Fabrication of a photocatalytic PAN supported C-TiO2-CFA nanocomposite for use in water treatment
- Authors: Mpelane, Amkelwa
- Date: 2020
- Subjects: Photocatalysis
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: http://hdl.handle.net/10353/18744 , vital:42729
- Description: The goal of this study was to fabricate a visible light responsive composite of C-TiO2-CFA. The prepared nanocomposite (C-TiO2-CFA) was immobilized on poly(acrylonitrile) membrane to address the drawback of recovering the nanosized photocatalyst from water after photodegradation experiments. The C-TiO2-CFA nanocomposites were fabricated using a modified sol-gel method, while the C-TiO2-CFA/PAN membranes were prepared via the phase inversion technique. The nanocomposites were fully characterized using FTIR, XRD, SEM-EDX, TEM, DRS, and BET surface area analysis. The prepared C-TiO2-CFA/PAN membranes were evaluated in the photodegradation of methyl orange and the golden yellow dyes, as well as the photoreduction of lead and cadmium heavy metals in synthetic wastewater. UV-Visible spectroscopy was used to follow the changes in the concentration of organic dyes, while inductively coupled plasma optical emission spectroscopy was used to follow changes in the concentration of the heavy metals. FTIR analysis confirmed the presence of functional groups expected on the prepared C-TiO2- CFA/PAN membranes and EDX analysis accounted for the elements expected. The prepared membranes all exhibited an asymmetric structure as depicted by cross-sectional view study via SEM analysis. TEM and SEM analyses revealed that the prepared C-TiO2-CFA nanocomposite was roughly spherical in shape with an estimate particle size of 10.94 nm according to TEM and 11.62 nm according to XRD using Scherrer equation. The incorporation of carbon into the lattice structure of titanium dioxide resulted in a reduction in bandgap from 3.19 eV to 2.78 eV through introduction of mid-band states, allowing visible light utilization. The best nanocomposite was obtained by doping TiO2 with 4% carbon and having a C-TiO2 to CFA ratio of 4:1 respectively. The C-TiO2-CFA nanocomposite exhibits a crystalline structure with a mixture of rutile and anatase phases. The parameters investigated in the evaluation of photocatalytic performance of C-TiO2- CFA/PAN were effect of photocatalyst load on PAN membrane, initial dye concentration, pH and light source in the activation of photocatalyst. For both dyes (methyl arrange and golden yellow), it was observed that photodegradation efficiencies increased with an increase in catalyst load. In the photodegradation of MO and GY using the membrane with 1% C-TiO2- CFA, removal efficiencies of 73.3% and 59.99% were attained respectively, while the membrane with 2% C-TiO2-CFA achieved MO and GY photodegradation efficiencies of 99.8% and 99.2% respectively. Photodegradation efficiencies of MO and GY were observed to decrease with an increase in dye concentration. Low pH (3) was observed to favour the photodegradation of MO and GY azo dyes. Photodegradation efficiencies of 99.8% and 99.2% were attained where obtained at lower MO and GY initial concentration. The modified photocatalyst (C-TiO2-CFA/PAN) exhibited better photoactivity under sunlight irradiation compared to strict UV light irradiation. Evidently, the C-TiO2-CFA/PAN membranes can be 4 Final Submission of Thesis, Dissertation or Research Report/Project, Conference or Exam Paper utilized as a sustainable and stable photocatalyst to efficiently eliminate methyl orange and golden yellow dyes. A PAN membrane with 2 wt% C-TiO2-CFA revealed enhanced cadmium and lead removal efficiencies in comparison to PAN membranes with 1 wt% and 1.5% C-TiO2-CFA. A Cd2+ removal efficiency of 95% was obtained using 2 wt% C-TiO2-CFA/PAN nanocomposite membranes. Cadmium removal efficiencies of 92.5% and 91% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. A lead removal efficiency of 97% was obtained using PAN membrane with 2 wt% C-TiO2-CFA. Pb2+ removal efficiencies of 90.9% and 94.6% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. The photoreduction activity was observed to decrease with an increase in cadmium and lead initial concentrations. A cadmium and lead removal efficiencies of 95% and 97% were observed at lower Cd2+ and Pb2+ initial concentrations (20 ppm), respectively. The removal efficiencies varied marginally with changes in pH values. The fouling activity of the C-TiO2 modified PAN asymmetric membranes and pure PAN was investigated by carrying out pure water filtration tests as well as bovine serum albumin (BSA) filtration tests. A bovine serum albumin rejection of 98% was obtained utilizing the 2 wt% CTiO2-CFA/PAN membrane.
