Does 'African mathematics' facilitate access to mathematics?: towards an ongoing critical analysis of ethnomathematics in a South African context
- Horsthemke, Kai, Schäfer, Marc
- Authors: Horsthemke, Kai , Schäfer, Marc
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141004 , vital:37936 , https://0-hdl.handle.net.wam.seals.ac.za/10520/EJC20885
- Description: Mosibudi Mangena, the Minister of Science and Technology, said in an address to the Annual Congress of the South African Mathematical Society at the University of the Potchefstroom, November 2, 2004: "There is one thing we need to address before anything else. We need to increase the number of young people, particularly blacks and women, who are able to successfully complete the first course in Mathematics at our universities." How is this to be achieved? A popular trend involves a call for the introduction and incorporation of so-called ethnomathematics, and more particularly 'African mathematics', into secondary and tertiary curricula. Although acknowledging the obvious benefits of so-called ethnomathematics, this paper critically analyses three aspects of ethnomathematics that have been neglected in past critiques. Our focus is not on the relationship as such between ethnomathematics and mathematics education. Our critique involves (1) epistemological and logical misgivings, (2) a new look at practices and skills, (3) concerns about embracing 'African mathematics' as valid and valuable - just because it is African.
- Full Text:
- Date Issued: 2007
- Authors: Horsthemke, Kai , Schäfer, Marc
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141004 , vital:37936 , https://0-hdl.handle.net.wam.seals.ac.za/10520/EJC20885
- Description: Mosibudi Mangena, the Minister of Science and Technology, said in an address to the Annual Congress of the South African Mathematical Society at the University of the Potchefstroom, November 2, 2004: "There is one thing we need to address before anything else. We need to increase the number of young people, particularly blacks and women, who are able to successfully complete the first course in Mathematics at our universities." How is this to be achieved? A popular trend involves a call for the introduction and incorporation of so-called ethnomathematics, and more particularly 'African mathematics', into secondary and tertiary curricula. Although acknowledging the obvious benefits of so-called ethnomathematics, this paper critically analyses three aspects of ethnomathematics that have been neglected in past critiques. Our focus is not on the relationship as such between ethnomathematics and mathematics education. Our critique involves (1) epistemological and logical misgivings, (2) a new look at practices and skills, (3) concerns about embracing 'African mathematics' as valid and valuable - just because it is African.
- Full Text:
- Date Issued: 2007
Editorial, 2007
- Lotz-Sisitka, Heila, O’Donoghue, Rob, Robottom, Ian
- Authors: Lotz-Sisitka, Heila , O’Donoghue, Rob , Robottom, Ian
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67345 , vital:29078 , https://www.ajol.info/index.php/sajee/article/view/122733
- Description: publisher version , The year 2007 is a significant year for environmental education. It marks 30 years since the first internationally agreed principles of environmental education were developed at Tbilisi, commonly known as the Tbilisi Principles. It is also the year in which human beings apparently are finally ‘waking up’ to the fact that human-induced environmental change is causing impacts which are infinitely complex and difficult to resolve. This year, through various highly publicised and politicised events, people have begun to recognise that it is getting hot on planet Earth, and that the associated social, economic and environmental costs are profoundly disturbing. The Stern Review and the UN Intergovernmental Panel on Climate Change both firmly indicated that human-induced environmental change will threaten human economies and security in ways that are unprecedented in human history.
- Full Text:
- Date Issued: 2007
- Authors: Lotz-Sisitka, Heila , O’Donoghue, Rob , Robottom, Ian
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67345 , vital:29078 , https://www.ajol.info/index.php/sajee/article/view/122733
- Description: publisher version , The year 2007 is a significant year for environmental education. It marks 30 years since the first internationally agreed principles of environmental education were developed at Tbilisi, commonly known as the Tbilisi Principles. It is also the year in which human beings apparently are finally ‘waking up’ to the fact that human-induced environmental change is causing impacts which are infinitely complex and difficult to resolve. This year, through various highly publicised and politicised events, people have begun to recognise that it is getting hot on planet Earth, and that the associated social, economic and environmental costs are profoundly disturbing. The Stern Review and the UN Intergovernmental Panel on Climate Change both firmly indicated that human-induced environmental change will threaten human economies and security in ways that are unprecedented in human history.
- Full Text:
- Date Issued: 2007
Education is a spring … it bubbles:
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159288 , vital:40284 , https://hdl.handle.net/10520/EJC144678
- Description: Asians, Americans, Australians. A handful of Africans and a couple of Arabs. A sprinkling of Canadians, Mexicans, Finns. An Israeli, a Chilean and quite a few others. In total, 450 people from some 50 countries. In common: they're all lecturers and trainers. Busy swopping notes in Singapore at the first-ever World Journalism Education Congress (WJEC) in July. It's a resource-rich pool of ideas and experiences.
- Full Text:
- Date Issued: 2007
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159288 , vital:40284 , https://hdl.handle.net/10520/EJC144678
- Description: Asians, Americans, Australians. A handful of Africans and a couple of Arabs. A sprinkling of Canadians, Mexicans, Finns. An Israeli, a Chilean and quite a few others. In total, 450 people from some 50 countries. In common: they're all lecturers and trainers. Busy swopping notes in Singapore at the first-ever World Journalism Education Congress (WJEC) in July. It's a resource-rich pool of ideas and experiences.
