Peer group supervision as an adjunct to individual supervision: an investigation of models of learning
- Akhurst, Jacqueline Elizabeth
- Authors: Akhurst, Jacqueline Elizabeth
- Date: 2000
- Subjects: Peer-group tutoring of students Psychotherapy -- Study and teaching -- Supervision Psychology -- Supervision of
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2922 , http://hdl.handle.net/10962/d1002431
- Description: Supervision of practice makes an important contribution to the development of psychotherapeutic skills in the training of psychologists (Bernard and Goodyear, 1998). Much research has, until recently, focussed on dyadic, hierarchical models of supervision, even though other forms of supervision have been developed. Peer group supervision has had little attention in the literature, although it is a common form of supervision utilised by psychologists in practice (Lewis, Greenburg and Hatch, 1988). A review of the literature considers the purposes of supervision; elements of dyadic supervision; various forms of group, peer and peer group supervision; and the leaming process in supervision. The development and implementation of a peer supervision group (pSG) of intern psychologists within the training setting of a University is described in this study. The PSG model was developed from the model proposed by Wilbur, Roberts-Wilbur, Morris, Betz and Hart (1991). Transcripts from nine audio-taped PSG sessions were analysed, and a comparison with four audio-taped dyadic supervision sessions was then undertaken. Grounded Theory methodology was employed in the design of the study and analysis of the data. The form and content of the two models of supervision were examined, with particular attention to the perspective of the trainees' learning experiences. The relative merits of both forms of supervision were assessed, and this analysis clearly demonstrates that peer group supervision has the potential to complement dyadic supervision by contributing differing learning experiences. A model of key influences upon, and effects of, participation in the two forms of supervision has been developed. Suggestions are made of ways in which dyadic supervision may be optimised, and recommendations for further development of the PSG emerge. The results were then considered from a neo-Vygotskian perspective. This enabled the findings to be linked to a comprehensive theory of learning, pointing to the key role of speech in thinking, and the contributions of the various forms of dialogue to deepened understandings. The discussion includes: consideration of techniques which enable trainees to obtain assistance from both more experienced practitioners as well as from their peers; an exploration of aspects of subjectivity and intersubjectivity; and contextual influences which have bearing on the study. This study identifies the need for further consideration of the supervision process in South Africa, and makes recommendations for the training of supervisors. The neo-Vygotskian model offers great promise both as a framework for understanding the leaming process in. supervision, and for developing guidelines for enhancing supervisory practice.
- Full Text:
- Date Issued: 2000
- Authors: Akhurst, Jacqueline Elizabeth
- Date: 2000
- Subjects: Peer-group tutoring of students Psychotherapy -- Study and teaching -- Supervision Psychology -- Supervision of
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2922 , http://hdl.handle.net/10962/d1002431
- Description: Supervision of practice makes an important contribution to the development of psychotherapeutic skills in the training of psychologists (Bernard and Goodyear, 1998). Much research has, until recently, focussed on dyadic, hierarchical models of supervision, even though other forms of supervision have been developed. Peer group supervision has had little attention in the literature, although it is a common form of supervision utilised by psychologists in practice (Lewis, Greenburg and Hatch, 1988). A review of the literature considers the purposes of supervision; elements of dyadic supervision; various forms of group, peer and peer group supervision; and the leaming process in supervision. The development and implementation of a peer supervision group (pSG) of intern psychologists within the training setting of a University is described in this study. The PSG model was developed from the model proposed by Wilbur, Roberts-Wilbur, Morris, Betz and Hart (1991). Transcripts from nine audio-taped PSG sessions were analysed, and a comparison with four audio-taped dyadic supervision sessions was then undertaken. Grounded Theory methodology was employed in the design of the study and analysis of the data. The form and content of the two models of supervision were examined, with particular attention to the perspective of the trainees' learning experiences. The relative merits of both forms of supervision were assessed, and this analysis clearly demonstrates that peer group supervision has the potential to complement dyadic supervision by contributing differing learning experiences. A model of key influences upon, and effects of, participation in the two forms of supervision has been developed. Suggestions are made of ways in which dyadic supervision may be optimised, and recommendations for further development of the PSG emerge. The results were then considered from a neo-Vygotskian perspective. This enabled the findings to be linked to a comprehensive theory of learning, pointing to the key role of speech in thinking, and the contributions of the various forms of dialogue to deepened understandings. The discussion includes: consideration of techniques which enable trainees to obtain assistance from both more experienced practitioners as well as from their peers; an exploration of aspects of subjectivity and intersubjectivity; and contextual influences which have bearing on the study. This study identifies the need for further consideration of the supervision process in South Africa, and makes recommendations for the training of supervisors. The neo-Vygotskian model offers great promise both as a framework for understanding the leaming process in. supervision, and for developing guidelines for enhancing supervisory practice.
- Full Text:
- Date Issued: 2000
Perspectives on inter-professional collaboration : mediation
- Authors: Tatchell, Dolores
- Date: 2000
- Subjects: Divorce mediation -- South Africa , Custody of children-- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:707 , http://hdl.handle.net/10962/d1006519 , Divorce mediation -- South Africa , Custody of children-- South Africa
- Description: This research is based on the continuous search for alternatives in dealing with custody and access of minor children in divorcing families. In spite of the Mediation in Certain Divorce Matters Act, 1987, providing for mediation, it did not lead to the widespread implementation of mediation as an alternative form of dispute resolution in divorce matters. The family advocate as provided for in the Act, serves to protect the interest of minor children in disputes. However, custody evaluation is still used to determine the custody of minor children. Custody evaluation comprises an in depth study and assessment of the structure and functioning of the family made by a social worker and written up in the form of an evaluative report which is then submitted to the family advocate. It occurred to the researcher that there had to be better ways of dealing with custody disputes and consequently the damage done by the parents who fight over their children without any regard for the children’s feelings. It was considered an option to find out from the professionals directly involved with divorce and custody disputes why they have not considered alternatives, such as mediation, to resolve the disputes arising out of a divorce. Semi-structured interviews were conducted with five social workers and five attorneys to gain their perspectives on mediation, how the two professions could cooperate to assist divorcing couples and how inter-professional collaboration could be used to promote the use of mediation in East London. The family advocate was identified as a key role player. The possibility of mandatory mediation was raised with recommendations that it be considered. The co-mediation model was raised to enhance inter-professional collaboration. Social workers see their role as mediating custody issues where the attorneys see their role as mediating division of property and assets. Both professions recognize that they have their own unique contribution to make. Both social workers and attorneys have been found to be willing to collaborate with each other to make a mediation service available to divorcing couples
- Full Text:
- Date Issued: 2000
- Authors: Tatchell, Dolores
- Date: 2000
- Subjects: Divorce mediation -- South Africa , Custody of children-- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:707 , http://hdl.handle.net/10962/d1006519 , Divorce mediation -- South Africa , Custody of children-- South Africa
- Description: This research is based on the continuous search for alternatives in dealing with custody and access of minor children in divorcing families. In spite of the Mediation in Certain Divorce Matters Act, 1987, providing for mediation, it did not lead to the widespread implementation of mediation as an alternative form of dispute resolution in divorce matters. The family advocate as provided for in the Act, serves to protect the interest of minor children in disputes. However, custody evaluation is still used to determine the custody of minor children. Custody evaluation comprises an in depth study and assessment of the structure and functioning of the family made by a social worker and written up in the form of an evaluative report which is then submitted to the family advocate. It occurred to the researcher that there had to be better ways of dealing with custody disputes and consequently the damage done by the parents who fight over their children without any regard for the children’s feelings. It was considered an option to find out from the professionals directly involved with divorce and custody disputes why they have not considered alternatives, such as mediation, to resolve the disputes arising out of a divorce. Semi-structured interviews were conducted with five social workers and five attorneys to gain their perspectives on mediation, how the two professions could cooperate to assist divorcing couples and how inter-professional collaboration could be used to promote the use of mediation in East London. The family advocate was identified as a key role player. The possibility of mandatory mediation was raised with recommendations that it be considered. The co-mediation model was raised to enhance inter-professional collaboration. Social workers see their role as mediating custody issues where the attorneys see their role as mediating division of property and assets. Both professions recognize that they have their own unique contribution to make. Both social workers and attorneys have been found to be willing to collaborate with each other to make a mediation service available to divorcing couples
- Full Text:
- Date Issued: 2000
Petrographic and geochemical constraints on the origin and post-depositional history of the Hotazel iron-manganese deposits, Kalahari Manganese Field, South Africa
- Authors: Tsikos, Harilaos
- Date: 2000
- Subjects: Manganese ores -- South Africa Manganese ores -- Geology -- South Africa Iron ores -- Geology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4987 , http://hdl.handle.net/10962/d1005599
- Description: The giant Palaeoproterozoic manganese deposits of the Kalahari manganese field (KMF), Northern Cape Province, South Mrica, have been a world renowned resource of manganese ore for many decades. In recent years, the mineralogical composition, geochemistry and genesis of these deposits have been the objects of many geological investigations, yet their origin remains contentious up to the present day. A characteristic feature of the Kalahari deposits is the intimate association of manganese ore and iron-formation of the Superior-type, in the form of three discrete sedimentary cycles constituting the Hotazel Formation. This striking lithological association is an almost unique feature on a global scale. From that point of view, the present study is effectively the first attempt to shed light on the origin and post-depositional history of the Hotazel succession, using as prime focus the petrographic and geochemical characteristics ofthe host iron-formation. Petrographic and whole-rock geochemical information of iron-formation from the southern parts of the KMF, suggests that the Hotazel iron-formation is almost identical to other iron-formations of the world of similar age and petrological character. The rock exhibits essentially no high-grade metamorphic or low-temperature alteration effects. Mineralogically, it contains abundant chert, magnetite, subordinate amounts of silicate minerals (greenalite, minnesotaite, stilpnomelane) and appreciable concentrations of carbonate constituents in the form of coexisting calcite and ankerite. Such mineralogical composition is indicative of processes occurring in a diagenetic" to burial (up to very low-greenschist facies) metamorphic environment. Bulk-rock geochemical data point towards a simple composition with Si02, total Fe-oxide and CaO being the chief major oxide components. Whole-rock rare-earth element data suggest that the iron-formation precipitated from a water column with chemical signatures comparable to modern, shallow oceanic seawater. The virtual absence of positive Eu anomalies is a feature that compares well with similar data from Neoproterozoic, glaciogenic iron-formations of the Rapitan type, and suggests but only a dilute hydrothermal signal, poten!ially derived from distal submarine volcanic activity. Carbon and oxygen isotope data from iron-formation and Mn-bearing carbonates as well as overlying ferriferous limestone of the Mooidraai Formation, compare well with the literature. The former exhibit variable depletion relative to seawater in terms of both BC and 180, while the latter have signatures comparable to normal marine bicarbonate. Isotopic variations appear to be related to fluctuations in the amount of co-precipitated marine carbonate, in conjunction with processes of coupled organic matter oxidation - FelMn reduction in the diagenetic environment. Oxygen isotope data from quartz-magnetite-calcite triplets suggest that crystallisation took place under open-system conditions, with magnetite being the most susceptible phase in terms of fluid-rock isotopic exchange. Data also suggest that the calcite-magnetite pair may constitute a more reliable geothermometer than the quartz-magnetite one, mainly due to the interlinked diagenetic histories between calcite and magnetite. Iron-formation from the northern parts of the KMF can by categorised into three main classes, namely pristine, altered and oxidised. Pristine iron-formation is identical to the one seen in the southernmost parts of the field. Altered iron-formation corresponds to a carbonate-free derivative of intense oxidation and leaching processes at the expense ofpristine iron-formation, and contains almost exclusively binary quartz-hematite mixtures. The rock appears to have lost essentially its entire pre-existing carbonate-related components (i.e., Ca, Mg, Sr, most Mn and Ba) and displays residual enrichments in elements such as Cr, Th, V, Ni and Pb, which would have behaved as immobile constituents during low-temperature alteration. The low temperature origin of altered iron-formation is supported by oxygen isotope data from quartz-hematite pairs which indicate that isotopically light hematite would have derived from oxidation of magneftte and other ferroussilicate compounds in the presence of a low-temperature meteoric fluid, while quartz would have remained isotopically unchanged. Occasional occurrences of acmite-hematite assemblages suggest localised metasomatic processes related to the action ofNaCI-rich fluids at the expense of altered iron-formation. The conditions of acmite genesis are very poorly constrained due to the very broad stability limits of the mineral in environments ranging from magmatic to surface-related. Oxidised iron-formation constitutes a distinct rock-type and shares common attributes with both the pristine and the altered iron-formation. The rock contains hematite as an important constituent while the amount of magnetite is substantially reduced. With regard to carbonate nlinerals, calcite contents are clearly very low or absent, having being replaced in most instances by a single, Mgenriched, dolomite/ankerite:type species. Oxidised iron-formation contains somewhat higher amounts of iron and reduced amounts of Sr and Ba relative to pristine iron-formation, whereas enrichments in elements such as Ni, Th, Pb, Cr, and V are seen, similar to altered iron-formation. Oxidised iron-formation appears to have originated from processes of dissolution-mobilisationreprecipitation of solutes derived primarily from leaching that produced altered iron-formation. It is proposed that the Hotazel iron-formation and associated manganese deposits were formed as a result of episodic sea-level fluctuations in a stratified depositional environment that gradually evolved into a shallow carbonate platform. A critical parameter in the development of manganese sediment may include regional climatic patterns related to a glacial event (Makganyene diamictite) prior to deposition of the Hotazel strata. This suggestion draws parallels with processes that are believed to have led to the formation of worldwide iron-formations and associated manganese deposits subsequent to Neoproterozoic episodes of glaciation. Submarine volcanism related to the underlying Ongeluk lavas appears to have had very little (if any) metallogenic significance, while evidence for a sudden rise in the oxygen contents of the atmosphere and ambient waters is lacking. With regard to later alteration processes, combination of geological and geochemical data point towards the potential influence of surface weathering prior to deposition of rocks of the unconformably overlying Olifantshoek Supergroup, possibly coupled with fault- and/or thrustcontrolled fluid-flow and leaching of the Hotazel succession during post-Olifantshoek times.
