A framework to evaluate usable security in online social networking
- Authors: Yeratziotis, Alexandros
- Date: 2011
- Subjects: Online social networks -- Security measures , Computer security , Data protection
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:9807 , http://hdl.handle.net/10948/d1012933
- Description: It is commonly held in the literature that users find security and privacy difficult to comprehend. It is also acknowledged that most end-user applications and websites have built-in security and privacy features. Users are expected to interact with these in order to protect their personal information. However, security is generally a secondary goal for users. Considering the complexity associated with security in combination with the notion that it is not users’ primary task, it makes sense that users tend to ignore their security responsibilities. As a result, they make poor security-related decisions and, consequently, their personal information is at risk. Usable Security is the field that investigates these types of issue, focusing on the design of security and privacy features that are usable. In order to understand and appreciate the complexities that exist in the field of Usable Security, the research fields of Human-Computer Interaction and Information Security should be examined. Accordingly, the Information Security field is concerned with all aspects pertaining to the security and privacy of information, while the field of Human-Computer Interaction is concerned with the design, evaluation and implementation of interactive computing systems for human use. This research delivers a framework to evaluate Usable Security in online social networks. In this study, online social networks that are particular to the health domain were used as a case study and contributed to the development of a framework consisting of three components: a process, a validation tool and a Usable Security heuristic evaluation. There is no existing qualitative process that describes how one would develop and validate a heuristic evaluation. In this regard a heuristic evaluation is a usability inspection method that is used to evaluate the design of an interface for any usability violations in the field of Human-Computer Interaction. Therefore, firstly, a new process and a validation tool were required to be developed. Once this had been achieved, the process could then be followed to develop a new heuristic evaluation that is specific to Usable Security. In order to assess the validity of a new heuristic evaluation a validation tool is used. The development of tools that can improve the design of security and privacy features on end-user applications and websites in terms of their usability is critical, as this will ensure that the intended users experience them as usable and can utilise them effectively. The framework for evaluating Usable Security contributes to this objective in the context of online social networks.
- Full Text:
- Date Issued: 2011
- Authors: Yeratziotis, Alexandros
- Date: 2011
- Subjects: Online social networks -- Security measures , Computer security , Data protection
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:9807 , http://hdl.handle.net/10948/d1012933
- Description: It is commonly held in the literature that users find security and privacy difficult to comprehend. It is also acknowledged that most end-user applications and websites have built-in security and privacy features. Users are expected to interact with these in order to protect their personal information. However, security is generally a secondary goal for users. Considering the complexity associated with security in combination with the notion that it is not users’ primary task, it makes sense that users tend to ignore their security responsibilities. As a result, they make poor security-related decisions and, consequently, their personal information is at risk. Usable Security is the field that investigates these types of issue, focusing on the design of security and privacy features that are usable. In order to understand and appreciate the complexities that exist in the field of Usable Security, the research fields of Human-Computer Interaction and Information Security should be examined. Accordingly, the Information Security field is concerned with all aspects pertaining to the security and privacy of information, while the field of Human-Computer Interaction is concerned with the design, evaluation and implementation of interactive computing systems for human use. This research delivers a framework to evaluate Usable Security in online social networks. In this study, online social networks that are particular to the health domain were used as a case study and contributed to the development of a framework consisting of three components: a process, a validation tool and a Usable Security heuristic evaluation. There is no existing qualitative process that describes how one would develop and validate a heuristic evaluation. In this regard a heuristic evaluation is a usability inspection method that is used to evaluate the design of an interface for any usability violations in the field of Human-Computer Interaction. Therefore, firstly, a new process and a validation tool were required to be developed. Once this had been achieved, the process could then be followed to develop a new heuristic evaluation that is specific to Usable Security. In order to assess the validity of a new heuristic evaluation a validation tool is used. The development of tools that can improve the design of security and privacy features on end-user applications and websites in terms of their usability is critical, as this will ensure that the intended users experience them as usable and can utilise them effectively. The framework for evaluating Usable Security contributes to this objective in the context of online social networks.
- Full Text:
- Date Issued: 2011
The efficacy and toxicological effects of aloe ferox mill. used in the management of constipation in Nkonkobe municipality of the Eastern Cape province, South Africa
- Authors: Wintola, Olubunmi Abosede A
- Date: 2011
- Subjects: Asphodelaceae -- South Africa -- Eastern Cape , Aloe -- South Africa -- Eastern Cape , Herbs -- Therapeutic use -- South Africa -- Eastern Cape , Medicinal plants -- South Africa -- Eastern Cape , Constipation -- South Africa -- Eastern Cape , Poisonous plants -- South Africa -- Eastern Cape , Traditional medicine -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD (Ethnobotany)
- Identifier: vital:11882 , http://hdl.handle.net/10353/485 , Asphodelaceae -- South Africa -- Eastern Cape , Aloe -- South Africa -- Eastern Cape , Herbs -- Therapeutic use -- South Africa -- Eastern Cape , Medicinal plants -- South Africa -- Eastern Cape , Constipation -- South Africa -- Eastern Cape , Poisonous plants -- South Africa -- Eastern Cape , Traditional medicine -- South Africa -- Eastern Cape
- Description: Herbal remedies are commonly used in developing countries for the treatment of various diseases, including constipation. The rationale for utilizing medicinal plants for the treatment of diseases rested largely on the belief that they are safe and free of side effects. However, there is limited scientific evidence on the safety and efficacy of these herbal medicines to back up their continued therapeutic application. Aloe ferox Mill. (Aspodelaceae), known as Cape aloe, locally called ikhala is a medicinal plant used by the people of the Eastern Cape Province for the treatment of gastrointestinal problems and constipation. The plant is a perennial shrub with thick succulent leaves bearing brown thorns on the margin and bright orange flowers arranged in oval lanceolate. It occurs in all weather in bush veld, road side, gardens and undisturbed places. According to the ethnomedicinal information, A. ferox is used as purgative. This research project was therefore designed to evaluate its ability in the treatment of constipation and to investigate its possible toxicological property. At the beginning of this programme, a survey of plants used for the treatment of constipation in Nkonkobe Municipality of the Eastern Cape Province was carried out using a questionnaire, which was administered to herbalists, traditional healers and rural dwellers. The study revealed 10 plant species from 8 families that are used for the treatment of constipation in the province. Four plants, Aloe ferox Mill, Boophone distischa L.f Herb, Alepidea amatybica Eckl and Artemisia afra Jacq, were repeatedly mentioned. Based on the frequency of usage, perceived efficacy and availability to the rural dwellers and the traditional healers, Aloe ferox was the most commonly used of the plants for the treatment of constipation. The plant was thus, chosen for the study. The invivo laxative effect of the aqueous extract of Aloe ferox in the treatment of loperamide-induced constipation in Wistar rats was investigated at varying concentrations. The leaf extract at all the dosages investigated (50, 100 and 200 mg/kg body weight) improved intestinal motility, increased fecal volume and normalized body weight in the constipated rats. This was an indication of its laxative properties. However, the laxative property of the herb at 200 mg/kg body weight of the extract showed best efficacy and compares favourably well with senokot, a standard laxative drug. These findings have therefore, lent scientific credence to the folkloric use of the herb by the people of the Eastern Cape of South Africa as a laxative agent. Toxicological evaluation of aqueous leaf extract of Aloe ferox in loperamide-induced constipation was studied at 50, 100, and 200 mg/kg body weight. The oral administration of the extracts did not show any significant effect on the liver and kidney body weight ratios as well as the kidney and liver function indices. The extracts, at all the dosages investigated, did not alter the levels of creatinine, uric acid, urea, calcium and potassium ions. Similarly, the levels of total protein, albumin, bilirubin and gamma glutamyl transferase (GGT) were not significantly different from the control. The plant extract appreciably normalized the elevated activities of alkaline phosphatase (ALP), alanine transaminase (ALT) and aspartate transaminase (AST) in the untreated constipated rats following treatment with the extract. The extract did not show a significant effect on the hematological parameters except for the increase in the lymphocyte count in the untreated constipated rats, which was attenuated after administering the herb. ThThe available evidence in this study suggests that A. ferox may be safe as an oral remedy for constipation. Generally, the effect of the extract compared favourably well with senokot, a recommended drug for the treatment of constipation. The antioxidant activities against 1, 1 diphenyl- 2 picrylhydrazl (DPPH), 2,2’ – azinobis [3- ethylbenzothiazoline -6- sulfonic acid] diammonium salt (ABTS), hydrogen peroxide (H2O2), Nitric oxide (NO), lipid peroxidation and the ferric reducing agents were investigated spectrophotometrically. Alkaloids, saponins, tannins, total phenols, flavonoids, flavonols and proanthocyanidin were also determined to assess their effects on the antioxidants activity of this plant. The phytochemical content of the ethanol and acetone extracts were consistently high compared to other solvents extracts. The level of tannins was not significant (P > 0.05) as compared with other solvent extracts. The free radical scavenging activity of the extracts was high even at lower concentrations (0.025 mg/ml) except in DPPH and lipid peroxidation. The ferric reducing potential of the extracts was concentration dependent and significantly different from Vitamin C and butylated hydroxytoluene (BHT) that were used as standard drugs. The present study showed a high level of scavenging activity of the leaf extracts of Aloe ferox in all the solvent extracts. Both ethanol and methanolic extract showed potent antioxidant activities than acetone and aqueous extracts. The study indicated that the leaf extracts of Aloe ferox might be a valuable source of natural antioxidant for both medicine and food industries. A. ferox leaf consists of the gel, latex and mesophyll layer; however, the main active constituents of the latex and the leaf exudate of Aloe ferox are anthraquinones which are believed to be responsible for the laxative property. The laxative compound in Aloe ferox leaf extract was isolated and characterized by extracting the plant material in methanol and extract suspended in distilled water. Partitioning was done with n-hexane, ethyl acetate and butanol respectively and was co-spotted with the over-the-counter (OTC) laxative drugs. This led to the successive column chromatography and thin layer chromatography (TLC) of the most active ethyl acetate fraction on silica gel with benzene/ethanol/ammonia hydroxide (BEA: 90:10:1), ethyl acetate/methanol/water (EMW: 40:5.4:5) and chloroform/ethyl acetate/formic acid (CEF: 50:40:10) as the mobile phase. The successive chromatograph and TLC afforded two compounds of Rf 0.420 (blue) and 0.831 (yellow) with the over-the-counter (OTC) drugs. These compounds were not totally elucidated due to their small quantity and instability. However, hydroxyl (OH) and carboxyl groups (COOH) was established as common to the extracted compounds, which might be responsible for the biological activity recorded for the plant extract.
- Full Text:
- Date Issued: 2011
- Authors: Wintola, Olubunmi Abosede A
- Date: 2011
- Subjects: Asphodelaceae -- South Africa -- Eastern Cape , Aloe -- South Africa -- Eastern Cape , Herbs -- Therapeutic use -- South Africa -- Eastern Cape , Medicinal plants -- South Africa -- Eastern Cape , Constipation -- South Africa -- Eastern Cape , Poisonous plants -- South Africa -- Eastern Cape , Traditional medicine -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD (Ethnobotany)
- Identifier: vital:11882 , http://hdl.handle.net/10353/485 , Asphodelaceae -- South Africa -- Eastern Cape , Aloe -- South Africa -- Eastern Cape , Herbs -- Therapeutic use -- South Africa -- Eastern Cape , Medicinal plants -- South Africa -- Eastern Cape , Constipation -- South Africa -- Eastern Cape , Poisonous plants -- South Africa -- Eastern Cape , Traditional medicine -- South Africa -- Eastern Cape
- Description: Herbal remedies are commonly used in developing countries for the treatment of various diseases, including constipation. The rationale for utilizing medicinal plants for the treatment of diseases rested largely on the belief that they are safe and free of side effects. However, there is limited scientific evidence on the safety and efficacy of these herbal medicines to back up their continued therapeutic application. Aloe ferox Mill. (Aspodelaceae), known as Cape aloe, locally called ikhala is a medicinal plant used by the people of the Eastern Cape Province for the treatment of gastrointestinal problems and constipation. The plant is a perennial shrub with thick succulent leaves bearing brown thorns on the margin and bright orange flowers arranged in oval lanceolate. It occurs in all weather in bush veld, road side, gardens and undisturbed places. According to the ethnomedicinal information, A. ferox is used as purgative. This research project was therefore designed to evaluate its ability in the treatment of constipation and to investigate its possible toxicological property. At the beginning of this programme, a survey of plants used for the treatment of constipation in Nkonkobe Municipality of the Eastern Cape Province was carried out using a questionnaire, which was administered to herbalists, traditional healers and rural dwellers. The study revealed 10 plant species from 8 families that are used for the treatment of constipation in the province. Four plants, Aloe ferox Mill, Boophone distischa L.f Herb, Alepidea amatybica Eckl and Artemisia afra Jacq, were repeatedly mentioned. Based on the frequency of usage, perceived efficacy and availability to the rural dwellers and the traditional healers, Aloe ferox was the most commonly used of the plants for the treatment of constipation. The plant was thus, chosen for the study. The invivo laxative effect of the aqueous extract of Aloe ferox in the treatment of loperamide-induced constipation in Wistar rats was investigated at varying concentrations. The leaf extract at all the dosages investigated (50, 100 and 200 mg/kg body weight) improved intestinal motility, increased fecal volume and normalized body weight in the constipated rats. This was an indication of its laxative properties. However, the laxative property of the herb at 200 mg/kg body weight of the extract showed best efficacy and compares favourably well with senokot, a standard laxative drug. These findings have therefore, lent scientific credence to the folkloric use of the herb by the people of the Eastern Cape of South Africa as a laxative agent. Toxicological evaluation of aqueous leaf extract of Aloe ferox in loperamide-induced constipation was studied at 50, 100, and 200 mg/kg body weight. The oral administration of the extracts did not show any significant effect on the liver and kidney body weight ratios as well as the kidney and liver function indices. The extracts, at all the dosages investigated, did not alter the levels of creatinine, uric acid, urea, calcium and potassium ions. Similarly, the levels of total protein, albumin, bilirubin and gamma glutamyl transferase (GGT) were not significantly different from the control. The plant extract appreciably normalized the elevated activities of alkaline phosphatase (ALP), alanine transaminase (ALT) and aspartate transaminase (AST) in the untreated constipated rats following treatment with the extract. The extract did not show a significant effect on the hematological parameters except for the increase in the lymphocyte count in the untreated constipated rats, which was attenuated after administering the herb. ThThe available evidence in this study suggests that A. ferox may be safe as an oral remedy for constipation. Generally, the effect of the extract compared favourably well with senokot, a recommended drug for the treatment of constipation. The antioxidant activities against 1, 1 diphenyl- 2 picrylhydrazl (DPPH), 2,2’ – azinobis [3- ethylbenzothiazoline -6- sulfonic acid] diammonium salt (ABTS), hydrogen peroxide (H2O2), Nitric oxide (NO), lipid peroxidation and the ferric reducing agents were investigated spectrophotometrically. Alkaloids, saponins, tannins, total phenols, flavonoids, flavonols and proanthocyanidin were also determined to assess their effects on the antioxidants activity of this plant. The phytochemical content of the ethanol and acetone extracts were consistently high compared to other solvents extracts. The level of tannins was not significant (P > 0.05) as compared with other solvent extracts. The free radical scavenging activity of the extracts was high even at lower concentrations (0.025 mg/ml) except in DPPH and lipid peroxidation. The ferric reducing potential of the extracts was concentration dependent and significantly different from Vitamin C and butylated hydroxytoluene (BHT) that were used as standard drugs. The present study showed a high level of scavenging activity of the leaf extracts of Aloe ferox in all the solvent extracts. Both ethanol and methanolic extract showed potent antioxidant activities than acetone and aqueous extracts. The study indicated that the leaf extracts of Aloe ferox might be a valuable source of natural antioxidant for both medicine and food industries. A. ferox leaf consists of the gel, latex and mesophyll layer; however, the main active constituents of the latex and the leaf exudate of Aloe ferox are anthraquinones which are believed to be responsible for the laxative property. The laxative compound in Aloe ferox leaf extract was isolated and characterized by extracting the plant material in methanol and extract suspended in distilled water. Partitioning was done with n-hexane, ethyl acetate and butanol respectively and was co-spotted with the over-the-counter (OTC) laxative drugs. This led to the successive column chromatography and thin layer chromatography (TLC) of the most active ethyl acetate fraction on silica gel with benzene/ethanol/ammonia hydroxide (BEA: 90:10:1), ethyl acetate/methanol/water (EMW: 40:5.4:5) and chloroform/ethyl acetate/formic acid (CEF: 50:40:10) as the mobile phase. The successive chromatograph and TLC afforded two compounds of Rf 0.420 (blue) and 0.831 (yellow) with the over-the-counter (OTC) drugs. These compounds were not totally elucidated due to their small quantity and instability. However, hydroxyl (OH) and carboxyl groups (COOH) was established as common to the extracted compounds, which might be responsible for the biological activity recorded for the plant extract.