- Full Text:
- Date Issued: 2007
Electroanalysis of thiocyanate using a novel glassy carbon electrode modified by aryl radicals and cobalt tetracarboxyphthalocyanine
- Matemadombo, Fungisai, Westbroek, Philippe, Nyokong, Tebello
- Authors: Matemadombo, Fungisai , Westbroek, Philippe , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268750 , vital:54228 , xlink:href="https://doi.org/10.1016/j.electacta.2007.06.064"
- Description: Electrochemical grafting of 4-nitrobenzenediazonium tetrafluoroborate onto a glassy carbon electrode (GCE) results in the formation of a nitrophenyl radical, which reacts with the surface to form a covalent bond (grafting) and results in a nitrophenyl modified electrode. The nitro group is electrochemically reduced to a NH2 group. Cobalt tetracarboxyphthalocyanine (CoTCPc) complex is then attached to the NH2 group using 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide (EDC) and N-hydroxysuccinimide (NHS) as coupling agents. The new CoTCPc modified electrode was characterized using cyclic voltammetry and then employed for the catalytic oxidation of thiocyanate.
- Full Text:
- Date Issued: 2007
- Authors: Matemadombo, Fungisai , Westbroek, Philippe , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268750 , vital:54228 , xlink:href="https://doi.org/10.1016/j.electacta.2007.06.064"
- Description: Electrochemical grafting of 4-nitrobenzenediazonium tetrafluoroborate onto a glassy carbon electrode (GCE) results in the formation of a nitrophenyl radical, which reacts with the surface to form a covalent bond (grafting) and results in a nitrophenyl modified electrode. The nitro group is electrochemically reduced to a NH2 group. Cobalt tetracarboxyphthalocyanine (CoTCPc) complex is then attached to the NH2 group using 1-ethyl-3-(3-dimethylaminopropyl)-carbodiimide (EDC) and N-hydroxysuccinimide (NHS) as coupling agents. The new CoTCPc modified electrode was characterized using cyclic voltammetry and then employed for the catalytic oxidation of thiocyanate.
- Full Text:
- Date Issued: 2007
Electrocatalytic activity of arylthio tetra-substituted oxotitanium (IV) phthalocyanines towards the oxidation of nitrite
- Tau, Prudence, Nyokong, Tebello
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281234 , vital:55704 , xlink:href="https://doi.org/10.1016/j.electacta.2006.12.059"
- Description: This paper investigates the catalytic activities of arylthio substituted oxotitanium phthalocyanine (OTiPc) complexes that are immobilized on the glassy carbon electrode by electropolymerization, towards the oxidation of nitrite. The complexes are peripherally and non-peripherally substituted with phenylthio and benzylthio groups, namely 1a, 1b, 2a and 2b. All the modified electrodes exhibited improved electrocatalytic oxidation of nitrite than the unmodified electrodes by a two-electron mechanism producing nitrate ions. Catalytic currents are enhanced and nitrite overpotential reduced to ∼0.60 V. Kinetic parameters are determined for all complexes and a mechanism is proposed.
- Full Text:
- Date Issued: 2007
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281234 , vital:55704 , xlink:href="https://doi.org/10.1016/j.electacta.2006.12.059"
- Description: This paper investigates the catalytic activities of arylthio substituted oxotitanium phthalocyanine (OTiPc) complexes that are immobilized on the glassy carbon electrode by electropolymerization, towards the oxidation of nitrite. The complexes are peripherally and non-peripherally substituted with phenylthio and benzylthio groups, namely 1a, 1b, 2a and 2b. All the modified electrodes exhibited improved electrocatalytic oxidation of nitrite than the unmodified electrodes by a two-electron mechanism producing nitrate ions. Catalytic currents are enhanced and nitrite overpotential reduced to ∼0.60 V. Kinetic parameters are determined for all complexes and a mechanism is proposed.
- Full Text:
- Date Issued: 2007
Electrocatalytic oxidation of chlorophenols by electropolymerised nickel (II) tetrakis benzylmercapto and dodecylmercapto metallophthalocyanines complexes on gold electrodes
- Agboola, Bolade, Nyokong, Tebello
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281247 , vital:55705 , xlink:href="https://doi.org/10.1016/j.electacta.2007.02.017"
- Description: This work reports on the use of nickel(II) tetrakis benzylmercapto (NiTBMPc) and dodecylmercapto (NiTDMPc) metallophthalocyanine complexes films on gold electrodes for the electrochemical oxidation of 4-chlorophenol (4-CP) and 2,4,5-trichlorophenol (TCP). Both NiTBMPc and NiTDMPc complexes were successfully deposited on gold electrodes by electropolymerisation. The films were electro-transformed in aqueous 0.1 M NaOH solution to the ‘O–Ni–O oxo’ bridged form. For both complexes, films with different thickness were prepared and characterised by electrochemical impedance and UV–vis (on indium tin oxide) spectroscopies and the results showed typical behaviour for modified electrodes with increasing charge transfer resistance values (Rp) with polymer thickness. The poly-Ni(OH)NiPcs showed better catalytic activity than their poly-NiPcs counterparts.
