A search for enhanced photodynamic activity against Staphylococcus aureus planktonic cells and biofilms: the evaluation of phthalocyanine–detonation nanodiamond–Ag nanoconjugates
- Authors: Openda, Yolande Ikala , Matshitse, Refilwe , Nyokong, Tebello
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/163825 , vital:41073 , DOI: 10.1039/D0PP00075B
- Description: The present work reports on the synthesis and characterization of novel zinc (2) and indium (3) 2-amino-4-bromophenoxy substituted phthalocyanines (Pcs) along with the self-assembled nanoconjugates formed via π–π stacking interaction onto detonation nanodiamonds (DNDs) to form 2@DNDs and 3@DNDs. 2@DNDs and 3@DNDs were covalently linked to chitosan–silver mediated nanoparticles (CSAg) to form 2@DNDs-CSAg and 3@DNDs-CSAg nanoconjugates. High singlet oxygen quantum yields in DMSO of 0.69 and 0.72 for Pcs alone and 0.90 and 0.92 for 2@DNDs-CSAg and 3@DNDs-CSAg, respectively, were obtained.
- Full Text:
- Date Issued: 2020
A skin that took them through
- Authors: Kgame, Mbali
- Date: 2020
- Subjects: South African fiction (English) -- 21st century , African fiction (English) -- History and criticism , Short stories, South African (English) -- 21st century , Diaries -- Authorship
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/147638 , vital:38656
- Description: This project comprises of interlinked fictional short stories capturing experiences of the “invisibilised’’ young people- the street kids, drug addicts, cashiers, childminders, the sick, first graduates etc. These stories are a way to interrogate the fallacy of a “free and fair” South Africa by noting events taking place within homes, communities and countrywide. Told in a playful, innocent, curious, childlike voice and reasoning, my work draws inspiration from Werewere Likings ‘The Amputated Memory,’ for its ability to narrate the current without divorcing the past. I draw inspiration from Liking’s way of writing family connectivity and employing an emerging voice of the narrator starting from being a child scribbling to later becoming an elder. Nana Kwame Adjei-Brenyah’s ‘Black Friday’ for scanning into young black people’s experiences in a society where their bodies move as misfits. My work also draws from Lesley Nneka Arimah’s ‘What It Means When a Man Falls from the Sky’ for the interlinked stories. Lastly the stories in this project take from Sindiwe Magona’s Mother to Mother for humanising bodies that have been reduced to frames.
- Full Text:
- Date Issued: 2020
A snapshot of early childhood care and education in South Africa: institutional offerings, challenges and recommendations
- Authors: Harrison, Giulietta D
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/160312 , vital:40433 , https://doi.org/10.4102/sajce.v10i1.797
- Description: This article draws from a research report on the Project for Inclusive Early Childhood Care and Education (PIECCE), which surveyed attitudes, training strategies, materials and entrance requirements across most relevant higher education institutions (HEIs), non-governmental organisations (NGOs) and technical and vocational education and training colleges (TVETs). The aim of this study was to identify what institutions were offering in terms of training teachers in the birth-to-four age group, to identify the challenges and provide recommendations based on the findings.
- Full Text:
- Date Issued: 2020
A social-ecological investigation into urban domestic gardens and avifauna in medium-sized towns of the Eastern Cape, South Africa
- Authors: Tricam, Shayla
- Date: 2020
- Subjects: Urban ecology (Biology) -- South Africa , Biotic communites -- South Africa , Gardens -- South Africa -- Managemenet , Birds – Ecology – South Africa , Gardening to attract birds -- South Africa
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/145314 , vital:38427
- Description: Urban domestic gardens are an often overlooked component of urban green infrastructure, despite their potential to contribute to the preservation of urban biodiversity. As opposed to public greenspaces, private gardens are individually owned and managed, thus act as social-ecological systems, where the cumulative actions of urban residents can scale up to influence ecological patterns and processes on a larger scale. The diversity of fauna and flora within urban gardens provide a range of ecosystem goods and services, as well as less tangible benefits in the form of recreation, education and culture. However, little is known about the contribution of urban domestic gardens to urban biodiversity and its potential conservation value in South Africa. This study investigated urban domestic gardens along a socio-economic gradient in two medium-sized towns, Grahamstown and Port Alfred in the Eastern Cape, South Africa. This study found distinct differences among urban resident garden management practices as well as the avifauna which were seen within the gardens across the socio-economic gradient. The Garden Management Intensity index was higher within affluent households compared to other socio-economic levels, with subsequent management scores not differing statistically along the gradient. While there was variation within garden management practices, as well as the number of residents who participated in supplementary bird feeding, little variation was seen in the activities which were enjoyed by the residents, indicating numerous benefits the garden environment provides for all urban residents. The bird community composition along the socio-economic gradient displayed patterns directly reflecting the “luxury effect”, where households with a higher socio-economic status had harbour gardens with greater levels of biodiversity. This study showed that affluent gardens displayed far greater diversity, richness and abundance of urban birds. Multivariate analyses confirmed the patterns by highlighting a distinct bird community in the affluent zone, compared to other two socio-economic zones, which housed a second bird community. Furthermore, the main driver of the bird community composition was dominated by vegetation complexity, most notably tree cover within the gardens. Therefore, this study highlighted that patterns of ecological inequality are highly evident in medium-sized towns in South Africa, where older, affluent suburbs households display greater diversity and abundance of birdlife, compared to subsequent socio-economic zones within the study. Prioritisation with regards to the benefits a garden environment brings to urban residents in terms of a connection to nature, access to urban greenery, and relationship to urban wildlife is vital and should be promoted and planned for across all socio-economic zones.
