Implementing non-photorealistic rendering enhancements with real-time performance
- Authors: Winnemöller, Holger
- Date: 2002 , 2013-05-09
- Subjects: Computer animation , Computer graphics , Real-time data processing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4580 , http://hdl.handle.net/10962/d1003135 , Computer animation , Computer graphics , Real-time data processing
- Description: We describe quality and performance enhancements, which work in real-time, to all well-known Non-photorealistic (NPR) rendering styles for use in an interactive context. These include Comic rendering, Sketch rendering, Hatching and Painterly rendering, but we also attempt and justify a widening of the established definition of what is considered NPR. In the individual Chapters, we identify typical stylistic elements of the different NPR styles. We list problems that need to be solved in order to implement the various renderers. Standard solutions available in the literature are introduced and in all cases extended and optimised. In particular, we extend the lighting model of the comic renderer to include a specular component and introduce multiple inter-related but independent geometric approximations which greatly improve rendering performance. We implement two completely different solutions to random perturbation sketching, solve temporal coherence issues for coal sketching and find an unexpected use for 3D textures to implement hatch-shading. Textured brushes of painterly rendering are extended by properties such as stroke-direction and texture, motion, paint capacity, opacity and emission, making them more flexible and versatile. Brushes are also provided with a minimal amount of intelligence, so that they can help in maximising screen coverage of brushes. We furthermore devise a completely new NPR style, which we call super-realistic and show how sample images can be tweened in real-time to produce an image-based six degree-of-freedom renderer performing at roughly 450 frames per second. Performance values for our other renderers all lie between 10 and over 400 frames per second on homePC hardware, justifying our real-time claim. A large number of sample screen-shots, illustrations and animations demonstrate the visual fidelity of our rendered images. In essence, we successfully achieve our attempted goals of increasing the creative, expressive and communicative potential of individual NPR styles, increasing performance of most of them, adding original and interesting visual qualities, and exploring new techniques or existing ones in novel ways. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2002
- Authors: Winnemöller, Holger
- Date: 2002 , 2013-05-09
- Subjects: Computer animation , Computer graphics , Real-time data processing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4580 , http://hdl.handle.net/10962/d1003135 , Computer animation , Computer graphics , Real-time data processing
- Description: We describe quality and performance enhancements, which work in real-time, to all well-known Non-photorealistic (NPR) rendering styles for use in an interactive context. These include Comic rendering, Sketch rendering, Hatching and Painterly rendering, but we also attempt and justify a widening of the established definition of what is considered NPR. In the individual Chapters, we identify typical stylistic elements of the different NPR styles. We list problems that need to be solved in order to implement the various renderers. Standard solutions available in the literature are introduced and in all cases extended and optimised. In particular, we extend the lighting model of the comic renderer to include a specular component and introduce multiple inter-related but independent geometric approximations which greatly improve rendering performance. We implement two completely different solutions to random perturbation sketching, solve temporal coherence issues for coal sketching and find an unexpected use for 3D textures to implement hatch-shading. Textured brushes of painterly rendering are extended by properties such as stroke-direction and texture, motion, paint capacity, opacity and emission, making them more flexible and versatile. Brushes are also provided with a minimal amount of intelligence, so that they can help in maximising screen coverage of brushes. We furthermore devise a completely new NPR style, which we call super-realistic and show how sample images can be tweened in real-time to produce an image-based six degree-of-freedom renderer performing at roughly 450 frames per second. Performance values for our other renderers all lie between 10 and over 400 frames per second on homePC hardware, justifying our real-time claim. A large number of sample screen-shots, illustrations and animations demonstrate the visual fidelity of our rendered images. In essence, we successfully achieve our attempted goals of increasing the creative, expressive and communicative potential of individual NPR styles, increasing performance of most of them, adding original and interesting visual qualities, and exploring new techniques or existing ones in novel ways. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2002
Improving job performance by using non-monetary reward systems to motivate low-skilled workers in the automotive component industry
- Authors: Taljaard, Jacob Johannes
- Date: 2002
- Subjects: Employee motivation -- South Africa , Performance awards
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:10910 , http://hdl.handle.net/10948/131 , Employee motivation -- South Africa , Performance awards
- Description: Automotive component manufacturing companies where the labour is low skilled and the processes are labour intensive, are being challenged on a more regular basis to find methods to satisfy needs to motivate employees to improve performance. Automotive companies are becoming more under pressure to motivate employees through non-monetary rewards, due to collective bargaining which has made pay for performance very inflexible. It is because of this fact that employers have to assess non-monetary reward methods to motivate employees to improve performance. To be motivators, rewards must be aligned with the needs of people and the things that they value. If these rewards are aligned with employees needs, this could lead to increase in employee motivation, which will in turn lead to improvement in performance, and therefore lead to companies becoming more competitive. This research paper aims to assess what would be the motivators when establishing a non-monetary reward system. To this end the various motivational theories are presented which clearly identifies what needs people have and how they can be satisfied to change behaviour and therefore improve performance. Secondly, reward systems are discussed with various types of rewards being considered and more specifically non-monetary rewards. Applied research was undertaken to determine non-monetary rewards that will motivate low-skilled employees to improve performance. A survey, with the aid of a structured questionnaire, was used to gain information from 60 employees. The research was conducted in three companies that manufacture components for the auto industry. The majority of the respondents indicated that: 1. basic needs must be satisfied with monetary rewards; 2. non-monetary rewards, if linked to higher hierarchical needs, will then motivate employees; 3. non-monetary rewards should preferably be of a physical nature such as certificates, caps and t-shirts; 4. satisfaction of these higher level needs motivate employees and improve their performance; 5. employees prefer feedback and recognition as a non-monetary reward on a regular basis, and 6. the needs of employees should be identified through a survey to establish which rewards will satisfy these needs.
- Full Text:
- Date Issued: 2002
- Authors: Taljaard, Jacob Johannes
- Date: 2002
- Subjects: Employee motivation -- South Africa , Performance awards
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:10910 , http://hdl.handle.net/10948/131 , Employee motivation -- South Africa , Performance awards
- Description: Automotive component manufacturing companies where the labour is low skilled and the processes are labour intensive, are being challenged on a more regular basis to find methods to satisfy needs to motivate employees to improve performance. Automotive companies are becoming more under pressure to motivate employees through non-monetary rewards, due to collective bargaining which has made pay for performance very inflexible. It is because of this fact that employers have to assess non-monetary reward methods to motivate employees to improve performance. To be motivators, rewards must be aligned with the needs of people and the things that they value. If these rewards are aligned with employees needs, this could lead to increase in employee motivation, which will in turn lead to improvement in performance, and therefore lead to companies becoming more competitive. This research paper aims to assess what would be the motivators when establishing a non-monetary reward system. To this end the various motivational theories are presented which clearly identifies what needs people have and how they can be satisfied to change behaviour and therefore improve performance. Secondly, reward systems are discussed with various types of rewards being considered and more specifically non-monetary rewards. Applied research was undertaken to determine non-monetary rewards that will motivate low-skilled employees to improve performance. A survey, with the aid of a structured questionnaire, was used to gain information from 60 employees. The research was conducted in three companies that manufacture components for the auto industry. The majority of the respondents indicated that: 1. basic needs must be satisfied with monetary rewards; 2. non-monetary rewards, if linked to higher hierarchical needs, will then motivate employees; 3. non-monetary rewards should preferably be of a physical nature such as certificates, caps and t-shirts; 4. satisfaction of these higher level needs motivate employees and improve their performance; 5. employees prefer feedback and recognition as a non-monetary reward on a regular basis, and 6. the needs of employees should be identified through a survey to establish which rewards will satisfy these needs.
