Pharmacological studies of Foeniculum Vulgare (Mill.) and Lippia Javanica (Burm.F.) spreng. used as spices in Nkonkobe Municipality of the Eastern Cape Province, South Africa
- Asowata-Ayodele, Abiola Mojisola
- Authors: Asowata-Ayodele, Abiola Mojisola
- Date: 2016
- Subjects: Medicinal plants -- South Africa -- Eastern Cape Fennel -- Utilization -- South Africa -- Eastern Cape Ethnopharmacology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/2777 , vital:28085
- Description: Spices are of great importance in the indigenous culinary and traditional medicine systems of the people of Nkonkobe Municipality of the Eastern Cape, South Africa. The present investigation evaluated the ethnopharmacological potentials of two indigenous South African spices- Foeniculum vulgare and Lippia javanica. The pharmacological investigations on these two plant species include ultra-morphology, nutrient and mineral analysis, evaluation of the essential oil, phytochemical and antioxidant assays, antimicrobial, anti-inflammatory as well as anti-urolithiatic assay of the acetone and aqueous extracts of the two plants. The species were selected for study as the most cited plants after an ethnobotanical survey conducted on the indigenous knowledge of plants used as spices and medicine in Nkonkobe Municipality, Eastern Cape of South Africa. Among the plants cited Foeniculum vulgare(Apiaceae) and Lippia javanica (Verbenaceae) stood out as the most commonly used spices. Others were members of the families; Solanaceae, Apiaceae, Amaryllidaceae, Amaranthaceae and Lamiaceae. Ultra-morphological studies conducted on the leaves of the two selected plants using scanning electron microscope revealed the presence of non-glandular and glandular trichomes, stomata and crystals. The leaf surfaces of these herbs may serve as secretory sites where aromatic secondary metabolites are produced. Analyses of the proximate, mineral, vitamin and anti-nutrients contents of these two spices showed that both species are good sources of these phytochemicals and may be used to enrich the human diet. Lippia javanica possesses lower lipid (0.50 percent), fibre (5 percent) and carbohydrate (64.96 percent) contents than Foeniculum vulgare. On the other hand, protein (20.54 percent), ash (11.60 percent) and moisture content (11.69 percent) were higher in Foeniculum vulgare than in Lippia javanica. Foeniculum vulgare showed higher N (3286 mg/100g), Mg (386.7 mg/100g), K (3187 mg/100g) and Na (1383 mg/100g) content while Lippia javanica was higher in Ca (1833 mg/100g), Zn (4.7 mg/100g), Cu (0.9 mg/100g) and Fe (78.4 mg/100g). Vitamins Aand E were also higher in Lippia javanica (1.31 mg/100g; 2.52 mg/100g) while Foeniculum vulgare (0.45 mg/100g) had higher vitamin C content. No significant differences were observed in the phytate, oxalate and tannin contents of the two spices, but saponin and cyanide were significantly lower in Lippia javanica (268.5 mg/100g; 8.45 mg/100g) than in Foeniculum vulgare (1855 mg/100g; 10.5 mg/100g) Evaluation of the essential oil component, cytotoxicity and antimicrobial activities of both fresh and dried leaves of Lippia javanica and Foeniculum vulgare revealed that the dried samples yielded more oil and also contain more chemical than the fresh samples of both plants. The overall antimicrobial activity evaluated using susceptibility and microdilution assays revealed that the oils of F. vulgare and L. javanica exhibited high antifungal and antibacterial activity, compared to the reference drugs. In addition, essential oil from fresh leaves of both spices was less toxic compared to the oil from the dried leaves. Polyphenolic evaluation of the aqueous and acetone extracts of the plants revealed that the acetone extract had higher phenol, flavanol, flavonoid and proanthocyanidin contents than the aqueous extracts. The total phenolic content of acetone and aqueous extracts were 4.49 ± 0.411 mg/g and 3.73 ± 0.498 mg/g tannic acid equivalent (TAE) respectively for Lippia javanica. The same trend was also observed in Foeniculum vulgare with total phenolic content of acetone and aqueous extracts were 4.22 ± 0.325 mg/g and 4.17 ± 0.651 mg/g tannic acid equivalent (TAE) respectively. Further assessment of the antioxidant activity of the solvent extracts revealed that both plants exhibited promising free radical scavenging potentials against 1,1 diphenyl-2-picrylhydrazyl (DPPH), 2, 2’-azino-bis(3- ethylbenzthiazoline-6-sulfonic acid (ABTS), reducing power, lipid peroxidation, nitric oxide, phosphomolybdate and hydrogen peroxide. Antimicrobial activities of the acetone and aqueous extracts of the two plants revealed moderate antibacterial and antifungal activities. They inhibited the growth of Microsporium canis and Trichophyton rubrum that were not susceptible to the standard antifungal drug used as control.
- Full Text:
- Authors: Asowata-Ayodele, Abiola Mojisola
- Date: 2016
- Subjects: Medicinal plants -- South Africa -- Eastern Cape Fennel -- Utilization -- South Africa -- Eastern Cape Ethnopharmacology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/2777 , vital:28085
- Description: Spices are of great importance in the indigenous culinary and traditional medicine systems of the people of Nkonkobe Municipality of the Eastern Cape, South Africa. The present investigation evaluated the ethnopharmacological potentials of two indigenous South African spices- Foeniculum vulgare and Lippia javanica. The pharmacological investigations on these two plant species include ultra-morphology, nutrient and mineral analysis, evaluation of the essential oil, phytochemical and antioxidant assays, antimicrobial, anti-inflammatory as well as anti-urolithiatic assay of the acetone and aqueous extracts of the two plants. The species were selected for study as the most cited plants after an ethnobotanical survey conducted on the indigenous knowledge of plants used as spices and medicine in Nkonkobe Municipality, Eastern Cape of South Africa. Among the plants cited Foeniculum vulgare(Apiaceae) and Lippia javanica (Verbenaceae) stood out as the most commonly used spices. Others were members of the families; Solanaceae, Apiaceae, Amaryllidaceae, Amaranthaceae and Lamiaceae. Ultra-morphological studies conducted on the leaves of the two selected plants using scanning electron microscope revealed the presence of non-glandular and glandular trichomes, stomata and crystals. The leaf surfaces of these herbs may serve as secretory sites where aromatic secondary metabolites are produced. Analyses of the proximate, mineral, vitamin and anti-nutrients contents of these two spices showed that both species are good sources of these phytochemicals and may be used to enrich the human diet. Lippia javanica possesses lower lipid (0.50 percent), fibre (5 percent) and carbohydrate (64.96 percent) contents than Foeniculum vulgare. On the other hand, protein (20.54 percent), ash (11.60 percent) and moisture content (11.69 percent) were higher in Foeniculum vulgare than in Lippia javanica. Foeniculum vulgare showed higher N (3286 mg/100g), Mg (386.7 mg/100g), K (3187 mg/100g) and Na (1383 mg/100g) content while Lippia javanica was higher in Ca (1833 mg/100g), Zn (4.7 mg/100g), Cu (0.9 mg/100g) and Fe (78.4 mg/100g). Vitamins Aand E were also higher in Lippia javanica (1.31 mg/100g; 2.52 mg/100g) while Foeniculum vulgare (0.45 mg/100g) had higher vitamin C content. No significant differences were observed in the phytate, oxalate and tannin contents of the two spices, but saponin and cyanide were significantly lower in Lippia javanica (268.5 mg/100g; 8.45 mg/100g) than in Foeniculum vulgare (1855 mg/100g; 10.5 mg/100g) Evaluation of the essential oil component, cytotoxicity and antimicrobial activities of both fresh and dried leaves of Lippia javanica and Foeniculum vulgare revealed that the dried samples yielded more oil and also contain more chemical than the fresh samples of both plants. The overall antimicrobial activity evaluated using susceptibility and microdilution assays revealed that the oils of F. vulgare and L. javanica exhibited high antifungal and antibacterial activity, compared to the reference drugs. In addition, essential oil from fresh leaves of both spices was less toxic compared to the oil from the dried leaves. Polyphenolic evaluation of the aqueous and acetone extracts of the plants revealed that the acetone extract had higher phenol, flavanol, flavonoid and proanthocyanidin contents than the aqueous extracts. The total phenolic content of acetone and aqueous extracts were 4.49 ± 0.411 mg/g and 3.73 ± 0.498 mg/g tannic acid equivalent (TAE) respectively for Lippia javanica. The same trend was also observed in Foeniculum vulgare with total phenolic content of acetone and aqueous extracts were 4.22 ± 0.325 mg/g and 4.17 ± 0.651 mg/g tannic acid equivalent (TAE) respectively. Further assessment of the antioxidant activity of the solvent extracts revealed that both plants exhibited promising free radical scavenging potentials against 1,1 diphenyl-2-picrylhydrazyl (DPPH), 2, 2’-azino-bis(3- ethylbenzthiazoline-6-sulfonic acid (ABTS), reducing power, lipid peroxidation, nitric oxide, phosphomolybdate and hydrogen peroxide. Antimicrobial activities of the acetone and aqueous extracts of the two plants revealed moderate antibacterial and antifungal activities. They inhibited the growth of Microsporium canis and Trichophyton rubrum that were not susceptible to the standard antifungal drug used as control.
- Full Text:
Population, communication and habitat comparisons between the major gummivorous strepsirhines of Madagascar (phaner) and Cameroon (euoticus)
- Authors: Forbanka, Derick Nomuh
- Date: 2016
- Subjects: Adaptation (Biology) , Mammals -- Evolution , Mammals -- Behavior
- Language: English
- Type: Thesis , Doctoral , Zoology
- Identifier: http://hdl.handle.net/10353/15957 , vital:40567
- Description: The suborder Strepsirhini contains a large proportion of the living gummivorous mammal taxa, and includes two genera of specialist gummivores, Euoticus and Phaner, which present particularly interesting cases of convergent adaptive evolution in Africa and Madagascar, respectively. Although these genera are not closely related, they share several anatomical, behavioural and physiological specialisations associated with their diets, and despite their biogeographical separation, there seems to be substantial coincidence in their habitats and habits. Neither the ecology nor the systematics of Phaner and Euoticus has been the subject of much detailed research, and little is known of the conservation status of the genera. Even their specific diversity is unresolved. In this study I investigated and compared aspects of their ecology at both a macro-and a microhabitat scale, including wild populations of all groups within the two genera that have been accorded species status in recent field guides and systematic reviews. I also studied aspects of their social communication behaviour as clues to their species-level diversity. Species and their formation (or speciation) have inspired a great deal of evolutionary research, but remain contentious issues in evolutionary biology. This is due both to the difficulties inherent in inferring the details of a dynamic biological process that occurred over some time in the past from the recent, relatively static patterns of variation observed, as well as the limited consensus among biologists in identifying such patterns. It is therefore important to distinguish the kinds of patterns in nature that are predicted by different views of species and speciation, and also to see how well these predictions fare when applied to the speciation patterns found in strepsirhine primates. Theories of speciation cannot be separated from species concepts, and one concept widely supported in primatology is the Recognition Concept of species because of its heuristic nature. The Recognition Concept is based on Specific-mate Recognition Systems (SMRS). I focussed on SMRS features of Euoticus and Phaner, loud call specificity, and species’ preferred habitats. My results provided some support for the distinctiveness of currently identified species, although this was not clear-cut. Population densities of both Phaner and Euoticus appear to have declined in recent years, even though both Phaner and Euoticus appear to be well adapted to both primary and secondary forest, and exhibit ecological plasticity. Statistically some loud call parameters vary among the putative species of the genus Phaner and not Euoticus. Phaner pallescens at Kirindy, Madasgascar was clearly able to discriminate loud calls of its own population from other proposed species within the genus. Most loud call parameters did not show any statistical degradation with increasing distance. A crucial finding of my study was that the two lineages are not only convergent in terms of dietary and locomotor aspects of their ecology, but also in the structures of their loud calls. The environmental adaptation of communication systems is often overlooked when studying adaptive convergence, but my study indicates that acoustic properties are a crucial aspect of a species’ preferred habitat. The results of this study can be used to improve conservation planning, and also add to our understanding of the evolutionary history of strepsirhine primates.
