Evaluating the importance of mangroves as fish nurseries in selected warm temperate South African estuaries
- Authors: Muller, Cuen
- Date: 2017
- Subjects: Mangrove ecology -- South Africa Mangrove fisheries -- South Africa , Estuarine ecology -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/12080 , vital:27029
- Description: The value of mangrove habitats as fish nurseries was assessed by comparing communities of early stage and juvenile fishes between estuaries with and without mangroves. Early stage fishes were sampled using boat-based plankton towing while juveniles were sampled by seine netting. Sampling took place at five sites spaced 1 km apart starting near the estuary mouth in four estuaries along the temperate coastline of the Eastern Cape Province of South Africa. Four estuaries were selected based on shared similarities which included catchment area, estuarine area and shared habitats barring the presence of mangroves which occupied the river margins of two systems. Results revealed that early stage and juvenile fish communities (both marine- and estuary-spawned) were similar between systems with and without mangrove habitats. Differences in fish communities among estuaries were rather attributed to axial salinity gradients associated with greater freshwater input, while season and temperature produced significant variances in fish densities with Generalised Additive Models revealing responses of communities to these variables. A common estuarine-dependent fish, Rhabdosargus holubi (Family Sparidae), was further investigated to determine habitat use, residency and dietary patterns in different mangrove habitats. High habitat residency in this species was revealed during a short-term tagging study using Visible Implant Elastomer tags and long-term isotope analysis in juveniles sampled from two contrasting mangrove habitats. A wider feeding niche was observed in an eelgrass-red mangrove connected habitat when compared with more exposed white mangrove areas. Low dependence on mangrove habitats in temperate estuaries is likely due to their tidally dominated inundation and limited refuge potential due to smaller area coverage by mangroves in temperate estuaries. Relatively lower primary productivity in warm temperate mangrove areas, relative to their tropical counterparts, provides no significant feeding advantage or refuge opportunities relative to other available habitats in these estuaries. Warm temperate estuaries, which are both spatially and temporally highly variable, instead host species which are habitat generalists, able to capitalise on these highly dynamic environments.
- Full Text:
- Date Issued: 2017
- Authors: Muller, Cuen
- Date: 2017
- Subjects: Mangrove ecology -- South Africa Mangrove fisheries -- South Africa , Estuarine ecology -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/12080 , vital:27029
- Description: The value of mangrove habitats as fish nurseries was assessed by comparing communities of early stage and juvenile fishes between estuaries with and without mangroves. Early stage fishes were sampled using boat-based plankton towing while juveniles were sampled by seine netting. Sampling took place at five sites spaced 1 km apart starting near the estuary mouth in four estuaries along the temperate coastline of the Eastern Cape Province of South Africa. Four estuaries were selected based on shared similarities which included catchment area, estuarine area and shared habitats barring the presence of mangroves which occupied the river margins of two systems. Results revealed that early stage and juvenile fish communities (both marine- and estuary-spawned) were similar between systems with and without mangrove habitats. Differences in fish communities among estuaries were rather attributed to axial salinity gradients associated with greater freshwater input, while season and temperature produced significant variances in fish densities with Generalised Additive Models revealing responses of communities to these variables. A common estuarine-dependent fish, Rhabdosargus holubi (Family Sparidae), was further investigated to determine habitat use, residency and dietary patterns in different mangrove habitats. High habitat residency in this species was revealed during a short-term tagging study using Visible Implant Elastomer tags and long-term isotope analysis in juveniles sampled from two contrasting mangrove habitats. A wider feeding niche was observed in an eelgrass-red mangrove connected habitat when compared with more exposed white mangrove areas. Low dependence on mangrove habitats in temperate estuaries is likely due to their tidally dominated inundation and limited refuge potential due to smaller area coverage by mangroves in temperate estuaries. Relatively lower primary productivity in warm temperate mangrove areas, relative to their tropical counterparts, provides no significant feeding advantage or refuge opportunities relative to other available habitats in these estuaries. Warm temperate estuaries, which are both spatially and temporally highly variable, instead host species which are habitat generalists, able to capitalise on these highly dynamic environments.
- Full Text:
- Date Issued: 2017
Evaluating the potential of monometallic and bimetallic nanomaterials as horseradish peroxidase mimetics
- Authors: Mvango, Sindisiwe
- Date: 2017
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/65134 , vital:28694
- Description: This study presents the synthesis of citrate-capped gold nanoparticles (cit-AuNPs), copper oxide nanoparticles (CuONPs), glutathione-capped gold nanoparticles (GSH-AuNPs), 4- aminothiophenol-capped gold nanoparticles (4-ATP-AuNPs), 4-mercapto benzoic acid- capped gold nanoparticles (4-MBA-AuNPs) and copper oxide gold nanoalloys (CuO-Au nanoalloys). Microscopy and spectroscopy techniques were used to confirm the successful synthesis of these nanoparticles. The synthesized nanoparticles were studied their potential applications as horseradish peroxidase (HPR) enzyme mimetics and for the detection of glucose. The cit-AuNPs and GSH-AuNPs exhibited peroxidase-like activity towards hydrogen peroxide (H2O2) with high Michaelis-Menten (Km) values of 61.5 mM and 30.8 mM, respectively. The other nanoparticles, that is, 4-ATP-AuNPs, CuONPs and CuO-Au nanoalloys gave lower Km values of 4.74 mM, 1.92 mM and 4.05 mM, respectively. The obtained Km values were comparable to those of HRP enzymes which ranged from 0.214 - 3.70 mM with 4-ATP-AuNPs and CuO-Au nanoalloys slightly higher. These values were within the reasonable experimental values of the HRP enzyme. The studies showed that the gold nanoparticles had low adsorptive efficiency towards H2O2 compared to the copper-based nanoparticles (CuONPs and CuO-Au nanoalloys). The CuO-Au nanoalloys also showed the synergistic effect between the gold and copper nanoparticles with extended linear concentration range for the quantification of H2O2. The mechanism of catalysis was confirmed using UV-vis spectroscopy and electron paramagnetic resonance (EPR) in that the generation of reactive oxygen species was observed. The use of 1,3-diphenylisobenzofuran (DPBF) as radical quencher and 5,5- dimethyl-1-pyrroline N-oxide (DMPO) as a radical scavenger confirmed the production of reductive reactive oxygen species using UV-vis and EPR studies. The rate of production of reactive oxygen species in the gold-based nanoparticles was small compared to the copper-based nanoparticles, that is CuONPs and CuO-Au (bimetallic) nanoalloys. The synthesized nanoparticles were further studied their potential use in the colorimetric detection of glucose. The copper-based nanomaterials, CuONPs and CuO-Au nanoalloys, were excellent towards detection of glucose, with a limit of detection (LoD) of 9.34 pM for CuONPs and 6.75 pM for CuO-Au nanoalloys. The linear concentration (LCR) range of CuONPs was 0 to 70 pM and for CuO-Au nanoalloys the LCR was 0.0 - 30 pM. , Thesis (MSc) -- Faculty of Science, Chemistry, 2017
- Full Text:
- Date Issued: 2017
- Authors: Mvango, Sindisiwe
- Date: 2017
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/65134 , vital:28694
- Description: This study presents the synthesis of citrate-capped gold nanoparticles (cit-AuNPs), copper oxide nanoparticles (CuONPs), glutathione-capped gold nanoparticles (GSH-AuNPs), 4- aminothiophenol-capped gold nanoparticles (4-ATP-AuNPs), 4-mercapto benzoic acid- capped gold nanoparticles (4-MBA-AuNPs) and copper oxide gold nanoalloys (CuO-Au nanoalloys). Microscopy and spectroscopy techniques were used to confirm the successful synthesis of these nanoparticles. The synthesized nanoparticles were studied their potential applications as horseradish peroxidase (HPR) enzyme mimetics and for the detection of glucose. The cit-AuNPs and GSH-AuNPs exhibited peroxidase-like activity towards hydrogen peroxide (H2O2) with high Michaelis-Menten (Km) values of 61.5 mM and 30.8 mM, respectively. The other nanoparticles, that is, 4-ATP-AuNPs, CuONPs and CuO-Au nanoalloys gave lower Km values of 4.74 mM, 1.92 mM and 4.05 mM, respectively. The obtained Km values were comparable to those of HRP enzymes which ranged from 0.214 - 3.70 mM with 4-ATP-AuNPs and CuO-Au nanoalloys slightly higher. These values were within the reasonable experimental values of the HRP enzyme. The studies showed that the gold nanoparticles had low adsorptive efficiency towards H2O2 compared to the copper-based nanoparticles (CuONPs and CuO-Au nanoalloys). The CuO-Au nanoalloys also showed the synergistic effect between the gold and copper nanoparticles with extended linear concentration range for the quantification of H2O2. The mechanism of catalysis was confirmed using UV-vis spectroscopy and electron paramagnetic resonance (EPR) in that the generation of reactive oxygen species was observed. The use of 1,3-diphenylisobenzofuran (DPBF) as radical quencher and 5,5- dimethyl-1-pyrroline N-oxide (DMPO) as a radical scavenger confirmed the production of reductive reactive oxygen species using UV-vis and EPR studies. The rate of production of reactive oxygen species in the gold-based nanoparticles was small compared to the copper-based nanoparticles, that is CuONPs and CuO-Au (bimetallic) nanoalloys. The synthesized nanoparticles were further studied their potential use in the colorimetric detection of glucose. The copper-based nanomaterials, CuONPs and CuO-Au nanoalloys, were excellent towards detection of glucose, with a limit of detection (LoD) of 9.34 pM for CuONPs and 6.75 pM for CuO-Au nanoalloys. The linear concentration (LCR) range of CuONPs was 0 to 70 pM and for CuO-Au nanoalloys the LCR was 0.0 - 30 pM. , Thesis (MSc) -- Faculty of Science, Chemistry, 2017
- Full Text:
- Date Issued: 2017
Evaluating the safety climate effects on employee safety behaviour in ESKOM distribution Eastern Cape operating unit
- Authors: Rondganger, Aron Dominique
- Date: 2017
- Subjects: Eskom (Firm) Industrial safety -- South Africa , Employee health promotion -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/47755 , vital:40368
- Description: Work-related injuries have a significant social and economic impact on organisations and countries. Safety climate has been found to be the leading indicator to predict employee safety behaviour in an effort to reduce incidents and injuries. The organisation selected has implemented a health and safety strategy that includes a safety management system that defines safety practices. There has been an improvement seen at an organisation level, however this improvement is not wide spread. The aim of this study is to understand the role of safety climate and its effect on safety behaviour within the Eastern Cape Operating Unit. The sample only consisted of employees from the organisation selected for this study. A stratified sampling method was chosen and three hundred (300) questionnaires were distributed to managers (10), supervisors (20) and field workers (270). A total of two hundred and seventy eight employees (92.7% response rate) participated in the study consisting of nine managers (90% response rate), seventeen supervisors (85% response rate) and two hundred and forty-nine field workers (92.2% response rate). The empirical results show that organisational-level safety climate has a significant influence on team-level safety climate. The overall safety climate within the organisation was not high and the safety climate perceptions of managers, supervisors and field workers were not related. Organisation-level and team-level safety climate was found to influence safety behaviour. The results also revealed that the compliance and participation safety behaviours reported by managers, supervisors and field workers are high. It was further discovered that the safety behaviours of these three groups are related. The implementation of the recommendations that were highlighted from these results would have a significant improvement in the organisation’s safety climate and this would lead to reduced unsafe acts and safety related incidents in the workplace.
- Full Text:
- Date Issued: 2017
- Authors: Rondganger, Aron Dominique
- Date: 2017
- Subjects: Eskom (Firm) Industrial safety -- South Africa , Employee health promotion -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/47755 , vital:40368
- Description: Work-related injuries have a significant social and economic impact on organisations and countries. Safety climate has been found to be the leading indicator to predict employee safety behaviour in an effort to reduce incidents and injuries. The organisation selected has implemented a health and safety strategy that includes a safety management system that defines safety practices. There has been an improvement seen at an organisation level, however this improvement is not wide spread. The aim of this study is to understand the role of safety climate and its effect on safety behaviour within the Eastern Cape Operating Unit. The sample only consisted of employees from the organisation selected for this study. A stratified sampling method was chosen and three hundred (300) questionnaires were distributed to managers (10), supervisors (20) and field workers (270). A total of two hundred and seventy eight employees (92.7% response rate) participated in the study consisting of nine managers (90% response rate), seventeen supervisors (85% response rate) and two hundred and forty-nine field workers (92.2% response rate). The empirical results show that organisational-level safety climate has a significant influence on team-level safety climate. The overall safety climate within the organisation was not high and the safety climate perceptions of managers, supervisors and field workers were not related. Organisation-level and team-level safety climate was found to influence safety behaviour. The results also revealed that the compliance and participation safety behaviours reported by managers, supervisors and field workers are high. It was further discovered that the safety behaviours of these three groups are related. The implementation of the recommendations that were highlighted from these results would have a significant improvement in the organisation’s safety climate and this would lead to reduced unsafe acts and safety related incidents in the workplace.
