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Aspects of heterothermy in four species of afrotropical bats

  • Authors: Doty, Anna Catherine
  • Date: 2012
  • Subjects: Body temperature -- Regulation , Afrotropical mammals , Body temperature , Bats
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10691 , http://hdl.handle.net/10948/d1008402 , Body temperature -- Regulation , Afrotropical mammals , Body temperature , Bats
  • Description: Torpor and hibernation, two distinct forms of heterothermy, are physiological responses employed by many endotherms to save energy during periods of cold, climatic unpredictability and food shortage. Heterothermy is characterized by varying body temperature and has been found to occur in various subtropical mammals. However, studies on thermoregulatory capabilities of South African Microchiroptera remain relatively scant. In this study, the capacity for use of heterothermy, the seasonal metabolic rates, and capacity for non-shivering thermogenesis were studied in four species of bats, namely Rhinolophus clivosus, Rhinolophus capensis, Miniopterus natalensis and Myotis tricolor. Animals were collected from a group of three mines in Sleepy Hollow Farm, 30km from Port Elizabeth, South Africa. All species demonstrated bouts of torpor in the winter while R. clivosus interestingly established a high propensity for torpor in the summer and normothermia in the winter. To my knowledge, this is the first study that has shown the down-regulation of metabolism and body temperature in summer and constant maintenance of normothermic body temperature in winter in a species of Microchiroptera. M. natalensis was thermolabile in both summer and winter and body temperatures closely tracked ambient temperatures. Mean ± SD normothermic body temperature measured of wild-caught R. clivosus and M. natalensis was 38.6 ± 1.7°C and 37.3 ± 2.2°C, respectively. Mean torpid body temperature measured of wild-caught R. clivosus, R. capensis and M. natalensis was 22.7 ± 3.3°C, 21.1 ± 3.2 °C, and 22.6 ± 3.1°C, respectively. Non-shivering thermogenesis was measured in R. clivosus and M. natalensis to determine the role of endogenous heat production in a volant mammal. The mean noradrenalineinduced thermogenesis ± SD in R. clivosus and M. natalensis was 2.6 ± 0.8 ml g-1 hr-1 and 2.7 ± 0.6 ml O2 g-1 hr-1, respectively. Both species demonstrated capacity for non-shivering thermogenesis, and this is the first study that has quantified the maximal response to noradrenaline in an Afrotropical Microchiropteran species. Physiology of Afrotropical bats is understudied and the extent to which torpor and/or hibernation is utilized amongst them remains relatively unknown. Heterothermy clearly plays a significant role in the energetic savings and balance of all four species in the study.
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  • Date Issued: 2012

Characterisation and optimisation of waterjet impact forces and energy parameters during hydroentanglement

  • Authors: Moyo, Doice
  • Date: 2012
  • Subjects: Textile chemistry , Nonwoven fabrics
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:10453 , http://hdl.handle.net/10948/d1020134
  • Description: Hydroentanglement is an important technique of bonding fibres to produce nonwovens using high velocity waterjets as the primary bonding tool. The work reported in this thesis addresses the gap in scientific knowledge and understanding, both theoretical and experimental, related to the impact forces and energy of the waterjets used in the hydroentanglement process. The current study focused on the impact forces and energy involved in, and the optimisation of, the hydroentanglement process. The results of the experimentally measured waterjet impact forces have been used to characterise the waterjets as well as to verify empirically the theoretical models currently available for explaining the mechanics of the hydroentanglement process. Since the process of supplying pressurised waterjets consumes a great deal of energy, the study of energy consumption and efficiency of the system has been critical. A method was proposed and used to determine the coefficients of velocity and water discharge of an industrial machine set-up, helping explain the mechanism of energy transfer during hydroentanglement and to concurrently optimise the process. Furthermore, a response surface experimental design was used to optimise the hydroentanglement of viscose and Polylactic acid (PLA) fibres into nonwovens. The selected Box-Behnken design, with four factors, namely the waterjet force, machine processing speed, input weight and fibre type, was employed to investigate the multivariate process factors and their interactive effects on physical and mechanical properties of nonwovens. Two sets of experiments, the later for validation, were performed to study the energy transfer efficiency. The results of the relative energy transfer to bond the fibrous web showed that it was possible to produce nonwovens using lower input energy without compromising the quality of the products. The optimum waterjet pressure and machine speed used to produce the Abstract nonwoven with the highest tensile strength for the least amount of energy supplied were identified.
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  • Date Issued: 2012

Characterization of cell mismatch in photovoltaic modules using electroluminescence and associated electro-optic techniques

  • Authors: Crozier, Jacqueline Louise
  • Date: 2012
  • Subjects: Photovoltaic cells , Solar cells
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10545 , http://hdl.handle.net/10948/d1015059
  • Description: Solar cells allow the energy from the sun to be converted into electrical energy; this makes solar energy much more environmentally friendly than fossil fuel energy sources. These solar cells are connected together in a photovoltaic (PV) module to provide the higher current, voltage and power outputs necessary for electrical applications. However, the performance of the PV module is limited by the performance of the individual cells. Cell mismatch occurs when some cells are damaged or shaded and produce lower current output than the other cells in the series connected string. The cell mismatch lowers the module performance and can result in further damage as the weak cells are reverse biased and dissipate heat. Bypass diodes can be connected into the module to increase the module current output and prevent further damage. Since cell mismatch results in a significant decrease in the performance of deployed modules it is important to fully understand and characterise its effect on PV modules. PV modules can be characterised using various techniques, each providing important information about the performance of the module. Most commonly the current-voltage (I-V) characteristic curve of a module is measured in outdoor, fully illuminated conditions. This allows performance parameters such as short circuit current (Isc), open circuit voltage (Voc) and maximum power (Pmax) to be determined. In addition to this the shape of the curve allows device parameters like series and shunt resistances to be determined using parameter extraction algorithms like Particle Swarm Optimisation (PSO). The extracted parameters can be entered into the diode equation to model the I-V curve of the module. The I-V characteristic of the module can also be used to identify poor current producing cells in the module by using the worst-case cell determination method. In this technique a cell is shaded and the greater the drop in current in the whole module the better the current production of the shaded cell. The photoresponse of cells in a module can be determined by the Large-area Light Beam Induced Current (LA-LBIC) technique which involves scanning a module with a laser beam and recording the current generated. Electroluminescence (EL) is emitted by a forward biased PV module and is used to identify defects in cell material. Defects such as cracks and broken fingers can be detected as well as material features such as grain boundaries. These techniques are used to in conjunction to characterise the modules used in this study. The modules investigated in this study each exhibit cell mismatch resulting from different causes. Each module is characterised using a combination of characterisation techniques which allows the effect of cell mismatch be investigated. EL imaging enabled cracks and defects, invisible to the naked eye, to be detected allowing the reduced performance observed in I-V curves to be explained. It was seen that the cracked cells have a significant effect on the current produced by a string, while the effect of delaminated areas is less severe. Hot spots are observed on weak cells indicating they are in reverse bias conditions and will degrade further with time. PSO parameter extraction from I-V curves revealed that the effect of module degradation of device parameters like series and shunt resistances. A module with cracked cells and degradation of the antireflective coating has low shunt resistance indicating current losses due to shunting. Similar shunting is observed in a module with delamination and moisture ingress. The extracted parameters are used to simulate the I-V curves of modules with reasonable fit. The fit could be improved around the “knee” of the I-V curve by improving the methods of parameter extraction. This study has shown the effects of cell mismatch on the performance and I-V curves of the PV modules. The different causes of cell mismatch are discussed and modules with different cell configuration and damage are characterised. The characterisation techniques used on each module provide information about the photoresponse, current generation, material properties and cell defects. A comprehensive understanding of these techniques allows the cell mismatch in the modules to be fully characterized.
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  • Date Issued: 2012

