In vitro photoinactivation of S. aureus and photocatalytic degradation of tetracycline by novel phthalocyanine-graphene quantum dots nano-assemblies
- Openda, Yolande Ikala, Mgidlana, Sithi, Nyokong, Tebello
- Authors: Openda, Yolande Ikala , Mgidlana, Sithi , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229895 , vital:49721 , xlink:href="https://doi.org/10.1016/j.jlumin.2022.118863"
- Description: A novel asymmetrical zinc (II) phthalocyanine (Pc) 4 bearing three dimethoxy groups and one carboxyl group was linked to glutathione capped graphene quantum dots (GQDs) by the reaction of carboxylic acid substituent on Pc 4 with the amino group on the GQDs. On the other side, the symmetrical Pc analog 3 was linked to the same nanoparticles through π-π interactions. The as-formed nano-photosensitizers were fully characterized by spectroscopic methods and their photophysicochemical properties were investigated as well. Photodynamic antimicrobial chemotherapy was performed on the planktonic cells of S. aureus strain. And the results show that these nano assemblies were able to completely inhibit the metabolic activity of the resistant bacteria strain S. aureus with a 10.26 log reduction in the viable count. Again, asymmetrical Pc showed higher photocatalytic activity compared to the symmetrical complex with higher kobs and fast initial rates for the former. The photocatalysis obeyed the Langmuir-Hinshelwood kinetic model. The target conjugates showed all the advantages of two different groups existing on a single entity.
- Full Text:
- Date Issued: 2022
- Authors: Openda, Yolande Ikala , Mgidlana, Sithi , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229895 , vital:49721 , xlink:href="https://doi.org/10.1016/j.jlumin.2022.118863"
- Description: A novel asymmetrical zinc (II) phthalocyanine (Pc) 4 bearing three dimethoxy groups and one carboxyl group was linked to glutathione capped graphene quantum dots (GQDs) by the reaction of carboxylic acid substituent on Pc 4 with the amino group on the GQDs. On the other side, the symmetrical Pc analog 3 was linked to the same nanoparticles through π-π interactions. The as-formed nano-photosensitizers were fully characterized by spectroscopic methods and their photophysicochemical properties were investigated as well. Photodynamic antimicrobial chemotherapy was performed on the planktonic cells of S. aureus strain. And the results show that these nano assemblies were able to completely inhibit the metabolic activity of the resistant bacteria strain S. aureus with a 10.26 log reduction in the viable count. Again, asymmetrical Pc showed higher photocatalytic activity compared to the symmetrical complex with higher kobs and fast initial rates for the former. The photocatalysis obeyed the Langmuir-Hinshelwood kinetic model. The target conjugates showed all the advantages of two different groups existing on a single entity.
- Full Text:
- Date Issued: 2022
Indium phthalocyanines
- Pinar, Sen, Mack, John, Nyokong, Tebello
- Authors: Pinar, Sen , Mack, John , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229998 , vital:49731 , xlink:href="https://doi.org/10.1016/j.molstruc.2021.131850"
- Description: In this study, the photodynamic antimicrobial activities of a series of new tetra-substituted indium phthalocyanine (InPc) complexes are assessed. An aldehyde substituted complex (2) was initially prepared, which was converted through a condensatioreaction to an imine-pyrrolidine substituted complex (3), which in turn was quaternized to form a tetracationic species (4). Favorable photophysicochemical properties were obtained by incorporating a heavy In(III) ion into the central cavity. Aggregation studies revealed that 2–4 remain non-aggregated in DMSO at concentration below 25 µM. The photodeactivation of S.aureus and E.coli was studied. Log reduction values > 9.0 were obtained for cationic InPc 4 after 30 min of incubation and exposure to light for 75 min.
- Full Text:
- Date Issued: 2022
- Authors: Pinar, Sen , Mack, John , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229998 , vital:49731 , xlink:href="https://doi.org/10.1016/j.molstruc.2021.131850"
- Description: In this study, the photodynamic antimicrobial activities of a series of new tetra-substituted indium phthalocyanine (InPc) complexes are assessed. An aldehyde substituted complex (2) was initially prepared, which was converted through a condensatioreaction to an imine-pyrrolidine substituted complex (3), which in turn was quaternized to form a tetracationic species (4). Favorable photophysicochemical properties were obtained by incorporating a heavy In(III) ion into the central cavity. Aggregation studies revealed that 2–4 remain non-aggregated in DMSO at concentration below 25 µM. The photodeactivation of S.aureus and E.coli was studied. Log reduction values > 9.0 were obtained for cationic InPc 4 after 30 min of incubation and exposure to light for 75 min.
- Full Text:
- Date Issued: 2022
Integrated photocatalyst adsorbents based on porphyrin anchored to activated carbon granules for water treatment
- Oyim, James, Amuhaya, Edith, Matshitse, Refilwe, Mack, John, Nyokong, Tebello
- Authors: Oyim, James , Amuhaya, Edith , Matshitse, Refilwe , Mack, John , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300101 , vital:57893 , xlink:href="https://doi.org/10.1016/j.cartre.2022.100191"
- Description: Integration of adsorption and photocatalysis processes can lead to several benefits in water treatment. Integrating well-known adsorbents with photocatalysts ensures that all the interesting components are preserved and helps to overcome the serious downsides of each material and technique when operated independently. In this work, we introduce a new concept of combining both absorption and photodegradation mechanisms using organic photocatalytic adsorbents for water purification. This was achieved by formulating photosensitizing hybrids based on a newly synthesized chloroindium (III) 5,10,15,20-tetrakis(4-acetamidophenyl) porphyrin (InTAAP) compound, anchored on oxygen functionalized coconut shell-based activated carbon granules supports. The fashioned integrated photocatalyst adsorbent hybrid (InTAAP(ACO)) was then studied for their adsorption and photodegradation efficiency using methylene blue dye, where InTAAP(ACO) showed excellent photocatalytic activity compared to ACO and unfunctionalized activated carbon granules (AC), with appreciably high and adsorption properties as AC and ACO.
- Full Text:
- Date Issued: 2022
- Authors: Oyim, James , Amuhaya, Edith , Matshitse, Refilwe , Mack, John , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300101 , vital:57893 , xlink:href="https://doi.org/10.1016/j.cartre.2022.100191"
- Description: Integration of adsorption and photocatalysis processes can lead to several benefits in water treatment. Integrating well-known adsorbents with photocatalysts ensures that all the interesting components are preserved and helps to overcome the serious downsides of each material and technique when operated independently. In this work, we introduce a new concept of combining both absorption and photodegradation mechanisms using organic photocatalytic adsorbents for water purification. This was achieved by formulating photosensitizing hybrids based on a newly synthesized chloroindium (III) 5,10,15,20-tetrakis(4-acetamidophenyl) porphyrin (InTAAP) compound, anchored on oxygen functionalized coconut shell-based activated carbon granules supports. The fashioned integrated photocatalyst adsorbent hybrid (InTAAP(ACO)) was then studied for their adsorption and photodegradation efficiency using methylene blue dye, where InTAAP(ACO) showed excellent photocatalytic activity compared to ACO and unfunctionalized activated carbon granules (AC), with appreciably high and adsorption properties as AC and ACO.
