Adol-Safety: A Framework for Empowering Parents to be Aware of Social Network Threats Affecting Adolescents
- Mjoli, Phumelela, Shibeshi, Z
- Authors: Mjoli, Phumelela , Shibeshi, Z
- Date: 2020
- Subjects: Social networks Social media|
- Language: English
- Type: Thesis , Masters , MSc (Computer Science )
- Identifier: http://hdl.handle.net/10353/12016 , vital:39127
- Description: The use of social networks has grown so much that adolescents have become active members of various social networks such as Twitter, Facebook, and Instagram, etc. The gradual change in how people choose to communicate, socialize and share ideas today has influenced adolescents to an extent that they find themselves wanting to engage more on social networks than they really should due to peer pressure. Whenever a person joins social networks or browses the Internet, they by default are exposed and become vulnerable to many cyber threats. Cyber threats are driven by users that have negative intentions on the Internet or social networks. Adolescents are no exception to these cyber threats. The findings of this research reveal that threats such as cyberbullying, harassment, and online predators to name a few are often designed to abuse and affect adolescents). Therefore, this research aims to prevent such threats from prevailing by empowering parents to be aware of the threats that affect their adolescents in an online environment, which typically includes social networks. To achieve this, this research starts by investigating the cyber threats that affect adolescents and then explores ways that can be used to empower parents. A framework is developed to handle this. The framework includes strategies that parents can adopt and ways in which safety on social networks can be increased, as well as guidelines that can be followed in order to prevent cyber threats. The framework also aims to enhance a parent-child relationship that can help in preventing social network threats. Lastly, the framework is implemented as a knowledgesharing website that can be used by parents to receive and give an insight into social network threats that influence adolescents on social networks.
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- Authors: Mjoli, Phumelela , Shibeshi, Z
- Date: 2020
- Subjects: Social networks Social media|
- Language: English
- Type: Thesis , Masters , MSc (Computer Science )
- Identifier: http://hdl.handle.net/10353/12016 , vital:39127
- Description: The use of social networks has grown so much that adolescents have become active members of various social networks such as Twitter, Facebook, and Instagram, etc. The gradual change in how people choose to communicate, socialize and share ideas today has influenced adolescents to an extent that they find themselves wanting to engage more on social networks than they really should due to peer pressure. Whenever a person joins social networks or browses the Internet, they by default are exposed and become vulnerable to many cyber threats. Cyber threats are driven by users that have negative intentions on the Internet or social networks. Adolescents are no exception to these cyber threats. The findings of this research reveal that threats such as cyberbullying, harassment, and online predators to name a few are often designed to abuse and affect adolescents). Therefore, this research aims to prevent such threats from prevailing by empowering parents to be aware of the threats that affect their adolescents in an online environment, which typically includes social networks. To achieve this, this research starts by investigating the cyber threats that affect adolescents and then explores ways that can be used to empower parents. A framework is developed to handle this. The framework includes strategies that parents can adopt and ways in which safety on social networks can be increased, as well as guidelines that can be followed in order to prevent cyber threats. The framework also aims to enhance a parent-child relationship that can help in preventing social network threats. Lastly, the framework is implemented as a knowledgesharing website that can be used by parents to receive and give an insight into social network threats that influence adolescents on social networks.
