Treating complex post-traumatic stress disorder following childhood neglect, sexual abuse and revictimisation : interpretative reflections on the case of Khuselwa
- Padmanabhanunni, A, Edwards, David J A
- Authors: Padmanabhanunni, A , Edwards, David J A
- Date: 2012
- Language: English
- Type: Article
- Identifier: vital:6233 , http://hdl.handle.net/10962/d1007783
- Description: This paper describes the psychological assessment and treatment process with Khuselwa, a South African adolescent survivor of multiple sexual traumas presenting with complex post-traumatic stress disorder (PTSD). The paper identifies some of the common barriers encountered by practitioners in delivering treatments in local contexts and highlights the role of external safety and stability and social support in providing a vehicle for change and a basis for overcoming the psychological handicaps reinforced by repeated and multiple traumas and chronic neglect.
- Full Text:
- Date Issued: 2012
- Authors: Padmanabhanunni, A , Edwards, David J A
- Date: 2012
- Language: English
- Type: Article
- Identifier: vital:6233 , http://hdl.handle.net/10962/d1007783
- Description: This paper describes the psychological assessment and treatment process with Khuselwa, a South African adolescent survivor of multiple sexual traumas presenting with complex post-traumatic stress disorder (PTSD). The paper identifies some of the common barriers encountered by practitioners in delivering treatments in local contexts and highlights the role of external safety and stability and social support in providing a vehicle for change and a basis for overcoming the psychological handicaps reinforced by repeated and multiple traumas and chronic neglect.
- Full Text:
- Date Issued: 2012
Treatment of post traumatic stress disorder following an armed robbery : a case study testing the transportability of trauma-focused cognitive-behavioural therapy to urban Africans
- Drake, B, Edwards, David J A
- Authors: Drake, B , Edwards, David J A
- Date: 2012
- Language: English
- Type: Article
- Identifier: vital:6225 , http://hdl.handle.net/10962/d1007775
- Description: John, an urban African male who developed post traumatic stress disorder (PTSD) following an armed robbery at the petrol station where he worked, was treated with 12 sessions of Trauma-focused cognitive behaviour therapy. Intervention involved a combination of psycho-education, prolonged imaginal exposure, cognitive restructuring and behavioural assignments. This article is a systematic case study of his treatment which included a comprehensive narrative and tracking of progress by means of the Post traumatic Diagnostic Scale. John responded well to the treatment, finding it acceptable and credible and remained free of PTSD symptoms at 15 months follow up. It is argued, based on the principles of Elliott’s Hermeneutic Single Case Efficacy Design, that there is evidence from within the narrative that it was the treatment that led to remission of symptoms. This case study demonstrates the cognitive, emotional and behavioural processes underlying John’s PTSD, which fits with those extensively described in the research literature, and that this evidence-based treatment developed in a westernised context is transportable to work with urban Africans.
- Full Text:
- Date Issued: 2012
- Authors: Drake, B , Edwards, David J A
- Date: 2012
- Language: English
- Type: Article
- Identifier: vital:6225 , http://hdl.handle.net/10962/d1007775
- Description: John, an urban African male who developed post traumatic stress disorder (PTSD) following an armed robbery at the petrol station where he worked, was treated with 12 sessions of Trauma-focused cognitive behaviour therapy. Intervention involved a combination of psycho-education, prolonged imaginal exposure, cognitive restructuring and behavioural assignments. This article is a systematic case study of his treatment which included a comprehensive narrative and tracking of progress by means of the Post traumatic Diagnostic Scale. John responded well to the treatment, finding it acceptable and credible and remained free of PTSD symptoms at 15 months follow up. It is argued, based on the principles of Elliott’s Hermeneutic Single Case Efficacy Design, that there is evidence from within the narrative that it was the treatment that led to remission of symptoms. This case study demonstrates the cognitive, emotional and behavioural processes underlying John’s PTSD, which fits with those extensively described in the research literature, and that this evidence-based treatment developed in a westernised context is transportable to work with urban Africans.
- Full Text:
- Date Issued: 2012
Western alumnae influencing the world
- Authors: Steyaert, Marcia
- Date: 2012
- Subjects: Nyokong, Tebello
- Language: English
- Type: Article , text
- Identifier: vital:7168 , http://hdl.handle.net/10962/d1006069 , Nyokong, Tebello
- Description: In September 2011, IT News Africa, named two Western alumnae, Uche Eze, HBA'06, and Tebello Nyokong, PhD1987 (Chemistry) in their list of top 10 most influential women in science and technology in Africa. Nyokong is a professor of medicinal chemistry and nanotechnology at Rhodes University and is recognized as one of the top three publishing scientists in South Africa.
