Africa: unity, sovereignty and sorrow A book review
- Authors: Matthews, Sally
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142387 , vital:38075 , DOI: 10.1080/02589001.2011.562007
- Description: This ambitious book begins with the statement ‘By and large, the states of sub-Saharan Africa are failures’ (p. 1) and then sets out to explain state failure in Africa and to provide some ‘rational policy fantasies’ in response to this failure. The book builds on the work of scholars like Robert Jackson, William Reno and Jeffrey Herbst, with the particular focus of Englebert's book being on the domestic implications of the unconditional recognition of the sovereignty of African states. African states are internationally recognised despite lacking the features and not being able to perform the functions typically associated with statehood. Englebert's interest is to examine some of the domestic effects of this unconditional international recognition.
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- Date Issued: 2011
African Languages And ICT Education
- Authors: Dalvit, Lorenzo , Murray, Sarah , Terzoli, Alfredo
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431166 , vital:72750 , https://www.scitepress.org/Papers/2011/33507/33507.pdf
- Description: In South Africa, English plays a dominant role compared to African lan-guages in empowering domain. Better access to Education through the use of African languages is an object of heated debate. This paper shows that an intervention involving the use of an African language in the domain of ICT Education can change the attitudes of Black universi-ty students. The methodology used included a survey with preliminary and follow-up questionnaires and interviews and an intervention involv-ing the use of localised software and of an on-line glossary of computer terms translated, explained and exemplified in an African language (isiXhosa). This experience increased the support for the use of African languages as additional LoLT, even in the English-dominated field of study of Computer Science. This is an initial step towards promoting linguistic equality between English and African languages and social equality between their speakers.
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- Date Issued: 2011
Age validation, growth, mortality, and demographic modeling of spotted gully shark (Triakis megalopterus) from the southeast coast of South Africa
- Authors: Booth, Anthony J , Foulis, Alan J , Smale, Malcolm J
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123630 , vital:35466 , https://spo.nmfs.noaa.gov/sites/default/files/pdf-content/2011/1091/booth.pdf
- Description: This study documents validation of vertebral band-pair formation in spotted gully shark (Triakis megalopterus) with the use of f luorochrome injection and tagging of captive and wild sharks over a 21-year period. Growth and mortality rates of T. megalopterus were also estimated and a demographic analysis of the species was conducted. Of the 23 OTC (oxytetracycline) -marked vertebrae examined (12 from captive and 11 from wild sharks), seven vertebrae (three from captive and four from wild sharks) exhibited chelation of the OTC and f luoresced under ultraviolet light. It was concluded that a single opaque and translucent band pair was deposited annually up to at least 25 years of age, the maximum age recorded. Reader precision was assessed by using an index of average percent error calculated at 5%. No significant differences were found between male and female growth patterns (P>0.05), and von Bertalanffy growth model parameters for combined sexes were estimated to be L∞=1711.07 mm TL, k=0.11/yr and t0= –2.43 yr (n=86). Natural mortality was estimated at 0.17/yr. Age at maturity was estimated at 11 years for males and 15 years for females. Results of the demographic analysis showed that the population, in the absence of fishing mortality, was stable and not significantly different from zero and particularly sensitive to overfishing. At the current age at first capture and natural mortality rate, the fishing mortality rate required to result in negative population growth was low at F>0.004/ yr. Elasticity analysis revealed that juvenile survival was the principal factor in explaining variability in population growth rate.
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An attempt to constrain the age, duration, and eruptive history of the Karoo flood basalt: Naude's Nek section (South Africa)
- Authors: Moulin, Maud , Fluteau, Frédéric , Courtillot, Vincent , Marsh, Julian S , Delpech, Guillaume , Quidelleur, Xavier , Gérard, Martine , Jay, Anne E
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145022 , vital:38401 , https://doi.org/10.1029/2011JB008210
- Description: We have carried out paleomagnetic sampling of a ∼750 m sequence of the Karoo large igneous province (Naude's Nek Pass, South Africa). K‐Ar dating (Cassignol‐Gillot) has been performed on four samples from the 650 m upper unit (mean age 179.2 ± 1.8 Ma) and a sample from the lower unit (184.8 ± 2.6 Ma). A succession of two phases of volcanism is suggested. The lower 25 flows (115 m thick) have recorded a reversed polarity; the next 23 flows (135 m thick) are transitional and contribute a detailed record of the “Van Zijl” (1962) Jurassic reversal.