- Full Text:
- Date Issued: 2022
Interaction between an entomopathogenic fungus and entomopathogenic nematodes for increased mortality of Thaumatotibia leucotreta (Lepidoptera: Tortricidae)
- Prinsloo, Sandra, Hill, Martin P, Moore, Sean D, Malan, Antoinette P, Coombes, Candice
- Authors: Prinsloo, Sandra , Hill, Martin P , Moore, Sean D , Malan, Antoinette P , Coombes, Candice
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/417738 , vital:71482 , xlink:href="https://doi.org/10.1080/09583157.2022.2099528"
- Description: Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae) is a major phytosanitary pest of citrus in South Africa. Although several management tools exist, control options registered for use against the soil-dwelling life stages are limited. Both entomopathogenic nematodes (EPNs) and entomopathogenic fungi have been investigated previously, but they have not been studied in combination against T. leucotreta. Thus, this study investigated the interaction of an indigenous entomopathogenic fungus, Metarhizium pinghaense (previously anisopliae) FCM Ar 23 B3 with three indigenous EPNs: Steinernema yirgalemense 157-C, S. jeffreyense J194 and Heterorhabditis noenieputensis 158-C for increased late instar T. leucotreta larval mortality. Before interaction experiments, lethal concentration (LC) values for each of these microbial agents were determined through dose–response bioassays. Heterorhabditis noenieputensis recorded the highest LC50 amongst the nematodes (7.11 IJs/50 µl). Using the pre-determined LC70 value of M. pinghaense and the LC50 values for each of the nematode species, interaction experiments were conducted. Combinations of the nematodes either applied simultaneously with the fungus or at 24, 48, 72 or 96 h post-fungal application showed predominantly additive interactions. Synergy between the simultaneous application of S. yirgalemense and M. pinghaense was found, whilst the interaction between H. noenieputensis and M. pinghaense applied simultaneously and S. jeffreyense applied 24 h post-fungal application, recorded antagonistic interactions. The use of these agents in combination may therefore have the potential to increase control of T. leucotreta soil-dwelling life stages in citrus orchards across South Africa and should be further investigated.
- Full Text:
- Date Issued: 2022
- Authors: Prinsloo, Sandra , Hill, Martin P , Moore, Sean D , Malan, Antoinette P , Coombes, Candice
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/417738 , vital:71482 , xlink:href="https://doi.org/10.1080/09583157.2022.2099528"
- Description: Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae) is a major phytosanitary pest of citrus in South Africa. Although several management tools exist, control options registered for use against the soil-dwelling life stages are limited. Both entomopathogenic nematodes (EPNs) and entomopathogenic fungi have been investigated previously, but they have not been studied in combination against T. leucotreta. Thus, this study investigated the interaction of an indigenous entomopathogenic fungus, Metarhizium pinghaense (previously anisopliae) FCM Ar 23 B3 with three indigenous EPNs: Steinernema yirgalemense 157-C, S. jeffreyense J194 and Heterorhabditis noenieputensis 158-C for increased late instar T. leucotreta larval mortality. Before interaction experiments, lethal concentration (LC) values for each of these microbial agents were determined through dose–response bioassays. Heterorhabditis noenieputensis recorded the highest LC50 amongst the nematodes (7.11 IJs/50 µl). Using the pre-determined LC70 value of M. pinghaense and the LC50 values for each of the nematode species, interaction experiments were conducted. Combinations of the nematodes either applied simultaneously with the fungus or at 24, 48, 72 or 96 h post-fungal application showed predominantly additive interactions. Synergy between the simultaneous application of S. yirgalemense and M. pinghaense was found, whilst the interaction between H. noenieputensis and M. pinghaense applied simultaneously and S. jeffreyense applied 24 h post-fungal application, recorded antagonistic interactions. The use of these agents in combination may therefore have the potential to increase control of T. leucotreta soil-dwelling life stages in citrus orchards across South Africa and should be further investigated.
- Full Text:
- Date Issued: 2022
Interdisciplinarity requires careful stewardship of powerful knowledge
- Authors: McKenna, Sioux , de Bie G J
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/434487 , vital:73068 , ISBN 9780367518707 , https://www.routledge.com/Enhancing-Science-Education-Exploring-Knowledge-Practices-with-Legitimation/Blackie-Adendorff-Mouton/p/book/9780367518707#:~:text=The%20book%20introduces%20Legitimation%20Code,grasp%20difficult%20and%20dense%20concepts
- Description: This book helps meet an urgent need for theorized, accessible and discipline-sensitive publications to assist science, technology, engineering and mathematics educators. The book introduces Legitimation Code Theory (LCT) and demonstrates how it can be used to improve teaching and learning in tertiary courses across the sciences. LCT provides a suite of tools which science educators can employ in order to help their students grasp difficult and dense concepts. The chapters cover a broad range of subjects, including biology, physics, chemistry and mathematics, as well as different curriculum, pedagogy and assessment practices. This is a crucial resource for any science educator who wants to better understand and improve their teaching.
- Full Text:
- Date Issued: 2022
- Authors: McKenna, Sioux , de Bie G J
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/434487 , vital:73068 , ISBN 9780367518707 , https://www.routledge.com/Enhancing-Science-Education-Exploring-Knowledge-Practices-with-Legitimation/Blackie-Adendorff-Mouton/p/book/9780367518707#:~:text=The%20book%20introduces%20Legitimation%20Code,grasp%20difficult%20and%20dense%20concepts
- Description: This book helps meet an urgent need for theorized, accessible and discipline-sensitive publications to assist science, technology, engineering and mathematics educators. The book introduces Legitimation Code Theory (LCT) and demonstrates how it can be used to improve teaching and learning in tertiary courses across the sciences. LCT provides a suite of tools which science educators can employ in order to help their students grasp difficult and dense concepts. The chapters cover a broad range of subjects, including biology, physics, chemistry and mathematics, as well as different curriculum, pedagogy and assessment practices. This is a crucial resource for any science educator who wants to better understand and improve their teaching.
- Full Text:
- Date Issued: 2022
Invasive alien aquatic plant species management drives aquatic ecosystem community recovery: An exploration using stable isotope analysis
- Motitsoe, Samuel N, Hill, Jaclyn M, Coetzee, Julie A, Hill, Martin P
- Authors: Motitsoe, Samuel N , Hill, Jaclyn M , Coetzee, Julie A , Hill, Martin P
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/423527 , vital:72069 , xlink:href="https://doi.org/10.1016/j.biocontrol.2022.104995"
- Description: The socio-economic and ecological impacts of invasive alien aquatic plant (IAAP) species have been well studied globally. However less is known about ecosystem recovery following the management of IAAP species. This study employed a before-after study design to investigate ecological recovery following the management of Salvinia molesta D.S. Mitchell, at four field sites in South Africa. We hypothesized that the presence of S. molesta would have a negative impact on the ecosystem food web structure, and that following S. molesta control, the systems would show positive ecosystem recovery. Aquatic macroinvertebrate and macrophyte samples collected before and after mechanical or biological control of S. molesta, were analysed for δ13C and δ15N stable isotopes. Salvinia molesta infestations negatively impacted the food web structure, indicated by reduced food chain length, trophic diversity and basal resources. This represented an altered aquatic food web structure, that in some cases, led to the collapse of the aquatic community. In contrast, after either mechanical or biological control, there were increases in food chain length, trophic diversity and abundance of energy resources accessed by consumers, indicating improved food web structure. Although the study showed positive ecosystem recovery following control, we noted that each control method followed a different recovery trajectory. We conclude that S. molesta invasions reduce aquatic biodiversity and alter ecosystem trophic dynamics and related ecosystem processes, necessitating control.
- Full Text:
- Date Issued: 2022
- Authors: Motitsoe, Samuel N , Hill, Jaclyn M , Coetzee, Julie A , Hill, Martin P
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/423527 , vital:72069 , xlink:href="https://doi.org/10.1016/j.biocontrol.2022.104995"
- Description: The socio-economic and ecological impacts of invasive alien aquatic plant (IAAP) species have been well studied globally. However less is known about ecosystem recovery following the management of IAAP species. This study employed a before-after study design to investigate ecological recovery following the management of Salvinia molesta D.S. Mitchell, at four field sites in South Africa. We hypothesized that the presence of S. molesta would have a negative impact on the ecosystem food web structure, and that following S. molesta control, the systems would show positive ecosystem recovery. Aquatic macroinvertebrate and macrophyte samples collected before and after mechanical or biological control of S. molesta, were analysed for δ13C and δ15N stable isotopes. Salvinia molesta infestations negatively impacted the food web structure, indicated by reduced food chain length, trophic diversity and basal resources. This represented an altered aquatic food web structure, that in some cases, led to the collapse of the aquatic community. In contrast, after either mechanical or biological control, there were increases in food chain length, trophic diversity and abundance of energy resources accessed by consumers, indicating improved food web structure. Although the study showed positive ecosystem recovery following control, we noted that each control method followed a different recovery trajectory. We conclude that S. molesta invasions reduce aquatic biodiversity and alter ecosystem trophic dynamics and related ecosystem processes, necessitating control.