- Full Text:
- Date Issued: 2007
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281247 , vital:55705 , xlink:href="https://doi.org/10.1016/j.electacta.2007.02.017"
- Description: This work reports on the use of nickel(II) tetrakis benzylmercapto (NiTBMPc) and dodecylmercapto (NiTDMPc) metallophthalocyanine complexes films on gold electrodes for the electrochemical oxidation of 4-chlorophenol (4-CP) and 2,4,5-trichlorophenol (TCP). Both NiTBMPc and NiTDMPc complexes were successfully deposited on gold electrodes by electropolymerisation. The films were electro-transformed in aqueous 0.1 M NaOH solution to the ‘O–Ni–O oxo’ bridged form. For both complexes, films with different thickness were prepared and characterised by electrochemical impedance and UV–vis (on indium tin oxide) spectroscopies and the results showed typical behaviour for modified electrodes with increasing charge transfer resistance values (Rp) with polymer thickness. The poly-Ni(OH)NiPcs showed better catalytic activity than their poly-NiPcs counterparts.
- Full Text:
- Date Issued: 2007
Electrocatalytic oxidation of nitrite by tetra-substituted oxotitanium (IV) phthalocyanines adsorbed or polymerised on glassy carbon electrode
- Tau, Prudence, Nyokong, Tebello
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268762 , vital:54230 , xlink:href="https://doi.org/10.1016/j.jelechem.2007.07.019"
- Description: Comparative electrocatalytic oxidation of nitrite by tetra aryloxy-substituted oxotitanium(IV) and tetraamino phthalocyanine complexes is investigated in this work. The aryloxy complexes are substituted at the peripheral (4) and non-peripheral (5) positions with phenoxy (complexes a), 4-tert-butylphenoxy (complexes b), benzyloxy (complexes c) and 4-(benzyloxy)phenoxy (complexes d) groups. The glassy carbon electrode was employed and modified with the tetra aryloxy-substituted titanium phthalocyanine complexes (4 and 5) by adsorption, and with titanium tetraamino phthalocyanine (TiTAPc) by polymerisation. All complexes reduced the overpotential of the nitrite electrooxidation as well as enhanced the catalytic current by a 2 electron process.
- Full Text:
- Date Issued: 2007
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268762 , vital:54230 , xlink:href="https://doi.org/10.1016/j.jelechem.2007.07.019"
- Description: Comparative electrocatalytic oxidation of nitrite by tetra aryloxy-substituted oxotitanium(IV) and tetraamino phthalocyanine complexes is investigated in this work. The aryloxy complexes are substituted at the peripheral (4) and non-peripheral (5) positions with phenoxy (complexes a), 4-tert-butylphenoxy (complexes b), benzyloxy (complexes c) and 4-(benzyloxy)phenoxy (complexes d) groups. The glassy carbon electrode was employed and modified with the tetra aryloxy-substituted titanium phthalocyanine complexes (4 and 5) by adsorption, and with titanium tetraamino phthalocyanine (TiTAPc) by polymerisation. All complexes reduced the overpotential of the nitrite electrooxidation as well as enhanced the catalytic current by a 2 electron process.
- Full Text:
- Date Issued: 2007
Electrochemical and photophysical characterization of non-peripherally-octaalkyl substituted dichlorotin (IV) phthalocyanine and tetrabenzotriazaporphyrin compounds
- Khene, Samson M, Cammidge, Andrew N, Cook, Michael J, Nyokong, Tebello
- Authors: Khene, Samson M , Cammidge, Andrew N , Cook, Michael J , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271216 , vital:54522 , xlink:href="https://doi.org/10.1142/S1088424607000886"
- Description: Three non-peripherally substituted tin(IV) macrocylic compounds, octahexylphthalocyaninato dichlorotin(IV) (3a), octahexyltetrabenzo-5,10,15- triazaporphyrinato dichlorotin(IV) (3b) and octadecylphthalocyaninato dichlorotin(IV) (3c) were synthesized and their photophysical and electrochemical behavior studied. Complex 3b, containing a CH group in place of one of the aza nitrogen atoms of the phthalocyanine core, shows a split Q-band due to its lower symmetry. The triplet state quantum yields were found to be lower than would be expected on the basis of the heavy atom effect of tin as the central metal for phthalocyanine derivatives (3a and 3c). In contrast, 3b shows a triplet quantum yield ΦT = 0.78. The triplet state lifetimes were solvent dependent, and were higher in tetrahydrofuran than in toluene. Cyclic voltammetry and spectroelectrochemistry of the complexes revealed only ring-based redox processes.
- Full Text:
- Date Issued: 2007
- Authors: Khene, Samson M , Cammidge, Andrew N , Cook, Michael J , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271216 , vital:54522 , xlink:href="https://doi.org/10.1142/S1088424607000886"
- Description: Three non-peripherally substituted tin(IV) macrocylic compounds, octahexylphthalocyaninato dichlorotin(IV) (3a), octahexyltetrabenzo-5,10,15- triazaporphyrinato dichlorotin(IV) (3b) and octadecylphthalocyaninato dichlorotin(IV) (3c) were synthesized and their photophysical and electrochemical behavior studied. Complex 3b, containing a CH group in place of one of the aza nitrogen atoms of the phthalocyanine core, shows a split Q-band due to its lower symmetry. The triplet state quantum yields were found to be lower than would be expected on the basis of the heavy atom effect of tin as the central metal for phthalocyanine derivatives (3a and 3c). In contrast, 3b shows a triplet quantum yield ΦT = 0.78. The triplet state lifetimes were solvent dependent, and were higher in tetrahydrofuran than in toluene. Cyclic voltammetry and spectroelectrochemistry of the complexes revealed only ring-based redox processes.