- Full Text:
- Date Issued: 2000
- Authors: Tsikos, Harilaos
- Date: 2000
- Subjects: Manganese ores -- South Africa Manganese ores -- Geology -- South Africa Iron ores -- Geology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4987 , http://hdl.handle.net/10962/d1005599
- Description: The giant Palaeoproterozoic manganese deposits of the Kalahari manganese field (KMF), Northern Cape Province, South Mrica, have been a world renowned resource of manganese ore for many decades. In recent years, the mineralogical composition, geochemistry and genesis of these deposits have been the objects of many geological investigations, yet their origin remains contentious up to the present day. A characteristic feature of the Kalahari deposits is the intimate association of manganese ore and iron-formation of the Superior-type, in the form of three discrete sedimentary cycles constituting the Hotazel Formation. This striking lithological association is an almost unique feature on a global scale. From that point of view, the present study is effectively the first attempt to shed light on the origin and post-depositional history of the Hotazel succession, using as prime focus the petrographic and geochemical characteristics ofthe host iron-formation. Petrographic and whole-rock geochemical information of iron-formation from the southern parts of the KMF, suggests that the Hotazel iron-formation is almost identical to other iron-formations of the world of similar age and petrological character. The rock exhibits essentially no high-grade metamorphic or low-temperature alteration effects. Mineralogically, it contains abundant chert, magnetite, subordinate amounts of silicate minerals (greenalite, minnesotaite, stilpnomelane) and appreciable concentrations of carbonate constituents in the form of coexisting calcite and ankerite. Such mineralogical composition is indicative of processes occurring in a diagenetic" to burial (up to very low-greenschist facies) metamorphic environment. Bulk-rock geochemical data point towards a simple composition with Si02, total Fe-oxide and CaO being the chief major oxide components. Whole-rock rare-earth element data suggest that the iron-formation precipitated from a water column with chemical signatures comparable to modern, shallow oceanic seawater. The virtual absence of positive Eu anomalies is a feature that compares well with similar data from Neoproterozoic, glaciogenic iron-formations of the Rapitan type, and suggests but only a dilute hydrothermal signal, poten!ially derived from distal submarine volcanic activity. Carbon and oxygen isotope data from iron-formation and Mn-bearing carbonates as well as overlying ferriferous limestone of the Mooidraai Formation, compare well with the literature. The former exhibit variable depletion relative to seawater in terms of both BC and 180, while the latter have signatures comparable to normal marine bicarbonate. Isotopic variations appear to be related to fluctuations in the amount of co-precipitated marine carbonate, in conjunction with processes of coupled organic matter oxidation - FelMn reduction in the diagenetic environment. Oxygen isotope data from quartz-magnetite-calcite triplets suggest that crystallisation took place under open-system conditions, with magnetite being the most susceptible phase in terms of fluid-rock isotopic exchange. Data also suggest that the calcite-magnetite pair may constitute a more reliable geothermometer than the quartz-magnetite one, mainly due to the interlinked diagenetic histories between calcite and magnetite. Iron-formation from the northern parts of the KMF can by categorised into three main classes, namely pristine, altered and oxidised. Pristine iron-formation is identical to the one seen in the southernmost parts of the field. Altered iron-formation corresponds to a carbonate-free derivative of intense oxidation and leaching processes at the expense ofpristine iron-formation, and contains almost exclusively binary quartz-hematite mixtures. The rock appears to have lost essentially its entire pre-existing carbonate-related components (i.e., Ca, Mg, Sr, most Mn and Ba) and displays residual enrichments in elements such as Cr, Th, V, Ni and Pb, which would have behaved as immobile constituents during low-temperature alteration. The low temperature origin of altered iron-formation is supported by oxygen isotope data from quartz-hematite pairs which indicate that isotopically light hematite would have derived from oxidation of magneftte and other ferroussilicate compounds in the presence of a low-temperature meteoric fluid, while quartz would have remained isotopically unchanged. Occasional occurrences of acmite-hematite assemblages suggest localised metasomatic processes related to the action ofNaCI-rich fluids at the expense of altered iron-formation. The conditions of acmite genesis are very poorly constrained due to the very broad stability limits of the mineral in environments ranging from magmatic to surface-related. Oxidised iron-formation constitutes a distinct rock-type and shares common attributes with both the pristine and the altered iron-formation. The rock contains hematite as an important constituent while the amount of magnetite is substantially reduced. With regard to carbonate nlinerals, calcite contents are clearly very low or absent, having being replaced in most instances by a single, Mgenriched, dolomite/ankerite:type species. Oxidised iron-formation contains somewhat higher amounts of iron and reduced amounts of Sr and Ba relative to pristine iron-formation, whereas enrichments in elements such as Ni, Th, Pb, Cr, and V are seen, similar to altered iron-formation. Oxidised iron-formation appears to have originated from processes of dissolution-mobilisationreprecipitation of solutes derived primarily from leaching that produced altered iron-formation. It is proposed that the Hotazel iron-formation and associated manganese deposits were formed as a result of episodic sea-level fluctuations in a stratified depositional environment that gradually evolved into a shallow carbonate platform. A critical parameter in the development of manganese sediment may include regional climatic patterns related to a glacial event (Makganyene diamictite) prior to deposition of the Hotazel strata. This suggestion draws parallels with processes that are believed to have led to the formation of worldwide iron-formations and associated manganese deposits subsequent to Neoproterozoic episodes of glaciation. Submarine volcanism related to the underlying Ongeluk lavas appears to have had very little (if any) metallogenic significance, while evidence for a sudden rise in the oxygen contents of the atmosphere and ambient waters is lacking. With regard to later alteration processes, combination of geological and geochemical data point towards the potential influence of surface weathering prior to deposition of rocks of the unconformably overlying Olifantshoek Supergroup, possibly coupled with fault- and/or thrustcontrolled fluid-flow and leaching of the Hotazel succession during post-Olifantshoek times.
- Full Text:
- Date Issued: 2000
Photocatalytic reactions of metal diphthalocyanine complexes
- Authors: Nensala, Ngudiankama
- Date: 2000
- Subjects: Metal complexes Electrochemistry Photochemistry Pentachlorophenol
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4328 , http://hdl.handle.net/10962/d1004989
- Description: Photocatalytic reactions of tin diphthalocyanine, Sn ^IVPc₂ and anionic form of Nd^III, Dy^III, Eu^III, Tm^III and Lu^III diphthalocyanine complexes ( [Pc(-2)Nd^IIIpc(-2)]⁻ , [Pc(-2)Dy^IIIPc(-2)]⁻ , [Pc(-2)Eu^IIIPc(-2)⁻, [Pc(-2)Tm^IIlPc(-2)r and [Pc(-2)LuIIIpc(-2)]⁻ respectively) in the presence of CH₂CI₂, S0₂, pentachlorophenol (PCP), 4-chlorophenol (4-Cp) and thionyl chloride have been studied. Photoreactions involving lanthanide diphthalocyanines, filtered and unfiltered radiations were employed, whereas for photoreactions involving tin diphthalocyanine, only unfiltered radiation was employed. For lanthanide diphthalocyanine complexes, LnPce-, the photosensitization power increases with the decrease of the lanthanide ionic radii, implying that the photocatalytic activity of LnPc₂⁻ complexes is associated with the π-π interaction between both phthalocyanine rings. Thus, LuPc₂⁻ is a better photocatalyst than other lanthanide diphthalocyanine complexes. Photolysis ofSnPc₂ in an acetonitrile/dichloromethane solvent mixture, using unfiltered radiation from a tungsten lamp, results in the one-electron oxidation of this species to [Pc( -2 )Sn(IV)Pc(-1)]⁻. The relative quantum yields for the disappearance of SnPc₂ are in the order of 10⁻¹. The photoreaction of SnPc₂ is preceded by excitation to nπ* excited states, before been ,quenched by CH₂CI₂. The one-electron oxidation species, [Pc(-2)Sn(lV)pc(-1)]⁻ was also formed during the photolysis of SnPc₂ in dichloromethane containing S0₂, and with quantum yields of order of 10⁻³. Visible photolysis of [Pc( -2)Nd^IIIpc(-2)]⁻, [Pc(-2)Dy^IIIPc(-2)]⁻ and [Pc(-2)Lu^IIIpc(-2)]⁻ in N,N. dimethylformamide (DMF)/dichloromethane solvent mixture containing SO₂, results in the formation of the one-electron oxidation species, Pc(-2 )Nd^IIIpc(-1), Pc( -2) Dyi^IIIPc(-1) and Pc(-2)Lu^IIIpc(-1), respectively. The relative quantum yields are in the order of 10². The photoreactions are preceded by population of the excited triplet state,³π-π* [ LnPc₂]⁻ complex, before exchanging an electron with S0₂. The one-electron oxidation species of Dy^III and Lu^III diphthalocyanine complexes have also been formed from visible photolysis of [Pc(-2 )Dy^IIIPc(-2)]⁻and [Pc(-2)Lu^IIIpc(-2)]⁻in acetonitrile containing PCP. The PCP is reductively dechlorinated to tetra- and trichlorophenols. The quantum yields for the photosensitization reactions are in the order of 1 0⁻. Photolysis, using visible radiation from 220 W Quartzline lamp, of an aqueous solution of 4-Cp, saturated with oxygen and containing a suspension of solid [Pc(-2)Nd^IIIpc(-2)]⁻, results in the formation of benzoquinone, hydro quinone and 4-chlorocatechol. The quantum yields for the degradation of 4-Cp are in the order of 10⁻. Langmuir-Hinshelwood kinetic model shows the adsorption of 4-chlorophenol onto solid [Pc(-2)Nd^IIIpc(-2)]⁻. Lanthanide diphthalocyanine complexes ([Pc-2)Nd^IIIpc(-2)]⁻. [Pc(-2)Eu^IIIpc(-2)]⁻, (Pc(-2)Tm^IIIpc( -2)]⁻ and (Pc(-2)Lu^IIIpc(-2)]⁻) undergo one or two-electron oxidation in the presence of thionyl chloride. At low concentrations of SOCI₂(<10⁻⁴ mol dm⁻³) the visible yhotolysis of [Pc(-2 )LnPc(-2)]⁻ complexes result in the one-electron oxidation, giving neutral lanthanide diphthalocyanine species, Pc(-2)Ln^IIIpc(-1). The Pc(-2 )LnPc(-I) species undergoes one-electron photooxidation to [Pc(-I )LnPc( -I)]⁻ in dichloromethane and in the presence of SOC₁₂. At large concentrations of SOC₁₂ (>10⁻² mol dm⁻³), direct two-electron oxidation of the (Pc(-2 )LnPc - 2)]⁻ species to (Pc(-1)LnPc(-1)]⁻ occurs. Spectroelectrochemical behaviours of Sn^IVPc₂ have been also studied. The cyclic voltammetry ofSnPc₂ in CH₂CI₂/TBAP show two reduction couples at -0.56 V and -0.89 V versus saturated calomel electrode (SCE) and one oxidation couple at 0.35 V versus SCE. In DMFITEAP system, the reduction couples are observed at -0.44 V and -0.81 V versus SCE whereas the oxidation couple occurred at 0.43 V versus SCE. The oxidation couple corresponds to [Pc(-2 )Sn^IVPc(-2 )]/[Pc(-2)Sn^IVPc( -I)] . and the reduction couples to [Pc(-2)Sn^IVPc( -2 )]/[Pc(-2 )Sn^IVPc( -3 )]⁻ and [Pc(-2)Snl^IVPc( -3)] ⁻/[Pc(-3 )Sn^IVPc(-3)]²⁻, respectively. The electronic absorption spectra of these reduced and oxidized species are reported.
