Customary marriage and family practices that discriminate against amaXhosa women: a critical study of selected isixhosa literary text
- Authors: Mbatyoti, Pheliwe Yvonne
- Date: 2019
- Subjects: Forced marriage -- South Africa -- Eastern Cape Customary law -- South Africa Xhosa (African people) -- Social life and customs
- Language: English
- Type: Thesis , Doctoral , D Litt et Phil (African Studies)
- Identifier: http://hdl.handle.net/10353/10736 , vital:35731
- Description: In many parts of Africa, the cultural practices and customs that were in use over the ages are still largely in place today. Many of these practices discriminate against individuals and compromise their human rights, particularly the rights of African women. The aim of this investigation is to study customary marital practices among the amaXhosa in order to establish their effect on modern amaXhosa society. In addition, this includes other discriminatory practices, such as the diminished status of wedded women. Within the study, the social status of women before and after 1994 is dealt with as depicted in the selected texts. The study further determines the current social status of married women under the current dispensation and finds out whether the rights of married women are sufficiently recognised in the texts under discussion. It is clear therefore that whilst Africa has made good progress on the political front, the same cannot be said for some of the cultural values that are still adhered to in the present age. This applies in particular to the rights of women in an African society. Globally, women and girls suffer the harmful and life-threatening effects of discriminatory traditional and cultural practices that continue under the guise of social, cultural and religious ceremonies. In the democratic South Africa, there is growing concern and awareness that some cultural practices are harmful to women and girls. The study analyses a number of texts namely, novels and drama, that were published before and after the 1994 era in South Africa with aims and objectives being outlined in Chapter 1. Chapter 2 is devoted to the theoretical framework, which includes the general theory pertaining to the status of women, feminism and human rights. Secondly, it deals with African theory pertaining to the status of African women as well as their rights; finally, it reflects on the role of women in societies where traditional marriage custom is still in use. Chapter 3 analyses the depiction of customary marriage as a theme in isiXhosa prose before and after 1994. Chapter 4 examines the depiction of customary marriage in v isiXhosa drama before and after 1994 and focuses more on human rights elements. Chapter 5 summarises the arguments distilled from the analysed works. The researcher came to the conclusion that the practice of forced marriage does not occur in amaXhosa society only but it is also found on a wider scale on the rest of the African continent and beyond. The study was concluded with a set of recommendations that were made to combat the scourge of anti-feminism that is found in modern society.
- Full Text:
- Date Issued: 2019
- Authors: Mbatyoti, Pheliwe Yvonne
- Date: 2019
- Subjects: Forced marriage -- South Africa -- Eastern Cape Customary law -- South Africa Xhosa (African people) -- Social life and customs
- Language: English
- Type: Thesis , Doctoral , D Litt et Phil (African Studies)
- Identifier: http://hdl.handle.net/10353/10736 , vital:35731
- Description: In many parts of Africa, the cultural practices and customs that were in use over the ages are still largely in place today. Many of these practices discriminate against individuals and compromise their human rights, particularly the rights of African women. The aim of this investigation is to study customary marital practices among the amaXhosa in order to establish their effect on modern amaXhosa society. In addition, this includes other discriminatory practices, such as the diminished status of wedded women. Within the study, the social status of women before and after 1994 is dealt with as depicted in the selected texts. The study further determines the current social status of married women under the current dispensation and finds out whether the rights of married women are sufficiently recognised in the texts under discussion. It is clear therefore that whilst Africa has made good progress on the political front, the same cannot be said for some of the cultural values that are still adhered to in the present age. This applies in particular to the rights of women in an African society. Globally, women and girls suffer the harmful and life-threatening effects of discriminatory traditional and cultural practices that continue under the guise of social, cultural and religious ceremonies. In the democratic South Africa, there is growing concern and awareness that some cultural practices are harmful to women and girls. The study analyses a number of texts namely, novels and drama, that were published before and after the 1994 era in South Africa with aims and objectives being outlined in Chapter 1. Chapter 2 is devoted to the theoretical framework, which includes the general theory pertaining to the status of women, feminism and human rights. Secondly, it deals with African theory pertaining to the status of African women as well as their rights; finally, it reflects on the role of women in societies where traditional marriage custom is still in use. Chapter 3 analyses the depiction of customary marriage as a theme in isiXhosa prose before and after 1994. Chapter 4 examines the depiction of customary marriage in v isiXhosa drama before and after 1994 and focuses more on human rights elements. Chapter 5 summarises the arguments distilled from the analysed works. The researcher came to the conclusion that the practice of forced marriage does not occur in amaXhosa society only but it is also found on a wider scale on the rest of the African continent and beyond. The study was concluded with a set of recommendations that were made to combat the scourge of anti-feminism that is found in modern society.
- Full Text:
- Date Issued: 2019
Customer loyalty programmes in the South African grocery and retail sector
- Authors: Harmse, Nyree
- Date: 2019
- Subjects: Customer loyalty programs -- South Africa , Customer clubs -- South Africa Grocery trade -- South Africa Food industry and trade -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/39599 , vital:35331
- Description: While there has been substantial research on loyalty programmes, few studies specifically focus on the attitudinal and behavioural components of a loyalty programmes within grocery and retail sector programmes in South Africa. This study is part of a broader study of South African loyalty programmes, but specifically examines the attitudinal and behavioural influences on loyalty programmes in the South African grocery and retail sector. A comprehensive literature review was conducted and factors influencing loyalty programmes were identified. The literature reviewed informed the conceptual model that proposed purchasing behaviour, trust, communication, personalisation, flexibility, rewards and method of participation influenced the success of grocery and retail sector loyalty programmes with attitude and behaviour serving as intermediate variables. The academic literature selected for the study is grounded in the academic theories of social exchange and planned behaviour. The methodology followed was through self-administered questionnaires developed from academic literature. Data were collected from 1090 respondents across South Africa, of which 643 respondents were members of grocery and retail sector loyalty programmes. The data analysis conducted through various descriptive and inferential statistical tests and exploratory factors analysis identified that factors of purchasing behaviour, trust, communication, personalisation, flexibility, rewards and general assessment were factors influencing loyalty programmes. Loyalty programme studies in South Africa are generally conducted on specific loyalty programmes, which are owned by the programme owners and therefore unpublished. This study contributes to the body of knowledge by using academic theory to establish the attitudinal and behavioural factors that affect loyalty programmes within the South African grocery and retail sector. The study concludes with managerial recommendations that grocery and retail sector managers can implement to influence the success of loyalty programmes. Some of the recommendations include the use of communication as a lever to influence other factors and the overall effectiveness of the programme. Other recommendations include data management and rewards that create flexible and personalised experiences.
- Full Text:
- Date Issued: 2019
- Authors: Harmse, Nyree
- Date: 2019
- Subjects: Customer loyalty programs -- South Africa , Customer clubs -- South Africa Grocery trade -- South Africa Food industry and trade -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/39599 , vital:35331
- Description: While there has been substantial research on loyalty programmes, few studies specifically focus on the attitudinal and behavioural components of a loyalty programmes within grocery and retail sector programmes in South Africa. This study is part of a broader study of South African loyalty programmes, but specifically examines the attitudinal and behavioural influences on loyalty programmes in the South African grocery and retail sector. A comprehensive literature review was conducted and factors influencing loyalty programmes were identified. The literature reviewed informed the conceptual model that proposed purchasing behaviour, trust, communication, personalisation, flexibility, rewards and method of participation influenced the success of grocery and retail sector loyalty programmes with attitude and behaviour serving as intermediate variables. The academic literature selected for the study is grounded in the academic theories of social exchange and planned behaviour. The methodology followed was through self-administered questionnaires developed from academic literature. Data were collected from 1090 respondents across South Africa, of which 643 respondents were members of grocery and retail sector loyalty programmes. The data analysis conducted through various descriptive and inferential statistical tests and exploratory factors analysis identified that factors of purchasing behaviour, trust, communication, personalisation, flexibility, rewards and general assessment were factors influencing loyalty programmes. Loyalty programme studies in South Africa are generally conducted on specific loyalty programmes, which are owned by the programme owners and therefore unpublished. This study contributes to the body of knowledge by using academic theory to establish the attitudinal and behavioural factors that affect loyalty programmes within the South African grocery and retail sector. The study concludes with managerial recommendations that grocery and retail sector managers can implement to influence the success of loyalty programmes. Some of the recommendations include the use of communication as a lever to influence other factors and the overall effectiveness of the programme. Other recommendations include data management and rewards that create flexible and personalised experiences.
- Full Text:
- Date Issued: 2019
Damage recovery for robot controllers and simulators evolved using bootstrapped neuro-simulation
- Authors: Leonard, Brydon Andrew
- Date: 2019
- Subjects: Robots -- Control systems , Robots -- Programming Robotics Neural networks (Computer science)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/40424 , vital:36164
- Description: Robots are becoming increasingly complex. This has made manually designing the software responsible for controlling these robots (controllers) challenging, leading to the creation of the field of evolutionary robotics (ER). The ER approach aims to automatically evolve robot controllers and morphologies by utilising concepts from biological evolution. ER techniques use evolutionary algorithms (EA) to evolve populations of controllers - a process that requires the evaluation of a large number of controllers. Performing these evaluations on a real-world robot is both infeasibly time-consuming and poses the risk of damage to the robot. Simulators present a solution to the issue by allowing the evaluation of controllers to take place on a virtual robot. Traditional methods of controller evolution in simulation encounter two major issues. Firstly, physics simulators are complex to create and are often very computationally expensive. Secondly, the reality gap is encountered when controllers are evolved in simulators that are unable to simulate the real world well enough due to implications or small inaccuracies in the simulation, which together cause controllers in the simulation to be unable to transfer effectively to reality. Bootstrapped Neuro-Simulation (BNS) is an ER algorithm that aims to address the issues inherent with the use of simulators. The algorithm concurrently creates a simulator and evolves a population of controllers. The process starts with an initially random population of controllers and an untrained simulator neural network (SNN), a type of robot simulator which utilises artificial neural networks (ANNs) to simulate a robot's behaviour. Controllers are then continually selected for evaluation in the real world, and the data from these real-world evaluations is used to train the controller-evaluation SNN. BNS is a relatively new algorithm that has not yet been explored in depth. An investigation was, therefore, conducted into BNS's ability to evolve closed-loop controllers. BNS was successful in evolving such controllers, and various adaptations to the algorithm were investigated for their ability to improve the evolution of closed-loop controllers. In addition, the factors which had the greatest impact on BNS's effectiveness were reported upon. Damage recovery is an area that has been the focus of a great deal of research. This is because the progression of the field of robotics means that robots no longer operate only in the safe environments that they once did. Robots are now put to use in areas as inaccessible as the surface of Mars, where repairs by a human are impossible. Various methods of damage recovery have previously been proposed and evaluated, but none focused on BNS as a method of damage recovery. In this research, it was hypothesised that BNS's constantly learning nature would allow it to recover from damage, as it would continue to use new information about the state of the real robot to evolve new controllers capable of functioning in the damaged robot. BNS was found to possess the hypothesised damage recovery ability. The algorithm's evaluation was carried out through the evolution of controllers for simple navigation and light-following tasks for a wheeled robot, as well as a locomotion task for a complex legged robot. Various adaptations to the algorithm were then evaluated through extensive parameter investigations in simulation, showing varying levels of effectiveness. These results were further confirmed through evaluation of the adaptations and effective parameter values in real-world evaluations on a real robot. Both a simple and more complex robot morphology were investigated.
