Photodynamic antimicrobial chemotherapy of a dimethylamino-functionalized asymmetric zinc (II) phthalocyanine and its quaternized derivative against Staphylococcus aureus when supported on asymmetric polystyrene polymer membranes
- Mafukidze, Donovan M, Nyokong, Tebello
- Authors: Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186168 , vital:44470 , xlink:href="https://doi.org/10.1016/j.reactfunctpolym.2020.104634"
- Description: Membrane applications are hindered by fouling. Photoactive membranes (containing photosensitizers) show photodynamic antimicrobial chemotherapy (PACT) activity which reduces biological fouling. In this work we use phthalocyanines (Pcs) as photosensitizers. The Pcs used are: 2-(4-carboxyphenoxy)-9(10), 16(17), 23(24)-tris(dimethylamino) phthalocyaninato zinc(II) (1) and the quaternized 2-(4-carboxyphenoxy)-9(10), 16(17), 23(24)-tris(trimethylamino) phthalocyanine zinc(II) methyl sulfate (2). Complex 2 showed an enhanced singlet oxygen quantum yield (ΦΔ) of 0.76 compared to 0.53 for 1. Complex 2 showed enhanced PACT activity against Staphylococcus aureus giving a log reduction value of 9.4, while its precursor (complex 1) gave 0.08. The complexes were then conjugated to amine-functionalized polystyrene and embedded into polystyrene to form membranes resulting in ΦΔ values of 0.24 and 0.27 for complexes 1 and 2 respectively in water. The latter membrane showed better PACT activity.
- Full Text:
- Date Issued: 2020
- Authors: Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186168 , vital:44470 , xlink:href="https://doi.org/10.1016/j.reactfunctpolym.2020.104634"
- Description: Membrane applications are hindered by fouling. Photoactive membranes (containing photosensitizers) show photodynamic antimicrobial chemotherapy (PACT) activity which reduces biological fouling. In this work we use phthalocyanines (Pcs) as photosensitizers. The Pcs used are: 2-(4-carboxyphenoxy)-9(10), 16(17), 23(24)-tris(dimethylamino) phthalocyaninato zinc(II) (1) and the quaternized 2-(4-carboxyphenoxy)-9(10), 16(17), 23(24)-tris(trimethylamino) phthalocyanine zinc(II) methyl sulfate (2). Complex 2 showed an enhanced singlet oxygen quantum yield (ΦΔ) of 0.76 compared to 0.53 for 1. Complex 2 showed enhanced PACT activity against Staphylococcus aureus giving a log reduction value of 9.4, while its precursor (complex 1) gave 0.08. The complexes were then conjugated to amine-functionalized polystyrene and embedded into polystyrene to form membranes resulting in ΦΔ values of 0.24 and 0.27 for complexes 1 and 2 respectively in water. The latter membrane showed better PACT activity.
- Full Text:
- Date Issued: 2020
Photodynamic antimicrobial chemotherapy of a dimethylamino-functionalized asymmetric zinc (II) phthalocyanine and its quaternized derivative against Staphylococcus aureus when supported on asymmetric polystyrene polymer membranes:
- Mafukidze, Donovan Musizvinoda Chidyamurimi, Nyokong, Tebello
- Authors: Mafukidze, Donovan Musizvinoda Chidyamurimi , Nyokong, Tebello
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148595 , vital:38753 , https://doi.org/10.1016/j.reactfunctpolym.2020.104634
- Description: Membrane applications are hindered by fouling. Photoactive membranes (containing photosensitizers) show photodynamic antimicrobial chemotherapy (PACT) activity which reduces biological fouling. In this work we use phthalocyanines (Pcs) as photosensitizers. The Pcs used are: 2-(4-carboxyphenoxy)-9(10), 16(17), 23(24)-tris(dimethylamino) phthalocyaninato zinc(II) (1) and the quaternized 2-(4-carboxyphenoxy)-9(10), 16(17), 23(24)-tris(trimethylamino) phthalocyanine zinc(II) methyl sulfate (2). Complex 2 showed an enhanced singlet oxygen quantum yield (ΦΔ) of 0.76 compared to 0.53 for 1. Complex 2 showed enhanced PACT activity against Staphylococcus aureus giving a log reduction value of 9.4, while its precursor (complex 1) gave 0.08. The complexes were then conjugated to amine-functionalized polystyrene and embedded into polystyrene to form membranes resulting in ΦΔ values of 0.24 and 0.27 for complexes 1 and 2 respectively in water. The latter membrane showed better PACT activity.
- Full Text:
- Date Issued: 2020
- Authors: Mafukidze, Donovan Musizvinoda Chidyamurimi , Nyokong, Tebello
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148595 , vital:38753 , https://doi.org/10.1016/j.reactfunctpolym.2020.104634
- Description: Membrane applications are hindered by fouling. Photoactive membranes (containing photosensitizers) show photodynamic antimicrobial chemotherapy (PACT) activity which reduces biological fouling. In this work we use phthalocyanines (Pcs) as photosensitizers. The Pcs used are: 2-(4-carboxyphenoxy)-9(10), 16(17), 23(24)-tris(dimethylamino) phthalocyaninato zinc(II) (1) and the quaternized 2-(4-carboxyphenoxy)-9(10), 16(17), 23(24)-tris(trimethylamino) phthalocyanine zinc(II) methyl sulfate (2). Complex 2 showed an enhanced singlet oxygen quantum yield (ΦΔ) of 0.76 compared to 0.53 for 1. Complex 2 showed enhanced PACT activity against Staphylococcus aureus giving a log reduction value of 9.4, while its precursor (complex 1) gave 0.08. The complexes were then conjugated to amine-functionalized polystyrene and embedded into polystyrene to form membranes resulting in ΦΔ values of 0.24 and 0.27 for complexes 1 and 2 respectively in water. The latter membrane showed better PACT activity.
- Full Text:
- Date Issued: 2020
Photodynamic antimicrobial chemotherapy of asymmetric porphyrin-silver conjugates towards photoinactivation of Staphylococcus aureus
- Shabangu, Samuel M, Babu, Balaji, Soy, Rodah C, Managa, Muthumuni, Sekhosana, Kutloano E, Nyokong, Tebello
- Authors: Shabangu, Samuel M , Babu, Balaji , Soy, Rodah C , Managa, Muthumuni , Sekhosana, Kutloano E , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186536 , vital:44509 , xlink:href="https://doi.org/10.1080/00958972.2020.1739273"
- Description: Asymmetric mono-carboxy-porphyrins, (5-(4-carboxyphenyl)10,15, 20-tris(pentafluorophenyl)porphyrinato zinc(II) (1), 5-(4- carboxyphenyl)10,15,20-triphenylporphyrinato zinc(II) (2) and 5-(4- carboxyphenyl)10,15,20-tris(2-thienyl)porphyrinato zinc(II) (3), were linked to Ag nanoparticles (AgNPs) through amide bonds and selfassembly (the latter only for 3). The porphyrins and conjugates were used for photodynamic antimicrobial chemotherapy (PACT) against Staphylococcus aureus. PACT uses singlet oxygen for antimicrobial activity. Complex 3 and its conjugates had higher singlet oxygen quantum yields and higher log reduction when compared with the rest of the porphyrins and corresponding conjugates. These high log reductions for 3 and its conjugate were attributed to the presence of sulfur groups whereby there was more interaction with the bacterial membrane.
- Full Text:
- Date Issued: 2020
- Authors: Shabangu, Samuel M , Babu, Balaji , Soy, Rodah C , Managa, Muthumuni , Sekhosana, Kutloano E , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186536 , vital:44509 , xlink:href="https://doi.org/10.1080/00958972.2020.1739273"
- Description: Asymmetric mono-carboxy-porphyrins, (5-(4-carboxyphenyl)10,15, 20-tris(pentafluorophenyl)porphyrinato zinc(II) (1), 5-(4- carboxyphenyl)10,15,20-triphenylporphyrinato zinc(II) (2) and 5-(4- carboxyphenyl)10,15,20-tris(2-thienyl)porphyrinato zinc(II) (3), were linked to Ag nanoparticles (AgNPs) through amide bonds and selfassembly (the latter only for 3). The porphyrins and conjugates were used for photodynamic antimicrobial chemotherapy (PACT) against Staphylococcus aureus. PACT uses singlet oxygen for antimicrobial activity. Complex 3 and its conjugates had higher singlet oxygen quantum yields and higher log reduction when compared with the rest of the porphyrins and corresponding conjugates. These high log reductions for 3 and its conjugate were attributed to the presence of sulfur groups whereby there was more interaction with the bacterial membrane.
