The structure of aliphatic amine adducts of uranyl acetylacetonate. II. Dioxobis(2,4-pentanedionato)mono (2-N,N-dimethylaminopentan-4-one)uranium(VI)
- Authors: Nassimbeni, L R , Orpen, G , Pauptit, R A , Rodgers, Allen L , Haigh, John M
- Date: 1977
- Language: English
- Type: text , Article
- Identifier: vital:6416 , http://hdl.handle.net/10962/d1006533
- Description: Introduction: In a previous analysis of a compound of this type, we have established that the adduct molecule is bonded through O and that the geometry about U is pentagonal bipyramidal (Haigh, Nassimbeni, Pauptit, Rodgers & Sheldrick, 1976). We have carried out the present analysis to study the conformational effects on the ligand brought about by substitution at N.
- Full Text:
- Date Issued: 1977
The structure of aliphatic amine adducts of uranyl acetylacetonate. IV. Dioxobis(2,4-pentanedionato) mono(2-aminopentan-4-one)uranium(VI)
- Authors: Rodgers, A L , Nassimbeni, L R , Pauptit, R A , Orpen, G , Haigh, John M
- Date: 1977
- Language: English
- Type: text , Article
- Identifier: vital:6420 , http://hdl.handle.net/10962/d1006555
- Description: Introduction: We have shown in three earlier determinations of aliphatic amine adducts of U02(AA)2 (part I: Haigh, Nassimbeni, Pauptit, Rodgers & Sheldrick, 1976; part II: Nassimbeni, Orpen, Pauptit, Rodgers & Haigh, 1977; part III: Rodgers, Nassimbeni & Haigh, 1977) that the conformation of the adduct is dependent on its ability to form hydrogen bonds. The present compound has two H atoms available for hydrogen bonding and may be regarded as the parent of the series.
- Full Text:
- Date Issued: 1977