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The effect of social capital on the performance of Small, Medium and Micro Enterprises (SMMES) in Makana Municipality
- Authors: Klaas, Anesipho
- Date: 2020
- Subjects: Small business Entrepreneurship
- Language: English
- Type: Thesis , Masters , MCom (Business Management)
- Identifier: http://hdl.handle.net/10353/12373 , vital:39258
- Description: The small, medium and micro-enterprises (SMMEs) are essential drivers to the social and economic growth. These enterprises have an essential role in employment creation and eradication of poverty in South Africa. SMMEs in South Africa are comprised of heterogeneous groups of businesses in various sectors including services, manufacturing and agriculture. This study investigated the effect of social capital on the performance of SMMEs. Thus, the primary objective of the study was is to investigate the impact of social capital on the performance of SMMEs in Makana Municipality, and the secondary objectives were to determine the effect of bonding social capital on the performance of SMMEs and determine the effect of bridging social capital on the performance of SMMEs. This study discovered that all three forms of social capital, namely: bonding, bridging and linking social capital have a positive effect on the performance of SMMEs. In order to collect data, the researcher distributed questionnaires to the sampled SMMEs in the towns within the Makana Municipality. All the questionnaires were completed by the respondents. The researcher did not interfere in this process but helped where necessary. Prior to the distribution of questionnaires, validity and reliability were ensured in order to eliminate problems in the questionnaires. A total of 126 questionnaires were distributed. To scale the responses in the questionnaires, Likert scale was used in this study. The sections in questionnaires were measuring the extent to which social capital contributes to the performance of SMMEs. Of the 126 questionnaires that were distributed, only 98 questionnaires were returned and used in this study. Thus, the response rate was 71% which is high. Because social capital affects the performance of SMMEs, this proves further the need for government to support these businesses. This study made a theoretical contribution to the literature on social capital and its important on the performance of SMMEs. The researcher recommends that all SMMEs across the world consider the effect of social capital on their performance. Given the importance of successful SMMEs in the growth of the country’s economy and, also the role they play in addressing the unemployment problem, it is recommended that all SMMEs consider the positive impact of social capital in their growth.
- Full Text:
- Authors: Klaas, Anesipho
- Date: 2020
- Subjects: Small business Entrepreneurship
- Language: English
- Type: Thesis , Masters , MCom (Business Management)
- Identifier: http://hdl.handle.net/10353/12373 , vital:39258
- Description: The small, medium and micro-enterprises (SMMEs) are essential drivers to the social and economic growth. These enterprises have an essential role in employment creation and eradication of poverty in South Africa. SMMEs in South Africa are comprised of heterogeneous groups of businesses in various sectors including services, manufacturing and agriculture. This study investigated the effect of social capital on the performance of SMMEs. Thus, the primary objective of the study was is to investigate the impact of social capital on the performance of SMMEs in Makana Municipality, and the secondary objectives were to determine the effect of bonding social capital on the performance of SMMEs and determine the effect of bridging social capital on the performance of SMMEs. This study discovered that all three forms of social capital, namely: bonding, bridging and linking social capital have a positive effect on the performance of SMMEs. In order to collect data, the researcher distributed questionnaires to the sampled SMMEs in the towns within the Makana Municipality. All the questionnaires were completed by the respondents. The researcher did not interfere in this process but helped where necessary. Prior to the distribution of questionnaires, validity and reliability were ensured in order to eliminate problems in the questionnaires. A total of 126 questionnaires were distributed. To scale the responses in the questionnaires, Likert scale was used in this study. The sections in questionnaires were measuring the extent to which social capital contributes to the performance of SMMEs. Of the 126 questionnaires that were distributed, only 98 questionnaires were returned and used in this study. Thus, the response rate was 71% which is high. Because social capital affects the performance of SMMEs, this proves further the need for government to support these businesses. This study made a theoretical contribution to the literature on social capital and its important on the performance of SMMEs. The researcher recommends that all SMMEs across the world consider the effect of social capital on their performance. Given the importance of successful SMMEs in the growth of the country’s economy and, also the role they play in addressing the unemployment problem, it is recommended that all SMMEs consider the positive impact of social capital in their growth.