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An evaluation of lightweight classification methods for identifying malicious URLs
- Authors: Egan, Shaun P , Irwin, Barry V W
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429839 , vital:72644 , 10.1109/ISSA.2011.6027532
- Description: Recent research has shown that it is possible to identify malicious URLs through lexical analysis of their URL structures alone. This paper intends to explore the effectiveness of these lightweight classification algorithms when working with large real world datasets including lists of malicious URLs obtained from Phishtank as well as largely filtered be-nign URLs obtained from proxy traffic logs. Lightweight algorithms are defined as methods by which URLs are analysed that do not use exter-nal sources of information such as WHOIS lookups, blacklist lookups and content analysis. These parameters include URL length, number of delimiters as well as the number of traversals through the directory structure and are used throughout much of the research in the para-digm of lightweight classification. Methods which include external sources of information are often called fully featured classifications and have been shown to be only slightly more effective than a purely lexical analysis when considering both false-positives and false-negatives. This distinction allows these algorithms to be run client side without the introduction of additional latency, but still providing a high level of accu-racy through the use of modern techniques in training classifiers. Anal-ysis of this type will also be useful in an incident response analysis where large numbers of URLs need to be filtered for potentially mali-cious URLs as an initial step in information gathering as well as end us-er implementations such as browser extensions which could help pro-tect the user from following potentially malicious links. Both AROW and CW classifier update methods will be used as prototype implementa-tions and their effectiveness will be compared to fully featured analysis results. These methods are interesting because they are able to train on any labelled data, including instances in which their prediction is cor-rect, allowing them to build a confidence in specific lexical features. This makes it possible for them to be trained using noisy input data, making them ideal for real world applications such as link filtering and information gathering.
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An Evaluation of Trading Bands as Indicators for Network Telescope Datasets
- Authors: Cowie, Bradley , Irwin, Barry V W
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428013 , vital:72480 , https://www.researchgate.net/profile/Barry-Ir-win/publication/326225071_An_Evaluation_of_Trading_Bands_as_Indicators_for_Network_Telescope_Datasets/links/5b3f231a4585150d2309e1c0/An-Evaluation-of-Trading-Bands-as-Indicators-for-Network-Telescope-Datasets.pdf
- Description: Large scale viral outbreaks such as Conficker, the Code Red worm and the Witty worm illustrate the importance of monitoring malevolent activity on the Internet. Careful monitoring of anomalous traffic allows organiza-tions to react appropriately and in a timely fashion to minimize economic damage. Network telescopes, a type of Internet monitor, provide ana-lysts with a way of decoupling anomalous traffic from legitimate traffic. Data from network telescopes is used by analysts to identify potential incidents by comparing recent trends with historical data. Analysis of network telescope datasets is complicated by the large quantity of data present, the number of subdivisions within the data and the uncertainty associated with received traffic. While there is considerable research being performed in the field of network telescopes little of this work is concerned with the analysis of alternative methods of incident identifi-cation. This paper considers trading bands, a subfield of technical analysis, as an approach to identifying potential Internet incidents such as worms. Trading bands construct boundaries that are used for meas-uring when certain quantities are high or low relative to recent values. This paper considers Bollinger Bands and associated Bollinger Indica-tors, Price Channels and Keltner Channels. These techniques are evaluated as indicators of malevolent activity by considering how these techniques react to incidents indentified in the captured data from a network telescope.
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- Date Issued: 2011
An illustrated leaflet containing antiretroviral information targeted for low-literate readers: development and evaluation
- Authors: Dowse, Roslind , Ramela, Thato , Browne, Sara H
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/156731 , vital:40043 , https://doi.org/10.1016/j.pec.2011.01.013
- Description: To apply a dual visual/textual modal approach in developing and evaluating a medicine information leaflet with pictograms suitable for low-literate HIV/AIDS patients. To identify and recommend best practices in this type of information design.
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- Date Issued: 2011
Becoming African: debating post-apartheid white South African identities
- Authors: Matthews, Sally
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142409 , vital:38077 , DOI: 10.1080/14725843.2011.530440
- Description: The post-apartheid era necessitates the rethinking of white identities in South Africa. One way in which some white South Africans are seeking to redefine themselves is through describing themselves as African. However, claims by white South Africans that they too are Africans have been met with mixed responses from black South Africans. In this article I use contributions to an online university students' forum to explore ways in which some white South Africans are embracing an African identity and to consider ways in which some black South Africans are responding to white South Africans' shifting identities. I use contributions to this forum as a starting point to think about the possibilities and limitations that the embracing of an African identity has for the development of what Frankenberg calls ‘anti-racist forms of whiteness’ among white South Africans.