- Full Text:
- Date Issued: 2020
- Authors: Mpelane, Amkelwa
- Date: 2020
- Subjects: Photocatalysis
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: http://hdl.handle.net/10353/18744 , vital:42729
- Description: The goal of this study was to fabricate a visible light responsive composite of C-TiO2-CFA. The prepared nanocomposite (C-TiO2-CFA) was immobilized on poly(acrylonitrile) membrane to address the drawback of recovering the nanosized photocatalyst from water after photodegradation experiments. The C-TiO2-CFA nanocomposites were fabricated using a modified sol-gel method, while the C-TiO2-CFA/PAN membranes were prepared via the phase inversion technique. The nanocomposites were fully characterized using FTIR, XRD, SEM-EDX, TEM, DRS, and BET surface area analysis. The prepared C-TiO2-CFA/PAN membranes were evaluated in the photodegradation of methyl orange and the golden yellow dyes, as well as the photoreduction of lead and cadmium heavy metals in synthetic wastewater. UV-Visible spectroscopy was used to follow the changes in the concentration of organic dyes, while inductively coupled plasma optical emission spectroscopy was used to follow changes in the concentration of the heavy metals. FTIR analysis confirmed the presence of functional groups expected on the prepared C-TiO2- CFA/PAN membranes and EDX analysis accounted for the elements expected. The prepared membranes all exhibited an asymmetric structure as depicted by cross-sectional view study via SEM analysis. TEM and SEM analyses revealed that the prepared C-TiO2-CFA nanocomposite was roughly spherical in shape with an estimate particle size of 10.94 nm according to TEM and 11.62 nm according to XRD using Scherrer equation. The incorporation of carbon into the lattice structure of titanium dioxide resulted in a reduction in bandgap from 3.19 eV to 2.78 eV through introduction of mid-band states, allowing visible light utilization. The best nanocomposite was obtained by doping TiO2 with 4% carbon and having a C-TiO2 to CFA ratio of 4:1 respectively. The C-TiO2-CFA nanocomposite exhibits a crystalline structure with a mixture of rutile and anatase phases. The parameters investigated in the evaluation of photocatalytic performance of C-TiO2- CFA/PAN were effect of photocatalyst load on PAN membrane, initial dye concentration, pH and light source in the activation of photocatalyst. For both dyes (methyl arrange and golden yellow), it was observed that photodegradation efficiencies increased with an increase in catalyst load. In the photodegradation of MO and GY using the membrane with 1% C-TiO2- CFA, removal efficiencies of 73.3% and 59.99% were attained respectively, while the membrane with 2% C-TiO2-CFA achieved MO and GY photodegradation efficiencies of 99.8% and 99.2% respectively. Photodegradation efficiencies of MO and GY were observed to decrease with an increase in dye concentration. Low pH (3) was observed to favour the photodegradation of MO and GY azo dyes. Photodegradation efficiencies of 99.8% and 99.2% were attained where obtained at lower MO and GY initial concentration. The modified photocatalyst (C-TiO2-CFA/PAN) exhibited better photoactivity under sunlight irradiation compared to strict UV light irradiation. Evidently, the C-TiO2-CFA/PAN membranes can be 4 Final Submission of Thesis, Dissertation or Research Report/Project, Conference or Exam Paper utilized as a sustainable and stable photocatalyst to efficiently eliminate methyl orange and golden yellow dyes. A PAN membrane with 2 wt% C-TiO2-CFA revealed enhanced cadmium and lead removal efficiencies in comparison to PAN membranes with 1 wt% and 1.5% C-TiO2-CFA. A Cd2+ removal efficiency of 95% was obtained using 2 wt% C-TiO2-CFA/PAN nanocomposite membranes. Cadmium removal efficiencies of 92.5% and 91% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. A lead removal efficiency of 97% was obtained using PAN membrane with 2 wt% C-TiO2-CFA. Pb2+ removal efficiencies of 90.9% and 94.6% were obtained using the 1.5 wt% and 1 wt% C-TiO2-CFA/PAN nanocomposite membranes. The photoreduction activity was observed to decrease with an increase in cadmium and lead initial concentrations. A cadmium and lead removal efficiencies of 95% and 97% were observed at lower Cd2+ and Pb2+ initial concentrations (20 ppm), respectively. The removal efficiencies varied marginally with changes in pH values. The fouling activity of the C-TiO2 modified PAN asymmetric membranes and pure PAN was investigated by carrying out pure water filtration tests as well as bovine serum albumin (BSA) filtration tests. A bovine serum albumin rejection of 98% was obtained utilizing the 2 wt% CTiO2-CFA/PAN membrane.
