The trophic and spatial ecology of juvenile porcupine rays Urogymnus asperrimus at the remote St. Joseph Atoll
- Authors: Elston, Chantel
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/965 , vital:20007
- Description: Little information exists for the widely occurring but rare porcupine ray Urogymnus asperrimus. This is a concern given that it is a vulnerable species and likely plays an important ecological role in tropical atoll ecosystems. The aims of this thesis were to investigate the trophic and spatial ecology of juvenile porcupine rays within the St. Joseph Atoll, which is hypothesized to be functioning as a nursery for this species. Specific objectives were to determine i) the dietary composition and resource selectivity displayed by juvenile porcupine rays, ii) residency to the atoll, space use, and seasonality in movements, and iii) whether environmental factors affect short-term movements. Gastric lavage was used to collect stomach contents from 55 juveniles and sediment samples were collected. Thirteen juveniles were implanted with acoustic transmitters and monitored for a year by an array of 88 acoustic receivers situated in and around the St. Joseph Atoll. Porcupine rays appeared to be generalist and opportunistic feeders, foraging predominantly on annelids with the highest environmental availability. Polychaetes of the family Capitellidae were the most important prey item (Index of Importance = 35%). Rays only fed on deep infaunal prey, likely because of their foraging behaviour, suggesting they may influence this community. There was a size-related shift in the crustacean families consumed. The tagged rays displayed high residency to the atoll (mean residency index of 64%) and restricted movements, with small core use and activity space areas (mean of 0.5km² and 3km² respectively) and the majority of detections were recorded within 1km of their tagging locations. The rays favoured the sand ats where 88% of detections occurred. Transient use of the lagoon and fringe reef peaked in the north-west monsoon season, indicating a seasonal usage of these habitats. The effects of temperature and water depth on movements were manifested as diel and tidal cyclical patterns in presence. Evidence illustrates that the St. Joseph Atoll constitutes an important nursery for this species, which has been declared a Marine Protected Area. A major determinant behind the dependence of this nursery habitat is related to predator avoidance. Thermoregulatory behaviours were identified, suggesting that this species is vulnerable to climate change.
- Full Text:
- Date Issued: 2016
- Authors: Elston, Chantel
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/965 , vital:20007
- Description: Little information exists for the widely occurring but rare porcupine ray Urogymnus asperrimus. This is a concern given that it is a vulnerable species and likely plays an important ecological role in tropical atoll ecosystems. The aims of this thesis were to investigate the trophic and spatial ecology of juvenile porcupine rays within the St. Joseph Atoll, which is hypothesized to be functioning as a nursery for this species. Specific objectives were to determine i) the dietary composition and resource selectivity displayed by juvenile porcupine rays, ii) residency to the atoll, space use, and seasonality in movements, and iii) whether environmental factors affect short-term movements. Gastric lavage was used to collect stomach contents from 55 juveniles and sediment samples were collected. Thirteen juveniles were implanted with acoustic transmitters and monitored for a year by an array of 88 acoustic receivers situated in and around the St. Joseph Atoll. Porcupine rays appeared to be generalist and opportunistic feeders, foraging predominantly on annelids with the highest environmental availability. Polychaetes of the family Capitellidae were the most important prey item (Index of Importance = 35%). Rays only fed on deep infaunal prey, likely because of their foraging behaviour, suggesting they may influence this community. There was a size-related shift in the crustacean families consumed. The tagged rays displayed high residency to the atoll (mean residency index of 64%) and restricted movements, with small core use and activity space areas (mean of 0.5km² and 3km² respectively) and the majority of detections were recorded within 1km of their tagging locations. The rays favoured the sand ats where 88% of detections occurred. Transient use of the lagoon and fringe reef peaked in the north-west monsoon season, indicating a seasonal usage of these habitats. The effects of temperature and water depth on movements were manifested as diel and tidal cyclical patterns in presence. Evidence illustrates that the St. Joseph Atoll constitutes an important nursery for this species, which has been declared a Marine Protected Area. A major determinant behind the dependence of this nursery habitat is related to predator avoidance. Thermoregulatory behaviours were identified, suggesting that this species is vulnerable to climate change.
- Full Text:
- Date Issued: 2016
The use of treated brewery effluent as a water and nutrient source in crop irrigation
- Authors: Taylor, Richard Peter
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5390 , http://hdl.handle.net/10962/d1021265
- Description: Brewery effluent (BE) needs to be treated before it can be released into the environment, reused or used in down-stream activities. Current technologies used to address this concern at the experimental wastewater treatment plant at Ibahyi Brewery (SAB Ltd) include anaerobic digestion (AD), primary facultative ponds (PFP), high rate algal ponds (HRAP) and constructed wetlands (CW). The aim of this work was to determine if BE treated in these systems might be suitable for crop irrigation. A test crop, cabbage (Brassica oleracea cv. Star 3301), grew best on post-AD and post-PFP BE compared to those irrigated with post-HRAP or post-CW effluent. However, the yield was 13% lower than cabbage plants irrigated with a commercial nutrient solution and fresh water. The relatively high conductivity (3019.05 ± 48.72 μs/cm2) of BE may be the main factor reducing the cabbage yields. Post-HRAP and post-CW BE were the least suitable for irrigated crop production due to the higher conductivity and lower nutrient content of these treated effluents. After three months, soils irrigated with post-AD and post-PFP BE had a significantly higher sodium content and sodium adsorption ratio (3919 ± 94.77 mg/kg & 8.18 ± 0.17) than soil irrigated with a commercial nutrient solution (920.58 ± 27.46 mg/kg & 2.20 ± 0.05; p<0.05). However, this was not accompanied by a deterioration in the soil’s hydro-physical properties, nor a change in the metabolic community structure of the soil (p>0.05). After prolonged irrigation with treated BE, sodium is likely to build up in the soil and this can be expected to be accompanied by a deterioration in the soil physical structure. However, crops species such as millet (Echinochloa esculenta), lucerne (Medicago sativa) and saltbush (Atriplex nummularia) reduced the build-up of sodium in the soil. The results suggest that sodium was mainly removed from the soil through plant-assisted leaching. Of the crops grown, lucerne showed the most promise because it improved the soil physical properties, is able to grow well in alkaline environments, is a popular fodder crop and can be harvested multiple times from a single stand. Brewery effluent is more suitable for soil production systems than hydroponic production systems because the soil was able to act as a buffer against the high pH of post-AD BE, whereas in a hydroponics systems the high pH reduced the availability of key minerals to plants. In conclusion brewery effluent contains sufficient plants nutrients to support the growth of cabbages, saltbush, lucerne and millet. However the sodium content of BE is a concern as it accumulates in the soil, and in the long-term it may lead to soil degradation. It is suggested that the brewery change the pH neutralising treatment of BE from sodium hydroxide to potassium hydroxide, or dolomitic lime (calcium and magnesium carbonate) because this would reduce the introduction of sodium into the system, and would increase the suitability of BE for crop production, given potassium and calcium are plant nutrients. The benefits of developing this nutrient and water resource could contribute to cost-reductions at the brewery, more efficient water, nutrient and energy management, create job opportunities with the potential of improving food security in the local community.