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Physiological traits, anthropometric characteristics and motor development of rural children in Nkonkobe Municipality, South Africa
- Authors: Idamokoro, Mere
- Date: 2018
- Subjects: Motor learning Children -- Physiology Children -- Anthropometry -- South Africa
- Language: English
- Type: Thesis , Masters , Human Movement Science
- Identifier: http://hdl.handle.net/10353/10061 , vital:35314
- Description: Aim: The purpose of this study was to examine the physiological, anthropometric and motor development characteristics of rural children between the ages of 5 – 7 years old. Methods: The study involved 305 school children (159 boys and 146 girls) randomly selected from primary schools in Alice sub-district, Nkonkobe Municipality. Body weight, height, skinfold thickness and girth measurements were measured using standard procedures. Overweight and obesity were defined using body mass index (BMI) for age and gender. Derived variables were: fat mass, fat-free mass, fat mass index, fat-free mass index, waist-to-hip ratio, waist-to-height ratio and subscapular-to-triceps ratio. Motor development levels were measured and assessed using Test of Gross Motor Development –Second Edition (TGMD-2). Blood pressure was measured using aneroid sphygmomanometer. Results: Boys had higher mean values of blood pressure (69.19 ± 7.30 and 38.15 ± 5.91) compared to girls (68.39 ± 7.97 and 37.11 ± 7.53). The proportion of overweight among girls (15.75 percent) was higher compared to boys (10.69 percent). Likewise, the percentage of obesity among boys (16.35 percent) was higher compared to girls (10.27 percent). The motor development results showed that girls (40.9 ± 6.54) performed better than boys (39.7 ± 6.64) in locomotor skills test. Conversely, boys (39.8 ± 7.62) performed better than girls (38.6 ± 7.29) in object control. Conclusion: The prevalence of overweight and obesity among the children is alarmingly high and concerning for the health. At all ages, girls had higher body fat percentage and fat mass than the boys. However, FFMI and WHR were higher in boys compared to the girls. There is no gender difference in the waist-to-height ratio and STR of both boys and girls. The locomotor raw score is higher in girls than in boys; however, the object control raw score is higher in boys compared to girls. The non-correlation of BMI with TGMD-2 tests suggests an equal potential of motor development among the children, regardless of their body fatness. There is need for obesity prevention programme in schools, which should involve all the stakeholders (teachers, parents/guardians, government, NGOs). The programme should focus on creating awareness concerning child body weight, healthy dietary intake and regular BMI screening in schools.
- Full Text:
- Authors: Idamokoro, Mere
- Date: 2018
- Subjects: Motor learning Children -- Physiology Children -- Anthropometry -- South Africa
- Language: English
- Type: Thesis , Masters , Human Movement Science
- Identifier: http://hdl.handle.net/10353/10061 , vital:35314
- Description: Aim: The purpose of this study was to examine the physiological, anthropometric and motor development characteristics of rural children between the ages of 5 – 7 years old. Methods: The study involved 305 school children (159 boys and 146 girls) randomly selected from primary schools in Alice sub-district, Nkonkobe Municipality. Body weight, height, skinfold thickness and girth measurements were measured using standard procedures. Overweight and obesity were defined using body mass index (BMI) for age and gender. Derived variables were: fat mass, fat-free mass, fat mass index, fat-free mass index, waist-to-hip ratio, waist-to-height ratio and subscapular-to-triceps ratio. Motor development levels were measured and assessed using Test of Gross Motor Development –Second Edition (TGMD-2). Blood pressure was measured using aneroid sphygmomanometer. Results: Boys had higher mean values of blood pressure (69.19 ± 7.30 and 38.15 ± 5.91) compared to girls (68.39 ± 7.97 and 37.11 ± 7.53). The proportion of overweight among girls (15.75 percent) was higher compared to boys (10.69 percent). Likewise, the percentage of obesity among boys (16.35 percent) was higher compared to girls (10.27 percent). The motor development results showed that girls (40.9 ± 6.54) performed better than boys (39.7 ± 6.64) in locomotor skills test. Conversely, boys (39.8 ± 7.62) performed better than girls (38.6 ± 7.29) in object control. Conclusion: The prevalence of overweight and obesity among the children is alarmingly high and concerning for the health. At all ages, girls had higher body fat percentage and fat mass than the boys. However, FFMI and WHR were higher in boys compared to the girls. There is no gender difference in the waist-to-height ratio and STR of both boys and girls. The locomotor raw score is higher in girls than in boys; however, the object control raw score is higher in boys compared to girls. The non-correlation of BMI with TGMD-2 tests suggests an equal potential of motor development among the children, regardless of their body fatness. There is need for obesity prevention programme in schools, which should involve all the stakeholders (teachers, parents/guardians, government, NGOs). The programme should focus on creating awareness concerning child body weight, healthy dietary intake and regular BMI screening in schools.