- Full Text:
- Date Issued: 2020
A socio-political analysis of the adoption of certain AmaXhosa surnames
- Authors: Johnson, Stembele
- Date: 2020
- Subjects: Names, Personal -- Xhosa , Names, Personal -- Xhosa -- Political aspects , Names, Personal -- Xhosa -- Sociological aspects , Xhosa (African people) -- Social life and customs , Onomastics -- South Africa
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/164298 , vital:41107
- Description: It is always assumed when you have a white surname that you have a white lineage or your forefathers were white, and that was always my struggle in school to explain the meaning of my surname and where it came from. Not only European surnames used by amaXhosa are difficult to explain but also many isiXhosa surnames are very hard to break down and explain. This is because many word from th e isiXhosa language, that are used in surnames are no longer used and if one does not know the history of certain names then it would be difficult to know the meaning of a surname or misinterpret its meaning to the modern words of isiXhosa that we know. S urnames are not of African origin, they came from the West, but because of colonialism surnames were enforced on African people. Most of the surnames they used, are said to be names of their forefathers (ancestors), and there is a small amount or none that links to femininity in these surnames. Surnames are part of naming and naming is part of onomastics. Naming is a very important tool used among various African cultures to convey certain messages, either to an individual, family members or a community. On omastics is multidisciplinary in nature. It can be approached from different perspectives. These include linguistic, historical, sociological, philosophical, economical and other perspectives. This research looks at the depth of certain amaXhosa surnames and even their links to other names like, nicknames and clan names etc.
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- Date Issued: 2020
A sociological analysis of the involvement of men in campaigns against sexual violence towards women at Rhodes University: the aftermath of the #RUReference protest
- Authors: Roboji, Philasande Milisa
- Date: 2020
- Subjects: #RUReferenceList , Rhodes University -- Students -- Attitudes , Rape in universities and colleges -- South Africa , Social movements -- South Africa -- Makhanda , Women college students -- Violence against -- South Africa , Male college students -- South Africa -- Attitudes
- Language: English
- Type: text , Thesis , Masters , MSocSci
- Identifier: http://hdl.handle.net/10962/148059 , vital:38706
- Description: Gender-based violence more especially sexual violence towards women is one of the biggest social issus affecting South Africa including higher institutions of learning, universities in this context. In recent years, we have seen students in universities protesting sexual violence demanding universities to improve their ways of dealing with this violence. The motivation behind this thesis is the notion that sexual violence is a women’s issue and how most men in our communities and universities do not involve themselves in campaigns that are designed to end sexual violence towards women. There is an assumption that women should be the ones fighting against sexual violence because it affects them when in fact sexual violence affects everyone and more importantly, is mostly perpetuated by men. Therefore, the main purpose of this thesis was to sociologically analyze the involvement of men in campaigns against sexual violence towards women and the aftermath of the #RUReferenceList protest that took place at Rhodes University in 2016. This protest started immediately after a list of students who were said to be alleged sexual perpetrators was published online. Attached to this primary objective, the sub-goals that informed the entire study were to investigate how the involvement of men in the #RUReferenceList protest has contributed to challenging rape culture at Rhodes University. Also, to investigate if there are any ongoing campaigns and/or projects that includes men and that are still addressing the issue of sexual violence towards women. There is however, a dearth of research on the involvement of men in campaigns against sexual violence in South Africa. Therefore, it was difficult finding existing literature that touches on the involvement of men in campaigns against sexual violence towards women particularly in the context of universities. This thesis was conducted within the premises of Rhodes University through a qualitative research approach in a form of in-depth interviews. Five participants were selected through purposive sampling which included the Chair of the Gender Action Forum, one former student representative council member, a sub-warden from a male residence and two students. The findings of this research are not the full representation of the entire university but opinions and perspective of the participants that were interviewed. Their opinions and perspectives have a potential of contributing to the factors and reasons as to why majority of men have not engaged themselves in issues of gender-based violence or involved themselves in campaigns against sexual violence towards women.