- Full Text:
- Date Issued: 2017
Evaluating the share performance of socially responsible investment on the Johannesburg Stock Exchange
- Authors: Cormack, Bradley Alexander
- Date: 2017
- Subjects: Investments -- Moral and ethical aspects -- South Africa , Johannesburg Stock Exchange , Social responsibility of business -- Standards , Social responsiblity of business -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10962/36251 , vital:24532
- Description: Socially responsible investing (SRI) integrates environmental, social and governance (ESG) issues into the investment decision-making process. Growing ESG concerns and the uncovering of corporate scandals have catalysed the substantial growth in SRI portfolios worldwide. Notwithstanding its increasing popularity, barriers to further SRI growth have been identified. Traditional investing practices suggest that theoretically, SRI may underperform conventional investment strategies. However, despite the vast amount of literature on SRI, empirical studies have yielded a mixture of results regarding fund performance. The JSE SRI Index was launched in 2004 to promote transparent business practices. It was discontinued at the end of 2015 succeeded by a new Responsible Investment Index established by the JSE in association with FTSE Russell. The aim of the research was to evaluate the share performance of the JSE SRI Index from 2004-2015. Additionally, the indices were categorised by environmental impact to further analyse disparity among share returns. The study was also divided into two sub-periods, 2004-2009 and 2010-2015, with the latter following the endorsement of integrated reporting by the King III Code as a listing requirement in 2010. A single-factor Capital Asset Pricing Model (CAPM) was used to assess differences in risk-adjusted returns. Engle-Granger and Johansen tests were employed to explore the possibility of a cointegrating relationship between the indices. No significant difference between returns was observed for 2004-2009, with the SRI Index exhibiting statistically significant inferior risk-adjusted returns for the latter half of the study. Overall, a significant difference between share returns was found, with CAPM results suggesting that the JSE SRI Index underperformed the All Share Index by -2.33% per annum throughout the time span of the study. Engle-Granger and Johansen test results indicated the existence of a cointegrating relationship over the first half of the study. However, there was no cointegration between the two indices for 2004-2015, which may be attributed to no significant relationship found for the latter years. Results support the notion that investors pay the price to invest ethically on the JSE. Inferior risk-adjusted returns associated with SRI may be a major barrier to its development in South African markets.
- Full Text:
- Date Issued: 2017
- Authors: Cormack, Bradley Alexander
- Date: 2017
- Subjects: Investments -- Moral and ethical aspects -- South Africa , Johannesburg Stock Exchange , Social responsibility of business -- Standards , Social responsiblity of business -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10962/36251 , vital:24532
- Description: Socially responsible investing (SRI) integrates environmental, social and governance (ESG) issues into the investment decision-making process. Growing ESG concerns and the uncovering of corporate scandals have catalysed the substantial growth in SRI portfolios worldwide. Notwithstanding its increasing popularity, barriers to further SRI growth have been identified. Traditional investing practices suggest that theoretically, SRI may underperform conventional investment strategies. However, despite the vast amount of literature on SRI, empirical studies have yielded a mixture of results regarding fund performance. The JSE SRI Index was launched in 2004 to promote transparent business practices. It was discontinued at the end of 2015 succeeded by a new Responsible Investment Index established by the JSE in association with FTSE Russell. The aim of the research was to evaluate the share performance of the JSE SRI Index from 2004-2015. Additionally, the indices were categorised by environmental impact to further analyse disparity among share returns. The study was also divided into two sub-periods, 2004-2009 and 2010-2015, with the latter following the endorsement of integrated reporting by the King III Code as a listing requirement in 2010. A single-factor Capital Asset Pricing Model (CAPM) was used to assess differences in risk-adjusted returns. Engle-Granger and Johansen tests were employed to explore the possibility of a cointegrating relationship between the indices. No significant difference between returns was observed for 2004-2009, with the SRI Index exhibiting statistically significant inferior risk-adjusted returns for the latter half of the study. Overall, a significant difference between share returns was found, with CAPM results suggesting that the JSE SRI Index underperformed the All Share Index by -2.33% per annum throughout the time span of the study. Engle-Granger and Johansen test results indicated the existence of a cointegrating relationship over the first half of the study. However, there was no cointegration between the two indices for 2004-2015, which may be attributed to no significant relationship found for the latter years. Results support the notion that investors pay the price to invest ethically on the JSE. Inferior risk-adjusted returns associated with SRI may be a major barrier to its development in South African markets.
- Full Text:
- Date Issued: 2017
Evaluation of groundwater potential using neotectonics and geophysics in the context of post Karoo tectonic framework around Fort Beaufort and Smithfield, Eastern Cape, South Africa
- Authors: Ndlovu, Nkosilathi
- Date: 2017
- Subjects: Neotectonics -- South Africa -- Eastern Cape Groundwater -- South Africa -- Eastern Cape Geophysical surveys -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12687 , vital:39299
- Description: Geological and geophysical methods were used to investigate the Karoo area extending from longitudes 25.50 E to 27.50 E and latitudes 300 S to 330 S in South Africa, particularly Fort Beaufort, Aliwal North, Venterstad and Smithfield. The geology of the area is dominated by the upper Beaufort Group (Adelaide Subgroup) with an extensive network of dolerite sills and dykes that intruded the sedimentary sequence. A relationship between neotectonics, post-Karoo tectonics, groundwater and lithology was investigated to locate suitable groundwater potential sites. Apart from studying the role of neotectonics and the post Karoo tectonics, this research aims at generating groundwater targets to alleviate water shortages mainly for farming and livestock, and prove that neotectonics is still active. Methodologies adopted for obtaining these results included a comprehensive literature review, thin section analysis, scanning electron microscopy, geophysical investigation (magnetic, gravity, and vertical electrical sounding), and the application of Geographical Information Systems (GIS) and remote sensing. Twenty samples were collected at various locations within the study area and were analyzed using the petrographic microscope while others were analyzed with the Scanning Electron Microscopic (SEM) combined with an Energy dispersive x-ray spectrometry. The results show that the rocks are fractured, porous and have variable mineralogy (presence of heavy minerals) within the rocks. The use of Geographical Information Systems (GIS) and remote sensing in geological surveys, especially hydrogeology, has gained momentum over the past few years. This research is no exception as ArcMap software was used to create a map of seismic epicentres of the Eastern Cape Province. From the map it can be observed that seismicity still occurs and thus leading to the notion of neotectonics being active. Lineaments were also automatically extracted using the ENVI 5.1 and Geomatica 2013 software. Lineaments are zones of weakness in the subsurface of the Earth and are very important in locating groundwater potential sites. Geophysical techniques are essential and highly accurate for groundwater studies. Gravity and magnetic techniques were applied on data which was supplied as grids. Analysis using Geosoft Oasis 8.3 revealed extensive lineaments and ring like patterns and these were inferred to be dolerite intrusions (sills and dykes). The morphology of the intrusions help in identifying possible groundwater potential zones and thus they should be investigated. Vertical electrical sounding (VES) technique using the Schlumberger array was carried out at three sites (Fort Beaufort fracture which is possibly related to Quaternary surface uplift of the Amatole-Swaziland axis, splay of the Fort Beaufort fracture and at a site which showed high groundwater potential) to explore subsurface layering. IP2win (lite), 1-D modelling software was used to model the apparent resistivity data to obtain the geoelectric parameters of the subsurface (thickness and resistivity). The VES results are consistent with fractured rocks that aid groundwater movement. The VES data for the three sites was further modelled by the RES2DINV software and this shows low resistivity values associated with loose, water saturated top sandy soil and higher resistivity values associated with sedimentary sequences and dolerite. Moreover, potential sites for citing wells are predicted to be between 79.5 and 128 m on the profile. Further neotectonic studies need to be done, especially on the quaternary sediments as they would have more neotectonic evidence. The use of geophysical techniques for groundwater search need to be intensified, with more emphasis being put to the sedimentary sequences bordered by dolerite intrusions and fractured zones.
- Full Text:
- Date Issued: 2017
- Authors: Ndlovu, Nkosilathi
- Date: 2017
- Subjects: Neotectonics -- South Africa -- Eastern Cape Groundwater -- South Africa -- Eastern Cape Geophysical surveys -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12687 , vital:39299
- Description: Geological and geophysical methods were used to investigate the Karoo area extending from longitudes 25.50 E to 27.50 E and latitudes 300 S to 330 S in South Africa, particularly Fort Beaufort, Aliwal North, Venterstad and Smithfield. The geology of the area is dominated by the upper Beaufort Group (Adelaide Subgroup) with an extensive network of dolerite sills and dykes that intruded the sedimentary sequence. A relationship between neotectonics, post-Karoo tectonics, groundwater and lithology was investigated to locate suitable groundwater potential sites. Apart from studying the role of neotectonics and the post Karoo tectonics, this research aims at generating groundwater targets to alleviate water shortages mainly for farming and livestock, and prove that neotectonics is still active. Methodologies adopted for obtaining these results included a comprehensive literature review, thin section analysis, scanning electron microscopy, geophysical investigation (magnetic, gravity, and vertical electrical sounding), and the application of Geographical Information Systems (GIS) and remote sensing. Twenty samples were collected at various locations within the study area and were analyzed using the petrographic microscope while others were analyzed with the Scanning Electron Microscopic (SEM) combined with an Energy dispersive x-ray spectrometry. The results show that the rocks are fractured, porous and have variable mineralogy (presence of heavy minerals) within the rocks. The use of Geographical Information Systems (GIS) and remote sensing in geological surveys, especially hydrogeology, has gained momentum over the past few years. This research is no exception as ArcMap software was used to create a map of seismic epicentres of the Eastern Cape Province. From the map it can be observed that seismicity still occurs and thus leading to the notion of neotectonics being active. Lineaments were also automatically extracted using the ENVI 5.1 and Geomatica 2013 software. Lineaments are zones of weakness in the subsurface of the Earth and are very important in locating groundwater potential sites. Geophysical techniques are essential and highly accurate for groundwater studies. Gravity and magnetic techniques were applied on data which was supplied as grids. Analysis using Geosoft Oasis 8.3 revealed extensive lineaments and ring like patterns and these were inferred to be dolerite intrusions (sills and dykes). The morphology of the intrusions help in identifying possible groundwater potential zones and thus they should be investigated. Vertical electrical sounding (VES) technique using the Schlumberger array was carried out at three sites (Fort Beaufort fracture which is possibly related to Quaternary surface uplift of the Amatole-Swaziland axis, splay of the Fort Beaufort fracture and at a site which showed high groundwater potential) to explore subsurface layering. IP2win (lite), 1-D modelling software was used to model the apparent resistivity data to obtain the geoelectric parameters of the subsurface (thickness and resistivity). The VES results are consistent with fractured rocks that aid groundwater movement. The VES data for the three sites was further modelled by the RES2DINV software and this shows low resistivity values associated with loose, water saturated top sandy soil and higher resistivity values associated with sedimentary sequences and dolerite. Moreover, potential sites for citing wells are predicted to be between 79.5 and 128 m on the profile. Further neotectonic studies need to be done, especially on the quaternary sediments as they would have more neotectonic evidence. The use of geophysical techniques for groundwater search need to be intensified, with more emphasis being put to the sedimentary sequences bordered by dolerite intrusions and fractured zones.
- Full Text:
- Date Issued: 2017
Evaluation of low-cost technology options for sustainable water supply and sanitation in two peri-urban areas of Lusaka, Zambia: opportunities and constraints
- Authors: Chiliboyi, Yvonne
- Date: 2017
- Subjects: Toilets -- Technological innovations -- South Africa , Sanitary engineering -- Technological innovations -- South Africa , Water resoures development -- Technological innovations -- South Africa , Water-supply -- Technological innovations -- South Africa , Household surveys -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/7960 , vital:21328
- Description: Presently, at least 70% of the total urban population in Zambia resides in peri-urban areas. Peri-urban settlements are characterized by high population growth, high poverty levels and inadequate access to water and sanitation which often result in increased prevalence of diseases. The situation is even made worse because of the position that many local authorities have taken regarding the implementation of infrastructure and service development in these settlements. Local authorities in developing countries have continuously focused on implementation of traditional and unsustainable technologies for service provision to meet the demand despite the technologies’ inability to serve the rapidly growing peri-urban areas. These technologies have high costs, lack proper operation and maintenance, and are not affordable to majority of peri-urban residents. Therefore, this study was set out to identify and evaluate the existing and possible low-cost technology options for sustainable water supply and sanitation in two selected peri-urban areas of Lusaka, Zambia, namely Kanyama and Chazanga. This was achieved through a household survey conducted in the selected communities. Questionnaires and focus group discussions were held in the respective areas to obtain baseline data on the current water supply and sanitation situation, the type of technologies used, challenges faced regarding water and sanitation technologies, and to get the communities perceptions and preferences of different technology options. Thereafter, a Multi-Criterion Analysis methodological approach was used to assess the selected technologies by the communities, taking into consideration of the economic, socio-cultural, technical, institutional and environmental aspects. Results from the study revealed that a few low-cost water supply and sanitation technologies are feasible for peri-urban areas. For Chazanga, communal taps, boreholes, protected wells, and rain water harvesting were found to be feasible for water supply. For sanitation, on-site sanitation services such as compost toilets, dry toilets, as well as Ventilated Improved Pits (VIP) and Pour-flush, Fossa Alterna and the Urine Diversion Dry Toilet (UDDT) are some of the low-cost technologies that can be implemented in the area. The VIP is suitable for households that rely on water from communal taps for their use. As majority of households in the area have taps on their plots, the Pour-flush can be an alternative. The Fossa Alterna and the Urine Diversion Dry Toilet (UDDT) have low initial cost and can accommodate different households. Additionally, the area has a lower household size and majority of the residents in the area landlords, which makes it easy to teach users how the toilet operates as well as its maintenance. For Kanyama, feasible and sustainable low-cost water supply facilities include boreholes and communal taps. Kanyama has limited plot sizes thereby causing the challenge of implementing infrastructure such as rainwater harvesting. Additionally, continuous increase in urban population in the area, coupled with the construction of unregulated households and sanitation facilities, renders protected wells not feasible to implement in Kanyama. In terms of sanitation, wet on-site sanitation facilities such as Ventilated Improved Pit (VIP) latrines are accepted by the community. The VIP does not require water for use and if properly constructed can be used as a bathroom. The Pour-flush toilet is also another alternative for provision of sanitation in the area. However, the latrine can be expensive to construct for majority of the residents. Dry sanitation such as the Urine Diversion Dry Toilet (UDDT) is not feasible for Kanyama. The UDDT requires continuous awareness on its use especially in rented households where tenants are constantly changing. The method of evaluating appropriate technology options for peri-urban areas and thereafter letting the users from the communities choose from the proposed technologies ensures a participatory approach. Results from Multi-Criterion Analysis (MCA) showed that stakeholders’ influence is essential for the selection of sustainable technology options. However, it is important that the implementation process of any technology in peri-urban areas consider different aspects including the local environmental, socio-cultural, economic, technical, and institutional conditions. Finally, the outcome of this study will not only provide baseline data for successful implementation of appropriate low-cost water supply and sanitation technology options in Chazanga and Kanyama, but also other peri-urban communities in Zambia.