- Full Text:
- Date Issued: 2019
- Authors: Leonard, Brydon Andrew
- Date: 2019
- Subjects: Robots -- Control systems , Robots -- Programming Robotics Neural networks (Computer science)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/40424 , vital:36164
- Description: Robots are becoming increasingly complex. This has made manually designing the software responsible for controlling these robots (controllers) challenging, leading to the creation of the field of evolutionary robotics (ER). The ER approach aims to automatically evolve robot controllers and morphologies by utilising concepts from biological evolution. ER techniques use evolutionary algorithms (EA) to evolve populations of controllers - a process that requires the evaluation of a large number of controllers. Performing these evaluations on a real-world robot is both infeasibly time-consuming and poses the risk of damage to the robot. Simulators present a solution to the issue by allowing the evaluation of controllers to take place on a virtual robot. Traditional methods of controller evolution in simulation encounter two major issues. Firstly, physics simulators are complex to create and are often very computationally expensive. Secondly, the reality gap is encountered when controllers are evolved in simulators that are unable to simulate the real world well enough due to implications or small inaccuracies in the simulation, which together cause controllers in the simulation to be unable to transfer effectively to reality. Bootstrapped Neuro-Simulation (BNS) is an ER algorithm that aims to address the issues inherent with the use of simulators. The algorithm concurrently creates a simulator and evolves a population of controllers. The process starts with an initially random population of controllers and an untrained simulator neural network (SNN), a type of robot simulator which utilises artificial neural networks (ANNs) to simulate a robot's behaviour. Controllers are then continually selected for evaluation in the real world, and the data from these real-world evaluations is used to train the controller-evaluation SNN. BNS is a relatively new algorithm that has not yet been explored in depth. An investigation was, therefore, conducted into BNS's ability to evolve closed-loop controllers. BNS was successful in evolving such controllers, and various adaptations to the algorithm were investigated for their ability to improve the evolution of closed-loop controllers. In addition, the factors which had the greatest impact on BNS's effectiveness were reported upon. Damage recovery is an area that has been the focus of a great deal of research. This is because the progression of the field of robotics means that robots no longer operate only in the safe environments that they once did. Robots are now put to use in areas as inaccessible as the surface of Mars, where repairs by a human are impossible. Various methods of damage recovery have previously been proposed and evaluated, but none focused on BNS as a method of damage recovery. In this research, it was hypothesised that BNS's constantly learning nature would allow it to recover from damage, as it would continue to use new information about the state of the real robot to evolve new controllers capable of functioning in the damaged robot. BNS was found to possess the hypothesised damage recovery ability. The algorithm's evaluation was carried out through the evolution of controllers for simple navigation and light-following tasks for a wheeled robot, as well as a locomotion task for a complex legged robot. Various adaptations to the algorithm were then evaluated through extensive parameter investigations in simulation, showing varying levels of effectiveness. These results were further confirmed through evaluation of the adaptations and effective parameter values in real-world evaluations on a real robot. Both a simple and more complex robot morphology were investigated.
- Full Text:
- Date Issued: 2019
Data quality issues in electronic health records for large-scale databases
- Authors: Saiod, Abdul Kader
- Date: 2019
- Subjects: Electronic Health Records , Electronic Health Records--organization & administration Database management
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/44940 , vital:38190
- Description: Data Quality (DQ) in Electronic Health Records (EHRs) is one of the core functions that play a decisive role to improve the healthcare service quality. The DQ issues in EHRs are a noticeable trend to improve the introduction of an adaptive framework for interoperability and standards in Large-Scale Databases (LSDB) management systems. Therefore, large data communications are challenging in the traditional approaches to satisfy the needs of the consumers, as data is often not capture directly into the Database Management Systems (DBMS) in a seasonably enough fashion to enable their subsequent uses. In addition, large data plays a vital role in containing plenty of treasures for all the fields in the DBMS. EHRs technology provides portfolio management systems that allow HealthCare Organisations (HCOs) to deliver a higher quality of care to their patients than that which is possible with paper-based records. EHRs are in high demand for HCOs to run their daily services as increasing numbers of huge datasets occur every day. Efficient EHR systems reduce the data redundancy as well as the system application failure and increase the possibility to draw all necessary reports. However, one of the main challenges in developing efficient EHR systems is the inherent difficulty to coherently manage data from diverse heterogeneous sources. It is practically challenging to integrate diverse data into a global schema, which satisfies the need of users. The efficient management of HER systems using an existing DBMS present challenges because of incompatibility and sometimes inconsistency of data structures. As a result, no common methodological approach is currently in existence to effectively solve every data integration problem. The challenges of the DQ issue raised the need to find an efficient way to integrate large EHRs from diverse heterogeneous sources. To handle and align a large dataset efficiently, the hybrid algorithm method with the logical combination of Fuzzy-Ontology along with a large-scale EHRs analysis platform has shown the results in term of improved accuracy. This study investigated and addressed the raised DQ issues to interventions to overcome these barriers and challenges, including the provision of EHRs as they pertain to DQ and has combined features to search, extract, filter, clean and integrate data to ensure that users can coherently create new consistent data sets. The study researched the design of a hybrid method based on Fuzzy-Ontology with performed mathematical simulations based on the Markov Chain Probability Model. The similarity measurement based on dynamic Hungarian algorithm was followed by the Design Science Research (DSR) methodology, which will increase the quality of service over HCOs in adaptive frameworks.
- Full Text:
- Date Issued: 2019
- Authors: Saiod, Abdul Kader
- Date: 2019
- Subjects: Electronic Health Records , Electronic Health Records--organization & administration Database management
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/44940 , vital:38190
- Description: Data Quality (DQ) in Electronic Health Records (EHRs) is one of the core functions that play a decisive role to improve the healthcare service quality. The DQ issues in EHRs are a noticeable trend to improve the introduction of an adaptive framework for interoperability and standards in Large-Scale Databases (LSDB) management systems. Therefore, large data communications are challenging in the traditional approaches to satisfy the needs of the consumers, as data is often not capture directly into the Database Management Systems (DBMS) in a seasonably enough fashion to enable their subsequent uses. In addition, large data plays a vital role in containing plenty of treasures for all the fields in the DBMS. EHRs technology provides portfolio management systems that allow HealthCare Organisations (HCOs) to deliver a higher quality of care to their patients than that which is possible with paper-based records. EHRs are in high demand for HCOs to run their daily services as increasing numbers of huge datasets occur every day. Efficient EHR systems reduce the data redundancy as well as the system application failure and increase the possibility to draw all necessary reports. However, one of the main challenges in developing efficient EHR systems is the inherent difficulty to coherently manage data from diverse heterogeneous sources. It is practically challenging to integrate diverse data into a global schema, which satisfies the need of users. The efficient management of HER systems using an existing DBMS present challenges because of incompatibility and sometimes inconsistency of data structures. As a result, no common methodological approach is currently in existence to effectively solve every data integration problem. The challenges of the DQ issue raised the need to find an efficient way to integrate large EHRs from diverse heterogeneous sources. To handle and align a large dataset efficiently, the hybrid algorithm method with the logical combination of Fuzzy-Ontology along with a large-scale EHRs analysis platform has shown the results in term of improved accuracy. This study investigated and addressed the raised DQ issues to interventions to overcome these barriers and challenges, including the provision of EHRs as they pertain to DQ and has combined features to search, extract, filter, clean and integrate data to ensure that users can coherently create new consistent data sets. The study researched the design of a hybrid method based on Fuzzy-Ontology with performed mathematical simulations based on the Markov Chain Probability Model. The similarity measurement based on dynamic Hungarian algorithm was followed by the Design Science Research (DSR) methodology, which will increase the quality of service over HCOs in adaptive frameworks.
- Full Text:
- Date Issued: 2019
Data quality issues in electronic health records for large-scale databases
- Authors: Saiod, Abdul Kader
- Date: 2019
- Subjects: Healthcare -- Data quality
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/44577 , vital:38145
- Description: Data Quality (DQ) in Electronic Health Records (EHRs) is one of the core functions that play a decisive role to improve the healthcare service quality. The DQ issues in EHRs are a noticeable trend to improve the introduction of an adaptive framework for interoperability and standards in Large-Scale Databases (LSDB) management systems. Therefore, large data communications are challenging in the traditional approaches to satisfy the needs of the consumers, as data is often not capture directly into the Database Management Systems (DBMS) in a seasonably enough fashion to enable their subsequent uses. In addition, large data plays a vital role in containing plenty of treasures for all the fields in the DBMS. EHRs technology provides portfolio management systems that allow HealthCare Organisations (HCOs) to deliver a higher quality of care to their patients than that which is possible with paper-based records. EHRs are in high demand for HCOs to run their daily services as increasing numbers of huge datasets occur every day. Efficient EHR systems reduce the data redundancy as well as the system application failure and increase the possibility to draw all necessary reports. However, one of the main challenges in developing efficient EHR systems is the inherent difficulty to coherently manage data from diverse heterogeneous sources. It is practically challenging to integrate diverse data into a global schema, which satisfies the need of users. The efficient management of EHR systems using an existing DBMS present challenges because of incompatibility and sometimes inconsistency of data structures. As a result, no common methodological approach is currently in existence to effectively solve every data integration problem. The challenges of the DQ issue raised the need to find an efficient way to integrate large EHRs from diverse heterogeneous sources. To handle and align a large dataset efficiently, the hybrid algorithm method with the logical combination of Fuzzy-Ontology along with a large-scale EHRs analysis platform has shown the results in term of improved accuracy. This study investigated and addressed the raised DQ issues to interventions to overcome these barriers and challenges, including the provision of EHRs as they pertain to DQ and has combined features to search, extract, filter, clean and integrate data to ensure that users can coherently create new consistent data sets. The study researched the design of a hybrid method based on Fuzzy-Ontology with performed mathematical simulations based on the Markov Chain Probability Model. The similarity measurement based on dynamic Hungarian algorithm was followed by the Design Science Research (DSR) methodology, which will increase the quality of service over HCOs in adaptive frameworks.