- Full Text:
- Date Issued: 2020
A sociological analysis of the sex education of young adult white womxn and their understandings and practices of ‘Safe Sex’
- Authors: Guerra, Cassandra Gadelha
- Date: 2020
- Subjects: Sex instruction , Sex instruction for girls , Women, White -- Psychology , Women, White -- Sexual behavior
- Language: English
- Type: text , Thesis , Masters , MSocSci
- Identifier: http://hdl.handle.net/10962/147267 , vital:38610
- Description: This research sets out to examine the experiences and perspectives of young adult white womxn regarding their respective sex education. This is in terms of how sex education may shape and influence sexual practices. The relevance of exploring the sex education of this group is to gain an understanding of how constructions of sex education may facilitate the negotiation of sexual practices, particularly as these practices relate to the negotiation of ‘safe sex’. This involves an exploration of definitions of ‘safe sex’ as well as an examination of the various sources of sex education. This research argues that sex education has been socially constructed within a ‘heterosexual matrix’ where both gender identities and sexuality are constructed in heterosexual terms in accordance with compulsory heterosexuality. Furthermore, that sex education as well as understandings and practices of ‘safe sex’ intersect with other social categories such as race, gender and sexuality. Much of the sex-related research conducted in South Africa focuses on people of colour, as a result very little is known about the sexual behaviours and practices of the white demographic. This research accounts for the absence of analysis of sexual practices and behaviour among white people by examining the sex education and sexual practices of young adult white womxn between the ages of 19 and 24. The research observed key sources of sex education which included parents, schools, religious institutions and the internet. Findings indicate that the sex education of participants reflected ideals of heteronormativity and misogyny which were found to directly influence their understandings and practices of both sex and ‘safe sex’. Furthermore, that the sex education participants received has ultimately failed to promote ‘safe’ sexual practices.
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- Date Issued: 2020
A sociological understanding of contemporary child marriage in Mabvuku, Harare, Zimbabwe
- Authors: Madzivire, Shamso Christine
- Date: 2020
- Subjects: Child marriage -- Zimbabwe -- Mabvuku , Child marriage -- Zimbabwe -- Case studies , Shona (African people) -- Social life and customs , Marriage customs and rites -- Zimbabwe , Shona (African people) -- Marriage customs and rites , Marriage -- Zimbabwe
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/142566 , vital:38091
- Description: Child marriage is a phenomenon that has been increasingly recognised as a global problem since the late nineteenth century. Since then, scholars across many disciplines along with various agencies such as government bodies and non-governmental organisations have tirelessly engaged in research exploring the causes and consequences of this practice and in developing prevention and mitigation strategies. These research efforts have been concentrated in some parts of the world and not others, with the findings in many cases being generalised problematically across different geographical areas. This thesis stands as a response to the dearth of academic research on child marriage in present-day Zimbabwe and simultaneously highlights the significance of studying the specificities of child marriage under particular historical and spatial conditions. The main objective of this thesis is to explore and understand child marriage as a part of modernday marriage practices in Zimbabwe, through a case study of child marriage in Mabvuku in Harare. In addressing this objective, it is hoped that new ways of thinking around this phenomenon will become evident. In addressing this main objective, the thesis considers the experiences of child brides, the drivers and consequences of child and post-child marriage experiences. It does this seeking to understand child marriage with reference to the types of marital unions which exist amongst Shona people in pre-colonial times and in post-colonial Zimbabwe. The thesis adopts a qualitative research methodology which involved in-depth semistructured interviews with 25 women in Mabvuku who were married before the age of 18, along with focus group discussions with community workers and interviews with pertinent government and non-government representatives. Due to certain challenges with current theorising about child marriage, there is an attempt to build theory by drawing upon in particular the Zimbabwean notion and practice of hunhu. A key conclusion is that child marriage in present-day Zimbabwe is in part a result of family transitions which arose during the time of colonialism and continue to this day.
- Full Text:
- Date Issued: 2020
A STAT3 of addiction: adipose tissue, adipocytokine signalling and STAT3 as mediators of metabolic remodelling in the tumour microenvironment
- Authors: Kadye, Rose , Stoffels, Mihlali , Fanucci, Sidne , Mbanxa, Siso , Prinsloo, Earl
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/149395 , vital:38846 , https://doi.org/10.3390/cells9041043
- Description: Metabolic remodelling of the tumour microenvironment is a major mechanism by which cancer cells survive and resist treatment. The pro-oncogenic inflammatory cascade released by adipose tissue promotes oncogenic transformation, proliferation, angiogenesis, metastasis and evasion of apoptosis. STAT3 has emerged as an important mediator of metabolic remodelling. As a downstream effector of adipocytokines and cytokines, its canonical and non-canonical activities affect mitochondrial functioning and cancer metabolism. In this review, we examine the central role played by the crosstalk between the transcriptional and mitochondrial roles of STAT3 to promote survival and further oncogenesis within the tumour microenvironment with a particular focus on adipose-breast cancer interactions.