- Full Text:
- Date Issued: 2011
Post-impoundment population dynamics of non-native common carp Cyprinus Carpio in relation to two large native cyprinids in Lake Gariep, South Africa
- Authors: Winker, Henning
- Date: 2011
- Subjects: Cyprinidae -- South Africa -- Gariep Dam Carp -- South Africa -- Gariep Dam Fish populations -- South Africa -- Gariep Dam Fishes -- Physiology -- South Africa -- Gariep Dam Barbus aeneus -- South Africa -- Gariep Dam Mudfishes -- South Africa -- Gariep Dam Freshwater fishes -- South Africa -- Gariep Dam
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5311 , http://hdl.handle.net/10962/d1005156
- Description: To contribute to the understanding of the invasion biology of common carp Cyprinus carpio in southern Africa, this thesis investigated the life history, relative abundance, long-term population demographics and trophic niche utilisations of non-native common carp C. carpio in relation to two endemic cyprinids, Orange River mudfish Labeo capensis and smallmouth yellowfish Labeobarbus aeneus in South Africa‟s largest impoundment, Lake Gariep. The growth zone deposition rates in astericus otoliths of the three species were validated as biannual for C. carpio and as annual for L. capensis and L. aeneus, which allowed for reliable estimation of lengths-at-age upon which growth, age-at-maturity and mortality rates could be estimated. Cyprinus carpio exhibited fast growth, matured relatively early at two years of age and attained a maximum age of seven years. Labeo capensis grew significantly slower, but attained older ages of up to 12 years. Females showed notably delayed maturation at approximately six years of age. The life history parameter estimates for L. aeneus were similar to those of L. capensis. These species-specific life history characteristics contributed to a substantially higher population growth potential of C. carpio compared to L. capensis and L. aeneus. Delta-lognormal and delta-gamma Generalized Linear Models (GLMs) were used to analyse patterns of relative abundance of L. capensis, L. aeneus and C. carpio. The application of these GLMs was necessary to account for large proportions of zeros and strong skewness in the catch-per-unit-effort (CPUE) from experimental gillnet and fisheries-dependent angler surveys. Confidence intervals around predicted abundance indices were obtained through the development of a generalised parametric bootstrap procedure. The resulting standardised abundance indices were coupled with results from analysis of stable isotope ratios of fish tissues and potential food resources and revealed that C. carpio was mainly confined to soft-bottom habitats, where it predominantly foraged on benthic invertebrates. Labeo capensis was abundant in a wide range of benthic habitats and was consumed basal food resources such as detritus. Labeobarbus aeneus was found to feed mostly on pelagic zooplankton. There were no significant interspecific differences in trophic niche space, suggesting limited resource competition among the three species. Standardised historical and contemporary gillnet CPUE data indicated slow population growth rates of L. capensis and L. aeneus during the first ten years postimpoundment, but showed high biomass levels some four decades after impoundment. These results could be corroborated by stochastic age-structured production model (ASPM) simulations. In contrast to the two endemic species, the gillnet CPUE of C. carpio showed a clear „boom and bust‟ pattern, which, based on ASPM simulations, could be best explained by increased food availability during the first five years postimpoundment, followed by suboptimal conditions thereafter. Together, these results provided evidence that the establishment of the C. carpio population did not prevent the slow but successful long-term establishment of the two large endemic cyprinids. Both endemic fishes revealed specialised feeding within the impoundment.
- Full Text:
- Date Issued: 2011
- Authors: Winker, Henning
- Date: 2011
- Subjects: Cyprinidae -- South Africa -- Gariep Dam Carp -- South Africa -- Gariep Dam Fish populations -- South Africa -- Gariep Dam Fishes -- Physiology -- South Africa -- Gariep Dam Barbus aeneus -- South Africa -- Gariep Dam Mudfishes -- South Africa -- Gariep Dam Freshwater fishes -- South Africa -- Gariep Dam
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5311 , http://hdl.handle.net/10962/d1005156
- Description: To contribute to the understanding of the invasion biology of common carp Cyprinus carpio in southern Africa, this thesis investigated the life history, relative abundance, long-term population demographics and trophic niche utilisations of non-native common carp C. carpio in relation to two endemic cyprinids, Orange River mudfish Labeo capensis and smallmouth yellowfish Labeobarbus aeneus in South Africa‟s largest impoundment, Lake Gariep. The growth zone deposition rates in astericus otoliths of the three species were validated as biannual for C. carpio and as annual for L. capensis and L. aeneus, which allowed for reliable estimation of lengths-at-age upon which growth, age-at-maturity and mortality rates could be estimated. Cyprinus carpio exhibited fast growth, matured relatively early at two years of age and attained a maximum age of seven years. Labeo capensis grew significantly slower, but attained older ages of up to 12 years. Females showed notably delayed maturation at approximately six years of age. The life history parameter estimates for L. aeneus were similar to those of L. capensis. These species-specific life history characteristics contributed to a substantially higher population growth potential of C. carpio compared to L. capensis and L. aeneus. Delta-lognormal and delta-gamma Generalized Linear Models (GLMs) were used to analyse patterns of relative abundance of L. capensis, L. aeneus and C. carpio. The application of these GLMs was necessary to account for large proportions of zeros and strong skewness in the catch-per-unit-effort (CPUE) from experimental gillnet and fisheries-dependent angler surveys. Confidence intervals around predicted abundance indices were obtained through the development of a generalised parametric bootstrap procedure. The resulting standardised abundance indices were coupled with results from analysis of stable isotope ratios of fish tissues and potential food resources and revealed that C. carpio was mainly confined to soft-bottom habitats, where it predominantly foraged on benthic invertebrates. Labeo capensis was abundant in a wide range of benthic habitats and was consumed basal food resources such as detritus. Labeobarbus aeneus was found to feed mostly on pelagic zooplankton. There were no significant interspecific differences in trophic niche space, suggesting limited resource competition among the three species. Standardised historical and contemporary gillnet CPUE data indicated slow population growth rates of L. capensis and L. aeneus during the first ten years postimpoundment, but showed high biomass levels some four decades after impoundment. These results could be corroborated by stochastic age-structured production model (ASPM) simulations. In contrast to the two endemic species, the gillnet CPUE of C. carpio showed a clear „boom and bust‟ pattern, which, based on ASPM simulations, could be best explained by increased food availability during the first five years postimpoundment, followed by suboptimal conditions thereafter. Together, these results provided evidence that the establishment of the C. carpio population did not prevent the slow but successful long-term establishment of the two large endemic cyprinids. Both endemic fishes revealed specialised feeding within the impoundment.
- Full Text:
- Date Issued: 2011
Using social marketing to bridge the gap between systematic conservation planning and implementation at the local government level
- Authors: Wilhelm-Rechmann, Angelika
- Date: 2011
- Subjects: Nature conservation -- South Africa -- Eastern Cape , Land use -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10603 , http://hdl.handle.net/10948/1550 , Nature conservation -- South Africa -- Eastern Cape , Land use -- South Africa -- Eastern Cape
- Description: The study presented here describes an attempt to bridge the gap between systematic conservation assessment and decision-making for land-use planning in the Eastern Cape province, South Africa. The aim was to investigate how to effectively convince officials concerned with land use planning processes in the local municipal sphere to include conservation priorities meaningfully in their processes. The approach used to reach this aim was social marketing, the use of marketing technologies and concepts to effect behavior changes to further societal good. So far social marketing is not commonly used in the conservation domain; I therefore aimed also at proving the usefulness of this approach for conservation. Following the introduction which provides background to the project and a more detailed summary, Chapter 2 provides a detailed and comprehensive review of the considerations and concepts regarding the use of social marketing in a context geared at protecting nature. The research on the primary target group for this study, officials concerned with land use planning processes in the local municipal sphere is described in Chapter 3. The main outcomes were that land use planners perceive few needs with regards to implementing the incorporation of biodiversity conservation issues in the land use planning process, and that the deficiencies in the land use planning process per se, as well as the lack of recognition in the political sphere (the domain of elected councilors), represent the core barriers to adopting the conservation priorities. I conclude that to effect behavior change towards adoption of conservation priorities the land use planning processes need to be supported and the political sphere need to be included in the behavior change process. 6 Chapter 4 therefore focuses on the new target group that emerged as essential in the previous chapter, locally elected councilors. I found that councilors do actually consider land use planning procedures as being important, but also as being dysfunctional. Councilors do value their natural environment for themselves as well as for its tourism value, but most councilors had little understanding of what the term “biodiversity” means and did not connect the term “sustainability” with the natural environment. It became also evident, that councilors do not see conservation in a predominantly positive manner. Chapter 5 therefore yields insight on councilor’s perception that environmental protection and development are mutually exclusive, and the negative frames attached to the conservation endeavor as being socially unjust, disrespectful and utopian. In Chapter 6 I investigated the usefulness of a tractable and well established measure of environmental attitudes or beliefs. I assessed my target audience’s responses to the New Ecological Paradigm scale and the Inclusion of Nature in Self scale. I conclude in Chapter 7 with an account of the difficulties I encountered during the project, an assessment of my project from a social marketing perspective, components of my project that did not yield the results expected, and a proposal for future research.
- Full Text:
- Date Issued: 2011
- Authors: Wilhelm-Rechmann, Angelika
- Date: 2011
- Subjects: Nature conservation -- South Africa -- Eastern Cape , Land use -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10603 , http://hdl.handle.net/10948/1550 , Nature conservation -- South Africa -- Eastern Cape , Land use -- South Africa -- Eastern Cape
- Description: The study presented here describes an attempt to bridge the gap between systematic conservation assessment and decision-making for land-use planning in the Eastern Cape province, South Africa. The aim was to investigate how to effectively convince officials concerned with land use planning processes in the local municipal sphere to include conservation priorities meaningfully in their processes. The approach used to reach this aim was social marketing, the use of marketing technologies and concepts to effect behavior changes to further societal good. So far social marketing is not commonly used in the conservation domain; I therefore aimed also at proving the usefulness of this approach for conservation. Following the introduction which provides background to the project and a more detailed summary, Chapter 2 provides a detailed and comprehensive review of the considerations and concepts regarding the use of social marketing in a context geared at protecting nature. The research on the primary target group for this study, officials concerned with land use planning processes in the local municipal sphere is described in Chapter 3. The main outcomes were that land use planners perceive few needs with regards to implementing the incorporation of biodiversity conservation issues in the land use planning process, and that the deficiencies in the land use planning process per se, as well as the lack of recognition in the political sphere (the domain of elected councilors), represent the core barriers to adopting the conservation priorities. I conclude that to effect behavior change towards adoption of conservation priorities the land use planning processes need to be supported and the political sphere need to be included in the behavior change process. 6 Chapter 4 therefore focuses on the new target group that emerged as essential in the previous chapter, locally elected councilors. I found that councilors do actually consider land use planning procedures as being important, but also as being dysfunctional. Councilors do value their natural environment for themselves as well as for its tourism value, but most councilors had little understanding of what the term “biodiversity” means and did not connect the term “sustainability” with the natural environment. It became also evident, that councilors do not see conservation in a predominantly positive manner. Chapter 5 therefore yields insight on councilor’s perception that environmental protection and development are mutually exclusive, and the negative frames attached to the conservation endeavor as being socially unjust, disrespectful and utopian. In Chapter 6 I investigated the usefulness of a tractable and well established measure of environmental attitudes or beliefs. I assessed my target audience’s responses to the New Ecological Paradigm scale and the Inclusion of Nature in Self scale. I conclude in Chapter 7 with an account of the difficulties I encountered during the project, an assessment of my project from a social marketing perspective, components of my project that did not yield the results expected, and a proposal for future research.
- Full Text:
- Date Issued: 2011
Thermal degradation of diamond compacts: a TEM investigation
- Authors: Westraadt, Johan Ewald
- Date: 2011
- Subjects: Materials -- Thermal properties Chemical weathering
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/10829 , vital:26827
- Description: Diamond compacts consist of fine diamond grains bonded together by using high pressure and high temperature. In this study transmission electron microscopy (TEM)was used to study thermal degradation of diamond compacts. Three different types of diamond compacts – namely cobalt polycrystalline diamond (PCD), calcium carbonate PCD, and diamond-SiC composites – were investigated with TEM to understand the processes that occur during synthesis. These compacts were then heated in inert atmospheres and the chemical changes studied with TEM. It was found that PCD, using cobalt as a bonding agent, will degrade after exposure to temperatures above 750ºC. The cobalt pools contain tungsten in solid solution. During heat treatment above 700ºC the solid solution tungsten combines with cobalt and dissolved carbon to form η-phase particles at the cobalt/diamond interface. At higher temperatures or insufficient tungsten levels the rate of dissolved carbon, into the cobalt pool, is too high and the excess carbon will form as graphite in the cobalt pool. Increased levels of solid solution tungsten, in the cobalt, is expected to delay the onset of graphitization in the diamond compact, thereby increasing the thermal stability of the diamond compact. Non-metallic PCD using calcium carbonate as a bonding agent was successfully sintered in this study. TEM revealed similar micro-structural features as in cobalt based PCD. No signs of thermal degradation were found after exposure to 1200ºC in vacuum for this PCD. Contaminants introduced during processing prevented a detailed study of the binder in this system. The effect of substitutional metal atoms and plastic deformation of diamond on the thermal stability of diamond-SiC composites were investigated. A piston cylinder press was developed and used to synthesize diamond-SiC composites with different levels of plastically deformed diamond. It was concluded that substitutional metal atoms and plastic deformation of diamond grains play no role in the thermal degradation of diamond compacts at 750ºC. The thermal degradation of cobalt PCD is therefore completely determined by the cobalt/diamond interaction at 750ºC.
- Full Text:
- Date Issued: 2011
- Authors: Westraadt, Johan Ewald
- Date: 2011
- Subjects: Materials -- Thermal properties Chemical weathering
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/10829 , vital:26827
- Description: Diamond compacts consist of fine diamond grains bonded together by using high pressure and high temperature. In this study transmission electron microscopy (TEM)was used to study thermal degradation of diamond compacts. Three different types of diamond compacts – namely cobalt polycrystalline diamond (PCD), calcium carbonate PCD, and diamond-SiC composites – were investigated with TEM to understand the processes that occur during synthesis. These compacts were then heated in inert atmospheres and the chemical changes studied with TEM. It was found that PCD, using cobalt as a bonding agent, will degrade after exposure to temperatures above 750ºC. The cobalt pools contain tungsten in solid solution. During heat treatment above 700ºC the solid solution tungsten combines with cobalt and dissolved carbon to form η-phase particles at the cobalt/diamond interface. At higher temperatures or insufficient tungsten levels the rate of dissolved carbon, into the cobalt pool, is too high and the excess carbon will form as graphite in the cobalt pool. Increased levels of solid solution tungsten, in the cobalt, is expected to delay the onset of graphitization in the diamond compact, thereby increasing the thermal stability of the diamond compact. Non-metallic PCD using calcium carbonate as a bonding agent was successfully sintered in this study. TEM revealed similar micro-structural features as in cobalt based PCD. No signs of thermal degradation were found after exposure to 1200ºC in vacuum for this PCD. Contaminants introduced during processing prevented a detailed study of the binder in this system. The effect of substitutional metal atoms and plastic deformation of diamond on the thermal stability of diamond-SiC composites were investigated. A piston cylinder press was developed and used to synthesize diamond-SiC composites with different levels of plastically deformed diamond. It was concluded that substitutional metal atoms and plastic deformation of diamond grains play no role in the thermal degradation of diamond compacts at 750ºC. The thermal degradation of cobalt PCD is therefore completely determined by the cobalt/diamond interaction at 750ºC.
