Construction and integration of a battery pack and management system into a solar car
- Authors: Kloeblen, Arne
- Date: 2013
- Subjects: Solar cars -- Batteries , Solar cars -- Design and construction
- Language: English
- Type: Thesis , Masters , MEngineering (Mechatronics)
- Identifier: vital:9653 , http://hdl.handle.net/10948/d1018654
- Description: In today’s world, we have reached the point where conventional energy forms are inevitably running out. At the same time, the technology for alternative energy harnessing is improving with big steps, especially with society rethinking their high consumption of finite energy and material. This opens the opportunity und increases acceptance for projects and research to prove its actual implementation and to push the boundaries of current technology further.One particular area of application is the automotive sector showcasing raise of costs due to depleting fuel. Solar powered cars are raising interest as it could be a way to complete independence of any resource that has to be produced, mined or in any way transported to the place of consumption. Involvement with the view to enhance their research in this field has become interesting for universities.With solar powered cars, new problems emerge, amongst others the amount of harnessed sun power and the storage to have it available at the point of use. Due to the low energy available, energy storage as light and as efficient as possible is needed. A system is required that allows to be operated independently of its surrounding in a way it is controllable.Lithium-ion based batteries were seen as the most applicable way to execute this, as they give the highest energy density with lower losses than stable, commercially available energy storage mediums.It was decided to design, build and integrate a battery system with its safety circuit into a solar car. After material selection suppliers were searched and contacted. With the successful manufacturing of this system combining different processing methods, partially at university and partially in the industry, the project included a monitoring and management system and protective measures. It was implemented so that neither the limitations of the chemistry and the physical cells nor the vibration occurring while driving the car prevents its proper use. Besides this, communication and dimensions to operate within the car followed, allowing the driver and convoy to access information and control the system.This battery system proved to be practical in street use comparable with that of regular cars and posed as a safe and effective energy supply for an electrically driven car, meeting the given demands.
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- Date Issued: 2013
Constructions of nationhood in secession debates related to Mthwakazi Liberation Front in Bulawayo's Chronicle and Newsday newspapers in 2011
- Authors: Ndlovu, Mphathisi
- Date: 2013
- Subjects: Newspapers , Bulawayo , Matabeleland , Zimbabwe , Chronicle , Newsday , Secession , Devolution , Nationhood , Ndebele , Ethnic identity , Mthwakazi Liberation Front , Mthwakazi Liberation Front -- Zimbabwe , Mass media and nationalism -- Research -- Zimbabwe , Bulawayo (Zimbabwe) -- Newspapers , Matabeleland (Zimbabwe) -- History -- Autonomy and independence movements , Matabeleland (Zimbabwe) -- Social conditions , Zimbabwe -- Social conditions
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:3415 , http://hdl.handle.net/10962/d1001846
- Description: This study investigates the constructions of nationhood in two Bulawayo newspapers, the Chronicle and Newsday. Against the backdrop of the emergence of a secessionist movement, Mthwakazi Liberation Front (MLF), this research examines the discourses of nationhood in the secessionist debates raging in these two newspapers. This study is premised on a view that nationhood constructions cannot be understood outside the broader context in which these newspapers are embedded. Accordingly, it traces the roots and resurgence of Matabeleland separatist politics, exploring the political-historical forces that have shaped a distinctive Ndebele identity that poses a threat to the one, indivisible Zimbabwean national identity. Further, the study situates Matabeleland separatist politics within the broader African secessionist discourse challenging the post-colonial nation-building project on the continent. Informed by Hall’s (1992, 1996) constructivist approach to identity, it considers national identities as fragmented, multiple and constantly evolving. Thus, this study is framed within Hall’s (1997) constructivist approach to representation, as it examines the constructions of nationhood in and through language. The study uses qualitative research methods, as it examines the meanings of nationhood in key media texts. Informed by Foucault’s discourse theory, this research employs critical discourse analysis (CDA) to analyse 12 articles from the two newspapers. The findings confirm that the representations of nationhood in the two newspapers are influenced by their position within the socio-political context. The state-owned Chronicle legitimates the unitary state discourse advocated by ZANU PF. On the other hand, Newsday’s representations are informed by the discourses of the opposition political parties and civil society that challenge the dominant nation-building project. Thus, within this paper, secession and devolution emerge as alternative imaginaries that contest the authoritarian discourse of nationhood
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- Date Issued: 2013
Content and language integrated learning (CLIL) as a language support strategy in a grade 8 natural sciences classroom
- Authors: Thorne, Rochelle
- Date: 2013
- Subjects: Language arts -- Correlation with content subjects , Science -- Study and teaching (Secondary)
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:9466 , http://hdl.handle.net/10948/d1020903
- Description: Content and Language Integrated Learning (CLIL) is an innovative educational approach in which an additional language is used for the learning and teaching of both language and subject content. Content and Language Integrated Learning is not commonly used in South African classrooms, but its application internationally has been shown by empirical research to significantly improve overall language competence in the target language. Reports indicate increased learner motivation and support for the learning of the content subject. This study sought to consider whether CLIL intervention would improve both language and science skills amongst Grade 8 learners in a Natural Sciences classroom. The researcher used a concurrent embedded mixed method design, including both quantitative and qualitative methodologies to gather data. An experimental test design with English Home Language classes and Afrikaans Home Language classes was employed. Hypothesis Testing was used as a statistical analysis to compare the pre-test and post-test results in order to ascertain the impact of CLIL intervention. In addition, the poster-activity and an open-ended questionnaire was used to qualitatively ascertain the impact of CLIL on learner literacy skills. The results showed that CLIL intervention improved learner performance significantly when compared to learners who were not exposed to CLIL. In addition, CLIL lessons were perceived as effective and learners verified that the approach was beneficial to their learning process.