- Full Text:
- Date Issued: 2002
In the best interests of the child? : a case study of the psychological discourses of the custody decision-making process in a South African context
- Authors: Durrbaum, René
- Date: 2002
- Subjects: Custody of children -- South Africa -- Psychological aspects Children of divorced parents -- South Africa -- Psychology
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3153 , http://hdl.handle.net/10962/d1007484
- Description: This study focuses on the process of custody decision-making in a South African divorce context with the aim of critically examining the operation of the principle of the best interests of the child. A narrative approach is incorporated into Parker and Fairclough's discourse analytic approaches in the context of an instrumental case study. More specifically, the focus falls on moving beyond the understandings of custody embodied within the current psychological literature in order to examine the relationship between theory and practice and to view custody as a dynamic process at both a textual and analytical level. Concepts of dialoguing, context, audience and intertextuality together with a storied approach are central. Further, an attempt is made to provide a disruptive reading of the case through the use of notions of power, ideology and institutional practices embedded within the case and its broader contexts. The analysis demonstrates the need for decision-making to be viewed as a broader process situated across multiple professional, institutional and socio-political texts and contexts. Further, it is argued that in order for the process to uphold the principle of the child's best interests, specialised training must be supplemented with changes at the level of policy, aimed at moving toward a more inclusive, process-oriented approach to custody decision-making.
- Full Text:
- Date Issued: 2002
- Authors: Durrbaum, René
- Date: 2002
- Subjects: Custody of children -- South Africa -- Psychological aspects Children of divorced parents -- South Africa -- Psychology
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3153 , http://hdl.handle.net/10962/d1007484
- Description: This study focuses on the process of custody decision-making in a South African divorce context with the aim of critically examining the operation of the principle of the best interests of the child. A narrative approach is incorporated into Parker and Fairclough's discourse analytic approaches in the context of an instrumental case study. More specifically, the focus falls on moving beyond the understandings of custody embodied within the current psychological literature in order to examine the relationship between theory and practice and to view custody as a dynamic process at both a textual and analytical level. Concepts of dialoguing, context, audience and intertextuality together with a storied approach are central. Further, an attempt is made to provide a disruptive reading of the case through the use of notions of power, ideology and institutional practices embedded within the case and its broader contexts. The analysis demonstrates the need for decision-making to be viewed as a broader process situated across multiple professional, institutional and socio-political texts and contexts. Further, it is argued that in order for the process to uphold the principle of the child's best interests, specialised training must be supplemented with changes at the level of policy, aimed at moving toward a more inclusive, process-oriented approach to custody decision-making.
- Full Text:
- Date Issued: 2002
Indigenous knowledge and the school curriculum: A review of developing methods and methodological perspectives
- O’Donoghue, Rob B, Neluvhalani, Edgar
- Authors: O’Donoghue, Rob B , Neluvhalani, Edgar
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/437292 , vital:73366 , ISBN 978-07969-2001-0 , https://www.hsrcpress.ac.za/books/environmental-education-ethics-action-in-southern-africa
- Description: Written by environmental practitioners from across the region, the Monograph is a window onto envi-ronmental challenges in a diversity of African con-texts. These contexts include Malawian officials and community leaders, new to multi-level governance, taking up the challenge of environmental manage-ment in villages and districts; Ugandan small-scale farmers in partnership with NGOs trying to produce sustainably for the household and the international market; and government-civil society partnerships in South Africa, where the political transformation of the education system introduced a focus on envi-ronment and human rights in the national school curriculum.
- Full Text:
- Date Issued: 2002
- Authors: O’Donoghue, Rob B , Neluvhalani, Edgar
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/437292 , vital:73366 , ISBN 978-07969-2001-0 , https://www.hsrcpress.ac.za/books/environmental-education-ethics-action-in-southern-africa
- Description: Written by environmental practitioners from across the region, the Monograph is a window onto envi-ronmental challenges in a diversity of African con-texts. These contexts include Malawian officials and community leaders, new to multi-level governance, taking up the challenge of environmental manage-ment in villages and districts; Ugandan small-scale farmers in partnership with NGOs trying to produce sustainably for the household and the international market; and government-civil society partnerships in South Africa, where the political transformation of the education system introduced a focus on envi-ronment and human rights in the national school curriculum.
- Full Text:
- Date Issued: 2002
Intelligent gripper design and application for automated part recognition and gripping
- Authors: Wang, Jianqiang
- Date: 2002
- Subjects: Automatic control , Robots, Industrial , Robotics
- Language: English
- Type: Thesis , Doctoral , DTech (Engineering)
- Identifier: vital:10816 , http://hdl.handle.net/10948/102 , Automatic control , Robots, Industrial , Robotics
- Description: Intelligent gripping may be achieved through gripper design, automated part recognition, intelligent algorithm for control of the gripper, and on-line decision-making based on sensory data. A generic framework which integrates sensory data, part recognition, decision-making and gripper control to achieve intelligent gripping based on ABB industrial robot is constructed. The three-fingered gripper actuated by a linear servo actuator designed and developed in this project for precise speed and position control is capable of handling a large variety of objects. Generic algorithms for intelligent part recognition are developed. Edge vector representation is discussed. Object geometric features are extracted. Fuzzy logic is successfully utilized to enhance the intelligence of the system. The generic fuzzy logic algorithm, which may also find application in other fields, is presented. Model-based gripping planning algorithm which is capable of extracting object grasp features from its geometric features and reasoning out grasp model for objects with different geometry is proposed. Manipulator trajectory planning solves the problem of generating robot programs automatically. Object-oriented programming technique based on Visual C++ MFC is used to constitute the system software so as to ensure the compatibility, expandability and modular programming design. Hierarchical architecture for intelligent gripping is discussed, which partitions the robot’s functionalities into high-level (modeling, recognizing, planning and perception) layers, and low-level (sensing, interfacing and execute) layers. Individual system modules are integrated seamlessly to constitute the intelligent gripping system.