Creating a space for integrative education within the sciences

  • Authors: Van der Post, Leda
  • Date: 2012
  • Subjects: Computer science -- Vocational guidance , Education, Cooperative , Curriculum evaluation , Experiential learning -- Science
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:10482 , http://hdl.handle.net/10948/d1012677 , Computer science -- Vocational guidance , Education, Cooperative , Curriculum evaluation , Experiential learning -- Science
  • Description: This thesis documents an action research project that was carried out within the Department of Computing Sciences at the Nelson Mandela Metropolitan University (NMMU), South Africa, from January 2010 to December 2011. The overall aim of the research was to foster an environment in which academics could explore ways to teach using an integrative approach to education. Previous research within the department had raised the concern that students were graduating without the type of high-level cognitive skills that were required in the workplace. While the students’ technical skills were perceived as being excellent, employers indicated that students would benefit from opportunities to develop or improve skills such as communication, teamwork, innovative thinking and time management. These skills include high-level cognitive skills, and are often referred to as “soft skills”. The academics participating in the research project came to believe that it was essential to develop teaching methods that would provide opportunities for students to develop these soft skills, in conjunction with the content and technical knowledge currently addressed in their courses. The research project followed the living theory approach to action research. A living theory action research project allows the researcher to investigate her own teaching, and develop a theory of practice. The theory of practice can be applied to the issues under investigation, to improve the situation or solve problems. At the same time, the theory of practice can contribute to the body of knowledge within the academic domain of the research. Action research is an iterative, cyclical process. There were four research cycles, each one semester in length, during the two years of the project. The project will continue, with a fifth research cycle, starting in January 2012. By the end of the fourth research cycle—Semester Two, 2011—there were eleven academics actively participating in the research group. The project had extended its influence to include academics from the Department of Mathematics at NMMU. The academics ranged from senior, long-serving professors to junior lecturing staff. The results of the research, or the researcher-practitioner’s living theory, explain the process by which an effective and enthusiastic community of practice, dedicated to improving the academics’ teaching and learning practice, was developed. The living theory is applicable to academics within a scientific discipline, desiring to explore and improve their education practice. My living theory explains the characteristics of the TLC (The Learning Community) space, and the action strategies for creating such a space. The explanation of the process of this project includes an analysis of the development process of the research group, typical characteristics of the environment or “space” of the group, and action strategies that other academics could use to create a similar community of practice.
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  • Date Issued: 2012

Creation of clay flameless burner for vaporizing an insect repellent containing pmd as an active ingredient

  • Authors: Akwi, Faith Mary
  • Date: 2012
  • Subjects: Insect baits and repellents , Montmorillonite
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10383 , http://hdl.handle.net/10948/d1008406 , Insect baits and repellents , Montmorillonite
  • Description: Insecticide treated mosquito bed nets, insecticide aerosol sprays, repellent lotions and creams, repellent candles, vaporizable repellent essential oils, mosquito mats and coils are some of the many malaria personal protection tools that are in use. The latter of these measures are the most accessible and affordable options for the rural population in sub-Saharan Africa. It is therefore important to determine how effective these personal protection measures are by determining their ability to efficiently disperse an active ingredient when the protection measure is in use. In this study, a copper II oxide montmorillonite clay burner (CuOMontmorillonite clay burner) was created to vaporize repellent formulations containing various concentrations of p-menthane-3,8-diol (PMD) as the active ingredient with the aim of determining the percentage of the active ingredient that is released into the air and the rate of release. The performance of the CuO-Montmorillonite clay burner was also compared to that of the Lampe Berger fragrance burner (LBFB). In addition to this, the percentage of PMD released from 6 percentage wt PMD candles of diameters 40mm, 69mm and 83mm was determined and compared to that released when the CuO-Montmorillonite clay burner and Lampe Berger Fragrance burner where used to vaporize PMD repellent formulations. It was found that the rate of vaporization of the various PMD repellent formulations vaporized using the Lampe Berger fragrance burner is affected by the mass of PMD present in the repellent formulations. The 6 percentage wt PMD repellent candles released the least percentage of PMD as compared to that released when the CuO-Montmorillonite clay burner and the Lampe Berger fragrance burner were used to vaporize the PMD repellent formulations.
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  • Date Issued: 2012

Curcumin analogues as ligands for Re (I) and (V)

