A data governance maturity evaluation model to enhance data management in Eastern Cape government departments
- Authors: Olaitan, Olutoyin
- Date: 2017
- Subjects: Electronic government information Data protection Public administration -- Data processing
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/7989 , vital:31448
- Description: The governance of data assets has become a topical issue in the public sector. Government departments are faced with increasingly complex data and information arising from multiple projects, different departments, divisions and several stakeholders seeking data for divergent end uses. However, an exploratory study of the literature regarding data governance in government departments of the Eastern Cape province of South Africa suggest that there are no clear data governance processes in place within the departments. The research question “How can a data governance maturity evaluation model enhance data governance processes in the Eastern Cape government departments” was derived as a result of a perceived need for government departments of the province to manage their critical data assets in a manner which promotes accurate, verifiable and relevant fiscal and strategic planning. Following the review of current literature in the data governance domain, a conceptual data governance evaluation maturity model was developed and produced. The conceptual model was influenced by the IBM data governance maturity model (2007) and it was aimed at addressing the gaps in the reference model to suit the context of the Eastern Cape government departments and the governance of their data assets. A qualitative phase of empirical data collection was conducted to test the components of the conceptual model. A quantitative instrument, derived from the findings of the qualitative study, as well as the components of the refined model was administered to 50 participants in the same departments where qualitative data was collected, with additional participants being drawn from three other departments. Pragmatism was the guiding philosophy for the research. The Contingency and Institutional theories form the theoretical grounding for the study. Design Science guidelines by Hevner et al (2004), Peffers et al’s (2008) Six Steps in Design Science and Drechsler & Hevner’s (2016) Fourth Cycle of Design Science were employed to construct, improve, validate and evaluate the final artefact. Findings confirmed the literature that data governance is lacking in government departments. It is asserted that the implementation of this model will improve the way data assets are recorded, used, archived and disposed in government departments of the Eastern Cape. The outcome of this research was the development and production of a data governance maturity evaluation model as well as a process document which gives a roadmap of how to move from one maturity level to another.
- Full Text:
- Authors: Olaitan, Olutoyin
- Date: 2017
- Subjects: Electronic government information Data protection Public administration -- Data processing
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/7989 , vital:31448
- Description: The governance of data assets has become a topical issue in the public sector. Government departments are faced with increasingly complex data and information arising from multiple projects, different departments, divisions and several stakeholders seeking data for divergent end uses. However, an exploratory study of the literature regarding data governance in government departments of the Eastern Cape province of South Africa suggest that there are no clear data governance processes in place within the departments. The research question “How can a data governance maturity evaluation model enhance data governance processes in the Eastern Cape government departments” was derived as a result of a perceived need for government departments of the province to manage their critical data assets in a manner which promotes accurate, verifiable and relevant fiscal and strategic planning. Following the review of current literature in the data governance domain, a conceptual data governance evaluation maturity model was developed and produced. The conceptual model was influenced by the IBM data governance maturity model (2007) and it was aimed at addressing the gaps in the reference model to suit the context of the Eastern Cape government departments and the governance of their data assets. A qualitative phase of empirical data collection was conducted to test the components of the conceptual model. A quantitative instrument, derived from the findings of the qualitative study, as well as the components of the refined model was administered to 50 participants in the same departments where qualitative data was collected, with additional participants being drawn from three other departments. Pragmatism was the guiding philosophy for the research. The Contingency and Institutional theories form the theoretical grounding for the study. Design Science guidelines by Hevner et al (2004), Peffers et al’s (2008) Six Steps in Design Science and Drechsler & Hevner’s (2016) Fourth Cycle of Design Science were employed to construct, improve, validate and evaluate the final artefact. Findings confirmed the literature that data governance is lacking in government departments. It is asserted that the implementation of this model will improve the way data assets are recorded, used, archived and disposed in government departments of the Eastern Cape. The outcome of this research was the development and production of a data governance maturity evaluation model as well as a process document which gives a roadmap of how to move from one maturity level to another.
- Full Text:
A framework for enhancing the effectiveness of strategic leadership in the Eastern Cape Education Department
- Authors: Govender, Surendran Perumal
- Date: 2017
- Subjects: Educational leadership Strategic planning Education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/8598 , vital:33180
- Description: In this study the analysis of the organisational practices in the South African public sector revealed that there is a practical limitation, anchored on the absence of a suitable framework for enhancing the effectiveness of strategic leadership. The research engaged with studies and theories that confirmed that the application of effective strategic leadership enhances the performance of public sector organisations. However, such an analysis revealed no well-defined strategic leadership framework that may be used for improving the successful implementation of programmes in the public sector as a whole and more especially, the Eastern Cape Department of Education (ECDoE). The study therefore interpreted that a significant improvement in the performance of the ECDoE may be effected through the prioritisation of strategic leadership and thereby enhancing its effectiveness. Hence, the primary research objective for this study was to examine strategic leadership and to consider the variables impacting the application of strategic leadership in the ECDoE, so that a framework may be formulated to enhance the effectiveness of strategic leadership in the ECDoE. The data analysis, research observations, findings and interpretations as well as the literature review enabled the researcher to determine the strategic leadership framework that may be postulated for application in the ECDoE. The research data in essence supports the indications in the literature that strategic leadership has a positive effect on enhancing organisational performance and success. The key findings and significant conclusions drawn from the study indicated a definite need to enhance the effectiveness of strategic leadership in the ECDoE and that the associated leadership challenges in the sector have to be addressed to enable more efficient and effective service delivery, increase learner performance and improve organisational success. The researcher has therefore postulated the framework in figure 10 to enhance the effectiveness of strategic leadership in ECDoE and presents it for consideration by the political and administrative leadership for adoption in the ECDoE. The development of this strategic leadership framework by the researcher was informed by the various leadership models, leadership theories, leadership styles and change management strategies examined in the literature review of this study and further directed by the research findings and conclusions that illuminated the challenges that confront ECDoE in the application of strategic leadership in the sector. The framework postulated has three distinct but inter-related steps and this study theorises that the effectiveness of strategic leadership is influenced by the extent to which the managers or leaders determine the specific context and apply the appropriate leadership style (Step 1), implement the selected leadership style in conjunction with the application of appropriate accompanying management strategies (Step 2), and monitor the resulting effects on enhancing the performance of the public sector organisations (Step 3). The researcher also adopted a systems-thinking approach and identified four pillars that transcend organisational service delivery and integrated them to constitute a proposed model for enhancing service delivery, improving implementation of plans and promoting organisational success in ECDoE. The model postulated by the researcher is based on “policies, procedures, systems and structures”, as illustrated in figure 11. The pillars of this proposed model for service delivery are inter-related, inter-locking and at times overlapping. Arising from the literature review and the case study of ECDoE, areas for further research have been identified such as: a more in-depth probing of the significance, role and impact of strategic leadership in all public sector institutions in South Africa; an examination of the Senior Management Services (SMS) mandates given by the Department of Public Service and Administration (DPSA) with regard to strategic leadership; an exploration of the implementation constraints of the National Development Plan (NDP) linked to the positioning of strategic leadership; and, an examination of the role and impact of the training and development programmes in strategic leadership, co-ordinated by the National School of Government (NSG) in South Africa.
- Full Text:
- Authors: Govender, Surendran Perumal
- Date: 2017
- Subjects: Educational leadership Strategic planning Education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/8598 , vital:33180
- Description: In this study the analysis of the organisational practices in the South African public sector revealed that there is a practical limitation, anchored on the absence of a suitable framework for enhancing the effectiveness of strategic leadership. The research engaged with studies and theories that confirmed that the application of effective strategic leadership enhances the performance of public sector organisations. However, such an analysis revealed no well-defined strategic leadership framework that may be used for improving the successful implementation of programmes in the public sector as a whole and more especially, the Eastern Cape Department of Education (ECDoE). The study therefore interpreted that a significant improvement in the performance of the ECDoE may be effected through the prioritisation of strategic leadership and thereby enhancing its effectiveness. Hence, the primary research objective for this study was to examine strategic leadership and to consider the variables impacting the application of strategic leadership in the ECDoE, so that a framework may be formulated to enhance the effectiveness of strategic leadership in the ECDoE. The data analysis, research observations, findings and interpretations as well as the literature review enabled the researcher to determine the strategic leadership framework that may be postulated for application in the ECDoE. The research data in essence supports the indications in the literature that strategic leadership has a positive effect on enhancing organisational performance and success. The key findings and significant conclusions drawn from the study indicated a definite need to enhance the effectiveness of strategic leadership in the ECDoE and that the associated leadership challenges in the sector have to be addressed to enable more efficient and effective service delivery, increase learner performance and improve organisational success. The researcher has therefore postulated the framework in figure 10 to enhance the effectiveness of strategic leadership in ECDoE and presents it for consideration by the political and administrative leadership for adoption in the ECDoE. The development of this strategic leadership framework by the researcher was informed by the various leadership models, leadership theories, leadership styles and change management strategies examined in the literature review of this study and further directed by the research findings and conclusions that illuminated the challenges that confront ECDoE in the application of strategic leadership in the sector. The framework postulated has three distinct but inter-related steps and this study theorises that the effectiveness of strategic leadership is influenced by the extent to which the managers or leaders determine the specific context and apply the appropriate leadership style (Step 1), implement the selected leadership style in conjunction with the application of appropriate accompanying management strategies (Step 2), and monitor the resulting effects on enhancing the performance of the public sector organisations (Step 3). The researcher also adopted a systems-thinking approach and identified four pillars that transcend organisational service delivery and integrated them to constitute a proposed model for enhancing service delivery, improving implementation of plans and promoting organisational success in ECDoE. The model postulated by the researcher is based on “policies, procedures, systems and structures”, as illustrated in figure 11. The pillars of this proposed model for service delivery are inter-related, inter-locking and at times overlapping. Arising from the literature review and the case study of ECDoE, areas for further research have been identified such as: a more in-depth probing of the significance, role and impact of strategic leadership in all public sector institutions in South Africa; an examination of the Senior Management Services (SMS) mandates given by the Department of Public Service and Administration (DPSA) with regard to strategic leadership; an exploration of the implementation constraints of the National Development Plan (NDP) linked to the positioning of strategic leadership; and, an examination of the role and impact of the training and development programmes in strategic leadership, co-ordinated by the National School of Government (NSG) in South Africa.