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Ruthenium (II) complexes of mixed bipyridyl and dithiolate/thiourea ligands :|bsynthesis, characterization, photophysical and electrochemical studies
- Authors: Nkombi, Pelokazi
- Date: 2018
- Subjects: Ruthenium Ruthenium compounds Ligands
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/10134 , vital:35358
- Description: Energy is one of the most important factor to influence human lives. The increased in energy demand as well as the detrimental effects posed by emission of greenhouse gases due to continue use of fossil fuels for electricity generation has led to a renewed focus on energy production using renewable energy sources which are relatively cheap, clean and environmentally sustainable. Among the various renewable energy sources used so far, the Dye Synthesized Solar Cells (DSSCs), a form of photovoltaic device is reported for their better efficiencies despite their low cost of production and ability to work relatively under low light conditions. A recent report on the solar-to-electricity conversion efficiency of a typical DSSC sensitizer made from zinc based porphyrin dye coupled with sintered titanium(IV) oxide as semiconductor was 13 percent. In this study, 2,2-bipyridyl-4,4-dicarboxylic acid (bpydc) was used as mixed ligand and four dithiolate ligands; L1 = dipotassium ethoxycarbonyl-1-cyanoethylene-2,2-dithiolate, L2 = dipotassium bis(ethoxycarbonyl)ethane-2,2-dithiolate, L3 = dipotassium cyanodithio imidocarbonate and L4 = dipotassium 2,2-dicyanoethylene-2,2-dithiolate were synthesized while four alkyl thiourea ligands, L5 = 1,3-dimethyl thiourea, L6 = 1,3-diethyl thiourea, L7 = 1,3-diisopropyl thiourea and L8 = 1-methyl thiourea were purchased and used as supplied without further purification. These ligands were used to prepare eight ruthenium(II) complexes of mixed bipyridyl/dithiolate/thiourea. The compounds were characterised by elemental analysis and spectroscopic techniques, namely: Fourier transform infrared (FTIR), Nuclear Magnetic Resonance (NMR), ultraviolet-visible and photoluminescence (PL). Cyclic voltammetry (CV) and square wave voltammetry (SWV) were used for the electrochemical studies. Photoluminescence and UV-Vis spectroscopies were used for geometric and photophysical studies of the complexes respectively. FTIR spectra confirmed presence of functional groups in ligands and coordination of these ligands to ruthenium(II) ions to form complexes. The UV-Vis confirmed that the Ru(II) dithiolene complexes exhibited square planar geometries while the Ru(II) thiourea complexes gave octahedral geometries, this was deduced from the transitions assigned to the complexes. All the ruthenium(II) complexes synthesized showed photoluminescence properties that are suitable for light harvesting and application for dye-sensitized solar cells. Cyclic and square wave voltammetry show Ru(II) thiourea complexes have better redox properties when compared to Ru(II) dithiolate complexes which is ascribed to ligand strength field possibly due to contribution from the two bonded NCS groups.