  • Authors: Schmitt, Bonell
  • Date: 2012
  • Subjects: Rhenium , Ligands , Chemistry, Inorganic
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10443 , http://hdl.handle.net/10948/d1020975
  • Description: Coordination properties of 4-bromo-N-(diethylcarbamothioyl)benzamide (Hbeb) and 4-bromo-N-(diphenylcarbamothioyl)benzamide (Hbpb) with oxorhenium(V) and rhenium(I) are reported and discussed. Transition metal complexes of these ligands were studied due to the wide range of applications of thiourea derivatives in biological fields. N-[Di(alkyl/aryl)carbamothioyl]benzamide derivatives readily coordinate to metal ions as O,S-donors and the catalytic property of the complexes can be altered by these ligands, due to steric and electronic properties provided by various substituents. The coordination possibilities of curcumin with rhenium(V) are discussed, as well as the difficulties encountered. Analogues of curcumin have been made, which also contains a seven-spacer unit between the phenyl rings, which would be more reactive and more effective in bonding to rhenium and which have greater or a similar biological activity to curcumin. This was done by assessing the coordination properties of 1,5-bis(salicylidene)thiocarbohydrazide (H4salt) and 2,4-bis(vanilidene)thiocarbohydrazide (H4vant) with oxorhenium(V) and rhenium(I) starting materials. Two rhenium(V) complex salts of the core [ReX(PPh3)2]4+ (X = Br, I), containing a coordinated imido nitrogen, are reported. One is a ‘2+1’ complex, coordinating bi- and monodentately, with the other a similar ‘3+0’ complex containing a tridentate imido-coordinated Schiff base. Selected compounds were tested against oesophageal cancer cell lines in order to evaluate and compare their effectiveness in eliminating or reducing the cancer cells in the test medium during biological testing.
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  • Date Issued: 2012

Development of a degreasing and anti-fogging formulation for wet wipe application for automotive glass surfaces

  • Authors: Bosch, Tanya
  • Date: 2012
  • Subjects: Porous materials -- Transport properties , Hydrophobic surfaces , Vapor degreasing , Cleaning compounds , Water-soluble polymers
  • Language: English
  • Type: Thesis , Masters , MTech
  • Identifier: vital:10418 , http://hdl.handle.net/10948/d1013177
  • Description: It was the objective of this project to provide a glass cleaner formulation for a wet wipe application with cleaning and anti-fogging properties. This glass cleaner formulation was developed for automotive glass i.e. interior of windscreens. This formulation relates to a glass cleaner with a composition comprising of: (a) a blend of amphoteric surfactants; (b) a solvent system with a combination of glycol ethers; and (c) an aqueous solvent system. This glass formulation must provide good cleaning properties while also providing good wetting and sheeting properties to assist with anti-fogging properties. The objectives were obtained using 2 specific approaches: The first was by using a blend of 2 amphoteric surfactants in an alkaline medium, allowing the glass surface to become more hydrophilic which will also assist with reduction of surface tension on the glass surface. The second was by using the glycol ethers that have good coupling properties and surface tension reducing properties. The formulation was evaluated using commercial standard test methods as per the industry. A predictive model was successfully obtained for each of the five criteria that were evaluated using the 25 formulations derived from the statistical design. There were variables and variable interactions that were antagonistic for some of the criteria which were found to be synergistic for others. To achieve satisfactory cleaning, the fogging rating had to be compromised.
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  • Date Issued: 2012

Effect of cultivar on the quality of flax and hemp grown in South Africa

  • Authors: Blouw, Langa Sunshine
  • Date: 2012
  • Subjects: Hemp -- South Africa , Flaxseed -- South Africa , Plant varieties , Textile industry
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:9387 , http://hdl.handle.net/10948/d1010997 , Hemp -- South Africa , Flaxseed -- South Africa , Plant varieties , Textile industry
  • Description: Bast fibrous renewable materials, as commercial crops for the manufacture of textile based and other products, have been used for thousands of years to satisfy certain human needs, such as for shelter, clothing, source of energy and tools, and to sustain the livelihood of many communities in countries, such as in Asia, Europe and Africa. Concern for the environment has led to a number of global initiatives that favour the use of natural fibres. It is forecast that the global fibre demand by 2050 will be 130 million tonnes, which the cotton and synthetic fibre production will not be able to meet. Other than the environmental concerns, the renewed global interest in natural fibres, such as flax and hemp, forms part of a strategy to satisfy the fibre demand. South Africa, notwithstanding the fact that the flax and hemp industries have long been established for thousands of years in Europe, Asia and Egypt (Africa), has no history of the breeding, growing, processing and production of these cash crops. The renewed global interest in these crops has also stimulated interest from South Africa with respect to the development of a flax and hemp fibre industry so as to address some of the socio-economic challenges confronting the country today in its attempts to bring about real development in the rural areas through the cultivation and complete beneficiation of these fibre crops. In this regard, the relevant stakeholders, namely government, research councils, tertiary education institutions, farmers and communities worked together to investigate whether South Africa has the agronomic and climatic conditions, technical expertise as well as the necessary processing and production infrastructure to support the development of a local flax and hemp agro-industry. The purpose of this study was firstly to evaluate the performance of EU flax and hemp cultivars grown under different agronomic conditions in South Africa, and their effect on straw biomass yield, fibre yield and total fibre yield per hectare as well as associated fibre properties, and secondly to undertake mechanical fibre modification trials aimed at producing flax and hemp fibres with fibre diameters close to those of cotton. The minimum fibre diameter targeted being 20μm. In accordance with the project objectives and work plan, selected dew retted flax and hemp straw samples from the various planting sites selected by the Agriculture Research Council – Institute for Industrial Crops, representing all the agronomic conditions under investigation, were taken to the CSIR for fibre extraction and testing. A relatively inexpensive and easy to operate Russian designed and manufactured machine, the CMT-200M breaker-cum-scutcher, was used for fibre extraction and the resultant extracted fibre bundles were further refined, using a steel comb, to obtain optimal fibre separation before their physical and chemical properties were evaluated. Results obtained in this research study proved that the climatic and agronomic conditions in South Africa were suitable for the cultivation of flax and hemp, notwithstanding the fact that the fibre yields achieved for hemp were lower than the minimum criteria of 23 percent, and that for flax only just exceeded the 25 percent minimum. The lack of local technical expertise on the growing and retting of flax and hemp, contributed to the low fibre yields. The planting parameters which were found to produce good results for the cultivation of hemp were the October planting date, using a row spacing of between 12.5 to 25 cm, with a seeding density of between 80 – 100kg, and the application of 50 – 100kg nitrogen fertiliser. The use of extra artificial lighting and herbicide treatment did not appear to beneficially improve the hemp fibre yields. Similar considerations for flax cultivation in the Southern Cape region, particularly Oudtshoorn and Outeniqua, indicated that May to July planting dates, using inter-row spacing of 25cm and sowing density of 63kg seed.haˉ¹, produced a fibre yield and total fibre yield per hectare above the minimum values of 25 percent and 0,8 tonnes per hectare, respectively, quoted in the literature.
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  • Date Issued: 2012