- Full Text:
- Date Issued: 2011
An analysis of sources and predictability of geomagnetic storms
- Authors: Uwamahoro, Jean
- Date: 2011
- Subjects: Ionospheric storms Solar flares Interplanetary magnetic fields Magnetospheric substorms Coronal mass ejections Space environment Neural networks (Computer science)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5451 , http://hdl.handle.net/10962/d1005236
- Description: Solar transient eruptions are the main cause of interplanetary-magnetospheric disturbances leading to the phenomena known as geomagnetic storms. Eruptive solar events such as coronal mass ejections (CMEs) are currently considered the main cause of geomagnetic storms (GMS). GMS are strong perturbations of the Earth’s magnetic field that can affect space-borne and ground-based technological systems. The solar-terrestrial impact on modern technological systems is commonly known as Space Weather. Part of the research study described in this thesis was to investigate and establish a relationship between GMS (periods with Dst ≤ −50 nT) and their associated solar and interplanetary (IP) properties during solar cycle (SC) 23. Solar and IP geoeffective properties associated with or without CMEs were investigated and used to qualitatively characterise both intense and moderate storms. The results of this analysis specifically provide an estimate of the main sources of GMS during an average 11-year solar activity period. This study indicates that during SC 23, the majority of intense GMS (83%) were associated with CMEs, while the non-associated CME storms were dominant among moderate storms. GMS phenomena are the result of a complex and non-linear chaotic system involving the Sun, the IP medium, the magnetosphere and ionosphere, which make the prediction of these phenomena challenging. This thesis also explored the predictability of both the occurrence and strength of GMS. Due to their nonlinear driving mechanisms, the prediction of GMS was attempted by the use of neural network (NN) techniques, known for their non-linear modelling capabilities. To predict the occurrence of storms, a combination of solar and IP parameters were used as inputs in the NN model that proved to predict the occurrence of GMS with a probability of 87%. Using the solar wind (SW) and IP magnetic field (IMF) parameters, a separate NN-based model was developed to predict the storm-time strength as measured by the global Dst and ap geomagnetic indices, as well as by the locally measured K-index. The performance of the models was tested on data sets which were not part of the NN training process. The results obtained indicate that NN models provide a reliable alternative method for empirically predicting the occurrence and strength of GMS on the basis of solar and IP parameters. The demonstrated ability to predict the geoeffectiveness of solar and IP transient events is a key step in the goal towards improving space weather modelling and prediction.
- Full Text:
- Date Issued: 2011
- Authors: Uwamahoro, Jean
- Date: 2011
- Subjects: Ionospheric storms Solar flares Interplanetary magnetic fields Magnetospheric substorms Coronal mass ejections Space environment Neural networks (Computer science)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5451 , http://hdl.handle.net/10962/d1005236
- Description: Solar transient eruptions are the main cause of interplanetary-magnetospheric disturbances leading to the phenomena known as geomagnetic storms. Eruptive solar events such as coronal mass ejections (CMEs) are currently considered the main cause of geomagnetic storms (GMS). GMS are strong perturbations of the Earth’s magnetic field that can affect space-borne and ground-based technological systems. The solar-terrestrial impact on modern technological systems is commonly known as Space Weather. Part of the research study described in this thesis was to investigate and establish a relationship between GMS (periods with Dst ≤ −50 nT) and their associated solar and interplanetary (IP) properties during solar cycle (SC) 23. Solar and IP geoeffective properties associated with or without CMEs were investigated and used to qualitatively characterise both intense and moderate storms. The results of this analysis specifically provide an estimate of the main sources of GMS during an average 11-year solar activity period. This study indicates that during SC 23, the majority of intense GMS (83%) were associated with CMEs, while the non-associated CME storms were dominant among moderate storms. GMS phenomena are the result of a complex and non-linear chaotic system involving the Sun, the IP medium, the magnetosphere and ionosphere, which make the prediction of these phenomena challenging. This thesis also explored the predictability of both the occurrence and strength of GMS. Due to their nonlinear driving mechanisms, the prediction of GMS was attempted by the use of neural network (NN) techniques, known for their non-linear modelling capabilities. To predict the occurrence of storms, a combination of solar and IP parameters were used as inputs in the NN model that proved to predict the occurrence of GMS with a probability of 87%. Using the solar wind (SW) and IP magnetic field (IMF) parameters, a separate NN-based model was developed to predict the storm-time strength as measured by the global Dst and ap geomagnetic indices, as well as by the locally measured K-index. The performance of the models was tested on data sets which were not part of the NN training process. The results obtained indicate that NN models provide a reliable alternative method for empirically predicting the occurrence and strength of GMS on the basis of solar and IP parameters. The demonstrated ability to predict the geoeffectiveness of solar and IP transient events is a key step in the goal towards improving space weather modelling and prediction.
- Full Text:
- Date Issued: 2011
A participatory communication approach of rural cattle project: a case study of Nguni cattle project in the Eastern Cape, South Africa
- Authors: Usadolo, Sam Erevbenagie
- Date: 2011
- Subjects: Communication in community development -- South Africa , Nguni cattle -- South Africa , Participatory rural appraisal
- Language: English
- Type: Thesis , Doctoral , PhD (Com)
- Identifier: vital:11370 , http://hdl.handle.net/10353/d1015407 , Communication in community development -- South Africa , Nguni cattle -- South Africa , Participatory rural appraisal
- Description: project. It did this by reviewing relevant literature in development communication. The review done showed that literature is replete with arguments critical of the dominant paradigm due to its top-down nature of communication. Scholars critical of dominant paradigm argue that participatory communication should be given a prominent role to ensure that stakeholders work in concert to realise the stated objectives of their development project. The study highlighted many contentious issues surrounding the nature and practices of participatory communication. It pointed out that the issues have played themselves out in literature in the form of different typologies of participatory practices, which were dealt with extensively in this study. The discussion of participatory communication in literature is also mindful of different models of communication and the space they occupy in participatory communication practices. In this study, there was a discussion of transactional communication models as depicted by Nair and White (1993:52) and Steinberg (1997:19). Both scholars emphasise that participatory communication will not achieve its stated purpose without mutual agreement of the parties in communication. They equally stress the recognition of the possible effects of some contextual factors which may have bearing on the prevailing nature of communication. A review of different communication tools used by participatory development communicator was given in the study. These different communication tools were discussed in view of how these tools can be used to advance participatory practice in a development project, especially with reference to the project examined in this study. Using qualitative research method, different and appropriate interview methods such as semi-structured, focus group and post-survey interviews were used to collect data from the respondents in this study. The analysis and discussion of the data revealed that different challenges on the ground could affect participatory communication practices in a development project. With regard to the project examined in this study, the analysis showed that there is a weak stakeholder relationship, especially stakeholders identified in this study as field officers. The study highlighted that stakeholders such as the agricultural extension officers and animal health technicians are not very active in the implementation process of the project. Some of the reasons pointed out is the fact that the secondary stakeholder such as the Provincial Department of Agricultural (PDoA) to which these field officers belong is not playing active role in ensuring that they complement the efforts of other field officers such as the IDC representatives. The second reason is the fact that the participatory focus of the project was not properly communicated to the beneficiaries. This also transpired in their inability to reflect participatory practice in their relationship with the beneficiaries and other stakeholders of the project. Other challenges, among others, as pointed out in the analysis showed that participatory communication practice requires expert personnel to be successful. In the case of the project examined, apart from the fact that there is shortage of manpower to handle the challenges mentioned in the study, there is no communication expert among the few active personnel in the field. The findings of this study showed that there was no clear role and identification of responsibilities let alone coordination of all actors involved in the project. Through the selected case study, this study has not only provided avenue to explore both theoretically and practically participatory communication, but has added to participatory communication discourse that there is no easy answer to challenges field officers encounter in practice. This is the reason the different participatory practices characterising nature of the project this study has investigated was given.
- Full Text:
- Date Issued: 2011
- Authors: Usadolo, Sam Erevbenagie
- Date: 2011
- Subjects: Communication in community development -- South Africa , Nguni cattle -- South Africa , Participatory rural appraisal
- Language: English
- Type: Thesis , Doctoral , PhD (Com)
- Identifier: vital:11370 , http://hdl.handle.net/10353/d1015407 , Communication in community development -- South Africa , Nguni cattle -- South Africa , Participatory rural appraisal
- Description: project. It did this by reviewing relevant literature in development communication. The review done showed that literature is replete with arguments critical of the dominant paradigm due to its top-down nature of communication. Scholars critical of dominant paradigm argue that participatory communication should be given a prominent role to ensure that stakeholders work in concert to realise the stated objectives of their development project. The study highlighted many contentious issues surrounding the nature and practices of participatory communication. It pointed out that the issues have played themselves out in literature in the form of different typologies of participatory practices, which were dealt with extensively in this study. The discussion of participatory communication in literature is also mindful of different models of communication and the space they occupy in participatory communication practices. In this study, there was a discussion of transactional communication models as depicted by Nair and White (1993:52) and Steinberg (1997:19). Both scholars emphasise that participatory communication will not achieve its stated purpose without mutual agreement of the parties in communication. They equally stress the recognition of the possible effects of some contextual factors which may have bearing on the prevailing nature of communication. A review of different communication tools used by participatory development communicator was given in the study. These different communication tools were discussed in view of how these tools can be used to advance participatory practice in a development project, especially with reference to the project examined in this study. Using qualitative research method, different and appropriate interview methods such as semi-structured, focus group and post-survey interviews were used to collect data from the respondents in this study. The analysis and discussion of the data revealed that different challenges on the ground could affect participatory communication practices in a development project. With regard to the project examined in this study, the analysis showed that there is a weak stakeholder relationship, especially stakeholders identified in this study as field officers. The study highlighted that stakeholders such as the agricultural extension officers and animal health technicians are not very active in the implementation process of the project. Some of the reasons pointed out is the fact that the secondary stakeholder such as the Provincial Department of Agricultural (PDoA) to which these field officers belong is not playing active role in ensuring that they complement the efforts of other field officers such as the IDC representatives. The second reason is the fact that the participatory focus of the project was not properly communicated to the beneficiaries. This also transpired in their inability to reflect participatory practice in their relationship with the beneficiaries and other stakeholders of the project. Other challenges, among others, as pointed out in the analysis showed that participatory communication practice requires expert personnel to be successful. In the case of the project examined, apart from the fact that there is shortage of manpower to handle the challenges mentioned in the study, there is no communication expert among the few active personnel in the field. The findings of this study showed that there was no clear role and identification of responsibilities let alone coordination of all actors involved in the project. Through the selected case study, this study has not only provided avenue to explore both theoretically and practically participatory communication, but has added to participatory communication discourse that there is no easy answer to challenges field officers encounter in practice. This is the reason the different participatory practices characterising nature of the project this study has investigated was given.
- Full Text:
- Date Issued: 2011
An evaluation of impact of co-operative societies on poverty alleviation among the urban poor in Harare, Zimbabwe during the period 2008-2010
- Authors: Tukuta, Marian
- Date: 2011
- Subjects: Poor -- Services for -- Zimbabwe -- Harare , Human services -- Zimbabwe -- Harare , Urban poor -- Zimbabwe -- Harare , Poverty -- Zimbabwe -- Harare , Cooperative societies -- Zimbabwe -- Harare , Commercial associations -- Zimbabwe -- Harare
- Language: English
- Type: Thesis , Doctoral , PhD (Social Science Dev)
- Identifier: vital:11422 , http://hdl.handle.net/10353/506 , Poor -- Services for -- Zimbabwe -- Harare , Human services -- Zimbabwe -- Harare , Urban poor -- Zimbabwe -- Harare , Poverty -- Zimbabwe -- Harare , Cooperative societies -- Zimbabwe -- Harare , Commercial associations -- Zimbabwe -- Harare
- Description: The main purpose of this study was to evaluate the impact of co-operative societies on poverty alleviation among the urban poor in Zimbabwe with particular reference to consumer co-operative societies in areas of agriculture, housing and micro- finance. The co-operative sector plays an important role in poverty alleviation since many unemployed people have turned to co-operative activities as a way of earning a lawful and decent living during a period in which Zimbabwe generally suffered immense impoverishment in the midst of the national economic meltdown that was characterised by hyper-inflation, de-industrialisation and mass unemployment. The period of study was as from January 2008 to August 2010. This period is significant in that many co-operative societies were formed with the following broad objectives: (a) economic power and through this power; (b) control of socio-economic institution, to eliminate exploitation of man by man to make the people of Zimbabwe self reliant; (c) skills management, goods and services and establish in themselves a sense of confidence, initiative and high development aspirations; (d) to provide an opportunity to develop the community; and a (e) collective way of living that provides a sound base for socialism and national solidarity ix In this study, two hundred and seventy four respondents were used as research subjects. This consisted of one hundred and sixty respondents from housing, twenty four from micro- finance, and eighty eight from agricultural co-operative societies which covered dairy, poultry and fishing co-operative societies. This also included the Registrar of Co-operatives and the Harare City Council Co-operative officer. The research instruments that were used for the purpose of this research study were questionnaires, field visits, interviews and observations. Use was also made of secondary data that was obtained from the offices of Registrar of Co-operatives and the Town clerk of the Harare City Council as well as from the various co-operative societies that constitute the research study’s sample. The key factors that account for the failure of co-operative societies included the lack of adequate funding, lack of relevant knowledge and experience about co-operative activities, conflict among co-operative society members, failure to follow co-operative principles, mixing politics with co-operative activities and lack of education and training. The study also found out that the key to the success of any co-operative venture includes some of the following factors: Proper application of co-operative principles, the provision of co-operative education to both the membership and management of co-operative societies and proper keeping of institutional records. Most important of which include membership, financial and asset registers. x The study recommends that the government should give adequate administrative and financial support to co-operative societies since they have a potential of alleviating poverty if properly managed. It is also further recommended that research be done in order to enhance the strategic management of co-operative societies since empirical evidence tends to suggest that they are a viable tool for broad –based participatory and democratic sustainable livelihoods development. The study also recommended further studies to be carried out on the applicability of cooperative principles in all environments since some co-operative societies that have followed these principles especially in the developed countries have proved to be suitable instruments for poverty alleviation.
- Full Text:
- Date Issued: 2011
- Authors: Tukuta, Marian
- Date: 2011
- Subjects: Poor -- Services for -- Zimbabwe -- Harare , Human services -- Zimbabwe -- Harare , Urban poor -- Zimbabwe -- Harare , Poverty -- Zimbabwe -- Harare , Cooperative societies -- Zimbabwe -- Harare , Commercial associations -- Zimbabwe -- Harare
- Language: English
- Type: Thesis , Doctoral , PhD (Social Science Dev)
- Identifier: vital:11422 , http://hdl.handle.net/10353/506 , Poor -- Services for -- Zimbabwe -- Harare , Human services -- Zimbabwe -- Harare , Urban poor -- Zimbabwe -- Harare , Poverty -- Zimbabwe -- Harare , Cooperative societies -- Zimbabwe -- Harare , Commercial associations -- Zimbabwe -- Harare
- Description: The main purpose of this study was to evaluate the impact of co-operative societies on poverty alleviation among the urban poor in Zimbabwe with particular reference to consumer co-operative societies in areas of agriculture, housing and micro- finance. The co-operative sector plays an important role in poverty alleviation since many unemployed people have turned to co-operative activities as a way of earning a lawful and decent living during a period in which Zimbabwe generally suffered immense impoverishment in the midst of the national economic meltdown that was characterised by hyper-inflation, de-industrialisation and mass unemployment. The period of study was as from January 2008 to August 2010. This period is significant in that many co-operative societies were formed with the following broad objectives: (a) economic power and through this power; (b) control of socio-economic institution, to eliminate exploitation of man by man to make the people of Zimbabwe self reliant; (c) skills management, goods and services and establish in themselves a sense of confidence, initiative and high development aspirations; (d) to provide an opportunity to develop the community; and a (e) collective way of living that provides a sound base for socialism and national solidarity ix In this study, two hundred and seventy four respondents were used as research subjects. This consisted of one hundred and sixty respondents from housing, twenty four from micro- finance, and eighty eight from agricultural co-operative societies which covered dairy, poultry and fishing co-operative societies. This also included the Registrar of Co-operatives and the Harare City Council Co-operative officer. The research instruments that were used for the purpose of this research study were questionnaires, field visits, interviews and observations. Use was also made of secondary data that was obtained from the offices of Registrar of Co-operatives and the Town clerk of the Harare City Council as well as from the various co-operative societies that constitute the research study’s sample. The key factors that account for the failure of co-operative societies included the lack of adequate funding, lack of relevant knowledge and experience about co-operative activities, conflict among co-operative society members, failure to follow co-operative principles, mixing politics with co-operative activities and lack of education and training. The study also found out that the key to the success of any co-operative venture includes some of the following factors: Proper application of co-operative principles, the provision of co-operative education to both the membership and management of co-operative societies and proper keeping of institutional records. Most important of which include membership, financial and asset registers. x The study recommends that the government should give adequate administrative and financial support to co-operative societies since they have a potential of alleviating poverty if properly managed. It is also further recommended that research be done in order to enhance the strategic management of co-operative societies since empirical evidence tends to suggest that they are a viable tool for broad –based participatory and democratic sustainable livelihoods development. The study also recommended further studies to be carried out on the applicability of cooperative principles in all environments since some co-operative societies that have followed these principles especially in the developed countries have proved to be suitable instruments for poverty alleviation.