- Full Text:
- Authors: Nkombi, Pelokazi
- Date: 2018
- Subjects: Ruthenium Ruthenium compounds Ligands
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/10134 , vital:35358
- Description: Energy is one of the most important factor to influence human lives. The increased in energy demand as well as the detrimental effects posed by emission of greenhouse gases due to continue use of fossil fuels for electricity generation has led to a renewed focus on energy production using renewable energy sources which are relatively cheap, clean and environmentally sustainable. Among the various renewable energy sources used so far, the Dye Synthesized Solar Cells (DSSCs), a form of photovoltaic device is reported for their better efficiencies despite their low cost of production and ability to work relatively under low light conditions. A recent report on the solar-to-electricity conversion efficiency of a typical DSSC sensitizer made from zinc based porphyrin dye coupled with sintered titanium(IV) oxide as semiconductor was 13 percent. In this study, 2,2-bipyridyl-4,4-dicarboxylic acid (bpydc) was used as mixed ligand and four dithiolate ligands; L1 = dipotassium ethoxycarbonyl-1-cyanoethylene-2,2-dithiolate, L2 = dipotassium bis(ethoxycarbonyl)ethane-2,2-dithiolate, L3 = dipotassium cyanodithio imidocarbonate and L4 = dipotassium 2,2-dicyanoethylene-2,2-dithiolate were synthesized while four alkyl thiourea ligands, L5 = 1,3-dimethyl thiourea, L6 = 1,3-diethyl thiourea, L7 = 1,3-diisopropyl thiourea and L8 = 1-methyl thiourea were purchased and used as supplied without further purification. These ligands were used to prepare eight ruthenium(II) complexes of mixed bipyridyl/dithiolate/thiourea. The compounds were characterised by elemental analysis and spectroscopic techniques, namely: Fourier transform infrared (FTIR), Nuclear Magnetic Resonance (NMR), ultraviolet-visible and photoluminescence (PL). Cyclic voltammetry (CV) and square wave voltammetry (SWV) were used for the electrochemical studies. Photoluminescence and UV-Vis spectroscopies were used for geometric and photophysical studies of the complexes respectively. FTIR spectra confirmed presence of functional groups in ligands and coordination of these ligands to ruthenium(II) ions to form complexes. The UV-Vis confirmed that the Ru(II) dithiolene complexes exhibited square planar geometries while the Ru(II) thiourea complexes gave octahedral geometries, this was deduced from the transitions assigned to the complexes. All the ruthenium(II) complexes synthesized showed photoluminescence properties that are suitable for light harvesting and application for dye-sensitized solar cells. Cyclic and square wave voltammetry show Ru(II) thiourea complexes have better redox properties when compared to Ru(II) dithiolate complexes which is ascribed to ligand strength field possibly due to contribution from the two bonded NCS groups.
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The effectiveness of juvenile delinquents rehabilitation programmes in Zimbabwe : a case study of Harare Central Prison
- Authors: Nyakatawa, Rumbidzai
- Date: 2018
- Subjects: Juvenile delinquency Juvenile delinquents Rehabilitation
- Language: English
- Type: Thesis , Masters , MSoc
- Identifier: http://hdl.handle.net/10353/12436 , vital:39263
- Description: The Zimbabwe Prison and Correctional Services records show that there are around 300 children incarcerated every year. Most of these children commit crimes such as rape, murder, theft, possession of drugs due to issues like poverty, substance abuse, peer pressure and neglect. A number of these children face many forms of abuse in their homes, including physical, emotional, mental abuse as well as rape. The major aim of the study was to investigate the effectiveness of juvenile delinquents’ rehabilitation programmes at Harare Central Prison. The qualitative methodology was appropriate for this study because it gives in depth information through conducting interviews and focus groups with participants. The sampling procedure involved deliberate choice of an informant due to the qualities the informant possessed. A sample size of thirty-seven participants comprising sixteen juvenile delinquents, four social workers, five prison guards, five probation officers and seven community members, were selected for this study. Their perceptions provided baseline data that helped in gaining a deeper understanding of the juvenile rehabilitation programmes. Despite the findings, gaps remain in the current system, for instance children continue to spend prolonged periods of time in adult prisons while they await repatriation to institutions due to resource constraints, and the rehabilitation programmes have proved to be partially effective, yet at the same time the post rehabilitation programmes are not being provided to juveniles after their release from prison. Key recommendations include expanding the Pre-trial Diversion Programme to all the provinces as it has yielded results that benefit the child as well introduction of alternatives of institutionalisation.
