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Supporting social learning and knowledge management withing the ecological infrastructure for water security project

The concurrent impacts of drought and leaf harvesting on two traditional African vegetable non-timber forest product species

  • Authors: Sinasson, Gisele K , Shackleton, Charlie M
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/399832 , vital:69562 , xlink:href="https://doi.org/10.1371/journal.pone.0283900"
  • Description: Investigating the concurrent impacts with harvesting on wild vegetables can guide their sustainable management while contributing to the understanding of such impacts on NTFP species. This study investigated leaf production, morphological and growth responses to the concurrent impacts of drought and leaf harvesting between two wild vegetables. A randomized greenhouse experiment was implemented with 1,334 plants of Amaranthus sp. and 391 of B. pilosa. A drought treatment was first implemented through six levels of drought stress and a control treatment. The harvesting treatment consisted of four harvesting levels and was implemented twice. Measurements were recorded before first and second harvests and at end of experiment. Data were separated into two periods (after first and second harvests) and analyzed using Multivariate Analysis of Variance and log-linear analysis. The results showed significant effects of drought on both species. However, Amaranthus sp. appeared more resilient to reduction in the daily amount of water than reduction in the frequency, while B. pilosa was resilient under both facets of drought stress. For Amaranthus sp., basal diameter, its growth, leaf production and survival increased with increase in the harvesting level (with some exceptions) after first harvest. After second harvest, there was decrease in plant height and leaf production. In B. pilosa, the impact was only significant on survival and leaf production (after first harvest). The effect of the interaction of the two drivers was significant for Amaranthus sp., but not for B. pilosa. The results also highlighted the possible negative impact of a prolonged high rate harvesting on the species performance, especially under severe drought. Basal diameter, its growth, survival and leaf production appeared more resilient to reduced amounts of watering in Amaranthus sp., and under both types of drought stress for B. pilosa. This suggests that both species could be sustained under medium drought stress.
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  • Date Issued: 2023

The importance of long-term post-release studies in classical biological control: Insect–plant monitoring and public awareness of water hyacinth management (Pontederia crassipes) in Dique Los Sauces, Argentina

  • Authors: Faltlhauser, Ana C , Jiménez, Nadia L , Righetti, Tomas , Visintin, Andrés M , Torrens, Javier , Salinas, Nicolás A , Mc Kay, Fernando , Hill, Martin P , Cordo, Hugo A , Sosa, Alejandro J
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/424828 , vital:72187 , xlink:href="https://doi.org/10.1111/eea.13355"
  • Description: Several components of classical biological control (CBC) programmes are necessary to assess the success of the management strategy (e.g., post-release monitoring) and also help prevent reintroductions or resurgences of invasive species (e.g., public awareness). Water hyacinth, Pontederia (= Eichhornia) crassipes (Mart.) Solms (Pontederiaceae) is an aquatic plant naturally distributed in the north-eastern region of the Del Plata basin in Argentina. In the 1960s it was introduced into the Dique Los Sauces reservoir located outside of its native range in La Rioja Province, in western Argentina, where it became invasive. The natural enemy, Neochetina bruchi Hustache (Coleoptera: Curculionidae), was intentionally introduced in 1974 to control the weed. To assess the success of this CBC programme, a long-term post-release study was conducted. Between 1965 and 2023, we monitored plant coverage, estimated N. bruchi densities, and quantified the associated damage by reanalysing previously published data and incorporating new sampling. We also conducted an online survey to analyse public knowledge and perception about this programme. Water hyacinth coverage fluctuated from its first record in 1965 (maximum coverage 90%) until the control of germinated plants (coverage 0%) in 2018. The plant decline was accompanied by an increase in the weevil population. In our survey, out of 325 respondents only a small group of mostly middle-aged and elderly people knew that the restoration had been achieved through a management strategy and even fewer were aware of the biocontrol approach taken. Respondents who had a positive approach to biological control were more aware of the management plan than respondents who had neutral or negative opinions. Neochetina bruchi has played a key factor in the control of P. crassipes. The intrinsic dynamics of these populations, the dormant seed bank, and the lack of public awareness support the need for long post-release evaluations including outreach campaigns to make a sustainable successful management programme.
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  • Date Issued: 2023

The in-vitro proliferation-suppression of MCF-7 and HeLa cell lines mediated by differently substituted ionic phthalocyanines in sonodynamic therapy supplemented-photodynamic therapy