- Full Text:
- Date Issued: 2020
Photophysical and nonlinear optical properties of the positional isomers of 4-(4-tertbutylphenoxy) substituted cobalt, nickel and copper phthalocyanines
- Neduvhuledza, Zelda, Nkaki, Thabo, Louzada, Marcel, Nyokong, Tebello, Khene, Samson M
- Authors: Neduvhuledza, Zelda , Nkaki, Thabo , Louzada, Marcel , Nyokong, Tebello , Khene, Samson M
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186067 , vital:44460 , xlink:href="https://doi.org/10.1016/j.optmat.2020.110195"
- Description: This paper reports on the third order nonlinear optical properties of cobalt, nickel and tetrakis(4- terbutylphenoxy)phthalocyaninatocopper(II) isomers, using the Z-scan technique. Metal-free isomers were found to have high nonlinear absorption coefficient (β) values compared to the metalated isomers. Metal-free C2v isomer was found to have the highest β value of 1.52 × 10− 10 mMW− 1 in THF. All the metal-free and metal phthalocyanine isomers nonlinear properties were found to be dependent on the singlet state absorption. Imaginary second order nonlinear hyperpolarizability (Im[γ]), ground state cross section (σg), excited states cross sections (σs and σt) and two photon absorption (TPA) cross section (σTPA) values are reported in this work. The five-energy level model rate equations were used to model the nonlinear response and absorption cross sections.
- Full Text:
- Date Issued: 2020
- Authors: Neduvhuledza, Zelda , Nkaki, Thabo , Louzada, Marcel , Nyokong, Tebello , Khene, Samson M
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186067 , vital:44460 , xlink:href="https://doi.org/10.1016/j.optmat.2020.110195"
- Description: This paper reports on the third order nonlinear optical properties of cobalt, nickel and tetrakis(4- terbutylphenoxy)phthalocyaninatocopper(II) isomers, using the Z-scan technique. Metal-free isomers were found to have high nonlinear absorption coefficient (β) values compared to the metalated isomers. Metal-free C2v isomer was found to have the highest β value of 1.52 × 10− 10 mMW− 1 in THF. All the metal-free and metal phthalocyanine isomers nonlinear properties were found to be dependent on the singlet state absorption. Imaginary second order nonlinear hyperpolarizability (Im[γ]), ground state cross section (σg), excited states cross sections (σs and σt) and two photon absorption (TPA) cross section (σTPA) values are reported in this work. The five-energy level model rate equations were used to model the nonlinear response and absorption cross sections.
- Full Text:
- Date Issued: 2020
Photophysico-chemical properties and photoinactivation of Staphylococcus Aureus using zinc phthalocyanines linked silver nanoparticles conjugates
- Matlou, Gauta G, Nyokong, Tebello
- Authors: Matlou, Gauta G , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186278 , vital:44481 , xlink:href="https://doi.org/10.1016/j.dyepig.2020.108237"
- Description: The synthesis of zinc (II) tri (tert-butyl phenoxy) mono cinnamic acid Pc (complex 1) is reported for the first time in this work. Complex 1 and the reported zinc (II) tri (tert-butyl), mono cinnamic acid phthalocyanine (2), zinc (II) mono cinnamic acid substituted phthalocyanine (3) and zinc (II) tetra cinnamic acid substituted phthalocyanine (4) are conjugated to cysteine capped silver nanoparticles (cys-AgNPs) through an amide bond. The photophysicochemical properties and the photodynamic antimicrobial chemotherapy (PACT) activities of the Pc-cys-AgNPs conjugates and the Pcs alone on S. Aureus are reported. Improved triplet and singlet oxygen quantum yields were observed for the conjugated complexes compared to Pcs alone, due to the heavy atom effect of cys-AgNPs. Asymmetric complexes 1,2, 3 and their respective conjugates recorded higher photosensitizing properties and PACT activities compared to 4 and 4-cys-AgNPs, respectively. Higher log reductions and percentage reductions of S. Aureus were recorded for conjugated complexes compared to ZnPcs only, showing enhanced PACT activities due to their higher singlet oxygen quantum yields.
- Full Text:
- Date Issued: 2020
- Authors: Matlou, Gauta G , Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186278 , vital:44481 , xlink:href="https://doi.org/10.1016/j.dyepig.2020.108237"
- Description: The synthesis of zinc (II) tri (tert-butyl phenoxy) mono cinnamic acid Pc (complex 1) is reported for the first time in this work. Complex 1 and the reported zinc (II) tri (tert-butyl), mono cinnamic acid phthalocyanine (2), zinc (II) mono cinnamic acid substituted phthalocyanine (3) and zinc (II) tetra cinnamic acid substituted phthalocyanine (4) are conjugated to cysteine capped silver nanoparticles (cys-AgNPs) through an amide bond. The photophysicochemical properties and the photodynamic antimicrobial chemotherapy (PACT) activities of the Pc-cys-AgNPs conjugates and the Pcs alone on S. Aureus are reported. Improved triplet and singlet oxygen quantum yields were observed for the conjugated complexes compared to Pcs alone, due to the heavy atom effect of cys-AgNPs. Asymmetric complexes 1,2, 3 and their respective conjugates recorded higher photosensitizing properties and PACT activities compared to 4 and 4-cys-AgNPs, respectively. Higher log reductions and percentage reductions of S. Aureus were recorded for conjugated complexes compared to ZnPcs only, showing enhanced PACT activities due to their higher singlet oxygen quantum yields.
- Full Text:
- Date Issued: 2020
Physical and thermal properties of binary and ternary blends of polypropylene, crumb rubber and wood flour
- Authors: Mosia, Lefika Ellen
- Date: 2020
- Subjects: Polypropylene , Polymers Materials science
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/49193 , vital:41609
- Description: The properties of binary and ternary blends of polypropylene (PP), crumb rubber (CR) and wood flour (WF), with and without ethylene-1-butene as a compatibiliser, were studied. The design of experiment (DoE) was used to determine the proportions of each component for various composites. The components were mixed using the Haake Thermo scientific Polylab QC internal mixer and the crumbs were then moulded into different shapes using the ARBURG 221-55-250 injection moulding machine. The properties of the blends were investigated using a scanning electron microscope (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dynamic mechanic analysis (DMA), tensile tester, water absorption and thickness swelling tests. The morphology of the blends showed the agglomeration of fillers (CR and WF) and more voids on untreated blends but on the treated blends fewer voids as well as improved distribution and dispersion were observed. PP bonded better with WF than with CR. The incorporation of both fillers improved the thermal stability, glass transition temperature, and melt temperature as well as crystallisation temperatures of the blends. Yet these fillers reduced the tensile strength and the yield strength of PP. The addition of WF increased the elongation at break and hardness of the blends but decreased the impact strength of the blends, whereas the addition of CR improved the elongation at break and impact strength of the blends and decreased the hardness of the blends. The blends with more WF absorbed more water and swelled more than the blends containing a high amount of CR. The incorporation of compatibiliser further decreased the tensile strength but improved the thermal stability and elongation at break of the blends. The water absorption and swelling of the blends seemed to decrease with the addition of the compatibiliser whereas the hardness increased. The impact strength of the blends containing more WF, increased after the addition of compatibiliser. The ternary blends showed better results than the binary blends.
- Full Text:
- Date Issued: 2020
- Authors: Mosia, Lefika Ellen
- Date: 2020
- Subjects: Polypropylene , Polymers Materials science
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/49193 , vital:41609
- Description: The properties of binary and ternary blends of polypropylene (PP), crumb rubber (CR) and wood flour (WF), with and without ethylene-1-butene as a compatibiliser, were studied. The design of experiment (DoE) was used to determine the proportions of each component for various composites. The components were mixed using the Haake Thermo scientific Polylab QC internal mixer and the crumbs were then moulded into different shapes using the ARBURG 221-55-250 injection moulding machine. The properties of the blends were investigated using a scanning electron microscope (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), dynamic mechanic analysis (DMA), tensile tester, water absorption and thickness swelling tests. The morphology of the blends showed the agglomeration of fillers (CR and WF) and more voids on untreated blends but on the treated blends fewer voids as well as improved distribution and dispersion were observed. PP bonded better with WF than with CR. The incorporation of both fillers improved the thermal stability, glass transition temperature, and melt temperature as well as crystallisation temperatures of the blends. Yet these fillers reduced the tensile strength and the yield strength of PP. The addition of WF increased the elongation at break and hardness of the blends but decreased the impact strength of the blends, whereas the addition of CR improved the elongation at break and impact strength of the blends and decreased the hardness of the blends. The blends with more WF absorbed more water and swelled more than the blends containing a high amount of CR. The incorporation of compatibiliser further decreased the tensile strength but improved the thermal stability and elongation at break of the blends. The water absorption and swelling of the blends seemed to decrease with the addition of the compatibiliser whereas the hardness increased. The impact strength of the blends containing more WF, increased after the addition of compatibiliser. The ternary blends showed better results than the binary blends.
