An investigation of enabling and constraining factors affecting the supply and demand of specific biodiversity scarce skills to the biodiversity sector
- Authors: Mckrill, Leanne Joy
- Date: 2015
- Subjects: Rhodes University , GreenMatter (South Africa) , CATHSSETA (South Africa) , Labor demand -- South Africa , Biodiversity conservation -- Employees -- Supply and demand -- South Africa , Wildlife veterinarians -- Supply and demand -- South Africa , Freshwater ecology -- Employees -- Supply and demand -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2067 , http://hdl.handle.net/10962/d1020837
- Description: This study is situated within the context of the emerging South African Biodiversity Sector and focuses on the supply of and demand for scarce skilled biodiversity professionals. It does so through investigating the transition a young biodiversity professional makes from a higher education institution to the workplace by drawing attention to the factors encountered or perceived to be encountered during this development. The study forms part of a research programme established between Rhodes University, GreenMatter and the Culture Arts Tourism Hospitality Sport Education and Training Authority (CATHSSETA), which seeks to contribute to the body of knowledge pertaining to "green" skills development and retention within the South African biodiversity sector. It is a qualitative study, comprising nested case studies within two larger case studies of scarce skills – those of wildlife veterinarians and freshwater ecologists – as identified by the biodiversity priority scarce skills list (SANBI & Lewis Foundation, 2012). The study is supported by Bronfenbrenner's (1979) Ecological Systems theory and underpinned by the principles of basic critical realism and emergence (Archer, Bhaskar, Collier, Lawson, & Norrie, 1998). Data was generated through a range of data collection methods, including semi-structured interviews, participant observation and document analysis. The aim of these methods was to enable a greater understanding of the factors influencing transitioning and the unique transitions of selected individuals. Findings revealed that the transitions of the participants, although unique to each of them, included the following commonalities: exposure to biodiversity at an early stage in an individual's life paved the way for the development and nurturing of an interest or passion in biodiversity; experience gained prior to entry into the workplace is a powerful enabling factor; the presence or absence of a mentor can be pivotal in the transition of an individual; the gap in knowledge pertaining to demand side or workplace information is a large constraining factor; workplace dynamics affect the demand for, and eventual supply of, biodiversity professionals; the presence of human capital development strategies and structures is beneficial to the individual's transition, and the overall ecosystemic development of an individual has an effect on the supply of specific scarce-skilled individuals to the workforce. This study demonstrates that through the employment of nested case studies, similar research focussing on other scarce skills within the biodiversity sector, as per the GreenMatter Priority Skills List of 2012, can be produced, which would help to address the knowledge gaps pertaining to scarce skills, as indicated by the Biodiversity Human Capital Development Strategy (2010).
- Full Text:
- Date Issued: 2015
- Authors: Mckrill, Leanne Joy
- Date: 2015
- Subjects: Rhodes University , GreenMatter (South Africa) , CATHSSETA (South Africa) , Labor demand -- South Africa , Biodiversity conservation -- Employees -- Supply and demand -- South Africa , Wildlife veterinarians -- Supply and demand -- South Africa , Freshwater ecology -- Employees -- Supply and demand -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2067 , http://hdl.handle.net/10962/d1020837
- Description: This study is situated within the context of the emerging South African Biodiversity Sector and focuses on the supply of and demand for scarce skilled biodiversity professionals. It does so through investigating the transition a young biodiversity professional makes from a higher education institution to the workplace by drawing attention to the factors encountered or perceived to be encountered during this development. The study forms part of a research programme established between Rhodes University, GreenMatter and the Culture Arts Tourism Hospitality Sport Education and Training Authority (CATHSSETA), which seeks to contribute to the body of knowledge pertaining to "green" skills development and retention within the South African biodiversity sector. It is a qualitative study, comprising nested case studies within two larger case studies of scarce skills – those of wildlife veterinarians and freshwater ecologists – as identified by the biodiversity priority scarce skills list (SANBI & Lewis Foundation, 2012). The study is supported by Bronfenbrenner's (1979) Ecological Systems theory and underpinned by the principles of basic critical realism and emergence (Archer, Bhaskar, Collier, Lawson, & Norrie, 1998). Data was generated through a range of data collection methods, including semi-structured interviews, participant observation and document analysis. The aim of these methods was to enable a greater understanding of the factors influencing transitioning and the unique transitions of selected individuals. Findings revealed that the transitions of the participants, although unique to each of them, included the following commonalities: exposure to biodiversity at an early stage in an individual's life paved the way for the development and nurturing of an interest or passion in biodiversity; experience gained prior to entry into the workplace is a powerful enabling factor; the presence or absence of a mentor can be pivotal in the transition of an individual; the gap in knowledge pertaining to demand side or workplace information is a large constraining factor; workplace dynamics affect the demand for, and eventual supply of, biodiversity professionals; the presence of human capital development strategies and structures is beneficial to the individual's transition, and the overall ecosystemic development of an individual has an effect on the supply of specific scarce-skilled individuals to the workforce. This study demonstrates that through the employment of nested case studies, similar research focussing on other scarce skills within the biodiversity sector, as per the GreenMatter Priority Skills List of 2012, can be produced, which would help to address the knowledge gaps pertaining to scarce skills, as indicated by the Biodiversity Human Capital Development Strategy (2010).
- Full Text:
- Date Issued: 2015
An investigation of ISO/IEC 27001 adoption in South Africa
- Authors: Coetzer, Christo
- Date: 2015
- Subjects: ISO 27001 Standard , Information technology -- Security measures , Computer security , Data protection
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4720 , http://hdl.handle.net/10962/d1018669
- Description: The research objective of this study is to investigate the low adoption of the ISO/IEC 27001 standard in South African organisations. This study does not differentiate between the ISO/IEC 27001:2005 and ISO/IEC 27001:2013 versions, as the focus is on adoption of the ISO/IEC 27001 standard. A survey-based research design was selected as the data collection method. The research instruments used in this study include a web-based questionnaire and in-person interviews with the participants. Based on the findings of this research, the organisations that participated in this study have an understanding of the ISO/IEC 27001 standard; however, fewer than a quarter of these have fully adopted the ISO/IEC 27001 standard. Furthermore, the main business objectives for organisations that have adopted the ISO/IEC 27001 standard were to ensure legal and regulatory compliance, and to fulfil client requirements. An Information Security Management System management guide based on the ISO/IEC 27001 Plan-Do-Check-Act model is developed to help organisations interested in the standard move towards ISO/IEC 27001 compliance.
- Full Text:
- Date Issued: 2015
- Authors: Coetzer, Christo
- Date: 2015
- Subjects: ISO 27001 Standard , Information technology -- Security measures , Computer security , Data protection
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4720 , http://hdl.handle.net/10962/d1018669
- Description: The research objective of this study is to investigate the low adoption of the ISO/IEC 27001 standard in South African organisations. This study does not differentiate between the ISO/IEC 27001:2005 and ISO/IEC 27001:2013 versions, as the focus is on adoption of the ISO/IEC 27001 standard. A survey-based research design was selected as the data collection method. The research instruments used in this study include a web-based questionnaire and in-person interviews with the participants. Based on the findings of this research, the organisations that participated in this study have an understanding of the ISO/IEC 27001 standard; however, fewer than a quarter of these have fully adopted the ISO/IEC 27001 standard. Furthermore, the main business objectives for organisations that have adopted the ISO/IEC 27001 standard were to ensure legal and regulatory compliance, and to fulfil client requirements. An Information Security Management System management guide based on the ISO/IEC 27001 Plan-Do-Check-Act model is developed to help organisations interested in the standard move towards ISO/IEC 27001 compliance.
- Full Text:
- Date Issued: 2015
An investigation of record-keeping as a catalyst in ensuring accountability and transparency : a case study of the Provincial Department of Basic Education in the Eastern Cape
- Authors: Ntontela, Majama
- Date: 2015
- Subjects: Public records -- Management Government information -- South Africa -- Management Transparency in government -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/4415 , vital:28336
- Description: Not all documents are records. One of the central concerns of contemporary governance is the reduced or complete lack of accountability among public officials when rendering public services. In the absence of accountability and records, corruption thrives. This research examines the relationship that exists between transparency, accountability and record keeping in order to find the effect that records has; in terms of producing positive audit outcomes and in eliminating corrupt activities by public official/s. Since the transition to democracy in South Africa, the new constitution demands transparency and accountability on matters of governance supported with available information (records). Various pieces of legislation in South Africa are available in support of timely, accessible and accurate information in pursuit of official duties. The difficulty in ensuring an effective record keeping creates an opportunity for governance, transparency and accountability to fail. The essence of this research undertaking was motivated by the fact that, absence of records (which has a negative effect in achieving clean audits) renders governance chaotic and infringes on the democratic principles enshrined in the Constitution such as accountability and transparency. The purpose of the study was to investigate the practice of record keeping in the Eastern Cape Provincial Department of Basic Education (ECDoE) in ensuring accountability and transparency. This research undertaking was guided by the following three research questions: (1) what is the legal/normative framework that governs record keeping in South African public service? (2) How does ECDoE practice record-keeping in ensuring accountability and transparency? And (3) how does the practice of ECDoE’s record-keeping compare with the requirements of the legal/normative framework? After all the gathering of information from different sources, it is therefore recommended that the ECDoE send its employees for records management courses and there must be strict adherence to legislation and recommendations made by the Auditor General in his last audit report for the department. During the conduct of this research undertaking, these are the findings that emerged from the study: at the ECDoE (1) There is no adequate training provided to employees in record keeping. (2) There are ineffective internal control systems. (3) There is no risk management contingency plan. (4) There is no proper record keeping. (5) There is non-compliance with legislation by officials. (6) There is no strong or effective leadership. (7) There is shortage of staff and qualified personnel. (8) Lack of commitment to excel. (9) No significant corrective action undertaken to eliminate past inaccuracies. (10) There is absence of following up on recommendations made by the external audit. Lastly, the researcher accepts the arguments raised by the different authors about record keeping, transparency and accountability in that: there can be no accountable and transparent government without an effective record-keeping in place. Records are vital sources of evidence admissible to any institution be it a court of law or standing committees should clarity be required.
- Full Text:
- Date Issued: 2015
- Authors: Ntontela, Majama
- Date: 2015
- Subjects: Public records -- Management Government information -- South Africa -- Management Transparency in government -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/4415 , vital:28336
- Description: Not all documents are records. One of the central concerns of contemporary governance is the reduced or complete lack of accountability among public officials when rendering public services. In the absence of accountability and records, corruption thrives. This research examines the relationship that exists between transparency, accountability and record keeping in order to find the effect that records has; in terms of producing positive audit outcomes and in eliminating corrupt activities by public official/s. Since the transition to democracy in South Africa, the new constitution demands transparency and accountability on matters of governance supported with available information (records). Various pieces of legislation in South Africa are available in support of timely, accessible and accurate information in pursuit of official duties. The difficulty in ensuring an effective record keeping creates an opportunity for governance, transparency and accountability to fail. The essence of this research undertaking was motivated by the fact that, absence of records (which has a negative effect in achieving clean audits) renders governance chaotic and infringes on the democratic principles enshrined in the Constitution such as accountability and transparency. The purpose of the study was to investigate the practice of record keeping in the Eastern Cape Provincial Department of Basic Education (ECDoE) in ensuring accountability and transparency. This research undertaking was guided by the following three research questions: (1) what is the legal/normative framework that governs record keeping in South African public service? (2) How does ECDoE practice record-keeping in ensuring accountability and transparency? And (3) how does the practice of ECDoE’s record-keeping compare with the requirements of the legal/normative framework? After all the gathering of information from different sources, it is therefore recommended that the ECDoE send its employees for records management courses and there must be strict adherence to legislation and recommendations made by the Auditor General in his last audit report for the department. During the conduct of this research undertaking, these are the findings that emerged from the study: at the ECDoE (1) There is no adequate training provided to employees in record keeping. (2) There are ineffective internal control systems. (3) There is no risk management contingency plan. (4) There is no proper record keeping. (5) There is non-compliance with legislation by officials. (6) There is no strong or effective leadership. (7) There is shortage of staff and qualified personnel. (8) Lack of commitment to excel. (9) No significant corrective action undertaken to eliminate past inaccuracies. (10) There is absence of following up on recommendations made by the external audit. Lastly, the researcher accepts the arguments raised by the different authors about record keeping, transparency and accountability in that: there can be no accountable and transparent government without an effective record-keeping in place. Records are vital sources of evidence admissible to any institution be it a court of law or standing committees should clarity be required.