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- Date Issued: 2013
Contributions of inshore and offshore sources of primary production to the foodweb, and the trophic connectivity between various habitats along a depth-gradient, in Sodwana Bay, Kwazulu-Natal, South Africa
- Authors: Parkinson, Matthew Cameron
- Date: 2013
- Subjects: Marine ecology -- South Africa -- Sodwana Bay , Food chains (Ecology) -- South Africa -- Sodwana Bay , Coastal ecology -- South Africa -- Sodwana Bay , Stable isotopes , Dinoflagellates , Marine algae
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5179 , http://hdl.handle.net/10962/d1001630 , Marine ecology -- South Africa -- Sodwana Bay , Food chains (Ecology) -- South Africa -- Sodwana Bay , Coastal ecology -- South Africa -- Sodwana Bay , Stable isotopes , Dinoflagellates , Marine algae
- Description: Sodwana Bay, situated within the iSimangaliso Wetland Park, is ecologically important as it contains high-latitude corals and the most southerly known population of coelacanths. This thesis utilised stable isotope and lipid analyses to investigate the trophic ecology of the area, in particular, understanding the relative contribution of inshore and offshore primary production to consumers inhabiting intertidal and shallow subtidal, coral reef, deep reef, canyon head and pelagic habitats. Seaweeds, excluding certain species of red seaweeds with highly depleted carbon signatures, and phytoplankton, such as diatoms, were found to be the principal sources of primary production for all consumers. Offshore production was typified by dinoflagellates. Particulate organic matter (POM) was spatio-temporally variable. Three distinct productivity periods related to nutrient cycling were noted with enriched carbon signatures and higher organic matter loads associated with warmer water. Inshore primary production was an important source of carbon to consumers in all habitats with the exception of zooplankton that were more reliant on pelagic primary production. Benthic invertebrates reflected a gradient in the utilisation of inshore production, due to the reduced availability of this source further offshore. Consumers at the furthest sites offshore were found to include a substantial quantity of inshore-derived production in their diets. Fishes, which are more mobile, were found to incorporate a similar proportion of inshore production into their diets regardless of where they were collected from.
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- Date Issued: 2013
Control protocol command translation for device interoperability on ethernet AVB networks
- Authors: Foss, Richard , Igumbor, Osedum P
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426978 , vital:72405 , https://www.aes.org/e-lib/browse.cfm?elib=16707
- Description: Audio/Video Bridging (AVB) on Ethernet refers to a suite of standards that allows for deterministic and guaranteed delivery of audio and video content on Virtual Local Area Networks (VLAN). A requirement for the networking of audio devices is to allow for remote establishment and destruction of audio stream connections. There are a number of sound control protocols that utilize AVB transport, and this paper describes an approach for common control and interoperability among them. To demonstrate this approach, this paper describes the design and implementation of a command translator that enables communication between AES64 and OSC-networked AVB devices. Results from a quantitative analysis reveal that when a proxy is used for connection management, noticeable delays are not added to a user’s visual and auditory perception.
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- Date Issued: 2013
Controls on the formation of Wakkerstroom Vlei, Mpumalanga province, South Africa:
- Authors: Joubert, R , Ellery, William F N
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144421 , vital:38344 , DOI: 10.2989/16085914.2012.762897
- Description: The present study investigated controls on the formation of Wakkerstroom Vlei, an 1 000 ha unchannelled valley-bottom wetland on the South African Highveld. Along the uppermost and lowermost reaches of the wetland, where dolerite outcrops occur along the main valley, hydrogeomorphic features typical of geological control on wetland formation are present, including a meandering river channel, oxbow lakes and greater than 3 m deep organic-poor alluvial fill. Along the main body of the wetland, however, floodplain features are absent, alluvial fill is up to 4.5 m deep and contains up to 2 m deep accumulations of peat. These characteristics deviate from the traditional model of dolerite control on wetland formation described by several other studies on Highveld wetland systems.