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- Date Issued: 2011
Being moved by a way the world is not
- Authors: Jones, Ward E
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/275631 , vital:55064 , xlink:href="https://doi.org/10.1007/s11229-009-9522-z"
- Description: At the end of Lecture 3 of The Empirical Stance, Bas van Fraassen suggests that we see the change of view involved in scientific revolutions as being, at least in part, emotional. In this paper, I explore one plausible way of cashing out this suggestion. Someone’s emotional approval of a description of the world, I argue, thereby shows that she takes herself to have reason to take that description seriously. This is true even if she is convinced—as a scientific community is when it considers alternative theories—that this description is false, that it is not the way the world is.
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Biphenyl sorption to different soil clay minerals
- Authors: Tandlich, Roman , Baláž, Štefan
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/76869 , vital:30632 , https://doi.org/10.5897/AJAR10.1012
- Description: Only limited information is available in the literature on the role of soil mineral surfaces in the sorption of hydrophobic organic pollutants. This knowledge gap is addressed through the assessment of biphenyl sorption to kaolinite, illite and bentonite; using the batch equilibration technique with incubations lasting 6 or 21 days at 28 ± 2°C in the dark [RT1]. Sorption of biphenyl onto kaolinite followed the Freundlich sorption isotherm, whereas linear sorption isotherms were observed on illite and bentonite [RT2]. The biphenyl sorption partition coefficient on kaolinite ranged from 0.1 to 9.1 cm3.g-1 after 6 days and no sorption was observed after 21 days. This could have been caused by a completely reversible sorption or a loss of binding capacity after 21 days [RT3]. The respective values of the biphenyl sorption partition coefficient on illite and bentonite ranged from 20.3 ± 0.3 to 120 ± 8 cm3.g-1.Sorption equilibrium on the internal clay surfaces was reached after 6 days, as indicated by the sorption data for illite and bentonite [RT4]. Access of biphenyl molecules to the internal clay surfaces is a function of the ionic strength of soil solution and the soil organic matter is the dominant site for biphenyl sorption after 6 to 21 days.
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Comfortably numb: Crump unveiled—a review of the 2011 Alan Crump retrospective exhibitio
- Authors: Cooper, Paul S
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147924 , vital:38685 , DOI:10.1080/00043389.2011.11877152
- Description: Writing can at times be difficult. It is not without considerable anxiety that I undertake to write this particular review. Perhaps I should offer a short qualifier: this is not strictly a review but rather a collection of ideas around the works and their arrangement, as well as my own musings and reflections on Crump. I want to pick up on what I identify to be an approach that personalises Crump as a professor, colleague and artist (we find this tone embedded throughout the accompanying exhibition catalogue). 1 I have chosen to structure this essay using a series of trigger headings, some provocative and possibly even inflammatory, others more neutral and concerned with getting to the core of what this retrospective and posthumous show is all about. All the while my thinking is to channel a sense (or lack thereof, as it may turn out) of my own experience of his work and person.
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Comparative behavior of conjugates of tantalum phthalocyanines with gold nanoparticles or single walled carbon nanotubes towards bisphenol A electrocatalysis
- Authors: Chauke, Vongani P , Antunes, Edith M , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/247152 , vital:51551 , xlink:href="https://doi.org/10.1016/j.jelechem.2011.06.019"
- Description: The characterization of tantalum phthalocyanine conjugates with gold nanoparticles and single wall carbon nanotubes as well as their electrocatalytic oxidation of bisphenol A is hereby presented. The formation of the conjugates was confirmed by X-ray diffraction and transmission electron microscope techniques. Single walled carbon nanotube conjugates of TaPc complexes showed the best catalysis as well as less passivation for bisphenol A detection and significant recovery of ∼98% compared to gold nanoparticle conjugates.
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- Date Issued: 2011
Comparative structural bioinformatics analysis of Bacillus amyloliquefaciens chemotaxis proteins within Bacillus subtilis group
- Authors: Yssel, Anna , Reva, Oleg , Tastan Bishop, Özlem
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123966 , vital:35521 , https://doi.10.1007/s00253-011-3582-y
- Description: Chemotaxis is a process in which bacteria sense their chemical environment and move towards more favorable conditions. Since plant colonization by bacteria is a multifaceted process which requires a response to the complex chemical environment, a finely tuned and sensitive chemotaxis system is needed. Members of the Bacillus subtilis group including Bacillus amyloliquefaciens are industrially important, for example, as bio-pesticides. The group exhibits plant growth-promoting characteristics, with different specificity towards certain host plants. Therefore, we hypothesize that while the principal molecular mechanisms of bacterial chemotaxis may be conserved, the bacterial chemotaxis system may need an evolutionary tweaking to adapt it to specific requirements, particularly in the process of evolution of free-living soil organisms, towards plant colonization behaviour. To date, almost nothing is known about what parts of the chemotaxis proteins are subjected to positive amino acid substitutions, involved in adjusting the chemotaxis system of bacteria during speciation. In this novel study, positively selected and purified sites of chemotaxis proteins were calculated, and these residues were mapped onto homology models that were built for the chemotaxis proteins, in an attempt to understand the spatial evolution of the chemotaxis proteins. Various positively selected amino acids were identified in semi-conserved regions of the proteins away from the known active sites.