- Full Text:
- Date Issued: 2000
- Authors: Nensala, Ngudiankama
- Date: 2000
- Subjects: Metal complexes Electrochemistry Photochemistry Pentachlorophenol
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4328 , http://hdl.handle.net/10962/d1004989
- Description: Photocatalytic reactions of tin diphthalocyanine, Sn ^IVPc₂ and anionic form of Nd^III, Dy^III, Eu^III, Tm^III and Lu^III diphthalocyanine complexes ( [Pc(-2)Nd^IIIpc(-2)]⁻ , [Pc(-2)Dy^IIIPc(-2)]⁻ , [Pc(-2)Eu^IIIPc(-2)⁻, [Pc(-2)Tm^IIlPc(-2)r and [Pc(-2)LuIIIpc(-2)]⁻ respectively) in the presence of CH₂CI₂, S0₂, pentachlorophenol (PCP), 4-chlorophenol (4-Cp) and thionyl chloride have been studied. Photoreactions involving lanthanide diphthalocyanines, filtered and unfiltered radiations were employed, whereas for photoreactions involving tin diphthalocyanine, only unfiltered radiation was employed. For lanthanide diphthalocyanine complexes, LnPce-, the photosensitization power increases with the decrease of the lanthanide ionic radii, implying that the photocatalytic activity of LnPc₂⁻ complexes is associated with the π-π interaction between both phthalocyanine rings. Thus, LuPc₂⁻ is a better photocatalyst than other lanthanide diphthalocyanine complexes. Photolysis ofSnPc₂ in an acetonitrile/dichloromethane solvent mixture, using unfiltered radiation from a tungsten lamp, results in the one-electron oxidation of this species to [Pc( -2 )Sn(IV)Pc(-1)]⁻. The relative quantum yields for the disappearance of SnPc₂ are in the order of 10⁻¹. The photoreaction of SnPc₂ is preceded by excitation to nπ* excited states, before been ,quenched by CH₂CI₂. The one-electron oxidation species, [Pc(-2)Sn(lV)pc(-1)]⁻ was also formed during the photolysis of SnPc₂ in dichloromethane containing S0₂, and with quantum yields of order of 10⁻³. Visible photolysis of [Pc( -2)Nd^IIIpc(-2)]⁻, [Pc(-2)Dy^IIIPc(-2)]⁻ and [Pc(-2)Lu^IIIpc(-2)]⁻ in N,N. dimethylformamide (DMF)/dichloromethane solvent mixture containing SO₂, results in the formation of the one-electron oxidation species, Pc(-2 )Nd^IIIpc(-1), Pc( -2) Dyi^IIIPc(-1) and Pc(-2)Lu^IIIpc(-1), respectively. The relative quantum yields are in the order of 10². The photoreactions are preceded by population of the excited triplet state,³π-π* [ LnPc₂]⁻ complex, before exchanging an electron with S0₂. The one-electron oxidation species of Dy^III and Lu^III diphthalocyanine complexes have also been formed from visible photolysis of [Pc(-2 )Dy^IIIPc(-2)]⁻and [Pc(-2)Lu^IIIpc(-2)]⁻in acetonitrile containing PCP. The PCP is reductively dechlorinated to tetra- and trichlorophenols. The quantum yields for the photosensitization reactions are in the order of 1 0⁻. Photolysis, using visible radiation from 220 W Quartzline lamp, of an aqueous solution of 4-Cp, saturated with oxygen and containing a suspension of solid [Pc(-2)Nd^IIIpc(-2)]⁻, results in the formation of benzoquinone, hydro quinone and 4-chlorocatechol. The quantum yields for the degradation of 4-Cp are in the order of 10⁻. Langmuir-Hinshelwood kinetic model shows the adsorption of 4-chlorophenol onto solid [Pc(-2)Nd^IIIpc(-2)]⁻. Lanthanide diphthalocyanine complexes ([Pc-2)Nd^IIIpc(-2)]⁻. [Pc(-2)Eu^IIIpc(-2)]⁻, (Pc(-2)Tm^IIIpc( -2)]⁻ and (Pc(-2)Lu^IIIpc(-2)]⁻) undergo one or two-electron oxidation in the presence of thionyl chloride. At low concentrations of SOCI₂(<10⁻⁴ mol dm⁻³) the visible yhotolysis of [Pc(-2 )LnPc(-2)]⁻ complexes result in the one-electron oxidation, giving neutral lanthanide diphthalocyanine species, Pc(-2)Ln^IIIpc(-1). The Pc(-2 )LnPc(-I) species undergoes one-electron photooxidation to [Pc(-I )LnPc( -I)]⁻ in dichloromethane and in the presence of SOC₁₂. At large concentrations of SOC₁₂ (>10⁻² mol dm⁻³), direct two-electron oxidation of the (Pc(-2 )LnPc - 2)]⁻ species to (Pc(-1)LnPc(-1)]⁻ occurs. Spectroelectrochemical behaviours of Sn^IVPc₂ have been also studied. The cyclic voltammetry ofSnPc₂ in CH₂CI₂/TBAP show two reduction couples at -0.56 V and -0.89 V versus saturated calomel electrode (SCE) and one oxidation couple at 0.35 V versus SCE. In DMFITEAP system, the reduction couples are observed at -0.44 V and -0.81 V versus SCE whereas the oxidation couple occurred at 0.43 V versus SCE. The oxidation couple corresponds to [Pc(-2 )Sn^IVPc(-2 )]/[Pc(-2)Sn^IVPc( -I)] . and the reduction couples to [Pc(-2)Sn^IVPc( -2 )]/[Pc(-2 )Sn^IVPc( -3 )]⁻ and [Pc(-2)Snl^IVPc( -3)] ⁻/[Pc(-3 )Sn^IVPc(-3)]²⁻, respectively. The electronic absorption spectra of these reduced and oxidized species are reported.
- Full Text:
- Date Issued: 2000
Physiological, perceptual and other performance decrements in combat related tasks following prolonged heavy-load marching
- Authors: Clark, Lisa Anne
- Date: 2000
- Subjects: Performance -- Psychological aspects , Performance standards -- Case studies , Exercise -- Physiological aspects , Exercise -- Psychological aspects , Marching -- Physiological aspects , Soldiers -- Job stress
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5130 , http://hdl.handle.net/10962/d1005209 , Performance -- Psychological aspects , Performance standards -- Case studies , Exercise -- Physiological aspects , Exercise -- Psychological aspects , Marching -- Physiological aspects , Soldiers -- Job stress
- Description: In response to challenging situations physiological and psychological adaptations result in elevated levels of arousal and when these levels are 'optimal' performance is enhanced. There are however, limitations to the amount of physiological and mental stimulation one can tolerate, with cumulative fatigue effects being the outcome when stressful conditions are imposed on the individual over an extended period of time. As a result of the extreme physical and cognitive demands placed on military forces while in combat, with soldiers being thrust into battle and required to make critical life-or-death determining decisions followed by appropriate motor responses, the physical and psychological capabilities of the troops are pushed to maximal limits, often resulting in undesirable decrements in physical and mental performance, with consequential human and materiel losses. Thirty-two soldiers participated in a battery of combat-related field and laboratory tests, first under 'normal' conditions with no prior physical activity and then immediately after the participation of an intensive bout of exercise. Physiological and perceptual responses plus standard of performance were measured at various stages of testing. Results of the Rating of Perceived Exertion (RPE), Body Discomfort Scale and heart rate responses revealed significantly higher levels of psychophysical strai,n in response to the strenuous physical activity. Despite these findings, the electromyographic (EMG) activity and efficiency of the combat-related skills were not negatively affected. Rather, nominal improvements in post-activity performance were noted, specifically response time, and this was attributed to elevated arousal and activation as a result of the exercise that was of sufficient duration to enhance arousal without imposing long term cumulative fatigue effects.
- Full Text:
- Date Issued: 2000
- Authors: Clark, Lisa Anne
- Date: 2000
- Subjects: Performance -- Psychological aspects , Performance standards -- Case studies , Exercise -- Physiological aspects , Exercise -- Psychological aspects , Marching -- Physiological aspects , Soldiers -- Job stress
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5130 , http://hdl.handle.net/10962/d1005209 , Performance -- Psychological aspects , Performance standards -- Case studies , Exercise -- Physiological aspects , Exercise -- Psychological aspects , Marching -- Physiological aspects , Soldiers -- Job stress
- Description: In response to challenging situations physiological and psychological adaptations result in elevated levels of arousal and when these levels are 'optimal' performance is enhanced. There are however, limitations to the amount of physiological and mental stimulation one can tolerate, with cumulative fatigue effects being the outcome when stressful conditions are imposed on the individual over an extended period of time. As a result of the extreme physical and cognitive demands placed on military forces while in combat, with soldiers being thrust into battle and required to make critical life-or-death determining decisions followed by appropriate motor responses, the physical and psychological capabilities of the troops are pushed to maximal limits, often resulting in undesirable decrements in physical and mental performance, with consequential human and materiel losses. Thirty-two soldiers participated in a battery of combat-related field and laboratory tests, first under 'normal' conditions with no prior physical activity and then immediately after the participation of an intensive bout of exercise. Physiological and perceptual responses plus standard of performance were measured at various stages of testing. Results of the Rating of Perceived Exertion (RPE), Body Discomfort Scale and heart rate responses revealed significantly higher levels of psychophysical strai,n in response to the strenuous physical activity. Despite these findings, the electromyographic (EMG) activity and efficiency of the combat-related skills were not negatively affected. Rather, nominal improvements in post-activity performance were noted, specifically response time, and this was attributed to elevated arousal and activation as a result of the exercise that was of sufficient duration to enhance arousal without imposing long term cumulative fatigue effects.
