Orthographic knowledge in isiXhosa and its relation to phonological processing, letter-sound knowledge, reading and spelling
- Authors: Daries, Mikaela Ann
- Date: 2022-10-14
- Subjects: Xhosa language Orthography and spelling , Phonological awareness , Psycholinguistics , Oral reading Usage , Literacy South Africa , Reading Phonetic method
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/406703 , vital:70300
- Description: Despite international research confirming its importance, writing and related metalinguistic skills have often been neglected in comparison to reading in literacy research (Cunningham et al., 2001; Castles & Coltheart, 2004; Nag, 2007; Roman et al., 2009; Zhao et al., 2017). On a national level there are very few studies that have explored the writing aspect of literacy in South Africa, and none that has investigated orthographic knowledge in a Southern Bantu language, such as isiXhosa. In an attempt to address this gap, this thesis explores orthographic knowledge and its components in isiXhosa. In particular, it seeks to investigate the unique predictors of word specific and general orthographic knowledge as well as their role for reading and spelling in isiXhosa while controlling for phonological awareness (PA), rapid automatized naming (RAN), and letter-sound knowledge. Furthermore, the thesis attempts to situate its findings within the main premises of the self-teaching hypothesis and dual route approach to orthographic processing in order to contribute to linguistic theories of reading with cross-linguistic evidence (Jorm & Share, 1983; Share & Jorm, 1987; Share, 1995; Grainger & Ziegler, 2011). A quantitative cross-sectional study was conducted with 140 isiXhosa home language third grade learners in which word specific and general orthographic knowledge tasks were specifically designed. These tasks were administered along with oral reading fluency (ORF), spelling, PA, RAN, and letter-sound knowledge. The findings revealed that letter-sound knowledge and PA contributed the largest variance towards both word specific and general orthographic knowledge. Further, word specific orthographic knowledge and letter-sound knowledge were the only significant predictors of spelling. Similarly, both word specific and letter-sound knowledge were significant predictors of reading, along with RAN and general orthographic knowledge. Quantile linear regression analyses revealed that word specific orthographic knowledge was a robust predictor of spelling and letter-sound knowledge was a robust predictor of reading across ability levels confirming the importance for word specific orthographic knowledge for spelling and letter-sound knowledge for reading in isiXhosa. In relation to the two reading theories considered in this thesis, the findings reflect similarities between the assertions of the self-teaching hypothesis and current thesis with suggestions made for further inquiry. The dual route approach to orthographic processing provides insights into the potential processing of orthographic information while reading in isiXhosa. The findings of this study confirm the importance of orthographic knowledge for reading and spelling for languages with transparent orthographies such as isiXhosa. , Thesis (MA) -- Faculty of Humanities, Linguistics and Applied Language Studies, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Daries, Mikaela Ann
- Date: 2022-10-14
- Subjects: Xhosa language Orthography and spelling , Phonological awareness , Psycholinguistics , Oral reading Usage , Literacy South Africa , Reading Phonetic method
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/406703 , vital:70300
- Description: Despite international research confirming its importance, writing and related metalinguistic skills have often been neglected in comparison to reading in literacy research (Cunningham et al., 2001; Castles & Coltheart, 2004; Nag, 2007; Roman et al., 2009; Zhao et al., 2017). On a national level there are very few studies that have explored the writing aspect of literacy in South Africa, and none that has investigated orthographic knowledge in a Southern Bantu language, such as isiXhosa. In an attempt to address this gap, this thesis explores orthographic knowledge and its components in isiXhosa. In particular, it seeks to investigate the unique predictors of word specific and general orthographic knowledge as well as their role for reading and spelling in isiXhosa while controlling for phonological awareness (PA), rapid automatized naming (RAN), and letter-sound knowledge. Furthermore, the thesis attempts to situate its findings within the main premises of the self-teaching hypothesis and dual route approach to orthographic processing in order to contribute to linguistic theories of reading with cross-linguistic evidence (Jorm & Share, 1983; Share & Jorm, 1987; Share, 1995; Grainger & Ziegler, 2011). A quantitative cross-sectional study was conducted with 140 isiXhosa home language third grade learners in which word specific and general orthographic knowledge tasks were specifically designed. These tasks were administered along with oral reading fluency (ORF), spelling, PA, RAN, and letter-sound knowledge. The findings revealed that letter-sound knowledge and PA contributed the largest variance towards both word specific and general orthographic knowledge. Further, word specific orthographic knowledge and letter-sound knowledge were the only significant predictors of spelling. Similarly, both word specific and letter-sound knowledge were significant predictors of reading, along with RAN and general orthographic knowledge. Quantile linear regression analyses revealed that word specific orthographic knowledge was a robust predictor of spelling and letter-sound knowledge was a robust predictor of reading across ability levels confirming the importance for word specific orthographic knowledge for spelling and letter-sound knowledge for reading in isiXhosa. In relation to the two reading theories considered in this thesis, the findings reflect similarities between the assertions of the self-teaching hypothesis and current thesis with suggestions made for further inquiry. The dual route approach to orthographic processing provides insights into the potential processing of orthographic information while reading in isiXhosa. The findings of this study confirm the importance of orthographic knowledge for reading and spelling for languages with transparent orthographies such as isiXhosa. , Thesis (MA) -- Faculty of Humanities, Linguistics and Applied Language Studies, 2022
- Full Text:
- Date Issued: 2022-10-14
Oversight mechanisms and service delivery: a case study of municipal public accounts committee oversight of electricity services in Raymond Mhlaba Local Municipality
- Authors: Mpofu, Sibabalwe
- Date: 2022-10-14
- Subjects: Municipal services South Africa , Local government South Africa , Local service delivery , Public sector , Oversight , Economics Sociological aspects , Government accountability South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/408671 , vital:70515
- Description: Over the last few years, there has been a notable increase in popularity in the use of cannabidiol (CBD) as a form of alternative medicinal treatment for various illnesses. CBD, a by-product of the cannabis plant, is an isolate and does not contain the psychoactive agent, tetrahydrocannabinol (THC). Endometriosis and Polycystic Ovarian Syndrome (PCOS) are chronic reproductive health sicknesses that are increasingly experienced by women. In the absence of cures, biomedical treatment for these diseases aim to manage symptoms, for example; heavy bleeding, heightened levels of pain, and insomnia. CBD offers an alternative to women who feel that biomedical interventions are no longer able to maintain their health and well-being. CBD positions itself as a natural remedy claiming to be safe and effective. This research study, mainly through qualitative data collection, focused on experiences of Zimbabwean and South African women living with endometriosis and/ or PCOS, who have turned to CBD to manage their symptoms. The importance of this study was to position itself within patients’ lived experiences. The research study found that CBD indeed has numerous benefits, including pain management, alleviating stress, and anxiety. Through the emergent themes from the data, it became clear that women are marginalised and treated unequally in the biomedical healthcare sphere. Feminist Anthropology and Structural Violence was applied to analyse the data collected to explore the patriarchal nature of the biomedical healthcare system and the experiences that women have, which has led them to turn to alternative treatments. , Thesis (MSocSci) -- Faculty of Humanities, Sociology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Mpofu, Sibabalwe
- Date: 2022-10-14
- Subjects: Municipal services South Africa , Local government South Africa , Local service delivery , Public sector , Oversight , Economics Sociological aspects , Government accountability South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/408671 , vital:70515
- Description: Over the last few years, there has been a notable increase in popularity in the use of cannabidiol (CBD) as a form of alternative medicinal treatment for various illnesses. CBD, a by-product of the cannabis plant, is an isolate and does not contain the psychoactive agent, tetrahydrocannabinol (THC). Endometriosis and Polycystic Ovarian Syndrome (PCOS) are chronic reproductive health sicknesses that are increasingly experienced by women. In the absence of cures, biomedical treatment for these diseases aim to manage symptoms, for example; heavy bleeding, heightened levels of pain, and insomnia. CBD offers an alternative to women who feel that biomedical interventions are no longer able to maintain their health and well-being. CBD positions itself as a natural remedy claiming to be safe and effective. This research study, mainly through qualitative data collection, focused on experiences of Zimbabwean and South African women living with endometriosis and/ or PCOS, who have turned to CBD to manage their symptoms. The importance of this study was to position itself within patients’ lived experiences. The research study found that CBD indeed has numerous benefits, including pain management, alleviating stress, and anxiety. Through the emergent themes from the data, it became clear that women are marginalised and treated unequally in the biomedical healthcare sphere. Feminist Anthropology and Structural Violence was applied to analyse the data collected to explore the patriarchal nature of the biomedical healthcare system and the experiences that women have, which has led them to turn to alternative treatments. , Thesis (MSocSci) -- Faculty of Humanities, Sociology, 2022
- Full Text:
- Date Issued: 2022-10-14
Photodynamic anticancer and antimicrobial activities of π-extended BODIPY dyes and cationic mitochondria-targeted porphyrins
- Authors: Chiyumba, Choonzo Nachoobe
- Date: 2022-10-14
- Subjects: Dyes and dyeing Chemistry , Mitochondria , Cancer Chemotherapy , Porphyrins , Molecules Models , Photochemotherapy
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362785 , vital:65362
- Description: Cancer is among the most devastating diseases and is mainly caused by gene mutation. This could be hereditary, or the mutation could be stimulated due to a lifestyle one lives, such as smoking, which induces lung cancer. The high morbidity rates of cancer are attributed to it being metastatic. The relatively poor physicochemical properties of existing drugs have caused treatment to be ineffective. Photofrin®, Foscan®, and Photogem® are some of the porphyrin-based derivatives approved by the Food and Drug Administration (FDA) for use in photodynamic therapy (PDT). Despite having such drugs, the quest to find better cancer drugs is still ongoing and 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes are among the molecules that are being studied as potential photosensitisers (PS) in PDT. However, these molecules suffer from poor solubility and ineffective generation of singlet oxygen, the main ingredient in PDT treatment. Furthermore, photosensitisers used in PDT face a problem with hypoxic conditions associated with cancer cells, which causes the generation of singlet oxygen to be relatively low. The PS also suffer from the untargeted treatment, increasing their toxicity. Therefore, the main aim of this study was to improve the bioavailability of BODIPY dyes. Thus, a series of BODPIY dyes were synthesised with hydrogen bond accepting atoms and heavy atoms that enhance singlet oxygen generation. Additionally, to override hypoxia conditions, porphyrins with mitochondria targeting properties were synthesised since it has been well established that the mitochondria will always have a decent amount of oxygen in cancerous cells. When employed as PS in PDT studies, these molecules have better cytotoxic abilities than BODIPY dyes, and this potency was credited to their mitochondria targeting ability and efficient singlet oxygen generation. Finally, this study reports the synthesis of di- and mono-substituted BODIPY dyes with improved solubility and porphyrins substituted with triphenyl phosphine, a mitochondria targeting moiety. On the other hand, the work further illustrates the synthesis of β-substituted cationic porphyrin with mitochondria targeting properties. , Thesis (MSc) -- Faculty of Science, Chemistry, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Chiyumba, Choonzo Nachoobe
- Date: 2022-10-14
- Subjects: Dyes and dyeing Chemistry , Mitochondria , Cancer Chemotherapy , Porphyrins , Molecules Models , Photochemotherapy
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362785 , vital:65362