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- Date Issued: 2011
Conjugates of low-symmetry Ge, Sn and Ti carboxy phthalocyanines with glutathione caped gold nanoparticles
- Authors: Masilela, Nkosiphile , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/247003 , vital:51536 , xlink:href="https://doi.org/10.1016/j.jphotochem.2011.08.009"
- Description: This work reports on conjugation of low symmetry Ge (GeMCPc), Ti (TiMCPc) and Sn (SnMCPc) carboxy phthalocyanines with glutathione capped gold nanoparticles (GSH-AuNPs). The photophysical behaviour of the novel phthalocyanines–GSH-AuNPs conjugate was investigated and compared to the monocarboxy Pcs and to the mixture of Pc with GSH-AuNPs without a chemical bond. Blue shifting of Q band of the phthalocyanines was observed on linking to GSH-AuNPs. An improvement in triplet lifetimes was obtained for all the MPcs–GSH-AuNPs-linked conjugates compared to the MPcs alone. The highest triplet quantum yield of 0.75 and the longest triplet lifetime of 130 μs were obtained for the GeMCPc–GSH-AuNPs-linked conjugate. Fluorescence quantum yields and lifetimes were low for the conjugates due to quenching by the nanoparticles.
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Cyclic voltammetry and spectroelectrochemistry of a novel manganese phthalocyanine substituted with hexynyl groups
- Authors: Quinton, Damien , Antunes, Edith M , Griveau, Sophie , Nyokong, Tebello , Bedioui, Fethi
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/248450 , vital:51687 , xlink:href="https://doi.org/10.1016/j.inoche.2010.11.029"
- Description: We report here on the synthesis of a new manganese phthalocyanine complex, namely Mn tetrakis(5-hexyn-oxy) phthalocyanine (3), specifically designed to possess an alkyne moiety for its potential use in controlled immobilization on electrodes via the so called “click” chemistry reaction. The electrochemical activity of complex 3 was investigated by cyclic voltammetry and the nature of the observed redox couples was elucidated by spectroelectrochemistry. This work has also shown that the reduction of Mn(III)Pc complex to Mn(II)Pc is accompanied by the formation of MnPc μ-oxo species. Further reduction results in the formation of Mn(II)Pc(− 3) rather than Mn(I)Pc(− 2).
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- Date Issued: 2011
Delivering a personalised video service using IPTV
- Authors: Shibeshi, Zelalem S , Ndakunda, Shanga , Terzoli, Alfredo , Bradshaw, Karen L
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429163 , vital:72564 , https://ieeexplore.ieee.org/abstract/document/5746086
- Description: Video oriented services are taking the lead in terms of revenue in the current Internet environment. In order to tap this revenue, Telcos are resorting to serious measures such as moving to Next Generation Network (NGN) where they can provide QoS for services that demand this feature, such as, IPTV. IPTV is more than just what its name implies and includes various types of additional services to make the TV a better entertainment and communication environment. Various innovative IPTV services have been proposed and developed by researchers and practitioners, including personalized advertisement, personalized EPG (Electronic Program Guide), and personalized VoD (Video on Demand). In this paper we introduce a new IPTV service called, the personalized dynamic video delivery service, which sends new video alerts (like breaking news alert) to subscribed users and notifies them when the video is available. If desired, users can watch the video automatically by switching from what they are currently watching without requiring explicitly a new video setup. Users can configure their profile and also set a policy on the way they wish to be notified and the types of video they wish to be alerted to. The paper describes the issues surrounding the delivery of this service and presents the architecture and the various open source technologies that are used to develop the service.