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- Date Issued: 2013
Coping with HIV and AIDS in marginal communities: a case study of Chivanhu Settlement in Nemanwa, Masvingo, Zimbabwe
- Authors: Makonese, Loveness
- Date: 2013
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3337 , http://hdl.handle.net/10962/d1003744
- Description: This thesis seeks to understand and analyse HIV and AIDS and rural livelihoods in Zimbabwe with particular reference to an isolated and marginalised informal settlement called Chivanhu in Masvingo Province. The focus is specifically on questions around HIV susceptibility, AIDS vulnerability and household resilience. In this regard, it is important to recognise that HIV and AIDS cannot be lumped together as one medical or social condition. Rather, there is a progression from HIV infection to AIDS-related chronic illnesses to possible death, and livelihood strategies often alter along this HIV and AIDS time-line. Zimbabwe for over a decade now has gone through a series of economic and political crises which have impacted detrimentally on both urban and rural livelihoods, even for those households which are not directly affected by the HIV and AIDS pandemic. With the economy in free-fall, households have had to pursue a range of livelihood strategies in order to sustain themselves. These socio-economic conditions have in many ways facilitated susceptibility to HIV infection and vulnerability to AIDS. Many studies have examined this in relation to wellentrenched and stable communities in rural Zimbabwe. But the livelihood dynamics for such communities are significantly different to more unstable and informal settlements like Chivanhu, as thesis seeks to show. At the same time, the thesis offers a longitudinal study which is able to map the changes to the livelihoods of infected and affected households in Chivanhu. Though recognising the debilitating effects of the pandemic on these households, it also raises questions about the possible resilience of certain households despite great adversity. In doing so, it goes beyond the individual and household levels of analysis to consider the role of clusters (or groups of households) in responding to the impacts of HIV and AIDS. In this regard, particular emphasis is placed on gender and orphanhood. In the end, the thesis offers a nuanced analysis of the everyday complexities and challenges for affected households in a marginalised and informal rural community in Zimbabwe and thereby makes a contribution to re-theorising HIV and AIDS and rural livelihoods more broadly.
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- Date Issued: 2013
Corporate social responsibility of private game reserves in the Eastern Cape Province
- Authors: Motala, Amina Sadiq
- Date: 2013
- Subjects: Social responsibility of busines -- South Africa -- Eastern Cape Game reserves -- South Africa -- Eastern Cape Ecotourism -- South Africa -- Eastern Cape Environmental responsibility -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1187 , http://hdl.handle.net/10962/d1004335
- Description: The primary aim of this research study was to determine the current state of practice of corporate social responsibility (CSR) within the ecotourism based private game reserve (PGR) industry in the Eastern Cape Province of South Africa. According to Carroll (1991) four kind of responsibilities constitute total CSR, namely economic, legal, ethical and philanthropic responsibilities. Given the context of this research a fifth responsibility concerning environmental responsibilities was added to Carroll 's (1991) pyramid ofCSR. A descriptive and illustrative case study approach, within the phenomenological research paradigm, was used for the purpose of this research. The unit of analysis is the Indalo group, the Association of Eastern Cape Private Game Reserves, made up of 12 ecotourism based PORs. As the current research focused on eight of the twelve PGRs a mUltiple case study was employed. To give effect to the aim a number of research objectives were identified. Firstly to desclibe and assess the current practice in implementing CSR within the ecotourism based PGR industry in the Eastern Cape Province. Secondly, to assess and evaluate the involvement of ecotourism based PGRs in the Eastern Cape Province in each of the five responsibilities comprising CSR. Thirdly, to identify the challenges faced by ecotourism based PGRs in the Eastern Cape Province with regard to the implementation of CSR initiatives. Lastly to provide pertinent conclusions and recommendations with regard to CSR strategies within the ecotourism based PGR industry in the Eastern Cape Province. Data were collected by means of in-depth interviews with the managers of each reserve. In addition the researcher conducted focus interviews with administrative employees at each of the member reserves of the Indalo group. Additionally the managers of each reserve were requested to respond to a structured five point Likert scale questionnaire based on the research by Aupperle, Carroll and Hatfield (1985). This research study found that the current practice at the Indalo group is towards a strategic, long term approach to CSR that aids in the development of a 'sustainable organisation.' The aspect of ' empowerment' emerged as the essence of the current practice ofCSR of the Indalo group. Based on the current practice it was concluded that the Indalo group is actively involved in the specific components of CSR namely, environmental, economic, legal, ethical and philanthropic responsibilities. With regard to the environmental responsibilities it was concluded that the environment is the foundation upon which all other components of CSR rest. In addition it was concluded that the economic responsibilities, if managed well, are key to unlocking the CSR potential of a reserve as well as ensuring widespread economic development. In terms of the legal and ethical responsibilities it was concluded that tourism policies both at the national and international level have not aided in the development of a CSR agenda of the Indalo group. Furthermore managers of the reserves have been instrumental in cultivating their own legal culture of CSR based on their experience in the tourism industry and their ethical stances. In terms of the philanthropic responsibilities it can be concluded that charitable activities that are long term and strategic in nature allow for direct and indirect benefits to all parties involved. Overall, it can further be concluded that despite Hudson and Miller's (2005:5) view that the "tourism industry is well hehind other industries in terms of CSR" the Indalo group is moving forward in terms of rooting CSR into their everyday operations.