- Full Text:
- Authors: Forbanka, Derick Nomuh
- Date: 2016
- Subjects: Adaptation (Biology) , Mammals -- Evolution , Mammals -- Behavior
- Language: English
- Type: Thesis , Doctoral , Zoology
- Identifier: http://hdl.handle.net/10353/15957 , vital:40567
- Description: The suborder Strepsirhini contains a large proportion of the living gummivorous mammal taxa, and includes two genera of specialist gummivores, Euoticus and Phaner, which present particularly interesting cases of convergent adaptive evolution in Africa and Madagascar, respectively. Although these genera are not closely related, they share several anatomical, behavioural and physiological specialisations associated with their diets, and despite their biogeographical separation, there seems to be substantial coincidence in their habitats and habits. Neither the ecology nor the systematics of Phaner and Euoticus has been the subject of much detailed research, and little is known of the conservation status of the genera. Even their specific diversity is unresolved. In this study I investigated and compared aspects of their ecology at both a macro-and a microhabitat scale, including wild populations of all groups within the two genera that have been accorded species status in recent field guides and systematic reviews. I also studied aspects of their social communication behaviour as clues to their species-level diversity. Species and their formation (or speciation) have inspired a great deal of evolutionary research, but remain contentious issues in evolutionary biology. This is due both to the difficulties inherent in inferring the details of a dynamic biological process that occurred over some time in the past from the recent, relatively static patterns of variation observed, as well as the limited consensus among biologists in identifying such patterns. It is therefore important to distinguish the kinds of patterns in nature that are predicted by different views of species and speciation, and also to see how well these predictions fare when applied to the speciation patterns found in strepsirhine primates. Theories of speciation cannot be separated from species concepts, and one concept widely supported in primatology is the Recognition Concept of species because of its heuristic nature. The Recognition Concept is based on Specific-mate Recognition Systems (SMRS). I focussed on SMRS features of Euoticus and Phaner, loud call specificity, and species’ preferred habitats. My results provided some support for the distinctiveness of currently identified species, although this was not clear-cut. Population densities of both Phaner and Euoticus appear to have declined in recent years, even though both Phaner and Euoticus appear to be well adapted to both primary and secondary forest, and exhibit ecological plasticity. Statistically some loud call parameters vary among the putative species of the genus Phaner and not Euoticus. Phaner pallescens at Kirindy, Madasgascar was clearly able to discriminate loud calls of its own population from other proposed species within the genus. Most loud call parameters did not show any statistical degradation with increasing distance. A crucial finding of my study was that the two lineages are not only convergent in terms of dietary and locomotor aspects of their ecology, but also in the structures of their loud calls. The environmental adaptation of communication systems is often overlooked when studying adaptive convergence, but my study indicates that acoustic properties are a crucial aspect of a species’ preferred habitat. The results of this study can be used to improve conservation planning, and also add to our understanding of the evolutionary history of strepsirhine primates.
- Full Text:
Post-2008 voter apathy among the youth in the Eastern Cape : a comparative study of urban and rural municipalities
- Authors: Peter, Bongeka
- Date: 2016
- Subjects: Youth -- Political activity -- South Africa -- Eastern Cape Political participation -- South Africa -- Eastern Cape Apathy -- South Africa Municipal government -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Soc Sci
- Identifier: http://hdl.handle.net/10353/630 , vital:26475
- Description: This dissertation deals with the nature of the black middle-class assimilation in the South African suburban space, a space that was the sole preserve of the white middle-class during apartheid. It explores the relationship between these races as they come to meet in this space and what new identities are being formed. It also explores the relationship between both the black and white suburbanites and the urban poor who stay in an adjacent area to the suburb. The study uses the Beacon Bay area, which is constituted by one of East London’s most affluent suburbs and a poor township, Nompumelelo, to show how the emergent black middle-class has managed to enter this space in the post-apartheid era. Previous studies by Richard Ballard (2004) and Grant Saff (2001) have shown how the white middle-class has always been against any form of race or class mixing. Within the suburb, the new black suburbanites in Beacon Bay appear to have been welcomed but with conditions by their fellow white counterparts. The relationship between these two races does not stretch beyond meet and greets and it is only in the second generation black middle-class that you find better and non-superficial relations with fellow white suburbanites. In the older generation, the generation that experienced apartheid, the relationship between these two races has been that of tolerance and serious escape of contact unless when necessary. The children of both white and black families, though, have a far better relationship in school and in sport than their parents. This has created another area of contact for both these races and it bears potential for meaningful integration in the suburban space. Externally as it relates to relations between the black middle-class and the urban poor, the findings show that these new black suburbanites express a similar discomfort as the white suburbanites about the urban poor’s presence in the area. This shows that the evolution of the Beacon Bay suburb, with its deep-rooted discourse of white middle-class exclusivity, has not been entirely about hatred of the urban poor necessarily but about an identity ascription of what it means to live in a suburb. Despite these realities traditional ceremonies organised by the black middle-class in the suburbs and the church appear to be playing a role in creating relations between these suburbanites and the Nompumelelo residents. This is why we have decided to use the conceptualisation of the 18th century frontier zone as the borders of segregation within the suburb and between the suburban residents and those of the township can be crossed and re-crossed.
- Full Text:
- Authors: Peter, Bongeka
- Date: 2016
- Subjects: Youth -- Political activity -- South Africa -- Eastern Cape Political participation -- South Africa -- Eastern Cape Apathy -- South Africa Municipal government -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Soc Sci
- Identifier: http://hdl.handle.net/10353/630 , vital:26475
- Description: This dissertation deals with the nature of the black middle-class assimilation in the South African suburban space, a space that was the sole preserve of the white middle-class during apartheid. It explores the relationship between these races as they come to meet in this space and what new identities are being formed. It also explores the relationship between both the black and white suburbanites and the urban poor who stay in an adjacent area to the suburb. The study uses the Beacon Bay area, which is constituted by one of East London’s most affluent suburbs and a poor township, Nompumelelo, to show how the emergent black middle-class has managed to enter this space in the post-apartheid era. Previous studies by Richard Ballard (2004) and Grant Saff (2001) have shown how the white middle-class has always been against any form of race or class mixing. Within the suburb, the new black suburbanites in Beacon Bay appear to have been welcomed but with conditions by their fellow white counterparts. The relationship between these two races does not stretch beyond meet and greets and it is only in the second generation black middle-class that you find better and non-superficial relations with fellow white suburbanites. In the older generation, the generation that experienced apartheid, the relationship between these two races has been that of tolerance and serious escape of contact unless when necessary. The children of both white and black families, though, have a far better relationship in school and in sport than their parents. This has created another area of contact for both these races and it bears potential for meaningful integration in the suburban space. Externally as it relates to relations between the black middle-class and the urban poor, the findings show that these new black suburbanites express a similar discomfort as the white suburbanites about the urban poor’s presence in the area. This shows that the evolution of the Beacon Bay suburb, with its deep-rooted discourse of white middle-class exclusivity, has not been entirely about hatred of the urban poor necessarily but about an identity ascription of what it means to live in a suburb. Despite these realities traditional ceremonies organised by the black middle-class in the suburbs and the church appear to be playing a role in creating relations between these suburbanites and the Nompumelelo residents. This is why we have decided to use the conceptualisation of the 18th century frontier zone as the borders of segregation within the suburb and between the suburban residents and those of the township can be crossed and re-crossed.
- Full Text:
Preparation and application of plasmon metal enhanced titanium dioxide photocatalyst for the removal of organics in water
- Authors: Nyamukamba, Pardon
- Date: 2016
- Subjects: Water -- Purification -- Photocatalysis Titanium dioxide Water chemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/2765 , vital:28074
- Description: Advanced oxidation processes are capable of removing organic compounds that cannot be removed by conventional water treatment methods. Among the oxidation processes, photo-catalysis using titanium dioxide (TiO2) is a promising method but suffers from rapid electron-hole recombination rates and only absorbs UV light which is a small percentage (5 percent) of the total solar radiation. Therefore there is a need to reduce the recombination rates and also extend the absorption of the photo-catalyst into the visible region which constitutes 55 percent of the total solar radiation. The major aims of this study were to prepare plasmon metal decorated and doped TiO2 photo-catalysts immobilized on quartz substrates and test their photo-catalytic and antimicrobial activities. The effect of film thickness (loading) and use of different shapes of plasmon metal nanostructures was investigated. TiO2 thin films were prepared by a sputter coating technique while plasmon metal (Au & Ag)/carbon co-doped TiO2 by a simple sol gel process and plasmon metal films were prepared by the thermal evaporation technique. Different plasmon metal nanostructures (nanorods, dendrites, nanowires and spherical nanoparticles) were prepared using a wet chemical technique using sodium borohydride as the reducing agent. Nanocomposites of co-doped TiO2 photo-catalyst and plasmon elements of different proportions were also prepared. The prepared photo-catalysts were coated onto etched and MPTMS (3-Mercaptopropyl trimethoxysliane) treated quartz glass substrate which is a stable support favouring easy recovery. The prepared materials were characterized by XRD, HRTEM, TEM, HRSEM, FT-IR, SEM, PIXE and TGA while the doped TiO2 was characterized by XPS, BET, CHNS and Raman Spectroscopy. The effect of pH of solution, presence of other contaminants and salts in solution, initial concentration of the model pollutant and type of the plasmonic elements on the photocatalytic activity of TiO2 towards 4-(4-sulfophenylazo)-N,N-dimethyl aniline (methyl orange) were also investigated. The selected TiO2 photo-catalyst films were tested for antimicrobial properties. The effect of different types of plasmon elements on the antimicrobial activity of TiO2 against E. coli ATCC 3695 was evaluated under both sunlight and weak UV light. Under UV light, Ag showed the highest enhancement in photo-catalytic activity of TiO2 than Au and Cu. The photo-catalytic activity of TiO2 increased with an increase in Ag content to an optimum loading and then started to decrease with a further increase in loading. For Cu and Au, photo-activity activity increased with an increase in plasmon metal content. Under sunlight, Cu showed the highest enhancement of TiO2 photocatalytic compared to Ag and Au. The change in order of deposition showed that Au films enhanced the photo-activity better when they were deposited underneath rather than on top of TiO2 on quartz supports but Ag films performed better in enhancing photo-activity when they were deposited on top of TiO2. The use of bimetallic layers and three layer systems of different plasmon elements enhanced photo-catalytic activity better than the use of a monometallic layer. The presence of other organic contaminants and salts in solutions was found to reduce the photo-degradation of methyl orange due to preferential adsorption of other contaminants. When the pH was increased, the photocatalytic activity of TiO2 towards methyl orange was reduced. In antimicrobial studies, it was found that the plasmon elements greatly improved the antibacterial action of TiO2 against Escherichia coli ATCC 3695 in water and the best antibacterial action was observed with silver/carbon co-doped TiO2 photo-catalyst under sunlight The doped samples consisted of polydisperse nanoparticles which were found to be beneficial for photo-catalytic activity enhancement under sunlight.
- Full Text:
- Authors: Nyamukamba, Pardon
- Date: 2016
- Subjects: Water -- Purification -- Photocatalysis Titanium dioxide Water chemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/2765 , vital:28074
- Description: Advanced oxidation processes are capable of removing organic compounds that cannot be removed by conventional water treatment methods. Among the oxidation processes, photo-catalysis using titanium dioxide (TiO2) is a promising method but suffers from rapid electron-hole recombination rates and only absorbs UV light which is a small percentage (5 percent) of the total solar radiation. Therefore there is a need to reduce the recombination rates and also extend the absorption of the photo-catalyst into the visible region which constitutes 55 percent of the total solar radiation. The major aims of this study were to prepare plasmon metal decorated and doped TiO2 photo-catalysts immobilized on quartz substrates and test their photo-catalytic and antimicrobial activities. The effect of film thickness (loading) and use of different shapes of plasmon metal nanostructures was investigated. TiO2 thin films were prepared by a sputter coating technique while plasmon metal (Au & Ag)/carbon co-doped TiO2 by a simple sol gel process and plasmon metal films were prepared by the thermal evaporation technique. Different plasmon metal nanostructures (nanorods, dendrites, nanowires and spherical nanoparticles) were prepared using a wet chemical technique using sodium borohydride as the reducing agent. Nanocomposites of co-doped TiO2 photo-catalyst and plasmon elements of different proportions were also prepared. The prepared photo-catalysts were coated onto etched and MPTMS (3-Mercaptopropyl trimethoxysliane) treated quartz glass substrate which is a stable support favouring easy recovery. The prepared materials were characterized by XRD, HRTEM, TEM, HRSEM, FT-IR, SEM, PIXE and TGA while the doped TiO2 was characterized by XPS, BET, CHNS and Raman Spectroscopy. The effect of pH of solution, presence of other contaminants and salts in solution, initial concentration of the model pollutant and type of the plasmonic elements on the photocatalytic activity of TiO2 towards 4-(4-sulfophenylazo)-N,N-dimethyl aniline (methyl orange) were also investigated. The selected TiO2 photo-catalyst films were tested for antimicrobial properties. The effect of different types of plasmon elements on the antimicrobial activity of TiO2 against E. coli ATCC 3695 was evaluated under both sunlight and weak UV light. Under UV light, Ag showed the highest enhancement in photo-catalytic activity of TiO2 than Au and Cu. The photo-catalytic activity of TiO2 increased with an increase in Ag content to an optimum loading and then started to decrease with a further increase in loading. For Cu and Au, photo-activity activity increased with an increase in plasmon metal content. Under sunlight, Cu showed the highest enhancement of TiO2 photocatalytic compared to Ag and Au. The change in order of deposition showed that Au films enhanced the photo-activity better when they were deposited underneath rather than on top of TiO2 on quartz supports but Ag films performed better in enhancing photo-activity when they were deposited on top of TiO2. The use of bimetallic layers and three layer systems of different plasmon elements enhanced photo-catalytic activity better than the use of a monometallic layer. The presence of other organic contaminants and salts in solutions was found to reduce the photo-degradation of methyl orange due to preferential adsorption of other contaminants. When the pH was increased, the photocatalytic activity of TiO2 towards methyl orange was reduced. In antimicrobial studies, it was found that the plasmon elements greatly improved the antibacterial action of TiO2 against Escherichia coli ATCC 3695 in water and the best antibacterial action was observed with silver/carbon co-doped TiO2 photo-catalyst under sunlight The doped samples consisted of polydisperse nanoparticles which were found to be beneficial for photo-catalytic activity enhancement under sunlight.