- Full Text:
- Date Issued: 2020
Phytoplankton of the Southern Agulhas Large Marine Ecosystem (sACLME)
- Authors: Sonnekus, Martinus Jakobus
- Date: 2020
- Subjects: Botanical chemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/47646 , vital:40261
- Description: The southern Agulhas Large Marine Ecosystem (sACLME) consists of the greater Agulhas Current system, including the areas influenced by the Agulhas Current, the Agulhas Shelf, Agulhas Bank, Agulhas Retroflection as well as the Agulhas Return Current. Four biogeographical regions were identified within the sACLME and the composition of the phytoplankton communities and the associated physico-chemical variables in each were investigated. Water temperature and nitrate concentration were found to be the main drivers of the sACLME phytoplankton community. A total of 215 phytoplankton taxa were identified that were separated into two groups: the Agulhas Current group and the Southwest Indian Ocean Ridge group. The structure of the phytoplankton community was consistently homogeneous throughout the sACLME. Nutrient concentrations of the water varied, but nitrate was the most abundant source of nitrogen, especially in regions that were subjected to the upwelling of cold nutrient-rich water. The phytoplankton communities were significantly influenced by the availability and stoichiometry of the macronutrients nitrogen; phosphorus and silicon. The low mean N:P ratio of 5.5 is an indication that the waters of the sACLME are generally nitrogen limited, as is typical of oceanic systems. There is a change in phytoplankton cell size and functional groups within in the various water masses that are specific to certain biogeographical regions within the Agulhas Current system. It is clear that frontal systems may form barriers between phytoplankton communities.
- Full Text:
- Date Issued: 2020
- Authors: Sonnekus, Martinus Jakobus
- Date: 2020
- Subjects: Botanical chemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/47646 , vital:40261
- Description: The southern Agulhas Large Marine Ecosystem (sACLME) consists of the greater Agulhas Current system, including the areas influenced by the Agulhas Current, the Agulhas Shelf, Agulhas Bank, Agulhas Retroflection as well as the Agulhas Return Current. Four biogeographical regions were identified within the sACLME and the composition of the phytoplankton communities and the associated physico-chemical variables in each were investigated. Water temperature and nitrate concentration were found to be the main drivers of the sACLME phytoplankton community. A total of 215 phytoplankton taxa were identified that were separated into two groups: the Agulhas Current group and the Southwest Indian Ocean Ridge group. The structure of the phytoplankton community was consistently homogeneous throughout the sACLME. Nutrient concentrations of the water varied, but nitrate was the most abundant source of nitrogen, especially in regions that were subjected to the upwelling of cold nutrient-rich water. The phytoplankton communities were significantly influenced by the availability and stoichiometry of the macronutrients nitrogen; phosphorus and silicon. The low mean N:P ratio of 5.5 is an indication that the waters of the sACLME are generally nitrogen limited, as is typical of oceanic systems. There is a change in phytoplankton cell size and functional groups within in the various water masses that are specific to certain biogeographical regions within the Agulhas Current system. It is clear that frontal systems may form barriers between phytoplankton communities.
- Full Text:
- Date Issued: 2020
Pied Crows in the Eastern Cape: what bird club records reveal
- Craig, Adrian J F K, Hulley, Patrick E
- Authors: Craig, Adrian J F K , Hulley, Patrick E
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/449461 , vital:74823 , https://doi.org/10.2989/00306525.2020.1782498
- Description: Published records by bird clubs in Port Elizabeth, Kenton-on-Sea and Grahamstown (Makhanda) show that until 1980 Pied Crows were seldom recorded in this sector of the Eastern Cape, South Africa. Port Elizabeth, and apparently also East London, was colonised by Pied Crows in the 1980s, whereas the first records for Kenton-on- Sea and Port Alfred on the coast, and also inland in the Grahamstown (Makhanda) area, were after 1990. Since 2010, this species has been recorded more often both on the coast and in the adjacent inland regions. However, records of both Cape Crows and White-necked Ravens have also increased over the same period, suggesting that there has been no species replacement among the local corvids. Citizen-science data provide valuable information on changes in distribution and abundance of this bird species.
- Full Text:
- Date Issued: 2020
- Authors: Craig, Adrian J F K , Hulley, Patrick E
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/449461 , vital:74823 , https://doi.org/10.2989/00306525.2020.1782498
- Description: Published records by bird clubs in Port Elizabeth, Kenton-on-Sea and Grahamstown (Makhanda) show that until 1980 Pied Crows were seldom recorded in this sector of the Eastern Cape, South Africa. Port Elizabeth, and apparently also East London, was colonised by Pied Crows in the 1980s, whereas the first records for Kenton-on- Sea and Port Alfred on the coast, and also inland in the Grahamstown (Makhanda) area, were after 1990. Since 2010, this species has been recorded more often both on the coast and in the adjacent inland regions. However, records of both Cape Crows and White-necked Ravens have also increased over the same period, suggesting that there has been no species replacement among the local corvids. Citizen-science data provide valuable information on changes in distribution and abundance of this bird species.
- Full Text:
- Date Issued: 2020
PKS 2250−351: A Giant Radio Galaxy in Abell 3936
- Seymour, N, Huynh, M, Shabala, S S, Rogers, J, Davies, L J M, Turner, R J, O'Brien, A, Ishwara-Chandra, C H, Thorne, J E, Galvin, T J, Jarrett, T, Anderbach, H, Anderson, A, Bunton, J, Chow, K, Collier, J D, Driver, S, Filipovic, M D, Gurkan, G, Hopkins, A M, Kapinska, A D, Leahy, D A, Marvil, J, Manojlovic, P, Norris, R P, Phillips, C, Robotham, A, Rudnick, L, Singh, V, White, S V
- Authors: Seymour, N , Huynh, M , Shabala, S S , Rogers, J , Davies, L J M , Turner, R J , O'Brien, A , Ishwara-Chandra, C H , Thorne, J E , Galvin, T J , Jarrett, T , Anderbach, H , Anderson, A , Bunton, J , Chow, K , Collier, J D , Driver, S , Filipovic, M D , Gurkan, G , Hopkins, A M , Kapinska, A D , Leahy, D A , Marvil, J , Manojlovic, P , Norris, R P , Phillips, C , Robotham, A , Rudnick, L , Singh, V , White, S V
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150320 , vital:38967 , https://doi.org/10.1017/pasa.2019.49
- Description: We present a detailed analysis of the radio galaxy PKS , a giant of 1.2 Mpc projected size, its host galaxy, and its environment. We use radio data from the Murchison Widefield Array, the upgraded Giant Metre-wavelength Radio Telescope, the Australian Square Kilometre Array Pathfinder, and the Australia Telescope Compact Array to model the jet power and age. Optical and IR data come from the Galaxy And Mass Assembly (GAMA) survey and provide information on the host galaxy and environment.
- Full Text:
- Date Issued: 2020
- Authors: Seymour, N , Huynh, M , Shabala, S S , Rogers, J , Davies, L J M , Turner, R J , O'Brien, A , Ishwara-Chandra, C H , Thorne, J E , Galvin, T J , Jarrett, T , Anderbach, H , Anderson, A , Bunton, J , Chow, K , Collier, J D , Driver, S , Filipovic, M D , Gurkan, G , Hopkins, A M , Kapinska, A D , Leahy, D A , Marvil, J , Manojlovic, P , Norris, R P , Phillips, C , Robotham, A , Rudnick, L , Singh, V , White, S V
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150320 , vital:38967 , https://doi.org/10.1017/pasa.2019.49
- Description: We present a detailed analysis of the radio galaxy PKS , a giant of 1.2 Mpc projected size, its host galaxy, and its environment. We use radio data from the Murchison Widefield Array, the upgraded Giant Metre-wavelength Radio Telescope, the Australian Square Kilometre Array Pathfinder, and the Australia Telescope Compact Array to model the jet power and age. Optical and IR data come from the Galaxy And Mass Assembly (GAMA) survey and provide information on the host galaxy and environment.