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- Date Issued: 2013
Could a regulated market approach for rhinoceros horns work in South Africa? Some practical issues and concerns
- Authors: Collins, Alan , Fraser, Gavin C G , Snowball, Jeanette D
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68600 , vital:29292 , http://www.essa2013.org.za/fullpaper/essa2013_2708.pdf
- Description: Publisher version , One of the proposals for fighting rhinoceros poaching is to legalise the trade in rhino horn and adopt a regulated market approach (RMA), which would require a vote at the 2016 CITES meeting in order to overturn the ban on the trade in rhino horn. The legal trade in rhino horn would enable the auctioning of stockpiles of horn and encourage captive breeding programmes. The aim of increasing the supply of horn is to reduce incentives to poach by driving down the price. This paper uses a conceptual/theoretical approach to consider the practical implications of the adoption of an RMA, drawing on demand, supply and production theory. The intention is explicitly to set out some practical concerns and issues that seem to have been underplayed or neglected in most published economic discourse on the subject. To secure a stockpile for some species needs biological success in captive breeding programs (CBPs) but this varies across species and habitats. Rhinoceros herds in a CBP would need relatively spatially extensive terrain and costly permanent security measures, and only appear feasible for the less aggressive “white” rhino. Thus, market price would actually need to be sustained at a high level to cover the start-up and security costs of such a programme that are unlikely to fall significantly. This is a double-edged sword in that the persistent high price of rhino horn provides an incentive for continued poaching activities. Supplementary policy measures that differentiate among consumer groups may also prove necessary.
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- Date Issued: 2013
Counting planes
- Authors: Rawlins, Isabel Bethan
- Date: 2013
- Subjects: Prose poems , Flash fiction , Short stories , English , Creative writing (Higher education) , Short stories, South African (English) -- 21st century , South African fiction (English) -- 21st century , South African poetry (English) -- 21st century , English language -- Writing
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:5966 , http://hdl.handle.net/10962/d1001816
- Description: This collection of prose-poems and flash fiction, together with a few short stories, shows how romantic relationships colour our perspectives on the world. The collection has echoes throughout of speakers' voices, theme, imagery and tone. There is a narrative logic too, but working on a subtle level of echo and resonance
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- Date Issued: 2013
Creating a new declaration of rights : a critical reconstruction of earth jurisprudence's global legislative framework
- Authors: Lenferna, Georges Alexandre
- Date: 2013
- Subjects: Universal Declaration , Rights , Earth , Environment , Ethics , Environmental law, International -- Research , Environmental law, International -- Philosophy , Environmental ethics -- Research , Nature conservation -- Law and legislation -- Research , Jurisprudence -- Research , Law -- Philosophy
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: vital:2704 , http://hdl.handle.net/10962/d1001979
- Description: This thesis aims to critique the Universal Declaration of the Rights of Mother Earth and its underlying moral justification in order to provide a stronger and improved version of both. In Chapter 1 I explore what sort of moral justification is necessary to establish the Universal Declaration on firm grounds and explore its relation to environmental ethics and rights discourse. I argue that a non-anthropocentric perspective is necessary to justify the Universal Declaration’s rights. In Chapter 2 I explore the underlying justification of the Universal Declaration as discovered in the works of Cormac Cullinan and Father Thomas Berry. I argue that their ethical framework is indeterminate, has many ambiguities and uncertainties, and, among other problems, it does not provide a clear action-guiding framework. In Chapter 3 I develop an alternative justification for the Universal Declaration. I argue against many predominant moral theories, that in light of our best scientific and moral understanding we should expand the realm of moral concern to include all living beings, a moral theory I call Life’s Imperative. In Chapter 4 I illustrate that Life’s Imperative is a much stronger, more coherent justification for the Universal Declaration, one that coheres with both our best understanding of the natural world and our relation to it, and to an environmental ethic reflective of that relationship. Unfortunately many of the weaknesses in the current implicit justification of the Universal Declaration have also led to it enshrining rights that are themselves problematic. In order to address these issues, I revise its rights to accord with the stronger justification that I established in Chapter 3. The end result of doing so is a revised version of the Universal Declaration
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- Date Issued: 2013
Cretaceous dyke swarms and brittle deformation structures in the upper continental crust flanking the Atlantic and Indian margins of Southern Africa, and their relationship to Gondwana break-up
- Authors: Muedi, Thomas Tshifhiwa