- Full Text:
- Date Issued: 2017
- Authors: Chiliboyi, Yvonne
- Date: 2017
- Subjects: Toilets -- Technological innovations -- South Africa , Sanitary engineering -- Technological innovations -- South Africa , Water resoures development -- Technological innovations -- South Africa , Water-supply -- Technological innovations -- South Africa , Household surveys -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/7960 , vital:21328
- Description: Presently, at least 70% of the total urban population in Zambia resides in peri-urban areas. Peri-urban settlements are characterized by high population growth, high poverty levels and inadequate access to water and sanitation which often result in increased prevalence of diseases. The situation is even made worse because of the position that many local authorities have taken regarding the implementation of infrastructure and service development in these settlements. Local authorities in developing countries have continuously focused on implementation of traditional and unsustainable technologies for service provision to meet the demand despite the technologies’ inability to serve the rapidly growing peri-urban areas. These technologies have high costs, lack proper operation and maintenance, and are not affordable to majority of peri-urban residents. Therefore, this study was set out to identify and evaluate the existing and possible low-cost technology options for sustainable water supply and sanitation in two selected peri-urban areas of Lusaka, Zambia, namely Kanyama and Chazanga. This was achieved through a household survey conducted in the selected communities. Questionnaires and focus group discussions were held in the respective areas to obtain baseline data on the current water supply and sanitation situation, the type of technologies used, challenges faced regarding water and sanitation technologies, and to get the communities perceptions and preferences of different technology options. Thereafter, a Multi-Criterion Analysis methodological approach was used to assess the selected technologies by the communities, taking into consideration of the economic, socio-cultural, technical, institutional and environmental aspects. Results from the study revealed that a few low-cost water supply and sanitation technologies are feasible for peri-urban areas. For Chazanga, communal taps, boreholes, protected wells, and rain water harvesting were found to be feasible for water supply. For sanitation, on-site sanitation services such as compost toilets, dry toilets, as well as Ventilated Improved Pits (VIP) and Pour-flush, Fossa Alterna and the Urine Diversion Dry Toilet (UDDT) are some of the low-cost technologies that can be implemented in the area. The VIP is suitable for households that rely on water from communal taps for their use. As majority of households in the area have taps on their plots, the Pour-flush can be an alternative. The Fossa Alterna and the Urine Diversion Dry Toilet (UDDT) have low initial cost and can accommodate different households. Additionally, the area has a lower household size and majority of the residents in the area landlords, which makes it easy to teach users how the toilet operates as well as its maintenance. For Kanyama, feasible and sustainable low-cost water supply facilities include boreholes and communal taps. Kanyama has limited plot sizes thereby causing the challenge of implementing infrastructure such as rainwater harvesting. Additionally, continuous increase in urban population in the area, coupled with the construction of unregulated households and sanitation facilities, renders protected wells not feasible to implement in Kanyama. In terms of sanitation, wet on-site sanitation facilities such as Ventilated Improved Pit (VIP) latrines are accepted by the community. The VIP does not require water for use and if properly constructed can be used as a bathroom. The Pour-flush toilet is also another alternative for provision of sanitation in the area. However, the latrine can be expensive to construct for majority of the residents. Dry sanitation such as the Urine Diversion Dry Toilet (UDDT) is not feasible for Kanyama. The UDDT requires continuous awareness on its use especially in rented households where tenants are constantly changing. The method of evaluating appropriate technology options for peri-urban areas and thereafter letting the users from the communities choose from the proposed technologies ensures a participatory approach. Results from Multi-Criterion Analysis (MCA) showed that stakeholders’ influence is essential for the selection of sustainable technology options. However, it is important that the implementation process of any technology in peri-urban areas consider different aspects including the local environmental, socio-cultural, economic, technical, and institutional conditions. Finally, the outcome of this study will not only provide baseline data for successful implementation of appropriate low-cost water supply and sanitation technology options in Chazanga and Kanyama, but also other peri-urban communities in Zambia.
- Full Text:
- Date Issued: 2017
Evaluation of medicine safety reporting systems in South Africa
- Thornborrow-Geswind, Kirsten
- Authors: Thornborrow-Geswind, Kirsten
- Date: 2017
- Subjects: Drugs -- Side effects -- Research -- South Africa Pharmacoepidemiology -- Research -- South Africa , Medicine -- South Africa -- Safety measures Public health -- South Africa
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: http://hdl.handle.net/10948/21439 , vital:29517
- Description: Pharmacovigilance is “the science and activities relating to the detection, assessment, understanding and prevention of adverse effects or any other drug-related problem”. To date, no comprehensive study has been performed to evaluate the pharmacovigilance system in the public health sector in South Africa. The primary aim of this study was to evaluate the current status of pharmacovigilance systems within the public healthcare sector in South Africa, and the level of functioning of these systems, in order to provide relevant recommendations, where necessary, for improvement, using the Indicator-based Pharmacogivilance Assessment Tool (IPAT). National and provincial entities were deemed compulsory (n=14), while facilities were selected via random, stratified sampling to obtain a representation at each facility level (n=101). The IPAT was amended for relevance at each level of data collection. Indicators are classified as core and supplementary and compliance with core indicators shows the level of functioning National entities obtained an IPAT score of 36 out of a maximum of 72, achieving 50% compliance. Province D and Province G obtained overall IPAT scores of 29 and 12 respectively out of a maximum of 40, achieving an overall 72.5% and 30% compliance respectively Results at provincial and facility levels were not fully representative due to a limited response rate of 22.2% and 65.3% respectively. Regional/tertiary facilities and district facilities displayed increased awareness and implementation of pharmacovigilance activity than the lower levels of Community Health Centres (CHCs) and Primary Health Centres (PHCs). South Africa”s public healthcare system possesses the infrastructure for a well functioning pharmacovigilance system. However there are gaps in level of functioning at a national, provincial and facility level. Addressing these gaps would show a marked improvement in the system and go a long way towards the contribution of medicine safety information not only locally, but to aid other developing nations.
- Full Text:
- Date Issued: 2017
- Authors: Thornborrow-Geswind, Kirsten
- Date: 2017
- Subjects: Drugs -- Side effects -- Research -- South Africa Pharmacoepidemiology -- Research -- South Africa , Medicine -- South Africa -- Safety measures Public health -- South Africa
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: http://hdl.handle.net/10948/21439 , vital:29517
- Description: Pharmacovigilance is “the science and activities relating to the detection, assessment, understanding and prevention of adverse effects or any other drug-related problem”. To date, no comprehensive study has been performed to evaluate the pharmacovigilance system in the public health sector in South Africa. The primary aim of this study was to evaluate the current status of pharmacovigilance systems within the public healthcare sector in South Africa, and the level of functioning of these systems, in order to provide relevant recommendations, where necessary, for improvement, using the Indicator-based Pharmacogivilance Assessment Tool (IPAT). National and provincial entities were deemed compulsory (n=14), while facilities were selected via random, stratified sampling to obtain a representation at each facility level (n=101). The IPAT was amended for relevance at each level of data collection. Indicators are classified as core and supplementary and compliance with core indicators shows the level of functioning National entities obtained an IPAT score of 36 out of a maximum of 72, achieving 50% compliance. Province D and Province G obtained overall IPAT scores of 29 and 12 respectively out of a maximum of 40, achieving an overall 72.5% and 30% compliance respectively Results at provincial and facility levels were not fully representative due to a limited response rate of 22.2% and 65.3% respectively. Regional/tertiary facilities and district facilities displayed increased awareness and implementation of pharmacovigilance activity than the lower levels of Community Health Centres (CHCs) and Primary Health Centres (PHCs). South Africa”s public healthcare system possesses the infrastructure for a well functioning pharmacovigilance system. However there are gaps in level of functioning at a national, provincial and facility level. Addressing these gaps would show a marked improvement in the system and go a long way towards the contribution of medicine safety information not only locally, but to aid other developing nations.
- Full Text:
- Date Issued: 2017
Evaluation of near infrared reflectance (NIR) spectroscopy to determine the nutrient composition of raw materials and compound ostrich feeds
- Swart, Etheresia, Lehmann-Maritz, Maryna
- Authors: Swart, Etheresia , Lehmann-Maritz, Maryna
- Date: 2017
- Subjects: Near infrared spectroscopy , Animal nutrition , Animal feeding
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/13779 , vital:27307
- Description: The chemical analysis of feed samples can be time consuming and expensive. The use of near infrared reflectance (NIR) spectroscopy was evaluated in a range of studies as a rapid technique to predict the chemical constituents in feedstuffs and compound ostrich feeds. The prediction of accurate results by NIR spectroscopy relies heavily upon obtaining a calibration set which represents the variation in the main population, accurate laboratory analyses and the application of the best mathematical procedures. This research project was designed to meet five objectives: The first objective was to determine the feasibility of using near infrared reflectance (NIR) spectroscopy to predict dry matter, ash, crude protein, crude fibre, oil content, and fatty acids such as palmitic acid (C16:0), stearic acid (C18:0), oleic acid (C18:1) and linoleic acid (C18:2) in sunflower seed meal. The second objective was to develop calibration models to predict the dry matter, crude protein and oil content in milled canola seed, compared to whole canola seeds. The third objective was to investigate the feasibility of using NIR spectroscopy to predict the dry matter, ash, crude protein, crude fibre and oil content in milled lupin seeds, compared to whole lupin seeds. The fourth objective was to describe the development of near infrared reflectance (NIR) spectroscopy calibration equations for the prediction of chemical composition and amino acid content from different populations of alfalfa hay (Medicago sativa L.). The last objective was to determine the potential of NIR spectroscopy to predict the dry matter, ash, crude protein, crude fibre, ether extract, acid detergent fibre (ADF), neutral detergent fibre (NDF), calcium, phosphorus, in vitro organic matter digestibility (IVOMD) and amino acids such as lysine, methionine, threonine and arginine in compound ostrich feed samples. The results of this study indicate that NIR spectroscopy calibrations in sunflower seed meal are only applicable in sunflower breeding programmes for a fast screening as it was not suitable for prediction purposes. Screening of sunflower seeds by NIR spectroscopy represents a rapid, simple and cost effective alternative that is a great utility for users who need to analyse a large number of samples. Calibrations developed for crude protein and oil content in milled canola seeds proved to be better than calibrations for whole canola seeds. Although the results indicated that calibrations were better for milled canola seeds, it indicated values that were typical of equations suitable for screening purposes to select samples for more detailed chemical analysis. According to calibration statistics obtained for crude protein, crude fibre and oil content in whole lupin seeds, there is no need to grind the seeds to scan the meal as similarly accurate results were obtained by analysing whole seeds. Screening of whole lupin seeds by NIR spectroscopy represents a rapid, simple and cost effective alternative that may be of great utility for users who need to analyse a large number of samples with no sample preparation. The calibration and validation statistics obtained in the study to test the potential of NIR spectroscopy to predict the chemical composition and amino acid contents in alfalfa hay, showed the accuracy was too low for routine analysis, although NIR spectroscopy could be used as a screening tool. Further research needs to be done to improve the accuracy of the NIR spectroscopy analysis, including more samples from different cultivars and years. In the study to examine the possibility of using NIR spectroscopy to predict the chemical composition of compound ostrich feeds, the results indicated that NIR spectroscopy is a suitable tool for a rapid and reliable prediction of the crude protein, crude fibre, ether extract, IVOMD, ADF and NDF in compound ostrich feeds. Calibrations can be improved for amino acids if a larger sample pool is used to develop the calibrations. These studies indicated that NIR spectroscopy can be a rapid and successful tool for the prediction of the nutritive value up to certain amino acid contents of feedstuffs and compound ostrich feeds.