- Full Text:
- Date Issued: 2007
Enabling and constraining ICT practice in secondary schools: case studies in South Africa
- Hodgkinson-Williams, Cheryl, Siebörger, Ingrid, Terzoli, Alfredo
- Authors: Hodgkinson-Williams, Cheryl , Siebörger, Ingrid , Terzoli, Alfredo
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428923 , vital:72546 , https://www.inderscienceonline.com/doi/epdf/10.1504/IJKL.2007.015551
- Description: The use of Information Communication Technology (ICT) in education is being seen as a way of widening access to education, particularly in developing countries. This paper addresses the issue of ICT implemen-tation in secondary schools and focuses specifically on the practices that enable or constrain the successful implementation of ICT for teach-ing and learning activities. It reflects upon the lessons learned from a collective case study undertaken in 12 of the 13 secondary schools in Grahamstown in the Eastern Cape in South Africa. School principals and designated IT teachers were interviewed and on-site infrastructure audits conducted. This paper identifies a number of key enabling and constraining factors surrounding practical issues, including sufficient hardware, appropriate software and affordable connectivity, sufficient technical support and training, policy-related issues such as the role of national, provincial and school policy, the vital contribution of principal leadership and champion teachers as well as ongoing teacher profes-sional development coupled with a willingness to change.
- Full Text:
- Date Issued: 2007
- Authors: Hodgkinson-Williams, Cheryl , Siebörger, Ingrid , Terzoli, Alfredo
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428923 , vital:72546 , https://www.inderscienceonline.com/doi/epdf/10.1504/IJKL.2007.015551
- Description: The use of Information Communication Technology (ICT) in education is being seen as a way of widening access to education, particularly in developing countries. This paper addresses the issue of ICT implemen-tation in secondary schools and focuses specifically on the practices that enable or constrain the successful implementation of ICT for teach-ing and learning activities. It reflects upon the lessons learned from a collective case study undertaken in 12 of the 13 secondary schools in Grahamstown in the Eastern Cape in South Africa. School principals and designated IT teachers were interviewed and on-site infrastructure audits conducted. This paper identifies a number of key enabling and constraining factors surrounding practical issues, including sufficient hardware, appropriate software and affordable connectivity, sufficient technical support and training, policy-related issues such as the role of national, provincial and school policy, the vital contribution of principal leadership and champion teachers as well as ongoing teacher profes-sional development coupled with a willingness to change.
- Full Text:
- Date Issued: 2007
Environment and sustainability education in a changing South Africa: A critical historical analysis of outline schemes for defining and guiding learning interactions
- Authors: O'Donoghue, Rob B
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/373634 , vital:66708 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122749"
- Description: This paper examines how, in response to emerging risk, methodological narratives for conservation (CE), environmental (EE) and now sustainability education (ESD) were constituted in diverse settings within a changing South African state. After documenting an awareness creation perspective underpinning early extension and experiential activities, the study examines shaping social processes and changing outline schemes for defining and guiding planned learning interactions (methodology) within the broadening field into the present day. The critical historical analysis developed in the study reflects a well-documented shift from early topdown (intervention/extension) to more participatory approaches (collaborative engagement/stewardship). A situated process-mapping of changing orientations also reveals characterising methodological features across the contours of an increasingly diverse field of conservation, environment and sustainability education.
- Full Text:
- Date Issued: 2007
- Authors: O'Donoghue, Rob B
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/373634 , vital:66708 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122749"
- Description: This paper examines how, in response to emerging risk, methodological narratives for conservation (CE), environmental (EE) and now sustainability education (ESD) were constituted in diverse settings within a changing South African state. After documenting an awareness creation perspective underpinning early extension and experiential activities, the study examines shaping social processes and changing outline schemes for defining and guiding planned learning interactions (methodology) within the broadening field into the present day. The critical historical analysis developed in the study reflects a well-documented shift from early topdown (intervention/extension) to more participatory approaches (collaborative engagement/stewardship). A situated process-mapping of changing orientations also reveals characterising methodological features across the contours of an increasingly diverse field of conservation, environment and sustainability education.
- Full Text:
- Date Issued: 2007
Evaluating compression as an enabler for centralised monitoring in a Next Generation Network
- Otten, Fred, Irwin, Barry V W, Slay, Hannah
- Authors: Otten, Fred , Irwin, Barry V W , Slay, Hannah
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428226 , vital:72495 , https://citeseerx.ist.psu.edu/document?repid=rep1andtype=pdfanddoi=f9ed69db7da44c168082934cd4ea5a413b2bf7f5
- Description: With the emergence of Next Generation Networks and a large number of next generation services, the volume and diversity of information is on the rise. These networks are often large, distributed and consist of het-erogeneous devices. In order to provide effective centralised monitoring and control we need to be able to assemble the relevant data at a cen-tral point. This becomes difficult because of the large quantity of data. We also would like to achieve this using the least amount of bandwidth, and minimise the latency. This paper investigates using compression to enable centralised monitoring and control. It presents the results of ex-periments showing that compression is an effective method of data re-duction, resulting in up to 93.3 percent reduction in bandwidth usage for point-to-point transmission. This paper also describes an architecture that incorporates compression and provides centralised monitoring and control.