- Full Text:
- Date Issued: 2019
- Authors: Saiod, Abdul Kader
- Date: 2019
- Subjects: Healthcare -- Data quality
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/44577 , vital:38145
- Description: Data Quality (DQ) in Electronic Health Records (EHRs) is one of the core functions that play a decisive role to improve the healthcare service quality. The DQ issues in EHRs are a noticeable trend to improve the introduction of an adaptive framework for interoperability and standards in Large-Scale Databases (LSDB) management systems. Therefore, large data communications are challenging in the traditional approaches to satisfy the needs of the consumers, as data is often not capture directly into the Database Management Systems (DBMS) in a seasonably enough fashion to enable their subsequent uses. In addition, large data plays a vital role in containing plenty of treasures for all the fields in the DBMS. EHRs technology provides portfolio management systems that allow HealthCare Organisations (HCOs) to deliver a higher quality of care to their patients than that which is possible with paper-based records. EHRs are in high demand for HCOs to run their daily services as increasing numbers of huge datasets occur every day. Efficient EHR systems reduce the data redundancy as well as the system application failure and increase the possibility to draw all necessary reports. However, one of the main challenges in developing efficient EHR systems is the inherent difficulty to coherently manage data from diverse heterogeneous sources. It is practically challenging to integrate diverse data into a global schema, which satisfies the need of users. The efficient management of EHR systems using an existing DBMS present challenges because of incompatibility and sometimes inconsistency of data structures. As a result, no common methodological approach is currently in existence to effectively solve every data integration problem. The challenges of the DQ issue raised the need to find an efficient way to integrate large EHRs from diverse heterogeneous sources. To handle and align a large dataset efficiently, the hybrid algorithm method with the logical combination of Fuzzy-Ontology along with a large-scale EHRs analysis platform has shown the results in term of improved accuracy. This study investigated and addressed the raised DQ issues to interventions to overcome these barriers and challenges, including the provision of EHRs as they pertain to DQ and has combined features to search, extract, filter, clean and integrate data to ensure that users can coherently create new consistent data sets. The study researched the design of a hybrid method based on Fuzzy-Ontology with performed mathematical simulations based on the Markov Chain Probability Model. The similarity measurement based on dynamic Hungarian algorithm was followed by the Design Science Research (DSR) methodology, which will increase the quality of service over HCOs in adaptive frameworks.
- Full Text:
- Date Issued: 2019
Deconstructing “the South African jazz feel”: roots, rhythms and features of South African jazz
- Authors: Thorpe, Christopher John
- Date: 2019
- Subjects: Jazz -- History and criticism , Jazz -- African influences , Jazz -- Africa --History and criticism , Jazz -- South Africa --History and criticism
- Language: English
- Type: text , Thesis , Masters , MMus
- Identifier: http://hdl.handle.net/10962/76649 , vital:30612
- Description: South African jazz has established itself as a distinct and influential genre in modern popular music that merges musical elements from traditional South African musics with influences from U.S.-American jazz. Formed during a time of extreme social inequality in a divided country, South African jazz became the soundtrack of the struggle against social injustice and racial oppression, and was brought to international attention by artists such as Hugh Masekela, Miriam Makeba, and Abdullah Ibrahim who gave poignant musical expression to the hardships of the time. South African jazz is celebrated for its unique sound, original catalogue and all-important “feel”. To many listeners, performers and musicologists, it is this concept of feel that makes South African jazz so distinctive and inimitable. To date, however, much of the scholarly and popular literature on South African jazz has centred on the historical, social and political aspects of the music, with less attention given to close musical-textual analysis. A few studies have considered the melodic and harmonic language of iconic saxophonists and bass players but there are – to date – no close studies of rhythm and feel in South African jazz. Beginning to address this gap in the literature, this study uncovers some of the elements that constitute the South African jazz feel through close rhythmic and more general musical analyses of a selection of South African jazz recordings.
- Full Text:
- Date Issued: 2019
- Authors: Thorpe, Christopher John
- Date: 2019
- Subjects: Jazz -- History and criticism , Jazz -- African influences , Jazz -- Africa --History and criticism , Jazz -- South Africa --History and criticism
- Language: English
- Type: text , Thesis , Masters , MMus
- Identifier: http://hdl.handle.net/10962/76649 , vital:30612
- Description: South African jazz has established itself as a distinct and influential genre in modern popular music that merges musical elements from traditional South African musics with influences from U.S.-American jazz. Formed during a time of extreme social inequality in a divided country, South African jazz became the soundtrack of the struggle against social injustice and racial oppression, and was brought to international attention by artists such as Hugh Masekela, Miriam Makeba, and Abdullah Ibrahim who gave poignant musical expression to the hardships of the time. South African jazz is celebrated for its unique sound, original catalogue and all-important “feel”. To many listeners, performers and musicologists, it is this concept of feel that makes South African jazz so distinctive and inimitable. To date, however, much of the scholarly and popular literature on South African jazz has centred on the historical, social and political aspects of the music, with less attention given to close musical-textual analysis. A few studies have considered the melodic and harmonic language of iconic saxophonists and bass players but there are – to date – no close studies of rhythm and feel in South African jazz. Beginning to address this gap in the literature, this study uncovers some of the elements that constitute the South African jazz feel through close rhythmic and more general musical analyses of a selection of South African jazz recordings.
- Full Text:
- Date Issued: 2019
Deriving a tool to aid maintenance budget forecasting within universities of selected countries of Southern Africa
- Authors: Peters, Peter Herman
- Date: 2019
- Subjects: Budget forecasting -- Universities -- Africa, Southern
- Language: English
- Type: Thesis , Doctoral , DBA
- Identifier: http://hdl.handle.net/10948/44574 , vital:38137
- Description: In general, facilities are constructed and equipment is procured to meet the functional and utilitarian needs of an organisation. Daily use and abuse can affect the functional value of these resources and without regular maintenance there will be no real benefits derived from non-functional facilities and equipment. Conducting effective and systematic maintenance is one of the fundamentals which underpins the success of an organisation and if ignored, could be costly to rectify. Costs escalate in the form of deferred maintenance budgets, which have a knock-on effect of growing year on year. This highlights the context of universities’ operations managers who may lack proper management and planning tools to either use or apply effective maintenance budget forecasting models. Having properly maintained facilities is imperative since deferring maintenance will adversely affect employees’ occupational health and safety, impact on the cost of operations and the morale of those who use the dysfunctional facility. The most daunting task of facility managers, is to ensure that all facilities remain fully and consistently operational. This entails providing an efficient maintenance service, which prevents system failures and extends the useful life of both the production plant and facilities to be managed. The need to protect costly and varied assets against the depredation of time and keeping it maintained for current use takes significant and continuous investment of time, money and human resources. Due to the cost of maintenance, in most instances maintenance is scheduled to be done when actual facilities are not in operation, usually at the end of a financial or calendar year. The intangible nature of the maintenance function and the inability to completely justify maintenance funding budgets, lead to the required funding not being obtained from a budgetary request. This inevitably has the undesirable consequences of huge capital backlogs in the form of deferred maintenance. This study moves the research problem and argument away from strictly for-profit business (manufacturing) entities to interrogate service-oriented parastatal and hybrid funded University facilities’ operations and maintenance management. Universities are multidisciplinary structures that encompass a broad spectrum of services required to ensure the effective and efficient academic, administrative, experimental and research focused operation of the Institution. Universities are not excluded from ensuring that sufficient funding is obtained for the effective maintenance of their facilities. This research aims to derive a tool to simplify the selection of a suitable maintenance budget forecasting model and to recommend a maintenance budgeting model for use within universities of selected countries of Southern Africa. The literature survey revealed that there are numerous maintenance budgeting forecasting models already in existence in many different shapes and sizes. For this reason, a content analysis was conducted of 31 maintenance budget forecasting models in order to be able to differentiate between the numerous models. This empirical study conducted among universities of selected countries of Southern Africa outlined the current maintenance funding models being used, inclusive of the amount of funding obtained and the existence/lack of deferred maintenance of various Institutions. After analysing the secondary data (in the form of a content analysis) and the empirical data collected, a model was chosen to recommend for implementation in future institutional planning and business practice. Based on the content analysis and empirical review, the recommended maintenance budget selection tool was derived focusing on sharpening the decision making process of selecting a suitable, fit for purpose, maintenance funding model. After this phase of the research, a follow up phase was conducted amongst high level executive decision makers, to qualitatively verify or support the findings from the first phase of the data collection. This research therefore concludes with recommendations to the respondent universities of selected countries of Southern Africa, about a suitable maintenance budgeting forecasting model. It also recommends a selection tool to use if alternative maintenance budget funding models need to be selected. This multidisciplinary study contributes to the literature by contextualising the maintenance budget forecasting for operational universities and in future adding significant value to the proactive management of deferred maintenance in practice.
- Full Text:
- Date Issued: 2019
- Authors: Peters, Peter Herman
- Date: 2019
- Subjects: Budget forecasting -- Universities -- Africa, Southern
- Language: English
- Type: Thesis , Doctoral , DBA
- Identifier: http://hdl.handle.net/10948/44574 , vital:38137
- Description: In general, facilities are constructed and equipment is procured to meet the functional and utilitarian needs of an organisation. Daily use and abuse can affect the functional value of these resources and without regular maintenance there will be no real benefits derived from non-functional facilities and equipment. Conducting effective and systematic maintenance is one of the fundamentals which underpins the success of an organisation and if ignored, could be costly to rectify. Costs escalate in the form of deferred maintenance budgets, which have a knock-on effect of growing year on year. This highlights the context of universities’ operations managers who may lack proper management and planning tools to either use or apply effective maintenance budget forecasting models. Having properly maintained facilities is imperative since deferring maintenance will adversely affect employees’ occupational health and safety, impact on the cost of operations and the morale of those who use the dysfunctional facility. The most daunting task of facility managers, is to ensure that all facilities remain fully and consistently operational. This entails providing an efficient maintenance service, which prevents system failures and extends the useful life of both the production plant and facilities to be managed. The need to protect costly and varied assets against the depredation of time and keeping it maintained for current use takes significant and continuous investment of time, money and human resources. Due to the cost of maintenance, in most instances maintenance is scheduled to be done when actual facilities are not in operation, usually at the end of a financial or calendar year. The intangible nature of the maintenance function and the inability to completely justify maintenance funding budgets, lead to the required funding not being obtained from a budgetary request. This inevitably has the undesirable consequences of huge capital backlogs in the form of deferred maintenance. This study moves the research problem and argument away from strictly for-profit business (manufacturing) entities to interrogate service-oriented parastatal and hybrid funded University facilities’ operations and maintenance management. Universities are multidisciplinary structures that encompass a broad spectrum of services required to ensure the effective and efficient academic, administrative, experimental and research focused operation of the Institution. Universities are not excluded from ensuring that sufficient funding is obtained for the effective maintenance of their facilities. This research aims to derive a tool to simplify the selection of a suitable maintenance budget forecasting model and to recommend a maintenance budgeting model for use within universities of selected countries of Southern Africa. The literature survey revealed that there are numerous maintenance budgeting forecasting models already in existence in many different shapes and sizes. For this reason, a content analysis was conducted of 31 maintenance budget forecasting models in order to be able to differentiate between the numerous models. This empirical study conducted among universities of selected countries of Southern Africa outlined the current maintenance funding models being used, inclusive of the amount of funding obtained and the existence/lack of deferred maintenance of various Institutions. After analysing the secondary data (in the form of a content analysis) and the empirical data collected, a model was chosen to recommend for implementation in future institutional planning and business practice. Based on the content analysis and empirical review, the recommended maintenance budget selection tool was derived focusing on sharpening the decision making process of selecting a suitable, fit for purpose, maintenance funding model. After this phase of the research, a follow up phase was conducted amongst high level executive decision makers, to qualitatively verify or support the findings from the first phase of the data collection. This research therefore concludes with recommendations to the respondent universities of selected countries of Southern Africa, about a suitable maintenance budgeting forecasting model. It also recommends a selection tool to use if alternative maintenance budget funding models need to be selected. This multidisciplinary study contributes to the literature by contextualising the maintenance budget forecasting for operational universities and in future adding significant value to the proactive management of deferred maintenance in practice.