Enhanced sensor-based interaction techniques for mobile map-based applications

  • Authors: Van Tonder, Bradley Paul
  • Date: 2012
  • Subjects: Cartography , User interfaces (Computer systems) -- Design , Digital mapping
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:10483 , http://hdl.handle.net/10948/d1012995
  • Description: Mobile phones are increasingly being equipped with a wide range of sensors which enable a variety of interaction techniques. Sensor-based interaction techniques are particularly promising for domains such as map-based applications, where the user is required to interact with a large information space on the small screen of a mobile phone. Traditional interaction techniques have several shortcomings for interacting with mobile map-based applications. Keypad interaction offers limited control over panning speed and direction. Touch-screen interaction is often a two-handed form of interaction and results in the display being occluded during interaction. Sensor-based interaction provides the potential to address many of these shortcomings, but currently suffers from several limitations. The aim of this research was to propose enhancements to address the shortcomings of sensor-based interaction, with a particular focus on tilt interaction. A comparative study between tilt and keypad interaction was conducted using a prototype mobile map-based application. This user study was conducted in order to identify shortcomings and opportunities for improving tilt interaction techniques in this domain. Several shortcomings, including controllability, mental demand and practicality concerns were highlighted. Several enhanced tilt interaction techniques were proposed to address these shortcomings. These techniques were the use of visual and vibrotactile feedback, attractors, gesture zooming, sensitivity adaptation and dwell-time selection. The results of a comparative user study showed that the proposed techniques achieved several improvements in terms of the problem areas identified earlier. The use of sensor fusion for tilt interaction was compared to an accelerometer-only approach which has been widely applied in existing research. This evaluation was motivated by advances in mobile sensor technology which have led to the widespread adoption of digital compass and gyroscope sensors. The results of a comparative user study between sensor fusion and accelerometer-only implementations of tilt interaction showed several advantages for the use of sensor fusion, particularly in a walking context of use. Modifications to sensitivity adaptation and the use of tilt to perform zooming were also investigated. These modifications were designed to address controllability shortcomings identified in earlier experimental work. The results of a comparison between tilt zooming and Summary gesture zooming indicated that tilt zooming offered better results, both in terms of performance and subjective user ratings. Modifications to the original sensitivity adaptation algorithm were only partly successful. Greater accuracy improvements were achieved for walking tasks, but the use of dynamic dampening factors was found to be confusing. The results of this research were used to propose a framework for mobile tilt interaction. This framework provides an overview of the tilt interaction process and highlights how the enhanced techniques proposed in this research can be integrated into the design of tilt interaction techniques. The framework also proposes an application architecture which was implemented as an Application Programming Interface (API). This API was successfully used in the development of two prototype mobile applications incorporating tilt interaction.
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  • Date Issued: 2012

Enumeration of insect viruses using microscopic and molecular analyses: South African isolate of cryotophlebia leucotreta granulovirus as a case study

  • Authors: Dhladhla, Busisiwe I R
  • Date: 2012
  • Subjects: Baculoviruses , Insects -- Viruses , Molecular genetics , Microbial genomics
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10318 , http://hdl.handle.net/10948/d1008395 , Baculoviruses , Insects -- Viruses , Molecular genetics , Microbial genomics
  • Description: Baculoviruses have been used as biocontrol agents to control insect pests in agriculture since the 1970s. Out of the fifteen virus families known to infect insects, baculoviruses offer the greatest potential as insect biopesticides, due to their high host specificity which makes them extremely safe to humans, other vertebrates, plants and non-target microorganisms. They comprise of two genera: nucleopolyhedroviruses (NPVs) and granuloviruses (GVs). The South African isolate of Cryptophlebia leucotreta granulovirus (CrleGV-SA) which is infectious for the false codling moth (FCM), Thaumatotibia leucotreta, (Meyrick) (Lepidoptera: Tortricidae), has been successfully developed into two commercial biopesticides; Cryptogran® and Cryptex®, for the control of FCM in citrus crops. The current method of enumeration used for CrleGV-SA virus particles in routine experiments during the production of the GV as biopesticides, is dark field microscopy. However, due to the small size of GVs (300-500 nm in length), the technique is not easy to perform on these viruses, and no systemic comparison has been made of potential alternative methods. Therefore, the main objective of this study was to develop a quantitative enumeration method for CrleGV-SA occlusion bodies (OBs) which is accurate, reliable, and feasible, and compare the developed methods of enumeration to the current method. Purified and semi-purified CrleGV-SA viral stocks were prepared for enumeration studies using spectrophotometry, dark field microscopy, scanning electron microscopy (SEM) and real time qPCR. Spectrophotometry was found to be an unreliable method for enumeration of GVs in the production, standardisation, and quality control of biopesticides. Dark field microscopy and SEM were found to be accurate, and statistically comparable (p = 0.064) enumeration techniques. qPCR is currently being optimised for the enumeration of GVs. This technique was demonstrated to generate accurate standard curves for absolute quantification of virus particles for pure and semi-pure virus preparations. qPCR offers the greatest potential as an accurate enumeration method because it is not affected by contamination with non-biological contaminating debris, nor by other biological material due to the specificity of PCR primers. Further work is required to fully develop qPCR as an enumeration method for GVs. However, dark field microscopy has been successfully validated as an enumeration method. SEM, which has a high resolution compared to light microscopy, has an added advantage over dark field microscopy, which is to distinguish virus particles in semi-pure viral stock preparations during counting. Therefore, SEM currently provides the most unambiguous and feasible enumeration method for GVs in both purified and semi-purified virus samples.
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  • Date Issued: 2012

Environmental cues and sensory preferences directing the nesting process in loggerhead turtles, caretta caretta, nesting in Maputaland, South Africa