- Full Text:
- Date Issued: 2016
- Authors: Taylor, Richard Peter
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5390 , http://hdl.handle.net/10962/d1021265
- Description: Brewery effluent (BE) needs to be treated before it can be released into the environment, reused or used in down-stream activities. Current technologies used to address this concern at the experimental wastewater treatment plant at Ibahyi Brewery (SAB Ltd) include anaerobic digestion (AD), primary facultative ponds (PFP), high rate algal ponds (HRAP) and constructed wetlands (CW). The aim of this work was to determine if BE treated in these systems might be suitable for crop irrigation. A test crop, cabbage (Brassica oleracea cv. Star 3301), grew best on post-AD and post-PFP BE compared to those irrigated with post-HRAP or post-CW effluent. However, the yield was 13% lower than cabbage plants irrigated with a commercial nutrient solution and fresh water. The relatively high conductivity (3019.05 ± 48.72 μs/cm2) of BE may be the main factor reducing the cabbage yields. Post-HRAP and post-CW BE were the least suitable for irrigated crop production due to the higher conductivity and lower nutrient content of these treated effluents. After three months, soils irrigated with post-AD and post-PFP BE had a significantly higher sodium content and sodium adsorption ratio (3919 ± 94.77 mg/kg & 8.18 ± 0.17) than soil irrigated with a commercial nutrient solution (920.58 ± 27.46 mg/kg & 2.20 ± 0.05; p<0.05). However, this was not accompanied by a deterioration in the soil’s hydro-physical properties, nor a change in the metabolic community structure of the soil (p>0.05). After prolonged irrigation with treated BE, sodium is likely to build up in the soil and this can be expected to be accompanied by a deterioration in the soil physical structure. However, crops species such as millet (Echinochloa esculenta), lucerne (Medicago sativa) and saltbush (Atriplex nummularia) reduced the build-up of sodium in the soil. The results suggest that sodium was mainly removed from the soil through plant-assisted leaching. Of the crops grown, lucerne showed the most promise because it improved the soil physical properties, is able to grow well in alkaline environments, is a popular fodder crop and can be harvested multiple times from a single stand. Brewery effluent is more suitable for soil production systems than hydroponic production systems because the soil was able to act as a buffer against the high pH of post-AD BE, whereas in a hydroponics systems the high pH reduced the availability of key minerals to plants. In conclusion brewery effluent contains sufficient plants nutrients to support the growth of cabbages, saltbush, lucerne and millet. However the sodium content of BE is a concern as it accumulates in the soil, and in the long-term it may lead to soil degradation. It is suggested that the brewery change the pH neutralising treatment of BE from sodium hydroxide to potassium hydroxide, or dolomitic lime (calcium and magnesium carbonate) because this would reduce the introduction of sodium into the system, and would increase the suitability of BE for crop production, given potassium and calcium are plant nutrients. The benefits of developing this nutrient and water resource could contribute to cost-reductions at the brewery, more efficient water, nutrient and energy management, create job opportunities with the potential of improving food security in the local community.
- Full Text:
- Date Issued: 2016
Thermoluminescence of annealed synthetic quartz
- Atang, Elizabeth Fende Midiki
- Authors: Atang, Elizabeth Fende Midiki
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/420 , vital:19957
- Description: The kinetic and dosimetric features of the main thermoluminescent peak of synthetic quartz have been investigated in quartz ordinarily annealed at 500_C as well as quartz annealed at 500_C for 10 minutes. The main peak is found at 78 _C for the samples annealed at 500_C for 10 minutes irradiated to 10 Gy and heated at 1.0 _C/s. For the samples ordinarily annealed at 500_C the main peak is found at 106 _C after the sample has been irradiated to 30 Gy and heated at 5.0 _C/s. In these samples, the intensity of the main peak is enhanced with repetitive measurement whereas its maximum temperature is unaffected. The peak position of the main peak in the sample is independent of the irradiation dose and this, together with its fading characteristics, are consistent with first-order kinetics. For doses between 5 and 25 Gy, the dose response of the main peak of the annealed sample is superlinear. The half-life of the main TL peak of the annealed sample is about 1 h. The activation energy E of the main peak is around 0.90 eV. For a heating rate of 0.4 _C/s, its order of kinetics b derived from the whole curve method of analysis is 1.0. Following irradiation, preheating and illumination with 470 nm blue light, the main peak in the annealed sample is regenerated during heating. The resulting phototransferred peak occurs at the same temperature as the original peak and has similar kinetic and dosimetric features, with a half-life of about 1 h. For a preheat temperature of 200 _C, the intensity of the phototransferred peak in the sample increases with illumination time up to a maximum and decreases thereafter. At longer illumination times, no further decrease in the intensity of the phototransferred peak is observed. The traps associated with the 325 _C peak are the main source of the electrons responsible for the regenerated peak.
- Full Text:
- Date Issued: 2016
- Authors: Atang, Elizabeth Fende Midiki
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/420 , vital:19957
- Description: The kinetic and dosimetric features of the main thermoluminescent peak of synthetic quartz have been investigated in quartz ordinarily annealed at 500_C as well as quartz annealed at 500_C for 10 minutes. The main peak is found at 78 _C for the samples annealed at 500_C for 10 minutes irradiated to 10 Gy and heated at 1.0 _C/s. For the samples ordinarily annealed at 500_C the main peak is found at 106 _C after the sample has been irradiated to 30 Gy and heated at 5.0 _C/s. In these samples, the intensity of the main peak is enhanced with repetitive measurement whereas its maximum temperature is unaffected. The peak position of the main peak in the sample is independent of the irradiation dose and this, together with its fading characteristics, are consistent with first-order kinetics. For doses between 5 and 25 Gy, the dose response of the main peak of the annealed sample is superlinear. The half-life of the main TL peak of the annealed sample is about 1 h. The activation energy E of the main peak is around 0.90 eV. For a heating rate of 0.4 _C/s, its order of kinetics b derived from the whole curve method of analysis is 1.0. Following irradiation, preheating and illumination with 470 nm blue light, the main peak in the annealed sample is regenerated during heating. The resulting phototransferred peak occurs at the same temperature as the original peak and has similar kinetic and dosimetric features, with a half-life of about 1 h. For a preheat temperature of 200 _C, the intensity of the phototransferred peak in the sample increases with illumination time up to a maximum and decreases thereafter. At longer illumination times, no further decrease in the intensity of the phototransferred peak is observed. The traps associated with the 325 _C peak are the main source of the electrons responsible for the regenerated peak.