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Production of Indigenous Leafy Vegetables (ILVs) and their contribution to household food security: evidence from Coffee Bay, Eastern Cape Province of South Africa
- Authors: Mayekiso Anele
- Date: 2016
- Subjects: Food security , Edible greens , Vegetable gardening -- South Africa , Food -- Preservation
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: http://hdl.handle.net/10353/712 , vital:26490 , Food security , Edible greens , Vegetable gardening -- South Africa , Food -- Preservation
- Description: This study used cross-sectional survey data to estimate farmers` perceptions of, and commonly cultivated ILVs, factors that influence the participation of smallholder famers in the production of Indigenous Leafy Vegetables and its contribution to household food security]. With regard to farmers` perceptions of ILVs, descriptive results reveal that a majority of the people from the study area share positive perceptions with respect to ILVs. Regression estimates for determinants of participation indicate that the production of ILVs is primarily conditioned by shared perceptions and institutional factors rather than the socio-economic attributes of farmers. Public policies that address the institutional framework (extension, credit, market and social networks) in favour of ILVs are more likely to promote production. Also, more research on the documentation and benefits of ILVs, supported by investments targeting educational campaigns towards promoting positive attitudes and dispelling fears and myths surrounding ILVs, will further promote production. With reference to the contribution of ILVs to food security, descriptive results indicate that participation in the production of ILVs leads to a higher HDDS and a lower HFIAS. Regression estimates further revealed that participation positively contributes to a higher HDDS and a lower HFIAS, suggesting that households who participate in the production of ILVs are more likely to be food secure than non-participants. Therefore, participation in the production of ILVs has significant potential to address household food security.
- Full Text:
- Authors: Mayekiso Anele
- Date: 2016
- Subjects: Food security , Edible greens , Vegetable gardening -- South Africa , Food -- Preservation
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: http://hdl.handle.net/10353/712 , vital:26490 , Food security , Edible greens , Vegetable gardening -- South Africa , Food -- Preservation
- Description: This study used cross-sectional survey data to estimate farmers` perceptions of, and commonly cultivated ILVs, factors that influence the participation of smallholder famers in the production of Indigenous Leafy Vegetables and its contribution to household food security]. With regard to farmers` perceptions of ILVs, descriptive results reveal that a majority of the people from the study area share positive perceptions with respect to ILVs. Regression estimates for determinants of participation indicate that the production of ILVs is primarily conditioned by shared perceptions and institutional factors rather than the socio-economic attributes of farmers. Public policies that address the institutional framework (extension, credit, market and social networks) in favour of ILVs are more likely to promote production. Also, more research on the documentation and benefits of ILVs, supported by investments targeting educational campaigns towards promoting positive attitudes and dispelling fears and myths surrounding ILVs, will further promote production. With reference to the contribution of ILVs to food security, descriptive results indicate that participation in the production of ILVs leads to a higher HDDS and a lower HFIAS. Regression estimates further revealed that participation positively contributes to a higher HDDS and a lower HFIAS, suggesting that households who participate in the production of ILVs are more likely to be food secure than non-participants. Therefore, participation in the production of ILVs has significant potential to address household food security.
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Professional behaviour among nursing students at a college in the Eastern Cape
- Authors: Magopeni, Sibongile Nomvuyo
- Date: 2016
- Subjects: Nursing students -- South Africa -- Eastern Cape Nursing -- Study and teaching -- South Africa -- Eastern Cape Nursing -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MCur
- Identifier: http://hdl.handle.net/10353/2566 , vital:27896
- Description: The focus of the study was to explore and describe reasons for poor professional behaviour among nursing students at a public nursing college in the Eastern Cape. The objectives of the study were to explore and describe the reasons for poor professional behaviour among nursing students and to describe strategies to improve poor professional behaviour. The study has significance for the college management, staff, nursing students, registered nurses and everyone involved in professional development of nursing students. The population for this study consisted of third-year nursing students following the four-year comprehensive basic course for registration leading to the Diploma in Nursing (General, Community & Psychiatry) and Midwifery at a public nursing college. The research questions were: What do you understand by professional behaviour? What are the reasons for poor professional behaviour among nursing students? What could be done to improve professionalism among college nursing students? A qualitative, explorative, descriptive and contextual design was used as a framework for the study. Permission to conduct the study was obtained from the University of Fort Hare ethics committee and other relevant authorities as indicated in the study. Ethical principles were maintained and informed consent obtained. Data collection was done using focus groups and an audiotape with a purposefully sampling of 30 third-year nursing students at the public college of nursing. Data were analysed using Tesch’s method of analysis for qualitative research. Three major themes emerged: students’ understanding of professional behaviour, reasons for poor professional behaviour and methods to improve poor professional behaviour. It was concluded that poor professional behaviour has an effect on professionalism and it should be addressed and corrected for protecting the professional image. Recommendations: Policies regarding inappropriate professional behaviour at the college should be in place and easily accessible to every staff member and nursing student. Department of Health should conduct reflective courses and seminars on professionalism and these should begin at the same time as the academic programme.
- Full Text:
- Authors: Magopeni, Sibongile Nomvuyo
- Date: 2016
- Subjects: Nursing students -- South Africa -- Eastern Cape Nursing -- Study and teaching -- South Africa -- Eastern Cape Nursing -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MCur
- Identifier: http://hdl.handle.net/10353/2566 , vital:27896
- Description: The focus of the study was to explore and describe reasons for poor professional behaviour among nursing students at a public nursing college in the Eastern Cape. The objectives of the study were to explore and describe the reasons for poor professional behaviour among nursing students and to describe strategies to improve poor professional behaviour. The study has significance for the college management, staff, nursing students, registered nurses and everyone involved in professional development of nursing students. The population for this study consisted of third-year nursing students following the four-year comprehensive basic course for registration leading to the Diploma in Nursing (General, Community & Psychiatry) and Midwifery at a public nursing college. The research questions were: What do you understand by professional behaviour? What are the reasons for poor professional behaviour among nursing students? What could be done to improve professionalism among college nursing students? A qualitative, explorative, descriptive and contextual design was used as a framework for the study. Permission to conduct the study was obtained from the University of Fort Hare ethics committee and other relevant authorities as indicated in the study. Ethical principles were maintained and informed consent obtained. Data collection was done using focus groups and an audiotape with a purposefully sampling of 30 third-year nursing students at the public college of nursing. Data were analysed using Tesch’s method of analysis for qualitative research. Three major themes emerged: students’ understanding of professional behaviour, reasons for poor professional behaviour and methods to improve poor professional behaviour. It was concluded that poor professional behaviour has an effect on professionalism and it should be addressed and corrected for protecting the professional image. Recommendations: Policies regarding inappropriate professional behaviour at the college should be in place and easily accessible to every staff member and nursing student. Department of Health should conduct reflective courses and seminars on professionalism and these should begin at the same time as the academic programme.
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Professional identity of teacher educators as assessors of teaching practice : a case study in a South African university
- Authors: Roy, Irene Juanita Sass
- Date: 2016
- Subjects: Teacher educators--Professional relationships Teachers--Training of
- Language: English
- Type: Thesis , Doctoral , Education
- Identifier: http://hdl.handle.net/10353/15969 , vital:40570
- Description: This study focuses on the professional identity of Teacher Educators as assessors of teaching practice for Post Graduate Certificate in Education (PGCE) student teachers.The research was presented as a case study at one institution of higher learning. The focus was on the professional identity of teacher educators as revealed in the assessment narratives they expressed as a report back to PGCE students and the verbalisation of their beliefs through semi-structured interviews at the particular institution. This study adopted a qualitative research methodology from an interpretivist paradigm whereby the collected data was coded and analysed through applying both inductive and deductive reasoning. Themes which emerged from the data were qualitatively analysed through the social-constructivist theories of Bernstein, Lave and Wenger and Feiman-Nemser. This study revealed that the professional identity of Teacher Educators plays a significant role in the way in which they assess students. The study showed that theprofessional identity (encompassing of professional knowledge) of Teacher Educators determines their assessment focus, professional knowledge and identity is reflected in the narrative feedback to PGCE student teachers and their views of the current assessment instrument as (in)effective. The study revealed that Teacher Educators have specific expectations (pedagogical skill, subject and content knowledge) but the complexities of their identity override how they apply the assessment instrument. In addition Teacher Educators are challenged by the PGCE cohort in that they expect this group to show the same competencies as students coming through the under-graduate programme. The study recommends that a collaborative approach be adopted in the preparation and assessment of PGCE student teachers; a re-conceptualisation of the requirements of teaching competence for this group be undertaken; and Teacher Educators be empowered to teach and assess PGCE student teachers aligned with the principles of andragogy and that Higher Education policy take cognisance of and make provision for the unique needs of PGCE teacher training. The study proposes a revised approach by Teacher Educators be considered which treat the assessment of teaching competence for PGCE student teachers in a less fragmented and individualised manner. This implies that a different organisational assessment culture is needed in order to democratize the assessment of PGCE student teachers, training in the GET band in South Africa.
- Full Text:
- Authors: Roy, Irene Juanita Sass
- Date: 2016
- Subjects: Teacher educators--Professional relationships Teachers--Training of
- Language: English
- Type: Thesis , Doctoral , Education
- Identifier: http://hdl.handle.net/10353/15969 , vital:40570
- Description: This study focuses on the professional identity of Teacher Educators as assessors of teaching practice for Post Graduate Certificate in Education (PGCE) student teachers.The research was presented as a case study at one institution of higher learning. The focus was on the professional identity of teacher educators as revealed in the assessment narratives they expressed as a report back to PGCE students and the verbalisation of their beliefs through semi-structured interviews at the particular institution. This study adopted a qualitative research methodology from an interpretivist paradigm whereby the collected data was coded and analysed through applying both inductive and deductive reasoning. Themes which emerged from the data were qualitatively analysed through the social-constructivist theories of Bernstein, Lave and Wenger and Feiman-Nemser. This study revealed that the professional identity of Teacher Educators plays a significant role in the way in which they assess students. The study showed that theprofessional identity (encompassing of professional knowledge) of Teacher Educators determines their assessment focus, professional knowledge and identity is reflected in the narrative feedback to PGCE student teachers and their views of the current assessment instrument as (in)effective. The study revealed that Teacher Educators have specific expectations (pedagogical skill, subject and content knowledge) but the complexities of their identity override how they apply the assessment instrument. In addition Teacher Educators are challenged by the PGCE cohort in that they expect this group to show the same competencies as students coming through the under-graduate programme. The study recommends that a collaborative approach be adopted in the preparation and assessment of PGCE student teachers; a re-conceptualisation of the requirements of teaching competence for this group be undertaken; and Teacher Educators be empowered to teach and assess PGCE student teachers aligned with the principles of andragogy and that Higher Education policy take cognisance of and make provision for the unique needs of PGCE teacher training. The study proposes a revised approach by Teacher Educators be considered which treat the assessment of teaching competence for PGCE student teachers in a less fragmented and individualised manner. This implies that a different organisational assessment culture is needed in order to democratize the assessment of PGCE student teachers, training in the GET band in South Africa.
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Reconfiguring international pharmaceutical patent protection principles to combat linkage evergreening :|b'de-linking the evergreen' and proposing a solution for developing countries
- Authors: Omino, Akinyi Melissa Anne
- Date: 2016
- Subjects: Patent medicines--Developing countries Drugs--Developing countries Patent laws and legislation--Developing countries
- Language: English
- Type: Thesis , Masters , Law
- Identifier: http://hdl.handle.net/10353/11663 , vital:39094
- Description: Recent remarks made by the current South African Minister of Health describing as a plot to ‘genocide’ a leaked document allegedly authored by a group of multinational pharmaceutical companies in response to the country’s Draft IP Policy is evidence of the importance of both pharmaceutical patents and the national intellectual property policies underpinning their legislative landscape. The proliferation of linkage evergreening provisions through multilateral agreements has also recently become a trend globally. Evergreening has been described as the various ways in which pharmaceutical patent owners use the law and related regulatory processes to extend the patent term of their high profit-making pharmaceuticals. The evergreening phenomenon has also been referred to as patent evergreening, which involves the practice of obtaining multiple patents that cover different aspects of the same product. Linkage evergreening however specifically refers to the phenomenon where generics pharmaceutical manufacturers cannot receive regulatory approval or marketing authorization for developing a pharmaceutical product that is still protected by a patent. The evergreening phenomenon is achieved through Free Trade Agreements (FTAs) which require participating nations to incorporate linkage and other intellectual property provisions in their national patent systems in exchange for preferential trade terms. These agreements generally provide for stronger provisions than the Agreement on Trade Related Aspects of Intellectual Property Rights (TRIPS) and are thus referred to as “TRIPS Plus". Not surprisingly, these “TRIPS Plus” FTAs are negotiated outside the purview of the World Trade Organization (WTO). This thesis examines the role, legality and impact of bilateral free trade agreements which include wide ranging provisions that allow the proliferation of linkage evergreening and thereby frustrate and delay generic medicines’ market entry, prolong and expand patent protections and constrain the exercise of TRIPS flexibilities intended to support access and promote public health. The free trade agreements discussed include the North American Free Trade Agreement (NAFTA), the US - Australia Free Trade Agreement (AUSFTA) and the US - Korea Free Trade Agreement (KORUSFTA). This study also examines the Economic Partnership Agreements (EPAs) in the context of access to medicines and linkage evergreening in developing countries and LDCs in Africa, with a focus on the recently concluded EU – SADC EPA and the EU-EAC EPA still under negotiation. Relevant legislation, policy documents and case law from South Africa, India, the EAC and ARIPO are also explored in this study to gauge their potential to effectively address the challenges of access to medicines and evergreening. This thesis offers a solution to evergreening through the recommendation of guidelines which show law and policy makers how to curtail linkage evergreening. More specifically, it is hoped that the said guidelines as well as the discussion and analyses presented in this thesis will assist in the development of national and regional intellectual property policies, amendment of national and regional legislative instruments as well as the negotiation of regional trade agreements aimed at securing the interests of LDCs and developing countries. It is further hoped that the recommendations made will contribute to ongoing efforts to improve access to affordable medicines in the developing world.