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- Date Issued: 2020
A structural modeling notation for the typed functional paradigm
- Authors: Motara, Yusuf, M
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428948 , vital:72548 , https://doi.org/10.1145/3341105.3373863
- Description: Although typed functional programming is becoming increasingly important for practical software development, it remains inaccessible from a modeling perspective. This paper develops and theoretically justifies an initial best-practices notation for the typed functional paradigm. A small case study explores how the same scenario is modeled differently in the object-oriented and typed functional paradigms, and it is argued that the notation developed is a necessary step on the path to a more comprehensive notation for modeling within the paradigm.
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- Date Issued: 2020
A study of why some physic concepts in the South African Physical Science curriculum are poorly understood in order to develop a targeted action-research intervention for Newton’s second law
- Authors: Cobbing, Kathleen Margaret
- Date: 2020
- Subjects: Physics -- Study and teaching (Secondary) -- South Africa , Physics -- Examinations, questions, etc. -- South Africa , Motion -- Study and teaching (Secondary) -- South Africa
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/146903 , vital:38575
- Description: Globally, many students show a poor understanding of concepts in high school physics and lack the necessary problem-solving skills that the course demands. The application of Newton’s second law was found to be particularly problematic through document analysis of South African examination feedback reports, as well as from an analysis of the physics examinations at a pair of well-resourced South African independent schools that follow the Independent Examination Board curriculum. Through an action-research approach, a resource for use by students was designed and modified to improve students’ understanding of this concept, while modelling problemsolving methods. The resource consisted of brief revision notes, worked examples and scaffolded exercises. The design of the resource was influenced by the theory of cognitive apprenticeship, cognitive load theory and conceptual change theory. One of the aims of the resource was to encourage students to translate between the different representations of a problem situation: symbolic, abstract, model and concrete. The impact of this resource was evaluated at a pair of schools using a mixed methods approach. This incorporated pre- and post-tests for a quantitative assessment, qualitative student evaluations and the analysis of examination scripts. There was an improvement from pre- to post-test for all four iterations of the intervention and these improvements were shown to be significant. The use of the resource led to an increase in the quality and quantity of diagrams drawn by students in subsequent assessments.
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- Date Issued: 2020
A systematic analysis of doctoral publication trends in South Africa
- Authors: van Schalkwyk, Susan , Mouton, Johann , Redlinghuys, Herman , McKenna, Sioux
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185826 , vital:44438 , xlink:href="http://dx.doi.org/10.17159/sajs.2020/7926"
- Description: It is incumbent upon doctoral students that their work makes a substantive contribution to the field within which it is conducted. Dissemination of this work beyond the dissertation, whether whilst studying or after graduation, is necessary to ensure that the contribution does not remain largely dormant. While dissemination can take many forms, peer-reviewed journal articles are the key medium by which knowledge is shared. We aimed to establish the proportion of doctoral theses that results in journal publications by linking South African doctoral thesis metadata to journal articles authored by doctoral candidates. To effect this matching, a customised data set was created that comprised two large databases: the South African Theses Database (SATD), which documented all doctoral degrees awarded in South Africa (2005-2014), and the South African Knowledgebase (SAK), which listed all publications submitted for subsidy to the South African Department of Higher Education and Training (2005-2017). The process followed several iterations of matching and verification, including manual inspection of the data, in order to isolate only those records for which the link was established beyond doubt. Over the period under review, 47.6% of graduates, representing 22 of the 26 higher education institutions, published at least one journal article. Results further indicate increasingly higher publication rates over time. To explore whether the journal article identified was a direct product of the study, a similarity index was developed. Over 75% of records demonstrated high similarity. While the trend towards increasing publications by graduates is promising, work in this area should be ongoing. In spite of increasing trends in publications by graduates, many are not disseminating their work, suggesting that significant bodies of research are potentially not being shared with the academic community and are therefore not contributing to the relevant discipline or field. •This study provides baseline data from which a number of further investigations can be launched, such as exploring the extent to which doctoral candidates who are also academics are publishing their work; the factors that enable or constrain publication; the other avenues of dissemination used; and whether publishing or not publishing can serve as a proxy for the quality of the doctoral work.