- Full Text:
- Authors: Nyakatawa, Rumbidzai
- Date: 2018
- Subjects: Juvenile delinquency Juvenile delinquents Rehabilitation
- Language: English
- Type: Thesis , Masters , MSoc
- Identifier: http://hdl.handle.net/10353/12436 , vital:39263
- Description: The Zimbabwe Prison and Correctional Services records show that there are around 300 children incarcerated every year. Most of these children commit crimes such as rape, murder, theft, possession of drugs due to issues like poverty, substance abuse, peer pressure and neglect. A number of these children face many forms of abuse in their homes, including physical, emotional, mental abuse as well as rape. The major aim of the study was to investigate the effectiveness of juvenile delinquents’ rehabilitation programmes at Harare Central Prison. The qualitative methodology was appropriate for this study because it gives in depth information through conducting interviews and focus groups with participants. The sampling procedure involved deliberate choice of an informant due to the qualities the informant possessed. A sample size of thirty-seven participants comprising sixteen juvenile delinquents, four social workers, five prison guards, five probation officers and seven community members, were selected for this study. Their perceptions provided baseline data that helped in gaining a deeper understanding of the juvenile rehabilitation programmes. Despite the findings, gaps remain in the current system, for instance children continue to spend prolonged periods of time in adult prisons while they await repatriation to institutions due to resource constraints, and the rehabilitation programmes have proved to be partially effective, yet at the same time the post rehabilitation programmes are not being provided to juveniles after their release from prison. Key recommendations include expanding the Pre-trial Diversion Programme to all the provinces as it has yielded results that benefit the child as well introduction of alternatives of institutionalisation.
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Seasonal variations in tick loads, coat characteristics, temperature-humidity index and blood metabolite profiles of extensively raised Boran cows
- Authors: Ntilini, Wonga John
- Date: 2017
- Subjects: Boran cattle -- South Africa Ticks -- South Africa
- Language: English
- Type: Thesis , Masters , MAgric
- Identifier: http://hdl.handle.net/10353/13471 , vital:39672
- Description: This study sought to determine the seasonal variations in tick loads, coat characteristics, temperature-humidity index and blood metabolite profiles of Boran cows reared in arid rangelands of South Africa. A total of 20 Boran cows of different age groups were used in this study. Tick counts, hair length, coat score, average temperature and relative humidity readings were measured twice (beginning and end) in each season (post-rainy, cold-dry, hot-dry, hot-wet). Blood samples were taken seasonally (beginning and end of the season) for the analysis of creatine kinase (CK) activity and haematological parameters (HP). Ticks were observed and counted from different anatomical sites, namely anterior (neck, head, ears, and around eyes), ventral (belly, udder, and limbs) and posterior (back and under the tail). The tick species observed from the Boran cows were Rhipicephalus evertsi evertsi (34.58percent), Amblyomma hebreaum (43.35percent), Rhipicephalus simus (4.48percent) and Rhipicephalus (Boophilus) decoloratus (17.59percent). Significant differences were observed in tick burdens at various anatomical sites, with posterior position having the highest tick loads during the post-rainy, cold-dry and hot-dry season. While the ventral position recorded the highest tick loads during the hot-wet season. It was also observed that the cattle had significantly long hair lengths during the cold-dry season. Furthermore, coat score and hair length were observed to be negatively (P<0.05) correlated with tick counts, while coat scores were positively (P<0.05) correlated with hair length. Significant differences were observed in CK activity across season, with higher levels during the hot-dry and hot-wet seasons compared to the post-rainy and cold-dry seasons. Boran cows were exposed to a mild stress condition during the hot-dry and hot-wet season when the THI values were high (>70). Seasonal variations had an effect (P<0.05) on some HP (HB, HCT, MCV, MCH, EOS, and BAS). Neutrophils (-0.267) and basophils (0.268) were significantly correlated with THI. In conclusion, the Boran cows were more susceptible to tick loads during the hot seasons. Likewise, the levels of creatine kinase activity and temperature-humidity index were high during the hot-dry and hot-wet season. Therefore, seasonal variations had an effect on tick loads, coat characteristics, temperature-humidity index and blood metabolite profiles of extensively raised Boran cows.