- Full Text:
A strategic framework for managing and implementation of the intergovernmental relations policy in selected Eastern Cape municipalities
- Authors: Shasha, Zamuxolo
- Date: 2017
- Subjects: Intergovernmental fiscal relations -- South Africa Local government -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/8353 , vital:32310
- Description: It is of paramount importance to highlight that the South African government is established in terms of the Constitution of the Republic of South Africa of 1996. Whilst the government of South Africa is one, it consists of three spheres namely; national, provincial and local. These spheres of government are naturally distinctive, interdependent and interrelated. This is expressed in terms of section 41(1) of the Constitution, which requires that there should be co-operation, mutual trust and good faith amongst these three spheres of government. This form of a relationship compels different spheres to inform and consult one another on matters of common interest, co-ordinate their legislation, and adhere to agreed procedures in accordance with the provisions of the constitution which is the supreme law of the Republic. The study sort to find a strategic framework for managing and implementation of the Intergovernmental Relations Policy in Selected Eastern Cape Municipalities. A purposive sampling technique was used to identify the sample elements. The sample was composed of 160 participants and a semi-structured questionnaire was administered to the participants to gather information pertaining the research problem. A mixed research method was used to analyse the data gathered. The sampled respondents were municipal and government employees from various departments who have knowledge of the IGR policy. The study findings pointed out that the current framework on intergovernmental relations was ineffective in the Eastern Cape municipalities that were surveyed. Respondents pointed to a number of shortfalls in the implementation of the intergovernmental relations, which made it ineffective in improving how these municipalities operated and rendered service delivery. A number of factors inhibiting the effectiveness of the intergovernmental relations included lack of communication, poor coordination, lack of clear strategy, poor budgets amongst other factors. Based on the findings of the study, the researcher developed a strategic framework that could be adopted by municipalities in the Eastern Cape. The functionality of this framework would be influenced by the corrective measures taken by the municipalities in addressing the underlying problems of the current intergovernmental relations, as identified by the respondents.
- Full Text: false
- Authors: Shasha, Zamuxolo
- Date: 2017
- Subjects: Intergovernmental fiscal relations -- South Africa Local government -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/8353 , vital:32310
- Description: It is of paramount importance to highlight that the South African government is established in terms of the Constitution of the Republic of South Africa of 1996. Whilst the government of South Africa is one, it consists of three spheres namely; national, provincial and local. These spheres of government are naturally distinctive, interdependent and interrelated. This is expressed in terms of section 41(1) of the Constitution, which requires that there should be co-operation, mutual trust and good faith amongst these three spheres of government. This form of a relationship compels different spheres to inform and consult one another on matters of common interest, co-ordinate their legislation, and adhere to agreed procedures in accordance with the provisions of the constitution which is the supreme law of the Republic. The study sort to find a strategic framework for managing and implementation of the Intergovernmental Relations Policy in Selected Eastern Cape Municipalities. A purposive sampling technique was used to identify the sample elements. The sample was composed of 160 participants and a semi-structured questionnaire was administered to the participants to gather information pertaining the research problem. A mixed research method was used to analyse the data gathered. The sampled respondents were municipal and government employees from various departments who have knowledge of the IGR policy. The study findings pointed out that the current framework on intergovernmental relations was ineffective in the Eastern Cape municipalities that were surveyed. Respondents pointed to a number of shortfalls in the implementation of the intergovernmental relations, which made it ineffective in improving how these municipalities operated and rendered service delivery. A number of factors inhibiting the effectiveness of the intergovernmental relations included lack of communication, poor coordination, lack of clear strategy, poor budgets amongst other factors. Based on the findings of the study, the researcher developed a strategic framework that could be adopted by municipalities in the Eastern Cape. The functionality of this framework would be influenced by the corrective measures taken by the municipalities in addressing the underlying problems of the current intergovernmental relations, as identified by the respondents.
- Full Text: false
An analysis of teachers' experiences in using English as medium of instruction among grade 4 learners in Maluti district
- Authors: Rabelemane, Tsielo Aron
- Date: 2017
- Subjects: English language -- Study and teaching Language and languages -- Study and teaching
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/8221 , vital:32058
- Description: The issue of medium of instruction has been a growing concern for most researchers, especially in contexts where English is used as medium of instruction at the expense of the learner’s mother tongue. In a South African context, the problem is being aggravated by the fact that English becomes a language of learning and teaching in Grade 4 whereas the learners’ medium of instruction in the lower grades has been their mother tongue and therefore did not have a firm grasp of the English language. Subsequently, there is a general outcry in South Africa that the shift from mother tongue to English as language of learning and teaching happens too early. The objectives in this thesis were to examine the experiences faced by Grade 4 teachers in using English as language of learning and teaching; to determine how these experiences impinge on learning and teaching in Grade 4 and to determine whether the teachers’ perceptions of English as the language of learning and teaching impinges on the success of the Grade 4 learners. The theoretical framework of this study is based on bilingualism and multilingualism theories. Qualitative and quantitative approaches were used in the study. The study followed a survey design and both purposive and convenience sampling techniques were used. A sample of 100 teachers from 30 selected schools was chosen. The researcher collected data using individual interviews, questionnaires and observation. The qualitative data was analysed thematically whereas SPSS was used for the quantitative data. The findings of the study revealed that learners lacked confidence in expressing themselves in English in front of their peers and as a result the majority of learners did not participate in class when teachers were teaching in English. The results further showed that learners were passive due to poor understanding of the English language which sometimes resulted in communication breakdown between the teacher and the learner. The researcher recommended that the Government should provide the teachers with workshops that will unpack the strategies of teaching Grade 4 learners in using English as a medium of instruction.
- Full Text:
- Authors: Rabelemane, Tsielo Aron
- Date: 2017
- Subjects: English language -- Study and teaching Language and languages -- Study and teaching
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/8221 , vital:32058
- Description: The issue of medium of instruction has been a growing concern for most researchers, especially in contexts where English is used as medium of instruction at the expense of the learner’s mother tongue. In a South African context, the problem is being aggravated by the fact that English becomes a language of learning and teaching in Grade 4 whereas the learners’ medium of instruction in the lower grades has been their mother tongue and therefore did not have a firm grasp of the English language. Subsequently, there is a general outcry in South Africa that the shift from mother tongue to English as language of learning and teaching happens too early. The objectives in this thesis were to examine the experiences faced by Grade 4 teachers in using English as language of learning and teaching; to determine how these experiences impinge on learning and teaching in Grade 4 and to determine whether the teachers’ perceptions of English as the language of learning and teaching impinges on the success of the Grade 4 learners. The theoretical framework of this study is based on bilingualism and multilingualism theories. Qualitative and quantitative approaches were used in the study. The study followed a survey design and both purposive and convenience sampling techniques were used. A sample of 100 teachers from 30 selected schools was chosen. The researcher collected data using individual interviews, questionnaires and observation. The qualitative data was analysed thematically whereas SPSS was used for the quantitative data. The findings of the study revealed that learners lacked confidence in expressing themselves in English in front of their peers and as a result the majority of learners did not participate in class when teachers were teaching in English. The results further showed that learners were passive due to poor understanding of the English language which sometimes resulted in communication breakdown between the teacher and the learner. The researcher recommended that the Government should provide the teachers with workshops that will unpack the strategies of teaching Grade 4 learners in using English as a medium of instruction.
- Full Text:
An assessment of the Millennium Development Goal's poverty reduction target in Ogun State, Nigeria
- Durokifa, Anuoluwapo Abosede
- Authors: Durokifa, Anuoluwapo Abosede
- Date: 2017
- Subjects: Millennium Development Goals Economic development projects -- Nigeria Sustainable development -- Nigeria
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/4649 , vital:28483
- Description: Nigeria, like many nations of the world, is confronted with a high level of poverty. Over the years the country has taken several initiatives to reduce the incidence of poverty. Nigeria was one of the earliest countries to adopt the Millennium Development Goals [MDGs] as a strategy in reducing poverty and promoting development across the vast nation. The federating states have also rolled out a number of poverty reduction programmes tailored along the millennium development goals. This study, therefore, evaluates the achievement of the millennium development poverty reduction target in Ogun State, South west Nigeria. The study seeks to ascertain whether the state was able to significantly reduce poverty with the introduction of the MDGs. The study also attempts to establish difference or similarity (if any) between past poverty reduction policies in the state and the MDGs poverty reduction strategies. In carrying out this study, related literature on poverty, development and poverty reduction efforts (strategies and programmes) implemented in the state were extensively reviewed and relevant information retrieved for the study. This study employed the mixed method research, comprising both the quantitative and qualitative data. Quantitative data through the administration of a questionnaire was obtained from 232 respondents. While in-depth interview with seven participants provided the qualitative data. Quantitative data was analyzed using Descriptive statistics, and chi-square statistical technique was used to analyze the quantitative data while qualitative data analysis was carried out using transcription and thematic clusters. The findings of the study, in general, revealed that the MDG poverty reduction strategy did not make any significant contribution in reducing poverty in the state. The MDG strategy was not any different from past poverty reduction strategies implemented in the state. The findings of the research also strongly indicated that there was low awareness regarding the MDGs poverty reduction strategies set up amongst the citizens of the state. The low awareness emerged as a major hindrance to the success of the MDG programme. Based on the findings of this study, a sustainable development poverty reduction model was developed. The model gives room for programme awareness; people’s consultation and participation. It emphasizes the need to consider the community setting or environment factors in the planning and execution of poverty reduction programme. This model contend that aligning strategies to the peculiar need of each environment is a critical component for the sustenance of any poverty reduction programme.