- Full Text:
- Date Issued: 2007
- Authors: Otten, Fred , Irwin, Barry V W , Slay, Hannah
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428226 , vital:72495 , https://citeseerx.ist.psu.edu/document?repid=rep1andtype=pdfanddoi=f9ed69db7da44c168082934cd4ea5a413b2bf7f5
- Description: With the emergence of Next Generation Networks and a large number of next generation services, the volume and diversity of information is on the rise. These networks are often large, distributed and consist of het-erogeneous devices. In order to provide effective centralised monitoring and control we need to be able to assemble the relevant data at a cen-tral point. This becomes difficult because of the large quantity of data. We also would like to achieve this using the least amount of bandwidth, and minimise the latency. This paper investigates using compression to enable centralised monitoring and control. It presents the results of ex-periments showing that compression is an effective method of data re-duction, resulting in up to 93.3 percent reduction in bandwidth usage for point-to-point transmission. This paper also describes an architecture that incorporates compression and provides centralised monitoring and control.
- Full Text:
- Date Issued: 2007
Excited state dynamics of zinc and aluminum phthalocyanine carboxylates
- Idowu, Mopelola, Ogunsipe, Abimbola, Nyokong, Tebello
- Authors: Idowu, Mopelola , Ogunsipe, Abimbola , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271228 , vital:54523 , xlink:href="https://doi.org/10.1016/j.saa.2007.01.025"
- Description: Photophysical parameters for zinc and aluminium tetracarboxylphthalocyanines (ZnTCPc and AlTCPc, respectively) and their octacarboxy substituted counterparts (ZnOCPc and AlOCPc) were studied. Data for the fluorescence quenching of the complexes by benzoquinone (BQ) were treated using the Stern–Volmer analysis, and the quenching was found to follow a diffusion-controlled (dynamic) bimolecular mechanism. Theoretical values of bimolecular rate constant for complex-BQ interactions were determined using the Stokes–Einstein–Smoluchowski model; and the values, together with the Stern–Volmer quenching constants were used in calculating the fluorescence lifetimes of the complexes. The thermodynamics of the MPc-BQ interaction, in terms of solvent reorientation energy is also discussed.
- Full Text:
- Date Issued: 2007
- Authors: Idowu, Mopelola , Ogunsipe, Abimbola , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271228 , vital:54523 , xlink:href="https://doi.org/10.1016/j.saa.2007.01.025"
- Description: Photophysical parameters for zinc and aluminium tetracarboxylphthalocyanines (ZnTCPc and AlTCPc, respectively) and their octacarboxy substituted counterparts (ZnOCPc and AlOCPc) were studied. Data for the fluorescence quenching of the complexes by benzoquinone (BQ) were treated using the Stern–Volmer analysis, and the quenching was found to follow a diffusion-controlled (dynamic) bimolecular mechanism. Theoretical values of bimolecular rate constant for complex-BQ interactions were determined using the Stokes–Einstein–Smoluchowski model; and the values, together with the Stern–Volmer quenching constants were used in calculating the fluorescence lifetimes of the complexes. The thermodynamics of the MPc-BQ interaction, in terms of solvent reorientation energy is also discussed.
- Full Text:
- Date Issued: 2007
Exploring the options for fuelwood policies to support poverty alleviation policies: Evolving dimensions in South Africa
- Shackleton, Charlie M, Buiten, Erik, Annecke, W, Banks, D, Bester, J, Everson, T, Fabricius, Christo, Ham, C, Kees, M, Modise, M, Phago, M, Prasad, Gisela, Twine, Wayne, Underwood, Michael, von Maltitz, Graham, Wentzel, P
- Authors: Shackleton, Charlie M , Buiten, Erik , Annecke, W , Banks, D , Bester, J , Everson, T , Fabricius, Christo , Ham, C , Kees, M , Modise, M , Phago, M , Prasad, Gisela , Twine, Wayne , Underwood, Michael , von Maltitz, Graham , Wentzel, P
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181213 , vital:43709 , xlink:href="https://doi.org/10.1080/14728028.2007.9752604"
- Description: Access to secure and affordable energy supplies is widely acknowledged as a critical foundation for sustainable development; inadequate access exacerbates household poverty. In the developing world poor households are frequently reliant upon fuel wood for all or most of their energy needs. However, national poverty alleviation policies commonly do not consider fuelwood within their strategies, and similarly, energy policies rarely consider the poverty alleviation potential of a comprehensive fuelwood strategy. Consequently, synergies between poverty alleviation and energy policies—with fuelwood (and its derivates) as the bridge—are needed. This paper discusses this potential using South Africa as a case example. The current policy environment that either favours or hinders a linkage between the poverty and energy sectors and policy options and strategies available to develop such links, are discussed.