- Full Text:
- Date Issued: 2015
An investigation of skills and knowledge of women participating in water and food security projects in the Eastern Cape Province: a case of Mbekweni village, Sirhosheni and Lutengele villages
- Authors: Makeleni, Maliviwe
- Date: 2015
- Subjects: Agricultural development projects -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: vital:11235 , http://hdl.handle.net/10353/d1021306 , Agricultural development projects -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape
- Description: The South African government initiated programmes to ensure that women in agriculture are empowered with sufficient agricultural skills and knowledge to engage in agriculture in order to alleviate poverty for their families and communities. Studies argue that within the agricultural sector, women are not capacitated adequately enough in terms of the skills and knowledge they need to acquire, and particularly as this relates to their ability to have knowledge about more advanced technologies in farming. This includes the most up to date knowledge related to sustainable-development. This study has attempted to investigate skills and knowledge possessed by women participating in water and food security projects in the Eastern Cape. Selected study areas were Mbekweni village located in Whittlesea, Sirhosheni village which is situated in Willowvale and Lutengele village in Port St Johns. The thesis was also aiming to find the skills/knowledge gap amongst the sample so as to come up with recommendations. The data was collected using two semi-structured questionnaires. The first questionnaire was for the main survey which mainly concentrated on the socio-economic information of the respondents. This data were collected from 163 households across three sites using systematic sampling. The second questionnaire was mainly used to gain more in-depth analysis. The data were collected from 30 households across three sites using purposive sampling. Both questionnaires were administered through face-to-face interviews. The majority of respondents have stated that they have basic knowledge and skills in farming, however they need further training on appropriate planting methods for various crops, irrigation scheduling and frequency, application of pesticides and marketing skills. Econometric analysis, through the use of the binomial regression model revealed that education affects the level of knowledge of farmers in selecting appropriate planting methods as well as farmers’ knowledge in determining seed depth of a crop. Gender influences the level of knowledge farmers have when selecting appropriate planting methods. Having extension assistance was recognised to affect farmers’ knowledge in determining irrigation scheduling and intensity. All variables were statistically significant showing a 5% level. The thesis ultimately argues that encouraging support to agricultural extension that respects local-level indigenous farming will increase the food-security potential of residents within the Eastern Cape.
- Full Text:
- Date Issued: 2015
- Authors: Makeleni, Maliviwe
- Date: 2015
- Subjects: Agricultural development projects -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: vital:11235 , http://hdl.handle.net/10353/d1021306 , Agricultural development projects -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape
- Description: The South African government initiated programmes to ensure that women in agriculture are empowered with sufficient agricultural skills and knowledge to engage in agriculture in order to alleviate poverty for their families and communities. Studies argue that within the agricultural sector, women are not capacitated adequately enough in terms of the skills and knowledge they need to acquire, and particularly as this relates to their ability to have knowledge about more advanced technologies in farming. This includes the most up to date knowledge related to sustainable-development. This study has attempted to investigate skills and knowledge possessed by women participating in water and food security projects in the Eastern Cape. Selected study areas were Mbekweni village located in Whittlesea, Sirhosheni village which is situated in Willowvale and Lutengele village in Port St Johns. The thesis was also aiming to find the skills/knowledge gap amongst the sample so as to come up with recommendations. The data was collected using two semi-structured questionnaires. The first questionnaire was for the main survey which mainly concentrated on the socio-economic information of the respondents. This data were collected from 163 households across three sites using systematic sampling. The second questionnaire was mainly used to gain more in-depth analysis. The data were collected from 30 households across three sites using purposive sampling. Both questionnaires were administered through face-to-face interviews. The majority of respondents have stated that they have basic knowledge and skills in farming, however they need further training on appropriate planting methods for various crops, irrigation scheduling and frequency, application of pesticides and marketing skills. Econometric analysis, through the use of the binomial regression model revealed that education affects the level of knowledge of farmers in selecting appropriate planting methods as well as farmers’ knowledge in determining seed depth of a crop. Gender influences the level of knowledge farmers have when selecting appropriate planting methods. Having extension assistance was recognised to affect farmers’ knowledge in determining irrigation scheduling and intensity. All variables were statistically significant showing a 5% level. The thesis ultimately argues that encouraging support to agricultural extension that respects local-level indigenous farming will increase the food-security potential of residents within the Eastern Cape.
- Full Text:
- Date Issued: 2015
An investigation of socio-ecological issues and risks and capabilities in the 'my future is my choice' HIV and AIDS programme : a case in northern Namibia
- Authors: Tjiveze, Wakaa
- Date: 2015
- Subjects: My Future is My Choice (Program : Namibia) , HIV infections -- Social aspects -- Namibia , AIDS (Disease) -- Social aspects -- Namibia , AIDS (Disease) -- Study and teaching -- Namibia , AIDS (Disease) -- Risk factors -- Namibia , AIDS (Disease) -- Moral and ethical aspects -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2050 , http://hdl.handle.net/10962/d1017769
- Description: The HIV and AIDS crisis can be presented as a socio-ecological issue, with an ever-increasing impact on both human beings and the environment. Teaching about socio-ecological issues and the consideration of individual capabilities has become crucial within HIV and AIDS education programmes. Issues of deforestation, land degradation and other environmental problems have worsened since the advent of HIV and AIDS, especially in developing countries. The My Future is My Choice (MFMC) programme has been identified as an important HIV and AIDS education initiative that caters for young people in Namibian secondary schools (Grades 8-12). One of the themes within the programme (Facing HIV and AIDS) is highlighted in this study. This study was constituted as a case study of one school in rural Omuthiya, in the Oshikoto region. The study investigated the opportunities for the integration of a focus on socio-ecological issues and risks, within the MFMC education programme. The study also investigated the way in which the program develops learners‟ capabilities to respond to HIV and AIDS related socio-ecological issues and risks/vulnerabilities. The study also presents the constraints and enabling factors influencing the implementation of the programme. This study used a qualitative, interpretive case study methodology. The research methods included the analysis of eight documents and nineteen semi-structured interviews, with the Programme Coordinator, the Programme Facilitator, the School Principal and with the programme participants. The analysis also included two focus group discussions with a group of learners; and two classroom observations; and the learners' submissions (reflection sheets). Convenience sampling was used, and ethical issues were taken into consideration throughout the study. The study revealed the following as key findings: The aims and objectives of the HIV and AIDS education programme can enhance and constrain the development of capabilities, as well as opportunities and challenges for the integration of a focus on socio-environmental issues and risks as additional learning content. Teaching and learning methods that are participatory and rooted within the learner centered approach can make the integration of HIV and AIDS inherent socio-environmental issues and risks into the MFMC education programme possible. The values and beliefs inherent within the MFMC education programme stand as opportunities for the successful development of capabilities in the education programme. The study concluded by recommending that capabilities within the MFMC programme be developed through teaching learners about their rights, respect for human dignity, and the right to health and to living the life free from discriminatory practices, as a moral entitlement of each and every individual. While teaching learners about their right to health and the importance of healthy diets, this study found that the programme could include learning about food production and handling practices for the benefit of those living with HIV and AIDS, while caring for the environment. Another recommendation was that future research should consider actively involving young people in decision-making with regard to the programme, as this will allow them to choose and decide on what knowledge and skills they need and want to acquire. The study further explained that this will promote the programme participants‟ sense of agency, and their freedom to choose what they value being and doing as an important element in enhancing learner capabilities. Ultimately, this will also enable the learners to acquire the necessary skills and knowledge they need in order to respond to the socio-ecological problems they face in their communities.
- Full Text:
- Date Issued: 2015
- Authors: Tjiveze, Wakaa
- Date: 2015
- Subjects: My Future is My Choice (Program : Namibia) , HIV infections -- Social aspects -- Namibia , AIDS (Disease) -- Social aspects -- Namibia , AIDS (Disease) -- Study and teaching -- Namibia , AIDS (Disease) -- Risk factors -- Namibia , AIDS (Disease) -- Moral and ethical aspects -- Namibia
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:2050 , http://hdl.handle.net/10962/d1017769
- Description: The HIV and AIDS crisis can be presented as a socio-ecological issue, with an ever-increasing impact on both human beings and the environment. Teaching about socio-ecological issues and the consideration of individual capabilities has become crucial within HIV and AIDS education programmes. Issues of deforestation, land degradation and other environmental problems have worsened since the advent of HIV and AIDS, especially in developing countries. The My Future is My Choice (MFMC) programme has been identified as an important HIV and AIDS education initiative that caters for young people in Namibian secondary schools (Grades 8-12). One of the themes within the programme (Facing HIV and AIDS) is highlighted in this study. This study was constituted as a case study of one school in rural Omuthiya, in the Oshikoto region. The study investigated the opportunities for the integration of a focus on socio-ecological issues and risks, within the MFMC education programme. The study also investigated the way in which the program develops learners‟ capabilities to respond to HIV and AIDS related socio-ecological issues and risks/vulnerabilities. The study also presents the constraints and enabling factors influencing the implementation of the programme. This study used a qualitative, interpretive case study methodology. The research methods included the analysis of eight documents and nineteen semi-structured interviews, with the Programme Coordinator, the Programme Facilitator, the School Principal and with the programme participants. The analysis also included two focus group discussions with a group of learners; and two classroom observations; and the learners' submissions (reflection sheets). Convenience sampling was used, and ethical issues were taken into consideration throughout the study. The study revealed the following as key findings: The aims and objectives of the HIV and AIDS education programme can enhance and constrain the development of capabilities, as well as opportunities and challenges for the integration of a focus on socio-environmental issues and risks as additional learning content. Teaching and learning methods that are participatory and rooted within the learner centered approach can make the integration of HIV and AIDS inherent socio-environmental issues and risks into the MFMC education programme possible. The values and beliefs inherent within the MFMC education programme stand as opportunities for the successful development of capabilities in the education programme. The study concluded by recommending that capabilities within the MFMC programme be developed through teaching learners about their rights, respect for human dignity, and the right to health and to living the life free from discriminatory practices, as a moral entitlement of each and every individual. While teaching learners about their right to health and the importance of healthy diets, this study found that the programme could include learning about food production and handling practices for the benefit of those living with HIV and AIDS, while caring for the environment. Another recommendation was that future research should consider actively involving young people in decision-making with regard to the programme, as this will allow them to choose and decide on what knowledge and skills they need and want to acquire. The study further explained that this will promote the programme participants‟ sense of agency, and their freedom to choose what they value being and doing as an important element in enhancing learner capabilities. Ultimately, this will also enable the learners to acquire the necessary skills and knowledge they need in order to respond to the socio-ecological problems they face in their communities.
- Full Text:
- Date Issued: 2015
An investigation of source rocks and depositional environments on acid mine drainage in South African coal mines: a comparison of the main Karoo basin and sub-basins.
