar and clay matrix; accompanied by albitization, i.e. albite replacing other feldspar minerals in a deep burial environment. Dissolution in the Ecca Group involved calcite and kaolinite dissolving and leaching, which created more pore-space and increased porosity. The sediments of the Ecca Group went through three stages of digenesis, namely the early stage, the late stage and the up lift stage which led the rocks being exposed on the Earth’s surface and being weathered. In each stage, some minerals became unstable, then replaced by a more stable mineral suitable for the new diagenetic environment. Precipitation of cements and formation of authigenic minerals mostly occurred in the early diagenetic stage, which led the soft sediments becoming a hard rock; whilst recrystallisation, replacement, and dissolution took place mostly in the later diageneti
- Full Text:
Structural, optical and electrical characterization of nano-sized c-tio2 quamtum dots synthesized by spray pyrolysis
- Authors: Taziwa, Raymond Tichaona
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11342 , http://hdl.handle.net/10353/d1016089
- Description: In the 21st century, scientific communities face challenges and opportunities concerning future development, where innovations must be a key driver over the past, evolution of African societies were based on incomplete models, only taking into account economical growth and not paying attention to environmental deterioration as a consequence of anthropogenic activity and environmental pollution. We have to learn from our past mistakes in order not to repeat them. Education and research of today as the embryonic stages of the development models of tomorrow should be directed toward a sustainable mentality. In this sense, solar energy technologies have emerged as key instruments for minimizing environmental impact as well as reducing economic cost in the field of renewable energies. Titanium dioxide is a fascinating low cost material exhibiting unique properties of stability and photo catalytic activities, leading to clean technologies in water purification and energy conversion of sunlight. However, conventional techniques (high temperature, high vacuum, high pressures) of processing titanium dioxide are a technological limitation due to excessive energy consumption. This poses a handicap for practical applications in areas such as preparation of hybrid organic/Titanium dioxide materials or devices on thermo flexible substrates such as plastic material. It is for this reason that the investigation presented in this Ph.D thesis deals with the development of spray pyrolysis techniques for preparation of carbon doped titanium dioxide nano powders for solar cell applications. This thesis is therefore structured as follows: Chapter 1 gives a general overview of the work done in this thesis. This work relies greatly on the excellent structural optical and electrical properties of TiO2 thin films, as well as its chemical resistance and insulating properties. A summary of the physical, optical, electrical and chemical properties reported in the literature, with an emphasis on those relevant to solar cell fabrication, is presented in Chapter 2. Chapter 3 gives a concise literature review on models governing droplet formation in ultrasonic spray pyrolysis (USP) techniques, the limitations of these models have been exposed and a new relation model for estimating the final particle size given a set of initial reaction conditions has been proposed. The presently derived model is quite advantageous in that it does not require the investigator to look up values of surface tension and density for every precursor solution. Chapter 4 presents in detail the designed and constructed spray pyrolysis system capable of realizing desired nano structures for photovoltaic applications. The first system employed an ultrasonic atomization spray nozzle in order to create an aerosol of the TiO2 precursor. The reasons for choosing ultrasonic spray deposition (USP) and the TiO2 precursors, titanium iso propoxide and titanium tetra butoxide are discussed. Chapter 5 outlines experimental methodologies used in synthesis and characterization of the materials used in this study. Chapter 5 further provides experimental methodologies used in fabrication of a new type of photo electrochemical solar cells (PECs). Chapter 6 reveals the opto-electrical results of PECs solar cells fabricated. There are numerous properties that are affected by the size but emphasis will be placed on nano-size and confinement effects. Chapter 7 presents a confirmation of the phonon confinement effects in C-TiO2 QDs for the first time. In addition Chapter 7 also presents a new phonon confinement model. Chapter 8 reveals the optical, structural and electronic properties of C-TiO2 QDs synthesized by USP and PSP techniques. In addition the electrical properties of C-TiO2 QDs PEC solar cells devices are reported in Chapter 8. Concluding remarks, with potential future research projects are presented in Chapter 9. Through these 9 chapters, all research questions have been answered satisfactorily and all objectives met. Most of the work contained in this thesis has been subjected to external reviews through publication of these peer reviewed articles.
- Full Text:
- Authors: Taziwa, Raymond Tichaona
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11342 , http://hdl.handle.net/10353/d1016089
- Description: In the 21st century, scientific communities face challenges and opportunities concerning future development, where innovations must be a key driver over the past, evolution of African societies were based on incomplete models, only taking into account economical growth and not paying attention to environmental deterioration as a consequence of anthropogenic activity and environmental pollution. We have to learn from our past mistakes in order not to repeat them. Education and research of today as the embryonic stages of the development models of tomorrow should be directed toward a sustainable mentality. In this sense, solar energy technologies have emerged as key instruments for minimizing environmental impact as well as reducing economic cost in the field of renewable energies. Titanium dioxide is a fascinating low cost material exhibiting unique properties of stability and photo catalytic activities, leading to clean technologies in water purification and energy conversion of sunlight. However, conventional techniques (high temperature, high vacuum, high pressures) of processing titanium dioxide are a technological limitation due to excessive energy consumption. This poses a handicap for practical applications in areas such as preparation of hybrid organic/Titanium dioxide materials or devices on thermo flexible substrates such as plastic material. It is for this reason that the investigation presented in this Ph.D thesis deals with the development of spray pyrolysis techniques for preparation of carbon doped titanium dioxide nano powders for solar cell applications. This thesis is therefore structured as follows: Chapter 1 gives a general overview of the work done in this thesis. This work relies greatly on the excellent structural optical and electrical properties of TiO2 thin films, as well as its chemical resistance and insulating properties. A summary of the physical, optical, electrical and chemical properties reported in the literature, with an emphasis on those relevant to solar cell fabrication, is presented in Chapter 2. Chapter 3 gives a concise literature review on models governing droplet formation in ultrasonic spray pyrolysis (USP) techniques, the limitations of these models have been exposed and a new relation model for estimating the final particle size given a set of initial reaction conditions has been proposed. The presently derived model is quite advantageous in that it does not require the investigator to look up values of surface tension and density for every precursor solution. Chapter 4 presents in detail the designed and constructed spray pyrolysis system capable of realizing desired nano structures for photovoltaic applications. The first system employed an ultrasonic atomization spray nozzle in order to create an aerosol of the TiO2 precursor. The reasons for choosing ultrasonic spray deposition (USP) and the TiO2 precursors, titanium iso propoxide and titanium tetra butoxide are discussed. Chapter 5 outlines experimental methodologies used in synthesis and characterization of the materials used in this study. Chapter 5 further provides experimental methodologies used in fabrication of a new type of photo electrochemical solar cells (PECs). Chapter 6 reveals the opto-electrical results of PECs solar cells fabricated. There are numerous properties that are affected by the size but emphasis will be placed on nano-size and confinement effects. Chapter 7 presents a confirmation of the phonon confinement effects in C-TiO2 QDs for the first time. In addition Chapter 7 also presents a new phonon confinement model. Chapter 8 reveals the optical, structural and electronic properties of C-TiO2 QDs synthesized by USP and PSP techniques. In addition the electrical properties of C-TiO2 QDs PEC solar cells devices are reported in Chapter 8. Concluding remarks, with potential future research projects are presented in Chapter 9. Through these 9 chapters, all research questions have been answered satisfactorily and all objectives met. Most of the work contained in this thesis has been subjected to external reviews through publication of these peer reviewed articles.