- Full Text:
- Date Issued: 2007
- Authors: Shackleton, Charlie M , Buiten, Erik , Annecke, W , Banks, D , Bester, J , Everson, T , Fabricius, Christo , Ham, C , Kees, M , Modise, M , Phago, M , Prasad, Gisela , Twine, Wayne , Underwood, Michael , von Maltitz, Graham , Wentzel, P
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181213 , vital:43709 , xlink:href="https://doi.org/10.1080/14728028.2007.9752604"
- Description: Access to secure and affordable energy supplies is widely acknowledged as a critical foundation for sustainable development; inadequate access exacerbates household poverty. In the developing world poor households are frequently reliant upon fuel wood for all or most of their energy needs. However, national poverty alleviation policies commonly do not consider fuelwood within their strategies, and similarly, energy policies rarely consider the poverty alleviation potential of a comprehensive fuelwood strategy. Consequently, synergies between poverty alleviation and energy policies—with fuelwood (and its derivates) as the bridge—are needed. This paper discusses this potential using South Africa as a case example. The current policy environment that either favours or hinders a linkage between the poverty and energy sectors and policy options and strategies available to develop such links, are discussed.
- Full Text:
- Date Issued: 2007
Exploring the practical adequacy of the normative framework guiding South Africa’s National Curriculum Statement
- Lotz-Sisitka, Heila, Schudel, Ingrid J
- Authors: Lotz-Sisitka, Heila , Schudel, Ingrid J
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/294386 , vital:57217 , xlink:href="https://doi.org/10.1080/13504620701284860"
- Description: This article examines the practical adequacy of the recent defining of a normative framework for the South African National Curriculum Statement that focuses on the relationship between human rights, social justice and a healthy environment. This politically framed and socially critical normative framework has developed in response to socio‐political and socio‐ecological histories in post‐apartheid curriculum transformation processes. The article critically considers the process of working with a normative framework in the defining of environmental education teaching and learning interactions, and seeks not only to explore the policy discourse critically, but also to explore what it is about the world that makes it work in different ways. Drawing on Sayer’s perspectives on the possibilities of enabling ‘situated universalism’ as a form of normative theory, and case‐based data from a teacher professional development programme in the Makana District (where the authors live and work), the article probes the relationship between the establishment of a ‘universalising’ normative framework to guide national curriculum, and situated engagements with this framework in/as democratic process. In this process it questions whether educators should adopt the ‘norms’ as presented by society and simply universalize and implement them as prescribed by curriculum statements, or whether educators should adopt the strategies of postmodernists and reduce normative frameworks to relations of power situated in particular contexts.
- Full Text:
- Date Issued: 2007
- Authors: Lotz-Sisitka, Heila , Schudel, Ingrid J
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/294386 , vital:57217 , xlink:href="https://doi.org/10.1080/13504620701284860"
- Description: This article examines the practical adequacy of the recent defining of a normative framework for the South African National Curriculum Statement that focuses on the relationship between human rights, social justice and a healthy environment. This politically framed and socially critical normative framework has developed in response to socio‐political and socio‐ecological histories in post‐apartheid curriculum transformation processes. The article critically considers the process of working with a normative framework in the defining of environmental education teaching and learning interactions, and seeks not only to explore the policy discourse critically, but also to explore what it is about the world that makes it work in different ways. Drawing on Sayer’s perspectives on the possibilities of enabling ‘situated universalism’ as a form of normative theory, and case‐based data from a teacher professional development programme in the Makana District (where the authors live and work), the article probes the relationship between the establishment of a ‘universalising’ normative framework to guide national curriculum, and situated engagements with this framework in/as democratic process. In this process it questions whether educators should adopt the ‘norms’ as presented by society and simply universalize and implement them as prescribed by curriculum statements, or whether educators should adopt the strategies of postmodernists and reduce normative frameworks to relations of power situated in particular contexts.
- Full Text:
- Date Issued: 2007
Factors influencing prices of medicinal plants traded in the Lowveld, South Africa
- Botha, Jenny, Witkowski, Ed T F, Shackleton, Charlie M
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181257 , vital:43713 , xlink:href="https://doi.org/10.1080/13504500709469745"
- Description: There has been limited research into pricing and consumer behaviour in the informal sector, an understanding of which is critical to effective management of extensively traded wildlife resources. This paper explores factors influencing prices of wild-collected medicinal plants traded in the Lowveld, South Africa. Resource management decisions relating to medicinal plants are often based on the high price/kg values of certain species, and the assumption that there is an inverse relationship between the availability of products and prices. Despite the high-utility value of these plants, subsistence consumers have historically paid low prices for products. In this study, price/kg fluctuated widely, as did market players' perceptions of species availability and consumer demand. Unit prices were low, with a few exceptions. There was no relationship between prices and perceptions of species availability. No relationship was found between prices and consumer demand in one study area, although there was a non-significant relationship in the other. The size of products was the main determinant of price. Consumers were prepared to pay higher prices for certain species, e.g.those used to treat children, those considered highly dangerous (culturally) to collect, or those used for anti-social purposes.
- Full Text:
- Date Issued: 2007
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181257 , vital:43713 , xlink:href="https://doi.org/10.1080/13504500709469745"
- Description: There has been limited research into pricing and consumer behaviour in the informal sector, an understanding of which is critical to effective management of extensively traded wildlife resources. This paper explores factors influencing prices of wild-collected medicinal plants traded in the Lowveld, South Africa. Resource management decisions relating to medicinal plants are often based on the high price/kg values of certain species, and the assumption that there is an inverse relationship between the availability of products and prices. Despite the high-utility value of these plants, subsistence consumers have historically paid low prices for products. In this study, price/kg fluctuated widely, as did market players' perceptions of species availability and consumer demand. Unit prices were low, with a few exceptions. There was no relationship between prices and perceptions of species availability. No relationship was found between prices and consumer demand in one study area, although there was a non-significant relationship in the other. The size of products was the main determinant of price. Consumers were prepared to pay higher prices for certain species, e.g.those used to treat children, those considered highly dangerous (culturally) to collect, or those used for anti-social purposes.