- Date: 2013
- Subjects: Dikes (Geology) -- Africa, Southern , Joints (Geology) -- Africa, Southern , Gondwana (Continent)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10675 , http://hdl.handle.net/10948/d1020896
- Description: Permanent brittle deformation of rocks of the upper crust is often manifested in the growth of fractures, or sliding along fractures, which may subsequently be intruded by magma and other fluids. The brittle deformation structures described here include faults, joints and dykes. Brittle deformation structures along passive continental margins result from continental fragmentation and related uplift, as is seen around the southern African margins in response to Gondwana break-up. In many cases the fragmentation is accompanied by significant magmatic events, for example the Cretaceous mafic dyke swarms that form major components of the South Atlantic Large Igneous Province (LIP) and originated during the break-up of West Gondwana (Africa and South America). The magmatic events accompanying the break-up of Gondwana resulted in crustal extension and the formation of joint systems and dyke swarms that exhibit distinct geometric features that appear to display fractal patterns. This work analyses the relationship between the Henties Bay-Outjo Dyke Swarm (HOD) on the west coast of Namibia, and the Ponta Grossa Dyke Swarm (PG) on the coast of Brazil, both of which formed ca. ~130 Ma, to test for their co-linearity and fractal geometry before and during West Gondwana break-up. This was achieved by reconstructing Gondwana‘s plates that contained the PG and HOD swarms, using ArcGIS and Gplates software. The dyke analyses was complemented with a comparative study of joints of the Table Mountain Group quartzites (TMG, ca. 400 Ma) in the Western Cape Province and Golden Valley Sill (GVS, ca. 180 Ma) in the Eastern Cape Province, to compare their fractal patterns and possible relationship. Mapping of joints was carried out in the field with the use of a compass and GPS. The HOD trend is positioned largely NNE > NE, but a NW dyke trend is also common. The dominant joints in the TMG trend NNW > WSW and the GVS joints trend WNW > NNE and others. The GVS and HOD orientations appear strongly correlated, while TMG shows no simple orientation correlation with GVS and HOD. The lack of correlation is attributed to the TMG‘s formation in different host-rocks with variable anisotropy and/or the presence of different mechanical processes acting at a different time in geological history. All mapped dykes and joints were analysed to test for fractal geometry. The fractal dimension results of about 18605 HOD dykes from microscopic to mega scale (0.1 mm – 100 km) shows fractal patterns that range between Df = 1.1 to 1.9; and the fractal dimension of about 1716 joints in the TMG and about 1026 joints in the GVS at all scales range between ca. Df = 1.6 to 1.9. The similarity of the fractal patterns indicates that joints and dykes may have formed in response to similar tectonic stress events; and similar orientations may indicate that joints pre-dated the dyke intrusions. However, the data also indicate that dykes are not always related to pre-existing joints.
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- Date Issued: 2013
Crime fiction, South Africa : a critical introduction
- Authors: Naidu, Samantha
- Date: 2013
- Language: English
- Type: Article
- Identifier: vital:26315 , http://hdl.handle.net/10962/53743 , http://0-dx.doi.org.wam.seals.ac.za/10.1080/1013929X.2013.833416 , https://orcid.org/0000-0001-9456-8657
- Description: Crime fiction is an emergent category in South African literary studies. This introduction positions South African crime fiction and its scholarship in a global lineage of crime and detective fiction. The survey addresses the question of its literary status as ‘highbrow’ or ‘lowbrow’. It also identifies and describes two distinct sub-genres of South African crime fiction: the crime thriller novel; and the literary detective novel. The argument is that South African crime fiction exhibits a unique capacity for social analysis: a capacity which is being optimised by authors and interrogated by scholars
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- Date Issued: 2013
Critical core competencies for effective strategic leadership in project management
- Authors: Jowah, Enoch Larry
- Date: 2013
- Subjects: Leadership -- Psychological aspects , Project management , Core competencies , Leadership
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: vital:9305 , http://hdl.handle.net/10948/d1017230
- Description: Project management is undeniably the fastest growing discipline as organizations move into the euphoria of projectification of their operations. Though projects have been a part of human life since time immemorial, there is a sudden realisation of the effectiveness of the methods used in project management. The enrolment of students studying for project management in tertiary institutions has shown tremendous increase. Yet the project execution process is mired by high failure rates and absence of clarity on the necessary skills required for effective project execution. The authority-gap in project management presents political and operational conflicts, and new innovative ways of authority-gap reduction need to be identified and taught in training programs. Simultaneously there is a realisation by both academics and practitioners that there is a difference between managers and leaders. Extensive studies on leadership have not