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Studies on the antimicrobial, antioxidant and antiproliferative potential of the ethyl acetate extract and compounds of Peltophorum africanum
- Authors: Okeleye, Benjamin Ifeoluwa
- Date: 2014
- Language: English
- Type: Thesis , Masters , MSc (Microbiology)
- Identifier: vital:11282 , http://hdl.handle.net/10353/d1016165
- Description: Cells are constantly exposed to a variety of oxidizing agents, some of which are necessary for life. Oxidants produced in excess can cause an imbalance, leading to oxidative stress, especially in chronic bacterial, viral, and parasitic infections. This can result to damage of biomolecules such as lipids, proteins, and DNA, hence, an increased risk for cancer. Plants have a long history of use in the treatment of cancer. Plant secondary metabolites have proved to be an excellent reservoir of new medical compounds. Fruits, vegetables, and whole grains contain a wide variety of antioxidant phytochemicals, such as phenolics and carotenoids, and may help protect cellular systems from oxidative damage and also may lower the risk of chronic diseases. Peltophorum africanum, a member of the family Fabaceae (Sond) is also known as the African weeping wattle and is used in traditional medicine in South Africa. This study investigated the antimicrobial, antioxidant and antiproliferative potential of the ethyl acetate extract and compounds of Peltophorum africanum in order to validate its pharmacological use. The study assessed the in vitro antimicrobial activity of ethyl acetate extract (EAE) of Peltophorum africanum stem bark and its fractions by the agar well and macrodilution methods. The toxicity on a normal human liver cell (Chang liver cell) and antiproliferation of human breast (MCF-7), colon (HT-29) and cervical (HeLa) cancer cell lines were determined using the CellTiter-Blue cell viability assay and the mechanism of action delineated using the Nucleic Acid and Protein Purification Nucleospin® Tissue Kit, Scanning Electron Microscopy (SEM), Propidium iodide (PI) and Acridine orange (AO) double-staining techniques, the Cleaved Caspase 3 (Asp 175) Alexa Fluor® 488 Antibody and the Coulter® DNA PrepTM Reagents Kit. Purification and identification of the compounds from EAE and fractions as well as the morphological alteration of bacteria, yeast and cancer cells were determined using thin layer chromatography, infrared spectra fingerprint and GC-MS analysis, micro-dilution and scanning electron microscopy with energy-dispersive X-ray analysis. In vitro antioxidant activity of EAE was determined by means of radical scavenging and ferric reducing power analysis using 2, 2-diphenyl-1-picrylhydrazyl (DPPH), 2, 2`-azino-bis (3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) kit, hydrogen peroxide (H2O2), iron (iii) chloride (Fe3+) and nitric oxide (NO). To assess the likely effects of secondary metabolites on the activities observed; total proanthocyanidins, phenolics, flavonols, and flavonoids were determined using standard phytochemical methods. Data were analyzed by one way analysis of variance (ANOVA; SPSS Version 17.0, 2011), regression analysis (MINITAB, version 12 for windows), probit analysis test (software NCSS, 2007) and GraphPad Prism4 software package. The p-values < 0.05 were considered significant. Marked activity of the extract was observed against Plesiomonas shigelloides ATCC 51903, with MIC and MLC values of 0.15625 and 0.3125mg/mL, respectively. The extract was both bactericidal (MICindex ≤ 2) and bacteriostatic/fungistatic (MICindex > 2) in activity. Lethal dose at 50 (LD50) showed 82.64 ± 1.40 degree of toxicity at 24 hrs, and 95 percentile of cell death dose activity ranged from log 3.12 ± 0.01 to 4.59 ± 0.03. The activity of the eight fractions tested ranged from 1.0 ± 0.5 to 3.7 ± 1.6 mg/mL (IC50) and from 2.1 ± 0.8 to 6.25 ± 0 mg/mL (IC90) (Chapter 3). Due to the effect of compounds present in the crude extract and fractions, the P. aeruginosa treated with EAE had a reduction of sodium from 5.55 % (untreated) - 1.50 %. For C. albicans, pottasium was reduced from 4.16 % (untreated) - 0.76 % (T1). Remarkable morphological alterations were observed including deformation of the germ tubes and perforation of the cell wall (Chapter 4). Extract scavenging activity of 88.73± 6.69 % (25 μg mL-1), 53.93±1.09 % (25 μg mL-1) were recorded for H2O2 and NO respectively with proanthocyanidins (92.18±4.68 mg/g) occurring more (p < 0.05) in the extract compared to all other phenolics compounds (Chapter 5). Significant reduction in cell viability of the cells was noted as the MCF-7 cells were reduced from 100 - 54.33±1.84 % after 72 hrs of treatment with 5 μg/mL of EAE (P. value < 0.05). TEt10 was cytotoxic against human normal cells (chang liver cell) at EC50 of 37 μg/mL and 74 μg/mL after 24 and 48 h of treatment respectively. Marked antiproliferative activity of 13.2 μg/mL (EC50) was observed when HeLa cells were treated for 48 h. Internucleosomal DNA of MCF-7, HT-29 and HeLa cells randomly fragmented into an uninterrupted spectrum of sizes, complemented by the intercalation of nucleic acid-specific fluorochromes by PI and AO spotting two phases of apoptosis; early (EA) and late (LA) apoptosis. Distinctive ultramorphological changes observed include; cell shrinkage, membrane blebbing, and typical cell induced death. The study also recorded 705.102 ± 28.56 % TEt10 caspase-3 activity compared to curcumin 592.857 ± 165.76 % (positive control) and untreated (negative control; 100 ± 15.81 %) cells. Percentage HeLa cell with Sub-G1 DNA phase increased from 0.13 ± 0.06 % (negative control) to 13.8 ± 3.04 % compared to curcumin (8.17 ± 2.20 %) after treatment with TEt10. The compounds identified in the fractions including Colchicine, N-(trifluoroacetyl)methyl-N-deacetyl-, Lupeol and .gamma.-Sitosterol may be responsible for the induction of apoptosis observed and could be further studied in vivo as a potential template for new anticancer treatment (Chapter 6 & 7).
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- Authors: Okeleye, Benjamin Ifeoluwa
- Date: 2014
- Language: English
- Type: Thesis , Masters , MSc (Microbiology)
- Identifier: vital:11282 , http://hdl.handle.net/10353/d1016165
- Description: Cells are constantly exposed to a variety of oxidizing agents, some of which are necessary for life. Oxidants produced in excess can cause an imbalance, leading to oxidative stress, especially in chronic bacterial, viral, and parasitic infections. This can result to damage of biomolecules such as lipids, proteins, and DNA, hence, an increased risk for cancer. Plants have a long history of use in the treatment of cancer. Plant secondary metabolites have proved to be an excellent reservoir of new medical compounds. Fruits, vegetables, and whole grains contain a wide variety of antioxidant phytochemicals, such as phenolics and carotenoids, and may help protect cellular systems from oxidative damage and also may lower the risk of chronic diseases. Peltophorum africanum, a member of the family Fabaceae (Sond) is also known as the African weeping wattle and is used in traditional medicine in South Africa. This study investigated the antimicrobial, antioxidant and antiproliferative potential of the ethyl acetate extract and compounds of Peltophorum africanum in order to validate its pharmacological use. The study assessed the in vitro antimicrobial activity of ethyl acetate extract (EAE) of Peltophorum africanum stem bark and its fractions by the agar well and macrodilution methods. The toxicity on a normal human liver cell (Chang liver cell) and antiproliferation of human breast (MCF-7), colon (HT-29) and cervical (HeLa) cancer cell lines were determined using the CellTiter-Blue cell viability assay and the mechanism of action delineated using the Nucleic Acid and Protein Purification Nucleospin® Tissue Kit, Scanning Electron Microscopy (SEM), Propidium iodide (PI) and Acridine orange (AO) double-staining techniques, the Cleaved Caspase 3 (Asp 175) Alexa Fluor® 488 Antibody and the Coulter® DNA PrepTM Reagents Kit. Purification and identification of the compounds from EAE and fractions as well as the morphological alteration of bacteria, yeast and cancer cells were determined using thin layer chromatography, infrared spectra fingerprint and GC-MS analysis, micro-dilution and scanning electron microscopy with energy-dispersive X-ray analysis. In vitro antioxidant activity of EAE was determined by means of radical scavenging and ferric reducing power analysis using 2, 2-diphenyl-1-picrylhydrazyl (DPPH), 2, 2`-azino-bis (3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) kit, hydrogen peroxide (H2O2), iron (iii) chloride (Fe3+) and nitric oxide (NO). To assess the likely effects of secondary metabolites on the activities observed; total proanthocyanidins, phenolics, flavonols, and flavonoids were determined using standard phytochemical methods. Data were analyzed by one way analysis of variance (ANOVA; SPSS Version 17.0, 2011), regression analysis (MINITAB, version 12 for windows), probit analysis test (software NCSS, 2007) and GraphPad Prism4 software package. The p-values < 0.05 were considered significant. Marked activity of the extract was observed against Plesiomonas shigelloides ATCC 51903, with MIC and MLC values of 0.15625 and 0.3125mg/mL, respectively. The extract was both bactericidal (MICindex ≤ 2) and bacteriostatic/fungistatic (MICindex > 2) in activity. Lethal dose at 50 (LD50) showed 82.64 ± 1.40 degree of toxicity at 24 hrs, and 95 percentile of cell death dose activity ranged from log 3.12 ± 0.01 to 4.59 ± 0.03. The activity of the eight fractions tested ranged from 1.0 ± 0.5 to 3.7 ± 1.6 mg/mL (IC50) and from 2.1 ± 0.8 to 6.25 ± 0 mg/mL (IC90) (Chapter 3). Due to the effect of compounds present in the crude extract and fractions, the P. aeruginosa treated with EAE had a reduction of sodium from 5.55 % (untreated) - 1.50 %. For C. albicans, pottasium was reduced from 4.16 % (untreated) - 0.76 % (T1). Remarkable morphological alterations were observed including deformation of the germ tubes and perforation of the cell wall (Chapter 4). Extract scavenging activity of 88.73± 6.69 % (25 μg mL-1), 53.93±1.09 % (25 μg mL-1) were recorded for H2O2 and NO respectively with proanthocyanidins (92.18±4.68 mg/g) occurring more (p < 0.05) in the extract compared to all other phenolics compounds (Chapter 5). Significant reduction in cell viability of the cells was noted as the MCF-7 cells were reduced from 100 - 54.33±1.84 % after 72 hrs of treatment with 5 μg/mL of EAE (P. value < 0.05). TEt10 was cytotoxic against human normal cells (chang liver cell) at EC50 of 37 μg/mL and 74 μg/mL after 24 and 48 h of treatment respectively. Marked antiproliferative activity of 13.2 μg/mL (EC50) was observed when HeLa cells were treated for 48 h. Internucleosomal DNA of MCF-7, HT-29 and HeLa cells randomly fragmented into an uninterrupted spectrum of sizes, complemented by the intercalation of nucleic acid-specific fluorochromes by PI and AO spotting two phases of apoptosis; early (EA) and late (LA) apoptosis. Distinctive ultramorphological changes observed include; cell shrinkage, membrane blebbing, and typical cell induced death. The study also recorded 705.102 ± 28.56 % TEt10 caspase-3 activity compared to curcumin 592.857 ± 165.76 % (positive control) and untreated (negative control; 100 ± 15.81 %) cells. Percentage HeLa cell with Sub-G1 DNA phase increased from 0.13 ± 0.06 % (negative control) to 13.8 ± 3.04 % compared to curcumin (8.17 ± 2.20 %) after treatment with TEt10. The compounds identified in the fractions including Colchicine, N-(trifluoroacetyl)methyl-N-deacetyl-, Lupeol and .gamma.-Sitosterol may be responsible for the induction of apoptosis observed and could be further studied in vivo as a potential template for new anticancer treatment (Chapter 6 & 7).
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Synoptic circulation patterns and its relationship with ground thermal characteristics along an altitudinal transect on sub-Antarctic Marion Island
- Authors: Bierman, Stefni
- Date: 2014
- Language: English
- Type: Thesis , Masters , MSc (Geography)
- Identifier: vital:11516 , http://hdl.handle.net/10353/d1015532
- Description: The climate of Marion Island is driven by synoptic weather patterns which have also been suggested to influence the soil thermal characteristics. The primary aim of this work was to examine the effect of synoptic weather systems on soil temperature dynamics on an altitudinal gradient on the eastern side of Marion Island. The study specifically addresses the implications of climate change on future soil thermal dynamics in a maritime sub-Antarctic environment. Ground temperature were obtained from three ground temperature monitoring stations on the eastern side of Marion Island, which were established along an altitudinal gradient at Long Ridge North (200m a.s.l.), Katedraalkrans (750m a.s.l) and at Delta Extension (1000m a.s.l.). To assess the synoptic weather circulation patterns, a synoptic climate classification methodology that is based on the single station principal component (PCA) and cluster analysis were used. Results show that certain clusters were more dominant than others and over the measured time span certain synoptic weather patterns, mainly cyclonic air circulation types, have decreased while anticyclonic circulation have increased. Soil frost occurs at all three stations on Marion Island, not only under cyclonic circulations (as previously suggested) but significantly under anticyclonic air mass circulation as well. Soil frost is dependent on the duration of post-cyclonic Antarctic air mass circulation. Synoptic weather patterns are also affecting ground surface lapse rates. Changes from positive to negative lapse rates were observed and this predominantly occurred under the atmospheric circulation pattern associated with clusters that are predominantly anticyclonic. Long term climatic change as predicted by the PCA show a reduction in low pressure systems or more anticyclonic conditions affecting the island. These change will significantly affect the soil thermal dynamics at an altitudinal scale on sub-Antarctic Marion Island.
