Developing Rural Economies through Small to Medium Tourism Enterprise: the case of Matatiele and Cedarville in the Eastern Cape, South Africas
- Authors: Mxunyelwa,Siyabonga , Matarinano, Obert , Vallabh, Dinesh
- Date: 2021
- Subjects: Matatiele, South Africa Small and medium-sized enterprises Small Business Computer File
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/6015 , vital:45081 , https://www.ijicc.net/index.php/ijicc-editions/2021/226-vol-15-iss-10
- Description: Globally, nations depend on small businesses as engines for economic growth. Small to Medium Tourism Enterprises (SMTEs), as part of the small business sector, are increasingly becoming important in terms of job creation, wealth creation and driving economic growth in smaller rural geographic areas. Utilising a mixed research approach, the paper identifies characteristics of SMTEs in Matatiele and Cedarville with the intention of identifying specific ways in which they can be supported to attain their real potential in enabling economic development in rural environment. Purposive sampling method was used to select respondents and self-administered questionnaires utilised to gather relevant data from managers/owners. The results indicate that the rural tourism is dominated by female-owned enterprises primarily offering accommodation services. Most of the enterprises have been in operation for a period of more than five years which points to potential growth as they are able to survive. The results further show that the businesses that participated in the survey intent employing more full-time employees. Furthermore, the results underscore that there is lack of local government support to promote entrepreneurship in the SMTEs sector particularly those that are located in the rural environment. The findings elucidate the ability of SMTEs to greatly reduce the high unemployment in rural economies if appropriate systems are put in place to support these enterprises. These findings have implications for the national, provincial and local government spheres in South Africa in their quest to create job opportunities in rural areas through entrepreneurship and SMTEs in order to provide impetus to the Eastern Cape Province and South African Economy. This paper
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- Date Issued: 2021
Developing Teacher Capabilities and Valued Functionings in Professional Learning Communities: Focus on Environmental Content Knowledge in Natural Sciences
- Authors: Thomas, Kgomotso , Songqwaru, Zintle
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/435234 , vital:73140 , ISBN 9781928502241 , https://library.oapen.org/handle/20.500.12657/64082
- Description: This study explored how professional learning communities can contribute to the development of teachers’ capabilities and the achievement of their valued functionings related to teaching environmental content knowledge in the ‘Life and Living’ strand of Grade 8 Natural Sciences (NS). This is in the context of the Natural Sciences Curriculum Assessment Policy Statement (CAPS) which is strongly content-referenced and is committed to learning approaches that are active and critical, and to environment and sustainability content knowledge (Lotz-Sisitka 2011). The integration of environmental education in the school’s curriculum is of significance as it addresses global and local environmental issues by preparing and actively involving learners in the planning, improvement and protection of the environment for the future (Unesco 2012). The successful implementation of CAPS requires that teachers attain necessary subject content knowledge and pedagogical content knowledge (PCK) for the integration of environment and sustainability concerns into the South African National Curriculum (Lotz-Sisitka 2011). Teachers are also required to have the requisite skills to implement pedagogical approaches that support environmental education.
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- Date Issued: 2021
Development and calidation of the psychometric properties underpinning the Kwaito Music Attitude and Perception Scale (KMP)
- Authors: Williams, Akhona
- Date: 2021
- Subjects: Kwaito-music Attitude and Perception , Chronbach's alpha , Kwaito (Music) , Psychotherapy and music -- South Africa , Problem youth -- Rehabilitation -- South Africa , Attitude (Psychology) -- Testing -- South Africa , Perception -- Testing -- South Africa
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/172478 , vital:42208
- Description: Music holds a privileged position in enhancing therapeutic well-being, supporting life skills development in youth and adolescents, and shaping cultural identities. As such, music has been closely related to youth culture, especially as it pertains to youth rehabilitation and identity formation. Studies (e.g., Duffy and Fuller, 2000; Miranda et al, 2013; Strayhorn, 2011; Tomasello, 2016) highlight the value of utilising music in youth rehabilitation, and acknowledge the intrinsic value of music to facilitate psychological and social change for individuals who would not otherwise benefit from psycho-education, or other didactic modes of youth rehabilitation. That said, Tyson (2005) developed the RAP music scale to psychometrically validate the underlying constructs of youth’ attitudes and perception of rap music in the United States of America, in order to use the instrument for music-based youth rehabilitation programs. The development of the RAP music scale informed the creation and validation of the Kwaito-music Attitude and Perception (KMP) Scale, the subject of my Masters thesis. Following suggestions from Morrison (2014), my study sought to psychometrically validate the properties of the Kwaito-music Attitude and Perception (KMP) Scale. The KMP was found to be a reliable measure of kwaito music attitudes and perception amongst a sample of South African youth who listen to this genre of music. The internal consistency of the questionnaire revealed a Cronbach’s α (Alpha) value of 0.820. Limitations of the project including reduced factor extraction and sample size constrains are discussed. It is envisioned that results from this study will find resonance with youth-community programs, and rehabilitation projects utilising music as a medium of healing amongst South African youth.
