The subjective experience of resilience among divorced african women in Cradock, Eastern Cape, South Africa
- Authors: Faxi, Nasiphi
- Date: 2018
- Subjects: Divorced women Divorce--Psychological aspects Divorced women--Psychology
- Language: English
- Type: Thesis , Masters , Psychology
- Identifier: http://hdl.handle.net/10353/17371 , vital:40960
- Description: The study aimed at investigating the resilience enhancement factors which promoted well-being among divorced African women in Cradock, the Eastern Cape, South Africa. A qualitative research design was used to investigate the factors which reinforced resilience and promoted well-being following divorce as studies have indicated the risk of not being able to cope following divorce trauma. Purposive sampling was used in recruiting twelve divorced participants (aged 25- 45) from a support group at a local church in Cradock. Data was collected by means of semistructured interviews following the permission of the church and the divorced women who gave their consent to conduct the study. Furthermore, ethical principles were adhered to, throughout the data collection process. Thirteen themes emerged in the study and they include; self-condemnation, self-blame and denial, loneliness depression, anger and embarrassment, stigma, personality change, sexual dissatisfaction, ambivalence, forgiveness, selfcontentment and self-compassion, personal growth, religious coping, social support and positive relations and resilience enhancement factors. Despite the achievement of the research objectives, the sample might not be the true representation of the population of women who experienced divorce. Also, the results might have been different if the study was quantitative in nature. Based on the findings, psychological support is needed for women who underwent divorce. Finally, churches should play a vital role in restoration of resilience among divorced women while the families and communities shift away from cultural beliefs of subjugating women.
- Full Text:
- Authors: Faxi, Nasiphi
- Date: 2018
- Subjects: Divorced women Divorce--Psychological aspects Divorced women--Psychology
- Language: English
- Type: Thesis , Masters , Psychology
- Identifier: http://hdl.handle.net/10353/17371 , vital:40960
- Description: The study aimed at investigating the resilience enhancement factors which promoted well-being among divorced African women in Cradock, the Eastern Cape, South Africa. A qualitative research design was used to investigate the factors which reinforced resilience and promoted well-being following divorce as studies have indicated the risk of not being able to cope following divorce trauma. Purposive sampling was used in recruiting twelve divorced participants (aged 25- 45) from a support group at a local church in Cradock. Data was collected by means of semistructured interviews following the permission of the church and the divorced women who gave their consent to conduct the study. Furthermore, ethical principles were adhered to, throughout the data collection process. Thirteen themes emerged in the study and they include; self-condemnation, self-blame and denial, loneliness depression, anger and embarrassment, stigma, personality change, sexual dissatisfaction, ambivalence, forgiveness, selfcontentment and self-compassion, personal growth, religious coping, social support and positive relations and resilience enhancement factors. Despite the achievement of the research objectives, the sample might not be the true representation of the population of women who experienced divorce. Also, the results might have been different if the study was quantitative in nature. Based on the findings, psychological support is needed for women who underwent divorce. Finally, churches should play a vital role in restoration of resilience among divorced women while the families and communities shift away from cultural beliefs of subjugating women.
- Full Text:
Appraisal of experimental performance and modelling of an on-farm dairy milk bulk cooler: Fort Hare Dairy Trust, South Africa
- Authors: Mhundwa, Russel
- Date: 2017
- Subjects: Milk -- Cooling Milk -- Cooling -- Equipment and supplies Milk tanks -- Specifications
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/4671 , vital:28487
- Description: South Africa contributes approximately 0.5 percent to the total world milk demand and is the third largest producer of fresh cow milk in Africa after Sudan and Kenya. In comparison to any other enterprise, the cost of milk production is influenced by numerous factors, that in turn affect the profitability of the farm enterprise; however one of such factors is high electricity cost. In this regard, there is need for efficient operation of the milk processing plant at all stages and at the same time maximising on product quality and minimising on the cost of production including energy. At the dairy farm, milk handling mainly commences as the milk leaves the cow udder at 35°C–37°C and must be cooled rapidly to a storage temperature of 4°C in a bid to stop microbial activity. The cooling of the milk can be done directly by the bulk milk cooler (BMC) from 37°C to the required storage temperature of 4°C or it can be done successively through pre-cooling. The process of pre-cooling involves the use of a heat exchanger where in most instances the plate heat exchanger (PHE) is used as the pre-cooler (PC) thereby leading to energy savings in a dairy facility. Cooling of milk involves significant amount of energy and it could account