  • Authors: Nene, Lindokuhle Cindy , Nyokong, Tebello
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/360461 , vital:65090 , xlink:href="https://doi.org/10.1016/j.jinorgbio.2022.112084"
  • Description: This work focuses on the study of the effects of the ultrasonic frequency (MHz) and power (W.cm−2) on the stability, reactive oxygen species yields and cytotoxicity activities of differently substituted ionic phthalocyanines (Pcs) in sonodynamic therapy (SDT). Four ultrasonic parameters were investigated: Par I (1 MHz: 1 W.cm−2), Par II (1 MHz: 2 W.cm−2), Par III (3 MHz: 1 W.cm−2) and Par IV (3 MHz: 2 W.cm−2). A higher degradation of the Pcs was observed with increasing power at the Par II. Two reactive oxygen species (ROS) were detected in the ultrasound treated Pcs: singlet oxygen and hydroxyl radicals. Due to minimal degradation of most Pcs, Par I was chosen for SDT, photodynamic therapy (PDT), and photo-sonodynamic therapy (PSDT) against Michigan Cancer Foundation-7 and Henrietta Lacks cancer cell lines. PSDT generally showed improved therapeutic efficacies of the Pcs compared to the SDT and PDT mono treatments.
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  • Date Issued: 2023

The prevalence, uses and cultural assimilation of shrub and tree invasive alien plants in a biodiversity hotspot along the Wild Coast, South Africa

  • Authors: Wootton, Oscar , Shackleton, Charlie M
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/401314 , vital:69725 , xlink:href="https://doi.org/10.1080/26395916.2023.2216804"
  • Description: Invasive alien plant species (IAPS) frequently offer both ecosystem services and disservices to rural communities with high livelihood dependency on local landscapes. However, biocultural relationships with IAPS may go deeper than just provisioning uses, as they may be assimilated into local belief systems manifest in them becoming embedded in cultural constructions such as naming, stories, songs and ceremonies. It is likely that IAPS that are culturally assimilated will represent a greater conflict of interest in the face of proposed controls of IAPS in biodiversity hotspots where conservation priorities are frequently deemed paramount by external agencies. Using a mixed-methods approach we undertook roadside surveys of 17 selected IAPS along the 250 km Wild Coast section of the Maputaland-Pondoland-Albany biodiversity hotspot, accompanied by questionnaire interviews with 48 local people. The mean number of IAPS per site was four, ranging from zero (only one site) to ten, and local inhabitants deemed the abundance of all but one of the species to be increasing. All species had been in the region for decades, had a vernacular name, and all but one had direct consumptive uses. Species with multiple uses were more widely recognised. However, there was only marginal incorporation of the IAPS into stories, songs and ceremonies, although medicinal uses of some IAPS were for cultural/spiritual needs rather than physical ailments per se. These results show that despite widespread use, there was as yet relatively limited cultural assimilation of the IAPS in the Wild Coast region.
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  • Date Issued: 2023

The Role of the University as Mediator in a Skills Ecosystem Approach to VET

  • Authors: Lotz-Sisitka, Heila , Openjuru, George , Zeelen, Jacques
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book chapter
  • Identifier: http://hdl.handle.net/10962/434907 , vital:73115 , ISBN 978-1529224634 , https://bristoluniversitypress.co.uk/transitioning-vocational-education-and-training-in-africa
  • Description: In this chapter, we focus particularly on the mediating role of the university, in close connection with vocational institutions and informal community actors, in developing an inclusive approach to vocational education and training (VET) through an expanded social ecosystem for skills model. Here we draw upon lessons learnt from the Alice and Gulu cases on communitybased approaches to establishing an expanded skills ecosystem approach to VET in Africa. The main ques-tion guiding this chapter relates to the possible mediating role of the university to enhance a regional expanded ecosystem for supporting quality vocational education that is also rele-vant to its context, including emergent possibilities to build skills and livelihoods linked to just transitions. Universities are not VET centres as conventionally understood, but they can contribute to VET in various ways. Most often, universities are identified as contributing to the qualifications and training of VET educators. In this chapter, we take a different angle and consider the role of engaged research and community engagement as two approaches that can contribute to the advancement of an expanded social ecosystem model with positive benefits for VET institutions. Drawing on insights gained in the earlier chapters of this book requires us to take into account several important realities as previously dis-cussed, as well as key ingredients for the development of a regional skills ecosystem of vocational education, as demon-strated by the two cases considered in this chapter.
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  • Date Issued: 2023

The Southern African Program on Ecosystem Change and Society: an emergent community of practice

Tragic Optimism: A Psychobiography of Morgan Richard Tsvangirai.