- Full Text:
- Date Issued: 2002
- Authors: Wang, Jianqiang
- Date: 2002
- Subjects: Automatic control , Robots, Industrial , Robotics
- Language: English
- Type: Thesis , Doctoral , DTech (Engineering)
- Identifier: vital:10816 , http://hdl.handle.net/10948/102 , Automatic control , Robots, Industrial , Robotics
- Description: Intelligent gripping may be achieved through gripper design, automated part recognition, intelligent algorithm for control of the gripper, and on-line decision-making based on sensory data. A generic framework which integrates sensory data, part recognition, decision-making and gripper control to achieve intelligent gripping based on ABB industrial robot is constructed. The three-fingered gripper actuated by a linear servo actuator designed and developed in this project for precise speed and position control is capable of handling a large variety of objects. Generic algorithms for intelligent part recognition are developed. Edge vector representation is discussed. Object geometric features are extracted. Fuzzy logic is successfully utilized to enhance the intelligence of the system. The generic fuzzy logic algorithm, which may also find application in other fields, is presented. Model-based gripping planning algorithm which is capable of extracting object grasp features from its geometric features and reasoning out grasp model for objects with different geometry is proposed. Manipulator trajectory planning solves the problem of generating robot programs automatically. Object-oriented programming technique based on Visual C++ MFC is used to constitute the system software so as to ensure the compatibility, expandability and modular programming design. Hierarchical architecture for intelligent gripping is discussed, which partitions the robot’s functionalities into high-level (modeling, recognizing, planning and perception) layers, and low-level (sensing, interfacing and execute) layers. Individual system modules are integrated seamlessly to constitute the intelligent gripping system.
- Full Text:
- Date Issued: 2002
Interaction of sulfur dioxide and cyanide with cobalt (II) tetrasulfophthalocyanine in aqueous media
- Thamae, Mamothibe, Nyokong, Tebello
- Authors: Thamae, Mamothibe , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289595 , vital:56652 , xlink:href="https://doi.org/10.1016/S0277-5387(01)00968-8"
- Description: Kinetic and equilibrium studies for the coordination of cyanide or sulfur dioxide to the cobalt(II) tetrasulfophthalocyanine ([CoTSPc]4−) complex are reported. The equilibrium constant for the coordination of the cyanide under pH 11 conditions and an oxygen atmosphere, and the formation of [(CN−)2Co(III)TSPc]5− species, was found to be 2.1×101 dm3 mol−1 and the rate constant, kf was found to be 7.4 dm3 mol−1 s−1. Similarly, the coordination of SO2 to [CoTSPc]4− occurred with an equilibrium constant of 8.7×101 dm3 mol−1 and a rate constant of 2.1×102 dm3 mol−1 s−1, at pH 11. These rate and equilibrium constants represent the coordination of the second cyanide or sulfur dioxide ligands to the [CoTSPc]4− species. Coordination of the first ligand occurred faster than that of the second ligand in both cases. The coordination is accompanied by the oxidation of the central Co(II) metal with the formation of a Co(III) tetrasulfophthalocyanine species.
- Full Text:
- Date Issued: 2002
Interaction of sulfur dioxide and cyanide with cobalt (II) tetrasulfophthalocyanine in aqueous media
- Authors: Thamae, Mamothibe , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289595 , vital:56652 , xlink:href="https://doi.org/10.1016/S0277-5387(01)00968-8"
- Description: Kinetic and equilibrium studies for the coordination of cyanide or sulfur dioxide to the cobalt(II) tetrasulfophthalocyanine ([CoTSPc]4−) complex are reported. The equilibrium constant for the coordination of the cyanide under pH 11 conditions and an oxygen atmosphere, and the formation of [(CN−)2Co(III)TSPc]5− species, was found to be 2.1×101 dm3 mol−1 and the rate constant, kf was found to be 7.4 dm3 mol−1 s−1. Similarly, the coordination of SO2 to [CoTSPc]4− occurred with an equilibrium constant of 8.7×101 dm3 mol−1 and a rate constant of 2.1×102 dm3 mol−1 s−1, at pH 11. These rate and equilibrium constants represent the coordination of the second cyanide or sulfur dioxide ligands to the [CoTSPc]4− species. Coordination of the first ligand occurred faster than that of the second ligand in both cases. The coordination is accompanied by the oxidation of the central Co(II) metal with the formation of a Co(III) tetrasulfophthalocyanine species.
- Full Text:
- Date Issued: 2002
Investigation of the bioconversion of constituents of olive effluents for the production of valuable chemical compounds
- Authors: Notshe, Thandiwe Loretta
- Date: 2002
- Subjects: Phenols , Sewage -- Purification , Effluent quality
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4078 , http://hdl.handle.net/10962/d1007446 , Phenols , Sewage -- Purification , Effluent quality
- Description: Olive mill wastewater is produced in large quantities during the production of olive oil and olive production effluents are produced during the processing of olives. This project was planned to find a use for constituents found in olive production wastewater. The task was carried out by first characterizing the olive effluents, then screening microorganisms for growth in the effluents and reduction of the pollutant properties of the effluents. An investigation into the biotransformation of aromatic compounds present in the effluents into useful chemicals, was carried out. The olive production effluents were collected from different stages in the process for treating olive wastewater, viz, a fermentation tank (FB), the surface of a digester (LV) and an evaporation pond (SO). The three effluents were characterized by investigating their phenolic composition. Protocatechuic acid, vanillic acid, syringic acid, hydroxyphenyl acetic acid, coumaric acid and ferulic acid were identified in an olive effluent, FB, using thin layer chromatography (TLC) and High perfomance liquid chromatography (HPLC). Hydroxyphenyl acetic acid constitutes almost 60% of the organics in olive effluent FB. Five bacteria, namely RU-LV1; RU-FBI and RU-FB2; RU-SOI and RU-S02, were isolated from the olive effluents LV, FB and SO respectively. These isolates were found to be halotolerant and were able to grow over a broad temperature and pH range, with the maximum temperature and pH for growth being 28°C and pH 7 respectively. A range of microorganisms were evaluated for their ability to grow and reduce the total phenolic content of the olive effluents. Among these Neurospora crassa showed the highest potential for the biological reduction of total phenolics in olive effluents. Approximately 70% of the total phenolic content was removed by N. crassa. Trametes verscilor, Pseudomonas putida strains, RU-KMI and RU-KM3s, and the bacteria isolated from olive effluents could also degrade the total phenolic content of olive effluents, but to a lesser extent. The ability of the five bacterial isolates to grow and degrade aromatic compounds was assessed by growing them in medium with standard aromatic compounds. RU-L V1 degraded 96%, 100%, 73% and 100% of caffeic acid, protocatechuic acid, p-coumaric acid and vanillic acid respectively. The other isolates degraded