- Full Text:
- Date Issued: 2016
Toward an automated botnet analysis framework: a darkcomet case-study
- Authors: du Bruyn, Jeremy Cecil
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/2937 , vital:20344
- Full Text:
- Date Issued: 2016
- Authors: du Bruyn, Jeremy Cecil
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/2937 , vital:20344
- Full Text:
- Date Issued: 2016
Towards an alternative spatial-based management approach for estuarine fisheries in South Africa, with a case study from the Sundays Estuary
- Authors: Kramer, Rachel
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/1007 , vital:20012
- Description: Estuaries are productive habitats and biologically important ecosystems which serve as juvenile nursery areas and feeding grounds for adults from a host of fish species. They are, however, threatened habitats, increasingly exposed to human disturbance and exploitation. The stocks of several South African estuary-dependent linefish species are now considered as either overexploited or collapsed. It is clear that their dependence on estuaries would warrant the inclusion of these ecosystems into marine reserve planning exercises. Since traditional management strategies (e.g. bag and size limit restrictions) have proven ineffective for estuarine fisheries, there is a need for alternative management measures, such as spatial and temporal restrictions, to ensure increased survival of juveniles and recovery of adult breeding populations. This thesis explored the potential for an ecosystem-based approach through the application of a rapid sustainability assessment technique, and a spatial-based management approach for an important fishery species, using conservation planning software. The Sundays Estuary, Eastern Cape, South Africa falls within the footprint of the Addo Elephant National Park, with a proposed expansion to include a marine protected area (MPA). However the estuaries resources were not considered during the planning of the proposed MPA. This study conducted an indicator-based sustainability assessment based on the principles of sustainable development. The results showed that present levels of exploitation, due to non-compliance and a lack of law enforcement are unsustainable. The sustainability of the Sundays Estuary had a low overall sustainability score of only 23.8%. With limited enforcement of estuarine fisheries regulations in South Africa, alternative management measures such as spatial regulations may provide a viable option forward. The sustainability of fishery resources depends on the comprehensive understanding of the fishery resource. Acoustic telemetry is a technique that has been widely adopted to infer habitat and area use patterns of fish species. The second component of this study made use of high resolution telemetry data collected on juvenile dusky kob Argyrosomus japonicus movements within the Sundays Estuary to conduct a scenario-based approach using Marxan conservation planning software. The best solution given by Marxan, in the form of a protected area for the conservation of juvenile A. japonicus in the Sundays Estuary was identified in the middle (starting 7km from the mouth) to the upper reaches (approximately 16km from the mouth) of the estuary, ultimately providing protection to tagged individuals for 61% of their time in the estuary. Although Marxan presented a best solution, the Sundays Estuary’s small size and shape, and minimal features used, was too simplistic to be included into a Marxan analysis. However, new methods and tools to analyse and plan spatial-based management options at this scale are currently being developed. Using the Sundays Estuary as a case study, a decision tree was then developed as a protocol to assist management address the challenges of effective estuarine management depending on the unique biological and socio-economic characteristics of individual estuaries in South Africa.
- Full Text:
- Date Issued: 2016
- Authors: Kramer, Rachel
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/1007 , vital:20012
- Description: Estuaries are productive habitats and biologically important ecosystems which serve as juvenile nursery areas and feeding grounds for adults from a host of fish species. They are, however, threatened habitats, increasingly exposed to human disturbance and exploitation. The stocks of several South African estuary-dependent linefish species are now considered as either overexploited or collapsed. It is clear that their dependence on estuaries would warrant the inclusion of these ecosystems into marine reserve planning exercises. Since traditional management strategies (e.g. bag and size limit restrictions) have proven ineffective for estuarine fisheries, there is a need for alternative management measures, such as spatial and temporal restrictions, to ensure increased survival of juveniles and recovery of adult breeding populations. This thesis explored the potential for an ecosystem-based approach through the application of a rapid sustainability assessment technique, and a spatial-based management approach for an important fishery species, using conservation planning software. The Sundays Estuary, Eastern Cape, South Africa falls within the footprint of the Addo Elephant National Park, with a proposed expansion to include a marine protected area (MPA). However the estuaries resources were not considered during the planning of the proposed MPA. This study conducted an indicator-based sustainability assessment based on the principles of sustainable development. The results showed that present levels of exploitation, due to non-compliance and a lack of law enforcement are unsustainable. The sustainability of the Sundays Estuary had a low overall sustainability score of only 23.8%. With limited enforcement of estuarine fisheries regulations in South Africa, alternative management measures such as spatial regulations may provide a viable option forward. The sustainability of fishery resources depends on the comprehensive understanding of the fishery resource. Acoustic telemetry is a technique that has been widely adopted to infer habitat and area use patterns of fish species. The second component of this study made use of high resolution telemetry data collected on juvenile dusky kob Argyrosomus japonicus movements within the Sundays Estuary to conduct a scenario-based approach using Marxan conservation planning software. The best solution given by Marxan, in the form of a protected area for the conservation of juvenile A. japonicus in the Sundays Estuary was identified in the middle (starting 7km from the mouth) to the upper reaches (approximately 16km from the mouth) of the estuary, ultimately providing protection to tagged individuals for 61% of their time in the estuary. Although Marxan presented a best solution, the Sundays Estuary’s small size and shape, and minimal features used, was too simplistic to be included into a Marxan analysis. However, new methods and tools to analyse and plan spatial-based management options at this scale are currently being developed. Using the Sundays Estuary as a case study, a decision tree was then developed as a protocol to assist management address the challenges of effective estuarine management depending on the unique biological and socio-economic characteristics of individual estuaries in South Africa.
