Photophysical, photochemical and bovine serum albumin binding studies on water-soluble gallium (III) phthalocyanine derivatives
- Ogunsipe, Abimbola, Nyokong, Tebello, Durmus, Mahmut
- Authors: Ogunsipe, Abimbola , Nyokong, Tebello , Durmus, Mahmut
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271239 , vital:54524 , xlink:href="https://doi.org/10.1142/S1088424607000746"
- Description: Spectral, photophysical, photochemical and bovine serum albumin binding studies on some gallium(III) derivatives - {1,(4)-(tetrapyridyloxyphthalocyaninato)gallium(III), (αGaPc); 2,(3)-(tetrapyridyloxyphthalocyaninato)gallium(III), (βGaPc); and their quaternized derivatives: QαGaPc and QβGaPc)} are hereby presented. β-Substituted complexes are more fluorescent, but show lower tendencies to undergo intersystem crossing than the α-substituted, as judged by their fluorescence and triplet quantum yield values. The quaternized derivatives (QGaPc) are water-soluble and non-aggregated, which makes them potential photosensitizers of choice for photodynamic therapy applications; these amphiphilic compounds also bind strongly to bovine serum albumin in 1:1 stoichiometries, and with binding constants (Kb) in the order of 106 M−1.
- Full Text:
- Date Issued: 2007
- Authors: Ogunsipe, Abimbola , Nyokong, Tebello , Durmus, Mahmut
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271239 , vital:54524 , xlink:href="https://doi.org/10.1142/S1088424607000746"
- Description: Spectral, photophysical, photochemical and bovine serum albumin binding studies on some gallium(III) derivatives - {1,(4)-(tetrapyridyloxyphthalocyaninato)gallium(III), (αGaPc); 2,(3)-(tetrapyridyloxyphthalocyaninato)gallium(III), (βGaPc); and their quaternized derivatives: QαGaPc and QβGaPc)} are hereby presented. β-Substituted complexes are more fluorescent, but show lower tendencies to undergo intersystem crossing than the α-substituted, as judged by their fluorescence and triplet quantum yield values. The quaternized derivatives (QGaPc) are water-soluble and non-aggregated, which makes them potential photosensitizers of choice for photodynamic therapy applications; these amphiphilic compounds also bind strongly to bovine serum albumin in 1:1 stoichiometries, and with binding constants (Kb) in the order of 106 M−1.
- Full Text:
- Date Issued: 2007
Phthalocyanines : photochemical, electrochemical and biomimetic catalytic behaviour
- Authors: Sehlotho, Nthapo
- Date: 2007
- Subjects: Phthalocyanines Photochemistry Electrochemistry Biomimetics Oxidation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4336 , http://hdl.handle.net/10962/d1004997
- Description: This thesis explored use of metallophthalocyanines as electrocatalysts towards thiol and thiocyanate oxidation, nitrosothiol decomposition and reduction of oxygen, as well as biomimetic and photo-catalysts of cyclohexene oxidation. 2-mercaptoethanol (2-ME), L-cysteine (CYS) and reduced glutathione (GSH) thiols were oxidized on cobalt tetra ethoxythiophene and cobalt tetra phenoxy pyrrole phthalocyanine modified glassy carbon electrodes, whose catalytic activity was found to depend on pH, film thickness and method of electrode modification. Oxidation of thiocyanate (SCN-), CYS and 2-ME was catalyzed by a selfassembled monolayer of cobalt tetraethoxythiophene Thiocyanate oxidation occurred via two electron transfer, whereas that of CYS and 2-ME required 1 electron. The oxidations of SCN- and 2-ME were catalyzed by ring based processes, while CYS was catalyzed by both Co[superscript III]/Co[superscript II] process and ring-based processes. Oxidation of GSH and 2-ME was conducted on screen printed graphite electrodes modified with cobalt phthalocyanine. Activity depended on method of electrode modification and CoPc % composition. Decomposition of Snitrosoglutathione occurred in the presence of copper ions and NaBH[subscript 4]. Reduced and oxidized glutathione were detected as products using cobalt phthalocyanine adsorbed on an ordinary pyrolytic graphite electrode. Reduction of oxygen was electro-catalyzed by adsorbed manganese phthalocyanine complexes on glassy carbon electrodes. FePc, FePc(Cl)[subscript 16], CoPc and CoPc substituted with phenoxypyrrole and ethoxythiophene ligands were also used as electro-catalysts. Oxygen reduction occurred via two electron transfer in acidic and neutral media forming hydrogen peroxide, while water was formed in basic media via four electron transfer. Cyclohexene oxidation using tert-butylhydroperoxide or chloroperoxy benzoic acid as oxidants in the presence of FePc, FePc(Cl)[subscript 16] and CoPc formed cyclohexene oxide, 2-cyclohexen-1-ol, 2- cyclohexen-1-one and adipic acid. Product selectivity depended on the nature of catalyst and oxidant. The FePc(Cl)[subscript 16] catalyst was transformed into a µ-oxo dimer during the oxidation process while M[superscript III]Pc intermediates were formed with Co[superscript II]Pc and Fe[superscript II]Pc catalysts. Cyclohexene photooxidation catalyzed by zinc phthalocyanine using either red or white light formed 2-cyclohexen-1-one, 2-cyclohexen-1-ol, transcyclohexane diol, cyclohexene oxide and cyclohexene hydroperoxide via singlet oxygen and radical mechanisms. Product yields depended on the light wavelength and intensity, solvent, irradiation time and the rate of photodegradation of the catalyst.
- Full Text:
- Date Issued: 2007
- Authors: Sehlotho, Nthapo
- Date: 2007
- Subjects: Phthalocyanines Photochemistry Electrochemistry Biomimetics Oxidation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4336 , http://hdl.handle.net/10962/d1004997
- Description: This thesis explored use of metallophthalocyanines as electrocatalysts towards thiol and thiocyanate oxidation, nitrosothiol decomposition and reduction of oxygen, as well as biomimetic and photo-catalysts of cyclohexene oxidation. 2-mercaptoethanol (2-ME), L-cysteine (CYS) and reduced glutathione (GSH) thiols were oxidized on cobalt tetra ethoxythiophene and cobalt tetra phenoxy pyrrole phthalocyanine modified glassy carbon electrodes, whose catalytic activity was found to depend on pH, film thickness and method of electrode modification. Oxidation of thiocyanate (SCN-), CYS and 2-ME was catalyzed by a selfassembled monolayer of cobalt tetraethoxythiophene Thiocyanate oxidation occurred via two electron transfer, whereas that of CYS and 2-ME required 1 electron. The oxidations of SCN- and 2-ME were catalyzed by ring based processes, while CYS was catalyzed by both Co[superscript III]/Co[superscript II] process and ring-based processes. Oxidation of GSH and 2-ME was conducted on screen printed graphite electrodes modified with cobalt phthalocyanine. Activity depended on method of electrode modification and CoPc % composition. Decomposition of Snitrosoglutathione occurred in the presence of copper ions and NaBH[subscript 4]. Reduced and oxidized glutathione were detected as products using cobalt phthalocyanine adsorbed on an ordinary pyrolytic graphite electrode. Reduction of oxygen was electro-catalyzed by adsorbed manganese phthalocyanine complexes on glassy carbon electrodes. FePc, FePc(Cl)[subscript 16], CoPc and CoPc substituted with phenoxypyrrole and ethoxythiophene ligands were also used as electro-catalysts. Oxygen reduction occurred via two electron transfer in acidic and neutral media forming hydrogen peroxide, while water was formed in basic media via four electron transfer. Cyclohexene oxidation using tert-butylhydroperoxide or chloroperoxy benzoic acid as oxidants in the presence of FePc, FePc(Cl)[subscript 16] and CoPc formed cyclohexene oxide, 2-cyclohexen-1-ol, 2- cyclohexen-1-one and adipic acid. Product selectivity depended on the nature of catalyst and oxidant. The FePc(Cl)[subscript 16] catalyst was transformed into a µ-oxo dimer during the oxidation process while M[superscript III]Pc intermediates were formed with Co[superscript II]Pc and Fe[superscript II]Pc catalysts. Cyclohexene photooxidation catalyzed by zinc phthalocyanine using either red or white light formed 2-cyclohexen-1-one, 2-cyclohexen-1-ol, transcyclohexane diol, cyclohexene oxide and cyclohexene hydroperoxide via singlet oxygen and radical mechanisms. Product yields depended on the light wavelength and intensity, solvent, irradiation time and the rate of photodegradation of the catalyst.
- Full Text:
- Date Issued: 2007
Phylogeographic structure of Octopus vulgaris in South Africa revisited: identification of a second lineage near Durban harbor
- Teske, Peter R, Oosthuizen, A, Papadopoulos, Isabelle, Barker, Nigel P
- Authors: Teske, Peter R , Oosthuizen, A , Papadopoulos, Isabelle , Barker, Nigel P
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6544 , http://hdl.handle.net/10962/d1006000
- Description: In a previous study that investigated genetic structure of Octopus vulgaris along the South African coast by sequencing the mitochondrial cytochrome oxidase III gene (COIII), all sequences generated were identical. Such a finding is unusual, because mitochondrial DNA mutates quickly, and several marine invertebrates present in southern Africa show considerable genetic variation and structure. We reanalysed the samples using two different mitochondrial markers, namely cytochrome oxidase I (COI) and the large ribosomal subunit (16S rRNA). Sequences of both these markers showed variation. The conclusion of the previous study, that South Africa’s O. vulgaris population is characterised by a lack of genetic structure along the coast, is rejected. Some specimens from Durban (southeast Africa) were genetically more different from those found in the remainder of the country than were specimens from other regions (Tristan da Cunha and Senegal). We suggest that the lineage in Durban may have been recently introduced.
- Full Text:
- Date Issued: 2007
- Authors: Teske, Peter R , Oosthuizen, A , Papadopoulos, Isabelle , Barker, Nigel P
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6544 , http://hdl.handle.net/10962/d1006000
- Description: In a previous study that investigated genetic structure of Octopus vulgaris along the South African coast by sequencing the mitochondrial cytochrome oxidase III gene (COIII), all sequences generated were identical. Such a finding is unusual, because mitochondrial DNA mutates quickly, and several marine invertebrates present in southern Africa show considerable genetic variation and structure. We reanalysed the samples using two different mitochondrial markers, namely cytochrome oxidase I (COI) and the large ribosomal subunit (16S rRNA). Sequences of both these markers showed variation. The conclusion of the previous study, that South Africa’s O. vulgaris population is characterised by a lack of genetic structure along the coast, is rejected. Some specimens from Durban (southeast Africa) were genetically more different from those found in the remainder of the country than were specimens from other regions (Tristan da Cunha and Senegal). We suggest that the lineage in Durban may have been recently introduced.
- Full Text:
- Date Issued: 2007
Phylogeographic structure of the caridean shrimp Palaemon peringueyi in South Africa: further evidence for intraspecific genetic units associated with marine biogeographic provinces
- Teske, Peter R, Froneman, P William, Barker, Nigel P, McQuaid, Christopher D
- Authors: Teske, Peter R , Froneman, P William , Barker, Nigel P , McQuaid, Christopher D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/445486 , vital:74392 , https://doi.org/10.2989/AJMS.2007.29.2.9.192
- Description: Recent genetic studies have shown that most widely distributed, passively dispersing invertebrates in southern Africa have regional intraspecific units that are associated with the three main marine biogeographic provinces (cool-temperate, warm-temperate and subtropical). The caridean shrimp Palaemon peringueyi also occurs in all three provinces, but the fact that it can disperse both actively and passively (i.e. larval drifting, adult walking/swimming and potential adult rafting by means of floating objects) suggests that the amount of gene flow between regions may be too high for evolutionary divergence to have taken place. Samples of P. peringueyi were collected throughout South Africa and an intraspecific phylogeny was reconstructed using mitochondrial COI and 16S rRNA sequences. Three major clades were recovered, which were broadly associated with the three biogeographic regions. This suggests that, even though P. peringueyi can disperse actively, the fact that neither larvae nor adults are strong swimmers has resulted in genetic subdivisons comparable to those of passively dispersing coastal invertebrates in southern Africa.
- Full Text:
- Date Issued: 2007
- Authors: Teske, Peter R , Froneman, P William , Barker, Nigel P , McQuaid, Christopher D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/445486 , vital:74392 , https://doi.org/10.2989/AJMS.2007.29.2.9.192
- Description: Recent genetic studies have shown that most widely distributed, passively dispersing invertebrates in southern Africa have regional intraspecific units that are associated with the three main marine biogeographic provinces (cool-temperate, warm-temperate and subtropical). The caridean shrimp Palaemon peringueyi also occurs in all three provinces, but the fact that it can disperse both actively and passively (i.e. larval drifting, adult walking/swimming and potential adult rafting by means of floating objects) suggests that the amount of gene flow between regions may be too high for evolutionary divergence to have taken place. Samples of P. peringueyi were collected throughout South Africa and an intraspecific phylogeny was reconstructed using mitochondrial COI and 16S rRNA sequences. Three major clades were recovered, which were broadly associated with the three biogeographic regions. This suggests that, even though P. peringueyi can disperse actively, the fact that neither larvae nor adults are strong swimmers has resulted in genetic subdivisons comparable to those of passively dispersing coastal invertebrates in southern Africa.
- Full Text:
- Date Issued: 2007
Physical and biological processes at the Subtropical Convergence in the South-west Indian Ocean
- Froneman, P William, Ansorge, Isabelle J, Richoux, Nicole B, Blake, Justin D, Daly, Ryan, Sterley, Jessica A, Mostert, Bruce P, Heyns, Elodie R, Sheppard, Jill N, Kuyper, B, Hart, N, George, C, Howard, J, Mustafa, E, Pey, F, Lutjeharms, Johan R E
- Authors: Froneman, P William , Ansorge, Isabelle J , Richoux, Nicole B , Blake, Justin D , Daly, Ryan , Sterley, Jessica A , Mostert, Bruce P , Heyns, Elodie R , Sheppard, Jill N , Kuyper, B , Hart, N , George, C , Howard, J , Mustafa, E , Pey, F , Lutjeharms, Johan R E
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6966 , http://hdl.handle.net/10962/d1012030
- Description: A detailed hydrographic and biological survey was conducted in the region of the Subtropical Convergence in the Indian sector of the Southern Ocean in April 2007. Hydrographic data revealed that the subsurface expression of the Subtropical Convergence (at 200 m), marked by the 10°C isotherm, appeared to meander considerably between 41°S and 42°15’S. Total surface chlorophyll- a concentration was low and ranged from 0.03 to 0.42 µg l–1 and was always dominated by the pico- (<2 µm) and nano- (2–120 µm) size classes, which contributed between 81% and 93% of the total pigment. The total chlorophyll-a integrated over the top 150m of the water column showed no distinct spatial trends, and ranged from 12.8 to 40.1mg chl-a m–2. There were no significant correlations between the total integrated chlorophyll- a concentration and temperature and salinity (P > 0.05). The zooplankton community was dominated, numerically and by biomass, by mesozooplankton comprising mainly copepods of the genera, Oithona,Paraeuchaeta, Pleuromamma, Calanus and Clausocalanus. An exception was recorded at those stations in the region of the front where the tunicate, Salpa thompsoni, dominated the total zooplankton biomass.
- Full Text:
- Date Issued: 2007
- Authors: Froneman, P William , Ansorge, Isabelle J , Richoux, Nicole B , Blake, Justin D , Daly, Ryan , Sterley, Jessica A , Mostert, Bruce P , Heyns, Elodie R , Sheppard, Jill N , Kuyper, B , Hart, N , George, C , Howard, J , Mustafa, E , Pey, F , Lutjeharms, Johan R E
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6966 , http://hdl.handle.net/10962/d1012030
- Description: A detailed hydrographic and biological survey was conducted in the region of the Subtropical Convergence in the Indian sector of the Southern Ocean in April 2007. Hydrographic data revealed that the subsurface expression of the Subtropical Convergence (at 200 m), marked by the 10°C isotherm, appeared to meander considerably between 41°S and 42°15’S. Total surface chlorophyll- a concentration was low and ranged from 0.03 to 0.42 µg l–1 and was always dominated by the pico- (<2 µm) and nano- (2–120 µm) size classes, which contributed between 81% and 93% of the total pigment. The total chlorophyll-a integrated over the top 150m of the water column showed no distinct spatial trends, and ranged from 12.8 to 40.1mg chl-a m–2. There were no significant correlations between the total integrated chlorophyll- a concentration and temperature and salinity (P > 0.05). The zooplankton community was dominated, numerically and by biomass, by mesozooplankton comprising mainly copepods of the genera, Oithona,Paraeuchaeta, Pleuromamma, Calanus and Clausocalanus. An exception was recorded at those stations in the region of the front where the tunicate, Salpa thompsoni, dominated the total zooplankton biomass.
- Full Text:
- Date Issued: 2007
Physical characteristics as performance indicators in surfing
- Hayselden, Kirsten Jacqui-Anne
- Authors: Hayselden, Kirsten Jacqui-Anne
- Date: 2007
- Subjects: Surfing -- South Africa , Athletic ability , Physical fitness -- Testing
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:10097 , http://hdl.handle.net/10948/662 , Surfing -- South Africa , Athletic ability , Physical fitness -- Testing
- Description: The aim of this study was to identify indictors of performance in surfing. Therefore the objectives of the study were to determine the following: {u100085} Anthropometric measures such as: height, weight, body proportions; {u100085} Flexibility measures such as: back extension, hip flexion, ankle plantarflexion and dorsiflexion; {u100085} Core stability; {u100085} Dynamic balance; {u100085} Explosive leg power; {u100085} Which of the physical characteristics measured discriminate between elite and non-elite surfers. To achieve the aim and objectives of this study, the literature pertaining to excellence in surfing, and the theory surrounding talent identification and the many factors that can contribute to success in sport, were reviewed. Potential criteria important for performance in surfing were identified and appropriate tests to assess these criteria were selected. An ex post facto quasi experimental design was used to assess which of the identified criteria best discriminated between elite and non-elite surfboard riders. The test battery included a personal information questionnaire and the assessment of: anthropometric variables, flexibility, core stability, dynamic balance and explosive leg power. These abovementioned physical characteristics were identified from the literature as the factors most important to success in surfing. Fifty five (55) surfers were assessed of which 28 were elite surfers and 27 were non-elite surfers. The results obtained from the evaluation of the samples were compared in terms of their descriptive statistics and the differences tested for statistical and practical significance. The variables of height, age started surfing, core stability, dynamic balance, number of days surfed per week and number of hours surfed per day were found to most discriminate between the elite and non-elite participants. Finally, a stepwise discriminant analysis was used to determine classification functions that could be used for future prediction purposes. The variables included in the discriminant analyses included height, age started surfing, number of years surfing, core stability and dynamic balance. To verify the prediction model a jack-knife procedure was performed. The results from the jack-knife procedure indicated that 85.5 perecent of the entire sample was correctly classified while 92.9 percent of the elite sample and 77.8 percent of the non-elite sample were correctly classified. Thus, the discriminant functions obtained can be used for predictive purposes.
- Full Text:
- Date Issued: 2007
- Authors: Hayselden, Kirsten Jacqui-Anne
- Date: 2007
- Subjects: Surfing -- South Africa , Athletic ability , Physical fitness -- Testing
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:10097 , http://hdl.handle.net/10948/662 , Surfing -- South Africa , Athletic ability , Physical fitness -- Testing
- Description: The aim of this study was to identify indictors of performance in surfing. Therefore the objectives of the study were to determine the following: {u100085} Anthropometric measures such as: height, weight, body proportions; {u100085} Flexibility measures such as: back extension, hip flexion, ankle plantarflexion and dorsiflexion; {u100085} Core stability; {u100085} Dynamic balance; {u100085} Explosive leg power; {u100085} Which of the physical characteristics measured discriminate between elite and non-elite surfers. To achieve the aim and objectives of this study, the literature pertaining to excellence in surfing, and the theory surrounding talent identification and the many factors that can contribute to success in sport, were reviewed. Potential criteria important for performance in surfing were identified and appropriate tests to assess these criteria were selected. An ex post facto quasi experimental design was used to assess which of the identified criteria best discriminated between elite and non-elite surfboard riders. The test battery included a personal information questionnaire and the assessment of: anthropometric variables, flexibility, core stability, dynamic balance and explosive leg power. These abovementioned physical characteristics were identified from the literature as the factors most important to success in surfing. Fifty five (55) surfers were assessed of which 28 were elite surfers and 27 were non-elite surfers. The results obtained from the evaluation of the samples were compared in terms of their descriptive statistics and the differences tested for statistical and practical significance. The variables of height, age started surfing, core stability, dynamic balance, number of days surfed per week and number of hours surfed per day were found to most discriminate between the elite and non-elite participants. Finally, a stepwise discriminant analysis was used to determine classification functions that could be used for future prediction purposes. The variables included in the discriminant analyses included height, age started surfing, number of years surfing, core stability and dynamic balance. To verify the prediction model a jack-knife procedure was performed. The results from the jack-knife procedure indicated that 85.5 perecent of the entire sample was correctly classified while 92.9 percent of the elite sample and 77.8 percent of the non-elite sample were correctly classified. Thus, the discriminant functions obtained can be used for predictive purposes.
- Full Text:
- Date Issued: 2007
Physical implications of prolonged sitting in a confined posture - a literature review
- Todd, Andrew I, Bennett, Anthea I, Christie, Candice J
- Authors: Todd, Andrew I , Bennett, Anthea I , Christie, Candice J
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6756 , http://hdl.handle.net/10962/d1009458
- Description: The main purpose of this review article was to highlight some of the physical consequences of sitting for prolonged periods in a confined setting. More specifically, the review relates this research to call centre work and where applicable comments on the limited literature relating specifically to ergonomics research within call centre settings. In particular the article explores the biomechanical stresses placed on the musculoskeletal system during prolonged sitting at a workstation, and the physiological consequences thereof. The paper then provides possible solutions to reduce the physical strain placed on these workers by looking at workstation design and work organisation emphasizing worker education and the promotion of worker well being.
- Full Text:
- Date Issued: 2007
- Authors: Todd, Andrew I , Bennett, Anthea I , Christie, Candice J
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6756 , http://hdl.handle.net/10962/d1009458
- Description: The main purpose of this review article was to highlight some of the physical consequences of sitting for prolonged periods in a confined setting. More specifically, the review relates this research to call centre work and where applicable comments on the limited literature relating specifically to ergonomics research within call centre settings. In particular the article explores the biomechanical stresses placed on the musculoskeletal system during prolonged sitting at a workstation, and the physiological consequences thereof. The paper then provides possible solutions to reduce the physical strain placed on these workers by looking at workstation design and work organisation emphasizing worker education and the promotion of worker well being.
- Full Text:
- Date Issued: 2007
Poetry and Languid Charm, 2007
- Authors: McConnachie, Boudina E
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/480714 , vital:78469 , xlink:href="https://doi.org/10.21504/amj.v8i1.1707"
- Description: In keeping with its aim for a wide dissemination of the music and information held in its considerable archive, the British Library Sound Archive presents a compilation of Swahili music from Tanzania and Kenya recorded from 1920 to 1950. The name of the compilation - Poetry and languid charm, as explained in the booklet text, is taken from a direct quote from recordist Hugh Tracey’s article “Recording Tour, May to November 1950 East Africa”. published in the African music Society Newsletter. After a particularly successful tour to East Africa in 1950 during which Tracey recorded over 1000 tracks (six of which are included in the compilation), he stated that he was impressed with the musical feeling of the Swahilis and that “Mombasa, like Dar es Salaam, proved to be a place of poetry and languid charm” (Tracey 1951:50)
- Full Text:
- Date Issued: 2007
- Authors: McConnachie, Boudina E
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/480714 , vital:78469 , xlink:href="https://doi.org/10.21504/amj.v8i1.1707"
- Description: In keeping with its aim for a wide dissemination of the music and information held in its considerable archive, the British Library Sound Archive presents a compilation of Swahili music from Tanzania and Kenya recorded from 1920 to 1950. The name of the compilation - Poetry and languid charm, as explained in the booklet text, is taken from a direct quote from recordist Hugh Tracey’s article “Recording Tour, May to November 1950 East Africa”. published in the African music Society Newsletter. After a particularly successful tour to East Africa in 1950 during which Tracey recorded over 1000 tracks (six of which are included in the compilation), he stated that he was impressed with the musical feeling of the Swahilis and that “Mombasa, like Dar es Salaam, proved to be a place of poetry and languid charm” (Tracey 1951:50)
- Full Text:
- Date Issued: 2007
Poets and the bells of Shandon
- Authors: Lewis, Colin A
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6176 , http://hdl.handle.net/10962/d1012369 , http://www.ringingworld.co.uk
- Description: Colin Lewis was Professor of Geography at Rhodes University, Grahamstown, South Africa from 1989 until his retirement at the end of 2007. In 1990, with the strong support of the incumbent Vice-Chancellor, Dr Derek Henderson, he instigated the Certificate in Change Ringing (Church Bell Ringing) in the Rhodes University Department of Music and Musicology - the first such course to be offered in Africa. Since that date he has lectured in the basic theory, and taught the practice of change ringing. He is the Ringing Master of the Cathedral of St Michael and St George, Grahamstown, South Africa.
- Full Text: false
- Date Issued: 2007
- Authors: Lewis, Colin A
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6176 , http://hdl.handle.net/10962/d1012369 , http://www.ringingworld.co.uk
- Description: Colin Lewis was Professor of Geography at Rhodes University, Grahamstown, South Africa from 1989 until his retirement at the end of 2007. In 1990, with the strong support of the incumbent Vice-Chancellor, Dr Derek Henderson, he instigated the Certificate in Change Ringing (Church Bell Ringing) in the Rhodes University Department of Music and Musicology - the first such course to be offered in Africa. Since that date he has lectured in the basic theory, and taught the practice of change ringing. He is the Ringing Master of the Cathedral of St Michael and St George, Grahamstown, South Africa.
- Full Text: false
- Date Issued: 2007
Population structure, growth and recruitment of two exploited infralittoral molluscs (Haliotis midae and Turbo sarmaticus) along the south east coast, South Africa
- Authors: Proudfoot, Lee-Anne
- Date: 2007
- Subjects: Abalones -- South Africa , Abalones -- Growth -- South Africa , Turbinidae -- South Africa , Mollusks -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5744 , http://hdl.handle.net/10962/d1005430 , Abalones -- South Africa , Abalones -- Growth -- South Africa , Turbinidae -- South Africa , Mollusks -- South Africa
- Description: The two most frequently exploited species along the south east coast of South Africa are the gastropods, Haliotis midae (abalone) and Turbo sarmaticus (alikreukel). H. midae is a high valued commercial species, and suffers intense levels of illegal fishing. T. sarmaticus however, has no commercial value but is the preferred food item for impoverished subsistence communities. Owing to the fact that no legal commercial fishery exists for either species along the south coast, very few studies have been undertaken, especially in the heavily exploited infralittoral. Infralittoral size frequency distributions for both species revealed significant variation in density and size among sites of varying exploitation pressure. Densities ranged between 0 – 2.23 m⁻² (H. midae) and 0.03 – 4.93 m⁻² (T. sarmaticus) and maximum shell lengths ranged from 49.4 – 153.5 mm (H. midae) and 28.3 – 104.4 mm (T. sarmaticus). Relatively high densities and large sizes were found in marine reserves and secluded areas, and low densities and small sizes at sites near to large population centres and within the former Ciskei homeland region. Mean size of the largest 10% of the population, total density and sexually mature density were significantly related to exploitation predictors for both species. In addition, densities of H. midae juveniles were significantly related to exploitation predictors, suggesting that recruitment may be suppressed at the most exploited sites. Exploitation of T. sarmaticus tended to be localized with refuge and subtidal populations persisting. H. midae exploitation was however, far more extensive and intense. Growth of H. midae was investigated using three methods; mark-recapture, cohort analysis and growth banding analysis at Kowie Rocks, Port Alfred. The most useful of these methods for determining growth was a new technique described for growth banding analysis; which was validated using cohort analysis and measurements of shells of known age. This technique was less time consuming and labour intensive than previously described methods. Abalone growth was best described by the Schnute (1981) growth function. Systematic geographic variation in growth was observed for 10 sites along the South African coastline. Significant differences in growth among sites existed for animals between 0-4 years (P < 0.0001) and 4-6 years (P < 0.0001), and in the mean maximum sizes attained (P < 0.001). In general, abalone from the south east/east coast were found to have faster growth rates, smaller mean maximum sizes and attained sexual maturity earlier than those along the south west/ west coast. Haliotis midae recruit and juvenile densities were found to differ significantly among sites of varying exploitation pressure (P < 0.0001) and among months for recruit densities (P < 0.001). Exploited sites had low recruit and juvenile densities compared to unexploited sites and peak recruitment occurred during October/ November 2005. Recruit densities were significantly related to infralittoral adult densities during two of the three sampling months (P<0.05), when recruitment was low. No relationship was observed during the period of high recruitment, with all sites receiving high recruit densities. It was concluded that variation in recruit densities was the result of a combination of both density-dependent relationships (i.e. local spawner density and temporal variability in recruitment intensity) and the possible dispersal capabilities of H. midae. In addition, it was concluded that at present recruitment overfishing was not occurring along the south east coast. Post-recruitment mortality rates were variable but relatively constant, with hypothetical percentage survival and density curves revealing high rates and similar mortality curves among sites. Variation in juvenile densities was consequently a result of initial recruit densities and not variation in post-recruitment mortality. T. sarmaticus populations were found to be regionally sustainable and persisted along the south east coast due to adjacent intertidal and subtidal refuge populations. However, H. midae populations are becoming decimated along the south east coast. From the information obtained in this study new management proposals were suggested and discussed, such as closed areas and region-based management fisheries together with stock enhancement. These suggestions may prove to be feasible alternatives to present management strategies.
- Full Text:
- Date Issued: 2007
- Authors: Proudfoot, Lee-Anne
- Date: 2007
- Subjects: Abalones -- South Africa , Abalones -- Growth -- South Africa , Turbinidae -- South Africa , Mollusks -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5744 , http://hdl.handle.net/10962/d1005430 , Abalones -- South Africa , Abalones -- Growth -- South Africa , Turbinidae -- South Africa , Mollusks -- South Africa
- Description: The two most frequently exploited species along the south east coast of South Africa are the gastropods, Haliotis midae (abalone) and Turbo sarmaticus (alikreukel). H. midae is a high valued commercial species, and suffers intense levels of illegal fishing. T. sarmaticus however, has no commercial value but is the preferred food item for impoverished subsistence communities. Owing to the fact that no legal commercial fishery exists for either species along the south coast, very few studies have been undertaken, especially in the heavily exploited infralittoral. Infralittoral size frequency distributions for both species revealed significant variation in density and size among sites of varying exploitation pressure. Densities ranged between 0 – 2.23 m⁻² (H. midae) and 0.03 – 4.93 m⁻² (T. sarmaticus) and maximum shell lengths ranged from 49.4 – 153.5 mm (H. midae) and 28.3 – 104.4 mm (T. sarmaticus). Relatively high densities and large sizes were found in marine reserves and secluded areas, and low densities and small sizes at sites near to large population centres and within the former Ciskei homeland region. Mean size of the largest 10% of the population, total density and sexually mature density were significantly related to exploitation predictors for both species. In addition, densities of H. midae juveniles were significantly related to exploitation predictors, suggesting that recruitment may be suppressed at the most exploited sites. Exploitation of T. sarmaticus tended to be localized with refuge and subtidal populations persisting. H. midae exploitation was however, far more extensive and intense. Growth of H. midae was investigated using three methods; mark-recapture, cohort analysis and growth banding analysis at Kowie Rocks, Port Alfred. The most useful of these methods for determining growth was a new technique described for growth banding analysis; which was validated using cohort analysis and measurements of shells of known age. This technique was less time consuming and labour intensive than previously described methods. Abalone growth was best described by the Schnute (1981) growth function. Systematic geographic variation in growth was observed for 10 sites along the South African coastline. Significant differences in growth among sites existed for animals between 0-4 years (P < 0.0001) and 4-6 years (P < 0.0001), and in the mean maximum sizes attained (P < 0.001). In general, abalone from the south east/east coast were found to have faster growth rates, smaller mean maximum sizes and attained sexual maturity earlier than those along the south west/ west coast. Haliotis midae recruit and juvenile densities were found to differ significantly among sites of varying exploitation pressure (P < 0.0001) and among months for recruit densities (P < 0.001). Exploited sites had low recruit and juvenile densities compared to unexploited sites and peak recruitment occurred during October/ November 2005. Recruit densities were significantly related to infralittoral adult densities during two of the three sampling months (P<0.05), when recruitment was low. No relationship was observed during the period of high recruitment, with all sites receiving high recruit densities. It was concluded that variation in recruit densities was the result of a combination of both density-dependent relationships (i.e. local spawner density and temporal variability in recruitment intensity) and the possible dispersal capabilities of H. midae. In addition, it was concluded that at present recruitment overfishing was not occurring along the south east coast. Post-recruitment mortality rates were variable but relatively constant, with hypothetical percentage survival and density curves revealing high rates and similar mortality curves among sites. Variation in juvenile densities was consequently a result of initial recruit densities and not variation in post-recruitment mortality. T. sarmaticus populations were found to be regionally sustainable and persisted along the south east coast due to adjacent intertidal and subtidal refuge populations. However, H. midae populations are becoming decimated along the south east coast. From the information obtained in this study new management proposals were suggested and discussed, such as closed areas and region-based management fisheries together with stock enhancement. These suggestions may prove to be feasible alternatives to present management strategies.
- Full Text:
- Date Issued: 2007
Postnatal women's experiences of the prevention of mother-to-child transmittion of HIV programme
- Authors: Links, Nomvuyiseko
- Date: 2007
- Subjects: AIDS (Disease) in pregnancy -- South Africa , HIV infections -- Children -- Transmission -- Prevention , Children -- Diseases -- Prevention , HIV infections -- Transmission , Maternal health services
- Language: English
- Type: Thesis , Masters , MCur
- Identifier: vital:10042 , http://hdl.handle.net/10948/545 , http://hdl.handle.net/10948/d1011704 , AIDS (Disease) in pregnancy -- South Africa , HIV infections -- Children -- Transmission -- Prevention , Children -- Diseases -- Prevention , HIV infections -- Transmission , Maternal health services
- Description: This research study endeavoured to explore and describe the experiences of women who participated in the Prevention of Mother-To-Child Transmission (PMTCT) of HIV Programme. Data relating to evaluation of the PMTCT Programme in the piloted sites compiled by other researchers in the Department of Health focus on the process, progress and extent of service implementation. There appears to be a dearth of information available from women participants in the PMTCT Programme. The objectives of the study were to: · Explore and describe postnatal women’s experiences of the PMTCT Programme offered in the East London Hospital Complex. · Propose recommendations into the existing guidelines for midwives who implement the PMTCT Programme in the health services to ensure optimal implementation of this programme. The research population included postnatal women who participated in the PMTCT of HIV Programme at the East London Hospital Complex (Frere site). Permission to conduct the research was obtained from the Eastern Cape Department of Health Ethics Committee, Chief Executive Officer of the hospital complex and the Advanced Degrees Committee and Human Ethics Committee at the Nelson Mandela Metropolitan University. The research study was qualitative, exploratory, descriptive and contextual in design. Data collection was carried out by face-to-face semi-structured interviews with postnatal women at the East London Hospital Complex (Frere site). The tape-recorded interviews were transcribed verbatim with the aid of field notes. Data analysis was done according to Tesch’s method of data analysis (in De Vos et al, 2000:343). Themes were identified from the transcriptions and finalised after consensus discussions with an independent coder who was experienced in qualitative research. Literature control, guided by the themes identified in the interviews, was carried out to compare and verify the findings of the study. Three major themes with sub-themes were identified during data analysis. The major themes were identified as follows: · The participants expressed feelings of being devastated by the results that confirmed their HIV positive status. · The participants expressed a thirst for knowledge on how to live with the diagnosis and on how to continue with the PMTCT Programme. · The physical environment where counselling and testing were done, as well as the practical arrangements, were not conducive to the full implementation of the PMTCT Programme at the antenatal clinic. Conclusions were drawn and recommendations were made in the form of additional guidelines for midwives implementing the PMTCT Programme in the antenatal clinic health services. Guidelines for further midwifery-related research were formulated.
- Full Text:
- Date Issued: 2007
- Authors: Links, Nomvuyiseko
- Date: 2007
- Subjects: AIDS (Disease) in pregnancy -- South Africa , HIV infections -- Children -- Transmission -- Prevention , Children -- Diseases -- Prevention , HIV infections -- Transmission , Maternal health services
- Language: English
- Type: Thesis , Masters , MCur
- Identifier: vital:10042 , http://hdl.handle.net/10948/545 , http://hdl.handle.net/10948/d1011704 , AIDS (Disease) in pregnancy -- South Africa , HIV infections -- Children -- Transmission -- Prevention , Children -- Diseases -- Prevention , HIV infections -- Transmission , Maternal health services
- Description: This research study endeavoured to explore and describe the experiences of women who participated in the Prevention of Mother-To-Child Transmission (PMTCT) of HIV Programme. Data relating to evaluation of the PMTCT Programme in the piloted sites compiled by other researchers in the Department of Health focus on the process, progress and extent of service implementation. There appears to be a dearth of information available from women participants in the PMTCT Programme. The objectives of the study were to: · Explore and describe postnatal women’s experiences of the PMTCT Programme offered in the East London Hospital Complex. · Propose recommendations into the existing guidelines for midwives who implement the PMTCT Programme in the health services to ensure optimal implementation of this programme. The research population included postnatal women who participated in the PMTCT of HIV Programme at the East London Hospital Complex (Frere site). Permission to conduct the research was obtained from the Eastern Cape Department of Health Ethics Committee, Chief Executive Officer of the hospital complex and the Advanced Degrees Committee and Human Ethics Committee at the Nelson Mandela Metropolitan University. The research study was qualitative, exploratory, descriptive and contextual in design. Data collection was carried out by face-to-face semi-structured interviews with postnatal women at the East London Hospital Complex (Frere site). The tape-recorded interviews were transcribed verbatim with the aid of field notes. Data analysis was done according to Tesch’s method of data analysis (in De Vos et al, 2000:343). Themes were identified from the transcriptions and finalised after consensus discussions with an independent coder who was experienced in qualitative research. Literature control, guided by the themes identified in the interviews, was carried out to compare and verify the findings of the study. Three major themes with sub-themes were identified during data analysis. The major themes were identified as follows: · The participants expressed feelings of being devastated by the results that confirmed their HIV positive status. · The participants expressed a thirst for knowledge on how to live with the diagnosis and on how to continue with the PMTCT Programme. · The physical environment where counselling and testing were done, as well as the practical arrangements, were not conducive to the full implementation of the PMTCT Programme at the antenatal clinic. Conclusions were drawn and recommendations were made in the form of additional guidelines for midwives implementing the PMTCT Programme in the antenatal clinic health services. Guidelines for further midwifery-related research were formulated.
- Full Text:
- Date Issued: 2007
Preface to Rhodes University Research Report, 2007
- Authors: Badat, Saleem
- Date: 2007
- Subjects: Rhodes University
- Language: English
- Type: text
- Identifier: vital:7654 , http://hdl.handle.net/10962/d1015782
- Full Text:
- Date Issued: 2007
- Authors: Badat, Saleem
- Date: 2007
- Subjects: Rhodes University
- Language: English
- Type: text
- Identifier: vital:7654 , http://hdl.handle.net/10962/d1015782
- Full Text:
- Date Issued: 2007
Preliminary survey of indigenous, non-indigenous and cryptogenic benthic invertebrates in Burrard Inlet, Vancover, British Columbia
- Richoux, Nicole B, Froneman, P William
- Authors: Richoux, Nicole B , Froneman, P William
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/457981 , vital:75705 , xlink:href="https://doi.org/10.1016/j.ecss.2006.09.007"
- Description: In a preliminary investigation into the presence of non-indigenous invertebrates in Burrard Inlet, Vancouver, British Columbia, qualitative sampling on rocky shores, pilings and floating docks was conducted in July and August 2004. Twenty-nine sites were established, 34 samples were analysed, and 103 different taxa were identified. Data were also obtained on habitat characteristics including substrate type, salinity and temperature. Identification of polychaetes, mussels from four sites, all amphipods, isopods and patellogastropods have been confirmed by taxonomic specialists.
- Full Text:
- Date Issued: 2007
- Authors: Richoux, Nicole B , Froneman, P William
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/457981 , vital:75705 , xlink:href="https://doi.org/10.1016/j.ecss.2006.09.007"
- Description: In a preliminary investigation into the presence of non-indigenous invertebrates in Burrard Inlet, Vancouver, British Columbia, qualitative sampling on rocky shores, pilings and floating docks was conducted in July and August 2004. Twenty-nine sites were established, 34 samples were analysed, and 103 different taxa were identified. Data were also obtained on habitat characteristics including substrate type, salinity and temperature. Identification of polychaetes, mussels from four sites, all amphipods, isopods and patellogastropods have been confirmed by taxonomic specialists.
- Full Text:
- Date Issued: 2007
Pretopological and topological lattice-valued convergence spaces
- Authors: Jäger, Gunter
- Date: 2007
- Language: English
- Type: text , Article
- Identifier: vital:6827 , http://hdl.handle.net/10962/d1012337
- Description: We show that the classical axiom which characterizes pretopological convergence spaces splits into two axioms in the general Heyting algebra-valued case. Furthermore we present a generalization of Kowalski’s diagonal condition to the lattice-valued case.
- Full Text:
- Date Issued: 2007
- Authors: Jäger, Gunter
- Date: 2007
- Language: English
- Type: text , Article
- Identifier: vital:6827 , http://hdl.handle.net/10962/d1012337
- Description: We show that the classical axiom which characterizes pretopological convergence spaces splits into two axioms in the general Heyting algebra-valued case. Furthermore we present a generalization of Kowalski’s diagonal condition to the lattice-valued case.
- Full Text:
- Date Issued: 2007
Pricing exotic options using C++
- Authors: Nhongo, Tawuya D R
- Date: 2007
- Subjects: C++ (Computer program language) , Monte Carlo method , Simulation methods , Options (Finance) -- Mathematical models , Pricing -- Mathematical models
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5577 , http://hdl.handle.net/10962/d1008373 , C++ (Computer program language) , Monte Carlo method , Simulation methods , Options (Finance) -- Mathematical models , Pricing -- Mathematical models
- Description: This document demonstrates the use of the C++ programming language as a simulation tool in the efficient pricing of exotic European options. Extensions to the basic problem of simulation pricing are undertaken including variance reduction by conditional expectation, control and antithetic variates. Ultimately we were able to produce a modularized, easily extend-able program which effectively makes use of Monte Carlo simulation techniques to price lookback, Asian and barrier exotic options. Theories of variance reduction were validated except in cases where we used control variates in combination with the other variance reduction techniques in which case we observed increased variance. Again, the main aim of this half thesis was to produce a C++ program which would produce stable pricings of exotic options.
- Full Text:
- Date Issued: 2007
- Authors: Nhongo, Tawuya D R
- Date: 2007
- Subjects: C++ (Computer program language) , Monte Carlo method , Simulation methods , Options (Finance) -- Mathematical models , Pricing -- Mathematical models
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5577 , http://hdl.handle.net/10962/d1008373 , C++ (Computer program language) , Monte Carlo method , Simulation methods , Options (Finance) -- Mathematical models , Pricing -- Mathematical models
- Description: This document demonstrates the use of the C++ programming language as a simulation tool in the efficient pricing of exotic European options. Extensions to the basic problem of simulation pricing are undertaken including variance reduction by conditional expectation, control and antithetic variates. Ultimately we were able to produce a modularized, easily extend-able program which effectively makes use of Monte Carlo simulation techniques to price lookback, Asian and barrier exotic options. Theories of variance reduction were validated except in cases where we used control variates in combination with the other variance reduction techniques in which case we observed increased variance. Again, the main aim of this half thesis was to produce a C++ program which would produce stable pricings of exotic options.
- Full Text:
- Date Issued: 2007
Prime near-ring modules and their links with the generalised group near-ring
- Authors: Juglal, Shaanraj
- Date: 2007
- Subjects: Near-rings
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10507 , http://hdl.handle.net/10948/714 , Near-rings
- Description: In view of the facts that the definition of a ring led to the definition of a near- ring, the definition of a ring module led to the definition of a near-ring module, prime rings resulted in investigations with respect to primeness in near-rings, one is naturally inclined to attempt to define the notion of a group near-ring seeing that the group ring had already been defined and investigated into by, interalia, Groenewald in [7] . However, in trying to define the group near-ring along the same lines as the group ring was defined, it was found that the resulting multiplication was, in general, not associative in the near-ring case due to the lack of one distributive property. In 1976, Meldrum [19] achieved success in defining the group near-ring. How- ever, in his definition, only distributively generated near-rings were considered and the distributive generators played a vital role in the construction. In 1989, Le Riche, Meldrum and van der Walt [17], adopted a similar approach to that which led to a successful and fruitful definition of matrix near-rings, and defined the group near-ring in a more general sense. In particular, they defined R[G], the group near-ring of a group G over a near-ring R, as a subnear-ring of M(RG), the near-ring of all mappings of the group RG into itself. More recently, Groenewald and Lee [14], further generalised the definition of R[G] to R[S : M], the generalised semigroup near-ring of a semigroup S over any faithful R-module M. Again, the natural thing to do would be to extend the results obtained for R[G] to R[S : M], and this they achieved with much success.
- Full Text:
- Date Issued: 2007
- Authors: Juglal, Shaanraj
- Date: 2007
- Subjects: Near-rings
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10507 , http://hdl.handle.net/10948/714 , Near-rings
- Description: In view of the facts that the definition of a ring led to the definition of a near- ring, the definition of a ring module led to the definition of a near-ring module, prime rings resulted in investigations with respect to primeness in near-rings, one is naturally inclined to attempt to define the notion of a group near-ring seeing that the group ring had already been defined and investigated into by, interalia, Groenewald in [7] . However, in trying to define the group near-ring along the same lines as the group ring was defined, it was found that the resulting multiplication was, in general, not associative in the near-ring case due to the lack of one distributive property. In 1976, Meldrum [19] achieved success in defining the group near-ring. How- ever, in his definition, only distributively generated near-rings were considered and the distributive generators played a vital role in the construction. In 1989, Le Riche, Meldrum and van der Walt [17], adopted a similar approach to that which led to a successful and fruitful definition of matrix near-rings, and defined the group near-ring in a more general sense. In particular, they defined R[G], the group near-ring of a group G over a near-ring R, as a subnear-ring of M(RG), the near-ring of all mappings of the group RG into itself. More recently, Groenewald and Lee [14], further generalised the definition of R[G] to R[S : M], the generalised semigroup near-ring of a semigroup S over any faithful R-module M. Again, the natural thing to do would be to extend the results obtained for R[G] to R[S : M], and this they achieved with much success.
- Full Text:
- Date Issued: 2007
Problematising race for journalists: critical reflections on the South African Human Rights Commission Inquiry into media racism
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147913 , vital:38684 , DOI: 10.1080/02560240185310081
- Description: How journalists report race and racism was at the centre of the South African Human Rights Commission (SAHRC) Inquiry into racism in the media. A critical analysis of the conceptual assumptions in the Inquiry's Final Report, however, reveals serious limitations to the enterprise. In particular the flawed conceptualisations, plus the generalised character of the findings are of little help in assisting the momentum of eradicating racism in South African media, and for linking race transformation to issues of class, gender, sexual orientation and xenophobia. This article identifies the problems as race essentialism and a relativism about what constitutes racism. It argues instead that journalists need the concept of racialisation in order to change their reporting. The argument upholds the desired role of the South African media as one that contributes to a non-racial, as opposed to a multi-racial, society.
- Full Text:
- Date Issued: 2007
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147913 , vital:38684 , DOI: 10.1080/02560240185310081
- Description: How journalists report race and racism was at the centre of the South African Human Rights Commission (SAHRC) Inquiry into racism in the media. A critical analysis of the conceptual assumptions in the Inquiry's Final Report, however, reveals serious limitations to the enterprise. In particular the flawed conceptualisations, plus the generalised character of the findings are of little help in assisting the momentum of eradicating racism in South African media, and for linking race transformation to issues of class, gender, sexual orientation and xenophobia. This article identifies the problems as race essentialism and a relativism about what constitutes racism. It argues instead that journalists need the concept of racialisation in order to change their reporting. The argument upholds the desired role of the South African media as one that contributes to a non-racial, as opposed to a multi-racial, society.
- Full Text:
- Date Issued: 2007
Psychosocial barriers to learning in a deprived environment
- Authors: Mack, Esmé Judy
- Date: 2007
- Subjects: Students -- South Africa -- Port Alizabeth -- Social conditions , Children with social disabilities -- Education -- South Africa -- Port Elizabeth , Learning disabilities -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:9481 , http://hdl.handle.net/10948/551 , Students -- South Africa -- Port Alizabeth -- Social conditions , Children with social disabilities -- Education -- South Africa -- Port Elizabeth , Learning disabilities -- South Africa
- Description: Many secondary schools in deprived environments are characterized by teenage pregnancies, drug and alcohol abuse, crime, high dropout rates, gangsterism and low pass rates. Teachers are confronted on a daily basis with learners who are exposed to barriers to learning. The purpose of this study is in line with the formulated problem, namely to: investigate the various dimensions of the relationship that exists between psychosocial barriers to learning and environmental deprivation; provide guidelines based on the findings of the research and present them as recommendations for teachers to support learners from a deprived environment who experience barriers to learning. A qualitative, exploratory, descriptive and interpretative research design was utilized to provide acceptable answers to the research problem. A literature study regarding psychosocial barriers to learning was done to explain the concept along with concepts related to environmental deprivation. This study was conducted in two phases: Phase 1 presented an exploration of the problem in the form of a single openended question: What hindrances to learning are you experiencing in your specific physical and social environment? Eight focus group interviews with learners were undertaken at a secondary school in the Nelson Mandela Metropolitan Municipality. A purposive sampling method was used. Data collection took place through open-ended interviews and Tesch’s model was used to analyse the data. After the research investigation was completed the researcher and an independent coder analyzed iv the results from the transcriptions of a voice-recorder. Guba’s model of data verification was used to ensure the trustworthiness of the data. Ethical measures were adhered to during the study. The research findings were evaluated for educational purposes. Consensus was reached between the researcher and the independent coder with regard to the identification of themes, categories and sub-categories. Phase 2 generated recommendations from the findings of Phase 1 to assist the teachers in dealing competently with learners from deprived environments. The following four themes emerged from the results which led to various conclusions: 1. A deprived home situation (relationships, abuse, no privacy, and poverty) generates barriers to learning. Neglect: no interest and a don’t care attitude of parents, no parents at home, rejection and no communication have a negative effect on the learners. Physical, sexual, alcohol and drug abuse in the home situation influence the learners negatively. No privacy: sexual behaviour of parents and overcrowding have a decisive effect on the learners. Poverty: factors such as unemployment, cannot afford school fees, no electricity and no breadwinner make the learner feel desperate and despondent. 2. A deprived school situation (social relationships, physical factors, no resources, racism and distances to school) creates barriers to learning. The following features of social relationships were identified as contributing factors to poor social relationships at school, namely: peer pressure: drugs, dropping out of school, unsafe school environment; relationships with teachers: no respect for teachers and teachers who degrade learners. The following physical factors have a detrimental effect on a learner’s progress: broken windows and roofs, lack of water, electricity and lights, the state of the school grounds, ablutions and big classes. Schools with no resources such as libraries and counselling centres contribute to the poor performance of the learners. Racism, language issues and no mixing of races are contributing factors to barriers to learning. The long distances to school, the cost of transport and the fact that they do not have time for homework affect the learners as hindrances to learning. 3. A deprived environment (with factors such as HIV/AIDS and TB, a community not conducive to learning, unsafe communities and overpopulation) causes barriers to learning. HIV/AIDS and TB, taking care of parents, tiredness, illnesses and discrimination are seen as factors that hamper learning. A community that is not conducive to learning, with a don’t care attitude and that is not very helpful, causes barriers to learning. Unsafe communities, where crime is rampant, with ineffective police services and overpopulation, where noise and loud music are the order of the day, have a negative effect on learning. 4. Learner-related factors (early pregnancies and the susceptibility of youth) create barriers to learning. Teenage pregnancies are detrimental to education where the mother must baby-sit, and is not studying, as well as sexual abuse and rape, are factors that contribute to school dropouts. Cigarettes, drugs, alcohol, taverns, discos, taxis and gangs were identified as factors contributing to learner delinquency. The conclusion was reached that learners in deprived environments are exposed to psychosocial barriers to learning. Recommendations in this regard were proposed to assist the teacher in understanding these learners and the barriers that they are exposed to on a daily basis.
- Full Text:
- Date Issued: 2007
- Authors: Mack, Esmé Judy
- Date: 2007
- Subjects: Students -- South Africa -- Port Alizabeth -- Social conditions , Children with social disabilities -- Education -- South Africa -- Port Elizabeth , Learning disabilities -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:9481 , http://hdl.handle.net/10948/551 , Students -- South Africa -- Port Alizabeth -- Social conditions , Children with social disabilities -- Education -- South Africa -- Port Elizabeth , Learning disabilities -- South Africa
- Description: Many secondary schools in deprived environments are characterized by teenage pregnancies, drug and alcohol abuse, crime, high dropout rates, gangsterism and low pass rates. Teachers are confronted on a daily basis with learners who are exposed to barriers to learning. The purpose of this study is in line with the formulated problem, namely to: investigate the various dimensions of the relationship that exists between psychosocial barriers to learning and environmental deprivation; provide guidelines based on the findings of the research and present them as recommendations for teachers to support learners from a deprived environment who experience barriers to learning. A qualitative, exploratory, descriptive and interpretative research design was utilized to provide acceptable answers to the research problem. A literature study regarding psychosocial barriers to learning was done to explain the concept along with concepts related to environmental deprivation. This study was conducted in two phases: Phase 1 presented an exploration of the problem in the form of a single openended question: What hindrances to learning are you experiencing in your specific physical and social environment? Eight focus group interviews with learners were undertaken at a secondary school in the Nelson Mandela Metropolitan Municipality. A purposive sampling method was used. Data collection took place through open-ended interviews and Tesch’s model was used to analyse the data. After the research investigation was completed the researcher and an independent coder analyzed iv the results from the transcriptions of a voice-recorder. Guba’s model of data verification was used to ensure the trustworthiness of the data. Ethical measures were adhered to during the study. The research findings were evaluated for educational purposes. Consensus was reached between the researcher and the independent coder with regard to the identification of themes, categories and sub-categories. Phase 2 generated recommendations from the findings of Phase 1 to assist the teachers in dealing competently with learners from deprived environments. The following four themes emerged from the results which led to various conclusions: 1. A deprived home situation (relationships, abuse, no privacy, and poverty) generates barriers to learning. Neglect: no interest and a don’t care attitude of parents, no parents at home, rejection and no communication have a negative effect on the learners. Physical, sexual, alcohol and drug abuse in the home situation influence the learners negatively. No privacy: sexual behaviour of parents and overcrowding have a decisive effect on the learners. Poverty: factors such as unemployment, cannot afford school fees, no electricity and no breadwinner make the learner feel desperate and despondent. 2. A deprived school situation (social relationships, physical factors, no resources, racism and distances to school) creates barriers to learning. The following features of social relationships were identified as contributing factors to poor social relationships at school, namely: peer pressure: drugs, dropping out of school, unsafe school environment; relationships with teachers: no respect for teachers and teachers who degrade learners. The following physical factors have a detrimental effect on a learner’s progress: broken windows and roofs, lack of water, electricity and lights, the state of the school grounds, ablutions and big classes. Schools with no resources such as libraries and counselling centres contribute to the poor performance of the learners. Racism, language issues and no mixing of races are contributing factors to barriers to learning. The long distances to school, the cost of transport and the fact that they do not have time for homework affect the learners as hindrances to learning. 3. A deprived environment (with factors such as HIV/AIDS and TB, a community not conducive to learning, unsafe communities and overpopulation) causes barriers to learning. HIV/AIDS and TB, taking care of parents, tiredness, illnesses and discrimination are seen as factors that hamper learning. A community that is not conducive to learning, with a don’t care attitude and that is not very helpful, causes barriers to learning. Unsafe communities, where crime is rampant, with ineffective police services and overpopulation, where noise and loud music are the order of the day, have a negative effect on learning. 4. Learner-related factors (early pregnancies and the susceptibility of youth) create barriers to learning. Teenage pregnancies are detrimental to education where the mother must baby-sit, and is not studying, as well as sexual abuse and rape, are factors that contribute to school dropouts. Cigarettes, drugs, alcohol, taverns, discos, taxis and gangs were identified as factors contributing to learner delinquency. The conclusion was reached that learners in deprived environments are exposed to psychosocial barriers to learning. Recommendations in this regard were proposed to assist the teacher in understanding these learners and the barriers that they are exposed to on a daily basis.
- Full Text:
- Date Issued: 2007
Public sector industrial relations in the context of alliance politics: the case of Makana Local Municipality, South Africa (1994-2006)
- Authors: Makwembere, Sandra
- Date: 2007
- Subjects: Makana Municipality , South African Municipal Workers Union , African National Congress , Cosatu , South African Communist Party , Local government -- South Africa -- Eastern Cape , Industrial relations -- South Africa -- Eastern Cape , Labor unions -- South Africa , South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3301 , http://hdl.handle.net/10962/d1003089 , Makana Municipality , South African Municipal Workers Union , African National Congress , Cosatu , South African Communist Party , Local government -- South Africa -- Eastern Cape , Industrial relations -- South Africa -- Eastern Cape , Labor unions -- South Africa , South Africa -- Politics and government -- 1994-
- Description: This thesis is in the field of Industrial Relations. It concerns a micro-level investigation of the dynamics of public sector industrial relations in post-apartheid South Africa. It focuses on the Tripartite Alliance between the African National Congress (ANC), the South African Communist Party (SACP) and the Congress of South African Trade Unions (COSATU) and explores what the Alliance relationship has meant for the traditional roles of employees and their representatives on the one hand, and employers and their representatives on the other. The thesis examines the political, organisational and societal contradictions and implications for COSATU public sector union affiliates and their members in their relationship to the ANC as an ally (via the Alliance) and the context in which ANC members form part of management (in government). The South African Municipal Workers’ Union (SAMWU) was used as an archetype of a COSATU public sector union affiliate that engages with the State as employer at the municipal level. It is a case study of Makana Local Municipality (Eastern Cape Province, South Africa) using qualitative research techniques and content analysis to derive the relevant information. The author conducted a series of in-depth interviews of key informants and observations at Makana Local Municipality were done. Based on the empirical data obtained from the investigation, the thesis argues that the traditional roles in the employment relationship at the workplace have been affected by the political alliance. Industrial relations roles have become increasingly vague especially since many within local government share ANC/SACP memberships with members of the trade union. The study also highlights that within an increasingly globalising post-apartheid environment, the Alliance provides mixture of benefits and challenges for workplace negotiations and employment relations in ways that macro-level analyses of employer-employee relationships do not always capture.
- Full Text:
- Date Issued: 2007
- Authors: Makwembere, Sandra
- Date: 2007
- Subjects: Makana Municipality , South African Municipal Workers Union , African National Congress , Cosatu , South African Communist Party , Local government -- South Africa -- Eastern Cape , Industrial relations -- South Africa -- Eastern Cape , Labor unions -- South Africa , South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:3301 , http://hdl.handle.net/10962/d1003089 , Makana Municipality , South African Municipal Workers Union , African National Congress , Cosatu , South African Communist Party , Local government -- South Africa -- Eastern Cape , Industrial relations -- South Africa -- Eastern Cape , Labor unions -- South Africa , South Africa -- Politics and government -- 1994-
- Description: This thesis is in the field of Industrial Relations. It concerns a micro-level investigation of the dynamics of public sector industrial relations in post-apartheid South Africa. It focuses on the Tripartite Alliance between the African National Congress (ANC), the South African Communist Party (SACP) and the Congress of South African Trade Unions (COSATU) and explores what the Alliance relationship has meant for the traditional roles of employees and their representatives on the one hand, and employers and their representatives on the other. The thesis examines the political, organisational and societal contradictions and implications for COSATU public sector union affiliates and their members in their relationship to the ANC as an ally (via the Alliance) and the context in which ANC members form part of management (in government). The South African Municipal Workers’ Union (SAMWU) was used as an archetype of a COSATU public sector union affiliate that engages with the State as employer at the municipal level. It is a case study of Makana Local Municipality (Eastern Cape Province, South Africa) using qualitative research techniques and content analysis to derive the relevant information. The author conducted a series of in-depth interviews of key informants and observations at Makana Local Municipality were done. Based on the empirical data obtained from the investigation, the thesis argues that the traditional roles in the employment relationship at the workplace have been affected by the political alliance. Industrial relations roles have become increasingly vague especially since many within local government share ANC/SACP memberships with members of the trade union. The study also highlights that within an increasingly globalising post-apartheid environment, the Alliance provides mixture of benefits and challenges for workplace negotiations and employment relations in ways that macro-level analyses of employer-employee relationships do not always capture.
- Full Text:
- Date Issued: 2007
Purchasing determinants of food insercurity conditions amongst shoppers in Klipplaat
- Ballantine, Nicole Marguerite
- Authors: Ballantine, Nicole Marguerite
- Date: 2007
- Subjects: Food -- Safety measures , Food supply -- South Africa -- Klipplaat , Households -- South Africa -- Klipplaat , Quality of life -- South Africa -- Klipplaat
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9404 , http://hdl.handle.net/10948/835 , Food -- Safety measures , Food supply -- South Africa -- Klipplaat , Households -- South Africa -- Klipplaat , Quality of life -- South Africa -- Klipplaat
- Description: This study sought to investigate the purchasing determinants of food insecurity conditions in Klipplaat, in the Eastern Cape. The study comprised a pilot study and main study (n=459) making use of an adapted version of the Household Food Insecurity Access Scale. It was found that food insecurity conditions in Klipplaat were high, with most households experiencing food insecurity conditions between three and ten times per month. Income level was found to have a significant effect on food insecurity conditions in Klipplaat. The availability of efficient transport and refrigeration was also found to significantly influence the experience of food insecurity conditions.
- Full Text:
- Date Issued: 2007
- Authors: Ballantine, Nicole Marguerite
- Date: 2007
- Subjects: Food -- Safety measures , Food supply -- South Africa -- Klipplaat , Households -- South Africa -- Klipplaat , Quality of life -- South Africa -- Klipplaat
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9404 , http://hdl.handle.net/10948/835 , Food -- Safety measures , Food supply -- South Africa -- Klipplaat , Households -- South Africa -- Klipplaat , Quality of life -- South Africa -- Klipplaat
- Description: This study sought to investigate the purchasing determinants of food insecurity conditions in Klipplaat, in the Eastern Cape. The study comprised a pilot study and main study (n=459) making use of an adapted version of the Household Food Insecurity Access Scale. It was found that food insecurity conditions in Klipplaat were high, with most households experiencing food insecurity conditions between three and ten times per month. Income level was found to have a significant effect on food insecurity conditions in Klipplaat. The availability of efficient transport and refrigeration was also found to significantly influence the experience of food insecurity conditions.
- Full Text:
- Date Issued: 2007