- Authors: Ncube, Lindani
- Date: 2015
- Subjects: Mine drainage -- Environmental aspects -- South Africa , Coal mines and mining -- Environmental aspects -- South Africa , Acid mine drainage -- Environmental aspects -- South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/19556 , vital:43139
- Description: The coal deposits have been and continue to be the primary source of energy in South Africa. The continuous use of coal presents many challenges that includes genesis of acid mine drainage (AMD) which is as a result of the oxidation of predominant pyrite (FeS2) and other sulphides. The aim of this study was to investigate the role of source rocks and their depositional environments on AMD generation in South African coal mine environments. Five collieries from five coalfields were selected as case studies: Brandspruit in the Highveld, Vaalkrantz in the Vryheid, the Elitheni in the Molteno-Indwe, the Arnot in the Witbank and the Malatleng Exploration Project in the Waterberg Coalfields. Brandspruit, Vaalkrantz and Elitheni Collieries are located in the Main Karoo Basin, while the Witbank and the Waterberg Coalfields are located in Sub-Basins. The study investigated a variety of indices such as palaeo-depositional environments, mineral assemblages, geochemical signatures, water quality parameters, acid base accounting (ABA) and water leach tests for the coal and associated non-coal strata. An effort was made to establish the relationship between the mineralogy of the studied lithologies and the associated water quality. The study resulted in delineation of detrital and diagenetic rock components and interpretation of source area of rock types and the origin and timing of diagenetic alterations. Sandstone units are prevalent, except in the Waterberg Coalfield where mudstones are prevalent. Classifications of the mineralogical composition with descriptive adjectives yield the rock names arkose to sub-arkose categories in the Main Karoo Basin, and sub-arenites to quartz arenites in the Sub-Basins with the sandstones of recycled origin. Further, the sandstones of the Main Karoo Basin are of mixed provenance whilst those of Sub-Basins represent cratonic interior provenance. Sandstone from the Main Karoo Basin generally exhibit high concentrations of feldspars, which favour either high relief, arid or arctic climates with less chemical weathering at the source area. The presence of glauconite in sediments of the Main Karoo Basin attests to a marine continental shelf depositional environment. Sediments of the Main Karoo Basin have high contents of tadpole-shaped pyrite in coal and non-coal strata as compared to sediments of the Sub-Basins. The observed pyrite is ascribed to early diagenetic origin, and is closely related to the generation of acid mining drainage. The sediments have experienced an involved sequence of diagenetic alterations. The alterations considered to be typical for sandstones in the Main Karoo Basin are calcite cementation, feldspar dissolution, kaolinite infilling, pyrite grain coatings, albitization and pressure solution; whereas, quartz overgrowth and clay matrix filling are characteristics of sediments of Sub-Basins. The sequence and distribution of these alterations are related to the source mineral composition, depositional environment, stratigraphic relationships and burial history of the sediments. A direct link exists among the depositional environments, the mineral assemblages and the geochemical compositions of the lithologies. SiO2 is the dominant major oxide and is abundant in coals from coalfields located in the Sub-Basins. Si, Al, Fe, Ca, S, Mg, K and Na show strong association with their discrete minerals. The sandstones are substantially enriched in elements that are chemically immobile and associated with terrigenous influx, such as SiO2, Al2O3, and TiO2. The observed high contents of SiO2 are probably due to source rocks and silicification. SiO2, Al2O3 and TiO2 are related to clay and heavy minerals, with elevated Fe2O3 (Total) content in sediments of the Main Karoo Basin ascribed to sulphidization. Sediments from the Main Karoo Basin are enriched in both Na2O and K2O due to albitization and muscovitization. Substantial concentrations of Ba, Rb and Zr are in accordance to the high amount of phyllosilicates and heavy minerals. Muscovitization contributes to the correlation of Rb and Ba with K2O. The shales are substantially depleted in SiO2, CaO, MgO, Na2O, K2O, TiO2 and Fe2O3 due to weathering and diagenetic alteration, but are enriched in Al2O3 and P2O5. The ABA test clearly indicates that sandstones from the Main Karoo Basin have a potential of generating AMD as they contain sufficient pyrite to generate acid, with the final pH values of the samples turning acidic upon complete oxidation of pyrite. On the contrary, sediments of SubBasins contain sufficient calcite that serves to limit the amount of acid generation. Both sandstone and coal from collieries representing the Main Karoo Basin are characterised by elevated contents of S percent in comparison to coal from collieries representing the Sub-Basins. In general, the quality of water is as a result of a combination of complex geochemical interactions that involves various ions from different sources. Water leaching test shows that the leachates have varied chemical compositions with pH values in the range of 4.5-9 for the sandstone, and 2– 8.9 for the coal leachates. Variations in the pH values are attributed to regional phenomena controlled by the mineralogical and hydrological environments. Furthermore, the variation in pH is ascribed to the presence of acid forming pyrite and acid neutralizing carbonate minerals that are highly reactive in the mining environment. Elements Na, Ca, Mg and K occur in non-compliant concentrations in both coal and non-coal leachates indicating their abundance in all of the lithologies. Na enrichment in the lithologies is associated with albite, clay minerals and Al-Ksulphate coatings. Elements Fe, Al, Cd and Pb are easily leached from the lithologies. According to the equilibrium model, gibbsite, cuprite, diaspore and boehmite are the supersaturated minerals in the lithologies. Influencing factors such as the mineralogical composition of rocks are reflected in the wide variation of pH, TDS, EC and the ion concentrations of the studied water samples. The pH of the studied areas is neutral to alkaline. High levels of TDS and EC are observed in the Brandspruit Colliery, which is due to dissolution of soluble salts from the rock sequence that the water passes through. The anion chemistry shows the dominance of SO4 2- in the surface and groundwater of Brandspruit, Vaalkrantz and Elitheni Collieries, whereas HCO3 - dominates in the Arnot Colliery. SO4 2- is ascribed to the oxidative weathering of pyrites. Cldominates in groundwater from the Arnot Colliery and the Waterberg Coalfield. The cation chemistry is dominated by Na+ in the surface and groundwater of the Brandspruit, Vaalkrantz and Elitheni Collieries. Mg2+ dominates in groundwater from the Arnot Colliery, while K+ dominates in the Waterberg Coalfield. Fe is highly enriched in water from the Brandspruit Colliery, and is linked to the oxidation of pyrite. Carbonates are the supersaturated minerals in the Sub-Basins whilst sulphates are supersaturated in the Main Karoo Basin. The research shows that variations in regional mineral distribution is a result of a palaeo-deposition environment that was of marine nature for the coal sequence in the Main Karoo Basin and of fresh water for the coal sequence in Sub-Basins. A direct link therefore exists between depositional environments, mineral assemblages and whole rock geochemistry. It can be concluded that AMD is directly linked to pyrite and other sulphides, the coal mines located in the Main Karoo Basin have the possibility to deteriorate surface- and ground-water quality and to generate AMD during the mining processes; coal miners need to seriously consider applying environmental protection measures when mining coal in the Main Karoo Basin. Whereas, coal mining in the Sub-Basins has low possibility of generating AMD and pollution. , Thesis (PhD) (Geology) -- University of Fort Hare, 2015
- Full Text:
- Date Issued: 2015
- Authors: Ncube, Lindani
- Date: 2015
- Subjects: Mine drainage -- Environmental aspects -- South Africa , Coal mines and mining -- Environmental aspects -- South Africa , Acid mine drainage -- Environmental aspects -- South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/19556 , vital:43139
- Description: The coal deposits have been and continue to be the primary source of energy in South Africa. The continuous use of coal presents many challenges that includes genesis of acid mine drainage (AMD) which is as a result of the oxidation of predominant pyrite (FeS2) and other sulphides. The aim of this study was to investigate the role of source rocks and their depositional environments on AMD generation in South African coal mine environments. Five collieries from five coalfields were selected as case studies: Brandspruit in the Highveld, Vaalkrantz in the Vryheid, the Elitheni in the Molteno-Indwe, the Arnot in the Witbank and the Malatleng Exploration Project in the Waterberg Coalfields. Brandspruit, Vaalkrantz and Elitheni Collieries are located in the Main Karoo Basin, while the Witbank and the Waterberg Coalfields are located in Sub-Basins. The study investigated a variety of indices such as palaeo-depositional environments, mineral assemblages, geochemical signatures, water quality parameters, acid base accounting (ABA) and water leach tests for the coal and associated non-coal strata. An effort was made to establish the relationship between the mineralogy of the studied lithologies and the associated water quality. The study resulted in delineation of detrital and diagenetic rock components and interpretation of source area of rock types and the origin and timing of diagenetic alterations. Sandstone units are prevalent, except in the Waterberg Coalfield where mudstones are prevalent. Classifications of the mineralogical composition with descriptive adjectives yield the rock names arkose to sub-arkose categories in the Main Karoo Basin, and sub-arenites to quartz arenites in the Sub-Basins with the sandstones of recycled origin. Further, the sandstones of the Main Karoo Basin are of mixed provenance whilst those of Sub-Basins represent cratonic interior provenance. Sandstone from the Main Karoo Basin generally exhibit high concentrations of feldspars, which favour either high relief, arid or arctic climates with less chemical weathering at the source area. The presence of glauconite in sediments of the Main Karoo Basin attests to a marine continental shelf depositional environment. Sediments of the Main Karoo Basin have high contents of tadpole-shaped pyrite in coal and non-coal strata as compared to sediments of the Sub-Basins. The observed pyrite is ascribed to early diagenetic origin, and is closely related to the generation of acid mining drainage. The sediments have experienced an involved sequence of diagenetic alterations. The alterations considered to be typical for sandstones in the Main Karoo Basin are calcite cementation, feldspar dissolution, kaolinite infilling, pyrite grain coatings, albitization and pressure solution; whereas, quartz overgrowth and clay matrix filling are characteristics of sediments of Sub-Basins. The sequence and distribution of these alterations are related to the source mineral composition, depositional environment, stratigraphic relationships and burial history of the sediments. A direct link exists among the depositional environments, the mineral assemblages and the geochemical compositions of the lithologies. SiO2 is the dominant major oxide and is abundant in coals from coalfields located in the Sub-Basins. Si, Al, Fe, Ca, S, Mg, K and Na show strong association with their discrete minerals. The sandstones are substantially enriched in elements that are chemically immobile and associated with terrigenous influx, such as SiO2, Al2O3, and TiO2. The observed high contents of SiO2 are probably due to source rocks and silicification. SiO2, Al2O3 and TiO2 are related to clay and heavy minerals, with elevated Fe2O3 (Total) content in sediments of the Main Karoo Basin ascribed to sulphidization. Sediments from the Main Karoo Basin are enriched in both Na2O and K2O due to albitization and muscovitization. Substantial concentrations of Ba, Rb and Zr are in accordance to the high amount of phyllosilicates and heavy minerals. Muscovitization contributes to the correlation of Rb and Ba with K2O. The shales are substantially depleted in SiO2, CaO, MgO, Na2O, K2O, TiO2 and Fe2O3 due to weathering and diagenetic alteration, but are enriched in Al2O3 and P2O5. The ABA test clearly indicates that sandstones from the Main Karoo Basin have a potential of generating AMD as they contain sufficient pyrite to generate acid, with the final pH values of the samples turning acidic upon complete oxidation of pyrite. On the contrary, sediments of SubBasins contain sufficient calcite that serves to limit the amount of acid generation. Both sandstone and coal from collieries representing the Main Karoo Basin are characterised by elevated contents of S percent in comparison to coal from collieries representing the Sub-Basins. In general, the quality of water is as a result of a combination of complex geochemical interactions that involves various ions from different sources. Water leaching test shows that the leachates have varied chemical compositions with pH values in the range of 4.5-9 for the sandstone, and 2– 8.9 for the coal leachates. Variations in the pH values are attributed to regional phenomena controlled by the mineralogical and hydrological environments. Furthermore, the variation in pH is ascribed to the presence of acid forming pyrite and acid neutralizing carbonate minerals that are highly reactive in the mining environment. Elements Na, Ca, Mg and K occur in non-compliant concentrations in both coal and non-coal leachates indicating their abundance in all of the lithologies. Na enrichment in the lithologies is associated with albite, clay minerals and Al-Ksulphate coatings. Elements Fe, Al, Cd and Pb are easily leached from the lithologies. According to the equilibrium model, gibbsite, cuprite, diaspore and boehmite are the supersaturated minerals in the lithologies. Influencing factors such as the mineralogical composition of rocks are reflected in the wide variation of pH, TDS, EC and the ion concentrations of the studied water samples. The pH of the studied areas is neutral to alkaline. High levels of TDS and EC are observed in the Brandspruit Colliery, which is due to dissolution of soluble salts from the rock sequence that the water passes through. The anion chemistry shows the dominance of SO4 2- in the surface and groundwater of Brandspruit, Vaalkrantz and Elitheni Collieries, whereas HCO3 - dominates in the Arnot Colliery. SO4 2- is ascribed to the oxidative weathering of pyrites. Cldominates in groundwater from the Arnot Colliery and the Waterberg Coalfield. The cation chemistry is dominated by Na+ in the surface and groundwater of the Brandspruit, Vaalkrantz and Elitheni Collieries. Mg2+ dominates in groundwater from the Arnot Colliery, while K+ dominates in the Waterberg Coalfield. Fe is highly enriched in water from the Brandspruit Colliery, and is linked to the oxidation of pyrite. Carbonates are the supersaturated minerals in the Sub-Basins whilst sulphates are supersaturated in the Main Karoo Basin. The research shows that variations in regional mineral distribution is a result of a palaeo-deposition environment that was of marine nature for the coal sequence in the Main Karoo Basin and of fresh water for the coal sequence in Sub-Basins. A direct link therefore exists between depositional environments, mineral assemblages and whole rock geochemistry. It can be concluded that AMD is directly linked to pyrite and other sulphides, the coal mines located in the Main Karoo Basin have the possibility to deteriorate surface- and ground-water quality and to generate AMD during the mining processes; coal miners need to seriously consider applying environmental protection measures when mining coal in the Main Karoo Basin. Whereas, coal mining in the Sub-Basins has low possibility of generating AMD and pollution. , Thesis (PhD) (Geology) -- University of Fort Hare, 2015