- Full Text:
- Date Issued: 2022
Is education blithely producing unemployed graduates?: A reflection based on a review of environmental skills initiatives 2016-2021
- Authors: Rosenberg, Eureta
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/370619 , vital:66360 , xlink:href="http://dx.doi.org/10.17159/2520-9868/i89a08"
- Description: A statement from the president of the Black Business Council (BBC) that "our education system continues to produce the unemployed graduates" (NewZRoomAfrika, 2021) because "the courses they are doing are not required by industry" reflects the perennial perception that South Africa's education system is a cause of unemployment. In this paper, I explore aspects of this perception through a meta-review of environmental skills-related studies conducted over the past five years. Data used in these studies include graduation trends based on higher education, employer surveys, analyses of skills needs in the workplace compared to courses offered, and case examples of internships and teacher development. Using an ecological-systems model, I relate the findings, in a layered critical realist analysis, to the socio-cultural milieu in South Africa. I challenge the conception of relevant graduate education evident in the BBC's statement.
- Full Text:
- Date Issued: 2022
- Authors: Rosenberg, Eureta
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/370619 , vital:66360 , xlink:href="http://dx.doi.org/10.17159/2520-9868/i89a08"
- Description: A statement from the president of the Black Business Council (BBC) that "our education system continues to produce the unemployed graduates" (NewZRoomAfrika, 2021) because "the courses they are doing are not required by industry" reflects the perennial perception that South Africa's education system is a cause of unemployment. In this paper, I explore aspects of this perception through a meta-review of environmental skills-related studies conducted over the past five years. Data used in these studies include graduation trends based on higher education, employer surveys, analyses of skills needs in the workplace compared to courses offered, and case examples of internships and teacher development. Using an ecological-systems model, I relate the findings, in a layered critical realist analysis, to the socio-cultural milieu in South Africa. I challenge the conception of relevant graduate education evident in the BBC's statement.
- Full Text:
- Date Issued: 2022
Is green space associated with reduced crime? A national-scale study from the Global South
- Venter, Zander S, Shackleton, Charlie M, Faull, Andrew, Lancaster, Lizette, Breetzke, Gregory, Edelstein, Ian
- Authors: Venter, Zander S , Shackleton, Charlie M , Faull, Andrew , Lancaster, Lizette , Breetzke, Gregory , Edelstein, Ian
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/402340 , vital:69843 , xlink:href="https://doi.org/10.1016/j.scitotenv.2022.154005"
- Description: Assumptions about the link between green space and crime mitigation are informed by literature that overwhelmingly originates in the Global North. Little is known about the association between green spaces and crime in the Global South. We utilized 10 years of precinct-level crime statistics (n = 1152) over South Africa, a global crime hotspot, to test the hypothesis that green space is associated with reduced crime rates. We found that, after controlling for a number of socio-demographic confounders (unemployment, income, age, education, land use and population density), for every 1% increase in total green space there is a 1.2% (0.7 to 1.7%; 95% confidence interval) decrease in violent crime, and 1.3% (0.8 to 1.8%) decrease in property crime, with no effect on sexual crimes. However, the direction of the association changed for property crimes when exploring the effect of green space characteristics including tree cover and park accessibility. Property crimes increase by 0.4% (0.1 to 0.7%) with a percentage increase in tree cover, and by 0.9% (0.5 to 1.3%) with every kilometer increase in proximity to a public park. Further research, including experimental studies, is needed to better isolate causal mechanisms behind crime-green space associations, especially considering that green space may map to race and income inequality and that there may be more crime reporting in affluent areas. Nevertheless, our results provide a complementary contribution to the evidence from the Global North, highlighting the need for more nuanced definitions of green space and its characteristics when considering links to crime. When viewed in light of the broader suite of ecosystem services provided by green space, our results support urban greening as a major strategy towards achieving just and sustainable cities and towns.
- Full Text:
- Date Issued: 2022
- Authors: Venter, Zander S , Shackleton, Charlie M , Faull, Andrew , Lancaster, Lizette , Breetzke, Gregory , Edelstein, Ian
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/402340 , vital:69843 , xlink:href="https://doi.org/10.1016/j.scitotenv.2022.154005"
- Description: Assumptions about the link between green space and crime mitigation are informed by literature that overwhelmingly originates in the Global North. Little is known about the association between green spaces and crime in the Global South. We utilized 10 years of precinct-level crime statistics (n = 1152) over South Africa, a global crime hotspot, to test the hypothesis that green space is associated with reduced crime rates. We found that, after controlling for a number of socio-demographic confounders (unemployment, income, age, education, land use and population density), for every 1% increase in total green space there is a 1.2% (0.7 to 1.7%; 95% confidence interval) decrease in violent crime, and 1.3% (0.8 to 1.8%) decrease in property crime, with no effect on sexual crimes. However, the direction of the association changed for property crimes when exploring the effect of green space characteristics including tree cover and park accessibility. Property crimes increase by 0.4% (0.1 to 0.7%) with a percentage increase in tree cover, and by 0.9% (0.5 to 1.3%) with every kilometer increase in proximity to a public park. Further research, including experimental studies, is needed to better isolate causal mechanisms behind crime-green space associations, especially considering that green space may map to race and income inequality and that there may be more crime reporting in affluent areas. Nevertheless, our results provide a complementary contribution to the evidence from the Global North, highlighting the need for more nuanced definitions of green space and its characteristics when considering links to crime. When viewed in light of the broader suite of ecosystem services provided by green space, our results support urban greening as a major strategy towards achieving just and sustainable cities and towns.
- Full Text:
- Date Issued: 2022
Is the instrumental approach a ‘silver bullet’for addressing non-compliance in recreational fisheries: A South African case study
- Bova, Christopher S, Stephens, Jed, Aswani, Shankar, Potts, Warren M
- Authors: Bova, Christopher S , Stephens, Jed , Aswani, Shankar , Potts, Warren M
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/391359 , vital:68644 , xlink:href="https://doi.org/10.1016/j.fishres.2022.106439"
- Description: Non-compliance with recreational fishery regulations is considered to be one of the biggest threats to the sustainability of fisheries. Dedicated non-compliance studies are seldom carried out at the national level which makes it difficult to discern the behavioural compliance norms within a population. The instrumental approach for compliance is the traditional paradigm in recreational fisheries. It postulates that increased enforcement activities and the corresponding punishment will improve compliance behaviour, although there is little empirical evidence for such a supposition within the recreational fisheries context. Using face-to-face encounter surveys employing the ballot box method for reducing social desirability bias (SDB), South African marine shore-based fishery (MSBF) participants were questioned on their compliance behaviour with a set of regulations pertaining to the fishery. Overall non-compliance levels were very high (52%), and non-compliance levels with individual regulations varied based on provincial locality. Perceptions and observations of enforcement activity had no significant impact on compliance behaviour. Participants that had previously been caught by law enforcement violating the regulations were still more likely to violate the regulations than participants that had not faced enforcement action. Results indicate that calls for increased enforcement as a means of improving compliance behaviour are questionable in the South African MSBF, and further emphasise the need to develop alternative approaches, such as those pertaining to normative theory, within recreational fisheries.
- Full Text:
- Date Issued: 2022
- Authors: Bova, Christopher S , Stephens, Jed , Aswani, Shankar , Potts, Warren M
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/391359 , vital:68644 , xlink:href="https://doi.org/10.1016/j.fishres.2022.106439"
- Description: Non-compliance with recreational fishery regulations is considered to be one of the biggest threats to the sustainability of fisheries. Dedicated non-compliance studies are seldom carried out at the national level which makes it difficult to discern the behavioural compliance norms within a population. The instrumental approach for compliance is the traditional paradigm in recreational fisheries. It postulates that increased enforcement activities and the corresponding punishment will improve compliance behaviour, although there is little empirical evidence for such a supposition within the recreational fisheries context. Using face-to-face encounter surveys employing the ballot box method for reducing social desirability bias (SDB), South African marine shore-based fishery (MSBF) participants were questioned on their compliance behaviour with a set of regulations pertaining to the fishery. Overall non-compliance levels were very high (52%), and non-compliance levels with individual regulations varied based on provincial locality. Perceptions and observations of enforcement activity had no significant impact on compliance behaviour. Participants that had previously been caught by law enforcement violating the regulations were still more likely to violate the regulations than participants that had not faced enforcement action. Results indicate that calls for increased enforcement as a means of improving compliance behaviour are questionable in the South African MSBF, and further emphasise the need to develop alternative approaches, such as those pertaining to normative theory, within recreational fisheries.