- Full Text:
- Date Issued: 2017
- Authors: Swart, Etheresia , Lehmann-Maritz, Maryna
- Date: 2017
- Subjects: Near infrared spectroscopy , Animal nutrition , Animal feeding
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: http://hdl.handle.net/10948/13779 , vital:27307
- Description: The chemical analysis of feed samples can be time consuming and expensive. The use of near infrared reflectance (NIR) spectroscopy was evaluated in a range of studies as a rapid technique to predict the chemical constituents in feedstuffs and compound ostrich feeds. The prediction of accurate results by NIR spectroscopy relies heavily upon obtaining a calibration set which represents the variation in the main population, accurate laboratory analyses and the application of the best mathematical procedures. This research project was designed to meet five objectives: The first objective was to determine the feasibility of using near infrared reflectance (NIR) spectroscopy to predict dry matter, ash, crude protein, crude fibre, oil content, and fatty acids such as palmitic acid (C16:0), stearic acid (C18:0), oleic acid (C18:1) and linoleic acid (C18:2) in sunflower seed meal. The second objective was to develop calibration models to predict the dry matter, crude protein and oil content in milled canola seed, compared to whole canola seeds. The third objective was to investigate the feasibility of using NIR spectroscopy to predict the dry matter, ash, crude protein, crude fibre and oil content in milled lupin seeds, compared to whole lupin seeds. The fourth objective was to describe the development of near infrared reflectance (NIR) spectroscopy calibration equations for the prediction of chemical composition and amino acid content from different populations of alfalfa hay (Medicago sativa L.). The last objective was to determine the potential of NIR spectroscopy to predict the dry matter, ash, crude protein, crude fibre, ether extract, acid detergent fibre (ADF), neutral detergent fibre (NDF), calcium, phosphorus, in vitro organic matter digestibility (IVOMD) and amino acids such as lysine, methionine, threonine and arginine in compound ostrich feed samples. The results of this study indicate that NIR spectroscopy calibrations in sunflower seed meal are only applicable in sunflower breeding programmes for a fast screening as it was not suitable for prediction purposes. Screening of sunflower seeds by NIR spectroscopy represents a rapid, simple and cost effective alternative that is a great utility for users who need to analyse a large number of samples. Calibrations developed for crude protein and oil content in milled canola seeds proved to be better than calibrations for whole canola seeds. Although the results indicated that calibrations were better for milled canola seeds, it indicated values that were typical of equations suitable for screening purposes to select samples for more detailed chemical analysis. According to calibration statistics obtained for crude protein, crude fibre and oil content in whole lupin seeds, there is no need to grind the seeds to scan the meal as similarly accurate results were obtained by analysing whole seeds. Screening of whole lupin seeds by NIR spectroscopy represents a rapid, simple and cost effective alternative that may be of great utility for users who need to analyse a large number of samples with no sample preparation. The calibration and validation statistics obtained in the study to test the potential of NIR spectroscopy to predict the chemical composition and amino acid contents in alfalfa hay, showed the accuracy was too low for routine analysis, although NIR spectroscopy could be used as a screening tool. Further research needs to be done to improve the accuracy of the NIR spectroscopy analysis, including more samples from different cultivars and years. In the study to examine the possibility of using NIR spectroscopy to predict the chemical composition of compound ostrich feeds, the results indicated that NIR spectroscopy is a suitable tool for a rapid and reliable prediction of the crude protein, crude fibre, ether extract, IVOMD, ADF and NDF in compound ostrich feeds. Calibrations can be improved for amino acids if a larger sample pool is used to develop the calibrations. These studies indicated that NIR spectroscopy can be a rapid and successful tool for the prediction of the nutritive value up to certain amino acid contents of feedstuffs and compound ostrich feeds.
- Full Text:
- Date Issued: 2017
Evaluation of self-efficacy in clinical performance of nurses initiate and management of anti-retroviral therapy by South African professional nurses
- Authors: Mangi, Nozuko Glenrose
- Date: 2017
- Subjects: Nursing assessment -- South Africa -- Eastern Cape Self-efficacy Nursing -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/4492 , vital:28344
- Description: Self-efficacy in clinical performance is a very important aspect in quality of health care, because it is the ability of the person to produce the desired outcomes. The aim of the study was to evaluate self-efficacy in clinical performance of NIMART programme by professional nurses in Buffalo City Metropolitan in Eastern Cape Province South Africa. A quantitative, descriptive survey design was used to examine self-efficacy in clinical performance during implementation of NIMART programme. A purposive sample of 358 NIMART programme trained professional nurses was included in the study. Analysis of the finding was done using SPSS version 21.0. Descriptive statistics (frequencies, percentage, mean and standard deviations) were used to analyse categorical variables. To reduce data volume, factor analysis was used to identify six variable clusters: Evaluation; planning, assessment, implementation, and patient care mentoring. Factor 1 (evaluation) was highly loaded on patient driven results (0.63); nursing interventions (0.70); breakdown point location (0.80); prognosis based care decisions (0.79); prognosis based outcome monitoring (0.70); and prognosis based settings adjustment (0.70). These items collectively define evaluation of self-efficacy clinical performance of the participants. Factor 2 (planning) was termed planning of patient care in a clinical setting was significantly loaded on these items: data driven nursing diagnosis (0.51); patient driven nursing diagnosis (0.52); settings based nursing diagnosis (0.49); overall care plan formulation (0.52); short-term patients care formulation (0.58); long-term patient care formulation (0.66); goal based measurable outcomes (0.80); goal based daily patient care plan (0.79); settings based daily patient care plan (0.73). Factor 3 (assessment) which was termed assessment in clinical performance was not significantly loaded in some of the items: physical assessment (0.64); patient history (0.65); energy restoration (0.56); time management (0.71); objective patient health data (0.61); subjective patient health data (0.49); data collection documentation (0.44). Factor 4 (implementation) data source correlation; patient health data analysis (0.45); patient strength (0.46); nurse-patient/family communication (0.55); nurse patient collaboration (0.64); Experience driven decision making (0.58). Factor 5 (patient care) patient care plan adherence (0.65); setting based overall patient care (0.74); resource based overall patient care (0.59). Factor 6 (mentoring) patient’s concerns identification (0.48); patient problems prioritisation (0.46); mentor/colleague advice (0.43); mentor/colleague feedback use (0.61); patient discharge strategies (0.71); continuous reporting/documenting (0.63). The mean scores produced by the Kruskal-Wallis test showed the lowest scoring pattern as follows: 20122013201120142010. This order was the same for all the variables, confirming that the 2010 group scored significantly higher than any other group on all the variables. The overall results of the study revealed that professional nurses have high self-efficacy in clinical performance in implementation of NIMART programme, except in evaluation aspect of self-efficacy where they scored lessor. Professional nurses trained by FPD scored higher in the aspects of self-efficacy in clinical performance compared to RTC trained; but scored lower in evaluative ability of self-efficacy in both institutions (FPD and RTC). The findings of this study showed that the overall self-efficacy of the professional nurses trained on NIMART programme performed clinically satisfactorily. It is recommended that in-service education or continuous professional development for professional nurses working in PHC’s should not only concentrate on updating clinical skills, but also create opportunity for reflection and strengthening of professional nurses’ self-efficacy in clinical performance. Also, further study on other processes of goal realisation will aid our understanding of self-efficacy in achieving the desirable goals of the professional nurses for patient quality care. Further research is also needed to evaluate clients’ satisfaction during care based on the NIMART intervention programme.
- Full Text:
- Date Issued: 2017
- Authors: Mangi, Nozuko Glenrose
- Date: 2017
- Subjects: Nursing assessment -- South Africa -- Eastern Cape Self-efficacy Nursing -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/4492 , vital:28344
- Description: Self-efficacy in clinical performance is a very important aspect in quality of health care, because it is the ability of the person to produce the desired outcomes. The aim of the study was to evaluate self-efficacy in clinical performance of NIMART programme by professional nurses in Buffalo City Metropolitan in Eastern Cape Province South Africa. A quantitative, descriptive survey design was used to examine self-efficacy in clinical performance during implementation of NIMART programme. A purposive sample of 358 NIMART programme trained professional nurses was included in the study. Analysis of the finding was done using SPSS version 21.0. Descriptive statistics (frequencies, percentage, mean and standard deviations) were used to analyse categorical variables. To reduce data volume, factor analysis was used to identify six variable clusters: Evaluation; planning, assessment, implementation, and patient care mentoring. Factor 1 (evaluation) was highly loaded on patient driven results (0.63); nursing interventions (0.70); breakdown point location (0.80); prognosis based care decisions (0.79); prognosis based outcome monitoring (0.70); and prognosis based settings adjustment (0.70). These items collectively define evaluation of self-efficacy clinical performance of the participants. Factor 2 (planning) was termed planning of patient care in a clinical setting was significantly loaded on these items: data driven nursing diagnosis (0.51); patient driven nursing diagnosis (0.52); settings based nursing diagnosis (0.49); overall care plan formulation (0.52); short-term patients care formulation (0.58); long-term patient care formulation (0.66); goal based measurable outcomes (0.80); goal based daily patient care plan (0.79); settings based daily patient care plan (0.73). Factor 3 (assessment) which was termed assessment in clinical performance was not significantly loaded in some of the items: physical assessment (0.64); patient history (0.65); energy restoration (0.56); time management (0.71); objective patient health data (0.61); subjective patient health data (0.49); data collection documentation (0.44). Factor 4 (implementation) data source correlation; patient health data analysis (0.45); patient strength (0.46); nurse-patient/family communication (0.55); nurse patient collaboration (0.64); Experience driven decision making (0.58). Factor 5 (patient care) patient care plan adherence (0.65); setting based overall patient care (0.74); resource based overall patient care (0.59). Factor 6 (mentoring) patient’s concerns identification (0.48); patient problems prioritisation (0.46); mentor/colleague advice (0.43); mentor/colleague feedback use (0.61); patient discharge strategies (0.71); continuous reporting/documenting (0.63). The mean scores produced by the Kruskal-Wallis test showed the lowest scoring pattern as follows: 20122013201120142010. This order was the same for all the variables, confirming that the 2010 group scored significantly higher than any other group on all the variables. The overall results of the study revealed that professional nurses have high self-efficacy in clinical performance in implementation of NIMART programme, except in evaluation aspect of self-efficacy where they scored lessor. Professional nurses trained by FPD scored higher in the aspects of self-efficacy in clinical performance compared to RTC trained; but scored lower in evaluative ability of self-efficacy in both institutions (FPD and RTC). The findings of this study showed that the overall self-efficacy of the professional nurses trained on NIMART programme performed clinically satisfactorily. It is recommended that in-service education or continuous professional development for professional nurses working in PHC’s should not only concentrate on updating clinical skills, but also create opportunity for reflection and strengthening of professional nurses’ self-efficacy in clinical performance. Also, further study on other processes of goal realisation will aid our understanding of self-efficacy in achieving the desirable goals of the professional nurses for patient quality care. Further research is also needed to evaluate clients’ satisfaction during care based on the NIMART intervention programme.
- Full Text:
- Date Issued: 2017
Evaluation of some pharmaceutical and personal care products and pesticide residues in selected wastewater treatment plants and receiving watersheds in Eastern Cape, South Africa
- Ademoyegun, Olufemi Temitope
- Authors: Ademoyegun, Olufemi Temitope
- Date: 2017
- Subjects: Emerging contaminants in water -- South Africa -- Eastern Cape Water treatment plants -- Waste disposal -- South Africa -- Eastern Cape Organic compounds -- Environmental aspects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/2922 , vital:28138
- Description: Emerging organic contaminants (EOCs) have been the focus of global environmental research for over three decades. EOCs have caused widespread concern due to their extensive use. As EOCs were designed to correct, enhance or protect a specific physiological, their target effects in humans and/or farm stocks are relatively well known and documented. However, there is limited knowledge about their unintended effects in the environment. To address the occurrence, distribution and fate of EOCs in the environment, efficient and reliable analytical methods are needed. The relatively low concentration, high polarity, and thermal lability of some EOCs, together with their interaction with complex environmental matrices, make their analysis challenging. Sample preparation followed by GC or HPLC separation and mass spectrometry (MS) detection has become the standard approach for evaluating EOCs in environmental samples. Physicochemical properties of EOCs range from highly water-soluble (hydrophylic) to highly water-insoluble (hydrophobic). Two groups of these EOCs were considered for study in this work. Pharmaceutical and personal care products (PPCPs) were comprehensively studied in five wastewater treatment plants and their receiving watersheds in Amathole districts in Eastern C ape, South Africa. PPCPs have been widely reported in wastewater influents, effluents, receiving rivers and biosolids, but reports of their occurrence in all these matrixes have been limited by the difficulty of analysis. Therefore, a comprehensive validation of methods was carried out on the influents, effluents, sludge and soil from the irrigated golf course where the effluent of one of the study sites was being used for over three decades now for irrigation. In all, thirteen PPCPs from five therapeutic groups were selected for study in this work because of their administering rate and availability of analytical instrument. Good limit of detection (LOD) and limit of quantification (LOQ) were achieved for the method used. The LOD for the aqueous Three different technologies were employed for the treatment of wastewater in the five selected wastewater treatment plants (WWTPs) and study was carried out to evaluate their ability to eliminate the selected compounds from the influents to the effluents using statistical analysis (ANOVA) at p<0.05 on the percentage removal rate across the three plants. The results had shown eight of the compounds having no significant difference among the treatment operations, whereas the remaining five compounds varied significantly among the treatment technologies under investigation. Principal component analysis was performed on the concentration of PPCPs, their removal rate and also on the physicochemical and treatment operation parameters. Hydraulic retention time (HRT) had correlation coefficient, r = 0.90 with the concentration of PPCPs and removal rates. Furthermore, occurrences, seasonal variation, mean concentration distribution pattern of the compounds, and temporal evaluation of the mean concentration of the pharmaceutical compounds in the five WWTPs during one year of sampling were considered. The results revealed that five products which were diclofenac, ibuprofen, paracetamol, triclosan and diethyl toluamide (DDET) were predominant among the PPCPs in all the WWTPs. The removal efficiency was highest in caffeine with 96 percent, and the lowest was obtained with carbamazepine (4 percent). Risk quotient of the concentration of PPCPs in the effluents and receiving waters was determined to assess their chronic toxicity at three trophic levels: fish, algae and matrixes studied ranged from 0.01 μg/L to 0.25 μg/L, and the LOQ from 0.02 μg/L to 0.78 μg/L. In the solid matrixes, LOD varied from 0.01 ng/g to 0.65 ng/g, and the LOQ between 0.08 ng/g and 5.17 ng/g. Better recovery efficiency was obtained with this mixture of solvents, acetone: dichloromethane (1:1), for the recovery of the five therapeutic groups in the solid matrixes using ultrasonication- assisted techniques. The results show percentage recovery values ranging from 68.8 percent to 107.5 percent diaphian. According to the environmental risk assessment results, ibuprofen and triclosan were found to be the most critical compounds due to their high risk quotient values. These findings will, therefore, help in the future evaluation of the efficiency of different treatment technologies in the removal of various PPCPs from the wastewater and their sustainable management in the aquatic resources in Eastern Cape, South Africa. For the lipophilic organochlorine pesticides (OCPs), the limits of detection (LODs) of the tested congeners varied from 0.04 ng/g (α-BHC) to 0.49 ng/g (endosulfan sulfate) and the limits of quantification ranging from 0.22 ng/g (aldrin) to 2.17 ng/g (δ-BHC).