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- Date Issued: 2020
A systematic review of the efficacy of internet-based interventions for depression and anxiety disorders: the possibilities and limitations for feasibility within South Africa
- Authors: Sealy-Fisher, Kay Tibeta
- Date: 2020
- Subjects: Depression, Mental -- Treatment -- South Africa , Anxiety disorders -- Treatment -- South Africa , Internet in psychotherapy -- South Africa
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/144632 , vital:38364
- Description: Technological advances may alleviate the burden on South Africa’s mental healthcare system. This study is a systematic review of literature that assesses the efficacy of high quality online interventions for depression and anxiety, and that compares the reviewed studies’ characteristics to the South African context to assist in future developments of online interventions for depression and anxiety within South Africa. This was achieved through using a 2010 systematic review of Griffiths, Farrer, and Christensen as point of departure. This research had two aims: to provide an updated systematic review of the literature reporting on the efficacy of internet-based interventions for depression and anxiety disorders; and to evaluate the possibilities and limitations for the feasibility of implementing internet-based interventions for depression and anxiety disorders in the South African context. Databases accessed were PubMed, PsycINFO, and Cochrane Central Register of Controlled Trials. Included studies must: (i) report on one or more internet-based intervention, (ii) target depression or anxiety or both, (iii) report the effect size or provide enough information to calculate it, (iv) report a measure of symptoms outcome, (v) be a Randomised Controlled Trial, (vi) include a control group that received no active intervention, (vii) be published and peer-reviewed, (viii) have been published after January 2010. The search yielded 2999 potential studies of which 20 full texts were reviewed. Of these, 75% (n=15) of the studies report effect sizes above 0.20, and 25% (n=5) of the studies report effect sizes above 0.80. Themes emergent from literature and included studies distinguished effective from non-effective studies included the use of cognitive behavioural therapy, therapist input and reminders to engage with the intervention, and duration of over 6 weeks. Attrition rates did not differ between experimental and control groups. Sample characteristics between the reviewed interventions and South Africa’s population were found to be different and is discussed. Unfortunately, 37 potential studies could not be accessed and thus not included, although several attempts were made. The majority of studies had effect sizes equal to that of face-to-face therapeutic interventions. Implications of application in South Africa’s context with limited technological familiarity, insufficiency of professionally trained therapists, poor literacy, and high costs of internet data are discussed. It is concluded that with appropriate adaptation, online internet interventions for depression and anxiety would be beneficial to South Africa’s people and assist in lowering the country’s burden of mental health disorders.
- Full Text:
- Date Issued: 2020
A tribute to you
- Authors: Ndlebe-September, Thobeka Veronica
- Date: 2020
- Subjects: South African fiction (English) -- 21st century , South African fiction (English) -- History and criticism , Short stories, South African (English) -- 21st century , Xhosa fiction -- 21st century , Xhosa fiction -- History and criticism , Short stories, Xhosa -- 21st century , Diaries -- Authorship
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/144989 , vital:38398
- Description: My collection of short stories reflects my interest in narrative biblical fiction, allegorical stories about people and nature that resonate with our daily lives. I have been greatly influenced by writers such as Joel Matlou, Flannery O’Connor, Barry Gifford, Miriam Tladi and Leah Harris amongst others. I have also been captivated by fairy tales and folk tales, and also the work of isiXhosa writers such as S. E. K. Mqhayi, Madiponi Masenya, and Hulisani Ramantswana. I have discovered that I can borrow certain styles and forms of writing to enhance my own stories which are situated within ‘local’ contexts such as education, poverty, employment, the body, life and death.