- Full Text:
- Authors: Ntilini, Wonga John
- Date: 2017
- Subjects: Boran cattle -- South Africa Ticks -- South Africa
- Language: English
- Type: Thesis , Masters , MAgric
- Identifier: http://hdl.handle.net/10353/13471 , vital:39672
- Description: This study sought to determine the seasonal variations in tick loads, coat characteristics, temperature-humidity index and blood metabolite profiles of Boran cows reared in arid rangelands of South Africa. A total of 20 Boran cows of different age groups were used in this study. Tick counts, hair length, coat score, average temperature and relative humidity readings were measured twice (beginning and end) in each season (post-rainy, cold-dry, hot-dry, hot-wet). Blood samples were taken seasonally (beginning and end of the season) for the analysis of creatine kinase (CK) activity and haematological parameters (HP). Ticks were observed and counted from different anatomical sites, namely anterior (neck, head, ears, and around eyes), ventral (belly, udder, and limbs) and posterior (back and under the tail). The tick species observed from the Boran cows were Rhipicephalus evertsi evertsi (34.58percent), Amblyomma hebreaum (43.35percent), Rhipicephalus simus (4.48percent) and Rhipicephalus (Boophilus) decoloratus (17.59percent). Significant differences were observed in tick burdens at various anatomical sites, with posterior position having the highest tick loads during the post-rainy, cold-dry and hot-dry season. While the ventral position recorded the highest tick loads during the hot-wet season. It was also observed that the cattle had significantly long hair lengths during the cold-dry season. Furthermore, coat score and hair length were observed to be negatively (P<0.05) correlated with tick counts, while coat scores were positively (P<0.05) correlated with hair length. Significant differences were observed in CK activity across season, with higher levels during the hot-dry and hot-wet seasons compared to the post-rainy and cold-dry seasons. Boran cows were exposed to a mild stress condition during the hot-dry and hot-wet season when the THI values were high (>70). Seasonal variations had an effect (P<0.05) on some HP (HB, HCT, MCV, MCH, EOS, and BAS). Neutrophils (-0.267) and basophils (0.268) were significantly correlated with THI. In conclusion, the Boran cows were more susceptible to tick loads during the hot seasons. Likewise, the levels of creatine kinase activity and temperature-humidity index were high during the hot-dry and hot-wet season. Therefore, seasonal variations had an effect on tick loads, coat characteristics, temperature-humidity index and blood metabolite profiles of extensively raised Boran cows.
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In vitro evaluation of antimicrobial and antioxidant activities of olea europaea subsp. africana and euryops brevipapposus used by Cala community folkloric medicine for the management of infections associated with chronic non-communicable diseases
- Authors: Adegborioye, Abiodun
- Date: 2016
- Subjects: Antioxidants , Medicinal plants , Traditional medicine -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/4869 , vital:28624
- Description: Chronic non-communicable diseses are a global public health challenge that continuously threatens the development and health of humans. Risk factors such as unbalanced diet-the high consumption of processed food or food from animal origin are responsible for NCDs. NCDs result in weakened immune system, making the host susceptible to opportunistic infections. Thus, the NCDs burden is most times chronic and multiple with the illness and suffering of the affected person numerous. The lack of cure for NCDs, the high cost of drugs, their high side-effects, and the emergence of multiple drug resistance has given rise to the investigation of other sources for therapeutic cure such as medicinal plants. The ethanol, n-hexane and ethyl acetate extracts of Olea europaea were analysed for their antioxidant and antimicrobial activities. The essential oil was also analysed for their chemical constituents. The n-hexane extracts of O. europaea exhibited no inhibition against all of the microorganisms tested, while the ethyl acetate and ethanol extracts exhibited inhibition, with minimum inhibitory concentration values between 0.625 mg/ml to 1.25 mg/ml. The ethanol leaf and ethyl acetate stem extracts exhibited significant activity in the inhibition of 2, 2-azinobis-(3-ethylbenzothiazolin - 6-sulfonic acid diammonium salt (ABTS) free radical, the n-hexane leaf extract had the overall significant lipid peroxidation inhibition activity, while in the inhibition of 2, 2- diphenyl-1-picrylhydrazyl radical (DPPH), the ethanol and ethyl acetate leaf extracts had strong activity. Nonanal, phytol, α-Pinene, α-Phellandrene, spatulenol and farnesol were some of chemical components identified after the GC-MS analysis of O. europaea oil. In the final part of the dissertation, Euryops brevipapposus essential oil was assessed for the antioxidant activities using free radical scavenging assays. In addition to this, the antimicrobial activities were assessed and the chemical composition was analysed using GC-MS. The essential oil demonstrated significant antioxidant activity against 2, 2-diphenyl-2-picryl-hydrazyl free radical (DPPH), 2, 2′-azino-bis (3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) and lipid peroxides with IC50 value of 0.0000000671 mg/ml, 1.05 mg/ml, and 1.170 mg/ml respectively. The essential oil also showed significant activity against all microorganisms tested with minimum inhibitory concentration (MIC) values between 0.055 mg/ml to 0.5 mg/ml. α-pinene, α- Phellandrene, germacrene D, β-pinene, trans- β.-Ocimene, bicyclogermacrene and β -Phellandrene were some of the chemical compounds identified in E. brevipapposus oil. The study has shown that E. brevipapposus and O. europaea are abundant in phytochemical compounds which were thought to be the root cause for the activities demonstrated. Therefore, these therapeutic properties observed validate and elucidate the traditional usage of the both plants in the treatment /management of diseases.