- Full Text:
- Date Issued: 2007
Field testing the Alvarion BreezeMAX as a last mile access technology
- Siebörger, Ingrid, Terzoli, Alfredo
- Authors: Siebörger, Ingrid , Terzoli, Alfredo
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428520 , vital:72517 , https://www.researchgate.net/profile/Ingrid-Sieboerger/publication/255048217_Field_testing_the_Alvarion_BreezeMAX_as_a_last_mile_access_technology/links/53ff2f290cf21edafd15bfad/Field-testing-the-Alvarion-BreezeMAX-as-a-last-mile-access-technology.pdf
- Description: With an alarmingly low teledensity of approximately 12% in South Afri-ca, and not much hope of further wired infrastructure at the local loop level–as the costs incurred are high compared to potential revenue–wireless connectivity could be a great asset and service in South Africa. This paper looks at how WiMAX technologies, and specifically the Al-varion BreezeMAX, could be used in providing much needed telecom-munications infrastructure to both rural and urban areas in South Africa, providing broadband data throughput rates together with excellent net-work reliability and low latency.
- Full Text:
- Date Issued: 2007
- Authors: Siebörger, Ingrid , Terzoli, Alfredo
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428520 , vital:72517 , https://www.researchgate.net/profile/Ingrid-Sieboerger/publication/255048217_Field_testing_the_Alvarion_BreezeMAX_as_a_last_mile_access_technology/links/53ff2f290cf21edafd15bfad/Field-testing-the-Alvarion-BreezeMAX-as-a-last-mile-access-technology.pdf
- Description: With an alarmingly low teledensity of approximately 12% in South Afri-ca, and not much hope of further wired infrastructure at the local loop level–as the costs incurred are high compared to potential revenue–wireless connectivity could be a great asset and service in South Africa. This paper looks at how WiMAX technologies, and specifically the Al-varion BreezeMAX, could be used in providing much needed telecom-munications infrastructure to both rural and urban areas in South Africa, providing broadband data throughput rates together with excellent net-work reliability and low latency.
- Full Text:
- Date Issued: 2007
Giving children a voice:
- Authors: Prinsloo, Jeanne
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159277 , vital:40283 , https://hdl.handle.net/10520/EJC144676
- Description: It was in Johannesburg, South Africa, that the fifth World Summit on Media and Children took place from 24 to 27 March - a great jamboree where a thousand or so delegates from around 86 countries congregated together with 300 young people between the ages of 13 and 16.
- Full Text:
- Date Issued: 2007
- Authors: Prinsloo, Jeanne
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159277 , vital:40283 , https://hdl.handle.net/10520/EJC144676
- Description: It was in Johannesburg, South Africa, that the fifth World Summit on Media and Children took place from 24 to 27 March - a great jamboree where a thousand or so delegates from around 86 countries congregated together with 300 young people between the ages of 13 and 16.
- Full Text:
- Date Issued: 2007
Identity in the Siyagruva Series of novels: Toward an intercultural
- Authors: Kaschula, Russell H
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175159 , vital:42548 , DOI: 10.4314/tvl.v44i2.29792
- Description: This article explores the notion of changing South African youth identity and how it is depicted in the Siyagruva [We are Grooving] Series of novels for young adults. The article highlights the need for a broadening of literary theory in order to include an appropriate theoretical approach for new South African youth literature. This theory explores intercultural literary discourse by making use of, for example, the work of intercultural theorists such as Ting-Toomey (1999), Gudykunst (2003) and others. It is argued that this form of literary discourse is now appropriate as a theoretical paradigm within multilingual South Africa where intercultural communication is becoming a reality. There is also reference to intracultural communication where differences are beginning to appear between young people who are perceived to come from the same cultural group, for example, the character Brunette in the Siyagruva Series who is perceived as a “coconut” by her friends, and thus finds herself having to justify her belonging within a particular in-group or culture. The article concentrates on selected novels, though reference is made to many of the twenty three published novels in the Siyagruva Series, twenty in English, and three translated into isiXhosa.
- Full Text:
- Date Issued: 2007
- Authors: Kaschula, Russell H
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175159 , vital:42548 , DOI: 10.4314/tvl.v44i2.29792
- Description: This article explores the notion of changing South African youth identity and how it is depicted in the Siyagruva [We are Grooving] Series of novels for young adults. The article highlights the need for a broadening of literary theory in order to include an appropriate theoretical approach for new South African youth literature. This theory explores intercultural literary discourse by making use of, for example, the work of intercultural theorists such as Ting-Toomey (1999), Gudykunst (2003) and others. It is argued that this form of literary discourse is now appropriate as a theoretical paradigm within multilingual South Africa where intercultural communication is becoming a reality. There is also reference to intracultural communication where differences are beginning to appear between young people who are perceived to come from the same cultural group, for example, the character Brunette in the Siyagruva Series who is perceived as a “coconut” by her friends, and thus finds herself having to justify her belonging within a particular in-group or culture. The article concentrates on selected novels, though reference is made to many of the twenty three published novels in the Siyagruva Series, twenty in English, and three translated into isiXhosa.