for about 20 percent of the total energy consumed on a farm. The aim of the research was to develop mathematical models that could be used to predict the electrical energy performance and capture the cooling saving of an on-farm direct expansion bulk milk cooler (DXBMC) during the milk cooling process. Accordingly, data acquisition system (DAS) was designed and built to accurately measure the power consumption of the BMC, temperature of raw milk, room temperature, temperature of cold water, relative humidity and ambient temperature. The volume of milk produced per day was extracted from the daily records on the farm. In addition, the temperature sensors were connected to a four channel HOBO data loggers which were configured to log at every five-minutes interval. The results were analysed and the mathematical models were developed using MATLAB. The statistical Toolbox in MATLAB was used to rank the predictors according to their weight of importance using the ReliefF Algorithm test. The results showed that on average, the daily electrical energy consumed by the BMC at the two milking times was higher during the peak period (127.82 kWh and 93.86 kWh) than the off-peak period (48.31 kWh and 43.23 kWh). On average, the electricity used for cooling of milk on the dairy farm was 17.06 kWh/m3 of milk. The average monthly electricity used per cow on the farm was 8.03 kWh/cow which translated to an average of 0.26 kWh/cow/day The average specific energy consumption of the cooling system per litre of milk cooled was 0.02 kWh/L and was almost constant throughout the whole period of monitoring. Furthermore, the BMC was able to cool 57.33 L/kWh during the off-peak period which increased by 7.7 percent to 62.13 L/kWh during the peak period. Furthermore, mathematical models represented as multiple linear regression (MLR) models were built and developed using the experimental data. The developed mathematical models had good agreement with the experimental data as evidenced by the correlation coefficients of 0.922 and 0.8995 along with 0.935 and 0.930. The ReliefF Algorithm test revealed that the volume of milk was the principal contributor to the energy consumption of the BMC for both the morning (AM) and afternoon (PM) milking period. The Relative Prediction Error (RPE) was used to evaluate the suitability of the developed models. In this light, the AM off-peak model had RPE of 18.54 percent while the PM off-peak model had 14.42 percent. In addition, the AM peak and PM peak models had RPE of 19.23 percent and 18.95 percent respectively. This suggested that the MLR models for the off-peak and peak milking periods (both AM and PM) had acceptable prediction accuracy since the RPE values were between 10 percent and 20 percent. The findings from the experimental study showed that the coefficient of performance (COP) of the AM milking period was higher (2.20) than that of the PM milking period of the BMC (1.93). Increase in the milk volume led to an increase in the COP such that the peak period with higher milk volumes recorded a high COP increase of 12.61 percent and 19.81 percent for the AM and PM milking periods respectively.
- Full Text:
- Authors: Mhundwa, Russel
- Date: 2017
- Subjects: Milk -- Cooling Milk -- Cooling -- Equipment and supplies Milk tanks -- Specifications
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/4671 , vital:28487
- Description: South Africa contributes approximately 0.5 percent to the total world milk demand and is the third largest producer of fresh cow milk in Africa after Sudan and Kenya. In comparison to any other enterprise, the cost of milk production is influenced by numerous factors, that in turn affect the profitability of the farm enterprise; however one of such factors is high electricity cost. In this regard, there is need for efficient operation of the milk processing plant at all stages and at the same time maximising on product quality and minimising on the cost of production including energy. At the dairy farm, milk handling mainly commences as the milk leaves the cow udder at 35°C–37°C and must be cooled rapidly to a storage temperature of 4°C in a bid to stop microbial activity. The cooling of the milk can be done directly by the bulk milk cooler (BMC) from 37°C to the required storage temperature of 4°C or it can be done successively through pre-cooling. The process of pre-cooling involves the use of a heat exchanger where in most instances the plate heat exchanger (PHE) is used as the pre-cooler (PC) thereby leading to energy savings in a dairy facility. Cooling of milk involves significant amount of energy and it could account for about 20 percent of the total energy consumed on a farm. The aim of the research was to develop mathematical models that could be used to predict the electrical energy performance and capture the cooling saving of an on-farm direct expansion bulk milk cooler (DXBMC) during the milk cooling process. Accordingly, data acquisition system (DAS) was designed and built to accurately measure the power consumption of the BMC, temperature of raw milk, room temperature, temperature of cold water, relative humidity and ambient temperature. The volume of milk produced per day was extracted from the daily records on the farm. In addition, the temperature sensors were connected to a four channel HOBO data loggers which were configured to log at every five-minutes interval. The results were analysed and the mathematical models were developed using MATLAB. The statistical Toolbox in MATLAB was used to rank the