- Full Text:
- Date Issued: 2022
It's a numbers game: inundative biological control of water hyacinth (Pontederia crassipes), using Megamelus scutellaris (Hemiptera: Delphacidae) yields success at a high elevation, hypertrophic reservoir in South Africa
- Coetzee, Julie A, Miller, Benjamin E, Kinsler, David, Sebola, Keneilwe, Hill, Martin P
- Authors: Coetzee, Julie A , Miller, Benjamin E , Kinsler, David , Sebola, Keneilwe , Hill, Martin P
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/417749 , vital:71483 , xlink:href="https://doi.org/10.1080/09583157.2022.2109594"
- Description: Classical biological control of water hyacinth in South Africa has been constrained by cool winter temperatures that limit population growth of the biological control agents, and highly eutrophic waters which enhance plant growth. However, inundative releases of the control agent, Megamelus scutellaris (Hemiptera: Delphacidae), at the Hartbeespoort Dam, South Africa, suggest that water hyacinth can be managed successfully using biological control as a standalone intervention for the first time in the absence of herbicide operations, despite eutrophication and a temperate climate. Sentinel-2 satellite images were used to measure the reduction in water hyacinth cover from over 37% to less than 6% over two consecutive years since M. scutellaris was first released on the dam in 2018, while site surveys confirmed a corresponding increase in M. scutellaris population density from fewer than 500 insects/m2 in October 2019, to more than 6000 insects/m2 by March 2020. Inundative release strategies are recommended for the control of water hyacinth in South Africa at key stages of its invasion, particularly after winter, and flooding events.
- Full Text:
- Date Issued: 2022
- Authors: Coetzee, Julie A , Miller, Benjamin E , Kinsler, David , Sebola, Keneilwe , Hill, Martin P
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/417749 , vital:71483 , xlink:href="https://doi.org/10.1080/09583157.2022.2109594"
- Description: Classical biological control of water hyacinth in South Africa has been constrained by cool winter temperatures that limit population growth of the biological control agents, and highly eutrophic waters which enhance plant growth. However, inundative releases of the control agent, Megamelus scutellaris (Hemiptera: Delphacidae), at the Hartbeespoort Dam, South Africa, suggest that water hyacinth can be managed successfully using biological control as a standalone intervention for the first time in the absence of herbicide operations, despite eutrophication and a temperate climate. Sentinel-2 satellite images were used to measure the reduction in water hyacinth cover from over 37% to less than 6% over two consecutive years since M. scutellaris was first released on the dam in 2018, while site surveys confirmed a corresponding increase in M. scutellaris population density from fewer than 500 insects/m2 in October 2019, to more than 6000 insects/m2 by March 2020. Inundative release strategies are recommended for the control of water hyacinth in South Africa at key stages of its invasion, particularly after winter, and flooding events.
- Full Text:
- Date Issued: 2022
Landscape drivers of mammal habitat use and richness in a protected area and its surrounding agricultural lands
- Bellón, Beatriz, Henry, Dominic AW, Renaud, Pierre-Cyril, Roque, Fabio de O, Santos, Cyntia Cavalcante, Melo, Isabel, Arvor, Damien, de Vos, Alta
- Authors: Bellón, Beatriz , Henry, Dominic AW , Renaud, Pierre-Cyril , Roque, Fabio de O , Santos, Cyntia Cavalcante , Melo, Isabel , Arvor, Damien , de Vos, Alta
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/415873 , vital:71296 , xlink:href="https://doi.org/10.1016/j.agee.2022.107989"
- Description: Protected areas (PAs) are key to conserving biodiversity and ecosystem services globally, but their effectiveness increasingly depends on the ability of the surrounding agricultural areas to support biodiversity and secure connectivity at the landscape level. This requires monitoring the broader multi-use landscapes in which PAs exist and identifying the landscape characteristics that support rich, functional wildlife communities. Here, we investigated the species richness and habitat use patterns of a mammal community in relation to different landscape variables and land use and land cover (LULC) types in a PA and its surrounding agricultural lands in the Cerrado. We first used a hierarchical multi-species occupancy model with input camera trap data and eight landscape variables (vegetation productivity, phenology, and heterogeneity, distance to water, roads and settlements, and the PA, slope, and elevation) to estimate the species richness and habitat use of 29 mammal species across the landscape. We then analyzed the relationships between the species richness and habitat use and the landscape variables at the site level, as well as the distribution of species at the landscape level in relation to the different natural and agricultural LULC types.
- Full Text:
- Date Issued: 2022
- Authors: Bellón, Beatriz , Henry, Dominic AW , Renaud, Pierre-Cyril , Roque, Fabio de O , Santos, Cyntia Cavalcante , Melo, Isabel , Arvor, Damien , de Vos, Alta
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/415873 , vital:71296 , xlink:href="https://doi.org/10.1016/j.agee.2022.107989"
- Description: Protected areas (PAs) are key to conserving biodiversity and ecosystem services globally, but their effectiveness increasingly depends on the ability of the surrounding agricultural areas to support biodiversity and secure connectivity at the landscape level. This requires monitoring the broader multi-use landscapes in which PAs exist and identifying the landscape characteristics that support rich, functional wildlife communities. Here, we investigated the species richness and habitat use patterns of a mammal community in relation to different landscape variables and land use and land cover (LULC) types in a PA and its surrounding agricultural lands in the Cerrado. We first used a hierarchical multi-species occupancy model with input camera trap data and eight landscape variables (vegetation productivity, phenology, and heterogeneity, distance to water, roads and settlements, and the PA, slope, and elevation) to estimate the species richness and habitat use of 29 mammal species across the landscape. We then analyzed the relationships between the species richness and habitat use and the landscape variables at the site level, as well as the distribution of species at the landscape level in relation to the different natural and agricultural LULC types.
- Full Text:
- Date Issued: 2022
Lessons from bright-spots for advancing knowledge exchange at the interface of marine science and policy
- Karcher, Denis B, Cvitanovic, Christopher, van Putten, Ingrid E, Colvin, Rebecca M, Armitage, Derek, Aswani, Shankar, Ballesteros, Marta, Ban, Natalie, Barragán-Paladines, María José, Bednarek, Angela, Bell, Johann D, Brooks, Cassandra M, Daw, Tim M, De la Cruz-Modino, Raquel, Francis, Tessa B, Fulton, Elizabeth A, Hobday, Alistair J, Holcer, Draško, Hudson, Charlotte, Jennerjahn, Tim C, Kinney, Aimee, Knol-Kauffman, Maaike, Löf, Marie F, Lopes, Priscila F, Mackelworth, Peter C, McQuatters-Gollop, Abigail, Muhl, Ella-Kari, Neihapi, Pita, Pascual-Fernández, José J, Posner, Stephpen M, Runhaar, Hens, Sainsbury, Keith, Sander, Gunnar, Steenbergen, Dirk J, Tuda, Paul M, Whiteman, Elizabeth, Zhang, Jialin
- Authors: Karcher, Denis B , Cvitanovic, Christopher , van Putten, Ingrid E , Colvin, Rebecca M , Armitage, Derek , Aswani, Shankar , Ballesteros, Marta , Ban, Natalie , Barragán-Paladines, María José , Bednarek, Angela , Bell, Johann D , Brooks, Cassandra M , Daw, Tim M , De la Cruz-Modino, Raquel , Francis, Tessa B , Fulton, Elizabeth A , Hobday, Alistair J , Holcer, Draško , Hudson, Charlotte , Jennerjahn, Tim C , Kinney, Aimee , Knol-Kauffman, Maaike , Löf, Marie F , Lopes, Priscila F , Mackelworth, Peter C , McQuatters-Gollop, Abigail , Muhl, Ella-Kari , Neihapi, Pita , Pascual-Fernández, José J , Posner, Stephpen M , Runhaar, Hens , Sainsbury, Keith , Sander, Gunnar , Steenbergen, Dirk J , Tuda, Paul M , Whiteman, Elizabeth , Zhang, Jialin
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/391378 , vital:68647 , xlink:href="https://doi.org/10.1016/j.jenvman.2022.114994"
- Description: Evidence-informed decision-making is in increasing demand given growing pressures on marine environments. A way to facilitate this is by knowledge exchange among marine scientists and decision-makers. While many barriers are reported in the literature, there are also examples whereby research has successfully informed marine decision-making (i.e., ‘bright-spots’). Here, we identify and analyze 25 bright-spots from a wide range of marine fields, contexts, and locations to provide insights into how to improve knowledge exchange at the interface of marine science and policy. Through qualitative surveys we investigate what initiated the bright-spots, their goals, and approaches to knowledge exchange. We also seek to identify what outcomes/impacts have been achieved, the enablers of success, and what lessons can be learnt to guide future knowledge exchange efforts. Results show that a diversity of approaches were used for knowledge exchange, from consultative engagement to genuine knowledge co-production. We show that diverse successes at the interface of marine science and policy are achievable and include impacts on policy, people, and governance. Such successes were enabled by factors related to the actors, processes, support, context, and timing. For example, the importance of involving diverse actors and managing positive relationships is a key lesson for success. However, enabling routine success will require: 1) transforming the ways in which we train scientists to include a greater focus on interpersonal skills, 2) institutionalizing and supporting knowledge exchange activities in organizational agendas, 3) conceptualizing and implementing broader research impact metrics, and 4) transforming funding mechanisms to focus on need-based interventions, impact planning, and an acknowledgement of the required time and effort that underpin knowledge exchange activities.