- Full Text:
- Date Issued: 2007
Immobilization of tetra-amine substituted metallophthalocyanines at gold surfaces modified with mercaptopropionic acid or DTSP-SAMs
- Matemadombo, Fungisai, Westbroek, Philippe, Nyokong, Tebello, Ozoemena, Kenneth, De Clerck, Karen, Kiekens, Paul
- Authors: Matemadombo, Fungisai , Westbroek, Philippe , Nyokong, Tebello , Ozoemena, Kenneth , De Clerck, Karen , Kiekens, Paul
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283924 , vital:56003 , xlink:href="https://doi.org/10.1016/j.electacta.2006.08.027"
- Description: This paper shows that amine substituted cobalt phthalocyanine (CoTAPc) can be deposited on gold surfaces by using an interconnecting layer of a self-assembled monolayer (SAM) of mercaptopropionic acid or Lomant's reagent (dithiobis(N-succinimidyl propionate) (DTSP)). In both cases the new bond formed is obtained by the creation of an amide. The layers were characterized by electrochemistry and showed high coverage fractions (near 100%). Reductive and oxidative desorption of the SAMs limit the useful potential window from −0.6 to +0.5 V versus Ag|AgCl. The SAM-CoTAPc layers show electrocatalytic activities towards oxygen reduction through the Co(I) central metal ion. The amount of CoTAPc molecules deposited (obtained from the Co central metal ion activity in nitrogen purged solutions) revealed that the CoTAPc molecules are bonded in a perpendicular manner at the surface. Taking into account a surface of 200 Å2 for a flatly bonded MPc, this should result in a four times less amount of deposited CoTAPc compared to the experimental value obtained. Both methods showed good results and promising long-term stability and will be interesting tools for further research in surface modification and sensor development.
- Full Text:
- Date Issued: 2007
- Authors: Matemadombo, Fungisai , Westbroek, Philippe , Nyokong, Tebello , Ozoemena, Kenneth , De Clerck, Karen , Kiekens, Paul
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283924 , vital:56003 , xlink:href="https://doi.org/10.1016/j.electacta.2006.08.027"
- Description: This paper shows that amine substituted cobalt phthalocyanine (CoTAPc) can be deposited on gold surfaces by using an interconnecting layer of a self-assembled monolayer (SAM) of mercaptopropionic acid or Lomant's reagent (dithiobis(N-succinimidyl propionate) (DTSP)). In both cases the new bond formed is obtained by the creation of an amide. The layers were characterized by electrochemistry and showed high coverage fractions (near 100%). Reductive and oxidative desorption of the SAMs limit the useful potential window from −0.6 to +0.5 V versus Ag|AgCl. The SAM-CoTAPc layers show electrocatalytic activities towards oxygen reduction through the Co(I) central metal ion. The amount of CoTAPc molecules deposited (obtained from the Co central metal ion activity in nitrogen purged solutions) revealed that the CoTAPc molecules are bonded in a perpendicular manner at the surface. Taking into account a surface of 200 Å2 for a flatly bonded MPc, this should result in a four times less amount of deposited CoTAPc compared to the experimental value obtained. Both methods showed good results and promising long-term stability and will be interesting tools for further research in surface modification and sensor development.
- Full Text:
- Date Issued: 2007
Inetvis: a graphical aid for the detection and visualisation of network scans
- Irwin, Barry V W, van Riel, Jean-Pierre
- Authors: Irwin, Barry V W , van Riel, Jean-Pierre
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430381 , vital:72687 , https://www.cs.ru.ac.za/research/g02V2468/publications/Irwin-VizSEC2007_draft.pdf
- Description: This paper presents an investigative analysis of network scans and scan detection algorithms. Visualisation is employed to review network telescope traffic and identify incidents of scan activity. Some of the identified phenomena appear to be novel forms of host discovery. The scan detection algorithms of Snort and Bro are critiqued by comparing the visualised scans with alert output. Where human assessment disa-grees with the alert output, explanations are sought after by analysing the detection algorithms. The algorithms of the Snort and Bro intrusion detection systems are based on counting unique connection attempts to destination addresses and ports. For Snort, notable false positive and false negative cases result due to a grossly oversimplified method of counting unique destination addresses and ports.
- Full Text:
- Date Issued: 2007
- Authors: Irwin, Barry V W , van Riel, Jean-Pierre
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430381 , vital:72687 , https://www.cs.ru.ac.za/research/g02V2468/publications/Irwin-VizSEC2007_draft.pdf
- Description: This paper presents an investigative analysis of network scans and scan detection algorithms. Visualisation is employed to review network telescope traffic and identify incidents of scan activity. Some of the identified phenomena appear to be novel forms of host discovery. The scan detection algorithms of Snort and Bro are critiqued by comparing the visualised scans with alert output. Where human assessment disa-grees with the alert output, explanations are sought after by analysing the detection algorithms. The algorithms of the Snort and Bro intrusion detection systems are based on counting unique connection attempts to destination addresses and ports. For Snort, notable false positive and false negative cases result due to a grossly oversimplified method of counting unique destination addresses and ports.
- Full Text:
- Date Issued: 2007