- Full Text:
- Date Issued: 2000
Portfolio of three projects
- Authors: Thomas, Lorraine
- Date: 2000
- Subjects: Educational leadership Organizational change Educational change School management and organization -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1707 , http://hdl.handle.net/10962/d1003590
- Description: Educational leadership and management is a very wide field of study with interdependent components that should form a chain reaction in order to bring about effective management. This study attempts to investigate planning in schools which is one of the educational leadership and management components or functions. Very little research work has been done on educational planning in the Ciskei schools. This is a shortcoming since the number of secondary schools has mushroomed in the late twentieth century. The Ciskei educational managers and parents need to know and take note of the possible situations in the various schools. This is opportune time, particularly that recent events, i.e. students' demands and strikes, are drawing parents closer to the education of their children. The researcher's experience of inspecting school administration since 1990 has reinforced his conviction that the managerial teams in the Ciskei secondary schools have little knowledge of management, and of planning in particular. Although the investigation is into secondary school administration, it is also pertinent to primary school planning. Management, i.e. school year-planning, control of work, staff development, appointment of teachers, policy governing students and teachers are discussed at length . Joint planning, i.e. a participative or consultative approach, and advance planning, are investigated in relation to the school year-programme. The existence of statutory bodies in the various schools is assessed in order to test parents' involvement in the education of their children. School tours are discussed in relation to students' involvement in the school activities. The analysis of the results highlights areas that require attention, and the recommendations given address the controversial issues in planning in the various schools.
- Full Text:
- Date Issued: 2000
- Authors: Thomas, Lorraine
- Date: 2000
- Subjects: Educational leadership Organizational change Educational change School management and organization -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1707 , http://hdl.handle.net/10962/d1003590
- Description: Educational leadership and management is a very wide field of study with interdependent components that should form a chain reaction in order to bring about effective management. This study attempts to investigate planning in schools which is one of the educational leadership and management components or functions. Very little research work has been done on educational planning in the Ciskei schools. This is a shortcoming since the number of secondary schools has mushroomed in the late twentieth century. The Ciskei educational managers and parents need to know and take note of the possible situations in the various schools. This is opportune time, particularly that recent events, i.e. students' demands and strikes, are drawing parents closer to the education of their children. The researcher's experience of inspecting school administration since 1990 has reinforced his conviction that the managerial teams in the Ciskei secondary schools have little knowledge of management, and of planning in particular. Although the investigation is into secondary school administration, it is also pertinent to primary school planning. Management, i.e. school year-planning, control of work, staff development, appointment of teachers, policy governing students and teachers are discussed at length . Joint planning, i.e. a participative or consultative approach, and advance planning, are investigated in relation to the school year-programme. The existence of statutory bodies in the various schools is assessed in order to test parents' involvement in the education of their children. School tours are discussed in relation to students' involvement in the school activities. The analysis of the results highlights areas that require attention, and the recommendations given address the controversial issues in planning in the various schools.
- Full Text:
- Date Issued: 2000
Possible crosstalk between signal transduction pathways in the induction of differentiation in HT-29 cells
- Authors: Jamie, Hajierah
- Date: 2000
- Subjects: Cellular signal transduction , Cell differentiation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:11096 , http://hdl.handle.net/10948/d1019684
- Description: The investigation into the mechanisms by which compounds such as butyrate induce differentiation in HT-29 cells, is lacking. The colonic carcinoma cell line, HT-29, undergoes differentiation induction in the presence of butyrate and acetoacetate. The Caco-2 cell line spontaneously differentiates on contact inhibition. In this study, a signal transduction pathway involving ATP, cAMP, Ca2+ and the transcriptional factor CREB was investigated following suggestions that the energy state of the cell and diffferentiation are linked. The activity of the MAP kinase cascade, including possible crosstalk that may exist between these pathways was determined. The HT-29 cells were exposed to 5 mM acetoacetate, butyrate, DMSO and propionate. The results of this differentiation induction were compared to Caco-2 and HeLa cells, which are cervical carcinoma cells. It was found that ATP levels are decreased on differentiation induction in HT-29 cells, which, in turn affected the cAMP concentrations. Theoretically, the inducers do not have any effect on PDE 4 activity, and may facilitate the interaction between cAMP and PKA. Influx of Ca2+ into the cells was inhibited to a degree by the inducers, which was possibly overcome by crosstalk between the cAMP and Ca2+ pathways. CREB activation, lineage-specific gene expression, ERK activity and c-myc expression were all dependent on both the inducers used and the cell-type. PKA played a major role in CREB activation in acetoacetate- and butyrate -induced HT-29, Caco-2 and HeLa cells, while a2+/Calmodulin-dependent kinases I/IV may have a secondary role. Alkaline phosphatase expression in HeLa cells was independent of CREB. Evidence that crosstalk between the MAP kinase cascade and the REBactivation pathways exist, was illustrated by increased CREB activation on ERK inhibition in acetoacetate- and butyrate-induced HT-29 and HeLa cells. Also, the role that ERK played in the cells differed with inducer and cell-type. The dependence of cmyc expression on c-jun and c-fos, appeared to be differentiation induction- and celltype specific. Results from this study indicate the potential use of acetoacetate and butyrate as anti-cancer compounds.
- Full Text:
- Date Issued: 2000
- Authors: Jamie, Hajierah
- Date: 2000
- Subjects: Cellular signal transduction , Cell differentiation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:11096 , http://hdl.handle.net/10948/d1019684
- Description: The investigation into the mechanisms by which compounds such as butyrate induce differentiation in HT-29 cells, is lacking. The colonic carcinoma cell line, HT-29, undergoes differentiation induction in the presence of butyrate and acetoacetate. The Caco-2 cell line spontaneously differentiates on contact inhibition. In this study, a signal transduction pathway involving ATP, cAMP, Ca2+ and the transcriptional factor CREB was investigated following suggestions that the energy state of the cell and diffferentiation are linked. The activity of the MAP kinase cascade, including possible crosstalk that may exist between these pathways was determined. The HT-29 cells were exposed to 5 mM acetoacetate, butyrate, DMSO and propionate. The results of this differentiation induction were compared to Caco-2 and HeLa cells, which are cervical carcinoma cells. It was found that ATP levels are decreased on differentiation induction in HT-29 cells, which, in turn affected the cAMP concentrations. Theoretically, the inducers do not have any effect on PDE 4 activity, and may facilitate the interaction between cAMP and PKA. Influx of Ca2+ into the cells was inhibited to a degree by the inducers, which was possibly overcome by crosstalk between the cAMP and Ca2+ pathways. CREB activation, lineage-specific gene expression, ERK activity and c-myc expression were all dependent on both the inducers used and the cell-type. PKA played a major role in CREB activation in acetoacetate- and butyrate -induced HT-29, Caco-2 and HeLa cells, while a2+/Calmodulin-dependent kinases I/IV may have a secondary role. Alkaline phosphatase expression in HeLa cells was independent of CREB. Evidence that crosstalk between the MAP kinase cascade and the REBactivation pathways exist, was illustrated by increased CREB activation on ERK inhibition in acetoacetate- and butyrate-induced HT-29 and HeLa cells. Also, the role that ERK played in the cells differed with inducer and cell-type. The dependence of cmyc expression on c-jun and c-fos, appeared to be differentiation induction- and celltype specific. Results from this study indicate the potential use of acetoacetate and butyrate as anti-cancer compounds.
- Full Text:
- Date Issued: 2000
Principals' perceptions of the management of staff appraisal in schools.
- Authors: Blaauw, Lindiwe Ellen
- Date: 2000
- Subjects: Educational evaluation , Teachers -- Rating of
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2011 , http://hdl.handle.net/10962/d1016080
- Description: Teacher appraisal has long been a contentious and contested area in educational management. The recent implementation of a new system of appraisal in Eastern Cape Schools has led to renewed interest in the role and management of appraisal. The objective of this study was to investigate principals' perception of the management of staff appraisal. An interpretive paradigm was adopted and the research is a case study of four secondary schools in Port Elizabeth. Two methods were used in collecting data, namely, questionnaires and interviews. The content comparative method was used to analyse the data. The findings of this study showed areas of continuities and discontinuities with the literature and the new document on appraisal. There is a clear understanding among the principals interviewed that staff appraisal should be used to assess individual teacher performance and that it should also be developmental. There is clear support from the principals on the involvement of other stakeholders. They see the process as transformative and participatory. They find it acceptable and are willing to be involved. However, the findings also indicate a lack of readiness on the part of the principals to fully embrace a fully participative and developmental approach to appraisal. On the strength of these findings I conclude the thesis by making recommendations for policy, principals, teachers and for future researchers in the field.
- Full Text:
- Date Issued: 2000
- Authors: Blaauw, Lindiwe Ellen
- Date: 2000
- Subjects: Educational evaluation , Teachers -- Rating of
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2011 , http://hdl.handle.net/10962/d1016080
- Description: Teacher appraisal has long been a contentious and contested area in educational management. The recent implementation of a new system of appraisal in Eastern Cape Schools has led to renewed interest in the role and management of appraisal. The objective of this study was to investigate principals' perception of the management of staff appraisal. An interpretive paradigm was adopted and the research is a case study of four secondary schools in Port Elizabeth. Two methods were used in collecting data, namely, questionnaires and interviews. The content comparative method was used to analyse the data. The findings of this study showed areas of continuities and discontinuities with the literature and the new document on appraisal. There is a clear understanding among the principals interviewed that staff appraisal should be used to assess individual teacher performance and that it should also be developmental. There is clear support from the principals on the involvement of other stakeholders. They see the process as transformative and participatory. They find it acceptable and are willing to be involved. However, the findings also indicate a lack of readiness on the part of the principals to fully embrace a fully participative and developmental approach to appraisal. On the strength of these findings I conclude the thesis by making recommendations for policy, principals, teachers and for future researchers in the field.
- Full Text:
- Date Issued: 2000
Professional development in environmental education in Zanzibar, Tanzania: distances encountered in a semi-distance learning course
- Authors: Heylings, Phillippa Frances
- Date: 2000
- Subjects: Environmental education -- Tanzania -- Zanzibar Distance education -- Tanzania -- Zanzibar Environmental education Distance education
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1715 , http://hdl.handle.net/10962/d1003598
- Description: In Zanzibar, in 1995, opportunities for professional development in environmental education were minimal. Yet the demand for professional development was high, especially because of an emphasis on formal qualifications in the country. Credibility was afforded to forms of professional development, aimed at creating more ‘experts’. Ongoing environmental education practice was not achieving its objectives. Into this setting, which was culturally and socio-politically different from the South African context where it was developed, I introduced the Rhodes University Certificate and Gold Fields Participatory Course in Environmental Education (RU/GF); a non-formal, counter-hegemonic course which encouraged critical reflection on the dominant orientations to environmental education practice – including professional development. I used critical ethnographic and action research methods to explore my praxiological interest, the adaptation of the RU/GF curriculum to the Zanzibar context. During the research process, a decision was made to formally accredit the RU/GF course. This decision did not alter the course orientation or the learning process but opened up possibilities for future curriculum development processes. It allowed the students both a formal qualification necessary for status and promotion, and participation in a learning process that challenged the dominant paradigm on professional development and status from within the socio-political context. The research took on a reflexive orientation to research and environmental education. Through a dialectical development of theory, method and results, several important issues emerged. These deal with the ‘distances’ encountered in attempting to address some of the perceived dichotomies in professional development in environmental education through semi-distance learning: the distances between status and learning; the need for career upgrading and the type of learning considered appropriate for professional development in environmental education; the non-quantifiable aims associated with a reflexive orientation to professional development and formal assessment demands for measurable criteria; the democratisation of open-entry courses and the elitism of restricted access; the focus on individual growth and the attainment of a normative grade; theory and practice; and finally distances between learner, text and language. The research supports similar findings emerging from evaluation of the RU/GF course in South Africa and resonates with, and contributes to, issues concerning professional development in environmental education being considered internationally.