- Full Text:
- Date Issued: 2015
An investigation of the consumer protection Act (2008) and plain language application at selected businesses in the Port Elizabeth metropole
- Authors: Van Jaarsveld, Roslynn
- Date: 2015
- Subjects: South Africa. Consumer Protection Act, 2008 , Consumer protection -- Law and legislation -- South Africa , Administrative law -- South Africa -- Language , Administrative law -- Language
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/4012 , vital:20504
- Description: Businesses communicate a wide variety of messages to diverse audiences using a number of different communication types and channels daily. For example, business communication includes business reports, documents (booklets, leaflets, and official communiqués), notices, agreements, web copy and advertisements that are produced continually to address a variety of business communication needs for a variety of audiences. Although written business communication has a significant impact on customer satisfaction and consumer attitude which, in turn, affects consumer behaviour positively or negatively, there is a lack of research investigating the knowledge and application of plain language in business communication. Many studies were found to be related to communication and language, however, studies about plain language use were less prevalent. Therefore, this study aimed to investigate the awareness of the plain language regulations stipulated in the South African Consumer Protection Act (CPA) 68 of 2008 (2009). The application of these plain language principles within businesses in the Port Elizabeth Metropole, with specific reference to its use in written business communication was also investigated. The study also aimed to identify plain language best practices and constraints resulting from plain language application or non-application within the selected organisations. The research focused attention on the impact of business communication on customer satisfaction, consumer attitude and, ultimately, consumer behaviour as well as the need for plain language use in written business communication practices to ensure effective and fair (ethical) communication. A comprehensive literature review was conducted on communication, communication theory and consumer behaviour, as well as on plain language principles which might add to the effectiveness of organisations’ written business communication, to provide a theoretical foundation for the study. The study’s research methodology was approached from a phenomenological (descriptive and interpretive), and somewhat positivistic perspective, utilising qualitative and limited quantitative measures to obtain data. For this reason, three managers from three respective organisations within the Port Elizabeth Metropole were interviewed and asked to complete a rating-scale survey to obtain insight on the written business communication practices of these organisations. A content analysis of documents supplied by the participating organisations were also reviewed to provide commentary on the plain language application in each organisation. Furthermore, Section 2 of the South African CPA 68 of 2008 (2009) was also reviewed to measure and comment on the application of plain language in these organisations. Based on the data analysis, it was evident that organisations in the Port Elizabeth Metropole were aware of plain language and the plain language regulations stipulated in the South African CPA 68 of 2008 (2009), but that they were not certain what the regulations entailed exactly. Furthermore, plain language principles were applied in the participating organisations, however, complications and areas for possible improvement were identified in the data. From the study’s findings, various recommendations were made that could assist the organisations to improve their organisations’ plain language application. These recommendations included, for example, appointing plain language champions to monitor plain language application in the organisation, as well as assessing language competence of staff and training them to improve their language competencies. Recommendations for future research suggested that future studies needed to include a larger research sample, a more diverse sample population to include consumers and a broader industrial demographic. In addition, future studies could attempt to investigate communication barriers that inhibit or challenge comprehension in consumer communication.
- Full Text:
- Date Issued: 2015
- Authors: Van Jaarsveld, Roslynn
- Date: 2015
- Subjects: South Africa. Consumer Protection Act, 2008 , Consumer protection -- Law and legislation -- South Africa , Administrative law -- South Africa -- Language , Administrative law -- Language
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/4012 , vital:20504
- Description: Businesses communicate a wide variety of messages to diverse audiences using a number of different communication types and channels daily. For example, business communication includes business reports, documents (booklets, leaflets, and official communiqués), notices, agreements, web copy and advertisements that are produced continually to address a variety of business communication needs for a variety of audiences. Although written business communication has a significant impact on customer satisfaction and consumer attitude which, in turn, affects consumer behaviour positively or negatively, there is a lack of research investigating the knowledge and application of plain language in business communication. Many studies were found to be related to communication and language, however, studies about plain language use were less prevalent. Therefore, this study aimed to investigate the awareness of the plain language regulations stipulated in the South African Consumer Protection Act (CPA) 68 of 2008 (2009). The application of these plain language principles within businesses in the Port Elizabeth Metropole, with specific reference to its use in written business communication was also investigated. The study also aimed to identify plain language best practices and constraints resulting from plain language application or non-application within the selected organisations. The research focused attention on the impact of business communication on customer satisfaction, consumer attitude and, ultimately, consumer behaviour as well as the need for plain language use in written business communication practices to ensure effective and fair (ethical) communication. A comprehensive literature review was conducted on communication, communication theory and consumer behaviour, as well as on plain language principles which might add to the effectiveness of organisations’ written business communication, to provide a theoretical foundation for the study. The study’s research methodology was approached from a phenomenological (descriptive and interpretive), and somewhat positivistic perspective, utilising qualitative and limited quantitative measures to obtain data. For this reason, three managers from three respective organisations within the Port Elizabeth Metropole were interviewed and asked to complete a rating-scale survey to obtain insight on the written business communication practices of these organisations. A content analysis of documents supplied by the participating organisations were also reviewed to provide commentary on the plain language application in each organisation. Furthermore, Section 2 of the South African CPA 68 of 2008 (2009) was also reviewed to measure and comment on the application of plain language in these organisations. Based on the data analysis, it was evident that organisations in the Port Elizabeth Metropole were aware of plain language and the plain language regulations stipulated in the South African CPA 68 of 2008 (2009), but that they were not certain what the regulations entailed exactly. Furthermore, plain language principles were applied in the participating organisations, however, complications and areas for possible improvement were identified in the data. From the study’s findings, various recommendations were made that could assist the organisations to improve their organisations’ plain language application. These recommendations included, for example, appointing plain language champions to monitor plain language application in the organisation, as well as assessing language competence of staff and training them to improve their language competencies. Recommendations for future research suggested that future studies needed to include a larger research sample, a more diverse sample population to include consumers and a broader industrial demographic. In addition, future studies could attempt to investigate communication barriers that inhibit or challenge comprehension in consumer communication.
- Full Text:
- Date Issued: 2015
An investigation of the effect of co-solvents on the hydrothermal liquefaction of microalgae biomass
- Authors: Nongauza, Sinethemba Aubrey
- Date: 2015
- Subjects: Biomass chemicals Microalgae -- Biotechnology , Supercritical fluids Solvents
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/21667 , vital:29731
- Description: The study introduces and demonstrates the viability of the continuous flow reactor (CFR) system for the production of bio-crude oil (BCO) from wet microalgae. Preliminary experiments conducted in the CFR system in hot compressed water (HCW) were successful in converting wet microalgae into liquid BCO. However, the synthesis and aggregation of high boiling point (HBP) components of BCO and the accumulation of char in the tubular piping of CFR system were identified as the limiting factor to the viability of the system. The aggregation of HBP components and the accumulation of char result to system blockage which prevents the continuous flow of the liquefaction product mixture in the CFR system. Inhibiting the reactions leading to the formation of HBP components and char will improve the performance of the CFR system. Therefore, the study seeks to incorporate co-solvents in the liquefaction reaction media in an attempt to inhibit or minimize the prevalence of HBP components of BCO. As such, different co-solvents were screened for their influence on improving the quality of BCO with respect to its boiling point profile (BPP), initial and final boiling point, as well as the amount of char recovered from each experiment. Only one co-solvent was chosen for further exploration in the CFR system. Batch liquefaction reactor’s (BLR) made up of stainless steel were used to carry out the co-solvent screening experiments. These experiments were carried out at a constant temperature (280 °C), pressure (75 bar), and co-solvent concentration (10 wt.%), at varying residence times. Solvent extraction with dichloromethane (DCM) was performed on the liquefaction product mixture to separate the products, viz. BCO, char and water soluble components. The extracted BCO was analysed through simulated distillation (SimDis) to obtain the BPP. The BPP properties of the BCO samples, from different liquefaction media, and the amount of char recovered were highly influenced by the addition of a co-solvent. The final boiling point (FBP) of tetralin, heptane, and n-octanol BCO products were significantly reduced to below 500 °C for all tested residence times except at 20 minutes. The residence time also proved to be influential in the processing of wet microalgae. n-Octanol was selected as the optimal performing co-solvent and was used for the continuous liquefaction of wet microalgae in the CFR system. The CFR system was modified by adding a co-solvent feed line into the continuous system since n-octanol was insoluble in water. The n-octanol pump was set at different flow rates, 0.2, 0.3, and 0.4 g/min, which resulted in a concentration of about 10 wt.% in the reactor feed. The concentration of n-octanol had a significant influence on the BPP of BCO components. The FBP’s were reduced with an increase in n-octanol concentration. The initial boiling point (IBP) of n-octanol BCO was increased to just above 100 °C which was required for the stability of the BCO product. The components of BCO were identified by GCMS. n-Octanol also proved to affect the composition of the BCO with respect to its components. HCW BCO components were significantly different from those identified from n-octanol BCO. A second co-solvent (tetralin) was used to prove whether the difference on the components of BCO was affected by n-octanol. The results proved that indeed the addition of different solvents in liquefaction reaction media favours the formation of different components. The amount of char formed was also reduced when using a co-solvent. A decrease in the oxygen/nitrogen compounds was also observed in the presence of a co-solvent, thus improving BCO properties.