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- Date Issued: 2011
Developing visual images for communicating information aboutantiretroviral side effects to a low-literate population:
- Authors: Dowse, Roslind , Ramela, Thato , Barford, Kirsty-Lee , Browne, Sara H
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/156769 , vital:40048 , https://doi.org/10.2989/16085906.2010.530172
- Description: The side effects of antiretroviral (ARV) therapy are linked to altered quality of life and adherence. Poor adherence has also been associated with low health-literacy skills, with an uninformed patient more likely to make ARV-related decisions that compromise the efficacy of the treatment. Low literacy skills disempower patients in interactions with healthcare providers and preclude the use of existing written patient information materials, which are generally written at a high reading level. Visual images or pictograms used as a counselling tool or included in patient information leaflets have been shown to improve patients’ knowledge, particularly in low-literate groups. The objective of this study was to design visuals or pictograms illustrating various ARV side effects and to evaluate them in a low-literate South African Xhosa population. Core images were generated either from a design workshop or from posed photos or images from textbooks. The research team worked closely with a graphic artist. Initial versions of the images were discussed and assessed in group discussions, and then modified and eventually evaluated quantitatively in individual interviews with 40 participants who each had a maximum of 10 years of schooling.
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- Date Issued: 2011
Development of an ICT road map for eservices in rural areas
- Authors: Jere, Norbert R , Thinyane, Mamello , Terzoli, Alfredo
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430695 , vital:72709 , https://ieeexplore.ieee.org/abstract/document/6144217
- Description: ICTs, driven by the convergence of computers, telecommunications and traditional media, are crucial for the knowledge-based economy of the future. The rapid technological changes have resulted in different ideas being suggested for the expected ICT applications. As a result, different e-Service applications have being developed as a way to fos-ter ICT developments. However, ICT applications deployed at the mo-ment may not be able to sustain the rural communities in maybe 10 years or more to come. The paper considers the past, analyzes the present and conduct surveys to gain insight into the future. Based on all of this information, the research tries to provide an ICT road map for what is to come. What kind of applications can we develop now to cater for the technological changes, so that the ICT applications developed today would still be compatible with those developed in years to come? The Siyakhula Living Lab (SLL) is used as the case study in this paper and some interviews and literature review are done to get different ide-as on the future of ICTs.
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- Date Issued: 2011
Development of an Interactive Real-Time Negotiation Module for an E-commerce Platform
- Authors: Jere, Norbert R , Thinyane, Mamello , Terzoli, Alfredo
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430742 , vital:72712 , https://ieeexplore.ieee.org/abstract/document/5954490
- Description: With developments in the Internet and Web-based technologies, dis-tinctions between traditional markets and the global electronic market-place-such as business capital size, are gradually being narrowed down. It is recognized that in the Information Age, e-Commerce is a powerful tool for economic growth of developing countries. While there are indications of e-Commerce patronage among large firms in devel-oping countries, there seems to be little and negligible use of the Inter-net for commerce among small and medium sized firms. However, many of these e-Commerce projects in marginalized areas fail as a re-sult of lack of the required resources to support ICTs. Different ways have been suggested for marketing products online and to create cus-tomer loyalty. This paper discusses a marketing and customer loyalty strategy through a real-time interactive negotiation application, aimed at improving the existing e-Commerce platform. The e-Commerce platform has been deployed as part of the Siyakhula Living Lab ICTD project which is undertaken for the Dwesa community in the Eastern Cape province of South Africa.
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- Date Issued: 2011
Drug transport mechanisms from carbopol/eudragit verapamil sustained-release tablets
- Authors: Khamanga, Sandile M , Walker, Roderick B
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184801 , vital:44273 , xlink:href="https://doi.org/10.14227/dt180311p30"
- Description: The objectives of this study were to compare dissolution profiles of a verapamil (VRP) formulation manufactured inhouse and Isoptin SR using USP Apparatus 2 and 3 and to elucidate drug release kinetics of these dosage forms. Eudragit NE 30D (ethyl acrylate–methyl methacrylate copolymer in a 2:1 ratio) aqueous dispersion was used as a granulating binder for the manufacture of VRP mini-matrix sustained-release tablets. The wet granulation process was performed to prepare free-flowing granules that were blended with Carbopol. The tablets were manufactured using a single-punch press by compression of the granules with magnesium stearate as a lubricant. Drug release was determined in phosphate buffer solution using USP Apparatus 2 and 3. Dissolution data were fitted to zero- and first-order models; in addition, the kinetic data were determined by evaluation of Higuchi release kinetics. The mechanism of drug release was established using the Korsmeyer–Peppas model. In general, all tablets showed high mechanical resistance with less than 1% friability. There was no significant difference between the dissolution profiles of the formulation manufactured in-house and the commercially available product. The release mechanism of the formulated and marketed products was controlled by anomalous non-Fickian diffusion. VRP release was prolonged for 12 h indicating the usefulness of the formulation as a twice-daily dosage form. The mechanism of drug release for the dosage forms was unaffected by the choice of apparatus.
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- Date Issued: 2011