- Full Text:
- Date Issued: 2000
- Authors: Heylings, Phillippa Frances
- Date: 2000
- Subjects: Environmental education -- Tanzania -- Zanzibar Distance education -- Tanzania -- Zanzibar Environmental education Distance education
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1715 , http://hdl.handle.net/10962/d1003598
- Description: In Zanzibar, in 1995, opportunities for professional development in environmental education were minimal. Yet the demand for professional development was high, especially because of an emphasis on formal qualifications in the country. Credibility was afforded to forms of professional development, aimed at creating more ‘experts’. Ongoing environmental education practice was not achieving its objectives. Into this setting, which was culturally and socio-politically different from the South African context where it was developed, I introduced the Rhodes University Certificate and Gold Fields Participatory Course in Environmental Education (RU/GF); a non-formal, counter-hegemonic course which encouraged critical reflection on the dominant orientations to environmental education practice – including professional development. I used critical ethnographic and action research methods to explore my praxiological interest, the adaptation of the RU/GF curriculum to the Zanzibar context. During the research process, a decision was made to formally accredit the RU/GF course. This decision did not alter the course orientation or the learning process but opened up possibilities for future curriculum development processes. It allowed the students both a formal qualification necessary for status and promotion, and participation in a learning process that challenged the dominant paradigm on professional development and status from within the socio-political context. The research took on a reflexive orientation to research and environmental education. Through a dialectical development of theory, method and results, several important issues emerged. These deal with the ‘distances’ encountered in attempting to address some of the perceived dichotomies in professional development in environmental education through semi-distance learning: the distances between status and learning; the need for career upgrading and the type of learning considered appropriate for professional development in environmental education; the non-quantifiable aims associated with a reflexive orientation to professional development and formal assessment demands for measurable criteria; the democratisation of open-entry courses and the elitism of restricted access; the focus on individual growth and the attainment of a normative grade; theory and practice; and finally distances between learner, text and language. The research supports similar findings emerging from evaluation of the RU/GF course in South Africa and resonates with, and contributes to, issues concerning professional development in environmental education being considered internationally.
- Full Text:
- Date Issued: 2000
Profile of paediatric psychosocial disorders in Frere Hospital and analysis of associated patterns of referrals
- Authors: Chukwuemeka, Gregory Adjuba
- Date: 2000
- Subjects: Child psychopathology , Frere Hospital
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2949 , http://hdl.handle.net/10962/d1002458 , Child psychopathology , Frere Hospital
- Description: The profile of psychosocial disorders in children and the attendant patterns of referrals and health communication, were investigated within the context of a tertiary referral centre in the Eastern Cape Province. Literature on childhood disorders points to a high level of functional and substance related disorders in technologically developed countries of Europe and North America, in contrast to the developing countries of Asia and Africa, where the burden of infectious diseases and disorders of deprivation and lack still predominate in the profile of psychosocial disorders in children. In South Africa however, there is almost non-existent research on clinical psychosocial disorders profile and the research sets out to be an exploratory study in this area. A combination design was employed in which interviews and observations complemented a primarily quantitative descriptive cross sectional analysis of hospitalcase records. A pilot study was performed using an information gathering questionnaire and interviews, with findings subsequently explored in the main study. The International Classification of Diseases (ICD-10) (WHO, 1992) diagnostic categories were used to create a profile of all ailments in the paediatric unit. Psychosocial disorders both in terms of aetiology and illness course, can be viewed from the perspective of socialadjustment and functioning (in which there is a potential role of social factors as provoking, causal or modifying factors) (Williams &Clare, 1979); and the DSM-IV (Diagnostic and Statistical Manual of Mental Disorders) (American Psychiatric Association,1994) criteria was used to create the profile of these disorders in the paediatric unit at Frere Hospital which accounted for 45% of the ailments managed in one year. The derived profile is a picture in between the profile found in technologically advanced countries, and developing countries. While the infection burden and malnutrition appear to be readily contained or curtailed, there appears to be a serious problem with access to health care services which manifest especially at the level of perinatal events, with resultant high level of hypoxic brain damage and consequently mental retardation and varying levels of impairment or disability. These medical consequences in turn are fundamentally psychosocial, requiring psychosocial care with heavy reliance on strategic communication and referrals. The referrals in respect of psychosocial disorders are mainly at primary care level revolving around local health care clinics, private clinics, special schools and rehabilitation centres.
- Full Text:
- Date Issued: 2000
- Authors: Chukwuemeka, Gregory Adjuba
- Date: 2000
- Subjects: Child psychopathology , Frere Hospital
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2949 , http://hdl.handle.net/10962/d1002458 , Child psychopathology , Frere Hospital
- Description: The profile of psychosocial disorders in children and the attendant patterns of referrals and health communication, were investigated within the context of a tertiary referral centre in the Eastern Cape Province. Literature on childhood disorders points to a high level of functional and substance related disorders in technologically developed countries of Europe and North America, in contrast to the developing countries of Asia and Africa, where the burden of infectious diseases and disorders of deprivation and lack still predominate in the profile of psychosocial disorders in children. In South Africa however, there is almost non-existent research on clinical psychosocial disorders profile and the research sets out to be an exploratory study in this area. A combination design was employed in which interviews and observations complemented a primarily quantitative descriptive cross sectional analysis of hospitalcase records. A pilot study was performed using an information gathering questionnaire and interviews, with findings subsequently explored in the main study. The International Classification of Diseases (ICD-10) (WHO, 1992) diagnostic categories were used to create a profile of all ailments in the paediatric unit. Psychosocial disorders both in terms of aetiology and illness course, can be viewed from the perspective of socialadjustment and functioning (in which there is a potential role of social factors as provoking, causal or modifying factors) (Williams &Clare, 1979); and the DSM-IV (Diagnostic and Statistical Manual of Mental Disorders) (American Psychiatric Association,1994) criteria was used to create the profile of these disorders in the paediatric unit at Frere Hospital which accounted for 45% of the ailments managed in one year. The derived profile is a picture in between the profile found in technologically advanced countries, and developing countries. While the infection burden and malnutrition appear to be readily contained or curtailed, there appears to be a serious problem with access to health care services which manifest especially at the level of perinatal events, with resultant high level of hypoxic brain damage and consequently mental retardation and varying levels of impairment or disability. These medical consequences in turn are fundamentally psychosocial, requiring psychosocial care with heavy reliance on strategic communication and referrals. The referrals in respect of psychosocial disorders are mainly at primary care level revolving around local health care clinics, private clinics, special schools and rehabilitation centres.
- Full Text:
- Date Issued: 2000
Replacement of seven 132/66 kv distance protection schemes by means of a generic relay implemented as a strategic spare
- Authors: Harris, Raymond Trevor
- Date: 2000
- Subjects: Protective relays , Electric power systems -- Protection
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10808 , http://hdl.handle.net/10948/34 , Protective relays , Electric power systems -- Protection
- Description: Eskom is experiencing problems in the field of protection maintenance and in-service breakdowns which negatively influence the quality of electrical supply to the consumer, an integral component of the utility business. These facts initiated the research into the further development of a generic relay to be implemented as a strategic spare for the replacement of several schemes operating within Eskom’s southern region. These include the electromechanical, solid state and numerical distance protection relay and scheme failures on the 132 / 66 kV feeder network. Hence, the primary objective of the research is to develop, test and configure the strategic spare in terms of software and peripheral hardware for the input and output terminal connections, generic equations and settings for the purpose of the scheme replacements. The various schemes are assessed for stepped distance and permissive intertripping for three or single pole operation. This is done in conjunction with the internal and external circuit diagrams in order to understand the detailed operation of the scheme and to ensure the effective implementation of the strategic spare. The generic relay is configured for the emergency replacement of the various schemes during in-service breakdowns. This constitutes a temporary installation and therefore the downtime in essence, of all the distance protection schemes that require replacement, is limited to a minimum. This dissertation therefore explores the implementation of the strategic spare.
- Full Text:
- Date Issued: 2000
- Authors: Harris, Raymond Trevor
- Date: 2000
- Subjects: Protective relays , Electric power systems -- Protection
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10808 , http://hdl.handle.net/10948/34 , Protective relays , Electric power systems -- Protection
- Description: Eskom is experiencing problems in the field of protection maintenance and in-service breakdowns which negatively influence the quality of electrical supply to the consumer, an integral component of the utility business. These facts initiated the research into the further development of a generic relay to be implemented as a strategic spare for the replacement of several schemes operating within Eskom’s southern region. These include the electromechanical, solid state and numerical distance protection relay and scheme failures on the 132 / 66 kV feeder network. Hence, the primary objective of the research is to develop, test and configure the strategic spare in terms of software and peripheral hardware for the input and output terminal connections, generic equations and settings for the purpose of the scheme replacements. The various schemes are assessed for stepped distance and permissive intertripping for three or single pole operation. This is done in conjunction with the internal and external circuit diagrams in order to understand the detailed operation of the scheme and to ensure the effective implementation of the strategic spare. The generic relay is configured for the emergency replacement of the various schemes during in-service breakdowns. This constitutes a temporary installation and therefore the downtime in essence, of all the distance protection schemes that require replacement, is limited to a minimum. This dissertation therefore explores the implementation of the strategic spare.
- Full Text:
- Date Issued: 2000
Research Portfolio
- Authors: Nts'aba, Likengkeng
- Date: 2000
- Subjects: School management and organization -- South Africa -- Eastern Cape , School board members -- South Africa -- Eastern Cape -- Decision making , Education -- Political aspects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2051 , http://hdl.handle.net/10962/d1018259
- Description: The move towards greater democracy and participation in our education system is legislated quite succinctly in our South African Schools Act. The Act furthermore, and more importantly for this case study, posits that decision-making should be democratic in nature and our schools should eventually become governed in a collaborative and co-operative manner. Other policy texts such as the Labour Relations Act and the South African Constitution canonise the demand for a democratic South African society. This study investigates how democratic decision-making practices are taking place in an East London Secondary School namely Ebenezer Majombozi High. Even though distinct links exist between management and governance arms of schools, this study concentrates predominantly on decision-making within the school governing body and touches briefly on management thinking trends as a theoretical background to the kind of management at the school. What makes the school interesting as a case study is its rich history and its location in a deprived and impoverished township environment. The school was also part of the ex-Department of Education and Training, the black educational department of the past apartheid state. The kind of research undertaken was in the form of unstructured personal :interviews with influential stakeholders at the school. Some of these stakeholders fonn part of the school governing body and the questions asked probed forms of governance at the school and how decision-making impacted on the overall school governance. The research fmdings acknowledges that decision-making does occur democratically at the school but that the practical implementation of positive consensual decisions are rarely realized. The school governing body only meets to deal with crises underpinned by a lack of learning and teaching and has not even debated the policies within the South African Schools Act. The study also argues that only by building capacity within the school and empowering the stakeholders, can constructive participation by all become a reality.