- Full Text:
- Date Issued: 2017
- Authors: Ademoyegun, Olufemi Temitope
- Date: 2017
- Subjects: Emerging contaminants in water -- South Africa -- Eastern Cape Water treatment plants -- Waste disposal -- South Africa -- Eastern Cape Organic compounds -- Environmental aspects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/2922 , vital:28138
- Description: Emerging organic contaminants (EOCs) have been the focus of global environmental research for over three decades. EOCs have caused widespread concern due to their extensive use. As EOCs were designed to correct, enhance or protect a specific physiological, their target effects in humans and/or farm stocks are relatively well known and documented. However, there is limited knowledge about their unintended effects in the environment. To address the occurrence, distribution and fate of EOCs in the environment, efficient and reliable analytical methods are needed. The relatively low concentration, high polarity, and thermal lability of some EOCs, together with their interaction with complex environmental matrices, make their analysis challenging. Sample preparation followed by GC or HPLC separation and mass spectrometry (MS) detection has become the standard approach for evaluating EOCs in environmental samples. Physicochemical properties of EOCs range from highly water-soluble (hydrophylic) to highly water-insoluble (hydrophobic). Two groups of these EOCs were considered for study in this work. Pharmaceutical and personal care products (PPCPs) were comprehensively studied in five wastewater treatment plants and their receiving watersheds in Amathole districts in Eastern C ape, South Africa. PPCPs have been widely reported in wastewater influents, effluents, receiving rivers and biosolids, but reports of their occurrence in all these matrixes have been limited by the difficulty of analysis. Therefore, a comprehensive validation of methods was carried out on the influents, effluents, sludge and soil from the irrigated golf course where the effluent of one of the study sites was being used for over three decades now for irrigation. In all, thirteen PPCPs from five therapeutic groups were selected for study in this work because of their administering rate and availability of analytical instrument. Good limit of detection (LOD) and limit of quantification (LOQ) were achieved for the method used. The LOD for the aqueous Three different technologies were employed for the treatment of wastewater in the five selected wastewater treatment plants (WWTPs) and study was carried out to evaluate their ability to eliminate the selected compounds from the influents to the effluents using statistical analysis (ANOVA) at p<0.05 on the percentage removal rate across the three plants. The results had shown eight of the compounds having no significant difference among the treatment operations, whereas the remaining five compounds varied significantly among the treatment technologies under investigation. Principal component analysis was performed on the concentration of PPCPs, their removal rate and also on the physicochemical and treatment operation parameters. Hydraulic retention time (HRT) had correlation coefficient, r = 0.90 with the concentration of PPCPs and removal rates. Furthermore, occurrences, seasonal variation, mean concentration distribution pattern of the compounds, and temporal evaluation of the mean concentration of the pharmaceutical compounds in the five WWTPs during one year of sampling were considered. The results revealed that five products which were diclofenac, ibuprofen, paracetamol, triclosan and diethyl toluamide (DDET) were predominant among the PPCPs in all the WWTPs. The removal efficiency was highest in caffeine with 96 percent, and the lowest was obtained with carbamazepine (4 percent). Risk quotient of the concentration of PPCPs in the effluents and receiving waters was determined to assess their chronic toxicity at three trophic levels: fish, algae and matrixes studied ranged from 0.01 μg/L to 0.25 μg/L, and the LOQ from 0.02 μg/L to 0.78 μg/L. In the solid matrixes, LOD varied from 0.01 ng/g to 0.65 ng/g, and the LOQ between 0.08 ng/g and 5.17 ng/g. Better recovery efficiency was obtained with this mixture of solvents, acetone: dichloromethane (1:1), for the recovery of the five therapeutic groups in the solid matrixes using ultrasonication- assisted techniques. The results show percentage recovery values ranging from 68.8 percent to 107.5 percent diaphian. According to the environmental risk assessment results, ibuprofen and triclosan were found to be the most critical compounds due to their high risk quotient values. These findings will, therefore, help in the future evaluation of the efficiency of different treatment technologies in the removal of various PPCPs from the wastewater and their sustainable management in the aquatic resources in Eastern Cape, South Africa. For the lipophilic organochlorine pesticides (OCPs), the limits of detection (LODs) of the tested congeners varied from 0.04 ng/g (α-BHC) to 0.49 ng/g (endosulfan sulfate) and the limits of quantification ranging from 0.22 ng/g (aldrin) to 2.17 ng/g (δ-BHC).
- Full Text:
- Date Issued: 2017
Evaluation of some pseudomonas species isolated from Hogsback forest reserve for the production of antibacterial compounds
- Authors: Mkono, Yonela Pelokazi
- Date: 2017
- Subjects: Bacteriology -- South Africa -- Eastern Cape Pseudomonas
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/5961 , vital:29458
- Description: Pseudomonas species are Gram-negative bacteria most abundant in soil and water bodies, with the capacity to thrive in varied environments. They are largely associated with resistant pathogenic bacteria linked to human and plant diseases. Species such as Pseudomonas aeruginosa have been particularly targeted as case studies due to the extremity to which they pose a threat to human health. With more focus directed at using these species for biocontrol and bioremediation purposes, their role in bioactive compound production may be equally important. As the crisis on antimicrobial resistance still persists, the need for effective antimicrobial compounds is ever more urgent and solutions may possibly still be dormant in bacterial species whose potential has not been fully investigated. On a bid to source out potential antimicrobial compound producers, soil samples were collected from Hogback forest reserve in the province of the Eastern Cape, South Africa. For bacterial screening, M1 and R2A agar were used and the cultures grown at 37˚C for a period of seven days. After the presumed Pseudomonas species were identified, antimicrobial production was determined by submerged fermentation method using nutrient broth as media of choice. Active isolates were further studied to determine the optimum conditions which best facilitate for antimicrobial compound production, with parameters such as temperature (25˚C – 40˚C) and pH (4 – 9) considered. The role plasmids play in antimicrobial compound production was also investigated. Each isolate was grown in fermentation media containing Sodium dodecyl sulphate and Ethedium Bromide, at varying concentrations, to facilitate for plasmid curing. With each sample, distinct colonies were identified with varying pigmentations most dominant being a cream colour. The identity of the isolated strains was achieved through sequencing of 16S rDNA. Phylogenetic analysis showed that isolate A16 had 80 percent homology with Pseudomonas plecoglossicida strain P4 and share a close ancestor with isolates Y52 and Y81, also isolate Y89 showed a 90 percent homology with Pseudomonas sp. Co-11a. With the exception of isolate A16, the isolates which were active against Gram-negative bacteria lost activity as the screening processes continued. When looking at temperature variations, isolates Y81 and A16 were highly active with maximum activity observed at 35˚C while Y89 performed best at 25˚C and Y52 showed constant activity across all studied temperatures. The plasmids in all isolates were found to be 48.5 kb in size with the exception of isolate Y89 which was 20 kb. The plasmids were cured at concentrations of (1 mg/ml; 5 mg/ml; 7 mg/ml; 10 mg/ml; 11 mg/ml) SDS and (125 μg/ml; 6.5 μg/ml; 5μg/ml) EtBr. The curing process also showed changes in both the antimicrobial activity of the isolates as well as their physical characteristics. The isolates are the first reported Pseudomonas species from Hogsback forest reserve with the ability to produce antimicrobial compounds which are active against Gram-positive and Gram-negative bacteria. These mesophilic bacteria also show that plasmids do not pay any role in the production of antimicrobial compounds and that the biosynthesis genes are highly likely to be chromosomal borne meaning that the production cannot be linked to horizontal transfer of genes. Therefore, these isolated Pseudomonas species provide a potential reservoir of antimicrobial compounds which may play an important role in the antimicrobial resistance phenomenon.
- Full Text:
- Date Issued: 2017
- Authors: Mkono, Yonela Pelokazi
- Date: 2017
- Subjects: Bacteriology -- South Africa -- Eastern Cape Pseudomonas
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/5961 , vital:29458
- Description: Pseudomonas species are Gram-negative bacteria most abundant in soil and water bodies, with the capacity to thrive in varied environments. They are largely associated with resistant pathogenic bacteria linked to human and plant diseases. Species such as Pseudomonas aeruginosa have been particularly targeted as case studies due to the extremity to which they pose a threat to human health. With more focus directed at using these species for biocontrol and bioremediation purposes, their role in bioactive compound production may be equally important. As the crisis on antimicrobial resistance still persists, the need for effective antimicrobial compounds is ever more urgent and solutions may possibly still be dormant in bacterial species whose potential has not been fully investigated. On a bid to source out potential antimicrobial compound producers, soil samples were collected from Hogback forest reserve in the province of the Eastern Cape, South Africa. For bacterial screening, M1 and R2A agar were used and the cultures grown at 37˚C for a period of seven days. After the presumed Pseudomonas species were identified, antimicrobial production was determined by submerged fermentation method using nutrient broth as media of choice. Active isolates were further studied to determine the optimum conditions which best facilitate for antimicrobial compound production, with parameters such as temperature (25˚C – 40˚C) and pH (4 – 9) considered. The role plasmids play in antimicrobial compound production was also investigated. Each isolate was grown in fermentation media containing Sodium dodecyl sulphate and Ethedium Bromide, at varying concentrations, to facilitate for plasmid curing. With each sample, distinct colonies were identified with varying pigmentations most dominant being a cream colour. The identity of the isolated strains was achieved through sequencing of 16S rDNA. Phylogenetic analysis showed that isolate A16 had 80 percent homology with Pseudomonas plecoglossicida strain P4 and share a close ancestor with isolates Y52 and Y81, also isolate Y89 showed a 90 percent homology with Pseudomonas sp. Co-11a. With the exception of isolate A16, the isolates which were active against Gram-negative bacteria lost activity as the screening processes continued. When looking at temperature variations, isolates Y81 and A16 were highly active with maximum activity observed at 35˚C while Y89 performed best at 25˚C and Y52 showed constant activity across all studied temperatures. The plasmids in all isolates were found to be 48.5 kb in size with the exception of isolate Y89 which was 20 kb. The plasmids were cured at concentrations of (1 mg/ml; 5 mg/ml; 7 mg/ml; 10 mg/ml; 11 mg/ml) SDS and (125 μg/ml; 6.5 μg/ml; 5μg/ml) EtBr. The curing process also showed changes in both the antimicrobial activity of the isolates as well as their physical characteristics. The isolates are the first reported Pseudomonas species from Hogsback forest reserve with the ability to produce antimicrobial compounds which are active against Gram-positive and Gram-negative bacteria. These mesophilic bacteria also show that plasmids do not pay any role in the production of antimicrobial compounds and that the biosynthesis genes are highly likely to be chromosomal borne meaning that the production cannot be linked to horizontal transfer of genes. Therefore, these isolated Pseudomonas species provide a potential reservoir of antimicrobial compounds which may play an important role in the antimicrobial resistance phenomenon.