- Full Text:
- Date Issued: 2015
An investigation of the effect of co-solvents on the hydrothermal liquefaction of microalgae biomass
- Authors: Nongauza, Sinethemba Aubrey
- Date: 2015
- Subjects: Biomass chemicals Microalgae -- Biotechnology , Supercritical fluids Solvents
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/21667 , vital:29731
- Description: The study introduces and demonstrates the viability of the continuous flow reactor (CFR) system for the production of bio-crude oil (BCO) from wet microalgae. Preliminary experiments conducted in the CFR system in hot compressed water (HCW) were successful in converting wet microalgae into liquid BCO. However, the synthesis and aggregation of high boiling point (HBP) components of BCO and the accumulation of char in the tubular piping of CFR system were identified as the limiting factor to the viability of the system. The aggregation of HBP components and the accumulation of char result to system blockage which prevents the continuous flow of the liquefaction product mixture in the CFR system. Inhibiting the reactions leading to the formation of HBP components and char will improve the performance of the CFR system. Therefore, the study seeks to incorporate co-solvents in the liquefaction reaction media in an attempt to inhibit or minimize the prevalence of HBP components of BCO. As such, different co-solvents were screened for their influence on improving the quality of BCO with respect to its boiling point profile (BPP), initial and final boiling point, as well as the amount of char recovered from each experiment. Only one co-solvent was chosen for further exploration in the CFR system. Batch liquefaction reactor’s (BLR) made up of stainless steel were used to carry out the co-solvent screening experiments. These experiments were carried out at a constant temperature (280 °C), pressure (75 bar), and co-solvent concentration (10 wt.%), at varying residence times. Solvent extraction with dichloromethane (DCM) was performed on the liquefaction product mixture to separate the products, viz. BCO, char and water soluble components. The extracted BCO was analysed through simulated distillation (SimDis) to obtain the BPP. The BPP properties of the BCO samples, from different liquefaction media, and the amount of char recovered were highly influenced by the addition of a co-solvent. The final boiling point (FBP) of tetralin, heptane, and n-octanol BCO products were significantly reduced to below 500 °C for all tested residence times except at 20 minutes. The residence time also proved to be influential in the processing of wet microalgae. n-Octanol was selected as the optimal performing co-solvent and was used for the continuous liquefaction of wet microalgae in the CFR system. The CFR system was modified by adding a co-solvent feed line into the continuous system since n-octanol was insoluble in water. The n-octanol pump was set at different flow rates, 0.2, 0.3, and 0.4 g/min, which resulted in a concentration of about 10 wt.% in the reactor feed. The concentration of n-octanol had a significant influence on the BPP of BCO components. The FBP’s were reduced with an increase in n-octanol concentration. The initial boiling point (IBP) of n-octanol BCO was increased to just above 100 °C which was required for the stability of the BCO product. The components of BCO were identified by GCMS. n-Octanol also proved to affect the composition of the BCO with respect to its components. HCW BCO components were significantly different from those identified from n-octanol BCO. A second co-solvent (tetralin) was used to prove whether the difference on the components of BCO was affected by n-octanol. The results proved that indeed the addition of different solvents in liquefaction reaction media favours the formation of different components. The amount of char formed was also reduced when using a co-solvent. A decrease in the oxygen/nitrogen compounds was also observed in the presence of a co-solvent, thus improving BCO properties.
- Full Text:
- Date Issued: 2015
An investigation of the strategies for sustainability of selected community radio stations in Transkei rural areas of the Eastern Cape
- Authors: Mafani, Hlanga Eric
- Date: 2015
- Subjects: Community radio -- South Africa -- Eastern Cape , Radio stations -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/5963 , vital:21020
- Description: This research project was aimed at investigating strategies that are used for the sustainability of selected rural-based community radio stations in the Transkei area of the Eastern Cape. The study was done under a hypothesis that, in the absence of big business and migration of literate people and skilled labour from rural communities to urban centres, rural-based community radios struggle to attract operational revenue through advertising, community support, etc., and that the supposedly high illiteracy in the rural areas render it difficult to run the stations. Two rural-based community radio stations were selected for this study: Alfred Nzo Community Radio at Mount Ayliff in the Alfred Nzo District Municipality area, and Vukani Community Radio at Cala in the Chris Hani District Municipality area. The aim was to study their activities with regard to the most and widely agreed three-dimensional method of sustaining community radio stations: Financial Sustainability, Institutional Sustainability, and Social Sustainability. Relevant literature has been reviewed and data have been collected using both quantitative and qualitative methods through questionnaires. The study however leans more on the qualitative approach and a quantitative approach has merely been used to identify the trends of the views of the participants. The analysis of data highlights the views of the respondents about these radio stations with regard to their strategies to sustain themselves. The views of the respondents represent all people from all levels of people involved in the stations: From the Member of the Board of Directors in the boardroom to stations’ members of management at their desks. From Presenters behind their microphones to the listener in the dusty streets of the poor rural areas. The results confirm the hypothesis that the areas have high unemployment and illiteracy rates, and that their sustainability depend largely on trade-outs with local business and government support. However, the study also shows that strategies for Financial Sustainability, Institutional Sustainability, and Social Sustainability may overlap or influence each other. For instance, an activity of Institutional Sustainability may result in Financial Sustainability, and visa-versa. The study also reveals that the stations struggle to establish and maintain effective Social Sustainability for the benefit of the station. In the light of this, a proposal for further study and recommendations are given at the end of the study.
- Full Text:
- Date Issued: 2015
- Authors: Mafani, Hlanga Eric
- Date: 2015
- Subjects: Community radio -- South Africa -- Eastern Cape , Radio stations -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/5963 , vital:21020
- Description: This research project was aimed at investigating strategies that are used for the sustainability of selected rural-based community radio stations in the Transkei area of the Eastern Cape. The study was done under a hypothesis that, in the absence of big business and migration of literate people and skilled labour from rural communities to urban centres, rural-based community radios struggle to attract operational revenue through advertising, community support, etc., and that the supposedly high illiteracy in the rural areas render it difficult to run the stations. Two rural-based community radio stations were selected for this study: Alfred Nzo Community Radio at Mount Ayliff in the Alfred Nzo District Municipality area, and Vukani Community Radio at Cala in the Chris Hani District Municipality area. The aim was to study their activities with regard to the most and widely agreed three-dimensional method of sustaining community radio stations: Financial Sustainability, Institutional Sustainability, and Social Sustainability. Relevant literature has been reviewed and data have been collected using both quantitative and qualitative methods through questionnaires. The study however leans more on the qualitative approach and a quantitative approach has merely been used to identify the trends of the views of the participants. The analysis of data highlights the views of the respondents about these radio stations with regard to their strategies to sustain themselves. The views of the respondents represent all people from all levels of people involved in the stations: From the Member of the Board of Directors in the boardroom to stations’ members of management at their desks. From Presenters behind their microphones to the listener in the dusty streets of the poor rural areas. The results confirm the hypothesis that the areas have high unemployment and illiteracy rates, and that their sustainability depend largely on trade-outs with local business and government support. However, the study also shows that strategies for Financial Sustainability, Institutional Sustainability, and Social Sustainability may overlap or influence each other. For instance, an activity of Institutional Sustainability may result in Financial Sustainability, and visa-versa. The study also reveals that the stations struggle to establish and maintain effective Social Sustainability for the benefit of the station. In the light of this, a proposal for further study and recommendations are given at the end of the study.
- Full Text:
- Date Issued: 2015
An organic rankine cycle heat engine using a rock thermal battery as the heat source
- Authors: Humm, Jason Christopher
- Date: 2015
- Subjects: Heat engineering Renewable energy sources
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/10960 , vital:26861
- Description: Organic Rankine cycles (ORC) have unique properties that are well suited to power generation from low grade heat sources. It is envisaged that a domestic scale ORC Heat Engine can be developed that will be able to run off heat stored in a solar charged rock thermal battery. The use of a thermal battery as the heat source for the ORC system will provide the user with electricity during the day and for a number of hours into the night. The concept presented consists of four key components: rock thermal battery, 1 kW scroll expander, condenser and working fluid pump.
- Full Text:
- Date Issued: 2015
- Authors: Humm, Jason Christopher
- Date: 2015
- Subjects: Heat engineering Renewable energy sources
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/10960 , vital:26861
- Description: Organic Rankine cycles (ORC) have unique properties that are well suited to power generation from low grade heat sources. It is envisaged that a domestic scale ORC Heat Engine can be developed that will be able to run off heat stored in a solar charged rock thermal battery. The use of a thermal battery as the heat source for the ORC system will provide the user with electricity during the day and for a number of hours into the night. The concept presented consists of four key components: rock thermal battery, 1 kW scroll expander, condenser and working fluid pump.
- Full Text:
- Date Issued: 2015
An overview of energy minerals in the Springbok Flatsbasin, South Africa : implications for geochemical and geophysical exploration
- Authors: Ledwaba, Lebogang John
- Date: 2015
- Subjects: Energy minerals -- South Africa -- Springbok Flats (Limpopo) , Geochemistry , Prospecting -- Geophysical methods , Coal -- South Africa -- Springbok Flats (Limpopo) , Uranium -- South Africa -- Springbok Flats (Limpopo) , Coalbed methane -- South Africa -- Springbok Flats (Limpopo)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5092 , http://hdl.handle.net/10962/d1019880
- Description: This study is informed by the rising demand for power needs in South Africa and aims at understanding the geophysical and geochemical characteristics of the energy minerals in the Springbok Flats Basin and relating them to the prevailing geological and structural setting for improved exploration targeting. The Springbok Flats Basin is part of the Karoo sediments and host to uranium, coal and coal bed methane (CBM) resources. The lithology sections in the basin indicate presence of basaltic lavas at the top, underlain by mudrocks, siltstones, sandstones, conglomerates and diamictite, with interbedded coal beds occasionally. The coals are uraniferous and shale bounded and of lower Beaufort age at 250 Ma. The regional radiometric data identifies the regional extent of the Springbok Flats Basin as a basin with low total count values. This information is useful in exploration as it gives an idea of the limits of the area where to focus application for prospecting licenses. The reduced to pole of the total magnetic field, residuals and first vertical derivative maps clearly show the high magnetic susceptibility nature of the surrounding Bushveld rocks as compared to the low Karoo sediment susceptibility within the basin. There are distinct ring shaped picks within the basin possibly due to known Karoo dolerite sills in particular to the central south western part of the grid. The regional geochemical mapping program is a cost-effective way of providing an overview of the relative abundance levels, regional trends and anomalous patterns in the underlying lithological units. Background values of elements in soils over different lithological units and the identification of anomalous values relative to these elements can easily be identified. The geochemical results show an excellent correlation between soil chemistry and underlying geological formations. A few distinct gravity highs are clearly shown within the basin. Assuming the effect of the Letaba basalt to the gravity readings is uniform across the basin; these distinct anomalies could be due to Karoo dolerite sills as they coincide with areas of distinct high magnetic signature. A conceptual model was generated assuming that the Karoo sediments’ layering is uniform across the gravity profile but changes in the residual are due to an increased thickness of the sill supported by the gentle changes on the surface topography. Satellite imagery has got its challenges especially in areas of vegetation but it does provide a very useful tool in exploration. A number of spectral analysis techniques and band rations can be used to differentiate the areas underlain by the Letaba basalts, the Karoo sandstones/shale and Bushveld granites for mapping purposes. The priority focus will be on the shallower Karoo sediments because of the potential for cheaper mining. Exploration targeting needs to be guided by observed geochemical and geophysical characteristics in order to prioritize areas taking into account the presence of Karoo intrusives such as the dolerite sills that tend to devolatize the coal hence affecting the quality/rank. Structures and gravity signatures are very important in delineating areas with thick sediments that have a potential for CBM. The same understanding in targeting goes a long way in planning drill holes, resource modelling and pre-feasibility stages for mine planning. A high resolution airborne geophysical survey is recommended over the basin to better resolve structures. Geophysical borehole logging is recommended to be part of the exploration drilling programs in the Springbok Flats Basin in order to define the in-situ geophysical characteristics. Geophysical logging is useful in particular for the uranium reserves that cannot be delineated from the surface due to deep intersection.