- Full Text:
- Authors: Omino, Akinyi Melissa Anne
- Date: 2016
- Subjects: Patent medicines--Developing countries Drugs--Developing countries Patent laws and legislation--Developing countries
- Language: English
- Type: Thesis , Masters , Law
- Identifier: http://hdl.handle.net/10353/11663 , vital:39094
- Description: Recent remarks made by the current South African Minister of Health describing as a plot to ‘genocide’ a leaked document allegedly authored by a group of multinational pharmaceutical companies in response to the country’s Draft IP Policy is evidence of the importance of both pharmaceutical patents and the national intellectual property policies underpinning their legislative landscape. The proliferation of linkage evergreening provisions through multilateral agreements has also recently become a trend globally. Evergreening has been described as the various ways in which pharmaceutical patent owners use the law and related regulatory processes to extend the patent term of their high profit-making pharmaceuticals. The evergreening phenomenon has also been referred to as patent evergreening, which involves the practice of obtaining multiple patents that cover different aspects of the same product. Linkage evergreening however specifically refers to the phenomenon where generics pharmaceutical manufacturers cannot receive regulatory approval or marketing authorization for developing a pharmaceutical product that is still protected by a patent. The evergreening phenomenon is achieved through Free Trade Agreements (FTAs) which require participating nations to incorporate linkage and other intellectual property provisions in their national patent systems in exchange for preferential trade terms. These agreements generally provide for stronger provisions than the Agreement on Trade Related Aspects of Intellectual Property Rights (TRIPS) and are thus referred to as “TRIPS Plus". Not surprisingly, these “TRIPS Plus” FTAs are negotiated outside the purview of the World Trade Organization (WTO). This thesis examines the role, legality and impact of bilateral free trade agreements which include wide ranging provisions that allow the proliferation of linkage evergreening and thereby frustrate and delay generic medicines’ market entry, prolong and expand patent protections and constrain the exercise of TRIPS flexibilities intended to support access and promote public health. The free trade agreements discussed include the North American Free Trade Agreement (NAFTA), the US - Australia Free Trade Agreement (AUSFTA) and the US - Korea Free Trade Agreement (KORUSFTA). This study also examines the Economic Partnership Agreements (EPAs) in the context of access to medicines and linkage evergreening in developing countries and LDCs in Africa, with a focus on the recently concluded EU – SADC EPA and the EU-EAC EPA still under negotiation. Relevant legislation, policy documents and case law from South Africa, India, the EAC and ARIPO are also explored in this study to gauge their potential to effectively address the challenges of access to medicines and evergreening. This thesis offers a solution to evergreening through the recommendation of guidelines which show law and policy makers how to curtail linkage evergreening. More specifically, it is hoped that the said guidelines as well as the discussion and analyses presented in this thesis will assist in the development of national and regional intellectual property policies, amendment of national and regional legislative instruments as well as the negotiation of regional trade agreements aimed at securing the interests of LDCs and developing countries. It is further hoped that the recommendations made will contribute to ongoing efforts to improve access to affordable medicines in the developing world.
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Relevance of the family assessment for least developed countries (FALDC) assessment tool rendering child protection services in the Eastern Cape, South Africa
- Authors: Mgidi, Siphelele
- Date: 2016
- Subjects: Child abuse -- South Africa -- Prevention Family social work -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/6335 , vital:29578
- Description: Assessment tools have been used for various purposes, including for protecting children from maltreatment. The main aim of this study was to to evaluate and determine the relevance of the Family Assessment for Leased Developed Countries (FALDC) assessment tool for child protection services in the Eastern Cape Province. The research was conducted using the social developmental welfare approach (Patel, 2005) and ecological systems theory (Healy, 2005). The study made use of the qualitative research method; in doing so the study made use of the case study design. In using the qualitative research method, focus group discussions were conducted with 29 social workers involved in child protection services. The findings of the study indicated that the FALDC assessment tool provides information useful for child protection services even though it contains sections that are regarded as less relevant to child protection. The study also founded that the FALDC assessment tool is relevant to child protection in the South African context, yet it needs to be aligned so that it provides much of the information desired by those involved in child protection. A conclusion drawn from this study is that the FALDC assessment tool appears to be relevant for child protection services. The FALDC assessment tool needs to be adjusted taking into consideration other aspects important to child protection in the South African child protection context.
- Full Text:
- Authors: Mgidi, Siphelele
- Date: 2016
- Subjects: Child abuse -- South Africa -- Prevention Family social work -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/6335 , vital:29578
- Description: Assessment tools have been used for various purposes, including for protecting children from maltreatment. The main aim of this study was to to evaluate and determine the relevance of the Family Assessment for Leased Developed Countries (FALDC) assessment tool for child protection services in the Eastern Cape Province. The research was conducted using the social developmental welfare approach (Patel, 2005) and ecological systems theory (Healy, 2005). The study made use of the qualitative research method; in doing so the study made use of the case study design. In using the qualitative research method, focus group discussions were conducted with 29 social workers involved in child protection services. The findings of the study indicated that the FALDC assessment tool provides information useful for child protection services even though it contains sections that are regarded as less relevant to child protection. The study also founded that the FALDC assessment tool is relevant to child protection in the South African context, yet it needs to be aligned so that it provides much of the information desired by those involved in child protection. A conclusion drawn from this study is that the FALDC assessment tool appears to be relevant for child protection services. The FALDC assessment tool needs to be adjusted taking into consideration other aspects important to child protection in the South African child protection context.
- Full Text:
Remediation of metal ions in aqueous solution using activated carbon from Zea may stem
- Authors: Matandabuzo, Mzukisi
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: vital:11360 , http://hdl.handle.net/10353/d1021328
- Description: Zea mays stem and its activated carbon were prepared through chemical activation method using four different activating reagents (NaOH, H₃PO₄, H₂SO₄, KOH) and were used as adsorbents for the removal of Pb(II), Cu(II), Hg(II) and Cr(III) from aqueous solution. The results shows that activated carbon has high surface area and pore volume compared to the powdered raw Zea mays stem. Prepared activated carbon was characterized using physico-chemical properties such as carbon yield, iodine number, moisture content, percentage adsorption, and analytical instruments such as Fourier transform Infrared spectroscopy (FTIR), atomic absorption spectrometer (AAS), scanning electron microscopy (SEM), Energy Dispersive X-ray analysis (EDS), powder X-ray Diffraction (pXRD). The adsorption of Pb(II), Cu(II), and Cr(III) ions were pH, contact time, and concentration dependent. Based on the results obtained from the batch experiments, activated carbon prepared from Zea mays stem is not good enough for the removal of Hg(II) from aqueous solution. Adsorption ability was calculated and found to be 66.67% for activated carbon obtained from H₂SO₄, 21.21% for activated carbon obtained from KOH, and 20% for activated carbons obtained from NaOH and H₃PO₄. The pH 5-6 was chosen for all experiments, contact time was 2 hours, and adsorbent dosage was 2 g, initial concentration range from 200, 400, 600, 800, and 1000 ppm at room temperature. The metal ion removal trend was found in the order Pb(II)>Cu(II)>Cr(III)>>Hg(II). The Langmuir model fitted well in most of the cases with > 0.99. Consequently, the adsorption of Pb(II) and Cu(II) followed Langmuir isotherm model while that of Cr(III) best fitted the Freundlich isotherm model. The results indicated that the adsorption process followed two possible mechanisms. (I) Metal ion – adsorbent complex model and (II) Metal ion – ion-exchange adsorbent complex model.
- Full Text:
- Authors: Matandabuzo, Mzukisi
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: vital:11360 , http://hdl.handle.net/10353/d1021328
- Description: Zea mays stem and its activated carbon were prepared through chemical activation method using four different activating reagents (NaOH, H₃PO₄, H₂SO₄, KOH) and were used as adsorbents for the removal of Pb(II), Cu(II), Hg(II) and Cr(III) from aqueous solution. The results shows that activated carbon has high surface area and pore volume compared to the powdered raw Zea mays stem. Prepared activated carbon was characterized using physico-chemical properties such as carbon yield, iodine number, moisture content, percentage adsorption, and analytical instruments such as Fourier transform Infrared spectroscopy (FTIR), atomic absorption spectrometer (AAS), scanning electron microscopy (SEM), Energy Dispersive X-ray analysis (EDS), powder X-ray Diffraction (pXRD). The adsorption of Pb(II), Cu(II), and Cr(III) ions were pH, contact time, and concentration dependent. Based on the results obtained from the batch experiments, activated carbon prepared from Zea mays stem is not good enough for the removal of Hg(II) from aqueous solution. Adsorption ability was calculated and found to be 66.67% for activated carbon obtained from H₂SO₄, 21.21% for activated carbon obtained from KOH, and 20% for activated carbons obtained from NaOH and H₃PO₄. The pH 5-6 was chosen for all experiments, contact time was 2 hours, and adsorbent dosage was 2 g, initial concentration range from 200, 400, 600, 800, and 1000 ppm at room temperature. The metal ion removal trend was found in the order Pb(II)>Cu(II)>Cr(III)>>Hg(II). The Langmuir model fitted well in most of the cases with > 0.99. Consequently, the adsorption of Pb(II) and Cu(II) followed Langmuir isotherm model while that of Cr(III) best fitted the Freundlich isotherm model. The results indicated that the adsorption process followed two possible mechanisms. (I) Metal ion – adsorbent complex model and (II) Metal ion – ion-exchange adsorbent complex model.