- Full Text:
- Date Issued: 2020
Plankton dynamics in response to algal blooms in a highly eutrophic estuary in South Africa
- Authors: Smit, Taryn
- Date: 2020
- Subjects: Algal blooms -- South Africa , Estuaries -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/49303 , vital:41619
- Description: The global rise in the incidence of harmful algal blooms in estuaries is a major concern given their importance as a nursery area for a variety of invertebrates and fishes. On the warm-temperate, south-east coast of South Africa, the Sundays Estuary experiences persistent, seasonal HABs due to stable eutrophic conditions. Spring blooms of the dinoflagellate, Heterosigma akashiwo, were recorded for several years in the estuary. This Raphidophyte is known for its consequences in fish and shellfish aquaculture and exhibits harmful properties such as mucilage and reactive oxygen species production. Subsequently, the dissertation investigated larval fish assemblage dynamics, larval prey and predator dynamics and body condition in association with H. akashiwo blooms. HABs mainly altered the water quality within the mesohaline zone in terms of microalgal biomass and dissolved oxygen. Hypereutrophic blooms of H. akashiwo reached 24 996 cells∙mL-1 during the study period. Supersaturated dissolved oxygen concentrations (up to ~13 mg∙L-1 at night and ~21 mg∙L-1 during the day) were recorded during hypereutrophic blooms (> 80 μg∙L-1, ≥ 2781 H. akashiwo cells∙mL-1). Dissolved oxygen differed significantly by bloom state, with the highest dissolved oxygen concentrations. Larval fish density, diversity and community structure variability were lower during hypereutrophic blooms compared to standard blooms and bloom absence, albeit statistically insignificant. Estuarine resident larval density was negatively correlated with dissolved oxygen concentration (P < 0.001). Dominant prey copepod of G. aestuaria larvae, P. hessei, was less abundant and variable during hypereutrophic blooms (mean: 664, range: 4-4301 individuals per m3) compared to standard blooms (mean: 950, range: 2-5237 individuals per m3) and bloom absence (mean: 1182, range: 23-7259 individuals per m3). Although HABs did not appear to drive a mismatch between prey and G. aestuaria larvae, early juvenile larvae made only a small contribution to the assemblage (0.2-1.8%). In terms of predator effects, yolk sac larvae were negatively related to R. terranatalis (P < 0.05). A significant positive relationship was found between prey, P. hessei and G. aestuaria preflexion (P < 0.001), flexion (P < 0.001) and postflexion (P < 0.05) larvae. In a world first, the effects of HABs were investigated on a larval fish species, Gilchristella aestuaria, using biochemical body condition analyses. During severe bloom conditions, G. aestuaria larvae were smaller and the assemblage consisted of mainly early developmental stages (stats). Body condition (RNA per dry weight) was poorest in the presence of hypereutrophic blooms (P < 0.001). A bell-curved relationship between RNA/DW and dissolved oxygen concentration was also produced in a 3-day time-lagged GAM (P < 0.001). In conclusion, hypereutrophic bloom conditions appeared to trigger adult G. aestuaria spawning in the upper mesohaline zone of the estuary in response to heightened primary productivity which occurs during the early bloom stage. However, reductions in copepod abundance (P. hessei) and unfavourable oxygen concentrations interfered with grow-out of G. aestuaria larvae. This research showed that HABs can alter nursery properties to the detriment of G. aestuaria larvae can have serious knock-on effects up the food chain. The loss in abundance of adult, juvenile and larval G. aestuaria, a key forage fish in South African estuaries, has major implications for estuarine food webs, especially in reduced prey availability to juvenile fishes and birds. There is still much to learn about the effects of HABs on the physiological and behavioural aspects on plankton communities worldwide.
- Full Text:
- Date Issued: 2020
- Authors: Smit, Taryn
- Date: 2020
- Subjects: Algal blooms -- South Africa , Estuaries -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/49303 , vital:41619
- Description: The global rise in the incidence of harmful algal blooms in estuaries is a major concern given their importance as a nursery area for a variety of invertebrates and fishes. On the warm-temperate, south-east coast of South Africa, the Sundays Estuary experiences persistent, seasonal HABs due to stable eutrophic conditions. Spring blooms of the dinoflagellate, Heterosigma akashiwo, were recorded for several years in the estuary. This Raphidophyte is known for its consequences in fish and shellfish aquaculture and exhibits harmful properties such as mucilage and reactive oxygen species production. Subsequently, the dissertation investigated larval fish assemblage dynamics, larval prey and predator dynamics and body condition in association with H. akashiwo blooms. HABs mainly altered the water quality within the mesohaline zone in terms of microalgal biomass and dissolved oxygen. Hypereutrophic blooms of H. akashiwo reached 24 996 cells∙mL-1 during the study period. Supersaturated dissolved oxygen concentrations (up to ~13 mg∙L-1 at night and ~21 mg∙L-1 during the day) were recorded during hypereutrophic blooms (> 80 μg∙L-1, ≥ 2781 H. akashiwo cells∙mL-1). Dissolved oxygen differed significantly by bloom state, with the highest dissolved oxygen concentrations. Larval fish density, diversity and community structure variability were lower during hypereutrophic blooms compared to standard blooms and bloom absence, albeit statistically insignificant. Estuarine resident larval density was negatively correlated with dissolved oxygen concentration (P < 0.001). Dominant prey copepod of G. aestuaria larvae, P. hessei, was less abundant and variable during hypereutrophic blooms (mean: 664, range: 4-4301 individuals per m3) compared to standard blooms (mean: 950, range: 2-5237 individuals per m3) and bloom absence (mean: 1182, range: 23-7259 individuals per m3). Although HABs did not appear to drive a mismatch between prey and G. aestuaria larvae, early juvenile larvae made only a small contribution to the assemblage (0.2-1.8%). In terms of predator effects, yolk sac larvae were negatively related to R. terranatalis (P < 0.05). A significant positive relationship was found between prey, P. hessei and G. aestuaria preflexion (P < 0.001), flexion (P < 0.001) and postflexion (P < 0.05) larvae. In a world first, the effects of HABs were investigated on a larval fish species, Gilchristella aestuaria, using biochemical body condition analyses. During severe bloom conditions, G. aestuaria larvae were smaller and the assemblage consisted of mainly early developmental stages (stats). Body condition (RNA per dry weight) was poorest in the presence of hypereutrophic blooms (P < 0.001). A bell-curved relationship between RNA/DW and dissolved oxygen concentration was also produced in a 3-day time-lagged GAM (P < 0.001). In conclusion, hypereutrophic bloom conditions appeared to trigger adult G. aestuaria spawning in the upper mesohaline zone of the estuary in response to heightened primary productivity which occurs during the early bloom stage. However, reductions in copepod abundance (P. hessei) and unfavourable oxygen concentrations interfered with grow-out of G. aestuaria larvae. This research showed that HABs can alter nursery properties to the detriment of G. aestuaria larvae can have serious knock-on effects up the food chain. The loss in abundance of adult, juvenile and larval G. aestuaria, a key forage fish in South African estuaries, has major implications for estuarine food webs, especially in reduced prey availability to juvenile fishes and birds. There is still much to learn about the effects of HABs on the physiological and behavioural aspects on plankton communities worldwide.
- Full Text:
- Date Issued: 2020
Planning considerations for smart meter implementations in South Africa
- Authors: Muchenje, Tonderai
- Date: 2020
- Subjects: Application software -- Development , Smart power grids
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/46218 , vital:39515
- Description: Smart meter implementations are still in their infancy in many African countries. This is evident by the lack of research on the subject in the African context. Most of the research studies are either Eurocentric or US-centric. Although these studies are important and informative, they might not address the African challenges in context. Hence, South Africa was chosen as the testbed for an investigation that addresses the apparent knowledge gap. This study set out to formulate a framework for planning considerations in the implementation of smart meter technology within South Africa. Through extensive literature review and analysis, the technology acceptance model (TAM) was chosen as a foundational framework for this study. Although TAM is widely used for researching technology acceptance and use, its applicability was found to be inadequate in explaining customer centric factors in smart metering. Therefore, it was supplemented with factors from the theory of reasoned action (TRA), the theory of planned behavior (TPB), privacy calculus theory (PCT), as well as the unified theory of acceptance and use of technology (UTAUT). A total of 11 consumer-centric factors were identified, and these were statistically analysed using the structural equation modelling technique (SEM). Ten (10) consumer-centric factors was found to be significant. These were attitude, perceived value, monetary cost, privacy risk, perceived ease of use, perceived usefulness, facilitating conditions, social norms, trust in technology and behavioral intention. Hypothesis testing confirmed that, not one acceptance model could adequately be used to identify and explain the consumer-centric factors that can be incorporated for planning considerations for smart meter implementation in South Africa. It was further observed that the consumer-centric factors such as environmental issues, security, reliability and health issues that were important in developed countries were not deemed so in South Africa. From a methodological perspective, the study attests to contextual localised application as opposed to universal meaning and measurement invariance when incorporating planning consideration for smart meter implementation in South Africa as compared to European countries and the United States of America. Finally, the findings hold some practical implications, as they showed the practical utility of the model in predicting the consumer-centric factors that can be incorporated for planning considerations. In support, the Business Model Canvas (BMC) was found to be a useful tool in deriving and reporting on the formulation of planning consideration guidelines. Using the BMC, five planning consideration guidelines were derived: customer segmentation, partnerships, benefits communication, value identification and customer attitude. These planning considerations will allow smart meter providers to identify their customers, partners and value propositions they might need to offer consumers to facilitate a higher smart meter acceptance and use. The proposed planning consideration guidelines can practically be used by policymakers and regulators for several aspects for future pervasive technology acceptance studies. This research has, therefore, created a platform for further research in the smart technology domain while providing a usable predictive framework for the identification of consumer-centric factors and formulation of planning considerations guidelines for smart meter implementation within the South African context.