- Full Text:
- Authors: Durokifa, Anuoluwapo Abosede
- Date: 2017
- Subjects: Millennium Development Goals Economic development projects -- Nigeria Sustainable development -- Nigeria
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/4649 , vital:28483
- Description: Nigeria, like many nations of the world, is confronted with a high level of poverty. Over the years the country has taken several initiatives to reduce the incidence of poverty. Nigeria was one of the earliest countries to adopt the Millennium Development Goals [MDGs] as a strategy in reducing poverty and promoting development across the vast nation. The federating states have also rolled out a number of poverty reduction programmes tailored along the millennium development goals. This study, therefore, evaluates the achievement of the millennium development poverty reduction target in Ogun State, South west Nigeria. The study seeks to ascertain whether the state was able to significantly reduce poverty with the introduction of the MDGs. The study also attempts to establish difference or similarity (if any) between past poverty reduction policies in the state and the MDGs poverty reduction strategies. In carrying out this study, related literature on poverty, development and poverty reduction efforts (strategies and programmes) implemented in the state were extensively reviewed and relevant information retrieved for the study. This study employed the mixed method research, comprising both the quantitative and qualitative data. Quantitative data through the administration of a questionnaire was obtained from 232 respondents. While in-depth interview with seven participants provided the qualitative data. Quantitative data was analyzed using Descriptive statistics, and chi-square statistical technique was used to analyze the quantitative data while qualitative data analysis was carried out using transcription and thematic clusters. The findings of the study, in general, revealed that the MDG poverty reduction strategy did not make any significant contribution in reducing poverty in the state. The MDG strategy was not any different from past poverty reduction strategies implemented in the state. The findings of the research also strongly indicated that there was low awareness regarding the MDGs poverty reduction strategies set up amongst the citizens of the state. The low awareness emerged as a major hindrance to the success of the MDG programme. Based on the findings of this study, a sustainable development poverty reduction model was developed. The model gives room for programme awareness; people’s consultation and participation. It emphasizes the need to consider the community setting or environment factors in the planning and execution of poverty reduction programme. This model contend that aligning strategies to the peculiar need of each environment is a critical component for the sustenance of any poverty reduction programme.
- Full Text:
Appraisal of experimental performance and modelling of an on-farm dairy milk bulk cooler: Fort Hare Dairy Trust, South Africa
- Authors: Mhundwa, Russel
- Date: 2017
- Subjects: Milk -- Cooling Milk -- Cooling -- Equipment and supplies Milk tanks -- Specifications
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/4671 , vital:28487
- Description: South Africa contributes approximately 0.5 percent to the total world milk demand and is the third largest producer of fresh cow milk in Africa after Sudan and Kenya. In comparison to any other enterprise, the cost of milk production is influenced by numerous factors, that in turn affect the profitability of the farm enterprise; however one of such factors is high electricity cost. In this regard, there is need for efficient operation of the milk processing plant at all stages and at the same time maximising on product quality and minimising on the cost of production including energy. At the dairy farm, milk handling mainly commences as the milk leaves the cow udder at 35°C–37°C and must be cooled rapidly to a storage temperature of 4°C in a bid to stop microbial activity. The cooling of the milk can be done directly by the bulk milk cooler (BMC) from 37°C to the required storage temperature of 4°C or it can be done successively through pre-cooling. The process of pre-cooling involves the use of a heat exchanger where in most instances the plate heat exchanger (PHE) is used as the pre-cooler (PC) thereby leading to energy savings in a dairy facility. Cooling of milk involves significant amount of energy and it could account for about 20 percent of the total energy consumed on a farm. The aim of the research was to develop mathematical models that could be used to predict the electrical energy performance and capture the cooling saving of an on-farm direct expansion bulk milk cooler (DXBMC) during the milk cooling process. Accordingly, data acquisition system (DAS) was designed and built to accurately measure the power consumption of the BMC, temperature of raw milk, room temperature, temperature of cold water, relative humidity and ambient temperature. The volume of milk produced per day was extracted from the daily records on the farm. In addition, the temperature sensors were connected to a four channel HOBO data loggers which were configured to log at every five-minutes interval. The results were analysed and the mathematical models were developed using MATLAB. The statistical Toolbox in MATLAB was used to rank the predictors according to their weight of importance using the ReliefF Algorithm test. The results showed that on average, the daily electrical energy consumed by the BMC at the two milking times was higher during the peak period (127.82 kWh and 93.86 kWh) than the off-peak period (48.31 kWh and 43.23 kWh). On average, the electricity used for cooling of milk on the dairy farm was 17.06 kWh/m3 of milk. The average monthly electricity used per cow on the farm was 8.03 kWh/cow which translated to an average of 0.26 kWh/cow/day The average specific energy consumption of the cooling system per litre of milk cooled was 0.02 kWh/L and was almost constant throughout the whole period of monitoring. Furthermore, the BMC was able to cool 57.33 L/kWh during the off-peak period which increased by 7.7 percent to 62.13 L/kWh during the peak period. Furthermore, mathematical models represented as multiple linear regression (MLR) models were built and developed using the experimental data. The developed mathematical models had good agreement with the experimental data as evidenced by the correlation coefficients of 0.922 and 0.8995 along with 0.935 and 0.930. The ReliefF Algorithm test revealed that the volume of milk was the principal contributor to the energy consumption of the BMC for both the morning (AM) and afternoon (PM) milking period. The Relative Prediction Error (RPE) was used to evaluate the suitability of the developed models. In this light, the AM off-peak model had RPE of 18.54 percent while the PM off-peak model had 14.42 percent. In addition, the AM peak and PM peak models had RPE of 19.23 percent and 18.95 percent respectively. This suggested that the MLR models for the off-peak and peak milking periods (both AM and PM) had acceptable prediction accuracy since the RPE values were between 10 percent and 20 percent. The findings from the experimental study showed that the coefficient of performance (COP) of the AM milking period was higher (2.20) than that of the PM milking period of the BMC (1.93). Increase in the milk volume led to an increase in the COP such that the peak period with higher milk volumes recorded a high COP increase of 12.61 percent and 19.81 percent for the AM and PM milking periods respectively.
- Full Text:
- Authors: Mhundwa, Russel
- Date: 2017
- Subjects: Milk -- Cooling Milk -- Cooling -- Equipment and supplies Milk tanks -- Specifications
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/4671 , vital:28487
- Description: South Africa contributes approximately 0.5 percent to the total world milk demand and is the third largest producer of fresh cow milk in Africa after Sudan and Kenya. In comparison to any other enterprise, the cost of milk production is influenced by numerous factors, that in turn affect the profitability of the farm enterprise; however one of such factors is high electricity cost. In this regard, there is need for efficient operation of the milk processing plant at all stages and at the same time maximising on product quality and minimising on the cost of production including energy. At the dairy farm, milk handling mainly commences as the milk leaves the cow udder at 35°C–37°C and must be cooled rapidly to a storage temperature of 4°C in a bid to stop microbial activity. The cooling of the milk can be done directly by the bulk milk cooler (BMC) from 37°C to the required storage temperature of 4°C or it can be done successively through pre-cooling. The process of pre-cooling involves the use of a heat exchanger where in most instances the plate heat exchanger (PHE) is used as the pre-cooler (PC) thereby leading to energy savings in a dairy facility. Cooling of milk involves significant amount of energy and it could account for about 20 percent of the total energy consumed on a farm. The aim of the research was to develop mathematical models that could be used to predict the electrical energy performance and capture the cooling saving of an on-farm direct expansion bulk milk cooler (DXBMC) during the milk cooling process. Accordingly, data acquisition system (DAS) was designed and built to accurately measure the power consumption of the BMC, temperature of raw milk, room temperature, temperature of cold water, relative humidity and ambient temperature. The volume of milk produced per day was extracted from the daily records on the farm. In addition, the temperature sensors were connected to a four channel HOBO data loggers which were configured to log at every five-minutes interval. The results were analysed and the mathematical models were developed using MATLAB. The statistical Toolbox in MATLAB was used to rank the predictors according to their weight of importance using the ReliefF Algorithm test. The results showed that on average, the daily electrical energy consumed by the BMC at the two milking times was higher during the peak period (127.82 kWh and 93.86 kWh) than the off-peak period (48.31 kWh and 43.23 kWh). On average, the electricity used for cooling of milk on the dairy farm was 17.06 kWh/m3 of milk. The average monthly electricity used per cow on the farm was 8.03 kWh/cow which translated to an average of 0.26 kWh/cow/day The average specific energy consumption of the cooling system per litre of milk cooled was 0.02 kWh/L and was almost constant throughout the whole period of monitoring. Furthermore, the BMC was able to cool 57.33 L/kWh during the off-peak period which increased by 7.7 percent to 62.13 L/kWh during the peak period. Furthermore, mathematical models represented as multiple linear regression (MLR) models were built and developed using the experimental data. The developed mathematical models had good agreement with the experimental data as evidenced by the correlation coefficients of 0.922 and 0.8995 along with 0.935 and 0.930. The ReliefF Algorithm test revealed that the volume of milk was the principal contributor to the energy consumption of the BMC for both the morning (AM) and afternoon (PM) milking period. The Relative Prediction Error (RPE) was used to evaluate the suitability of the developed models. In this light, the AM off-peak model had RPE of 18.54 percent while the PM off-peak model had 14.42 percent. In addition, the AM peak and PM peak models had RPE of 19.23 percent and 18.95 percent respectively. This suggested that the MLR models for the off-peak and peak milking periods (both AM and PM) had acceptable prediction accuracy since the RPE values were between 10 percent and 20 percent. The findings from the experimental study showed that the coefficient of performance (COP) of the AM milking period was higher (2.20) than that of the PM milking period of the BMC (1.93). Increase in the milk volume led to an increase in the COP such that the peak period with higher milk volumes recorded a high COP increase of 12.61 percent and 19.81 percent for the AM and PM milking periods respectively.
- Full Text:
Commerce powered by 'National culture'? : an assessment of "Wear Local" campaigns as tools for reinvigorating the textile and clothing industries in Ghana and South Africa
- Authors: Darku, Esther Naa Dodua
- Date: 2017
- Subjects: Textile industry -- Economic aspects -- Ghana Textile industry -- Economic aspects -- South Africa Sustainable development -- Ghana , Sustainable development -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/2172 , vital:27619
- Description: This study examines the use of ‘cultural’ imagery and messaging as a tool to revitalise crucial national industries. Specifically, it examines the use of Wear Local campaigns in Ghana and South Africa as strategies to rejuvenate their textile industries and to make them viable in an increasingly competitive global market. Conceptualising Wear Local campaigns as possessing both cultural and economic imperatives, this study highlights how both factors contribute to making products of Buy Local campaigns marketable by showing their importance as both cultural and economic products. Using a descriptive-evaluative design, the study adopted a triangulated research approach comprising a survey, key informant interviews and document analysis. Survey questionnaires were administered to a total sample of 308 respondents in Ghana and South Africa. The qualitative phase of the study involved 10 key informant interviews (comprising textile labour unions, clothing designers, and government officials in both countries) and document/documentary research. The quantitative data were analysed using descriptive and inferential statistics, while the qualitative data were analysed using interpretive approaches, such as content analysis. The results indicate significant uses of national cultural elements in the campaign messaging in both Ghana and South Africa, as well as notable differences in the ways in which these campaigns resonated with consumers in the two countries. For instance, cultural differences accounted for high popularity of the campaign in Ghana and low popularity in South Africa. Following from these findings, the study concludes that the discourse on Buy Local and Wear Local, and the use of national culture in commerce, must go beyond the question of efficacy to examine the conditions under which these campaigns can become an effective economic/market tool. The study makes an important contribution to the existing knowledge on national culture, national economy and globalisation.