- Full Text:
- Date Issued: 2000
- Authors: Nts'aba, Likengkeng
- Date: 2000
- Subjects: School management and organization -- South Africa -- Eastern Cape , School board members -- South Africa -- Eastern Cape -- Decision making , Education -- Political aspects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2051 , http://hdl.handle.net/10962/d1018259
- Description: The move towards greater democracy and participation in our education system is legislated quite succinctly in our South African Schools Act. The Act furthermore, and more importantly for this case study, posits that decision-making should be democratic in nature and our schools should eventually become governed in a collaborative and co-operative manner. Other policy texts such as the Labour Relations Act and the South African Constitution canonise the demand for a democratic South African society. This study investigates how democratic decision-making practices are taking place in an East London Secondary School namely Ebenezer Majombozi High. Even though distinct links exist between management and governance arms of schools, this study concentrates predominantly on decision-making within the school governing body and touches briefly on management thinking trends as a theoretical background to the kind of management at the school. What makes the school interesting as a case study is its rich history and its location in a deprived and impoverished township environment. The school was also part of the ex-Department of Education and Training, the black educational department of the past apartheid state. The kind of research undertaken was in the form of unstructured personal :interviews with influential stakeholders at the school. Some of these stakeholders fonn part of the school governing body and the questions asked probed forms of governance at the school and how decision-making impacted on the overall school governance. The research fmdings acknowledges that decision-making does occur democratically at the school but that the practical implementation of positive consensual decisions are rarely realized. The school governing body only meets to deal with crises underpinned by a lack of learning and teaching and has not even debated the policies within the South African Schools Act. The study also argues that only by building capacity within the school and empowering the stakeholders, can constructive participation by all become a reality.
- Full Text:
- Date Issued: 2000
Research portfolio
- Authors: Ngwane, Mandisa Sweetness
- Date: 2000
- Subjects: Educational surveys -- South Africa -- Grahamstown Educational evaluation -- South Africa -- Grahamstown Education -- Environmental aspects Environmental education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1728 , http://hdl.handle.net/10962/d1003611
- Full Text:
- Date Issued: 2000
- Authors: Ngwane, Mandisa Sweetness
- Date: 2000
- Subjects: Educational surveys -- South Africa -- Grahamstown Educational evaluation -- South Africa -- Grahamstown Education -- Environmental aspects Environmental education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1728 , http://hdl.handle.net/10962/d1003611
- Full Text:
- Date Issued: 2000
Research Projects Portfolio.
- Authors: Schudel, Ingrid Joan
- Date: 2000
- Subjects: Environmental education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2015 , http://hdl.handle.net/10962/d1016368
- Description: This collection of research projects tells a story of the time I have spent with members of the Albany Working for Water team; including preparations made, lessons learned and insights gained. My first project was to analyse the methodology of a research paper. I chose the paper by Arjen Wals because I intended, like him, to examine people's perceptions of environmental issues. From this paper I gained ideas for a qualitative research process and learnt the importance of theoretical and methodological consistency. My next project was to present a report on my research into the perceptions of workrelated environmental issues among the Albany Working for Water workers. From this research I gained insight into the knowledge of the workers and also some of the misconceptions that they have about social and ecological issues. I made educational recommendations based on these insights. This experience inspired me to initiate a play with a group of the workers about alien plant eradication. The process of developing this play formed the basis for a research paper that I have submitted as another research project. Concurrent with the development of the play, I conducted a fourth research project that was a situational analysis of the Albany Workingfor Water Project. I hoped that this analysis would provide useful insight into the context of the above two projects. Overall, I hope the story reflects how I have grown through the learning experiences I shared with the Albany Working for Water team. I would like to extend to my thanks to all those who assisted and shared my journey with me.
- Full Text:
- Date Issued: 2000
- Authors: Schudel, Ingrid Joan
- Date: 2000
- Subjects: Environmental education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2015 , http://hdl.handle.net/10962/d1016368
- Description: This collection of research projects tells a story of the time I have spent with members of the Albany Working for Water team; including preparations made, lessons learned and insights gained. My first project was to analyse the methodology of a research paper. I chose the paper by Arjen Wals because I intended, like him, to examine people's perceptions of environmental issues. From this paper I gained ideas for a qualitative research process and learnt the importance of theoretical and methodological consistency. My next project was to present a report on my research into the perceptions of workrelated environmental issues among the Albany Working for Water workers. From this research I gained insight into the knowledge of the workers and also some of the misconceptions that they have about social and ecological issues. I made educational recommendations based on these insights. This experience inspired me to initiate a play with a group of the workers about alien plant eradication. The process of developing this play formed the basis for a research paper that I have submitted as another research project. Concurrent with the development of the play, I conducted a fourth research project that was a situational analysis of the Albany Workingfor Water Project. I hoped that this analysis would provide useful insight into the context of the above two projects. Overall, I hope the story reflects how I have grown through the learning experiences I shared with the Albany Working for Water team. I would like to extend to my thanks to all those who assisted and shared my journey with me.
- Full Text:
- Date Issued: 2000
Road culture : an investigation of the road as a means of mental and physical exploration
- Authors: Meistre, Brent Arthur
- Date: 2000
- Subjects: Roads in art , Travel in art , Travel -- Psychological aspects , Travelers -- Psychology
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2414 , http://hdl.handle.net/10962/d1002210 , Roads in art , Travel in art , Travel -- Psychological aspects , Travelers -- Psychology
- Description: Chapter one considers various manifestations of the concept of ‘journey’ and how they have changed over history. The Odyssean journey that the hero undertakes to reach a point of self-realisation is investigated. This leads to a other discussion of types of journeys such as pilgrimages, as well as ‘wandering’. These are contrasted with the twentieth century perceptions of journey. Questions of travel are then dealt with: how the nature of the traveller's path has changed over the centuries, various points of travel and gender, and how in the last century solitary travel has been transformed into mass tourism. The second chapter deals specifically with the motorcar, the mobility it enables and how it has led to the rise of a roadside culture. Different factors that influenced the rise of the motorcar are looked at. The motorcar as a cell and eroticism and the car are also investigated. The twentieth century city, it's restructuring, as well as the highway systems is discussed. In Chapter Three, the sense of freedom that the motorcar created is considered in particular reference to escape, aimlessness, and road weariness, as well as the landscape as a symbol of freedom. This leads to a discussion on the notion of speed, the sense of power and the romanticisation of death in car crashes. Chapter Four investigates masculinity and the road. The frontier as a place in the psyche of the male is also dealt with. The road as a means of testing and regaining masculinity in the mid-twentieth century is considered. Issues of the male domination of the land and the feminine are discussed, with the chapter ending with a brief examination of the woman as traveller. Lastly the masters’ submission exhibition, entitled RODE is discussed with direct reference to the theories investigated in the previous chapters. Individual works as well as the methodology are looked at closely.
- Full Text:
- Date Issued: 2000
- Authors: Meistre, Brent Arthur
- Date: 2000
- Subjects: Roads in art , Travel in art , Travel -- Psychological aspects , Travelers -- Psychology
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2414 , http://hdl.handle.net/10962/d1002210 , Roads in art , Travel in art , Travel -- Psychological aspects , Travelers -- Psychology
- Description: Chapter one considers various manifestations of the concept of ‘journey’ and how they have changed over history. The Odyssean journey that the hero undertakes to reach a point of self-realisation is investigated. This leads to a other discussion of types of journeys such as pilgrimages, as well as ‘wandering’. These are contrasted with the twentieth century perceptions of journey. Questions of travel are then dealt with: how the nature of the traveller's path has changed over the centuries, various points of travel and gender, and how in the last century solitary travel has been transformed into mass tourism. The second chapter deals specifically with the motorcar, the mobility it enables and how it has led to the rise of a roadside culture. Different factors that influenced the rise of the motorcar are looked at. The motorcar as a cell and eroticism and the car are also investigated. The twentieth century city, it's restructuring, as well as the highway systems is discussed. In Chapter Three, the sense of freedom that the motorcar created is considered in particular reference to escape, aimlessness, and road weariness, as well as the landscape as a symbol of freedom. This leads to a discussion on the notion of speed, the sense of power and the romanticisation of death in car crashes. Chapter Four investigates masculinity and the road. The frontier as a place in the psyche of the male is also dealt with. The road as a means of testing and regaining masculinity in the mid-twentieth century is considered. Issues of the male domination of the land and the feminine are discussed, with the chapter ending with a brief examination of the woman as traveller. Lastly the masters’ submission exhibition, entitled RODE is discussed with direct reference to the theories investigated in the previous chapters. Individual works as well as the methodology are looked at closely.
- Full Text:
- Date Issued: 2000
Rural students' local knowledge of learning in formal and informal contexts
- Authors: Visser, Alvin-Jon
- Date: 2000
- Subjects: Non-formal education -- South Africa , Education and state -- South Africa , Rural children -- Education -- South Africa , Black people -- Education -- South Africa , Community and school -- South Africa , Education, Rural -- Social Aspects -- South Africa , Rural schools -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3079 , http://hdl.handle.net/10962/d1002588 , Non-formal education -- South Africa , Education and state -- South Africa , Rural children -- Education -- South Africa , Black people -- Education -- South Africa , Community and school -- South Africa , Education, Rural -- Social Aspects -- South Africa , Rural schools -- South Africa
- Description: The general aim of this thesis is to illuminate the process of learning as it occurs in formal and informal contexts. The study focuses on South African scholars attending school in rural areas where the contrast between learning in formal and informal learning contexts is more pronounced than that in urban areas. The research draws on rural scholars' local knowledge of formal and informal learning contexts in order to gain a rich insight into how cognition is situated in different learning contexts. This is accomplished through investigating the structure of the respective learning tasks, the mediators involved, the task objectives and the means for achieving these objectives in the different learning contexts. The thesis draws on a socio-cultural approach to the study of cognitive development to probe the activity of learning in a formal and informal learning context. Through the use of a context sensitive methodological methods especially Participatory Rural Appraisal (PRA) tools and techniques, it was possible to illuminate tacit local knowledge structures and to get participants to actively explicate their understandings related to learning in different contexts The research results illustrate the assertion that the activity of learning is fundamentally situated in the learning context from which it arises. Learning is framed by the community of practice which structures affordances for situated learning, through mediation, within zones of proximal development. Learning in a formal context such as the school is often abstract, rule-based, standardised and theory related. Learners also find it difficult to reflect on the learning tasks and the mediational means used in a formal learning context. In contrast, the learning which takes place in an informal setting is often practical, individualised, flexible and environment based. This learning is structured around everyday activities and is dynamically defined and supported. In a situation where a learner is exposed to dislocated learning contexts, the essential goal of educational initiatives is to bridge the gap between the two. This can be achieved through mediators creating effective zones of proximal development which facilitate the individuals adaptation between learning contexts. Exposing rural scholars' local knowledge of learning in formal and informal contexts allows for a fuller understanding of the cognitive development structured within formal and informal communities of practice. It is this understanding that is necessary to address the situation where learning contexts, drawing on different knowledge bases find ways of thinking, prove challenging and/or conflicting to the scholar.