- Full Text:
- Authors: Bierman, Stefni
- Date: 2014
- Language: English
- Type: Thesis , Masters , MSc (Geography)
- Identifier: vital:11516 , http://hdl.handle.net/10353/d1015532
- Description: The climate of Marion Island is driven by synoptic weather patterns which have also been suggested to influence the soil thermal characteristics. The primary aim of this work was to examine the effect of synoptic weather systems on soil temperature dynamics on an altitudinal gradient on the eastern side of Marion Island. The study specifically addresses the implications of climate change on future soil thermal dynamics in a maritime sub-Antarctic environment. Ground temperature were obtained from three ground temperature monitoring stations on the eastern side of Marion Island, which were established along an altitudinal gradient at Long Ridge North (200m a.s.l.), Katedraalkrans (750m a.s.l) and at Delta Extension (1000m a.s.l.). To assess the synoptic weather circulation patterns, a synoptic climate classification methodology that is based on the single station principal component (PCA) and cluster analysis were used. Results show that certain clusters were more dominant than others and over the measured time span certain synoptic weather patterns, mainly cyclonic air circulation types, have decreased while anticyclonic circulation have increased. Soil frost occurs at all three stations on Marion Island, not only under cyclonic circulations (as previously suggested) but significantly under anticyclonic air mass circulation as well. Soil frost is dependent on the duration of post-cyclonic Antarctic air mass circulation. Synoptic weather patterns are also affecting ground surface lapse rates. Changes from positive to negative lapse rates were observed and this predominantly occurred under the atmospheric circulation pattern associated with clusters that are predominantly anticyclonic. Long term climatic change as predicted by the PCA show a reduction in low pressure systems or more anticyclonic conditions affecting the island. These change will significantly affect the soil thermal dynamics at an altitudinal scale on sub-Antarctic Marion Island.
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Synthesis, characterization & comparative evaluation of photo-catalytic & antimicrobial activity of Ag2O and TiO2 immobilized on nanofibres for treatment
- Authors: Gxumisa, Xoliswa
- Date: 2014
- Subjects: Pollution http://id.loc.gov/authorities/subjects/sh85104530 , Titanium dioxide http://id.loc.gov/authorities/subjects/sh85135627 , Photocatalysis http://id.loc.gov/authorities/subjects/sh93001301
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/19545 , vital:43138
- Description: Water is a very essential substance for the existence of organisms and the environment where it functions as a transport medium for valuable chemicals, minerals, nutrients and also as a reaction medium. However, the remarkable water properties are not just limited to the dissolution of biological valuable substances, but also to harmful entities during pollution. This has led to research in the improvement and development of new techniques for water treatment. In this study, titanium dioxide (TiO2) and silver oxide (Ag2O) were prepared using the sol gel process and precipitation method respectively. The TiO2 was doped using a sol gel process with carbon and nitrogen so as to reduce the band gap. TiO2/Ag2O, N-TiO2/Ag2O and C-TiO2/Ag2O composites were also prepared using a precipitation method. The average particle size of prepared TiO2, C-TiO2, N-TiO2, Ag2O, TiO2/Ag2O, N-TiO2/Ag2O and CTiO2/Ag2O was found to be 13nm, 7nm, 10nm, 23nm, 28nm, 24nm and 21nm respectively as measured by TEM analysis. The photo-catalysts, Ag2O and TiO2 and their composites were immobilized on stabilized nanofibres using the electrospinning process to allow subsequent separation and reconciliation of the photo-catalyst after use in water treatment. The photocatalytic and antimicrobial activities of photo-catalysts were also evaluated using water contaminated with phenol red dye and Escherichia coli. The prepared materials were characterized by XRD, TEM, HRSEM, DRS, EDX, FT-IR, and TGA. Carbon was found to be more effective as a dopant than nitrogen. It reduced the band gap by 0.4 while nitrogen doping showed a reduction in band gap of 0.2 compared to undoped titanium dioxide. The doped TiO2 exhibited higher photo-catalytic and antimicrobial activity than the undoped TiO2. Introduction of Ag2O allowed utilization of visible light by the TiO2- Ag2O nano-composite leading to an improved rate of photo-degradation of phenol red and inactivation of E coli. Photo-catalytic properties showed that carbon doped materials have a higher photo-catalytic activity than nitrogen doped materials, while for antimicrobial v properties it is vice-versa. The immobilization of photo-catalysts on support material made it less effective towards the degradation of phenol red. The rate of photo-oxidation of phenol red was three times faster using powder TiO2 compared to immobilized TiO2. Therefore, this study suggests that photo-catalysis can be used as an effective method for water disinfection and production of potable and pathogen free drinking water even though better methods of immobilization should be sought. , Thesis (MSc) (Chemistry) -- University of Fort Hare, 2014
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- Authors: Gxumisa, Xoliswa
- Date: 2014
- Subjects: Pollution http://id.loc.gov/authorities/subjects/sh85104530 , Titanium dioxide http://id.loc.gov/authorities/subjects/sh85135627 , Photocatalysis http://id.loc.gov/authorities/subjects/sh93001301
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/19545 , vital:43138
- Description: Water is a very essential substance for the existence of organisms and the environment where it functions as a transport medium for valuable chemicals, minerals, nutrients and also as a reaction medium. However, the remarkable water properties are not just limited to the dissolution of biological valuable substances, but also to harmful entities during pollution. This has led to research in the improvement and development of new techniques for water treatment. In this study, titanium dioxide (TiO2) and silver oxide (Ag2O) were prepared using the sol gel process and precipitation method respectively. The TiO2 was doped using a sol gel process with carbon and nitrogen so as to reduce the band gap. TiO2/Ag2O, N-TiO2/Ag2O and C-TiO2/Ag2O composites were also prepared using a precipitation method. The average particle size of prepared TiO2, C-TiO2, N-TiO2, Ag2O, TiO2/Ag2O, N-TiO2/Ag2O and CTiO2/Ag2O was found to be 13nm, 7nm, 10nm, 23nm, 28nm, 24nm and 21nm respectively as measured by TEM analysis. The photo-catalysts, Ag2O and TiO2 and their composites were immobilized on stabilized nanofibres using the electrospinning process to allow subsequent separation and reconciliation of the photo-catalyst after use in water treatment. The photocatalytic and antimicrobial activities of photo-catalysts were also evaluated using water contaminated with phenol red dye and Escherichia coli. The prepared materials were characterized by XRD, TEM, HRSEM, DRS, EDX, FT-IR, and TGA. Carbon was found to be more effective as a dopant than nitrogen. It reduced the band gap by 0.4 while nitrogen doping showed a reduction in band gap of 0.2 compared to undoped titanium dioxide. The doped TiO2 exhibited higher photo-catalytic and antimicrobial activity than the undoped TiO2. Introduction of Ag2O allowed utilization of visible light by the TiO2- Ag2O nano-composite leading to an improved rate of photo-degradation of phenol red and inactivation of E coli. Photo-catalytic properties showed that carbon doped materials have a higher photo-catalytic activity than nitrogen doped materials, while for antimicrobial v properties it is vice-versa. The immobilization of photo-catalysts on support material made it less effective towards the degradation of phenol red. The rate of photo-oxidation of phenol red was three times faster using powder TiO2 compared to immobilized TiO2. Therefore, this study suggests that photo-catalysis can be used as an effective method for water disinfection and production of potable and pathogen free drinking water even though better methods of immobilization should be sought. , Thesis (MSc) (Chemistry) -- University of Fort Hare, 2014
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Synthesis, characterization, and biological studies of pyrazolone Schiff bases and their transition metal complexes
- Authors: Idemudia, Omoruyi Gold
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11340 , http://hdl.handle.net/10353/d1016068
- Description: Some new acylpyrazolone Schiff bases have been synthesized from the condensation reaction of two acylpyrazolone diketone precursors with phenylhydrazine, 2,4-dinitrophenylhydrazine and sulfanilamide. They have been fully characterized by elemental analysis and spectroscopic techniques (IR,1H and 13C NMR, and mass-spectra). The single crystal structure of the benzoyl derivative acylpyrazolone Schiff bases have been obtained and analyzed by X-ray crystallography technique. Solid state X-ray diffraction revealed a keto tautomer Schiff base in solid state. Mn(II), Co(II), Ni(II) and Cu(II) complexes with the Schiff bases have been synthesized and characterized by elemental analysis, IR and UV-VIS spectroscopy, magnetic susceptibility measurements, and thermal studies (TGA and DTG). An octahedral geometry around the transition metal ion, consisting of two bidentate Schiff base ligands bonding through the azometine nitrogen and ketonic oxygen have been proposed based on careful interpretation of available analytical and spectroscopic characterization results. Two water molecules as ligands complete the octahedral geometry in all cases. Using the invitro disc diffusion method for screening synthesized compounds against selected gram positive and gram negative bacterial at 40 mg/mL, and the DPPH free radical scavenging methods at 0.50, 0.25 and 0.13 mg/mL, the synthesized Schiff base and metal complexes showed varying biological activities. 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one sul29 fanilamide showed more activity generally, exhibiting a broad spectrum activity against all selected bacterial in some cases. Mn(II), Co(II) and Ni(II) complexes of sulfanilamide Schiff base with the acetylpyrazolone derivative 4-acetyl-3-methyl-1-phenyl-2-pyrazolin-5-one sulfanilamide, exhibited a stronger and very good DPPH radical scavenging activity as good as ascorbic acid on comparing, but not with Cu(II). As such they could be important antitumour candidates.