  • Authors: Harry, Tinashe T , van Niekerk, Roelf
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book chapter
  • Identifier: http://hdl.handle.net/10962/434439 , vital:73060 , ISBN 978-3-031-28826-5 , https://link.springer.com/chapter/10.1007/978-3-031-28827-2_5
  • Description: For many Zimbabweans, Morgan Richard Tsvangirai (1952–2018) became the face of courage and hope during his political career. Tsvangirai was subjected to and witnessed political violence, physical abuse, brutality, emotional humiliation, unlawful detentions, and persecution. He challenged the ruling party in Zimbabwe, and his leadership gave many people hope for the future. In the context of living in a colonial era, poverty, and having to endure the brutality of the Mugabe era, he lived a meaningful life that saw him becoming a Prime Minister of Zimbabwe (2009–2013). This single-case study explores and describes Tsvangirai’s life and interprets it in terms of Frankl’s existential theory. More specifically, Tsvangirai’s life is interpreted from the perspective of Frankl’s three triads, the fundamental, meaning, and tragic triads, as well as the noetic dimension. Tsvangirai was selected through purposive sampling based on his important role in Zimbabwean politics. The primary source of data was biographical and autobiographical publications. The findings indicate that Tsvangirai shifted emphasis within the meaning triad in living a meaningful life and that he was able to use the human capacity of self-distancing/detachment and self-transcendence to find meaning in his life. This chapter sheds light on how individuals make sense of their circumstances and search for meaning and purpose in adverse conditions. It also contributes towards the development of psychobiographical research among non-WEIRD samples.
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  • Date Issued: 2023

Transboundary Fisheries Management in Kavango–Zambezi Transfrontier Conservation Area (KAZA-TFCA): Prospects and Dilemmas

  • Authors: Imbwae, Imikendu , Aswani, Shankar , Sauer, Warwick H H , Hay, Clinton
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/391433 , vital:68651 , xlink:href="https://doi.org/10.3390/su15054406"
  • Description: Inland fisheries in the Kavango–Zambezi Transfrontier Conservation Area (KAZA-TFCA) offer food security to the riverine communities across the region. They also contribute towards the attainment of the United Nations’ Sustainable Development Goals 1 and 15, which aim to alleviate poverty and maintain biodiversity conservation. Despite this significant role, the fisheries have suffered severe declines in the previous decades due to multiple factors, such as overfishing and poor legislation. Furthermore, climate change is exerting pressure by altering the ecology and productivity of the river systems. The unprecedented challenges of the COVID-19 pandemic have further constrained management efforts. Attempts to address these challenges have pointed towards transboundary fisheries management as a silver bullet in moving towards sustainable fisheries management. However, the implementation of this strategy in the region has encountered numerous roadblocks, thereby subjecting the river ecosystem to a wider environmental threat, with dire consequences on livelihoods. This paper reviews existing management and governance structures together with key informant interviews to elicit primary and secondary data essential for management at the regional level. The study identifies conflicting regulations, and inadequate policies and institutions across the region as major bottlenecks affecting the successful implementation of transboundary fisheries management. Finally, the paper offers some suggestions for the improvement of fisheries management in the region.
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  • Date Issued: 2023

TVET SI: Evaluating Boundary Crossing Social Learning in Vocational Education and Training: A value creation approach