- Full Text:
- Date Issued: 2020
Synthesis and application of coal fly ash supported C doped TiO2/SnO2 photocatalyst in water treatment
- Authors: Sambakanya, Siyasanga
- Date: 2020
- Subjects: Photocatalysis
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: http://hdl.handle.net/10353/18838 , vital:42869
- Description: Coal fly ash supported carbon doped titanium dioxide/tin oxide (C doped TiO2-SnO2/CFA) nanoparticles were successfully synthesised using a sol gel method and calcined at 550 °C. The crystal structure, optical properties, morphology and other properties were analysed using XRD, UV-Vis, FTIR, TEM, SEM, DRS and EDX. SEM analysis showed that the nanoparticles (NPs) of C doped TiO2-SnO2/CFA were quasi spherical. XRD showed that C doped TiO2-SnO2/CFA nanoparticles were polycrystalline and consisted of both rutile and anatase phases. TEM analysis also displayed small NPs of C-TiO2-SnO2/CFA (12.62 nm) than TiO2 (16.19 nm) and SnO2 (19.98 nm). DRS revealed reduced band gap of C-TiO2 (2.78 eV) than TiO2 (3.19 eV) after doping. The photocatalytic efficiency of the prepared C-TiO2-SnO2/CFA nanoparticles was determined using methyl orange (MO) and methylene blue dye (MB) as standard dyes in the photodegradation as well as lead and mercury in the photoreduction of lead and mercury ions in water. The degradation experiments were carried under natural solar irradiation and UV light. The photodegradation experiments carried under visible light showed excellent photodegradation of MO & MB in water. This is a good indication that doping was successful as it imparted visible light activity in the C-TiO2-SnO2/CFA NPs. The photocatalyst efficiency was further tested while varying parameters including photocatalyst load, pH, and initial pollutant concentration in the photodegradation of MO & MB as well as in photoreduction of Pb2+ and Hg2+ in water to establish optimum operating conditions. The degradation rate of MO & MB increased when photocatalyst loading increased. When the pH was increased, the photocatalytic efficiency of the prepared photocatalyst towards methyl orange was reduced; however methylene blue degradation increased with increase in pH. The reduction of Pb2+ also increased with increasing pH whereas that of Hg2+ increased with decreasing pH. It was found that photodegradation was directly proportional to and photoreduction was inversely proportional to initial pollutant concentration.