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- Date Issued: 2021
Development and education that sustain: Expanding value chains in agriculture, mining and higher education in southern Africa
- Authors: Rosenberg, Eureta , Shumba, Overson , Ngoma, Justine , Cobban, Leigh
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/435811 , vital:73203 , ISBN 978-3-030-74693-3 , https://doi.org/10.1007/978-3-030-74693-3_16
- Description: Deep sustainability, as defined in this chapter, requires a rad-ical conceptual shift, and aligned practical strategies for cre-ating livelihoods and value in new ways. This chapter ex-plores an expanded value chain approach through which in-dustries, communities and higher education institutions in Af-rica can transition towards development that sustains eco-systems and society. An analysis is presented, based on ex-amples from agriculture and mining, two of the most signifi-cant industries on the continent, as well as higher education. The analysis is done by applying key concepts to existing case studies from Zambia and South Africa, and then explor-ing implications for higher education institutions. The chapter concludes that possibilities for more sustainable and shared value creation are already evident in the selected industries, but achieving the shifts required is challenging. Higher edu-cation emerges as having a very significant role to play, through new curriculum and research directions, with greater local relevance, to enable graduates and industries to critical-ly and creatively engage with the challenges on the road to greater sustainability. In this way, higher education institu-tions would become partners in expanded, shared value cre-ation towards deep sustainability.
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- Date Issued: 2021
Developments and prospects for biological control of Prosopis (Leguminosae) in South Africa
- Authors: Kleinjan,Catharina , Hoffman, John H , Heystek, F , Ivey, Philip J , Kistensamy, Y
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/414360 , vital:71139 , xlink:href="https://hdl.handle.net/10520/ejc-ento_v29_n3_a13"
- Description: South Africa was the first country to deploy biological control (biocontrol) against invasive Prosopis populations. Developments in this regard have been ongoing, and have been reviewed, at approximately 10-year intervals, since 1991. This review spans the period 2011-2020, a timespan globally characterised by increased awareness of the impacts of invasive Prosopis populations, and recognition of the need for improved management. Concerted international collaboration has resulted in enhanced clarity on phylogenetic relationships within the Leguminosae and the phylogenetic placement of Prosopis. These advances have improved the framework for interpreting the host range of potential agents and for evaluating risk. At the outset of the biocontrol programme, in the 1980s, only agents that consumed mature seeds were considered. The intention was to reduce the invasiveness of Prosopis while simultaneously retaining it as a usable resource. The programme was subsequently expanded to investigate agents that prevent pod set or maturation of seed. More recently, potential agents that damage the vegetative growth of the plants have been included in response to recognition in South Africa, that there is no other route to successful management of Prosopis. There is a wealth of largely unexplored potential in this regard.
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- Date Issued: 2021
Disilane-bridged architectures with high optical transparency for optical limiting
- Authors: Feng, Hongjie , Zhou, Zhikuan , May, Aviwe K , Chen, Jiaying , Mack, John , Nyokong, Tebello , Gai, Lizhi , Lu, Hua
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190623 , vital:45011 , xlink:href="https://doi.org/10.1039/D1TC01488A"
- Description: A novel tetraphenylethylene (TPE) architecture that makes use of a disilane bridge was developed to successfully prepare organic optical power limiting (OPL) materials with high transparency. The σ-bridged TPE derivatives exhibit enhanced solid-state emission efficacies up to 4 times that of TPE. Due to the unique σ-electron delocalization, the incorporated Si–Si bridge gives rise to intense nonlinear optics (NLO) properties. These compounds show favorable optical transparency in the visible region, since the σ–π interaction has a relatively minor effect on the absorption properties of TPE. The poly(bisphenol A carbonate) (PBC) thin films of disilane-bridged compounds exhibit significant reverse saturable absorbance (RSA) responses during Z-scan measurements at 532 nm. In contrast, negligible OPL properties were observed in tetrahydrofuran (THF) solution and when a PBC thin film was prepared with TPE. The disilane-bridged molecular system represents a novel and easily prepared architecture for the construction of solid-state optical limiting materials.