- Full Text:
- Date Issued: 2020
- Authors: Muchenje, Tonderai
- Date: 2020
- Subjects: Application software -- Development , Smart power grids
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/46218 , vital:39515
- Description: Smart meter implementations are still in their infancy in many African countries. This is evident by the lack of research on the subject in the African context. Most of the research studies are either Eurocentric or US-centric. Although these studies are important and informative, they might not address the African challenges in context. Hence, South Africa was chosen as the testbed for an investigation that addresses the apparent knowledge gap. This study set out to formulate a framework for planning considerations in the implementation of smart meter technology within South Africa. Through extensive literature review and analysis, the technology acceptance model (TAM) was chosen as a foundational framework for this study. Although TAM is widely used for researching technology acceptance and use, its applicability was found to be inadequate in explaining customer centric factors in smart metering. Therefore, it was supplemented with factors from the theory of reasoned action (TRA), the theory of planned behavior (TPB), privacy calculus theory (PCT), as well as the unified theory of acceptance and use of technology (UTAUT). A total of 11 consumer-centric factors were identified, and these were statistically analysed using the structural equation modelling technique (SEM). Ten (10) consumer-centric factors was found to be significant. These were attitude, perceived value, monetary cost, privacy risk, perceived ease of use, perceived usefulness, facilitating conditions, social norms, trust in technology and behavioral intention. Hypothesis testing confirmed that, not one acceptance model could adequately be used to identify and explain the consumer-centric factors that can be incorporated for planning considerations for smart meter implementation in South Africa. It was further observed that the consumer-centric factors such as environmental issues, security, reliability and health issues that were important in developed countries were not deemed so in South Africa. From a methodological perspective, the study attests to contextual localised application as opposed to universal meaning and measurement invariance when incorporating planning consideration for smart meter implementation in South Africa as compared to European countries and the United States of America. Finally, the findings hold some practical implications, as they showed the practical utility of the model in predicting the consumer-centric factors that can be incorporated for planning considerations. In support, the Business Model Canvas (BMC) was found to be a useful tool in deriving and reporting on the formulation of planning consideration guidelines. Using the BMC, five planning consideration guidelines were derived: customer segmentation, partnerships, benefits communication, value identification and customer attitude. These planning considerations will allow smart meter providers to identify their customers, partners and value propositions they might need to offer consumers to facilitate a higher smart meter acceptance and use. The proposed planning consideration guidelines can practically be used by policymakers and regulators for several aspects for future pervasive technology acceptance studies. This research has, therefore, created a platform for further research in the smart technology domain while providing a usable predictive framework for the identification of consumer-centric factors and formulation of planning considerations guidelines for smart meter implementation within the South African context.
- Full Text:
- Date Issued: 2020
Plant Fibre Crafts Production, Trade and Income in Eswatini, Malawi and Zimbabwe
- Thondhlana, Gladman, Pullanikkatil, Deepa, Shackleton, Charlie M
- Authors: Thondhlana, Gladman , Pullanikkatil, Deepa , Shackleton, Charlie M
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175936 , vital:42642 , https://doi.org/10.3390/f11080832 , https://doi.org/10.21504/RUR.c.5388470.v1
- Description: The production of plant fibre products is considered a promising pathway for contributing to people’s livelihoods particularly in developing countries, where economic options might be limited. However, there are limited comparative studies across countries on plant fibre products, making it difficult to examine how local and broader biophysical, socioeconomic, cultural and policy contexts influence craft production patterns in terms of primary plant resources used, products made and contributions to livelihoods. Using household surveys for data collection, this paper presents findings from a comparative analysis of plant fibre craft production and income in three southern African countries, Eswatini, Malawi and Zimbabwe.
- Full Text:
- Date Issued: 2020
- Authors: Thondhlana, Gladman , Pullanikkatil, Deepa , Shackleton, Charlie M
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175936 , vital:42642 , https://doi.org/10.3390/f11080832 , https://doi.org/10.21504/RUR.c.5388470.v1
- Description: The production of plant fibre products is considered a promising pathway for contributing to people’s livelihoods particularly in developing countries, where economic options might be limited. However, there are limited comparative studies across countries on plant fibre products, making it difficult to examine how local and broader biophysical, socioeconomic, cultural and policy contexts influence craft production patterns in terms of primary plant resources used, products made and contributions to livelihoods. Using household surveys for data collection, this paper presents findings from a comparative analysis of plant fibre craft production and income in three southern African countries, Eswatini, Malawi and Zimbabwe.
- Full Text:
- Date Issued: 2020
Plant-Based Synthesis of Silver Nanoparticles Using Aqueous Leaf Extract of Salvia officinalis: Characterization and its Antiplasmodial Activity
- Okaiyeto, Kunle, Hoppe, Heinrich C, Okoh, Anthony I
- Authors: Okaiyeto, Kunle , Hoppe, Heinrich C , Okoh, Anthony I
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429472 , vital:72613 , xlink:href="https://doi.org/10.1007/s10876-020-01766-y"
- Description: In the present study, an aqueous leaf extract of Salvia officinalis was used to synthesize silver nanoparticles (AgNPs) and characterized with different techniques such as UV–vis spectroscopy, Fourier transform infrared (FTIR), X-ray diffraction (XRD), Scanning electron microscope (SEM), Energy dispersive X-ray spectroscopy (EDX), Transmission electron microscope (TEM) and thermogravimetric analysis (TGA). Subsequently, its cytotoxic effect against human cervix adenocarcinoma (HeLa) cells and antiplasmodial activity against Plasmodium falciparum were investigated. UV–vis spectrum of AgNPs displayed an absorption peak at 323 nm and TEM result revealed it to be spherical in shape with average size of 41 nm. FTIR results highlighted the key bioactive compounds that could be responsible for the reduction and capping of AgNPs and XRD analysis showed its crystalline nature with a face-centered cubic (fcc) structure. The synthesized AgNPs was found to be less cytotoxic against HeLa cells line and demonstrated good antiplasmodial potential (IC50 = 3.6 µg/mL). Findings from this study indicated that the AgNPs could serve as a template in the development of new drugs for the control of malaria and hence, further study is needed to identify and characterize the potent molecules that suppress the malaria parasite.
- Full Text:
- Date Issued: 2020
- Authors: Okaiyeto, Kunle , Hoppe, Heinrich C , Okoh, Anthony I
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/429472 , vital:72613 , xlink:href="https://doi.org/10.1007/s10876-020-01766-y"
- Description: In the present study, an aqueous leaf extract of Salvia officinalis was used to synthesize silver nanoparticles (AgNPs) and characterized with different techniques such as UV–vis spectroscopy, Fourier transform infrared (FTIR), X-ray diffraction (XRD), Scanning electron microscope (SEM), Energy dispersive X-ray spectroscopy (EDX), Transmission electron microscope (TEM) and thermogravimetric analysis (TGA). Subsequently, its cytotoxic effect against human cervix adenocarcinoma (HeLa) cells and antiplasmodial activity against Plasmodium falciparum were investigated. UV–vis spectrum of AgNPs displayed an absorption peak at 323 nm and TEM result revealed it to be spherical in shape with average size of 41 nm. FTIR results highlighted the key bioactive compounds that could be responsible for the reduction and capping of AgNPs and XRD analysis showed its crystalline nature with a face-centered cubic (fcc) structure. The synthesized AgNPs was found to be less cytotoxic against HeLa cells line and demonstrated good antiplasmodial potential (IC50 = 3.6 µg/mL). Findings from this study indicated that the AgNPs could serve as a template in the development of new drugs for the control of malaria and hence, further study is needed to identify and characterize the potent molecules that suppress the malaria parasite.
- Full Text:
- Date Issued: 2020
Policies to reduce single-use plastic marine pollution in West Africa:
- Adam, Issahaku, Walker, Tony R, Bezerra, Joana C, Clayton, Andrea
- Authors: Adam, Issahaku , Walker, Tony R , Bezerra, Joana C , Clayton, Andrea
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150196 , vital:38948 , https://doi.org/10.1016/j.marpol.2020.103928
- Description: Countries in Africa are increasingly adopting policies to reduce single-use plastic (SUP) pollution, yet there has been limited analysis of policies adopted by African countries. This paper reviews SUP reduction policies, specifically in West Africa.
- Full Text:
- Date Issued: 2020
- Authors: Adam, Issahaku , Walker, Tony R , Bezerra, Joana C , Clayton, Andrea
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150196 , vital:38948 , https://doi.org/10.1016/j.marpol.2020.103928
- Description: Countries in Africa are increasingly adopting policies to reduce single-use plastic (SUP) pollution, yet there has been limited analysis of policies adopted by African countries. This paper reviews SUP reduction policies, specifically in West Africa.