- Full Text:
- Date Issued: 2015
- Authors: Ledwaba, Lebogang John
- Date: 2015
- Subjects: Energy minerals -- South Africa -- Springbok Flats (Limpopo) , Geochemistry , Prospecting -- Geophysical methods , Coal -- South Africa -- Springbok Flats (Limpopo) , Uranium -- South Africa -- Springbok Flats (Limpopo) , Coalbed methane -- South Africa -- Springbok Flats (Limpopo)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5092 , http://hdl.handle.net/10962/d1019880
- Description: This study is informed by the rising demand for power needs in South Africa and aims at understanding the geophysical and geochemical characteristics of the energy minerals in the Springbok Flats Basin and relating them to the prevailing geological and structural setting for improved exploration targeting. The Springbok Flats Basin is part of the Karoo sediments and host to uranium, coal and coal bed methane (CBM) resources. The lithology sections in the basin indicate presence of basaltic lavas at the top, underlain by mudrocks, siltstones, sandstones, conglomerates and diamictite, with interbedded coal beds occasionally. The coals are uraniferous and shale bounded and of lower Beaufort age at 250 Ma. The regional radiometric data identifies the regional extent of the Springbok Flats Basin as a basin with low total count values. This information is useful in exploration as it gives an idea of the limits of the area where to focus application for prospecting licenses. The reduced to pole of the total magnetic field, residuals and first vertical derivative maps clearly show the high magnetic susceptibility nature of the surrounding Bushveld rocks as compared to the low Karoo sediment susceptibility within the basin. There are distinct ring shaped picks within the basin possibly due to known Karoo dolerite sills in particular to the central south western part of the grid. The regional geochemical mapping program is a cost-effective way of providing an overview of the relative abundance levels, regional trends and anomalous patterns in the underlying lithological units. Background values of elements in soils over different lithological units and the identification of anomalous values relative to these elements can easily be identified. The geochemical results show an excellent correlation between soil chemistry and underlying geological formations. A few distinct gravity highs are clearly shown within the basin. Assuming the effect of the Letaba basalt to the gravity readings is uniform across the basin; these distinct anomalies could be due to Karoo dolerite sills as they coincide with areas of distinct high magnetic signature. A conceptual model was generated assuming that the Karoo sediments’ layering is uniform across the gravity profile but changes in the residual are due to an increased thickness of the sill supported by the gentle changes on the surface topography. Satellite imagery has got its challenges especially in areas of vegetation but it does provide a very useful tool in exploration. A number of spectral analysis techniques and band rations can be used to differentiate the areas underlain by the Letaba basalts, the Karoo sandstones/shale and Bushveld granites for mapping purposes. The priority focus will be on the shallower Karoo sediments because of the potential for cheaper mining. Exploration targeting needs to be guided by observed geochemical and geophysical characteristics in order to prioritize areas taking into account the presence of Karoo intrusives such as the dolerite sills that tend to devolatize the coal hence affecting the quality/rank. Structures and gravity signatures are very important in delineating areas with thick sediments that have a potential for CBM. The same understanding in targeting goes a long way in planning drill holes, resource modelling and pre-feasibility stages for mine planning. A high resolution airborne geophysical survey is recommended over the basin to better resolve structures. Geophysical borehole logging is recommended to be part of the exploration drilling programs in the Springbok Flats Basin in order to define the in-situ geophysical characteristics. Geophysical logging is useful in particular for the uranium reserves that cannot be delineated from the surface due to deep intersection.
- Full Text:
- Date Issued: 2015
Analysing from experience : Gustav Mahler’s Quartetsatz for piano and strings
- Authors: Du Plessis, Jacques
- Date: 2015
- Subjects: Mahler, Gustav, 1860-1911. -- Quartet, piano, violin, viola, cello, A minor , Musical analysis , Music appreciation , Phenomenology and music
- Language: English
- Type: Thesis , Masters , MMus
- Identifier: vital:2696 , http://hdl.handle.net/10962/d1017818
- Description: Musical analysis has traditionally been located within the context of musicology. It is therefore an activity usually considered the purview of music scholars rather than practical musicians. The musical analyses produced by music scholars therefore provide us with intellectual understandings of musical works, rather than insights into the experience of listening to or playing music. In this thesis, I will propose that those agents involved in practical music-making can produce insights into musical works that are as valid as the work of traditional music scholarship. I will attempt to re-conceptualize the position of the ‘knower’ or ‘experiencer’ - the performer - of music as one with primary access to knowledge of a musical work, and therefore ideally suited to offer analyses of these works. The establishment of the performer as a bearer of central analytical knowledge functions in direct opposition to the traditional distinction between ‘theory’ and ‘practice’. My thesis will trace the Platonic origins of the philosophical separation of practice and research, and as an alternative to the traditional separation of practice and research, I shall explore the concept of Practice-Based Research (PBR). My exploration of PBR will be informed by phenomenological approaches to music scholarship. As a field of enquiry which concerns itself with experience, the phenomenology of music suggests that the mind and body of the practitioner are important sources of musical insight. To address this issue, Bourdieu’s notion of habitus will be explored. The habitus will be shown to contain a vast network of socio-cultural codes informing the practitioner’s relationship with the musical work. A central aim of this thesis is to explore the possibilities of using practice-based research as the foundation for the study and analysis of a composition, in order to allow for a deeper understanding of the work by means of the generation and harnessing of practical knowledge. Thus, the theoretical outline of PBR provided in this thesis will be applied to a piece of practical performance-based analysis. As such, an analysis of Mahler’s Quartetsatz will be used as the basis on which to draw knowledge in this project.
- Full Text:
- Date Issued: 2015
- Authors: Du Plessis, Jacques
- Date: 2015
- Subjects: Mahler, Gustav, 1860-1911. -- Quartet, piano, violin, viola, cello, A minor , Musical analysis , Music appreciation , Phenomenology and music
- Language: English
- Type: Thesis , Masters , MMus
- Identifier: vital:2696 , http://hdl.handle.net/10962/d1017818
- Description: Musical analysis has traditionally been located within the context of musicology. It is therefore an activity usually considered the purview of music scholars rather than practical musicians. The musical analyses produced by music scholars therefore provide us with intellectual understandings of musical works, rather than insights into the experience of listening to or playing music. In this thesis, I will propose that those agents involved in practical music-making can produce insights into musical works that are as valid as the work of traditional music scholarship. I will attempt to re-conceptualize the position of the ‘knower’ or ‘experiencer’ - the performer - of music as one with primary access to knowledge of a musical work, and therefore ideally suited to offer analyses of these works. The establishment of the performer as a bearer of central analytical knowledge functions in direct opposition to the traditional distinction between ‘theory’ and ‘practice’. My thesis will trace the Platonic origins of the philosophical separation of practice and research, and as an alternative to the traditional separation of practice and research, I shall explore the concept of Practice-Based Research (PBR). My exploration of PBR will be informed by phenomenological approaches to music scholarship. As a field of enquiry which concerns itself with experience, the phenomenology of music suggests that the mind and body of the practitioner are important sources of musical insight. To address this issue, Bourdieu’s notion of habitus will be explored. The habitus will be shown to contain a vast network of socio-cultural codes informing the practitioner’s relationship with the musical work. A central aim of this thesis is to explore the possibilities of using practice-based research as the foundation for the study and analysis of a composition, in order to allow for a deeper understanding of the work by means of the generation and harnessing of practical knowledge. Thus, the theoretical outline of PBR provided in this thesis will be applied to a piece of practical performance-based analysis. As such, an analysis of Mahler’s Quartetsatz will be used as the basis on which to draw knowledge in this project.
- Full Text:
- Date Issued: 2015
Analysis of calendar effects and market anomalies on the Johannesburg Stock Exchange
- Atsin, Achiapo Jessica Lisette
- Authors: Atsin, Achiapo Jessica Lisette
- Date: 2015
- Subjects: Stock exchanges -- South Africa -- Johannesburg , Stocks -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:9028 , http://hdl.handle.net/10948/d1020372
- Description: This study sought to empirically investigate the existence of calendar effects and market anomalies on the JSE using monthly and daily closing prices of the ALSI, Top 40, Mid Cap and Small Cap index; as well as, daily closing prices on the Value, Growth and Dividend Plus index during the sample period 2002 – 2013. The anomalies analysed are the January effect, the weekend effect, the size effect, the value effect, and the dividend yield effect. The empirical analysis uses a number of MSAR with a different number of regimes and lag orders. The results from the investigation of the January effect show the non-existence of the January effect and the value effect on the JSE during the periods 2002 – 2013 and 2004 – 2013, respectively. However, the weekend effect was found significant in the Mid Cap and the Small Cap index, and the size effect was also found significant during the same period 2002 - 2013. Finally the results from a Granger causality test concluded that there is a relationship between the returns on the Dividend Plus index and the ALSI, effectively proving the existence of the dividend yield effect on the JSE between 2006 and 2013. Additionally, the anomalies found imply the opportunity for investors to make returns above buy-and-hold.
- Full Text:
- Date Issued: 2015
- Authors: Atsin, Achiapo Jessica Lisette
- Date: 2015
- Subjects: Stock exchanges -- South Africa -- Johannesburg , Stocks -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:9028 , http://hdl.handle.net/10948/d1020372
- Description: This study sought to empirically investigate the existence of calendar effects and market anomalies on the JSE using monthly and daily closing prices of the ALSI, Top 40, Mid Cap and Small Cap index; as well as, daily closing prices on the Value, Growth and Dividend Plus index during the sample period 2002 – 2013. The anomalies analysed are the January effect, the weekend effect, the size effect, the value effect, and the dividend yield effect. The empirical analysis uses a number of MSAR with a different number of regimes and lag orders. The results from the investigation of the January effect show the non-existence of the January effect and the value effect on the JSE during the periods 2002 – 2013 and 2004 – 2013, respectively. However, the weekend effect was found significant in the Mid Cap and the Small Cap index, and the size effect was also found significant during the same period 2002 - 2013. Finally the results from a Granger causality test concluded that there is a relationship between the returns on the Dividend Plus index and the ALSI, effectively proving the existence of the dividend yield effect on the JSE between 2006 and 2013. Additionally, the anomalies found imply the opportunity for investors to make returns above buy-and-hold.
- Full Text:
- Date Issued: 2015
Analysis of predictive power of binding affinity of PBM-derived sequences
- Authors: Matereke, Lavious Tapiwa
- Date: 2015
- Subjects: Transcription factors , Protein binding , DNA-binding proteins , Chromatin , Protein microarrays
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4161 , http://hdl.handle.net/10962/d1018666
- Description: A transcription factor (TF) is a protein that binds to specific DNA sequences as part of the initiation stage of transcription. Various methods of finding these transcription factor binding sites (TFBS) have been developed. In vivo technologies analyze DNA binding regions known to have bound to a TF in a living cell. Most widely used in vivo methods at the moment are chromatin immunoprecipitation followed by deep sequencing (ChIP-seq) and DNase I hypersensitive sites sequencing. In vitro methods derive TFBS based on experiments with TFs and DNA usually in artificial settings or computationally. An example is the Protein Binding Microarray which uses artificially constructed DNA sequences to determine the short sequences that are most likely to bind to a TF. The major drawback of this approach is that binding of TFs in vivo is also dependent on other factors such as chromatin accessibility and the presence of cofactors. Therefore TFBS derived from the PBM technique might not resemble the true DNA binding sequences. In this work, we use PBM data from the UniPROBE motif database, ChIP-seq data and DNase I hypersensitive sites data. Using the Spearman’s rank correlation and area under receiver operating characteristic curve, we compare the enrichment scores which the PBM approach assigns to its identified sequences and the frequency of these sequences in likely binding regions and the human genome as a whole. We also use central motif enrichment analysis (CentriMo) to compare the enrichment of UniPROBE motifs with in vivo derived motifs (from the JASPAR CORE database) in their respective TF ChIP-seq peak region. CentriMo is applied to 14 TF ChIP-seq peak regions from different cell lines. We aim to establish if there is a relationship between the occurrences of UniPROBE 8-mer patterns in likely binding regions and their enrichment score and how well the in vitro derived motifs match in vivo binding specificity. We did not come out with a particular trend showing failure of the PBM approach to predict in vivo binding specificity. Our results show Ets1, Hnf4a and Tcf3 show prediction failure by the PBM technique in terms of our Spearman’s rank correlation for ChIP-seq data and central motif enrichment analysis. However, the PBM technique also matched the in vivo binding specificities of FoxA2, Pou2f2 and Mafk. Failure of the PBM approach was found to be a result of variability in the TF’s binding specificity, the presence of cofactors, narrow binding specificity and the presence ubiquitous binding patterns.