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- Date Issued: 2021
Diversity is an asset to science not a threat
- Authors: Blackie, Margaret A
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426624 , vital:72373 , xlink:href="https://www.jstor.org/stable/48687065"
- Description: In this paper, Critical Realism is used as a theoretical framework to show that diversity is an asset to science not a threat. Critical Realism situates the reliability and reproducibility of science in the realm of the real and thus relocates the notion of “objectivity” from the person of the scientist to the process of science. This means that it no longer necessary to attempt to minimise the person of the scientist in pursuit of rigorous knowledge. The implication is that diversity both in terms of intellectual training (within limits) and in terms of being multicultural, gender, sexuality, multilingual, is revealed to be an asset. This is because the construction of knowledge draws on personal experience and having people with divergent experience interrogating the same problem is more likely to provide a reliable, reproducible solution. In the latter parts of the paper, the implications for teaching are described. In addition, it is demonstrated that this argument can be extended into different knowledge areas.
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- Date Issued: 2021
Doctors’ practice and attitudes towards red blood cell transfusion at Mthatha Regional Hospital, Eastern Cape, South Africa: A mixed methods study
- Authors: O’Mahony, Don , Adedayo, Temitope , Adeleke, Olukayode
- Date: 2021
- Subjects: Physicians Erythrocytes--Transfusion Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7989 , vital:57871 , xlink:href="https://doi.org/10.4102/phcfm.v13i1.2889"
- Description: Background: Unnecessary blood transfusion exposes recipients to potential harms. Aim: The aim of this study was to describe blood transfusion practice and explore doctors’ attitudes towards transfusion. Setting: A hospital providing level 1 and 2 services. Methods: A mixed-methods study design was used. In the cross-sectional descriptive component, a sample was taken from patients transfused over a 2-month period. Blood use was categorised as for medical anaemia or haemorrhage, and appropriate or not. The qualitative component comprised a purposeful sample for focus group and individual semistructured interviews. Results: Of 239 patients sampled, 62% were transfused for medical anaemia and 38% for haemorrhage. In the medical anaemia group, compliance with age-appropriate transfusion thresholds was 69%. In medical anaemia and haemorrhage, 114 (77%) and 85 (93.4%) of recipients had orders for ≥ 2 red blood cell (RBC) units, respectively. In adults ≥ 18 years old with medical anaemia, 47.1% of orders would have resulted in a haemoglobin (Hb) > 8 g/dL. Six doctors participated in focus group and eleven in individual interviews. There was a lack of awareness of institutional transfusion guidelines, disagreement on appropriate RBC transfusion thresholds and comments that more than one RBC unit should always be transfused. Factors informing decisions to transfuse included advice from senior colleagues, relieving symptoms of anaemia and high product costs. Conclusion: Most orders were for two or more units. In medical anaemia, doctors’ compliance with RBC transfusion thresholds was reasonable; however, almost half of the orders would have resulted in overtransfusion. The attitudes of doctors sampled suggest that their transfusion practice is influenced more by institutional values than formal guidelines. Keywords: red blood cell transfusion; doctors’ attitudes; doctors’ practice; transfusion thresholds; overtransfusion; descriptive study; qualitative study.
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- Date Issued: 2021
Doctors’ practice and attitudes towards red blood cell transfusion at Mthatha Regional Hospital, Eastern Cape, South Africa: A mixed methods study
- Authors: Mabunda, Sikhumbuzo A , O’Mahony, Don , Adedayo, Temitope , Adeleke, Olukayode
- Date: 2021
- Subjects: Physicians Erythrocytes--Transfusion Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7216 , vital:53088 , xlink:href="https://doi.org/10.4102/phcfm.v13i1.2889"
- Description: Background: Unnecessary blood transfusion exposes recipients to potential harms. Aim: The aim of this study was to describe blood transfusion practice and explore doctors’ attitudes towards transfusion. Setting: A hospital providing level 1 and 2 services. Methods: A mixed-methods study design was used. In the cross-sectional descriptive component, a sample was taken from patients transfused over a 2-month period. Blood use was categorised as for medical anaemia or haemorrhage, and appropriate or not. The qualitative component comprised a purposeful sample for focus group and individual semistructured interviews. Results: Of 239 patients sampled, 62% were transfused for medical anaemia and 38% for haemorrhage. In the medical anaemia group, compliance with age-appropriate transfusion thresholds was 69%. In medical anaemia and haemorrhage, 114 (77%) and 85 (93.4%) of recipients had orders for ≥ 2 red blood cell (RBC) units, respectively. In adults ≥ 18 years old with medical anaemia, 47.1% of orders would have resulted in a haemoglobin (Hb) > 8 g/dL. Six doctors participated in focus group and eleven in individual interviews. There was a lack of awareness of institutional transfusion guidelines, disagreement on appropriate RBC transfusion thresholds and comments that more than one RBC unit should always be transfused. Factors informing decisions to transfuse included advice from senior colleagues, relieving symptoms of anaemia and high product costs. Conclusion: Most orders were for two or more units. In medical anaemia, doctors’ compliance with RBC transfusion thresholds was reasonable; however, almost half of the orders would have resulted in overtransfusion. The attitudes of doctors sampled suggest that their transfusion practice is influenced more by institutional values than formal guidelines. Keywords: red blood cell transfusion; doctors’ attitudes; doctors’ practice; transfusion thresholds; overtransfusion; descriptive study; qualitative study.