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- Authors: Idemudia, Omoruyi Gold
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11340 , http://hdl.handle.net/10353/d1016068
- Description: Some new acylpyrazolone Schiff bases have been synthesized from the condensation reaction of two acylpyrazolone diketone precursors with phenylhydrazine, 2,4-dinitrophenylhydrazine and sulfanilamide. They have been fully characterized by elemental analysis and spectroscopic techniques (IR,1H and 13C NMR, and mass-spectra). The single crystal structure of the benzoyl derivative acylpyrazolone Schiff bases have been obtained and analyzed by X-ray crystallography technique. Solid state X-ray diffraction revealed a keto tautomer Schiff base in solid state. Mn(II), Co(II), Ni(II) and Cu(II) complexes with the Schiff bases have been synthesized and characterized by elemental analysis, IR and UV-VIS spectroscopy, magnetic susceptibility measurements, and thermal studies (TGA and DTG). An octahedral geometry around the transition metal ion, consisting of two bidentate Schiff base ligands bonding through the azometine nitrogen and ketonic oxygen have been proposed based on careful interpretation of available analytical and spectroscopic characterization results. Two water molecules as ligands complete the octahedral geometry in all cases. Using the invitro disc diffusion method for screening synthesized compounds against selected gram positive and gram negative bacterial at 40 mg/mL, and the DPPH free radical scavenging methods at 0.50, 0.25 and 0.13 mg/mL, the synthesized Schiff base and metal complexes showed varying biological activities. 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one sul29 fanilamide showed more activity generally, exhibiting a broad spectrum activity against all selected bacterial in some cases. Mn(II), Co(II) and Ni(II) complexes of sulfanilamide Schiff base with the acetylpyrazolone derivative 4-acetyl-3-methyl-1-phenyl-2-pyrazolin-5-one sulfanilamide, exhibited a stronger and very good DPPH radical scavenging activity as good as ascorbic acid on comparing, but not with Cu(II). As such they could be important antitumour candidates.
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Targeting and characterizing potentially high yield aquifers in the neotectonic zones in the Eastern Cape Province in South Africa
- Authors: Madi, Kakaba
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Geology)
- Identifier: vital:11530 , http://hdl.handle.net/10353/d1021270
- Description: The Eastern Cape Province has, besides the three known neotectonic belts (southern, eastern and northern) a fourth zone, which is inactive. This inactive zone is located almost in its central part north of the southern neotectonic zone, and south of the northern neotectonic belt. The three above mentioned neotectonic belts (southern, eastern and northern) were chosen for this study, each one with its own characteristics. This study aims at characterizing and targeting potentially high yield aquifers in the neotectonic zones in the Eastern Cape Province. The methods used in this study include: 1) A comprehensive literature review on neotectonics in South Africa in general and in the Eastern Cape Province in particular; 2) Extraction of lineaments through remote sensing and examination of digital elevation models; 3) Examination of seismic data for the subsurface visualization onshore and offshore; 4) Study on the genesis of the Grahamstown kaolin deposits through the structural component; and 5) Acquisition and interpretation of magnetic, electromagnetic and radiometric data from three of the hot springs in the northern neotectonic belt. The results indicate the following: 1) Old map of seismic epicentres in South Africa need to be reviewed continually. The Eastern Cape was regarded as quiescent in terms of seismicity. However, the investigation from recent seismic epicenters downloadable from the IRIS website has shown that recent seismic events occurred in the Eastern Cape Province especially in the northern and southern neotectonic belts. The central part located north of the southern neotectonic belt and south of the northern neotectonic belt is inactive. This inactive zone can be considered for the storage of nuclear wastes. 2) The eastern neotectonic belt has, like the northern neotectonic belt, a higher density of lineaments oriented northwest-southeast, which makes it the second important neotectonic belt. These lineaments correlate with the normalized difference vegetation index indicative of a good circulation of groundwater. In the south, the Eastern Cape great lineament oriented east-west is now considered a neotectonic domain because many seismic epicentres occur therein. Its geomorphologic shape in graben type form is a favourable structure for groundwater catchment. The surface topography is not uniform and high elevations in the east are related to the uplift that took place in the Quaternary. Most vector gradients are oriented east-west, a fact to be reckon with in the study of surface water flow and aquifers characterization. 3) Offshore along the east coast, the subsurface is affected by neotectonic faults, which are probably splays of the Agulhas Falkland Fractured Zone (AFFZ). The folds that occur are related to the regional compressional stress known as the Wegener Stress Anomaly (WSM). On land, straight lines from seismic profiles indicate that weathering occurs in consolidated materials probably along faults or fractures, unconsolidated sediments always have wavy profiles. On the other hand, field observations in King Williams Town have clearly shown that a tectonic uplift took place on a dolerite sill overlain by mudstones and sandstones. The uplift is possibly related to the Amatole-Swaziland event that occurred in the last five millions years. The escarpment along this dolerite sill overlain by sedimentary rocks is a meso-scale fault with a dip-slip component. Healthy vegetation and a river flowing parallel to the cliff indicate groundwater flow in the zone of weakness. 4) In the southern neotectonic belt there is a clear northwest-southeast horizontal compression and a southwest-northeast vertical to sub-vertical extension. Enrichment of granitic breccias and feldspar in the Grahamstown Dwyka tillite is the source for the formation of kaolin deposits. The weathering starts in the granitic breccias through their extensional fractures and then extends in the matrix, which has micro-fractures that are only visible with the transmitted microscope. Combined extensional strike-slip and dip-slip faulting is responsible for the earthquakes in the region of Grahamstown where the kaolin is formed. There is also an unreported thermal (quartz veins) and neotectonic event identified in this region. 5) The hot springs in the northern neotectonic belt are connected by a regional neotectonic fault. The use of magnetic and electromagnetic methods helped to decipher the occurrence of faults, fractures, dolerite dykes, and variable degree of weathering. Uranium/potassium ratios derived from radiometric surveys show that areas around some hot springs are characterized by enrichment in uranium. High concentrations of thorium are related to its low capacity of being easily dissolved in water. It can be concluded that seismicity, hot springs and accordingly deep groundwater circulation, high density of lineaments, quaternary tectonic uplift, are the predominate characteristics of the three neotectonic zones. Furthermore, on the environmental point of view, thorium concentration is higher than that of either uranium or potassium. Although it is nonetheless below the world average threshold of 7.4 ppm according to United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR), it may be a source of radiation hazard to humans and animals if they are subjected to prolonged exposure. All the neotectonic zones in the Eastern Cape Province present potentials to host good and important aquifers. It is suggested that the Eastern Cape great lineament in the southern neotectonic belt and the Kokstad-Koffiefontein seismic belt in the northern neotectonic belt, be monitored for future research regarding, neotectonics, seismic risk assessment and hydrogeology.
- Full Text:
- Authors: Madi, Kakaba
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Geology)
- Identifier: vital:11530 , http://hdl.handle.net/10353/d1021270
- Description: The Eastern Cape Province has, besides the three known neotectonic belts (southern, eastern and northern) a fourth zone, which is inactive. This inactive zone is located almost in its central part north of the southern neotectonic zone, and south of the northern neotectonic belt. The three above mentioned neotectonic belts (southern, eastern and northern) were chosen for this study, each one with its own characteristics. This study aims at characterizing and targeting potentially high yield aquifers in the neotectonic zones in the Eastern Cape Province. The methods used in this study include: 1) A comprehensive literature review on neotectonics in South Africa in general and in the Eastern Cape Province in particular; 2) Extraction of lineaments through remote sensing and examination of digital elevation models; 3) Examination of seismic data for the subsurface visualization onshore and offshore; 4) Study on the genesis of the Grahamstown kaolin deposits through the structural component; and 5) Acquisition and interpretation of magnetic, electromagnetic and radiometric data from three of the hot springs in the northern neotectonic belt. The results indicate the following: 1) Old map of seismic epicentres in South Africa need to be reviewed continually. The Eastern Cape was regarded as quiescent in terms of seismicity. However, the investigation from recent seismic epicenters downloadable from the IRIS website has shown that recent seismic events occurred in the Eastern Cape Province especially in the northern and southern neotectonic belts. The central part located north of the southern neotectonic belt and south of the northern neotectonic belt is inactive. This inactive zone can be considered for the storage of nuclear wastes. 2) The eastern neotectonic belt has, like the northern neotectonic belt, a higher density of lineaments oriented northwest-southeast, which makes it the second important neotectonic belt. These lineaments correlate with the normalized difference vegetation index indicative of a good circulation of groundwater. In the south, the Eastern Cape great lineament oriented east-west is now considered a neotectonic domain because many seismic epicentres occur therein. Its geomorphologic shape in graben type form is a favourable structure for groundwater catchment. The surface topography is not uniform and high elevations in the east are related to the uplift that took place in the Quaternary. Most vector gradients are oriented east-west, a fact to be reckon with in the study of surface water flow and aquifers characterization. 3) Offshore along the east coast, the subsurface is affected by neotectonic faults, which are probably splays of the Agulhas Falkland Fractured Zone (AFFZ). The folds that occur are related to the regional compressional stress known as the Wegener Stress Anomaly (WSM). On land, straight lines from seismic profiles indicate that weathering occurs in consolidated materials probably along faults or fractures, unconsolidated sediments always have wavy profiles. On the other hand, field observations in King Williams Town have clearly shown that a tectonic uplift took place on a dolerite sill overlain by mudstones and sandstones. The uplift is possibly related to the Amatole-Swaziland event that occurred in the last five millions years. The escarpment along this dolerite sill overlain by sedimentary rocks is a meso-scale fault with a dip-slip component. Healthy vegetation and a river flowing parallel to the cliff indicate groundwater flow in the zone of weakness. 4) In the southern neotectonic belt there is a clear northwest-southeast horizontal compression and a southwest-northeast vertical to sub-vertical extension. Enrichment of granitic breccias and feldspar in the Grahamstown Dwyka tillite is the source for the formation of kaolin deposits. The weathering starts in the granitic breccias through their extensional fractures and then extends in the matrix, which has micro-fractures that are only visible with the transmitted microscope. Combined extensional strike-slip and dip-slip faulting is responsible for the earthquakes in the region of Grahamstown where the kaolin is formed. There is also an unreported thermal (quartz veins) and neotectonic event identified in this region. 5) The hot springs in the northern neotectonic belt are connected by a regional neotectonic fault. The use of magnetic and electromagnetic methods helped to decipher the occurrence of faults, fractures, dolerite dykes, and variable degree of weathering. Uranium/potassium ratios derived from radiometric surveys show that areas around some hot springs are characterized by enrichment in uranium. High concentrations of thorium are related to its low capacity of being easily dissolved in water. It can be concluded that seismicity, hot springs and accordingly deep groundwater circulation, high density of lineaments, quaternary tectonic uplift, are the predominate characteristics of the three neotectonic zones. Furthermore, on the environmental point of view, thorium concentration is higher than that of either uranium or potassium. Although it is nonetheless below the world average threshold of 7.4 ppm according to United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR), it may be a source of radiation hazard to humans and animals if they are subjected to prolonged exposure. All the neotectonic zones in the Eastern Cape Province present potentials to host good and important aquifers. It is suggested that the Eastern Cape great lineament in the southern neotectonic belt and the Kokstad-Koffiefontein seismic belt in the northern neotectonic belt, be monitored for future research regarding, neotectonics, seismic risk assessment and hydrogeology.