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Seasonal variations of essential oil composition and some biological evaluation of Pelargonium inquinans (L.) Ait. South Africa
- Authors: Tembeni, Babalwa
- Date: 2016
- Subjects: Pelargoniums Essences and essential oils Medicinal plants
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/6281 , vital:29537
- Description: Pelargonium inquinans which belongs to the family Geraniaceae, is an essential oil yielding plant. P. inquinans was collected from two different sites in Grahamstown (wild) and Alice, at the University of Fort Hare botanical garden. Authentication of the plant was done by Dr. T. Dold at Schonland herbarium, and the voucher specimen being T01. This study is focused at determining the chemical constituents and biological properties of the essential oils of wild and cultivated P. inquinans across different seasons, as the plant grows throughout the year. Seasonal collection of wild and cultivated P. inquinans was achieved in a duration of 12 months. 32 essential oil samples of P. inquinans were obtained by extraction using hydro-distillation technique for 3-4 hours. The chemical composition of the essential oils was determined using GC/MS and GC/FID. Amongst the 32 essential oils only 4 samples wild ( fresh stem and leaf) and cultivated ( fresh stem and leaf) from summer season were evaluated for analgesic activity using acetic acid induced writhings and hot plate nociception models in mice, anti-inflammatory activity was determined on the egg albumin- induced rat paw oedema in rats. The results obtained from GC-MS revealed a total of 169 components obtained from the leafstem, fresh/dry wild and cultivated P. inquinans. These essential oils showed a great deal of chemotaxonomic variation and similarity in the major and minor components along the season. In spring season the essential oils of wild and cultivated P. inquinans had abundance of hydrogenated sesquiterpenes (20.6percent-66.7percent). The major components were found to be α-caryophyllene (9.1percent-26.8percent), p-xylene (23.3percent-27.5percent), β-caryophyllene (11.4percent-30.9percent), o-xylene (6.3percent-39.4percent), β-thujene (8.7percent), isocaryophyllene (13.9percent), isoborneol (14.2percent), β-myrcene (5.7percent), geranyl acetate (13.8percent), toluene (7.9percent), β-gurjunene (18.5percent), α-cadinene (15.8percent), β-farnesene (14.2percent), 3-carene (12.1percent) and camphene (9.0percent). In summer season the essential oils of wild and cultivated P. inquinans were found to have abundance of hydrogenated sesquiterpenes (50.3percent- 63.0percent), oxygenated monoterpenes (30.4percent) and hydrogenated monoterpenes (20.8percent- 61.0percent). The major components were found to be α-caryophyllene (12.3percent-25.8percent), β-caryophyllene (15.1percent- 31.7percent), trans-caryophyllene (10.3percent- 17.8percent), phytol (14.2percent- 20.2percent), camphor (46.5percent), sabinene (27.8percent), elemol (18.1percent), z3-hexenyl isobutyrate (16.3percent), limonene (12.1percent), menthone (12.1percent)< E.E-β-farnesene (14.7percent), palmitic acid (9.6percent), eugenol (9.4percent), cis- β-ocimene (8.7percent), α-terpineol (8.7percent), geranyl acetone (7.8percent), β- humulene (7.5percent). linoleic acid (7.4percent), trans-linalool oxide (7.4percent), β-bisabolene (7.1percent), cis- linalool oxide (7.1percent), ionone (6.9percent), caryophyllene oxide (6.9percent) and germacrene d (6.3percent). In autumn season the essential oils of wild and cultivated P. inquinans were found to be rich in hydrogenated sesquiterpenes (29.3percent- 65.2percent) and oxygenated sesquiterpenes (22.8percent- 31.4percent). The major components were found to be α-caryophyllene (15.5percent- 23.4percent), β-caryophyllene (15.2percent- 17.2percent), β-myrcene (7.7percent-13.8percent), β-humulene (8.7percent- 15.2percent), caryophyllene oxide (9.8- 16.2percent), trans- caryophyllene (16.7percent- 23.3percent), α-humulene (11.8percent- 18.6percent), linoleic acid (11.2percent), palmitic acid (10.4percent), phytol acetate (8.5percent), -longipinene (8.3percent) and citronellol (7.8percent). In winter season the essential oils of wild and cultivated P. inquinans were found to have abundance of hydrogenated sesquiterpenes (25.1percent- 48.6percent), oxygenated monoterpenes (47.6percent), oxygenated sesquiterpenes (22.2percent- 28.0percent). The major components were found to be β-caryophyllene (14.6percent- 23.0percent), α-caryophyllene (9.4percent- 18.0percent), trans- caryophyllene (12.2percent- 14.6percent), α-cedrene (26.2percent), germacrene –d-4-ol (16.8percent), 2,6-dihydroxyacetophenone (15.6percent), (+) epibicyclosesquiphellandrene (15.3percent), E-β- farnesene (13.0percent), β-phellandrene (11.7percent), 2-nitrophenol (9.5percent), palatinol (8.4percent), geranyl acetate (7.7percent) and linoleic acid (7.4percent). The oils from the wild and cultivated sources showed significant (p<0.05-0.001) decrease in number of writhes induced by the acetic acid compared to vehicle; caused significant (p<0.05-0.001) delay in reaction time on the hot plate at 60 and 90 min post-treatment and significantly (p<0.05-0.001) reduced oedema size caused by the egg albumin injection compared to the vehicle. The oils from the wild plant showed more potency compared to the cultivated. The essential oils of wild and cultivated P. inquinans showed qualitative, quantitative and chemotaxonomic variation with analgesic and anti-inflammatory activity. These essential oils need to be explored for further biological analysis because of the major components they contain.
- Full Text:
- Authors: Tembeni, Babalwa
- Date: 2016
- Subjects: Pelargoniums Essences and essential oils Medicinal plants
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/6281 , vital:29537
- Description: Pelargonium inquinans which belongs to the family Geraniaceae, is an essential oil yielding plant. P. inquinans was collected from two different sites in Grahamstown (wild) and Alice, at the University of Fort Hare botanical garden. Authentication of the plant was done by Dr. T. Dold at Schonland herbarium, and the voucher specimen being T01. This study is focused at determining the chemical constituents and biological properties of the essential oils of wild and cultivated P. inquinans across different seasons, as the plant grows throughout the year. Seasonal collection of wild and cultivated P. inquinans was achieved in a duration of 12 months. 32 essential oil samples of P. inquinans were obtained by extraction using hydro-distillation technique for 3-4 hours. The chemical composition of the essential oils was determined using GC/MS and GC/FID. Amongst the 32 essential oils only 4 samples wild ( fresh stem and leaf) and cultivated ( fresh stem and leaf) from summer season were evaluated for analgesic activity using acetic acid induced writhings and hot plate nociception models in mice, anti-inflammatory activity was determined on the egg albumin- induced rat paw oedema in rats. The results obtained from GC-MS revealed a total of 169 components obtained from the leafstem, fresh/dry wild and cultivated P. inquinans. These essential oils showed a great deal of chemotaxonomic variation and similarity in the major and minor components along the season. In spring season the essential oils of wild and cultivated P. inquinans had abundance of hydrogenated sesquiterpenes (20.6percent-66.7percent). The major components were found to be α-caryophyllene (9.1percent-26.8percent), p-xylene (23.3percent-27.5percent), β-caryophyllene (11.4percent-30.9percent), o-xylene (6.3percent-39.4percent), β-thujene (8.7percent), isocaryophyllene (13.9percent), isoborneol (14.2percent), β-myrcene (5.7percent), geranyl acetate (13.8percent), toluene (7.9percent), β-gurjunene (18.5percent), α-cadinene (15.8percent), β-farnesene (14.2percent), 3-carene (12.1percent) and camphene (9.0percent). In summer season the essential oils of wild and cultivated P. inquinans were found to have abundance of hydrogenated sesquiterpenes (50.3percent- 63.0percent), oxygenated monoterpenes (30.4percent) and hydrogenated monoterpenes (20.8percent- 61.0percent). The major components were found to be α-caryophyllene (12.3percent-25.8percent), β-caryophyllene (15.1percent- 31.7percent), trans-caryophyllene (10.3percent- 17.8percent), phytol (14.2percent- 20.2percent), camphor (46.5percent), sabinene (27.8percent), elemol (18.1percent), z3-hexenyl isobutyrate (16.3percent), limonene (12.1percent), menthone (12.1percent)< E.E-β-farnesene (14.7percent), palmitic acid (9.6percent), eugenol (9.4percent), cis- β-ocimene (8.7percent), α-terpineol (8.7percent), geranyl acetone (7.8percent), β- humulene (7.5percent). linoleic acid (7.4percent), trans-linalool oxide (7.4percent), β-bisabolene (7.1percent), cis- linalool oxide (7.1percent), ionone (6.9percent), caryophyllene oxide (6.9percent) and germacrene d (6.3percent). In autumn season the essential oils of wild and cultivated P. inquinans were found to be rich in hydrogenated sesquiterpenes (29.3percent- 65.2percent) and oxygenated sesquiterpenes (22.8percent- 31.4percent). The major components were found to be α-caryophyllene (15.5percent- 23.4percent), β-caryophyllene (15.2percent- 17.2percent), β-myrcene (7.7percent-13.8percent), β-humulene (8.7percent- 15.2percent), caryophyllene oxide (9.8- 16.2percent), trans- caryophyllene (16.7percent- 23.3percent), α-humulene (11.8percent- 18.6percent), linoleic acid (11.2percent), palmitic acid (10.4percent), phytol acetate (8.5percent), -longipinene (8.3percent) and citronellol (7.8percent). In winter season the essential oils of wild and cultivated P. inquinans were found to have abundance of hydrogenated sesquiterpenes (25.1percent- 48.6percent), oxygenated monoterpenes (47.6percent), oxygenated sesquiterpenes (22.2percent- 28.0percent). The major components were found to be β-caryophyllene (14.6percent- 23.0percent), α-caryophyllene (9.4percent- 18.0percent), trans- caryophyllene (12.2percent- 14.6percent), α-cedrene (26.2percent), germacrene –d-4-ol (16.8percent), 2,6-dihydroxyacetophenone (15.6percent), (+) epibicyclosesquiphellandrene (15.3percent), E-β- farnesene (13.0percent), β-phellandrene (11.7percent), 2-nitrophenol (9.5percent), palatinol (8.4percent), geranyl acetate (7.7percent) and linoleic acid (7.4percent). The oils from the wild and cultivated sources showed significant (p<0.05-0.001) decrease in number of writhes induced by the acetic acid compared to vehicle; caused significant (p<0.05-0.001) delay in reaction time on the hot plate at 60 and 90 min post-treatment and significantly (p<0.05-0.001) reduced oedema size caused by the egg albumin injection compared to the vehicle. The oils from the wild plant showed more potency compared to the cultivated. The essential oils of wild and cultivated P. inquinans showed qualitative, quantitative and chemotaxonomic variation with analgesic and anti-inflammatory activity. These essential oils need to be explored for further biological analysis because of the major components they contain.
- Full Text:
Self-reflection practices of school-management teams in the Capricorn District : towards a reflective management strategy for South African schools
- Authors: Malatji, Khashane Stephen
- Date: 2016
- Subjects: School management teams -- South Africa Educational leadership -- South Africa School management and organization -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/3021 , vital:28238
- Description: The study investigated the self-reflection practices of School Management Teams (SMTs) in the Capricorn District. The purpose of the study was to establish self-reflective practices employed by SMT in performing their management functions, and to suggest a reflective model for the enhancement of SMT performance. The study followed the qualitative approach with a case-study research design. The population consisted of SMTs from primary, secondary and special schools. Purposive sampling was utilised to select 8 Head of Departments from less experienced to more experienced in management positions, while 9 principal and 9 deputy principals were randomly selected. Literature reviewed focused on the aims of self-reflection; the functions of SMT; the strengths and weaknesses of self-reflection; self-reflective practices and enhanced performance; models of school management; challenges in school management; and previous studies on SMT and school management. Henderson’s Ethical Model of Enquiry on reflective practice was used. The theory discusses what characterises reflective practitioners. Data was collected from quest views, individual interviews and focus group interviews. The interpretation and understanding were organised in the form of descriptive accounts. Tape-recorded interviews and data from quest views were transcribed verbatim. After transcribing data a sense of the whole was obtained by reading carefully with understanding, and then summarizing the salient aspects. Themes were identified from the responses and discussed. The study found that SMT members were not fully aware of all of their daily functions and poor reflective practices made it difficult for them to effectively fulfil their management functions. Furthermore, the study revealed that SMT members experienced challenges, such as dealing with unprofessional teachers, poor parental involvement, poor communication, poor infrastructure and lack of resources amd these impacted negatively on their performance. The study provided insights into the practice of self-reflection and how SMT members could become reflective practitioners. A new framework was suggested that SMTs should continuously and critically reflect on their management practices and decisions. The study recommends that SMT be trained and oriented about management functions prior to their appointment in the positions. The study further recommends that SMTs consider self-reflection as part of their daily activities.
- Full Text:
- Authors: Malatji, Khashane Stephen
- Date: 2016
- Subjects: School management teams -- South Africa Educational leadership -- South Africa School management and organization -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/3021 , vital:28238
- Description: The study investigated the self-reflection practices of School Management Teams (SMTs) in the Capricorn District. The purpose of the study was to establish self-reflective practices employed by SMT in performing their management functions, and to suggest a reflective model for the enhancement of SMT performance. The study followed the qualitative approach with a case-study research design. The population consisted of SMTs from primary, secondary and special schools. Purposive sampling was utilised to select 8 Head of Departments from less experienced to more experienced in management positions, while 9 principal and 9 deputy principals were randomly selected. Literature reviewed focused on the aims of self-reflection; the functions of SMT; the strengths and weaknesses of self-reflection; self-reflective practices and enhanced performance; models of school management; challenges in school management; and previous studies on SMT and school management. Henderson’s Ethical Model of Enquiry on reflective practice was used. The theory discusses what characterises reflective practitioners. Data was collected from quest views, individual interviews and focus group interviews. The interpretation and understanding were organised in the form of descriptive accounts. Tape-recorded interviews and data from quest views were transcribed verbatim. After transcribing data a sense of the whole was obtained by reading carefully with understanding, and then summarizing the salient aspects. Themes were identified from the responses and discussed. The study found that SMT members were not fully aware of all of their daily functions and poor reflective practices made it difficult for them to effectively fulfil their management functions. Furthermore, the study revealed that SMT members experienced challenges, such as dealing with unprofessional teachers, poor parental involvement, poor communication, poor infrastructure and lack of resources amd these impacted negatively on their performance. The study provided insights into the practice of self-reflection and how SMT members could become reflective practitioners. A new framework was suggested that SMTs should continuously and critically reflect on their management practices and decisions. The study recommends that SMT be trained and oriented about management functions prior to their appointment in the positions. The study further recommends that SMTs consider self-reflection as part of their daily activities.