- Full Text:
- Date Issued: 2020
Poor whites and the post-apartheid labour market: a study of perceptions and experiences of work among residents in a homeless shelter in Johannesburg
- Authors: Wollnik, Nadjeschda
- Date: 2020
- Subjects: Poor whites -- South Africa , Poor whites -- South Africa -- Atitudes , Shelters for the homeless -- South Africa , Unemployed -- South Africa -- Attitudes , Unemployed -- South Africa , South Africa -- Social conditions -- 1994- , South Africa -- Economic conditions -- 1991-
- Language: English
- Type: text , Thesis , Masters , MSocSci
- Identifier: http://hdl.handle.net/10962/148540 , vital:38748
- Description: Despite historical precedents, poverty among white people in South Africa remains an anomaly and a paradox. Likewise, the perceptions of work and employment among poor (under- and unemployed) whites in contemporary South Africa have received scant attention in the scholarly literature. Using the conceptual frameworks of critical whiteness studies and segmented labour market theory – as a way of combining subjective and objective considerations – this research seeks to describe and explain the perceptions and experiences of the labour market among poor whites living in a homeless shelter in Johannesburg. Eight respondents were chosen for extended, in-depth interviews in an effort to develop a fine-grained understanding of the pre-existing circumstances that affected their access to information and thus shaped their choices in the labour market, as well as to ascertain what they believed to be the barriers that they face in the labour market. The findings varied, with most of the interviewees seeing ‘being white’ as the reason for their poverty and unemployment, while others exhibited some awareness of the role of their lack of skills and qualifications in their capacity to compete in higher segments of the labour market. The findings were also varied in the sense that not all interviewees experienced poverty in the same manner, with some having been part of the middle class prior to becoming poor, while others having been poor their entire lives. It was also found that class or socio-economic status seemed to have a greater impact than race on the labour market prospects of the interviewees. It is argued that the perceptions of these poor whites, which are informed by their lack of information about the workings of the labour market, rather than their lack of qualifications or their race, most affected their prospects in the labour market. The mechanisms they rely on when seeking employment reveal a poor knowledge of the local labour market and the ways in which they think their skillsets match up to the types of jobs they desire. The lack of understanding of the South African labour market and the policies that are in place to redress the legacies of apartheid are among the factors influencing the lack of success these poor whites are experiencing in their search for work.
- Full Text:
- Date Issued: 2020
- Authors: Wollnik, Nadjeschda
- Date: 2020
- Subjects: Poor whites -- South Africa , Poor whites -- South Africa -- Atitudes , Shelters for the homeless -- South Africa , Unemployed -- South Africa -- Attitudes , Unemployed -- South Africa , South Africa -- Social conditions -- 1994- , South Africa -- Economic conditions -- 1991-
- Language: English
- Type: text , Thesis , Masters , MSocSci
- Identifier: http://hdl.handle.net/10962/148540 , vital:38748
- Description: Despite historical precedents, poverty among white people in South Africa remains an anomaly and a paradox. Likewise, the perceptions of work and employment among poor (under- and unemployed) whites in contemporary South Africa have received scant attention in the scholarly literature. Using the conceptual frameworks of critical whiteness studies and segmented labour market theory – as a way of combining subjective and objective considerations – this research seeks to describe and explain the perceptions and experiences of the labour market among poor whites living in a homeless shelter in Johannesburg. Eight respondents were chosen for extended, in-depth interviews in an effort to develop a fine-grained understanding of the pre-existing circumstances that affected their access to information and thus shaped their choices in the labour market, as well as to ascertain what they believed to be the barriers that they face in the labour market. The findings varied, with most of the interviewees seeing ‘being white’ as the reason for their poverty and unemployment, while others exhibited some awareness of the role of their lack of skills and qualifications in their capacity to compete in higher segments of the labour market. The findings were also varied in the sense that not all interviewees experienced poverty in the same manner, with some having been part of the middle class prior to becoming poor, while others having been poor their entire lives. It was also found that class or socio-economic status seemed to have a greater impact than race on the labour market prospects of the interviewees. It is argued that the perceptions of these poor whites, which are informed by their lack of information about the workings of the labour market, rather than their lack of qualifications or their race, most affected their prospects in the labour market. The mechanisms they rely on when seeking employment reveal a poor knowledge of the local labour market and the ways in which they think their skillsets match up to the types of jobs they desire. The lack of understanding of the South African labour market and the policies that are in place to redress the legacies of apartheid are among the factors influencing the lack of success these poor whites are experiencing in their search for work.
- Full Text:
- Date Issued: 2020
Possible futures for the health system of South Africa towards 2030
- Authors: Lourens, Stephanus Johannes
- Date: 2020
- Subjects: Health services administration -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/48720 , vital:41065
- Description: The South African health system is in crisis. To improve access to health services and move towards universal health coverage the South African government has decided to implement National Health Insurance (NHI). The implementation of such health reforms to the health system of SA is further complicated by the rapidly changing technological environment in the form of the fourth industrial revolution. The NHI and the fourth industrial revolution are expected to impact on the health system of the country, but what the impacts will be remain unclear. A review of the theory and practice of future studies support the notion that change management for healthcare organisations operating within the SA health system must be approached differently. The volatility introduced by the NHI within the context of the fourth industrial revolution necessitates the creation of strategic foresight using futures methodologies. The research has attempted to gain an understanding of the impact of National Health Insurance and the fourth industrial revolution on the health system of SA through the creation of possible futures for the health system, in the form of four alternative scenarios, towards 2030. The six pillars of future studies as stated by Inayatullah (2008) were used as a research methodology and assisted in the mapping, anticipation and timing of the issues facing the health system. The future was deepened using causal layered analysis and alternative futures were constructed through double-variable scenario creation methods using the worldviews identified during the causal layered analysis. From the constructed scenarios the research attempted to identify the preferred future for the health system of South Africa. The preferred future was used in the development of the Future Vision for the Health System of South Africa towards 2030. It is clear to achieve the desired health system towards 2030 the private and the public sectors must collaborate to create a hybrid health system which is supported by fourth industrial revolution technologies.
- Full Text:
- Date Issued: 2020
- Authors: Lourens, Stephanus Johannes
- Date: 2020
- Subjects: Health services administration -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/48720 , vital:41065
- Description: The South African health system is in crisis. To improve access to health services and move towards universal health coverage the South African government has decided to implement National Health Insurance (NHI). The implementation of such health reforms to the health system of SA is further complicated by the rapidly changing technological environment in the form of the fourth industrial revolution. The NHI and the fourth industrial revolution are expected to impact on the health system of the country, but what the impacts will be remain unclear. A review of the theory and practice of future studies support the notion that change management for healthcare organisations operating within the SA health system must be approached differently. The volatility introduced by the NHI within the context of the fourth industrial revolution necessitates the creation of strategic foresight using futures methodologies. The research has attempted to gain an understanding of the impact of National Health Insurance and the fourth industrial revolution on the health system of SA through the creation of possible futures for the health system, in the form of four alternative scenarios, towards 2030. The six pillars of future studies as stated by Inayatullah (2008) were used as a research methodology and assisted in the mapping, anticipation and timing of the issues facing the health system. The future was deepened using causal layered analysis and alternative futures were constructed through double-variable scenario creation methods using the worldviews identified during the causal layered analysis. From the constructed scenarios the research attempted to identify the preferred future for the health system of South Africa. The preferred future was used in the development of the Future Vision for the Health System of South Africa towards 2030. It is clear to achieve the desired health system towards 2030 the private and the public sectors must collaborate to create a hybrid health system which is supported by fourth industrial revolution technologies.
- Full Text:
- Date Issued: 2020
Possible hydraulics futures for South Africa towards 2055
- Authors: Naidoo, Franck
- Date: 2020
- Subjects: Climate changes -- South Africa , Shale gas industry -- Case Studies
- Language: English
- Type: Thesis , Doctoral , DBA
- Identifier: http://hdl.handle.net/10948/50620 , vital:42279
- Description: This research makes a contribution to the body of knowledge on unconventional oil and gas extraction (UOG) in the Karoo, South Africa. It provides a detailed analysis grounded in future studies theory and practice, which supports the argument that UOG extraction in the Karoo may potentially be conducted under the careful guidance of sustainable development and climate change principles. It is informed by the researcher’s perceptive and experience as a manufacturer of oil and gas products and his understanding of the fossil fuel sector and the role it currently plays in the South African economy. It is further informed by the researcher s understanding of the sector’s damaging climatic and environmental impacts. The practice of offering new insights through the application of futures studies is central to the process, and specific methodologies and tools have been used to develop four scenarios for the UOG extraction in South Africa. This framework allows for easy assessment for policy-making. Never has scenario art, which has been expertly created during the workshops, been used in South Africa to generate memorable and lasting scenarios memorable and lasting scenarios. This research seeks to provide insight regarding for South Africa’s quest for energy security in ways that support the climate change agenda. Given the shale controversies, most environmentalists prefer lower-carbon and reduced fossil fuel usage. However, South Africa can ill-afford this luxury at this stage and while the research considers the option of no-shale exploration and a direct path to renewable energy solutions (the ‘No-Shale, what now?’ scenario) it also. proposes other options for consideration. An integrated vision is put forth as the preferred scenario in which shale is the conduit to a sustainable energy future and which implements wide-scale climate change mitigation and adaptation strategies.