  • Authors: Brazier, Wayne
  • Date: 2012
  • Subjects: Sea turtles
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10721 , http://hdl.handle.net/10948/d1015688
  • Description: Animals use their senses for everything on an immediate, and day to day fashion – detecting danger, finding food, finding mates among other activities. In sea turtles and other migratory species senses are used for long-distance migrations. Senses such as smell, vision and hearing, have been studied experimentally under laboratory conditions but seldom have been investigated in the field. This thesis takes a combination of field and laboratory experiments and investigates some of the hypotheses involved in natal homing and nest site selection. The loggerhead’s nesting distribution in Maputaland is distinct with characteristic high and low density nesting areas which are consistent from year to year. Investigations by earlier researchers on these beaches suggested that beach characteristics, such as beach morphodynamic type and beach width, do not appear to influence the beaches at which loggerheads emerge to nest. The high density nesting area (with approximately 440 loggerhead emergences/km) have similar beach characteristics as the low density nesting area (with <50 loggerhead emergences/km). It is therefore suggested that there is another cue that drives nest site selection. It can either be related to a physical characteristic not yet realised, or is a non-physical (but chemical or biological) cue. This dissertation aims to identify the sensory inputs received during the nest selection process, as well as sea-finding ability after nesting. To investigate the mechanism causing the high-density as opposed to the low-density nesting area, three potential drivers were investigated namely: chemical imprinting (as a natal beach cue), ambient and artificial light (as deterrents) and social facilitation (as a learned behaviour). It was also attempted to identify the strength of the most common senses – vision, hearing and smell. As animal ethics restricts interfering with emerging or nesting turtles, the strengths of these senses were tested during sea-finding by adult loggerheads. The results indicate that sulfide concentrations appear to be used as chemical cues for nesting as these concentrations are elevated (>150 percent) in the high density nesting beaches compared to the low density nesting beaches within and among seasons however further investigations are required. Artificial light (range: 0.045–0.5 lux) is an active deterrent of female emergences while ambient light, even under extreme conditions such as lightning during electric storms (up to 8.2 lux), appears to have no observable influence on the spatial or temporal distributions of emergences. Social facilitation appears unlikely as a primary nest site selection factor for loggerheads. It may however, play a minor secondary role to preferred areas or hotspots. Sea-finding in post-nesting female loggerheads appears to be driven exclusively by visual cues such as the light horizon, with minimal to no influence from other cues (the sound of the breakers, slope or smell of the ocean) which solidify the visual system’s use in sea-finding. This research on the nest site selection of loggerheads and the sensory systems involved in this process has added valuable information to the limited pool of knowledge already present and has created a solid framework on which further investigations can be based. Future work in this field should focus on integrating a suite of sensory stimuli and cues to receive a greater understanding of the sensory systems used in nest site selection.
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  • Date Issued: 2012

Evaluation for harnessing low-enthalpy geothermal energy in South Africa based on a model pilot plant in the Limpopo Mobile Belt

  • Authors: Dhansay, Taufeeq
  • Date: 2012
  • Subjects: Geothermal resources -- South Africa -- Limpopo , Renewable energy sources -- South Africa -- Limpopo , Climatic changes -- South Africa -- Limpopo
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10667 , http://hdl.handle.net/10948/d1019789
  • Description: South Africa generates more than 90 percent of its total energy capacity through non-renewable sources. With coal forming the predominant energy source, South Africa became the leading carbon emissive nation in Africa, emitting 450 million tonnes of CO2 in 2011. In an international effort to restrict global average temperature rise to 2° C above the average prior the industrial revolution, the Kyoto Protocol has been extended for another 8-year commitment period. This is complementary to an expected resolution of a new legally binding climate change policy in 2015. This policy will aim to introduce financial penalties for nations failing to meet ascribed GHG emission targets by 2020. In an attempt to meet these climate change resolutions South Africa will research and develop cleaner, alternative forms of energy, including hydro, wind, and biomass forms of renewable energy, in addition to designating stringent building regulations for the Incorporation of solar energy. These measures form part of an Integrated evelopment Plan that aims to generate a target of 10,000 GWh of renewable energy in 2013. South Africa is also investigating the possibilities of extracting its shale gas reserves and implementing it as a major energy source. This energy mix has given little attention to geothermal energy. The reasons for this omission appears to be the lack of active volcanism and previous research that suggests South Africa, largely underlain by the Kaapvaal Craton, has a relatively low heat Flow profile, deemed insufficient for harnessing geothermal energy.
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  • Date Issued: 2012

Evaluation of noise levels of micro-wind turbines using a randomised experiment

  • Authors: Clohessy, Chantelle May
  • Date: 2012
  • Subjects: Wind turbines -- Noise , Wind turbines -- valuation
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10508 , http://hdl.handle.net/10948/d1015974
  • Description: One of the biggest environmental concerns of a wind turbine is the wind turbine noise (Prospathopoulos and Voutsinas, 2007). This study assesses the noise impacts of wind turbines on the environment by comparing the micro-wind turbine noise to traditional accepted surrounding sounds. The collection of the sound level data was done by using a randomised experiment. The sound level data was then fitted to a General Linear Model to determine the relationship between the sound levels generated at a given site to the time of day, wind speed, wind direction and distance from the sound source. An additional study was conducted to determine the relationship between wind speed and the sound levels of wind turbines. The distribution of frequency components of wind turbine sound was also determined.
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  • Date Issued: 2012

Exploring the linkages between biodiversity conservation and ecotourism in protected areas

  • Authors: Maciejewski, Kristine
  • Date: 2012
  • Subjects: Biodiversity conservation , Ecotourism
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:10709 , http://hdl.handle.net/10948/d1011033 , Biodiversity conservation , Ecotourism
  • Description: The prospect of using ecotourism to add value to conservation initiatives has frequently been stated. However, there is a general lack of information on the costs and benefits of biodiversity and its management, and how this can be influenced by the ecotourism industry. This study seeks to explore the value of biodiversity from the perspective of ecotourism in a hierarchical series of studies that move from the biome-level perspective down to the value of juveniles in ecotourism. Ecotourism plays a significant role in the establishment and management of Private Protected Areas (PPAs) and hence the opportunity to be added to the conservation estate. The financial opportunity to be found in ‘big five’ areas had led to an uneven biome coverage of PPAs which has resulted in the over-representation of certain areas and a skewed contribution towards national conservation targets. The landscape-use of PPAs have indicated that ecotourism operators are largely driven to achieve successful game-viewing sightings which has influenced management and affected the landscape use of PPAs, the stocking rate of species, the introduction of extralimital species, and management of flagship species. These management decisions are based on anecdotal sources and have been made at the expense of biodiversity and therefore apparent conflict exists between ecotourism and conservation objectives. This is based on lack of information: ecotourism operators, despite the large area they protect, have not realised their potential to contribute to conservation. It is therefore important to develop policy and incentives to motivate the establishment of PPAs in areas of high conservation significance in order to contribute to national conservation targets. Ecotourism should be used as a solution to provide important insights into tourist preferences which contribute to the larger debate of how to establish a balance between managing animal populations to ensure tourist satisfaction while supporting conservation. To ensure sustainability of PPAs, it is strongly recommended to manage PPAs more intensively with regards to PPA size, species stocking rates and landscape use. The presence of juveniles at an animal sighting significantly contributes to tourist satisfaction which suggests that the loss of juveniles may reduce the attraction. This is used to provide recommendations that using contraception to control elephant population numbers should be applied with caution as a management tool as it may be counterproductive by negatively impacting ecotourism. The findings from this study not only contribute to the conservation of biodiversity through the use of ecotourism, but will also ensure sustainability of the ecotourism industry and build capacity for sustainable living.
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  • Date Issued: 2012