- Full Text:
Smallholder farmer's adoption decision-making processes in the utilisation of soil conservation practices in South Africa: the case of Qamata Irrigation Scheme, in the Eastern Cape
- Authors: David, Ighodaro Ikponmwosa
- Date: 2016
- Subjects: Qamata Irrigation Scheme (South Africa) Irrigation -- South Africa -- Eastern Cape Farm management -- South Africa -- Decision making , Farms, Small -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/1740 , vital:27554
- Description: The goal of this study was to determine the nature and factors influencing smallholder farmers in their adoption decision-making regarding the use of soil conservation practices introduced by extension practitioners in South Africa, using the case of farming at Qamata Irrigation Scheme, Eastern Cape. Using a central argument (thesis statement), the study argued that an adequate understanding and definition of smallholder farmers’ adoption decision-making process is very crucial to solving the problem of soil erosion/ degradation problem amongst smallholder farmers. Adopting the case study research design, information from 70 crop farmers (in a farmer focus group interviews) form the basis of the study. Basic models of analysis were the multiple, probit and logit, as well as the binary logistic regression analyses. According to the empirical results, perception was found very relevant in adoption decision-making, interacting positively and significantly with eight of the seventeen adoption variables chosen for the study. The indication therefore is that age (p<0.050), education (p<0.0030), and marriage (p<0.036), have more potentials to improve farmers’ perception. Similarly, higher farmer incomes (from crops [p<0.017], off-farm [p<0.038] and overall [p<0.011] income) also have a likelihood to improve farmers’ perception regarding soil conservation, for improved adoption. Further indication is that farmers who are aware (p<0.015) of the soil practices introduced by extension are also those who participate in their use (p<0.041). Employing the binary logistic, probit and logit regression models, results suggest that the nature of adoption decision-making processes of smallholder farmers is complex (not straight), being influenced by multiple factors. While age (p<0.099), gender (p<0.031), total income (p<0.081) impacted positively significant on smallholder farmers’ adoption decision-making, marital status (p<0.025), sources of land (p<0.063), length of continuously farming on same piece of land (p<0.013), and level of crop production (p<0.002) impacted negatively. The indication therefore was that older farmers preferred their own practices to the recommended practices by extension, which is in line with literature. Also as expected, more females preferred their own practices to extension recommended, while more males preferred the recommended practices. Similarly, marriage, land ownership, farming continuously on a spot for a long period, as well as increase in the level of crop production, all had a propensity to influence farmers toward the adoption of extension recommended practices as against farmers’ practices. Further results indicate, that farmers’ education (p<0.032), household size (p<0.37), and income (off-farm [p<0.036] and total [p<0.004]), measures used to measure farmers’ livelihood standards in the study, were positively significant in association with adoption. The indication was that, adoption decision-making is potentially capable of improving education level of farmers; increase the size of household, thus providing easy family labour; and as well improve level of income for the farmer. Based on the foregoing, the suggestion therefore is that any technology intervention programme that will succeed must begin with a clear understanding and analysis of farmers’ adoption process. This is better achieved when the adoption process is seen as a four-stage process, where the farmer first forms a view about the innovation (perception stage), and then decides whether or not to use it (adoption stage), as well as how much of the innovation to adopt (level of adoption stage), and finally how much is this innovation going to affect my livelihood (impact of adoption stage). Also, due to the particular relevance of perception in the adoption decision-making process, technology disseminators (extension), researchers and policy makers alike must never conclude on the rejection of any technology, not until factors determining perception of individuals have been well studied. The notion here is that, even at the confirmation stage of the adoption process of an individual adopter, when a rejection is confirmed, for an example, analysing factors of the adopter’s perception at play at the particular time of the innovation in question, could go a long way to redirecting the course of the adoption process of the said individual.
- Full Text:
- Authors: David, Ighodaro Ikponmwosa
- Date: 2016
- Subjects: Qamata Irrigation Scheme (South Africa) Irrigation -- South Africa -- Eastern Cape Farm management -- South Africa -- Decision making , Farms, Small -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/1740 , vital:27554
- Description: The goal of this study was to determine the nature and factors influencing smallholder farmers in their adoption decision-making regarding the use of soil conservation practices introduced by extension practitioners in South Africa, using the case of farming at Qamata Irrigation Scheme, Eastern Cape. Using a central argument (thesis statement), the study argued that an adequate understanding and definition of smallholder farmers’ adoption decision-making process is very crucial to solving the problem of soil erosion/ degradation problem amongst smallholder farmers. Adopting the case study research design, information from 70 crop farmers (in a farmer focus group interviews) form the basis of the study. Basic models of analysis were the multiple, probit and logit, as well as the binary logistic regression analyses. According to the empirical results, perception was found very relevant in adoption decision-making, interacting positively and significantly with eight of the seventeen adoption variables chosen for the study. The indication therefore is that age (p<0.050), education (p<0.0030), and marriage (p<0.036), have more potentials to improve farmers’ perception. Similarly, higher farmer incomes (from crops [p<0.017], off-farm [p<0.038] and overall [p<0.011] income) also have a likelihood to improve farmers’ perception regarding soil conservation, for improved adoption. Further indication is that farmers who are aware (p<0.015) of the soil practices introduced by extension are also those who participate in their use (p<0.041). Employing the binary logistic, probit and logit regression models, results suggest that the nature of adoption decision-making processes of smallholder farmers is complex (not straight), being influenced by multiple factors. While age (p<0.099), gender (p<0.031), total income (p<0.081) impacted positively significant on smallholder farmers’ adoption decision-making, marital status (p<0.025), sources of land (p<0.063), length of continuously farming on same piece of land (p<0.013), and level of crop production (p<0.002) impacted negatively. The indication therefore was that older farmers preferred their own practices to the recommended practices by extension, which is in line with literature. Also as expected, more females preferred their own practices to extension recommended, while more males preferred the recommended practices. Similarly, marriage, land ownership, farming continuously on a spot for a long period, as well as increase in the level of crop production, all had a propensity to influence farmers toward the adoption of extension recommended practices as against farmers’ practices. Further results indicate, that farmers’ education (p<0.032), household size (p<0.37), and income (off-farm [p<0.036] and total [p<0.004]), measures used to measure farmers’ livelihood standards in the study, were positively significant in association with adoption. The indication was that, adoption decision-making is potentially capable of improving education level of farmers; increase the size of household, thus providing easy family labour; and as well improve level of income for the farmer. Based on the foregoing, the suggestion therefore is that any technology intervention programme that will succeed must begin with a clear understanding and analysis of farmers’ adoption process. This is better achieved when the adoption process is seen as a four-stage process, where the farmer first forms a view about the innovation (perception stage), and then decides whether or not to use it (adoption stage), as well as how much of the innovation to adopt (level of adoption stage), and finally how much is this innovation going to affect my livelihood (impact of adoption stage). Also, due to the particular relevance of perception in the adoption decision-making process, technology disseminators (extension), researchers and policy makers alike must never conclude on the rejection of any technology, not until factors determining perception of individuals have been well studied. The notion here is that, even at the confirmation stage of the adoption process of an individual adopter, when a rejection is confirmed, for an example, analysing factors of the adopter’s perception at play at the particular time of the innovation in question, could go a long way to redirecting the course of the adoption process of the said individual.
- Full Text:
Solid waste management and its implications on livestock health in selected abattoirs of the Eastern Cape province, South Africa
- Authors: Nongcula, Vikhaya Vincent
- Date: 2016
- Subjects: Refuse and refuse disposal -- South Africa -- Eastern Cape Recycling (Waste, etc.) -- South Africa -- Eastern Cape Livestock -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12293 , vital:39250
- Description: An investigation was carried out on the implications of solid waste management on livestock health in selected abattoirs of the Eastern Cape Province of South Africa. The main objective of the study was to determine the effects of solid waste management on livestock health as well as to assess the perceptions of solid waste management among livestock owners. In this study, a questionnaire was designed to obtain information regarding farmer’s perceptions on solid waste and how it affects animal health, and active abattoir inspection were conducted to assess how solid waste affects the animal. The results revealed that most farmers practiced poor solid waste management as a result animals were exposed to ingestion of indigestible materials. This was confirmed on the basis that most farmers (99.2 percent) had no municipal dustbins in their areas, no recycling programmes (94.2 percent) and 51.7percent of the farmers disposed their litter in open land as a result most farmers (75.9percent) agreed that solid waste management was a problem in their areas. Due to poor solid waste management, 53.8 percent of the farmers confirmed that they have seen livestock ingesting indigestible materials such as plastics and 69.0 percent of the farmers suspected that ingestion of such materials caused some of the health issue experienced by animals on their farm. The active abattoir inspection revealed that plastics, wires, nails, ropes, stones, bones, cloths, hairs and polybezoars were frequently occurring in slaughter cattle stomachs particularly in the rumen and reticulum and in female and older cattle. As a result most affected cattle were in thin and average condition. The effect of indigestible objects on body condition score (BCS) and organ condemnation was determined using linear regression analysis test; where BCS and condemnation were the dependent variables and indigestible objects were the independent variables. The results revealed that some organs were condemned in affected cattle and the statistical analysis showed that there was no significant difference (p< 0.05) between the prevalence of indigestible materials and organ condemnation. However, there was a significant difference between the prevalence of indigestible materials and body condition score of affected cattle although they were coming from different farming systems. It was concluded that livestock health was affected by solid waste and recommended that practice of good animal husbandry and proper solid waste management be practiced to overcome the implications (poor body condition score) of solid waste in livestock. Furthermore, close cooperation between government extension officers, commercial and communal farmers in knowledge-sharing regarding health issues of livestock is recommended.
- Full Text:
- Authors: Nongcula, Vikhaya Vincent
- Date: 2016
- Subjects: Refuse and refuse disposal -- South Africa -- Eastern Cape Recycling (Waste, etc.) -- South Africa -- Eastern Cape Livestock -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12293 , vital:39250
- Description: An investigation was carried out on the implications of solid waste management on livestock health in selected abattoirs of the Eastern Cape Province of South Africa. The main objective of the study was to determine the effects of solid waste management on livestock health as well as to assess the perceptions of solid waste management among livestock owners. In this study, a questionnaire was designed to obtain information regarding farmer’s perceptions on solid waste and how it affects animal health, and active abattoir inspection were conducted to assess how solid waste affects the animal. The results revealed that most farmers practiced poor solid waste management as a result animals were exposed to ingestion of indigestible materials. This was confirmed on the basis that most farmers (99.2 percent) had no municipal dustbins in their areas, no recycling programmes (94.2 percent) and 51.7percent of the farmers disposed their litter in open land as a result most farmers (75.9percent) agreed that solid waste management was a problem in their areas. Due to poor solid waste management, 53.8 percent of the farmers confirmed that they have seen livestock ingesting indigestible materials such as plastics and 69.0 percent of the farmers suspected that ingestion of such materials caused some of the health issue experienced by animals on their farm. The active abattoir inspection revealed that plastics, wires, nails, ropes, stones, bones, cloths, hairs and polybezoars were frequently occurring in slaughter cattle stomachs particularly in the rumen and reticulum and in female and older cattle. As a result most affected cattle were in thin and average condition. The effect of indigestible objects on body condition score (BCS) and organ condemnation was determined using linear regression analysis test; where BCS and condemnation were the dependent variables and indigestible objects were the independent variables. The results revealed that some organs were condemned in affected cattle and the statistical analysis showed that there was no significant difference (p< 0.05) between the prevalence of indigestible materials and organ condemnation. However, there was a significant difference between the prevalence of indigestible materials and body condition score of affected cattle although they were coming from different farming systems. It was concluded that livestock health was affected by solid waste and recommended that practice of good animal husbandry and proper solid waste management be practiced to overcome the implications (poor body condition score) of solid waste in livestock. Furthermore, close cooperation between government extension officers, commercial and communal farmers in knowledge-sharing regarding health issues of livestock is recommended.
- Full Text:
South Africa's 2015 immigration regulations and the controversy concerning the right of the child traveller
- Muvhevhi, Roseline Rumbidzai
- Authors: Muvhevhi, Roseline Rumbidzai
- Date: 2016
- Subjects: Emigration and immigration law -- South Africa Emigration and Immigration -- Government policy -- South Africa
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/5422 , vital:29232
- Description: Over the years, human trafficking has become one of the fastest growing crimes in the world. According to a report of the United Nations Office on Drugs and Crime, Women and Children account for 75 percent of trafficked victims. Between 2007 and 2010, children accounted for 20 percent of the trafficked victims which is approximately 1343 children per year. Sadly, these statistics continue to rise annually. It is from this premise that no one can doubt the rationale behind the 2015 Immigration Regulations that affect children travelling in and out of South Africa. However, in terms of section 28 (2) of the Constitution of the Republic of South Africa, it is a prerequisite that in any matter affecting a child, the best interest of the child be of paramount importance. This mini dissertation seeks to establish whether these Immigration Regulations which initially came into effect in May 2014, are in the best interest of child travellers. This has been done by looking at the old system which regulated the movement of children; its loopholes and shortcomings, thereby establishing whether Regulation 6 (12) is a panacea or in fact the hallmark of a series of problems that have a detrimental effect on the well-being as well as the rights of the child. The research methodology is mainly based on a study of existing literature. This largely includes internet sources, national legislation, regional and international instruments as well as case law. The South African Immigration Act 2002 is the primary reference with regards to regulatory information. However, lessons are drawn from legislation from other jurisdictions, notably Zimbabwean Immigration laws as well as those of Namibia. This is because South Africa shares a border with Zimbabwe and it also has a historical connection with Namibia and has good relations with both States. The mini dissertation analyses the impact of the 2015 Immigration Regulations not only on children but on other sectors as well. Lastly, the latter makes recommendations on how to improve these Regulations without affecting the best interest of child travellers.