- Full Text:
- Date Issued: 2019
Descriptive guidelines for mediation to enhance the parental involvement of unmarried fathers
- Authors: Nordien-Lagardien, Razia
- Date: 2019
- Subjects: Mediation , Unmarried fathers -- South Africa Father and child -- South Africa Unmarried mothers -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/30462 , vital:30948
- Description: A significant change brought about by the Children’s Act 38 of 2005 (RSA, 2006), is that of the status of unmarried fathers. The parental rights of unmarried fathers have evolved in South Africa, especially since the Children’s Act 38 of 2005 (RSA, 2006) now recognises that unmarried fathers should have inherent right of contact, guardianship and care. These rights are, however, not automatic and need to be acquired through a process of mediation. While this legislation aims to facilitate the parental involvement of fathers by giving them rights as per Section 21 of the Children’s Act 38 of 2005 (RSA, 2006), the reality is that many unmarried fathers still remain challenged in this regard despite the change in their legal position as fathers. Unmarried fathers are often compelled to take the matter further through protracted court processes. Unmarried fathers face unique challenges with parental involvement after separation and they often need to negotiate their involvement with the mother after separation. Given that mediation between unmarried parents is in its infancy in South Africa, very little research has been done in this area. It was envisaged that this study would highlight the important aspects of mediation which need to be considered in order for mediation outcomes to be more successful and to enhance the co-parenting relationship. The study employed a qualitative research approach that was exploratory, descriptive and contextual in design. The research study consisted of three phases. Phase 1 employed a multiple case study design in order to develop an understanding of the experiences and perceptions of unmarried fathers and mothers, as well as mediators, regarding the parental responsibilities of unmarried fathers in addition to their experiences of mediation. The data collection process comprised in-depth semi-structured interviews with three sample groups, namely unmarried fathers, and mothers, and mediators. The data collected from the interviews were transcribed, coded and analysed by the researcher through the use of two techniques, namely: within-case analysis and cross-case synthesis. An independent coder was utilised to verify the coding and analysis process. The analysis of the data in Phase 1 revealed that the construction of the role of unmarried fathers is influenced by various factors such as cultural and religious influences; childhood experiences of fatherhood; societal constructions of the father’s role, and the perception of the legal rights of unmarried fathers. The new legislation pertaining to the responsibilities and rights of unmarried fathers, as contained in the Children’s Act 38 of 2005 (RSA, 2006), has resulted in increased parental conflict between parents after separation owing to their lack of awareness and confusion regarding the changes in legislation pertaining to the rights of unmarried fathers and the role of customary law in this regard. This has resulted in misconceptions about the legal rights of unmarried fathers, which have influenced unmarried parents’ attitudes and receptiveness to mediation. A significant barrier to father involvement emanating from the findings was relationship conflict experienced after separation, which was also identified as a significant challenge in mediation. The discussion of the themes reflected both positive and negative experiences of mediation for the study participants. While the parents derived educational and therapeutic benefits from mediation; there were also several factors such as relationship conflict, cultural barriers, influences of the extended family, and the approach and skills of the mediator, which influenced the mediation process. In Phase 2 of the study an integrative literature review and synthesis of the literature was conducted and critically appraised in terms of emergent themes and relevant research in the area of family mediation, which would inform the process of developing the descriptive guidelines for mediation with unmarried parents. The empirical findings from the study were synthesised with the findings from the integrative literature review, thus enabling conclusions to be drawn in order to generate descriptive guidelines for mediation. Phase 3 of the study describes the guidelines for mediation which emanated from the synthesis of the findings in Phase 1 and Phase 2 of the study. As part of a qualitative evaluation, the guidelines were presented to an expert panel for review, after which the guidelines were finalised. The proposed guidelines for mediation to enhance the parental involvement of unmarried fathers is based on the hybrid model of mediation, which incorporates elements from the Transformative approach, the African centred approach and the co-mediation model. The guidelines are further described in terms of a phased approach to mediation.
- Full Text:
- Date Issued: 2019
- Authors: Nordien-Lagardien, Razia
- Date: 2019
- Subjects: Mediation , Unmarried fathers -- South Africa Father and child -- South Africa Unmarried mothers -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/30462 , vital:30948
- Description: A significant change brought about by the Children’s Act 38 of 2005 (RSA, 2006), is that of the status of unmarried fathers. The parental rights of unmarried fathers have evolved in South Africa, especially since the Children’s Act 38 of 2005 (RSA, 2006) now recognises that unmarried fathers should have inherent right of contact, guardianship and care. These rights are, however, not automatic and need to be acquired through a process of mediation. While this legislation aims to facilitate the parental involvement of fathers by giving them rights as per Section 21 of the Children’s Act 38 of 2005 (RSA, 2006), the reality is that many unmarried fathers still remain challenged in this regard despite the change in their legal position as fathers. Unmarried fathers are often compelled to take the matter further through protracted court processes. Unmarried fathers face unique challenges with parental involvement after separation and they often need to negotiate their involvement with the mother after separation. Given that mediation between unmarried parents is in its infancy in South Africa, very little research has been done in this area. It was envisaged that this study would highlight the important aspects of mediation which need to be considered in order for mediation outcomes to be more successful and to enhance the co-parenting relationship. The study employed a qualitative research approach that was exploratory, descriptive and contextual in design. The research study consisted of three phases. Phase 1 employed a multiple case study design in order to develop an understanding of the experiences and perceptions of unmarried fathers and mothers, as well as mediators, regarding the parental responsibilities of unmarried fathers in addition to their experiences of mediation. The data collection process comprised in-depth semi-structured interviews with three sample groups, namely unmarried fathers, and mothers, and mediators. The data collected from the interviews were transcribed, coded and analysed by the researcher through the use of two techniques, namely: within-case analysis and cross-case synthesis. An independent coder was utilised to verify the coding and analysis process. The analysis of the data in Phase 1 revealed that the construction of the role of unmarried fathers is influenced by various factors such as cultural and religious influences; childhood experiences of fatherhood; societal constructions of the father’s role, and the perception of the legal rights of unmarried fathers. The new legislation pertaining to the responsibilities and rights of unmarried fathers, as contained in the Children’s Act 38 of 2005 (RSA, 2006), has resulted in increased parental conflict between parents after separation owing to their lack of awareness and confusion regarding the changes in legislation pertaining to the rights of unmarried fathers and the role of customary law in this regard. This has resulted in misconceptions about the legal rights of unmarried fathers, which have influenced unmarried parents’ attitudes and receptiveness to mediation. A significant barrier to father involvement emanating from the findings was relationship conflict experienced after separation, which was also identified as a significant challenge in mediation. The discussion of the themes reflected both positive and negative experiences of mediation for the study participants. While the parents derived educational and therapeutic benefits from mediation; there were also several factors such as relationship conflict, cultural barriers, influences of the extended family, and the approach and skills of the mediator, which influenced the mediation process. In Phase 2 of the study an integrative literature review and synthesis of the literature was conducted and critically appraised in terms of emergent themes and relevant research in the area of family mediation, which would inform the process of developing the descriptive guidelines for mediation with unmarried parents. The empirical findings from the study were synthesised with the findings from the integrative literature review, thus enabling conclusions to be drawn in order to generate descriptive guidelines for mediation. Phase 3 of the study describes the guidelines for mediation which emanated from the synthesis of the findings in Phase 1 and Phase 2 of the study. As part of a qualitative evaluation, the guidelines were presented to an expert panel for review, after which the guidelines were finalised. The proposed guidelines for mediation to enhance the parental involvement of unmarried fathers is based on the hybrid model of mediation, which incorporates elements from the Transformative approach, the African centred approach and the co-mediation model. The guidelines are further described in terms of a phased approach to mediation.