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- Date Issued: 2020
A Veblenian Dichotomy re-examination of labour brokerage and South African labour market functionality
- Authors: Haaketa, Bernadatte Tina
- Date: 2020
- Subjects: Veblen, Thorstein, 1857-1929 , Contracting out -- South Africa , Temporary employment -- South Africa , Industrial relations -- South Africa , Labor supply -- South Africa , Labor supply -- Effect of technological innovations on -- South Africa , Manpower policy -- South Africa , Labor market -- South Africa
- Language: English
- Type: text , Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/168446 , vital:41583
- Description: Labour markets ar ound the world have witnessed a great change in labour relations. The introduction of globa lisation, increased competition and technological advancements has caused business organisations to change their employment methods. While trying to survive and remain profitable, employers have adopted a new form of triangular employment relationship. Thi s form of employment relationship known as labour broking and which forms part of the Temporary Employment Services (TES) involves a relationship between the worker, labour agent (broker) and a client c ompany. Although it may seem like a good strategy for business organisations, the change in employment relationships has had negative effects and contributed to labour market dysfunctionalities . This has resulted in critics of labour broking calling or an end in labour broking and supporters of labour broking asking for better regulation of the industry. Labour markets are me When it comes to analysing labour broking and its impact on labour market functionality in South Africa. Scholars and analysts such as Budlender ( 2013 ) and Bhorat, Lil enstein, Oosthuizen , and Thornton ( 2016 ) have used the Neoclassical , New Institutional Economics and Marxist approach es. The current views on labour broking and the current schools of thought fail to look at the underlying behavioural aspect of labour brokers and the client c ompanies. Hence making it easy for labour brokers and their client companies to continue with their unscrupulous activities. However, this t hesis adapted the Veblenian Dichotomy framework which focuses on understanding the role of the evolutionary proce ss and the role of institutions in shaping economic behaviour. The Veblenian dichotomy shows that power plays an important role in how labour markets are run. Similarly, behaviour also influences the manner in which labour brokers and client companies trea t workers. And lastly the Veblenian dichotomy shows that in order for the industry to be run better there has to be change in the behaviour and cultu re of the labour brokers and client companies . This view allows for deeper analysis of the reasons for the flour ishing nature of labour broking and the rationale behind the behaviour of economic players and attempts to provide solutions on how labour brok ing can be correctly administered in South Africa. The Veblenian Dichotomy categorises institutions into t wo sets, namely the ceremonial institutions and instrumental institutions. Where Ceremonial institutions are said to be institutions that foster the interests of business such as profitability and earning of free income, even if there is no corresponding i ncrease in production. While Instrumental institutions, usually working through the influence of technology, address the interests of the common pers on and the labourer as well as business (Waller, 1982; Foster, 1981; Veblen, 1919). These two systems of va lues and institutions are antagonistic and the relative strength of one to the other determines economic outcomes and in whose interests the outcomes would be (Waller, 1982; Foster, 1981; Veblen, 1919). The Veblenian Dichotomy further looks at ceremonial encapsulation which occurs when ceremonial systems prevail over instrumental systems. Ceremonial encapsulation presents the hypothesis that the insti tutional structure will absorb new technology only to the extent that it can do so without disrupting the e xisting value structure (Waller, 1987; Bush, 1979.) The thesis use d various sources , such as working papers, public hearings, court cases, trade union submissions, integrated reports from companies, employee submissions and media publications on the debate about labour broking whether labour broking and applied the Interpretative Phenomenological Analysi s (IPA) research approach, in the process of data collection and analysis . The thesis further applied thematic analysis to derive themes that would be used to analyse the impact of labour broking on labour market functionality in South Africa. The emergent themes and subthemes were Exploitative lab our relations subthemes; job Insecurity, increased financial burden and no skills development. The second theme was; Competitive advantage and the subthemes were; i ncreased profits and organisational efficiency. The third theme was l abour market efficiency and the subthemes were. E mployment creation and labour market flexibility. And, the last theme was a mbiguous l abour regulation s with subthemes; n o freedom of association and a tool for circumventing labour regulations . Lastly, Tool’s (1994) criteria of j udgement for institutional adjustments was used to evaluate the emergent themes and to evaluate the impact of l abour broking on the overall welfare of individuals, which includes determining whether employees in the TES sector gain skills and improved stan dards of living. The findings of the research the TES sector is characterised by ceremonial values. Ceremonial values (as mentioned in section 3.3) are those values that are warranted by the ways of life that prescribe status and hierarchies and unpleasant distinctions to apply value and status on other people (Bush, 1987, 1988; Ayres, 1967). Thus changing the way in which labour brokers conduct themselves or handle labour broking activities would prove to be difficult . T he power that is mostly used in TES employment sectors is condign power. Condign power is explained as the form of power that is predominantly used in ceremonially encapsulated markets. And it involves making use of punishment or fear in order to get people to do something. This is because w orkers in the TES sector are forced to submit to conditions that they would not normally have submitted to if t hey did not have a fear of losing their jobs. This supports existing literature which shows that in the TES sector, TES employers use force and p ower in order to get the workers to do something, and this results in a master - servant relationship between the employer and the employee. Furthermore, the protests that erupt in the TES sector agree with Marxist theory which notes that the frustrations in the way workers are treated would result in a revolution of the working class against the employers. However, now, workers have not been able to overcome the employers and take over the industry. In addition to what current literature says, the research found that some managers make use of labour broking as a way of manifesting their exploitative characteristics on the labour market, thus creating information asymmetries in order to advance their own personal needs. Situations such as these reve al characteristics of opportunistic behaviour, which is perpetuated by the imperfect flow of information. This means th at the market is imperfect, and imperfect markets are characteristics of dysfunctional labour markets. The research also found that it i s the South African Constitution that protects labour brokers and client companies from accounting for the unfair treatm ent of workers. Labour brokers and client companies rely on the South African Constitution to defend them when it comes to banning labou r broking. This is because section 22 of the Constitution talks about the right of every individual to trade freely in S outh Africa (Kutumela, 2015). When institutional adjustments do not meet the requirements of the progressive criteria, it means they are regressive. Based on the data that was collected and the responses and remarks of the workers, trade unions, and trade union federations, it can be said that TES employment and labour broking hinders labour market functionality. Hence, it can be concluded that, due to the characteristics mentioned, labour broking does indeed have a regressive element which hinders labour m arket functionality. An area for further research for TES employment would be to look at the impact of the amendments to the Labour Rela tions Act. Specifically focusing on the Constitutional Court ruling, which forces labour brokers to treat employees who have been employed for longer than three months as permanent employees.