caffeic acid and protocatechuic acid, but their ability to degraded p-coumaric acid and vanillic acid was found to be lesser than the ability of RU-LV1 to degrade the same aromatic compounds. Whole cells of RU-LV1 degraded vanillic acid but no metabolic products were observed on HPLC analysis. Resting cells, French pressed extract, cell free extracts and cell debris from RU-LV1 cells induced with vanillic acid degraded vanillic acid, ferulic acid and vanillin at rates higher than those obtained from non-induced cultures. No products were observed during the degradation of vanillic acid. Ferulic acid was converted into vanillic acid by French pressed extract, cell free extract and cell debris of RU-LV1. The maximum yield of vanillic acid as a product (0 .23 mM, 50 %yield) was obtained when cell free extracts of RU-LVI, grown in glucose and induced by vanillic acid, were used for the degradation of 0.4 mM ferulic acid. Vanillin was rapidly converted into vanillic acid by resting cells, cell free extracts and French pressed extract of RU-LVI. Using molecular techniques, the similarity ranking of the RU-LVI 16S rRNA gene and its clone showed a high similarity to Corynebacterium glutamicum and Corynebacterium acedopltilum. The rapid degradation of vanillin to vanillic acid suggests that extracts from RU-LV1 degrade ferulic acid into vanillin which is immediately oxidized to vanillic acid. Vanillic acid is also considered as a high value chemical. This project has a potential of producing useful chemicals from cheap substrates that can be found in olive effluents. , KMBT_363
- Full Text:
- Date Issued: 2002
- Authors: Notshe, Thandiwe Loretta
- Date: 2002
- Subjects: Phenols , Sewage -- Purification , Effluent quality
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4078 , http://hdl.handle.net/10962/d1007446 , Phenols , Sewage -- Purification , Effluent quality
- Description: Olive mill wastewater is produced in large quantities during the production of olive oil and olive production effluents are produced during the processing of olives. This project was planned to find a use for constituents found in olive production wastewater. The task was carried out by first characterizing the olive effluents, then screening microorganisms for growth in the effluents and reduction of the pollutant properties of the effluents. An investigation into the biotransformation of aromatic compounds present in the effluents into useful chemicals, was carried out. The olive production effluents were collected from different stages in the process for treating olive wastewater, viz, a fermentation tank (FB), the surface of a digester (LV) and an evaporation pond (SO). The three effluents were characterized by investigating their phenolic composition. Protocatechuic acid, vanillic acid, syringic acid, hydroxyphenyl acetic acid, coumaric acid and ferulic acid were identified in an olive effluent, FB, using thin layer chromatography (TLC) and High perfomance liquid chromatography (HPLC). Hydroxyphenyl acetic acid constitutes almost 60% of the organics in olive effluent FB. Five bacteria, namely RU-LV1; RU-FBI and RU-FB2; RU-SOI and RU-S02, were isolated from the olive effluents LV, FB and SO respectively. These isolates were found to be halotolerant and were able to grow over a broad temperature and pH range, with the maximum temperature and pH for growth being 28°C and pH 7 respectively. A range of microorganisms were evaluated for their ability to grow and reduce the total phenolic content of the olive effluents. Among these Neurospora crassa showed the highest potential for the biological reduction of total phenolics in olive effluents. Approximately 70% of the total phenolic content was removed by N. crassa. Trametes verscilor, Pseudomonas putida strains, RU-KMI and RU-KM3s, and the bacteria isolated from olive effluents could also degrade the total phenolic content of olive effluents, but to a lesser extent. The ability of the five bacterial isolates to grow and degrade aromatic compounds was assessed by growing them in medium with standard aromatic compounds. RU-L V1 degraded 96%, 100%, 73% and 100% of caffeic acid, protocatechuic acid, p-coumaric acid and vanillic acid respectively. The other isolates degraded caffeic acid and protocatechuic acid, but their ability to degraded p-coumaric acid and vanillic acid was found to be lesser than the ability of RU-LV1 to degrade the same aromatic compounds. Whole cells of RU-LV1 degraded vanillic acid but no metabolic products were observed on HPLC analysis. Resting cells, French pressed extract, cell free extracts and cell debris from RU-LV1 cells induced with vanillic acid degraded vanillic acid, ferulic acid and vanillin at rates higher than those obtained from non-induced cultures. No products were observed during the degradation of vanillic acid. Ferulic acid was converted into vanillic acid by French pressed extract, cell free extract and cell debris of RU-LV1. The maximum yield of vanillic acid as a product (0 .23 mM, 50 %yield) was obtained when cell free extracts of RU-LVI, grown in glucose and induced by vanillic acid, were used for the degradation of 0.4 mM ferulic acid. Vanillin was rapidly converted into vanillic acid by resting cells, cell free extracts and French pressed extract of RU-LVI. Using molecular techniques, the similarity ranking of the RU-LVI 16S rRNA gene and its clone showed a high similarity to Corynebacterium glutamicum and Corynebacterium acedopltilum. The rapid degradation of vanillin to vanillic acid suggests that extracts from RU-LV1 degrade ferulic acid into vanillin which is immediately oxidized to vanillic acid. Vanillic acid is also considered as a high value chemical. This project has a potential of producing useful chemicals from cheap substrates that can be found in olive effluents. , KMBT_363
- Full Text:
- Date Issued: 2002
Iron perchlorophthalocyanine and tetrasulfophthalocyanine catalyzed oxidation of cyclohexane using hydrogen peroxide, chloroperoxybenzoic acid and tert-butylhydroperoxide as oxidants
- Grootboom, Natasha, Nyokong, Tebello
- Authors: Grootboom, Natasha , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289606 , vital:56653 , xlink:href="https://doi.org/10.1016/S1381-1169(01)00404-6"
- Description: Polychlorophthalocyanine (Cl16PcFeII) and tetrasulfophthalocyanine ([FeIITSPc]4−) complexes of iron are employed as catalysts for the oxidation of cyclohexane using tert-butyl hydroperoxide (TBHP), m-chloroperoxybenzoic acid (m-CPBA) and hydrogen peroxide as oxidants. Catalysis using the Cl16PcFeII was performed in a dimethylformamide:dichloromethane (3:7) solvent mixture. For the [FeIITSPc]4−catalyst, a water:methanol (1:9) mixture was employed. The products of the catalysis are cyclohexanone, cyclohexanol and cyclohexanediol. The relative yields of the products depended on oxidant and the catalyst. TBHP was found to be the best oxidant since minimal destruction of the catalyst and higher selectivity in the products were observed when this oxidant was employed. The mechanism of the oxidation of cyclohexane in the presence of the Cl16PcFeII and [FeIITSPc]4− involves the oxidation of these catalysts, forming an Fe(III) phthalocyanine species as an intermediate. Higher yields were observed when [FeTSPc]4− was employed as a catalyst, which is more soluble than the perchlorinated iron phthalocyanine catalyst.