- Full Text:
- Date Issued: 2019
Design and Characterization of a 5 kw Xe-Lamp Solar Simulator
- Authors: Nwodo, Julian Chizoba
- Date: 2019
- Subjects: Solar energy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/14671 , vital:40042
- Description: The design and characterisation of a 5kW Xenon lamp solar simulator is presented. This was accomplished through considering the design features of an ellipsoidal reflector, Xe lamp characteristics and casing, and power supply; assembly of an ellipsoidal, Xe-lamp simulator; design and building of an automated control system capable of remotely controlling the operating mode of the simulator; establishing the 3 scenarios that must be met to conform to a AAA class simulator; characterization of the simulator in terms of temporal stability, irradiance uniformity and spectral match; and application of the simulator and comparing it with STC rated values. The considerations for the type of material used for housing the components of the solar simulator were made. A 5kW DC power supply and igniter for the Xe-lamp was carefully selected since they provide necessary power for running the simulator. The simulator has the ability to be used in either horizontal or vertical position by adjusting the reflector. An automated control system capable of remotely controlling the operating mode of the simulator was built for this study, this system enables the simulator to be operated in either auto or manual modes. It also incorporates an irradiance, temperature, current and voltage feedback. The characterisation of the solar simulator was over a 2.1 m X 1.6 m test plane. The area under which the characterisation was carried out within the test plane is 110 cm x 129.5 cm. At the end of the steady state large area solar simulator characterisation, a class A spectral match, class A spatial uniformity, and a class B temporal instability was obtained
- Full Text:
- Date Issued: 2019
- Authors: Nwodo, Julian Chizoba
- Date: 2019
- Subjects: Solar energy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/14671 , vital:40042
- Description: The design and characterisation of a 5kW Xenon lamp solar simulator is presented. This was accomplished through considering the design features of an ellipsoidal reflector, Xe lamp characteristics and casing, and power supply; assembly of an ellipsoidal, Xe-lamp simulator; design and building of an automated control system capable of remotely controlling the operating mode of the simulator; establishing the 3 scenarios that must be met to conform to a AAA class simulator; characterization of the simulator in terms of temporal stability, irradiance uniformity and spectral match; and application of the simulator and comparing it with STC rated values. The considerations for the type of material used for housing the components of the solar simulator were made. A 5kW DC power supply and igniter for the Xe-lamp was carefully selected since they provide necessary power for running the simulator. The simulator has the ability to be used in either horizontal or vertical position by adjusting the reflector. An automated control system capable of remotely controlling the operating mode of the simulator was built for this study, this system enables the simulator to be operated in either auto or manual modes. It also incorporates an irradiance, temperature, current and voltage feedback. The characterisation of the solar simulator was over a 2.1 m X 1.6 m test plane. The area under which the characterisation was carried out within the test plane is 110 cm x 129.5 cm. At the end of the steady state large area solar simulator characterisation, a class A spectral match, class A spatial uniformity, and a class B temporal instability was obtained
- Full Text:
- Date Issued: 2019
Design and fabrication of components of dye sensitised solar cells
- Authors: Msane, Gugu
- Date: 2019
- Subjects: Dye-sensitized solar cells
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/117106 , vital:34478
- Description: In recent decades there has been increasing global concern about the sustainability of our use of fossil fuels, which has led to increased interest in carbon–free sustainable renewable sources such as solar energy. Dye sensitized solar cells (DSSCs) are a cheap and clean technology that harnesses solar energy efficiently and convert it to electrical energy. A DSSC consists of a transparent working electrode coated with a dye-sensitized mesoporous film of nanocrystalline particles of semiconductor e.g. TiO2, an electrolyte containing a suitable redox couple and a platinized counter electrode. All the components of the DSSCs play vital roles in controlling the performance of the cell. The synergy of these components of the cells also needs to be investigated to optimise their interaction and create efficient and stable DSSCs. The information gathered from this investigation can give insight on how to improve the efficiencies of DSSCs. In this research study the semiconductor, transparent conducting layer and sensitizer were designed, optimized one at a time and their effect on the overall efficiency of the DSSCs studied. In this way it was easy to observe the effect of the individual components on the efficiency of the DSSCs. The conventional DSSCs usually use TiO2 as a semiconductor. In this research TiO2 was doped with cerium (Ce) to enhance its optical properties by reducing the band gap. A series of Ce-doped TiO2 with Ce content ranging from 0.1 to 1 mol % were successfully synthesized by an acid catalyzed sol-gel method, and their performance as the photoanodes of dye-sensitized solar cells (DSSCs) was investigated. Ce doping resulted in a red shift in the absorption of the TiO2 indicating narrowing of the band gap. The band gap first narrowed with increase in concentration of dopant up until 0.9 % dopant concentration. After this optimum doping concentration the band gap widened again. DFT calculations showed that Ce doping introduces Ce4f impurity states located just below the conduction band resulting in band gap narrowing. Ce content (0.9%) doped TiO2 photoanodes improved the performance of DSSCs with a conversion efficiency of 2.11% compared to 0,21% for the one with a pure TiO2 under 1 sun, AM1.5. Graphitised/TiO2 nanocomposites were also used a semiconductor to slow down recombination of electrons and holes in the cells. Electrophoretic deposition (EPD) was used to deposit graphitised/TiO2 nanocomposites onto an FTO electrode for application as photoelectrode in dye-sensitized solar cells (DSSCs). An enhanced power conversion efficiency (PCE) of 2.25% was observed for the 0.5 wt% graphene oxide/TiO2 (GO/TiO2) based DSSC which was higher than that of the conversion efficiency of pure TiO2 nanoparticles (i.e. 0.52%). Graphene oxide led to high migration of photoinduced electrons to the conduction band of the collection electrode and inhibition of charge carriers recombination resulting in enhanced photoconversion efficiency. A GO content above 0.5 % resulted in a reduced transparency leading to a decrease in the PCE. 0.5 wt % GO/0.9 Ce–TiO2 Ce based DSSC showed a slightly enhanced efficiency of 2.45%. 0.5 rGO/TiO2 based DSSCs had a high efficiency than 0.5 rGO/TiO2 due to improved conductivity of rGO nanosheets and suppressed recombination of charge carriers. To cut down DSSC production costs a silver wire network transparent conducting polyethylene electrodes was fabricated and used as an indium tin oxide (ITO) alternative substrates in DSSCs. The transmittance of the AgNW network was 82 % which is comparable to ITO substrates. Titanium oxide (TiO2) films on the AgWN/PET substrates were obtained using the electrophoresis method. These substrates were sensitised and used to fabricate a dye sensitised solar cell. From the measured current–voltage or I-V characteristic under AM1.5 illumination of the formed DSSC using AgWN substrates, an open circuit voltage (VOC) of 0.377 V, a short circuit current (ISC) of 0.0067 mA and a fill factor (FF) 25.7 % with an efficiency of 0.00862 % were obtained from a cell of 0.075 cm2 working area. The stability of the cell improved when a room temperature ionic liquid electrolyte was used. Gold nanofiber transparent electrodes were also prepared by the electrospinning techniques and used as an alternative to indium tin oxides substrates. Transparent conducting gold nanofiber (AuNF) transparent conducting electrodes were fabricated by using a low–cost electrospinning process and used as photoelectrodes for DSSCs. TiO2 was deposited on these electrodes by using an electrospray method. DSSC using AuNF as transparent electrodes had a power efficiency of 0.52%, compared to devices made with FTO electrodes (1.48%). DSSCs. Versatile dyes with increased spectral response, stability and suppressed recombination of holes and electrons were synthesised and used as a sensitizers for DSSCs. The boron dipyrrin (BODIPY) chromophore was combined with a carboxy coumarin moiety to create donor–acceptor (dyad) system dyes. Regenerative dyad dyes were formed through covalently linking a porphyrin chromophore to a manganese(II) ion through bridging ligands. These chromophores and also porphyrin and BODIPY dyes were used as sensitisers for DSSCs. The regenerative dye based DSSCs showed a photoconversion efficiency of 4.09% which was higher than the efficiency of the parent porphyrin (2.57%). The enhanced efficiency was attributed to the manganese bypridine cluster in the ZnTPP–Mn bpy supramolecule which acted as an electron donor to the photo-oxidized porphyrin continuously regenerating the porphyrin and preventing its decay.
- Full Text:
- Date Issued: 2019
- Authors: Msane, Gugu
- Date: 2019
- Subjects: Dye-sensitized solar cells
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/117106 , vital:34478
- Description: In recent decades there has been increasing global concern about the sustainability of our use of fossil fuels, which has led to increased interest in carbon–free sustainable renewable sources such as solar energy. Dye sensitized solar cells (DSSCs) are a cheap and clean technology that harnesses solar energy efficiently and convert it to electrical energy. A DSSC consists of a transparent working electrode coated with a dye-sensitized mesoporous film of nanocrystalline particles of semiconductor e.g. TiO2, an electrolyte containing a suitable redox couple and a platinized counter electrode. All the components of the DSSCs play vital roles in controlling the performance of the cell. The synergy of these components of the cells also needs to be investigated to optimise their interaction and create efficient and stable DSSCs. The information gathered from this investigation can give insight on how to improve the efficiencies of DSSCs. In this research study the semiconductor, transparent conducting layer and sensitizer were designed, optimized one at a time and their effect on the overall efficiency of the DSSCs studied. In this way it was easy to observe the effect of the individual components on the efficiency of the DSSCs. The conventional DSSCs usually use TiO2 as a semiconductor. In this research TiO2 was doped with cerium (Ce) to enhance its optical properties by reducing the band gap. A series of Ce-doped TiO2 with Ce content ranging from 0.1 to 1 mol % were successfully synthesized by an acid catalyzed sol-gel method, and their performance as the photoanodes of dye-sensitized solar cells (DSSCs) was investigated. Ce doping resulted in a red shift in the absorption of the TiO2 indicating narrowing of the band gap. The band gap first narrowed with increase in concentration of dopant up until 0.9 % dopant concentration. After this optimum doping concentration the band gap widened again. DFT calculations showed that Ce doping introduces Ce4f impurity states located just below the conduction band resulting in band gap narrowing. Ce content (0.9%) doped TiO2 photoanodes improved the performance of DSSCs with a conversion efficiency of 2.11% compared to 0,21% for the one with a pure TiO2 under 1 sun, AM1.5. Graphitised/TiO2 nanocomposites were also used a semiconductor to slow down recombination of electrons and holes in the cells. Electrophoretic deposition (EPD) was used to deposit graphitised/TiO2 nanocomposites onto an FTO electrode for application as photoelectrode in dye-sensitized solar cells (DSSCs). An enhanced power conversion efficiency (PCE) of 2.25% was observed for the 0.5 wt% graphene oxide/TiO2 (GO/TiO2) based DSSC which was higher than that of the conversion efficiency of pure TiO2 nanoparticles (i.e. 0.52%). Graphene oxide led to high migration of photoinduced electrons to the conduction band of the collection electrode and inhibition of charge carriers recombination resulting in enhanced photoconversion efficiency. A GO content above 0.5 % resulted in a reduced transparency leading to a decrease in the PCE. 0.5 wt % GO/0.9 Ce–TiO2 Ce based DSSC showed a slightly enhanced efficiency of 2.45%. 0.5 rGO/TiO2 based DSSCs had a high efficiency than 0.5 rGO/TiO2 due to improved conductivity of rGO nanosheets and suppressed recombination of charge carriers. To cut down DSSC production costs a silver wire network transparent conducting polyethylene electrodes was fabricated and used as an indium tin oxide (ITO) alternative substrates in DSSCs. The transmittance of the AgNW network was 82 % which is comparable to ITO substrates. Titanium oxide (TiO2) films on the AgWN/PET substrates were obtained using the electrophoresis method. These substrates were sensitised and used to fabricate a dye sensitised solar cell. From the measured current–voltage or I-V characteristic under AM1.5 illumination of the formed DSSC using AgWN substrates, an open circuit voltage (VOC) of 0.377 V, a short circuit current (ISC) of 0.0067 mA and a fill factor (FF) 25.7 % with an efficiency of 0.00862 % were obtained from a cell of 0.075 cm2 working area. The stability of the cell improved when a room temperature ionic liquid electrolyte was used. Gold nanofiber transparent electrodes were also prepared by the electrospinning techniques and used as an alternative to indium tin oxides substrates. Transparent conducting gold nanofiber (AuNF) transparent conducting electrodes were fabricated by using a low–cost electrospinning process and used as photoelectrodes for DSSCs. TiO2 was deposited on these electrodes by using an electrospray method. DSSC using AuNF as transparent electrodes had a power efficiency of 0.52%, compared to devices made with FTO electrodes (1.48%). DSSCs. Versatile dyes with increased spectral response, stability and suppressed recombination of holes and electrons were synthesised and used as a sensitizers for DSSCs. The boron dipyrrin (BODIPY) chromophore was combined with a carboxy coumarin moiety to create donor–acceptor (dyad) system dyes. Regenerative dyad dyes were formed through covalently linking a porphyrin chromophore to a manganese(II) ion through bridging ligands. These chromophores and also porphyrin and BODIPY dyes were used as sensitisers for DSSCs. The regenerative dye based DSSCs showed a photoconversion efficiency of 4.09% which was higher than the efficiency of the parent porphyrin (2.57%). The enhanced efficiency was attributed to the manganese bypridine cluster in the ZnTPP–Mn bpy supramolecule which acted as an electron donor to the photo-oxidized porphyrin continuously regenerating the porphyrin and preventing its decay.