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- Date Issued: 2021
Does the absence of community involvement underpin the demise of urban neighbourhood parks in the Eastern Cape, South Africa?:
- Authors: Shackleton, Charlie M , Njwaxu, Afrika
- Date: 2021
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175791 , vital:42624 , https://doi.org/10.1016/j.landurbplan.2020.104006
- Description: Public urban green spaces are essential for urban sustainability and the physical and mental wellbeing of urban residents. Yet in some settings they may face a number of threats, ranging from land transformation and development, through to poor maintenance and vandalism. It has been posited that community engagement is a crucial strategy in addressing or minimising many of these threats. Here we report on the condition of 11 newly created or renovated parks in poorer neighbourhoods of six towns over a three year period, along with in-depth interviews regarding the sentiments of local residents and officials to the (re)creation of the parks and their subsequent deterioration.
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- Date Issued: 2021
Ecological patterns and effectiveness of protected areas in the preservation of Mimusops species’ habitats under climate change
- Authors: Sinasson, Gisèle K S , Shackleton, Charlie M , Teka, Oscar , Sinsin, Brice
- Date: 2021
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175812 , vital:42626 , https://doi.org/10.1016/j.gecco.2021.e01527 , https://researchdata.ru.ac.za/search?q=:keyword: "Gap analysis"
- Description: Understanding the niche and habitat requirements of useful and threatened species, their shifts under climate change and how well protected areas (PAs) preserve these habitats is relevant for guiding sustainable management actions. Here we assessed the ecological factors underlying the distribution of two multipurpose and threatened species, Mimusops andongensis and M. kummel, in Benin, and potential changes in the suitable habitats covered by PAs, under climate change scenarios. Fifty seven occurrence points were collected for M. andongensis and 81 for M. kummel.
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- Date Issued: 2021
Ecosystem provisioning services in Global South cities
- Authors: Shackleton, Charlie M
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/433764 , vital:72999 , ISBN 978-3-030-67650-6 , https://doi.org/10.1007/978-3-030-67650-6_8
- Description: All of humankind, urban and rural, rich and poor and whether living in the Global South or the Global North rely to some degree on provisioning ecosystem services such as food, water, timber, fibre and medicinal products. However, in contrast to the Global North the contextual forces shaping many urban livelihoods in the Global South necessitate that many people access the needed provisioning services themselves by directly harvesting or collecting from the immediate, local urban and peri-urban environments, or purchasing them from those who do. Thus, the need for and local availability of provisioning services has profound implications for not only the quality of urban livelihoods, but also the urban ecology in relation to extent and use of urban green infrastructure from where the provisioning services are sourced and the species within them. This chapter summarises compelling evidence from throughout the Global South regarding the extent of use of locally sourced provisioning services by urban communities. It shows that Global South contexts prompt the use of a diverse array of resource types and hundreds of different species in specific settings, much greater than found in Global North cities.
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- Date Issued: 2021
Editorial
- Authors: Rosenberg, Eureta
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/389759 , vital:68481 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/216901"
- Description: This issue of the Southern African Journal of Environmental Education coincides with the start of the 26th United Nations Conference on Climate Change. COP26 in Glasgow is, like its predecessors, a Conference of Parties who will deliberate how to lower global greenhouse emissions and build adaptive capacity so as to reduce the risk and impacts of climate change.