Factors affecting survivorship of loggerhead (Caretta caretta) and leatherback (Dermochelys coriacea) sea turtles of South Africa

  • Authors: De Wet, Anje
  • Date: 2012
  • Subjects: Loggerhead turtle -- South Africa , Leatherback turtle -- South Africa , Sea turtles -- South Africa
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10686 , http://hdl.handle.net/10948/d1007900 , Loggerhead turtle -- South Africa , Leatherback turtle -- South Africa , Sea turtles -- South Africa
  • Description: Loggerhead (Caretta caretta) and leatherback (Dermochelys coriacea) sea turtles as well as their eggs and hatchlings have been protected on their nesting beach in South Africa (SA) since 1963. Both nesting populations were expected to show similar trends in recovery following the application of identical protection and conservation measures. The loggerhead nesting population has responded favourably to these protection efforts. In contrast, the leatherback nesting population showed an initial increase but is currently stable. The reason for this difference in response is thought to be due to differential offshore mortality of these two species. This prompted an investigation into the different sources of sea turtle mortality in the South Western Indian Ocean (SWIO). Specific aims were to identify and quantify sources of loggerhead and leatherback mortality on nesting beaches as well as in the oceans. Reasonable survivorship at all age classes is important to ensure recruitment of new nesting individuals into sea turtle populations. Mortality of nests, eggs per nest and hatchlings were quantified over two seasons for the loggerheads and leatherbacks nesting in SA. The beach was patrolled on foot to encounter and record females emerging from the ocean and later, hatchlings from their nests. The nests were then monitored during the incubation period and excavated once hatched. The fates of 925 nests were determined during these two nesting seasons (2009/2010 and 2010/2011). The main source of loggerhead and leatherback nest destruction was predation (8.6 percent and 15.7 percent respectively) followed by nest erosion (2.2 percent and 6.3 percent respectively). Overall nest success was high but higher for loggerheads (89 percent) than for leatherbacks (78 percent). The main cause of egg mortality for both species was early developmental arrest, followed by predation by ants and ghost crabs. Hatchlings en route to the sea were almost exclusively predated by ghost crabs (4.2 percent of emerged loggerhead hatchlings and 3.2 percent of emerged leatherback hatchlings). It appears that both species benefit from the coastal conservation efforts. When sea turtles leave the nesting beach, either as hatchlings or adults, conservation and monitoring becomes more difficult and sea turtles are exposed to a multitude of threats, including anthropogenic threats. Age classes tend to be spatially separated due to different habitat and dietary requirements. The type of threat sea turtles are exposed to thus depends on the current age class. Offshore sources of mortality in the SWIO were identified and where possible loggerhead and leatherback mortality was quantified and mapped spatially. Loggerheads were mostly exposed to and had the highest mortality in the artisanal fisheries in the SWIO (> 1000 per annum), inshore trawling (ca. 41 per annum), shark nets (protective gill nets) (21.6 ± 6.7 per annum) and the pelagic longline fishery (5.0 ± 4.4 per annum). In contrast, leatherbacks with a pelagic lifestyle, were mostly exposed to pelagic longline fisheries (7.8 ± 7.8 per annum). A spatial analysis of fishing activities indicated that leatherback home ranges overlapped 41percent with pelagic longline fishing activity in the SA EEZ, whereas the overlap between pelagic longliners and loggerhead home ranges was 29 percent. The quantified sources of mortality provide some explanation for the trend in the loggerhead nesting population but not the trend in the leatherback nesting population. Hatchling survivorship to adulthood was estimated to determine the viability of the two nesting populations as well as to determine whether offshore mortality was responsible for the difference in recovery of the two populations. Loggerhead hatchling survivorship to adulthood was estimated at between 2 and 10 per 1000 hatchlings, the minimum requirement for an increasing population. The adopted sophisticated model shows that leatherbacks have a survival rate of 5 to 10 per 1 000 hatchlings. However, this suggests that the population is increasing, but the leatherback population is stable. Perhaps the age to maturity of SA leatherbacks is greater than 12 years, or fisheries-related mortality affects younger age classes than initially thought. It is therefore recommended that the turtle monitoring area is extended to include other potential nesting grounds. In addition, observer or monitoring programs for commercial as well as artisanal fisheries needs to be extended throughout the SWIO to quantify sea turtle mortality. Ultimately a comprehensive multi-regional approach is required for the conservation of these highly migratory species.
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  • Date Issued: 2012

Feeding ecology and dietary patterns of the Indo-Pacific bottlenose dolphin (Tursiops Aduncus) off KwaZulu-Natal, South Africa