- Full Text:
- Authors: Muvhevhi, Roseline Rumbidzai
- Date: 2016
- Subjects: Emigration and immigration law -- South Africa Emigration and Immigration -- Government policy -- South Africa
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/5422 , vital:29232
- Description: Over the years, human trafficking has become one of the fastest growing crimes in the world. According to a report of the United Nations Office on Drugs and Crime, Women and Children account for 75 percent of trafficked victims. Between 2007 and 2010, children accounted for 20 percent of the trafficked victims which is approximately 1343 children per year. Sadly, these statistics continue to rise annually. It is from this premise that no one can doubt the rationale behind the 2015 Immigration Regulations that affect children travelling in and out of South Africa. However, in terms of section 28 (2) of the Constitution of the Republic of South Africa, it is a prerequisite that in any matter affecting a child, the best interest of the child be of paramount importance. This mini dissertation seeks to establish whether these Immigration Regulations which initially came into effect in May 2014, are in the best interest of child travellers. This has been done by looking at the old system which regulated the movement of children; its loopholes and shortcomings, thereby establishing whether Regulation 6 (12) is a panacea or in fact the hallmark of a series of problems that have a detrimental effect on the well-being as well as the rights of the child. The research methodology is mainly based on a study of existing literature. This largely includes internet sources, national legislation, regional and international instruments as well as case law. The South African Immigration Act 2002 is the primary reference with regards to regulatory information. However, lessons are drawn from legislation from other jurisdictions, notably Zimbabwean Immigration laws as well as those of Namibia. This is because South Africa shares a border with Zimbabwe and it also has a historical connection with Namibia and has good relations with both States. The mini dissertation analyses the impact of the 2015 Immigration Regulations not only on children but on other sectors as well. Lastly, the latter makes recommendations on how to improve these Regulations without affecting the best interest of child travellers.
- Full Text:
South Africa's 2015 immigration regulations and the controversy concerning the right of the child traveller
- Muvhevhi, Roseline Rumbidzai
- Authors: Muvhevhi, Roseline Rumbidzai
- Date: 2016
- Subjects: Emigration and immigration law Emigration and Immigration -- Government policy -- South Africa
- Language: English
- Type: Thesis , Masters , MA (Human Rights)
- Identifier: http://hdl.handle.net/10353/2545 , vital:27890
- Description: Over the years, human trafficking has become one of the fastest growing crimes in the world. According to a report of the United Nations Office on Drugs and Crime, Women and Children account for 75 percent of trafficked victims. Between 2007 and 2010, children accounted for 20 percent of the trafficked victims which is approximately 1343 children per year. Sadly, these statistics continue to rise annually. It is from this premise that no one can doubt the rationale behind the 2015 Immigration Regulations that affect children travelling in and out of South Africa. However, in terms of section 28 (2) of the Constitution of the Republic of South Africa, it is a prerequisite that in any matter affecting a child, the best interest of the child be of paramount importance. This mini dissertation seeks to establish whether these Immigration Regulations which initially came into effect in May 2014, are in the best interest of child travellers. This has been done by looking at the old system which regulated the movement of children; its loopholes and shortcomings, thereby establishing whether Regulation 6 (12) is a panacea or in fact the hallmark of a series of problems that have a detrimental effect on the well-being as well as the rights of the child. The research methodology is mainly based on a study of existing literature. This largely includes internet sources, national legislation, regional and international instruments as well as case law. The South African Immigration Act 2002 is the primary reference with regards to regulatory information. However, lessons are drawn from legislation from other jurisdictions, notably Zimbabwean Immigration laws as well as those of Namibia. This is because South Africa shares a border with Zimbabwe and it also has a historical connection with Namibia and has good relations with both States. The mini dissertation analyses the impact of the 2015 Immigration Regulations not only on children but on other sectors as well. Lastly, the latter makes recommendations on how to improve these Regulations without affecting the best interest of child travellers.
- Full Text:
- Authors: Muvhevhi, Roseline Rumbidzai
- Date: 2016
- Subjects: Emigration and immigration law Emigration and Immigration -- Government policy -- South Africa
- Language: English
- Type: Thesis , Masters , MA (Human Rights)
- Identifier: http://hdl.handle.net/10353/2545 , vital:27890
- Description: Over the years, human trafficking has become one of the fastest growing crimes in the world. According to a report of the United Nations Office on Drugs and Crime, Women and Children account for 75 percent of trafficked victims. Between 2007 and 2010, children accounted for 20 percent of the trafficked victims which is approximately 1343 children per year. Sadly, these statistics continue to rise annually. It is from this premise that no one can doubt the rationale behind the 2015 Immigration Regulations that affect children travelling in and out of South Africa. However, in terms of section 28 (2) of the Constitution of the Republic of South Africa, it is a prerequisite that in any matter affecting a child, the best interest of the child be of paramount importance. This mini dissertation seeks to establish whether these Immigration Regulations which initially came into effect in May 2014, are in the best interest of child travellers. This has been done by looking at the old system which regulated the movement of children; its loopholes and shortcomings, thereby establishing whether Regulation 6 (12) is a panacea or in fact the hallmark of a series of problems that have a detrimental effect on the well-being as well as the rights of the child. The research methodology is mainly based on a study of existing literature. This largely includes internet sources, national legislation, regional and international instruments as well as case law. The South African Immigration Act 2002 is the primary reference with regards to regulatory information. However, lessons are drawn from legislation from other jurisdictions, notably Zimbabwean Immigration laws as well as those of Namibia. This is because South Africa shares a border with Zimbabwe and it also has a historical connection with Namibia and has good relations with both States. The mini dissertation analyses the impact of the 2015 Immigration Regulations not only on children but on other sectors as well. Lastly, the latter makes recommendations on how to improve these Regulations without affecting the best interest of child travellers.
- Full Text:
Spatio-temporal analyses of woody vegetation cover using remote sensing techniques: the case of Alice - King Williams Town route, Eastern Cape, South Africa
- Authors: Fundisi, Emmanuel
- Date: 2016
- Subjects: Woody plants -- South Africa -- Eastern Cape Vegetation classification -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/1830 , vital:27564
- Description: Expansion of woody vegetation results in the transformation of a grass-dominated ecosystem to a tree-dominated ecosystem causing land degradation in most semi-arid areas. The imbalance in the natural ecosystem between herbaceous plants and woody vegetation poses a threat to the natural environment. Such changes alter the flow, availability and quality of nutrient resources in the biogeochemical cycle. Most of the dominating woody plants are often unpalatable to domestic livestock. Therefore, the objective is to assess the spatial extent of woody vegetation over time. Knowledge of the spatial and temporal characteristics of woody vegetation dynamics will enable the development of management plans. These characteristics can be derived using remote sensing techniques which have become efficient in such studies. This study aimed to characterize woody vegetation dynamics along the route between Alice and King Williams’s town in Eastern Cape Province South Africa using Landsat data. This aim was achieved by focussing on three specific objectives. The first objective was to compare the performance of multispectral data and Normalized Difference Vegetation Index (NDVI) data of Landsat imagery in mapping woody vegetation cover. The second objective was to investigate the effect of the spatial resolution of remotely-sensed data on discrimination of woody vegetation from other land cover types. The third objective characterised woody vegetation dynamics between 1986 and 2013/2014 using the results from the first objective. The study used Landsat imagery acquired in November or February of 1986, 1994/1995, 2002/2003 and 2013/2014. Due to lack of data which covered the study area two separate dates (November and February) where used for the study resulting in naming the study area western and eastern parts. Unsupervised classification was performed on the multispectral, NDVI and pan-sharpened images to generate four generic land cover classes, namely water, bare land, grassland and woodland. Accuracy assessments of the classified images was done using error matrix. The results showed that the classification based on NDVI images yielded a better overall accuracy than the classification based on multispectral images for the western (83 percent and 75 percent, respectively) and eastern (82 percent and 76 percent, respectively) parts of the study area. Similarly, pan-sharpening resulted in better overall classification accuracy than multispectral, but comparable to the classification of the NDVI images for both the western (82 percent) and eastern (83 percent) parts of the study area. Remote sensing is an effective tool in assessing changes in the physical environment. Landsat imagery is suitable in assessing land cover dynamics given the long-term and free availability of the image. In addition, the large spatial coverage it provides, enables Landsat data to be used on studies that have wide spatial coverage. Classification for the purpose of time-series analysis was then performed on the NDVI images of each date (1986, 1994/1995, 2002/2003 and 2013/2014). Both woody vegetation and grassland experienced changes from 1986 to 2013/2014 with grassland occupying (75 percent) compared to woodland (17 percent) in 1986. In the year 2013/14 grassland occupied 32 percent and woodland occupied 51 percent of the study area. The increase in woody vegetation in the study area can be attributed to livestock rearing and migration of people from the rural to urban areas post-Apartheid. The study output will aid in the development of a database on land cover distribution of the area between King William’s town and Alice town, providing useful information to decision-making and further studies on woody vegetation.
- Full Text:
- Authors: Fundisi, Emmanuel
- Date: 2016
- Subjects: Woody plants -- South Africa -- Eastern Cape Vegetation classification -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/1830 , vital:27564
- Description: Expansion of woody vegetation results in the transformation of a grass-dominated ecosystem to a tree-dominated ecosystem causing land degradation in most semi-arid areas. The imbalance in the natural ecosystem between herbaceous plants and woody vegetation poses a threat to the natural environment. Such changes alter the flow, availability and quality of nutrient resources in the biogeochemical cycle. Most of the dominating woody plants are often unpalatable to domestic livestock. Therefore, the objective is to assess the spatial extent of woody vegetation over time. Knowledge of the spatial and temporal characteristics of woody vegetation dynamics will enable the development of management plans. These characteristics can be derived using remote sensing techniques which have become efficient in such studies. This study aimed to characterize woody vegetation dynamics along the route between Alice and King Williams’s town in Eastern Cape Province South Africa using Landsat data. This aim was achieved by focussing on three specific objectives. The first objective was to compare the performance of multispectral data and Normalized Difference Vegetation Index (NDVI) data of Landsat imagery in mapping woody vegetation cover. The second objective was to investigate the effect of the spatial resolution of remotely-sensed data on discrimination of woody vegetation from other land cover types. The third objective characterised woody vegetation dynamics between 1986 and 2013/2014 using the results from the first objective. The study used Landsat imagery acquired in November or February of 1986, 1994/1995, 2002/2003 and 2013/2014. Due to lack of data which covered the study area two separate dates (November and February) where used for the study resulting in naming the study area western and eastern parts. Unsupervised classification was performed on the multispectral, NDVI and pan-sharpened images to generate four generic land cover classes, namely water, bare land, grassland and woodland. Accuracy assessments of the classified images was done using error matrix. The results showed that the classification based on NDVI images yielded a better overall accuracy than the classification based on multispectral images for the western (83 percent and 75 percent, respectively) and eastern (82 percent and 76 percent, respectively) parts of the study area. Similarly, pan-sharpening resulted in better overall classification accuracy than multispectral, but comparable to the classification of the NDVI images for both the western (82 percent) and eastern (83 percent) parts of the study area. Remote sensing is an effective tool in assessing changes in the physical environment. Landsat imagery is suitable in assessing land cover dynamics given the long-term and free availability of the image. In addition, the large spatial coverage it provides, enables Landsat data to be used on studies that have wide spatial coverage. Classification for the purpose of time-series analysis was then performed on the NDVI images of each date (1986, 1994/1995, 2002/2003 and 2013/2014). Both woody vegetation and grassland experienced changes from 1986 to 2013/2014 with grassland occupying (75 percent) compared to woodland (17 percent) in 1986. In the year 2013/14 grassland occupied 32 percent and woodland occupied 51 percent of the study area. The increase in woody vegetation in the study area can be attributed to livestock rearing and migration of people from the rural to urban areas post-Apartheid. The study output will aid in the development of a database on land cover distribution of the area between King William’s town and Alice town, providing useful information to decision-making and further studies on woody vegetation.