- Description: Cancer is among the most devastating diseases and is mainly caused by gene mutation. This could be hereditary, or the mutation could be stimulated due to a lifestyle one lives, such as smoking, which induces lung cancer. The high morbidity rates of cancer are attributed to it being metastatic. The relatively poor physicochemical properties of existing drugs have caused treatment to be ineffective. Photofrin®, Foscan®, and Photogem® are some of the porphyrin-based derivatives approved by the Food and Drug Administration (FDA) for use in photodynamic therapy (PDT). Despite having such drugs, the quest to find better cancer drugs is still ongoing and 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes are among the molecules that are being studied as potential photosensitisers (PS) in PDT. However, these molecules suffer from poor solubility and ineffective generation of singlet oxygen, the main ingredient in PDT treatment. Furthermore, photosensitisers used in PDT face a problem with hypoxic conditions associated with cancer cells, which causes the generation of singlet oxygen to be relatively low. The PS also suffer from the untargeted treatment, increasing their toxicity. Therefore, the main aim of this study was to improve the bioavailability of BODIPY dyes. Thus, a series of BODPIY dyes were synthesised with hydrogen bond accepting atoms and heavy atoms that enhance singlet oxygen generation. Additionally, to override hypoxia conditions, porphyrins with mitochondria targeting properties were synthesised since it has been well established that the mitochondria will always have a decent amount of oxygen in cancerous cells. When employed as PS in PDT studies, these molecules have better cytotoxic abilities than BODIPY dyes, and this potency was credited to their mitochondria targeting ability and efficient singlet oxygen generation. Finally, this study reports the synthesis of di- and mono-substituted BODIPY dyes with improved solubility and porphyrins substituted with triphenyl phosphine, a mitochondria targeting moiety. On the other hand, the work further illustrates the synthesis of β-substituted cationic porphyrin with mitochondria targeting properties. , Thesis (MSc) -- Faculty of Science, Chemistry, 2022
- Full Text:
- Date Issued: 2022-10-14
Poems caught in dreams
- Jafta, Nthabiseng Rose JahRose
- Authors: Jafta, Nthabiseng Rose JahRose
- Date: 2022-10-14
- Subjects: Creative writing (Higher education) South Africa , South African poetry (English) 21st century
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/406249 , vital:70252
- Description: My thesis is a collection of Lyrical and Prose Poetry. I am strongly influenced by Marina Tsvetaeva’s observation that “The condition of creation is a condition of dreaming.” As a writer I want to contribute to human knowledge by drawing from a wide literary ancestry, participating in a community of distinct voices and styles to capture and preserve the language of dreams. I fuse inherited knowledge, visions, dreams, my own experiences and what I have discovered through listening to music, reading and my own experiments in exploring poetry in dreams, thoughts and lived experiences. I am inspired by Sindiwe Magona, how she chose to express her spirituality and personal narratives into her work, and Aimé Césaire’s vision “The ground of poetic knowledge, [is] an astonishing mobilization of all human and cosmic forces.” I particularly enjoy intense forms of expression that hold substance and provoke one to elevate in knowledge and in writing. Exploring these combination of forces from these writers affords me an opportunity to write my dreams as reality. Exploring the characters, the different scenes, symbols and colours as poems flashing super/naturally yet leave one with fathomable felt, though sometimes hazy interpretations. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Jafta, Nthabiseng Rose JahRose
- Date: 2022-10-14
- Subjects: Creative writing (Higher education) South Africa , South African poetry (English) 21st century
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/406249 , vital:70252
- Description: My thesis is a collection of Lyrical and Prose Poetry. I am strongly influenced by Marina Tsvetaeva’s observation that “The condition of creation is a condition of dreaming.” As a writer I want to contribute to human knowledge by drawing from a wide literary ancestry, participating in a community of distinct voices and styles to capture and preserve the language of dreams. I fuse inherited knowledge, visions, dreams, my own experiences and what I have discovered through listening to music, reading and my own experiments in exploring poetry in dreams, thoughts and lived experiences. I am inspired by Sindiwe Magona, how she chose to express her spirituality and personal narratives into her work, and Aimé Césaire’s vision “The ground of poetic knowledge, [is] an astonishing mobilization of all human and cosmic forces.” I particularly enjoy intense forms of expression that hold substance and provoke one to elevate in knowledge and in writing. Exploring these combination of forces from these writers affords me an opportunity to write my dreams as reality. Exploring the characters, the different scenes, symbols and colours as poems flashing super/naturally yet leave one with fathomable felt, though sometimes hazy interpretations. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2022
- Full Text:
- Date Issued: 2022-10-14
Population dynamics, fire, and reproductive ecology of Oldenburgia grandis (Asteraceae), an unusual fynbos tree endemic to the Eastern Cape
- Authors: Mostert, Emma Charlotte
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/365268 , vital:65722
- Description: Thesis embargoed. Possible release date set for early 2024. , Thesis (MSc) -- Faculty of Science, Botany, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Mostert, Emma Charlotte
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/365268 , vital:65722
- Description: Thesis embargoed. Possible release date set for early 2024. , Thesis (MSc) -- Faculty of Science, Botany, 2022
- Full Text:
- Date Issued: 2022-10-14
Portraits
- Authors: Fredericks, Gaireyah
- Date: 2022-10-14
- Subjects: Kaaps , Creative writing (Higher education) South Africa , Diaries -- Authorship , Books Reviews , Afrikaans essays 21st century , Short stories, Afrikaans 21st century
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/406238 , vital:70251
- Description: Die portfolio bestaan yt reflections op my writing process during die course, my reading, my poetics essay en vier boek resensies. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Fredericks, Gaireyah
- Date: 2022-10-14
- Subjects: Kaaps , Creative writing (Higher education) South Africa , Diaries -- Authorship , Books Reviews , Afrikaans essays 21st century , Short stories, Afrikaans 21st century
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/406238 , vital:70251
- Description: Die portfolio bestaan yt reflections op my writing process during die course, my reading, my poetics essay en vier boek resensies. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2022
- Full Text:
- Date Issued: 2022-10-14
Production of mannooligosaccharides from pineapple pulp and pine sawdust using Aspergillus niger derived Man26A and determination of their prebiotic effect
- Authors: Hlalukana, Nosipho Pretty
- Date: 2022-10-14
- Subjects: Oligosaccharides , Prebiotics , Lignocellulose , Mannans
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362853 , vital:65368
- Description: Lignocellulosic biomass is the most abundant source of renewable biomass on earth. Lignocellulosic biomass consists of cellulose, hemicelluloses and lignin. These can be used as a source of renewable fuel as well as other value-added products . Mannans are part of the hemicellulose fraction of lignocellulosic biomass and are the major hemicellulosic polysaccharide fraction in softwoods, where they are found as galactoglucomannans and as glucomannans. Mannans are also found in hardwoods in the form of glucomannans. Mannans can be enzymatically hydrolysed using endo-mannanases to produce of short chain mannooligosaccharides (MOS). MOS have received significant attention for their prebiotic properties, as they promote the growth of probiotic bacteria, which have positively affects on gut health. This study focused on the production of prebiotic MOS from lignocellulosic biomass waste (LBW) and an evaluation of the prebiotic potential of the produced MOS. An Aspergillus niger derived endo-mannanase, Man26A, was fractionated and biochemically analysed. Purified Man26A had a fold purification of 1.25 and a yield of 41.1%. SDS-PAGE analysis of the enzyme revealed that it had a molecular weight of 46 kDa. The pH and temperature optima of Man26A were determined and the pH optimum was found to be pH 4.0 (but the enzyme displayed high activity over a broad acidic pH range, with up to 90% of the activity retained between pH 3.0 and 7.0). The temperature optimum was 50℃. The enzyme was shown to have the highest specific activity on locust bean gum (52.27 U/mg) and ivory nut mannan (57.25 U/mg), compared to guar gum (29.07 U/mg), which indicated that it was affected by the substitution pattern of the mannans. Man26A produced MOS of different diversity on model mannan substrates, where the MOS produced were mannobiose, mannotriose, and mannotetraose for ivory nut mannan, mannobiose, mannotriose, mannotetraose, and mannopentaose and MOS with a higher degree of polymerisation for locust bean gum, and mannobiose, mannotriose, mannotetraose, mannopentaose, and mannohexose and MOS with a higher degree of polymerisation for guar gum, as determined by thin layer chromatography (TLC) and high-performance liquid chromatography (HPLC). Pretreatment and characterisation of pineapple pulp (PP) and pine sawdust (PSD) was conducted, and the impact of the pretreatment procedures was analysed using Megazyme sugar kits, thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FTIR), and microscopic analysis using scanning electron microscopy (SEM) and light microscopy. Compositional analysis of the carbohydrates present in both substrates revealed that they had a glucan content of 36.41 and 50.47% for untreated PP and PSD, respectively. Their respective mannan content was 6.74 and 11.59% and was deemed sufficient for the production of MOS via enzymatic hydrolysis. TGA analysis revealed that untreated and sodium chlorite-acetic acid delignified samples decomposed at approximately the same time, and had a negligible ash content at 600℃, while delignified plus phosphoric acid swollen substrates decomposed at a faster rate, but had a residual ash content at 600℃. FTIR analysis of the substrates revealed slight changes in the structures of untreated and pretreated samples. SEM analysis of PP and PSD showed a change in the morphology of the substrates with subsequent pretreatment steps. Histochemical analysis for lignin for PP and PSD showed successful delignification upon pretreatment. Untreated and sodium chlorite delignified PP and PSD released low amounts of reducing sugars compared to delignified + phosphoric acid swollen substrates. The delignified + phosphoric acid swollen substrates were used for further experiments. MOS produced from delignified and phosphoric acid swollen (Del + PAS) PP and PSD at 0.1 mg/ml enzyme loading and 80 mg/ml (8% (w/v)) substrate concentration, ran between mannose and mannobiose and between mannobiose and manotriose on TLC, with low concentrations of MOS running between mannotetraose and mannopentaose. HPLC analysis of the MOS revealed that Del + PAS PP produced mannose to mannohexose, while Del + PAS PSD produced mannose, mannobiose, and mannotetraose. The MOS were analysed using FTIR, to determine whether the MOS produced contained any acetyl groups, which were present for Del + PAS PSD at 1706 cm-1. The MOS were stable at different pHs, and at temperatures below 200℃. The MOS were also found to be stable in a simulated gastrointestinal environment, in the presence of bile salts and digestive enzymes. The prebiotic effect of the MOS derived from Del + PAS PP and PSD was evaluated. MOS had a proliferative effect on probiotic bacteria (Lactobacillus bulgaricus, Bacillus subtilis and Streptococcus thermophilus). The production of short chain fatty acids (SCFAs) was evaluated on TLC, where no SCFAs were observed on the plate. The effect of MOS on the adhesion ability of bacteria revealed that they do not positively influence the adhesion of probiotic bacteria. The antioxidant activities of 1 mg/ml MOS produced from both substrates were determined to be approximately 15% using the ABTS radical scavenging assay, compared to a radical scavenging activity of 45% for the 0.02 mg/ml gallic acid standard. This study demonstrated that biomass waste could be used to produce prebiotic MOS, which play a positive role in gut ecology and provide health benefits. , Thesis (MSc) -- Faculty of Science, Biochemistry and Microbiology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Hlalukana, Nosipho Pretty
- Date: 2022-10-14
- Subjects: Oligosaccharides , Prebiotics , Lignocellulose , Mannans
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362853 , vital:65368