  • Authors: Kaiser, Sabina Marie Luise
  • Date: 2012
  • Subjects: Bottlenose dolphin -- Ecology -- South Africa -- KwaZulu-Natal , Bottlenose dolphin -- Feeding and feeds -- South Africa -- KwaZulu-Natal
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10710 , http://hdl.handle.net/10948/d1011509 , Bottlenose dolphin -- Ecology -- South Africa -- KwaZulu-Natal , Bottlenose dolphin -- Feeding and feeds -- South Africa -- KwaZulu-Natal
  • Description: The Indo-Pacific bottlenose dolphin (Tursiops aduncus) is a common top predator along the KwaZulu-Natal coast. There have been several dietary studies done on this species, most of which have classed this predator as an opportunistic feeder preying on the most abundant prey species in that area. In KwaZulu-Natal (KZN) a dietary study was carried out in 1990, but there have been no followup studies to examine potential changes in diet. A number of bottlenose dolphins get entangled in the shark-nets set off the KZN coast each year. These dolphins provide a valuable source of information about different aspects of the ecology of this population. The aim of this study was to examine the diet of bottlenose dolphins off the KwaZulu-Natal coast with particular emphasis on temporal change in diet composition. The contents of 102 stomachs of bottlenose dolphins (58 females, 44 males) accidentally caught in the shark nets between 1985 and 2010 were analysed, and compared to historical data from dolphins caught between 1975 and 1986. A total of 94 different prey species from 37 families (32 fish families, five cephalopod families) were identified in the stomach contents. Teleosts made up the most important prey group in numbers and weight constituting 84 percent and 67 percent, respectively, while cephalopods made up 15 percent of the number and 30 percent of the weight of the prey items. Multi Dimensional Scaling (MDS) indicated that there is no resource partitioning between males and females, but significant partitioning between juveniles and adults. Six prey species contributed more than 60 percent of the weight of all prey species in the diet. These species are the most important according to their calculated index of relative importance score and are, in order of importance: Sepia sp. (cuttlefish)., Pomadasys olivaceus (piggy), Trachurus delagoa (maasbanker), Scomber japonicus (mackeral), Loligo sp. (squid). and Pagellus bellottii natalensis (pandora or red tjor-tjor). When compared to historic data, no changes in the main prey species has occurred, but the piggy has decreased in importance (1976-1986 percent IRI=45; 2000-2010 percent IRI=22), while the maasbanker has increased (1975-1986, percent RI=4; 2000-2010 percent RI=20). Stable carbon and nitrogen isotope analysis performed on tissue from the teeth of T. aduncus caught in the shark nets between 1970 and 2010 showed that there has been no significant shift in trophic level (δ15N) or in primary prey source (δ13C) over this time. The isotopic signatures of different tissues from an individual were used to create a base line and describe the differences in tissue signatures. Blubber was found to be significantly different from skin and muscle, which were found to be isotopically similar. Skin from remote biopsies can therefore probably be used in place of muscle for isotopic studies of bottlenose dolphins, while caution should be taken when using blubber. Given that T. aduncus is still listed as “data deficient” by the International Union for the Conservation of Nature (IUCN), and the potential for climate change and expanding fisheries to alter the distribution and abundance of their prey species, long term dietary studies such as this are important in order for their effective conservation and management.
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  • Date Issued: 2012

Fertility decline among Abagusii women : the application of an adapted proximate determinants model

  • Authors: Onsongo, Francis Omweri
  • Date: 2012
  • Subjects: Fertility, Human -- Kenya , Birth control -- Kenya , Women, Gusii -- Social conditions , Women's rights -- Kenya , Gusii (African people) -- Social conditions
  • Language: English
  • Type: Thesis , Doctoral , DPhil
  • Identifier: vital:10669 , http://hdl.handle.net/10948/d1019924
  • Description: The primary objective of this thesis is to account for the fertility decline among Abagusii women in South-western Kenya. The motivation behind the study was based on the fact that the fertility trends associated with this group of people had not been studied before. This is surprising because the Abagusii recorded one of the world's highest total fertility rates of 10.4 in 1979 (Omosa 1994; Osiemo 1986; Oucho 1990), but has also experienced significant fertility decline. The total fertility rate in 2004 stood at 4.7, (Anyara 2009). The analytical framework that is adopted is Stover's (1998) adaptation of the Bongaarts et. al. (1984) Proximate Determinants Model. These determinants such as contraceptive use, post-partum insusceptibility, sexual activity, abortion and sterility represent behavioural and biological variables that affect fertility directly. The manner in which they are employed involves using the index which indicates the extent to which each proximate determinant reduces the fertility of the group in question.
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  • Date Issued: 2012

Finite element analysis of the heat transfer in friction stir welding with experimental validation

  • Authors: Vosloo, Natalie
  • Date: 2012
  • Subjects: Finite element method , Heat -- Transmission , Friction welding
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10511 , http://hdl.handle.net/10948/d1019981
  • Description: Friction stir welding is a relatively new joining process. The heat transfer involved is crucial in determining the quality of the weld. Experimenrtal data, though important, does not provide enough information about the heat transfer process and experiments can be costly and time consuming. A numerical model, using the finite element method, was developed to stimulate the heat transfer in the workpiece in which the heat generation due to friction and plastic deformation was modelled as a surface heat flux boundary condition. This model was applied to Aluminium AL6082-T6 and Titanium Ti6A1-4V for different welding condiitions. Results were validated with experimental results. The model was shown to give better predictions of the maximum temperatures at locations in the workpiece than the overall temperature trend. A parametric study was also performed on the Aluminium model in order o predict temperature fields of the workpiece for welding conditions that were additional to those undertaken experimentally. It was found that rotational speed had a larger effect on the change in temperature than the feed rate. From the parametric study it was also clear that lower rotational speeds (300 to 660 rpm) had a greater effect on the change in temperature than the higher rotational speeds (840 to 1200 rpm). It was concluded that the model was well suited for the estimation of temperatures involved in the FSw of Aluminium Al6082-T6 but was not as accurate when applied to the FSW of Titanium.
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  • Date Issued: 2012