- Full Text:
- Authors: Adegborioye, Abiodun
- Date: 2016
- Subjects: Antioxidants , Medicinal plants , Traditional medicine -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/4869 , vital:28624
- Description: Chronic non-communicable diseses are a global public health challenge that continuously threatens the development and health of humans. Risk factors such as unbalanced diet-the high consumption of processed food or food from animal origin are responsible for NCDs. NCDs result in weakened immune system, making the host susceptible to opportunistic infections. Thus, the NCDs burden is most times chronic and multiple with the illness and suffering of the affected person numerous. The lack of cure for NCDs, the high cost of drugs, their high side-effects, and the emergence of multiple drug resistance has given rise to the investigation of other sources for therapeutic cure such as medicinal plants. The ethanol, n-hexane and ethyl acetate extracts of Olea europaea were analysed for their antioxidant and antimicrobial activities. The essential oil was also analysed for their chemical constituents. The n-hexane extracts of O. europaea exhibited no inhibition against all of the microorganisms tested, while the ethyl acetate and ethanol extracts exhibited inhibition, with minimum inhibitory concentration values between 0.625 mg/ml to 1.25 mg/ml. The ethanol leaf and ethyl acetate stem extracts exhibited significant activity in the inhibition of 2, 2-azinobis-(3-ethylbenzothiazolin - 6-sulfonic acid diammonium salt (ABTS) free radical, the n-hexane leaf extract had the overall significant lipid peroxidation inhibition activity, while in the inhibition of 2, 2- diphenyl-1-picrylhydrazyl radical (DPPH), the ethanol and ethyl acetate leaf extracts had strong activity. Nonanal, phytol, α-Pinene, α-Phellandrene, spatulenol and farnesol were some of chemical components identified after the GC-MS analysis of O. europaea oil. In the final part of the dissertation, Euryops brevipapposus essential oil was assessed for the antioxidant activities using free radical scavenging assays. In addition to this, the antimicrobial activities were assessed and the chemical composition was analysed using GC-MS. The essential oil demonstrated significant antioxidant activity against 2, 2-diphenyl-2-picryl-hydrazyl free radical (DPPH), 2, 2′-azino-bis (3-ethylbenzthiazoline-6-sulfonic acid) (ABTS) and lipid peroxides with IC50 value of 0.0000000671 mg/ml, 1.05 mg/ml, and 1.170 mg/ml respectively. The essential oil also showed significant activity against all microorganisms tested with minimum inhibitory concentration (MIC) values between 0.055 mg/ml to 0.5 mg/ml. α-pinene, α- Phellandrene, germacrene D, β-pinene, trans- β.-Ocimene, bicyclogermacrene and β -Phellandrene were some of the chemical compounds identified in E. brevipapposus oil. The study has shown that E. brevipapposus and O. europaea are abundant in phytochemical compounds which were thought to be the root cause for the activities demonstrated. Therefore, these therapeutic properties observed validate and elucidate the traditional usage of the both plants in the treatment /management of diseases.
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