- Description: Lignocellulosic biomass is the most abundant source of renewable biomass on earth. Lignocellulosic biomass consists of cellulose, hemicelluloses and lignin. These can be used as a source of renewable fuel as well as other value-added products . Mannans are part of the hemicellulose fraction of lignocellulosic biomass and are the major hemicellulosic polysaccharide fraction in softwoods, where they are found as galactoglucomannans and as glucomannans. Mannans are also found in hardwoods in the form of glucomannans. Mannans can be enzymatically hydrolysed using endo-mannanases to produce of short chain mannooligosaccharides (MOS). MOS have received significant attention for their prebiotic properties, as they promote the growth of probiotic bacteria, which have positively affects on gut health. This study focused on the production of prebiotic MOS from lignocellulosic biomass waste (LBW) and an evaluation of the prebiotic potential of the produced MOS. An Aspergillus niger derived endo-mannanase, Man26A, was fractionated and biochemically analysed. Purified Man26A had a fold purification of 1.25 and a yield of 41.1%. SDS-PAGE analysis of the enzyme revealed that it had a molecular weight of 46 kDa. The pH and temperature optima of Man26A were determined and the pH optimum was found to be pH 4.0 (but the enzyme displayed high activity over a broad acidic pH range, with up to 90% of the activity retained between pH 3.0 and 7.0). The temperature optimum was 50℃. The enzyme was shown to have the highest specific activity on locust bean gum (52.27 U/mg) and ivory nut mannan (57.25 U/mg), compared to guar gum (29.07 U/mg), which indicated that it was affected by the substitution pattern of the mannans. Man26A produced MOS of different diversity on model mannan substrates, where the MOS produced were mannobiose, mannotriose, and mannotetraose for ivory nut mannan, mannobiose, mannotriose, mannotetraose, and mannopentaose and MOS with a higher degree of polymerisation for locust bean gum, and mannobiose, mannotriose, mannotetraose, mannopentaose, and mannohexose and MOS with a higher degree of polymerisation for guar gum, as determined by thin layer chromatography (TLC) and high-performance liquid chromatography (HPLC). Pretreatment and characterisation of pineapple pulp (PP) and pine sawdust (PSD) was conducted, and the impact of the pretreatment procedures was analysed using Megazyme sugar kits, thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FTIR), and microscopic analysis using scanning electron microscopy (SEM) and light microscopy. Compositional analysis of the carbohydrates present in both substrates revealed that they had a glucan content of 36.41 and 50.47% for untreated PP and PSD, respectively. Their respective mannan content was 6.74 and 11.59% and was deemed sufficient for the production of MOS via enzymatic hydrolysis. TGA analysis revealed that untreated and sodium chlorite-acetic acid delignified samples decomposed at approximately the same time, and had a negligible ash content at 600℃, while delignified plus phosphoric acid swollen substrates decomposed at a faster rate, but had a residual ash content at 600℃. FTIR analysis of the substrates revealed slight changes in the structures of untreated and pretreated samples. SEM analysis of PP and PSD showed a change in the morphology of the substrates with subsequent pretreatment steps. Histochemical analysis for lignin for PP and PSD showed successful delignification upon pretreatment. Untreated and sodium chlorite delignified PP and PSD released low amounts of reducing sugars compared to delignified + phosphoric acid swollen substrates. The delignified + phosphoric acid swollen substrates were used for further experiments. MOS produced from delignified and phosphoric acid swollen (Del + PAS) PP and PSD at 0.1 mg/ml enzyme loading and 80 mg/ml (8% (w/v)) substrate concentration, ran between mannose and mannobiose and between mannobiose and manotriose on TLC, with low concentrations of MOS running between mannotetraose and mannopentaose. HPLC analysis of the MOS revealed that Del + PAS PP produced mannose to mannohexose, while Del + PAS PSD produced mannose, mannobiose, and mannotetraose. The MOS were analysed using FTIR, to determine whether the MOS produced contained any acetyl groups, which were present for Del + PAS PSD at 1706 cm-1. The MOS were stable at different pHs, and at temperatures below 200℃. The MOS were also found to be stable in a simulated gastrointestinal environment, in the presence of bile salts and digestive enzymes. The prebiotic effect of the MOS derived from Del + PAS PP and PSD was evaluated. MOS had a proliferative effect on probiotic bacteria (Lactobacillus bulgaricus, Bacillus subtilis and Streptococcus thermophilus). The production of short chain fatty acids (SCFAs) was evaluated on TLC, where no SCFAs were observed on the plate. The effect of MOS on the adhesion ability of bacteria revealed that they do not positively influence the adhesion of probiotic bacteria. The antioxidant activities of 1 mg/ml MOS produced from both substrates were determined to be approximately 15% using the ABTS radical scavenging assay, compared to a radical scavenging activity of 45% for the 0.02 mg/ml gallic acid standard. This study demonstrated that biomass waste could be used to produce prebiotic MOS, which play a positive role in gut ecology and provide health benefits. , Thesis (MSc) -- Faculty of Science, Biochemistry and Microbiology, 2022
- Full Text:
- Date Issued: 2022-10-14
Profiling Rhodes University students’ substance use during the Covid-19 pandemic lockdown: comparing the AUDIT and CCAPS-62 substance abuse sub-scale
- Authors: Goosen, Jeslyn Chrismaré
- Date: 2022-10-14
- Subjects: College students Substance use South Africa Makhanda , College students Alcohol use South Africa Makhanda , College students Mental health South Africa Makhanda , College students Attitudes , College students Economic conditions , COVID-19 (Disease) , Rhodes University
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/405974 , vital:70224
- Description: Students are vulnerable to academic distress and mental health concerns. Many struggle to effectively cope with the many demands placed on them from various factions; included but not limited to institutional demands, financial concerns, and parental expectations. With the most recent outbreak of the SARS-Co V-2 (better known as the COVID-19 pandemic) many students have struggled to effectively cope with the changes relating to the nationwide lockdown. Universities had to change the way in which they provide students with the necessary academic material, and many had to return to their familial homes. This had a deleterious effect on the way students performed their daily activities and coping. A rise in impaired mental health was noted. Many students used alcohol as a means of coping during this tumultuous and unprecedented time. Undergraduate students at Rhodes University were asked to complete a survey questionnaire via SurveyMonkey, an online survey service. Data was collected over a ten-day period during July 2020. The AUDIT and the CCAPS-62 Substance Use subscale were used to measure their alcohol intake during lockdown and results was compared. Results indicated a significant positive correlation between the CCAPS-62 substance use subscale and the AUDIT (r = 0.80, n = 930, p < 0.01). Outcomes identified that men tend to drink more than females, and white students tend to drink more than black students. Findings suggests that the CCAPS-62 a multidimensional instrument measuring general distress among students could positively contribute to the reliability and validity of the measure used in a multicultural and multilingual society such as South Africa. , Thesis (MA) -- Faculty of Humanities, Psychology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Goosen, Jeslyn Chrismaré
- Date: 2022-10-14
- Subjects: College students Substance use South Africa Makhanda , College students Alcohol use South Africa Makhanda , College students Mental health South Africa Makhanda , College students Attitudes , College students Economic conditions , COVID-19 (Disease) , Rhodes University
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/405974 , vital:70224
- Description: Students are vulnerable to academic distress and mental health concerns. Many struggle to effectively cope with the many demands placed on them from various factions; included but not limited to institutional demands, financial concerns, and parental expectations. With the most recent outbreak of the SARS-Co V-2 (better known as the COVID-19 pandemic) many students have struggled to effectively cope with the changes relating to the nationwide lockdown. Universities had to change the way in which they provide students with the necessary academic material, and many had to return to their familial homes. This had a deleterious effect on the way students performed their daily activities and coping. A rise in impaired mental health was noted. Many students used alcohol as a means of coping during this tumultuous and unprecedented time. Undergraduate students at Rhodes University were asked to complete a survey questionnaire via SurveyMonkey, an online survey service. Data was collected over a ten-day period during July 2020. The AUDIT and the CCAPS-62 Substance Use subscale were used to measure their alcohol intake during lockdown and results was compared. Results indicated a significant positive correlation between the CCAPS-62 substance use subscale and the AUDIT (r = 0.80, n = 930, p < 0.01). Outcomes identified that men tend to drink more than females, and white students tend to drink more than black students. Findings suggests that the CCAPS-62 a multidimensional instrument measuring general distress among students could positively contribute to the reliability and validity of the measure used in a multicultural and multilingual society such as South Africa. , Thesis (MA) -- Faculty of Humanities, Psychology, 2022
- Full Text:
- Date Issued: 2022-10-14
Puma (Puma concolor) diet and habitat use in south-west New Mexico
- Authors: Bernard, Kelly Monica Tandi
- Date: 2022-10-14
- Subjects: Puma Food New Mexico , Puma Habitat New Mexico , Puma Nutrition New Mexico , Puma Conservation New Mexico , Carnivorous animals New Mexico , Red deer , Elk , Mule deer , Ungulates
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362752 , vital:65359
- Description: The puma (Puma concolor) is a wide-ranging large felid species occupying an extensive geographic range throughout North and South America, and site-specific research on their diet is important for local management. Like other large felids, puma diet may differ between sexes due to size dimorphism, and between seasons due to changes in prey vulnerability and availability. This study assessed the influence of sex and season on puma diet in south-west New Mexico in terms of prey species and prey size categories. Pumas specialised on mule deer and elk throughout the year, and killed a range of other species of different sizes. The diet of the smaller female puma was nested within the diet of males, supporting the size-nested strategy. The effect of puma sex on prey species and size categories was independent of season, and vice versa, and the probability of a female making a medium-sized kill such as mule deer was higher than for males, while the probability of an extra-large kill such as elk was substantially greater for males. The probability of pumas killing either mule deer or elk in each season was similar, and greater than other species categories. Additionally, individual puma strongly influenced all prey species and size categories killed. The results from this study concur with previous findings on the importance of mule deer and elk in puma diet, and suggest that puma predation may also impact a number of other species, particularly smaller herbivores like collared peccary, and mesocarnivores such as skunks. , Thesis (MSc) -- Faculty of Science, Zoology and Entomology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Bernard, Kelly Monica Tandi
- Date: 2022-10-14
- Subjects: Puma Food New Mexico , Puma Habitat New Mexico , Puma Nutrition New Mexico , Puma Conservation New Mexico , Carnivorous animals New Mexico , Red deer , Elk , Mule deer , Ungulates
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362752 , vital:65359
- Description: The puma (Puma concolor) is a wide-ranging large felid species occupying an extensive geographic range throughout North and South America, and site-specific research on their diet is important for local management. Like other large felids, puma diet may differ between sexes due to size dimorphism, and between seasons due to changes in prey vulnerability and availability. This study assessed the influence of sex and season on puma diet in south-west New Mexico in terms of prey species and prey size categories. Pumas specialised on mule deer and elk throughout the year, and killed a range of other species of different sizes. The diet of the smaller female puma was nested within the diet of males, supporting the size-nested strategy. The effect of puma sex on prey species and size categories was independent of season, and vice versa, and the probability of a female making a medium-sized kill such as mule deer was higher than for males, while the probability of an extra-large kill such as elk was substantially greater for males. The probability of pumas killing either mule deer or elk in each season was similar, and greater than other species categories. Additionally, individual puma strongly influenced all prey species and size categories killed. The results from this study concur with previous findings on the importance of mule deer and elk in puma diet, and suggest that puma predation may also impact a number of other species, particularly smaller herbivores like collared peccary, and mesocarnivores such as skunks. , Thesis (MSc) -- Faculty of Science, Zoology and Entomology, 2022
- Full Text:
- Date Issued: 2022-10-14
Reforging Ockham’s Razor: an enquiry into the ontology of parsimony arguments
- Authors: Dichmont, Thomas
- Date: 2022-10-14
- Subjects: Logic , Metaphysics , Ontology , Knowledge, Theory of , Epistemology , Philosophy and science , Occam's razor
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/406736 , vital:70303