Fire regimes in eastern coastal fynbos: drivers, ecology and management

  • Authors: Kraaij, Tineke
  • Date: 2012
  • Subjects: Forest fires -- South Africa , Climatic changes , Prescribed burning , Fire ecology -- South Africa
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:10607 , http://hdl.handle.net/10948/d1008047 , Forest fires -- South Africa , Climatic changes , Prescribed burning , Fire ecology -- South Africa
  • Description: Conventional knowledge of fynbos fire ecology is based on the summer-autumn fire regimes of the western Cape Floral Kingdom (CFK) where the climate is Mediterranean. However, the climate in the eastern coastal-CFK is milder and rainfall occurs year-round, with presumed effects on fire regimes. The Garden Route National Park (GRNP) has recently been established in the region, in a landscape where indigenous forests, fire-prone fynbos shrublands and fire-sensitive plantations of invasive alien trees are interspersed. The park faces considerable challenges related to the management of fire, including significant pressure from the adjacent plantation industry to reduce wildfire hazard by burning fynbos at short intervals, and high levels of invasion by alien trees (largely Pinus species originating from plantations). This study sought to improve understanding of fire regimes in eastern coastal fynbos shrublands, and to provide guidelines for ecologically sound management of fire in the area. My approach entailed (i) an assessment of the context within which fire management was practiced during the past century; (ii) characterisation of the recent fire history and fire regime (1900–2010); (iii) characterisation of the seasonality of fire weather and lightning; (iv) estimation of minimum fire return intervals (FRIs) from juvenile periods and post-fire recruitment success of overstorey proteoids (non-sprouting, slow-maturing, serotinous Proteaceae); and (v) determination of the ecologically appropriate fire season from post-fire recruitment seasonality of proteoids. I established that historically, plantation protection enjoyed priority over fynbos conservation in the area that is now the GRNP. Fynbos close to plantations has most likely been compromised by frequent and low-intensity burning in the past, as well as by invasion by alien trees. In terms of area burnt (1900–2010), natural (lightning-ignited) fires dominated the fire regime, particularly in the east, whereas prescribed burning was relatively unimportant. Typical fire return intervals (FRIs; 8–26 years; 1980–2010) were comparable to those in other fynbos protected areas and appeared to be shorter in the eastern Tsitsikamma than in the western Outeniqua halves of the study area. Proteaceae juvenile periods (4–9 years) and post-fire recruitment success (following fires in ≥7 year-old vegetation) suggested that for biodiversity conservation purposes, FRIs should be no less than nine years in moist, productive fynbos. Increases in the total area burnt annually (since 1980) were correlated with long-term increases in average fire danger weather, suggesting that fire regime changes may be related to global change. Collectively, findings on the seasonality of actual fires and the seasonality of fire danger weather, lightning, and post-fire proteoid recruitment suggested that fires in eastern coastal fynbos are not limited to any particular season, and for this reason managers do not need to be concerned if fires occur in any season. The ecological requirements for higher fire intensity may nonetheless be constrained by a need for safety. I articulated these findings into ecological thresholds pertaining to the different elements of the fire regime in eastern coastal fynbos, to guide adaptive management of fire in the Garden Route National Park. I also recommended a fire management strategy for the park to address the aforementioned operational considerations within the constraints posed by ecological thresholds. Finally, I highlighted further research and monitoring needs.
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  • Date Issued: 2012

Growth and characterization of ZnO nanorods using chemical bath deposition

  • Authors: Urgessa, Zelalem Nigussa
  • Date: 2012
  • Subjects: Zinc oxide , Photoluminescence , Semiconductor nanocrystals , Semiconductors -- Materials , Chemical reactions
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:10559 , http://hdl.handle.net/10948/d1021124 , http://hdl.handle.net/10948/d1021119
  • Description: Semiconductor devices are commonplace in every household. One application of semiconductors in particular, namely solid state lighting technology, is destined for a bright future. To this end, ZnO nanostructures have gained substantial interest in the research community, in part because of its requisite large direct band gap. Furthermore, the stability of the exciton (binding energy 60 meV) in this material, can lead to lasing action based on exciton recombination and possibly exciton interaction, even above room temperature. Therefore, it is very important to realize controllable growth of ZnO nanostructures and investigate their properties. The main motivation for this thesis is not only to successfully realize the controllable growth of ZnO nanorods, but also to investigate the structure, optical and electrical properties in detail by means of scanning electron microscopy (SEM), transmission electron microscopy (TEM), photoluminescence (PL) spectroscopy (steady state and time resolved) and X-ray diffraction (XRD). Furthermore, strong rectification in the ZnO/p-Si heterojunction is demonstrated. Nanorods have been successfully synthesized on silicon by a two-step process, involving the pre-coating of the substrate by a seed layer, followed by the chemical bath deposition of the nanorods. ZnO seed layers with particle sizes of about 5 nm are achieved by the thermal decomposition of zinc acetate dihydrate dissolved in ethanol. The effects of the seed layer density on the distribution, alignment and uniformity of subsequently grown nanorods were studied. The aspect ratio, orientation and distribution of nanorods are shown to be well controlled through adjusting the density of the ZnO nanoparticles pre-coated onto the substrates. It is shown that the seed layer is a prerequisite for the growth of well aligned ZnO nanorods on lattice mismatched Si substrate. The influence of various nanorod growth parameters on the morphology, optical and electrical properties of the nanorods were also systematically studied. These include the oxygen to zinc molar ratio, the pH of the growth solution, the concentration of the reactants, the growth temperature and growth time, different hydroxide precursors and the addition of surface passivating agents to the growth solution. By controlling these xii parameters different architectures of nanostructures, like spherical particles, well aligned nanorods, nanoflowers and thin films of different thicknesses are demonstrated. A possible growth mechanism for ZnO nanostructures in solution is proposed. XRD indicated that all the as-grown nanostructures produced above 45 C crystallize in the wurtzite structure and post growth annealing does not significantly enhance the crystalline quality of the material. In material grown at lower temperature, traces of zinc hydroxide were observed. The optical quality of the nanostructures was investigated using both steady-state PL and time-resolved (TR) PL from 4 K to room temperature. In the case of as-grown samples, both UV and defect related emissions have been observed for all nanostructures. The effect of post-growth annealing on the optical quality of the nanostructures was carefully examined. The effect of annealing in different atmospheres was also investigated. Regardless of the annealing environment annealing at a temperature as low as 300 C enhances the UV emission and suppresses defect related deep level emission. However, annealing above 500 C is required to out-diffuse hydrogen, the presence of which is deduced from the I4 line in the low temperature PL spectra of ZnO. TRPL was utilized to investigate lifetime decay profiles of nanorods upon different post growth treatments. The bound exciton lifetime strongly depends on the post-growth annealing temperature: the PL decay time is much faster for as grown rods, confirming the domination of surface assisted recombination. In general, the PL analysis showed that the PL of nanorods have the same characteristics as that of bulk ZnO, except for the stronger contribution from surface related bound excitons in the former case. Surface adsorbed impurities causing depletion and band bending in the near surface region is implied from both time resolved and steady state PL. Finally, although strong rectification in the ZnO/p-Si heterojunction is illustrated, no electroluminescence has been achieved. This is explained in terms of the band offset between ZnO and Si and interfacial states. Different schemes are proposed to improve the performance of ZnO/Si heterojunction light emitting devices.
  • Full Text:
  • Date Issued: 2012
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