- Full Text:
- Date Issued: 2011
Dryland conservation areas, indigenous people, livelihoods and natural resource values in South Africa: the case of Kgalagadi Transfrontier Park
- Authors: Thondhlana, Gladman
- Date: 2011
- Subjects: Human ecology -- Kgalagadi Transfrontier Park (Botswana and South Africa) Arid regions biodiversity conservation -- Kgalagadi Transfrontier Park (Botswana and South Africa) Arid regions agriculture -- Kgalagadi Transfrontier Park (Botswana and South Africa) Indigenous peoples -- Ecology -- Kgalagadi Transfrontier Park (Botswana and South Africa) Natural resources conservation areas -- Kgalagadi Transfrontier Park (Botswana and South Africa) Natural resources -- Government policy -- Kgalagadi Transfrontier Park (Botswana and South Africa) Natural resources -- Kgalagadi Transfrontier Park (Botswana and South Africa) -- Management
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4777 , http://hdl.handle.net/10962/d1011732
- Description: Contemporary conservation and development understanding in both policy and academic circles espouses that natural resources have a significant contribution to the livelihoods of local people and that knowledge of this can better foster conservation policies that are consistent with livelihood and ecological needs. This thesis is based on research conducted in the southern Kalahari region, South Africa among the San and Mier communities bordering Kgalagadi Transfrontier Park. It looks at the importance of natural resources to the San and Mier community groups and ascertains the extent of resource use and its value within broader livelihood portfolios. It also focuses on the cultural values of natural resources and interactions among institutions and actors and how these shape natural resource governance and livelihood outcomes. Overall, natural resources represent an important livelihood source contributing up to 32 % and 9 % of the total income of the San and Mier respectively or up to 46 % and 23 % if livestock incomes are included. However, the dependence on, diversification patterns and distribution of natural resource income vary substantially between and within the two communities. With regards to the cultural values attached to natural resources by the San and Mier, the findings show that these arise from an incredibly diverse and sometimes conflicting array of values that punctuate the two communities’ way of life and they are inextricably linked to resource use. Lastly, governance of natural resources in the co-managed Park and communitymanaged resettlement farms is characterised by complex institutional arrangements, compounded by the existence of multiple actors that have multiple and sometimes conflicting objectives – as shaped by different meanings and interpretations of natural resources. Heightened inter- and intra-community conflicts are common, notably resource use conflicts between the San and Mier and between the San ‘modernist’ and ‘traditionalist’ groups. This demonstrates that the communities’ livelihood dynamics in general and the dependence on natural resources in particular, are closely linked with ecological, economic and social factors including history, culture and present livelihood needs. By exploring the social-environment interactions, the study highlights the complexities and diversity of resource use for livelihoods that should be taken into consideration for both conservation and development policy interventions and research. The main argument of the study is that the contribution of natural resources to local livelihood portfolios in co- and community-managed areas, can be better understood through a consideration of cultural dynamics and institutional arrangements since these condition natural resource access, value and use.
- Full Text:
- Date Issued: 2011
- Authors: Thondhlana, Gladman
- Date: 2011
- Subjects: Human ecology -- Kgalagadi Transfrontier Park (Botswana and South Africa) Arid regions biodiversity conservation -- Kgalagadi Transfrontier Park (Botswana and South Africa) Arid regions agriculture -- Kgalagadi Transfrontier Park (Botswana and South Africa) Indigenous peoples -- Ecology -- Kgalagadi Transfrontier Park (Botswana and South Africa) Natural resources conservation areas -- Kgalagadi Transfrontier Park (Botswana and South Africa) Natural resources -- Government policy -- Kgalagadi Transfrontier Park (Botswana and South Africa) Natural resources -- Kgalagadi Transfrontier Park (Botswana and South Africa) -- Management
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4777 , http://hdl.handle.net/10962/d1011732
- Description: Contemporary conservation and development understanding in both policy and academic circles espouses that natural resources have a significant contribution to the livelihoods of local people and that knowledge of this can better foster conservation policies that are consistent with livelihood and ecological needs. This thesis is based on research conducted in the southern Kalahari region, South Africa among the San and Mier communities bordering Kgalagadi Transfrontier Park. It looks at the importance of natural resources to the San and Mier community groups and ascertains the extent of resource use and its value within broader livelihood portfolios. It also focuses on the cultural values of natural resources and interactions among institutions and actors and how these shape natural resource governance and livelihood outcomes. Overall, natural resources represent an important livelihood source contributing up to 32 % and 9 % of the total income of the San and Mier respectively or up to 46 % and 23 % if livestock incomes are included. However, the dependence on, diversification patterns and distribution of natural resource income vary substantially between and within the two communities. With regards to the cultural values attached to natural resources by the San and Mier, the findings show that these arise from an incredibly diverse and sometimes conflicting array of values that punctuate the two communities’ way of life and they are inextricably linked to resource use. Lastly, governance of natural resources in the co-managed Park and communitymanaged resettlement farms is characterised by complex institutional arrangements, compounded by the existence of multiple actors that have multiple and sometimes conflicting objectives – as shaped by different meanings and interpretations of natural resources. Heightened inter- and intra-community conflicts are common, notably resource use conflicts between the San and Mier and between the San ‘modernist’ and ‘traditionalist’ groups. This demonstrates that the communities’ livelihood dynamics in general and the dependence on natural resources in particular, are closely linked with ecological, economic and social factors including history, culture and present livelihood needs. By exploring the social-environment interactions, the study highlights the complexities and diversity of resource use for livelihoods that should be taken into consideration for both conservation and development policy interventions and research. The main argument of the study is that the contribution of natural resources to local livelihood portfolios in co- and community-managed areas, can be better understood through a consideration of cultural dynamics and institutional arrangements since these condition natural resource access, value and use.
- Full Text:
- Date Issued: 2011
Adaptation choices, community perceptions, livelihood linkages and income dynamics for district producer communities surrounding Nyatana Game Park in Zimbabwe
- Authors: Taruvinga, Amon
- Date: 2011
- Subjects: Game reserves -- Zimbabwe , Wildlife conservation -- Zimbabwe , Wildlife management -- Zimbabwe , Sustainable development -- Zimbabwe , Game farms -- Zimbabwe , Rural poor -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , PhD (Agricultural Economics)
- Identifier: vital:11154 , http://hdl.handle.net/10353/476 , Game reserves -- Zimbabwe , Wildlife conservation -- Zimbabwe , Wildlife management -- Zimbabwe , Sustainable development -- Zimbabwe , Game farms -- Zimbabwe , Rural poor -- Zimbabwe
- Description: This thesis explores human-wildlife interactions under community managed game parks. The thesis consists of an introductory chapter, study location chapter and four self-contained studies based on different samples from created clusters surrounding Nyatana Game Park, which make up the rest of the thesis chapters. Chapter one presents an introductory overview of wildlife management in Zimbabwe, specifically looking at human-wildlife interactions under CAMPFIRE projects, welfare dynamics and conservation implications for the surrounding communities who share boundaries with community-managed game parks. The chapter concludes by highlighting the challenges facing community-based wildlife conservation in Zimbabwe as well as the key concepts that will be the subject of the rest of the thesis. Chapter two presents the study location; it highlights the road map to the study area, starting with the provincial location, and indicates the specific districts from which respondents were selected. A brief agro-ecological summary of the study area is also presented; it looks specifically at climate, vegetation and a demographic data of the study area. Chapter three: Can game parks be trusted as livelihood sources? To answer this topical question, Chapter three explores livelihood adaptation strategies for households who share boundaries with Nyatana Game Park. Most of the community managed game parks, under CAMPFIRE principles in Zimbabwe, were established with the primary objective of generating revenue for the surrounding communities; this was done in the hope of using positive returns from game farming to promote the conservation of wildlife. Has this materialised in practice? Descriptive results from this study seem to suggest otherwise, where mixed farming and gold panning were the major livelihood adaptation choices reported by most households. The revenue from game farming was reported to be too low and inconsistent, to such an extent that the majority of the community regarded it as risky and unreliable. A multinomial logistic regression model for correlates of adaptation choices indicated that access to credit, markets, and extension may be some of the current institutional constraints inhibiting households from accessing off-farm sources for their livelihoods. In addition, household size, gender and age may enhance the adaptive capacity of households to move out of risky crop faming into other off-farm portfolio diversifications. The study, therefore, suggests that game parks, according to the evidence uncovered by the study, may not be trusted as a reliable and sustainable livelihood source. If local communities who share boundaries with game parks do not view them as reliable and sustainable livelihood sources, as concluded in Chapter three, how can they (local communities) be trusted to conserve them? To assess their perceptions of game parks, Chapter four presents a multinomial logistic regression model for perceptions of society on game parks using the African elephant as a typical example. The results suggest that Problem Animal Control (PAC) perceptions, livestock predation and issues of low and poor revenue distribution may be some of the critical perceptions capable of influencing surrounding communities to negatively participate in the conservation of wildlife. The results further suggest that using wildlife proceeds to finance observable local common pool infrastructure may positively influence the surrounding communities to conserve wildlife. The chief conclusion regarding game parks, therefore, was that the surrounding communities were in favour of the obliteration pathway, although minimal conservation perceptions were also available. Given the negative conclusions regarding game parks, as suggested in Chapters three and four, citizens would then wonder if any meaningful hope for community managed game parks exists. Chapter five probes the buffer zone livelihood link under community managed game parks, using evidence from the Nyatana Game Park. The binary logistic regression model results, for buffer zone participation and resource extraction combinations by surrounding communities, suggest that resource extraction may be market driven rather than focussing on domestic consumption. The study therefore concludes that the buffer zone livelihood link as currently practiced, though potential, may fail to address the livelihood expectations of the sub-district producer communities. The study therefore calls for extreme caution whenever the buffer zone livelihood link is considered, because several institutional and design conflicts exist within this dynamic. In Chapter six, the study further probed the buffer zone income dynamics for the sub-district producer community. The results of descriptive statistics suggest that the contribution of buffer zone activities to household income may be significant with a positive correlation to household agricultural income for communities who reside inside or close to the park (primary sub-district producer community). Using the Gini decomposition approach and Lorenz curves, the study concluded that a buffer zone income may be capable of contributing to more equally distributed incomes for rural communities who share boundaries with game parks. With respect to the correlates of household income, the results suggest that household size and age may negatively influence income from buffer zone activities, while gender may have a positive effect. This was also true for education and Livestock Units (LUs) with respect to income from self employment; the former positively and the latter negatively related. The results further suggest that land size may also be positively significant in order to explain income from agriculture as well as total income. With regard to the distance from the buffer zone, the results suggest a negative influence with respect to the buffer zone, agriculture and total income. The implied message therefore suggests that buffer zones may provide active livelihood sources which are capable of financing rural household agriculture. The income equalizing effect which is portrayed may also further imply that, if correctly targeted and promoted, a buffer zone income could possibly address the current income inequality which is generic in rural areas. However, this potential may not be realized due to the current buffer zone design status (created for local secondary use as opposed to commercial primary use), restrictive policies and poor institutional support. With this dilemma facing community managed game parks (threats as summarised in Chapters three and four amid the potential hope summarized in Chapters five and six), Chapter 7 concludes the study by suggesting that the human-wildlife interaction model, though currently theoretical, may have significant practical potential in addressing the livelihoods of the surrounding communities as well as promoting the conservation of wildlife. This could be possible if available challenges that range from low revenue, insecure property rights, high human-elephant conflict and institutional design conflict for buffer zone utilization are corrected by means of the free market system. This would allow market forces to deliver on the expectations of the ―human-wildlife interactions model‖ – sustainable livelihoods for the former and intergenerational conservation for the latter.
- Full Text:
- Date Issued: 2011
- Authors: Taruvinga, Amon
- Date: 2011
- Subjects: Game reserves -- Zimbabwe , Wildlife conservation -- Zimbabwe , Wildlife management -- Zimbabwe , Sustainable development -- Zimbabwe , Game farms -- Zimbabwe , Rural poor -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , PhD (Agricultural Economics)
- Identifier: vital:11154 , http://hdl.handle.net/10353/476 , Game reserves -- Zimbabwe , Wildlife conservation -- Zimbabwe , Wildlife management -- Zimbabwe , Sustainable development -- Zimbabwe , Game farms -- Zimbabwe , Rural poor -- Zimbabwe
- Description: This thesis explores human-wildlife interactions under community managed game parks. The thesis consists of an introductory chapter, study location chapter and four self-contained studies based on different samples from created clusters surrounding Nyatana Game Park, which make up the rest of the thesis chapters. Chapter one presents an introductory overview of wildlife management in Zimbabwe, specifically looking at human-wildlife interactions under CAMPFIRE projects, welfare dynamics and conservation implications for the surrounding communities who share boundaries with community-managed game parks. The chapter concludes by highlighting the challenges facing community-based wildlife conservation in Zimbabwe as well as the key concepts that will be the subject of the rest of the thesis. Chapter two presents the study location; it highlights the road map to the study area, starting with the provincial location, and indicates the specific districts from which respondents were selected. A brief agro-ecological summary of the study area is also presented; it looks specifically at climate, vegetation and a demographic data of the study area. Chapter three: Can game parks be trusted as livelihood sources? To answer this topical question, Chapter three explores livelihood adaptation strategies for households who share boundaries with Nyatana Game Park. Most of the community managed game parks, under CAMPFIRE principles in Zimbabwe, were established with the primary objective of generating revenue for the surrounding communities; this was done in the hope of using positive returns from game farming to promote the conservation of wildlife. Has this materialised in practice? Descriptive results from this study seem to suggest otherwise, where mixed farming and gold panning were the major livelihood adaptation choices reported by most households. The revenue from game farming was reported to be too low and inconsistent, to such an extent that the majority of the community regarded it as risky and unreliable. A multinomial logistic regression model for correlates of adaptation choices indicated that access to credit, markets, and extension may be some of the current institutional constraints inhibiting households from accessing off-farm sources for their livelihoods. In addition, household size, gender and age may enhance the adaptive capacity of households to move out of risky crop faming into other off-farm portfolio diversifications. The study, therefore, suggests that game parks, according to the evidence uncovered by the study, may not be trusted as a reliable and sustainable livelihood source. If local communities who share boundaries with game parks do not view them as reliable and sustainable livelihood sources, as concluded in Chapter three, how can they (local communities) be trusted to conserve them? To assess their perceptions of game parks, Chapter four presents a multinomial logistic regression model for perceptions of society on game parks using the African elephant as a typical example. The results suggest that Problem Animal Control (PAC) perceptions, livestock predation and issues of low and poor revenue distribution may be some of the critical perceptions capable of influencing surrounding communities to negatively participate in the conservation of wildlife. The results further suggest that using wildlife proceeds to finance observable local common pool infrastructure may positively influence the surrounding communities to conserve wildlife. The chief conclusion regarding game parks, therefore, was that the surrounding communities were in favour of the obliteration pathway, although minimal conservation perceptions were also available. Given the negative conclusions regarding game parks, as suggested in Chapters three and four, citizens would then wonder if any meaningful hope for community managed game parks exists. Chapter five probes the buffer zone livelihood link under community managed game parks, using evidence from the Nyatana Game Park. The binary logistic regression model results, for buffer zone participation and resource extraction combinations by surrounding communities, suggest that resource extraction may be market driven rather than focussing on domestic consumption. The study therefore concludes that the buffer zone livelihood link as currently practiced, though potential, may fail to address the livelihood expectations of the sub-district producer communities. The study therefore calls for extreme caution whenever the buffer zone livelihood link is considered, because several institutional and design conflicts exist within this dynamic. In Chapter six, the study further probed the buffer zone income dynamics for the sub-district producer community. The results of descriptive statistics suggest that the contribution of buffer zone activities to household income may be significant with a positive correlation to household agricultural income for communities who reside inside or close to the park (primary sub-district producer community). Using the Gini decomposition approach and Lorenz curves, the study concluded that a buffer zone income may be capable of contributing to more equally distributed incomes for rural communities who share boundaries with game parks. With respect to the correlates of household income, the results suggest that household size and age may negatively influence income from buffer zone activities, while gender may have a positive effect. This was also true for education and Livestock Units (LUs) with respect to income from self employment; the former positively and the latter negatively related. The results further suggest that land size may also be positively significant in order to explain income from agriculture as well as total income. With regard to the distance from the buffer zone, the results suggest a negative influence with respect to the buffer zone, agriculture and total income. The implied message therefore suggests that buffer zones may provide active livelihood sources which are capable of financing rural household agriculture. The income equalizing effect which is portrayed may also further imply that, if correctly targeted and promoted, a buffer zone income could possibly address the current income inequality which is generic in rural areas. However, this potential may not be realized due to the current buffer zone design status (created for local secondary use as opposed to commercial primary use), restrictive policies and poor institutional support. With this dilemma facing community managed game parks (threats as summarised in Chapters three and four amid the potential hope summarized in Chapters five and six), Chapter 7 concludes the study by suggesting that the human-wildlife interaction model, though currently theoretical, may have significant practical potential in addressing the livelihoods of the surrounding communities as well as promoting the conservation of wildlife. This could be possible if available challenges that range from low revenue, insecure property rights, high human-elephant conflict and institutional design conflict for buffer zone utilization are corrected by means of the free market system. This would allow market forces to deliver on the expectations of the ―human-wildlife interactions model‖ – sustainable livelihoods for the former and intergenerational conservation for the latter.