- Description: Nearly every philosopher in English-speaking world has heard of Ockham’s Razor, which is given in one of two ways, don’t multiply entities beyond necessity and all things being equal choose the simpler explanation. Yet it is unclear from the scholarship whether the use of Ockham’s Razor is justified in science and philosophy. However, if it can be shown to ‘get’ us truth, it would gain an unequivocal justification, as disputes that are continued after the parties to the substantive truth of one or the other are defined as frivolous. Alternative, one may contend that explanation could have other criteria of success. The implication of a direct connection between the razor and truth comes with ontological commitments, namely a commitment to realism (about universals) and philosophical theism. This is contrary to the razor’s use as a tool of nominalism and naturalism. I argue in this thesis there that the only possible non-circular justification for Ockham’s Razor is truth and that therefore certain philosophical positions are excluded from using the razor to animate their positions. There is an additional, second criteria for the success of our inquiry, namely the justification must in some way be consistent with the razor, which means the chosen explanation for the razor, must be simpler than any of its rivals and not have superfluous entities, otherwise our justification would be contrary to the advice of the razor. We are presented with a Scylla and Charybdis type problem, we avoid a circularity on the one hand and on the other we must not contradict the razor itself, these are contrary intellectual impulses. So firstly I will look at disciplines outside philosophy for some initial inspiration. If we could answer this question in a ‘non’ philosophical way, the problem would have solved itself in a way that require little change of practice. If lawyers or scientist can account for the razor properly, there is not really a problem of justification, at least not a philosophical one. Second, I consider the realist and theist positions, namely an argument of Aristotle’s in the Posterior Analytics and part of Aquinas’ On the Divine Simplicity. Further, I consider the work of Ockham as a nominalist. Lastly, I consider modern and contemporary philosophy, in the form of Hume, Quine and Sober (a modern writer on the razor). The aim here is to ‘stress test’ the philosophical resources of the various systems and analyse the results to see if they can produce a non-circular result. , Thesis (MA) -- Faculty of Humanities, Philosophy, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Dichmont, Thomas
- Date: 2022-10-14
- Subjects: Logic , Metaphysics , Ontology , Knowledge, Theory of , Epistemology , Philosophy and science , Occam's razor
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/406736 , vital:70303
- Description: Nearly every philosopher in English-speaking world has heard of Ockham’s Razor, which is given in one of two ways, don’t multiply entities beyond necessity and all things being equal choose the simpler explanation. Yet it is unclear from the scholarship whether the use of Ockham’s Razor is justified in science and philosophy. However, if it can be shown to ‘get’ us truth, it would gain an unequivocal justification, as disputes that are continued after the parties to the substantive truth of one or the other are defined as frivolous. Alternative, one may contend that explanation could have other criteria of success. The implication of a direct connection between the razor and truth comes with ontological commitments, namely a commitment to realism (about universals) and philosophical theism. This is contrary to the razor’s use as a tool of nominalism and naturalism. I argue in this thesis there that the only possible non-circular justification for Ockham’s Razor is truth and that therefore certain philosophical positions are excluded from using the razor to animate their positions. There is an additional, second criteria for the success of our inquiry, namely the justification must in some way be consistent with the razor, which means the chosen explanation for the razor, must be simpler than any of its rivals and not have superfluous entities, otherwise our justification would be contrary to the advice of the razor. We are presented with a Scylla and Charybdis type problem, we avoid a circularity on the one hand and on the other we must not contradict the razor itself, these are contrary intellectual impulses. So firstly I will look at disciplines outside philosophy for some initial inspiration. If we could answer this question in a ‘non’ philosophical way, the problem would have solved itself in a way that require little change of practice. If lawyers or scientist can account for the razor properly, there is not really a problem of justification, at least not a philosophical one. Second, I consider the realist and theist positions, namely an argument of Aristotle’s in the Posterior Analytics and part of Aquinas’ On the Divine Simplicity. Further, I consider the work of Ockham as a nominalist. Lastly, I consider modern and contemporary philosophy, in the form of Hume, Quine and Sober (a modern writer on the razor). The aim here is to ‘stress test’ the philosophical resources of the various systems and analyse the results to see if they can produce a non-circular result. , Thesis (MA) -- Faculty of Humanities, Philosophy, 2022
- Full Text:
- Date Issued: 2022-10-14
Regulation of Oct4 expression during cell stress
- Authors: Samson, William John
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/365712 , vital:65778
- Description: Thesis embargoed. Expected release date early 2025. , Thesis (PhD) -- Faculty of Science, Biochemistry and Microbiology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Samson, William John
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/365712 , vital:65778
- Description: Thesis embargoed. Expected release date early 2025. , Thesis (PhD) -- Faculty of Science, Biochemistry and Microbiology, 2022
- Full Text:
- Date Issued: 2022-10-14
Revitalisation and indigenisation of the Science curriculum through drum making, drumming, music and dance
- Authors: Liveve, Angelius Kanyanga
- Date: 2022-10-14
- Subjects: Curriculum change Namibia , Science Study and teaching (Secondary) Namibia , Traditional ecological knowledge Namibia , Drum Performance , Drum making , Pedagogical content knowledge , Social learning
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/405482 , vital:70175 , DOI 10.21504/10962/405482
- Description: The integration of IK is a common phenomenon in many postcolonial states, where it is viewed as a means to redress the injustices of the colonial era. It is believed that the recognition of IK in education represents an acknowledgement of diversity and other ways of knowing. In Namibia, for instance, the National Curriculum for Basic Education encourages the integration of IK in Science teaching. However, this goal is still far from being achieved because the curriculum seems to be silent on how teachers should integrate IK into their teaching. As a result, research shows that many Science teachers in Namibia seem to find it difficult to integrate IK into their science teaching because they were not properly trained to do so during both their pre-service and in-service training. This suggests that there is a dire need to empower science teachers who are implementers of the curriculum on appropriate pedagogical content knowledge on how to integrate IK into their science teaching in particular. It is against this backdrop that this interventionist study sought to explore how to mobilise the indigenous technology of drum making, drumming, music and dance for cultural revitalisation and indigenisation of the science curriculum. The study is underpinned by an interpretivist paradigm and augmented with an indigenous research paradigm. The interpretivist paradigm enabled me to understand the teachers’ perspectives in their contexts. On the other hand, within the indigenous research paradigm, I used the Ubuntu perspective which afforded each of us an opportunity to understand each other’s ways of knowing, doing and being. Within these two complementary paradigms, a qualitative case study approach was employed. The case study was in the form of intervention with six Grade 10 Physics teachers from three senior secondary schools in the Kavango West Region in Namibia. Moreover, a critical friend who was a lecturer at the university and expert community members of the Unongo Cultural Youth Group who are the custodians of the cultural heritage. Data were generated using semi-structured interviews, workshop discussions (audio-recorded), observations (participatory and lesson observations), stimulated recall interviews as well as journal reflections. Vygotsky’s Socio-cultural Theory, Ogunniyi’s Contiguity Argumentation Theory and Mavhunga and Rollnick’s Topic-specific Pedagogical Content Knowledge were used as the theoretical lenses in this study. The data gathered were analysed thematically and then categorised into sub-themes and themes. The findings of the study revealed that tapping into the cultural heritage of community members through giving them a voice has great potential to revitalise and indigenise the science curriculum. It also emerged in this study that storytelling is a potential instructional strategy to make science accessible and relevant to learners. The use of the indigenous technology of drum making, drumming, music and dance contributed to the Physics teachers’ agency and empowered them to co-develop their learning and teaching support materials in the form of exemplar lesson plans that integrated IK. Moreover, their pedagogical content knowledge was enhanced through enacting such exemplar lessons and thereafter reflecting on them. The study thus recommends that those in academia should promote the use of indigenous technologies as hubs for mediating the learning of science concepts. It also recommends that learners should be taken out of their science classrooms into the community to learn IK and wisdom from expert community members, something which could assist them in understanding the science taught at school. This might also benefit teachers in effectively implementing the integration of IK in schools and thereby use learners’ cultural heritage as a starting point to enrich meaningful and authentic learning. , Thesis (PhD) -- Faculty of Education, Education, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Liveve, Angelius Kanyanga
- Date: 2022-10-14
- Subjects: Curriculum change Namibia , Science Study and teaching (Secondary) Namibia , Traditional ecological knowledge Namibia , Drum Performance , Drum making , Pedagogical content knowledge , Social learning
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/405482 , vital:70175 , DOI 10.21504/10962/405482
- Description: The integration of IK is a common phenomenon in many postcolonial states, where it is viewed as a means to redress the injustices of the colonial era. It is believed that the recognition of IK in education represents an acknowledgement of diversity and other ways of knowing. In Namibia, for instance, the National Curriculum for Basic Education encourages the integration of IK in Science teaching. However, this goal is still far from being achieved because the curriculum seems to be silent on how teachers should integrate IK into their teaching. As a result, research shows that many Science teachers in Namibia seem to find it difficult to integrate IK into their science teaching because they were not properly trained to do so during both their pre-service and in-service training. This suggests that there is a dire need to empower science teachers who are implementers of the curriculum on appropriate pedagogical content knowledge on how to integrate IK into their science teaching in particular. It is against this backdrop that this interventionist study sought to explore how to mobilise the indigenous technology of drum making, drumming, music and dance for cultural revitalisation and indigenisation of the science curriculum. The study is underpinned by an interpretivist paradigm and augmented with an indigenous research paradigm. The interpretivist paradigm enabled me to understand the teachers’ perspectives in their contexts. On the other hand, within the indigenous research paradigm, I used the Ubuntu perspective which afforded each of us an opportunity to understand each other’s ways of knowing, doing and being. Within these two complementary paradigms, a qualitative case study approach was employed. The case study was in the form of intervention with six Grade 10 Physics teachers from three senior secondary schools in the Kavango West Region in Namibia. Moreover, a critical friend who was a lecturer at the university and expert community members of the Unongo Cultural Youth Group who are the custodians of the cultural heritage. Data were generated using semi-structured interviews, workshop discussions (audio-recorded), observations (participatory and lesson observations), stimulated recall interviews as well as journal reflections. Vygotsky’s Socio-cultural Theory, Ogunniyi’s Contiguity Argumentation Theory and Mavhunga and Rollnick’s Topic-specific Pedagogical Content Knowledge were used as the theoretical lenses in this study. The data gathered were analysed thematically and then categorised into sub-themes and themes. The findings of the study revealed that tapping into the cultural heritage of community members through giving them a voice has great potential to revitalise and indigenise the science curriculum. It also emerged in this study that storytelling is a potential instructional strategy to make science accessible and relevant to learners. The use of the indigenous technology of drum making, drumming, music and dance contributed to the Physics teachers’ agency and empowered them to co-develop their learning and teaching support materials in the form of exemplar lesson plans that integrated IK. Moreover, their pedagogical content knowledge was enhanced through enacting such exemplar lessons and thereafter reflecting on them. The study thus recommends that those in academia should promote the use of indigenous technologies as hubs for mediating the learning of science concepts. It also recommends that learners should be taken out of their science classrooms into the community to learn IK and wisdom from expert community members, something which could assist them in understanding the science taught at school. This might also benefit teachers in effectively implementing the integration of IK in schools and thereby use learners’ cultural heritage as a starting point to enrich meaningful and authentic learning. , Thesis (PhD) -- Faculty of Education, Education, 2022