- Full Text:
- Date Issued: 2020
- Authors: Sambakanya, Siyasanga
- Date: 2020
- Subjects: Photocatalysis
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: http://hdl.handle.net/10353/18838 , vital:42869
- Description: Coal fly ash supported carbon doped titanium dioxide/tin oxide (C doped TiO2-SnO2/CFA) nanoparticles were successfully synthesised using a sol gel method and calcined at 550 °C. The crystal structure, optical properties, morphology and other properties were analysed using XRD, UV-Vis, FTIR, TEM, SEM, DRS and EDX. SEM analysis showed that the nanoparticles (NPs) of C doped TiO2-SnO2/CFA were quasi spherical. XRD showed that C doped TiO2-SnO2/CFA nanoparticles were polycrystalline and consisted of both rutile and anatase phases. TEM analysis also displayed small NPs of C-TiO2-SnO2/CFA (12.62 nm) than TiO2 (16.19 nm) and SnO2 (19.98 nm). DRS revealed reduced band gap of C-TiO2 (2.78 eV) than TiO2 (3.19 eV) after doping. The photocatalytic efficiency of the prepared C-TiO2-SnO2/CFA nanoparticles was determined using methyl orange (MO) and methylene blue dye (MB) as standard dyes in the photodegradation as well as lead and mercury in the photoreduction of lead and mercury ions in water. The degradation experiments were carried under natural solar irradiation and UV light. The photodegradation experiments carried under visible light showed excellent photodegradation of MO & MB in water. This is a good indication that doping was successful as it imparted visible light activity in the C-TiO2-SnO2/CFA NPs. The photocatalyst efficiency was further tested while varying parameters including photocatalyst load, pH, and initial pollutant concentration in the photodegradation of MO & MB as well as in photoreduction of Pb2+ and Hg2+ in water to establish optimum operating conditions. The degradation rate of MO & MB increased when photocatalyst loading increased. When the pH was increased, the photocatalytic efficiency of the prepared photocatalyst towards methyl orange was reduced; however methylene blue degradation increased with increase in pH. The reduction of Pb2+ also increased with increasing pH whereas that of Hg2+ increased with decreasing pH. It was found that photodegradation was directly proportional to and photoreduction was inversely proportional to initial pollutant concentration.
- Full Text:
- Date Issued: 2020
Performance comparison of iron pillared montmorillonite, raw and modified zeolites sorption for Cu(II), Pb(II) and Ni(II) in water
- Authors: Madigoe, Marakeng Rhudolf
- Date: 2017
- Subjects: Water -- Purification -- Biological treatment Adsorption Montmorillonite
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8078 , vital:31516
- Description: The higher concentration of heavy metals and pollutants is toxic to human health and the environment. It is essential to remove these toxics from contaminated water. There are several methods developed for water treatment. These include adsorption, reverse osmosis, precipitation, coagulation and cation exchange. Adsorbents of various characteristics are considered for removal of heavy metals and pollutants. The study investigated the performance of iron pillared Montmorillonite, raw and modified zeolite (acid and base) for the removal of Cu(II), Pb(II) and Ni(II) in artificially contaminated water. The adsorbents were characterized by X-ray Diffraction (XRD), Fourier Transformation Infrared spectroscopy (FTIR) and Scanning Electron Microscope (SEM) instruments. The percentage removal of Cu(II), Pb(II) and Ni(II) after adsorption process were determined. Iron pillared Montmorillonite showed efficient removal for lead and zeolite for copper and nickel.
- Full Text:
- Date Issued: 2017
- Authors: Madigoe, Marakeng Rhudolf
- Date: 2017
- Subjects: Water -- Purification -- Biological treatment Adsorption Montmorillonite
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8078 , vital:31516
- Description: The higher concentration of heavy metals and pollutants is toxic to human health and the environment. It is essential to remove these toxics from contaminated water. There are several methods developed for water treatment. These include adsorption, reverse osmosis, precipitation, coagulation and cation exchange. Adsorbents of various characteristics are considered for removal of heavy metals and pollutants. The study investigated the performance of iron pillared Montmorillonite, raw and modified zeolite (acid and base) for the removal of Cu(II), Pb(II) and Ni(II) in artificially contaminated water. The adsorbents were characterized by X-ray Diffraction (XRD), Fourier Transformation Infrared spectroscopy (FTIR) and Scanning Electron Microscope (SEM) instruments. The percentage removal of Cu(II), Pb(II) and Ni(II) after adsorption process were determined. Iron pillared Montmorillonite showed efficient removal for lead and zeolite for copper and nickel.