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- Date Issued: 2020
Absent fathers: psychological and socio-economic implications for black children and directions for future research
- Authors: Magqamfana, Simnikiwe H , Bazana, Sandiso
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/163443 , vital:41038 , DOI: 10.1080/14330237.2020.1744299
- Description: This study investigated fathers’ absence influences on the self-perceptions of South African young adults. Informants were five black university students (two females, three males; age range 20 to 28 years). They responded to semi-structured face-to-face interviews on self-perceptions from having matured in the absence of their biological fathers. Thematic analysis of the data revealed that the informants consider the father-absence when they grapple with material well-being shortage. Participants had mixed perceptions about the psychosocial effects on them from father-absence, with some believing to be thriving despite a history of father-absence. Overall, the findings suggest a need for caution in pathologising young adults with a history of father-absence as necessarily deprived.
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- Date Issued: 2020
Acceptance of ambulatory blood pressure monitoring in a semi-rural population in South Africa:
- Authors: Chiwanza, Farisai , Irwin, Yoland , Dowse, Roslind
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/157072 , vital:40084 , DOI: https://doi.org/10.4102/hsag.v25i0.1336
- Description: Ambulatory blood pressure monitoring is a valuable tool that helps in providing an insight into the diagnosis and management of hypertension; however, no evidence exists of its acceptance in the diverse South African population. We assessed the acceptance of an ambulatory blood pressure monitor in patients attending public sector primary health care (PHC) clinics. Five PHC clinics in the Makana subdistrict in the Eastern Cape.
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- Date Issued: 2020
Acetophenone substituted phthalocyanines and their graphene quantum dots conjugates as photosensitizers for photodynamic antimicrobial chemotherapy against Staphylococcus aureus
- Authors: Openda, Yolande I , Sen, Pinar , Managa, Muthumuni , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186507 , vital:44506 , xlink:href="https://doi.org/10.1016/j.pdpdt.2019.101607"
- Description: This work reports on the synthesis and characterization of novel acetophenone substituted phthalocyanines along with the self-assembled nanoconjugates formed via π-π stacking interaction between the synthesized unmetalated (2), zinc (3) and indium (4) phthalocyanines and graphene quantum dots (GQDs) to form 2@GQDs, 3@GQDs and 4@GQDs. The complexes and conjugates exhibited high singlet oxygen ranging from 0.20 to 0.79 in DMSO for Pcs and nanoconjugates where in all cases, the indium complexes showed the highest singlet oxygen quantum yields. The photodynamic antimicrobial chemotherapy activity of both phthalocyanines and nanoconjugates were tested against Staphylococcus aureus. 4@GQDs was found to be highly effective causing a 9.68 log reduction of the bacteria at 10 μM (based on Pc) when compared to 3.77 log reduction of 3@GQDs.