- Full Text:
- Date Issued: 2022-10-14
Rural households’ perceptions of an invasive alien species rosa rubiginosa l. (rosehip) and the role it plays in rural livelihoods in Lesotho
- Authors: Makhorole, Thato Violet
- Date: 2022-10-14
- Subjects: Rose hips Lesotho , Invasive plants Lesotho , Rural poor Lesotho , Probit model , Principal components analysis
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/403069 , vital:69919
- Description: Despite the vast research on the negative impacts of invasive alien species on the environment, these species remain part of the rural communities due to their numerous livelihood uses. Thus, more research is required, focusing mainly on the impacts of invasive alien species on the livelihoods of rural communities. This study investigated the community perceptions of rosehip (Rosa rubiginosa) and its contribution to rural communities as an invasive alien species. Four community councils, Pitseng, Matlameng, Limamarela and Mphorosane in the Leribe District Lesotho, were assessed. The study followed the pragmatism paradigm. The contribution of rosehip to rural livelihoods was analysed by comparing income from rosehip with other income sources. The study used simple random sampling and snowball sampling to select a representative of 160 respondents. The primary data was collected using semi-structured questionnaires. Moreover, SPSS and Stata statistical package programs were used for statistical analyses. The results showed that rosehip's livelihood benefits, its negative impacts, the length of time it has been available in the area, and its abundance highly influence the social, economic and environmental perception of rural communities. Furthermore, the study revealed that although the income from rosehip is extremely low and available for only three months of the year, the income plays an important part to the poorer households who have no other income sources. The study found that the main reason for engagement in rosehip harvesting despite its challenging nature was unemployment. The study also revealed that rosehip is part of the risk-reducing strategy or income diversification. Some households used it to complement other sources of income, such as agricultural production. Rosehip trade, if well-controlled, has the potential to alleviate rural poverty by creating job opportunities, providing a source of household income, and acting as a safety net in the face of shocks such as limited job opportunities and food shortages. In conclusion, households’ perceptions of rosehip have proven that rosehip is a valuable resource that provides a supplementary income that contributes towards alleviating poverty in Lesotho’s rural communities. The study recommends the private sector to establish and manages small agro-processing industries focusing on products used daily. The study also encourages environmental education and indigenous knowledge among community members, which would include knowledge and recognition of invasive alien species and their potential benefits and threats. , Thesis (MEcon) -- Faculty of Commerce, Economics and Economic History, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Makhorole, Thato Violet
- Date: 2022-10-14
- Subjects: Rose hips Lesotho , Invasive plants Lesotho , Rural poor Lesotho , Probit model , Principal components analysis
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/403069 , vital:69919
- Description: Despite the vast research on the negative impacts of invasive alien species on the environment, these species remain part of the rural communities due to their numerous livelihood uses. Thus, more research is required, focusing mainly on the impacts of invasive alien species on the livelihoods of rural communities. This study investigated the community perceptions of rosehip (Rosa rubiginosa) and its contribution to rural communities as an invasive alien species. Four community councils, Pitseng, Matlameng, Limamarela and Mphorosane in the Leribe District Lesotho, were assessed. The study followed the pragmatism paradigm. The contribution of rosehip to rural livelihoods was analysed by comparing income from rosehip with other income sources. The study used simple random sampling and snowball sampling to select a representative of 160 respondents. The primary data was collected using semi-structured questionnaires. Moreover, SPSS and Stata statistical package programs were used for statistical analyses. The results showed that rosehip's livelihood benefits, its negative impacts, the length of time it has been available in the area, and its abundance highly influence the social, economic and environmental perception of rural communities. Furthermore, the study revealed that although the income from rosehip is extremely low and available for only three months of the year, the income plays an important part to the poorer households who have no other income sources. The study found that the main reason for engagement in rosehip harvesting despite its challenging nature was unemployment. The study also revealed that rosehip is part of the risk-reducing strategy or income diversification. Some households used it to complement other sources of income, such as agricultural production. Rosehip trade, if well-controlled, has the potential to alleviate rural poverty by creating job opportunities, providing a source of household income, and acting as a safety net in the face of shocks such as limited job opportunities and food shortages. In conclusion, households’ perceptions of rosehip have proven that rosehip is a valuable resource that provides a supplementary income that contributes towards alleviating poverty in Lesotho’s rural communities. The study recommends the private sector to establish and manages small agro-processing industries focusing on products used daily. The study also encourages environmental education and indigenous knowledge among community members, which would include knowledge and recognition of invasive alien species and their potential benefits and threats. , Thesis (MEcon) -- Faculty of Commerce, Economics and Economic History, 2022
- Full Text:
- Date Issued: 2022-10-14
Settling in: Investigating the experiences of social media use of a group of international students in their integration into the Rhodes University environment
- Authors: Losa Reinoso, Kelia
- Date: 2022-10-14
- Subjects: Students, Foreign South Africa , Social media and society South Africa , Students, Foreign Social conditions , Student adjustment South Africa , Students, Foreign Social networks , Social media and college students South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/405941 , vital:70221
- Description: The South African government and its institutions of higher education take deliberate measures to attract international students to this country which is marketed as an appealing option for for international study because it is cheaper than in European countries and the US, courses that may be unavailable or difficult to get into in their home countries are available in South Africa, there is a high quality of education, a greater variety of qualifications, technologically advanced facilities and a geographical proximity of South Africa to international students’ home countries in the SADC region. While many international students find living in a new country exciting, fulfilling and stimulating, it may at the same time be frustrating and confusing. Students may find it difficult to adjust to their general living arrangements, new housing and transportation environments and dealing with financial and health care concerns. Also, there may be academic challenges and socio-cultural difficulties to navigate. Problems of adjustment may force international students into isolation, creating feelings of alienation and so they develop mechanisms to adjust, to feel better integrated and cope with situations that they might find difficult and alienating. One of the most important of these is to find social support which can come from friends, family, academic staff, classmates or colleagues. Social networking through social media is also important as it can ameliorate feelings of alienation and contribute significantly to the creation of an active social network and its use is therefore associated with social support for, and social adjustment of international students. This study investigates the positive and negative impacts of social media on the integration of international students into the Rhodes University environment. The study uses an exploratory survey, focus groups and semi-structured interviews to gather data which was analysed using a thematic analysis. This analysis shows that international students make use of a variety social media platforms, each with its own specific purpose – WhatsApp to communicate with friends and family, Twitter for news, Instagram for entertainment and Facebook for information and entertainment, etc. Interestingly, while social media is used in the maintenance of strong social connections it is not used to create those relationships. Rather, meeting new people and the initiation and building of relationships was done through meeting at parties and pubs and in university organised social events, clubs and societies. While social media reporting of issues like xenophobic attacks made international students anxious, none of those involved in the study were subjected to such attacks through social media. , Thesis (MA) -- Faculty of Humanities, School of Journalism and Media Studies, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Losa Reinoso, Kelia
- Date: 2022-10-14
- Subjects: Students, Foreign South Africa , Social media and society South Africa , Students, Foreign Social conditions , Student adjustment South Africa , Students, Foreign Social networks , Social media and college students South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/405941 , vital:70221
- Description: The South African government and its institutions of higher education take deliberate measures to attract international students to this country which is marketed as an appealing option for for international study because it is cheaper than in European countries and the US, courses that may be unavailable or difficult to get into in their home countries are available in South Africa, there is a high quality of education, a greater variety of qualifications, technologically advanced facilities and a geographical proximity of South Africa to international students’ home countries in the SADC region. While many international students find living in a new country exciting, fulfilling and stimulating, it may at the same time be frustrating and confusing. Students may find it difficult to adjust to their general living arrangements, new housing and transportation environments and dealing with financial and health care concerns. Also, there may be academic challenges and socio-cultural difficulties to navigate. Problems of adjustment may force international students into isolation, creating feelings of alienation and so they develop mechanisms to adjust, to feel better integrated and cope with situations that they might find difficult and alienating. One of the most important of these is to find social support which can come from friends, family, academic staff, classmates or colleagues. Social networking through social media is also important as it can ameliorate feelings of alienation and contribute significantly to the creation of an active social network and its use is therefore associated with social support for, and social adjustment of international students. This study investigates the positive and negative impacts of social media on the integration of international students into the Rhodes University environment. The study uses an exploratory survey, focus groups and semi-structured interviews to gather data which was analysed using a thematic analysis. This analysis shows that international students make use of a variety social media platforms, each with its own specific purpose – WhatsApp to communicate with friends and family, Twitter for news, Instagram for entertainment and Facebook for information and entertainment, etc. Interestingly, while social media is used in the maintenance of strong social connections it is not used to create those relationships. Rather, meeting new people and the initiation and building of relationships was done through meeting at parties and pubs and in university organised social events, clubs and societies. While social media reporting of issues like xenophobic attacks made international students anxious, none of those involved in the study were subjected to such attacks through social media. , Thesis (MA) -- Faculty of Humanities, School of Journalism and Media Studies, 2022
- Full Text:
- Date Issued: 2022-10-14
Simplified menu-driven data analysis tool with macro-like automation
- Authors: Kazembe, Luntha
- Date: 2022-10-14
- Subjects: Data analysis , Macro instructions (Electronic computers) , Quantitative research Software , Python (Computer program language) , Scripting languages (Computer science)