predictors according to their weight of importance using the ReliefF Algorithm test. The results showed that on average, the daily electrical energy consumed by the BMC at the two milking times was higher during the peak period (127.82 kWh and 93.86 kWh) than the off-peak period (48.31 kWh and 43.23 kWh). On average, the electricity used for cooling of milk on the dairy farm was 17.06 kWh/m3 of milk. The average monthly electricity used per cow on the farm was 8.03 kWh/cow which translated to an average of 0.26 kWh/cow/day The average specific energy consumption of the cooling system per litre of milk cooled was 0.02 kWh/L and was almost constant throughout the whole period of monitoring. Furthermore, the BMC was able to cool 57.33 L/kWh during the off-peak period which increased by 7.7 percent to 62.13 L/kWh during the peak period. Furthermore, mathematical models represented as multiple linear regression (MLR) models were built and developed using the experimental data. The developed mathematical models had good agreement with the experimental data as evidenced by the correlation coefficients of 0.922 and 0.8995 along with 0.935 and 0.930. The ReliefF Algorithm test revealed that the volume of milk was the principal contributor to the energy consumption of the BMC for both the morning (AM) and afternoon (PM) milking period. The Relative Prediction Error (RPE) was used to evaluate the suitability of the developed models. In this light, the AM off-peak model had RPE of 18.54 percent while the PM off-peak model had 14.42 percent. In addition, the AM peak and PM peak models had RPE of 19.23 percent and 18.95 percent respectively. This suggested that the MLR models for the off-peak and peak milking periods (both AM and PM) had acceptable prediction accuracy since the RPE values were between 10 percent and 20 percent. The findings from the experimental study showed that the coefficient of performance (COP) of the AM milking period was higher (2.20) than that of the PM milking period of the BMC (1.93). Increase in the milk volume led to an increase in the COP such that the peak period with higher milk volumes recorded a high COP increase of 12.61 percent and 19.81 percent for the AM and PM milking periods respectively.
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Perceptions of male teachers on under-representation of female teachers in high school management positions in the Queenstown Education District
- Authors: Nyikanyika, Khaya
- Date: 2017
- Subjects: Women school administrators -- South Africa -- Eastern Cape Women teachers -- South Africa -- Eastern Cape School management and organization -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10353/5036 , vital:29018
- Description: The purpose of this study was to find out the perceptions of male teachers on the under-representation of female teachers in high school management position in the Queenstown Education District and to find the barriers that cause this perception to determine the possible solutions for these problems. To carry out this study descriptive method was employed. Participants of the study were 60 male teachers, selected by using stratified random sampling techniques. The data were collected by using questionnaire and interview. Both qualitative and quantitative data analysis methods were employed in order to turn up at the results. The findings of the study revealed that, despite the male teachers perceptions on the under-representation of female school managers in high school management positon has been changing, but not as expected still they believe that female teachers are reluctant to accept responsibilities of school management positions Some of the challenges which could hinder female teachers representation in high school management positions were for instance; pressure of home responsibilities, men dominance of management position, political appointment, unclear promotion procedures or informal recruitment selection and discrimination.
- Full Text:
- Authors: Nyikanyika, Khaya
- Date: 2017
- Subjects: Women school administrators -- South Africa -- Eastern Cape Women teachers -- South Africa -- Eastern Cape School management and organization -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10353/5036 , vital:29018
- Description: The purpose of this study was to find out the perceptions of male teachers on the under-representation of female teachers in high school management position in the Queenstown Education District and to find the barriers that cause this perception to determine the possible solutions for these problems. To carry out this study descriptive method was employed. Participants of the study were 60 male teachers, selected by using stratified random sampling techniques. The data were collected by using questionnaire and interview. Both qualitative and quantitative data analysis methods were employed in order to turn up at the results. The findings of the study revealed that, despite the male teachers perceptions on the under-representation of female school managers in high school management positon has been changing, but not as expected still they believe that female teachers are reluctant to accept responsibilities of school management positions Some of the challenges which could hinder female teachers representation in high school management positions were for instance; pressure of home responsibilities, men dominance of management position, political appointment, unclear promotion procedures or informal recruitment selection and discrimination.