  • Authors: Lotz-Sisitka, Heila , Sisitka, Lawrence , Chakona, Gamuchirai , Matiwane, Mandilive L , Matambo, Chamu
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/389925 , vital:68495 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/238540"
  • Description: This article focuses on the development and application of an evaluation model and approach for evaluating boundary crossing social learning in a Vocational Education and Training (VET) learning network in South Africa, with an emphasis on a Training of Trainers (ToT) course that helped to catalyse and strengthen this learning network via two iterations of the course over an eight-year period. The article shares how we adapted the value creation framework (VCF) of Wenger, Traynor and De Laat (2011; Wenger and Wenger-Traynor, 2020) in the evaluation of a VET Training of Trainers (ToT) programme and learning network that focussed on the uptake and circulation of rainwater harvesting and conservation (RWHandC) knowledge in a particular formal and informal VET context in the Eastern Cape, South Africa, where smallholder farmers were struggling to find water for producing food. The evaluated ToT course was catalytic in establishing a boundary crossing social learning network approach in a VET context that linked formal and informal VET (Lotz-Sisitka et al., 2016; Lotz-Sisitka et al., 2022; Pesanayi, 2019); hence we found it important to develop adequate tools for its evaluation. The focus of this article is to share how we developed an evaluation approach to this work. We share insights on the indicators developed for diff erent types of value created, and also insights gained into the use of this evaluation approach in a boundary crossing VET social learning project that took a ToT course as focus. In short, evaluation findings show that the boundary crossing ToT course off ers strong immediate, potential and applied value that can lead to realised and reframed value, especially if supported by ongoing learning network activities that follow the initial engagement in the boundary crossing ToT course. Th is leads, over time, to transformative value which is important in achieving the overall objective of such social learning, namely making knowledge more co-engaging, accessible and useful in the context where improved food security via better use of rainwater harvesting and conservation amongst smallholder farmers and household food producers is a necessary form of sustainable development. Orientation value, and enabling value were found to be vital for the emergence of other kinds of value. The evaluation model also allows for the lifting out of strategic value which points to wider uptake potential. All this creates the possibility for indicator development that can help inform iterative development of boundary crossing VET courses used to stimulate the co-construction of learning networks and ongoing social learning for sustainable development.
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  • Date Issued: 2023

Understanding foraging practices in Lagos metropolis to redesign urban greenspaces in support of human-nature interactions

  • Authors: Adeyemi, Opeyemi , Shackleton, Charlie M
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/401353 , vital:69728 , xlink:href="https://doi.org/10.1016/j.ufug.2022.127805"
  • Description: Enhancing knowledge of urban foraging across different urban landscapes is an urgent matter given that about two-thirds of the world’s population is projected to live in urban areas by 2050, whilst 50 % of Africa’s population is expected to live in cities by 2030. This study was conducted in Lagos metropolis which is the economic hub of Africa’s most populous country. Data was collected using an in-person, semi-structured questionnaire from 347 persons who were 18 years or older to identify foragers and non-foragers, their sociodemographic profiles, and their foraging practices. Results revealed that about two out of three persons sampled forage to some degree. The collection happened more in domestic gardens (34 %) and streets (27 %) than in other foraging sites (such as unused lands, institutional grounds and lakes and riparian fringes). A total of 35 species were reportedly foraged within the metropolis, mostly for food (71 %) and medicine (26 %). Mango (Mangifera indica), pawpaw (Carica papaya), tropical almond (Terminalia catappa), fish (various species), bitter leaf (Vernonia amygdalina) and spinach (Spinacia oleracea) were the most gathered species. The distance travelled to foraging wild species ranged from 5 m to 25 km. The primary motivation for foraging was the acquisition of fresh and natural materials. However, some felt that foraging was a stressful activity. The unavailability of foraging sites and species was the major constraint to foraging in this megacity. Hence, efforts to increase the edible components of public green spaces and to provide free access could potentially allow more people to forage and make current foraging more secure. We suggest that making provisions for foraging in urban planning goals could contribute to the sustainable development of cities in Africa and elsewhere.
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  • Date Issued: 2023

Using Citizen Science to Protect Natural Untreated Drinking Water Sources: Natural Springs in Rural Catchments and B3 Municipalities in the Eastern Cape

  • Authors: Mtati, Nosi , Chetty, Preven , Norman, Yondela , Mvulane, Paulose , Libala, Notiswa , Weaver, Matthew J , Wolff, Margaret M , Cockburn, Jessica J , Mazibuko, Thembalani
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book
  • Identifier: http://hdl.handle.net/10962/425732 , vital:72279 , ISBN 978-0-6392-0550-2 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/3097%20final.pdf
  • Description: Citizen science is a well-known mechanism used by researchers to col-lect scientific data working together with citizens. It can also be used by interested and concerned citizens (social activists regarding environ-mental threats) to protect natural occurring things like biodiversity, rare species that are threatened extension and much more. It can be a natu-ral occurring process that evolves with time but it can also have some guidelines of how to monitor, collect, analyse and disseminate data. In this project we used participatory action research processes to co-develop tools (co-create being one of the types of citizen science) with local communities, using their knowledge of their area to monitor and protect natural springs. Springs are useful for providing drinking water for people but also for livestock. In rural areas and small towns where service delivery is not reliable, natural occurring water sources become the reliable supply for these communities. Springs also provide ecosys-tem services as they are a keystone ecological infrastructure. These natural water sources can be threatened by pollution, especially that of livestock which is mostly unattended, because they are sometimes shared by people and animals. This poses health risks to the users. This study co-developed the “spring protection and sustainable use” tool/s that can be used to guide communities and local government on how to protect these important water sources. Citizen science also cre-ates opportunities for learning to take place among the participants as well as the researchers involved.
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  • Date Issued: 2023