- Full Text:
- Date Issued: 2022
- Authors: Karcher, Denis B , Cvitanovic, Christopher , van Putten, Ingrid E , Colvin, Rebecca M , Armitage, Derek , Aswani, Shankar , Ballesteros, Marta , Ban, Natalie , Barragán-Paladines, María José , Bednarek, Angela , Bell, Johann D , Brooks, Cassandra M , Daw, Tim M , De la Cruz-Modino, Raquel , Francis, Tessa B , Fulton, Elizabeth A , Hobday, Alistair J , Holcer, Draško , Hudson, Charlotte , Jennerjahn, Tim C , Kinney, Aimee , Knol-Kauffman, Maaike , Löf, Marie F , Lopes, Priscila F , Mackelworth, Peter C , McQuatters-Gollop, Abigail , Muhl, Ella-Kari , Neihapi, Pita , Pascual-Fernández, José J , Posner, Stephpen M , Runhaar, Hens , Sainsbury, Keith , Sander, Gunnar , Steenbergen, Dirk J , Tuda, Paul M , Whiteman, Elizabeth , Zhang, Jialin
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/391378 , vital:68647 , xlink:href="https://doi.org/10.1016/j.jenvman.2022.114994"
- Description: Evidence-informed decision-making is in increasing demand given growing pressures on marine environments. A way to facilitate this is by knowledge exchange among marine scientists and decision-makers. While many barriers are reported in the literature, there are also examples whereby research has successfully informed marine decision-making (i.e., ‘bright-spots’). Here, we identify and analyze 25 bright-spots from a wide range of marine fields, contexts, and locations to provide insights into how to improve knowledge exchange at the interface of marine science and policy. Through qualitative surveys we investigate what initiated the bright-spots, their goals, and approaches to knowledge exchange. We also seek to identify what outcomes/impacts have been achieved, the enablers of success, and what lessons can be learnt to guide future knowledge exchange efforts. Results show that a diversity of approaches were used for knowledge exchange, from consultative engagement to genuine knowledge co-production. We show that diverse successes at the interface of marine science and policy are achievable and include impacts on policy, people, and governance. Such successes were enabled by factors related to the actors, processes, support, context, and timing. For example, the importance of involving diverse actors and managing positive relationships is a key lesson for success. However, enabling routine success will require: 1) transforming the ways in which we train scientists to include a greater focus on interpersonal skills, 2) institutionalizing and supporting knowledge exchange activities in organizational agendas, 3) conceptualizing and implementing broader research impact metrics, and 4) transforming funding mechanisms to focus on need-based interventions, impact planning, and an acknowledgement of the required time and effort that underpin knowledge exchange activities.
- Full Text:
- Date Issued: 2022
Lessons from COVID-19 for wildlife ranching in a changing world
- Clements, Hayley S, Child, Matthew F, Lindeque, Lehman, Lunderstedt, Kyra, de Vos, Alta
- Authors: Clements, Hayley S , Child, Matthew F , Lindeque, Lehman , Lunderstedt, Kyra , de Vos, Alta
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/415886 , vital:71297 , xlink:href="https://doi.org/10.1038/s41893-022-00961-1"
- Description: The COVID-19 pandemic provided an opportunity to assess the impacts of a global disturbance on conservation land uses and learn from responses to the crisis to enable more resilient conservation systems. To understand socio-economic responses of diverse wildlife working lands to COVID-19, we surveyed owners and managers of 78 private wildlife ranches (wildlife working lands), 23 agricultural farms (conventional working lands) and six public protected areas (conventional conservation lands) in South Africa. Most protected areas lost more than 75% of their revenues during 2020, while most agricultural farms lost less than 10%. The impact on wildlife ranches was more varied. Ranches with more diverse activities, particularly mixed wildlife–agriculture systems, lost less revenue, shifting their activities from those heavily impacted (international ecotourism, trophy hunting) to those less afected (for example, wildlife meat, livestock). This adaptive capacity suggests that wildlife-based enterprises could represent key ecosystem-based adaptations, providing lessons for integrated global policies that seek to incorporate private land models in the 2030 Biodiversity Framework.
- Full Text:
- Date Issued: 2022
- Authors: Clements, Hayley S , Child, Matthew F , Lindeque, Lehman , Lunderstedt, Kyra , de Vos, Alta
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/415886 , vital:71297 , xlink:href="https://doi.org/10.1038/s41893-022-00961-1"
- Description: The COVID-19 pandemic provided an opportunity to assess the impacts of a global disturbance on conservation land uses and learn from responses to the crisis to enable more resilient conservation systems. To understand socio-economic responses of diverse wildlife working lands to COVID-19, we surveyed owners and managers of 78 private wildlife ranches (wildlife working lands), 23 agricultural farms (conventional working lands) and six public protected areas (conventional conservation lands) in South Africa. Most protected areas lost more than 75% of their revenues during 2020, while most agricultural farms lost less than 10%. The impact on wildlife ranches was more varied. Ranches with more diverse activities, particularly mixed wildlife–agriculture systems, lost less revenue, shifting their activities from those heavily impacted (international ecotourism, trophy hunting) to those less afected (for example, wildlife meat, livestock). This adaptive capacity suggests that wildlife-based enterprises could represent key ecosystem-based adaptations, providing lessons for integrated global policies that seek to incorporate private land models in the 2030 Biodiversity Framework.
- Full Text:
- Date Issued: 2022
Light-driven antimicrobial therapy of palladium porphyrins and their chitosan immobilization derivatives and their photophysical-chemical properties
- Sen, Pinar, Soy, Rodah, Mgidlana, Sithi, Mack, John, Nyokong, Tebello
- Authors: Sen, Pinar , Soy, Rodah , Mgidlana, Sithi , Mack, John , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300112 , vital:57894 , xlink:href="https://doi.org/10.1016/j.dyepig.2022.110313"
- Description: The emergence of antimicrobial resistance has made the development of photodynamic therapy (PDT) related applications essential, since microorganisms can not form resistance to this method. Porphyrins are well-known photosensitizers for PDT related applications. Thus, the present study outlines the synthesis, characterization and evaluation of the utility of palladium porphyrins and their chitosan inclusion complexes as photosensitizer dye in photodynamic antimicrobial therapy (PACT). Before in vitro cell studies, the photophysical-chemical studies of all obtained structures were performed in solution. It was observed that the immobilization of the porphyrins into the chitosan influenced the photophysical-chemical and PACT activity properties. The determined fluorescence quantum yield was very low, in the range of 0.007–0.028 for all samples indicating the efficient triplet state population to cause high singlet oxygen quantum yield (ΦΔ). The measured ΦΔ values were in the range of 0.51–0.61 for the porphyrins and 0.53–0.66 for porphyrin chitosan immobilization complexes. Our results demonstrate that the PACT activity of cationic porphyrin (P3) and its chitosan immobilization form (P3-Ct) were more efficient in decreasing the number of viable cells up to 100% in vitro.