- Full Text:
- Date Issued: 2020
- Authors: Naidoo, Franck
- Date: 2020
- Subjects: Climate changes -- South Africa , Shale gas industry -- Case Studies
- Language: English
- Type: Thesis , Doctoral , DBA
- Identifier: http://hdl.handle.net/10948/50620 , vital:42279
- Description: This research makes a contribution to the body of knowledge on unconventional oil and gas extraction (UOG) in the Karoo, South Africa. It provides a detailed analysis grounded in future studies theory and practice, which supports the argument that UOG extraction in the Karoo may potentially be conducted under the careful guidance of sustainable development and climate change principles. It is informed by the researcher’s perceptive and experience as a manufacturer of oil and gas products and his understanding of the fossil fuel sector and the role it currently plays in the South African economy. It is further informed by the researcher s understanding of the sector’s damaging climatic and environmental impacts. The practice of offering new insights through the application of futures studies is central to the process, and specific methodologies and tools have been used to develop four scenarios for the UOG extraction in South Africa. This framework allows for easy assessment for policy-making. Never has scenario art, which has been expertly created during the workshops, been used in South Africa to generate memorable and lasting scenarios memorable and lasting scenarios. This research seeks to provide insight regarding for South Africa’s quest for energy security in ways that support the climate change agenda. Given the shale controversies, most environmentalists prefer lower-carbon and reduced fossil fuel usage. However, South Africa can ill-afford this luxury at this stage and while the research considers the option of no-shale exploration and a direct path to renewable energy solutions (the ‘No-Shale, what now?’ scenario) it also. proposes other options for consideration. An integrated vision is put forth as the preferred scenario in which shale is the conduit to a sustainable energy future and which implements wide-scale climate change mitigation and adaptation strategies.
- Full Text:
- Date Issued: 2020
Post release evaluation of the distribution and efficacy of Eccritotarsus catarinensis and Eccritotarsus eichhorniae on Pontederia crassipes in South Africa
- Authors: Maseko, Zolile
- Date: 2020
- Subjects: Water hyacinth -- Biological control -- South Africa , Weeds -- Biological control -- South Africa , Miridae -- South Africa , Insects as biological pest control agents -- South Africa
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/143046 , vital:38196
- Description: Biological control involves the release of new species into the environment and therefore, needs to be carefully monitored through post-release assessments which have been largely neglected in the science. Post-release evaluations of biological control programmes reveal whether the control agent has established and if it impacts weed demography, while cost-benefit analyses require a different set of data that show the magnitude on return on investment. The biological control effort on Pontederia crassipes in South Africa uses, amongst others, two species of mirid, Eccritotarsus catarinensis and E. eichhorniae. Initially, they were released as a single species, but were recently divided using molecular techniques. Eccritotarsus catarinensis was released in 1999, and E. eichhorniae in 2007. After many releases over two decades, there was need to assess where each species was established in the country. Molecular techniques proved to be valuable in identifying the two species as they are morphologically indistinguishable in the field. Therefore, molecular techniques should be routinely used for screening biocontrol agents, whether new or as re-introductions. Annual surveys of the mirid release sites around South Africa were undertaken between 2016 and 2019. At each site both insect and plant parameters were measured. Only E. catarinensis is established in the field in South Africa despite the multiple releases of E. eichhorniae at over 70 sites across the country, and E. catarinensis has established at only 22 of the 45 release sites accessed during this study. This thesis tested climate, interaction with other agents already on P. crassipes, and direct competition between the two mirid species as reasons for the lack of establishment of E. eichhorniae. The results of the country-wide surveys showed that climate and water trophic status were the major determinants in the establishment of E. catarinensis. Most of the establishment was recorded in the warmer regions of the country, however, a few populations of the mirid also established in cooler areas, thus demonstrating a degree of thermal plasticity, and possible microclimates as the mirids persisted at sites shaded by riparian vegetation. Stochastic events such as active herbicide campaigns, winter frosts, droughts and floods were responsible for the absence of the mirid at some sites. At some of the eutrophic sites, despite the abundance of E. catarinensis, plants still proliferated as the water trophic status facilitated plant growth, thus, plants were able to compensate for the damage inflicted by the mirid. A more intensive, monthly, post-release evaluation was conducted on the Kubusi River, Eastern Cape Province between 2016 and 2019. This is regarded as one of the cooler water hyacinth sites. Populations of biological control agents at this site fluctuated seasonally. At this site, cold winters caused frosting of the leaves of P. crassipes with the exception of plants growing under overhanging vegetation that provided a refuge for the mirid. But, cool temperatures in the winter months (May to August) severely reduced the populations of E. catarinensis that required a long recovery phase in spring. The consequence of this was that the plants grew unchecked from the onset of the growing season forming dense mats. Of the four agents at the Kubusi River site, Eccritotarsus catarinensis recovered slowest after winter, with lag phases ranging from two months to several months of the three-year period. The release of a suite of agents has implications on the agents themselves, where interactions between the agents can be important. Interactions between pairs and even multiple agents can have implications for biocontrol, where agents are either complimentary or interfere with each other. In this case, because E. catarinensis recovered the slowest of the four agents at the site, plants were of a poor quality by mid-summer resulting in low mirid populations. Competition in weed biological control could be expected to be strongest between pairs of agents that share the same niche, and this could be the reason why E. eichhorniae failed to establish at sites where E. catarinensis had already been established for several years. When the two mirids were combined in manipulated trials in a polytunnel, populations were lower compared to when the two mirids occurred separately. Under warm conditions, it is likely that E. eichhorniae would be the superior agent compared to E. catarinensis. The evaluations discussed in this thesis highlighted gaps in agent release methodology in multispecies settings, as well as the need for strategic augmentation pre- and post-winter. It is important to release agents that will complement each other rather than compete, therefore, when releasing agents in a multispecies setting, niche differentiation needs to be considered. Here it is concluded that the best practice for dealing with the mirids is that they should be released individually, and at sites that have no other biological control agents in order to ultimately assess their efficacy. Landscape level, long-term monitoring of biological control programmes shows the impact of the control programme at a broader scale and, are far more informative than short-term studies and at fewer sites. Long-term post-release evaluations should be mandatory in biological control programmes. Furthermore, these assessments will help develop new strategies or improve on existing ones, thus achieve greater success in control.