- Full Text:
Pharmacological evaluation of phragmanthera capitata (sprengel) balle, loranthaceae :a parasiticmistletoe growing on rubber trees
- Ohikhena, Franklin Uangbaoje
- Authors: Ohikhena, Franklin Uangbaoje
- Date: 2017
- Subjects: Hevea Hevea -- Diseases and pests Rubber
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/8899 , vital:33937
- Description: Rubber tree (Hevea brasiliensis Muell.) is the world’s major source of natural rubber and a major non-oil, agricultural export commodity in the producing countries in Africa. However, it is highly susceptible to specific mistletoes of the Loranthaceae family. Phragmanthera capitate (Sprengel) Balle is the major mistletoe parasitizing the rubber tree plantations in Africa and hence, alongside with other mistletoes, has attracted indiscriminate destruction from plantation owners. Indiscriminate destruction of plants could be as a result of ignorance of the importance or benefit(s) of the plants and this could lead to their extinction if not checked. Hence, there is the need for scientific documentation of plants and their uses because, from the pharmacological perception, the destruction of a plant could result in the permanent loss of a potential drug. Therefore, this study was aimed at documenting and evaluating the pharmacological potentials of P. capitata collected from rubber tree. Fresh leaves were gently rinsed with water and dried. Dried leaves were pulverised and kept at 4oC when not in use. Pulverised leaves were extracted with acetone, methanol, ethanol and water and concentrated to give the respective solvent crude extracts used in most of the assays. From the extraction, Methanol had the highest yield of 21.5percent, water had 10.8percent and acetone was 6.87percent while ethanol had the lowest yield of 4.3percent. Standard spectrophotometry assays on the extracts were used to quantify some major phytochemicals of pharmacological interest and also to determine the antioxidant potentials of the sample. The result revealed high amounts of phenols (175.53 ± 0.32 mg GAE/g to 218.62 ± 3.38 mg GAE/g), flavonoids (197.06 ± 3.80 mg QE/mg to 679.82 ± 6.26 mg QE/g) and proanthocyanidins (128.83 ± 1.69 mg CE/g to 645.68 ± 6.35 mg CE/g) with the acetone extract having the highest amount of the phytochemicals while the aqueous extract had the least. The results of the antioxidant assays revealed that the sample had high radical scavenging potentials with comparable inhibitory concentrations to standard antioxidant drugs. The proximate and mineral analysis on the pulverised sample showed that it is rich in carbohydrate with a composition of 57.73 ± 0.33 g/100 g. Protein, fat and fibre compositions were 12.50 ± 0.50 g/100 g, 3.34 ± 0.18 g/100 g and 11.66 ± 0.54 g/100g. The total energy composition was 310.97 ± 2.30 Kcal/100 g. The mineral composition revealed high potassium level of 1047.83 ± 34 mg/100g. Calcium (6.22.58 ± 0.01 mg/100g), magnesium (361.15 ± 0.01 mg/100 g) and phosphorous (115.40 ± 0.01 mg/100 g) were also present in appreciable amounts. The toxicity of the four extracts was assayed using brine shrimp. The LC50 in all the solvent extracts was greater than 1 mg/mL which according to Meyer’s index and other indexes signify “no toxicity” for crude plant extracts. Antimicrobial activity of the extracts was done using the minimal inhibitory concentration (MIC) assay against 10 bacteria (Enterococcus faecalis, Staphylococcus aureus, Bacillus subtilis, Bacillus cereus, Streptococcus pyogenes, Vibrio cholera, Klebsiella pneumonia, Pseudomonas aeruginosa, Salmonella typhi and Escherichia coli) and 4 fungi (Trichophyton mucoides, Trichophyton tonsurans, Candida albicans and Aspergillus niger) of human pathogenic strains. The MIC of the antibacterial assay ranged from 1.25 mg/mL to 5 mg/mL for the organic extracts while no activity was observed in the aqueous extract at the highest concentration tested. However, the aqueous extract had a great inhibitory activity on all four of the tested fungi with a MIC of ≤ 0.3125 mg/mL to 1.25 mg/mL while only two fungi (Trichophyton Tonsurans and Aspergillus niger) were susceptible to the organic extracts. The MIC of the TB causative pathogen, Mycobacterium tuberculosis (H37Rv) strain ranged from 25 μg/mL (acetone and aqueous extracts) to 50 μg/mL in the ethanol extract while it was > 50 μg/mL (highest concentration tested) in the methanol extract. This study revealed that the sample has the potential in phytotherapy against oxidative stresses (inflammations) caused by free radicals. It could also be a useful herb in combating diseases caused by pathogenic organisms. The high anti-Mycobacterium tuberculosis activity observed in this study suggests it could be a plant with high promise in the fight against tuberculosis. The toxicity evaluation signifies it is safe for further plant-based pharmaceutical explorations. This study also validated some reported ethnopharmacological uses of this plant and call for its protection from indiscriminate destruction in rubber plantations and other crop gardens/plantations in the world.