- Full Text:
- Date Issued: 2022
- Authors: Sen, Pinar , Soy, Rodah , Mgidlana, Sithi , Mack, John , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/300112 , vital:57894 , xlink:href="https://doi.org/10.1016/j.dyepig.2022.110313"
- Description: The emergence of antimicrobial resistance has made the development of photodynamic therapy (PDT) related applications essential, since microorganisms can not form resistance to this method. Porphyrins are well-known photosensitizers for PDT related applications. Thus, the present study outlines the synthesis, characterization and evaluation of the utility of palladium porphyrins and their chitosan inclusion complexes as photosensitizer dye in photodynamic antimicrobial therapy (PACT). Before in vitro cell studies, the photophysical-chemical studies of all obtained structures were performed in solution. It was observed that the immobilization of the porphyrins into the chitosan influenced the photophysical-chemical and PACT activity properties. The determined fluorescence quantum yield was very low, in the range of 0.007–0.028 for all samples indicating the efficient triplet state population to cause high singlet oxygen quantum yield (ΦΔ). The measured ΦΔ values were in the range of 0.51–0.61 for the porphyrins and 0.53–0.66 for porphyrin chitosan immobilization complexes. Our results demonstrate that the PACT activity of cationic porphyrin (P3) and its chitosan immobilization form (P3-Ct) were more efficient in decreasing the number of viable cells up to 100% in vitro.
- Full Text:
- Date Issued: 2022
Livestock ecosystem services and disservices in a medium-sized South African town
- Thondhlana, Gladman, Papama Yose, Papama, Cockburn, Jessica, Shackleton, Charlie M
- Authors: Thondhlana, Gladman , Papama Yose, Papama , Cockburn, Jessica , Shackleton, Charlie M
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/403241 , vital:69937 , xlink:href="https://doi.org/10.1080/26395916.2021.2019833"
- Description: Production of livestock in urban spaces is a common phenomenon globally, particularly in the Global South. Livestock provides multiple benefits to society yet its production in urban spaces can result in adverse impacts to residents that can trigger conflicts. Understanding of the ecosystem services and disservices of livestock from the perspectives of residents can inform inclusive local management plans. Using household surveys and key informant interviews, this study sought to examine the contribution of livestock to owners, and perceptions of livestock services and disservices among non-livestock owners and key informants in Makhanda, a medium-sized South African town. Livestock owners derived multiple benefits from their livestock, including provisioning services such as meat, milk, skins and draught, and use livestock and livestock products in cultural activities such as rituals, bride price payments and funerals that are key elements of local identity. Among residents, there were marked differences in perceptions on the services and disservices of livestock which points to potential conflicts over urban land use and the need for addressing trade-offs. A key trade-off for local municipal authorities is addressing hunger and poverty by supporting well-regulated urban livestock production versus managing potential livestock disservices such as injuries to humans, livestock-vehicle collisions, health hazards and damage to urban green infrastructure. The trade-offs should be understood and considered by local authorities and residents as a basis for collectively developing strategies that can integrate livelihoods and cultural realities to balance competing demands for urban spaces including livestock production and other uses.
- Full Text:
- Date Issued: 2022
- Authors: Thondhlana, Gladman , Papama Yose, Papama , Cockburn, Jessica , Shackleton, Charlie M
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/403241 , vital:69937 , xlink:href="https://doi.org/10.1080/26395916.2021.2019833"
- Description: Production of livestock in urban spaces is a common phenomenon globally, particularly in the Global South. Livestock provides multiple benefits to society yet its production in urban spaces can result in adverse impacts to residents that can trigger conflicts. Understanding of the ecosystem services and disservices of livestock from the perspectives of residents can inform inclusive local management plans. Using household surveys and key informant interviews, this study sought to examine the contribution of livestock to owners, and perceptions of livestock services and disservices among non-livestock owners and key informants in Makhanda, a medium-sized South African town. Livestock owners derived multiple benefits from their livestock, including provisioning services such as meat, milk, skins and draught, and use livestock and livestock products in cultural activities such as rituals, bride price payments and funerals that are key elements of local identity. Among residents, there were marked differences in perceptions on the services and disservices of livestock which points to potential conflicts over urban land use and the need for addressing trade-offs. A key trade-off for local municipal authorities is addressing hunger and poverty by supporting well-regulated urban livestock production versus managing potential livestock disservices such as injuries to humans, livestock-vehicle collisions, health hazards and damage to urban green infrastructure. The trade-offs should be understood and considered by local authorities and residents as a basis for collectively developing strategies that can integrate livelihoods and cultural realities to balance competing demands for urban spaces including livestock production and other uses.
- Full Text:
- Date Issued: 2022
Low-Symmetry Phthalocyanines Bearing Carboxy-Groups
- Bunin, Dmitry A, Ndebele, Nobuhle, Martynov, Alexander G, Mack, John, Gorbunova, Yulia G, Nyokong, Tebello
- Authors: Bunin, Dmitry A , Ndebele, Nobuhle , Martynov, Alexander G , Mack, John , Gorbunova, Yulia G , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231262 , vital:49870 , xlink:href="https://doi.org/10.3390/molecules27020524" "
- Description: The synthesis and characterization of A3B-type phthalocyanines, ZnPc1–4, bearing bulky 2,6-diisopropylphenoxy-groups or chlorine atoms on isoindoline units “A” and either one or two carboxylic anchors on isoindoline unit “B” are reported. A comparison of molecular modelling with the conventional time dependent—density functional theory (TD-DFT) approach and its simplified sTD-DFT approximation provides further evidence that the latter method accurately reproduces the key trends in the spectral properties, providing colossal savings in computer time for quite large molecules. This demonstrates that it is a valuable tool for guiding the rational design of new phthalocyanines for practical applications.
- Full Text:
- Date Issued: 2022
- Authors: Bunin, Dmitry A , Ndebele, Nobuhle , Martynov, Alexander G , Mack, John , Gorbunova, Yulia G , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231262 , vital:49870 , xlink:href="https://doi.org/10.3390/molecules27020524" "
- Description: The synthesis and characterization of A3B-type phthalocyanines, ZnPc1–4, bearing bulky 2,6-diisopropylphenoxy-groups or chlorine atoms on isoindoline units “A” and either one or two carboxylic anchors on isoindoline unit “B” are reported. A comparison of molecular modelling with the conventional time dependent—density functional theory (TD-DFT) approach and its simplified sTD-DFT approximation provides further evidence that the latter method accurately reproduces the key trends in the spectral properties, providing colossal savings in computer time for quite large molecules. This demonstrates that it is a valuable tool for guiding the rational design of new phthalocyanines for practical applications.
- Full Text:
- Date Issued: 2022
Male Peer Talk About Menstruation: Discursively Bolstering Hegemonic Masculinities Among Young Men in South Africa
- Macleod, Catriona I, Glover, Jonothan M, Makusem, Manase, Kelland, Lindsay, Paphitis, Sharli A
- Authors: Macleod, Catriona I , Glover, Jonothan M , Makusem, Manase , Kelland, Lindsay , Paphitis, Sharli A
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426502 , vital:72358 , xlink:href="https://doi.org/10.1080/23293691.2022.2057830"
- Description: In this paper, we show how male peer talk about menstruating women may be used to discursively bolster hegemonic masculinities and denigrate women. Focus group discussions among 37 young isiXhosa-speaking men from two South African schools were facilitated by two young men; statements garnered from a sexuality education class about menstruation conducted in the same schools were used as cues. Data were analyzed using discourse analysis. The interactive talk constructed a bifurcation: “disgusting” menstruating women versus “reasonable” non-menstruating women who abide by idealized feminine behavior and are available sexually. We argue that as the non-menstruating woman cyclically become the other (menstruating woman) in women of particular ages, the trace of disgust inhabits the signifier “woman” for these men. Menstruation also disrupted a core identity strategy of local hegemonic masculinities: virile (hetero)sexuality. Given this, discursive distancing of the self from the very topic of menstruation is necessary. Small moments of resistance to these constructions were quickly closed down, and caring masculinity emerged only in the context of negotiating sex during menstruation. Involving men in menstrual hygiene management programs may provide spaces for resistance to denigrating discourses about menstruation.