- Full Text:
- Date Issued: 2017
Evaluation of the acceptability of ambulatory blood pressure monitoring in a semi-rural, Eastern Cape population
- Authors: Chiwanza, Farisai
- Date: 2017
- Language: English
- Type: text , Thesis , Masters , MPharm
- Identifier: http://hdl.handle.net/10962/59161 , vital:27447
- Description: Expected release date-April 2019
- Full Text:
- Date Issued: 2017
- Authors: Chiwanza, Farisai
- Date: 2017
- Language: English
- Type: text , Thesis , Masters , MPharm
- Identifier: http://hdl.handle.net/10962/59161 , vital:27447
- Description: Expected release date-April 2019
- Full Text:
- Date Issued: 2017
Evaluation of the physicochemical qualities and heavy metal regimes of the final effluents of some wastewater treatment facilties in Berlin, Alice and Bedford communities in the Eastern Cape, South Africa
- Authors: Agoro, Mojeed Adedoyin
- Date: 2017
- Subjects: Water -- Purification -- South Africa -- Eastern Cape Sewage -- Purification -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/5003 , vital:28924
- Description: Wastewater treatment facilities have been identified as potential source of surface water pollution worldwide. In this study, the physicochemical qualities and heavy metal (including Zinc, Cadmium, Iron, Lead and Copper) concentrations in the final effluents, as well as the reduction efficiencies of three municipal wastewater plants in the Eastern Cape, South Africa were evaluated from September 2015 to February 2016 using standard methods. Wastewater effluent and sludge samples were collected from the selected plants on monthly basis over a period of six months from September 2015 to February 2016. Standard analytical method (Atomic absorption spectroscopy [AAS]) was used to assess the concentration levels of heavy metals. The physicochemical parameters assessed include pH, Temperature, Total Dissolved Solid, Turbidity, Biochemical Oxygen Demand, Chemical Oxygen Demand, Alkalinity, Dissolved Oxygen, Free chlorine, Chloride, Sulphate, Phosphate, Ammonium and Electrical Conductivity. The results of the evaluation showed that temperature ranges from 19 to 36 °C, Electrical Conductivity from 60-1095 mS/m, Alkalinity from 2.6-20.9 mg/L, Nitrate from 0.24-26.5 mg/L, Nitrite from 0.01-90 mg/L, Phosphate from 0.02-5.12 mg/L, Ammonium from 0.06-112 mg/L, Sulphate from 3-72 mg/L, Chloride from 3.25-224 mg/L, Chemical Oxygen Demand from 17-394 mg/L and Turbidity from 1.96-715 NTU. Free chlorine concentrations and dissolved oxygen were within the recommended limits for most part of the sampling period and ranged between 0.17-0.48 mg/L and 0.19-21.9 mg/L respectively. The pH, Phosphate, Sulphate and Free chlorine were within acceptable limits while Electrical Conductivity, Temperature, Total Dissolved Solid, Turbidity, Chemical Oxygen Demand, Chloride, Ammonium, Nitrate and Nitrite were not within specified limits. The reduction efficiencies observed generally ranged between 43.9 and 100 percent at all sampling points while zinc and lead were not detected throughout the sampling period. Cadmium showed low reduction rate ranging from 0 to 11.7 percent, while the rate of Copper reduction ranged from 0 to25 percent in January and February 2016. Zinc, lead and cadmium were generally not detected in the sludge samples except in January and February which could be due to the prevailing atmospheric conditions during the sampling period. Cu and Fe were detected through the sampling months of the study. We conclude that these municipal sewage plants are sources of pollution to their receiving watersheds and threats to public and environmental health.
- Full Text:
- Date Issued: 2017
- Authors: Agoro, Mojeed Adedoyin
- Date: 2017
- Subjects: Water -- Purification -- South Africa -- Eastern Cape Sewage -- Purification -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/5003 , vital:28924
- Description: Wastewater treatment facilities have been identified as potential source of surface water pollution worldwide. In this study, the physicochemical qualities and heavy metal (including Zinc, Cadmium, Iron, Lead and Copper) concentrations in the final effluents, as well as the reduction efficiencies of three municipal wastewater plants in the Eastern Cape, South Africa were evaluated from September 2015 to February 2016 using standard methods. Wastewater effluent and sludge samples were collected from the selected plants on monthly basis over a period of six months from September 2015 to February 2016. Standard analytical method (Atomic absorption spectroscopy [AAS]) was used to assess the concentration levels of heavy metals. The physicochemical parameters assessed include pH, Temperature, Total Dissolved Solid, Turbidity, Biochemical Oxygen Demand, Chemical Oxygen Demand, Alkalinity, Dissolved Oxygen, Free chlorine, Chloride, Sulphate, Phosphate, Ammonium and Electrical Conductivity. The results of the evaluation showed that temperature ranges from 19 to 36 °C, Electrical Conductivity from 60-1095 mS/m, Alkalinity from 2.6-20.9 mg/L, Nitrate from 0.24-26.5 mg/L, Nitrite from 0.01-90 mg/L, Phosphate from 0.02-5.12 mg/L, Ammonium from 0.06-112 mg/L, Sulphate from 3-72 mg/L, Chloride from 3.25-224 mg/L, Chemical Oxygen Demand from 17-394 mg/L and Turbidity from 1.96-715 NTU. Free chlorine concentrations and dissolved oxygen were within the recommended limits for most part of the sampling period and ranged between 0.17-0.48 mg/L and 0.19-21.9 mg/L respectively. The pH, Phosphate, Sulphate and Free chlorine were within acceptable limits while Electrical Conductivity, Temperature, Total Dissolved Solid, Turbidity, Chemical Oxygen Demand, Chloride, Ammonium, Nitrate and Nitrite were not within specified limits. The reduction efficiencies observed generally ranged between 43.9 and 100 percent at all sampling points while zinc and lead were not detected throughout the sampling period. Cadmium showed low reduction rate ranging from 0 to 11.7 percent, while the rate of Copper reduction ranged from 0 to25 percent in January and February 2016. Zinc, lead and cadmium were generally not detected in the sludge samples except in January and February which could be due to the prevailing atmospheric conditions during the sampling period. Cu and Fe were detected through the sampling months of the study. We conclude that these municipal sewage plants are sources of pollution to their receiving watersheds and threats to public and environmental health.
- Full Text:
- Date Issued: 2017
Evaluation of the socio-economic performance of smallholder irrigation schemes in Idutywa Village of the Eastern Cape Province
- Authors: Jiba, Phiwe
- Date: 2017
- Subjects: Irrigation farming -- Economic aspects Farms, Small -- South Africa -- Eastern Cape Agricultural development projects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/4705 , vital:28497
- Description: South Africa and other African countries are faced with high levels of food insecurity and poverty levels as a result of slow growth of the macro economy and weak or sluggish rural development. Irrigation scheme development is seen as an important strategy to address the challenges faced by households in rural areas and restores growth and enhanced livelihoods. While the international experience shows that Irrigation schemes are potentially transformative of poor communities and have been operational for many years now, there is no marked improvement in living conditions of rural households in terms of livelihoods and income. This raises the question as to whether or not the schemes are viable from a socio-economic perspective and whether or not there are reasons for concern and revision of the policy framework for smallholder irrigation schemes. As a result of that, the broad objective of the study was to evaluate the contribution of smallholder irrigation schemes to household income and food security of rural households in Idutywa village of the Eastern Cape Province in South Africa. Specifically, this research investigated the major factors that influence their performance, impact of irrigation farming on rural livelihood and household food security as well as identifying the possible opportunities of production that would improve their performance. The study was carried out in Idutywa villages of the Eastern Cape Province in South Africa and employed survey data obtained from 107 households. The study employed a cross-sectional research design and the study employed stratified random sampling. The study made use of descriptive and inferential statistics to estimate the central tendency and dispersion as well as testing the hypothesis that there is a difference in the contribution between irrigators and non-irrigators using STATA and SPSS. Probit regression model was used to estimate factors that influenced the performance of smallholder irrigation schemes. The descriptive statistics employed included means, percentages and frequencies on the socio-economic characteristics of households in the study areas. The results show that females were dominant with a representation of 66.7 percent. The majority of households were aged and the mean age was 65 years. High level of illiteracy in the project area was revealed by the data. The average number of years, households spent in school was between 6 years to 10 years in school. Farming was found to be the major agricultural economic activity. Sixty-three (63 percent) were full time farmers. The results further show that household size ranges between 1 to 5 persons. The households were shown to be mostly dependent on social grant with household income hovering around R 1 000. The results from propensity score matching revealed that irrigation exerts a positive impact on household income. This provides sufficient evidence that irrigation schemes do make a contribution to rural livelihoods through their effect on household income and food security. This implies that government should continue investing in irrigation schemes as part of a strategy to grow the rural economy and improve rural livelihoods. This is in line with the Agricultural Policy Action Plan (APAP) and National Development Plan (NDP) of South Africa. Probit analysis suggests that age of the households, household size and market were some of the key determinants that positively influenced households’ decision to participate in smallholder irrigation schemes while access to credit had significant but negative effect on households’ decision to participate in smallholder irrigation schemes. Based on the findings highlighted above, it is recommended that addressing such barriers may create enabling conditions that would encourage households to access and participate more effectively in smallholder irrigation schemes.
- Full Text:
- Date Issued: 2017
- Authors: Jiba, Phiwe
- Date: 2017
- Subjects: Irrigation farming -- Economic aspects Farms, Small -- South Africa -- Eastern Cape Agricultural development projects -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/4705 , vital:28497
- Description: South Africa and other African countries are faced with high levels of food insecurity and poverty levels as a result of slow growth of the macro economy and weak or sluggish rural development. Irrigation scheme development is seen as an important strategy to address the challenges faced by households in rural areas and restores growth and enhanced livelihoods. While the international experience shows that Irrigation schemes are potentially transformative of poor communities and have been operational for many years now, there is no marked improvement in living conditions of rural households in terms of livelihoods and income. This raises the question as to whether or not the schemes are viable from a socio-economic perspective and whether or not there are reasons for concern and revision of the policy framework for smallholder irrigation schemes. As a result of that, the broad objective of the study was to evaluate the contribution of smallholder irrigation schemes to household income and food security of rural households in Idutywa village of the Eastern Cape Province in South Africa. Specifically, this research investigated the major factors that influence their performance, impact of irrigation farming on rural livelihood and household food security as well as identifying the possible opportunities of production that would improve their performance. The study was carried out in Idutywa villages of the Eastern Cape Province in South Africa and employed survey data obtained from 107 households. The study employed a cross-sectional research design and the study employed stratified random sampling. The study made use of descriptive and inferential statistics to estimate the central tendency and dispersion as well as testing the hypothesis that there is a difference in the contribution between irrigators and non-irrigators using STATA and SPSS. Probit regression model was used to estimate factors that influenced the performance of smallholder irrigation schemes. The descriptive statistics employed included means, percentages and frequencies on the socio-economic characteristics of households in the study areas. The results show that females were dominant with a representation of 66.7 percent. The majority of households were aged and the mean age was 65 years. High level of illiteracy in the project area was revealed by the data. The average number of years, households spent in school was between 6 years to 10 years in school. Farming was found to be the major agricultural economic activity. Sixty-three (63 percent) were full time farmers. The results further show that household size ranges between 1 to 5 persons. The households were shown to be mostly dependent on social grant with household income hovering around R 1 000. The results from propensity score matching revealed that irrigation exerts a positive impact on household income. This provides sufficient evidence that irrigation schemes do make a contribution to rural livelihoods through their effect on household income and food security. This implies that government should continue investing in irrigation schemes as part of a strategy to grow the rural economy and improve rural livelihoods. This is in line with the Agricultural Policy Action Plan (APAP) and National Development Plan (NDP) of South Africa. Probit analysis suggests that age of the households, household size and market were some of the key determinants that positively influenced households’ decision to participate in smallholder irrigation schemes while access to credit had significant but negative effect on households’ decision to participate in smallholder irrigation schemes. Based on the findings highlighted above, it is recommended that addressing such barriers may create enabling conditions that would encourage households to access and participate more effectively in smallholder irrigation schemes.
- Full Text:
- Date Issued: 2017
Evictions, migrations and epidemiology in Gokwe during the colonial era
- Authors: Mudzimu, Asa
- Date: 2017
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/6946 , vital:21203
- Description: Gokwe, being infested with tsetse and mosquito was seen as a ‘diseased’ environment by the Europeans. Thus, colonial anti-disease campaigns were introduced during the first decade of the 20th century. Initially, the campaigns sought to address economic challenges in the colony as they involved African relocations for the benefit of the Europeans. However, this study argues that these anti-disease campaigns were modified with time and space. The key thrust of the paper is to examine the imbrication between evictions, migrations and disease control in the context of colonial public health system. Apartfrom examining the development of Western medical practices in Gokwe the dissertation explores how this colonial public health system coalesced or clashed with African worldviews. Gokwe matters as a ‘frontier’ society in many senses. Given colonial efforts to occupy Gokwe and the influx of new evictees and migrants in the 1960s, the study depicts Gokwe as a frontier. The study sees evictions and displacements as programmes tailored to arrest tsetse and the associated diseases in the Zambezi Valley.