- Full Text:
- Date Issued: 2000
- Authors: Visser, Alvin-Jon
- Date: 2000
- Subjects: Non-formal education -- South Africa , Education and state -- South Africa , Rural children -- Education -- South Africa , Black people -- Education -- South Africa , Community and school -- South Africa , Education, Rural -- Social Aspects -- South Africa , Rural schools -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3079 , http://hdl.handle.net/10962/d1002588 , Non-formal education -- South Africa , Education and state -- South Africa , Rural children -- Education -- South Africa , Black people -- Education -- South Africa , Community and school -- South Africa , Education, Rural -- Social Aspects -- South Africa , Rural schools -- South Africa
- Description: The general aim of this thesis is to illuminate the process of learning as it occurs in formal and informal contexts. The study focuses on South African scholars attending school in rural areas where the contrast between learning in formal and informal learning contexts is more pronounced than that in urban areas. The research draws on rural scholars' local knowledge of formal and informal learning contexts in order to gain a rich insight into how cognition is situated in different learning contexts. This is accomplished through investigating the structure of the respective learning tasks, the mediators involved, the task objectives and the means for achieving these objectives in the different learning contexts. The thesis draws on a socio-cultural approach to the study of cognitive development to probe the activity of learning in a formal and informal learning context. Through the use of a context sensitive methodological methods especially Participatory Rural Appraisal (PRA) tools and techniques, it was possible to illuminate tacit local knowledge structures and to get participants to actively explicate their understandings related to learning in different contexts The research results illustrate the assertion that the activity of learning is fundamentally situated in the learning context from which it arises. Learning is framed by the community of practice which structures affordances for situated learning, through mediation, within zones of proximal development. Learning in a formal context such as the school is often abstract, rule-based, standardised and theory related. Learners also find it difficult to reflect on the learning tasks and the mediational means used in a formal learning context. In contrast, the learning which takes place in an informal setting is often practical, individualised, flexible and environment based. This learning is structured around everyday activities and is dynamically defined and supported. In a situation where a learner is exposed to dislocated learning contexts, the essential goal of educational initiatives is to bridge the gap between the two. This can be achieved through mediators creating effective zones of proximal development which facilitate the individuals adaptation between learning contexts. Exposing rural scholars' local knowledge of learning in formal and informal contexts allows for a fuller understanding of the cognitive development structured within formal and informal communities of practice. It is this understanding that is necessary to address the situation where learning contexts, drawing on different knowledge bases find ways of thinking, prove challenging and/or conflicting to the scholar.
- Full Text:
- Date Issued: 2000
Rural underdevelopment in the former Ciskei with specific reference to Glenmore Village
- Authors: Malila, Brett
- Date: 2000
- Subjects: Rural development -- South Africa -- Eastern Cape , Poverty -- South Africa -- Eastern Cape , Eastern Cape (South Africa) -- Social conditions , Glenmore (South Africa) -- Economic conditions
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3288 , http://hdl.handle.net/10962/d1003076 , Rural development -- South Africa -- Eastern Cape , Poverty -- South Africa -- Eastern Cape , Eastern Cape (South Africa) -- Social conditions , Glenmore (South Africa) -- Economic conditions
- Description: This thesis examines development changes that took place in Glenmore after 1994. To examine such change one needs to have a concise historical understanding of the situation in Glenmore before democracy. The aim of the work is to critique development at a local, rural level, pinpointing the major changes, if any, that came with the incorporation of the former homeland of Ciskei (and thus Glenmore village) with South Africa. These people were forcibly resettled in 1979 for political and economic reasons. Their situation then was one of dire poverty; it is argued here that even with democracy, their history of underdevelopment has continued. The reason for this continued underdevelopment is the structure of the former reserves. The overall political context has changed in South Africa but the most important aspect with regard to the development of the homelands: land, has not. At the central level, the government has churned out a wide variety of development policies, which due to the prevailing political and economic context of the times are fraught with inconsistencies. The example used here to show some of these inconsistencies is the 1997 White Paper on Land Reform. This confusion at the central level with regard to the perceived future of South Africa has managed to adversely affect the rural areas and their development. There very well might be policies in abundance to improve the life-world of the rural poor, but there are inconsistencies between this policy and actual practice. With regard to Glenmore the confusion in the present government’s central development policy is arguably the main reason for the underdevelopment of the village. The inconsistencies in policy such as the 1997 White Paper on Land Reform, have meant that the structure of the reserves has not changed. Vital issues such as land tenure and ownership have not been dealt with. The study thus shows that unless the structure of the homeland system which is predominantly based on issues of land, is changed, genuine social and economic development will not take place in areas like Glenmore.
- Full Text:
- Date Issued: 2000
- Authors: Malila, Brett
- Date: 2000
- Subjects: Rural development -- South Africa -- Eastern Cape , Poverty -- South Africa -- Eastern Cape , Eastern Cape (South Africa) -- Social conditions , Glenmore (South Africa) -- Economic conditions
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3288 , http://hdl.handle.net/10962/d1003076 , Rural development -- South Africa -- Eastern Cape , Poverty -- South Africa -- Eastern Cape , Eastern Cape (South Africa) -- Social conditions , Glenmore (South Africa) -- Economic conditions
- Description: This thesis examines development changes that took place in Glenmore after 1994. To examine such change one needs to have a concise historical understanding of the situation in Glenmore before democracy. The aim of the work is to critique development at a local, rural level, pinpointing the major changes, if any, that came with the incorporation of the former homeland of Ciskei (and thus Glenmore village) with South Africa. These people were forcibly resettled in 1979 for political and economic reasons. Their situation then was one of dire poverty; it is argued here that even with democracy, their history of underdevelopment has continued. The reason for this continued underdevelopment is the structure of the former reserves. The overall political context has changed in South Africa but the most important aspect with regard to the development of the homelands: land, has not. At the central level, the government has churned out a wide variety of development policies, which due to the prevailing political and economic context of the times are fraught with inconsistencies. The example used here to show some of these inconsistencies is the 1997 White Paper on Land Reform. This confusion at the central level with regard to the perceived future of South Africa has managed to adversely affect the rural areas and their development. There very well might be policies in abundance to improve the life-world of the rural poor, but there are inconsistencies between this policy and actual practice. With regard to Glenmore the confusion in the present government’s central development policy is arguably the main reason for the underdevelopment of the village. The inconsistencies in policy such as the 1997 White Paper on Land Reform, have meant that the structure of the reserves has not changed. Vital issues such as land tenure and ownership have not been dealt with. The study thus shows that unless the structure of the homeland system which is predominantly based on issues of land, is changed, genuine social and economic development will not take place in areas like Glenmore.
- Full Text:
- Date Issued: 2000
Searching for new relevance in the 1990s: the Organization of African Unity as an instrument of conflict resolution
- Authors: Dlamini, Thandeka Lungile
- Date: 2000
- Subjects: Organization of African Unity , Africa -- Foreign relations , Conflict management -- Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2770 , http://hdl.handle.net/10962/d1002980 , Organization of African Unity , Africa -- Foreign relations , Conflict management -- Africa
- Description: The 1960's and the 1970's marked a great Pan-African movement in Africa, that saw the liberation of most African states. This Pan-African movement, was spearheaded by a quest to unite Africa, and to abate foreign occupation. Amidst the spirit of unity, lay a promise of an organization that would embody the hopes and aspirations of a continent undergoing a re-birth; a progression towards self-determination, economic development and integration, and the maintenance of peace. Therefore, the inception ofthe Organization of African Unity (OAD) was not only a symbol of a unifying force for Africans, but a diplomatic platform that would promote African needs on the international arena. In effect the OAU, at its inception, was for specific ideals that would guarantee liberation and unity of African states. The outcome of these ideals would be greater regional economic integration and the achievement of peace and stability. These ideals mirrored the structural definition of regional organization, with the inclusion of a Commission for Mediation Arbitration and Conciliation under the OAU Charter, to handle disputes among member states. However, the mere fact that this commission lacked the political wherewithal to resolve conflicts, by its sheer lack of a standing peacekeeping force, contributed to the inefficiency of the organization to play an effective role in conflict management. This study attempts to examine the role ofthe OAU in settling disputes. The study sought to accomplish this, in the following manner. Firstly, an investigation into the nature of conflict and why it persists in Africa was conducted. Further, an examination ofthe tools that practitioners utilize not only to study conflict, but to prevent, manage and resolve it, was done. During the investigation it was found that, although the OAU's greatest successes have come from preventive diplomacy, its structural foundations limit the capabilities of the organization to become more relevant. The Charter of the OAU alludes vaguely to the settlement of disputes, but without an executive political decision-making body able to deploy peacekeepers, its principles are largely meaningless. Amidst the growing concerns, the OAU as a matter of survival, developed initiatives it hopes will make it more effective and relevant. The focus ofthe study was the evolving role ofthe OAU, from its inception to its new role as an instrument of conflict resolution. Most of the scholarly work conducted on the OAU, is concerned with depicting a terminal organization, with little or no hope of surviving. Little emphasis is placed on prescribing remedies on how to improve and restructure the organization. The findings included, inter alia, that the organization is faced with enormous challenges, as the sources of conflict are varied and complex. Africa is now the landscape of collapsed states, economic stagnation, environmental degradation, disease and chronic conflicts. The OAU shoulders much ofthe responsibility for not sanctioning governments that contribute to the decay and suffering of the African peoples. Most ofthe criticism of the OAU, stem from the inability of the organization to play an effective role in resolving conflicts in Africa. Most of Africa's conflicts stem from a lack of political legitimacy, lack of democratic institutions, uneven distribution of resources, ethnic tensions and economic stagnation. Until such problems are addressed, Africa will continue to host the world's deadliest conflicts.
- Full Text:
- Date Issued: 2000
- Authors: Dlamini, Thandeka Lungile
- Date: 2000
- Subjects: Organization of African Unity , Africa -- Foreign relations , Conflict management -- Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2770 , http://hdl.handle.net/10962/d1002980 , Organization of African Unity , Africa -- Foreign relations , Conflict management -- Africa
- Description: The 1960's and the 1970's marked a great Pan-African movement in Africa, that saw the liberation of most African states. This Pan-African movement, was spearheaded by a quest to unite Africa, and to abate foreign occupation. Amidst the spirit of unity, lay a promise of an organization that would embody the hopes and aspirations of a continent undergoing a re-birth; a progression towards self-determination, economic development and integration, and the maintenance of peace. Therefore, the inception ofthe Organization of African Unity (OAD) was not only a symbol of a unifying force for Africans, but a diplomatic platform that would promote African needs on the international arena. In effect the OAU, at its inception, was for specific ideals that would guarantee liberation and unity of African states. The outcome of these ideals would be greater regional economic integration and the achievement of peace and stability. These ideals mirrored the structural definition of regional organization, with the inclusion of a Commission for Mediation Arbitration and Conciliation under the OAU Charter, to handle disputes among member states. However, the mere fact that this commission lacked the political wherewithal to resolve conflicts, by its sheer lack of a standing peacekeeping force, contributed to the inefficiency of the organization to play an effective role in conflict management. This study attempts to examine the role ofthe OAU in settling disputes. The study sought to accomplish this, in the following manner. Firstly, an investigation into the nature of conflict and why it persists in Africa was conducted. Further, an examination ofthe tools that practitioners utilize not only to study conflict, but to prevent, manage and resolve it, was done. During the investigation it was found that, although the OAU's greatest successes have come from preventive diplomacy, its structural foundations limit the capabilities of the organization to become more relevant. The Charter of the OAU alludes vaguely to the settlement of disputes, but without an executive political decision-making body able to deploy peacekeepers, its principles are largely meaningless. Amidst the growing concerns, the OAU as a matter of survival, developed initiatives it hopes will make it more effective and relevant. The focus ofthe study was the evolving role ofthe OAU, from its inception to its new role as an instrument of conflict resolution. Most of the scholarly work conducted on the OAU, is concerned with depicting a terminal organization, with little or no hope of surviving. Little emphasis is placed on prescribing remedies on how to improve and restructure the organization. The findings included, inter alia, that the organization is faced with enormous challenges, as the sources of conflict are varied and complex. Africa is now the landscape of collapsed states, economic stagnation, environmental degradation, disease and chronic conflicts. The OAU shoulders much ofthe responsibility for not sanctioning governments that contribute to the decay and suffering of the African peoples. Most ofthe criticism of the OAU, stem from the inability of the organization to play an effective role in resolving conflicts in Africa. Most of Africa's conflicts stem from a lack of political legitimacy, lack of democratic institutions, uneven distribution of resources, ethnic tensions and economic stagnation. Until such problems are addressed, Africa will continue to host the world's deadliest conflicts.