allowed for a one-stop-leadership-style to be used in leadership of any form, let alone project leadership. In fact there is no standard definition of leadership as this has been heavily contextualized and thereby disallowing the creation of a universal definition. No cast-in-stone leadership styles are known and thereby leaving the research on leadership to concentrate on critical competencies required for effective leadership of projects. This study seeks to establish the core competencies needed by the project leaders and other practitioners to reduce the failure rate and maximise the benefits currently sought after by organisations. Studies have shown that the matrix structure within which the embedded projects work is a contributing factor to the failure of projects. Because projects are executed by people, it would be the proper utilisation of people’s talents and competencies that are expected to yield favourable results. Thus, whilst the matrix structure creates the authority-gap that presents a problem for effective project execution, management-by-projects still remains the best way known to add economic value to performance and productivity. The study therefore focuses on those characteristics of project leaders that will most likely make the difference in the way people perform in the workplace. The research findings emphasised the importance of empowerment of project managers and the development of their interpersonal skills of the project leader with special emphasis on extroversion, genuineness of senior management, and the responsiveness of the project leaders as important requirements for effective authority- gap reduction. These critical competencies will therefore facilitate the project execution process and enhance the empowered project leader’s ability to reduce the high project failure rate and high cost overruns. These competencies apply specifically to the human element as it relates to the role of the project leader and the interaction with the team members, this new knowledge needs to be introduced into training programs and project practitioners.
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- Date Issued: 2013
Critical factors for business success in co-operatives
- Authors: Mpongoshe, Lukhanyiso
- Date: 2013
- Subjects: Cooperative societies -- South Africa -- Nelson Mandela Bay Municipality , Success in business -- South Africa -- Nelson Mandela Bay Municipality
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8842 , http://hdl.handle.net/10948/d1020041
- Description: Many countries that have achieved economic development have a dynamic co-operative sector which contributes substantially to the development of these economies. From a global perspective, co-operatives have been proven to be flexible in meeting a wide variety of social and economic human needs such as job creation, alleviation of poverty and building of communities. With the drive to decrease poverty in South Africa, there has been an increased interest to support co-operatives with the intention to provide employment, social development and building communities/ community care. It seems, however, that South Africa has not yet reached the same momentum in the co-operatives movement as elsewhere in the world and the economy is still characterized by a high unemployment rate and a low growth rate (Van der Walt, 2002). This study is an attempt to determine the factors for business success in co-operatives by assessing the strengths and weaknesses of co-operative businesses within the Nelson Mandela Metropolitan Municipality in the Eastern Cape. The study includes an extensive literature review on the nature and prevalence of co-operatives in South Africa where challenges faced by South African co-operatives and particularly those in the Eastern Cape Province, are indicated. It also highlights international best practice and reveals that for co-operative success, apart for functioning by the International Seven Cooperative Principles, knowledge and expertise in business management are absolutely necessary so that co-operatives can be profitable and sustainable. With this knowledge, an adapted form of the Small Enterprise Development Agency (SEDA) Small Business Assessment Tool was used to formulate the questionnaire and to review business management literature. A survey conducted involved fifty-one co-operative members on the database of the Nelson Mandela Metropolitan University Business Unit. The opinions of the respondents were compared with the guidelines provided by the literature in the study in order to identify the strengths and weaknesses of these co-operatives, which then determine the critical success factors for business success in co-operatives. The empirical results show that the co-operative members understand co-operative principles and function through them. They have a fairly general knowledge of business management. The results also show significantly positive correlations between Marketing Management, Financial Management, Operations Management, Human Resources Management and General Management, on the one hand, and the business success of co-operatives, on the other hand. This indicates that these respondents recognize the importance of these business functions in the success of their businesses. However, failures and weaknesses experienced in these areas lead to the recommendations that they need to be mentored as they cannot put this knowledge into application, and secondly, they need financial assistance and support to sustain the co-operative businesses.