- Full Text:
- Authors: Darku, Esther Naa Dodua
- Date: 2017
- Subjects: Textile industry -- Economic aspects -- Ghana Textile industry -- Economic aspects -- South Africa Sustainable development -- Ghana , Sustainable development -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/2172 , vital:27619
- Description: This study examines the use of ‘cultural’ imagery and messaging as a tool to revitalise crucial national industries. Specifically, it examines the use of Wear Local campaigns in Ghana and South Africa as strategies to rejuvenate their textile industries and to make them viable in an increasingly competitive global market. Conceptualising Wear Local campaigns as possessing both cultural and economic imperatives, this study highlights how both factors contribute to making products of Buy Local campaigns marketable by showing their importance as both cultural and economic products. Using a descriptive-evaluative design, the study adopted a triangulated research approach comprising a survey, key informant interviews and document analysis. Survey questionnaires were administered to a total sample of 308 respondents in Ghana and South Africa. The qualitative phase of the study involved 10 key informant interviews (comprising textile labour unions, clothing designers, and government officials in both countries) and document/documentary research. The quantitative data were analysed using descriptive and inferential statistics, while the qualitative data were analysed using interpretive approaches, such as content analysis. The results indicate significant uses of national cultural elements in the campaign messaging in both Ghana and South Africa, as well as notable differences in the ways in which these campaigns resonated with consumers in the two countries. For instance, cultural differences accounted for high popularity of the campaign in Ghana and low popularity in South Africa. Following from these findings, the study concludes that the discourse on Buy Local and Wear Local, and the use of national culture in commerce, must go beyond the question of efficacy to examine the conditions under which these campaigns can become an effective economic/market tool. The study makes an important contribution to the existing knowledge on national culture, national economy and globalisation.
- Full Text:
Community policing and partnership policing : a case study of shared responsibilities between the police and Alice community
- Authors: Manganyi, Foster Mzamani
- Date: 2017
- Subjects: Police-community relations -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , DPhil
- Identifier: http://hdl.handle.net/10353/8386 , vital:32558
- Description: The purpose of this study was to explore the shared responsibilities between the police and the community on crime prevention. Various authorities such as Sir Robert Peel (1829), Sower (1957), William and Kelling (1982), Roelofse (2007), to mention a few, had been advocating community policing as an essential component of democratic policing. In an attempt to understand the shared responsibilities between the police and the community, a thorough literature review had been presented in chapter two. Through the intertwined approach of secondary data, explorations had been noted on the shared responsibility between the police and the community. Literature and theoretical review had been presented in the thesis to clarify critical aspects of the topic. Triangulation approach was adopted for the purpose of this study. The researcher triangulated, methodologies, sampling methods, data collection methods as well as data analysis methods. Using qualitative approach in Phase A, data was collected through structured interview, observation and content analysis which was thematically presented. The quantitative data (Phase B) was collected through structured questionnaire. In case of codding and analysis SPSS was utilised. The findings of the study in chapter six shows the shared responsibilities between the police and the community exist within Alice. Moreover, the findings shows that there is a need for community empowerment on human rights and its applicability.
- Full Text:
- Authors: Manganyi, Foster Mzamani
- Date: 2017
- Subjects: Police-community relations -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , DPhil
- Identifier: http://hdl.handle.net/10353/8386 , vital:32558
- Description: The purpose of this study was to explore the shared responsibilities between the police and the community on crime prevention. Various authorities such as Sir Robert Peel (1829), Sower (1957), William and Kelling (1982), Roelofse (2007), to mention a few, had been advocating community policing as an essential component of democratic policing. In an attempt to understand the shared responsibilities between the police and the community, a thorough literature review had been presented in chapter two. Through the intertwined approach of secondary data, explorations had been noted on the shared responsibility between the police and the community. Literature and theoretical review had been presented in the thesis to clarify critical aspects of the topic. Triangulation approach was adopted for the purpose of this study. The researcher triangulated, methodologies, sampling methods, data collection methods as well as data analysis methods. Using qualitative approach in Phase A, data was collected through structured interview, observation and content analysis which was thematically presented. The quantitative data (Phase B) was collected through structured questionnaire. In case of codding and analysis SPSS was utilised. The findings of the study in chapter six shows the shared responsibilities between the police and the community exist within Alice. Moreover, the findings shows that there is a need for community empowerment on human rights and its applicability.
- Full Text:
Development of conservation strategies for Alepidea Amatymbica ECKL. & ZEYH. : a rare medicinal plant in the Eastern Cape, South Africa
- Mangoale, Ramatsobane Maureen
- Authors: Mangoale, Ramatsobane Maureen
- Date: 2017
- Subjects: Medicinal plants Plants, Cultivated
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/8667 , vital:33400
- Description: Conservation through cultivation has been recommended as a means to relieve overexploitation of medicinal plants. However, the medicinal plants users believe that plants collected from the wild are more potent than cultivated ones. Hence, there is a need for scientific documentation of the potency of cultivated medicinal plants to contribute to the development of a sustainable management strategy to conserve wild populations. This study was aimed at documenting cultivation techniques of a known medicinal plant, Alepidea amatymbica and to validate its medicinal efficacy. In order to identify overexploited medicinal plants in the study area and thus develop their conservation strategy, a survey on the trade of medicinal plants was conducted in selected towns of Amathole District Municipality of the Eastern Cape, South Africa. The survey revealed 67 plants belonging to 46 different families. Twenty-five medicinal plants were identified as overexploited and scarce and they were prioritized for conservation. Furthermore, 69.14 percent of the respondents were not willing to use cultivated medicinal plants. Lack of belief on the potency of cultivated plants and cultivation techniques were mentioned as the most significant constraints to conservation of medicinal plants. Also, the time for cultivated plants to reach maturity deterred herbal medicine practitioners from cultivating them. Alepidea amatymbica was mentioned as one of the most overexploited medicinal plants which has become scarce in the study area. This medicinal plant was therefore selected for this study. In order to develop sustainable conservation program for the species, various studies which include survey on the medicinal plants trade, cultivation, comparative micromorphology, elemental composition, toxicity, phytochemical and antioxidant activity of the wild and cultivated A. amatymbica were conducted. Cultivation of Alepidea amatymbica was conducted to determine the appropriate planting depth and rhizome fragment length for the growth of this plant. The experiment was laid out in a Complete Randomized Block Design (CRBD) with two factors in 6×3 factorial design. There were six levels of fragment length (1, 2, 3, 4, 5 and 6 cm) and three levels of burial depth (2.5, 5 and 7.5 cm). Emergence rate, number of leaves, leaf area, and plant height, number of florets, rhizome length gain, rhizome weight gain, shoot moisture and rhizome moisture were measured as growth parameters. The best overall yield in terms of plant height, shoot emergence, rhizome weight gain, number of florets and number of leaves was observed in 7.5 cm planting depth at 6 cm rhizome length. Four centimetre rhizome length had the highest leaf area of 111.9±3.5 cm2, 101.3±3.5 cm2, 105±3.5 cm2 at 2.5, 5, 7.5 cm planting depth respectively. Shorter fragment lengths showed high potential for vegetative propagation in terms of rhizome length gain at all burial depths. Scanning electron microscopy (SEM) was used to examine the foliar micro morphological characteristics while energy dispersive x-ray spectroscopy (EDXS) was used to determine the elemental composition in different parts of the wild and cultivated plants. The study revealed numerous differences between the wild and cultivated ones. These include deposition of epicuticular waxes, stomatal apparatus, helical thickening of the xylem walls, thickening of the epidermal cell layer and presence of starch grains in the parenchyma cells of the cortex. The EDXS analysis also revealed disproportionate quantities of C, O, Ca, K, Al, Mg, Si, Br and N as the major constituents in both cultivated and wild A. amatymbica specimens. The quantities of elements varied in the different parts of wild and cultivated plants. Toxicity of the methanol, water and acetone extracts of the fresh rhizome of the wild and cultivated A. amatymbica were evaluated using hatchability of cysts and lethality on the hatched cysts (nauplii) of Artemia salina. The highest hatching success was observed in the water extracts of the wild plant (46.16percent) with a MIC of 0.184 mg/ml while the cultivated plants had a hatching success of 40.83percent with MIC of 0.208 mg/ml. Highest mortality was observed in the acetone extract of the wild plants at the lethal dose of 0.191 mg/ml while the cultivated plant had a lethal dose of 0.270 mg/ml. Water extracts of both wild and cultivated plants showed similar lethal dose (LD50) of >1 mg/ml. Methanol extracts of both the wild and cultivated species exhibited almost the same level of toxicity (0.695 mg/ml and 0.628 mg/ml, respectively). Based on the Bastos criterion of toxicity indices of the lethality test, all the plant fractions demonstrated cytotoxicity effect, although the degree of their toxicity varied among the plants used. Standard spectrophotometry assays were used to quantify the phytochemical contents and to determine the antioxidant potentials of the cultivated and wild A. amatymbica. The results revealed different levels of phytochemicals with corresponding antioxidant activities. The wild extracts had higher phytochemical contents in most of the assays than cultivated extracts. Total phenol in the wild extracts ranged from 32.30±3.43 to 117.8±8.45 mg GAE/g with the acetone extracts having the highest content while the water extracts was the least. The range in the total phenol of the cultivated species was 66.46±5.29 to 98.44±6.08 mg GAE/g with the methanol extracts having the highest content while water extracts was the least. The flavonoids content ranged from 55.01±6.51 to 99.09±7.20 mg QE/mg and from 48.65±7.74 to 67.32±4.1 mg QE/mg for the wild and cultivated plants, respectively. The alkaloids contents ranged from 14.70±0.04 to 17.80±0.015 percent in the wild species while it ranged from 11.98±0.14 to 13.21±0.06 percent in the cultivated species. The wild species also showed higher antioxidant activities in most of the assays evaluated. The study revealed successful cultivation of the wild species of Alepidea amatymbica using fragments from the rhizome. The micromorphological study of both the wild and cultivated species showed minimal differences in the helical thickening of the walls in the xylem vessels and starch grain accumulation pattern. Although herbal medicine practitioners believe that cultivated species are not potent, however this study revealed some levels of phytochemicals contents and antioxidant activities which are comparable to the wild species. Cultivation is a major strategy in conserving nature and their resources. Hence, the successful domestication of A. amatymbica would help in reducing the pressure on the wild species while also meeting their medicinal demands purposes, utilisation and conserving for future generations.