- Full Text:
Teaching strategies to improve the writing skills for grade and 9 learners in English first additional language: a case study of Forth High School in the Cradock Education district
- Authors: Kalipha, Zimkhitha
- Date: 2014
- Subjects: Teaching strategies -- writing skills , Writing skills -- Study and teaching -- South Africa , English language -- Study and teaching -- South Africa
- Language: English
- Type: Thesis , Masters , M Ed
- Identifier: vital:16215 , http://hdl.handle.net/10353/d1017297 , Teaching strategies -- writing skills , Writing skills -- Study and teaching -- South Africa , English language -- Study and teaching -- South Africa
- Description: Writing skills is are an essential requirement to lifelong learner success yet the way teachers teach and provide feedback to their learners on writing is quite challenging. This study sought to explore the teaching strategies to improve writing skills as an essential requirement for effective learning in schools for grade 8 and 9 learners in English First Additional Language. For people living in the townships and rural areas in South Africa, exposure to English is limited, because the majority of people communicate with each other in local languages. With teachers and learners residing in the townships where communication occurs mostly in isiXhosa, problems in language proficiency, in particular writing in English First Additional Language, are often encountered not only by the learners, but by educators as well. This was a case study of four high schools in the Cradock Education District. In-depth interviews were conducted with eight participants in the four schools. There were eight main findings, which are as follows: Lack of support for teachers, lack of a culture of learning amongst learners, and lack of competence in English for both learners and parents, which need to be addressed; and strategies proposed to improve writing skills are: the importance of creative writing; regular feedback and the importance of drafts.
- Full Text:
- Authors: Kalipha, Zimkhitha
- Date: 2014
- Subjects: Teaching strategies -- writing skills , Writing skills -- Study and teaching -- South Africa , English language -- Study and teaching -- South Africa
- Language: English
- Type: Thesis , Masters , M Ed
- Identifier: vital:16215 , http://hdl.handle.net/10353/d1017297 , Teaching strategies -- writing skills , Writing skills -- Study and teaching -- South Africa , English language -- Study and teaching -- South Africa
- Description: Writing skills is are an essential requirement to lifelong learner success yet the way teachers teach and provide feedback to their learners on writing is quite challenging. This study sought to explore the teaching strategies to improve writing skills as an essential requirement for effective learning in schools for grade 8 and 9 learners in English First Additional Language. For people living in the townships and rural areas in South Africa, exposure to English is limited, because the majority of people communicate with each other in local languages. With teachers and learners residing in the townships where communication occurs mostly in isiXhosa, problems in language proficiency, in particular writing in English First Additional Language, are often encountered not only by the learners, but by educators as well. This was a case study of four high schools in the Cradock Education District. In-depth interviews were conducted with eight participants in the four schools. There were eight main findings, which are as follows: Lack of support for teachers, lack of a culture of learning amongst learners, and lack of competence in English for both learners and parents, which need to be addressed; and strategies proposed to improve writing skills are: the importance of creative writing; regular feedback and the importance of drafts.
- Full Text:
The analysis of the economic impact of climate change on maize production under different farming systems: the case of smallholder Farmers in Jozini Municipality, KwaZulu Natal Province, South Africa
- Authors: Nxumalo, Bongiwe Goodness
- Date: 2014
- Subjects: Climate change mitigation -- South Africa -- KwaZulu-Natal , Irrigation farming -- South Africa -- KwaZulu-Natal , Dry farming -- South Africa -- KwaZulu-Natal , Food supply -- South Africa -- KwaZulu-Natal , Corn -- South Africa -- KwaZulu-Natal
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: vital:11229 , http://hdl.handle.net/10353/d1021277 , Climate change mitigation -- South Africa -- KwaZulu-Natal , Irrigation farming -- South Africa -- KwaZulu-Natal , Dry farming -- South Africa -- KwaZulu-Natal , Food supply -- South Africa -- KwaZulu-Natal , Corn -- South Africa -- KwaZulu-Natal
- Description: Maize is the most grown crop by the farmers in Jozini. Therefore, the main objective of the study was to assess the economic impact of climate change on maize production under different farming systems in Jozini Municipality in KwaZulu Natal (KZN). The study was looking at the smallholder farmers producing maize under dryland and irrigation system. A total of 100 farmers were selected for the study (40 from dry-land and 60 from irrigating farmers). Cluster and random sampling procedures were used to select the sample. Questionnaires were used for the collection of primary data, from the respondents (maize farmers). Data was analysed using descriptive statistics (frequency, percentages), gross margin, regression analysis and the Ricardian model. Data for computing gross margins and net revenue was taken from the on-farm trials. Gross margin was used on regression analysis and the net revenue was used on the Ricardian modelThe results of the regression analysis indicated that land size, farmer’s experience to farming, level of education, use of fertiliser, use of irrigation and the yield obtained were significant and have a positive relationship with farmers gross margin. The results of the Ricardian model indicated that climate change affects both farming systems, but farmers that are producing under dryland are the most affected farmers because they rely more on climate variables especially rainfall for their production. So a change in climate variables affects maize farmers’ productivity and thus affecting farmers’ gross margin and net revenue. The study recommends that the farmers must use irrigation in order to support maize production even in the absence of rainfall. Farmers must also adapt to the short growing season so that they will be able to produce even in the presence of climate change.
- Full Text:
- Authors: Nxumalo, Bongiwe Goodness
- Date: 2014
- Subjects: Climate change mitigation -- South Africa -- KwaZulu-Natal , Irrigation farming -- South Africa -- KwaZulu-Natal , Dry farming -- South Africa -- KwaZulu-Natal , Food supply -- South Africa -- KwaZulu-Natal , Corn -- South Africa -- KwaZulu-Natal
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: vital:11229 , http://hdl.handle.net/10353/d1021277 , Climate change mitigation -- South Africa -- KwaZulu-Natal , Irrigation farming -- South Africa -- KwaZulu-Natal , Dry farming -- South Africa -- KwaZulu-Natal , Food supply -- South Africa -- KwaZulu-Natal , Corn -- South Africa -- KwaZulu-Natal
- Description: Maize is the most grown crop by the farmers in Jozini. Therefore, the main objective of the study was to assess the economic impact of climate change on maize production under different farming systems in Jozini Municipality in KwaZulu Natal (KZN). The study was looking at the smallholder farmers producing maize under dryland and irrigation system. A total of 100 farmers were selected for the study (40 from dry-land and 60 from irrigating farmers). Cluster and random sampling procedures were used to select the sample. Questionnaires were used for the collection of primary data, from the respondents (maize farmers). Data was analysed using descriptive statistics (frequency, percentages), gross margin, regression analysis and the Ricardian model. Data for computing gross margins and net revenue was taken from the on-farm trials. Gross margin was used on regression analysis and the net revenue was used on the Ricardian modelThe results of the regression analysis indicated that land size, farmer’s experience to farming, level of education, use of fertiliser, use of irrigation and the yield obtained were significant and have a positive relationship with farmers gross margin. The results of the Ricardian model indicated that climate change affects both farming systems, but farmers that are producing under dryland are the most affected farmers because they rely more on climate variables especially rainfall for their production. So a change in climate variables affects maize farmers’ productivity and thus affecting farmers’ gross margin and net revenue. The study recommends that the farmers must use irrigation in order to support maize production even in the absence of rainfall. Farmers must also adapt to the short growing season so that they will be able to produce even in the presence of climate change.
- Full Text:
The challenges facing the National Rural Youth Service Corps' (NARYSEC) skills development programme implementation in the Eastern Cape province of South Africa : a case study of O.R. Tambo district municipality
- Authors: Magwentshu, Kanyisa
- Date: 2014
- Subjects: Youth -- Employment Vocational guidance Youth development
- Language: English
- Type: Thesis , Masters , MSoc
- Identifier: http://hdl.handle.net/10353/12803 , vital:39363
- Description: The purpose of the study was to investigate the challenges facing the National Youth Service Corps’ (NARYSEC) skills development programme implementation in the OR Tambo District in the Eastern Cape Province. A secondary aim was to determine whether the actual NARYSEC implementation matches the desirable needs of the poverty-stricken unemployed NARYSEC beneficiary participants and their communities. The study, which was framed within Amartya Sen’s Capability and Entitlement Approaches (1985), used multiple data collection instruments – (1) semi-structured survey questionnaire, (2) face-to-face semi-structured interviews, (3) semi-structured telephonic interviews and (4) key expert informant in-depth face-to-face interviews – to collect data from 73 NARYSEC participants and three expert informants (N=76). The study used purposive and snowball sampling strategies in selecting the participants. Data was analysed using thematic data analysis technique and the results suggested that the NARYSEC skills development programme offered to unemployed youth in the resource depleted former homeland districts of the former Transkei of the Eastern Cape Province, did not achieve the NARYSEC objectives and the desirable needs of the NARYSEC beneficiaries and their communities. The evidence suggested that failure of the NARYSEC programme could be attributed to the implementation methods as well repeated cycles of mismatch between the official NARYSEC objectives of recruiting and developing rural youth to perform community service in their own communities and the actual NARYSEC implementation results. The study showed that one of the challenges NARYSEC programme faced was from the poorly structured implementation mechanisms, which were manned by untrained civil servants and not by skills development experts who were capable of implementing the programme successfully. The research findings also seemed to suggest that two of the major factors responsible for the NARYSEC programme failure in the Eastern Cape were the chronic implementation weaknesses stemming from the historical and contextual constraints dating back to the apartheid era. To enhance the NARYSEC objectives and the desirable needs of the unemployed rural youth and their communities, the study suggests the following: Firstly, it was recommended that policy planners and implementers should incorporate the desirable needs and aspirations of the youth and their communities into the NARYSEC programme design and implementation process. This recommendation is informed by the divergence that characterized the NARYSEC programme implementation. Secondly, it is suggested that the NARYSEC Monitoring &Evaluation process must be revamped in order to reverse the general trend of the poor monitoring and evaluation performance that characterised the NARYSEC programme implementation.