- Full Text:
- Date Issued: 2015
- Authors: Matereke, Lavious Tapiwa
- Date: 2015
- Subjects: Transcription factors , Protein binding , DNA-binding proteins , Chromatin , Protein microarrays
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4161 , http://hdl.handle.net/10962/d1018666
- Description: A transcription factor (TF) is a protein that binds to specific DNA sequences as part of the initiation stage of transcription. Various methods of finding these transcription factor binding sites (TFBS) have been developed. In vivo technologies analyze DNA binding regions known to have bound to a TF in a living cell. Most widely used in vivo methods at the moment are chromatin immunoprecipitation followed by deep sequencing (ChIP-seq) and DNase I hypersensitive sites sequencing. In vitro methods derive TFBS based on experiments with TFs and DNA usually in artificial settings or computationally. An example is the Protein Binding Microarray which uses artificially constructed DNA sequences to determine the short sequences that are most likely to bind to a TF. The major drawback of this approach is that binding of TFs in vivo is also dependent on other factors such as chromatin accessibility and the presence of cofactors. Therefore TFBS derived from the PBM technique might not resemble the true DNA binding sequences. In this work, we use PBM data from the UniPROBE motif database, ChIP-seq data and DNase I hypersensitive sites data. Using the Spearman’s rank correlation and area under receiver operating characteristic curve, we compare the enrichment scores which the PBM approach assigns to its identified sequences and the frequency of these sequences in likely binding regions and the human genome as a whole. We also use central motif enrichment analysis (CentriMo) to compare the enrichment of UniPROBE motifs with in vivo derived motifs (from the JASPAR CORE database) in their respective TF ChIP-seq peak region. CentriMo is applied to 14 TF ChIP-seq peak regions from different cell lines. We aim to establish if there is a relationship between the occurrences of UniPROBE 8-mer patterns in likely binding regions and their enrichment score and how well the in vitro derived motifs match in vivo binding specificity. We did not come out with a particular trend showing failure of the PBM approach to predict in vivo binding specificity. Our results show Ets1, Hnf4a and Tcf3 show prediction failure by the PBM technique in terms of our Spearman’s rank correlation for ChIP-seq data and central motif enrichment analysis. However, the PBM technique also matched the in vivo binding specificities of FoxA2, Pou2f2 and Mafk. Failure of the PBM approach was found to be a result of variability in the TF’s binding specificity, the presence of cofactors, narrow binding specificity and the presence ubiquitous binding patterns.
- Full Text:
- Date Issued: 2015
Androcentrism and misogyny in late twentieth century rock music
- Authors: Berkland, Darren Gary
- Date: 2015
- Subjects: Music -- Social aspects , Gender identity in music , Music -- Performance -- Psychological aspects , Emotions in music , Rock musicians
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:8440 , http://hdl.handle.net/10948/d1021199
- Description: Judith Butler’s writings on gender ostensibly changed the way gender is considered with regard to an individual’s subjectivity. Her writings expressed a discursive parameter that changed the theoretical standpoint of gender from that of performance, to that of performativity. In short, the notion of gender became understood as a power mechanism operating within society that compels individuals along the heteronormal binary tracts of male or female, man or woman. Within the strata of popular culture, this binarism is seemingly ritualized and repeated, incessantly. This treatise examines how rock music, as a popular and widespread mode of popular music, exemplifies gender binarism through a notable ndrocentrism. The research will examine how gender performativity operates within the taxonomy of rock music, and how the message communicated by rock music becomes translated into a listener’s subjectivity.
- Full Text:
- Date Issued: 2015
- Authors: Berkland, Darren Gary
- Date: 2015
- Subjects: Music -- Social aspects , Gender identity in music , Music -- Performance -- Psychological aspects , Emotions in music , Rock musicians
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:8440 , http://hdl.handle.net/10948/d1021199
- Description: Judith Butler’s writings on gender ostensibly changed the way gender is considered with regard to an individual’s subjectivity. Her writings expressed a discursive parameter that changed the theoretical standpoint of gender from that of performance, to that of performativity. In short, the notion of gender became understood as a power mechanism operating within society that compels individuals along the heteronormal binary tracts of male or female, man or woman. Within the strata of popular culture, this binarism is seemingly ritualized and repeated, incessantly. This treatise examines how rock music, as a popular and widespread mode of popular music, exemplifies gender binarism through a notable ndrocentrism. The research will examine how gender performativity operates within the taxonomy of rock music, and how the message communicated by rock music becomes translated into a listener’s subjectivity.
- Full Text:
- Date Issued: 2015
Antibiotic stewardship: the role of clinical pharmacist
- Authors: Ramkhalawon, Shabeerah
- Date: 2015
- Subjects: Hospital pharmacies -- South Africa Pharmacists -- South Africa
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: http://hdl.handle.net/10948/10858 , vital:26830
- Description: South Africa has a high prevalence of infectious diseases; the major ones being the Human Immunodeficiency Virus/Acquired Immune Deficiency Syndrome epidemic, and tuberculosis. South Africa’s burden of resistant bacteria is also increasing. Antibiotic resistance in hospitalised patients leads to an increase in morbidity and mortality, resulting in longer hospital stays, and an increase in hospital costs. In order to counteract the problem of antibiotic resistance in hospitals and other healthcare facilities and preserve the efficacy of currently available antibiotics, there is a need for serious antibiotic management. Antibiotic stewardship initiatives have thus been put in place to guide healthcare professionals on the correct use of antibiotics. Clinical pharmacists can intervene and contribute to antibiotic stewardship owing to comprehensive knowledge of antibiotics, including the properties, uses, safety and efficacy of individual agents. There is a paucity of research to support the role of the clinical pharmacist in antibiotic stewardship in public sector hospitals. The current pharmacist staffing system within public sector hospitals does not adequately support pharmacists, in particular clinical pharmacists, to participate actively in antibiotic stewardship. The primary aim of the study was to evaluate the role of the clinical pharmacist in antibiotic stewardship in a public hospital setting. A secondary aim was to contribute towards more rational inpatient use of antibiotics in the general medical ward. The hypothesis for the study was that clinical pharmacists can make a positive contribution to the correct use of antibiotics in a public hospital setting. The study showed that the introduction of a pharmacist-driven antibiotic stewardship in the ward, using a prospective audit and feedback strategy, had a positive effect on overall appropriateness of antibiotic prescribing (Chi2=7.89; df=3; p=0.04815, Cramer’s V=0.13). However, this finding did not show any reduction in the volume of antibiotic use. Positive patient outcomes were achieved and shown through a reduction in the length of hospital stay (p=0.00487; one-way ANOVA). Although patients were not followed up on discharge to assess re-admission rates, the results are relevant in order to inform the hospital staff about the implementation of antibiotic stewardship at the public hospital setting with the aims of reducing inappropriate antibiotic prescribing and improving patient outcomes. From the results of the study, it can be concluded that the hypothesis was achieved and that the clinical pharmacist did play an integral role in antibiotic prescribing at the public hospital setting. Thus, it can be concluded that the study, though limited in its scope, achieved its aims and objectives, and showed that the clinical pharmacist does play an integral role in the rational use of antibiotics in a public hospital setting.
- Full Text:
- Date Issued: 2015
- Authors: Ramkhalawon, Shabeerah
- Date: 2015
- Subjects: Hospital pharmacies -- South Africa Pharmacists -- South Africa
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: http://hdl.handle.net/10948/10858 , vital:26830
- Description: South Africa has a high prevalence of infectious diseases; the major ones being the Human Immunodeficiency Virus/Acquired Immune Deficiency Syndrome epidemic, and tuberculosis. South Africa’s burden of resistant bacteria is also increasing. Antibiotic resistance in hospitalised patients leads to an increase in morbidity and mortality, resulting in longer hospital stays, and an increase in hospital costs. In order to counteract the problem of antibiotic resistance in hospitals and other healthcare facilities and preserve the efficacy of currently available antibiotics, there is a need for serious antibiotic management. Antibiotic stewardship initiatives have thus been put in place to guide healthcare professionals on the correct use of antibiotics. Clinical pharmacists can intervene and contribute to antibiotic stewardship owing to comprehensive knowledge of antibiotics, including the properties, uses, safety and efficacy of individual agents. There is a paucity of research to support the role of the clinical pharmacist in antibiotic stewardship in public sector hospitals. The current pharmacist staffing system within public sector hospitals does not adequately support pharmacists, in particular clinical pharmacists, to participate actively in antibiotic stewardship. The primary aim of the study was to evaluate the role of the clinical pharmacist in antibiotic stewardship in a public hospital setting. A secondary aim was to contribute towards more rational inpatient use of antibiotics in the general medical ward. The hypothesis for the study was that clinical pharmacists can make a positive contribution to the correct use of antibiotics in a public hospital setting. The study showed that the introduction of a pharmacist-driven antibiotic stewardship in the ward, using a prospective audit and feedback strategy, had a positive effect on overall appropriateness of antibiotic prescribing (Chi2=7.89; df=3; p=0.04815, Cramer’s V=0.13). However, this finding did not show any reduction in the volume of antibiotic use. Positive patient outcomes were achieved and shown through a reduction in the length of hospital stay (p=0.00487; one-way ANOVA). Although patients were not followed up on discharge to assess re-admission rates, the results are relevant in order to inform the hospital staff about the implementation of antibiotic stewardship at the public hospital setting with the aims of reducing inappropriate antibiotic prescribing and improving patient outcomes. From the results of the study, it can be concluded that the hypothesis was achieved and that the clinical pharmacist did play an integral role in antibiotic prescribing at the public hospital setting. Thus, it can be concluded that the study, though limited in its scope, achieved its aims and objectives, and showed that the clinical pharmacist does play an integral role in the rational use of antibiotics in a public hospital setting.
- Full Text:
- Date Issued: 2015
Antjie Krog and the post-apartheid public sphere: Speaking poetry to power
- Authors: Garman, Anthea
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/159913 , vital:40355 , ISBN 978-1869142933
- Description: Antjie Krog has been known in Afrikaans literary circles and the media for decades because of her poetry and her strong political convictions. Often known simply as 'Antjie,' she is also affectionately called 'our beloved poet' and our 'Joan of Arc' by Afrikaans commentators. It was through her work on the Truth and Reconciliation Commission as an SABC radio journalist and her subsequent book, Country of My Skull, that Antjie Krog then became known to English-speakers in South Africa and across the world. Her work catapulted her particular brand of poetics and politics, honed over many years of her opposition to apartheid, into the South African public sphere at a time when the country was not only looking for a humane and just resolution after the apartheid era, but was also establishing itself as a new democracy.
- Full Text:
- Date Issued: 2015
- Authors: Garman, Anthea
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/159913 , vital:40355 , ISBN 978-1869142933
- Description: Antjie Krog has been known in Afrikaans literary circles and the media for decades because of her poetry and her strong political convictions. Often known simply as 'Antjie,' she is also affectionately called 'our beloved poet' and our 'Joan of Arc' by Afrikaans commentators. It was through her work on the Truth and Reconciliation Commission as an SABC radio journalist and her subsequent book, Country of My Skull, that Antjie Krog then became known to English-speakers in South Africa and across the world. Her work catapulted her particular brand of poetics and politics, honed over many years of her opposition to apartheid, into the South African public sphere at a time when the country was not only looking for a humane and just resolution after the apartheid era, but was also establishing itself as a new democracy.
- Full Text:
- Date Issued: 2015
Anton and Vale van der Merwe: reinterpreting Afro-Oriental studio ceramics traditions in South Africa
- Authors: Steele, John
- Date: 2015
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/11260/968 , vital:30077
- Description: Growing awareness of ancient Chinese Song and Yuan ceramics, amongst other Oriental traditions, by people with western connections such as Bernard Leach and Michael Cardew, in conjunction with influences from Japanese associates such as Soyetsu Yanagi, Kenkichi Tomimoto, and Shoji Hamada, (De Waal 1997, Harrod 2012, Kikuchi 1977, Leach 1976) has had many consequences. It spread a consciousness idealizing self-sufficient pottery studios where potters were in touch with all aspects of creating utilityware, largely from local materials for local use. Out of this emerged an Anglo-Oriental studio ceramic philosophy of form and practice, associated mainly with hand-made high temperature reduction fired ceramics. These ideas spread to South Africa in the late 1950s, and by the early 1960s local studios were being established along these lines. This studio ceramics movement grew exponentially in South Africa, initiating a phase of Afro-Oriental ceramics that remains a powerful way of life and visual arts influence. This paper seeks to explore aspects of Afro- Oriental studio ceramics in South Africa, with particular reference to the Leach/Hamada/Cardew to Rabinowitz, and Van der Merwe lineage.