- Full Text:
- Date Issued: 2002
- Authors: Grootboom, Natasha , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289606 , vital:56653 , xlink:href="https://doi.org/10.1016/S1381-1169(01)00404-6"
- Description: Polychlorophthalocyanine (Cl16PcFeII) and tetrasulfophthalocyanine ([FeIITSPc]4−) complexes of iron are employed as catalysts for the oxidation of cyclohexane using tert-butyl hydroperoxide (TBHP), m-chloroperoxybenzoic acid (m-CPBA) and hydrogen peroxide as oxidants. Catalysis using the Cl16PcFeII was performed in a dimethylformamide:dichloromethane (3:7) solvent mixture. For the [FeIITSPc]4−catalyst, a water:methanol (1:9) mixture was employed. The products of the catalysis are cyclohexanone, cyclohexanol and cyclohexanediol. The relative yields of the products depended on oxidant and the catalyst. TBHP was found to be the best oxidant since minimal destruction of the catalyst and higher selectivity in the products were observed when this oxidant was employed. The mechanism of the oxidation of cyclohexane in the presence of the Cl16PcFeII and [FeIITSPc]4− involves the oxidation of these catalysts, forming an Fe(III) phthalocyanine species as an intermediate. Higher yields were observed when [FeTSPc]4− was employed as a catalyst, which is more soluble than the perchlorinated iron phthalocyanine catalyst.
- Full Text:
- Date Issued: 2002
Issues in contemporary geographical hydrology
- Authors: Hughes, Denis A
- Date: 2002
- Language: English
- Type: text , Article
- Identifier: vital:7083 , http://hdl.handle.net/10962/d1012340
- Description: Finding solutions to the many water resource utilisation problems that face South Africa has been the driving force behind a large part of the hydrological research that has been undertaken in the country. Any review of the methodology and past or present issues of hydrology in South Africa would find it difficult to distinguish between those that are part of engineering hydrology, and those that are part of geographical hydrology. Both have a great deal to contribute to solving the water resource management problems of South Africa and these contributions should be made in a co-operative framework. As will be demonstrated in the paper, the changing face of South Africa and the requirements of managing water in a transformed, democratic society have made the need for co-operation across various disciplines even more essential.
- Full Text: false
- Date Issued: 2002
- Authors: Hughes, Denis A
- Date: 2002
- Language: English
- Type: text , Article
- Identifier: vital:7083 , http://hdl.handle.net/10962/d1012340
- Description: Finding solutions to the many water resource utilisation problems that face South Africa has been the driving force behind a large part of the hydrological research that has been undertaken in the country. Any review of the methodology and past or present issues of hydrology in South Africa would find it difficult to distinguish between those that are part of engineering hydrology, and those that are part of geographical hydrology. Both have a great deal to contribute to solving the water resource management problems of South Africa and these contributions should be made in a co-operative framework. As will be demonstrated in the paper, the changing face of South Africa and the requirements of managing water in a transformed, democratic society have made the need for co-operation across various disciplines even more essential.
- Full Text: false
- Date Issued: 2002
John Jolly : the Grahamstown bell founder
- Authors: Lewis, Colin A
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6173 , http://hdl.handle.net/10962/d1012364 , http://www.ringingworld.co.uk
- Description: Colin Lewis was Professor of Geography at Rhodes University, Grahamstown, South Africa from 1989 until his retirement at the end of 2007. In 1990, with the strong support of the incumbent Vice-Chancellor, Dr Derek Henderson, he instigated the Certificate in Change Ringing (Church Bell Ringing) in the Rhodes University Department of Music and Musicology - the first such course to be offered in Africa. Since that date he has lectured in the basic theory, and taught the practice of change ringing. He is the Ringing Master of the Cathedral of St Michael and St George, Grahamstown, South Africa.
- Full Text:
- Date Issued: 2002
- Authors: Lewis, Colin A
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6173 , http://hdl.handle.net/10962/d1012364 , http://www.ringingworld.co.uk
- Description: Colin Lewis was Professor of Geography at Rhodes University, Grahamstown, South Africa from 1989 until his retirement at the end of 2007. In 1990, with the strong support of the incumbent Vice-Chancellor, Dr Derek Henderson, he instigated the Certificate in Change Ringing (Church Bell Ringing) in the Rhodes University Department of Music and Musicology - the first such course to be offered in Africa. Since that date he has lectured in the basic theory, and taught the practice of change ringing. He is the Ringing Master of the Cathedral of St Michael and St George, Grahamstown, South Africa.
- Full Text:
- Date Issued: 2002
Knowledge on Sclerocarya birrea subsp. caffra with emphasis on its importance as a non-timber forest product in South and southern Africa, a summary: Part 1 Taxonomy, ecology and role in rural livelihoods
- Shackleton, Sheona E, Shackleton, Charlie M, Cunningham, Tony, Lombard, Cyril, Sullivan, Caroline A, Netshiluvhi, Thiambi
- Authors: Shackleton, Sheona E , Shackleton, Charlie M , Cunningham, Tony , Lombard, Cyril , Sullivan, Caroline A , Netshiluvhi, Thiambi
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182251 , vital:43815 , xlink:href="https://doi.org/10.1080/20702620.2002.10434589"
- Description: Sclerocarya birrea (marula) is a widespread species throughout the semi-arid, deciduous savannas of much of sub-Saharan Africa. It is widely used by rural populations in most countries in which it is found. It has multiple uses, including the fruits, kernels, oil, bark, wood and leaves. Because of these multiple uses, and its significance in the landscape, several African cultures have specific beliefs and ceremonies associated with this species, and it is often maintained in homestead and arable plots. Because of the widespread occurrence, potentially high fruit production and use of S. birrea it has frequently been identified as a key species to support the development of rural enterprises based on the fruit, beer, oil or nuts and therefore as a species for potential domestication. Localised breeding and cultivation initiatives commenced in the 1970s and some continue. Interest in this species was renewed after the development of a highly successful liqueur using extracts from the fruit. This has developed further in southern Africa over the last 3 to 5 years, especially commercialisation initiatives orientated towards befitting the rural poor. Recently, the UK Department for International Development (DFID) initiated a project to examine the impacts of commercialisation of non-timber forest products, such as marula, on the livelihood capital of the rural poor. As a first phase, the research team compiled a comprehensive literature review of S. birrea, with emphasis on possible commercialisation. This is to be published in two parts. The first part deals with the taxonomy, ecology and its subsistence use and cultural value to rural households. The second part of the review will focus on issues relating to specific properties of the marula, management, intellectual property and its potential commercialisation.