- Full Text:
- Date Issued: 2022
- Authors: Macleod, Catriona I , Glover, Jonothan M , Makusem, Manase , Kelland, Lindsay , Paphitis, Sharli A
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426502 , vital:72358 , xlink:href="https://doi.org/10.1080/23293691.2022.2057830"
- Description: In this paper, we show how male peer talk about menstruating women may be used to discursively bolster hegemonic masculinities and denigrate women. Focus group discussions among 37 young isiXhosa-speaking men from two South African schools were facilitated by two young men; statements garnered from a sexuality education class about menstruation conducted in the same schools were used as cues. Data were analyzed using discourse analysis. The interactive talk constructed a bifurcation: “disgusting” menstruating women versus “reasonable” non-menstruating women who abide by idealized feminine behavior and are available sexually. We argue that as the non-menstruating woman cyclically become the other (menstruating woman) in women of particular ages, the trace of disgust inhabits the signifier “woman” for these men. Menstruation also disrupted a core identity strategy of local hegemonic masculinities: virile (hetero)sexuality. Given this, discursive distancing of the self from the very topic of menstruation is necessary. Small moments of resistance to these constructions were quickly closed down, and caring masculinity emerged only in the context of negotiating sex during menstruation. Involving men in menstrual hygiene management programs may provide spaces for resistance to denigrating discourses about menstruation.
- Full Text:
- Date Issued: 2022
Marine robots for coastal ocean research in the Western Indian Ocean
- Palmer, Matthew R, Shagude, Yohana W, Roberts, Michael J, Popva, Ekaterina, Wihsgott, Juliane U, Aswani, Shankar, Coupland, Jack, Howe, John A, Bett, Brian J, Osuka, Kennedy E, Abernethy, Colin, Alexiou, Sofia, Painter, Stuart C, Kamau, Joseph N, Nyandwi, Ntahondi, Sekadende, Baraka
- Authors: Palmer, Matthew R , Shagude, Yohana W , Roberts, Michael J , Popva, Ekaterina , Wihsgott, Juliane U , Aswani, Shankar , Coupland, Jack , Howe, John A , Bett, Brian J , Osuka, Kennedy E , Abernethy, Colin , Alexiou, Sofia , Painter, Stuart C , Kamau, Joseph N , Nyandwi, Ntahondi , Sekadende, Baraka
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/403445 , vital:69962 , xlink:href="https://hdl.handle.net/10520/ejc-cristal-v10-n1-a7"
- Description: Marine robots have the potential to enhance WIO marine research to improve regional adaptation to the challenges presented by climate change by providing enhanced research capacity that bypasses the requirement for expensive infrastructure, such as large research vessels. This paper tests this potential and assesses the readiness of WIO communities to adopt autonomous technologies to meet its marine research priorities. We apply a range of analyses to a marine robots case study undertaken in waters around the island of Pemba, part of the Zanzibar archipelago, in Tanzania in 2019. The campaign formed part of a multinational project focused on increasing WIO capacity to meet food security and ocean sustainability challenges. A community engagement programme with six Tanzanian coastal communities resulted in positive changes in attitudes towards marine robots with reported increases in understanding and acceptance of such technologies. Suspicion of the robots was reduced and a lower risk of removing operational equipment was recorded following the provision of educational material. Cost, risk and benefit analysis shows that marine robots are perceived to provide high level benefits, but come at a high cost that is difficult to achieve using national or regional funding. An assessment of the capacity of WIO marine institutes to adopt such technologies shows that prior to this work, few skills or infrastructure related to marine robots were available to researchers and further confirmed that funding opportunities were perceived to be largely unavailable at institutional, national, regional or international levels. Responses from regional partners following completion of the case study however, revealed an uplift in perceived capacity, particularly related to access to infrastructure and expertise as well as support and opportunities for funding at each level. The presented case study is shown to have been a valuable demonstrator of the benefits of using marine robots to meet WIO coastal ocean research requirements and regional capacity was shown to be substantially increased within the broad range of marine institutes surveyed throughout the case study period. This study demonstrates that taking early steps towards adopting marine autonomous robots has increased WIO regional marine research capacity and increased the confidence and willingness of local researchers to seek alternative solutions to ongoing marine research challenges. Recommendations for future action that will continue to increase the capacity and readiness for regional adoption of marine robots include investment at local, national and regional levels to provide accessible training opportunities and to facilitate regional and international collaborations; investment in a regional hub, or centre of excellence for marine robotic technology; early adoption of newly emerging smaller, cheaper autonomous technologies; investment in local skills and support facilities to aid local buy-in and acceptance while supporting regional capacity.
- Full Text:
- Date Issued: 2022
- Authors: Palmer, Matthew R , Shagude, Yohana W , Roberts, Michael J , Popva, Ekaterina , Wihsgott, Juliane U , Aswani, Shankar , Coupland, Jack , Howe, John A , Bett, Brian J , Osuka, Kennedy E , Abernethy, Colin , Alexiou, Sofia , Painter, Stuart C , Kamau, Joseph N , Nyandwi, Ntahondi , Sekadende, Baraka
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/403445 , vital:69962 , xlink:href="https://hdl.handle.net/10520/ejc-cristal-v10-n1-a7"
- Description: Marine robots have the potential to enhance WIO marine research to improve regional adaptation to the challenges presented by climate change by providing enhanced research capacity that bypasses the requirement for expensive infrastructure, such as large research vessels. This paper tests this potential and assesses the readiness of WIO communities to adopt autonomous technologies to meet its marine research priorities. We apply a range of analyses to a marine robots case study undertaken in waters around the island of Pemba, part of the Zanzibar archipelago, in Tanzania in 2019. The campaign formed part of a multinational project focused on increasing WIO capacity to meet food security and ocean sustainability challenges. A community engagement programme with six Tanzanian coastal communities resulted in positive changes in attitudes towards marine robots with reported increases in understanding and acceptance of such technologies. Suspicion of the robots was reduced and a lower risk of removing operational equipment was recorded following the provision of educational material. Cost, risk and benefit analysis shows that marine robots are perceived to provide high level benefits, but come at a high cost that is difficult to achieve using national or regional funding. An assessment of the capacity of WIO marine institutes to adopt such technologies shows that prior to this work, few skills or infrastructure related to marine robots were available to researchers and further confirmed that funding opportunities were perceived to be largely unavailable at institutional, national, regional or international levels. Responses from regional partners following completion of the case study however, revealed an uplift in perceived capacity, particularly related to access to infrastructure and expertise as well as support and opportunities for funding at each level. The presented case study is shown to have been a valuable demonstrator of the benefits of using marine robots to meet WIO coastal ocean research requirements and regional capacity was shown to be substantially increased within the broad range of marine institutes surveyed throughout the case study period. This study demonstrates that taking early steps towards adopting marine autonomous robots has increased WIO regional marine research capacity and increased the confidence and willingness of local researchers to seek alternative solutions to ongoing marine research challenges. Recommendations for future action that will continue to increase the capacity and readiness for regional adoption of marine robots include investment at local, national and regional levels to provide accessible training opportunities and to facilitate regional and international collaborations; investment in a regional hub, or centre of excellence for marine robotic technology; early adoption of newly emerging smaller, cheaper autonomous technologies; investment in local skills and support facilities to aid local buy-in and acceptance while supporting regional capacity.