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- Date Issued: 2013
Critical indirect effects of climate change on sub-A ntarctic ecosystem functioning
- Authors: Allan, E Louise , Froneman, P William , Durgadoo, Jonathan V , McQuaid, Christopher D , Ansorge, Isabelle J , Richoux, Nicole B
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/457934 , vital:75696 , xlink:href="https://doi.org/10.1002/ece3.678"
- Description: Sub‐Antarctic islands represent critical breeding habitats for land‐based top predators that dominate Southern Ocean food webs. Reproduction and molting incur high energetic demands that are sustained at the sub‐Antarctic Prince Edward Islands (PEIs) by both inshore (phytoplankton blooms; “island mass effect”; autochthonous) and offshore (allochthonous) productivity. As the relative contributions of these sustenance pathways are, in turn, affected by oceanographic conditions around the PEIs, we address the consequences of climatically driven changes in the physical environment on this island ecosystem. We show that there has been a measurable long‐term shift in the carbon isotope signatures of the benthos inhabiting the shallow shelf region of the PEIs, most likely reflecting a long‐term decline in enhanced phytoplankton productivity at the islands in response to a climate‐driven shift in the position of the sub‐Antarctic Front. Our results indicate that regional climate change has affected the balance between allochthonous and autochthonous productivity at the PEIs. Over the last three decades, inshore‐feeding top predators at the islands have shown a marked decrease in their population sizes. Conversely, population sizes of offshore‐feeding predators that forage over great distances from the islands have remained stable or increased, with one exception. Population decline of predators that rely heavily on organisms inhabiting the inshore region strongly suggest changes in prey availability, which are likely driven by factors such as fisheries impacts on some prey populations and shifts in competitive interactions among predators. In addition to these local factors, our analysis indicates that changes in prey availability may also result indirectly through regional climate change effects on the islands' marine ecosystem. Most importantly, our results indicate that a fundamental shift in the balance between allochthonous and autochthonous trophic pathways within this island ecosystem may be detected throughout the food web, demonstrating that the most powerful effects of climate change on marine systems may be indirect.
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- Date Issued: 2013
Critical studies in carbon electrode materials with applications in the electroanalysis of the mycotoxin citrinin
- Authors: Niland, Michael John
- Date: 2013
- Subjects: Electrodes, Carbon , Mycotoxins
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4555 , http://hdl.handle.net/10962/d1018256
- Description: Guided by increasing legislation, the analysis of food borne toxins, including mycotoxins, seeks to address market related demands for the development of analytical systems to monitor this threat to food security and human health. This Thesis is directed at the assessment of the application of electrochemistry for direct electroanalysis and characterisation of the mycotoxin citrinin (CIT) in aqueous media as well as fundamental investigations of the surface of polished and oxidised glassy carbon electrodes (GCE). This study provides the first known account of CIT detection through electrochemical methods. Although electrochemically active, CIT current responses (Ip) were highly irreproducible at polished GCE with a coefficient of variation (C.V.) of 20.16 %. As stability of Ip across multiple electrode preparations is a key requirement in electroanalysis, investigations were directed at attaining stability in CIT Ip. Achieving stability in CIT Ip was investigated via two approaches, including: accounting for Ip variability between electrode preparations as a result of variable GCE surface conditions as a post-data-acquisition analysis and secondly, removing Ip variability through modification of GCE. Accounting for variability in Ip was investigated through the application of double layer capacitance as an indicator of the activity of an electrode, and in so doing serving as a relative mediator of Ip responses between electrodes. Application of this procedure dropped CIT C.V. to a third of starting value across polished GCE (C.V. = 7.18 %), chemically oxidised GCE (Pi-GCE, C.V = 8.47 %) and functionalised multi-walled carbon nanotube modified GCE (fMWCNT, C.V. = 25.79 %) and was effective with analysis of structurally distinct molecules, 2,4-dimethylaniline (2,4-DMA) and 1,2,4-trihydroxybenzene (Triol). Furthermore, it afforded the ability to determine discreet solution overlapping data sets of Ip. Stabilising Ip through GCE surface modification was achieved by anodic electro-oxidation of GCE and allowed for direct electroanalysis of CIT and subsequent characterisation and analysis of CIT in complex media as it reduced C.V. of CIT Ip to 0.73 %. Fundamental investigations of the electrode surface condition are described such that the source of variability could be identified and the interactions of CIT with the electrode understood. Two surface oxidation techniques were applied in modification of GCE; anodic electro-oxidation (EOx GCE) and chemical oxidation using piranha solution (Pi-GCE), analysis of which has previously not been reported. Fundamental analyses to determine surface morphology and chemistry of Pi-GCE, EOx-GCE and polished GCE were conducted using high resolution scanning electron microscopy (HRSEM), scanning electrochemical microscopy (SECM), energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), fourier transform infrared spectroscopy (FTIR) and via electroanalytical methods. These studies showed that both oxidation procedures introduced a variety of oxide species at GCE surface, and further that the extent