- Full Text:
- Date Issued: 2019
Design of metal ion-selective reagents for recovery of precious metals
- Authors: Moleko-Boyce, Pulleng
- Date: 2019
- Subjects: Bioinorganic chemistry , Metal complexes Speciation (Chemistry)
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/42510 , vital:36664
- Description: The study is divided into two sections; namely, (1) the design of rhodium(III) specific chelating ligands (tridentate bis-benzimidazole derivatives), and (2) the development of iridium(IV)-specific quaternary diammonium cations with electron donating and electron withdrawing groups. Bis-benzimidazole chelating ligands used were bis((1H-benzimidazol-2-yl)methyl)amine (NNN1), bis((1H-benzimidazol-2-yl)ethyl)amine (NNN2), bis((1H-benzimidazol-2-yl)methyl)sulfide (NSN1) and bis((1H-benzimidazol-2-yl)ethyl)sulfide (NSN2). Quaternary diammonium cations used were tetramethylbenzyl-1,10-diammonium chloride (QuatDMDAMeBnz), tetrabenzyl-1,10-diammonium chloride (QuatDMDABnz), tetratrifluoromethylbenzyl-1,10-diammonium chloride (QuatDMDACF3Bnz) and tetranitrobenzyl-1,10-diammonium chloride (QuatDMDANO2Bnz). For both studies, polyvinylbenzylchloride (PVBC) nanofibers were used as support material. The PVBC nanofibers which were functionalised with bis-benzimidazole derivatives and quaternary diammonium cations, respectively, were investigated for the selectivity for Rh(III) over Ir(III), Pt(II), Pd(II) and Ni(II), and for separation of Ir(IV) from Rh(III), respectively. The sorbent materials were characterised by FTIR, SEM, BET surface area, TGA, EDS and elemental analysis, and the results showed that the functionalization of the sorbent materials was successful.The efficiency of bis-benzimidazole derivatives and quaternary diammonium cations, respectively, were investigated in a column study under dynamic flow adsorption conditions. The adsorption kinetics and isotherms were investigated under batch conditions and fitted on pseudo-first-order and pseudo-second-order model, and Freundlich and Langmuir isotherm, respectively. It was observed that the bis-benzimidazole derivatives showed uptake of [RhCl3(H2O)3], and the loading capacities were observed in the following order; NSN1 (181.06 mg/g) > NSN2 (148.55 mg/g) > NNN1 (131.88 mg/g) > NNN2 (75.87 mg/g). The bis-benzimidazole derivatives preference for metal ions was further investigated with a multi-element solution containing Rh(III), Ir(III), Pt(II), Pd(II) and Ni(II). The bis-benzimidazole derivatives showed the following order of loading capacity: NSN1 (47.28 mg/g) > NSN2 (23.89 mg/g) > NNN1 (17.47 mg/g) > NNN2 (14.91 mg/g) for Rh(III); NSN2 (10.64 mg/g) > NNN2 (6.84 mg/g) > NSN1 (5.74 mg/g) > NNN1 (5.02 mg/g) for Ir(III); NNN2 (33.96 mg/g) > NSN1 (30.95 mg/g) > NSN2 (19.95 mg/g) > NNN1 (14.92 mg/g) for Pt(II); NNN1 (47.94 mg/g) > NNN2 (28.90 mg/g) > NSN1 (16.22 mg/g) > NSN2 (15.83 mg/g) for Pd(II). Bis-benzimidazole derivatives showed no uptake of nickel(II) under these conditions. It was observed the ligand-selectivity order for Rh(III) was similar in both single-element and multi-element studies. This order showed that the bis-benzimidazoles containing a sulfur atom showed a high preference for rhodium(III) compared to Pt(II) which had a high preference for NNN2 as well as Pd(II) which had a high preference for NNN1. Ir(III) generally had a lower preference for the ligands presumably due to its higher kinetic inertness compared with Rh(III). Column sorption of [IrCl6]2- and [RhCl5(H2O)]2- on nanofibers functionalized with diammonium cations was carried out and the loading capacities of [IrCl6]2- were obtained. [RhCl5(H2O)]2- was not adsorbed by the sorbent materials while [IrCl6]2- was loaded onto the column. The loading capacities of [IrCl6]2- with the quaternary diammonium sorbent materials increased in the order of F-QuatDMDAMeBnz (60.29 mg/g) < F-QuatDMDABnz (67.61 mg/g) < F-QuatDMDACF3Bnz (107.59 mg/g) < F-QuatDMDANO2Bnz (140.47 mg/g). The loading capacity for Ir(IV) with quaternary diammonium cationic nanofibers increased with an increase in the electron-withdrawing nature of the quaternizing group. The charge delocalizing ability of the nitrobenzyl group resulted in the best interaction of the diammonium cation with [IrCl6]2-. Batch equilibrium studies were carried out to assess the efficiency of bis-benzimidazole chelating derivatives as adsorbents using a multi-metal solution (Rh(III), Ir(III), Pt(II), Pd(II) and Ni(II)) in 0.5 M HCl. The efficiency of the quaternary diammonium cations was tested using a binary metal solution (Ir(IV) and Rh(III)) in 6 M HCl. The isothermal batch adsorption studies of a multi-metal solution with bis-benzimidazoles derivatives fitted the Langmuir isotherm model which confirmed monolayer adsorption onto a homogeneous surface. The Langmuir isotherm parameter (qe (mg/g)), using functionalized nanofibers, showed the order of NNN2 (128.21 mg/g) > NSN1 (99.01 mg/g) > NSN2 (91.74 mg/g) > NNN1 (84.03 mg/g) for Pt(II); NNN1 (66.23 mg/g) > NNN2 (5.89 mg/g) > NSN1 (1.40 mg/g) > NSN2 (0.59 mg/g) for Pd(II); NSN2 (10.64 mg/g) > NNN2 (6.84 mg/g) > NSN1 (5.74 mg/g) > NNN1 (5.02 mg/g) for Ir(III); NSN1 (140.85 mg/g) > NSN2 (109.89 mg/g) > NNN1 (104.17 mg/g) > NNN2 (91.74 mg/g) for Rh(III). The pseudo-first-order kinetics model was found to be the best fit to describe the adsorption kinetics of all metal ions onto all the sorbent materials. K1 (min-1) value in pseudo-first-order kinetics showed the same order of adsorption as observed in the Langmuir isotherms. The isothermal batch adsorption studies of [IrCl6]2- and [RhCl5(H2O)]2- with quaternary diammonium cations fitted the Freundlich isotherm model and confirmed to be effective for multiple-layered adsorption onto a heterogeneous surface. The Freundlich isotherm parameter (kf (mg/g)) using functionalized quaternary diammonium cationic nanofibers increased in the order of F-QuatDMDANO2Bnz (794.33 mg/g) > F-QuatDMDACF3Bnz (185.35 mg/g) > F-QuatDMDABnz (156.32 mg/g) > F-QuatDMDAMeBnz (112.46 mg/g) for Ir(IV) uptake. F-QuatDMDANO2Bnz resin showed the highest adsorption than that of F-QuatDMDAMeBnz, F-QuatDMDABnz and F-QuatDMDACF3Bnz and this order is similar to what was observed in column studies. The quaternary diammonium cations were shown to have the highest adsorption capacity for Ir(IV) compared with Rh(III). The adsorption of Rh(III) was also observed to increase in the order of F-QuatDMDANO2Bnz (177.83 mg/g) > F-QuatDMDACF3Bnz (40.37 mg/g) > F-QuatDMDABnz (36.98 mg/g) > F-QuatDMDAMeBnz (12.71 mg/g). The pseudo-second-order kinetic model was found to be the best fit to describe the adsorption kinetics of both metal ions onto all the sorbent materials. K2 (g.mg-1min-1) value in pseudo-second-order kinetics showed the same order of adsorption as observed in the Freundlich isotherms. The adsorption studies showed adsorption takes place via chemisorption process. This thesis presents PGMs and iridium-specific materials that could be applied in solutions of secondary PGMs sources containing rhodium, platinum and palladium with bis-benzimidazoles as well as in feed solutions from ore processing with diammonium cations for iridium recovery.