- Full Text:
- Authors: Magwentshu, Kanyisa
- Date: 2014
- Subjects: Youth -- Employment Vocational guidance Youth development
- Language: English
- Type: Thesis , Masters , MSoc
- Identifier: http://hdl.handle.net/10353/12803 , vital:39363
- Description: The purpose of the study was to investigate the challenges facing the National Youth Service Corps’ (NARYSEC) skills development programme implementation in the OR Tambo District in the Eastern Cape Province. A secondary aim was to determine whether the actual NARYSEC implementation matches the desirable needs of the poverty-stricken unemployed NARYSEC beneficiary participants and their communities. The study, which was framed within Amartya Sen’s Capability and Entitlement Approaches (1985), used multiple data collection instruments – (1) semi-structured survey questionnaire, (2) face-to-face semi-structured interviews, (3) semi-structured telephonic interviews and (4) key expert informant in-depth face-to-face interviews – to collect data from 73 NARYSEC participants and three expert informants (N=76). The study used purposive and snowball sampling strategies in selecting the participants. Data was analysed using thematic data analysis technique and the results suggested that the NARYSEC skills development programme offered to unemployed youth in the resource depleted former homeland districts of the former Transkei of the Eastern Cape Province, did not achieve the NARYSEC objectives and the desirable needs of the NARYSEC beneficiaries and their communities. The evidence suggested that failure of the NARYSEC programme could be attributed to the implementation methods as well repeated cycles of mismatch between the official NARYSEC objectives of recruiting and developing rural youth to perform community service in their own communities and the actual NARYSEC implementation results. The study showed that one of the challenges NARYSEC programme faced was from the poorly structured implementation mechanisms, which were manned by untrained civil servants and not by skills development experts who were capable of implementing the programme successfully. The research findings also seemed to suggest that two of the major factors responsible for the NARYSEC programme failure in the Eastern Cape were the chronic implementation weaknesses stemming from the historical and contextual constraints dating back to the apartheid era. To enhance the NARYSEC objectives and the desirable needs of the unemployed rural youth and their communities, the study suggests the following: Firstly, it was recommended that policy planners and implementers should incorporate the desirable needs and aspirations of the youth and their communities into the NARYSEC programme design and implementation process. This recommendation is informed by the divergence that characterized the NARYSEC programme implementation. Secondly, it is suggested that the NARYSEC Monitoring &Evaluation process must be revamped in order to reverse the general trend of the poor monitoring and evaluation performance that characterised the NARYSEC programme implementation.
- Full Text:
The challenges of re-skilling former prison inmates in the 21st century: a case study of Nkonkobe municipality, Eastern Cape - South Africa
- Authors: Ralasi, Nolusindiso
- Date: 2014
- Subjects: Criminals -- Rehabilitation , Prisoners -- Education , Alternatives to imprisonment
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10353/25687 , vital:64432
- Description: The main aim of this study is to investigate challenges of re-skilling former inmates in South Africa in the 21st century. This is a case study of the Nkonkobe Municipality, Eastern Cape - South Africa. The objectives of this research are: to identify the current skills and education programmes offered by the DCS, to establish perceptions of inmates regarding the role of the DCS in skills training and education, to find out whether the current former inmates feel the support of society, to ascertain the offenders’ education levels, professional skills and job experience before and after prison, to identify the status of the offenders’ rights and rehabilitation programmes, to provide recommendations on ways to cement policy loopholes that have a deleterious effect on the government’s drive to create a whole new world for the ex-inmates and their holding communities. A qualitative research design was used to collect data from the participants in order to obtain in-depth information concerning the perceived impact of the life skills programmes on the behaviour and conduct of former inmates who participated in the programme. The findings reveal that the life skills programmes had an impact on the behaviour of former inmates because the life skills that they had gained from the programme mostly helped them desist from committing the offences that they used to commit. The life skills also curbed their anti-social behaviour tendencies. The factors that contributed to the success of the project included the approaches that the facilitators used to run the project, such as, motivating the inmates in everything that they did and the cooperation between the facilitators, the prison and the community. The findings also reveal that the good team work that occurred between the former inmates, support from the community, as well as the support from the Department of Correctional Services contributed to the success of the project. It was also suggested that the project should include all youths in the community; imprisonment should not be a passport to empowerment. The final suggestion was that the project should include all stakeholders in the community. The life skills projects should target unemployed youths in the communities so that they can gain skills that can help them become self-employed. The study also recommends that the life skills programmes should be implemented in all prisons in South Africa to provide inmates with life skills that can help them face day-to-day life challenges. This study culminates in the realisation that no life skills programmes can be successful in any society if they exclude the core social members who are law-abiding citizens. This is key to ensure that these programmes do not polarise the society due to empowerment being erroneously viewed as a preserve of those who did not abide by societal laws. This would set a wrong precedence that this study seeks to forestall. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2014
- Full Text:
- Authors: Ralasi, Nolusindiso
- Date: 2014
- Subjects: Criminals -- Rehabilitation , Prisoners -- Education , Alternatives to imprisonment
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10353/25687 , vital:64432
- Description: The main aim of this study is to investigate challenges of re-skilling former inmates in South Africa in the 21st century. This is a case study of the Nkonkobe Municipality, Eastern Cape - South Africa. The objectives of this research are: to identify the current skills and education programmes offered by the DCS, to establish perceptions of inmates regarding the role of the DCS in skills training and education, to find out whether the current former inmates feel the support of society, to ascertain the offenders’ education levels, professional skills and job experience before and after prison, to identify the status of the offenders’ rights and rehabilitation programmes, to provide recommendations on ways to cement policy loopholes that have a deleterious effect on the government’s drive to create a whole new world for the ex-inmates and their holding communities. A qualitative research design was used to collect data from the participants in order to obtain in-depth information concerning the perceived impact of the life skills programmes on the behaviour and conduct of former inmates who participated in the programme. The findings reveal that the life skills programmes had an impact on the behaviour of former inmates because the life skills that they had gained from the programme mostly helped them desist from committing the offences that they used to commit. The life skills also curbed their anti-social behaviour tendencies. The factors that contributed to the success of the project included the approaches that the facilitators used to run the project, such as, motivating the inmates in everything that they did and the cooperation between the facilitators, the prison and the community. The findings also reveal that the good team work that occurred between the former inmates, support from the community, as well as the support from the Department of Correctional Services contributed to the success of the project. It was also suggested that the project should include all youths in the community; imprisonment should not be a passport to empowerment. The final suggestion was that the project should include all stakeholders in the community. The life skills projects should target unemployed youths in the communities so that they can gain skills that can help them become self-employed. The study also recommends that the life skills programmes should be implemented in all prisons in South Africa to provide inmates with life skills that can help them face day-to-day life challenges. This study culminates in the realisation that no life skills programmes can be successful in any society if they exclude the core social members who are law-abiding citizens. This is key to ensure that these programmes do not polarise the society due to empowerment being erroneously viewed as a preserve of those who did not abide by societal laws. This would set a wrong precedence that this study seeks to forestall. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2014
- Full Text:
The delivery of the clothing and textiles curriculum in Zimbabwean universities: towards an integrated approach to vertical and horizontal discourses
- Authors: Muzenda, Verity
- Date: 2014
- Subjects: Clothing and dress -- Study and teaching --Zimbabwe , Education -- Curricula -- Zimbabwe , Textile industry -- Study and teaching -- Zimbabwe , Universities and colleges -- Zimbabwe
- Language: English
- Type: Thesis , Masters , M Ed
- Identifier: vital:16227 , http://hdl.handle.net/10353/d1019748 , Clothing and dress -- Study and teaching --Zimbabwe , Education -- Curricula -- Zimbabwe , Textile industry -- Study and teaching -- Zimbabwe , Universities and colleges -- Zimbabwe
- Description: The introduction of Technical Vocational Education (TVE) has been marred by a myriad of challenges, and this has not spared universities. The incompetency of lecturers, the perceptions of both lecturers and students, the relationship between universities and the world of work as well as support strategies have been the most contested issues in TVE. The researcher used the mixed method design which is rooted in the post-positivist research paradigm that integrates concurrent procedures in the collection, analysis and interpretation of the data. Post-positivist research paradigm attempts to enhance one’s understanding of the way certain phenomena are and that objectivity is an ideal that can never be achieved. The sample of the study comprised two Heads of Department (HODs) from the universities under study, 18 lecturers for the interviews, 18 lecturers who responded to the questionnaire, 24 students formed the 4 focus groups for both universities with 6 students each. Two industrial personnel were also interviewed. Questionnaires were used to collect quantitative data while qualitative data were collected through interviews, focus group discussions, observations and document analysis. The researcher employed the Statistical Packages for Social Sciences (SPSS) to summarise, compile tables and graphs on quantitative data and qualitative data was analysed using content analysis through emerging themes. The study established that lecturers were not competent enough to deliver CT curriculum in universities and this was as a result of the type of training lecturers received which was no longer congruent with the technological advancement which have taken place in the textile industry. It was also instituted that universities were producing students who lacked the hands-on skills necessary for them to be acceptable in the world of work. There was a stern shortage of equipment and machinery in CT departments in universities. The machinery and equipment in the departments were too old and broken. Furthermore, the study established that there was no collaboration between universities and industries. Industrial personnel lamented that universities were not willing to put into consideration all the suggestions they gave them and that time for Work-Integrated Learning (WIL) or placement was too short for them to impart all the requisite skills to students. It was also established that students were discontented by the teaching methods that lecturers were using and the way they were being assessed. Students conveyed their desire for the industry to be involved in assessing them whilst they were in universities. Based on the above findings, the study concluded that lecturers were incapacitated to deliver CT due to the training they received in colleges and universities which was no longer congruent with the dynamics of technology. The study also concluded that the shortage of machinery and equipment also demotivated lecturers and incapacitated them. It was also concluded that the lack of collaboration between universities and industries posed serious challenges to both lecturers and students. The study recommends that the quality of the existing lecturing force must be improved mainly through extensive staff development training programmes.There is need for lecturers to be staff developed through training workshops in order to improve on competence. There should be collaboration among University management, lecturers and the industry during curriculum design, implementation and monitoring to improve their attachment and sense of ownership of CT programmes. To improve on students’ acquisition of skills, the study recommends that time for Work-Integrated Learning should be lengthened so that students leave the industry well equipped with relevant skills and knowledge.