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- Date Issued: 2020
Activity of diverse chalcones against several targets: statistical analysis of a high-throughput virtual screen of a custom chalcone library
- Authors: Sarron, Arthur F D
- Date: 2020
- Subjects: Acetophenone , Benzaldehyde , Ketones , Pyruvate kinase , Drug development , Aromatic compounds , Heat shock proteins
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/116028 , vital:34291
- Description: Chalcone family molecules are well known to have therapeutic proprieties (anti-inflammatory, anti-microbial or anti-cancer, etc). However the mechanism of action in some cases is not well known. A virtual library of this family of compounds was constructed using custom scripts, based on the aldol condensation, and this library was modified further to analogues by expansion of the α,β-unsaturated ketone linker. Acetophenone and benzaldehyde derivatives which are available and purchasable were used as a base to design the chalcone virtual library. 8063 chalcones were constructed and geometrically optimized with Gaussian 09. Their physicochemical characteristics linked to the Lipinski rules were analyzed with Knime and CDK. The entire library was after docked against several targets including HIV-1 integrase, MRSA pyruvate kinase, HSP90, COX-1, COX-2, ALR2, MAOA, MAOB, acetylcholinesterase, butyrylcholinesterase and PLA2. With the exception of MAOA, which does not have a crystal structure ligand, all dockings were validated by redocking the original ligand provided by the literature. These targets are known in the literature to be inhibited by chalcone-derivatives. However, specificity of the particular known chalcone inhibitors to the particular targets is not known. To this end the performance of the generated chalcone library against the list of targets was of interest. The binding energy of ligand-protein complexes was generally good across the library. Statistical analysis including principal component analysis and hierarchical clustering analysis were made in order to investigate for any physical/chemical characteristics which might explain what chalcone features affect the binding energy of the ligand-protein complexes. The spherical polar coordinates defining the orientation of the binding poses were also calculated and used in the statistical analysis. The statistical analysis has allowed us to hypothesize the importance of these radial distances and the polar angles of key atoms in the chalcones in binding to the pyruvate kinase crystal structure. This was validated by the docking of another small library of compound models in which the α,β-unsaturated ketone chain of the chalcone was replaced by incrementally longer conjugated chains. Further studies on the chalcones themselves reveal rotameric systems in both cis and trans-configurations (which may impact binding), and also studied was the effect of Topliss-based modification and its impact of binding to HSP90. Molecular dynamics confirmed good binding of identified chalcone hits.
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- Date Issued: 2020
African Foreign Policies: Selecting signifiers to explain agency
- Authors: Bischoff, Paul, 1954-
- Date: 2020
- Subjects: Africa Foreign relations 1960- , Africa Politics and government 1960-
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/161716 , vital:40657 , ISBN 9780367348281 , https://www.routledge.com/African-Foreign-Policies-Selecting-Signifiers-to-Explain-Agency/Bischoff/p/book/9780367348281
- Description: This book explores, at a time when several powers have become serious players on the continent, aspects of African agency, past and present, by African writers on foreign policy, representative of geography, language and state size. In the past, African foreign policy has largely been considered within the context of reactions to the international or global 'external factor'. This ground-breaking book, however, looks at how foreign policy has been crafted and used in response not just to external, but also, mainly, domestic imperatives or (theoretical) signifiers. As such, it narrates individual and changing foreign policy orientations over time - and as far back as independence - with mainly African-based scholars who present their own constructs of what is a useful theoretical narrative regarding foreign policy on the continent - how theory is adapted to local circumstance or substituted for continentally based ontologies. The book therefore contends that the African experience carries valuable import for expanding general understandings of foreign policy in general. This book will be of key interest to scholars and students of Foreign Policy Analysis, Foreign Policy Studies, African International Relations/Politics/Studies, Diplomacy and more broadly to International Relations. , Introduction / Paul-Henri Bischoff -- What Next? Past and present African foreign policy concepts and practices / Paul-Henri Bischoff -- The African Union as a Foreign Policy Player: African Agency in International Cooperation / Tshepo Gwatiwa -- Unprincipled Pragmatism and Anti-Imperialist Impulses in an Interconnected World: The Zuma Presidency, 2009-2017 / Mzukisi Qobo -- Towards A Strategic Culture Approach to Understanding and Conceptualising Ethiopia's Foreign Policy Towards Israel and the Middle Eastern Arab Countries / Makonnen Tesfaye -- Nigeria's Foreign Policy and Intervention Behaviour in Africa: What Role for Agency? / Olumuyiwa Amao -- Zimbabwe and New Signifiers: Towards a cultural political economy of Foreign Policy Making / Mike Mavura -- Realist Conceptions of Kenya's Foreign Policy and Foreign Policy Behaviour: A Theoretical and Contextual Disposition / Korwa Gombe Adar and Mercy Kathambi Kaburu -- Addressing the Conceptual Void of African Small State Foreign Policy in Orthodox Theory: A Case Study of Botswana's Principled Pragmatism / Kabelo M. Mahupela -- Tunisia's Foreign Policy Towards France Before and After an Undemanding 'Revolution': A Theoretical Explanation of the An-Nahdha-led Interim Governments' Soft Policy / Ahmed Ali Salem -- Straddling Between Convergence and Divergence: A Constructivist's View of Malawi's Foreign Policy in Post-independence Africa / Eugenio Njoloma -- Strategies of a Small State Between Realism and Liberalism: Sixty Years of Guinea's Diplomacy and Foreign Policy (1958-2018) / Issaka K. Souaré -- Rethinking SADC's Collective Policymaking Processes on External Relations and Non-state Participation for Region-building / Cecilia Lwiindi Nedziwe -- Towards an Understanding of the Interplay Between Ghana's Foreign and Defence Policies / Kwesi Aning and Kwaku Danso -- Conclusion / Paul-Henri Bischoff
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- Date Issued: 2020