Water, Transport, Oil and Food: A Political–Economy–Ecology Lens on Changing Conceptions of Work, Learning and Skills Development in Africa

  • Authors: Lotz-Sisitka, Heila
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , book chapter
  • Identifier: http://hdl.handle.net/10962/434894 , vital:73114 , ISBN 978-1529224634 , https://bristoluniversitypress.co.uk/transitioning-vocational-education-and-training-in-africa
  • Description: Not enough has been said about the kinds of skills develop-ment that are needed if we are to stem the rising tides and impacts of political economies that have been driving what some call ‘fossil capital’(Malm, 2016). In this book, we are producing an emerging argument that it is necessary to also rethink and reframe vocational education and training (VET) logics and approaches if we are to fully consider the implica-tions of a warming future. This chapter provides the context of why this is such an urgent challenge and some thinking tools for understanding where we have come from and where we need to go. The prognosis is that it is now almost impossible to stop global warming below 2oC. The 2021 In-tergovernmental Panel on Climate Change (IPCC) report is-sued a ‘red alert’for humanity, noting climate change to be one of the most severe challenges facing human societies for decades and potentially centuries to come. Scientists are warning that we have entered a new ‘geological epoch’, named the ‘Anthropocene’, in which human activity, especial-ly the release of carbon dioxide into the atmosphere through fossil-based pollution, is transforming the stability of the earth system and creating knock on effects such as ice melt and methane release, which exacerbate the impacts of pollutants on the stability of the earth system.
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  • Date Issued: 2023

Women farmers leading and co-learning in an agroecology movement at the intersections of gender and climate

  • Authors: Chanyau, Ludwig , Rosenberg, Eureta
  • Date: 2023
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/373873 , vital:66730 , xlink:href="https://doi.org/10.1080/10130950.2023.2239313"
  • Description: This study, carried out in the Eastern Cape Province of South Africa, was particularly interested in women farmers’ access to social learning spaces for expanding their knowledge about farming in the context of climate change. Small-scale women and peasant farmers face historical intersectional inequalities as a result of the colonial and apartheid past which has continued to disadvantage women in the present through exclusion, limited or no access to finance, insecure or no land tenure, little bargaining power and unequal access to water. The gender prejudices and unequal access to resources experienced by women is brought into sharp relief by climate change. The article provides a case study of an agroecology movement led by women farmers that promotes climate-appropriate, low-cost farming practices using community and home gardens. The practices are tried out and further developed by women farmers themselves, relying on agroecology-informed extension services, open dialogue and the support of communities of practice. Unlike traditional top-down approaches to farmer learning common in public extension services, extension officers in the movement participate in creating conditions for co-learning and co-construction of new knowledge − that is, social learning − thus responding directly to their needs as farmers. The lead researcher joined in and observed farming and learning activities following an ethnographic approach. Farmers and other movement members were engaged in semi-structured interviews which explored the value derived from social learning (Wenger-Trayner and Wenger-Trayner Citation2020). The article concludes that the movement is responding to many of the intersectional challenges that women farmers in the Eastern Cape face. Further, its social learning approach holds potential for expanding women farmers’ ability to provide for themselves and their communities and inform their climate change adaptation.
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  • Date Issued: 2023

A Change Project story: learning and caring for South Africa’s rivers

  • Authors: Chetty, Preven
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/391060 , vital:68613 , xlink:href="https://eeasa.org.za/wp-content/uploads/2023/02/Final-EEASA-Bulletin-20212022-Final.pdf"
  • Description: Water quality and scarcity is a major concern in Southern Africa and globally especially as the threat of climate change looms even closer. The current drought in South Africa and worsening rainfall has exposed the brittle nature of this country’s resilience to water shortages. Compounded to this is the fact that most rivers in South Africa are not adequately cared for and are under tremendous strain. Everyone who depends on these rivers whether directly or indirectly will soon be entering a new era where water will no longer be a ubiquitous commodity.
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  • Date Issued: 2022