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- Date Issued: 2021
Effect of ultrasonic frequency and power on the sonodynamic therapy activity of cationic Zn (II) phthalocyanines
- Authors: Nene, Lindokuhle C , Sindelo, Azole , Britton, Jonathan , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185737 , vital:44419 , xlink:href="https://doi.org/10.1016/j.jinorgbio.2021.111397"
- Description: We report on the sonodynamic activity of cationic phthalocyanines (Pcs) and the effect of the variation of two parameters: ultrasound frequency and power (Par I (1 MHz, 1 W cm−2), Par II (1 MHz, 2 W cm−2), Par III (3 MHz, 1 W cm−2) and Par IV (3 MHz, 2 W cm−2)) on the efficiency of their reactive oxygen species generation and cancer eradication in vitro thereof. Where Par stands for the various combinations of these parameters. Four Pcs were investigated with substituents bearing diethylamine, ortho- and para-pyridine and morpholine groups. Overall, the para-pyridine and morpholine Pcs showed substantial sono-activity in the various ultrasound parameters with Par I and IV generally showing better singlet oxygen and hydroxyl radicals generation confirmed by electron paramagnetic resonance spectroscopy. In some cases, very high hydroxyl radicals' generation was observed at Par II. Furthermore, the fragmentation of the Pcs after Par II treatments was confirmed using UV–vis and magnetic circular dichroism spectroscopy. The reactive species generation efficacy decreased at Par III for all samples. Ultrasound assisted cytotoxicity of the Pcs was confirmed in vitro using the human (Michigan Cancer Foundation-7) breast cancer cell line.
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- Date Issued: 2021
Efforts towards engaging communities to promote the benefits of biological control research and implementation in South Africa
- Authors: Weaver, Kim N , Hill, Martin P , Byrne, Marcus J , Ivey, Philip J
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/414428 , vital:71146 , xlink:href="https://hdl.handle.net/10520/ejc-ento_v29_n3_a23"
- Description: In the last decade, biological control in South Africa has evolved from a classical applied science, allied to an extension service, to a more community engagement-based activity. Therefore, capacity building is important for the sustainability of biological control research and its implementation. In South Africa, a broad approach has been taken to build capacity in weed biological control, starting at grass-roots level with primary and secondary school learner programmes, through to developing research capacity at the tertiary level and enhancing technical capacity through adult education. Non-specialists are empowered through access to knowledge. The dissemination of accurate information through the most appropriate outlets has become increasingly important, including non-traditional science communication through the internet and, more importantly, social media, which has the potential to reach a far wider audience. Public understanding of biological control has the potential to contribute significantly to the green and knowledge economies of South Africa, but relies on government support for the sustainability of this discipline.
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- Date Issued: 2021
Electrocatalytic Activity of Cobalt Phthalocyanines Revisited: Effect of the Number of Oxygen Atoms and Conjugation to Carbon Nanomaterials
- Authors: Ndebele, Nobuhle , Mgidlana, Sithi , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185700 , vital:44416 , xlink:href="https://doi.org/10.1007/s12678-021-00670-x"
- Description: The synthesis and characterization of tetrakis[4(4-acetlyphenoxy)phthalocyanato] cobalt (II) (1) are presented. Complex 1 together with the reported tetrakis dimethyl 5-(phenoxy)-isophthalatephthalocyaninato] cobalt (II) (2) are conjugated to carbon-based nanomaterials: graphene quantum dots (GQDs) and single-walled carbon nanotubes (SWCNTs) via π-π stacking, taking advantage of the π electrons on the graphitic structure of the nanomaterial as well as on the aromatic rings of the Co phthalocyanines (CoPcs). The electrocatalytic behaviour of the CoPcs, GQDs, SWCNTs and their respective conjugates towards the electrochemical oxidation of catechol was studied. The electrocatalytic probes were drop-dried onto the electrode surface of the glassy carbon electrode (GCE). The electrochemical oxidation of catechol was studied using cyclic voltammetry, electrochemical impedance spectroscopy and chronoamperometry. Complex 2 when linked to GQDs gave the lowest oxidation peak potentials of 0.33 V. Low catechol detection limits (LOD) of 0.057 µM was obtained for complex 2 with SWCNT. Thus, complex 2 containing more oxygen atoms outperformed complex 1 with less oxygen atoms. The CoPcs on their own showed moderate electrocatalytic behaviour, hence showing the importance of conjugating them to the carbon nanomaterials. SWCNT-based electrodes performed better than GQDs, and an improvement in the LoDs, sensitivity and the catalytic rate was observed upon conjugation.