- Full Text:
- Date Issued: 2002
- Authors: Shackleton, Sheona E , Shackleton, Charlie M , Cunningham, Tony , Lombard, Cyril , Sullivan, Caroline A , Netshiluvhi, Thiambi
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182251 , vital:43815 , xlink:href="https://doi.org/10.1080/20702620.2002.10434589"
- Description: Sclerocarya birrea (marula) is a widespread species throughout the semi-arid, deciduous savannas of much of sub-Saharan Africa. It is widely used by rural populations in most countries in which it is found. It has multiple uses, including the fruits, kernels, oil, bark, wood and leaves. Because of these multiple uses, and its significance in the landscape, several African cultures have specific beliefs and ceremonies associated with this species, and it is often maintained in homestead and arable plots. Because of the widespread occurrence, potentially high fruit production and use of S. birrea it has frequently been identified as a key species to support the development of rural enterprises based on the fruit, beer, oil or nuts and therefore as a species for potential domestication. Localised breeding and cultivation initiatives commenced in the 1970s and some continue. Interest in this species was renewed after the development of a highly successful liqueur using extracts from the fruit. This has developed further in southern Africa over the last 3 to 5 years, especially commercialisation initiatives orientated towards befitting the rural poor. Recently, the UK Department for International Development (DFID) initiated a project to examine the impacts of commercialisation of non-timber forest products, such as marula, on the livelihood capital of the rural poor. As a first phase, the research team compiled a comprehensive literature review of S. birrea, with emphasis on possible commercialisation. This is to be published in two parts. The first part deals with the taxonomy, ecology and its subsistence use and cultural value to rural households. The second part of the review will focus on issues relating to specific properties of the marula, management, intellectual property and its potential commercialisation.
- Full Text:
- Date Issued: 2002
Language as a ‘resource’ in South Africa: the economic life of language in a globalising society
- Authors: Wright, Laurence
- Date: 2002
- Language: English
- Type: text , article
- Identifier: vital:7035 , http://hdl.handle.net/10962/d1007370 , https://doi.org/10.1080/10131750285310031
- Description: preprint , We need to develop a much more refined and specific understanding of what is meant when people refer to language is a ‘resource’. If something can accurately be described as a resource, then by its very nature it carries with it or attracts, at least in potential, the social motivation associated with the utilization, development or exploitation of that resource. This is strikingly true where language is the resource in question, because language is so intimately bound up with human activity. Where it exists, such social motivation can be augmented and supported so as to realize the ends of language policy. Contrastingly, where it is seen that social motivation informing a particular language situation is at odds with the intent of language policy, then either implementation must retreat and move to other arenas, other points of influence, where intervention can be more effective, or those charged with implementation must resign themselves to costly and messy efforts to force unwanted change through legal authority.
- Full Text:
- Date Issued: 2002
- Authors: Wright, Laurence
- Date: 2002
- Language: English
- Type: text , article
- Identifier: vital:7035 , http://hdl.handle.net/10962/d1007370 , https://doi.org/10.1080/10131750285310031
- Description: preprint , We need to develop a much more refined and specific understanding of what is meant when people refer to language is a ‘resource’. If something can accurately be described as a resource, then by its very nature it carries with it or attracts, at least in potential, the social motivation associated with the utilization, development or exploitation of that resource. This is strikingly true where language is the resource in question, because language is so intimately bound up with human activity. Where it exists, such social motivation can be augmented and supported so as to realize the ends of language policy. Contrastingly, where it is seen that social motivation informing a particular language situation is at odds with the intent of language policy, then either implementation must retreat and move to other arenas, other points of influence, where intervention can be more effective, or those charged with implementation must resign themselves to costly and messy efforts to force unwanted change through legal authority.
- Full Text:
- Date Issued: 2002
Leaders' and participants' perceptions of the management of the Life Science Project in Namibia
- Authors: Kirkegaard, Niels Hugo
- Date: 2002
- Subjects: Life Science Project (Namibia) Educational leadership Educational leadership -- Namibia School management and organization School management and organization -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1662 , http://hdl.handle.net/10962/d1003545
- Description: After Independence in 1991, Namibia embarked on implementing a new and different educational system. This system was seen as a radical departure from the old apartheid system. The Namibian government approached Ibis, a Danish NGO, to support the change process by establishing and developing a new subject, life science, in Junior Secondary schools in Namibia through the Life Science Project (LSP). In a project of this nature, where a foreign (Danish) educational intervention in a relatively young and new democracy is the issue, cross-cultural aspects are likely to emerge, and these are the focus of this study. This half-thesis is an attempt to illuminate, not to evaluate, managerial as well as cross-cultural features of the project based on perceptions of selected Danish managers and Namibian advisory teachers from the former LSP expressed in the goal of the research: - To explore selected leaders’ and participants’ perception of the management of the Life Science Project. In line with this goal, I elected to conduct the research in the interpretive paradigm, using unstructured interviews as my chief source of data. The findings illuminate what would appear to be an inconsistency in the management of the project. The project seemed to be able to accommodate regional and even personal differences and to be flexible to internal changes. At the same time it appears that in its relationship to the external or task environment it did not show the same openness and flexibility to accommodate diversity. It is suggested that this could be a result of the apparent failure on the part of the project to clarify its own underlying values. The study also reveals interesting and unexpected perceptions of leadership, which may also be interpreted in terms of cultural values and beliefs. These two features of managerial issues could lead one to reflect upon the importance of recognising values in organisations which work across cultures.
- Full Text:
- Date Issued: 2002
- Authors: Kirkegaard, Niels Hugo
- Date: 2002
- Subjects: Life Science Project (Namibia) Educational leadership Educational leadership -- Namibia School management and organization School management and organization -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1662 , http://hdl.handle.net/10962/d1003545
- Description: After Independence in 1991, Namibia embarked on implementing a new and different educational system. This system was seen as a radical departure from the old apartheid system. The Namibian government approached Ibis, a Danish NGO, to support the change process by establishing and developing a new subject, life science, in Junior Secondary schools in Namibia through the Life Science Project (LSP). In a project of this nature, where a foreign (Danish) educational intervention in a relatively young and new democracy is the issue, cross-cultural aspects are likely to emerge, and these are the focus of this study. This half-thesis is an attempt to illuminate, not to evaluate, managerial as well as cross-cultural features of the project based on perceptions of selected Danish managers and Namibian advisory teachers from the former LSP expressed in the goal of the research: - To explore selected leaders’ and participants’ perception of the management of the Life Science Project. In line with this goal, I elected to conduct the research in the interpretive paradigm, using unstructured interviews as my chief source of data. The findings illuminate what would appear to be an inconsistency in the management of the project. The project seemed to be able to accommodate regional and even personal differences and to be flexible to internal changes. At the same time it appears that in its relationship to the external or task environment it did not show the same openness and flexibility to accommodate diversity. It is suggested that this could be a result of the apparent failure on the part of the project to clarify its own underlying values. The study also reveals interesting and unexpected perceptions of leadership, which may also be interpreted in terms of cultural values and beliefs. These two features of managerial issues could lead one to reflect upon the importance of recognising values in organisations which work across cultures.