- Full Text:
- Date Issued: 2017
- Authors: Mudzimu, Asa
- Date: 2017
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/6946 , vital:21203
- Description: Gokwe, being infested with tsetse and mosquito was seen as a ‘diseased’ environment by the Europeans. Thus, colonial anti-disease campaigns were introduced during the first decade of the 20th century. Initially, the campaigns sought to address economic challenges in the colony as they involved African relocations for the benefit of the Europeans. However, this study argues that these anti-disease campaigns were modified with time and space. The key thrust of the paper is to examine the imbrication between evictions, migrations and disease control in the context of colonial public health system. Apartfrom examining the development of Western medical practices in Gokwe the dissertation explores how this colonial public health system coalesced or clashed with African worldviews. Gokwe matters as a ‘frontier’ society in many senses. Given colonial efforts to occupy Gokwe and the influx of new evictees and migrants in the 1960s, the study depicts Gokwe as a frontier. The study sees evictions and displacements as programmes tailored to arrest tsetse and the associated diseases in the Zambezi Valley.
- Full Text:
- Date Issued: 2017
Evidence for a biological control-induced regime shift between floating and submerged invasive plant dominance in South Africa
- Authors: Strange, Emily Frances
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/32448 , vital:24044
- Description: South Africa has a long history battling the establishment and spread of invasive floating macrophytes. The negative consequences of these are costly both economically and ecologically. They form dense mats on the water's surface that deplete resources such as light and oxygen to the submerged community, which creates anoxic conditions, reduces biodiversity and limits access to freshwater. The past thirty years of South African invasive plant research and the implementation of nationwide biological control programmes has led to widespread control of these species in many degraded systems. Such initiatives are aimed at restoring access to potable freshwater and increasing native biodiversity. However, in recent years, where there has been a decline in floating invasive plant populations, an increase in the establishment and spread of submerged invasive plant species has been observed. Species such as Brazilian waterweed (Egeria densa (Planch.) (Hydrocharitaceae)) and Eurasian watermilfoil (Myriophyllum spicatum (L.) (Haloragaceae)) have been recorded in South African freshwater systems, posing significant threats to aquatic ecosystems. This thesis proposes that the biological control of floating invasive plants, which occurs in numerous dams and rivers nationwide, is the catalyst of a regime shift from floating invasive to submerged invasive plant dominance. Regime shifts are large and often sudden changes in the key structure and functioning of ecosystems, and studies into their occurrence and driving mechanisms broadens understanding of community structures and can guide effective resource management. In order to explore the existence of this new regime shift, a multi-platform approach using controlled experiments and ecological modelling techniques was employed. A model system was created consisting of a floating invasive (Pistia stratiotes L. (Araceae)), a submerged invasive (E. densa) and an ecologically analogous submerged native plant species (Lagarosiphon major (Ridl.) Moss (Hydrocharitaceae)). A suite of experiments was conducted to explore the interactions between the floating and submerged plants under varying regimes of floating plant biological control and levels of nutrient loading. These experiments revealed a competitive advantage of the invasive E. densa over the native L. major that increased by 86% under heavy nutrient loading. The relative growth rate and accumulated biomass of E. densa was significantly higher for plants grown in the presence of biologically controlled P. stratiotes (compared to insect free plants). This demonstrates a high capacity for the invasive E. densa to capitalise on resources made newly available through the biological control of the floating plants. In contrast, the native L. major fared poorly when grown in the presence of the floating P. stratiotes, regardless of applied biological control measures. The experimental observations were then used to parameterise a mathematical model, built to provide a holistic understanding of the individually assessed interactions which work together as the driving mechanisms underpinning the newly identified regime shift. This thesis utilised a multi-platform approach to build the first body of evidence in support of a newly recognised regime shift between floating invasive and submerged invasive plant dominance, as driven by biological control. The results indicate that a reduction in the nutrient loading of South Africa's freshwater systems will reduce negative impacts of submerged invasive macrophytes, whilst increasing system resilience against future invasion. The evidence presented has the potential to better inform management of South Africa's freshwater systems and highlights the importance of integrating multi-trophic interactions when considering future invasive plant management. This research also opens up a multitude of possibilities for studies into submerged plant invasion mechanisms and resilience of native macrophyte communities in South Africa, and further afield.
- Full Text:
- Date Issued: 2017
- Authors: Strange, Emily Frances
- Date: 2017
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/32448 , vital:24044
- Description: South Africa has a long history battling the establishment and spread of invasive floating macrophytes. The negative consequences of these are costly both economically and ecologically. They form dense mats on the water's surface that deplete resources such as light and oxygen to the submerged community, which creates anoxic conditions, reduces biodiversity and limits access to freshwater. The past thirty years of South African invasive plant research and the implementation of nationwide biological control programmes has led to widespread control of these species in many degraded systems. Such initiatives are aimed at restoring access to potable freshwater and increasing native biodiversity. However, in recent years, where there has been a decline in floating invasive plant populations, an increase in the establishment and spread of submerged invasive plant species has been observed. Species such as Brazilian waterweed (Egeria densa (Planch.) (Hydrocharitaceae)) and Eurasian watermilfoil (Myriophyllum spicatum (L.) (Haloragaceae)) have been recorded in South African freshwater systems, posing significant threats to aquatic ecosystems. This thesis proposes that the biological control of floating invasive plants, which occurs in numerous dams and rivers nationwide, is the catalyst of a regime shift from floating invasive to submerged invasive plant dominance. Regime shifts are large and often sudden changes in the key structure and functioning of ecosystems, and studies into their occurrence and driving mechanisms broadens understanding of community structures and can guide effective resource management. In order to explore the existence of this new regime shift, a multi-platform approach using controlled experiments and ecological modelling techniques was employed. A model system was created consisting of a floating invasive (Pistia stratiotes L. (Araceae)), a submerged invasive (E. densa) and an ecologically analogous submerged native plant species (Lagarosiphon major (Ridl.) Moss (Hydrocharitaceae)). A suite of experiments was conducted to explore the interactions between the floating and submerged plants under varying regimes of floating plant biological control and levels of nutrient loading. These experiments revealed a competitive advantage of the invasive E. densa over the native L. major that increased by 86% under heavy nutrient loading. The relative growth rate and accumulated biomass of E. densa was significantly higher for plants grown in the presence of biologically controlled P. stratiotes (compared to insect free plants). This demonstrates a high capacity for the invasive E. densa to capitalise on resources made newly available through the biological control of the floating plants. In contrast, the native L. major fared poorly when grown in the presence of the floating P. stratiotes, regardless of applied biological control measures. The experimental observations were then used to parameterise a mathematical model, built to provide a holistic understanding of the individually assessed interactions which work together as the driving mechanisms underpinning the newly identified regime shift. This thesis utilised a multi-platform approach to build the first body of evidence in support of a newly recognised regime shift between floating invasive and submerged invasive plant dominance, as driven by biological control. The results indicate that a reduction in the nutrient loading of South Africa's freshwater systems will reduce negative impacts of submerged invasive macrophytes, whilst increasing system resilience against future invasion. The evidence presented has the potential to better inform management of South Africa's freshwater systems and highlights the importance of integrating multi-trophic interactions when considering future invasive plant management. This research also opens up a multitude of possibilities for studies into submerged plant invasion mechanisms and resilience of native macrophyte communities in South Africa, and further afield.
- Full Text:
- Date Issued: 2017
Evidence for rangewide panmixia despite multiple barriers to dispersal in a marine mussel
- Lourenço, Carla R, Nicastro, Katy R, McQuaid, Christopher D, Chefaoui, Rosa M, Assis, Jorge, Taleb, Mohammed Z, Zardi, Gerardo I
- Authors: Lourenço, Carla R , Nicastro, Katy R , McQuaid, Christopher D , Chefaoui, Rosa M , Assis, Jorge , Taleb, Mohammed Z , Zardi, Gerardo I
- Date: 2017
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59952 , vital:27714 , doi:10.1038/s41598-017-10753-9
- Description: Oceanographic features shape the distributional and genetic patterns of marine species by interrupting or promoting connections among populations. Although general patterns commonly arise, distributional ranges and genetic structure are species-specific and do not always comply with the expected trends. By applying a multimarker genetic approach combined with Lagrangian particle simulations (LPS) we tested the hypothesis that oceanographic features along northeastern Atlantic and Mediterranean shores influence dispersal potential and genetic structure of the intertidal mussel Perna perna. Additionally, by performing environmental niche modelling we assessed the potential and realized niche of P. perna along its entire native distributional range and the environmental factors that best explain its realized distribution. Perna perna showed evidence of panmixia across 4,000 km despite several oceanographic breaking points detected by LPS. This is probably the result of a combination of life history traits, continuous habitat availability and stepping-stone dynamics. Moreover, the niche modelling framework depicted minimum sea surface temperatures (SST) as the major factor shaping P. perna distributional range limits along its native areas. Forthcoming warming SST is expected to further change these limits and allow the species to expand its range polewards though this may be accompanied by retreat from warmer areas.
- Full Text:
- Date Issued: 2017
- Authors: Lourenço, Carla R , Nicastro, Katy R , McQuaid, Christopher D , Chefaoui, Rosa M , Assis, Jorge , Taleb, Mohammed Z , Zardi, Gerardo I
- Date: 2017
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59952 , vital:27714 , doi:10.1038/s41598-017-10753-9
- Description: Oceanographic features shape the distributional and genetic patterns of marine species by interrupting or promoting connections among populations. Although general patterns commonly arise, distributional ranges and genetic structure are species-specific and do not always comply with the expected trends. By applying a multimarker genetic approach combined with Lagrangian particle simulations (LPS) we tested the hypothesis that oceanographic features along northeastern Atlantic and Mediterranean shores influence dispersal potential and genetic structure of the intertidal mussel Perna perna. Additionally, by performing environmental niche modelling we assessed the potential and realized niche of P. perna along its entire native distributional range and the environmental factors that best explain its realized distribution. Perna perna showed evidence of panmixia across 4,000 km despite several oceanographic breaking points detected by LPS. This is probably the result of a combination of life history traits, continuous habitat availability and stepping-stone dynamics. Moreover, the niche modelling framework depicted minimum sea surface temperatures (SST) as the major factor shaping P. perna distributional range limits along its native areas. Forthcoming warming SST is expected to further change these limits and allow the species to expand its range polewards though this may be accompanied by retreat from warmer areas.
- Full Text:
- Date Issued: 2017
Evil and the Hero-Villain Binary in Deon Meyer’s Post-Apartheid Crime Thriller, Devil’s Peak:
- Naidu, Samantha, Van der Wielen, Karlien
- Authors: Naidu, Samantha , Van der Wielen, Karlien
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/157991 , vital:40137 , ISBN 9781498533423
- Description: The Functions of Evil Across Disciplinary Contexts explores answers to two important questions about the age-old theme of evil: is there any use in using the concept of evil in cultural, psychological, or other secular evaluations of the world and its productions? Most importantly, if there is, what might these functions be? By looking across several disciplines and analyzing evil as it is referenced across a broad spectrum of phenomena, this work demonstrates the varying ways that we interact with the ethical dilemma as academics, as citizens, and as people. The work draws from authors in different fields—including history, literary and film studies, philosophy, and psychology—and from around the world to provide an analysis of evil in such topics as deeply canonical as Beowulf and Shakespeare to subjects as culturally resonant as Stephen King, Captain America, or the War on Terror. By bringing together this otherwise disparate collection of scholarship, this collection reveals that discussions of evil across disciplines have always been questions of how cultures represent that which they find socially abhorrent. This work thus opens the conversation about evil outside of field-specific limitations, simultaneously demonstrating the assumptions that undergird the manner by which such a conversation proceeds.
- Full Text:
- Date Issued: 2017
- Authors: Naidu, Samantha , Van der Wielen, Karlien
- Date: 2017
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/157991 , vital:40137 , ISBN 9781498533423
- Description: The Functions of Evil Across Disciplinary Contexts explores answers to two important questions about the age-old theme of evil: is there any use in using the concept of evil in cultural, psychological, or other secular evaluations of the world and its productions? Most importantly, if there is, what might these functions be? By looking across several disciplines and analyzing evil as it is referenced across a broad spectrum of phenomena, this work demonstrates the varying ways that we interact with the ethical dilemma as academics, as citizens, and as people. The work draws from authors in different fields—including history, literary and film studies, philosophy, and psychology—and from around the world to provide an analysis of evil in such topics as deeply canonical as Beowulf and Shakespeare to subjects as culturally resonant as Stephen King, Captain America, or the War on Terror. By bringing together this otherwise disparate collection of scholarship, this collection reveals that discussions of evil across disciplines have always been questions of how cultures represent that which they find socially abhorrent. This work thus opens the conversation about evil outside of field-specific limitations, simultaneously demonstrating the assumptions that undergird the manner by which such a conversation proceeds.