- Full Text:
- Date Issued: 2016
Towards an industrial ecology for the Nelson Mandela Bay: Metropolitan area
- Authors: Dalindyebo, Litha
- Date: 2016
- Subjects: Industrial ecology -- South Africa -- Port Elizabeth
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/9263 , vital:26556
- Description: The aim of this study is to formulate a model of industrial ecology for wider application in the Nelson Mandel Bay (NMB) Metropole. To achieve this aim, the following objectives will be pursued: • A theoretical investigation of the concept of industrial ecology – in an attempt to establish its meaning, as well as the implications thereof. • A theoretical investigation of the operational implications of industrial ecology, including existing methodologies, such as Material Flow Analysis (MFA) and Life Cycle Assessment (LCA) that can be applied, in order to develop a system of industrial ecology between different companies. • The formulation of a methodology for application to the case study. • Presenting and discussing the research results produced by the application of the industrial ecology related methodology to the case study. • To present a synthesis of the research results of this study. This objective includes a critical evaluation of the research methodology and results, as well as some recommendations for the facilitation of industrial ecology. The methodology of the research involved conducting semi structured interviews, conducting a Material Flow Analysis and Life Cycle Analysis using SIMAPRO software. There interview with Goodyear management took place (see Appendix A), while the management at Sovereign Foods agreed to an interview however they didn’t honour the agreement. During the interview at Goodyear understanding of the operational process was achieved by conducting the interviews. The three areas that were discussed during the interview process were: 1. How the boiler works; 2. Current Air-Emission results; and 3. The process of steam generation. An MFA and an LCA on the production process of comparing the boiler functionality was conducted, so that there is an adequate understanding of the environmental performance of the two different boilers. The results of the MFA are presented as follows, namely: the goal and scope definition and the inventory results. Coal boiler versus fluidised boiler data where modelled. The modelling is done on comparing the flow of chemicals during steam production process, and which chemicals have a significant environmental impact. The LCA results looked at the basis of the symbiotic approach by identifying sustainable choices of design, production and consumption. The findings of this research have been obtained from the investigation of industrial ecology framework planning at Goodyear SA and Sovereign Foods. The findings have revealed that there is a synergy that exists between the two case-study areas. However, this is based on Goodyear changing the technology of the boiler they use (a boiler creates steam for the tyre-building process). The company will be required to use a fluidised boiler, instead of the current coal boiler. The use of the fluidised boiler will ensure that all waste streams at Goodyear will be reused and recycled, thereby creating the framework for industrial ecology. The results that are firstly drawn out of SIMAPRO is the Life Cycle Inventory. In this research, there is a flow of 1437 chemical materials and substances in the production of steam using both coal boiler and fluidized boiler. Due to the number of substance flow elements, the research has presented only the significant substances that influence the environmental performance of steam production using the two different feeder materials, which are coal and chicken matter (see Figure 4.4). In the coal boiler process, sulfur comprises the largest amount of chemical substance. The other top five chemical components that contribute to the steam production process are: nickel, chromium, arsenic and iodosulfuron-methyl-sodium. The scale of figure 4.4 is reduced to show the various number of chemical flows found in the steam production process through SIMAPRO software. The Life Cycle Assessment (LCA) results were presented looking at namely the following characterization, normalization, weighting, single score and damage assessment (see Figure 4.7 – 4.10 p87 – p90). The figures are presented as taken directly from the reports drawn from the SIMAPRO software. Figure 4.7 gives the characterisation results up to 100%, where 0% has a minimal environmental effect; whereas 100% has the most significant environmental effect. Oxidation of coal is compared versus the oxidation of chicken matter, the coal boiler process has higher environmental impacts. Figure 4.8 shows the normalisation results of the coal boiler versus the fluidised boiler for the functional unit steam production. The environmental degradation under normalisation between the two boilers are measured, based on three parameters, namely: human health, ecosystems and resources. In all three parameters that are measured under normalisation, the production of steam using the coal boiler has the highest impacts. The weighting results in Figure 4.9 show a mirror image of the normalisation results. Finally, a gap analysis of the theoretical requirements for industrial ecology is displayed versus what currently exists in the case study area. The gap analysis will assist in the development of recommendations. These will be presented in the next chapter. A gap analysis of findings is discussed leading into the synthesis. The value of this research is that the baseline data of planning for an industrial ecology create a platform that can be used for implementing an industrial ecology between Goodyear SA and Sovereign Foods. This will, in time, have wider applications for the entire NMB metropole.
- Full Text:
- Date Issued: 2016
- Authors: Dalindyebo, Litha
- Date: 2016
- Subjects: Industrial ecology -- South Africa -- Port Elizabeth
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/9263 , vital:26556
- Description: The aim of this study is to formulate a model of industrial ecology for wider application in the Nelson Mandel Bay (NMB) Metropole. To achieve this aim, the following objectives will be pursued: • A theoretical investigation of the concept of industrial ecology – in an attempt to establish its meaning, as well as the implications thereof. • A theoretical investigation of the operational implications of industrial ecology, including existing methodologies, such as Material Flow Analysis (MFA) and Life Cycle Assessment (LCA) that can be applied, in order to develop a system of industrial ecology between different companies. • The formulation of a methodology for application to the case study. • Presenting and discussing the research results produced by the application of the industrial ecology related methodology to the case study. • To present a synthesis of the research results of this study. This objective includes a critical evaluation of the research methodology and results, as well as some recommendations for the facilitation of industrial ecology. The methodology of the research involved conducting semi structured interviews, conducting a Material Flow Analysis and Life Cycle Analysis using SIMAPRO software. There interview with Goodyear management took place (see Appendix A), while the management at Sovereign Foods agreed to an interview however they didn’t honour the agreement. During the interview at Goodyear understanding of the operational process was achieved by conducting the interviews. The three areas that were discussed during the interview process were: 1. How the boiler works; 2. Current Air-Emission results; and 3. The process of steam generation. An MFA and an LCA on the production process of comparing the boiler functionality was conducted, so that there is an adequate understanding of the environmental performance of the two different boilers. The results of the MFA are presented as follows, namely: the goal and scope definition and the inventory results. Coal boiler versus fluidised boiler data where modelled. The modelling is done on comparing the flow of chemicals during steam production process, and which chemicals have a significant environmental impact. The LCA results looked at the basis of the symbiotic approach by identifying sustainable choices of design, production and consumption. The findings of this research have been obtained from the investigation of industrial ecology framework planning at Goodyear SA and Sovereign Foods. The findings have revealed that there is a synergy that exists between the two case-study areas. However, this is based on Goodyear changing the technology of the boiler they use (a boiler creates steam for the tyre-building process). The company will be required to use a fluidised boiler, instead of the current coal boiler. The use of the fluidised boiler will ensure that all waste streams at Goodyear will be reused and recycled, thereby creating the framework for industrial ecology. The results that are firstly drawn out of SIMAPRO is the Life Cycle Inventory. In this research, there is a flow of 1437 chemical materials and substances in the production of steam using both coal boiler and fluidized boiler. Due to the number of substance flow elements, the research has presented only the significant substances that influence the environmental performance of steam production using the two different feeder materials, which are coal and chicken matter (see Figure 4.4). In the coal boiler process, sulfur comprises the largest amount of chemical substance. The other top five chemical components that contribute to the steam production process are: nickel, chromium, arsenic and iodosulfuron-methyl-sodium. The scale of figure 4.4 is reduced to show the various number of chemical flows found in the steam production process through SIMAPRO software. The Life Cycle Assessment (LCA) results were presented looking at namely the following characterization, normalization, weighting, single score and damage assessment (see Figure 4.7 – 4.10 p87 – p90). The figures are presented as taken directly from the reports drawn from the SIMAPRO software. Figure 4.7 gives the characterisation results up to 100%, where 0% has a minimal environmental effect; whereas 100% has the most significant environmental effect. Oxidation of coal is compared versus the oxidation of chicken matter, the coal boiler process has higher environmental impacts. Figure 4.8 shows the normalisation results of the coal boiler versus the fluidised boiler for the functional unit steam production. The environmental degradation under normalisation between the two boilers are measured, based on three parameters, namely: human health, ecosystems and resources. In all three parameters that are measured under normalisation, the production of steam using the coal boiler has the highest impacts. The weighting results in Figure 4.9 show a mirror image of the normalisation results. Finally, a gap analysis of the theoretical requirements for industrial ecology is displayed versus what currently exists in the case study area. The gap analysis will assist in the development of recommendations. These will be presented in the next chapter. A gap analysis of findings is discussed leading into the synthesis. The value of this research is that the baseline data of planning for an industrial ecology create a platform that can be used for implementing an industrial ecology between Goodyear SA and Sovereign Foods. This will, in time, have wider applications for the entire NMB metropole.