- Full Text:
- Date Issued: 2011
Towards community environmental education using current institutional resources, GIS and remote sensing, and local knowledge: a case of the Nandi Hills and Nandi Forests, Western Kenya
- Authors: Tanui, Julius Gordon
- Date: 2011
- Subjects: Environmental education -- Kenya -- Western Province , Community-based conservation -- Kenya -- Western Province , Conservation of natural resources -- Kenya -- Western Province
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: vital:9568 , http://hdl.handle.net/10948/d1016074
- Description: The Nandi Hills and Nandi Forests in Nandi County, Kenya are major water catchments for Lake Victoria. However, these resources have faced significant decline and degradation in recent times, thereby impacting the hydrological quality and quantity in the Lake Victoria Basin. This study was informed by the observed degradation of the Nandi Hills and Nandi Forests, epitomized by the receding forest cover, drying up of previously permanent streams, instances of mudslides and rock falls, and downstream flooding. The study therefore sought to interrogate the current institutional environmental and educational arrangements and practices which are pertinent to the sustainable management of the Nandi Hills Forests, the perceptions and understandings of the local population in terms of forest resources and land use, and the information that can be provided by GIS and Remote Sensing data, in order to produce a heuristic for planning community environmental education in the Nandi County. To achieve this, a mixed methodological design which incorporated both qualitative and quantitative data was embraced. The mixed method approaches used in this study were the concurrent triangulation and nested/embedded designs. A four-tier analysis was carried out once all the data had been coded and grouped. The analysis covered three categories of the population in the study area; namely the households, institutions and community groups, and analysis of Landsat images for change detection. The study reveals that there are several state and non-state institutions that are involved in the management of the Nandi Hills Forests and that their efforts have seen an improvement in the perceptions of the local population in terms of the importance of environmental management of the forests. Analysis of the Landsat images has revealed receding natural forest cover. The contribution of informal, local and indigenous knowledge to sustainable management of the Nandi Hills Forest was notable (85 percent of the population attribute their knowledge on forests and forestry to informal knowledge sources). These results informed the development of a heuristic to enable the adoption of strategies using readily accessible, though loosely applicable, information for problem solving in developing and implementing community environmental education practices for effective forest management and conservation practices that are responsive to the needs of the Nandi Forest community.
- Full Text:
- Date Issued: 2011
- Authors: Tanui, Julius Gordon
- Date: 2011
- Subjects: Environmental education -- Kenya -- Western Province , Community-based conservation -- Kenya -- Western Province , Conservation of natural resources -- Kenya -- Western Province
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: vital:9568 , http://hdl.handle.net/10948/d1016074
- Description: The Nandi Hills and Nandi Forests in Nandi County, Kenya are major water catchments for Lake Victoria. However, these resources have faced significant decline and degradation in recent times, thereby impacting the hydrological quality and quantity in the Lake Victoria Basin. This study was informed by the observed degradation of the Nandi Hills and Nandi Forests, epitomized by the receding forest cover, drying up of previously permanent streams, instances of mudslides and rock falls, and downstream flooding. The study therefore sought to interrogate the current institutional environmental and educational arrangements and practices which are pertinent to the sustainable management of the Nandi Hills Forests, the perceptions and understandings of the local population in terms of forest resources and land use, and the information that can be provided by GIS and Remote Sensing data, in order to produce a heuristic for planning community environmental education in the Nandi County. To achieve this, a mixed methodological design which incorporated both qualitative and quantitative data was embraced. The mixed method approaches used in this study were the concurrent triangulation and nested/embedded designs. A four-tier analysis was carried out once all the data had been coded and grouped. The analysis covered three categories of the population in the study area; namely the households, institutions and community groups, and analysis of Landsat images for change detection. The study reveals that there are several state and non-state institutions that are involved in the management of the Nandi Hills Forests and that their efforts have seen an improvement in the perceptions of the local population in terms of the importance of environmental management of the forests. Analysis of the Landsat images has revealed receding natural forest cover. The contribution of informal, local and indigenous knowledge to sustainable management of the Nandi Hills Forest was notable (85 percent of the population attribute their knowledge on forests and forestry to informal knowledge sources). These results informed the development of a heuristic to enable the adoption of strategies using readily accessible, though loosely applicable, information for problem solving in developing and implementing community environmental education practices for effective forest management and conservation practices that are responsive to the needs of the Nandi Forest community.
- Full Text:
- Date Issued: 2011
Development of MgZnO-grown MOCVD for UV Photonic applications
- Authors: Talla, Kharouna
- Date: 2011
- Subjects: Photoluminescence , Photonics , Zinc oxide
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10537 , http://hdl.handle.net/10948/d1012585 , Photoluminescence , Photonics , Zinc oxide
- Description: MgxZn1-xO has emerged as a material of great technological importance. Having a direct energy band gap that is tunable throughout much of the ultraviolet (UV) region of the spectrum from the near-UV (~370 nm) to the deep-UV (~176 nm), this compound is of interest for a variety of optoelectronic devices operating in this part of the electromagnetic spectrum. MgxZn1-xO offers advantages over the more mature compound semiconductor AlGaN which stem mainly from the unusually high exciton binding energy (60 meV in ZnO). In this study the growth of ZnO and MgxZn1-xO thin films using metal organic chemical vapour deposition (MOCVD) is systematically investigated. The films are mainly grown on c-Al2O3 and Si (100) and characterized using various techniques, such as photoluminescence (PL), x-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and auger electron spectroscopy (AES). The optical and the structural properties are essentially inspected in order to improve their quality. In this thesis the optimisation of ZnO grown using oxygen gas as a new oxidant in our reactor is investigated. The growth temperature and VI/II ratio are varied in order to find optimum parameters giving high quality layers. The effects of Si (100), Si (111), c- and r-sapphire, glass, GaAs and ZnO substrates on the optical, structural and morphological properties of ZnO thin films grown with tert-butanol (TBOH) is examined. Similar morphologies are observed for all substrates, with the films comprising hexagonal columns having cone shaped ends. The photoluminescence spectra are similar, but the various transitions have different relative intensities. It is clear that the different substrates influence neither the orientation of the films, nor the surface morphology, significantly. The photoluminescence hints at larger stacking fault densities in films grown on silicon and glass, however, as evidenced by stronger basal plane stacking fault-related luminescence at ~3.319 eV in the relevant low temperature photoluminescence spectra. The morphology changes with Mg incorporation, from hexagonal columnar structures to cubic faceted columns. From PL, the full with at half maximum is found to gradually increase with Mg content due to alloy broadening. The deep level emission (DLE) is observed to shift with Mg content. By changing the Mg content, the band gap of MgxZn1-xO film is tuned by ~450 meV, which provides an excellent opportunity for band gap engineering for optoelectronic applications. The c-lattice constant of ZnO (5.205 Å) decreases by only 0.6% when the Mg content reaches x=0.39. The introduction of Mg into ZnO is shown to increase the relative PL intensity of stacking fault-related transitions (at 3.314 eV for ZnO). This becomes the dominant near band edge emission. Using TEM a thin Mg rich layer is observed at the interface between the film and the Si or Al2O3. Temperature dependent PL measurements on layers with low Mg concentration (x=0.05 and 0.1) show that the main bound exciton peak exhibits an “s-shaped” temperature dependence, characteristic of localization in a disordered alloy. The origin of the PL line broadening of MgxZn1-xO (x≤0.04) is also analyzed with respect to alloy broadening, taking into account a random cation distribution and alloy clustering. The influence of various MOCVD growth parameters such as growth temperature and VI/II ratio is studied. Varying the temperature from 280 ˚C to 580 ˚C reveals strong morphological changes and optical degradation of the films. Low (<280 ˚C) and high (>580 ˚C) growth temperatures reduce the Mg incorporation. High VI/II ratios also decrease the Mg incorporation, as evidenced by the red-shift of the donor bound exciton (D°X) line. This is ascribed to a stronger premature reaction between (MeCp)2Mg and the oxidant or a preferential heterogeneous interaction between the Mg and oxygen species on the growth front. For both oxidizing agents (O2 and TBOH), the growth at 420 ˚C and a VI-II ratio of 60 on c-Al2O3 gave optimal quality layers in terms of their optical and structural quality. A comparison of films grown using TBOH and O2 gas as oxidizing agent shows no major difference in terms of Mg incorporation. The effect of annealing, the inclusion of a buffer layer and the influence of growth rate on the properties MgxZn1-xO thin films are also reported.
- Full Text:
- Date Issued: 2011
- Authors: Talla, Kharouna
- Date: 2011
- Subjects: Photoluminescence , Photonics , Zinc oxide
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10537 , http://hdl.handle.net/10948/d1012585 , Photoluminescence , Photonics , Zinc oxide
- Description: MgxZn1-xO has emerged as a material of great technological importance. Having a direct energy band gap that is tunable throughout much of the ultraviolet (UV) region of the spectrum from the near-UV (~370 nm) to the deep-UV (~176 nm), this compound is of interest for a variety of optoelectronic devices operating in this part of the electromagnetic spectrum. MgxZn1-xO offers advantages over the more mature compound semiconductor AlGaN which stem mainly from the unusually high exciton binding energy (60 meV in ZnO). In this study the growth of ZnO and MgxZn1-xO thin films using metal organic chemical vapour deposition (MOCVD) is systematically investigated. The films are mainly grown on c-Al2O3 and Si (100) and characterized using various techniques, such as photoluminescence (PL), x-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and auger electron spectroscopy (AES). The optical and the structural properties are essentially inspected in order to improve their quality. In this thesis the optimisation of ZnO grown using oxygen gas as a new oxidant in our reactor is investigated. The growth temperature and VI/II ratio are varied in order to find optimum parameters giving high quality layers. The effects of Si (100), Si (111), c- and r-sapphire, glass, GaAs and ZnO substrates on the optical, structural and morphological properties of ZnO thin films grown with tert-butanol (TBOH) is examined. Similar morphologies are observed for all substrates, with the films comprising hexagonal columns having cone shaped ends. The photoluminescence spectra are similar, but the various transitions have different relative intensities. It is clear that the different substrates influence neither the orientation of the films, nor the surface morphology, significantly. The photoluminescence hints at larger stacking fault densities in films grown on silicon and glass, however, as evidenced by stronger basal plane stacking fault-related luminescence at ~3.319 eV in the relevant low temperature photoluminescence spectra. The morphology changes with Mg incorporation, from hexagonal columnar structures to cubic faceted columns. From PL, the full with at half maximum is found to gradually increase with Mg content due to alloy broadening. The deep level emission (DLE) is observed to shift with Mg content. By changing the Mg content, the band gap of MgxZn1-xO film is tuned by ~450 meV, which provides an excellent opportunity for band gap engineering for optoelectronic applications. The c-lattice constant of ZnO (5.205 Å) decreases by only 0.6% when the Mg content reaches x=0.39. The introduction of Mg into ZnO is shown to increase the relative PL intensity of stacking fault-related transitions (at 3.314 eV for ZnO). This becomes the dominant near band edge emission. Using TEM a thin Mg rich layer is observed at the interface between the film and the Si or Al2O3. Temperature dependent PL measurements on layers with low Mg concentration (x=0.05 and 0.1) show that the main bound exciton peak exhibits an “s-shaped” temperature dependence, characteristic of localization in a disordered alloy. The origin of the PL line broadening of MgxZn1-xO (x≤0.04) is also analyzed with respect to alloy broadening, taking into account a random cation distribution and alloy clustering. The influence of various MOCVD growth parameters such as growth temperature and VI/II ratio is studied. Varying the temperature from 280 ˚C to 580 ˚C reveals strong morphological changes and optical degradation of the films. Low (<280 ˚C) and high (>580 ˚C) growth temperatures reduce the Mg incorporation. High VI/II ratios also decrease the Mg incorporation, as evidenced by the red-shift of the donor bound exciton (D°X) line. This is ascribed to a stronger premature reaction between (MeCp)2Mg and the oxidant or a preferential heterogeneous interaction between the Mg and oxygen species on the growth front. For both oxidizing agents (O2 and TBOH), the growth at 420 ˚C and a VI-II ratio of 60 on c-Al2O3 gave optimal quality layers in terms of their optical and structural quality. A comparison of films grown using TBOH and O2 gas as oxidizing agent shows no major difference in terms of Mg incorporation. The effect of annealing, the inclusion of a buffer layer and the influence of growth rate on the properties MgxZn1-xO thin films are also reported.
- Full Text:
- Date Issued: 2011
The implementation of the right to education in South Africa and Nigeria
- Authors: Taiwo, Elijah Adewale
- Date: 2011
- Subjects: Right to education -- South Africa , Right to education -- Nigeria , Human rights -- Study and teaching , Comparative education , Education -- South Africa , Education -- Nigeria , Right to education -- Law and legislation -- South Africa , Right to education -- Law and legislation -- Nigeria
- Language: English
- Type: Thesis , Doctoral , LLD
- Identifier: vital:10279 , http://hdl.handle.net/10948/1392 , Right to education -- South Africa , Right to education -- Nigeria , Human rights -- Study and teaching , Comparative education , Education -- South Africa , Education -- Nigeria , Right to education -- Law and legislation -- South Africa , Right to education -- Law and legislation -- Nigeria
- Description: The thesis examines the right to education in South Africa and Nigeria. It presents the right to education as an empowerment right which is given a wide recognition in a number of important international and regional human rights instruments as well as in national constitutions. It asserts that the right to education is a right with a multiplying effect in the sense that where it is effectively guaranteed, it enhances the enjoyment of all other rights and freedoms, and when it is denied, it precludes the enjoyment of many other human rights. The thesis examines the provisions of relevant international and regional human rights instruments to assess the adequacy of a framework that applies to South Africa and Nigeria's obligations regarding the right to education. It argues that those instruments impose obligations on all the States to make primary, secondary and higher levels of education available, accessible, acceptable and adaptable to all in their territories. It argues that by having ratified those international agreements in which the right to education is protected, both South Africa and Nigeria assume obligations under international law, enjoining them to realise the right to education and to respect freedoms in education. The study adopts a comparative approach and relies on primary and secondary sources of data; the data is subjected to an in-depth content analysis. The focus of the comparison is on whether the South African's position regarding the right to education can inform Nigeria's interpretation of the right to education. The reason being that the Nigerian Constitution does not provide for the right to education as a basic right as exists in South Africa. The Nigerian Constitution categorised the right to education under “fundamental objectives and directive principles” which are non-justiciable. In this sense, the thesis argues that the legal classification of the right to education, to a large extent, affects its realisation in Nigeria. It suggests that an important area where Nigeria could learn from South Africa is the issue of justiciability and constitutionalising the right to education as well as other socio-economic rights. In terms of implementation, the thesis submits that despite the international obligations and commitments to provide education for all, there is a significant gap between what is stipulated and the practical realities in the two countries. It argues that the right to education is more than a mere school attendance, how well a learner progresses in school is equally important. It posits that the high failure rates and the progressive slide in students' performances in schools xx examinations as shown in the study illustrate the poor quality and falling standard of education in the two countries. South Africa enjoys one of the highest rates of formal school enrolment of any developing country, yet the link between access and success is also weak in the South African schools just as in Nigerian schools. Inadequate planning, poor implementation of policies, lack of adequate resources and commitments are identified as the prime factors hampering the implementation of the right to education in both countries. Solving these problems and making the right to education realisable call for a renewed government commitments and investment of appropriate human and financial resources on education. This also requires a strong political will as well as concerted efforts of all the various actors in the educational sector in the two countries.