- Full Text:
- Date Issued: 2017
The influence of extraction techniques on the chemical composition of essential oils from Pelargonium cv.rose in the Eastern Cape
- Authors: Ngcangatha-Maqhude, Bulelwa
- Date: 2017
- Subjects: Essences and essential oils Pelargoniums Rose geranium oil
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8111 , vital:31524
- Description: Rose geranium is a world known essential oil plant priced for its high grade essential oil mostly utilized in the perfumery industry. However, South Africa has just joined the geranium oil production industry and still battling with the variations in oil yield and composition. Volatile components from Rose geranium were respectively extracted by three methods including hydro-distillation, steam distillation and solvent free microwave. The composition was characterized by GC-FID and GC-MS .No significant differences were found in the oil constituents, colour of the oil was the same in hydro-distillation and steam distillation (light green) but in solvent free microwave extraction the oil was clear because in the receiving flask there was hexane and the quantity of the oil was not the same. The difference was the time taken to extract the oil: Hydro-distillation took 3 hours, steam distillation took 1 hour, 30 minutes and solvent free microwave took only 30 minutes. The main constituents of the essential oil of rose geranium (steam distillation) are Dohne: Citronellol (20.61percent), geraniol (14.79percent), linalool (1.98percent), citronellyl formate (14.25percent), geranyl formate (10.25percent) and guaiadiene 6, 9 (7.22percent). Kieskammahoek: Citronellol (20.36percent), geraniol (9.81percent), linalool (1.54percent), citronellyl formate (16.09percent), geranyl formate F (8.96percent) and guaiadiene 6, 9 (8. 22percent).University of FortHare: Citronellol (21.55percent), geraniol (9.41percent), linalool (1.40percent), citronellyl formate (16.37percent), geranyl formate (8.10percent) and guaiadiene 6, 9 7.92percent). For hydro-distillation, Dohne: Citronellol (24.68percent), geraniol (11.68percent), linalool (11.74percent), citronellyl formate (14.97percent), geranyl formate (5.95percent) and guaiadiene 6, 9 (4.63percent). Kieskammahoek: Citronellol (25.25percent), geraniol (13.44percent), linalool (3.35percent), citronellyl formate (15.62percent), geranyl formate (5.40percent) and guaiadiene 6, 9(4.96percent).University of FortHare: Citronellol (24.73percent), geraniol (8.35percent), linalool (9.76percent), citronellyl formate (16.54percent), geranyl formate (4.42percent) and guaiadiene 6, 9(9.76percent). The solvent free microwave extraction , Dohne: Citronellol (20.87), geraniol (17.85percent), linalool (1.21percent), citronellyl formate (13.44percent), geranyl formate (10.26percent) and guaiadiene 6, 9 (4.59percent).Kieskammahoek: Citronellol (20.13percent), geraniol (5.40percent), linalool (0.28percent), citronellyl formate (14.22percent), geranyl formate (6.04percent) and guaiadiene 6, 9(8.63percent).University of FortHare: Citronellol (21.15percent), geraniol (22.36percent), linalool (1.37percent), citronellyl formate (12.13percent), geranyl formate (8.91percent) and guaiadiene 6, 9 (5.82percent).The percentage of oil composition in hydro-distillation and Solvent Free Microwave Extraction was higher than steam distillation.
- Full Text:
- Date Issued: 2017
- Authors: Ngcangatha-Maqhude, Bulelwa
- Date: 2017
- Subjects: Essences and essential oils Pelargoniums Rose geranium oil
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8111 , vital:31524
- Description: Rose geranium is a world known essential oil plant priced for its high grade essential oil mostly utilized in the perfumery industry. However, South Africa has just joined the geranium oil production industry and still battling with the variations in oil yield and composition. Volatile components from Rose geranium were respectively extracted by three methods including hydro-distillation, steam distillation and solvent free microwave. The composition was characterized by GC-FID and GC-MS .No significant differences were found in the oil constituents, colour of the oil was the same in hydro-distillation and steam distillation (light green) but in solvent free microwave extraction the oil was clear because in the receiving flask there was hexane and the quantity of the oil was not the same. The difference was the time taken to extract the oil: Hydro-distillation took 3 hours, steam distillation took 1 hour, 30 minutes and solvent free microwave took only 30 minutes. The main constituents of the essential oil of rose geranium (steam distillation) are Dohne: Citronellol (20.61percent), geraniol (14.79percent), linalool (1.98percent), citronellyl formate (14.25percent), geranyl formate (10.25percent) and guaiadiene 6, 9 (7.22percent). Kieskammahoek: Citronellol (20.36percent), geraniol (9.81percent), linalool (1.54percent), citronellyl formate (16.09percent), geranyl formate F (8.96percent) and guaiadiene 6, 9 (8. 