- Full Text:
- Date Issued: 2019
- Authors: Moleko-Boyce, Pulleng
- Date: 2019
- Subjects: Bioinorganic chemistry , Metal complexes Speciation (Chemistry)
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/42510 , vital:36664
- Description: The study is divided into two sections; namely, (1) the design of rhodium(III) specific chelating ligands (tridentate bis-benzimidazole derivatives), and (2) the development of iridium(IV)-specific quaternary diammonium cations with electron donating and electron withdrawing groups. Bis-benzimidazole chelating ligands used were bis((1H-benzimidazol-2-yl)methyl)amine (NNN1), bis((1H-benzimidazol-2-yl)ethyl)amine (NNN2), bis((1H-benzimidazol-2-yl)methyl)sulfide (NSN1) and bis((1H-benzimidazol-2-yl)ethyl)sulfide (NSN2). Quaternary diammonium cations used were tetramethylbenzyl-1,10-diammonium chloride (QuatDMDAMeBnz), tetrabenzyl-1,10-diammonium chloride (QuatDMDABnz), tetratrifluoromethylbenzyl-1,10-diammonium chloride (QuatDMDACF3Bnz) and tetranitrobenzyl-1,10-diammonium chloride (QuatDMDANO2Bnz). For both studies, polyvinylbenzylchloride (PVBC) nanofibers were used as support material. The PVBC nanofibers which were functionalised with bis-benzimidazole derivatives and quaternary diammonium cations, respectively, were investigated for the selectivity for Rh(III) over Ir(III), Pt(II), Pd(II) and Ni(II), and for separation of Ir(IV) from Rh(III), respectively. The sorbent materials were characterised by FTIR, SEM, BET surface area, TGA, EDS and elemental analysis, and the results showed that the functionalization of the sorbent materials was successful.The efficiency of bis-benzimidazole derivatives and quaternary diammonium cations, respectively, were investigated in a column study under dynamic flow adsorption conditions. The adsorption kinetics and isotherms were investigated under batch conditions and fitted on pseudo-first-order and pseudo-second-order model, and Freundlich and Langmuir isotherm, respectively. It was observed that the bis-benzimidazole derivatives showed uptake of [RhCl3(H2O)3], and the loading capacities were observed in the following order; NSN1 (181.06 mg/g) > NSN2 (148.55 mg/g) > NNN1 (131.88 mg/g) > NNN2 (75.87 mg/g). The bis-benzimidazole derivatives preference for metal ions was further investigated with a multi-element solution containing Rh(III), Ir(III), Pt(II), Pd(II) and Ni(II). The bis-benzimidazole derivatives showed the following order of loading capacity: NSN1 (47.28 mg/g) > NSN2 (23.89 mg/g) > NNN1 (17.47 mg/g) > NNN2 (14.91 mg/g) for Rh(III); NSN2 (10.64 mg/g) > NNN2 (6.84 mg/g) > NSN1 (5.74 mg/g) > NNN1 (5.02 mg/g) for Ir(III); NNN2 (33.96 mg/g) > NSN1 (30.95 mg/g) > NSN2 (19.95 mg/g) > NNN1 (14.92 mg/g) for Pt(II); NNN1 (47.94 mg/g) > NNN2 (28.90 mg/g) > NSN1 (16.22 mg/g) > NSN2 (15.83 mg/g) for Pd(II). Bis-benzimidazole derivatives showed no uptake of nickel(II) under these conditions. It was observed the ligand-selectivity order for Rh(III) was similar in both single-element and multi-element studies. This order showed that the bis-benzimidazoles containing a sulfur atom showed a high preference for rhodium(III) compared to Pt(II) which had a high preference for NNN2 as well as Pd(II) which had a high preference for NNN1. Ir(III) generally had a lower preference for the ligands presumably due to its higher kinetic inertness compared with Rh(III). Column sorption of [IrCl6]2- and [RhCl5(H2O)]2- on nanofibers functionalized with diammonium cations was carried out and the loading capacities of [IrCl6]2- were obtained. [RhCl5(H2O)]2- was not adsorbed by the sorbent materials while [IrCl6]2- was loaded onto the column. The loading capacities of [IrCl6]2- with the quaternary diammonium sorbent materials increased in the order of F-QuatDMDAMeBnz (60.29 mg/g) < F-QuatDMDABnz (67.61 mg/g) < F-QuatDMDACF3Bnz (107.59 mg/g) < F-QuatDMDANO2Bnz (140.47 mg/g). The loading capacity for Ir(IV) with quaternary diammonium cationic nanofibers increased with an increase in the electron-withdrawing nature of the quaternizing group. The charge delocalizing ability of the nitrobenzyl group resulted in the best interaction of the diammonium cation with [IrCl6]2-. Batch equilibrium studies were carried out to assess the efficiency of bis-benzimidazole chelating derivatives as adsorbents using a multi-metal solution (Rh(III), Ir(III), Pt(II), Pd(II) and Ni(II)) in 0.5 M HCl. The efficiency of the quaternary diammonium cations was tested using a binary metal solution (Ir(IV) and Rh(III)) in 6 M HCl. The isothermal batch adsorption studies of a multi-metal solution with bis-benzimidazoles derivatives fitted the Langmuir isotherm model which confirmed monolayer adsorption onto a homogeneous surface. The Langmuir isotherm parameter (qe (mg/g)), using functionalized nanofibers, showed the order of NNN2 (128.21 mg/g) > NSN1 (99.01 mg/g) > NSN2 (91.74 mg/g) > NNN1 (84.03 mg/g) for Pt(II); NNN1 (66.23 mg/g) > NNN2 (5.89 mg/g) > NSN1 (1.40 mg/g) > NSN2 (0.59 mg/g) for Pd(II); NSN2 (10.64 mg/g) > NNN2 (6.84 mg/g) > NSN1 (5.74 mg/g) > NNN1 (5.02 mg/g) for Ir(III); NSN1 (140.85 mg/g) > NSN2 (109.89 mg/g) > NNN1 (104.17 mg/g) > NNN2 (91.74 mg/g) for Rh(III). The pseudo-first-order kinetics model was found to be the best fit to describe the adsorption kinetics of all metal ions onto all the sorbent materials. K1 (min-1) value in pseudo-first-order kinetics showed the same order of adsorption as observed in the Langmuir isotherms. The isothermal batch adsorption studies of [IrCl6]2- and [RhCl5(H2O)]2- with quaternary diammonium cations fitted the Freundlich isotherm model and confirmed to be effective for multiple-layered adsorption onto a heterogeneous surface. The Freundlich isotherm parameter (kf (mg/g)) using functionalized quaternary diammonium cationic nanofibers increased in the order of F-QuatDMDANO2Bnz (794.33 mg/g) > F-QuatDMDACF3Bnz (185.35 mg/g) > F-QuatDMDABnz (156.32 mg/g) > F-QuatDMDAMeBnz (112.46 mg/g) for Ir(IV) uptake. F-QuatDMDANO2Bnz resin showed the highest adsorption than that of F-QuatDMDAMeBnz, F-QuatDMDABnz and F-QuatDMDACF3Bnz and this order is similar to what was observed in column studies. The quaternary diammonium cations were shown to have the highest adsorption capacity for Ir(IV) compared with Rh(III). The adsorption of Rh(III) was also observed to increase in the order of F-QuatDMDANO2Bnz (177.83 mg/g) > F-QuatDMDACF3Bnz (40.37 mg/g) > F-QuatDMDABnz (36.98 mg/g) > F-QuatDMDAMeBnz (12.71 mg/g). The pseudo-second-order kinetic model was found to be the best fit to describe the adsorption kinetics of both metal ions onto all the sorbent materials. K2 (g.mg-1min-1) value in pseudo-second-order kinetics showed the same order of adsorption as observed in the Freundlich isotherms. The adsorption studies showed adsorption takes place via chemisorption process. This thesis presents PGMs and iridium-specific materials that could be applied in solutions of secondary PGMs sources containing rhodium, platinum and palladium with bis-benzimidazoles as well as in feed solutions from ore processing with diammonium cations for iridium recovery.
- Full Text:
- Date Issued: 2019
Determinants of a competitive bunkering service: a South African model
- Authors: Mdlalose, Silindile
- Date: 2019
- Subjects: Ships -- Fuel -- South Africa , Oil transfer operations -- South Africa Coastal water transportation -- Economic aspects -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/41471 , vital:36487
- Description: South Africa is one of the best strategically positioned countries in the world in terms of trade routes from the west to the east. According to the Operation Phakisa research team, about 13 000 vessels visit South African ports annually and nearly 30 000 vessels sail along the South African coast yearly. Yet, less than ten percent of visiting vessels replenish bunkers in the country. This is a lost business opportunity for the South African bunker industry. South Africa has struggled to attract and maintain bunker business for some time. The aim of this study is to establish what the determinants of a competitive bunker industry are. A positivism philosophy is adopted to conduct the study. Using information gathered through a literature review, a conceptualised model for a competitive bunker industry is formulated. The model claims that there is a positive relationship between bunker industry competitiveness and eight independent variables identified in literature. The eight independent variables identified are (i) Bunker Fuel, (ii) Location, (iii) Port Accessibility, (iv) Rules and Regulations, (v) Service, (vi) Infrastructure, (vii) Cost of Service and (viii) Human Capital. A survey is conducted using a questionnaire. The questionnaire was generated specifically to collect primary data. There are 104 usable responses received back from the survey. The response data are used for quantitative data analysis. Quantitative data analysis methods like the EFA, Cronbach’s alpha, one sample t-test and Pearson Moment Correlations’ analysis are employed to test the conceptualised model. Findings show that independent variables (i) Service, (ii) Infrastructure, (iii) Port Accessibility, (iv) Location and (v) Bunker Industry Competitiveness (the independent variable) are contributors to bunker industry competitiveness (dependent variable). The results indicate that to achieve bunker industry competitiveness, the best approach will be to employ a collective approach that will simultaneously consider all of the literature-identified variables. All of the variables will have to be considered and aligned when the strategy for a competitive bunker industry is created.
- Full Text:
- Date Issued: 2019
- Authors: Mdlalose, Silindile
- Date: 2019
- Subjects: Ships -- Fuel -- South Africa , Oil transfer operations -- South Africa Coastal water transportation -- Economic aspects -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/41471 , vital:36487
- Description: South Africa is one of the best strategically positioned countries in the world in terms of trade routes from the west to the east. According to the Operation Phakisa research team, about 13 000 vessels visit South African ports annually and nearly 30 000 vessels sail along the South African coast yearly. Yet, less than ten percent of visiting vessels replenish bunkers in the country. This is a lost business opportunity for the South African bunker industry. South Africa has struggled to attract and maintain bunker business for some time. The aim of this study is to establish what the determinants of a competitive bunker industry are. A positivism philosophy is adopted to conduct the study. Using information gathered through a literature review, a conceptualised model for a competitive bunker industry is formulated. The model claims that there is a positive relationship between bunker industry competitiveness and eight independent variables identified in literature. The eight independent variables identified are (i) Bunker Fuel, (ii) Location, (iii) Port Accessibility, (iv) Rules and Regulations, (v) Service, (vi) Infrastructure, (vii) Cost of Service and (viii) Human Capital. A survey is conducted using a questionnaire. The questionnaire was generated specifically to collect primary data. There are 104 usable responses received back from the survey. The response data are used for quantitative data analysis. Quantitative data analysis methods like the EFA, Cronbach’s alpha, one sample t-test and Pearson Moment Correlations’ analysis are employed to test the conceptualised model. Findings show that independent variables (i) Service, (ii) Infrastructure, (iii) Port Accessibility, (iv) Location and (v) Bunker Industry Competitiveness (the independent variable) are contributors to bunker industry competitiveness (dependent variable). The results indicate that to achieve bunker industry competitiveness, the best approach will be to employ a collective approach that will simultaneously consider all of the literature-identified variables. All of the variables will have to be considered and aligned when the strategy for a competitive bunker industry is created.