- Full Text:
- Authors: Ohikhena, Franklin Uangbaoje
- Date: 2017
- Subjects: Hevea Hevea -- Diseases and pests Rubber
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/8899 , vital:33937
- Description: Rubber tree (Hevea brasiliensis Muell.) is the world’s major source of natural rubber and a major non-oil, agricultural export commodity in the producing countries in Africa. However, it is highly susceptible to specific mistletoes of the Loranthaceae family. Phragmanthera capitate (Sprengel) Balle is the major mistletoe parasitizing the rubber tree plantations in Africa and hence, alongside with other mistletoes, has attracted indiscriminate destruction from plantation owners. Indiscriminate destruction of plants could be as a result of ignorance of the importance or benefit(s) of the plants and this could lead to their extinction if not checked. Hence, there is the need for scientific documentation of plants and their uses because, from the pharmacological perception, the destruction of a plant could result in the permanent loss of a potential drug. Therefore, this study was aimed at documenting and evaluating the pharmacological potentials of P. capitata collected from rubber tree. Fresh leaves were gently rinsed with water and dried. Dried leaves were pulverised and kept at 4oC when not in use. Pulverised leaves were extracted with acetone, methanol, ethanol and water and concentrated to give the respective solvent crude extracts used in most of the assays. From the extraction, Methanol had the highest yield of 21.5percent, water had 10.8percent and acetone was 6.87percent while ethanol had the lowest yield of 4.3percent. Standard spectrophotometry assays on the extracts were used to quantify some major phytochemicals of pharmacological interest and also to determine the antioxidant potentials of the sample. The result revealed high amounts of phenols (175.53 ± 0.32 mg GAE/g to 218.62 ± 3.38 mg GAE/g), flavonoids (197.06 ± 3.80 mg QE/mg to 679.82 ± 6.26 mg QE/g) and proanthocyanidins (128.83 ± 1.69 mg CE/g to 645.68 ± 6.35 mg CE/g) with the acetone extract having the highest amount of the phytochemicals while the aqueous extract had the least. The results of the antioxidant assays revealed that the sample had high radical scavenging potentials with comparable inhibitory concentrations to standard antioxidant drugs. The proximate and mineral analysis on the pulverised sample showed that it is rich in carbohydrate with a composition of 57.73 ± 0.33 g/100 g. Protein, fat and fibre compositions were 12.50 ± 0.50 g/100 g, 3.34 ± 0.18 g/100 g and 11.66 ± 0.54 g/100g. The total energy composition was 310.97 ± 2.30 Kcal/100 g. The mineral composition revealed high potassium level of 1047.83 ± 34 mg/100g. Calcium (6.22.58 ± 0.01 mg/100g), magnesium (361.15 ± 0.01 mg/100 g) and phosphorous (115.40 ± 0.01 mg/100 g) were also present in appreciable amounts. The toxicity of the four extracts was assayed using brine shrimp. The LC50 in all the solvent extracts was greater than 1 mg/mL which according to Meyer’s index and other indexes signify “no toxicity” for crude plant extracts. Antimicrobial activity of the extracts was done using the minimal inhibitory concentration (MIC) assay against 10 bacteria (Enterococcus faecalis, Staphylococcus aureus, Bacillus subtilis, Bacillus cereus, Streptococcus pyogenes, Vibrio cholera, Klebsiella pneumonia, Pseudomonas aeruginosa, Salmonella typhi and Escherichia coli) and 4 fungi (Trichophyton mucoides, Trichophyton tonsurans, Candida albicans and Aspergillus niger) of human pathogenic strains. The MIC of the antibacterial assay ranged from 1.25 mg/mL to 5 mg/mL for the organic extracts while no activity was observed in the aqueous extract at the highest concentration tested. However, the aqueous extract had a great inhibitory activity on all four of the tested fungi with a MIC of ≤ 0.3125 mg/mL to 1.25 mg/mL while only two fungi (Trichophyton Tonsurans and Aspergillus niger) were susceptible to the organic extracts. The MIC of the TB causative pathogen, Mycobacterium tuberculosis (H37Rv) strain ranged from 25 μg/mL (acetone and aqueous extracts) to 50 μg/mL in the ethanol extract while it was > 50 μg/mL (highest concentration tested) in the methanol extract. This study revealed that the sample has the potential in phytotherapy against oxidative stresses (inflammations) caused by free radicals. It could also be a useful herb in combating diseases caused by pathogenic organisms. The high anti-Mycobacterium tuberculosis activity observed in this study suggests it could be a plant with high promise in the fight against tuberculosis. The toxicity evaluation signifies it is safe for further plant-based pharmaceutical explorations. This study also validated some reported ethnopharmacological uses of this plant and call for its protection from indiscriminate destruction in rubber plantations and other crop gardens/plantations in the world.