- Full Text:
- Date Issued: 2012
- Authors: Steyaert, Marcia
- Date: 2012
- Subjects: Nyokong, Tebello
- Language: English
- Type: Article , text
- Identifier: vital:7168 , http://hdl.handle.net/10962/d1006069 , Nyokong, Tebello
- Description: In September 2011, IT News Africa, named two Western alumnae, Uche Eze, HBA'06, and Tebello Nyokong, PhD1987 (Chemistry) in their list of top 10 most influential women in science and technology in Africa. Nyokong is a professor of medicinal chemistry and nanotechnology at Rhodes University and is recognized as one of the top three publishing scientists in South Africa.
- Full Text:
- Date Issued: 2012
The Educational Journal
- Date: 2011-09
- Subjects: Education – South Africa , South Africa – Economic conditions , South Africa – Social conditions
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/41687 , vital:36555 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa. From the 2000s, the journal was published by the National Union of Public Service and Allied Workers (NUPSAW), a trade union formed in August 1998 from the amalgamation of militant and moderate trade unions and also operated in the education sphere.
- Full Text: false
- Date Issued: 2011-09
- Date: 2011-09
- Subjects: Education – South Africa , South Africa – Economic conditions , South Africa – Social conditions
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/41687 , vital:36555 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa. From the 2000s, the journal was published by the National Union of Public Service and Allied Workers (NUPSAW), a trade union formed in August 1998 from the amalgamation of militant and moderate trade unions and also operated in the education sphere.
- Full Text: false
- Date Issued: 2011-09
APDUSA Views
- Date: 2011-06
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10948/33486 , vital:32879 , Bulk File 7
- Description: APDUSA Views was published by the African People’s Democratic Union of Southern Africa (Natal), an affiliate of the New Unity Movement.
- Full Text: false
- Date Issued: 2011-06
- Date: 2011-06
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10948/33486 , vital:32879 , Bulk File 7
- Description: APDUSA Views was published by the African People’s Democratic Union of Southern Africa (Natal), an affiliate of the New Unity Movement.
- Full Text: false
- Date Issued: 2011-06
APDUSA Views
- Date: 2011- 06
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/33536 , vital:32884 , Bulk File 7
- Description: APDUSA Views was published by the African People’s Democratic Union of Southern Africa (Natal), an affiliate of the New Unity Movement.
- Full Text: false
- Date Issued: 2011- 06
- Date: 2011- 06
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/33536 , vital:32884 , Bulk File 7
- Description: APDUSA Views was published by the African People’s Democratic Union of Southern Africa (Natal), an affiliate of the New Unity Movement.
- Full Text: false
- Date Issued: 2011- 06
3000 miles from home: a new Gastrosericus baobabicus Pulawski, 1995 (Hymenoptera, Larridae) distribution record highlights that the Sahel has a distinct entomofaunal signature
- Clitheroe, C-L, Villet, Martin H
- Authors: Clitheroe, C-L , Villet, Martin H
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6846 , http://hdl.handle.net/10962/d1011099
- Description: [from introduction] On October 30, 1953, an unidentified female wasp (Fig. 1) was collected from ‘Belet Uen, Somaliland’ (= Beledweyne, 4°44’N 45°12’E), situated in the valley of the Shebelle River, HiraanProvince,Somalia. It was deposited in the aculeate Hymenoptera collection of the Albany Museum, Grahamstown by D. Greathead prior to 1968. Apart from the words ‘Somaliland’ and ‘Desert Locust Survey’ the label is handwritten and the collector’snameis not recorded. Greathead’s sister, S. Gess (Albany Museum), deciphered the label and stated that he had worked for the Desert Locust Survey, investigating the natural enemies of locusts and had been in Somalia (then Somaliland) at that time (Murphy & Cock 2007). The specimen was sent in 2004 by F. Gess to W. Pulawski, who determined it as Gastrosericus baobabicus Pulawski, 1995. Gastrosericus species prey on spiders and a variety of small insects (Pulawski 1995), including Orthoptera (Krombein & Pulawski 1986), so it is likely that Greathead collected the specimen in connection with his interest in the insect enemies of Acridoidea (Orthoptera) (Greathead 1962).
- Full Text:
- Date Issued: 2011
- Authors: Clitheroe, C-L , Villet, Martin H
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6846 , http://hdl.handle.net/10962/d1011099
- Description: [from introduction] On October 30, 1953, an unidentified female wasp (Fig. 1) was collected from ‘Belet Uen, Somaliland’ (= Beledweyne, 4°44’N 45°12’E), situated in the valley of the Shebelle River, HiraanProvince,Somalia. It was deposited in the aculeate Hymenoptera collection of the Albany Museum, Grahamstown by D. Greathead prior to 1968. Apart from the words ‘Somaliland’ and ‘Desert Locust Survey’ the label is handwritten and the collector’snameis not recorded. Greathead’s sister, S. Gess (Albany Museum), deciphered the label and stated that he had worked for the Desert Locust Survey, investigating the natural enemies of locusts and had been in Somalia (then Somaliland) at that time (Murphy & Cock 2007). The specimen was sent in 2004 by F. Gess to W. Pulawski, who determined it as Gastrosericus baobabicus Pulawski, 1995. Gastrosericus species prey on spiders and a variety of small insects (Pulawski 1995), including Orthoptera (Krombein & Pulawski 1986), so it is likely that Greathead collected the specimen in connection with his interest in the insect enemies of Acridoidea (Orthoptera) (Greathead 1962).
- Full Text:
- Date Issued: 2011
A South African response to ethics in legal education
- Authors: Kruuse, Helen
- Date: 2011
- Language: English
- Type: Article , text
- Identifier: http://hdl.handle.net/10962/54174 , vital:26399 , https://www.routledge.com/The-Ethics-Project-in-Legal-Education/Robertson-Corbin-Tranter-Bartlett/p/book/9780415546515
- Description: The contributions in this volume suggest that "the ethics project in legal education" is increasingly an international one. Even though the strength of commitment by both the profession and the legal academy to "ethics learning" within law schools varies, two fundamental questions confront all who work in this area. First, what is it that we want our students to learn (or, perhaps, in what manner do we want our students to develop) from the teaching of "legal ethics"? Second, how can we create a learning environment that will encourage the nature and quality of learning we think is important?.
- Full Text: false
- Date Issued: 2011
- Authors: Kruuse, Helen
- Date: 2011
- Language: English
- Type: Article , text
- Identifier: http://hdl.handle.net/10962/54174 , vital:26399 , https://www.routledge.com/The-Ethics-Project-in-Legal-Education/Robertson-Corbin-Tranter-Bartlett/p/book/9780415546515
- Description: The contributions in this volume suggest that "the ethics project in legal education" is increasingly an international one. Even though the strength of commitment by both the profession and the legal academy to "ethics learning" within law schools varies, two fundamental questions confront all who work in this area. First, what is it that we want our students to learn (or, perhaps, in what manner do we want our students to develop) from the teaching of "legal ethics"? Second, how can we create a learning environment that will encourage the nature and quality of learning we think is important?.
- Full Text: false
- Date Issued: 2011
Above ground woody community attributes, biomass and carbon stocks along a rainfall gradient in the savannas of the central lowveld, South Africa
- Shackleton, Charlie M, Scholes, Robert J
- Authors: Shackleton, Charlie M , Scholes, Robert J
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6658 , http://hdl.handle.net/10962/d1007079
- Description: Enumeration of carbon stocks at benchmark sites is a necessary activity in assessing the potential carbon sequestration and possible generation of credits through restoration of intensively impacted sites. However, there is a lack of empirical studies throughout much of the savannas of sub-Saharan Africa, including South Africa. We report an estimation of species specific and site biomass and carbon stocks, and general vegetation structural attributes from three protected areas along a rainfall gradient in the central lowveld, South Africa. Estimates of biomass and carbon stocks were effected through destructive sampling to establish locally derived allometric equations. There was a gradient of increasing woody density, height of the canopy, number of species, density of regenerative stems and a greater proportion of stems in small size classes from the arid locality to the mesic locality, with the semi-arid locality being intermediate. The proportion of spinescent species decreased with increasing rainfall. The mesic locality was significantly more woody than either the arid or semi-arid sites, having double the biomass, four times the density and 40% higher basal area. Above ground carbon pools were also higher; carbon stocks were approximately 9 t/ha for the arid and semi-arid sites and 18 t/ha for the mesic site.
- Full Text:
- Date Issued: 2011
- Authors: Shackleton, Charlie M , Scholes, Robert J
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6658 , http://hdl.handle.net/10962/d1007079
- Description: Enumeration of carbon stocks at benchmark sites is a necessary activity in assessing the potential carbon sequestration and possible generation of credits through restoration of intensively impacted sites. However, there is a lack of empirical studies throughout much of the savannas of sub-Saharan Africa, including South Africa. We report an estimation of species specific and site biomass and carbon stocks, and general vegetation structural attributes from three protected areas along a rainfall gradient in the central lowveld, South Africa. Estimates of biomass and carbon stocks were effected through destructive sampling to establish locally derived allometric equations. There was a gradient of increasing woody density, height of the canopy, number of species, density of regenerative stems and a greater proportion of stems in small size classes from the arid locality to the mesic locality, with the semi-arid locality being intermediate. The proportion of spinescent species decreased with increasing rainfall. The mesic locality was significantly more woody than either the arid or semi-arid sites, having double the biomass, four times the density and 40% higher basal area. Above ground carbon pools were also higher; carbon stocks were approximately 9 t/ha for the arid and semi-arid sites and 18 t/ha for the mesic site.
- Full Text:
- Date Issued: 2011
Culture as a discursive resource opposing legal abortion
- Macleod, Catriona I, Sigcau, Nomakhosi, Luwaca, Pumeza
- Authors: Macleod, Catriona I , Sigcau, Nomakhosi , Luwaca, Pumeza
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6293 , http://hdl.handle.net/10962/d1014721 , http://dx.doi.org/10.1080/09581596.2010.492211
- Description: The notion of ‘culture’ features in the abortion literature to explicate, first, contestation of the meaning of abortion (as in the ‘culture wars’ about abortion), second, the normalisation of abortion in certain countries (as in ‘abortion culture’), third, the response of women to abortion within a particular social milieu and fourth, cross-cultural variability in attitudes towards and experiences of abortion. What is missing is an exploration of how ‘culture’ may be deployed as a discursive resource to oppose legal abortion. In this article, we report on a study conducted in a rural area of South Africa. We conducted focus group discussions utilising hypothetical vignettes to stimulate talk. Although, inconsistencies were evident in participants’ talk, in the context of cultural discussions, abortion was constructed as killing and inevitably destructive of cultural values and traditions. Abortion was equated with colonialist interventions and as something that should be opposed in the preservation of culture. Furthermore, cultural opposition to abortion was rooted in fears around the breakdown of gendered and generational power relations. Examples of how culture may be used in everyday interactions to induce shame and negative experiences are also discussed.
- Full Text:
- Date Issued: 2011
- Authors: Macleod, Catriona I , Sigcau, Nomakhosi , Luwaca, Pumeza
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6293 , http://hdl.handle.net/10962/d1014721 , http://dx.doi.org/10.1080/09581596.2010.492211
- Description: The notion of ‘culture’ features in the abortion literature to explicate, first, contestation of the meaning of abortion (as in the ‘culture wars’ about abortion), second, the normalisation of abortion in certain countries (as in ‘abortion culture’), third, the response of women to abortion within a particular social milieu and fourth, cross-cultural variability in attitudes towards and experiences of abortion. What is missing is an exploration of how ‘culture’ may be deployed as a discursive resource to oppose legal abortion. In this article, we report on a study conducted in a rural area of South Africa. We conducted focus group discussions utilising hypothetical vignettes to stimulate talk. Although, inconsistencies were evident in participants’ talk, in the context of cultural discussions, abortion was constructed as killing and inevitably destructive of cultural values and traditions. Abortion was equated with colonialist interventions and as something that should be opposed in the preservation of culture. Furthermore, cultural opposition to abortion was rooted in fears around the breakdown of gendered and generational power relations. Examples of how culture may be used in everyday interactions to induce shame and negative experiences are also discussed.
- Full Text:
- Date Issued: 2011
Designer ligands : the search for metal ion selectivity
- Authors: Kaye, P T
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6576 , http://hdl.handle.net/10962/d1004139
- Description: The paper reviews research conducted at Rhodes University towards the development of metal-selective ligands. The research has focused on the rational design, synthesis and evaluation of novel ligands for use in the formation of copper complexes as biomimetic models of the metalloenzyme, tyrosinase, and for the selective extraction of silver, nickel and platinum group metal ions in the presence of contaminating metal ions. Attention has also been given to the development of efficient, metal-selective molecular imprinted polymers.
- Full Text:
- Date Issued: 2011
- Authors: Kaye, P T
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6576 , http://hdl.handle.net/10962/d1004139
- Description: The paper reviews research conducted at Rhodes University towards the development of metal-selective ligands. The research has focused on the rational design, synthesis and evaluation of novel ligands for use in the formation of copper complexes as biomimetic models of the metalloenzyme, tyrosinase, and for the selective extraction of silver, nickel and platinum group metal ions in the presence of contaminating metal ions. Attention has also been given to the development of efficient, metal-selective molecular imprinted polymers.
- Full Text:
- Date Issued: 2011
Dimethylglyoxime based ion-imprinted polymer for the determination of Ni(II) ions from aqueous samples
- Rammika, M, Darko, G, Tshentu, Z, Sewry, J D, Torto, N
- Authors: Rammika, M , Darko, G , Tshentu, Z , Sewry, J D , Torto, N
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6590 , http://hdl.handle.net/10962/d1004173
- Description: A Ni(II)-dimethylglyoxime ion-imprinted polymer {Ni(II)-DMG IIP} was synthesised by the bulk polymerisation method. The morphology of the Ni(II)-DMG IIP and non-imprinted polymer were observed by scanning electron microscopy and the chemical structures were evaluated by infrared spectroscopy. Selectivity of the Ni(II)-DMG IIP was studied by analysing, using an inductively coupled plasma-optical emission spectrometer, for Ni(II) ions that were spiked with varying concentrations of Co(II), Cu(II), Zn(II), Pd(II), Fe(II), Ca(II), Mg(II), Na(I) and K(I) in aqueous samples. The studies revealed Ni(II) recoveries ranging from 93 to 100% in aqueous solutions with minimal interference from competing ions. Enrichment factors ranged from 2 to 18 with a binding capacity of 120 μg∙g−1. Co(II) was the only ion found to slightly interfere with the determination of Ni(II). Selectivity studies confirmed that the Ni(II)-DMG IIP had very good selectivity, characterised by %RSD of less than 5%. The limits of detection and quantification were 3x10-4 μg∙mℓ−1 and 9x10-4 μg∙mℓ−1, respectively. The accuracy of the method was validated by analysing a custom solution of certified reference material (SEP-3) and the concentration of Ni(II) obtained was in close agreement with the certified one. The Ni(II)-DMG IIP was successfully employed to trap Ni(II) ions from a matrix of sea, river and sewage water. It is believed that the Ni(II)-DMG IIP has potential to be used as sorbent material for pre-concentration of Ni(II) ions from aqueous solutions by solid-phase extraction.
- Full Text:
- Date Issued: 2011
- Authors: Rammika, M , Darko, G , Tshentu, Z , Sewry, J D , Torto, N
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6590 , http://hdl.handle.net/10962/d1004173
- Description: A Ni(II)-dimethylglyoxime ion-imprinted polymer {Ni(II)-DMG IIP} was synthesised by the bulk polymerisation method. The morphology of the Ni(II)-DMG IIP and non-imprinted polymer were observed by scanning electron microscopy and the chemical structures were evaluated by infrared spectroscopy. Selectivity of the Ni(II)-DMG IIP was studied by analysing, using an inductively coupled plasma-optical emission spectrometer, for Ni(II) ions that were spiked with varying concentrations of Co(II), Cu(II), Zn(II), Pd(II), Fe(II), Ca(II), Mg(II), Na(I) and K(I) in aqueous samples. The studies revealed Ni(II) recoveries ranging from 93 to 100% in aqueous solutions with minimal interference from competing ions. Enrichment factors ranged from 2 to 18 with a binding capacity of 120 μg∙g−1. Co(II) was the only ion found to slightly interfere with the determination of Ni(II). Selectivity studies confirmed that the Ni(II)-DMG IIP had very good selectivity, characterised by %RSD of less than 5%. The limits of detection and quantification were 3x10-4 μg∙mℓ−1 and 9x10-4 μg∙mℓ−1, respectively. The accuracy of the method was validated by analysing a custom solution of certified reference material (SEP-3) and the concentration of Ni(II) obtained was in close agreement with the certified one. The Ni(II)-DMG IIP was successfully employed to trap Ni(II) ions from a matrix of sea, river and sewage water. It is believed that the Ni(II)-DMG IIP has potential to be used as sorbent material for pre-concentration of Ni(II) ions from aqueous solutions by solid-phase extraction.
- Full Text:
- Date Issued: 2011
Diverse pollination systems of the twin-spurred orchid genus Satyrium in African grasslands
- Johnson, S.D, Peter, C.I, Ellis, A.G, Boberg, E, Botes, C, Van der Niet, T
- Authors: Johnson, S.D , Peter, C.I , Ellis, A.G , Boberg, E , Botes, C , Van der Niet, T
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6558 , http://hdl.handle.net/10962/d1006025 , http://dx.doi.org/10.1007/s00606-010-0411-1
- Description: The large terrestrial orchid genus Satyrium underwent evolutionary radiations in the Cape floral region and the grasslands of southern and eastern Africa. These radiations were accompanied by tremendous diversification of the unusual twin-spurred flowers that characterize the genus, but pollination data required to interpret these patterns of floral evolution have been lacking for grassland species in the genus. Here we document pollinators, nectar properties, and levels of pollination success for 11 grassland Satyrium species in southern and south-central Africa. Pollinators of these species include bees, beetles, butterflies, hawkmoths, noctuid moths, long-proboscid flies, and sunbirds. Most species appear to be specialized for pollination by one functional pollinator group. Long-proboscid fly pollination systems are reported for the first time in Satyrium (in S. macrophyllum and a high-altitude form of S. neglectum). Floral morphology, especially spur length and rostellum structure, differs markedly among plants with different pollinators, while nectar volume, concentration, and sugar composition are fairly uniform across species. Most taxa exhibited high levels of pollination success (>50% of flowers pollinated), a trend that can be attributed to the presence of nectar in the twin spurs.
- Full Text:
- Date Issued: 2011
- Authors: Johnson, S.D , Peter, C.I , Ellis, A.G , Boberg, E , Botes, C , Van der Niet, T
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6558 , http://hdl.handle.net/10962/d1006025 , http://dx.doi.org/10.1007/s00606-010-0411-1
- Description: The large terrestrial orchid genus Satyrium underwent evolutionary radiations in the Cape floral region and the grasslands of southern and eastern Africa. These radiations were accompanied by tremendous diversification of the unusual twin-spurred flowers that characterize the genus, but pollination data required to interpret these patterns of floral evolution have been lacking for grassland species in the genus. Here we document pollinators, nectar properties, and levels of pollination success for 11 grassland Satyrium species in southern and south-central Africa. Pollinators of these species include bees, beetles, butterflies, hawkmoths, noctuid moths, long-proboscid flies, and sunbirds. Most species appear to be specialized for pollination by one functional pollinator group. Long-proboscid fly pollination systems are reported for the first time in Satyrium (in S. macrophyllum and a high-altitude form of S. neglectum). Floral morphology, especially spur length and rostellum structure, differs markedly among plants with different pollinators, while nectar volume, concentration, and sugar composition are fairly uniform across species. Most taxa exhibited high levels of pollination success (>50% of flowers pollinated), a trend that can be attributed to the presence of nectar in the twin spurs.
- Full Text:
- Date Issued: 2011
Does the growth of structure affect our dynamical models of the Universe? The averaging, backreaction, and fitting problems in cosmology
- Clarkson, C, Ellis, G, Larena, Julien, Umeh, O
- Authors: Clarkson, C , Ellis, G , Larena, Julien , Umeh, O
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6791 , http://hdl.handle.net/10962/d1006944
- Description: Structure occurs over a vast range of scales in the Universe. Our large-scale cosmological models are coarse-grained representations of what exists, which have much less structure than there really is. An important problem for cosmology is determining the influence the small-scale structure in the Universe has on its large-scale dynamics and observations. Is there a significant, general relativistic, backreaction effect from averaging over structure? One issue is whether the process of smoothing over structure can contribute to an acceleration term and so alter the apparent value of the cosmological constant. If this is not the case, are there other aspects of concordance cosmology that are affected by backreaction effects? Despite much progress, this 'averaging problem' is still unanswered, but it cannot be ignored in an era of precision cosmology, for instance it may affect aspects of baryon acoustic oscillation observations.
- Full Text:
- Date Issued: 2011
- Authors: Clarkson, C , Ellis, G , Larena, Julien , Umeh, O
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6791 , http://hdl.handle.net/10962/d1006944
- Description: Structure occurs over a vast range of scales in the Universe. Our large-scale cosmological models are coarse-grained representations of what exists, which have much less structure than there really is. An important problem for cosmology is determining the influence the small-scale structure in the Universe has on its large-scale dynamics and observations. Is there a significant, general relativistic, backreaction effect from averaging over structure? One issue is whether the process of smoothing over structure can contribute to an acceleration term and so alter the apparent value of the cosmological constant. If this is not the case, are there other aspects of concordance cosmology that are affected by backreaction effects? Despite much progress, this 'averaging problem' is still unanswered, but it cannot be ignored in an era of precision cosmology, for instance it may affect aspects of baryon acoustic oscillation observations.
- Full Text:
- Date Issued: 2011
Elucidation of the complex Baylis-Hillman reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone
- Idahosa, Kenudi C, Molefe, Duduzile M, Pakade, Vusumzi E, Brown, Michael E
- Authors: Idahosa, Kenudi C , Molefe, Duduzile M , Pakade, Vusumzi E , Brown, Michael E
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6574 , http://hdl.handle.net/10962/d1004137
- Description: DABCO-catalyzed reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone (MVK) affords a mixture of products, comprising the ‘normal’ Baylis-Hillman adduct, theMVKdimer and a pair of diastereomeric bis-(MVK)Baylis-Hillman adducts. 1HNMRspectroscopy-based kinetic studies have provided clear insights into the competing pathways and product distribution in this complex reaction.
- Full Text:
- Date Issued: 2011
- Authors: Idahosa, Kenudi C , Molefe, Duduzile M , Pakade, Vusumzi E , Brown, Michael E
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6574 , http://hdl.handle.net/10962/d1004137
- Description: DABCO-catalyzed reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone (MVK) affords a mixture of products, comprising the ‘normal’ Baylis-Hillman adduct, theMVKdimer and a pair of diastereomeric bis-(MVK)Baylis-Hillman adducts. 1HNMRspectroscopy-based kinetic studies have provided clear insights into the competing pathways and product distribution in this complex reaction.
- Full Text:
- Date Issued: 2011
Energy versus angular momentum in black hole binaries
- Damour, T, Nagar, A, Pollney, D, Reisswig, C
- Authors: Damour, T , Nagar, A , Pollney, D , Reisswig, C
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6792 , http://hdl.handle.net/10962/d1006946
- Description: Using accurate numerical-relativity simulations of (nonspinning) black-hole binaries with mass ratios 1∶1, 2∶1, and 3∶1, we compute the gauge-invariant relation between the (reduced) binding energy E and the (reduced) angular momentum j of the system. We show that the relation E(j) is an accurate diagnostic of the dynamics of a black-hole binary in a highly relativistic regime. By comparing the numerical-relativity ENR(j) curve with the predictions of several analytic approximation schemes, we find that, while the canonically defined, nonresummed post-Newtonian–expanded EPN(j) relation exhibits large and growing deviations from ENR(j), the prediction of the effective one body formalism, based purely on known analytical results (without any calibration to numerical relativity), agrees strikingly well with the numerical-relativity results.
- Full Text:
- Date Issued: 2011
- Authors: Damour, T , Nagar, A , Pollney, D , Reisswig, C
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6792 , http://hdl.handle.net/10962/d1006946
- Description: Using accurate numerical-relativity simulations of (nonspinning) black-hole binaries with mass ratios 1∶1, 2∶1, and 3∶1, we compute the gauge-invariant relation between the (reduced) binding energy E and the (reduced) angular momentum j of the system. We show that the relation E(j) is an accurate diagnostic of the dynamics of a black-hole binary in a highly relativistic regime. By comparing the numerical-relativity ENR(j) curve with the predictions of several analytic approximation schemes, we find that, while the canonically defined, nonresummed post-Newtonian–expanded EPN(j) relation exhibits large and growing deviations from ENR(j), the prediction of the effective one body formalism, based purely on known analytical results (without any calibration to numerical relativity), agrees strikingly well with the numerical-relativity results.
- Full Text:
- Date Issued: 2011
Evaluating the Wald entropy from two-derivative terms in quadratic actions
- Brustein, R, Gorbonos, D, Hadad, M, Medved, A J M
- Authors: Brustein, R , Gorbonos, D , Hadad, M , Medved, A J M
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6816 , http://hdl.handle.net/10962/d1004326
- Description: We evaluate the Wald Noether charge entropy for a black hole in generalized theories of gravity. Expanding the Lagrangian to second order in gravitational perturbations, we show that contributions to the entropy density originate only from the coefficients of two-derivative terms. The same considerations are extended to include matter fields and to show that arbitrary powers of matter fields and their symmetrized covariant derivatives cannot contribute to the entropy density. We also explain how to use the linearized gravitational field equation rather than quadratic actions to obtain the same results. Several explicit examples are presented that allow us to clarify subtle points in the derivation and application of our method.
- Full Text:
- Date Issued: 2011
- Authors: Brustein, R , Gorbonos, D , Hadad, M , Medved, A J M
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6816 , http://hdl.handle.net/10962/d1004326
- Description: We evaluate the Wald Noether charge entropy for a black hole in generalized theories of gravity. Expanding the Lagrangian to second order in gravitational perturbations, we show that contributions to the entropy density originate only from the coefficients of two-derivative terms. The same considerations are extended to include matter fields and to show that arbitrary powers of matter fields and their symmetrized covariant derivatives cannot contribute to the entropy density. We also explain how to use the linearized gravitational field equation rather than quadratic actions to obtain the same results. Several explicit examples are presented that allow us to clarify subtle points in the derivation and application of our method.
- Full Text:
- Date Issued: 2011
Evaluation of the kinetics and mechanism of drug release from Econazole nitrate nanosponge loaded Carbapol Hydrogel
- Sharma, Renuka, Walker, Roderick B, Pathak, Kamla
- Authors: Sharma, Renuka , Walker, Roderick B , Pathak, Kamla
- Date: 2011
- Language: English
- Type: text , Article
- Identifier: vital:6437 , http://hdl.handle.net/10962/d1006614
- Description: The objective of this study was to investigate the mechanism of release of econazole nitrate (EN) nanosponges loaded hydrogel and to compare it with EN hydrogel so as to develop an extended release topical drug delivery system of EN. Nanosponges of EN were prepared using ethyl cellulose and PVA by emulsion solvent evaporation method. On the basis of pharmacotechnical evaluation nanosponges with least particle size of 230.1 nm and good rheological properties were formulated as hydrogel (F1 – F7). In vitro drug release data of EN nanosponges loaded hydrogels in phosphate buffer pH 6.8 and 7.4 when analysed by GraphPad Prism software version 4.0 San Diego, USA best fitted the Makoid-2 Banakar model (R value greater than 0.98). The Korsmeyer-Peppas release exponent (n) ranged between 0.331 – 0.418, which confirmed diffusion as the principle mechanism of drug release. The release mechanism was further confirmed by calculating the ratio of exponents A/B ratio derived from the Kopcha model.
- Full Text:
- Date Issued: 2011
- Authors: Sharma, Renuka , Walker, Roderick B , Pathak, Kamla
- Date: 2011
- Language: English
- Type: text , Article
- Identifier: vital:6437 , http://hdl.handle.net/10962/d1006614
- Description: The objective of this study was to investigate the mechanism of release of econazole nitrate (EN) nanosponges loaded hydrogel and to compare it with EN hydrogel so as to develop an extended release topical drug delivery system of EN. Nanosponges of EN were prepared using ethyl cellulose and PVA by emulsion solvent evaporation method. On the basis of pharmacotechnical evaluation nanosponges with least particle size of 230.1 nm and good rheological properties were formulated as hydrogel (F1 – F7). In vitro drug release data of EN nanosponges loaded hydrogels in phosphate buffer pH 6.8 and 7.4 when analysed by GraphPad Prism software version 4.0 San Diego, USA best fitted the Makoid-2 Banakar model (R value greater than 0.98). The Korsmeyer-Peppas release exponent (n) ranged between 0.331 – 0.418, which confirmed diffusion as the principle mechanism of drug release. The release mechanism was further confirmed by calculating the ratio of exponents A/B ratio derived from the Kopcha model.
- Full Text:
- Date Issued: 2011
Good Chemistry
- Authors: Grange, Helen
- Date: 2011
- Subjects: Nyokong, Tebello , Africa-Arab State 2009 Unesco-L'Oreal Award for Women in Science
- Language: English
- Type: Article , text
- Identifier: vital:7185 , http://hdl.handle.net/10962/d1006276 , Nyokong, Tebello , Africa-Arab State 2009 Unesco-L'Oreal Award for Women in Science
- Description: Helen Grange profiles four women who've fearlessly taken on the complex predominantly male-dominated field of science.
- Full Text:
- Date Issued: 2011
- Authors: Grange, Helen
- Date: 2011
- Subjects: Nyokong, Tebello , Africa-Arab State 2009 Unesco-L'Oreal Award for Women in Science
- Language: English
- Type: Article , text
- Identifier: vital:7185 , http://hdl.handle.net/10962/d1006276 , Nyokong, Tebello , Africa-Arab State 2009 Unesco-L'Oreal Award for Women in Science
- Description: Helen Grange profiles four women who've fearlessly taken on the complex predominantly male-dominated field of science.
- Full Text:
- Date Issued: 2011
Has deregulation of non-timber forest product controls and marketing in Orissa state (India) affected local patterns of use and marketing
- Mahapatra, A K, Shackleton, Charlie M
- Authors: Mahapatra, A K , Shackleton, Charlie M
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6643 , http://hdl.handle.net/10962/d1006872
- Description: State control of marketing agricultural or forestry products may lead to a trade monopoly and restricted competition, resulting in inequitable returns to producers. Consequently, market deregulation for agriculture and other natural products has been advocated to improve market efficiencies, participation and returns for the producers and local traders. The study examines the impact of deregulation of state marketing controls on collection, sale and returns to extractors and traders from non-timber forest products. It assessed whether deregulation policy resulted in greater benefits to primary extractors and a win–win situation for both producers and traders? Mixed effects were found, with no significant changes in terms of trade, demand, or quantum of consumption; but there was an overall increase in the procurement price for several products following deregulation. The collection and farm gate price of tree based oilseeds and honey increased due to lower transaction costs, and ease of trading with a continued demand for these products. The impact on less valuable products was insignificant. Abolition of monopolistic trading increased competition and had a pull effect on the local market prices of several NTFPs. Although traders paid a higher price to procure products, overall they also benefited being able to sell the purchased products to merchants and manufacturers at a better margin than previously.
- Full Text:
- Date Issued: 2011
- Authors: Mahapatra, A K , Shackleton, Charlie M
- Date: 2011
- Language: English
- Type: Article
- Identifier: vital:6643 , http://hdl.handle.net/10962/d1006872
- Description: State control of marketing agricultural or forestry products may lead to a trade monopoly and restricted competition, resulting in inequitable returns to producers. Consequently, market deregulation for agriculture and other natural products has been advocated to improve market efficiencies, participation and returns for the producers and local traders. The study examines the impact of deregulation of state marketing controls on collection, sale and returns to extractors and traders from non-timber forest products. It assessed whether deregulation policy resulted in greater benefits to primary extractors and a win–win situation for both producers and traders? Mixed effects were found, with no significant changes in terms of trade, demand, or quantum of consumption; but there was an overall increase in the procurement price for several products following deregulation. The collection and farm gate price of tree based oilseeds and honey increased due to lower transaction costs, and ease of trading with a continued demand for these products. The impact on less valuable products was insignificant. Abolition of monopolistic trading increased competition and had a pull effect on the local market prices of several NTFPs. Although traders paid a higher price to procure products, overall they also benefited being able to sell the purchased products to merchants and manufacturers at a better margin than previously.
- Full Text:
- Date Issued: 2011