of those species was similar with total % O being 27.67 % and 33.47 % at Pi-GCE and EOx-GCE respectively. Although chemically similar, each surface was morphologically distinct. Electrochemical analyses at the surfaces revealed Pi-GCE to behave more similarly to polished GCE than EOx-GCE. As CIT responses were found to be stable at EOx-GCE (C.V. = 0.73 %) as opposed to Pi-GCE (C.V. = 22.87 %), stability of CIT Ip was likely to be as a result of a physical interaction with electrode morphology rather than interaction on a chemical basis. Morphological analyses revealed polished GCE and Pi-GCE to be highly morphologically irregular at the micro-scale. Although comparatively smooth, the surface morphology of EOx-GCE does not account for the stability of Ip. This study thus proposed a theory to describe the mechanism by which the limited conductivity and porosity of EOx-GCE allow for it to provide a relatively stable surface area within the oxide layer, adjacent to the electrode surface, and thus provided a stable platform for electroanalysis. Voltammetric characterization of CIT at EOx-GCE revealed that anodic oxidation in aqueous media involved an uneven number of electrons to protons via an ECE mechanism. This was illustrated to be nt = 2e- accompanied by the transfer of 1H⁺ per molecule oxidised. A proposed reaction scheme for the initial stages of CIT oxidation was suggested to involve both hydroxyl and carboxyl moieties of the CIT molecule. CIT oxidation was shown to arise as a result of a relatively complex mass transport regime which included both adsorptive and diffusive derived Ip₁. The LOD in buffered aqueous media was found to be 16 nM, a highly competitive result in relation to chromatographic techniques. Further application of EOx-GCE in complex media illustrated that CIT associates non-specifically with the components of food samples, primarily proteins. As a result of this, extraction of CIT from such media is mandatory. Liquid-liquid extraction illustrated a recovery in CIT Ip₁ and in so doing provided a means of accurately and sensitively detecting CIT from food samples with an LOD of 20 nM. These responses were corroborated by HPLC analyses on the same extractions and illustrate the applicability of electroanalysis as an analytical technique.
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- Date Issued: 2013
Current and potential carbon stocks of trees in urban parking lots in towns of the Eastern Cape, South Africa
- Authors: O'Donoghue, Alexandra , Shackleton, Charlie M
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181037 , vital:43689 , xlink:href="https://doi.org/10.1016/j.ufug.2013.07.001"
- Description: Greening of shopping centre parking lots is a potentially important strategy that can contribute to urban carbon mitigation efforts, improve aesthetics and the shopping experience of consumers, whilst adding to urban biodiversity. Twenty-eight shopping centre parking lots in six Eastern Cape urban centres, South Africa, were sampled to determine tree species composition, density and annual carbon sequestration potential. The best case parking lot found during the study was used as a benchmark to display the difference between current tree density and above-ground carbon stocks relative to the potential optimum. The highest tree density was 66 trees ha−1, whereas the average density across all sampled parking lots was less than half that (27.2 ± 22.6 trees ha−1). The average annual carbon sequestration potential per parking lot was 1390 ± 2503 kg ha−1. Planting density was positively related to annual sequestration rates, whilst parking lot age and the mean annual rainfall of the town had no influence. Mean tree species richness per parking lot was 2.3 ± 1.8 species, with a positive relationship to parking lot size, but not to mean annual rainfall of the site. The majority of trees (62.5%) in parking lots were alien species, although newer parking lots had significantly greater proportions of indigenous species. There was no difference in mean annual carbon sequestration rate per tree between indigenous and alien trees species. Low tree densities and small parking lot areas constrained the potential for earning carbon credits from trees in parking lots. Nonetheless, planners and designers need to be more aware of the potential contribution of trees towards urban sustainability.
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- Date Issued: 2013
Curriculum Vitae of Prof Tebello Nyokong (OMB)
- Authors: Nyokong, Tebello
- Date: 2013
- Language: English
- Type: Article , text
- Identifier: vital:7233 , http://hdl.handle.net/10962/d1006180
- Description: Department of Science and Technology (DST) and National Research Foundation (NRF) Professor of Medicinal Chemistry and Nanotechnology and Distinguished Professor of Chemistry at Rhodes University.
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- Date Issued: 2013
Customising a BBVC for Asterisk VoIP Services
- Authors: Oyedele, Y , Terzoli, Alfredo , Mufeti, K
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430942 , vital:72730 , https://doi.org/10.1007/978-1-4614-3558-7_62
- Description: Browser-based Voice over Internet Protocol Clients (BBVC) are used to access pre-determined VoIP services from VoIP service providers through Internet connections. For nomadic users within an organisa-tion’s Intranet, connections are made to the Internet to utilise these BBVC. An Intranet with an Asterisk Private Branch Exchange (PBX) as a VoIP provider however can be linked with any form of VoIP client to improve service accessibility for its users. This study aims to find a BBVC that can be customised to provide such accessibility within an Intranet. The study revealed that three BBVC are compatible. One of three BBVC was selected for customisation to provide nomadic acces-sibility to Asterisk. The functionality of the customised BBVC depended on the web technologies used and the available VoIP services.
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- Date Issued: 2013