- Full Text:
- Date Issued: 2016
Towards determining the dietary lysine requirement in the South African abalone, Haliotis midae
- Authors: Lloyd, Kyle Everett
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/1024 , vital:20014
- Description: Animals generally do not have a requirement for protein, but instead have a requirement for specific essential amino acids (EAAs) and non-essential amino acids (NEAAs). The NEAAs are those that can be synthesised by the animal, however, EAAs cannot be synthesised and must therefore be supplied as part of the diet. When these amino acids (AAs) are supplied in the correct ratios and with the correct level of digestible energy, nutritionists can maximise somatic growth from proteins. This has resulted in increased research into the use of crystalline AAs as a tool in feed formulation research in order to quantify the AA requirements in aquaculture species, and allow for alternative protein sources (other than fishmeal) to be utilised. In common with other water soluble nutrients, leaching of crystalline AAs from diets prior to ingestion is of concern in an aquatic environment. Microencapsulation techniques have been successfully employed to restrict micronutrient leaching, and improve ingestion rates. In this research, LysiPEARL™ (Kemin®) was used as a means to determine the lysine requirement in Haliotis. midae. This encapsulated lysine product is used in the dairy cattle industry as an effective source of rumen bypass for intestinal release of lysine. It has previously been proposed that crystalline AAs are not suitable for AA studies in H. midae due to the slow feeding rates of the species as well as the solubility of these AAs. However, 90.00 % of supplemented lysine was maintained in this study after a six hour period of leaching, showing that if effective microencapsulation techniques are used, it is possible to use crystalline amino acids to supplement protein bound lysine in abalone feeds. Six isoenergetic (15.90 MJ/kg), isolipidic (6.00 %) and isonitrogenous (29.00 %) diets enriched with 5.52, 6.40, 7.28, 8.14, 9.00 and 9.86 % lysine (as a % of protein) were fed to triplicate groups of 20 H. midae (20.41 ± 1.95 mm SL 1.51 ± 0.44 g w.wt) for 90 days. Wet weight and shell length measurements were taken every 30 days and specific growth rate (SGR) (% body weight.day-1), feed conversion ratio (FCR), protein efficiency ratio (PER), feed consumption (% body weight.day-1) and condition factor were calculated for each dietary treatment. Linear regression showed that FCR increased as dietary lysine increased (Regression analysis, p=0.031), and that PER reduced as dietary lysine increased (Regression analysis, p=0.026). Feed consumption also increased as dietary lysine increased (Regression analysis, p<0.001). The inclusion of lysine at 7.28 % of the total protein in the diet resulted in significantly superior SGR (0.57±0.01 % body weight.day-1) to that of 5.52 % (0.42±0.05 % body weight.day-1), FCR (1.51±0.05) to that of 8.14 % (1.99±0.21) and PER (2.45±0.07) to that of 8.14 % (1.99±0.18; ANOVA, p<0.05). There was a significant difference found in feed consumption (% body wt.d-1), with consumption increasing significantly between the first three dietary treatments and the last three dietary treatments (ANOVA, p<0.001). There was no significant improvement in SGR when dietary lysine increased above 7.28 % of the dietary protein in the diet, indicating that dietary lysine requirement was being met at 7.28 %, after which excess lysine promoted no growth response. The diet producing the best SGR, PER and FCR in this study was diet 3 which had a measured lysine content of 6.90 %. The results of the present study suggest that the lysine requirement in H. midae is in the range of 6.00 - 7.00 % of dietary protein. From these data amino acid ratios were used to estimate optimum inclusion levels of other essential amino acids. However, lysine availability in LysiPEARL™ may have resulted in over estimations due to the lipid encapsulation technique used, and haliotids limited ability to efficiently digest lipids. For this reason EAA requirements were suggested based on three different hypothetical scenarios of lysine availability from LysiPEARL™.
- Full Text:
- Date Issued: 2016
- Authors: Lloyd, Kyle Everett
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/1024 , vital:20014
- Description: Animals generally do not have a requirement for protein, but instead have a requirement for specific essential amino acids (EAAs) and non-essential amino acids (NEAAs). The NEAAs are those that can be synthesised by the animal, however, EAAs cannot be synthesised and must therefore be supplied as part of the diet. When these amino acids (AAs) are supplied in the correct ratios and with the correct level of digestible energy, nutritionists can maximise somatic growth from proteins. This has resulted in increased research into the use of crystalline AAs as a tool in feed formulation research in order to quantify the AA requirements in aquaculture species, and allow for alternative protein sources (other than fishmeal) to be utilised. In common with other water soluble nutrients, leaching of crystalline AAs from diets prior to ingestion is of concern in an aquatic environment. Microencapsulation techniques have been successfully employed to restrict micronutrient leaching, and improve ingestion rates. In this research, LysiPEARL™ (Kemin®) was used as a means to determine the lysine requirement in Haliotis. midae. This encapsulated lysine product is used in the dairy cattle industry as an effective source of rumen bypass for intestinal release of lysine. It has previously been proposed that crystalline AAs are not suitable for AA studies in H. midae due to the slow feeding rates of the species as well as the solubility of these AAs. However, 90.00 % of supplemented lysine was maintained in this study after a six hour period of leaching, showing that if effective microencapsulation techniques are used, it is possible to use crystalline amino acids to supplement protein bound lysine in abalone feeds. Six isoenergetic (15.90 MJ/kg), isolipidic (6.00 %) and isonitrogenous (29.00 %) diets enriched with 5.52, 6.40, 7.28, 8.14, 9.00 and 9.86 % lysine (as a % of protein) were fed to triplicate groups of 20 H. midae (20.41 ± 1.95 mm SL 1.51 ± 0.44 g w.wt) for 90 days. Wet weight and shell length measurements were taken every 30 days and specific growth rate (SGR) (% body weight.day-1), feed conversion ratio (FCR), protein efficiency ratio (PER), feed consumption (% body weight.day-1) and condition factor were calculated for each dietary treatment. Linear regression showed that FCR increased as dietary lysine increased (Regression analysis, p=0.031), and that PER reduced as dietary lysine increased (Regression analysis, p=0.026). Feed consumption also increased as dietary lysine increased (Regression analysis, p<0.001). The inclusion of lysine at 7.28 % of the total protein in the diet resulted in significantly superior SGR (0.57±0.01 % body weight.day-1) to that of 5.52 % (0.42±0.05 % body weight.day-1), FCR (1.51±0.05) to that of 8.14 % (1.99±0.21) and PER (2.45±0.07) to that of 8.14 % (1.99±0.18; ANOVA, p<0.05). There was a significant difference found in feed consumption (% body wt.d-1), with consumption increasing significantly between the first three dietary treatments and the last three dietary treatments (ANOVA, p<0.001). There was no significant improvement in SGR when dietary lysine increased above 7.28 % of the dietary protein in the diet, indicating that dietary lysine requirement was being met at 7.28 %, after which excess lysine promoted no growth response. The diet producing the best SGR, PER and FCR in this study was diet 3 which had a measured lysine content of 6.90 %. The results of the present study suggest that the lysine requirement in H. midae is in the range of 6.00 - 7.00 % of dietary protein. From these data amino acid ratios were used to estimate optimum inclusion levels of other essential amino acids. However, lysine availability in LysiPEARL™ may have resulted in over estimations due to the lipid encapsulation technique used, and haliotids limited ability to efficiently digest lipids. For this reason EAA requirements were suggested based on three different hypothetical scenarios of lysine availability from LysiPEARL™.