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362905 , vital:65373
- Description: This study seeks to improve the data analysis process for individuals and small businesses with limited resources by developing a simplified data analysis software tool that allows users to carry out data analysis effectively and efficiently. Design considerations were identified to address limitations common in such environments, these included making the tool easy-to-use, requiring only a basic understanding of the data analysis process, designing the tool in manner that minimises computing resource requirements and user interaction and implementing it using Python which is open-source, effective and efficient in processing data. We develop a prototype simplified data analysis tool as a proof-of-concept. The tool has two components, namely, core elements which provide functionality for the data anal- ysis process including data collection, transformations, analysis and visualizations, and automation and performance enhancements to improve the data analysis process. The automation enhancements consist of the record and playback macro feature while the performance enhancements include multiprocessing and multi-threading abilities. The data analysis software was developed to analyse various alpha-numeric data formats by using a variety of statistical and mathematical techniques. The record and playback macro feature enhances the data analysis process by saving users time and computing resources when analysing large volumes of data or carrying out repetitive data analysis tasks. The feature has two components namely, the record component that is used to record data analysis steps and the playback component used to execute recorded steps. The simplified data analysis tool has parallelization designed and implemented which allows users to carry out two or more analysis tasks at a time, this improves productivity as users can do other tasks while the tool is processing data using recorded steps in the background. The tool was created and subsequently tested using common analysis scenarios applied to network data, log data and stock data. Results show that decision-making requirements such as accurate information, can be satisfied using this analysis tool. Based on the functionality implemented, similar analysis functionality to that provided by Microsoft Excel is available, but in a simplified manner. Moreover, a more sophisticated macro functionality is provided for the execution of repetitive tasks using the recording feature. Overall, the study found that the simplified data analysis tool is functional, usable, scalable, efficient and can carry out multiple analysis tasks simultaneously. , Thesis (MSc) -- Faculty of Science, Computer Science, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Kazembe, Luntha
- Date: 2022-10-14
- Subjects: Data analysis , Macro instructions (Electronic computers) , Quantitative research Software , Python (Computer program language) , Scripting languages (Computer science)
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362905 , vital:65373
- Description: This study seeks to improve the data analysis process for individuals and small businesses with limited resources by developing a simplified data analysis software tool that allows users to carry out data analysis effectively and efficiently. Design considerations were identified to address limitations common in such environments, these included making the tool easy-to-use, requiring only a basic understanding of the data analysis process, designing the tool in manner that minimises computing resource requirements and user interaction and implementing it using Python which is open-source, effective and efficient in processing data. We develop a prototype simplified data analysis tool as a proof-of-concept. The tool has two components, namely, core elements which provide functionality for the data anal- ysis process including data collection, transformations, analysis and visualizations, and automation and performance enhancements to improve the data analysis process. The automation enhancements consist of the record and playback macro feature while the performance enhancements include multiprocessing and multi-threading abilities. The data analysis software was developed to analyse various alpha-numeric data formats by using a variety of statistical and mathematical techniques. The record and playback macro feature enhances the data analysis process by saving users time and computing resources when analysing large volumes of data or carrying out repetitive data analysis tasks. The feature has two components namely, the record component that is used to record data analysis steps and the playback component used to execute recorded steps. The simplified data analysis tool has parallelization designed and implemented which allows users to carry out two or more analysis tasks at a time, this improves productivity as users can do other tasks while the tool is processing data using recorded steps in the background. The tool was created and subsequently tested using common analysis scenarios applied to network data, log data and stock data. Results show that decision-making requirements such as accurate information, can be satisfied using this analysis tool. Based on the functionality implemented, similar analysis functionality to that provided by Microsoft Excel is available, but in a simplified manner. Moreover, a more sophisticated macro functionality is provided for the execution of repetitive tasks using the recording feature. Overall, the study found that the simplified data analysis tool is functional, usable, scalable, efficient and can carry out multiple analysis tasks simultaneously. , Thesis (MSc) -- Faculty of Science, Computer Science, 2022
- Full Text:
- Date Issued: 2022-10-14
Social upgrading or dependency?: Investigating the implications of the inclusion of commercial wine farms within South African Fairtrade certification
- Authors: Bell, Joshua
- Date: 2022-10-14
- Subjects: Competition, Unfair South Africa , Wine industry South Africa Employees , Unfair labor practices South Africa , Fairtrade International , International trade , Economic development Moral and ethical aspects South Africa , Wine industry Moral and ethical aspects South Africa , Work environment South Africa
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/327155 , vital:61086 , DOI 10.21504/10962/327155
- Description: The South African wine industry is one of the oldest sectors of the country’s economy, beginning in the early years of South African colonialism in the 17th century through the use of slave and slave-like labour. As an industry that has been defined by farm paternalism and dependency, the South African wine industry has had to demonstrate changes from its history of extreme racial and gendered exploitation to an industry that reflects the democratic values of a new South Africa. Ethical certifications are considered one way through which the post-apartheid South African wine industry can demonstrate that it has moved away from its historical practices and is now characterised by practices of decent work and social transformation. An important certificatory label that allows local wine producers entry into global wine production networks is Fairtrade International. While Fairtrade certification is often reserved for small-scale producers, this certification has been extended to large-scale, commercial producers within the South African wine industry despite its history of farm paternalism and dependency. This research asks if this inclusion promotes decent work through social upgrading or if it offers a platform for the continuation of farm dependency under the guise of ‘Fairtrade’. In this study, social upgrading has been defined through a ‘bottom-up’ approach that prioritises workers’ independence as a key means of improvement. Four key pillars are applied as embodying the concept of social upgrading: regular employment with set working hours; legally enforceable worker rights; social protection through collective and individual bargaining power; and non-discriminatory social dialogue that promotes significant socio-economic progression. A key finding of this research is that practices of dependency and paternalism continue on some large-scale commercial farms, despite their Fairtrade certification. Furthermore, the findings suggest that the benefits that farmworkers receive lock farmworkers into their position on the farm with marginally improved conditions and cease if workers depart from the Fairtrade wine farm. This suggests that, at best, this inclusion of commercial farmers within Fairtrade certification appears to create a top-down form of social upgrading that locks farmworkers into their position on the farm with marginally improved conditions and beneath a glass ceiling of development. At worst, this Fairtrade inclusion facilitates a global poverty network through paternalism and dependency under the guise of ‘Fairtrade’. As a result, where meaningful, bottom-up social upgrading may occur on South African wine farms, the study suggests that this is despite the presence of Fairtrade and not a result of it. , Thesis (PhD) -- Faculty of Humanities, Political and Interntional Studies, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Bell, Joshua
- Date: 2022-10-14
- Subjects: Competition, Unfair South Africa , Wine industry South Africa Employees , Unfair labor practices South Africa , Fairtrade International , International trade , Economic development Moral and ethical aspects South Africa , Wine industry Moral and ethical aspects South Africa , Work environment South Africa
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/327155 , vital:61086 , DOI 10.21504/10962/327155
- Description: The South African wine industry is one of the oldest sectors of the country’s economy, beginning in the early years of South African colonialism in the 17th century through the use of slave and slave-like labour. As an industry that has been defined by farm paternalism and dependency, the South African wine industry has had to demonstrate changes from its history of extreme racial and gendered exploitation to an industry that reflects the democratic values of a new South Africa. Ethical certifications are considered one way through which the post-apartheid South African wine industry can demonstrate that it has moved away from its historical practices and is now characterised by practices of decent work and social transformation. An important certificatory label that allows local wine producers entry into global wine production networks is Fairtrade International. While Fairtrade certification is often reserved for small-scale producers, this certification has been extended to large-scale, commercial producers within the South African wine industry despite its history of farm paternalism and dependency. This research asks if this inclusion promotes decent work through social upgrading or if it offers a platform for the continuation of farm dependency under the guise of ‘Fairtrade’. In this study, social upgrading has been defined through a ‘bottom-up’ approach that prioritises workers’ independence as a key means of improvement. Four key pillars are applied as embodying the concept of social upgrading: regular employment with set working hours; legally enforceable worker rights; social protection through collective and individual bargaining power; and non-discriminatory social dialogue that promotes significant socio-economic progression. A key finding of this research is that practices of dependency and paternalism continue on some large-scale commercial farms, despite their Fairtrade certification. Furthermore, the findings suggest that the benefits that farmworkers receive lock farmworkers into their position on the farm with marginally improved conditions and cease if workers depart from the Fairtrade wine farm. This suggests that, at best, this inclusion of commercial farmers within Fairtrade certification appears to create a top-down form of social upgrading that locks farmworkers into their position on the farm with marginally improved conditions and beneath a glass ceiling of development. At worst, this Fairtrade inclusion facilitates a global poverty network through paternalism and dependency under the guise of ‘Fairtrade’. As a result, where meaningful, bottom-up social upgrading may occur on South African wine farms, the study suggests that this is despite the presence of Fairtrade and not a result of it. , Thesis (PhD) -- Faculty of Humanities, Political and Interntional Studies, 2022
- Full Text:
- Date Issued: 2022-10-14
Socio-historical analysis of organisational change: a case study of Zimbabwe posts (Zimpost), 2010–2020
- Kambarami-Zengeni, Faith Chipo
- Authors: Kambarami-Zengeni, Faith Chipo
- Date: 2022-10-14
- Subjects: Organizational change Zimbabwe , Fordism , Industrial management , Taylor, Frederick Winslow, 1856-1915 , Industrial relations , Postal service Management
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/327920 , vital:61170 , DOI 10.21504/10962/327920