- Full Text:
- Authors: Muzenda, Verity
- Date: 2014
- Subjects: Clothing and dress -- Study and teaching --Zimbabwe , Education -- Curricula -- Zimbabwe , Textile industry -- Study and teaching -- Zimbabwe , Universities and colleges -- Zimbabwe
- Language: English
- Type: Thesis , Masters , M Ed
- Identifier: vital:16227 , http://hdl.handle.net/10353/d1019748 , Clothing and dress -- Study and teaching --Zimbabwe , Education -- Curricula -- Zimbabwe , Textile industry -- Study and teaching -- Zimbabwe , Universities and colleges -- Zimbabwe
- Description: The introduction of Technical Vocational Education (TVE) has been marred by a myriad of challenges, and this has not spared universities. The incompetency of lecturers, the perceptions of both lecturers and students, the relationship between universities and the world of work as well as support strategies have been the most contested issues in TVE. The researcher used the mixed method design which is rooted in the post-positivist research paradigm that integrates concurrent procedures in the collection, analysis and interpretation of the data. Post-positivist research paradigm attempts to enhance one’s understanding of the way certain phenomena are and that objectivity is an ideal that can never be achieved. The sample of the study comprised two Heads of Department (HODs) from the universities under study, 18 lecturers for the interviews, 18 lecturers who responded to the questionnaire, 24 students formed the 4 focus groups for both universities with 6 students each. Two industrial personnel were also interviewed. Questionnaires were used to collect quantitative data while qualitative data were collected through interviews, focus group discussions, observations and document analysis. The researcher employed the Statistical Packages for Social Sciences (SPSS) to summarise, compile tables and graphs on quantitative data and qualitative data was analysed using content analysis through emerging themes. The study established that lecturers were not competent enough to deliver CT curriculum in universities and this was as a result of the type of training lecturers received which was no longer congruent with the technological advancement which have taken place in the textile industry. It was also instituted that universities were producing students who lacked the hands-on skills necessary for them to be acceptable in the world of work. There was a stern shortage of equipment and machinery in CT departments in universities. The machinery and equipment in the departments were too old and broken. Furthermore, the study established that there was no collaboration between universities and industries. Industrial personnel lamented that universities were not willing to put into consideration all the suggestions they gave them and that time for Work-Integrated Learning (WIL) or placement was too short for them to impart all the requisite skills to students. It was also established that students were discontented by the teaching methods that lecturers were using and the way they were being assessed. Students conveyed their desire for the industry to be involved in assessing them whilst they were in universities. Based on the above findings, the study concluded that lecturers were incapacitated to deliver CT due to the training they received in colleges and universities which was no longer congruent with the dynamics of technology. The study also concluded that the shortage of machinery and equipment also demotivated lecturers and incapacitated them. It was also concluded that the lack of collaboration between universities and industries posed serious challenges to both lecturers and students. The study recommends that the quality of the existing lecturing force must be improved mainly through extensive staff development training programmes.There is need for lecturers to be staff developed through training workshops in order to improve on competence. There should be collaboration among University management, lecturers and the industry during curriculum design, implementation and monitoring to improve their attachment and sense of ownership of CT programmes. To improve on students’ acquisition of skills, the study recommends that time for Work-Integrated Learning should be lengthened so that students leave the industry well equipped with relevant skills and knowledge.
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The effect of real exchange rate volatility on export performance: evidence from South Africa (2000-2011)
- Authors: Chamunorwa, Wilson
- Date: 2014
- Subjects: Monetary policy -- South Africa , Economic development -- South Africa , Foreign exchange rates -- South Africa
- Language: English
- Type: Thesis , Masters , M Com
- Identifier: vital:11499 , http://hdl.handle.net/10353/d1018600 , Monetary policy -- South Africa , Economic development -- South Africa , Foreign exchange rates -- South Africa
- Description: The effect of real exchange rate volatility on export performance: evidence from South Africa (2000-2011) This study sought to investigate the relationship between exchange rate volatility and export performance in South Africa. The main objective of the study was to examine the impact of exchange rate volatility on export performance in South Africa. This relationship was examined using GARCH methods. Exports were regressed against real effective exchange rate, trade openness and capacity utilisation. The research aimed to establish whether exchange rate volatility impacts negatively on export performance in the manner suggested by the econometric model. The result obtained showed that exchange rate volatility had a significantly negative effect on South African exports in the period 2000-2011.
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- Authors: Chamunorwa, Wilson
- Date: 2014
- Subjects: Monetary policy -- South Africa , Economic development -- South Africa , Foreign exchange rates -- South Africa
- Language: English
- Type: Thesis , Masters , M Com
- Identifier: vital:11499 , http://hdl.handle.net/10353/d1018600 , Monetary policy -- South Africa , Economic development -- South Africa , Foreign exchange rates -- South Africa
- Description: The effect of real exchange rate volatility on export performance: evidence from South Africa (2000-2011) This study sought to investigate the relationship between exchange rate volatility and export performance in South Africa. The main objective of the study was to examine the impact of exchange rate volatility on export performance in South Africa. This relationship was examined using GARCH methods. Exports were regressed against real effective exchange rate, trade openness and capacity utilisation. The research aimed to establish whether exchange rate volatility impacts negatively on export performance in the manner suggested by the econometric model. The result obtained showed that exchange rate volatility had a significantly negative effect on South African exports in the period 2000-2011.
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The effectiveness of centralised human resource management on service delivery: a case of Bedford Hospital, Department of Health, Province of the Eastern Cape
- Authors: Ncebakazi, Frances Qalase
- Date: 2014
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: vital:11683 , http://hdl.handle.net/10353/d1013557
- Description: The Eastern Cape Department of Health centralised Human Resource functions from the facilities to the provincial office. This according to the provincial office was to address the over expenditure on Compensation of employees that was highlighted by the Auditor General report of 2008/2009. The researcher was of the opinion that various issues of concern were over looked by the provincial office before or during the implementation of the centralisation of HRM. The primary objective of this study was to examine the effectiveness of the centralisation of HRM on service delivery in the ECDoH and Bedford hospital. The secondary objective was to find out what centralisation is and its implications. Lastly, to develop recommendations which address the outcomes of the study. Purposive sampling was used to identify key informants from Bedford hospital and the provincial office. Interview questions were used to collect data from both respondents. The study examined both responses and grouped them into themes. The findings did not imply that centralisation does not improve service delivery but have indicated a lack of service delivery focus on the part of the provincial office. The Eastern Cape Department of Health centralised Human Resource functions from the facilities to the provincial office. This according to the provincial office was to address the over expenditure on Compensation of employees that was highlighted by the Auditor General report of 2008/2009. The researcher was of the opinion that various issues of concern were over looked by the provincial office before or during the implementation of the centralisation of HRM. The primary objective of this study was to examine the effectiveness of the centralisation of HRM on service delivery in the ECDoH and Bedford hospital. The secondary objective was to find out what centralisation is and its implications. Lastly, to develop recommendations which address the outcomes of the study. Purposive sampling was used to identify key informants from Bedford hospital and the provincial office. Interview questions were used to collect data from both respondents. The study examined both responses and grouped them into themes. The findings did not imply that centralisation does not improve service delivery but have indicated a lack of service delivery focus on the part of the provincial office. The research has also revealed that amongst the challenges identified, there were those that were key challenges. The researcher was of the opinion that addressing those key generic challenges would minimise all other challenges and improve service delivery. Lack of communication on organisation strategies and lack of Monitoring and Evaluation systems were identified as key challenges that cut across the entire ECDoH. The study has recommended that the provincial office should improve on communication strategies with the facilities whenever decisions are taken. Secondly, to develop M&E systems in order to ensure that performance standards are monitored and evaluated. This according to the researcher would improve service delivery in the ECDoH and Bedford hospital.that were key challenges. The researcher was of the opinion that addressing those key generic challenges would minimise all other challenges and improve service delivery. Lack of communication on organisation strategies and lack of Monitoring and Evaluation systems were identified as key challenges that cut across the entire ECDoH. The study has recommended that the provincial office should improve on communication strategies with the facilities whenever decisions are taken. Secondly, to develop M&E systems in order to ensure that performance standards are monitored and evaluated. This according to the researcher would improve service delivery in the ECDoH and Bedford hospital.
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- Authors: Ncebakazi, Frances Qalase
- Date: 2014
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: vital:11683 , http://hdl.handle.net/10353/d1013557
- Description: The Eastern Cape Department of Health centralised Human Resource functions from the facilities to the provincial office. This according to the provincial office was to address the over expenditure on Compensation of employees that was highlighted by the Auditor General report of 2008/2009. The researcher was of the opinion that various issues of concern were over looked by the provincial office before or during the implementation of the centralisation of HRM. The primary objective of this study was to examine the effectiveness of the centralisation of HRM on service delivery in the ECDoH and Bedford hospital. The secondary objective was to find out what centralisation is and its implications. Lastly, to develop recommendations which address the outcomes of the study. Purposive sampling was used to identify key informants from Bedford hospital and the provincial office. Interview questions were used to collect data from both respondents. The study examined both responses and grouped them into themes. The findings did not imply that centralisation does not improve service delivery but have indicated a lack of service delivery focus on the part of the provincial office. The Eastern Cape Department of Health centralised Human Resource functions from the facilities to the provincial office. This according to the provincial office was to address the over expenditure on Compensation of employees that was highlighted by the Auditor General report of 2008/2009. The researcher was of the opinion that various issues of concern were over looked by the provincial office before or during the implementation of the centralisation of HRM. The primary objective of this study was to examine the effectiveness of the centralisation of HRM on service delivery in the ECDoH and Bedford hospital. The secondary objective was to find out what centralisation is and its implications. Lastly, to develop recommendations which address the outcomes of the study. Purposive sampling was used to identify key informants from Bedford hospital and the provincial office. Interview questions were used to collect data from both respondents. The study examined both responses and grouped them into themes. The findings did not imply that centralisation does not improve service delivery but have indicated a lack of service delivery focus on the part of the provincial office. The research has also revealed that amongst the challenges identified, there were those that were key challenges. The researcher was of the opinion that addressing those key generic challenges would minimise all other challenges and improve service delivery. Lack of communication on organisation strategies and lack of Monitoring and Evaluation systems were identified as key challenges that cut across the entire ECDoH. The study has recommended that the provincial office should improve on communication strategies with the facilities whenever decisions are taken. Secondly, to develop M&E systems in order to ensure that performance standards are monitored and evaluated. This according to the researcher would improve service delivery in the ECDoH and Bedford hospital.that were key challenges. The researcher was of the opinion that addressing those key generic challenges would minimise all other challenges and improve service delivery. Lack of communication on organisation strategies and lack of Monitoring and Evaluation systems were identified as key challenges that cut across the entire ECDoH. The study has recommended that the provincial office should improve on communication strategies with the facilities whenever decisions are taken. Secondly, to develop M&E systems in order to ensure that performance standards are monitored and evaluated. This according to the researcher would improve service delivery in the ECDoH and Bedford hospital.