- Full Text:
- Date Issued: 2011
- Authors: Taiwo, Elijah Adewale
- Date: 2011
- Subjects: Right to education -- South Africa , Right to education -- Nigeria , Human rights -- Study and teaching , Comparative education , Education -- South Africa , Education -- Nigeria , Right to education -- Law and legislation -- South Africa , Right to education -- Law and legislation -- Nigeria
- Language: English
- Type: Thesis , Doctoral , LLD
- Identifier: vital:10279 , http://hdl.handle.net/10948/1392 , Right to education -- South Africa , Right to education -- Nigeria , Human rights -- Study and teaching , Comparative education , Education -- South Africa , Education -- Nigeria , Right to education -- Law and legislation -- South Africa , Right to education -- Law and legislation -- Nigeria
- Description: The thesis examines the right to education in South Africa and Nigeria. It presents the right to education as an empowerment right which is given a wide recognition in a number of important international and regional human rights instruments as well as in national constitutions. It asserts that the right to education is a right with a multiplying effect in the sense that where it is effectively guaranteed, it enhances the enjoyment of all other rights and freedoms, and when it is denied, it precludes the enjoyment of many other human rights. The thesis examines the provisions of relevant international and regional human rights instruments to assess the adequacy of a framework that applies to South Africa and Nigeria's obligations regarding the right to education. It argues that those instruments impose obligations on all the States to make primary, secondary and higher levels of education available, accessible, acceptable and adaptable to all in their territories. It argues that by having ratified those international agreements in which the right to education is protected, both South Africa and Nigeria assume obligations under international law, enjoining them to realise the right to education and to respect freedoms in education. The study adopts a comparative approach and relies on primary and secondary sources of data; the data is subjected to an in-depth content analysis. The focus of the comparison is on whether the South African's position regarding the right to education can inform Nigeria's interpretation of the right to education. The reason being that the Nigerian Constitution does not provide for the right to education as a basic right as exists in South Africa. The Nigerian Constitution categorised the right to education under “fundamental objectives and directive principles” which are non-justiciable. In this sense, the thesis argues that the legal classification of the right to education, to a large extent, affects its realisation in Nigeria. It suggests that an important area where Nigeria could learn from South Africa is the issue of justiciability and constitutionalising the right to education as well as other socio-economic rights. In terms of implementation, the thesis submits that despite the international obligations and commitments to provide education for all, there is a significant gap between what is stipulated and the practical realities in the two countries. It argues that the right to education is more than a mere school attendance, how well a learner progresses in school is equally important. It posits that the high failure rates and the progressive slide in students' performances in schools xx examinations as shown in the study illustrate the poor quality and falling standard of education in the two countries. South Africa enjoys one of the highest rates of formal school enrolment of any developing country, yet the link between access and success is also weak in the South African schools just as in Nigerian schools. Inadequate planning, poor implementation of policies, lack of adequate resources and commitments are identified as the prime factors hampering the implementation of the right to education in both countries. Solving these problems and making the right to education realisable call for a renewed government commitments and investment of appropriate human and financial resources on education. This also requires a strong political will as well as concerted efforts of all the various actors in the educational sector in the two countries.
- Full Text:
- Date Issued: 2011
Studies in marine quinone chemistry
- Authors: Sunassee, Suthananda Naidu
- Date: 2011
- Subjects: Quinone Marine natural products Marine invertebrates Marine pharmacology Cancer -- Treatment
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4355 , http://hdl.handle.net/10962/d1005020
- Description: This thesis is divided into two parts and the rationale of the research conducted is based on the cytotoxicity of the prenylated quinones 1.24-1.29, isolated from the South African nudibranch Leminda millecra, against oesophageal cancer cells. The first part (Chapters 2 and 3) of the thesis initially documents the distribution of cytotoxic and antioxidant prenylated quinones and hydroquinones in the marine environment. We have been able to show, for the first time, that these compounds can be divided into eight structural classes closely related to their phyletic distribution. Secondly, we attempted to synthesize the two marine natural products 1.24 and 1.26 in an effort to contribute to an ongoing collaborative search with the Division of Medical Biochemistry at the University of Cape Town for new compounds with anti-oesophageal cancer activity. Accordingly, we followed the published synthetic procedure for 1.26 and, although we were unable to reproduce the reported results, we have generated five new prenylated quinone analogues 3.53-3.55, 3.63 and 3.71, which are a potentially viable addition to our ongoing structure-activity relationship (SAR) studies. Moreover, we embarked on a 7Li NMR mechanistic study for the synthesis of 3.2 from 3.1 which rewarded us with an improved and reproducible methodology for this crucial reaction that is detailed in Chapter 3. The second part of this thesis (Chapters 4 and 5) is concerned with a synthetic, structural, electrochemical and biological exploration of the 1,4-naphthoquinone nucleus as a primary pharmacophore in our search for new chemical entities which can induce apoptosis in oesophageal cancer cells, thus contributing to our overall ongoing SAR study in this class of compounds. Seven new naphthoquinone derivatves (4.19, 4.30, 4.31, 4.33 and 4.46-4.48) of the natural products 2-deoxylapachol (2.44), lapachol (4.1) and β-lapachone (5.2) were synthesized and 2-(1`-hydroxy-`-phenylmethyl)-1,4-naphthoquinone (4.29) was found to be the most cytotoxic (IC50 1.5 μM) against the oesophageal cancer cell line WHCO1, while 5.2, which is currently in phase II clinical trials as an anticancer drug, was found to be similarly active (IC50 1.6 μM). Electrochemical investigations of the redox properties of the benzylic alcohol derivatives 4.29-4.31 indicated a higher reduction potential compared to their oxidized counterparts 4.45-4.48, and this finding has been correlated to the increased activity of 4.29-4.31 against the WHCO1 cell line. Additionally, 4.29 is synthetically more accessible than either 1.26 or 5.2 and potentially a lead compound in our search for new and more effective chemotherapeutic agents against oesophageal cancer
- Full Text:
- Date Issued: 2011
- Authors: Sunassee, Suthananda Naidu
- Date: 2011
- Subjects: Quinone Marine natural products Marine invertebrates Marine pharmacology Cancer -- Treatment
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4355 , http://hdl.handle.net/10962/d1005020
- Description: This thesis is divided into two parts and the rationale of the research conducted is based on the cytotoxicity of the prenylated quinones 1.24-1.29, isolated from the South African nudibranch Leminda millecra, against oesophageal cancer cells. The first part (Chapters 2 and 3) of the thesis initially documents the distribution of cytotoxic and antioxidant prenylated quinones and hydroquinones in the marine environment. We have been able to show, for the first time, that these compounds can be divided into eight structural classes closely related to their phyletic distribution. Secondly, we attempted to synthesize the two marine natural products 1.24 and 1.26 in an effort to contribute to an ongoing collaborative search with the Division of Medical Biochemistry at the University of Cape Town for new compounds with anti-oesophageal cancer activity. Accordingly, we followed the published synthetic procedure for 1.26 and, although we were unable to reproduce the reported results, we have generated five new prenylated quinone analogues 3.53-3.55, 3.63 and 3.71, which are a potentially viable addition to our ongoing structure-activity relationship (SAR) studies. Moreover, we embarked on a 7Li NMR mechanistic study for the synthesis of 3.2 from 3.1 which rewarded us with an improved and reproducible methodology for this crucial reaction that is detailed in Chapter 3. The second part of this thesis (Chapters 4 and 5) is concerned with a synthetic, structural, electrochemical and biological exploration of the 1,4-naphthoquinone nucleus as a primary pharmacophore in our search for new chemical entities which can induce apoptosis in oesophageal cancer cells, thus contributing to our overall ongoing SAR study in this class of compounds. Seven new naphthoquinone derivatves (4.19, 4.30, 4.31, 4.33 and 4.46-4.48) of the natural products 2-deoxylapachol (2.44), lapachol (4.1) and β-lapachone (5.2) were synthesized and 2-(1`-hydroxy-`-phenylmethyl)-1,4-naphthoquinone (4.29) was found to be the most cytotoxic (IC50 1.5 μM) against the oesophageal cancer cell line WHCO1, while 5.2, which is currently in phase II clinical trials as an anticancer drug, was found to be similarly active (IC50 1.6 μM). Electrochemical investigations of the redox properties of the benzylic alcohol derivatives 4.29-4.31 indicated a higher reduction potential compared to their oxidized counterparts 4.45-4.48, and this finding has been correlated to the increased activity of 4.29-4.31 against the WHCO1 cell line. Additionally, 4.29 is synthetically more accessible than either 1.26 or 5.2 and potentially a lead compound in our search for new and more effective chemotherapeutic agents against oesophageal cancer
- Full Text:
- Date Issued: 2011
Mutational analysis of the PacC binding sites within the aflR promoter in Aspergillus flavus
- Authors: Suleman, Essa
- Date: 2011
- Subjects: Mutation (Biology) , Genetic regulation , Proteins -- Synthesis , Microbiological synthesis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10336 , http://hdl.handle.net/10948/d1012683 , Mutation (Biology) , Genetic regulation , Proteins -- Synthesis , Microbiological synthesis
- Description: It is generally known that media containing simple sugars (sucrose, glucose) and organic nitrogen sources (ammonium) when buffered to acidic pH stimulates aflatoxin production in Aspergillus flavus & A. parasiticus while lactose, nitrate and an alkaline pH inhibit aflatoxin biosynthesis. It has been shown that pH of the growth medium is the most important regulatory factor for aflatoxin biosynthesis since media containing stimulatory carbon and/or nitrogen sources (sucrose and ammonia) do not enhance aflatoxin (or sterigmatocystin) production at alkaline pH. RNA interference (in A. flavus) of the pH regulatory transcription factor, PacC, resulted in aflatoxin production under acidic and alkaline pH conditions whilst wildtype Aspergillus flavus produced aflatoxins only under acidic conditions. This conclusively proved that PacC negatively regulates aflatoxin production at alkaline pH in A. flavus. However the exact mechanism involved in PacC repression of aflatoxin biosynthesis at alkaline pH still remains unknown. The AflR protein is essential for expression of several genes in the aflatoxin biosynthetic cluster. In the current study, sequence analysis of the aflR promoter indicated the presence of two putative PacC binding sites within the aflR promoter of A. flavus 3357WT located at positions -162 and -487 bp from the start codon. The presence of the PacC binding sites in the aflR promoter indicated a possible link between aflR expression and PacC regulation under alkaline conditions. Thus, in this study, it was hypothesized that at alkaline pH, PacC inhibits aflR expression by binding to one or both of the PacC binding sites within the aflR promoter. This in turn, would result in inhibition of aflatoxin biosynthesis since expression of several aflatoxin biosynthetic pathway genes is dependent on activation by AflR. The aim and objective of this study was to test the validity of this hypothesis i.e. that at alkaline pH PacC binds to one or both of its recognition sites within the aflR promoter thereby inhibiting aflR expression which subsequently would result in inhibition of aflatoxin biosynthesis. This was done by first mutating each individual and then both PacC binding sites in the A. flavus 3357 aflR promoter via Single-Joint PCR (SJ-PCR) and fusing the wildtype and each mutated aflR promoter to the Green Fluorescent Protein (gfp) gene and the trpC terminator to yield a functional expression vector. These constructs were then transformed into A. flavus 3357.5. Positive transformants were confirmed to express GFP by fluorescence microscopy and spectrofluorometry. Quantification of GFP protein levels of the various transformants in this study indicated that PacC negatively regulated aflR promoter activity at alkaline pH. RT-qPCR was performed on positive transformants after growth on SLS medium at acidic and alkaline pH to determine if PacC negatively regulated aflR promoter activity at alkaline pH and to determine whether PacC binds preferentially to one or both recognition sites within the aflR promoter. RT-qPCR analysis suggest that PacC binds non-preferentially to both recognition sites within the aflR promoter on sucrose and lactose media at alkaline pH, although mutation of PacC binding site 2 results in a slightly higher expression compared to mutation of PacC binding site 1. Increasing the concentration of an aflatoxin conducive nitrogen source stimulated aflR promoter activity but this was not sufficient to overcome negative regulation by PacC. It is generally known that repression of aflR expression results in repression of aflatoxin biosynthesis irrespective of pH. The results of this study strongly suggest that PacC negatively regulates aflR promoter activity at alkaline pH by binding to one or both PacC recognition sites within the aflR promoter. Since aflR promoter activity is repressed by PacC at alkaline pH, this substantiates the hypothesis that PacC represses aflatoxin biosynthesis by inhibiting expression of aflR. Furthermore, the results of this study indicated that there may be some PacC protein present in the active form at acidic pH irrespective of the carbon source and nitrogen source used in the growth medium. RT-qPCR analysis indicated that any active PacC present at acidic pH may cause repression of the aflR promoter based on the position of the PacC binding site relative to the aflR start codon, although it appears that PacC may have a higher affinity for PacC binding site 2 (which is closer to the aflR start codon).
- Full Text:
- Date Issued: 2011
- Authors: Suleman, Essa
- Date: 2011
- Subjects: Mutation (Biology) , Genetic regulation , Proteins -- Synthesis , Microbiological synthesis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10336 , http://hdl.handle.net/10948/d1012683 , Mutation (Biology) , Genetic regulation , Proteins -- Synthesis , Microbiological synthesis
- Description: It is generally known that media containing simple sugars (sucrose, glucose) and organic nitrogen sources (ammonium) when buffered to acidic pH stimulates aflatoxin production in Aspergillus flavus & A. parasiticus while lactose, nitrate and an alkaline pH inhibit aflatoxin biosynthesis. It has been shown that pH of the growth medium is the most important regulatory factor for aflatoxin biosynthesis since media containing stimulatory carbon and/or nitrogen sources (sucrose and ammonia) do not enhance aflatoxin (or sterigmatocystin) production at alkaline pH. RNA interference (in A. flavus) of the pH regulatory transcription factor, PacC, resulted in aflatoxin production under acidic and alkaline pH conditions whilst wildtype Aspergillus flavus produced aflatoxins only under acidic conditions. This conclusively proved that PacC negatively regulates aflatoxin production at alkaline pH in A. flavus. However the exact mechanism involved in PacC repression of aflatoxin biosynthesis at alkaline pH still remains unknown. The AflR protein is essential for expression of several genes in the aflatoxin biosynthetic cluster. In the current study, sequence analysis of the aflR promoter indicated the presence of two putative PacC binding sites within the aflR promoter of A. flavus 3357WT located at positions -162 and -487 bp from the start codon. The presence of the PacC binding sites in the aflR promoter indicated a possible link between aflR expression and PacC regulation under alkaline conditions. Thus, in this study, it was hypothesized that at alkaline pH, PacC inhibits aflR expression by binding to one or both of the PacC binding sites within the aflR promoter. This in turn, would result in inhibition of aflatoxin biosynthesis since expression of several aflatoxin biosynthetic pathway genes is dependent on activation by AflR. The aim and objective of this study was to test the validity of this hypothesis i.e. that at alkaline pH PacC binds to one or both of its recognition sites within the aflR promoter thereby inhibiting aflR expression which subsequently would result in inhibition of aflatoxin biosynthesis. This was done by first mutating each individual and then both PacC binding sites in the A. flavus 3357 aflR promoter via Single-Joint PCR (SJ-PCR) and fusing the wildtype and each mutated aflR promoter to the Green Fluorescent Protein (gfp) gene and the trpC terminator to yield a functional expression vector. These constructs were then transformed into A. flavus 3357.5. Positive transformants were confirmed to express GFP by fluorescence microscopy and spectrofluorometry. Quantification of GFP protein levels of the various transformants in this study indicated that PacC negatively regulated aflR promoter activity at alkaline pH. RT-qPCR was performed on positive transformants after growth on SLS medium at acidic and alkaline pH to determine if PacC negatively regulated aflR promoter activity at alkaline pH and to determine whether PacC binds preferentially to one or both recognition sites within the aflR promoter. RT-qPCR analysis suggest that PacC binds non-preferentially to both recognition sites within the aflR promoter on sucrose and lactose media at alkaline pH, although mutation of PacC binding site 2 results in a slightly higher expression compared to mutation of PacC binding site 1. Increasing the concentration of an aflatoxin conducive nitrogen source stimulated aflR promoter activity but this was not sufficient to overcome negative regulation by PacC. It is generally known that repression of aflR expression results in repression of aflatoxin biosynthesis irrespective of pH. The results of this study strongly suggest that PacC negatively regulates aflR promoter activity at alkaline pH by binding to one or both PacC recognition sites within the aflR promoter. Since aflR promoter activity is repressed by PacC at alkaline pH, this substantiates the hypothesis that PacC represses aflatoxin biosynthesis by inhibiting expression of aflR. Furthermore, the results of this study indicated that there may be some PacC protein present in the active form at acidic pH irrespective of the carbon source and nitrogen source used in the growth medium. RT-qPCR analysis indicated that any active PacC present at acidic pH may cause repression of the aflR promoter based on the position of the PacC binding site relative to the aflR start codon, although it appears that PacC may have a higher affinity for PacC binding site 2 (which is closer to the aflR start codon).