- Full Text:
- Date Issued: 2017
Evolution of Fe-Ti-V oxides from the main magnetite layer, Upper Zone, Bushveld Complex, South Africa: a comparison across the Western, Northern and Eastern Lobes
- Authors: Iorga-Pavel, Adina
- Date: 2017
- Subjects: Magnetite -- South Africa -- Bushveld Complex , Mineralogy -- South Africa -- Bushveld Complex , Oxides
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/7357 , vital:21248
- Description: The Main Magnetite Layer (MML) from the Northern, Eastern and Western lobes of the Bushveld Complex shows significant differences in textures and in mineral chemistry. The MML in the Eastern and Western lobes is massive, with rare, small and altered pyroxene inclusions. By contrast, the MML in the Northern Lobe is more heterogeneous, and it is made of anastomosed and sometimes imbricated, thin layers of magnetitite, magnetite-rich and silicate-rich rocks, where the inclusions in Ti-magnetite are more numerous and consist of mainly altered subhedral and anhedral plagioclase. The comparison of the maximum values of the oxides shows that the MML in the Northern Lobe has the highest content of V2O3 (1.97 wt%), TiO2 (22.49 wt%) and MgO (2.92 wt%), while the MML in the Eastern Lobe has the highest content of Cr2O3 (2.92 wt%) and Al2O3 (9.80 wt%), but lowest V2O3 (0.52 wt%). The lower TiO2 content and higher V2O3 content in the MML of the Northern and Western Lobes suggest lower oxidising conditions during the crystallization of oxides. The MML in all three studied lobes consists of two layers of magnetitite, suggesting that MML was formed by two separate magma influxes, probably on a diverse and complex type of magma chamber floor. The high TiO2 content in magnetite, together with the negative correlation between TiO2 and V2O3 suggest that the maximum V content should represent a “less evolved” and less oxidized melt. In this respect, higher concentrations V2O3 in magnetite can be expected in magnetitite layers with lower TiO2. It can be inferred that the Ti-magetite in the MML from the Eastern Lobe was formed from a more evolved (TiO2 and FeO enriched) and more oxidized (lower V2O3) melt, compared with the MML from the Northern and Western lobes. These findings can be used to illustrate: a) that high fO2 can be responsible for the relatively low V content in magnetite from Fe-Ti oxide ores and b) the vanadium in magnetite decreases significantly in more evolved cumulates, due to a decreasing fO2 with differentiation. Compositional profiles of Ti- magnetite along the stratigraphic height of the MML in the Eastern Lobe (composed of two layers, separated in the outcrop by a parting plane) depicts a cryptic variation with depth in each of the two layers, where each layer can be divided into four sublayers, labelled upwards as A, B, C (with C1, C2, C3 and C4) and D based on Cr, Mg, Ti, Al and V variation. Small scale reversals of the mentioned elements and the repetition of A, B, C and D sub-layers in each layer suggest that MML formed from two successive influxes of magma (indicated by relatively elevated values of MgO), which evolved by crystallization and cooling in a similar manner, to produce the A to D variation. Based on these observations and theoretical considerations, this study dismisses several models for the genesis of the MML: the immiscibility, the increased oxygen fugacity, the relative increase of H2O content of the melt, pressure variation within the magma chamber, magma mixing, and crustal rock contamination. The model proposed here for MML genesis involves the crystallization of both Ti-magnetite and ilmenite from a Fe-Ti-Ca-Al-rich melt (ferro-diorite) along its line of descent, and gravitational settling of oxides in a dynamic regime. The factor which triggered the crystallization of magnetite is a critical saturation of melt in magnetite (attaining saturation of magnetite and ilmenite in the melt after some silicates crystallized). The difference between the nature of silicate inclusions in magnetite and the nature of the magnetite floor, suggest that the Fe-rich magma was not in equilibrium with the cumulates from the present floor, but rather it was emplaced laterally on long distances, the melt being disrupted from its own cumulates. The absence of correlation between the Cr2O3 in magnetite and co-existing ilmenite can indicate than no in-situ fractional crystallization took place at the moment of magnetite accumulation, but rather that magnetite and ilmenite gravitationally accumulated and the grains mechanically mixed from a flowing magma. The model presented herein proposes a five stage model of MML formation: Stage 1 is represented by the intrusion of a Fe-T-Ca-Al-rich magma which expands laterally within a flat and thin magma chamber. Oxides start to crystallize within a dynamic regime of the magma. Stage 2 is given by the accumulation of oxides at the bottom of the new floor. Some plagioclase starts to crystallize (e.g. subhedral plagioclase in the MML of the Northern Lobe). Stage 3 is a short living static regime, where both plagioclase and magnetite crystallized, without fractionation, forming the thin magnetite-anorthosite layer separating the MML into two layers. Stage 4 is represented by a new influx of Fe-Ti-Ca-Al-rich magma which is emplaced above the magnetite-bearing anorthosite, flushing out the liquid which was in equilibrium with the anorthosite. The oxides started crystallizing in a dynamic regime, as in Stage 1. In stage 5, the accumulation of oxides produced the upper layer of the MML. Our interpretation is that the flow of the magma was more dynamic (probably more turbulent on long distances) in the MML of the Northern Lobe, compared to the MML in the Western and Eastern lobes, producing highly heterogeneous and imbricated thin layers of magnetitite and silicates. The presence of olivine corona around orthopyroxene suggests the incongruent melting of orthopyroxene, which points out towards a local re-heating of existing silicate layers, this being a strong argument for multiple injections in generation of MML. Massive crystallization of oxides produced the sulphur saturation of the magma and caused the precipitation of the igneous sulphides, which nucleated on the existing oxides. Later hydrothermal fluids (and/or late magmatic volatiles?) percolated the MML, producing chloritization of the included silicates, remobilization of igneous sulphides and precipitation of hydrothermal sulphides.
- Full Text:
- Date Issued: 2017
- Authors: Iorga-Pavel, Adina
- Date: 2017
- Subjects: Magnetite -- South Africa -- Bushveld Complex , Mineralogy -- South Africa -- Bushveld Complex , Oxides
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/7357 , vital:21248
- Description: The Main Magnetite Layer (MML) from the Northern, Eastern and Western lobes of the Bushveld Complex shows significant differences in textures and in mineral chemistry. The MML in the Eastern and Western lobes is massive, with rare, small and altered pyroxene inclusions. By contrast, the MML in the Northern Lobe is more heterogeneous, and it is made of anastomosed and sometimes imbricated, thin layers of magnetitite, magnetite-rich and silicate-rich rocks, where the inclusions in Ti-magnetite are more numerous and consist of mainly altered subhedral and anhedral plagioclase. The comparison of the maximum values of the oxides shows that the MML in the Northern Lobe has the highest content of V2O3 (1.97 wt%), TiO2 (22.49 wt%) and MgO (2.92 wt%), while the MML in the Eastern Lobe has the highest content of Cr2O3 (2.92 wt%) and Al2O3 (9.80 wt%), but lowest V2O3 (0.52 wt%). The lower TiO2 content and higher V2O3 content in the MML of the Northern and Western Lobes suggest lower oxidising conditions during the crystallization of oxides. The MML in all three studied lobes consists of two layers of magnetitite, suggesting that MML was formed by two separate magma influxes, probably on a diverse and complex type of magma chamber floor. The high TiO2 content in magnetite, together with the negative correlation between TiO2 and V2O3 suggest that the maximum V content should represent a “less evolved” and less oxidized melt. In this respect, higher concentrations V2O3 in magnetite can be expected in magnetitite layers with lower TiO2. It can be inferred that the Ti-magetite in the MML from the Eastern Lobe was formed from a more evolved (TiO2 and FeO enriched) and more oxidized (lower V2O3) melt, compared with the MML from the Northern and Western lobes. These findings can be used to illustrate: a) that high fO2 can be responsible for the relatively low V content in magnetite from Fe-Ti oxide ores and b) the vanadium in magnetite decreases significantly in more evolved cumulates, due to a decreasing fO2 with differentiation. Compositional profiles of Ti- magnetite along the stratigraphic height of the MML in the Eastern Lobe (composed of two layers, separated in the outcrop by a parting plane) depicts a cryptic variation with depth in each of the two layers, where each layer can be divided into four sublayers, labelled upwards as A, B, C (with C1, C2, C3 and C4) and D based on Cr, Mg, Ti, Al and V variation. Small scale reversals of the mentioned elements and the repetition of A, B, C and D sub-layers in each layer suggest that MML formed from two successive influxes of magma (indicated by relatively elevated values of MgO), which evolved by crystallization and cooling in a similar manner, to produce the A to D variation. Based on these observations and theoretical considerations, this study dismisses several models for the genesis of the MML: the immiscibility, the increased oxygen fugacity, the relative increase of H2O content of the melt, pressure variation within the magma chamber, magma mixing, and crustal rock contamination. The model proposed here for MML genesis involves the crystallization of both Ti-magnetite and ilmenite from a Fe-Ti-Ca-Al-rich melt (ferro-diorite) along its line of descent, and gravitational settling of oxides in a dynamic regime. The factor which triggered the crystallization of magnetite is a critical saturation of melt in magnetite (attaining saturation of magnetite and ilmenite in the melt after some silicates crystallized). The difference between the nature of silicate inclusions in magnetite and the nature of the magnetite floor, suggest that the Fe-rich magma was not in equilibrium with the cumulates from the present floor, but rather it was emplaced laterally on long distances, the melt being disrupted from its own cumulates. The absence of correlation between the Cr2O3 in magnetite and co-existing ilmenite can indicate than no in-situ fractional crystallization took place at the moment of magnetite accumulation, but rather that magnetite and ilmenite gravitationally accumulated and the grains mechanically mixed from a flowing magma. The model presented herein proposes a five stage model of MML formation: Stage 1 is represented by the intrusion of a Fe-T-Ca-Al-rich magma which expands laterally within a flat and thin magma chamber. Oxides start to crystallize within a dynamic regime of the magma. Stage 2 is given by the accumulation of oxides at the bottom of the new floor. Some plagioclase starts to crystallize (e.g. subhedral plagioclase in the MML of the Northern Lobe). Stage 3 is a short living static regime, where both plagioclase and magnetite crystallized, without fractionation, forming the thin magnetite-anorthosite layer separating the MML into two layers. Stage 4 is represented by a new influx of Fe-Ti-Ca-Al-rich magma which is emplaced above the magnetite-bearing anorthosite, flushing out the liquid which was in equilibrium with the anorthosite. The oxides started crystallizing in a dynamic regime, as in Stage 1. In stage 5, the accumulation of oxides produced the upper layer of the MML. Our interpretation is that the flow of the magma was more dynamic (probably more turbulent on long distances) in the MML of the Northern Lobe, compared to the MML in the Western and Eastern lobes, producing highly heterogeneous and imbricated thin layers of magnetitite and silicates. The presence of olivine corona around orthopyroxene suggests the incongruent melting of orthopyroxene, which points out towards a local re-heating of existing silicate layers, this being a strong argument for multiple injections in generation of MML. Massive crystallization of oxides produced the sulphur saturation of the magma and caused the precipitation of the igneous sulphides, which nucleated on the existing oxides. Later hydrothermal fluids (and/or late magmatic volatiles?) percolated the MML, producing chloritization of the included silicates, remobilization of igneous sulphides and precipitation of hydrothermal sulphides.
- Full Text:
- Date Issued: 2017
Evolution of foraging behaviour: Deep intra-generic genetic divergence between territorial and non-territorial southern African patellid limpets
- Mmonwa, Kolobe L, Teske, Peter R, McQuaid, Christopher D, Barker, Nigel P
- Authors: Mmonwa, Kolobe L , Teske, Peter R , McQuaid, Christopher D , Barker, Nigel P
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/444798 , vital:74299 , https://doi.org/10.1016/j.ympev.2017.05.024
- Description: Southern Africa is a biodiversity hotspot of patellid limpets, with three genera (Helcion, Cymbula and Scutellastra) identified and described in the region. Scutellastra is the most diverse and most frequently studied of these and, along with Cymbula, includes species with territorial and non-territorial foraging behaviours. We used three mitochondrial markers (12S rRNA, 16S rRNA and COI) and one nuclear marker (ATPSβ intron) to assess evolutionary relationships among species of Cymbula and Scutellastra with these two foraging behaviours and to identify which foraging mode is the more ancient. Maximum Likelihood and Bayesian Inference phylogenetic analyses revealed that the species sharing a foraging type are monophyletic in both genera. Territoriality is a derived character, as the clades with this foraging type are nested within a tree that otherwise comprises non-territorial taxa. These include Helcion, which was recovered as sister to the Cymbula/Scutellastra clade, and the next basal genus, Patella, which is ancestral to all southern African patellogastropods. Deep genetic divergence between the two foraging traits reflects strong adaptive effects of resource partitioning in the evolution of southern African patellid limpets.
- Full Text:
- Date Issued: 2017
- Authors: Mmonwa, Kolobe L , Teske, Peter R , McQuaid, Christopher D , Barker, Nigel P
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/444798 , vital:74299 , https://doi.org/10.1016/j.ympev.2017.05.024
- Description: Southern Africa is a biodiversity hotspot of patellid limpets, with three genera (Helcion, Cymbula and Scutellastra) identified and described in the region. Scutellastra is the most diverse and most frequently studied of these and, along with Cymbula, includes species with territorial and non-territorial foraging behaviours. We used three mitochondrial markers (12S rRNA, 16S rRNA and COI) and one nuclear marker (ATPSβ intron) to assess evolutionary relationships among species of Cymbula and Scutellastra with these two foraging behaviours and to identify which foraging mode is the more ancient. Maximum Likelihood and Bayesian Inference phylogenetic analyses revealed that the species sharing a foraging type are monophyletic in both genera. Territoriality is a derived character, as the clades with this foraging type are nested within a tree that otherwise comprises non-territorial taxa. These include Helcion, which was recovered as sister to the Cymbula/Scutellastra clade, and the next basal genus, Patella, which is ancestral to all southern African patellogastropods. Deep genetic divergence between the two foraging traits reflects strong adaptive effects of resource partitioning in the evolution of southern African patellid limpets.
- Full Text:
- Date Issued: 2017