- Full Text:
- Date Issued: 2016
Two uses of DNA sequence variation in tracing evolutionary processes in Old World primates (Primates: Catarrhini)
- Authors: Dosi, Banele
- Date: 2016
- Subjects: Primates -- Evolution Monkeys Cercopithecidae
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8022 , vital:31464
- Description: Primate evolution is particularly interesting to humans, because it includes our own history. Molecular genetics is by far the most dynamic field in contemporary biology, and offers a host of new techniques for investigating evolutionary processes and patterns. In the mid-twentieth century molecular genetics evolved from being a means of visualising hidden variation (e.g. allozymes) to tracing phylogenetic relationships between and among species (evolutionary histories of populations), and now has a wide variety of applications in medicine, species identification and relationships, and even wildlife forensics. For my Master’s project I investigated two applications of molecular genetic analysis to questions regarding the evolution of Old World monkeys (Catarrhini). First, I participated in a study designed to test the hypothesis that different primate social structures – particularly mating systems – may be reflected in the structure of a species genome. We investigated whether increased sperm production as a result of sexual selection increases the number of copy number variations (CNVs) that can be detected by comparing the male specific region Y (MSY) located on the Y chromosome in a sample of primate species. We did not find a clear differentiation between the primate species as hypothesised, which thus requires a more complex explanation, e.g. in terms of the type of environment rather than the mating system of the species, or possibly the active/inactive status of the genes. The second part of my study was phylogeographic in approach. I collaborated with researchers studying the distribution of Afromontane samango monkeys (Cercopithecus albogularis labiatus) in the Eastern Cape. I sequenced tissues from 5 samango monkey specimens found opportunistically in the Hogsback and coastal forests and analysed their genetic variation relative to the data published by Dalton et al. 2015. The Hogsback sample was not monophyletic relative to the sample from the coastal forests, indicating that, on the basis of this very small sample size, these populations have not been separated historically. In order to validate this conclusion, I will need to investigate a larger sample size. From this study I developed valuable skills in the areas of the laboratory techniques involved in molecular sequence analysis, and an appreciation for the importance of large sample sizes in deriving reliable results. I intend to continue in the future with a phylogeographic study of samango monkeys.
- Full Text:
- Date Issued: 2016
- Authors: Dosi, Banele
- Date: 2016
- Subjects: Primates -- Evolution Monkeys Cercopithecidae
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/8022 , vital:31464
- Description: Primate evolution is particularly interesting to humans, because it includes our own history. Molecular genetics is by far the most dynamic field in contemporary biology, and offers a host of new techniques for investigating evolutionary processes and patterns. In the mid-twentieth century molecular genetics evolved from being a means of visualising hidden variation (e.g. allozymes) to tracing phylogenetic relationships between and among species (evolutionary histories of populations), and now has a wide variety of applications in medicine, species identification and relationships, and even wildlife forensics. For my Master’s project I investigated two applications of molecular genetic analysis to questions regarding the evolution of Old World monkeys (Catarrhini). First, I participated in a study designed to test the hypothesis that different primate social structures – particularly mating systems – may be reflected in the structure of a species genome. We investigated whether increased sperm production as a result of sexual selection increases the number of copy number variations (CNVs) that can be detected by comparing the male specific region Y (MSY) located on the Y chromosome in a sample of primate species. We did not find a clear differentiation between the primate species as hypothesised, which thus requires a more complex explanation, e.g. in terms of the type of environment rather than the mating system of the species, or possibly the active/inactive status of the genes. The second part of my study was phylogeographic in approach. I collaborated with researchers studying the distribution of Afromontane samango monkeys (Cercopithecus albogularis labiatus) in the Eastern Cape. I sequenced tissues from 5 samango monkey specimens found opportunistically in the Hogsback and coastal forests and analysed their genetic variation relative to the data published by Dalton et al. 2015. The Hogsback sample was not monophyletic relative to the sample from the coastal forests, indicating that, on the basis of this very small sample size, these populations have not been separated historically. In order to validate this conclusion, I will need to investigate a larger sample size. From this study I developed valuable skills in the areas of the laboratory techniques involved in molecular sequence analysis, and an appreciation for the importance of large sample sizes in deriving reliable results. I intend to continue in the future with a phylogeographic study of samango monkeys.
