Studies on flax/polypropylene-reinforced composites for automotive applications
- Authors: Biyana, Nobuhle Yvonne
- Date: 2015
- Subjects: Polypropylene fibers , Fibrous composites , Reinforced plastics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10456 , http://hdl.handle.net/10948/d1021150
- Description: The use of natural fibers as reinforcement in thermoplastics presents an interesting alternative for the production of low cost and ecologically friendly composites. One of the advantages of using natural fibres is their low specific weight, resulting in higher specific strength and stiffness when compared to glass reinforced composites. Natural fibres also present safer handling and working conditions. They are non-abrasive to mixing and can contribute to significant cost reduction. This work is divided into two phases: Phase 1 deals with developing nonwoven mats composites from flax/polypropylene (PP) and evaluating their properties. Flax/polypropylene fibres (at different weight ratios) were processed by needle-punching technique in order to form nonwoven mats. The mats were compression-molded at a temperature of 180oC to form composite materials. The mechanical, thermal and viscoelastic properties of the composites were analyzed. Composites (untreated and silane-treated) were also subjected to varying conditions of temperature and humidity and the tensile properties of the conditioned and unconditioned composites were investigated. The mechanical properties (tensile, flexural and impact) of flax/PP composites were found to increase and reach maximum values at 30 per cent fibre loading and then decrease at higher fibre content. Thermal studies revealed that the composites were stable up to 320oC and samples containing 40 per cent flax fibres were found to exhibit greater thermal stability than neat PP. The dynamic mechanical analyses of the composites showed that the incorporation of flax in the composites resulted in an increase of the storage modulus with a maximum value exhibited by composite containing 40 per cent fibre loading. Composites containing chemically modified fibres exhibited low tensile modulus after conditioning. Phase 2 is based on the investigation of the effect of nano-calcium carbonate (CaCO3) on the properties of two types of polymer matrices: recycled PP and virgin PP. In this case, composites were prepared by melt-mixing and injection molding. The mechanical and thermal properties of the composites were characterized. The tensile modulus of the nano-CaCO3 filled PP (virgin and recycled) composites were found to increase and reach maximum at 30 per cent nano-CaCO3 loading, while the tensile strength decreased with increasing filler content. Thermal studies showed that the nano-CaCO3 filled PP samples exhibited a one-step degradation pattern and are thermally stable up to 450oC. The thermal stability of the samples was found to decrease following the addition of nano-CaCO3. SEM micrographs of the tensile fractured surfaces of composites of the nano-CaCO3 filled virgin and recycled PP revealed the presence of nano-CaCO3 agglomeration.
- Full Text:
- Date Issued: 2015
- Authors: Biyana, Nobuhle Yvonne
- Date: 2015
- Subjects: Polypropylene fibers , Fibrous composites , Reinforced plastics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10456 , http://hdl.handle.net/10948/d1021150
- Description: The use of natural fibers as reinforcement in thermoplastics presents an interesting alternative for the production of low cost and ecologically friendly composites. One of the advantages of using natural fibres is their low specific weight, resulting in higher specific strength and stiffness when compared to glass reinforced composites. Natural fibres also present safer handling and working conditions. They are non-abrasive to mixing and can contribute to significant cost reduction. This work is divided into two phases: Phase 1 deals with developing nonwoven mats composites from flax/polypropylene (PP) and evaluating their properties. Flax/polypropylene fibres (at different weight ratios) were processed by needle-punching technique in order to form nonwoven mats. The mats were compression-molded at a temperature of 180oC to form composite materials. The mechanical, thermal and viscoelastic properties of the composites were analyzed. Composites (untreated and silane-treated) were also subjected to varying conditions of temperature and humidity and the tensile properties of the conditioned and unconditioned composites were investigated. The mechanical properties (tensile, flexural and impact) of flax/PP composites were found to increase and reach maximum values at 30 per cent fibre loading and then decrease at higher fibre content. Thermal studies revealed that the composites were stable up to 320oC and samples containing 40 per cent flax fibres were found to exhibit greater thermal stability than neat PP. The dynamic mechanical analyses of the composites showed that the incorporation of flax in the composites resulted in an increase of the storage modulus with a maximum value exhibited by composite containing 40 per cent fibre loading. Composites containing chemically modified fibres exhibited low tensile modulus after conditioning. Phase 2 is based on the investigation of the effect of nano-calcium carbonate (CaCO3) on the properties of two types of polymer matrices: recycled PP and virgin PP. In this case, composites were prepared by melt-mixing and injection molding. The mechanical and thermal properties of the composites were characterized. The tensile modulus of the nano-CaCO3 filled PP (virgin and recycled) composites were found to increase and reach maximum at 30 per cent nano-CaCO3 loading, while the tensile strength decreased with increasing filler content. Thermal studies showed that the nano-CaCO3 filled PP samples exhibited a one-step degradation pattern and are thermally stable up to 450oC. The thermal stability of the samples was found to decrease following the addition of nano-CaCO3. SEM micrographs of the tensile fractured surfaces of composites of the nano-CaCO3 filled virgin and recycled PP revealed the presence of nano-CaCO3 agglomeration.