A laminated, emergentist view of skills ecosystems

  • Authors: Ramsarup, Presha , Lotz-Sisitka, Heila , McGrath, Simon
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/370074 , vital:66295 , xlink:href="https://doi.org/10.1080/14767430.2022.2145768"
  • Description: In this paper we present a model of vocational education and training (VET) that can be used to guide decisions relating to VET in Africa today. This model takes the critique of the neoclassical, neoliberal model of VET as its starting point. Guided by Bhaskar's Critical Naturalism, we use immanent critique to consider the adequacy of proposed alternatives to the neoclassical approach, such as: the heterodox approach, which foregrounds explanations based on human capital and political economy; and Hodgson and Spours' social ecosystem model, which addresses some of the limitations of the heterodox account by including, social and ecosystem elements. Finally, we offer a version of the social ecosystem model that, according to our analysis, explains more of the empirical evidence than previous models. Our version of the social ecosystem model differs from earlier versions in terms of its explicit reference to the critical realist ideas of position- practices and emergence.
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  • Date Issued: 2022

A simple quinoline-thiophene Schiff base turn-off chemosensor for Hg2+ detection

  • Authors: Musikavanhu, Brian , Muthusamy, Selvaraj , Zhu, Dongwei , Xue, Zhaoli , Yu, Qian , Chivumba, Choonzo N , Mack, John , Nyokong, Tebello , Wang, Shengjun , Zhao, Long
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/230362 , vital:49771 , xlink:href="https://doi.org/10.1016/j.saa.2021.120338"
  • Description: A new Schiff base probe (QT) consisting of 8-aminoquinoline (Q) and thiophene-2-carboxaldehyde (T) moieties has been synthesized. QT undergoes chelation-enhanced fluorescence quenching when exposed to Hg2+ due to coordination by the sulfur and nitrogen atoms of QT thus forming a facile “turn-off” sensor. The formation of the chelation complex was confirmed by UV–visible absorption and emission spectral measurements, 1H NMR titration and density functional theory calculations. These studies revealed that the probe exhibits high selectivity and sensitivity towards Hg2+ in the presence of other common metal ions. A low detection limit of 23.4 nM was determined and a Job plot confirmed a 2:1 stoichiometry between QT and Hg2+. The potential utility of QT as a sensor for Hg2+ ions in human HeLa cells was determined by confocal fluorescence microscopy, and its suitability for use in the field with environmental samples was tested with Whatman filter paper strips.
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  • Date Issued: 2022

A Sn (iv) porphyrin with mitochondria targeting properties for enhanced photodynamic activity against MCF-7 cells

  • Authors: Babu, Balaji , Mack, John , Nyokong, Tebello
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/230897 , vital:49829 , xlink:href="https://doi.org/10.1039/D2NJ00350C"
  • Description: Two readily synthesized Sn(IV) porphyrins (SnP, SnPH) have been prepared with and without the cationic triphenylphosphonium moiety (TPP+), which have high singlet oxygen quantum yields (ca. 0.72) and long triplet state lifetimes. The Sn(IV) porphyrin with a TPP+ moiety (SnPH) exhibits favorable photodynamic activity against MCF-7 cells with IC50 values of 2.9 μM. SnPH exhibits higher cellular uptake than SnP in MCF-7 cells. A Rhodamine 123 (Rh123) assay showed that SnPH targets mitochondria and induces apoptosis by generating reactive oxygen species. The results demonstrate that this structural modification strategy merits further in-depth study.
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  • Date Issued: 2022

Alignment, scaling and resourcing of citizen-based water quality monitoring Initiatives

  • Authors: Lotz-Sisitka, Heila , Ward, Mike , Taylor, Jim , Vallabh, Priya , Madiba, Morakane , Graham, P Mark , Louw, Adrienne J , Brownell, Faye
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , report
  • Identifier: http://hdl.handle.net/10962/435729 , vital:73195 , ISBN 978-0-6392-0344-7 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/2854%20final.pdf
  • Description: This action-oriented research project seeks to address the policy-practice contradiction that exists between commit-ments and requirements for citizen engagement and in-volvement in Integrated Water Quality Management (IWQM) and a lack of sustainable support for scaling high quality Citi-zen-based Water Quality Monitoring (CBWQM) practices that exist in South Africa.
  • Full Text:
  • Date Issued: 2022

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