- Full Text:
- Date Issued: 2015
- Authors: Steele, John
- Date: 2015
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/11260/968 , vital:30077
- Description: Growing awareness of ancient Chinese Song and Yuan ceramics, amongst other Oriental traditions, by people with western connections such as Bernard Leach and Michael Cardew, in conjunction with influences from Japanese associates such as Soyetsu Yanagi, Kenkichi Tomimoto, and Shoji Hamada, (De Waal 1997, Harrod 2012, Kikuchi 1977, Leach 1976) has had many consequences. It spread a consciousness idealizing self-sufficient pottery studios where potters were in touch with all aspects of creating utilityware, largely from local materials for local use. Out of this emerged an Anglo-Oriental studio ceramic philosophy of form and practice, associated mainly with hand-made high temperature reduction fired ceramics. These ideas spread to South Africa in the late 1950s, and by the early 1960s local studios were being established along these lines. This studio ceramics movement grew exponentially in South Africa, initiating a phase of Afro-Oriental ceramics that remains a powerful way of life and visual arts influence. This paper seeks to explore aspects of Afro- Oriental studio ceramics in South Africa, with particular reference to the Leach/Hamada/Cardew to Rabinowitz, and Van der Merwe lineage.
- Full Text:
- Date Issued: 2015
Application of bacteriocins in the preservation of fruit juice
- Authors: Bodley, Mark David
- Date: 2015
- Subjects: Bacteriocins , Fruit juices -- Preservation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10345 , http://hdl.handle.net/10948/d1020188
- Description: Bacteriocins (BCNs) are ribosomally synthesized polypeptides or proteins with antimicrobial activity, produced by different groups of bacteria. Many lactic acid bacteria (LAB) produce BCNs with broad spectra of inhibition. The antimicrobial activity of BCNs against spoilage organisms (SPOs) has raised considerable interest in their application in juice preservation. The objectives of the study were to: (i) isolate, identify and screen BCN producing bacteria for antimicrobial activity against spoilage bacteria and fungi, (ii) optimize production of BCN from selected producers and (iii) investigate the industrial application of the BCN as a preservative in fruit juice. Eleven LAB strains of BCN producers were screened for antimicrobial activity. BCNs from Lactobacillus plantarum and Pediococcus pentosaceus 34 were the most effective against juice spoilage bacteria and fungi. The effect of medium components on bacteriocin production in L. plantarum and P. pentosaceus 34 was also determined. Clementine:Valencia (1:1) juice was used for the first time as the growth medium for L. plantarum and P. pentosaceus 34. The BCN from L. plantarum showed the highest activity and was, therefore, chosen for juice fermentation studies. The identification of L. plantarum was confirmed by biochemical tests, polymerase chain reaction (PCR) and sequencing of the recA gene. The highest BCN activity was observed for L. plantarum grown in De Man-Rogosa-Sharpe (MRS) and a combination of all supplements (i.e. peptone, MnSO4.H2O, Tween 80, glucose and whey), followed by MRS and Tween 80, peptone, MnSO4.H2O and MRS alone. MRS was a better medium for BCN production than juice [Clementine:Valencia (1:1)]. Size exclusion chromatography (SEC) was used to isolate the active L. plantarum BCN fraction which corresponded to an approximate molecular weight of 3.2 kDa and was proteinaceous in nature. Plantaricin structural genes (plnEF, plnJ, plnK, plnN) were detected in the L. plantarum strain by PCR and sequenced, and were chromosomally encoded as no plasmids could be detected. This implies that the BCN from L. plantarum is most likely a type of class IIa plantaricin which is responsible for the broad inhibitory activity observed. For the industrial application studies, L. plantarum BCN-containing cell free supernatant (BCNsup) added to “Ready to Drink” (RTD) Clementine:Valencia (1:1) juice at concentrations of 3 600 - 500 000 ppm decreased growth of SPOs, Lactobacillus acidophilus and Streptococcus thermophilus. At 250 000 ppm, the L. plantarum BCNsup achieved 5.3 and 6.8 log reductions of the L. acidophilus, after 24 and 48 h, respectively, which is larger than the USFDA (2001) requirement of a 5 log reduction in SPO activity, for preservation of fruit juices. However, there was a decrease in the activity when the BCNsup was applied to industrial (Valor) RTD juice (mango-orange) at decreasing concentrations of 100 000, 50 000 and 25 000 ppm. Organoleptic tests showed that the BCN did not alter flavor or taste of the juice and did not cause toxicity or allergic reactions. A food safety risk assessment was conducted in order to determine the Critical Control Point(s) [CCP(s)] at which the BCN could be applied to control identified microbiological hazards, and a Hazard Analysis and Critical Control Point (HACCP) plan was developed. This is the first report on the optimisation of L. plantarum BCN production in juice [Clementine:Valencia (1:1)], followed by inoculation into RTD juice (mango-orange), including a HACCP plan for the application of the BCN as a preservative in juice.
- Full Text:
- Date Issued: 2015
- Authors: Bodley, Mark David
- Date: 2015
- Subjects: Bacteriocins , Fruit juices -- Preservation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10345 , http://hdl.handle.net/10948/d1020188
- Description: Bacteriocins (BCNs) are ribosomally synthesized polypeptides or proteins with antimicrobial activity, produced by different groups of bacteria. Many lactic acid bacteria (LAB) produce BCNs with broad spectra of inhibition. The antimicrobial activity of BCNs against spoilage organisms (SPOs) has raised considerable interest in their application in juice preservation. The objectives of the study were to: (i) isolate, identify and screen BCN producing bacteria for antimicrobial activity against spoilage bacteria and fungi, (ii) optimize production of BCN from selected producers and (iii) investigate the industrial application of the BCN as a preservative in fruit juice. Eleven LAB strains of BCN producers were screened for antimicrobial activity. BCNs from Lactobacillus plantarum and Pediococcus pentosaceus 34 were the most effective against juice spoilage bacteria and fungi. The effect of medium components on bacteriocin production in L. plantarum and P. pentosaceus 34 was also determined. Clementine:Valencia (1:1) juice was used for the first time as the growth medium for L. plantarum and P. pentosaceus 34. The BCN from L. plantarum showed the highest activity and was, therefore, chosen for juice fermentation studies. The identification of L. plantarum was confirmed by biochemical tests, polymerase chain reaction (PCR) and sequencing of the recA gene. The highest BCN activity was observed for L. plantarum grown in De Man-Rogosa-Sharpe (MRS) and a combination of all supplements (i.e. peptone, MnSO4.H2O, Tween 80, glucose and whey), followed by MRS and Tween 80, peptone, MnSO4.H2O and MRS alone. MRS was a better medium for BCN production than juice [Clementine:Valencia (1:1)]. Size exclusion chromatography (SEC) was used to isolate the active L. plantarum BCN fraction which corresponded to an approximate molecular weight of 3.2 kDa and was proteinaceous in nature. Plantaricin structural genes (plnEF, plnJ, plnK, plnN) were detected in the L. plantarum strain by PCR and sequenced, and were chromosomally encoded as no plasmids could be detected. This implies that the BCN from L. plantarum is most likely a type of class IIa plantaricin which is responsible for the broad inhibitory activity observed. For the industrial application studies, L. plantarum BCN-containing cell free supernatant (BCNsup) added to “Ready to Drink” (RTD) Clementine:Valencia (1:1) juice at concentrations of 3 600 - 500 000 ppm decreased growth of SPOs, Lactobacillus acidophilus and Streptococcus thermophilus. At 250 000 ppm, the L. plantarum BCNsup achieved 5.3 and 6.8 log reductions of the L. acidophilus, after 24 and 48 h, respectively, which is larger than the USFDA (2001) requirement of a 5 log reduction in SPO activity, for preservation of fruit juices. However, there was a decrease in the activity when the BCNsup was applied to industrial (Valor) RTD juice (mango-orange) at decreasing concentrations of 100 000, 50 000 and 25 000 ppm. Organoleptic tests showed that the BCN did not alter flavor or taste of the juice and did not cause toxicity or allergic reactions. A food safety risk assessment was conducted in order to determine the Critical Control Point(s) [CCP(s)] at which the BCN could be applied to control identified microbiological hazards, and a Hazard Analysis and Critical Control Point (HACCP) plan was developed. This is the first report on the optimisation of L. plantarum BCN production in juice [Clementine:Valencia (1:1)], followed by inoculation into RTD juice (mango-orange), including a HACCP plan for the application of the BCN as a preservative in juice.
- Full Text:
- Date Issued: 2015
Application of Baylis-Hillman methodology in the synthesis of HIV-1 enzyme inhibitors
- Authors: Manyeruke, Meloddy Hlatini
- Date: 2015
- Subjects: HIV infections , Enzyme inhibitors , AZT (Drug) , Bioconjugates
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4540 , http://hdl.handle.net/10962/d1017920
- Description: The application of Baylis-Hillman methodology has afforded access to a range of β-hydroxypropionate ester-AZT conjugates as potential dual-action HIV-1 IN/RT inhibitors. Two families comprising a total of nine β-hydroxypropionate ester-AZT conjugates were synthesised. The first family was accessed using O-benzylated salicylaldehydes and methyl acrylate and the second from unprotected salicylaldehydes using tert-butyl acrylate as the activated alkene. Spectroscopic methods were employed to fully characterize the compounds. Propargylation of the respective Baylis-Hillman adducts was achieved via conjugate addition of propargylamine. The resulting products were then employed in Cu(I)-catalysed “click” reactions with azidothymidine (AZT) to yield the desired β-hydroxypropionate ester-AZT conjugates. Exploratory studies were also conducted to access 4-hydroxycoumarins from Baylis-Hillman derived adducts and to construct customized chiral Baylis-Hillman reaction sites. Many 4- hydroxycoumarins are known to exhibit a wide range of biological activities, and extending Baylis-Hillman methodology to access these systems is an important challenge. Two approaches were investigated. The first involved the formation of a 4-phthalimidocoumarin, aromatisation and hydrolysis of which was expected to lead to the 4-hydroxycoumarin target. The second, a variation of the first, involved the use of 4-(chrolomethyl)coumarin intermediates. Unfortunately, while various intermediates were prepared and characterised, neither approach led ultimately to the desired targets. N-substituted borneol-10-sulfonamides were constructed from camphor-10- sulfonyl chloride as chiral Baylis-Hillman reaction sites. In a preliminary study, however, none of the N-substituted borneol-10-sulfonamides exhibited Baylis-Hillman catalytic activity.
- Full Text:
- Date Issued: 2015
- Authors: Manyeruke, Meloddy Hlatini
- Date: 2015
- Subjects: HIV infections , Enzyme inhibitors , AZT (Drug) , Bioconjugates
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4540 , http://hdl.handle.net/10962/d1017920
- Description: The application of Baylis-Hillman methodology has afforded access to a range of β-hydroxypropionate ester-AZT conjugates as potential dual-action HIV-1 IN/RT inhibitors. Two families comprising a total of nine β-hydroxypropionate ester-AZT conjugates were synthesised. The first family was accessed using O-benzylated salicylaldehydes and methyl acrylate and the second from unprotected salicylaldehydes using tert-butyl acrylate as the activated alkene. Spectroscopic methods were employed to fully characterize the compounds. Propargylation of the respective Baylis-Hillman adducts was achieved via conjugate addition of propargylamine. The resulting products were then employed in Cu(I)-catalysed “click” reactions with azidothymidine (AZT) to yield the desired β-hydroxypropionate ester-AZT conjugates. Exploratory studies were also conducted to access 4-hydroxycoumarins from Baylis-Hillman derived adducts and to construct customized chiral Baylis-Hillman reaction sites. Many 4- hydroxycoumarins are known to exhibit a wide range of biological activities, and extending Baylis-Hillman methodology to access these systems is an important challenge. Two approaches were investigated. The first involved the formation of a 4-phthalimidocoumarin, aromatisation and hydrolysis of which was expected to lead to the 4-hydroxycoumarin target. The second, a variation of the first, involved the use of 4-(chrolomethyl)coumarin intermediates. Unfortunately, while various intermediates were prepared and characterised, neither approach led ultimately to the desired targets. N-substituted borneol-10-sulfonamides were constructed from camphor-10- sulfonyl chloride as chiral Baylis-Hillman reaction sites. In a preliminary study, however, none of the N-substituted borneol-10-sulfonamides exhibited Baylis-Hillman catalytic activity.
- Full Text:
- Date Issued: 2015