- Full Text:
- Date Issued: 2022
Measuring discrimination experienced by people with a mental illness
- Brohan, Elaine, Thornicroft, Graham, Rüsch, Nicolas, Lasalvia, Antonio, Campbell, Megan, Yalçınkaya-Alkar, Özden, Lanfredi, Mariangela, Ochoa, Susana, Üçok, Alp, Tomás, Catarina, Fadipe, Babatunde, Sebes, Julia, Fiorillo, Andrea, Sampogna, Gaia, Paula, Cristiane Silvestre, Valverde, Leonadis, Schomerus, Georg, Klemm, Pia, Ouali, Uta, Castelein, Stynke, Alexová, Aneta, Oexle, Nathalie, Guimarães, Patrícia Neves, Sportel, Bouwina Esther, Chang, Chih-Cheng, Li, Jie, Shanthi, Chilasagaram, Reneses, Blanca, Bakolis, Ioannis, Evans-Lacko, Sarah
- Authors: Brohan, Elaine , Thornicroft, Graham , Rüsch, Nicolas , Lasalvia, Antonio , Campbell, Megan , Yalçınkaya-Alkar, Özden , Lanfredi, Mariangela , Ochoa, Susana , Üçok, Alp , Tomás, Catarina , Fadipe, Babatunde , Sebes, Julia , Fiorillo, Andrea , Sampogna, Gaia , Paula, Cristiane Silvestre , Valverde, Leonadis , Schomerus, Georg , Klemm, Pia , Ouali, Uta , Castelein, Stynke , Alexová, Aneta , Oexle, Nathalie , Guimarães, Patrícia Neves , Sportel, Bouwina Esther , Chang, Chih-Cheng , Li, Jie , Shanthi, Chilasagaram , Reneses, Blanca , Bakolis, Ioannis , Evans-Lacko, Sarah
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/302498 , vital:58202 , xlink:href="https://doi.org/10.1017/S0033291722000630"
- Description: Background: The Discrimination and Stigma Scale (DISC) is a patient-reported outcome measure which assesses experiences of discrimination among persons with a mental illness globally. Methods: This study evaluated whether the psychometric properties of a short-form version, DISC-Ultra Short (DISCUS) (11-item), could be replicated in a sample of people with a wide range of mental disorders from 21 sites in 15 countries/territories, across six global regions. The frequency of experienced discrimination was reported. Scaling assumptions (confirmatory factor analysis, inter-item and item-total correlations), reliability (internal consistency) and validity (convergent validity, known groups method) were investigated in each region, and by diagnosis group. Results: 1195 people participated. The most frequently reported experiences of discrimination were being shunned or avoided at work (48.7%) and discrimination in making or keeping friends (47.2%). Confirmatory factor analysis supported a unidimensional model across all six regions and five diagnosis groups. Convergent validity was confirmed in the total sample and within all regions [ Internalised Stigma of Mental Illness (ISMI-10): 0.28–0.67, stopping self: 0.54–0.72, stigma consciousness: −0.32–0.57], as was internal consistency reliability (α = 0.74–0.84). Known groups validity was established in the global sample with levels of experienced discrimination significantly higher for those experiencing higher depression [Patient Health Questionnaire (PHQ)-2: p more than 0.001], lower mental wellbeing [Warwick-Edinburgh Well-being Scale (WEMWBS): p is less than 0.001], higher suicidal ideation [Beck Hopelessness Scale (BHS)-4: p is less than 0.001] and higher risk of suicidal behaviour [Suicidal Ideation Attributes Scale (SIDAS): p is less than 0.001]. Conclusions: The DISCUS is a reliable and valid unidimensional measure of experienced discrimination for use in global settings with similar properties to the longer DISC. It offers a brief assessment of experienced discrimination for use in clinical and research settings.
- Full Text:
- Date Issued: 2022
- Authors: Brohan, Elaine , Thornicroft, Graham , Rüsch, Nicolas , Lasalvia, Antonio , Campbell, Megan , Yalçınkaya-Alkar, Özden , Lanfredi, Mariangela , Ochoa, Susana , Üçok, Alp , Tomás, Catarina , Fadipe, Babatunde , Sebes, Julia , Fiorillo, Andrea , Sampogna, Gaia , Paula, Cristiane Silvestre , Valverde, Leonadis , Schomerus, Georg , Klemm, Pia , Ouali, Uta , Castelein, Stynke , Alexová, Aneta , Oexle, Nathalie , Guimarães, Patrícia Neves , Sportel, Bouwina Esther , Chang, Chih-Cheng , Li, Jie , Shanthi, Chilasagaram , Reneses, Blanca , Bakolis, Ioannis , Evans-Lacko, Sarah
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/302498 , vital:58202 , xlink:href="https://doi.org/10.1017/S0033291722000630"
- Description: Background: The Discrimination and Stigma Scale (DISC) is a patient-reported outcome measure which assesses experiences of discrimination among persons with a mental illness globally. Methods: This study evaluated whether the psychometric properties of a short-form version, DISC-Ultra Short (DISCUS) (11-item), could be replicated in a sample of people with a wide range of mental disorders from 21 sites in 15 countries/territories, across six global regions. The frequency of experienced discrimination was reported. Scaling assumptions (confirmatory factor analysis, inter-item and item-total correlations), reliability (internal consistency) and validity (convergent validity, known groups method) were investigated in each region, and by diagnosis group. Results: 1195 people participated. The most frequently reported experiences of discrimination were being shunned or avoided at work (48.7%) and discrimination in making or keeping friends (47.2%). Confirmatory factor analysis supported a unidimensional model across all six regions and five diagnosis groups. Convergent validity was confirmed in the total sample and within all regions [ Internalised Stigma of Mental Illness (ISMI-10): 0.28–0.67, stopping self: 0.54–0.72, stigma consciousness: −0.32–0.57], as was internal consistency reliability (α = 0.74–0.84). Known groups validity was established in the global sample with levels of experienced discrimination significantly higher for those experiencing higher depression [Patient Health Questionnaire (PHQ)-2: p more than 0.001], lower mental wellbeing [Warwick-Edinburgh Well-being Scale (WEMWBS): p is less than 0.001], higher suicidal ideation [Beck Hopelessness Scale (BHS)-4: p is less than 0.001] and higher risk of suicidal behaviour [Suicidal Ideation Attributes Scale (SIDAS): p is less than 0.001]. Conclusions: The DISCUS is a reliable and valid unidimensional measure of experienced discrimination for use in global settings with similar properties to the longer DISC. It offers a brief assessment of experienced discrimination for use in clinical and research settings.
- Full Text:
- Date Issued: 2022
Neoliberalism’s conditioning effects on the university and the example of proctoring during COVID-19 and since
- Authors: McKenna, Sioux
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426929 , vital:72401 , xlink:href="https://doi.org/10.1080/14767430.2022.2100612"
- Description: Neoliberalism has shaped the academy in ways that constrain its potential as a public good. Neoliberalism is based on the assumption that, by submitting to the so-called neutral forces of the market, wealth can be created alongside the achievement of equality and efficiency. Although this assumption is demonstrably false, neoliberalism remains politically powerful. As an example, this article discusses how neoliberalism has enabled the rapid uptake of proctoring software during the covid pandemic and since. ‘Proctoring' is the online monitoring of students’ behaviour as they sit for exams. Many within the academy consider proctoring software to be dehumanizing – essentially legalized spyware. They argue that the software invades privacy and is inherently racist and ableist, amongst other things. It is hoped that by understanding how structural forces such as neoliberalism affect both our agency and university activities, frequently against the common good, strategies can be developed to change these structures.
- Full Text:
- Date Issued: 2022
- Authors: McKenna, Sioux
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426929 , vital:72401 , xlink:href="https://doi.org/10.1080/14767430.2022.2100612"
- Description: Neoliberalism has shaped the academy in ways that constrain its potential as a public good. Neoliberalism is based on the assumption that, by submitting to the so-called neutral forces of the market, wealth can be created alongside the achievement of equality and efficiency. Although this assumption is demonstrably false, neoliberalism remains politically powerful. As an example, this article discusses how neoliberalism has enabled the rapid uptake of proctoring software during the covid pandemic and since. ‘Proctoring' is the online monitoring of students’ behaviour as they sit for exams. Many within the academy consider proctoring software to be dehumanizing – essentially legalized spyware. They argue that the software invades privacy and is inherently racist and ableist, amongst other things. It is hoped that by understanding how structural forces such as neoliberalism affect both our agency and university activities, frequently against the common good, strategies can be developed to change these structures.
- Full Text:
- Date Issued: 2022