- Full Text:
- Date Issued: 2002
Magma flow inferred from AMS fabrics in a layered mafic sill, Insizwa, South Africa
- Ferré, Eric C, Bordarier, Cecile, Marsh, Julian S
- Authors: Ferré, Eric C , Bordarier, Cecile , Marsh, Julian S
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6733 , http://hdl.handle.net/10962/d1007543
- Description: The Insizwa sill, is a 25-km-diameter, >1000-m-thick layered mafic intrusion, part of the Karoo Igneous Province in South Africa. The peridotitic and gabbronoritic rocks are undeformed and mineral fabrics demonstrably result from magma flow. A horizontal, centimeter-scale model layering is visible in numerous outcrops. Plagioclase crystals are both tabular and elongated. Their preferred orientation, parallel to the layering, forms a foliation and a NW–SE lineation, respectively interpreted as the magma flow plane and flow direction. Throughout the 78 stations of this study (699 specimens), magnetic susceptibilities (K[subscript m]) range from 750 to 10,000×10[superscript (−6)] SI. The magnetic anisotropy (P[subscript j]) ranges from 1.03 to 1.08. Magnetic ellipsoids are both prolate and oblate (average T[subscript j]≈0). Anisotropy of magnetic susceptibility (AMS) fabrics are dominated by multidomain to pseudo-single domain magnetite. High-field magnetic experiments indicate that the paramagnetic contribution from the mafic silicates is less than 50 percentage for low susceptibility rock types. The anisotropy results from magnetite grain shape solely as shown by no significant increase in P[subscript j] with increasing K[subscript m]. The magnetic lineation (305°, 05°) is consistent throughout the sill at various scales and coincides with the mineral lineation in average. In contrast, the magnetic foliation (125° NE 10°) is generally perpendicular to the mineral foliation and to the layering. Several explanations for this odd configuration are discussed. The variations of magnetic parameters across the layering and field observations point to a multiple injection. The magnetic lineation is consistent with the presence of a single feeder dike situated to the SE of the sill.
- Full Text:
- Date Issued: 2002
- Authors: Ferré, Eric C , Bordarier, Cecile , Marsh, Julian S
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6733 , http://hdl.handle.net/10962/d1007543
- Description: The Insizwa sill, is a 25-km-diameter, >1000-m-thick layered mafic intrusion, part of the Karoo Igneous Province in South Africa. The peridotitic and gabbronoritic rocks are undeformed and mineral fabrics demonstrably result from magma flow. A horizontal, centimeter-scale model layering is visible in numerous outcrops. Plagioclase crystals are both tabular and elongated. Their preferred orientation, parallel to the layering, forms a foliation and a NW–SE lineation, respectively interpreted as the magma flow plane and flow direction. Throughout the 78 stations of this study (699 specimens), magnetic susceptibilities (K[subscript m]) range from 750 to 10,000×10[superscript (−6)] SI. The magnetic anisotropy (P[subscript j]) ranges from 1.03 to 1.08. Magnetic ellipsoids are both prolate and oblate (average T[subscript j]≈0). Anisotropy of magnetic susceptibility (AMS) fabrics are dominated by multidomain to pseudo-single domain magnetite. High-field magnetic experiments indicate that the paramagnetic contribution from the mafic silicates is less than 50 percentage for low susceptibility rock types. The anisotropy results from magnetite grain shape solely as shown by no significant increase in P[subscript j] with increasing K[subscript m]. The magnetic lineation (305°, 05°) is consistent throughout the sill at various scales and coincides with the mineral lineation in average. In contrast, the magnetic foliation (125° NE 10°) is generally perpendicular to the mineral foliation and to the layering. Several explanations for this odd configuration are discussed. The variations of magnetic parameters across the layering and field observations point to a multiple injection. The magnetic lineation is consistent with the presence of a single feeder dike situated to the SE of the sill.
- Full Text:
- Date Issued: 2002
Mandendende
- Venda men and boys, Tracey, Andrew T N
- Authors: Venda men and boys , Tracey, Andrew T N
- Date: 2002
- Subjects: Venda, (African people) , Folk dancing, Venda , Reed pipes (Organ pipes) , Drum , Instrumental music , Sub-Saharan African music , Africa South Africa Venda f-sa
- Language: Venda
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/112125 , vital:33550 , International Library of African Music, Rhodes University, Grahamstown, South Africa , ATC126a-05
- Description: Instrumental Venda Tshikona reed pipe dance music.
- Full Text: false
- Date Issued: 2002
- Authors: Venda men and boys , Tracey, Andrew T N
- Date: 2002
- Subjects: Venda, (African people) , Folk dancing, Venda , Reed pipes (Organ pipes) , Drum , Instrumental music , Sub-Saharan African music , Africa South Africa Venda f-sa
- Language: Venda
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/112125 , vital:33550 , International Library of African Music, Rhodes University, Grahamstown, South Africa , ATC126a-05
- Description: Instrumental Venda Tshikona reed pipe dance music.
- Full Text: false
- Date Issued: 2002
Mandendende vanachiambela
- Venda boys, Tracey, Andrew T N
- Authors: Venda boys , Tracey, Andrew T N
- Date: 2002
- Subjects: Venda --(African people) , Folk dancing, Venda , Folk dance music , Sub-Saharan African music , Africa South Africa Venda f-sa
- Language: Venda
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/112134 , vital:33551 , International Library of African Music, Rhodes University, Grahamstown, South Africa , ATC126a-06
- Description: Unaccompanied traditional Venda Tshikona dance song.
- Full Text: false
- Date Issued: 2002
- Authors: Venda boys , Tracey, Andrew T N
- Date: 2002
- Subjects: Venda --(African people) , Folk dancing, Venda , Folk dance music , Sub-Saharan African music , Africa South Africa Venda f-sa
- Language: Venda
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/112134 , vital:33551 , International Library of African Music, Rhodes University, Grahamstown, South Africa , ATC126a-06
- Description: Unaccompanied traditional Venda Tshikona dance song.