- Description: Postal organisations play an important role in the provision of basic communication services. In Zimbabwe, post offices have a large physical distribution network of over 240 post offices country-wide to make communication services accessible to the populace. However, e-substitution has threatened mail business significantly. Postal operators globally are experiencing declining mail volumes in the face of advanced information and communication technologies. The overall goal of this thesis was to undertake a socio-historical analysis of organisational change at ZimPost using Taylorism, Fordism and post-Fordism as broad ideal types to explain how industry evolves in different phases of capitalism. National politics and economics play an integral role in how Taylorism, Fordism and post-Fordism assumed at ZimPost. Studies on these broad organising types have mainly focused on private sector organisations. However, this thesis argues that these analytical paradigms are also valid in public sector organisations, but they will unfold differently given the context in which change is experienced. Using a qualitative approach, the study established that the 1980s and 1990s can best be described as the ‘golden years’ of postal services in Zimbabwe, characterised by mass production and mass consumption of postal products and services. At that time the Posts and Telecommunications Corporation enjoyed a monopoly of postal services in the country. The stable market share, competitive salaries for postal workers, increased unionisation and a fairly stable economy enabled a Fordist regime of accumulation to develop. The cycle broke down when the mode of regulation was weakened by national economic and political changes towards the late 1990s. PTC started to experience a decline in the consumption of postal products. The decline was also attributed to increased competition from smaller private courier operators that could provide specialised services to a market with changing needs. With increased competition, the advancement of information, and communication technologies, mail volumes dwindled. This period can best be described as the crisis of Fordism at ZimPost. In the year 2000, the government unbundled the posts and telecommunications corporation to create four companies including Zimbabwe Posts. This was perceived as one of the most radical organisational changes in the history of postal services in Zimbabwe. More organisational changes took place at ZimPost that can best be described as characteristics of post-Fordism. These changes were attempts by ZimPost to remain relevant in light of the economic, political and technological changes taking place in the country. The postal operator introduced customised products in the form of agency services, supported by increased use of information and communication technologies in the post office. Organisational changes at ZimPost were shaped mainly by the economic and political environment in which they took place. Organisational change is complex, changes do not follow a linear pattern, they are processual. , Thesis (PhD) -- Faculty of Humanities, Sociology, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Kambarami-Zengeni, Faith Chipo
- Date: 2022-10-14
- Subjects: Organizational change Zimbabwe , Fordism , Industrial management , Taylor, Frederick Winslow, 1856-1915 , Industrial relations , Postal service Management
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/327920 , vital:61170 , DOI 10.21504/10962/327920
- Description: Postal organisations play an important role in the provision of basic communication services. In Zimbabwe, post offices have a large physical distribution network of over 240 post offices country-wide to make communication services accessible to the populace. However, e-substitution has threatened mail business significantly. Postal operators globally are experiencing declining mail volumes in the face of advanced information and communication technologies. The overall goal of this thesis was to undertake a socio-historical analysis of organisational change at ZimPost using Taylorism, Fordism and post-Fordism as broad ideal types to explain how industry evolves in different phases of capitalism. National politics and economics play an integral role in how Taylorism, Fordism and post-Fordism assumed at ZimPost. Studies on these broad organising types have mainly focused on private sector organisations. However, this thesis argues that these analytical paradigms are also valid in public sector organisations, but they will unfold differently given the context in which change is experienced. Using a qualitative approach, the study established that the 1980s and 1990s can best be described as the ‘golden years’ of postal services in Zimbabwe, characterised by mass production and mass consumption of postal products and services. At that time the Posts and Telecommunications Corporation enjoyed a monopoly of postal services in the country. The stable market share, competitive salaries for postal workers, increased unionisation and a fairly stable economy enabled a Fordist regime of accumulation to develop. The cycle broke down when the mode of regulation was weakened by national economic and political changes towards the late 1990s. PTC started to experience a decline in the consumption of postal products. The decline was also attributed to increased competition from smaller private courier operators that could provide specialised services to a market with changing needs. With increased competition, the advancement of information, and communication technologies, mail volumes dwindled. This period can best be described as the crisis of Fordism at ZimPost. In the year 2000, the government unbundled the posts and telecommunications corporation to create four companies including Zimbabwe Posts. This was perceived as one of the most radical organisational changes in the history of postal services in Zimbabwe. More organisational changes took place at ZimPost that can best be described as characteristics of post-Fordism. These changes were attempts by ZimPost to remain relevant in light of the economic, political and technological changes taking place in the country. The postal operator introduced customised products in the form of agency services, supported by increased use of information and communication technologies in the post office. Organisational changes at ZimPost were shaped mainly by the economic and political environment in which they took place. Organisational change is complex, changes do not follow a linear pattern, they are processual. , Thesis (PhD) -- Faculty of Humanities, Sociology, 2022
- Full Text:
- Date Issued: 2022-10-14
Socio-historical analysis of organisational change: a case study of Zimbabwe Posts (Zimpost), 2010–2020
- Kambarami-Zengeni, Faith Chipo
- Authors: Kambarami-Zengeni, Faith Chipo
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/422518 , vital:71954 , DOI 10.21504/10962/422518
- Description: Postal organisations play an important role in the provision of basic communication services. In Zimbabwe, post offices have a large physical distribution network of over 240 post offices country-wide to make communication services accessible to the populace. However, e-substitution has threatened mail business significantly. Postal operators globally are experiencing declining mail volumes in the face of advanced information and communication technologies. The overall goal of this thesis was to undertake a socio-historical analysis of organisational change at ZimPost using Taylorism, Fordism and post-Fordism as broad ideal types to explain how industry evolves in different phases of capitalism. National politics and economics play an integral role in how Taylorism, Fordism and post-Fordism assumed at ZimPost. Studies on these broad organising types have mainly focused on private sector organisations. However, this thesis argues that these analytical paradigms are also valid in public sector organisations, but they will unfold differently given the context in which change is experienced. Using a qualitative approach, the study established that the 1980s and 1990s can best be described as the ‘golden years’ of postal services in Zimbabwe, characterised by mass production and mass consumption of postal products and services. At that time the Posts and Telecommunications Corporation enjoyed a monopoly of postal services in the country. The stable market share, competitive salaries for postal workers, increased unionisation and a fairly stable economy enabled a Fordist regime of accumulation to develop. The cycle broke down when the mode of regulation was weakened by national economic and political changes towards the late 1990s. PTC started to experience a decline in the consumption of postal products. The decline was also attributed to increased competition from smaller private courier operators that could provide specialised services to a market with changing needs. With increased competition, the advancement of information, and communication technologies, mail volumes dwindled. This period can best be described as the crisis of Fordism at ZimPost. In the year 2000, the government unbundled the posts and telecommunications corporation to create four companies including Zimbabwe Posts. This was perceived as one of the most radical organisational changes in the history of postal services in Zimbabwe. More organisational changes took place at ZimPost that can best be described as characteristics of post-Fordism. These changes were attempts by ZimPost to remain relevant in light of the economic, political and technological changes taking place in the country. The postal operator introduced customised products in the form of agency services, supported by increased use of information and communication technologies in the post office. Organisational changes at ZimPost were shaped mainly by the economic and political environment in which they took place. Organisational change is complex, changes do not follow a linear pattern, they are processual. , Thesis (PhD) -- Faculty of Humanities, Sociology, 2023
- Full Text:
- Date Issued: 2022-10-14
- Authors: Kambarami-Zengeni, Faith Chipo
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/422518 , vital:71954 , DOI 10.21504/10962/422518
- Description: Postal organisations play an important role in the provision of basic communication services. In Zimbabwe, post offices have a large physical distribution network of over 240 post offices country-wide to make communication services accessible to the populace. However, e-substitution has threatened mail business significantly. Postal operators globally are experiencing declining mail volumes in the face of advanced information and communication technologies. The overall goal of this thesis was to undertake a socio-historical analysis of organisational change at ZimPost using Taylorism, Fordism and post-Fordism as broad ideal types to explain how industry evolves in different phases of capitalism. National politics and economics play an integral role in how Taylorism, Fordism and post-Fordism assumed at ZimPost. Studies on these broad organising types have mainly focused on private sector organisations. However, this thesis argues that these analytical paradigms are also valid in public sector organisations, but they will unfold differently given the context in which change is experienced. Using a qualitative approach, the study established that the 1980s and 1990s can best be described as the ‘golden years’ of postal services in Zimbabwe, characterised by mass production and mass consumption of postal products and services. At that time the Posts and Telecommunications Corporation enjoyed a monopoly of postal services in the country. The stable market share, competitive salaries for postal workers, increased unionisation and a fairly stable economy enabled a Fordist regime of accumulation to develop. The cycle broke down when the mode of regulation was weakened by national economic and political changes towards the late 1990s. PTC started to experience a decline in the consumption of postal products. The decline was also attributed to increased competition from smaller private courier operators that could provide specialised services to a market with changing needs. With increased competition, the advancement of information, and communication technologies, mail volumes dwindled. This period can best be described as the crisis of Fordism at ZimPost. In the year 2000, the government unbundled the posts and telecommunications corporation to create four companies including Zimbabwe Posts. This was perceived as one of the most radical organisational changes in the history of postal services in Zimbabwe. More organisational changes took place at ZimPost that can best be described as characteristics of post-Fordism. These changes were attempts by ZimPost to remain relevant in light of the economic, political and technological changes taking place in the country. The postal operator introduced customised products in the form of agency services, supported by increased use of information and communication technologies in the post office. Organisational changes at ZimPost were shaped mainly by the economic and political environment in which they took place. Organisational change is complex, changes do not follow a linear pattern, they are processual. , Thesis (PhD) -- Faculty of Humanities, Sociology, 2023
- Full Text:
- Date Issued: 2022-10-14
Stock structure of Patagonian toothfish Dissostichus eleginoides (Smitt 1898, family Nototheniidae) in the Southwest Atlantic
- Authors: Lee, Brendon
- Date: 2022-10-14
- Subjects: Otoliths , Patagonian toothfish Geographical distribution , Fish tagging , Biogeography , Microstructure , Microchemistry
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/365599 , vital:65763 , DOI https://doi.org/10.21504/10962/365599