- Full Text:
- Date Issued: 2000
Serotonin-melatonin interactions in acetaminophen and N,N-dimethylformamide toxicity
- Anoopkumar-Dukie, Shailendra
- Authors: Anoopkumar-Dukie, Shailendra
- Date: 2000
- Subjects: Serotonin , Acetaminophen , Melatonin
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3898 , http://hdl.handle.net/10962/d1003957 , Serotonin , Acetaminophen , Melatonin
- Description: Acetaminophen and N,N-dimethylformamide (DMF) are compounds which are extremely toxic to the liver. Acetaminophen is a drug which is well known for its analgesic and antipyretic properties. However, the abuse potential of this agent as a non-narcotic analgesic in alcoholics is well known. It is also the leading cause of overdose in England. DMF toxicity results mainly from occupational exposure. At present there are no known reports of an antidote for DMF poisoning, while N-acetylcysteine, the antidote for acetaminophen poisoning, is known to produce adverse effects. The present study evaluates the potential of melatonin as an antidote for acetaminophen and DMF poisoning. This study also investigates the mechanism underlying acetaminophen addiction and abuse. Initial studies involved in vitro techniques in an attempt to remove the complexities of organ interactions. The photodegradation studies, using ultraviolet (UV) light, revealed that melatonin accelerates the rate of acetaminophen degradation in the presence of air, and reduces the rate of degradation in the presence of nitrogen. This study also revealed that melatonin is rapidly degraded in the presence of air, following UV irradiation. The effect of DMF on hydroxyl radical generation was also determined. DMF was shown to act as a free radical scavenger, rather that a generator of free radicals. The in vitro studies were followed by lipid peroxidation determination. DMF (0.4ml/kg and 0.8ml/kg) did not produce any significant increases in lipid peroxidation in the liver. Three different doses of acetaminophen (30mg/kg, 100mg/kg, and 500mg/kg) were administered to rats for seven days. Acetaminophen (500mg/kg) was shown to significantly increase (p<0.05) lipid peroxidation in the liver. Melatonin (2.5mg/kg) was not able to significantly reduce the damage. The lower doses of acetaminophen (30mg/kg and 100mg/kg) did not increase lipid peroxidation. Electron microscopy studies showed that DMF adversely affects the liver, and in particular, the endoplasmic reticulum. Co administration of melatonin (2.5mg/kg) was able to reduce the damage. Further experiments need to be performed before an accurate assessment can be made on the ability of melatonin as an antidote for DMF and acetaminophen poisoning. Several experiments were done in an attempt to uncover the biochemical mechanism underlying acetaminophen addiction and abuse. The first experiment targeted the liver enzyme tryptophan-2,3-dioxygenase (TDO). This enzyme is the major determinant of tryptophan levels in vivo. Acetaminophen administration (100mg/kg for three hours) was shown to significantly inhibit (p<0.05) the activity of TDO, indicating increased peripheral levels of tryptophan. This experiment was followed up with determination of brain serotonin and pineal melatonin. Brain serotonin was determined using the ELISA technique. Melatonin was estimated using this technique as well as with pineal organ culture. Acetaminophen administration (100mg/kg for three hours) significantly increased (p<0.05) brain serotonin levels. Using organ culture where exogenous (3H) tryptophan is metabolised to (3H) melatonin, acetaminophen (100mg/kg for three hours) was shown to significantly increase (p<0.05) pineal melatonin concentrations. However, the ELISA technique did not reveal any changes in endogenous pineal melatonin levels. The final experiment was the determination of urinary 5-hydroxyindole acetic acid (5- HIAA), the major metabolite of serotonin, following acetaminophen administration (100mg/kg for three hours). Acetaminophen was shown to significantly reduce 5-HIAA levels (p<0.05) suggesting reduced catabolism of serotonin. The findings of this study indicate that acetaminophen mimics the actions of an antidepressant. This compelling finding has important clinical implications, and needs to be examined further.
- Full Text:
- Date Issued: 2000
- Authors: Anoopkumar-Dukie, Shailendra
- Date: 2000
- Subjects: Serotonin , Acetaminophen , Melatonin
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3898 , http://hdl.handle.net/10962/d1003957 , Serotonin , Acetaminophen , Melatonin
- Description: Acetaminophen and N,N-dimethylformamide (DMF) are compounds which are extremely toxic to the liver. Acetaminophen is a drug which is well known for its analgesic and antipyretic properties. However, the abuse potential of this agent as a non-narcotic analgesic in alcoholics is well known. It is also the leading cause of overdose in England. DMF toxicity results mainly from occupational exposure. At present there are no known reports of an antidote for DMF poisoning, while N-acetylcysteine, the antidote for acetaminophen poisoning, is known to produce adverse effects. The present study evaluates the potential of melatonin as an antidote for acetaminophen and DMF poisoning. This study also investigates the mechanism underlying acetaminophen addiction and abuse. Initial studies involved in vitro techniques in an attempt to remove the complexities of organ interactions. The photodegradation studies, using ultraviolet (UV) light, revealed that melatonin accelerates the rate of acetaminophen degradation in the presence of air, and reduces the rate of degradation in the presence of nitrogen. This study also revealed that melatonin is rapidly degraded in the presence of air, following UV irradiation. The effect of DMF on hydroxyl radical generation was also determined. DMF was shown to act as a free radical scavenger, rather that a generator of free radicals. The in vitro studies were followed by lipid peroxidation determination. DMF (0.4ml/kg and 0.8ml/kg) did not produce any significant increases in lipid peroxidation in the liver. Three different doses of acetaminophen (30mg/kg, 100mg/kg, and 500mg/kg) were administered to rats for seven days. Acetaminophen (500mg/kg) was shown to significantly increase (p<0.05) lipid peroxidation in the liver. Melatonin (2.5mg/kg) was not able to significantly reduce the damage. The lower doses of acetaminophen (30mg/kg and 100mg/kg) did not increase lipid peroxidation. Electron microscopy studies showed that DMF adversely affects the liver, and in particular, the endoplasmic reticulum. Co administration of melatonin (2.5mg/kg) was able to reduce the damage. Further experiments need to be performed before an accurate assessment can be made on the ability of melatonin as an antidote for DMF and acetaminophen poisoning. Several experiments were done in an attempt to uncover the biochemical mechanism underlying acetaminophen addiction and abuse. The first experiment targeted the liver enzyme tryptophan-2,3-dioxygenase (TDO). This enzyme is the major determinant of tryptophan levels in vivo. Acetaminophen administration (100mg/kg for three hours) was shown to significantly inhibit (p<0.05) the activity of TDO, indicating increased peripheral levels of tryptophan. This experiment was followed up with determination of brain serotonin and pineal melatonin. Brain serotonin was determined using the ELISA technique. Melatonin was estimated using this technique as well as with pineal organ culture. Acetaminophen administration (100mg/kg for three hours) significantly increased (p<0.05) brain serotonin levels. Using organ culture where exogenous (3H) tryptophan is metabolised to (3H) melatonin, acetaminophen (100mg/kg for three hours) was shown to significantly increase (p<0.05) pineal melatonin concentrations. However, the ELISA technique did not reveal any changes in endogenous pineal melatonin levels. The final experiment was the determination of urinary 5-hydroxyindole acetic acid (5- HIAA), the major metabolite of serotonin, following acetaminophen administration (100mg/kg for three hours). Acetaminophen was shown to significantly reduce 5-HIAA levels (p<0.05) suggesting reduced catabolism of serotonin. The findings of this study indicate that acetaminophen mimics the actions of an antidepressant. This compelling finding has important clinical implications, and needs to be examined further.
- Full Text:
- Date Issued: 2000
Settler women's experiences of fear, illness and isolation, with particular reference to the Eastern Cape Frontier, 1820-1890
- Authors: Dampier, Helen
- Date: 2000
- Subjects: Women -- South Africa -- History , Women -- South Africa -- Eastern Cape -- Social conditions , Women -- South Africa -- Eastern Cape -- History , British settlers of 1820 (South Africa) , Frontier and pioneer life -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2537 , http://hdl.handle.net/10962/d1002389 , Women -- South Africa -- History , Women -- South Africa -- Eastern Cape -- Social conditions , Women -- South Africa -- Eastern Cape -- History , British settlers of 1820 (South Africa) , Frontier and pioneer life -- South Africa
- Description: This thesis is an exploration of diaries and letters written by middle-class English-speaking settler women living on the Eastern Cape frontier between 1820 and 1890. By according primacy to these women’s experiences and perceptions, it aims for a greater understanding of women’s encounters with the frontier, and how these were articulated in their personal writing. An emphasis on the recurrent themes of ill-health, fearfulness and solitude undermines the popular myth of the brave, conquering, invincible pioneers which dominates settler historiography to date. The tensions felt by white women living on the frontier disrupted their identities as middle-class Victorian ‘ladies’, and as a result these women either constantly re-established a sense of self, or absorbed some aspects of the Eastern Cape, and thus redefined themselves. Settler women’s experiences of the frontier changed little during the seventy year period spanned by this study, indicating that frontier life led to a rigidification and reinforcement of old, familiar values and behaviours. Rather than adapting to and embracing their new surroundings, settler women sought to duplicate accepted, conventional Victorian ideals and customs. White Victorian women identified themselves as refined, civilized, moral and respectable, and perceived Africa and Africans as untamed, immoral, uncivilized and threatening. To keep these menacing, destabilizing forces at bay, settler women attempted to recreate ‘home’ in the Eastern Cape; to domesticate the frontier by rendering it as familiar and predictable as possible. The fear, illness and solitariness that characterise settler women’s personal writings manifest their attempts to eliminate alienating difference, and record their refusal to truly engage with the frontier landscape and its inhabitants.
- Full Text:
- Date Issued: 2000
- Authors: Dampier, Helen
- Date: 2000
- Subjects: Women -- South Africa -- History , Women -- South Africa -- Eastern Cape -- Social conditions , Women -- South Africa -- Eastern Cape -- History , British settlers of 1820 (South Africa) , Frontier and pioneer life -- South Africa
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2537 , http://hdl.handle.net/10962/d1002389 , Women -- South Africa -- History , Women -- South Africa -- Eastern Cape -- Social conditions , Women -- South Africa -- Eastern Cape -- History , British settlers of 1820 (South Africa) , Frontier and pioneer life -- South Africa
- Description: This thesis is an exploration of diaries and letters written by middle-class English-speaking settler women living on the Eastern Cape frontier between 1820 and 1890. By according primacy to these women’s experiences and perceptions, it aims for a greater understanding of women’s encounters with the frontier, and how these were articulated in their personal writing. An emphasis on the recurrent themes of ill-health, fearfulness and solitude undermines the popular myth of the brave, conquering, invincible pioneers which dominates settler historiography to date. The tensions felt by white women living on the frontier disrupted their identities as middle-class Victorian ‘ladies’, and as a result these women either constantly re-established a sense of self, or absorbed some aspects of the Eastern Cape, and thus redefined themselves. Settler women’s experiences of the frontier changed little during the seventy year period spanned by this study, indicating that frontier life led to a rigidification and reinforcement of old, familiar values and behaviours. Rather than adapting to and embracing their new surroundings, settler women sought to duplicate accepted, conventional Victorian ideals and customs. White Victorian women identified themselves as refined, civilized, moral and respectable, and perceived Africa and Africans as untamed, immoral, uncivilized and threatening. To keep these menacing, destabilizing forces at bay, settler women attempted to recreate ‘home’ in the Eastern Cape; to domesticate the frontier by rendering it as familiar and predictable as possible. The fear, illness and solitariness that characterise settler women’s personal writings manifest their attempts to eliminate alienating difference, and record their refusal to truly engage with the frontier landscape and its inhabitants.
- Full Text:
- Date Issued: 2000