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Ni(II) and Pb(II) dithiocarbamate complexes as precursors for the synthesis of HDA-capped NiS and PbS nanoparticles
- Authors: Chintso, Thobani
- Date: 2015
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: vital:11349 , http://hdl.handle.net/10353/d1020201
- Description: Ni(II) and Pb(II) dithiocarbamate complexes were synthesized and characterized by elemental analysis, UV-Vis, FTIR and TGA and some of the Ni(II) complexes and one Pb(II) were further analyzed by 1H-NMR and 13C-NMR spectroscopy. Generally all the dithiocarbamate ligands are soluble in water while the complexes were soluble mostly in solvents such as chloroform, toluene, DMSO and DCM. Based on the elemental analysis, the dithiocarbamate complexes are formulated as four coordinate (tetrahedral or square planar) compounds. However, the FTIR showed that each of the dithiocarbamate ligands acted as bidentate ligand through two sulfur atoms. The TGA of the most complexes showed one major decomposition step to give respective metal sulfide above 200 oC. In this research project, dithiocarbamate complexes were used as single source precursor for the synthesis of metal sulfide nanoparticles. We studied the optical and structural properties of metal sulfide nanoparticles using UV-Vis, photoluminescence (PL), powder X-ray diffraction (XRD), energy dispersive X-ray (EDX), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The absorption spectra of the metal sulfide nanoparticles are blue shifted in respect to bulk material and they also showed broad emission. The XRD of the NiS nanoparticles were indexed to the cubic and rhombohedral phase, with crystallite sizes of 15 - 18 nm. The XRD of PbS nanoparticles were indexed to the face centered cubic and cubic rock salts, with the crystallite sizes 12 - 18 nm. The TEM images of the metal sulfide nanoparticles showed particles with spherical and rectangular shapes with crystallite sizes 4 - 35 nm.
- Full Text:
- Authors: Chintso, Thobani
- Date: 2015
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: vital:11349 , http://hdl.handle.net/10353/d1020201
- Description: Ni(II) and Pb(II) dithiocarbamate complexes were synthesized and characterized by elemental analysis, UV-Vis, FTIR and TGA and some of the Ni(II) complexes and one Pb(II) were further analyzed by 1H-NMR and 13C-NMR spectroscopy. Generally all the dithiocarbamate ligands are soluble in water while the complexes were soluble mostly in solvents such as chloroform, toluene, DMSO and DCM. Based on the elemental analysis, the dithiocarbamate complexes are formulated as four coordinate (tetrahedral or square planar) compounds. However, the FTIR showed that each of the dithiocarbamate ligands acted as bidentate ligand through two sulfur atoms. The TGA of the most complexes showed one major decomposition step to give respective metal sulfide above 200 oC. In this research project, dithiocarbamate complexes were used as single source precursor for the synthesis of metal sulfide nanoparticles. We studied the optical and structural properties of metal sulfide nanoparticles using UV-Vis, photoluminescence (PL), powder X-ray diffraction (XRD), energy dispersive X-ray (EDX), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The absorption spectra of the metal sulfide nanoparticles are blue shifted in respect to bulk material and they also showed broad emission. The XRD of the NiS nanoparticles were indexed to the cubic and rhombohedral phase, with crystallite sizes of 15 - 18 nm. The XRD of PbS nanoparticles were indexed to the face centered cubic and cubic rock salts, with the crystallite sizes 12 - 18 nm. The TEM images of the metal sulfide nanoparticles showed particles with spherical and rectangular shapes with crystallite sizes 4 - 35 nm.
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