22percent).University of FortHare: Citronellol (21.55percent), geraniol (9.41percent), linalool (1.40percent), citronellyl formate (16.37percent), geranyl formate (8.10percent) and guaiadiene 6, 9 7.92percent). For hydro-distillation, Dohne: Citronellol (24.68percent), geraniol (11.68percent), linalool (11.74percent), citronellyl formate (14.97percent), geranyl formate (5.95percent) and guaiadiene 6, 9 (4.63percent). Kieskammahoek: Citronellol (25.25percent), geraniol (13.44percent), linalool (3.35percent), citronellyl formate (15.62percent), geranyl formate (5.40percent) and guaiadiene 6, 9(4.96percent).University of FortHare: Citronellol (24.73percent), geraniol (8.35percent), linalool (9.76percent), citronellyl formate (16.54percent), geranyl formate (4.42percent) and guaiadiene 6, 9(9.76percent). The solvent free microwave extraction , Dohne: Citronellol (20.87), geraniol (17.85percent), linalool (1.21percent), citronellyl formate (13.44percent), geranyl formate (10.26percent) and guaiadiene 6, 9 (4.59percent).Kieskammahoek: Citronellol (20.13percent), geraniol (5.40percent), linalool (0.28percent), citronellyl formate (14.22percent), geranyl formate (6.04percent) and guaiadiene 6, 9(8.63percent).University of FortHare: Citronellol (21.15percent), geraniol (22.36percent), linalool (1.37percent), citronellyl formate (12.13percent), geranyl formate (8.91percent) and guaiadiene 6, 9 (5.82percent).The percentage of oil composition in hydro-distillation and Solvent Free Microwave Extraction was higher than steam distillation.
- Full Text:
- Date Issued: 2017
Studies on comparison of aluminium-pillared montmorillonite clay with silica gel on adsorption of methylene blue in waste water
- Authors: Mselana, Sinazo
- Date: 2016
- Subjects: Clay Silica gel Montmorillonite
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8011 , vital:31462
- Description: Adsorption equilibrium and kinetics of methylene blue (MB) onto silica gel and aluminum pillared montmorillonite was studied in a batch system. Variables of the system include contact time, salt concentration and initial methylene blue concentration. Langmuir and Freundlich isotherm models were applied to experimental equilibrium data of methylene blue adsorption. Both models were suitable for the parameters. The advantage of silica gel as applied to water treatment is its high porosity when compared to aluminum pillared montmorillonite clay. Water molecules adhere to the silica gels surface because it exhibits a lower vapour pressure than the surrounding air. When equilibrium of equal pressure is reached, no more adsorption occurs. Thus the higher the humidity of the surrounding air, the greater the amount of water that is adsorbed before equilibrium is reached. The increase in pressure loss on the silica gel filters is 1.5 - 2.0 times smaller than in the case of sand filters, Lorenc (2007).
- Full Text:
- Date Issued: 2016
- Authors: Mselana, Sinazo
- Date: 2016
- Subjects: Clay Silica gel Montmorillonite
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8011 , vital:31462
- Description: Adsorption equilibrium and kinetics of methylene blue (MB) onto silica gel and aluminum pillared montmorillonite was studied in a batch system. Variables of the system include contact time, salt concentration and initial methylene blue concentration. Langmuir and Freundlich isotherm models were applied to experimental equilibrium data of methylene blue adsorption. Both models were suitable for the parameters. The advantage of silica gel as applied to water treatment is its high porosity when compared to aluminum pillared montmorillonite clay. Water molecules adhere to the silica gels surface because it exhibits a lower vapour pressure than the surrounding air. When equilibrium of equal pressure is reached, no more adsorption occurs. Thus the higher the humidity of the surrounding air, the greater the amount of water that is adsorbed before equilibrium is reached. The increase in pressure loss on the silica gel filters is 1.5 - 2.0 times smaller than in the case of sand filters, Lorenc (2007).
- Full Text:
- Date Issued: 2016
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