- Full Text:
- Authors: Mangoale, Ramatsobane Maureen
- Date: 2017
- Subjects: Medicinal plants Plants, Cultivated
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/8667 , vital:33400
- Description: Conservation through cultivation has been recommended as a means to relieve overexploitation of medicinal plants. However, the medicinal plants users believe that plants collected from the wild are more potent than cultivated ones. Hence, there is a need for scientific documentation of the potency of cultivated medicinal plants to contribute to the development of a sustainable management strategy to conserve wild populations. This study was aimed at documenting cultivation techniques of a known medicinal plant, Alepidea amatymbica and to validate its medicinal efficacy. In order to identify overexploited medicinal plants in the study area and thus develop their conservation strategy, a survey on the trade of medicinal plants was conducted in selected towns of Amathole District Municipality of the Eastern Cape, South Africa. The survey revealed 67 plants belonging to 46 different families. Twenty-five medicinal plants were identified as overexploited and scarce and they were prioritized for conservation. Furthermore, 69.14 percent of the respondents were not willing to use cultivated medicinal plants. Lack of belief on the potency of cultivated plants and cultivation techniques were mentioned as the most significant constraints to conservation of medicinal plants. Also, the time for cultivated plants to reach maturity deterred herbal medicine practitioners from cultivating them. Alepidea amatymbica was mentioned as one of the most overexploited medicinal plants which has become scarce in the study area. This medicinal plant was therefore selected for this study. In order to develop sustainable conservation program for the species, various studies which include survey on the medicinal plants trade, cultivation, comparative micromorphology, elemental composition, toxicity, phytochemical and antioxidant activity of the wild and cultivated A. amatymbica were conducted. Cultivation of Alepidea amatymbica was conducted to determine the appropriate planting depth and rhizome fragment length for the growth of this plant. The experiment was laid out in a Complete Randomized Block Design (CRBD) with two factors in 6×3 factorial design. There were six levels of fragment length (1, 2, 3, 4, 5 and 6 cm) and three levels of burial depth (2.5, 5 and 7.5 cm). Emergence rate, number of leaves, leaf area, and plant height, number of florets, rhizome length gain, rhizome weight gain, shoot moisture and rhizome moisture were measured as growth parameters. The best overall yield in terms of plant height, shoot emergence, rhizome weight gain, number of florets and number of leaves was observed in 7.5 cm planting depth at 6 cm rhizome length. Four centimetre rhizome length had the highest leaf area of 111.9±3.5 cm2, 101.3±3.5 cm2, 105±3.5 cm2 at 2.5, 5, 7.5 cm planting depth respectively. Shorter fragment lengths showed high potential for vegetative propagation in terms of rhizome length gain at all burial depths. Scanning electron microscopy (SEM) was used to examine the foliar micro morphological characteristics while energy dispersive x-ray spectroscopy (EDXS) was used to determine the elemental composition in different parts of the wild and cultivated plants. The study revealed numerous differences between the wild and cultivated ones. These include deposition of epicuticular waxes, stomatal apparatus, helical thickening of the xylem walls, thickening of the epidermal cell layer and presence of starch grains in the parenchyma cells of the cortex. The EDXS analysis also revealed disproportionate quantities of C, O, Ca, K, Al, Mg, Si, Br and N as the major constituents in both cultivated and wild A. amatymbica specimens. The quantities of elements varied in the different parts of wild and cultivated plants. Toxicity of the methanol, water and acetone extracts of the fresh rhizome of the wild and cultivated A. amatymbica were evaluated using hatchability of cysts and lethality on the hatched cysts (nauplii) of Artemia salina. The highest hatching success was observed in the water extracts of the wild plant (46.16percent) with a MIC of 0.184 mg/ml while the cultivated plants had a hatching success of 40.83percent with MIC of 0.208 mg/ml. Highest mortality was observed in the acetone extract of the wild plants at the lethal dose of 0.191 mg/ml while the cultivated plant had a lethal dose of 0.270 mg/ml. Water extracts of both wild and cultivated plants showed similar lethal dose (LD50) of >1 mg/ml. Methanol extracts of both the wild and cultivated species exhibited almost the same level of toxicity (0.695 mg/ml and 0.628 mg/ml, respectively). Based on the Bastos criterion of toxicity indices of the lethality test, all the plant fractions demonstrated cytotoxicity effect, although the degree of their toxicity varied among the plants used. Standard spectrophotometry assays were used to quantify the phytochemical contents and to determine the antioxidant potentials of the cultivated and wild A. amatymbica. The results revealed different levels of phytochemicals with corresponding antioxidant activities. The wild extracts had higher phytochemical contents in most of the assays than cultivated extracts. Total phenol in the wild extracts ranged from 32.30±3.43 to 117.8±8.45 mg GAE/g with the acetone extracts having the highest content while the water extracts was the least. The range in the total phenol of the cultivated species was 66.46±5.29 to 98.44±6.08 mg GAE/g with the methanol extracts having the highest content while water extracts was the least. The flavonoids content ranged from 55.01±6.51 to 99.09±7.20 mg QE/mg and from 48.65±7.74 to 67.32±4.1 mg QE/mg for the wild and cultivated plants, respectively. The alkaloids contents ranged from 14.70±0.04 to 17.80±0.015 percent in the wild species while it ranged from 11.98±0.14 to 13.21±0.06 percent in the cultivated species. The wild species also showed higher antioxidant activities in most of the assays evaluated. The study revealed successful cultivation of the wild species of Alepidea amatymbica using fragments from the rhizome. The micromorphological study of both the wild and cultivated species showed minimal differences in the helical thickening of the walls in the xylem vessels and starch grain accumulation pattern. Although herbal medicine practitioners believe that cultivated species are not potent, however this study revealed some levels of phytochemicals contents and antioxidant activities which are comparable to the wild species. Cultivation is a major strategy in conserving nature and their resources. Hence, the successful domestication of A. amatymbica would help in reducing the pressure on the wild species while also meeting their medicinal demands purposes, utilisation and conserving for future generations.
- Full Text:
Effects of Vigna unguiculata and Lablab purpureus on methanogenesis, haematological parameters and the quality of meat from Xhosa Lop Ear goats
- Authors: Washaya, Soul
- Date: 2017
- Subjects: Legumes Forage Forage plants
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/9996 , vital:35249
- Description: The objective of the current study was to evaluate the nutritive value of forage legumes Lablab purpureus (Lablab) and Vigna unguiculata (Cowpea) and their effects on intake, growth, blood parameters and meat quality in Xhosa goats. Forages were established at UFH research farm in the summer of the 2014 /15 growing season in blocks measuring 8m width x 16m long for each legume, replicated three times, making a total of four blocks, and eight treatment units for each legume. Samples were collected at three different stages of growth of preanthesis, anthesis and post anthesis for biomass yield determination. A homogenous sub-sample was then oven dried for 72 hours at 60 0C. After drying the forage samples were milled through a 1mm screen and a 20g sample from each stage of growth and forage sample was subjected to proximate analysis, in-vitro digestibility and anti-nutrient evaluation. The in-vitro digestibility experiment was done with rumen liquor of cattle and sheep collected from an abbatoir. Tannins, total phenolics and sapponins were the only anti-nutrients evaluated as they are perceived to influence methanogenesis in ruminat animals. At 50percent flowering, forage legumes were harvested for hay making which was then used in an in-vivo trial to evaluate the nutritive value of forages. This trial was conducted using eighteen one-year-old goats of average weight 14.2±0.24 kg over a period of sixty days. The results showed that biomass yield, which increased with stage of growth, was significantly higher (P < 0.05) for Lablab than Cowpea (7.968t/ha vs 7.105t/ha). Cowpea exhibited higher moisture content (7.72percent), Ash (13.11percent), acid detergent fibre (ADF) (38.42percent) and crude protein (CP) (20.23percent) than Lablab which had 7.50percent, 11.45 percent, 36.17percent and 19percent, respectively. Lablab forage had significantly higher (P < 0.05) fat content (2.41percent), neutral detergent fibre (NDF) (49.27percent) and hemicellulose (13.07percent) than Cowpea which had 2.1percent; 46.91percent and 8.48percent, respectively. The stage of growth significantly (P < 0.05) affected the mineral content of both forages. Lablab showed significantly higher (P < 0.05) values (1.22percent 0.55percent, 2.67percent) than Cowpea (1.00percent, 0.45percent, 2.30percent) for calcium (Ca), phosphorus (P), and potassium (K) respectively. Lablab forage had significantly higher (P < 0.05) tannin (3.345mgCAE/gDM), phenolic (13.47mgGAE/gDM) and saponin (0.75percent) content compared to Cowpea with values of 1.494mgCAEg/DM; 9.402mgGAE/gDM and vs 1.55percent respectively. The tannin content significantly influenced in-vitro digestibility and enteric methane production. The forage type, harvesting stage and inoculum source significantly (P < 0.05) affected the in-vitro digestibility of the forages. The in-vitro dry matter (IVDM) and in-vitro organic matter (IVOM) digestibility was significantly higher (P < 0.05) for Lablab (41.13percent; 39.63percent) than Cowpea (39.86percent; 19.44percent), respectively. Both forages recorded higher dry matter (DM) digestibility coefficients at anthesis stage of growth 61.58percent, and 51.5 percent for Lablab and Cowpea respectively. The IVOM digestibility increased with stage of harvest (23.7percent to 25.57percent) for Cowpea while Lablab showed a decrease (44.6 percent to 43.9percent) when cattle inoculum was used. The IVDM digestibility was higher (P < 0.05) for Lablab (50.5percent) when cattle inoculum was used while Cowpea was observed to have higher digestibility co-efficiencies (38.54percent) when sheep inoculum was used. Cowpea had lower (P < 0.05) IVOM digestibility than Lablab (19.44percent) vs. 39.6percent). Lablab exhibited higher (P < 0.05) metabolisable energy (ME) values than Cowpea (6.21 