- Full Text:
- Date Issued: 2015
Investigation of the effect of selected polypropylene fibres and ultra-fine aggregate on plastic shrinkage cracks on South African roads
- Authors: Kluyts, Grant
- Date: 2005
- Subjects: Concrete roads -- South Africa -- Design and construction , Fiber-reinforced concrete , Reinforced concrete -- Cracking , Concrete -- Expansion and contraction , Polypropylene fibers
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9592 , http://hdl.handle.net/10948/174 , Concrete roads -- South Africa -- Design and construction , Fiber-reinforced concrete , Reinforced concrete -- Cracking , Concrete -- Expansion and contraction , Polypropylene fibers
- Description: Plastic shrinkage cracks, although not inherently structurally debilitating, expose the reinforcement in low-volume reinforced concrete roads to deleterious substances, which may reduce its effectiveness leading ultimately to structural failure. In un-reinforced low-volume concrete road these cracks appear unsightly and cause the road user an unpleasant riding experience. Many researchers believe that plastic shrinkage crack development remains a concern to the concrete industry, occurring in particularly large–area pours such as low-volume concrete roads, and therefore requires further research to understand their formation and minimization. This study reports findings on the effectiveness of oxyfluorinated polypropylene fibres to control plastic shrinkage cracks, and the effect the addition of ultra-fine material has on the formation and/or propagation of these cracks. Findings indicate that low volume dosages (2 kg/m³), of oxyfluorinated polypropylene fibre significantly reduced the formation of plastic shrinkage cracks under test conditions. Furthermore, that the addition of ultra-fine material in excess of 63 kg/m³ increased the formation and/or development of plastic shrinkage cracks.
- Full Text:
- Date Issued: 2005
- Authors: Kluyts, Grant
- Date: 2005
- Subjects: Concrete roads -- South Africa -- Design and construction , Fiber-reinforced concrete , Reinforced concrete -- Cracking , Concrete -- Expansion and contraction , Polypropylene fibers
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9592 , http://hdl.handle.net/10948/174 , Concrete roads -- South Africa -- Design and construction , Fiber-reinforced concrete , Reinforced concrete -- Cracking , Concrete -- Expansion and contraction , Polypropylene fibers
- Description: Plastic shrinkage cracks, although not inherently structurally debilitating, expose the reinforcement in low-volume reinforced concrete roads to deleterious substances, which may reduce its effectiveness leading ultimately to structural failure. In un-reinforced low-volume concrete road these cracks appear unsightly and cause the road user an unpleasant riding experience. Many researchers believe that plastic shrinkage crack development remains a concern to the concrete industry, occurring in particularly large–area pours such as low-volume concrete roads, and therefore requires further research to understand their formation and minimization. This study reports findings on the effectiveness of oxyfluorinated polypropylene fibres to control plastic shrinkage cracks, and the effect the addition of ultra-fine material has on the formation and/or propagation of these cracks. Findings indicate that low volume dosages (2 kg/m³), of oxyfluorinated polypropylene fibre significantly reduced the formation of plastic shrinkage cracks under test conditions. Furthermore, that the addition of ultra-fine material in excess of 63 kg/m³ increased the formation and/or development of plastic shrinkage cracks.
- Full Text:
- Date Issued: 2005
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