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Stratigraphic interrelationships, sedimentology and post Karoo intrusions in the Katberg and Burgersdorp formations around the town of Whittlesea, Eastern Cape province, South Africa
- Authors: Mzana, Siphokazi Kwamnandi
- Date: 2016
- Subjects: Formations (Geology) -- South Africa -- Eastern Cape Sedimentology -- South Africa -- Eastern Cape Geology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/15046 , vital:40157
- Description: Concentrating on the Katberg and Burgersdorp Formations, this research examined the sedimentary environments inter alia by conducting heavy mineral analysis, interpreting provenance and determining stratigraphic interrelationships of the two formations in the Tarkastad Subgroup (Beaufort Group, Karoo Supergroup) around the town of Whittlesea in the Eastern Cape Province of South Africa. It has been observed that the strata of the Katberg Formation are dominated by sandstones of a braided river system. On the other hand, the Burgersdorp Formation comprises mainly dark greyish-red mudstone, red shale with subordinate siltstone and red sandstone deposited on floodplains and channels of meandering rivers. The Katberg Formation becomes progressively less arenaceous to the north of the study area until it is virtually indistinguishable from the overlying Burgersdorp Formation. Dolerite dykes and sills that intruded the Karoo Supergroup disturbed and baked the sedimentary strata of the Tarkastad Subgroup as well as other Karoo successions. The Katberg formation is mostly found in elevated areas, commonly metamorphosed and capped by dolerite sills while the Burgersdorp is found in low lying areas and is less metamorphosed or not metamorphosed at all. Lithologies of the two formations and the Karoo dolerites have been geologically mapped and the interfingering relationship between the Burgersdorp and Katberg Formation is also shown on the map. Horizontal laminae, planar bedding and planar and trough cross-bedding characterise lithofacies in the two formations. The fossil hunt done during the course of the study did not yield any positive results in both formations. Initially, the pebbles from outcrops of the Katberg Formation in the East London area were described in hand specimen by Mountain (1939). This study took it further with petrographic- and modal analysis as well as grain size analysis for the sedimentary pebbles. Microscopic studies done on the rock samples collected in the study area revealed quartz and feldspar as the dominant constituents. Most of the feldspar is hazy as a result of dissolution and alteration to clays. Sparse sedimentary rock fragments and quartz overgrowths in some of the rocks and grains respectively, indicate phases of recycling from older sedimentary sources. Furthermore, the samples have a wide range of grain sizes, sorting, grain shapes and classification categories. Textural attributes of sediments such as mean grain size, sorting, skewness and kurtosis were used to characterise the nature of the transport processes and to reconstruct the depositional environment of the sediments. The sandstones of both the Katberg and Burgersdorp Formations are medium-grained and moderately sorted to moderately well sorted but the pebbles are very coarse- to coarse-grained. Deducing sediment provenance from the final product of a basin fill is anything but straight-forward because rocks break down and unstable minerals change during transportation along the pathways from source to basin and afterwards during diagenesis. Heavy mineral studies coupled with geochemical sandstone analysis were used to unravel the sources of sediments. Among the heavies found were opaque and non-opaque minerals which are highly resistant to weathering with zircon being the most dominant. The heavy mineral grains vary in shape from subround to angular-subround in shape. The integrated results of petrography, XRD, XRF and SEM/EDX were used to identify the source rock character and to evaluate the relative role of tectonics and climate in determining the geochemical composition of the Katberg and Burgersdorp sandstones. Sandstone composition was used to decipher the provenance and tectonic setting of source areas by standard triangular QtFL and QmFLt diagrams, tectonic setting discrimination diagrams and source rock composition diagrams to characterise the source rocks.
- Full Text:
- Authors: Mzana, Siphokazi Kwamnandi
- Date: 2016
- Subjects: Formations (Geology) -- South Africa -- Eastern Cape Sedimentology -- South Africa -- Eastern Cape Geology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/15046 , vital:40157
- Description: Concentrating on the Katberg and Burgersdorp Formations, this research examined the sedimentary environments inter alia by conducting heavy mineral analysis, interpreting provenance and determining stratigraphic interrelationships of the two formations in the Tarkastad Subgroup (Beaufort Group, Karoo Supergroup) around the town of Whittlesea in the Eastern Cape Province of South Africa. It has been observed that the strata of the Katberg Formation are dominated by sandstones of a braided river system. On the other hand, the Burgersdorp Formation comprises mainly dark greyish-red mudstone, red shale with subordinate siltstone and red sandstone deposited on floodplains and channels of meandering rivers. The Katberg Formation becomes progressively less arenaceous to the north of the study area until it is virtually indistinguishable from the overlying Burgersdorp Formation. Dolerite dykes and sills that intruded the Karoo Supergroup disturbed and baked the sedimentary strata of the Tarkastad Subgroup as well as other Karoo successions. The Katberg formation is mostly found in elevated areas, commonly metamorphosed and capped by dolerite sills while the Burgersdorp is found in low lying areas and is less metamorphosed or not metamorphosed at all. Lithologies of the two formations and the Karoo dolerites have been geologically mapped and the interfingering relationship between the Burgersdorp and Katberg Formation is also shown on the map. Horizontal laminae, planar bedding and planar and trough cross-bedding characterise lithofacies in the two formations. The fossil hunt done during the course of the study did not yield any positive results in both formations. Initially, the pebbles from outcrops of the Katberg Formation in the East London area were described in hand specimen by Mountain (1939). This study took it further with petrographic- and modal analysis as well as grain size analysis for the sedimentary pebbles. Microscopic studies done on the rock samples collected in the study area revealed quartz and feldspar as the dominant constituents. Most of the feldspar is hazy as a result of dissolution and alteration to clays. Sparse sedimentary rock fragments and quartz overgrowths in some of the rocks and grains respectively, indicate phases of recycling from older sedimentary sources. Furthermore, the samples have a wide range of grain sizes, sorting, grain shapes and classification categories. Textural attributes of sediments such as mean grain size, sorting, skewness and kurtosis were used to characterise the nature of the transport processes and to reconstruct the depositional environment of the sediments. The sandstones of both the Katberg and Burgersdorp Formations are medium-grained and moderately sorted to moderately well sorted but the pebbles are very coarse- to coarse-grained. Deducing sediment provenance from the final product of a basin fill is anything but straight-forward because rocks break down and unstable minerals change during transportation along the pathways from source to basin and afterwards during diagenesis. Heavy mineral studies coupled with geochemical sandstone analysis were used to unravel the sources of sediments. Among the heavies found were opaque and non-opaque minerals which are highly resistant to weathering with zircon being the most dominant. The heavy mineral grains vary in shape from subround to angular-subround in shape. The integrated results of petrography, XRD, XRF and SEM/EDX were used to identify the source rock character and to evaluate the relative role of tectonics and climate in determining the geochemical composition of the Katberg and Burgersdorp sandstones. Sandstone composition was used to decipher the provenance and tectonic setting of source areas by standard triangular QtFL and QmFLt diagrams, tectonic setting discrimination diagrams and source rock composition diagrams to characterise the source rocks.
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Studies on comparison of aluminium-pillared montmorillonite clay with silica gel on adsorption of methylene blue in waste water
- Authors: Mselana, Sinazo
- Date: 2016
- Subjects: Clay Silica gel Montmorillonite
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8011 , vital:31462
- Description: Adsorption equilibrium and kinetics of methylene blue (MB) onto silica gel and aluminum pillared montmorillonite was studied in a batch system. Variables of the system include contact time, salt concentration and initial methylene blue concentration. Langmuir and Freundlich isotherm models were applied to experimental equilibrium data of methylene blue adsorption. Both models were suitable for the parameters. The advantage of silica gel as applied to water treatment is its high porosity when compared to aluminum pillared montmorillonite clay. Water molecules adhere to the silica gels surface because it exhibits a lower vapour pressure than the surrounding air. When equilibrium of equal pressure is reached, no more adsorption occurs. Thus the higher the humidity of the surrounding air, the greater the amount of water that is adsorbed before equilibrium is reached. The increase in pressure loss on the silica gel filters is 1.5 - 2.0 times smaller than in the case of sand filters, Lorenc (2007).
- Full Text:
- Authors: Mselana, Sinazo
- Date: 2016
- Subjects: Clay Silica gel Montmorillonite
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8011 , vital:31462
- Description: Adsorption equilibrium and kinetics of methylene blue (MB) onto silica gel and aluminum pillared montmorillonite was studied in a batch system. Variables of the system include contact time, salt concentration and initial methylene blue concentration. Langmuir and Freundlich isotherm models were applied to experimental equilibrium data of methylene blue adsorption. Both models were suitable for the parameters. The advantage of silica gel as applied to water treatment is its high porosity when compared to aluminum pillared montmorillonite clay. Water molecules adhere to the silica gels surface because it exhibits a lower vapour pressure than the surrounding air. When equilibrium of equal pressure is reached, no more adsorption occurs. Thus the higher the humidity of the surrounding air, the greater the amount of water that is adsorbed before equilibrium is reached. The increase in pressure loss on the silica gel filters is 1.5 - 2.0 times smaller than in the case of sand filters, Lorenc (2007).
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Synthesis and characterization of group 12 dithiolate complexes as single source precursors for the preparation of hexadecylamine capped metal sulfide nanoparticles and polymer
- Authors: Osuntokun, Jejenija
- Date: 2016
- Subjects: Nanotechnology Nanoparticles Semiconductors
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/14060 , vital:39801
- Description: A series of heteroleptic mixed ligand complexes of some alkyl substituted thiourea, tetramethyl thiuram disulfide and 1-cyano-1-carboethoxy-2,2 ditholate of Zn(II) Cd(II) and Hg(II) have been synthesized by stoichiometry reactions of the ligands with respective metal salts. They have been characterized with analytical and spectroscopic techniques. Seven out of the 19 complexes synthesized are pyridine 2, 2 bipyridine and 1, 10 phenanthroline adducts of dissopropyl parent adducts of Zn(II) and Cd(II) complexes. All the complexes are proposed as four coordinate except the pyridine adducts, 2, 2’ bipyridine and 1, 10 phenanhroline adducts that are proposed as five and six coordinate respectively. All the complexes are solid, air stable and moisture stable for a many months. They are not soluble in common organic solvents but partially soluble in coordinating solvents like DMF and DMSO and due to their insolubility problems all attempts to grow single crystal of the complexes proved abortive. The complexes gave respective metal sulfide on thermal decomposition in TGA and this makes them to be potentially useful single source precursor for the synthesis of metal sulfide. All the complexes were invariably thermolysed in HDA to synthesis a series of HDA-capped ZnS, CdS and HgS nanoparticles. The optical properties of the nanoparticles reveal that they are all blue-shifted from the absorbance edge and this confirms quantum confinement of the nanoparticles. The transmittance electron microscope showed that the nanoparticles are in nanodimension. ZnS nanoparticles from the pyridine adducts gave HDA-capped ZnS nanoparticles with a mixture of hexagonal and cubic phases while the HDA capped CdS from the 2, 2 bipyridine and 1,10 phenanthroline gave anisotropic nanoparticles. The sizes of the CdS from the 1,10 phenanthroline adducts were also found to be biggest while CdS nanoparticles from 2,2 bipyridine adduct were also revealed to be bigger than the particle sizes obtained from the parent complex, (1-cyano-1 carboethoxyethylene-2,2-dithiolato- κ,S’S)-bis(N, N’-diisopropylthiourea -κS)cadmium(II). ZnS and CdS polymer encapsulated nanocomposites were also synthesized using a solution casting method. The polymers employed were; Polymethyl metharcrylate (PMMA), Poly(vinly alcohol) (PVA), and poly vinyl pyrrolidone (PVP). The structural and thermal properties of the pure polymers and the respective nanocomposites were investigated. It was observed that the ZnS/PVA and CdS/PVA were the most thermally stable composites when the thermal stability of the pure polymers were compared relative to the nanocomposites using data obtained from thermal decomposition results of the TGA.
- Full Text:
- Authors: Osuntokun, Jejenija
- Date: 2016
- Subjects: Nanotechnology Nanoparticles Semiconductors
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/14060 , vital:39801
- Description: A series of heteroleptic mixed ligand complexes of some alkyl substituted thiourea, tetramethyl thiuram disulfide and 1-cyano-1-carboethoxy-2,2 ditholate of Zn(II) Cd(II) and Hg(II) have been synthesized by stoichiometry reactions of the ligands with respective metal salts. They have been characterized with analytical and spectroscopic techniques. Seven out of the 19 complexes synthesized are pyridine 2, 2 bipyridine and 1, 10 phenanthroline adducts of dissopropyl parent adducts of Zn(II) and Cd(II) complexes. All the complexes are proposed as four coordinate except the pyridine adducts, 2, 2’ bipyridine and 1, 10 phenanhroline adducts that are proposed as five and six coordinate respectively. All the complexes are solid, air stable and moisture stable for a many months. They are not soluble in common organic solvents but partially soluble in coordinating solvents like DMF and DMSO and due to their insolubility problems all attempts to grow single crystal of the complexes proved abortive. The complexes gave respective metal sulfide on thermal decomposition in TGA and this makes them to be potentially useful single source precursor for the synthesis of metal sulfide. All the complexes were invariably thermolysed in HDA to synthesis a series of HDA-capped ZnS, CdS and HgS nanoparticles. The optical properties of the nanoparticles reveal that they are all blue-shifted from the absorbance edge and this confirms quantum confinement of the nanoparticles. The transmittance electron microscope showed that the nanoparticles are in nanodimension. ZnS nanoparticles from the pyridine adducts gave HDA-capped ZnS nanoparticles with a mixture of hexagonal and cubic phases while the HDA capped CdS from the 2, 2 bipyridine and 1,10 phenanthroline gave anisotropic nanoparticles. The sizes of the CdS from the 1,10 phenanthroline adducts were also found to be biggest while CdS nanoparticles from 2,2 bipyridine adduct were also revealed to be bigger than the particle sizes obtained from the parent complex, (1-cyano-1 carboethoxyethylene-2,2-dithiolato- κ,S’S)-bis(N, N’-diisopropylthiourea -κS)cadmium(II). ZnS and CdS polymer encapsulated nanocomposites were also synthesized using a solution casting method. The polymers employed were; Polymethyl metharcrylate (PMMA), Poly(vinly alcohol) (PVA), and poly vinyl pyrrolidone (PVP). The structural and thermal properties of the pure polymers and the respective nanocomposites were investigated. It was observed that the ZnS/PVA and CdS/PVA were the most thermally stable composites when the thermal stability of the pure polymers were compared relative to the nanocomposites using data obtained from thermal decomposition results of the TGA.
- Full Text: