Development & evaluation of modified lignocellulose-clinoptilolite composites for water treatment
- Authors: Vala, Mavula Kikwe Remy
- Date: 2012-12
- Subjects: Lignocellulose , Lignocellulose -- Biotechnology
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24521 , vital:63051
- Description: Municipalities, mining, textile and many other industries release wastewater into water bodies. Thus, the entire ecosystem (biota and abiota) including drinking water is affected by polluted effluents. The growing environmental concern over water pollution (due to inorganic and persistent organic compounds) attracts a significant amount of research in the removal of pollutants from water. In this study, lignocellulose and clinoptilolite were modified for the preparation of composites, with high adsorption properties, suitable for the removal of pollutants. Grass (Kikuyu grass) material was first treated with boiling water in order to remove soluble compounds and then with sulfuric acid in order to free functional groups within lignocellulose. The lignocellulose obtained was then chemically modified with three different siloxanes (3-aminopropyl-terminated poly (di)methylsiloxanes) of different molecular weights. For clinoptilolite, impurities were removed by reflux in hydrochloric acid before chemical modification with siloxanes. Grafting of siloxanes onto lignocellulose and clinoptilolite as well as the preparation of composites were successfully achieved by means of dibutyltin dilaurate (catalyst) after reflux under nitrogen. The modified materials were characterized by FT-IR, XRD, SEM and TGA and results confirmed successful modification of the materials. Solid state 29Si and 13C NMR were used to investigate the nature of the composite prepared with siloxane NH40D (CNH40D). The investigation revealed a possible bond between the modified lignocellulose and the modified clinoptilolite in the composite. The sorptive and/or ion exchange properties of the materials prepared for the removal of pollutants from water were then investigated. Phenol red, used motor (engine) oil and cyanide were used (with regard to textile, oil spill and gold mining effluents respectively) to simulate water pollution in the laboratory. It was found that adsorption properties of lignocellulose were significantly increased after sulfuric acid treatment, suggesting the availability of lignocellulose functional groups as adsorption sites. When further modified with siloxanes, lignocellulose showed less efficiency in adsorbing phenol red. The general mechanism of phenol red uptake onto lignocellulose and clinoptilolite modified with siloxane or composites was: rapid initial adsorption, slow uptake, small rate increase and then equilibrium. The mechanism of phenol red uptake could be well represented by the pseudo second-order kinetic model with equilibrium being reached after a period of time, ranging between 1-5 hours. The linear Langmuir model was the best model for describing adsorption of phenol red onto lignocellulose modified with siloxanes and composites while the Freundlich model appeared to be best for clinoptilolite modified with siloxanes. The general mechanism of used motor oil uptake onto lignocellulose and clinoptilolite modified with siloxane or composites was: rapid uptake, equilibrium and the process occurs over a short period (10 min). The pseudo second-order kinetic model appeared to be the best representation of this adsorption. The linear Langmuir isotherms are the best fitted model for used motor oil uptake onto the adsorbents prepared. Adsorption of cyanide occurred very quickly (10 to 30 min). For lignocellulose and clinoptilolite modified with siloxanes, desorption occurred soon after adsorption and thus no kinetic model nor isotherms of adsorption were deduced. However, adsorption of cyanide onto composites could be represented by the pseudo second-order kinetic model. Nanofibres were fabricated by electrospinning of the modified lignocellulose and composites by blending them with PAN in a solvent mixture of DMF-DMSO. Nanofiltration was achieved by packing the nanofibres prepared into a pipette and filtering polluted water. Nanofiltration was assessed by measurement of the turbidity of water which dropped from 63 NTU for polluted water to 3.06 NTU for filtered water. , Thesis (PhD) -- Faculty of Science and Agriculture, 2012
- Full Text:
- Date Issued: 2012-12
- Authors: Vala, Mavula Kikwe Remy
- Date: 2012-12
- Subjects: Lignocellulose , Lignocellulose -- Biotechnology
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24521 , vital:63051
- Description: Municipalities, mining, textile and many other industries release wastewater into water bodies. Thus, the entire ecosystem (biota and abiota) including drinking water is affected by polluted effluents. The growing environmental concern over water pollution (due to inorganic and persistent organic compounds) attracts a significant amount of research in the removal of pollutants from water. In this study, lignocellulose and clinoptilolite were modified for the preparation of composites, with high adsorption properties, suitable for the removal of pollutants. Grass (Kikuyu grass) material was first treated with boiling water in order to remove soluble compounds and then with sulfuric acid in order to free functional groups within lignocellulose. The lignocellulose obtained was then chemically modified with three different siloxanes (3-aminopropyl-terminated poly (di)methylsiloxanes) of different molecular weights. For clinoptilolite, impurities were removed by reflux in hydrochloric acid before chemical modification with siloxanes. Grafting of siloxanes onto lignocellulose and clinoptilolite as well as the preparation of composites were successfully achieved by means of dibutyltin dilaurate (catalyst) after reflux under nitrogen. The modified materials were characterized by FT-IR, XRD, SEM and TGA and results confirmed successful modification of the materials. Solid state 29Si and 13C NMR were used to investigate the nature of the composite prepared with siloxane NH40D (CNH40D). The investigation revealed a possible bond between the modified lignocellulose and the modified clinoptilolite in the composite. The sorptive and/or ion exchange properties of the materials prepared for the removal of pollutants from water were then investigated. Phenol red, used motor (engine) oil and cyanide were used (with regard to textile, oil spill and gold mining effluents respectively) to simulate water pollution in the laboratory. It was found that adsorption properties of lignocellulose were significantly increased after sulfuric acid treatment, suggesting the availability of lignocellulose functional groups as adsorption sites. When further modified with siloxanes, lignocellulose showed less efficiency in adsorbing phenol red. The general mechanism of phenol red uptake onto lignocellulose and clinoptilolite modified with siloxane or composites was: rapid initial adsorption, slow uptake, small rate increase and then equilibrium. The mechanism of phenol red uptake could be well represented by the pseudo second-order kinetic model with equilibrium being reached after a period of time, ranging between 1-5 hours. The linear Langmuir model was the best model for describing adsorption of phenol red onto lignocellulose modified with siloxanes and composites while the Freundlich model appeared to be best for clinoptilolite modified with siloxanes. The general mechanism of used motor oil uptake onto lignocellulose and clinoptilolite modified with siloxane or composites was: rapid uptake, equilibrium and the process occurs over a short period (10 min). The pseudo second-order kinetic model appeared to be the best representation of this adsorption. The linear Langmuir isotherms are the best fitted model for used motor oil uptake onto the adsorbents prepared. Adsorption of cyanide occurred very quickly (10 to 30 min). For lignocellulose and clinoptilolite modified with siloxanes, desorption occurred soon after adsorption and thus no kinetic model nor isotherms of adsorption were deduced. However, adsorption of cyanide onto composites could be represented by the pseudo second-order kinetic model. Nanofibres were fabricated by electrospinning of the modified lignocellulose and composites by blending them with PAN in a solvent mixture of DMF-DMSO. Nanofiltration was achieved by packing the nanofibres prepared into a pipette and filtering polluted water. Nanofiltration was assessed by measurement of the turbidity of water which dropped from 63 NTU for polluted water to 3.06 NTU for filtered water. , Thesis (PhD) -- Faculty of Science and Agriculture, 2012
- Full Text:
- Date Issued: 2012-12
The implementation of HIV and AIDS prevention programmes in three Universities in Zimbabwe
- Muzenda, Denias https://orcid.org/0000-0002-6552-7319
- Authors: Muzenda, Denias https://orcid.org/0000-0002-6552-7319
- Date: 2012-12
- Subjects: Universities and colleges -- Health promotion services , AIDS (Disease) -- Prevention
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/25022 , vital:63891
- Description: Given the nature and devastating effects of HIV and AIDS and its impact on society, the universities in Zimbabwe have affirmed the need to define their institutional policy aimed at managing and mitigating the effects of HIV and AIDS. In this regard they have also put in place programmes to address the epidemic. Among the programmes are HIV and AIDS prevention programmes which are being implemented. However, there have been concerns that despite the fact that the programmes are being implemented as planned they have not met their objectives as HIV and AIDS infections have not decreased as expected. Hence this study assesses the implementation of HIV and AIDS prevention programmes in three universities in Zimbabwe. To achieve these objectives, the researcher opted for the mixed method methodology which is embedded in the post-positivist research paradigm. Post-positivist research paradigm attempts to increase our understanding of the way things are and that objectivity is an ideal that can never be achieved, and research is conducted with greater awareness of subjectivity. The researcher had to opt for questionnaires, interviews, document analysis and observations as data collecting instruments. From the Data presented the study found that universities lack adequately professionally qualified HIV and AIDS lecturers. Results on capacity of implementers in the study revealed that an insignificant number of lecturers have the capacity while the majority significant number lacked the capacity to implement the programmes. HIV and AIDS prevention is being implemented by unqualified lecturers who lack training and prerequisite skills for the programme. Furthermore, the study found that Lecturers do not get the necessary professional and institutional support to implement successfully HIV and AIDS programmes in universities. HIV and AIDS Coordinators and NGOs expressed concern over the inadequacy of learning and teaching support material. Funding and lack of resources such as specialist rooms and learning materials are a major impediment to successful implementation of HIV and AIDS. Implementation of HIV and AIDS programmes suffers from inadequate supervision by the relevant stakeholders due to unavailability of transport and financial cost. It also emerged that Human resource is also a major problem since there is a great staff turnover as specialist lecturers leave the system for better paid opportunities in the private sector. Most university lecturer respondents cited staff turnover as long-established and skilled lecturers look for greener pastures within and outside the country. The dominant methods used to implement HIV and AIDS programmes do not give enough room for group work discussions to effect behaviour change in students. Rather, more emphasis is on factual knowledge for assignments and examination purposes. On monitoring and evaluation of HIV and AIDS programmes, the study found that lecturers and students are unaware of their programmes progress bench marks. Universities have not been carrying out internal audits over the past years. This implies that the universities are divorced from Ministry of Higher Education Policy on monitoring and evaluation. Also, less people are involved in the monitoring process of HIV and AIDS programmes. The study found from the universities records that an HIV and AIDS Policy document exists at each university. However, the implementation of HIV and AIDS prevention programmes seemed to have a number of controversies and challenges. The study made the following recommendations against each major finding: Within the organisation, university works continually to equip staff with the knowledge, skills and tools required to analyse programme, implement and monitor interventions for HIV prevention. Capacity to support innovations includes aspects which hinder or support the implementation of new practices and ideas in the new curriculum. Universities should have trained HIV and AIDS Peer educators. For a lecturer to be considered as professionally qualified personnel in universities, the Ministry of Higher and Tertiary Education should stipulate possession of a Master‟s degree or a Doctorate. The researcher provided a section on contribution of the study to new knowledge whereby the researcher proposed an alternative model for HIV and AIDS implementation for universities in Zimbabwe. This model was derived after a thorough analysis of the findings from the study as well as an extensive literature review on the subject. Areas for further research have been suggested in this study. , Thesis (PhD) -- Faculty of Education, 2012
- Full Text:
- Date Issued: 2012-12
- Authors: Muzenda, Denias https://orcid.org/0000-0002-6552-7319
- Date: 2012-12
- Subjects: Universities and colleges -- Health promotion services , AIDS (Disease) -- Prevention
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/25022 , vital:63891
- Description: Given the nature and devastating effects of HIV and AIDS and its impact on society, the universities in Zimbabwe have affirmed the need to define their institutional policy aimed at managing and mitigating the effects of HIV and AIDS. In this regard they have also put in place programmes to address the epidemic. Among the programmes are HIV and AIDS prevention programmes which are being implemented. However, there have been concerns that despite the fact that the programmes are being implemented as planned they have not met their objectives as HIV and AIDS infections have not decreased as expected. Hence this study assesses the implementation of HIV and AIDS prevention programmes in three universities in Zimbabwe. To achieve these objectives, the researcher opted for the mixed method methodology which is embedded in the post-positivist research paradigm. Post-positivist research paradigm attempts to increase our understanding of the way things are and that objectivity is an ideal that can never be achieved, and research is conducted with greater awareness of subjectivity. The researcher had to opt for questionnaires, interviews, document analysis and observations as data collecting instruments. From the Data presented the study found that universities lack adequately professionally qualified HIV and AIDS lecturers. Results on capacity of implementers in the study revealed that an insignificant number of lecturers have the capacity while the majority significant number lacked the capacity to implement the programmes. HIV and AIDS prevention is being implemented by unqualified lecturers who lack training and prerequisite skills for the programme. Furthermore, the study found that Lecturers do not get the necessary professional and institutional support to implement successfully HIV and AIDS programmes in universities. HIV and AIDS Coordinators and NGOs expressed concern over the inadequacy of learning and teaching support material. Funding and lack of resources such as specialist rooms and learning materials are a major impediment to successful implementation of HIV and AIDS. Implementation of HIV and AIDS programmes suffers from inadequate supervision by the relevant stakeholders due to unavailability of transport and financial cost. It also emerged that Human resource is also a major problem since there is a great staff turnover as specialist lecturers leave the system for better paid opportunities in the private sector. Most university lecturer respondents cited staff turnover as long-established and skilled lecturers look for greener pastures within and outside the country. The dominant methods used to implement HIV and AIDS programmes do not give enough room for group work discussions to effect behaviour change in students. Rather, more emphasis is on factual knowledge for assignments and examination purposes. On monitoring and evaluation of HIV and AIDS programmes, the study found that lecturers and students are unaware of their programmes progress bench marks. Universities have not been carrying out internal audits over the past years. This implies that the universities are divorced from Ministry of Higher Education Policy on monitoring and evaluation. Also, less people are involved in the monitoring process of HIV and AIDS programmes. The study found from the universities records that an HIV and AIDS Policy document exists at each university. However, the implementation of HIV and AIDS prevention programmes seemed to have a number of controversies and challenges. The study made the following recommendations against each major finding: Within the organisation, university works continually to equip staff with the knowledge, skills and tools required to analyse programme, implement and monitor interventions for HIV prevention. Capacity to support innovations includes aspects which hinder or support the implementation of new practices and ideas in the new curriculum. Universities should have trained HIV and AIDS Peer educators. For a lecturer to be considered as professionally qualified personnel in universities, the Ministry of Higher and Tertiary Education should stipulate possession of a Master‟s degree or a Doctorate. The researcher provided a section on contribution of the study to new knowledge whereby the researcher proposed an alternative model for HIV and AIDS implementation for universities in Zimbabwe. This model was derived after a thorough analysis of the findings from the study as well as an extensive literature review on the subject. Areas for further research have been suggested in this study. , Thesis (PhD) -- Faculty of Education, 2012
- Full Text:
- Date Issued: 2012-12
Biological activities and mechanisms of action of two ethnobotanically selected South African medicinal plants on some bacteria associated with gastrointestinal infections
- Olajuyigbe, Olufunmiso Olusola https://orcid.org/0000-0002-7889-0416
- Authors: Olajuyigbe, Olufunmiso Olusola https://orcid.org/0000-0002-7889-0416
- Date: 2012-08
- Subjects: Medicinal plants , Herbs -- Therapeutic use , Gastrointestinal system
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/25439 , vital:64249
- Description: In this study, 36 plant species representing 24 families were found to be commonly used for the treatment of a variety of gastrointestinal disorders in Eastern Cape, South Africa. The family Fabaceae had the highest number of species. Out of these, 47.06percent were used in the treatment of dysentery alone while 46.15percent were used in the treatment of diarrhoea. Acacia mearnsii De Wild and Ziziphus mucronata subsp. mucronata Willd were selected for this research because they are extensively used in folkloric medicine in South Africa and there was lack of scientific reports that documented their biological activities. The phytochemical screening, antioxidant activities, in vitro antimicrobial activities, cytotoxicity, the synergistic potentials and mechanisms of actions of these plants were investigated. The phytochemical screening and the antioxidant activities of the two species showed that the quantity of the phenolic compounds, flavonoids and proanthocyanidins detected differ significantly in the various extracts. Of the aqueous, acetone, ethanolic and methanolic extracts of A. mearnsii, the ethanolic extract had the highest flavonoids while the acetone extract had the highest phenolic contents. The proanthocyanidins were highest in the methanol extract while aqueous extracts had the least phytochemicals. Aqueous extract showed the least ferric reducing power but methanol extract indicated the highest reducing power. The reducing power of the extracts was lower than those obtained from the reference standard such as butylated hydroxytoluene (BHT), rutin and ascorbic acid. 2,2’-azinobis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) diammonium salt showed that ethanol extract exhibited the highest antioxidant activity at the highest concentration tested. Also, 1,1-diphenyl-2-picrylhydrazyl (DPPH) assay indicated that ethanol extract had the highest radical scavenging activity at the lowest concentration and the activities of all the extracts decreased with increase in their concentrations. In Z. mucronata subsp. mucronata, the phenolics were significantly higher than the flavonoids and proanthocyanidin contents in all the extracts investigated. The ethanol extract had the highest antioxidant activity, followed by the acetone extract while the aqueous extract was the least active. Reacting with ABTS, the 50percent inhibitory concentrations (IC50) were (0.0429 ± 0.04 mg/ml) for aqueous, (0.0317 ± 0.04 mg/ml) for acetone and (0.0306 ± 0.04 mg/ml) for ethanol extracts while they inhibited DPPH radical with 50percent inhibitory concentration (IC50) values of 0.0646 ± 0.02 mg/ml (aqueous), 0.0482 ± 0.02 mg/ml (acetone) and 0.0422 ± 0.03 mg/ml (ethanol). The investigation showed that a positive linear correlation existed between the total phenolic content and antioxidant activity of the extracts and that these plants have strong antioxidant property and free radical scavenging capability. The in vitro antibacterial activities of Acacia mearnsii and Z. mucronata subsp. mucronata showed that their minimum inhibitory concentrations ranged between 0.039 mg/ml and 1.25 mg/ml. With the exception of acetone extract of A. mearnsii having MICs greater than 1.0 mg/ml for Enterococcus faecalis ATCC 29212 and Bacillus subtilis KZN, all other isolates had MICs less than 0.7 mg/ml. In all the bacteria treated with Z. mucronata subsp. mucronata extracts, Enterobacter cloacae ATCC 13047 had MIC greater than 1 mg/ml in methanol extract, Enterococcus faecalis ATCC 29212 and Staphylococcus aureus ATCC 6538 had MICs greater than 1 mg/ml in acetone extract while all other isolates were highly susceptible to the different extracts of Z. mucronata subsp. mucronata and had MICs less than 0.7 mg/ml. While aqueous extract was as active as the alcoholic extracts in A. mearnsii, that of Z. mucronata had no effect. The ethanol extracts exhibited the highest degree of antibacterial activity in both plants. This study, also, showed that the antifungal activity of A. mearnsii ranging 0.3125 – 5.0 mg/ml was higher than those of the different extracts of Z. mucronata subsp. mucronata ranging 1.25 – 10.0 mg/ml. It is evident from the results of the brine shrimp lethality assay that the crude extracts of A. mearnsii with the LC50 equaled 112.36 µg/ml and having the highest levels of toxicity (100percent) death at 500 μg/ml was non toxic (LC50 > 100 μg/ml) while the LC50 for Z. mucronata subsp. mucronata equaled 90.27 µg/ml indicated a low level of toxicity. The effects of combining the crude extracts of these plants with eight antibiotics were investigated by means of checkerboard and agar diffusion methods. On using the methanol extract of A. mearnsii, the agar diffusion assay showed that extract-kanamycin combination had zones of inhibition ≥ 20 ± 1.0 mm in all the bacteria tested (100percent), followed by extract chloramphenicol (90percent) > extract-ciprofloxacin = extract-tetracycline (70percent) > extract amoxicillin (60percent) > extract-nalidixic acid (50percent) > extract-erythromycin (40percent) > extract metronidazole (20percent). The checkerboard showed synergistic interaction (61.25percent), additivity/indifference (23.75percent) and antagonistic (15percent) effects. I, therefore, concluded that the antibacterial potentials of the antibiotics were improved and combining natural products with antibiotic could be a potential source of resistance-modifying agents useful against multi-drug resistant bacteria. The influences of these extracts on the ultrastructures, elemental components, protein and lipid leakages of five different bacteria were determined as the possible mechanisms of action of the extracts investigated. The scanning electron microscopy indicated varied ultrastructural changes in the morphology of bacterial cells treated with the extracts. The X-ray microanalysis showed significant differences between the elemental contents of extract-treated and untreated bacteria while lipids and proteins were leaked to a great extent from the extract-treated bacterial strains in comparison with the untreated ones. The possible mechanisms of action of the extracts may include inhibition of a significant step in peptidoglycan assembly, inhibition of metabolic processes, disruption of cell wall and cell membranes resulting in the efflux of lipid and protein in all the bacteria tested. The possible mechanism of action involved in the lipid and protein leakages in the bacterial cells could be attributed to lipid peroxidation and protein oxidation owing to the antioxidant activities of the extracts that were active beyond the protective levels. I concluded that the morphological changes and the observed leakages showed rapid killing, significant membrane depolarization resulting in leakages and efflux of disintegrated cellular materials. In general, this study has justified the ethnotherapeutic importance of A. mearnsii and Z. mucronata subsp. mucronata in the treatment of microbial infections by indicating the possible mechanisms of action of the crude extracts on the tested bacteria. , Thesis (PhD) -- Faculty of Science and Agriculture, 2012
- Full Text:
- Date Issued: 2012-08
- Authors: Olajuyigbe, Olufunmiso Olusola https://orcid.org/0000-0002-7889-0416
- Date: 2012-08
- Subjects: Medicinal plants , Herbs -- Therapeutic use , Gastrointestinal system
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/25439 , vital:64249
- Description: In this study, 36 plant species representing 24 families were found to be commonly used for the treatment of a variety of gastrointestinal disorders in Eastern Cape, South Africa. The family Fabaceae had the highest number of species. Out of these, 47.06percent were used in the treatment of dysentery alone while 46.15percent were used in the treatment of diarrhoea. Acacia mearnsii De Wild and Ziziphus mucronata subsp. mucronata Willd were selected for this research because they are extensively used in folkloric medicine in South Africa and there was lack of scientific reports that documented their biological activities. The phytochemical screening, antioxidant activities, in vitro antimicrobial activities, cytotoxicity, the synergistic potentials and mechanisms of actions of these plants were investigated. The phytochemical screening and the antioxidant activities of the two species showed that the quantity of the phenolic compounds, flavonoids and proanthocyanidins detected differ significantly in the various extracts. Of the aqueous, acetone, ethanolic and methanolic extracts of A. mearnsii, the ethanolic extract had the highest flavonoids while the acetone extract had the highest phenolic contents. The proanthocyanidins were highest in the methanol extract while aqueous extracts had the least phytochemicals. Aqueous extract showed the least ferric reducing power but methanol extract indicated the highest reducing power. The reducing power of the extracts was lower than those obtained from the reference standard such as butylated hydroxytoluene (BHT), rutin and ascorbic acid. 2,2’-azinobis-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) diammonium salt showed that ethanol extract exhibited the highest antioxidant activity at the highest concentration tested. Also, 1,1-diphenyl-2-picrylhydrazyl (DPPH) assay indicated that ethanol extract had the highest radical scavenging activity at the lowest concentration and the activities of all the extracts decreased with increase in their concentrations. In Z. mucronata subsp. mucronata, the phenolics were significantly higher than the flavonoids and proanthocyanidin contents in all the extracts investigated. The ethanol extract had the highest antioxidant activity, followed by the acetone extract while the aqueous extract was the least active. Reacting with ABTS, the 50percent inhibitory concentrations (IC50) were (0.0429 ± 0.04 mg/ml) for aqueous, (0.0317 ± 0.04 mg/ml) for acetone and (0.0306 ± 0.04 mg/ml) for ethanol extracts while they inhibited DPPH radical with 50percent inhibitory concentration (IC50) values of 0.0646 ± 0.02 mg/ml (aqueous), 0.0482 ± 0.02 mg/ml (acetone) and 0.0422 ± 0.03 mg/ml (ethanol). The investigation showed that a positive linear correlation existed between the total phenolic content and antioxidant activity of the extracts and that these plants have strong antioxidant property and free radical scavenging capability. The in vitro antibacterial activities of Acacia mearnsii and Z. mucronata subsp. mucronata showed that their minimum inhibitory concentrations ranged between 0.039 mg/ml and 1.25 mg/ml. With the exception of acetone extract of A. mearnsii having MICs greater than 1.0 mg/ml for Enterococcus faecalis ATCC 29212 and Bacillus subtilis KZN, all other isolates had MICs less than 0.7 mg/ml. In all the bacteria treated with Z. mucronata subsp. mucronata extracts, Enterobacter cloacae ATCC 13047 had MIC greater than 1 mg/ml in methanol extract, Enterococcus faecalis ATCC 29212 and Staphylococcus aureus ATCC 6538 had MICs greater than 1 mg/ml in acetone extract while all other isolates were highly susceptible to the different extracts of Z. mucronata subsp. mucronata and had MICs less than 0.7 mg/ml. While aqueous extract was as active as the alcoholic extracts in A. mearnsii, that of Z. mucronata had no effect. The ethanol extracts exhibited the highest degree of antibacterial activity in both plants. This study, also, showed that the antifungal activity of A. mearnsii ranging 0.3125 – 5.0 mg/ml was higher than those of the different extracts of Z. mucronata subsp. mucronata ranging 1.25 – 10.0 mg/ml. It is evident from the results of the brine shrimp lethality assay that the crude extracts of A. mearnsii with the LC50 equaled 112.36 µg/ml and having the highest levels of toxicity (100percent) death at 500 μg/ml was non toxic (LC50 > 100 μg/ml) while the LC50 for Z. mucronata subsp. mucronata equaled 90.27 µg/ml indicated a low level of toxicity. The effects of combining the crude extracts of these plants with eight antibiotics were investigated by means of checkerboard and agar diffusion methods. On using the methanol extract of A. mearnsii, the agar diffusion assay showed that extract-kanamycin combination had zones of inhibition ≥ 20 ± 1.0 mm in all the bacteria tested (100percent), followed by extract chloramphenicol (90percent) > extract-ciprofloxacin = extract-tetracycline (70percent) > extract amoxicillin (60percent) > extract-nalidixic acid (50percent) > extract-erythromycin (40percent) > extract metronidazole (20percent). The checkerboard showed synergistic interaction (61.25percent), additivity/indifference (23.75percent) and antagonistic (15percent) effects. I, therefore, concluded that the antibacterial potentials of the antibiotics were improved and combining natural products with antibiotic could be a potential source of resistance-modifying agents useful against multi-drug resistant bacteria. The influences of these extracts on the ultrastructures, elemental components, protein and lipid leakages of five different bacteria were determined as the possible mechanisms of action of the extracts investigated. The scanning electron microscopy indicated varied ultrastructural changes in the morphology of bacterial cells treated with the extracts. The X-ray microanalysis showed significant differences between the elemental contents of extract-treated and untreated bacteria while lipids and proteins were leaked to a great extent from the extract-treated bacterial strains in comparison with the untreated ones. The possible mechanisms of action of the extracts may include inhibition of a significant step in peptidoglycan assembly, inhibition of metabolic processes, disruption of cell wall and cell membranes resulting in the efflux of lipid and protein in all the bacteria tested. The possible mechanism of action involved in the lipid and protein leakages in the bacterial cells could be attributed to lipid peroxidation and protein oxidation owing to the antioxidant activities of the extracts that were active beyond the protective levels. I concluded that the morphological changes and the observed leakages showed rapid killing, significant membrane depolarization resulting in leakages and efflux of disintegrated cellular materials. In general, this study has justified the ethnotherapeutic importance of A. mearnsii and Z. mucronata subsp. mucronata in the treatment of microbial infections by indicating the possible mechanisms of action of the crude extracts on the tested bacteria. , Thesis (PhD) -- Faculty of Science and Agriculture, 2012
- Full Text:
- Date Issued: 2012-08
Performance monitoring and evaluation for sustainable public service delivery: the case for the South African police service
- Authors: Reddy, Michael
- Date: 2012-04
- Subjects: Performance -- Evaluation , Civil service -- Labor productivity
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24399 , vital:62767
- Description: The public service which is the delivery arm of government, has to rise constantly to the massive challenge of service delivery to ensure that government achieves its ideal of creating a better life for all in accordance with the people’s contract. The research analyzed the question: To what extent can monitoring and evaluation of performance provide sustainable public service delivery by the public sector? Against this milieu, the study examined the monitoring and evaluation approaches adopted by the governments of Mexico and Spain (international) and South Africa (local). Further, an analogous of both the international and local experiences was conducted in the study. The state of service delivery was examined by studying the South African Police Service. It was evidenced in the study that sustainable service delivery in the SAPS is influenced by various factors, such as performance monitoring and evaluation. Although the SAPS reported the successful achievement of certain performance targets relating to its planned activities and financial performance, it became clear that the performance monitoring and evaluation framework is not adequate to effectively address the service delivery expectations in the South African context. This thesis presents an inclusive and comprehensive approach towards performance monitoring and evaluation, which seeks to shape the South African Police Service’s current framework positively towards promoting sustainable service delivery. The features of this new proposed approach include the involvement and/ or meaningful consultation with the broad South African community, effective communication; promotion of accountability; professional and ethical standards; and expansion and development of the current and future leadership at all levels in the organization. Further, a call for greater regional and international cohesion is made, to benchmark best practices relating to performance monitoring and evaluation; this was found necessary, as a global effort is required to successfully prevent and realize a significant reduction in crime levels. The study finally presents an alternative In year Monitoring Model (IYMM) to manage the budget performance against the predetermined plan. It links the key performance areas, as contained in the cost centre’s business plan to the allocated budget; produces unique projected spending patterns (PSP) for each cost centre; thereby propelling departments from old paradigms of monitoring financial performance. The IYMM provides management with an excellent tool to monitor and evaluate performance during the year. The performance monitoring and evaluation approach and the IYMM developed in this study are flexible and adaptable, as it can be applied successfully in other government departments locally, regionally and internationally. The thesis thus proposes a pragmatic approach towards performance monitoring and evaluation that promotes sustainable service delivery in South Africa. , Thesis (PhD) -- Faculty of Management and Commerce, 2012
- Full Text:
- Date Issued: 2012-04
- Authors: Reddy, Michael
- Date: 2012-04
- Subjects: Performance -- Evaluation , Civil service -- Labor productivity
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24399 , vital:62767
- Description: The public service which is the delivery arm of government, has to rise constantly to the massive challenge of service delivery to ensure that government achieves its ideal of creating a better life for all in accordance with the people’s contract. The research analyzed the question: To what extent can monitoring and evaluation of performance provide sustainable public service delivery by the public sector? Against this milieu, the study examined the monitoring and evaluation approaches adopted by the governments of Mexico and Spain (international) and South Africa (local). Further, an analogous of both the international and local experiences was conducted in the study. The state of service delivery was examined by studying the South African Police Service. It was evidenced in the study that sustainable service delivery in the SAPS is influenced by various factors, such as performance monitoring and evaluation. Although the SAPS reported the successful achievement of certain performance targets relating to its planned activities and financial performance, it became clear that the performance monitoring and evaluation framework is not adequate to effectively address the service delivery expectations in the South African context. This thesis presents an inclusive and comprehensive approach towards performance monitoring and evaluation, which seeks to shape the South African Police Service’s current framework positively towards promoting sustainable service delivery. The features of this new proposed approach include the involvement and/ or meaningful consultation with the broad South African community, effective communication; promotion of accountability; professional and ethical standards; and expansion and development of the current and future leadership at all levels in the organization. Further, a call for greater regional and international cohesion is made, to benchmark best practices relating to performance monitoring and evaluation; this was found necessary, as a global effort is required to successfully prevent and realize a significant reduction in crime levels. The study finally presents an alternative In year Monitoring Model (IYMM) to manage the budget performance against the predetermined plan. It links the key performance areas, as contained in the cost centre’s business plan to the allocated budget; produces unique projected spending patterns (PSP) for each cost centre; thereby propelling departments from old paradigms of monitoring financial performance. The IYMM provides management with an excellent tool to monitor and evaluate performance during the year. The performance monitoring and evaluation approach and the IYMM developed in this study are flexible and adaptable, as it can be applied successfully in other government departments locally, regionally and internationally. The thesis thus proposes a pragmatic approach towards performance monitoring and evaluation that promotes sustainable service delivery in South Africa. , Thesis (PhD) -- Faculty of Management and Commerce, 2012
- Full Text:
- Date Issued: 2012-04
A study of the selected wild edible plants utilized by indigenous people of the Amathole District in the Eastern Cape Province of South Africa
- Kwinana-Mandindi, Thozama Ndileka
- Authors: Kwinana-Mandindi, Thozama Ndileka
- Date: 2012
- Subjects: Wild plants, Edible http://id.loc.gov/authorities/subjects/sh85146686
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/19598 , vital:43147
- Description: Wild edible plants are an indispensible part of diets in some of the poor resourced rural societies. In many less resourced households a main meal comprises of a starch staple which is accompanied by a supplement of vegetables that provide the other nutritional elements as well as flavour to the meals. The vegetable relish (isishebo) thus, becomes an important component of the diet. The sustenance of many such resource poor indigenous societies over many generations has been as a result of their reliance on a readily available supply of their nutritional requirements, where edible wild plants formed the major food source. Wild edible plants provided the most important source of nutritional supply even during times of drought and famine. However, lifestyle changes have caused a serious reduction of the gathering and use of the wild edible vegetables, knowledge about them and the local culture are also lost with them. Unfortunately, others have come to regard their traditional food resource base as primitive and inferior and have come to rely on new exotic food plant whose supply is unstable and narrow compared to the wide variety of wild edible plants. Even when drought challenges play destruction with food availability, resulting in food shortages due to the reliance on cultivated crops that are poorly adapted to local conditions, communities cannot go back to the unknown food plants. However, detailed scientific investigations are needed to understand and preserve wild food uses. This study was undertaken to add to that body of knowledge. It started with an ethnobotanic survey of the use of wild food plants in 10 selected rural villages and peri-urban dwellings in the Amathole District of the Eastern Cape. These rural areas were chosen because of the belief that there are still individuals who possess the wealth of traditional knowledge within those remote areas in addition to that the villages are surrounded by indigenous vegetation from which they could be harvesting some indigenous food plants. Furthermore, the relationship between people and plants are often clearer in indigenous/traditional societies since the link between production and consumption is more direct. Besides the survey, this research employed various methods including Inductively Coupled Argon (ICP) analyses of minerals and vitamins, determination of phytochemicals and antioxidant/bio-activity that of, higher performance liquid chromatography (HPLC) determination of other vitamins, assessment of proximate and anti-nutrient compositions of raw and cooked samples of plants, scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDXS) to look into the micro-morphology of leaves for details that might have a bearing in the nutrient composition of the wild edible vegetables. This was done with the aim to explore and highlight the wild-food-plant base of indigenous people, to investigate the nutritional value of the selected frequently consumed wild vegetables and to recommend ways of educating people on the value of such plants and the need to promote their continued sustainable use as well as preservation of them for the benefit of people who cannot afford a continuous nutritious meal particularly among rural communities. Twenty-five (25) indigenous wild food plants which included leafy vegetables, nuts and fruits species were identified as being arbitrarily gathered and utilised as food, of which seven wild leafy vegetable species were often mentioned as common among the 15 dwellings surveyed and most frequently consumed by the respondents. Two additional plants were also frequently used as flavoring and in their raw state respectively. Wild edible vegetables were mainly eaten boiled as ‘laxa’, mixed with maize meal as ‘imifino’, fried as relish ‘isishebo’ or raw for both snacking purposes and medicinal functions. Wild edible plant species in the Amathole District of the Eastern Cape-South Africa were documented with respect to their uses and knowledge or identification. Four indigenous wild vegetables (Chenopodium album, Solanum nigrum/nodiflorum, Amaranthus dubius and Urtica lobulata) frequently consumed by the indigenous communities in the study region were selected. All the plant species had a remarkably high content of pro-anthocyanidins (between 58.42 and 65.18 mg/g) and also exhibited high radical scavenging activity in vitro. S. nigrum and C. album were found to be rich sources of ascorbic acid, having 1.05mg/100g and 1.01mg/100g, respectively. The entire wild, traditionally edible plants contain reasonably good concentrations of riboflavin while U. lobulata was found to contain maximum amount of thiamine. All plant species were rich sources of minerals and vitamins (both water soluble and fat soluble). Appropriate cooking methods are to be used to enhance the bio-availability of vitamins and nutrients in general. Cooking generally improved the nutritive value in certain wild vegetables. However, some nutrients were drained away. For example micro-nutrient and anti-nutrient component in the ash were reduced in cooking. The EDXS analysis has shown that the indigenous, wild vegetables in the Amathole District of South Africa are excellent sources of minerals, while the mineral crystals present at the level of the mesophyll of the indigenous wild vegetables were probably mixtures of calcium oxalate, calcium sulphate and silica. Saponin, tannins, oxalates, phytates and alkaloids are present in all the indigenous wild vegetables, but in minimal safe quantities. Nutritional analysis of some wild food plants demonstrates that in many cases the nutritional quality of the plants is comparable and in some cases even superior to domesticated exotic varieties. Knowledge about gathering and use of some wild food species is common among the rural dwellers. However, most uses are known by few elderly informants only. Education, awareness campaigns and revival of use of wild edible plants directed at the youth particularly is essential and this can be done through all forms of media. , Thesis (PhD) (Ethnobotany) -- University of Fort Hare, 2012
- Full Text:
- Date Issued: 2012
- Authors: Kwinana-Mandindi, Thozama Ndileka
- Date: 2012
- Subjects: Wild plants, Edible http://id.loc.gov/authorities/subjects/sh85146686
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/19598 , vital:43147
- Description: Wild edible plants are an indispensible part of diets in some of the poor resourced rural societies. In many less resourced households a main meal comprises of a starch staple which is accompanied by a supplement of vegetables that provide the other nutritional elements as well as flavour to the meals. The vegetable relish (isishebo) thus, becomes an important component of the diet. The sustenance of many such resource poor indigenous societies over many generations has been as a result of their reliance on a readily available supply of their nutritional requirements, where edible wild plants formed the major food source. Wild edible plants provided the most important source of nutritional supply even during times of drought and famine. However, lifestyle changes have caused a serious reduction of the gathering and use of the wild edible vegetables, knowledge about them and the local culture are also lost with them. Unfortunately, others have come to regard their traditional food resource base as primitive and inferior and have come to rely on new exotic food plant whose supply is unstable and narrow compared to the wide variety of wild edible plants. Even when drought challenges play destruction with food availability, resulting in food shortages due to the reliance on cultivated crops that are poorly adapted to local conditions, communities cannot go back to the unknown food plants. However, detailed scientific investigations are needed to understand and preserve wild food uses. This study was undertaken to add to that body of knowledge. It started with an ethnobotanic survey of the use of wild food plants in 10 selected rural villages and peri-urban dwellings in the Amathole District of the Eastern Cape. These rural areas were chosen because of the belief that there are still individuals who possess the wealth of traditional knowledge within those remote areas in addition to that the villages are surrounded by indigenous vegetation from which they could be harvesting some indigenous food plants. Furthermore, the relationship between people and plants are often clearer in indigenous/traditional societies since the link between production and consumption is more direct. Besides the survey, this research employed various methods including Inductively Coupled Argon (ICP) analyses of minerals and vitamins, determination of phytochemicals and antioxidant/bio-activity that of, higher performance liquid chromatography (HPLC) determination of other vitamins, assessment of proximate and anti-nutrient compositions of raw and cooked samples of plants, scanning electron microscopy (SEM) and energy dispersive x-ray spectroscopy (EDXS) to look into the micro-morphology of leaves for details that might have a bearing in the nutrient composition of the wild edible vegetables. This was done with the aim to explore and highlight the wild-food-plant base of indigenous people, to investigate the nutritional value of the selected frequently consumed wild vegetables and to recommend ways of educating people on the value of such plants and the need to promote their continued sustainable use as well as preservation of them for the benefit of people who cannot afford a continuous nutritious meal particularly among rural communities. Twenty-five (25) indigenous wild food plants which included leafy vegetables, nuts and fruits species were identified as being arbitrarily gathered and utilised as food, of which seven wild leafy vegetable species were often mentioned as common among the 15 dwellings surveyed and most frequently consumed by the respondents. Two additional plants were also frequently used as flavoring and in their raw state respectively. Wild edible vegetables were mainly eaten boiled as ‘laxa’, mixed with maize meal as ‘imifino’, fried as relish ‘isishebo’ or raw for both snacking purposes and medicinal functions. Wild edible plant species in the Amathole District of the Eastern Cape-South Africa were documented with respect to their uses and knowledge or identification. Four indigenous wild vegetables (Chenopodium album, Solanum nigrum/nodiflorum, Amaranthus dubius and Urtica lobulata) frequently consumed by the indigenous communities in the study region were selected. All the plant species had a remarkably high content of pro-anthocyanidins (between 58.42 and 65.18 mg/g) and also exhibited high radical scavenging activity in vitro. S. nigrum and C. album were found to be rich sources of ascorbic acid, having 1.05mg/100g and 1.01mg/100g, respectively. The entire wild, traditionally edible plants contain reasonably good concentrations of riboflavin while U. lobulata was found to contain maximum amount of thiamine. All plant species were rich sources of minerals and vitamins (both water soluble and fat soluble). Appropriate cooking methods are to be used to enhance the bio-availability of vitamins and nutrients in general. Cooking generally improved the nutritive value in certain wild vegetables. However, some nutrients were drained away. For example micro-nutrient and anti-nutrient component in the ash were reduced in cooking. The EDXS analysis has shown that the indigenous, wild vegetables in the Amathole District of South Africa are excellent sources of minerals, while the mineral crystals present at the level of the mesophyll of the indigenous wild vegetables were probably mixtures of calcium oxalate, calcium sulphate and silica. Saponin, tannins, oxalates, phytates and alkaloids are present in all the indigenous wild vegetables, but in minimal safe quantities. Nutritional analysis of some wild food plants demonstrates that in many cases the nutritional quality of the plants is comparable and in some cases even superior to domesticated exotic varieties. Knowledge about gathering and use of some wild food species is common among the rural dwellers. However, most uses are known by few elderly informants only. Education, awareness campaigns and revival of use of wild edible plants directed at the youth particularly is essential and this can be done through all forms of media. , Thesis (PhD) (Ethnobotany) -- University of Fort Hare, 2012
- Full Text:
- Date Issued: 2012
The capacity of Nelson Mandela Bay Municipality in refuse management: a policy investigation
- Authors: Pafa, Zolekile Willie
- Date: 2012-01
- Subjects: Refuse and refuse disposal--Government policy , Municipal services--Management
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24969 , vital:63763
- Description: In this dissertation, a study is undertaken to investigate the effectiveness of the public participation in the policy process at the Nelson Mandela Bay Municipality. The study presents an overview of the legislative framework and the role the public can play in the policy process. This is followed by the theoretical framework of the municipal policy process. Based on the theoretical framework presented, an analysis is then made to prove whether the public do participate in the policy process in the Nelson Mandela Bay Municipality. It is envisaged that this study will promote the involvement of the public in the policy process in the Nelson Mandela Bay Municipality. Secondly, the study presents an overview of the legislative framework and the role the public can play in the management of refuse. This is followed by the theoretical framework of refuse management as functional area. Based on the theoretical framework presented, an analysis is then made to prove whether the public is involved in the management of refuse at the Nelson Mandela Bay Municipality. It is envisaged that this study will promote the active involvement of the public in refuse management in the Nelson Mandela Bay Municipality. Finally, the study ends by providing recommendations that will not only assist Nelson Mandela Bay Municipality alone, but the population and the government of the Republic of South Africa. , Thesis (PhD) -- Faculty of Management and Commerce, 2012
- Full Text:
- Date Issued: 2012-01
- Authors: Pafa, Zolekile Willie
- Date: 2012-01
- Subjects: Refuse and refuse disposal--Government policy , Municipal services--Management
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24969 , vital:63763
- Description: In this dissertation, a study is undertaken to investigate the effectiveness of the public participation in the policy process at the Nelson Mandela Bay Municipality. The study presents an overview of the legislative framework and the role the public can play in the policy process. This is followed by the theoretical framework of the municipal policy process. Based on the theoretical framework presented, an analysis is then made to prove whether the public do participate in the policy process in the Nelson Mandela Bay Municipality. It is envisaged that this study will promote the involvement of the public in the policy process in the Nelson Mandela Bay Municipality. Secondly, the study presents an overview of the legislative framework and the role the public can play in the management of refuse. This is followed by the theoretical framework of refuse management as functional area. Based on the theoretical framework presented, an analysis is then made to prove whether the public is involved in the management of refuse at the Nelson Mandela Bay Municipality. It is envisaged that this study will promote the active involvement of the public in refuse management in the Nelson Mandela Bay Municipality. Finally, the study ends by providing recommendations that will not only assist Nelson Mandela Bay Municipality alone, but the population and the government of the Republic of South Africa. , Thesis (PhD) -- Faculty of Management and Commerce, 2012
- Full Text:
- Date Issued: 2012-01
The role of confession in achieving reconciliation among people living in conflict: guidelines for pastoral care
- Sulo, Mmeli Othniel https://orcid.org/0000-0003-1448-9452
- Authors: Sulo, Mmeli Othniel https://orcid.org/0000-0003-1448-9452
- Date: 2012-01
- Subjects: Pastoral counseling , Pastoral care , Confession--Biblical teaching
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24993 , vital:63775
- Description: Introduction: To confess is to acknowledge guilt before God and fellow human beings. The act of confession emanates from awareness of guilt and serves to restore damaged relationships. It is naturally difficult to confess one‟s wrongs, and, in doing so, to render oneself vulnerable to censure. For Christians, however, within an environment, of pastoral concern, confession is essential for the enhancement of fellowship and for the ongoing reconstruction of a believer‟s integrity and a better society. Anyone seeking to resolve conflict through the pastoral function of confession should be properly motivated. Confession does not come cheap. Ecclesiastical conflict among Christians in South Africa has caused hurt. Christians of different colour, language and culture have hurt each other despite sharing the same Christian background and ecclesiastical traditions. It is suggested in this study that the Dutch Reformed Church (DRC) has hurt the other member churches of the DRC family. The DRC, accordingly should become the confessant and the other churches in the DRC family, should be open and receptive to hear the confessant‟s confession. As Boesak puts it, “within the [Dutch] Reformed family racism has made it virtually impossible to share in…that most significant act within the community of the faithful,…of the unity of the Body of Christ, the Lord‟s Supper. And so white and 11 black [Dutch] Reformed Christians miss the meaning of the sacrament which Calvin so much wanted to impress upon our minds” (Boesak, 1987:7). Boesak‟s observation concerns the DRC‟s decision1 to segregate believers from each other. This not only affected the DRC family negatively but also the ecumenical church and the wider society of South Africa. , Thesis (PhD) -- Faculty of Social Sciences and Humanities, 2012
- Full Text:
- Date Issued: 2012-01
- Authors: Sulo, Mmeli Othniel https://orcid.org/0000-0003-1448-9452
- Date: 2012-01
- Subjects: Pastoral counseling , Pastoral care , Confession--Biblical teaching
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24993 , vital:63775
- Description: Introduction: To confess is to acknowledge guilt before God and fellow human beings. The act of confession emanates from awareness of guilt and serves to restore damaged relationships. It is naturally difficult to confess one‟s wrongs, and, in doing so, to render oneself vulnerable to censure. For Christians, however, within an environment, of pastoral concern, confession is essential for the enhancement of fellowship and for the ongoing reconstruction of a believer‟s integrity and a better society. Anyone seeking to resolve conflict through the pastoral function of confession should be properly motivated. Confession does not come cheap. Ecclesiastical conflict among Christians in South Africa has caused hurt. Christians of different colour, language and culture have hurt each other despite sharing the same Christian background and ecclesiastical traditions. It is suggested in this study that the Dutch Reformed Church (DRC) has hurt the other member churches of the DRC family. The DRC, accordingly should become the confessant and the other churches in the DRC family, should be open and receptive to hear the confessant‟s confession. As Boesak puts it, “within the [Dutch] Reformed family racism has made it virtually impossible to share in…that most significant act within the community of the faithful,…of the unity of the Body of Christ, the Lord‟s Supper. And so white and 11 black [Dutch] Reformed Christians miss the meaning of the sacrament which Calvin so much wanted to impress upon our minds” (Boesak, 1987:7). Boesak‟s observation concerns the DRC‟s decision1 to segregate believers from each other. This not only affected the DRC family negatively but also the ecumenical church and the wider society of South Africa. , Thesis (PhD) -- Faculty of Social Sciences and Humanities, 2012
- Full Text:
- Date Issued: 2012-01
A participatory communication approach of a rural cattle project: : a case study of Nguni cattle project in the Eastern Cape, South Africa.
- Usadolo, Sam Erevbenagie (https://orcid.org/0000-0001-6291-7680)
- Authors: Usadolo, Sam Erevbenagie (https://orcid.org/0000-0001-6291-7680)
- Date: 2011-12
- Subjects: Communication in Community Development , Community Development , Nguni Cattle
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24076 , vital:62339
- Description: This study examined the participatory communication practices of a rural cattle project. It did this by reviewing relevant literature in development communication. The review done showed that literature is replete with arguments critical of the dominant paradigm due to its top-down nature of communication. Scholars critical of dominant paradigm argue that participatory communication should be given a prominent role to ensure that stakeholders work in concert to realise the stated objectives of their development project. The study highlighted many contentious issues surrounding the nature and practices of participatory communication. It pointed out that the issues have played themselves out in literature in the form of different typologies of participatory practices, which were dealt with extensively in this study. The discussion of participatory communication in literature is also mindful of different models of communication and the space they occupy in participatory communication practices. In this study, there was a discussion of transactional communication models as depicted by Nair and White (1993:52) and Steinberg (1997:19). Both scholars emphasise that participatory communication will not achieve its stated purpose without mutual agreement of the parties in communication. They equally stress the recognition of the possible effects of some contextual factors which may have bearing on the prevailing nature of communication. A review of different communication tools used by participatory development communicator was given in the study. These different communication tools were discussed in view of how these tools can be used to advance participatory practice in a development project, especially with reference to the project examined in this study. Using qualitative research method, different and appropriate interview methods such as semi-structured, focus group and post-survey interviews were used to collect data from the respondents in this study. The analysis and discussion of the data revealed that different challenges on the ground could affect participatory communication practices in a development project. With regard to the project examined in this study, the analysis showed that there is a weak stakeholder relationship, especially stakeholders identified in this study as field officers. The study highlighted that stakeholders such as the agricultural extension officers and animal health technicians are not very active in the implementation process of the project. Some of the reasons pointed out is the fact that the secondary stakeholder such as the Provincial Department of Agricultural (PDoA) to which these field officers belong is not playing active role in ensuring that they complement the efforts of other field officers such as the IDC representatives. The second reason is the fact that the participatory focus of the project was not properly communicated to the beneficiaries. This also transpired in their inability to reflect participatory practice in their relationship with the beneficiaries and other stakeholders of the project. Other challenges, among others, as pointed out in the analysis showed that participatory communication practice requires expert personnel to be successful. In the case of the project examined, apart from the fact that there is shortage of manpower to handle the challenges mentioned in the study, there is no communication expert among the few active personnel in the field. The findings of this study showed that there was no clear role and identification of responsibilities let alone coordination of all actors involved in the project. Through the selected case study, this study has not only provided avenue to explore both theoretically and practically participatory communication, but has added to participatory communication discourse that there is no easy answer to challenges field officers encounter in practice. This is the reason the different participatory practices characterising nature of the project this study has investigated was given. , Thesis (PhD) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-12
- Authors: Usadolo, Sam Erevbenagie (https://orcid.org/0000-0001-6291-7680)
- Date: 2011-12
- Subjects: Communication in Community Development , Community Development , Nguni Cattle
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24076 , vital:62339
- Description: This study examined the participatory communication practices of a rural cattle project. It did this by reviewing relevant literature in development communication. The review done showed that literature is replete with arguments critical of the dominant paradigm due to its top-down nature of communication. Scholars critical of dominant paradigm argue that participatory communication should be given a prominent role to ensure that stakeholders work in concert to realise the stated objectives of their development project. The study highlighted many contentious issues surrounding the nature and practices of participatory communication. It pointed out that the issues have played themselves out in literature in the form of different typologies of participatory practices, which were dealt with extensively in this study. The discussion of participatory communication in literature is also mindful of different models of communication and the space they occupy in participatory communication practices. In this study, there was a discussion of transactional communication models as depicted by Nair and White (1993:52) and Steinberg (1997:19). Both scholars emphasise that participatory communication will not achieve its stated purpose without mutual agreement of the parties in communication. They equally stress the recognition of the possible effects of some contextual factors which may have bearing on the prevailing nature of communication. A review of different communication tools used by participatory development communicator was given in the study. These different communication tools were discussed in view of how these tools can be used to advance participatory practice in a development project, especially with reference to the project examined in this study. Using qualitative research method, different and appropriate interview methods such as semi-structured, focus group and post-survey interviews were used to collect data from the respondents in this study. The analysis and discussion of the data revealed that different challenges on the ground could affect participatory communication practices in a development project. With regard to the project examined in this study, the analysis showed that there is a weak stakeholder relationship, especially stakeholders identified in this study as field officers. The study highlighted that stakeholders such as the agricultural extension officers and animal health technicians are not very active in the implementation process of the project. Some of the reasons pointed out is the fact that the secondary stakeholder such as the Provincial Department of Agricultural (PDoA) to which these field officers belong is not playing active role in ensuring that they complement the efforts of other field officers such as the IDC representatives. The second reason is the fact that the participatory focus of the project was not properly communicated to the beneficiaries. This also transpired in their inability to reflect participatory practice in their relationship with the beneficiaries and other stakeholders of the project. Other challenges, among others, as pointed out in the analysis showed that participatory communication practice requires expert personnel to be successful. In the case of the project examined, apart from the fact that there is shortage of manpower to handle the challenges mentioned in the study, there is no communication expert among the few active personnel in the field. The findings of this study showed that there was no clear role and identification of responsibilities let alone coordination of all actors involved in the project. Through the selected case study, this study has not only provided avenue to explore both theoretically and practically participatory communication, but has added to participatory communication discourse that there is no easy answer to challenges field officers encounter in practice. This is the reason the different participatory practices characterising nature of the project this study has investigated was given. , Thesis (PhD) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-12
Characterisation of communal rangeland degradation and evaluation of vegetation restoration techniques in the Eastern Cape, South Africa
- Authors: Lesoli, 'Mota Samuel
- Date: 2011-12
- Subjects: Communal rangelands , Grazing
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24316 , vital:62624
- Description: This study assessed the social factors influencing poor communal rangeland management, which are assumed to result in rangeland degradation. This was followed by, examination of biophysical characteristics of rangeland degradation in communal areas. To relate social factors featuring in communal rangeland management with rangeland degradation, biophysical factors influencing livestock grazing distribution patterns were studied. To establish the solution to communal rangeland degradation, rangeland restoration techniques were evaluated. The study was conducted at Amakhuze Tribal Authority (ATA) (S32o 38´, E26o56, 763 - 1500 m.a.s.l) composed of six villages and Phandulwazi Agricultural High School (S32o 39´ and E26o 55´, 747 m.a.s.l). Focus group discussions were conducted in six villages and questionnaire surveys in four randomly selected villages to assess social factors influencing communal rangeland degradation. Communal rangeland degradation biophysical characteristics were assessed. Biophysical factors affecting livestock grazing distribution pattern were examined through direct field observations for 12 months. Restoration techniques were evaluated on 26 plots. The social factors influencing communal rangeland management include lack of skills on rangeland management for farmers, lack of individual/community obligation on grazing management, lack of effective policies and/or poor enforcement accompanied by lack of effective institutions governing rangeland utilisation and management. Communal rangelands were more (χ 2 = 2612.07, df = 26, p < 0.01) degraded compared with controlled grazing areas. Within the communal rangelands, land degradation was higher at the low-lying areas, compared to foothills, midslopes, and mountaintop (crest). Rangeland degradation in communal areas was characterised by poor forage productivity and poor vegetation cover , higher soil unconfined compressive strength (UCS) (4.5 kg/cm2) with low hydraulic conductivity (5.21 x 10-3) and physical soil loss characteristics such presence of terracettes, pedestals, rills and gullies. Grazing distribution was higher at valley bottom (r2 = 0.404, p < 0.001), low altitude (r2 = -0.007, p < 0.001), closer to water points (r2 = -0.001, p < 0.001), and on grassland vegetation (r2 = 0.620, p < 0.001). Introduction of seedlings with microcatchment combined with brushpack promoted (p < 0.05) higher number of tillers (13), leaves (42) and reduced seedling mortality (10.4percent). T. triandra produced higher (p < 0.05) number of tillers (12) and leaves (39) but low number of inflorescence (0.7) with higher mortality rates (25.3percent) compared to P. dilatatum. Where plant propagules were introduced as seeds, use of microcatchment promoted higher seed germination (F = 38.84, p < 0.05) and maintained higher plant density (F = 37.43, p < 0.05). E. curvula seeds attained higher germination rate and maintained higher plant density compared to D. eriantha and P. Maximum. Use of microcatchment, brushpack, and water spreading system promoted soil water retention. It is important that any interventions aimed at improving communal rangeland management, controlling rangeland degradation in the communal areas, or restoring degraded rangelands to consider the social factors driving rangeland management and biophysical factors influencing grazing distribution pattern. Rangeland restoration techniques for communal areas should be centred on their ability to collect and retain water to promote restoration performance of introduced plant propagules. , Thesis (PhD) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-12
- Authors: Lesoli, 'Mota Samuel
- Date: 2011-12
- Subjects: Communal rangelands , Grazing
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24316 , vital:62624
- Description: This study assessed the social factors influencing poor communal rangeland management, which are assumed to result in rangeland degradation. This was followed by, examination of biophysical characteristics of rangeland degradation in communal areas. To relate social factors featuring in communal rangeland management with rangeland degradation, biophysical factors influencing livestock grazing distribution patterns were studied. To establish the solution to communal rangeland degradation, rangeland restoration techniques were evaluated. The study was conducted at Amakhuze Tribal Authority (ATA) (S32o 38´, E26o56, 763 - 1500 m.a.s.l) composed of six villages and Phandulwazi Agricultural High School (S32o 39´ and E26o 55´, 747 m.a.s.l). Focus group discussions were conducted in six villages and questionnaire surveys in four randomly selected villages to assess social factors influencing communal rangeland degradation. Communal rangeland degradation biophysical characteristics were assessed. Biophysical factors affecting livestock grazing distribution pattern were examined through direct field observations for 12 months. Restoration techniques were evaluated on 26 plots. The social factors influencing communal rangeland management include lack of skills on rangeland management for farmers, lack of individual/community obligation on grazing management, lack of effective policies and/or poor enforcement accompanied by lack of effective institutions governing rangeland utilisation and management. Communal rangelands were more (χ 2 = 2612.07, df = 26, p < 0.01) degraded compared with controlled grazing areas. Within the communal rangelands, land degradation was higher at the low-lying areas, compared to foothills, midslopes, and mountaintop (crest). Rangeland degradation in communal areas was characterised by poor forage productivity and poor vegetation cover , higher soil unconfined compressive strength (UCS) (4.5 kg/cm2) with low hydraulic conductivity (5.21 x 10-3) and physical soil loss characteristics such presence of terracettes, pedestals, rills and gullies. Grazing distribution was higher at valley bottom (r2 = 0.404, p < 0.001), low altitude (r2 = -0.007, p < 0.001), closer to water points (r2 = -0.001, p < 0.001), and on grassland vegetation (r2 = 0.620, p < 0.001). Introduction of seedlings with microcatchment combined with brushpack promoted (p < 0.05) higher number of tillers (13), leaves (42) and reduced seedling mortality (10.4percent). T. triandra produced higher (p < 0.05) number of tillers (12) and leaves (39) but low number of inflorescence (0.7) with higher mortality rates (25.3percent) compared to P. dilatatum. Where plant propagules were introduced as seeds, use of microcatchment promoted higher seed germination (F = 38.84, p < 0.05) and maintained higher plant density (F = 37.43, p < 0.05). E. curvula seeds attained higher germination rate and maintained higher plant density compared to D. eriantha and P. Maximum. Use of microcatchment, brushpack, and water spreading system promoted soil water retention. It is important that any interventions aimed at improving communal rangeland management, controlling rangeland degradation in the communal areas, or restoring degraded rangelands to consider the social factors driving rangeland management and biophysical factors influencing grazing distribution pattern. Rangeland restoration techniques for communal areas should be centred on their ability to collect and retain water to promote restoration performance of introduced plant propagules. , Thesis (PhD) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-12
The string vibrator experiment-experimental and analytical determination of system fundamental natural frequencies
- Authors: Gordon, Mark Leonard
- Date: 2011-11
- Subjects: Vibration , Nonlinear oscillations , Waves
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24002 , vital:62245
- Description: This thesis represents an experimental and intellectual journey of more than three years. The String Vibrator Experiment (SVE) is an experimental payload on the SumbandilaSat, satellite. The experiment was initially designed to compare low-earthorbitstretched string nonlinear dynamics with those found terrestrially, with particular emphasis on the effects of micro-gravity and near vacuum. Due to the damage of some internal components of the SVE, the terrestrial experiment had to be characterized by finding both transverse fundamental natural frequencies and the longitudinal system fundamental natural frequency. Forced and free vibration tests were performed on the SVE, with comparable results. The percentage frequency difference between measurement results obtained for the said natural frequencies was found to be acceptable. An analytical model for the string longitudinal system was developed using Energy Methods, assuming linear coupling of the stretched string and the flexible support. Bessel Functions were used to find the natural frequency of the flexible support, which is made of a thin-circular plate loaded centrally by the stretched string and fixed on its outer boundary. The natural frequency thus predicted, corresponds closely with that measured by Laser Doppler Vibrometry. It was found that the longitudinal system behaves in an uncoupled, manner. In this study use was made of piezo bi-morph sensors as vibration measuring devices, with promising results. A method called the peak amplitude discrimination method is introduced to find the respective resonant frequencies; this method is an adaptation of the sweptsine frequency method Nonlinear behavior of the SVE was found to exist exhibiting Sub-harmonics, Super-harmonics, Combination harmonics and Internal Resonances. It is hoped that the experimental methods used in this study would aid in the measurement and analysis of longitudinal vibrations found in flexible cables, rods and rigid bars. , Thesis (PhD) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-11
- Authors: Gordon, Mark Leonard
- Date: 2011-11
- Subjects: Vibration , Nonlinear oscillations , Waves
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24002 , vital:62245
- Description: This thesis represents an experimental and intellectual journey of more than three years. The String Vibrator Experiment (SVE) is an experimental payload on the SumbandilaSat, satellite. The experiment was initially designed to compare low-earthorbitstretched string nonlinear dynamics with those found terrestrially, with particular emphasis on the effects of micro-gravity and near vacuum. Due to the damage of some internal components of the SVE, the terrestrial experiment had to be characterized by finding both transverse fundamental natural frequencies and the longitudinal system fundamental natural frequency. Forced and free vibration tests were performed on the SVE, with comparable results. The percentage frequency difference between measurement results obtained for the said natural frequencies was found to be acceptable. An analytical model for the string longitudinal system was developed using Energy Methods, assuming linear coupling of the stretched string and the flexible support. Bessel Functions were used to find the natural frequency of the flexible support, which is made of a thin-circular plate loaded centrally by the stretched string and fixed on its outer boundary. The natural frequency thus predicted, corresponds closely with that measured by Laser Doppler Vibrometry. It was found that the longitudinal system behaves in an uncoupled, manner. In this study use was made of piezo bi-morph sensors as vibration measuring devices, with promising results. A method called the peak amplitude discrimination method is introduced to find the respective resonant frequencies; this method is an adaptation of the sweptsine frequency method Nonlinear behavior of the SVE was found to exist exhibiting Sub-harmonics, Super-harmonics, Combination harmonics and Internal Resonances. It is hoped that the experimental methods used in this study would aid in the measurement and analysis of longitudinal vibrations found in flexible cables, rods and rigid bars. , Thesis (PhD) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-11
Medicinal properties of Moringa (Moringa Oleifera Lam) leaves and the effect of its use as a supplement on goat growth performance and meat characteristics
- Moyo, Busani https://orcid.org/0000-0001-7002-7266
- Authors: Moyo, Busani https://orcid.org/0000-0001-7002-7266
- Date: 2011-09
- Subjects: Moringa , Medicinal plants
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24376 , vital:62662
- Description: The main objective of the study was to determine if feeding goats with Moringa oleifera leaves would lead to an increase in productivity and in value of the meat. The proximate, van Soet, atomic absorption spectrophotometric and soxhlet extraction methods were used to determine the nutritional value M. oleifera leaves of the South African. The in-vitro antimicrobial screening methods were used to determine antimicrobial activities M. oleifera extracts while in vitro and invivo models were used to determine the antioxidant activities of M. oleifera leaves. An evaluation of the potential of M. oleifera leaf meal as a feed supplement in terms of its effect on helminth load, goat growth performance, carcass characteristics, meat quality attributes, nutritional and consumer sensory characteristics of goat meat was done. A total of 24, eight month old goats were randomly allocated to dietary treatments of M. oleifera leaf meal (MOL), sunflower seed cake (SC) and GH (grass hay) which was the control. All the groups were fed on basal diet of grass hay ad libitum and 200g wheat bran per head per day. The MOL group was given an additional 200 g of dried M. oleifera leaves while the SC group was offered 170 g sunflower seed cake per head/day. The study showed that the dried leaves had crude protein levels of 30.3 percent, polyunsaturated fatty acids (52.21 percent), Saturated fatty acids (43.31), n-3 (44.57 percent), n-6 (7.64 percent), 19 amino acids, vitamin E (77 mg/100 g) and Beta-carotene (18.5 mg/100 g). The M. oleifera leaf extracts showed antibacterial activities against Escherichia coli, Enterobacter cloace, Proteus vulgaris, Staphylococcus aureus and Micrococcus kristinae. The supplementation of goats with MOL and SC resulted in decreased feacal larval count and lower Haemonchus contortus, Trichostrongylus colubriforms and Oesophagastum columbianum worm burdens than those in the non-supplemented goats. Goats supplemented with SC and MOL had higher average daily weight gain and heavier carcasses than those in the GH group. Higher pH1 scores were observed in chevon from GH diet than the supplemented ones. The MOL and SC supplemented goats had chevon with higher values for lightness (L*) 24 hr post-mortem than the one from the GH group. The redness (a*) values of chevon 24 hr post mortem was highest in MOL supplemented goats. Warner Bratzler shear force (WBSF) values of SC (30.1 N) and MOL (29.8 N) supplemented goats were lower than those from GH diet (32.6 N). Chevon from goats fed GH diet had significantly higher cooking losses (29.5 percent) than that from MOL (25.4 percent) and SC (25.6 percent) fed groups. It was observed that chevon from MOL and SC supplemented groups had higher crude protein (23.57 and 22.95 percent, respectively) than the one from the GH group (21.20 percent). Cholesterol levels were higher in chevon from SC (42.84) supplemented goats than those from MOL (38.76) and GH (35.63 mg). Chevon from GH and MOL group had higher (P < 0.05) proportions of PUFA, n-3, PUFA/SFA ratio and lower n-6/n-3 ratio. Mean consumer scores for first bite, aroma, flavour and juiceness were higher in the MOL group than in the GH group (P < 0.05). The acetone extract exhibited higher concentrations of total flavonoids, flavonols, phenolics. The acetone extracts depicted higher percentage inhibition against DPPH, ABTS and nitric oxide radicals which were comparable with reference antioxidant (vitamin C and BHT). The M. oleifera leaf meal increased the antioxidant activity of GSH, SOD and catalase. Moringa oleifera leaves also exhibited medicinal properties by having anthelmintic, antibacterial activities and showed antioxidant properties. It was also observed that protein supplementation improved the animal growth performance, the physico-chemical characteristics, nutritional and fatty acids composition of meat hence meeting the consumer needs. , Thesis (PhD) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-09
- Authors: Moyo, Busani https://orcid.org/0000-0001-7002-7266
- Date: 2011-09
- Subjects: Moringa , Medicinal plants
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24376 , vital:62662
- Description: The main objective of the study was to determine if feeding goats with Moringa oleifera leaves would lead to an increase in productivity and in value of the meat. The proximate, van Soet, atomic absorption spectrophotometric and soxhlet extraction methods were used to determine the nutritional value M. oleifera leaves of the South African. The in-vitro antimicrobial screening methods were used to determine antimicrobial activities M. oleifera extracts while in vitro and invivo models were used to determine the antioxidant activities of M. oleifera leaves. An evaluation of the potential of M. oleifera leaf meal as a feed supplement in terms of its effect on helminth load, goat growth performance, carcass characteristics, meat quality attributes, nutritional and consumer sensory characteristics of goat meat was done. A total of 24, eight month old goats were randomly allocated to dietary treatments of M. oleifera leaf meal (MOL), sunflower seed cake (SC) and GH (grass hay) which was the control. All the groups were fed on basal diet of grass hay ad libitum and 200g wheat bran per head per day. The MOL group was given an additional 200 g of dried M. oleifera leaves while the SC group was offered 170 g sunflower seed cake per head/day. The study showed that the dried leaves had crude protein levels of 30.3 percent, polyunsaturated fatty acids (52.21 percent), Saturated fatty acids (43.31), n-3 (44.57 percent), n-6 (7.64 percent), 19 amino acids, vitamin E (77 mg/100 g) and Beta-carotene (18.5 mg/100 g). The M. oleifera leaf extracts showed antibacterial activities against Escherichia coli, Enterobacter cloace, Proteus vulgaris, Staphylococcus aureus and Micrococcus kristinae. The supplementation of goats with MOL and SC resulted in decreased feacal larval count and lower Haemonchus contortus, Trichostrongylus colubriforms and Oesophagastum columbianum worm burdens than those in the non-supplemented goats. Goats supplemented with SC and MOL had higher average daily weight gain and heavier carcasses than those in the GH group. Higher pH1 scores were observed in chevon from GH diet than the supplemented ones. The MOL and SC supplemented goats had chevon with higher values for lightness (L*) 24 hr post-mortem than the one from the GH group. The redness (a*) values of chevon 24 hr post mortem was highest in MOL supplemented goats. Warner Bratzler shear force (WBSF) values of SC (30.1 N) and MOL (29.8 N) supplemented goats were lower than those from GH diet (32.6 N). Chevon from goats fed GH diet had significantly higher cooking losses (29.5 percent) than that from MOL (25.4 percent) and SC (25.6 percent) fed groups. It was observed that chevon from MOL and SC supplemented groups had higher crude protein (23.57 and 22.95 percent, respectively) than the one from the GH group (21.20 percent). Cholesterol levels were higher in chevon from SC (42.84) supplemented goats than those from MOL (38.76) and GH (35.63 mg). Chevon from GH and MOL group had higher (P < 0.05) proportions of PUFA, n-3, PUFA/SFA ratio and lower n-6/n-3 ratio. Mean consumer scores for first bite, aroma, flavour and juiceness were higher in the MOL group than in the GH group (P < 0.05). The acetone extract exhibited higher concentrations of total flavonoids, flavonols, phenolics. The acetone extracts depicted higher percentage inhibition against DPPH, ABTS and nitric oxide radicals which were comparable with reference antioxidant (vitamin C and BHT). The M. oleifera leaf meal increased the antioxidant activity of GSH, SOD and catalase. Moringa oleifera leaves also exhibited medicinal properties by having anthelmintic, antibacterial activities and showed antioxidant properties. It was also observed that protein supplementation improved the animal growth performance, the physico-chemical characteristics, nutritional and fatty acids composition of meat hence meeting the consumer needs. , Thesis (PhD) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-09
Social policy and the state in South Africa: pathways for human capability development
- Monyai, Priscilla B. (https://orcid.org/0000-0003-0139-0939)
- Authors: Monyai, Priscilla B. (https://orcid.org/0000-0003-0139-0939)
- Date: 2011-08
- Subjects: Social Policy , Human Capital , Apartheid
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24059 , vital:62334
- Description: The main focus of this thesis is the challenges that are facing social policy development and implementation in South Africa in relation to the enhancement of human capability. The study adopted a historical approach to assess the model of social policy in South Africa and identified that social relations of domination inherited from the apartheid era continuing to produce inequalities in opportunities. Social policy under the democratic government has not managed to address social inequalities and the main drivers of poverty in the form of income poverty, asset poverty and capability poverty which are the underlying factors reproducing deprivation and destitution of the majority of the population. Although South Africa prides itself of a stable democracy, social inequalities continue to undermine the benefits of social citizenship because political participation in the midst of unequal access to economic and social resources undermine the value of citizenship. Also, inequalities in the distribution of income and wealth, and in the control of economic production undermine political equality which is an ethic upon which social rights are predicated. As a result, state interventions are lacking inherent potential to build human capability for people to live the life that they have reason to value. The paradox of social policy in South Africa is that the majority of those who are marginalised are those who were excluded by the apartheid regime even though state intervention is claimed to be targeting them. This points to the failure of incremental equalisation of opportunities within a context of stark social inequities. It is also an indication that the economic growth path delivered by the political. , Thesis (Doctoral) -- Faculty of Management and Commerce, 2011
- Full Text:
- Date Issued: 2011-08
- Authors: Monyai, Priscilla B. (https://orcid.org/0000-0003-0139-0939)
- Date: 2011-08
- Subjects: Social Policy , Human Capital , Apartheid
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24059 , vital:62334
- Description: The main focus of this thesis is the challenges that are facing social policy development and implementation in South Africa in relation to the enhancement of human capability. The study adopted a historical approach to assess the model of social policy in South Africa and identified that social relations of domination inherited from the apartheid era continuing to produce inequalities in opportunities. Social policy under the democratic government has not managed to address social inequalities and the main drivers of poverty in the form of income poverty, asset poverty and capability poverty which are the underlying factors reproducing deprivation and destitution of the majority of the population. Although South Africa prides itself of a stable democracy, social inequalities continue to undermine the benefits of social citizenship because political participation in the midst of unequal access to economic and social resources undermine the value of citizenship. Also, inequalities in the distribution of income and wealth, and in the control of economic production undermine political equality which is an ethic upon which social rights are predicated. As a result, state interventions are lacking inherent potential to build human capability for people to live the life that they have reason to value. The paradox of social policy in South Africa is that the majority of those who are marginalised are those who were excluded by the apartheid regime even though state intervention is claimed to be targeting them. This points to the failure of incremental equalisation of opportunities within a context of stark social inequities. It is also an indication that the economic growth path delivered by the political. , Thesis (Doctoral) -- Faculty of Management and Commerce, 2011
- Full Text:
- Date Issued: 2011-08
On the design, evaluation and performance of an energy efficient solar house with integrated photovoltaics
- Authors: Ziuku, Sosten
- Date: 2011-06
- Subjects: Solar energy , Solar energy -- Environmental aspects , Photovoltaic power generation
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/27473 , vital:67331
- Description: The design, construction and performance monitoring of an energy efficient house with integrated photovoltaics is considered. Unlike conventional housing, the house design combines energy efficiency measures and renewable energy technologies into one building structure. The objective of the study was to investigate the feasibility of using energy efficient solar designs to regulate indoor thermal environment, and determine thecost effectiveness and environmental benefits of such housing designs. The use of ordinary photovoltaic panels as a building element for South Africa’s latitude and meteorological conditions was also investigated. The house model was designed using Autodesk Revit architecture and Ecotect building simulation software. Electrical performance was analyzed using RETScreen and PVDesignPRO software. In addition to passive solar design features and clerestory windows, the design has solar water heaters for hot water supply. The designed energy efficient building integrated photovoltaic (EEBIPV) house was built at the University of Fort Hare. A 3.8 kW BIPV generator was mounted on the north facing roof in such a way that the solar panels replace conventional roofing material. A data acquisition system that monitors thermal and electrical performance was installed. The grid independent house has been occupied since February 2009 and its winter indoor thermal efficiency improved from 70 to more than 78% after ceiling installation. Models for indoor thermal performance and BIPV energy and exergy contributions were developed. The avoided energy consumption from the grid has potential to reduce carbon emissions by 12.41 tons per annum. The total building cost per m2 of floor area compares favourably with the cost of commercial middle-to-upper income domestic housing units without energy efficiency measures and building integrated photovoltaics. The research output provides a good framework for the integration of passive solar designs, natural ventilation and lighting, solar water heaters and building integrated photovoltaics into new and existing housing units. , Thesis (MSci) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-06
- Authors: Ziuku, Sosten
- Date: 2011-06
- Subjects: Solar energy , Solar energy -- Environmental aspects , Photovoltaic power generation
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/27473 , vital:67331
- Description: The design, construction and performance monitoring of an energy efficient house with integrated photovoltaics is considered. Unlike conventional housing, the house design combines energy efficiency measures and renewable energy technologies into one building structure. The objective of the study was to investigate the feasibility of using energy efficient solar designs to regulate indoor thermal environment, and determine thecost effectiveness and environmental benefits of such housing designs. The use of ordinary photovoltaic panels as a building element for South Africa’s latitude and meteorological conditions was also investigated. The house model was designed using Autodesk Revit architecture and Ecotect building simulation software. Electrical performance was analyzed using RETScreen and PVDesignPRO software. In addition to passive solar design features and clerestory windows, the design has solar water heaters for hot water supply. The designed energy efficient building integrated photovoltaic (EEBIPV) house was built at the University of Fort Hare. A 3.8 kW BIPV generator was mounted on the north facing roof in such a way that the solar panels replace conventional roofing material. A data acquisition system that monitors thermal and electrical performance was installed. The grid independent house has been occupied since February 2009 and its winter indoor thermal efficiency improved from 70 to more than 78% after ceiling installation. Models for indoor thermal performance and BIPV energy and exergy contributions were developed. The avoided energy consumption from the grid has potential to reduce carbon emissions by 12.41 tons per annum. The total building cost per m2 of floor area compares favourably with the cost of commercial middle-to-upper income domestic housing units without energy efficiency measures and building integrated photovoltaics. The research output provides a good framework for the integration of passive solar designs, natural ventilation and lighting, solar water heaters and building integrated photovoltaics into new and existing housing units. , Thesis (MSci) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-06
A study of rural self-help groups in the context of government-assisted community development: the case of Peddie, Eastern Cape, South Africa.
- Pakade-Yokwana, Nozuko zandiswa Gloria
- Authors: Pakade-Yokwana, Nozuko zandiswa Gloria
- Date: 2011
- Subjects: Community development http://id.loc.gov/authorities/subjects/sh85029215 , Rural development http://id.loc.gov/authorities/subjects/sh85115899
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/19616 , vital:43152
- Description: This study was conducted against the backdrop of growing scholarly interest in the epistemic divide between formal, institutionalised knowledge, which guide government interventions in rural community development, and local knowledge, upon which rural communities construct their social existence. The study sought to understand why, despite their resilience and cultural embeddedness in South Africa's rural communities, indigenous self-help groups (SHGs) - as a particular form of indigenous rationality - remained on the periphery of contemporary community development interventions. The study was conducted in the communities of Dabhana, Feni and Mgwanlana in Peddie (Ngqushwa Local Municipality), Eastern Cape. Three SHG variants were eselected: a funeral group (Masingcwabane), an HIV and AIDS support groups, and a financial mutual (mgalelo) – all in the context of government-assisted community development. Empirical data was collected using a mini-survey, focus group discussion, in-depth interviews and key informant interviews. The findings revealed that SHGs were a collective model of indigenous knowledge and social interaction, driven by the belief that through 'sharing', 'reciprocity' and 'collectivism', what would ordinarily be a heavy burden for individuals became 'lighter'. Furthermore, while the institutional framework for community development mandated collaboration between government and SHGs, this framework created a stiff, bureaucratic canvass that alienated SHGs and stifled their operations. The study also found that partnership between the government and SHGs was characterised by fear and distrust on the part of government, and reluctance on the part of SHGs. Government's distrust was premised on the "informality" and "traditionality" of SHGs, and the fear that any investment in SHGs would go to waste. On the other hand, SHGs' reluctance to make themselves amenable to partnership with government seemed like a reaction to a "faulty, culturally insensitive" institutional framework which "delegitimised" grassroots development impulses. The study concluded that there existed in the rural community development arena an epistemic, ideational and practical chasm between government-driven development praxis and age-old indigenous initiatives, and that while the weaknesses of each knowledge domain were accentuated through this divide, development would continue to elude the grassroots communities unless the two knowledge domains interacted with, and leveraged, each other. , Thesis (PhD) (Sociology) -- University of Fort Hare, 2018
- Full Text:
- Date Issued: 2011
- Authors: Pakade-Yokwana, Nozuko zandiswa Gloria
- Date: 2011
- Subjects: Community development http://id.loc.gov/authorities/subjects/sh85029215 , Rural development http://id.loc.gov/authorities/subjects/sh85115899
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/19616 , vital:43152
- Description: This study was conducted against the backdrop of growing scholarly interest in the epistemic divide between formal, institutionalised knowledge, which guide government interventions in rural community development, and local knowledge, upon which rural communities construct their social existence. The study sought to understand why, despite their resilience and cultural embeddedness in South Africa's rural communities, indigenous self-help groups (SHGs) - as a particular form of indigenous rationality - remained on the periphery of contemporary community development interventions. The study was conducted in the communities of Dabhana, Feni and Mgwanlana in Peddie (Ngqushwa Local Municipality), Eastern Cape. Three SHG variants were eselected: a funeral group (Masingcwabane), an HIV and AIDS support groups, and a financial mutual (mgalelo) – all in the context of government-assisted community development. Empirical data was collected using a mini-survey, focus group discussion, in-depth interviews and key informant interviews. The findings revealed that SHGs were a collective model of indigenous knowledge and social interaction, driven by the belief that through 'sharing', 'reciprocity' and 'collectivism', what would ordinarily be a heavy burden for individuals became 'lighter'. Furthermore, while the institutional framework for community development mandated collaboration between government and SHGs, this framework created a stiff, bureaucratic canvass that alienated SHGs and stifled their operations. The study also found that partnership between the government and SHGs was characterised by fear and distrust on the part of government, and reluctance on the part of SHGs. Government's distrust was premised on the "informality" and "traditionality" of SHGs, and the fear that any investment in SHGs would go to waste. On the other hand, SHGs' reluctance to make themselves amenable to partnership with government seemed like a reaction to a "faulty, culturally insensitive" institutional framework which "delegitimised" grassroots development impulses. The study concluded that there existed in the rural community development arena an epistemic, ideational and practical chasm between government-driven development praxis and age-old indigenous initiatives, and that while the weaknesses of each knowledge domain were accentuated through this divide, development would continue to elude the grassroots communities unless the two knowledge domains interacted with, and leveraged, each other. , Thesis (PhD) (Sociology) -- University of Fort Hare, 2018
- Full Text:
- Date Issued: 2011
Functionalized Ru(II) polypyridines and phthalocyanines: Potential dyes for dye-sensitized solar cells(DSSCs)
- Adeloye, Adewale Olufunsho https://orcid.org/0000-0003-1736-5738
- Authors: Adeloye, Adewale Olufunsho https://orcid.org/0000-0003-1736-5738
- Date: 2011-01
- Subjects: Phthalocyanines , Dye-sensitized solar cells
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24365 , vital:62645
- Description: This study describes the design, synthesis, characterization and preliminary investigation of the solar-to-electrical energy conversion efficiency of ruthenium(II) functionalized polypyridine and phthalocyanine complexes with extended π-conjugation. Polypyridinyl functionalized with anthracene, 2,3-dimethylacrylic acid and 1-methoxy-1-buten-3-yne were synthesized and characterized by infrared, UV-Vis, photoluminescence, 1H and 13C NMR and elemental analysis. The functionalized polypyridine molecules were used to synthesize various ruthenium(II) homoleptic/heteroleptic and/or heteronuclear complexes and their photophysical and electrochemical properties evaluated. The preliminary results of the solar-to-electrical conversion efficiencies of some synthesized Ru(II) polypyridyl complexes were presented in chapter 5. It was found out as expected that the ruthenium(II) polypyridine complexes containing either heteronuclear polypyridine ligands or their thiocyanate analogues of the types [Ru(L1)2L2(PF6)2], [RuL1(L2)2(PF6)2] and [RuL1L2(NCS)2], showed better photophysical properties (red-shifted metal-to-ligand charge-transfer (MLCT) transitions concomitant with enhanced molar extinction coefficients), luminescence and interesting electrochemical redox properties than those containing homonuclear ligand types [Ru(L1)3(PF6)2]. The ruthenium(II) anthracenyl functionalized phthalocyanine complexes which were obtained by electrophilic aromatic substitution reactions in the peripheral positions gave good solubility properties in various organic solvents and also showed interesting near infrared absorption and electroredox characteristics. Cyclic and square wave voltammetries of these complexes revealed major redox processes and the numbers of electron(s) transfer were determined by chronocoulometry. It was established that a mono- and/or multi-electronic transfer reactions can occur in the various ruthenium(II) complexes. The photophysical properties of some complexes showed them to be better and promising candidates in the design of chemosensors, organic light emitting diodes (OLEDs) and as photosensitizers, while their redox-active natures make them potential mediators in electron-transfer for various photochemical processes. However, due to low surface concentration and/or adsorption of some tested complexes on TiO2 semiconductor nanocrystalline particle, low currents were generated and the highest solar-to- electrical conversion efficiency recorded in this study was 0.10 percent. , Thesis (PhD) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-01
- Authors: Adeloye, Adewale Olufunsho https://orcid.org/0000-0003-1736-5738
- Date: 2011-01
- Subjects: Phthalocyanines , Dye-sensitized solar cells
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24365 , vital:62645
- Description: This study describes the design, synthesis, characterization and preliminary investigation of the solar-to-electrical energy conversion efficiency of ruthenium(II) functionalized polypyridine and phthalocyanine complexes with extended π-conjugation. Polypyridinyl functionalized with anthracene, 2,3-dimethylacrylic acid and 1-methoxy-1-buten-3-yne were synthesized and characterized by infrared, UV-Vis, photoluminescence, 1H and 13C NMR and elemental analysis. The functionalized polypyridine molecules were used to synthesize various ruthenium(II) homoleptic/heteroleptic and/or heteronuclear complexes and their photophysical and electrochemical properties evaluated. The preliminary results of the solar-to-electrical conversion efficiencies of some synthesized Ru(II) polypyridyl complexes were presented in chapter 5. It was found out as expected that the ruthenium(II) polypyridine complexes containing either heteronuclear polypyridine ligands or their thiocyanate analogues of the types [Ru(L1)2L2(PF6)2], [RuL1(L2)2(PF6)2] and [RuL1L2(NCS)2], showed better photophysical properties (red-shifted metal-to-ligand charge-transfer (MLCT) transitions concomitant with enhanced molar extinction coefficients), luminescence and interesting electrochemical redox properties than those containing homonuclear ligand types [Ru(L1)3(PF6)2]. The ruthenium(II) anthracenyl functionalized phthalocyanine complexes which were obtained by electrophilic aromatic substitution reactions in the peripheral positions gave good solubility properties in various organic solvents and also showed interesting near infrared absorption and electroredox characteristics. Cyclic and square wave voltammetries of these complexes revealed major redox processes and the numbers of electron(s) transfer were determined by chronocoulometry. It was established that a mono- and/or multi-electronic transfer reactions can occur in the various ruthenium(II) complexes. The photophysical properties of some complexes showed them to be better and promising candidates in the design of chemosensors, organic light emitting diodes (OLEDs) and as photosensitizers, while their redox-active natures make them potential mediators in electron-transfer for various photochemical processes. However, due to low surface concentration and/or adsorption of some tested complexes on TiO2 semiconductor nanocrystalline particle, low currents were generated and the highest solar-to- electrical conversion efficiency recorded in this study was 0.10 percent. , Thesis (PhD) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-01
Functionalized Ru(II) polypyridines and phthalocyanines: Potential dyes for dye-sensitized solar cells(DSSCs)
- Adeloye, Adewale Olufunsho https://orcid.org/0000-0003-1736-5738
- Authors: Adeloye, Adewale Olufunsho https://orcid.org/0000-0003-1736-5738
- Date: 2011-01
- Subjects: Phthalocyanines , Dye-sensitized solar cells
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24343 , vital:62638
- Description: This study describes the design, synthesis, characterization and preliminary investigation of the solar-to-electrical energy conversion efficiency of ruthenium(II) functionalized polypyridine and phthalocyanine complexes with extended π-conjugation. Polypyridinyl functionalized with anthracene, 2,3-dimethylacrylic acid and 1-methoxy-1-buten-3-yne were synthesized and characterized by infrared, UV-Vis, photoluminescence, 1H and 13C NMR and elemental analysis. The functionalized polypyridine molecules were used to synthesize various ruthenium(II) homoleptic/heteroleptic and/or heteronuclear complexes and their photophysical and electrochemical properties evaluated. The preliminary results of the solar-to-electrical conversion efficiencies of some synthesized Ru(II) polypyridyl complexes were presented in chapter 5. It was found out as expected that the ruthenium(II) polypyridine complexes containing either heteronuclear polypyridine ligands or their thiocyanate analogues of the types [Ru(L1)2L2(PF6)2], [RuL1(L2)2(PF6)2] and [RuL1L2(NCS)2], showed better photophysical properties (red-shifted metal-to-ligand charge-transfer (MLCT) transitions concomitant with enhanced molar extinction coefficients), luminescence and interesting electrochemical redox properties than those containing homonuclear ligand types [Ru(L1)3(PF6)2]. The ruthenium(II) anthracenyl functionalized phthalocyanine complexes which were obtained by electrophilic aromatic substitution reactions in the peripheral positions gave good solubility properties in various organic solvents and also showed interesting near infrared absorption and electroredox characteristics. Cyclic and square wave voltammetries of these complexes revealed major redox processes and the numbers of electron(s) transfer were determined by chronocoulometry. It was established that a mono- and/or multi-electronic transfer reactions can occur in the various ruthenium(II) complexes. The photophysical properties of some complexes showed them to be better and promising candidates in the design of chemosensors, organic light emitting diodes (OLEDs) and as photosensitizers, while their redox-active natures make them potential mediators in electron-transfer for various photochemical processes. However, due to low surface concentration and/or adsorption of some tested complexes on TiO2 semiconductor nanocrystalline particle, low currents were generated and the highest solar-to-electrical conversion efficiency recorded in this study was 0.10 percent. , Thesis (PhD) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-01
- Authors: Adeloye, Adewale Olufunsho https://orcid.org/0000-0003-1736-5738
- Date: 2011-01
- Subjects: Phthalocyanines , Dye-sensitized solar cells
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24343 , vital:62638
- Description: This study describes the design, synthesis, characterization and preliminary investigation of the solar-to-electrical energy conversion efficiency of ruthenium(II) functionalized polypyridine and phthalocyanine complexes with extended π-conjugation. Polypyridinyl functionalized with anthracene, 2,3-dimethylacrylic acid and 1-methoxy-1-buten-3-yne were synthesized and characterized by infrared, UV-Vis, photoluminescence, 1H and 13C NMR and elemental analysis. The functionalized polypyridine molecules were used to synthesize various ruthenium(II) homoleptic/heteroleptic and/or heteronuclear complexes and their photophysical and electrochemical properties evaluated. The preliminary results of the solar-to-electrical conversion efficiencies of some synthesized Ru(II) polypyridyl complexes were presented in chapter 5. It was found out as expected that the ruthenium(II) polypyridine complexes containing either heteronuclear polypyridine ligands or their thiocyanate analogues of the types [Ru(L1)2L2(PF6)2], [RuL1(L2)2(PF6)2] and [RuL1L2(NCS)2], showed better photophysical properties (red-shifted metal-to-ligand charge-transfer (MLCT) transitions concomitant with enhanced molar extinction coefficients), luminescence and interesting electrochemical redox properties than those containing homonuclear ligand types [Ru(L1)3(PF6)2]. The ruthenium(II) anthracenyl functionalized phthalocyanine complexes which were obtained by electrophilic aromatic substitution reactions in the peripheral positions gave good solubility properties in various organic solvents and also showed interesting near infrared absorption and electroredox characteristics. Cyclic and square wave voltammetries of these complexes revealed major redox processes and the numbers of electron(s) transfer were determined by chronocoulometry. It was established that a mono- and/or multi-electronic transfer reactions can occur in the various ruthenium(II) complexes. The photophysical properties of some complexes showed them to be better and promising candidates in the design of chemosensors, organic light emitting diodes (OLEDs) and as photosensitizers, while their redox-active natures make them potential mediators in electron-transfer for various photochemical processes. However, due to low surface concentration and/or adsorption of some tested complexes on TiO2 semiconductor nanocrystalline particle, low currents were generated and the highest solar-to-electrical conversion efficiency recorded in this study was 0.10 percent. , Thesis (PhD) -- Faculty of Science and Agriculture, 2011
- Full Text:
- Date Issued: 2011-01
The role of the Department of Education in addressing the education of children living and working in the street in the Eastern Cape:
- Authors: Mawisa, Nompumelelo Mavis
- Date: 2011-01
- Subjects: Street children , Social Conditions , Education
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/23337 , vital:57354
- Description: A UNICEF report on the drastic effects of child labour in developing countries indicates there are 4040 million children under the age of 18 not attending school (1977). Many are street and working children who deserve the chance, but face parental neglect and poverty to attend school and become conscious and productive citizens. Non-formal education has been identified as an alternative to traditional schooling, in which children learn vocational trades or academic subjects, aimed at enhancing their lives. This alternative approach is considered non-formal education because it is typically short–term and non – degree granting. Though non-formal education can be used for rehabilitation purposes, it cannot replace ultimate schooling. All children want to graduate and compete in the job market. The main aim of this study is to determine the role of the Department of Education in addressing the education of children working and living in the street in the Eastern Cape. The children working and living in the street phenomenon is a major development problem that is experienced all over the developing world. A major cause of this problem in the Eastern Cape is drop–outs due to parental negligence and poverty. To assist children working and living in the street and those in conflict with the law, child and youth care centres in East London, King William’s Town and Queenstown have been established. However, they have not had a very noticeable impact on the magnitude of the problem. Potential for such an impact seems to lie in the domain of collaboration with other non-governmental organisations, other departments and education providers. This study evaluated the quality of education of child and youth care centres and non-formal education programmes in providing education to children working and living in the street, with a view to highlighting the difference that formal education in mainstream schools has, in relation to these centres. The descriptive survey design was used in this study. The sample comprised ten children working and living in the street three child and youth care centres in East London, King William’s Town and Queenstown, ten children working and living in the street in East London, three managers from these centres, and two managers from the Department of Education and the Department of Social Development. The study employed the purposive sampling technique. Data to answer the research questions were collected mainly through questionnaires and interviews. The following conclusions were drawn from this study regarding empowering of children who are working and living in the street: (1) children were acutely cognisant of their impoverished positions in society but were unable to alleviate their economic burdens due to poverty. (2) The lack of teacher training strongly impacted on the children’s self concept to achieve empowerment (3) Non-formal education programmes should be used temporary whilst children working and living in the street are being rehabilitated. Thereafter children should join mainstream schools where they can obtain certificates on completion of their studies. The age factor should be considered when administering non-formal education. (4) Parents were the most important stakeholders in facilitating the enrolment of children in schools and monitoring their attendance. (5) Collaboration of all relevant stakeholders in the education of children working and living in the street is key to their education. , Thesis (PHD) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-01
- Authors: Mawisa, Nompumelelo Mavis
- Date: 2011-01
- Subjects: Street children , Social Conditions , Education
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/23337 , vital:57354
- Description: A UNICEF report on the drastic effects of child labour in developing countries indicates there are 4040 million children under the age of 18 not attending school (1977). Many are street and working children who deserve the chance, but face parental neglect and poverty to attend school and become conscious and productive citizens. Non-formal education has been identified as an alternative to traditional schooling, in which children learn vocational trades or academic subjects, aimed at enhancing their lives. This alternative approach is considered non-formal education because it is typically short–term and non – degree granting. Though non-formal education can be used for rehabilitation purposes, it cannot replace ultimate schooling. All children want to graduate and compete in the job market. The main aim of this study is to determine the role of the Department of Education in addressing the education of children working and living in the street in the Eastern Cape. The children working and living in the street phenomenon is a major development problem that is experienced all over the developing world. A major cause of this problem in the Eastern Cape is drop–outs due to parental negligence and poverty. To assist children working and living in the street and those in conflict with the law, child and youth care centres in East London, King William’s Town and Queenstown have been established. However, they have not had a very noticeable impact on the magnitude of the problem. Potential for such an impact seems to lie in the domain of collaboration with other non-governmental organisations, other departments and education providers. This study evaluated the quality of education of child and youth care centres and non-formal education programmes in providing education to children working and living in the street, with a view to highlighting the difference that formal education in mainstream schools has, in relation to these centres. The descriptive survey design was used in this study. The sample comprised ten children working and living in the street three child and youth care centres in East London, King William’s Town and Queenstown, ten children working and living in the street in East London, three managers from these centres, and two managers from the Department of Education and the Department of Social Development. The study employed the purposive sampling technique. Data to answer the research questions were collected mainly through questionnaires and interviews. The following conclusions were drawn from this study regarding empowering of children who are working and living in the street: (1) children were acutely cognisant of their impoverished positions in society but were unable to alleviate their economic burdens due to poverty. (2) The lack of teacher training strongly impacted on the children’s self concept to achieve empowerment (3) Non-formal education programmes should be used temporary whilst children working and living in the street are being rehabilitated. Thereafter children should join mainstream schools where they can obtain certificates on completion of their studies. The age factor should be considered when administering non-formal education. (4) Parents were the most important stakeholders in facilitating the enrolment of children in schools and monitoring their attendance. (5) Collaboration of all relevant stakeholders in the education of children working and living in the street is key to their education. , Thesis (PHD) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-01
ZIMBABWE’S LIBERATION STRUGGLE: A CRITICAL DECADE OF THE ZIMBABWE AFRICAN NATIONAL UNION (ZANU)’S GUERRILLA WAR, 1970-1980
- Dzimbanhete, Jephias Andrew (https://orcid.org/0000-0002-7648-8722)
- Authors: Dzimbanhete, Jephias Andrew (https://orcid.org/0000-0002-7648-8722)
- Date: 2011-01
- Subjects: National Liberation Movements -- Zimbabwe , Guerillas , Zimbabwe -- History -- Chimurenga
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/23315 , vital:57048
- Description: This study offers a comprehensive examination of the Zimbabwean war of independence depicting the mobilisation of forces of liberation against an intransigent colonial Rhodesian settler state during a critical decade of the 1970s. Its introductory outline presents a broad historical context to the decolonisation processes in Africa. It also introduces the two liberation movements that drove the war of independence, and these revolved around the Zimbabwe African People’s Union (ZAPU) and the Zimbabwe African National Union (ZANU). The empirical chapters of the thesis narrow the focus to the main research subject, that explain the ZANU’s guerrilla warfare and how that was launched under the military wing of the Zimbabwe African National Liberation Army (ZANLA). The study looks, particularly on how and why that formation assembled groundswell support and generated pervasive intelligence to operate relentlessly against the Rhodesian colonial government resulting in a compromised independence in 1980. In addition to a wide-ranging survey of literature that deals with the Zimbabwean war of independence, the production of this thesis is thoroughly grounded on empirical methods that hinge on archival research and oral testimonies. The study breaks new ground in outlining the various facets and different phases of the Zimbabwean liberation war. It reveals that the liberation fighters were not merely provided with arms and deployed to fight the Rhodesian army. Rather they underwent a methodical process, which comprised recruitment, extensive training and fundamental political education. This re-represents an alternative narrative or even eccentric paradigm to that persistently presented within the conventional Zimbabwean liberation war historiography. The thesis breaks further new ground in discussing the complex nature of how intelligence gathering and propaganda uses were also centrally linked to the cooperation of or assistance from the various segments of the colonial African society. Its empirical chapters outline the various actions undertaken by the various groups and individuals, the language they adopted in expressing themselves and the convivial connections between them and the guerrilla fighters in the countryside as the war front expanded within the home boundaries. Chapters also explore in greater detail how the liberation movement bred the complex relation and contestation between the political formation of ZANU and its military wing, ZANLA. The uneven power relations between these two formations somehow dictated the course and the outcome of the liberation war. As a result a constitutional settlement or military victory became the two options by which the Rhodesian question could be resolved in the later 1970s. As it turned out, attempts to seek a constitutional solution became a feature of diplomatic dimensions of the postcolonial Rhodesian political landscape. The study concludes with the latter point. , Thesis (PHD) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-01
- Authors: Dzimbanhete, Jephias Andrew (https://orcid.org/0000-0002-7648-8722)
- Date: 2011-01
- Subjects: National Liberation Movements -- Zimbabwe , Guerillas , Zimbabwe -- History -- Chimurenga
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/23315 , vital:57048
- Description: This study offers a comprehensive examination of the Zimbabwean war of independence depicting the mobilisation of forces of liberation against an intransigent colonial Rhodesian settler state during a critical decade of the 1970s. Its introductory outline presents a broad historical context to the decolonisation processes in Africa. It also introduces the two liberation movements that drove the war of independence, and these revolved around the Zimbabwe African People’s Union (ZAPU) and the Zimbabwe African National Union (ZANU). The empirical chapters of the thesis narrow the focus to the main research subject, that explain the ZANU’s guerrilla warfare and how that was launched under the military wing of the Zimbabwe African National Liberation Army (ZANLA). The study looks, particularly on how and why that formation assembled groundswell support and generated pervasive intelligence to operate relentlessly against the Rhodesian colonial government resulting in a compromised independence in 1980. In addition to a wide-ranging survey of literature that deals with the Zimbabwean war of independence, the production of this thesis is thoroughly grounded on empirical methods that hinge on archival research and oral testimonies. The study breaks new ground in outlining the various facets and different phases of the Zimbabwean liberation war. It reveals that the liberation fighters were not merely provided with arms and deployed to fight the Rhodesian army. Rather they underwent a methodical process, which comprised recruitment, extensive training and fundamental political education. This re-represents an alternative narrative or even eccentric paradigm to that persistently presented within the conventional Zimbabwean liberation war historiography. The thesis breaks further new ground in discussing the complex nature of how intelligence gathering and propaganda uses were also centrally linked to the cooperation of or assistance from the various segments of the colonial African society. Its empirical chapters outline the various actions undertaken by the various groups and individuals, the language they adopted in expressing themselves and the convivial connections between them and the guerrilla fighters in the countryside as the war front expanded within the home boundaries. Chapters also explore in greater detail how the liberation movement bred the complex relation and contestation between the political formation of ZANU and its military wing, ZANLA. The uneven power relations between these two formations somehow dictated the course and the outcome of the liberation war. As a result a constitutional settlement or military victory became the two options by which the Rhodesian question could be resolved in the later 1970s. As it turned out, attempts to seek a constitutional solution became a feature of diplomatic dimensions of the postcolonial Rhodesian political landscape. The study concludes with the latter point. , Thesis (PHD) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-01
Evaluation of the impact of financial fraud and corruption on the sustainable development of selected municipalities in South Africa
- Okubena, Olumuyiwa Olamilekan
- Authors: Okubena, Olumuyiwa Olamilekan
- Date: 2010-12
- Subjects: Sustainable development -- South Africa , Fraud -- South Africa -- Eastern Cape , Municipal services -- South Africa -- Eastern Cape
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/25569 , vital:64335
- Description: This thesis explored the pernicious effects of financial fraud and corruption and the importance of the rule of law, transparency and accountability of public sector. These critical conditions serve as the foundation for the effective and efficient governance and the economic growth of a nation, especially through utilizing the opportunities provided by globalization through increased investment and trade. The thesis looks at the importance of upholding the rule of law and fostering transparency and accountability in the public sector in combating financial fraud and corruption, particularly as components of effective national strategies. The rule of law, transparency and accountability in the public sector serve not only as means to counter financial fraud and corruption but also as fundamental conditions of effective governance. It was discovered that financial fraud and corruption is a complex phenomenon, present in all countries. Its causes are engendered by conditions of underdevelopment. Hence, its effects hinder and impede the development process itself. It was also confirmed that financial fraud and corruption are co-determined by many other factors, including cultural and moral values. The motivation to remain honest may be weakened by low public official’s salaries, promotion of personnel unconnected to performance, dysfunctional government budgets, loss of organizational purpose, bad example by chief official’s and political leaders, or long established patron-client relationships, in which the sharing of bribes or the exchange of favors has become entrenched. Financial fraud and corruption can be highly concentrated at the top of a political system and associated with political power, or broadly based at lower levels in the system, associated with administrative processes and discretionary powers. Hence, bribes can be blatant or subtle and take many different forms, including cash payments, job offers, scholarships, foreign trips or political and other favors. Furthermore, the development of sustainable local authorities however is an ambitious issue that requires local authorities to focus on the improvement of the quality of life of present and future communities without depleting the natural resources at their disposal. For sustainable and equitable development, this study espouses on the far-reaching implications for local authorities through multiple regression analysis due to various economic, social and institutional challenges that have to be taken into consideration when a process to promote sustainable development is considered. To comprehensively actualize the implications of financial fraud and corruption on the sustainable development of local authorities, a multistage cluster sampling, a form of probability sampling technique was adopted. Semantically, to identify the research paradigms suitable for this study, a hybrid approach to research design was used (quantitative and qualitative). This however enables the impact of financial fraud and corruption on the sustainable development of selected local authorities in South Africa to be ascertained. Moreover, the study explores the circumstances and implications surrounding financial fraud and corruption in the local authorities in South-Africa. Financial fraud and corruption tends to emerge when an organization or a public official has monopoly power over a good or service that generates rent, has the discretionary power to decide who will receive it, and is not accountable. Financial fraud and corruption’s roots are grounded in a country’s social and cultural history, political and economic development, bureaucratic traditions and policies. This study also identifies that, direct and indirect factors promote financial fraud and corruption. Direct factors include regulations and authorizations, taxation, spending decisions, provision of goods and services at below market prices, and financing political parties. On the other hand, quality of bureaucracy, level of public sector wages, penalty systems, institutional controls, and transparency of rules, laws, and processes are the indirect factors that promote financial fraud and corruption. Financial fraud and corruption is a symptom of deep institutional weaknesses that leads to inefficient economic, social, and political outcomes. It reduces economic growth, retards long-term foreign and domestic investments, enhances inflation, depreciates national currency, reduces expenditures for education and health, increases military expenditures, misallocates talent to rent-seeking activities, pushes firms underground, distorts markets and the allocation of resources, increases income inequality and poverty, reduces tax revenue, increases child and infant mortality rates, distorts the fundamental role of the government (on enforcement of contracts and protection of property. Nonetheless, this study concludes that financial fraud and corruption impedes economic efficiency which could slow or shrink economic growth. This will adversely affect all income classes, especially the most vulnerable, the poor. The effect of financial fraud and corruption through investment expenditure on health and education critical to sustainable development was noted in this study. In practice, the distinction between governance and government and the resultant mechanisms directed at local sustainable development do not seem to be clear. Hence, lack of understanding of the meaning of sustainability and governance for local development is still lacking. Recommendations on the serious consequences of financial fraud and corruption on economic growth, capital formation, poverty and inequality to foster and address sustainable development are also provided in this study. , Thesis (PhD) -- Faculty of Management and Commerce, 2010
- Full Text:
- Date Issued: 2010-12
- Authors: Okubena, Olumuyiwa Olamilekan
- Date: 2010-12
- Subjects: Sustainable development -- South Africa , Fraud -- South Africa -- Eastern Cape , Municipal services -- South Africa -- Eastern Cape
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/25569 , vital:64335
- Description: This thesis explored the pernicious effects of financial fraud and corruption and the importance of the rule of law, transparency and accountability of public sector. These critical conditions serve as the foundation for the effective and efficient governance and the economic growth of a nation, especially through utilizing the opportunities provided by globalization through increased investment and trade. The thesis looks at the importance of upholding the rule of law and fostering transparency and accountability in the public sector in combating financial fraud and corruption, particularly as components of effective national strategies. The rule of law, transparency and accountability in the public sector serve not only as means to counter financial fraud and corruption but also as fundamental conditions of effective governance. It was discovered that financial fraud and corruption is a complex phenomenon, present in all countries. Its causes are engendered by conditions of underdevelopment. Hence, its effects hinder and impede the development process itself. It was also confirmed that financial fraud and corruption are co-determined by many other factors, including cultural and moral values. The motivation to remain honest may be weakened by low public official’s salaries, promotion of personnel unconnected to performance, dysfunctional government budgets, loss of organizational purpose, bad example by chief official’s and political leaders, or long established patron-client relationships, in which the sharing of bribes or the exchange of favors has become entrenched. Financial fraud and corruption can be highly concentrated at the top of a political system and associated with political power, or broadly based at lower levels in the system, associated with administrative processes and discretionary powers. Hence, bribes can be blatant or subtle and take many different forms, including cash payments, job offers, scholarships, foreign trips or political and other favors. Furthermore, the development of sustainable local authorities however is an ambitious issue that requires local authorities to focus on the improvement of the quality of life of present and future communities without depleting the natural resources at their disposal. For sustainable and equitable development, this study espouses on the far-reaching implications for local authorities through multiple regression analysis due to various economic, social and institutional challenges that have to be taken into consideration when a process to promote sustainable development is considered. To comprehensively actualize the implications of financial fraud and corruption on the sustainable development of local authorities, a multistage cluster sampling, a form of probability sampling technique was adopted. Semantically, to identify the research paradigms suitable for this study, a hybrid approach to research design was used (quantitative and qualitative). This however enables the impact of financial fraud and corruption on the sustainable development of selected local authorities in South Africa to be ascertained. Moreover, the study explores the circumstances and implications surrounding financial fraud and corruption in the local authorities in South-Africa. Financial fraud and corruption tends to emerge when an organization or a public official has monopoly power over a good or service that generates rent, has the discretionary power to decide who will receive it, and is not accountable. Financial fraud and corruption’s roots are grounded in a country’s social and cultural history, political and economic development, bureaucratic traditions and policies. This study also identifies that, direct and indirect factors promote financial fraud and corruption. Direct factors include regulations and authorizations, taxation, spending decisions, provision of goods and services at below market prices, and financing political parties. On the other hand, quality of bureaucracy, level of public sector wages, penalty systems, institutional controls, and transparency of rules, laws, and processes are the indirect factors that promote financial fraud and corruption. Financial fraud and corruption is a symptom of deep institutional weaknesses that leads to inefficient economic, social, and political outcomes. It reduces economic growth, retards long-term foreign and domestic investments, enhances inflation, depreciates national currency, reduces expenditures for education and health, increases military expenditures, misallocates talent to rent-seeking activities, pushes firms underground, distorts markets and the allocation of resources, increases income inequality and poverty, reduces tax revenue, increases child and infant mortality rates, distorts the fundamental role of the government (on enforcement of contracts and protection of property. Nonetheless, this study concludes that financial fraud and corruption impedes economic efficiency which could slow or shrink economic growth. This will adversely affect all income classes, especially the most vulnerable, the poor. The effect of financial fraud and corruption through investment expenditure on health and education critical to sustainable development was noted in this study. In practice, the distinction between governance and government and the resultant mechanisms directed at local sustainable development do not seem to be clear. Hence, lack of understanding of the meaning of sustainability and governance for local development is still lacking. Recommendations on the serious consequences of financial fraud and corruption on economic growth, capital formation, poverty and inequality to foster and address sustainable development are also provided in this study. , Thesis (PhD) -- Faculty of Management and Commerce, 2010
- Full Text:
- Date Issued: 2010-12
International legal protection of women's reproductive rights: a comparative analysis of abortion laws and policies in four jurisdictions-Nigeria, Ghana, South Africa and U.S.A.
- Authors: Abiodun, Adeleke Funminiyi
- Date: 2010-10
- Subjects: Abortion -- Law and legislation , Reproductive right
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/25839 , vital:64491
- Description: The subject matter of abortion law is extremely broad and multi-disciplinary. While naturally having its basis in criminal and constitutional law of individual states, the global development of abortion discourse has been influenced by the need to protect the reproductive rights of women as a sub-set of international human rights laws; thereby advocating not only the decriminalisation of abortion but also, that individual State should take affirmative actions in promoting abortion as a right for every woman. However, that induced abortion is a punishable criminal act or a “protectable” woman’s reproductive right remains controversial due to the plethora of perspectives, beliefs and reservations held by different groups of people which are multi-dimensional and contradictory. This thesis therefore attempts a comparative study of abortion laws and policies in four jurisdictions: Nigeria and Ghana, operating criminalised abortion laws, South Africa and United States which operate liberalised/permissive abortion laws and policies. The study basically examines the legal status and reproductive rights of women to legal and safe abortion within the existing legal framework of national laws of the four selected jurisdictions vis-à-vis the legal protection offered by various international instruments on human rights. While we show that strict and restrictive abortion laws, and also, failure of States to create conditions for safe abortion constitute infractions of the reproductive rights of women, we submit further that over-liberalisation of abortion laws and policies could also amount to infringement of the basic rights of other people, thus there is need to ensure a legal and acceptable balance. The study finally acknowledges the role of international human rights laws in the protection of women’s right to legal and safe abortion but asserts that there can be no universally acceptable morality to which the whole world could subsume in term of women’s right to abortion due to the interplay of socio-cultural, religious, and moral affiliations of the people in different communities. , Thesis (LLD) -- Faculty of Law, 2010
- Full Text:
- Date Issued: 2010-10
- Authors: Abiodun, Adeleke Funminiyi
- Date: 2010-10
- Subjects: Abortion -- Law and legislation , Reproductive right
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/25839 , vital:64491
- Description: The subject matter of abortion law is extremely broad and multi-disciplinary. While naturally having its basis in criminal and constitutional law of individual states, the global development of abortion discourse has been influenced by the need to protect the reproductive rights of women as a sub-set of international human rights laws; thereby advocating not only the decriminalisation of abortion but also, that individual State should take affirmative actions in promoting abortion as a right for every woman. However, that induced abortion is a punishable criminal act or a “protectable” woman’s reproductive right remains controversial due to the plethora of perspectives, beliefs and reservations held by different groups of people which are multi-dimensional and contradictory. This thesis therefore attempts a comparative study of abortion laws and policies in four jurisdictions: Nigeria and Ghana, operating criminalised abortion laws, South Africa and United States which operate liberalised/permissive abortion laws and policies. The study basically examines the legal status and reproductive rights of women to legal and safe abortion within the existing legal framework of national laws of the four selected jurisdictions vis-à-vis the legal protection offered by various international instruments on human rights. While we show that strict and restrictive abortion laws, and also, failure of States to create conditions for safe abortion constitute infractions of the reproductive rights of women, we submit further that over-liberalisation of abortion laws and policies could also amount to infringement of the basic rights of other people, thus there is need to ensure a legal and acceptable balance. The study finally acknowledges the role of international human rights laws in the protection of women’s right to legal and safe abortion but asserts that there can be no universally acceptable morality to which the whole world could subsume in term of women’s right to abortion due to the interplay of socio-cultural, religious, and moral affiliations of the people in different communities. , Thesis (LLD) -- Faculty of Law, 2010
- Full Text:
- Date Issued: 2010-10