- Full Text: false
- Date Issued: 2002
Maybe the courts are not such a Bleak House after all - or please sir, I want some more copyright
- Authors: Glover, Graham B
- Date: 2002
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70841 , vital:29749 , https://heinonline.org/HOL/P?h=hein.journals/soaf119&i=101
- Description: In our advanced technological age the law of copyright faces tremendous challenges. In particular, the Internet has created serious problems for those who wish to enforce their proprietary rights, and to protect their textual (and other) creations from unregulated and uninhibited reproduction.
- Full Text: false
- Date Issued: 2002
- Authors: Glover, Graham B
- Date: 2002
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70841 , vital:29749 , https://heinonline.org/HOL/P?h=hein.journals/soaf119&i=101
- Description: In our advanced technological age the law of copyright faces tremendous challenges. In particular, the Internet has created serious problems for those who wish to enforce their proprietary rights, and to protect their textual (and other) creations from unregulated and uninhibited reproduction.
- Full Text: false
- Date Issued: 2002
Melatonin protects against copper‐mediated free radical damage
- Parmar, Paresh, Limson, Janice L, Nyokong, Tebello, Daya, Santy
- Authors: Parmar, Paresh , Limson, Janice L , Nyokong, Tebello , Daya, Santy
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289617 , vital:56654 , xlink:href=" https://doi.org/10.1034/j.1600-079X.2002.01859.x"
- Description: Copper is an essential trace element which forms an integral component of many enzymes. While trace amounts of copper are needed to sustain life, excess copper is extremely toxic. Copper has been implicated in various neurodegenerative disorders, such as Wilson's and Alzheimer's diseases. Previous studies showed that melatonin, the principle secretory product of the pineal gland, binds Cupric chloride (Cu2+) and that this may have implications in copper-induced neurodegenerative diseases. In the present study, in vitro copper-mediated lipid peroxidation was induced. Melatonin (5 mM) protected against copper-mediated lipid peroxidation in liver homogenates. Electron micrographs of in vivo administered Cu2+ and melatonin show that melatonin affords some protection to rat hepatocytes in the presence of copper. Electrochemical studies performed show that melatonin, in addition to binding Cu2+, may provide protection against copper-mediated free radical damage by binding Cu1+. The findings of these studies provide further evidence for the neuroprotective role of melatonin.
- Full Text:
- Date Issued: 2002
- Authors: Parmar, Paresh , Limson, Janice L , Nyokong, Tebello , Daya, Santy
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289617 , vital:56654 , xlink:href=" https://doi.org/10.1034/j.1600-079X.2002.01859.x"
- Description: Copper is an essential trace element which forms an integral component of many enzymes. While trace amounts of copper are needed to sustain life, excess copper is extremely toxic. Copper has been implicated in various neurodegenerative disorders, such as Wilson's and Alzheimer's diseases. Previous studies showed that melatonin, the principle secretory product of the pineal gland, binds Cupric chloride (Cu2+) and that this may have implications in copper-induced neurodegenerative diseases. In the present study, in vitro copper-mediated lipid peroxidation was induced. Melatonin (5 mM) protected against copper-mediated lipid peroxidation in liver homogenates. Electron micrographs of in vivo administered Cu2+ and melatonin show that melatonin affords some protection to rat hepatocytes in the presence of copper. Electrochemical studies performed show that melatonin, in addition to binding Cu2+, may provide protection against copper-mediated free radical damage by binding Cu1+. The findings of these studies provide further evidence for the neuroprotective role of melatonin.
- Full Text:
- Date Issued: 2002
Mental illness and the consciousness of freedom: the phenomenology of psychiatric labelling
- Authors: Bradfield, Bruce
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6264 , http://hdl.handle.net/10962/d1007882
- Description: Paradigmatically led by existential phenomenological premises, as formulated by Jean-Paul Sartre and Edmund Husserl specifically, this paper aims at a deconstruction of the value of psychiatric labelling in terms of the implications of such labelling for the labelled individual's experience of freedom as a conscious imperative. This work has as its intention the destabilisation of labelling as a stubborn and inexorable mechanism for social propriety and regularity, which in its unyielding classificatory brandings is.
- Full Text:
- Date Issued: 2002
- Authors: Bradfield, Bruce
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6264 , http://hdl.handle.net/10962/d1007882
- Description: Paradigmatically led by existential phenomenological premises, as formulated by Jean-Paul Sartre and Edmund Husserl specifically, this paper aims at a deconstruction of the value of psychiatric labelling in terms of the implications of such labelling for the labelled individual's experience of freedom as a conscious imperative. This work has as its intention the destabilisation of labelling as a stubborn and inexorable mechanism for social propriety and regularity, which in its unyielding classificatory brandings is.
- Full Text:
- Date Issued: 2002
Metabolic responses to various combinations of gradient, load and marching speed
- Todd, Andrew I, Scott, Patricia A
- Authors: Todd, Andrew I , Scott, Patricia A
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6751 , http://hdl.handle.net/10962/d1009331
- Description: This study examined the metabolic cost of South African soldiers carrying loads under various conditions of gradient and marching speed. Thirty-two male soldiers participated in the study. Three speed and load combinations, 4, 5 and 6 km.h[superscript (-1)] carrying of 50, 35 and 20 kg respectively, were imposed, on each of three gradients: -10%, 0% and +10%; a total of nine experimental conditions. Subjects wore standardized military uniforms and breathed into a portable ergospirometer (Metamax) for the duration of each condition. Subjects were required to march for six minutes under each condition, and metabolic responses were monitored during the third and sixth minute of each condition. The metabolic responses to the three level marching conditions showed no significant differences. Marching uphill resulted in a significant increase in metabolic demands under all three speed and load onditions. Downhill marching elicited significant decreases only under the two lighter load conditions. Downhill marching with heavy loads appears to show no reduction in metabolic demands placed on soldiers.
- Full Text:
- Date Issued: 2002
- Authors: Todd, Andrew I , Scott, Patricia A
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6751 , http://hdl.handle.net/10962/d1009331
- Description: This study examined the metabolic cost of South African soldiers carrying loads under various conditions of gradient and marching speed. Thirty-two male soldiers participated in the study. Three speed and load combinations, 4, 5 and 6 km.h[superscript (-1)] carrying of 50, 35 and 20 kg respectively, were imposed, on each of three gradients: -10%, 0% and +10%; a total of nine experimental conditions. Subjects wore standardized military uniforms and breathed into a portable ergospirometer (Metamax) for the duration of each condition. Subjects were required to march for six minutes under each condition, and metabolic responses were monitored during the third and sixth minute of each condition. The metabolic responses to the three level marching conditions showed no significant differences. Marching uphill resulted in a significant increase in metabolic demands under all three speed and load onditions. Downhill marching elicited significant decreases only under the two lighter load conditions. Downhill marching with heavy loads appears to show no reduction in metabolic demands placed on soldiers.
- Full Text:
- Date Issued: 2002