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The efficacy of revenue collection strategies in local government: the case of Yei River County, South Sudan
- Authors: Logoro, John Mogga Ezekiel
- Date: 2014
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/1092 , vital:26526
- Description: The study explores the Efficacy of Revenue Collection Strategies in Local Government as a Public Sector management tool for service provision in Yei River County – Republic of South Sudan. The main research question being pursued sought to find out the extent to which Revenue collection strategies can be an effective tool for public sector management and service provision in Yei River County. The study used both quantitative data (obtained through questionnaire survey) and qualitative data (through in-depth responses from County staff). The findings of the study seem to indicate that ineffective revenue collection strategies are being utilised by the local government officials. Some members of the communities and traders were still ignorant as to why they should be paying taxes which makes many of them to evade paying taxes. The study also reveals some challenges such as corrupt practices, poverty and illiteracy as some of the hindrances to effective revenue collection. However, there is a degree of success in revenue collection in the County as evidenced by the ongoing development activities such as urban road repairs which were financed by local taxes. A lot needs to be done in order to improve revenue collection in this County of Yei River County if services are to be delivered effectively and efficiently to the people. It is therefore strongly recommended that there is a need to put in place good educative measures to ensure that the citizens are informed about why they should be paying taxes to the County other than evading taxes and above all, the County need to strengthen the County Revenue Authority for better revenue collection.
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- Authors: Logoro, John Mogga Ezekiel
- Date: 2014
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/1092 , vital:26526
- Description: The study explores the Efficacy of Revenue Collection Strategies in Local Government as a Public Sector management tool for service provision in Yei River County – Republic of South Sudan. The main research question being pursued sought to find out the extent to which Revenue collection strategies can be an effective tool for public sector management and service provision in Yei River County. The study used both quantitative data (obtained through questionnaire survey) and qualitative data (through in-depth responses from County staff). The findings of the study seem to indicate that ineffective revenue collection strategies are being utilised by the local government officials. Some members of the communities and traders were still ignorant as to why they should be paying taxes which makes many of them to evade paying taxes. The study also reveals some challenges such as corrupt practices, poverty and illiteracy as some of the hindrances to effective revenue collection. However, there is a degree of success in revenue collection in the County as evidenced by the ongoing development activities such as urban road repairs which were financed by local taxes. A lot needs to be done in order to improve revenue collection in this County of Yei River County if services are to be delivered effectively and efficiently to the people. It is therefore strongly recommended that there is a need to put in place good educative measures to ensure that the citizens are informed about why they should be paying taxes to the County other than evading taxes and above all, the County need to strengthen the County Revenue Authority for better revenue collection.
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The enforcement of the right of access to adequate housing in South Africa: a lesson for Lesotho
- Authors: Pule, Sesinyi Edwin
- Date: 2014
- Subjects: Housing -- Law and legislation -- South Africa , Housing -- Law and legislation -- Lesotho
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:11122 , http://hdl.handle.net/10353/d1016249 , Housing -- Law and legislation -- South Africa , Housing -- Law and legislation -- Lesotho
- Description: South Africa is one of the countries with a very horrifying history. However, in the dawn of democratic governance, a worldly admirable constitution was brought into picture. The 1993 and 1996 South African Constitutions entrenched an elaborate Bill of Rights with provisions empowering courts to grant “appropriate relief and to make “just and equitable” orders. Happily, the Bill of Rights included justiciable and enforceable socio-economic rights. Amongst them, there is a right of access to adequate housing, for which this work is about. South Africa is viewed as a country with developed jurisprudence in the enforcement of socio-economic rights, hence it has been used as a lesson for Lesotho. Lesotho is still drowning in deep blue seas on enforcement of socio-economic rights either because the constitution itself hinders the progress thereon or because the parliament is unwilling to commit execute to the obligations found in the socio-economic rights filed. This work scrutinizes many jurisdictions and legal systems with a view to draw lively examples that may be followed by Lesotho courts towards enforcing housing rights. Indian and South African jurisprudences epitomize this notion.
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- Authors: Pule, Sesinyi Edwin
- Date: 2014
- Subjects: Housing -- Law and legislation -- South Africa , Housing -- Law and legislation -- Lesotho
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:11122 , http://hdl.handle.net/10353/d1016249 , Housing -- Law and legislation -- South Africa , Housing -- Law and legislation -- Lesotho
- Description: South Africa is one of the countries with a very horrifying history. However, in the dawn of democratic governance, a worldly admirable constitution was brought into picture. The 1993 and 1996 South African Constitutions entrenched an elaborate Bill of Rights with provisions empowering courts to grant “appropriate relief and to make “just and equitable” orders. Happily, the Bill of Rights included justiciable and enforceable socio-economic rights. Amongst them, there is a right of access to adequate housing, for which this work is about. South Africa is viewed as a country with developed jurisprudence in the enforcement of socio-economic rights, hence it has been used as a lesson for Lesotho. Lesotho is still drowning in deep blue seas on enforcement of socio-economic rights either because the constitution itself hinders the progress thereon or because the parliament is unwilling to commit execute to the obligations found in the socio-economic rights filed. This work scrutinizes many jurisdictions and legal systems with a view to draw lively examples that may be followed by Lesotho courts towards enforcing housing rights. Indian and South African jurisprudences epitomize this notion.
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The establishment of a mobile phone information security culture: linking student awareness and behavioural intent
- Authors: Bukelwa, Ngoqo
- Date: 2014
- Subjects: Information security awareness -- Mobile phone security , Information safety
- Language: English
- Type: Thesis , Doctoral , PhD (Information Systems)
- Identifier: http://hdl.handle.net/10353/657 , vital:26485 , Information security awareness -- Mobile phone security , Information safety
- Description: The information security behaviour of technology users has become an increasingly popular research area as security experts have come to recognise that while securing technology by means of firewalls, passwords and offsite backups is important, such security may be rendered ineffective if the technology users themselves are not information security conscious. The mobile phone has become a necessity for many students but, at the same time, it exposes them to security threats that may result in a loss of information. Students in developing countries are at a disadvantage because they have limited access to information relating to information security threats, unlike their counterparts in more developed societies who can readily access this information from sources like the Internet. The developmental environment is plagued with challenges like access to the Internet or limited access to computers. The poor security behaviour exhibited by student mobile phone users, which was confirmed by the findings of this study, is of particular interest in the university context as most undergraduate students are offered a computer-related course which covers certain information security-related principles. During the restructuring of the South African higher education system, smaller universities and technikons (polytechnics) were merged to form comprehensive universities. Thus, the resultant South African university landscape is made up of traditional and comprehensive universities as well as universities of technology. Ordinarily, one would expect university students to have similar profiles. However in the case of this study, the environment was a unique factor which had a direct impact on students’ learning experiences and learning outcomes. Mbeki (2004) refers to two economies within South Africa the first one is financially sound and globally integrated, and the other found in urban and rural areas consists of unemployed and unemployable people who do not benefit from progress in the first economy. Action research was the methodological approach which was chosen for the purposes of this study to collect the requisite data among a population of university students from the ‘second economy’. The study focuses on the relationship between awareness and behavioural intention in understanding mobile phone user information security behaviour. The study concludes by proposing a behaviour profile forecasting framework based on predefined security behavioural profiles. A key finding of this study is that the security behaviour exhibited by mobile phone users is influenced by a combination of information security awareness and information security behavioural intention, and not just information security awareness.
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- Authors: Bukelwa, Ngoqo
- Date: 2014
- Subjects: Information security awareness -- Mobile phone security , Information safety
- Language: English
- Type: Thesis , Doctoral , PhD (Information Systems)
- Identifier: http://hdl.handle.net/10353/657 , vital:26485 , Information security awareness -- Mobile phone security , Information safety
- Description: The information security behaviour of technology users has become an increasingly popular research area as security experts have come to recognise that while securing technology by means of firewalls, passwords and offsite backups is important, such security may be rendered ineffective if the technology users themselves are not information security conscious. The mobile phone has become a necessity for many students but, at the same time, it exposes them to security threats that may result in a loss of information. Students in developing countries are at a disadvantage because they have limited access to information relating to information security threats, unlike their counterparts in more developed societies who can readily access this information from sources like the Internet. The developmental environment is plagued with challenges like access to the Internet or limited access to computers. The poor security behaviour exhibited by student mobile phone users, which was confirmed by the findings of this study, is of particular interest in the university context as most undergraduate students are offered a computer-related course which covers certain information security-related principles. During the restructuring of the South African higher education system, smaller universities and technikons (polytechnics) were merged to form comprehensive universities. Thus, the resultant South African university landscape is made up of traditional and comprehensive universities as well as universities of technology. Ordinarily, one would expect university students to have similar profiles. However in the case of this study, the environment was a unique factor which had a direct impact on students’ learning experiences and learning outcomes. Mbeki (2004) refers to two economies within South Africa the first one is financially sound and globally integrated, and the other found in urban and rural areas consists of unemployed and unemployable people who do not benefit from progress in the first economy. Action research was the methodological approach which was chosen for the purposes of this study to collect the requisite data among a population of university students from the ‘second economy’. The study focuses on the relationship between awareness and behavioural intention in understanding mobile phone user information security behaviour. The study concludes by proposing a behaviour profile forecasting framework based on predefined security behavioural profiles. A key finding of this study is that the security behaviour exhibited by mobile phone users is influenced by a combination of information security awareness and information security behavioural intention, and not just information security awareness.
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