vs. 2.70 MJ/kgDM). In the feeding study, the total DM intake by goats for Lablab was higher (P < 0.05) compared to Cowpea (688.1 vs. 607.8 g/head/ day). There was a positive (P < 0.05) correlation between dry matter intake and average daily gain (r= 0.8513, and r=0.5279) for Cowpea and Lablab respectively. Lablab and Cowpea promoted growth of Xhosa goats at a rate of 35.0g/d; and 38.3g/d, respectively which was not significantly different (P > 0.05). However, this growth was associated with a significantly higher (P < 0.05) food conversion ratio (FCR) of 19.16 vs 18.11 for Cowpea and Lablab, respectively. The apparent DM, non structural carbohydrate (NSC) nutrient digestibilities were significantly different (P < 0.05) for Lablab and Cowpea. Furthermore sex of animal influenced significantly (P < 0.05) the DM, ADF, NSC and NDF digestibilities. Lablab and Cowpea did not influence (P > 0.05) individual VFA molar concentrations in both sexes. However, animals fed Lablab had significantly higher butyrate concentrations (P < 0.05). Lablab and Cowpea forages significantly lowered (P > 0.05) enteric methane production in goats compared to a concentrate diet, and this was related to animal activity. Animals produced significantly more (P < 0.05) methane gas when ruminating than feeding or just standing. The average methane produced each year was lower but not significant (P > 0.05) for animals fed Cowpea than Lablab (4.602kg CH4, vs. 4.719kg CH4) when expressed per year. Male animals produced more gas than females with values of 17.40L/day; 12.46 g/kg DMI and 0.126g/day vs. 15.47L/day, 12.28 g/kg DMI, and 0.0109g/day, respectively. Forage legumes had no significant effects (P > 0.05) on serum total proteins (TP), globulin, urea, creatinine, alanine aminotransferase (ALT), alkaline phosphatase (ALP), and gamma- glutamyl transferase (GGT) concentrations, but serum concentration of albumin was influenced by the diets (P < 0.05). Sex of animals significantly influenced ALP concentration (P < 0.05) with male animals exhibiting higer ALP values than females. Measured over time, the plasma concentration of urea and ALP significantly increased (P < 0.05) while creatinine and cholesterol concentration decreased (P < 0.05). Although the overall serum concentration of urea, total proteins, globulin, creatinine, ALT, ALP and GGT remained unchanged among the treatments and between sexes; treatment by sex, treatment by day and sex by day interactions were significant (P < 0.05). The white blood cell (WBC), red blood cell (RBC), mean corpuscular haemoglobin (MCH), mean corpuscular haemoglobin concentration (MCHC), haemoglobin, haematocrite, platelet and mean platelet volume (MPV) levels were similar among treatments and between sexes (P > 0.05). The WBC decreased with time by 8.07 x10 9/l while mean crepuscular volume (MCV) increased by 11.83(fl) from day 15 to day 55. Treatment diets significantly (P < 0.05) influenced neutrophile (percent) content while sex influenced basophile (percent) content. There were no treatment or sex effects (P > 0.05) on lymphocytes (percent), monocytes (percent) and eosinophiles (percent). In the meat quality study, the dietary treatments and sex had a significant (P < 0.05) effect on dressing out percent (DPpercent), initial pH, redness (a*), yellowness (b*), Warner Blartze Shear force (WBS) , drip loss and cooking loss in the chevon from Xhosa goats. Compared with a commercial pellet diet, Lablab and Cowpea diets resulted in similar slaughter body weights (SBW), hot carcass weight (HCW) and cold dressed mass (CDM) of carcasses. However, female animals exhibited a significantly (P < 0.05) higher DPpercent than male animals (42.3percent vs. 38.9percent) for all treatments. The male animals exhibited significantly (P < 0.05) higher pH values one hour after slaughter than females (5.79 vs 5.67). Neverthreless the diet and gender did not significantly (P > 0.05) affect the ultimate pH (pHu). Meat samples from male animals had significantly (P < 0.05) higher redness values than females. Feeding cowpea significantly (P < 0.05) increased meat redness with the least drip loss of chevon. Female animals produced significantly (P < 0.05) tougher chevon compared to male animals; 4.16kg and 3.36kg for female and male, respectively. Lablab and Cowpea posses high CP levels and moderately lower NDF with high ADF values that influences dry matter intake (DMI), digestibility and growth of goats. These forage legumes meet animal requirements for fat, ADF, NDF, CP, Ca, Mn, zinc and Cu and their biomass yield is satisfactory.
- Full Text:
- Authors: Washaya, Soul
- Date: 2017
- Subjects: Legumes Forage Forage plants
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/9996 , vital:35249
- Description: The objective of the current study was to evaluate the nutritive value of forage legumes Lablab purpureus (Lablab) and Vigna unguiculata (Cowpea) and their effects on intake, growth, blood parameters and meat quality in Xhosa goats. Forages were established at UFH research farm in the summer of the 2014 /15 growing season in blocks measuring 8m width x 16m long for each legume, replicated three times, making a total of four blocks, and eight treatment units for each legume. Samples were collected at three different stages of growth of preanthesis, anthesis and post anthesis for biomass yield determination. A homogenous sub-sample was then oven dried for 72 hours at 60 0C. After drying the forage samples were milled through a 1mm screen and a 20g sample from each stage of growth and forage sample was subjected to proximate analysis, in-vitro digestibility and anti-nutrient evaluation. The in-vitro digestibility experiment was done with rumen liquor of cattle and sheep collected from an abbatoir. Tannins, total phenolics and sapponins were the only anti-nutrients evaluated as they are perceived to influence methanogenesis in ruminat animals. At 50percent flowering, forage legumes were harvested for hay making which was then used in an in-vivo trial to evaluate the nutritive value of forages. This trial was conducted using eighteen one-year-old goats of average weight 14.2±0.24 kg over a period of sixty days. The results showed that biomass yield, which increased with stage of growth, was significantly higher (P < 0.05) for Lablab than Cowpea (7.968t/ha vs 7.105t/ha). Cowpea exhibited higher moisture content (7.72percent), Ash (13.11percent), acid detergent fibre (ADF) (38.42percent) and crude protein (CP) (20.23percent) than Lablab which had 7.50percent, 11.45 percent, 36.17percent and 19percent, respectively. Lablab forage had significantly higher (P < 0.05) fat content (2.41percent), neutral detergent fibre (NDF) (49.27percent) and hemicellulose (13.07percent) than Cowpea which had 2.1percent; 46.91percent and 8.48percent, respectively. The stage of growth significantly (P < 0.05) affected the mineral content of both forages. Lablab showed significantly higher (P < 0.05) values (1.22percent 0.55percent, 2.67percent) than Cowpea (1.00percent, 0.45percent, 2.30percent) for calcium (Ca), phosphorus (P), and potassium (K) respectively. Lablab forage had significantly higher (P < 0.05) tannin (3.345mgCAE/gDM), phenolic (13.47mgGAE/gDM) and saponin (0.75percent) content compared to Cowpea with values of 1.494mgCAEg/DM; 9.402mgGAE/gDM and vs 1.55percent respectively. The tannin content significantly influenced in-vitro digestibility and enteric methane production. The forage type, harvesting stage and inoculum source significantly (P < 0.05) affected the in-vitro digestibility of the forages. The in-vitro dry matter (IVDM) and in-vitro organic matter (IVOM) digestibility was significantly higher (P < 0.05) for Lablab (41.13percent; 39.63percent) than Cowpea (39.86percent; 19.44percent), respectively. Both forages recorded higher dry matter (DM) digestibility coefficients at anthesis stage of growth 61.58percent, and 51.5 percent for Lablab and Cowpea respectively. The IVOM digestibility increased with stage of harvest (23.7percent to 25.57percent) for Cowpea while Lablab showed a decrease (44.6 percent to 43.9percent) when cattle inoculum was used. The IVDM digestibility was higher (P < 0.05) for Lablab (50.5percent) when cattle inoculum was used while Cowpea was observed to have higher digestibility co-efficiencies (38.54percent) when sheep inoculum was used. Cowpea had lower (P < 0.05) IVOM digestibility than Lablab (19.44percent) vs. 39.6percent). Lablab exhibited higher (P < 0.05) metabolisable energy (ME) values than Cowpea (6.21 vs. 2.70 MJ/kgDM). In the feeding study, the total DM intake by goats for Lablab was higher (P < 0.05) compared to Cowpea (688.1 vs. 607.8 g/head/ day). There was a positive (P < 0.05) correlation between dry matter intake and average daily gain (r= 0.8513, and r=0.5279) for Cowpea and Lablab respectively. Lablab and Cowpea promoted growth of Xhosa goats at a rate of 35.0g/d; and 38.3g/d, respectively which was not significantly different (P > 0.05). However, this growth was associated with a significantly higher (P < 0.05) food conversion ratio (FCR) of 19.16 vs 18.11 for Cowpea and Lablab, respectively. The apparent DM, non structural carbohydrate (NSC) nutrient digestibilities were significantly different (P < 0.05) for Lablab and Cowpea. Furthermore sex of animal influenced significantly (P < 0.05) the DM, ADF, NSC and NDF digestibilities. Lablab and Cowpea did not influence (P > 0.05) individual VFA molar concentrations in both sexes. However, animals fed Lablab had significantly higher butyrate concentrations (P < 0.05). Lablab and Cowpea forages significantly lowered (P > 0.05) enteric methane production in goats compared to a concentrate diet, and this was related to animal activity. Animals produced significantly more (P < 0.05) methane gas when ruminating than feeding or just standing. The average methane produced each year was lower but not significant (P > 0.05) for animals fed Cowpea than Lablab (4.602kg CH4, vs. 4.719kg CH4) when expressed per year. Male animals produced more gas than females with values of 17.40L/day; 12.46 g/kg DMI and 0.126g/day vs. 15.47L/day, 12.28 g/kg DMI, and 0.0109g/day, respectively. Forage legumes had no significant effects (P > 0.05) on serum total proteins (TP), globulin, urea, creatinine, alanine aminotransferase (ALT), alkaline phosphatase (ALP), and gamma- glutamyl transferase (GGT) concentrations, but serum concentration of albumin was influenced by the diets (P < 0.05). Sex of animals significantly influenced ALP concentration (P < 0.05) with male animals exhibiting higer ALP values than females. Measured over time, the plasma concentration of urea and ALP significantly increased (P < 0.05) while creatinine and cholesterol concentration decreased (P < 0.05). Although the overall serum concentration of urea, total proteins, globulin, creatinine, ALT, ALP and GGT remained unchanged among the treatments and between sexes; treatment by sex, treatment by day and sex by day interactions were significant (P < 0.05). The white blood cell (WBC), red blood cell (RBC), mean corpuscular haemoglobin (MCH), mean corpuscular haemoglobin concentration (MCHC), haemoglobin, haematocrite, platelet and mean platelet volume (MPV) levels were similar among treatments and between sexes (P > 0.05). The WBC decreased with time by 8.07 x10 9/l while mean crepuscular volume (MCV) increased by 11.83(fl) from day 15 to day 55. Treatment diets significantly (P < 0.05) influenced neutrophile (percent) content while sex influenced basophile (percent) content. There were no treatment or sex effects (P > 0.05) on lymphocytes (percent), monocytes (percent) and eosinophiles (percent). In the meat quality study, the dietary treatments and sex had a significant (P < 0.05) effect on dressing out percent (DPpercent), initial pH, redness (a*), yellowness (b*), Warner Blartze Shear force (WBS) , drip loss and cooking loss in the chevon from Xhosa goats. Compared with a commercial pellet diet, Lablab and Cowpea diets resulted in similar slaughter body weights (SBW), hot carcass weight (HCW) and cold dressed mass (CDM) of carcasses. However, female animals exhibited a significantly (P < 0.05) higher DPpercent than male animals (42.3percent vs. 38.9percent) for all treatments. The male animals exhibited significantly (P < 0.05) higher pH values one hour after slaughter than females (5.79 vs 5.67). Neverthreless the diet and gender did not significantly (P > 0.05) affect the ultimate pH (pHu). Meat samples from male animals had significantly (P < 0.05) higher redness values than females. Feeding cowpea significantly (P < 0.05) increased meat redness with the least drip loss of chevon. Female animals produced significantly (P < 0.05) tougher chevon compared to male animals; 4.16kg and 3.36kg for female and male, respectively. Lablab and Cowpea posses high CP levels and moderately lower NDF with high ADF values that influences dry matter intake (DMI), digestibility and growth of goats. These forage legumes meet animal requirements for fat, ADF, NDF, CP, Ca, Mn, zinc and Cu and their biomass yield is satisfactory.
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Energy services and energy poverty for sustainable development in Zimbabwe
- Authors: Mupindu, Chipo
- Date: 2017
- Subjects: Sustainable development -- Zimbabwe Zimbabwe -- Economic conditions
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/8408 , vital:32743
- Description: This study examines the effects of energy poverty on sustainable development in Zimbabwe. The principal objective of this study was to analyse Zimbabwe energy poverty as a contributing factor impacting on sustainable development. Access to energy was viewed as a human right in this study and attributes of ecological modernization and energy ladder theories were incorporated in the study so as to foster sustainable development. The study developed a symbiosis between energy poverty and human development in Zimbabwe. The power shortages have caused a lot of energy poverty and load shedding in the country and this has had adverse consequences on the transformation of the economy as well as the general human capacity development in the country. The supply shortage was as a result of many factors which include the lack of investment in the power sector by government for expanded generation capacity, ageing equipment, incorrect pricing, bad debts, droughts, internal conflicts, skills flight, and government energy sector regulation, vandalisation of equipment and under supply of coal to thermal power stations. The country needs to commit itself towards improving the current situation by revising the energy policy to include alternative sources, the integration of regional power systems and construction of more power stations, and by putting research monitoring and evaluation mechanisms in place so as to improve power generation capacity which meets the demand of the country. The evidence from the findings gathered in this study led to the conclusion that the Zimbabwe energy and power sector lacks the capacity to provide adequate reliable clean energy to the nation and this has affected the development of the country.
- Full Text:
- Authors: Mupindu, Chipo
- Date: 2017
- Subjects: Sustainable development -- Zimbabwe Zimbabwe -- Economic conditions
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/8408 , vital:32743
- Description: This study examines the effects of energy poverty on sustainable development in Zimbabwe. The principal objective of this study was to analyse Zimbabwe energy poverty as a contributing factor impacting on sustainable development. Access to energy was viewed as a human right in this study and attributes of ecological modernization and energy ladder theories were incorporated in the study so as to foster sustainable development. The study developed a symbiosis between energy poverty and human development in Zimbabwe. The power shortages have caused a lot of energy poverty and load shedding in the country and this has had adverse consequences on the transformation of the economy as well as the general human capacity development in the country. The supply shortage was as a result of many factors which include the lack of investment in the power sector by government for expanded generation capacity, ageing equipment, incorrect pricing, bad debts, droughts, internal conflicts, skills flight, and government energy sector regulation, vandalisation of equipment and under supply of coal to thermal power stations. The country needs to commit itself towards improving the current situation by revising the energy policy to include alternative sources, the integration of regional power systems and construction of more power stations, and by putting research monitoring and evaluation mechanisms in place so as to improve power generation capacity which meets the demand of the country. The evidence from the findings gathered in this study led to the conclusion that the Zimbabwe energy and power sector lacks the capacity to provide adequate reliable clean energy to the nation and this has affected the development of the country.
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Market participation and value chain integration among smallholder homestead and irrigated crop farmers in the Eastern Cape province of South Africa
- Authors: Mdoda, Lelethu
- Date: 2017
- Subjects: Farms, Small -- South Africa -- Eastern Cape Irrigation farming -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/15023 , vital:40152
- Description: The irrigation schemes had been established over the years and now are operational but there is no marked improvement in the living conditions of the rural farmers and households. Smallholder farmers still face numerous constraints in market participation that hinder smallholder farmers, irrigators and homestead growth which have been attributed to lack of access to markets and technical expertise. Despite the government efforts, smallholder farmers effectively functioning in the agro-food chains, high-valued markets and commercial agricultural markets are rare; this indicates that the objective to allow smallholder farmers to advance their livelihood through participating in commercial agro-food chains has not yet been met. Farmers in the Eastern Cape produce many crops which they mainly sell in informal local markets; there is minimal number of smallholder farmers supplying their produce to the formal markets. Irrigation development is very crucial to the development of the agricultural sector as it ensures improvement in yields and reduces rural poverty through creating rural employment, enhance smallholder farmers’ market participation and enhance market access policies by smallholder farmers as means to achieve the Sustainable Development Goals The study was conducted in the Eastern Cape Province and employed survey data obtained from 200 smallholder irrigated crop farmers and homestead gardeners. A multistage stratified sampling procedure was used in which the first stage involved selecting the study areas. This was followed by the selection of the district and then the respondents. The farmers were selected from three District Municipalities which have operational irrigation schemes, namely OR Tambo, Amathole and Chris Hani District Municipalities in the province. STATA and SPSS were used to analyze the data. The Heckman model was applied to examine factors influencing farmers’ decision to participate in market among crop producing farmers in the province. In the first stage Heckman analysis, the decision as to whether or not to participate (which is a binary choice situation) is used to undertake the maximum likelihood estimation (MLE). In the second stage, the conditional quantity sold (continuous variable) is assumed to follow a truncated normal regression model, whereby the MLE is estimated by fitting a truncated normal regression of quantity sold. Gross Margin and Net Farm Income were used to measure farm profit as well as multiple regression analysis to estimate determinants of profitability in the study area. Profit efficiency was measured using the normalized transcendent logarithmic profit frontier approach (translog). he descriptive statistics employed include means, percentages and frequencies mostly of the socio-economic characteristics of farmers in the study area. The results show that males were dominant with the representation of 61.7percent. The majority of farmers were aged and the mean age was 60 years, indicating that farmers in the province are old which has implication for productivity and market participation. High level of illiteracy is shown in the data and mean household size of 5 persons with the household head having at least obtained some primary school education.The irrigated crop farmers and homesteads were found to have farm size under 4 ha. About 86.5percent were full time farmers and Farming is their major source of livelihood. Smallholder irrigators and homestead gardeners derive their income from social grants and remittances. This thesis found out that majority of the farmers do not participate in markets. In this instance, farming becomes a scapegoat for failure to enter alternative labour markets. The average annual on-farm production income from smallholder irrigators was R7 860.27 and homestead gardeners was R5 915.50. The empirical results from probit model suggest that age of the farmer, level of education of the farmer, household size, farm organization, access to extension, distance to markets, occupation and farm experience were some of the key determinants that had significant and positive effects on farmers’ decision to participate in markets while access to credit, transport to the markets and farm size were some of the key determinants that had significant and negative effect on farmers’ decision to participate in markets. The volume of crops sold to the market is determined by gender, age, years spent in school, distance to the market, farm experience, household size, access to extension, membership in farm organization and non-farm income.