- Full Text:
- Date Issued: 2016
Using bioinformatics tools to screen for trypanosomal cathepsin B cysteine protease inhibitors from the SANCDB as a novel therapeutic modality against Human African Trypanosomiasis (HAT)
- Authors: Mokhawa, Gaone
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/3304 , vital:20470
- Description: Human African Trypanosomiasis (HAT), also known as sleeping sickness, is a fatal chronic disease that is caused by flagellated protozoans, Trypanosoma brucei gambiense and Trypanosoma brucei rhodesiense. HAT is spread by a bite from an infected tsetse fly of the Glosina genus. Up to 60 million people in 36 countries in sub-Saharan Africa are at a risk of infection from HAT with up to 30 000 deaths reported every year. Current chemotherapy for HAT is insufficient since the available drugs exhibit unacceptable side effects (toxicity) and parasite resistance. Novel treatments and approaches for development of specific and more potent drugs for HAT are therefore required. One approach is to target vital proteins that are essential to the life cycle of the parasite. The main interest of this study is to explore Trypanosoma brucei cathepsin B-like protease (TbCatB) structural and functional properties with the primary goal of discovering non peptide small molecule inhibitors of TbCatB using bioinformatics approaches. TbCatB is a papain family C1 cysteine protease which belongs to clan CA group and it has emerged as a potential HAT drug target. Papain family cysteine proteases of Clan CA group of Trypanosoma brucei (rhodesain and TbCatB) have demonstrated potential as chemotherapeutic targets using synthetic protease inhibitors like Z-Phe-Ala-CHN2 to kill the parasite in vitro and in vivo. TbCatB has been identified as the essential cysteine protease of T. brucei since mRNA silencing of TbCatB killed the parasite and resulted in a cure in mice infected with T. brucei while mRNA silencing of rhodesain only extended mice life. TbCatB is therefore a promising drug target against HAT and the discovery and development of compounds that can selectively inhibit TbCatB without posing any danger to the human host represent a great therapeutic solution for treatment of HAT. To understand protein-inhibitor interactions, useful information can be obtained from high resolution protease-inhibitor crystal structure complexes. This study aims to use bioinformatics approaches to carry out comparative sequence, structural and functional analysis of TbCatB protease and its homologs from T. congolense, T, cruzi, T. vivax and H. sapien as well as to identify non-peptide small molecule inhibitors of TbCatB cysteine proteases from natural compounds of South African origin. Sequences of TbCatB (PDB ID: 3HHI) homologs were retrieved by a BLAST search. Human cathepsin B (PDB ID: 3CBJ) was selected from a list of templates for homology modelling found by HHpred. MODELLER version 9.10 program was used to generate a hundred models for T. congolense, T, cruzi and T. vivax cathepsin B like proteases using 3HHI and 3CBJ as templates. The best models were chosen based on their low DOPE Z scores before validation using MetaMQAPII, ANOLEA, PROCHECK and QMEAN6. The DOPE Z scores and the RMSD (RMS) values of the calculated models indicate that the models are of acceptable energy (stability) and fold (conformation). Results from the different MQAPs indicate the models are of acceptable quality and they can be used for docking studies. High throughput screening of SANCDB using AutoDock Vina revealed nine compounds, SANC00 478, 479, 480, 481, 482, 488, 489, 490 and 491, having a strong affinity for Trypanosoma spp. cathepsin B proteases than HsCatB. SANC00488 has the strongest binding to Trypanosoma spp. cathepsin B proteases and the weakest binding to HsCatB protease. Molecular dynamics (MD) simulations show that the complexes between SANC00488 and TbCatB, TcCatB, TcrCatB and TvCatB are stable and do not come apart during simulation. The complex between this compound and HsCatB however is unstable and comes apart during simulation. Residues that are important for the stability of SANC00488-TbCatB complex are Gly328 of the S2 subsite, Phe208, and Ala256. In conclusion SANC00488 is a good candidate for development of a drug against HAT.
- Full Text:
- Date Issued: 2016
- Authors: Mokhawa, Gaone
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/3304 , vital:20470
- Description: Human African Trypanosomiasis (HAT), also known as sleeping sickness, is a fatal chronic disease that is caused by flagellated protozoans, Trypanosoma brucei gambiense and Trypanosoma brucei rhodesiense. HAT is spread by a bite from an infected tsetse fly of the Glosina genus. Up to 60 million people in 36 countries in sub-Saharan Africa are at a risk of infection from HAT with up to 30 000 deaths reported every year. Current chemotherapy for HAT is insufficient since the available drugs exhibit unacceptable side effects (toxicity) and parasite resistance. Novel treatments and approaches for development of specific and more potent drugs for HAT are therefore required. One approach is to target vital proteins that are essential to the life cycle of the parasite. The main interest of this study is to explore Trypanosoma brucei cathepsin B-like protease (TbCatB) structural and functional properties with the primary goal of discovering non peptide small molecule inhibitors of TbCatB using bioinformatics approaches. TbCatB is a papain family C1 cysteine protease which belongs to clan CA group and it has emerged as a potential HAT drug target. Papain family cysteine proteases of Clan CA group of Trypanosoma brucei (rhodesain and TbCatB) have demonstrated potential as chemotherapeutic targets using synthetic protease inhibitors like Z-Phe-Ala-CHN2 to kill the parasite in vitro and in vivo. TbCatB has been identified as the essential cysteine protease of T. brucei since mRNA silencing of TbCatB killed the parasite and resulted in a cure in mice infected with T. brucei while mRNA silencing of rhodesain only extended mice life. TbCatB is therefore a promising drug target against HAT and the discovery and development of compounds that can selectively inhibit TbCatB without posing any danger to the human host represent a great therapeutic solution for treatment of HAT. To understand protein-inhibitor interactions, useful information can be obtained from high resolution protease-inhibitor crystal structure complexes. This study aims to use bioinformatics approaches to carry out comparative sequence, structural and functional analysis of TbCatB protease and its homologs from T. congolense, T, cruzi, T. vivax and H. sapien as well as to identify non-peptide small molecule inhibitors of TbCatB cysteine proteases from natural compounds of South African origin. Sequences of TbCatB (PDB ID: 3HHI) homologs were retrieved by a BLAST search. Human cathepsin B (PDB ID: 3CBJ) was selected from a list of templates for homology modelling found by HHpred. MODELLER version 9.10 program was used to generate a hundred models for T. congolense, T, cruzi and T. vivax cathepsin B like proteases using 3HHI and 3CBJ as templates. The best models were chosen based on their low DOPE Z scores before validation using MetaMQAPII, ANOLEA, PROCHECK and QMEAN6. The DOPE Z scores and the RMSD (RMS) values of the calculated models indicate that the models are of acceptable energy (stability) and fold (conformation). Results from the different MQAPs indicate the models are of acceptable quality and they can be used for docking studies. High throughput screening of SANCDB using AutoDock Vina revealed nine compounds, SANC00 478, 479, 480, 481, 482, 488, 489, 490 and 491, having a strong affinity for Trypanosoma spp. cathepsin B proteases than HsCatB. SANC00488 has the strongest binding to Trypanosoma spp. cathepsin B proteases and the weakest binding to HsCatB protease. Molecular dynamics (MD) simulations show that the complexes between SANC00488 and TbCatB, TcCatB, TcrCatB and TvCatB are stable and do not come apart during simulation. The complex between this compound and HsCatB however is unstable and comes apart during simulation. Residues that are important for the stability of SANC00488-TbCatB complex are Gly328 of the S2 subsite, Phe208, and Ala256. In conclusion SANC00488 is a good candidate for development of a drug against HAT.