- Description: The identification of discrete self-sustaining productive units in marine populations is essential for achieving sustainable fisheries objectives. Marine fish populations frequently exhibit dynamic characteristics across their life-histories, displaying variability in spatial structure and mixing patterns, both within and among populations. The incoherent application of management boundaries on biological populations can bias stock assessment results and have important implications on sustainable fisheries management. Patagonian toothfish (Dissostichus eleginoides) is a long-lived, slow-growing, late-maturing, deep-sea, benthopelagic species. It forms the basis of important and highly lucrative industrial and artisanal fisheries across its distribution. Patagonian toothfish have complex life-histories characterised by high dispersal potential during the egg and larval phase, a wide depth range because of their ontogenetic migratory behaviour, and large adult size that is capable of undertaking long-distance active movements (>200 km). These characteristics provide opportunities for high levels of connectivity, and as such, the stock structure is not well understood. We applied an integrated, multidisciplinary approach to provide an improved understanding of the complex stock structure dynamics for Patagonian toothfish on the Patagonian Shelf, specifically in relation to the shelf, slope, and deep-sea plains around the Falkland Islands. Research results were focused on aspects pertaining to (1) geographic variation in phenotypic characters (otolith shape); (2) a description of the spatial-temporal distribution patterns; (3) the active movements of deep-sea adults (tag-recapture study); and (4) the identification of early life-history dispersal through otolith microstructure and microchemical chronologies. Results from the study indicate high regional connectivity during the early life-history stages derived from at least two spawning contingents into spatially discrete nursery areas (cohort groups) on the Falklands Shelf. Fish followed distinct ontogenetic pathways into deeper waters adjacent to the areas wherein juvenile settlement into a demersal habitat occurred. There is little to no evidence of mixing among cohort groups during their ontogenetic migration into deep-sea adult habitats, reflecting a mixed population based on oceanographically defined egg and larval dispersal. The majority of the adult component of the population continue to display high site fidelity. However, between 9 and 25% of the population, consisting predominantly of larger reproductively capable adults undertake long-distance dispersal behaviour, identified as home-range relocations from the adult deep-sea habitats towards three of the known southern spawning grounds in the region. Results are suggestive of a requirement for improved collaborative efforts for regionally-based management approaches with careful consideration of local stock contingents. Future monitoring and research priorities should focus on the identification of reproductive potential, dispersal pathways and settlement patterns of stock contingents to inform the dynamics of mixed stock origins across the Patagonian region. While many aspects regarding the stock structure remain unresolved, results derived from the current studies can be used to inform the development of management measures to ensure the continued recovery and sustainable management of Patagonian toothfish within the region. , Thesis (PhD) -- Faculty of Science, Ichthyology and Fisheries Science, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Lee, Brendon
- Date: 2022-10-14
- Subjects: Otoliths , Patagonian toothfish Geographical distribution , Fish tagging , Biogeography , Microstructure , Microchemistry
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/365599 , vital:65763 , DOI https://doi.org/10.21504/10962/365599
- Description: The identification of discrete self-sustaining productive units in marine populations is essential for achieving sustainable fisheries objectives. Marine fish populations frequently exhibit dynamic characteristics across their life-histories, displaying variability in spatial structure and mixing patterns, both within and among populations. The incoherent application of management boundaries on biological populations can bias stock assessment results and have important implications on sustainable fisheries management. Patagonian toothfish (Dissostichus eleginoides) is a long-lived, slow-growing, late-maturing, deep-sea, benthopelagic species. It forms the basis of important and highly lucrative industrial and artisanal fisheries across its distribution. Patagonian toothfish have complex life-histories characterised by high dispersal potential during the egg and larval phase, a wide depth range because of their ontogenetic migratory behaviour, and large adult size that is capable of undertaking long-distance active movements (>200 km). These characteristics provide opportunities for high levels of connectivity, and as such, the stock structure is not well understood. We applied an integrated, multidisciplinary approach to provide an improved understanding of the complex stock structure dynamics for Patagonian toothfish on the Patagonian Shelf, specifically in relation to the shelf, slope, and deep-sea plains around the Falkland Islands. Research results were focused on aspects pertaining to (1) geographic variation in phenotypic characters (otolith shape); (2) a description of the spatial-temporal distribution patterns; (3) the active movements of deep-sea adults (tag-recapture study); and (4) the identification of early life-history dispersal through otolith microstructure and microchemical chronologies. Results from the study indicate high regional connectivity during the early life-history stages derived from at least two spawning contingents into spatially discrete nursery areas (cohort groups) on the Falklands Shelf. Fish followed distinct ontogenetic pathways into deeper waters adjacent to the areas wherein juvenile settlement into a demersal habitat occurred. There is little to no evidence of mixing among cohort groups during their ontogenetic migration into deep-sea adult habitats, reflecting a mixed population based on oceanographically defined egg and larval dispersal. The majority of the adult component of the population continue to display high site fidelity. However, between 9 and 25% of the population, consisting predominantly of larger reproductively capable adults undertake long-distance dispersal behaviour, identified as home-range relocations from the adult deep-sea habitats towards three of the known southern spawning grounds in the region. Results are suggestive of a requirement for improved collaborative efforts for regionally-based management approaches with careful consideration of local stock contingents. Future monitoring and research priorities should focus on the identification of reproductive potential, dispersal pathways and settlement patterns of stock contingents to inform the dynamics of mixed stock origins across the Patagonian region. While many aspects regarding the stock structure remain unresolved, results derived from the current studies can be used to inform the development of management measures to ensure the continued recovery and sustainable management of Patagonian toothfish within the region. , Thesis (PhD) -- Faculty of Science, Ichthyology and Fisheries Science, 2022
- Full Text:
- Date Issued: 2022-10-14
Synthesis, characterization and host-guest complexes of supramolecular assemblies based on calixarenes and cucurbiturils
- Authors: Baa, Ebenezer
- Date: 2022-10-14
- Subjects: Supramolecular chemistry , Calixarenes , Cucurbiturils , Metal-organic frameworks , Macrocyclic compounds , Drug delivery systems
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/365621 , vital:65765 , DOI https://doi.org/10.21504/10962/365621
- Description: The field of supramolecular chemistry has grown large and wide in both deepness of understanding, range of topics covered and scope and applications. Supramolecular self-assemblies are facilitated by a wide range of non-covalent intra and inter molecular interactions that range from hydrogen bonding to π-interaction and van der Waals. Macrocyclic compounds such as cucurbiturils and calixarenes have emerged as important classes of compounds with excellent potential of forming supramolecular assemblies. The porous nature of these compounds enables them to form host-guest supramolecular complexes stabilized by diverse range of non-covalent interactions. Furthermore, these compounds contain donor atoms capable of forming bonds with metal ions to yield metal complexes with interesting porous characteristics that deviate from their traditional hydrophobic cavity. The versatile nature of the resulting pores imply that they can accommodate diverse types of guests. This work explores the synthesis and characterization of a host of calixarenes and cucurbiturils. Self-assembly of these macrocycles with various metal ions results to the formation of porous metal organic framework (MOF) complexes. Four new calixarene typed compounds obtained from aromatic aldehydes and twenty-six cucurbituril metal complexes are reported. These macrocylces and their metal complexes also form supramolecular complexes with DMSO, methanol, isoniazid hydrochloride and ciprofloxacin hydrochlorides through either self-assembly, mechanochemistry and exposure to solvent vapors. The bulk materials have been characterized using nuclear magnetic resonance spectroscopy (NMR), Fourier transformed infrared spectroscopy (FTIR), powder and single crystal diffraction techniques and thermal studies thermogravimetric analysis (TGA) and differential thermal calorimetry (DSC). Data obtained from this study reveals that calixarenes can form supramolecular complexes with a frequently used laboratory solvents with BN22 showing appreciable selectivity for DMSO sorption from a solvent mixture. These compounds also form supramolecular complexes with drug molecules such as isoniazid and ciprofloxacin. Furthermore, the data reveals that choice of synthetic route of supramolecular ensembles dictates if the guest drug molecule will occupy the intrinsic or extrinsic pores of cucurbituril complexes. Biological studies on the obtained complexes reveal that the cucurbituril complexes are non-cytotoxic while the calixarenes show antibacterial activity against Escherichia coli and Staphylococcus aureus. Additionally, the study showed that ciprofloxacin can be successfully released from a calixarene host in a simulated body fluid although the host was also found to cross the dialysis membrane. The results of this study are important in that; - they can be exploited and developed in the selective sorption of certain guests and - that they can be used in the development of drug delivery systems that play a dual role of delivery and therapeutic activity. , Thesis (PhD) -- Faculty of Science, Chemistry, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Baa, Ebenezer
- Date: 2022-10-14
- Subjects: Supramolecular chemistry , Calixarenes , Cucurbiturils , Metal-organic frameworks , Macrocyclic compounds , Drug delivery systems
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/365621 , vital:65765 , DOI https://doi.org/10.21504/10962/365621
- Description: The field of supramolecular chemistry has grown large and wide in both deepness of understanding, range of topics covered and scope and applications. Supramolecular self-assemblies are facilitated by a wide range of non-covalent intra and inter molecular interactions that range from hydrogen bonding to π-interaction and van der Waals. Macrocyclic compounds such as cucurbiturils and calixarenes have emerged as important classes of compounds with excellent potential of forming supramolecular assemblies. The porous nature of these compounds enables them to form host-guest supramolecular complexes stabilized by diverse range of non-covalent interactions. Furthermore, these compounds contain donor atoms capable of forming bonds with metal ions to yield metal complexes with interesting porous characteristics that deviate from their traditional hydrophobic cavity. The versatile nature of the resulting pores imply that they can accommodate diverse types of guests. This work explores the synthesis and characterization of a host of calixarenes and cucurbiturils. Self-assembly of these macrocycles with various metal ions results to the formation of porous metal organic framework (MOF) complexes. Four new calixarene typed compounds obtained from aromatic aldehydes and twenty-six cucurbituril metal complexes are reported. These macrocylces and their metal complexes also form supramolecular complexes with DMSO, methanol, isoniazid hydrochloride and ciprofloxacin hydrochlorides through either self-assembly, mechanochemistry and exposure to solvent vapors. The bulk materials have been characterized using nuclear magnetic resonance spectroscopy (NMR), Fourier transformed infrared spectroscopy (FTIR), powder and single crystal diffraction techniques and thermal studies thermogravimetric analysis (TGA) and differential thermal calorimetry (DSC). Data obtained from this study reveals that calixarenes can form supramolecular complexes with a frequently used laboratory solvents with BN22 showing appreciable selectivity for DMSO sorption from a solvent mixture. These compounds also form supramolecular complexes with drug molecules such as isoniazid and ciprofloxacin. Furthermore, the data reveals that choice of synthetic route of supramolecular ensembles dictates if the guest drug molecule will occupy the intrinsic or extrinsic pores of cucurbituril complexes. Biological studies on the obtained complexes reveal that the cucurbituril complexes are non-cytotoxic while the calixarenes show antibacterial activity against Escherichia coli and Staphylococcus aureus. Additionally, the study showed that ciprofloxacin can be successfully released from a calixarene host in a simulated body fluid although the host was also found to cross the dialysis membrane. The results of this study are important in that; - they can be exploited and developed in the selective sorption of certain guests and - that they can be used in the development of drug delivery systems that play a dual role of delivery and therapeutic activity. , Thesis (PhD) -- Faculty of Science, Chemistry, 2022
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- Date Issued: 2022-10-14