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- Date Issued: 2021
Electrocatalytic activity of manganese tetra 4-aminophenyl porphyrin in the presence of graphene quantum dots
- Authors: Jokzai, Mbulelo , Mpeta, Lekhetho S , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231443 , vital:49888 , xlink:href="https://doi.org/10.1016/j.molstruc.2015.02.040"
- Description: A manganese tetra 4-aminophenyl porphyrin (MnTAPP) was synthesized and attached to graphene quantum dots (GQDs) via covalent and π-π interaction to give MnTAPP@GQDs and MnTAPP--GQDs, respectively. There was an increase (using dynamic light scattering and transmission electron microscopy) in size of the GQDs in the presence of the porphyrin due to aggregation. The porphyrins in the absence and presence of GQDs were then adsorbed onto a glassy carbon electrode using drop and dry method. The electrochemical behavior was tested by cyclic voltammetry and chronoamperometry towards hydrazine. Both methods of combining MnTAPP with GQDs improved the activity of the electrocatalysis compared to individual components. MnTAPP@GQDs showed better catalytic rate constant of 4.36 × 102 Ms−1 and lowest LoD of 0.0023 mM followed by MnTAPP--GQDs. Furthermore, the sensor showed good selectivity in the presence of interfering analytes. All probes showed good stability.
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- Date Issued: 2021
Electrocatalytic activity of Schiff base containing copper phthalocyanines towards the detection of catechol
- Authors: Ndebele, Nobuhle , Sen, Pinar , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231410 , vital:49885 , xlink:href="https://doi.org/10.1016/j.poly.2021.115518"
- Description: In this study, four new copper phthalocyanine complexes were synthesised and studied as electrocatalysts for the detection of catechol. Two of these complexes were derived from a symmetrical benzaldehyde phthalocyanine complex via the condensation of the benzaldehyde substituents with amine reagents. The electrocatalysts proved to be highly stable towards the detection of catechol. The oxidation peaks obtained using cyclic voltammetry range from 0.20 to 0.38 V. Detection limits were obtained via chronoamperometry and are as low as 0.16 µM with fairly high sensitives being obtained. Overall all four copper complexes exhibited excellent electrocatalytic activity towards the electrooxidation of catechol.
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- Date Issued: 2021
Electrocatalytic detection of l-cysteine using molybdenum POM doped-HKUST-1 metal organic frameworks
- Authors: Murinzi, Tafadzwa W , Watkins, Gareth M , Shumba, Munyaradzi , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185748 , vital:44420 , xlink:href="https://doi.org/10.1080/00958972.2021.1907573"
- Description: Glass carbon electrodes (GCE) were modified with metal organic frameworks (MOFs) containing molybdenum polyoxometallates (Mo POMs) in a copper benzene tricarboxylate framework (HKUST-1). The Mo POMs were introduced via one-pot synthesis (Mo2) and post-synthetic modification (Mo1) techniques. The electrode modifiers were characterized by powder X-ray diffraction (PXRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and thermal analysis. The modified electrodes’ oxidation capacity toward L-cysteine was studied. Mo POMs significantly improved electron transfer kinetics compared to the bare GCE. The best Mo POM doped electrode (Mo1-GCE) had a catalytic rate constant of 2.2 × 104 M−1 s−1 and a limit of detection of 3.07 × 10−7 M. Under the employed experimental conditions, the detection response for L-cysteine was very fast (within 0.1 s) for all the modified electrodes and selective toward L-cysteine in the presence of other amino acids.
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- Date Issued: 2021
Electrochemical detection of dopamine using phthalocyanine-nitrogen-doped graphene quantum dot conjugates
- Authors: Ndebele Nobuhle , Sen, Pinar , Nyokong, Tebello
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/185724 , vital:44418 , xlink:href="https://doi.org/10.1016/j.jelechem.2021.115111"
- Description: Two cobalt phthalocyanine molecules were synthesized, a symmetrically substituted CoPc (1) and an unsymmetrically substituted CoPc (2). These CoPcs were π-π stacked onto nitrogen-doped graphene quantum dots (NGQDs). The CoPcs, NGQDs and their respective conjugates were used as electro-catalytic probes in the electrochemical oxidation of dopamine. The molecules were adsorbed onto a glassy carbon electrode (GCE) using the drop dry method, the GCE was used to support those catalysts. The electrooxidation of dopamine was studied using cyclic voltammetry and chronoamperometry. An improvement in the sensitivity and limit of detection was observed upon conjugation.
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- Date Issued: 2021