- Full Text:
- Date Issued: 2016
Using data mining techniques for the prediction of student dropouts from university science programs
- Authors: Vambe, William Tichaona
- Date: 2016
- Subjects: Data mining Dropout behavior, Prediction of
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12314 , vital:39252
- Description: Data Mining has taken a center stage in education for addressing student dropout challenges as it has become one of the major threat affecting Higher Educational Institutes (HEIs). Being able to predict students who are likely to dropout helps the university to assist those facing challenges early. This will results in producing more graduates with the intellectual capital who will provide skills in the industries, hence addressing the major challenge of skill shortage being faced in South Africa. Studies and researches as purported in literature have been done to address this major threat of dropout challenge by using the theoretical approach which banked on Tinto’s model, followed by the traditional and statistical approach. However, the two lacked accuracy and the automation aspect which makes them difficult and time-consuming to use as they require to be tested periodically for them to be validated. Recently data mining has become a vital tool for predicting non-linear phenomenon including where there is missing data and bringing about accuracy and automation aspect. Data mining usefulness and reliability assessment in education made it possible to be used for prediction by different researchers. As such this research used data mining approach that integrates classification and prediction techniques to analyze student academic data at the University of Fort Hare to create a model for student dropout using preentry data and university academic performance of each student. Following Knowledge Discovery from Database (KDD) framework, data for the students enrolled in the Bachelor of Science programs between 2003 and 2014 was selected. It went through preprocessing and transformation as to deal with the missing data and noise data. Classification algorithms were then used for student characterization. Decision trees (J48) which are found in Weka software were used to build the model for data mining and prediction. The reason for choosing decision trees was it’s ability to deal with textual, nominal and numeric data as was the case with our input data and because they have good precision.The model was then trained using a train data set, validated and evaluated with another data set. Experimental results demonstrations that data mining is useful in predicting students who have chances to drop out. A critical analysis of correctly classifying instances, the confusion matrix and ROC area shows that the model can correctly classify and predict those who are likely to dropout. The model accuracy was 66percent which is a good percentage as supported in literature which means the results produced can be reliably used for assessment and make strategic decisions. Furthermore, the model took a matter of seconds to compute the results when supplied with 400 instances which prove that it is effective and efficient. Grounding our conclusion from these experimental results, this research proved that Data Mining is useful for bringing about automation, accuracy in prediction of student dropouts and the results can be reliably depended on for decision making by faculty managers who are the decision makers.
- Full Text:
- Date Issued: 2016
Using data mining techniques for the prediction of student dropouts from university science programs
- Authors: Vambe, William Tichaona
- Date: 2016
- Subjects: Data mining Dropout behavior, Prediction of
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12314 , vital:39252
- Description: Data Mining has taken a center stage in education for addressing student dropout challenges as it has become one of the major threat affecting Higher Educational Institutes (HEIs). Being able to predict students who are likely to dropout helps the university to assist those facing challenges early. This will results in producing more graduates with the intellectual capital who will provide skills in the industries, hence addressing the major challenge of skill shortage being faced in South Africa. Studies and researches as purported in literature have been done to address this major threat of dropout challenge by using the theoretical approach which banked on Tinto’s model, followed by the traditional and statistical approach. However, the two lacked accuracy and the automation aspect which makes them difficult and time-consuming to use as they require to be tested periodically for them to be validated. Recently data mining has become a vital tool for predicting non-linear phenomenon including where there is missing data and bringing about accuracy and automation aspect. Data mining usefulness and reliability assessment in education made it possible to be used for prediction by different researchers. As such this research used data mining approach that integrates classification and prediction techniques to analyze student academic data at the University of Fort Hare to create a model for student dropout using preentry data and university academic performance of each student. Following Knowledge Discovery from Database (KDD) framework, data for the students enrolled in the Bachelor of Science programs between 2003 and 2014 was selected. It went through preprocessing and transformation as to deal with the missing data and noise data. Classification algorithms were then used for student characterization. Decision trees (J48) which are found in Weka software were used to build the model for data mining and prediction. The reason for choosing decision trees was it’s ability to deal with textual, nominal and numeric data as was the case with our input data and because they have good precision.The model was then trained using a train data set, validated and evaluated with another data set. Experimental results demonstrations that data mining is useful in predicting students who have chances to drop out. A critical analysis of correctly classifying instances, the confusion matrix and ROC area shows that the model can correctly classify and predict those who are likely to dropout. The model accuracy was 66percent which is a good percentage as supported in literature which means the results produced can be reliably used for assessment and make strategic decisions. Furthermore, the model took a matter of seconds to compute the results when supplied with 400 instances which prove that it is effective and efficient. Grounding our conclusion from these experimental results, this research proved that Data Mining is useful for bringing about automation, accuracy in prediction of student dropouts and the results can be reliably depended on for decision making by faculty managers who are the decision makers.
- Full Text:
- Date Issued: 2016
Wavelength-modulation spectroscopy for the evaluation of the photoresponse of solar cells
- Mandanirina, Nambinintsoa Roméoh Hasinjatovo
- Authors: Mandanirina, Nambinintsoa Roméoh Hasinjatovo
- Date: 2016
- Subjects: Gallium arsenide semiconductors , Solar cells , Modulation spectroscopy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/7244 , vital:21312
- Description: This study describes the development of a wavelength-modulation spectroscopy technique for the evaluation of solar cell devices. In particular, the technique is used to investigate the sub-bandgap response associated with the incorporation of GaSb quantum rings into the active region of a conventional GaAs p-i-n solar cell. These GaSb/GaAs quantum ring solar cells are a class of third generation cells, with the potential to exceed the Shockley-Queisser efficiency limit of single junction devices. Wavelength-modulation spectroscopy (WMS) techniques involve the modulation of the wavelength of a pseudo-monochromatic light source, with the resulting variation in the measured photocurrent then being a measure of the differential optical response of the solar cell. Although the conventional photocurrent spectrum of a solar cell is a good measure of the optical response characteristics, the differential technique gives supplemental detail related to the absorption spectrum. In addition to the basic WMS setup, we also developed an in situ flux correction module to ensure that a constant excitation intensity is maintained during the wavelength modulation. The excitation source inherently has a spectral dependence that leads to an undesirable contribution to the photocurrent signal. The operation of the flux corrected WMS setup has been demonstrated by photocurrent and photo-capacitance response measurements to obtain the differential quantum efficiency and charging characteristics of the quantum ring solar cells.
- Full Text:
- Date Issued: 2016
- Authors: Mandanirina, Nambinintsoa Roméoh Hasinjatovo
- Date: 2016
- Subjects: Gallium arsenide semiconductors , Solar cells , Modulation spectroscopy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/7244 , vital:21312
- Description: This study describes the development of a wavelength-modulation spectroscopy technique for the evaluation of solar cell devices. In particular, the technique is used to investigate the sub-bandgap response associated with the incorporation of GaSb quantum rings into the active region of a conventional GaAs p-i-n solar cell. These GaSb/GaAs quantum ring solar cells are a class of third generation cells, with the potential to exceed the Shockley-Queisser efficiency limit of single junction devices. Wavelength-modulation spectroscopy (WMS) techniques involve the modulation of the wavelength of a pseudo-monochromatic light source, with the resulting variation in the measured photocurrent then being a measure of the differential optical response of the solar cell. Although the conventional photocurrent spectrum of a solar cell is a good measure of the optical response characteristics, the differential technique gives supplemental detail related to the absorption spectrum. In addition to the basic WMS setup, we also developed an in situ flux correction module to ensure that a constant excitation intensity is maintained during the wavelength modulation. The excitation source inherently has a spectral dependence that leads to an undesirable contribution to the photocurrent signal. The operation of the flux corrected WMS setup has been demonstrated by photocurrent and photo-capacitance response measurements to obtain the differential quantum efficiency and charging characteristics of the quantum ring solar cells.
- Full Text:
- Date Issued: 2016