- Full Text:
- Date Issued: 2020
- Authors: Maseko, Zolile
- Date: 2020
- Subjects: Water hyacinth -- Biological control -- South Africa , Weeds -- Biological control -- South Africa , Miridae -- South Africa , Insects as biological pest control agents -- South Africa
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/143046 , vital:38196
- Description: Biological control involves the release of new species into the environment and therefore, needs to be carefully monitored through post-release assessments which have been largely neglected in the science. Post-release evaluations of biological control programmes reveal whether the control agent has established and if it impacts weed demography, while cost-benefit analyses require a different set of data that show the magnitude on return on investment. The biological control effort on Pontederia crassipes in South Africa uses, amongst others, two species of mirid, Eccritotarsus catarinensis and E. eichhorniae. Initially, they were released as a single species, but were recently divided using molecular techniques. Eccritotarsus catarinensis was released in 1999, and E. eichhorniae in 2007. After many releases over two decades, there was need to assess where each species was established in the country. Molecular techniques proved to be valuable in identifying the two species as they are morphologically indistinguishable in the field. Therefore, molecular techniques should be routinely used for screening biocontrol agents, whether new or as re-introductions. Annual surveys of the mirid release sites around South Africa were undertaken between 2016 and 2019. At each site both insect and plant parameters were measured. Only E. catarinensis is established in the field in South Africa despite the multiple releases of E. eichhorniae at over 70 sites across the country, and E. catarinensis has established at only 22 of the 45 release sites accessed during this study. This thesis tested climate, interaction with other agents already on P. crassipes, and direct competition between the two mirid species as reasons for the lack of establishment of E. eichhorniae. The results of the country-wide surveys showed that climate and water trophic status were the major determinants in the establishment of E. catarinensis. Most of the establishment was recorded in the warmer regions of the country, however, a few populations of the mirid also established in cooler areas, thus demonstrating a degree of thermal plasticity, and possible microclimates as the mirids persisted at sites shaded by riparian vegetation. Stochastic events such as active herbicide campaigns, winter frosts, droughts and floods were responsible for the absence of the mirid at some sites. At some of the eutrophic sites, despite the abundance of E. catarinensis, plants still proliferated as the water trophic status facilitated plant growth, thus, plants were able to compensate for the damage inflicted by the mirid. A more intensive, monthly, post-release evaluation was conducted on the Kubusi River, Eastern Cape Province between 2016 and 2019. This is regarded as one of the cooler water hyacinth sites. Populations of biological control agents at this site fluctuated seasonally. At this site, cold winters caused frosting of the leaves of P. crassipes with the exception of plants growing under overhanging vegetation that provided a refuge for the mirid. But, cool temperatures in the winter months (May to August) severely reduced the populations of E. catarinensis that required a long recovery phase in spring. The consequence of this was that the plants grew unchecked from the onset of the growing season forming dense mats. Of the four agents at the Kubusi River site, Eccritotarsus catarinensis recovered slowest after winter, with lag phases ranging from two months to several months of the three-year period. The release of a suite of agents has implications on the agents themselves, where interactions between the agents can be important. Interactions between pairs and even multiple agents can have implications for biocontrol, where agents are either complimentary or interfere with each other. In this case, because E. catarinensis recovered the slowest of the four agents at the site, plants were of a poor quality by mid-summer resulting in low mirid populations. Competition in weed biological control could be expected to be strongest between pairs of agents that share the same niche, and this could be the reason why E. eichhorniae failed to establish at sites where E. catarinensis had already been established for several years. When the two mirids were combined in manipulated trials in a polytunnel, populations were lower compared to when the two mirids occurred separately. Under warm conditions, it is likely that E. eichhorniae would be the superior agent compared to E. catarinensis. The evaluations discussed in this thesis highlighted gaps in agent release methodology in multispecies settings, as well as the need for strategic augmentation pre- and post-winter. It is important to release agents that will complement each other rather than compete, therefore, when releasing agents in a multispecies setting, niche differentiation needs to be considered. Here it is concluded that the best practice for dealing with the mirids is that they should be released individually, and at sites that have no other biological control agents in order to ultimately assess their efficacy. Landscape level, long-term monitoring of biological control programmes shows the impact of the control programme at a broader scale and, are far more informative than short-term studies and at fewer sites. Long-term post-release evaluations should be mandatory in biological control programmes. Furthermore, these assessments will help develop new strategies or improve on existing ones, thus achieve greater success in control.
- Full Text:
- Date Issued: 2020
Post-apartheid nostalgia and the future of the black visual archive
- Nsele, Zamansele Nsikakazi Busisiwe
- Authors: Nsele, Zamansele Nsikakazi Busisiwe
- Date: 2020
- Subjects: Nostalgia in art , Memory in art , Africa -- In art , Africans in art , Fanon, Frantz, 1925-1961. Peau noire, masques blancs. English , South Africa -- In art , Black people in art
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/167177 , vital:41444
- Description: The implications of nostalgia often strike a discordant note in post-apartheid discourse and this has opened up critical possibilities for research scholarship. For instance, Jacob Dlamini’s memoir Native Nostalgia entered the discursive fray in 2009, and it was subsequently followed by Derek Hook’s psychoanalytical approach in (Post) apartheid Conditions: Psychoanalysis and Social Formation in 2014. Notably, there is not yet a sustained and intensive research focus that has been conducted on post-apartheid forms of nostalgia within the discipline of art history and visual culture. I present this dissertation as a response to this gap. This thesis identifies mainly two competing nostalgias in post-apartheid South Africa. Through the analysis of selected artwork and media imagery, this dissertation critiques the connections of these nostalgias to the representation of the black figure in post-apartheid visual culture and the implications thereof. I argue that nostalgias for an apartheid-colonial-imperialist past operate through erasure and in the sanitisation of memory and as a result they render suffering indiscernible or in a sadomasochistic way consumes suffering as enjoyable. This thesis simultaneously critiques art work and visual representation that responds to South Africa’s nostalgia for the future: a restorative nostalgia that has emerged in the form of “rainbow nationalism”. This is a form of nostalgia that is underpinned by a dogged commitment to triumphalism and as a result erases the ongoing scenes of abjection. I use nostalgia and Afropessimism as analytical frameworks to argue that both real and visual representational forces work in tandem to restrain the future and this, I suggest is fulfilled by the transference of the black body from one state of unfreedom to next, resonating with a cyclical pattern. Frantz Fanon’s (1967) Black Skin White Mask forms the conceptual bedrock of my study, particularly his visual layout of “negrophobogenesis” and colonial temporality, which he describes as a “hellish cycle” or as an “infernal cycle” wherein the past overwhelms the present and ideas of the future.
- Full Text:
- Date Issued: 2020
- Authors: Nsele, Zamansele Nsikakazi Busisiwe
- Date: 2020
- Subjects: Nostalgia in art , Memory in art , Africa -- In art , Africans in art , Fanon, Frantz, 1925-1961. Peau noire, masques blancs. English , South Africa -- In art , Black people in art
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/167177 , vital:41444
- Description: The implications of nostalgia often strike a discordant note in post-apartheid discourse and this has opened up critical possibilities for research scholarship. For instance, Jacob Dlamini’s memoir Native Nostalgia entered the discursive fray in 2009, and it was subsequently followed by Derek Hook’s psychoanalytical approach in (Post) apartheid Conditions: Psychoanalysis and Social Formation in 2014. Notably, there is not yet a sustained and intensive research focus that has been conducted on post-apartheid forms of nostalgia within the discipline of art history and visual culture. I present this dissertation as a response to this gap. This thesis identifies mainly two competing nostalgias in post-apartheid South Africa. Through the analysis of selected artwork and media imagery, this dissertation critiques the connections of these nostalgias to the representation of the black figure in post-apartheid visual culture and the implications thereof. I argue that nostalgias for an apartheid-colonial-imperialist past operate through erasure and in the sanitisation of memory and as a result they render suffering indiscernible or in a sadomasochistic way consumes suffering as enjoyable. This thesis simultaneously critiques art work and visual representation that responds to South Africa’s nostalgia for the future: a restorative nostalgia that has emerged in the form of “rainbow nationalism”. This is a form of nostalgia that is underpinned by a dogged commitment to triumphalism and as a result erases the ongoing scenes of abjection. I use nostalgia and Afropessimism as analytical frameworks to argue that both real and visual representational forces work in tandem to restrain the future and this, I suggest is fulfilled by the transference of the black body from one state of unfreedom to next, resonating with a cyclical pattern. Frantz Fanon’s (1967) Black Skin White Mask forms the conceptual bedrock of my study, particularly his visual layout of “negrophobogenesis” and colonial temporality, which he describes as a “hellish cycle” or as an “infernal cycle” wherein the past overwhelms the present and ideas of the future.
- Full Text:
- Date Issued: 2020
Post-release monitoring in classical biological control of weeds: higher trophic levels modify competitive interactions between invasive macrophytes
- Schaffner, Urs, Hill, Martin P, Dudley, Tom, D’Antonio, Carla
- Authors: Schaffner, Urs , Hill, Martin P , Dudley, Tom , D’Antonio, Carla
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150200 , vital:38949 , https://doi.org/10.1016/j.cois.2020.02.008
- Description: While various aspects of classical biological control (CBC) of weeds, including non-target risk assessment, have been continuously improved in the past few decades, post-release monitoring remains neglected and underfunded. Detailed assessments of the population, community and ecosystem outcomes of CBC introductions, including reasons for success/failure and absence or evidence of non-target effects are generally lacking or fragmentary. Here we review recent advances in understanding the demography of biological control agents released into a novel environment, their impact on the target weed and on non-target species, and the consequences for the resident plant and animal communities and ecosystem functioning, including the restoration of ecosystem services. We argue that post-release monitoring of CBC programs offers unique but largely underutilized opportunities to improve our understanding of CBC outcomes and to inform management and decision-makers on when and how CBC should be integrated with other management options to enhance ecosystem restoration.
- Full Text:
- Date Issued: 2020
- Authors: Schaffner, Urs , Hill, Martin P , Dudley, Tom , D’Antonio, Carla
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150200 , vital:38949 , https://doi.org/10.1016/j.cois.2020.02.008
- Description: While various aspects of classical biological control (CBC) of weeds, including non-target risk assessment, have been continuously improved in the past few decades, post-release monitoring remains neglected and underfunded. Detailed assessments of the population, community and ecosystem outcomes of CBC introductions, including reasons for success/failure and absence or evidence of non-target effects are generally lacking or fragmentary. Here we review recent advances in understanding the demography of biological control agents released into a novel environment, their impact on the target weed and on non-target species, and the consequences for the resident plant and animal communities and ecosystem functioning, including the restoration of ecosystem services. We argue that post-release monitoring of CBC programs offers unique but largely underutilized opportunities to improve our understanding of CBC outcomes and to inform management and decision-makers on when and how CBC should be integrated with other management options to enhance ecosystem restoration.
- Full Text:
- Date Issued: 2020