- Full Text:
- Date Issued: 2011
Identity, belonging and ecological crisis in South African speculative fiction
- Authors: Steenkamp, Elzette Lorna
- Date: 2011
- Subjects: South African fiction -- History and criticism Identity (Philosophical concept) in literature Group identity in literature Ecology in literature Science fiction, South African -- History and criticism Fantasy fiction, South African -- History and criticism Ecofiction -- History and criticism Ecocriticism
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2219 , http://hdl.handle.net/10962/d1002262
- Description: This study examines a range of South African speculative novels which situate their narratives in futuristic or ‘alternative’ milieus, exploring how these narratives not only address identity formation in a deeply divided and rapidly changing society, but also the ways in which human beings place themselves in relation to Nature and form notions of ‘ecological’ belonging. It offers close readings of these speculative narratives in order to investigate the ways in which they evince concerns which are rooted in the natural, social and political landscapes which inform them. Specific attention is paid to the texts’ treatment of the intertwined issues of identity, belonging and ecological crisis. This dissertation draws on the fields of Ecocriticism, Postcolonial Studies and Science Fiction Studies, and assumes a culturally specific approach to primary texts while investigating possible cross-cultural commonalities between Afrikaans and English speculative narratives, as well as the cross-fertilisation of global SF/speculative features. It is suggested that South African speculative fiction presents a socio-historically situated, rhizomatic approach to ecology – one that is attuned to the tension between humanistic- and ecological concerns.
- Full Text:
- Date Issued: 2011
- Authors: Steenkamp, Elzette Lorna
- Date: 2011
- Subjects: South African fiction -- History and criticism Identity (Philosophical concept) in literature Group identity in literature Ecology in literature Science fiction, South African -- History and criticism Fantasy fiction, South African -- History and criticism Ecofiction -- History and criticism Ecocriticism
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2219 , http://hdl.handle.net/10962/d1002262
- Description: This study examines a range of South African speculative novels which situate their narratives in futuristic or ‘alternative’ milieus, exploring how these narratives not only address identity formation in a deeply divided and rapidly changing society, but also the ways in which human beings place themselves in relation to Nature and form notions of ‘ecological’ belonging. It offers close readings of these speculative narratives in order to investigate the ways in which they evince concerns which are rooted in the natural, social and political landscapes which inform them. Specific attention is paid to the texts’ treatment of the intertwined issues of identity, belonging and ecological crisis. This dissertation draws on the fields of Ecocriticism, Postcolonial Studies and Science Fiction Studies, and assumes a culturally specific approach to primary texts while investigating possible cross-cultural commonalities between Afrikaans and English speculative narratives, as well as the cross-fertilisation of global SF/speculative features. It is suggested that South African speculative fiction presents a socio-historically situated, rhizomatic approach to ecology – one that is attuned to the tension between humanistic- and ecological concerns.
- Full Text:
- Date Issued: 2011
Sedimentology of plio-pleistocene gravel barrier deposits in the palaeo-Orange River mouth, Namibia : depositional history and diamond mineralisation
- Authors: Spaggiari, Renato Igino
- Date: 2011 , 2013-08-19
- Subjects: Diamond mines and mining -- Namibia Sediments (Geology) -- South Africa and Namibia -- Orange River Estuary Diamond deposits -- Namibia Orange River Estuary (Namibia and South Africa)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4927 , http://hdl.handle.net/10962/d1004636
- Description: The largest known marine diamond placer, the Namibian mega-placer, lies along the Atlantic coast of south-western Africa from the Orange River mouth 1,000 km northwards to the Namibian-Angolan border. The most economically viable portion of the Namibian mega-placer (>75 million carats recovered at >95% gem quality) comprises onshore and offshore marine deposits that are developed within ∼100km of the Orange River outfall. For much of the Cainozoic, this long-lived fluvial system has been the main conduit transporting diamonds from kimberlitic and secondary sources in the cratonic hinterland of southern Africa to the Atlantic shelf that has been neutrally buoyant over this period. Highly energetic marine processes, driven in part, by southerly winds with an attendant northward-directed longshore drift, have generated terminal placers that are preserved both onshore and offshore. This study, through detailed field sedimentological and diamond analyses, investigates the development and mineralisation of gravel barrier deposits within the ancestral Orange River mouth area during a major ∼30 m regional transgression ('30 m Package') in the Late Pliocene. At that time, diamond supply from this fluvial conduit was minimal, yet the corresponding onshore marine deposits to the north of the Orange River mouth were significantly diamond enriched, enabling large-scale alluvial diamond mining to take place for over 75 years. Of the entire coastline of south-western Africa, the most complete accumulation of the '30 m Package' is preserved within the palaeo-Orange River mouth as barrier spit and barrier beach deposits. Arranged vertically and laterally in a 16m thick succession, these are deposits of: (1) intertidal beach, (2) lagoon and washover, (3) tidal inlet and spit recurve and (4) storm-dominated subtidal settings. These were parts of larger barrier features, the bulk of which are preserved as highstand deposits that are diamond-bearing with varying, but generally low grades (<13 stones (diamonds) per hundred tons, spht). Intertidal beach and spit recurve deposits have higher economic grades (12-13 spht) due to the energetic sieving and mobile trapping mechanisms associated with their emplacement. In contrast, the less reworked and more sandy subtidal, tidal inlet and washover deposits have un-economic grades (<2 spht). Despite these low grades, the barrier deposits have the largest average stone (diamond) size (1-2 carats/stone, cts/stn) of the entire Namibian mega-placer, given their proximity to the ancestral Orange River outfall. This study demonstrates that barrier shoreline evolution at the fluvial/marine interface was controlled by: (1) a strong and coarse fluvial sediment supply that sustained shoreline growth on a highly energetic coast, (2) accommodation space facilitating sediment preservation and (3) short-duration, high-frequency sea-level cycles superimposed on the∼30 m regional transgression, promoting hierarchal stacking of progradational deposits. During these sea-level fluctuations, diamonds were 'farmed' from older, shelf sequences in the offshore and driven landward to accumulate in '30 m Package' highstand barrier deposits. In spite of the large supply of diamonds, their retention in these deposits was poor due to an incompetent footwall of ancestral Orange River mouth sediment and the inherent cobble-boulder size of the barrier gravels. Thus the principal process controlling diamond entrapment in these barrier deposits was kinetic sieving in a coarse-grained framework. Consequently, at the marine/fluvial interface and down-drift for ∼5 km, larger diamonds (1-2 cts/stn) were retained in low-grade (<2 spht), coarse-gravel barrier shorelines. Smaller diamonds (mostly < I cts/stn) were rejected into the northward-driven littoral sediments and further size-sorted along ∼95 km of Namibian coast to accumulate in finer, high-grade beach placers (> 100 spht) where bedrock footwall promoted such high concentrations. The gravel-dominated palaeo-Orange River mouth is considered to be the ' heart' of the Namibian mega-placer, controlling sediment and diamond supply to the littoral zone further north. Although coarse gravel is retained at the river mouth, the incompetence of this highly energetic setting to trap diamonds renders it sub-economic. This ineffectiveness at the fluvial/marine interface is thus fundamental in enriching the coastal tract farther down-drift and developing highly economic coastal placers along the Atlantic coast of south-western Africa. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2011
- Authors: Spaggiari, Renato Igino
- Date: 2011 , 2013-08-19
- Subjects: Diamond mines and mining -- Namibia Sediments (Geology) -- South Africa and Namibia -- Orange River Estuary Diamond deposits -- Namibia Orange River Estuary (Namibia and South Africa)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4927 , http://hdl.handle.net/10962/d1004636
- Description: The largest known marine diamond placer, the Namibian mega-placer, lies along the Atlantic coast of south-western Africa from the Orange River mouth 1,000 km northwards to the Namibian-Angolan border. The most economically viable portion of the Namibian mega-placer (>75 million carats recovered at >95% gem quality) comprises onshore and offshore marine deposits that are developed within ∼100km of the Orange River outfall. For much of the Cainozoic, this long-lived fluvial system has been the main conduit transporting diamonds from kimberlitic and secondary sources in the cratonic hinterland of southern Africa to the Atlantic shelf that has been neutrally buoyant over this period. Highly energetic marine processes, driven in part, by southerly winds with an attendant northward-directed longshore drift, have generated terminal placers that are preserved both onshore and offshore. This study, through detailed field sedimentological and diamond analyses, investigates the development and mineralisation of gravel barrier deposits within the ancestral Orange River mouth area during a major ∼30 m regional transgression ('30 m Package') in the Late Pliocene. At that time, diamond supply from this fluvial conduit was minimal, yet the corresponding onshore marine deposits to the north of the Orange River mouth were significantly diamond enriched, enabling large-scale alluvial diamond mining to take place for over 75 years. Of the entire coastline of south-western Africa, the most complete accumulation of the '30 m Package' is preserved within the palaeo-Orange River mouth as barrier spit and barrier beach deposits. Arranged vertically and laterally in a 16m thick succession, these are deposits of: (1) intertidal beach, (2) lagoon and washover, (3) tidal inlet and spit recurve and (4) storm-dominated subtidal settings. These were parts of larger barrier features, the bulk of which are preserved as highstand deposits that are diamond-bearing with varying, but generally low grades (<13 stones (diamonds) per hundred tons, spht). Intertidal beach and spit recurve deposits have higher economic grades (12-13 spht) due to the energetic sieving and mobile trapping mechanisms associated with their emplacement. In contrast, the less reworked and more sandy subtidal, tidal inlet and washover deposits have un-economic grades (<2 spht). Despite these low grades, the barrier deposits have the largest average stone (diamond) size (1-2 carats/stone, cts/stn) of the entire Namibian mega-placer, given their proximity to the ancestral Orange River outfall. This study demonstrates that barrier shoreline evolution at the fluvial/marine interface was controlled by: (1) a strong and coarse fluvial sediment supply that sustained shoreline growth on a highly energetic coast, (2) accommodation space facilitating sediment preservation and (3) short-duration, high-frequency sea-level cycles superimposed on the∼30 m regional transgression, promoting hierarchal stacking of progradational deposits. During these sea-level fluctuations, diamonds were 'farmed' from older, shelf sequences in the offshore and driven landward to accumulate in '30 m Package' highstand barrier deposits. In spite of the large supply of diamonds, their retention in these deposits was poor due to an incompetent footwall of ancestral Orange River mouth sediment and the inherent cobble-boulder size of the barrier gravels. Thus the principal process controlling diamond entrapment in these barrier deposits was kinetic sieving in a coarse-grained framework. Consequently, at the marine/fluvial interface and down-drift for ∼5 km, larger diamonds (1-2 cts/stn) were retained in low-grade (<2 spht), coarse-gravel barrier shorelines. Smaller diamonds (mostly < I cts/stn) were rejected into the northward-driven littoral sediments and further size-sorted along ∼95 km of Namibian coast to accumulate in finer, high-grade beach placers (> 100 spht) where bedrock footwall promoted such high concentrations. The gravel-dominated palaeo-Orange River mouth is considered to be the ' heart' of the Namibian mega-placer, controlling sediment and diamond supply to the littoral zone further north. Although coarse gravel is retained at the river mouth, the incompetence of this highly energetic setting to trap diamonds renders it sub-economic. This ineffectiveness at the fluvial/marine interface is thus fundamental in enriching the coastal tract farther down-drift and developing highly economic coastal placers along the Atlantic coast of south-western Africa. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2011
Modelling the relationship between flow and water quality in South African rivers
- Authors: Slaughter, Andrew Robert
- Date: 2011
- Subjects: Water quality -- Measurement -- South Africa Water quality -- Mathematical models -- South Africa Streamflow -- South Africa Stream measurements -- Mathematical models -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:6039 , http://hdl.handle.net/10962/d1006196
- Description: The National Water Act (Act 36 of 1998) provides for an ecological Reserve as the quantity (flow) and quality of water needed to protect aquatic ecosystems. While there are methods available to quantify the ecological Reserve in terms of flow, methods of linking flow to water quality are lacking. Therefore, the research presented in this thesis investigated various modelling techniques to estimate the effect of flow on water quality. The aims of the research presented in this thesis were: Aim 1: Can the relationship between flow and water quality be accurately represented by simple statistical models? Aim 2: Can relatively simple models accurately represent the relationship between flow and water quality? Aim 3: Can the effect of diffuse sources be omitted from a water quality model and still obtain realistic simulations, and if so under what conditions? Aim 4: Can models that solely use historical monitoring data, accurately represent the relationships between flow and water quality? In Chapter 3, simple Q-C regressions of flow and water quality were investigated using Department of Water Affairs (DWA) historical monitoring data. It was found that while flow versus salinity regressions gave good regression fits in many cases, the Q-C regression approach is limited. A mechanistic/statistical model that attempted to estimate the point and diffuse signatures of nutrients in response to flow was developed in Chapter 4 using DWA historical monitoring data. The model was verified as accurate in certain case studies using observed point loading information. In Chapter 5, statistical models that link land cover information to diffuse nutrient signatures in response to flow using DWA historical data were developed. While the model estimations are uncertain due to a lack of data, they do provide an estimation of the diffuse signature within catchments where there is flow and land cover information available. Chapter 6 investigates the extension of an existing mass-balance salinity model to estimate the effect of saline irrigation return flow on in-stream salinity. The model gave accurate salinity estimates for a low order stream with little or no irrigation within its catchment, and for a permanently flowing river within a catchment used extensively for irrigation. Chapter 7 investigated a modelling method to estimate the reaction coefficients involved in nitrification using only DWA historical monitoring data. Here, the model used flow information to estimate the residence time of nutrients within the studied river reaches. While the model obtained good estimations of nitrification for the data it was applied to, very few DWA data sets were suitable for the model. Chapter 8 investigated the ability of the in-stream model QUAL2K to estimate nutrient concentrations downstream of point and diffuse inputs of nutrients. It was found that the QUAL2K model can give accurate results in cases where point sources dominate the total nutrient inputs into a river. However, the QUAL2K simulations are too uncertain in cases where there are large diffuse source inputs of nutrients as the load of the diffuse inputs is difficult to measure in the field. This research highlights the problem of data scarcity in terms of temporal resolution as well as the range of constituents measured within DWA historical monitoring data for water quality. This thesis in addition argues that the approach of applying a number of models is preferable to applying one model to investigate the research aims, as particular models would be suited to particular circumstances, and the development of new models allowed the research aims of this thesis to be explored more thoroughly. It is also argued that simpler models that simulate a few key processes that explain the variation in observed data, are more suitable for implementing Integrated Water Resource Management (IWRM) than large comprehensive water quality models. From this research, it is clear that simple statistical models are not adequate for modelling the relationship between flow and water quality, however, relatively simple mechanistic models that simulate a limited number of processes and water quality variables, can provide accurate representations of this relationship. Under conditions where diffuse sources are not a major factor within a catchment, models that omit diffuse sources can obtain realistic simulations of the relationship between flow and water quality. Most of the models investigated in this thesis demonstrate that accurate simulations of the relationships between flow and water quality can be obtained using solely historical monitoring data.
- Full Text:
- Date Issued: 2011
- Authors: Slaughter, Andrew Robert
- Date: 2011
- Subjects: Water quality -- Measurement -- South Africa Water quality -- Mathematical models -- South Africa Streamflow -- South Africa Stream measurements -- Mathematical models -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:6039 , http://hdl.handle.net/10962/d1006196
- Description: The National Water Act (Act 36 of 1998) provides for an ecological Reserve as the quantity (flow) and quality of water needed to protect aquatic ecosystems. While there are methods available to quantify the ecological Reserve in terms of flow, methods of linking flow to water quality are lacking. Therefore, the research presented in this thesis investigated various modelling techniques to estimate the effect of flow on water quality. The aims of the research presented in this thesis were: Aim 1: Can the relationship between flow and water quality be accurately represented by simple statistical models? Aim 2: Can relatively simple models accurately represent the relationship between flow and water quality? Aim 3: Can the effect of diffuse sources be omitted from a water quality model and still obtain realistic simulations, and if so under what conditions? Aim 4: Can models that solely use historical monitoring data, accurately represent the relationships between flow and water quality? In Chapter 3, simple Q-C regressions of flow and water quality were investigated using Department of Water Affairs (DWA) historical monitoring data. It was found that while flow versus salinity regressions gave good regression fits in many cases, the Q-C regression approach is limited. A mechanistic/statistical model that attempted to estimate the point and diffuse signatures of nutrients in response to flow was developed in Chapter 4 using DWA historical monitoring data. The model was verified as accurate in certain case studies using observed point loading information. In Chapter 5, statistical models that link land cover information to diffuse nutrient signatures in response to flow using DWA historical data were developed. While the model estimations are uncertain due to a lack of data, they do provide an estimation of the diffuse signature within catchments where there is flow and land cover information available. Chapter 6 investigates the extension of an existing mass-balance salinity model to estimate the effect of saline irrigation return flow on in-stream salinity. The model gave accurate salinity estimates for a low order stream with little or no irrigation within its catchment, and for a permanently flowing river within a catchment used extensively for irrigation. Chapter 7 investigated a modelling method to estimate the reaction coefficients involved in nitrification using only DWA historical monitoring data. Here, the model used flow information to estimate the residence time of nutrients within the studied river reaches. While the model obtained good estimations of nitrification for the data it was applied to, very few DWA data sets were suitable for the model. Chapter 8 investigated the ability of the in-stream model QUAL2K to estimate nutrient concentrations downstream of point and diffuse inputs of nutrients. It was found that the QUAL2K model can give accurate results in cases where point sources dominate the total nutrient inputs into a river. However, the QUAL2K simulations are too uncertain in cases where there are large diffuse source inputs of nutrients as the load of the diffuse inputs is difficult to measure in the field. This research highlights the problem of data scarcity in terms of temporal resolution as well as the range of constituents measured within DWA historical monitoring data for water quality. This thesis in addition argues that the approach of applying a number of models is preferable to applying one model to investigate the research aims, as particular models would be suited to particular circumstances, and the development of new models allowed the research aims of this thesis to be explored more thoroughly. It is also argued that simpler models that simulate a few key processes that explain the variation in observed data, are more suitable for implementing Integrated Water Resource Management (IWRM) than large comprehensive water quality models. From this research, it is clear that simple statistical models are not adequate for modelling the relationship between flow and water quality, however, relatively simple mechanistic models that simulate a limited number of processes and water quality variables, can provide accurate representations of this relationship. Under conditions where diffuse sources are not a major factor within a catchment, models that omit diffuse sources can obtain realistic simulations of the relationship between flow and water quality. Most of the models investigated in this thesis demonstrate that accurate simulations of the relationships between flow and water quality can be obtained using solely historical monitoring data.
- Full Text:
- Date Issued: 2011
Time series models for paired comparisons
- Authors: Sjolander, Morne Rowan
- Date: 2011
- Subjects: Paired comparisons (Statistics)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10577 , http://hdl.handle.net/10948/d1012858
- Description: The method of paired comparisons is seen as a technique used to rank a set of objects with respect to an abstract or immeasurable property. To do this, the objects get to be compared two at a time. The results are input into a model, resulting in numbers known as weights being assigned to the objects. The weights are then used to rank the objects. The method of paired comparisons was first used for psychometric investigations. Various other applications of the method are also present, for example economic applications, and applications in sports statistics. This study involves taking paired comparison models and making them time-dependent. Not much research has been done in this area. Three new time series models for paired comparisons are created. Simulations are done to support the evidence obtained, and theoretical as well as practical examples are given to illustrate the results and to verify the efficiency of the new models. A literature study is given on the method of paired comparisons, as well as on the areas in which we apply our models. Our first two time series models for paired comparisons are the Linear-Trend Bradley- Terry Model and the Sinusoidal Bradley-Terry Model. We use the maximum likelihood approach to solve these models. We test our models using exact and randomly simulated data for various time periods and various numbers of objects. We adapt the Linear-Trend Bradley-Terry Model and received our third time series model for paired comparisons, the Log Linear-Trend Bradley-Terry Model. The daily maximum and minimum temperatures were received for Port Elizabeth, Uitenhage and Coega for 2005 until 2009. To evaluate the performance of the Linear-Trend Bradley-Terry Model and the Sinusoidal Bradley-Terry Model on estimating missing temperature data, we artificially remove observations of temperature from Coega’s temperature dataset for 2006 until 2008, and use various forms of these models to estimate the missing data points. The exchange rates for 2005 until 2008 between the following currencies: the Rand, Dollar, Euro, Pound and Yen, were obtained and various forms of our Log Linear-Trend Bradley-Terry Model are used to forecast the exchange rate for one day ahead for each month in 2006 until 2008. One of the features of this study is that we apply our time series models for paired comparisons to areas which comprise non-standard paired comparisons; and we want to encourage the use of the method of paired comparisons in a broader sense than what it is traditionally used for. The results of this study can be used in various other areas, like for example, in sports statistics, to rank the strength of sports players and predict their future scores; in Physics, to calculate weather risks of electricity generation, particularly risks related to nuclear power plants, and so forth, as well as in many other areas. It is hoped that this research will open the door to much more research in combining time series analysis with the method of paired comparisons.
- Full Text:
- Date Issued: 2011
- Authors: Sjolander, Morne Rowan
- Date: 2011
- Subjects: Paired comparisons (Statistics)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10577 , http://hdl.handle.net/10948/d1012858
- Description: The method of paired comparisons is seen as a technique used to rank a set of objects with respect to an abstract or immeasurable property. To do this, the objects get to be compared two at a time. The results are input into a model, resulting in numbers known as weights being assigned to the objects. The weights are then used to rank the objects. The method of paired comparisons was first used for psychometric investigations. Various other applications of the method are also present, for example economic applications, and applications in sports statistics. This study involves taking paired comparison models and making them time-dependent. Not much research has been done in this area. Three new time series models for paired comparisons are created. Simulations are done to support the evidence obtained, and theoretical as well as practical examples are given to illustrate the results and to verify the efficiency of the new models. A literature study is given on the method of paired comparisons, as well as on the areas in which we apply our models. Our first two time series models for paired comparisons are the Linear-Trend Bradley- Terry Model and the Sinusoidal Bradley-Terry Model. We use the maximum likelihood approach to solve these models. We test our models using exact and randomly simulated data for various time periods and various numbers of objects. We adapt the Linear-Trend Bradley-Terry Model and received our third time series model for paired comparisons, the Log Linear-Trend Bradley-Terry Model. The daily maximum and minimum temperatures were received for Port Elizabeth, Uitenhage and Coega for 2005 until 2009. To evaluate the performance of the Linear-Trend Bradley-Terry Model and the Sinusoidal Bradley-Terry Model on estimating missing temperature data, we artificially remove observations of temperature from Coega’s temperature dataset for 2006 until 2008, and use various forms of these models to estimate the missing data points. The exchange rates for 2005 until 2008 between the following currencies: the Rand, Dollar, Euro, Pound and Yen, were obtained and various forms of our Log Linear-Trend Bradley-Terry Model are used to forecast the exchange rate for one day ahead for each month in 2006 until 2008. One of the features of this study is that we apply our time series models for paired comparisons to areas which comprise non-standard paired comparisons; and we want to encourage the use of the method of paired comparisons in a broader sense than what it is traditionally used for. The results of this study can be used in various other areas, like for example, in sports statistics, to rank the strength of sports players and predict their future scores; in Physics, to calculate weather risks of electricity generation, particularly risks related to nuclear power plants, and so forth, as well as in many other areas. It is hoped that this research will open the door to much more research in combining time series analysis with the method of paired comparisons.
- Full Text:
- Date Issued: 2011
Exploring opportunities for action competence development through learners' participation in waste management activities in selected primary schools in Botswana
- Authors: Silo, Nthalivi
- Date: 2011
- Subjects: Environmental education -- Botswana -- Case studies Environmental education -- Study and teaching (Primary) -- Botswana -- Case studies Environmental education -- Activity programs -- Botswana -- Case studies Student-centered learning -- Botswana -- Case studies Refuse and refuse disposal -- Environmental aspects -- Botswana -- Case studies Active learning -- Botswana -- Case studies Competency-based education -- Botswana -- Case studies Teacher-student relationships -- Botswana -- Case studies
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1541 , http://hdl.handle.net/10962/d1003423
- Description: The broader aim of this study is to probe participation of learners in waste management activities in selected primary schools in Botswana and through these activities, explore opportunities for action competence development. The study starts by tracing and outlining the socio-ecological challenges that confront children and the historical background of learner-centred education which gave rise to an emphasis on learner participation in Botswana education policy. It then maps out the development of children's participation in the global, regional and Botswana contexts by tracing the development of environmental education from early ecological and issue resolution goals of environmental education to sustainable development discourses. The focus is on policy issues and how learner participation has been represented and implemented in environmental education. The study then probes the rhetorical and normalised emphases on participation, and seeks further insight into how learners can be engaged in participatory learning processes that are meaningful, purposeful and that broaden their action competence and civic agency. The study uses the Cultural Historical Activity Theory (CHAT) methodology to build a picture of waste management activity systems in primary schools and to bring to the surface contradictions and tensions in learner participation in these activity systems. These contradictions are used to open up expansive learning participatory processes with learners using the Danish action competence framework. The expansive learning process uses action competence models that provide potential for transformative participation with learners, and new and different opportunities for learner participation. Case study research was used and conducted in the south eastern region of Botswana in three primary schools in three contexts, namely urban, peri-urban and rural. The data was largely generated through focus group interviews during workshops with children and observations of waste management activities. These two methods formed the main data generation methods. They were complemented by semi-structured interviews with teachers, and other actors in the waste management activities, learners' activities and work, learners' notes, photographs and children's drawings as well as show-and-tell explanations by learners. Content analysis and the abductive mode of inference were used to analyse data in all three case studies. Findings from the first phase of the study reveal that participation of learners in waste management activities was largely teacher-directed. This resulted in a mis-match between teachers views of what practices are necessary and important, and children's views of what practices are necessary and important in and for environmental education. Due to culturally and historically formed views of environmental education, the study reveals that teachers wanted children to pick up litter, and this was their primary environmental education concern. Learners on the other hand, identified sanitation management in the school toilets as their primary waste management concern. Teachers had not considered this an environmental education concern. Using the action competence expansive learning approach, the second phase of the study addressed this tension by opening up dialogue between teachers and learners and amongst the learners themselves through an expansive learning process supporting children's participation and action competence development. Through this teacher-learner dialogical engagement, a broader range of possibilities became available and ideas around participation were radically changed. The study further reveals that the achievement of this open dialogue provided for a better relationship within the school community. And with improved communication came better ideas to solve waste management issues that the community still face on a daily basis, such as too much litter. Newly devised solutions were practical and had a broader impact than the initial ones that teachers had always focussed on. They included mobilising the maintenance of toilets, landscaping the school premises and even re-contextualising the litter management that had always caused tensions between learners and teachers. Children seemed to be developing not only a better understanding of the environment, but also developing the ability to resolve conflict amongst themselves and with their elders. By engaging in dialogue with children, they became co-catalysts for change in the school community. This study shows that if children's participation is taken seriously, and if opportunities for dialogue exist between teachers and children, positive changes for a healthier environment can be created in schools. It reveals that children also appeared to be feeling more confident and more equipped to consider changes in their environment outside of the school community. The study further shows that participation in environmental education involves more than cognitive changes as proposed in earlier constructivist literature; it includes in-depth engagement with socio-cultural dynamics and histories in the school context, such as the cultural histories of teachers, schooling and authority structures in the cultural community of the school. The study recommends that there is need to strengthen Teacher Education programmes to develop teaching practices and support for teachers to identify ways of engaging learners' views on issues in the school in open, dialogical ways. Such Teacher Education programmes should deepen teachers' understandings of learners' zone of proximal development (ZPD), demonstrating how dialogue and scaffolding are part of a teacher's role in supporting learning. This is shown in the three case studies that form part of this study. Finally, the study also deepens insights of using the Cultural Historical Activity theory (CHAT) to shed light on issues surrounding learner participation within the socio-cultural and historical environmental education contexts of the schools. The action competence models used in the study provide a tool for revealing forms of learner participation. This tool can be used for critical reflections and monitoring of teaching practices in schools.
- Full Text:
- Date Issued: 2011
- Authors: Silo, Nthalivi
- Date: 2011
- Subjects: Environmental education -- Botswana -- Case studies Environmental education -- Study and teaching (Primary) -- Botswana -- Case studies Environmental education -- Activity programs -- Botswana -- Case studies Student-centered learning -- Botswana -- Case studies Refuse and refuse disposal -- Environmental aspects -- Botswana -- Case studies Active learning -- Botswana -- Case studies Competency-based education -- Botswana -- Case studies Teacher-student relationships -- Botswana -- Case studies
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1541 , http://hdl.handle.net/10962/d1003423
- Description: The broader aim of this study is to probe participation of learners in waste management activities in selected primary schools in Botswana and through these activities, explore opportunities for action competence development. The study starts by tracing and outlining the socio-ecological challenges that confront children and the historical background of learner-centred education which gave rise to an emphasis on learner participation in Botswana education policy. It then maps out the development of children's participation in the global, regional and Botswana contexts by tracing the development of environmental education from early ecological and issue resolution goals of environmental education to sustainable development discourses. The focus is on policy issues and how learner participation has been represented and implemented in environmental education. The study then probes the rhetorical and normalised emphases on participation, and seeks further insight into how learners can be engaged in participatory learning processes that are meaningful, purposeful and that broaden their action competence and civic agency. The study uses the Cultural Historical Activity Theory (CHAT) methodology to build a picture of waste management activity systems in primary schools and to bring to the surface contradictions and tensions in learner participation in these activity systems. These contradictions are used to open up expansive learning participatory processes with learners using the Danish action competence framework. The expansive learning process uses action competence models that provide potential for transformative participation with learners, and new and different opportunities for learner participation. Case study research was used and conducted in the south eastern region of Botswana in three primary schools in three contexts, namely urban, peri-urban and rural. The data was largely generated through focus group interviews during workshops with children and observations of waste management activities. These two methods formed the main data generation methods. They were complemented by semi-structured interviews with teachers, and other actors in the waste management activities, learners' activities and work, learners' notes, photographs and children's drawings as well as show-and-tell explanations by learners. Content analysis and the abductive mode of inference were used to analyse data in all three case studies. Findings from the first phase of the study reveal that participation of learners in waste management activities was largely teacher-directed. This resulted in a mis-match between teachers views of what practices are necessary and important, and children's views of what practices are necessary and important in and for environmental education. Due to culturally and historically formed views of environmental education, the study reveals that teachers wanted children to pick up litter, and this was their primary environmental education concern. Learners on the other hand, identified sanitation management in the school toilets as their primary waste management concern. Teachers had not considered this an environmental education concern. Using the action competence expansive learning approach, the second phase of the study addressed this tension by opening up dialogue between teachers and learners and amongst the learners themselves through an expansive learning process supporting children's participation and action competence development. Through this teacher-learner dialogical engagement, a broader range of possibilities became available and ideas around participation were radically changed. The study further reveals that the achievement of this open dialogue provided for a better relationship within the school community. And with improved communication came better ideas to solve waste management issues that the community still face on a daily basis, such as too much litter. Newly devised solutions were practical and had a broader impact than the initial ones that teachers had always focussed on. They included mobilising the maintenance of toilets, landscaping the school premises and even re-contextualising the litter management that had always caused tensions between learners and teachers. Children seemed to be developing not only a better understanding of the environment, but also developing the ability to resolve conflict amongst themselves and with their elders. By engaging in dialogue with children, they became co-catalysts for change in the school community. This study shows that if children's participation is taken seriously, and if opportunities for dialogue exist between teachers and children, positive changes for a healthier environment can be created in schools. It reveals that children also appeared to be feeling more confident and more equipped to consider changes in their environment outside of the school community. The study further shows that participation in environmental education involves more than cognitive changes as proposed in earlier constructivist literature; it includes in-depth engagement with socio-cultural dynamics and histories in the school context, such as the cultural histories of teachers, schooling and authority structures in the cultural community of the school. The study recommends that there is need to strengthen Teacher Education programmes to develop teaching practices and support for teachers to identify ways of engaging learners' views on issues in the school in open, dialogical ways. Such Teacher Education programmes should deepen teachers' understandings of learners' zone of proximal development (ZPD), demonstrating how dialogue and scaffolding are part of a teacher's role in supporting learning. This is shown in the three case studies that form part of this study. Finally, the study also deepens insights of using the Cultural Historical Activity theory (CHAT) to shed light on issues surrounding learner participation within the socio-cultural and historical environmental education contexts of the schools. The action competence models used in the study provide a tool for revealing forms of learner participation. This tool can be used for critical reflections and monitoring of teaching practices in schools.
- Full Text:
- Date Issued: 2011