- Full Text:
- Authors: Mdoda, Lelethu
- Date: 2017
- Subjects: Farms, Small -- South Africa -- Eastern Cape Irrigation farming -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/15023 , vital:40152
- Description: The irrigation schemes had been established over the years and now are operational but there is no marked improvement in the living conditions of the rural farmers and households. Smallholder farmers still face numerous constraints in market participation that hinder smallholder farmers, irrigators and homestead growth which have been attributed to lack of access to markets and technical expertise. Despite the government efforts, smallholder farmers effectively functioning in the agro-food chains, high-valued markets and commercial agricultural markets are rare; this indicates that the objective to allow smallholder farmers to advance their livelihood through participating in commercial agro-food chains has not yet been met. Farmers in the Eastern Cape produce many crops which they mainly sell in informal local markets; there is minimal number of smallholder farmers supplying their produce to the formal markets. Irrigation development is very crucial to the development of the agricultural sector as it ensures improvement in yields and reduces rural poverty through creating rural employment, enhance smallholder farmers’ market participation and enhance market access policies by smallholder farmers as means to achieve the Sustainable Development Goals The study was conducted in the Eastern Cape Province and employed survey data obtained from 200 smallholder irrigated crop farmers and homestead gardeners. A multistage stratified sampling procedure was used in which the first stage involved selecting the study areas. This was followed by the selection of the district and then the respondents. The farmers were selected from three District Municipalities which have operational irrigation schemes, namely OR Tambo, Amathole and Chris Hani District Municipalities in the province. STATA and SPSS were used to analyze the data. The Heckman model was applied to examine factors influencing farmers’ decision to participate in market among crop producing farmers in the province. In the first stage Heckman analysis, the decision as to whether or not to participate (which is a binary choice situation) is used to undertake the maximum likelihood estimation (MLE). In the second stage, the conditional quantity sold (continuous variable) is assumed to follow a truncated normal regression model, whereby the MLE is estimated by fitting a truncated normal regression of quantity sold. Gross Margin and Net Farm Income were used to measure farm profit as well as multiple regression analysis to estimate determinants of profitability in the study area. Profit efficiency was measured using the normalized transcendent logarithmic profit frontier approach (translog). he descriptive statistics employed include means, percentages and frequencies mostly of the socio-economic characteristics of farmers in the study area. The results show that males were dominant with the representation of 61.7percent. The majority of farmers were aged and the mean age was 60 years, indicating that farmers in the province are old which has implication for productivity and market participation. High level of illiteracy is shown in the data and mean household size of 5 persons with the household head having at least obtained some primary school education.The irrigated crop farmers and homesteads were found to have farm size under 4 ha. About 86.5percent were full time farmers and Farming is their major source of livelihood. Smallholder irrigators and homestead gardeners derive their income from social grants and remittances. This thesis found out that majority of the farmers do not participate in markets. In this instance, farming becomes a scapegoat for failure to enter alternative labour markets. The average annual on-farm production income from smallholder irrigators was R7 860.27 and homestead gardeners was R5 915.50. The empirical results from probit model suggest that age of the farmer, level of education of the farmer, household size, farm organization, access to extension, distance to markets, occupation and farm experience were some of the key determinants that had significant and positive effects on farmers’ decision to participate in markets while access to credit, transport to the markets and farm size were some of the key determinants that had significant and negative effect on farmers’ decision to participate in markets. The volume of crops sold to the market is determined by gender, age, years spent in school, distance to the market, farm experience, household size, access to extension, membership in farm organization and non-farm income.
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Ruthenium sulphide nanoparticles derived from tri-dithiocarbamato ruthenium (III) complexes : synthesis, optical and structural studies
- Authors: Mbese, Johannes Zanoxolo
- Date: 2017
- Subjects: Nanoparticles Ruthenium compounds
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/15420 , vital:40406
- Description: The present Thesis pioneer the application of single-source molecular precursor method for the synthesis of ruthenium sulfide nanoparticles using a series of novel self-prepared single-source molecular precursors. The preparation of precursors involved the design and synthesis of compounds containing all the desired elements required within the coordination compound. Good precursors are tailored to give reproducible, clean decomposition at moderate temperatures, leading to high quality, defect free, mono-dispersed nanoparticles. Nine (9) homonuclear tris-dithiocarbamato ruthenium(III) complexes, [Ru(S2CNR2)3] were prepared from a stoichiometric reaction of RuCl3·H2O with self-prepared dithiocarbamate ligands at room temperature in a molar ratio of Ru3+: Ligand of 1:3. Dithiocarbamate ligands were derived from a stoichiometric reaction of carbon disulfide with (aniline, N-allylmethylamine, p-toluidine, p-anisidine, N-ethyl-m-toluidine, piperidine, morpholine, di-isopropylamine, and diallylamine) in the presence of concentrated ammonia or potassium hydroxide in ice cold bath. The dithiocarbamate ligands and complexes were characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopy (FTIR), 1H- and 13C-NMR spectroscopy. Thermogravimetric analyses (TGA) was used to study the decomposition profiles of the precursor complexes. The results obtained from the TGA of precursors showed that the complexes decompose to ruthenium sulfide nanoparticles. The FTIR spectra of the ligands revealed prominent strong absorption bands ascribed to v(N-H) stretching vibrations and also confirm the bidentate coordination of the dithiocarbamate ligands. Ruthenium(III) complexes show absorption spectra in the visible region that exhibit bands attributed to n → π* electronic transitions located on the sulfur atoms located in the S–C–S and N–C–S chromophores of the bidentate dithiocarbamate ligands respectively. The absorption spectra also confirmed the geometry of ruthenium(III) complexes to be octahedral. The proposed structures of dithiocarbamate ligands and ruthenium(III) complexes were confirmed by the 1H- and 13C-NMR. The complexes were used as single-source molecular precursors for the synthesis of ruthenium sulfide nanoparticles. The structural and optical properties were studied using transmission electron microscope (TEM), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), UV-Vis absorption and photoluminescence (PL) spectra. FTIR revealed that Ru2S3 nanoparticles are capped through the interaction of the –NH2 group of hexadecylamine HDA adsorbed on the surfaces of nanoparticles and it also showed that oleic acid (OA) is acting as both coordinating stabilizing surfactant and capping agent. The XRD confirmed the successful formation of Ru2S3 nanoparticles induced by the thermal decomposition of series of [Ru(S2CNR2)3] complexes. The diffraction peaks: 2θ = 29.43, 40.54, 49.33, 51.86, 61.92, and 75.94 were assign the Miler indices (hkl) to be (111), (211), (220), (300), (222) and (330) reflections, respectively, and were found to be in agreement with a cubic crystal structure reported in database file of (JCPDS 19-1107). The particle sizes estimated from Scherer's equation were found in a range between 2.5 and 4.9 nm. EDS spectra reveal that the prepared nanoparticles are mainly composed of Ru and S, confirming the presence of Ru2S3 nanoparticles in cubic phase. The inner morphology of nanoparticles was obtained by transmission electron microscopy (TEM) and most nanoparticles had narrow particle size distribution characterized by an average diameter of 8.45 nm with a standard deviation of 1.6 nm. The optical band gap (Eg) determined from Tauc plot was found in the range (3.44 to 4.18 eV) values.
- Full Text:
- Authors: Mbese, Johannes Zanoxolo
- Date: 2017
- Subjects: Nanoparticles Ruthenium compounds
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/15420 , vital:40406
- Description: The present Thesis pioneer the application of single-source molecular precursor method for the synthesis of ruthenium sulfide nanoparticles using a series of novel self-prepared single-source molecular precursors. The preparation of precursors involved the design and synthesis of compounds containing all the desired elements required within the coordination compound. Good precursors are tailored to give reproducible, clean decomposition at moderate temperatures, leading to high quality, defect free, mono-dispersed nanoparticles. Nine (9) homonuclear tris-dithiocarbamato ruthenium(III) complexes, [Ru(S2CNR2)3] were prepared from a stoichiometric reaction of RuCl3·H2O with self-prepared dithiocarbamate ligands at room temperature in a molar ratio of Ru3+: Ligand of 1:3. Dithiocarbamate ligands were derived from a stoichiometric reaction of carbon disulfide with (aniline, N-allylmethylamine, p-toluidine, p-anisidine, N-ethyl-m-toluidine, piperidine, morpholine, di-isopropylamine, and diallylamine) in the presence of concentrated ammonia or potassium hydroxide in ice cold bath. The dithiocarbamate ligands and complexes were characterized by elemental analyses, UV-Vis, Fourier transform infrared spectroscopy (FTIR), 1H- and 13C-NMR spectroscopy. Thermogravimetric analyses (TGA) was used to study the decomposition profiles of the precursor complexes. The results obtained from the TGA of precursors showed that the complexes decompose to ruthenium sulfide nanoparticles. The FTIR spectra of the ligands revealed prominent strong absorption bands ascribed to v(N-H) stretching vibrations and also confirm the bidentate coordination of the dithiocarbamate ligands. Ruthenium(III) complexes show absorption spectra in the visible region that exhibit bands attributed to n → π* electronic transitions located on the sulfur atoms located in the S–C–S and N–C–S chromophores of the bidentate dithiocarbamate ligands respectively. The absorption spectra also confirmed the geometry of ruthenium(III) complexes to be octahedral. The proposed structures of dithiocarbamate ligands and ruthenium(III) complexes were confirmed by the 1H- and 13C-NMR. The complexes were used as single-source molecular precursors for the synthesis of ruthenium sulfide nanoparticles. The structural and optical properties were studied using transmission electron microscope (TEM), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), UV-Vis absorption and photoluminescence (PL) spectra. FTIR revealed that Ru2S3 nanoparticles are capped through the interaction of the –NH2 group of hexadecylamine HDA adsorbed on the surfaces of nanoparticles and it also showed that oleic acid (OA) is acting as both coordinating stabilizing surfactant and capping agent. The XRD confirmed the successful formation of Ru2S3 nanoparticles induced by the thermal decomposition of series of [Ru(S2CNR2)3] complexes. The diffraction peaks: 2θ = 29.43, 40.54, 49.33, 51.86, 61.92, and 75.94 were assign the Miler indices (hkl) to be (111), (211), (220), (300), (222) and (330) reflections, respectively, and were found to be in agreement with a cubic crystal structure reported in database file of (JCPDS 19-1107). The particle sizes estimated from Scherer's equation were found in a range between 2.5 and 4.9 nm. EDS spectra reveal that the prepared nanoparticles are mainly composed of Ru and S, confirming the presence of Ru2S3 nanoparticles in cubic phase. The inner morphology of nanoparticles was obtained by transmission electron microscopy (TEM) and most nanoparticles had narrow particle size distribution characterized by an average diameter of 8.45 nm with a standard deviation of 1.6 nm. The optical band gap (Eg) determined from Tauc plot was found in the range (3.44 to 4.18 eV) values.
- Full Text:
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