- Full Text:
- Date Issued: 2019
Determinants of consumerisation of information technology and its effect on employee performance
- Authors: Khayundi, Hilda
- Date: 2019
- Subjects: Information technology -- Economic aspect Organizational effectiveness
- Language: English
- Type: Thesis , Masters , MCom (Business Management)
- Identifier: http://hdl.handle.net/10353/16906 , vital:40784
- Description: The ubiquitous nature of personally technological advanced devices and applications has engendered various predictions for the current employee at the workplace. With the introduction and adoption of mobile phones, tablets, laptops and even software, organisations are gradually allowing employees to utilise their personal mobile devices at the office to accomplish their tasks. This has led to the term Consumerisation of Information Technology (CIT) or IT consumerisation. The purpose of this study was to investigate the determinants of consumerisation of IT and its effect on job performance of staff at an institution of higher learning. This study used a theoretical framework - The Unified Theory of Acceptance and Usage of Technology – to find out if indeed consumerisation of IT has an effect on job performance. An online questionnaire was sent to the university’s staff email and a total of 230 responses were recorded. The study used a quantitative research approach. The Statistical Package for Social Sciences (SPSS) software was used for data analysis to test the hypotheses. Tests such as the multiple linear regression, factor analysis, correlations, ANOVA and t-tests were used to test the hypotheses. The findings of the study showed that there is a relationship between the determinants of consumerisation of IT and their effect on job performance at the workplace. These determinants are performance expectancy, social influence and facilitating conditions. Effort expectancy was the only factor that did not have an effect on consumerisation of IT. As such the study suggested that institutions and organisations to take note of the technological development of devices that can help employees improve their productivity. However, this should be treated with caution as there are also negative effects such as technostress and cyberloafing which may be associated with the advent of consumerisation of IT, therefore it should be a gradual process in order to see the benefits.
- Full Text:
- Date Issued: 2019
- Authors: Khayundi, Hilda
- Date: 2019
- Subjects: Information technology -- Economic aspect Organizational effectiveness
- Language: English
- Type: Thesis , Masters , MCom (Business Management)
- Identifier: http://hdl.handle.net/10353/16906 , vital:40784
- Description: The ubiquitous nature of personally technological advanced devices and applications has engendered various predictions for the current employee at the workplace. With the introduction and adoption of mobile phones, tablets, laptops and even software, organisations are gradually allowing employees to utilise their personal mobile devices at the office to accomplish their tasks. This has led to the term Consumerisation of Information Technology (CIT) or IT consumerisation. The purpose of this study was to investigate the determinants of consumerisation of IT and its effect on job performance of staff at an institution of higher learning. This study used a theoretical framework - The Unified Theory of Acceptance and Usage of Technology – to find out if indeed consumerisation of IT has an effect on job performance. An online questionnaire was sent to the university’s staff email and a total of 230 responses were recorded. The study used a quantitative research approach. The Statistical Package for Social Sciences (SPSS) software was used for data analysis to test the hypotheses. Tests such as the multiple linear regression, factor analysis, correlations, ANOVA and t-tests were used to test the hypotheses. The findings of the study showed that there is a relationship between the determinants of consumerisation of IT and their effect on job performance at the workplace. These determinants are performance expectancy, social influence and facilitating conditions. Effort expectancy was the only factor that did not have an effect on consumerisation of IT. As such the study suggested that institutions and organisations to take note of the technological development of devices that can help employees improve their productivity. However, this should be treated with caution as there are also negative effects such as technostress and cyberloafing which may be associated with the advent of consumerisation of IT, therefore it should be a gradual process in order to see the benefits.
- Full Text:
- Date Issued: 2019
Determination of social, environmental and economic benefits for community participation in forestry in Mpumalanga, South Africa
- Long, Leo Searle, Chirwa, Paxie
- Authors: Long, Leo Searle , Chirwa, Paxie
- Date: 2019
- Subjects: Forests and forestry -- South Africa -- Mpumalanga
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/34339 , vital:33307
- Description: Rural communities living adjacent to commercial forestry operations are often affected by numerous negative social issues such as poverty, unemployment, poor healthcare, and limited infrastructure, amongst others. In excess of 61% of forestry land managed by the state owned SAFCOL SOC Ltd is under land claim, as part of the Restitution of Land Rights Act (Act 22 of 1994). It is therefore necessary for forest companies to seek active means of engaging and partnering with these communities through a participatory forest management (PFM) approach. This study explored the sustainable (social, environmental and economic), benefits of such an approach as perceived (experienced) by these local rural communities, and specifically land claimants. The study was conducted in communities adjacent to SAFCOL plantations in the Mpumalanga Province of South Africa. Data were collected between May and June 2017 by means of a structured questionnaire. Surveys were conducted on 46 households within the identified communities so as to verify and evaluate perceived benefits in terms of forest products, ecosystem services and amenities/services/infrastructure provided by SAFCOL and the broader forest industry. The results indicated that these communities recognize and obtain numerous social, environmental and economic benefits from the forest including Non-Timber Forest Products (NTFPs) such as firewood; forest provisioning ecosystem services (FPESs) such as improved water quality; and more metaphysical benefits such as access to gravesites and the protection of traditions and customs. These benefits have the ability to improve the social well-being, economic independence, and the quality of environmental services obtained by the associated communities. It was however found that the utilization of these benefits was widely differentiated according to gender and land claimant status. Whilst males and females largely benefitted equally, there was a distinct benefit preference between genders for different NTFPs. For example males showed preference for the collection of building material, bush meat and for livestock husbandry, whilst females showed preference for the collection of firewood, medicinal plants and fruit, amongst others. Similarly, it was found that overall, non-land claimants benefited more than land claimants. Reasons for this are primarily due to the increased distance with which the land claimants live from the forest resource when compared to non-land claimants. The empirical value of the data produced through this study will be invaluable in negotiations with the land claimant communities on land settlement agreements, joint venture proposals, including Participatory Forest Management, and future land tenure. Through such inclusivity and vested interest in the sustainable management of the forests, corporate risk is reduced and community/land claimant relationships are reinforced. Such Participatory Forest Management arrangements are key to ensuring the longevity and resilience to the forest sector post-transfer of claimed land.
- Full Text:
- Date Issued: 2019
- Authors: Long, Leo Searle , Chirwa, Paxie
- Date: 2019
- Subjects: Forests and forestry -- South Africa -- Mpumalanga
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/34339 , vital:33307
- Description: Rural communities living adjacent to commercial forestry operations are often affected by numerous negative social issues such as poverty, unemployment, poor healthcare, and limited infrastructure, amongst others. In excess of 61% of forestry land managed by the state owned SAFCOL SOC Ltd is under land claim, as part of the Restitution of Land Rights Act (Act 22 of 1994). It is therefore necessary for forest companies to seek active means of engaging and partnering with these communities through a participatory forest management (PFM) approach. This study explored the sustainable (social, environmental and economic), benefits of such an approach as perceived (experienced) by these local rural communities, and specifically land claimants. The study was conducted in communities adjacent to SAFCOL plantations in the Mpumalanga Province of South Africa. Data were collected between May and June 2017 by means of a structured questionnaire. Surveys were conducted on 46 households within the identified communities so as to verify and evaluate perceived benefits in terms of forest products, ecosystem services and amenities/services/infrastructure provided by SAFCOL and the broader forest industry. The results indicated that these communities recognize and obtain numerous social, environmental and economic benefits from the forest including Non-Timber Forest Products (NTFPs) such as firewood; forest provisioning ecosystem services (FPESs) such as improved water quality; and more metaphysical benefits such as access to gravesites and the protection of traditions and customs. These benefits have the ability to improve the social well-being, economic independence, and the quality of environmental services obtained by the associated communities. It was however found that the utilization of these benefits was widely differentiated according to gender and land claimant status. Whilst males and females largely benefitted equally, there was a distinct benefit preference between genders for different NTFPs. For example males showed preference for the collection of building material, bush meat and for livestock husbandry, whilst females showed preference for the collection of firewood, medicinal plants and fruit, amongst others. Similarly, it was found that overall, non-land claimants benefited more than land claimants. Reasons for this are primarily due to the increased distance with which the land claimants live from the forest resource when compared to non-land claimants. The empirical value of the data produced through this study will be invaluable in negotiations with the land claimant communities on land settlement agreements, joint venture proposals, including Participatory Forest Management, and future land tenure. Through such inclusivity and vested interest in the sustainable management of the forests, corporate risk is reduced and community/land claimant relationships are reinforced. Such Participatory Forest Management arrangements are key to ensuring the longevity and resilience to the forest sector post-transfer of claimed land.
- Full Text:
- Date Issued: 2019
Determining the effects of debt-to-GDP ratio on the economic growth of Greece, Italy and South Africa
- Mowoe, Merioboroghene Oreoluwa
- Authors: Mowoe, Merioboroghene Oreoluwa
- Date: 2019
- Subjects: Debts, Public -- Greece , Debts, Public -- Italy Debts, Public -- South Africa Economic development Greece -- Economic conditions Italy -- Economic conditions South Africa -- Economic conditions
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10948/41942 , vital:36611
- Description: A major challenge that most countries currently face, is to bring their economies out of indebtedness. In this study, the impact of public debt on the economic growth of Greece, Italy, and South Africa, and any similarities between them, was analysed. Two models were adopted for this purpose, the ARDL model and the VEC model. The ARDL was used to conduct a co-integration relationship between public debts, economic growth, with four controlled variables: inflation, government spending, net export, and investment. The results showed a negative co-integrating relationship for all three countries. In addition, the VEC model was adopted to determine whether there was causation between public debt and economic growth in each of the three countries. It was found that a unidirectional causality between public debt and economic growth exists for all three countries. For Greece, a long-run causality was found moving from economic growth to public debt. For Italy, short-run and long-run causalities were found, moving from economic growth to public debt. For South Africa, both a long-run and a short-run causality were found moving from public debt to economic growth. The economic growth and development policies for reducing the public debt of these countries, are recommended in accordance with the findings of the research results.
- Full Text:
- Date Issued: 2019
- Authors: Mowoe, Merioboroghene Oreoluwa
- Date: 2019
- Subjects: Debts, Public -- Greece , Debts, Public -- Italy Debts, Public -- South Africa Economic development Greece -- Economic conditions Italy -- Economic conditions South Africa -- Economic conditions
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10948/41942 , vital:36611
- Description: A major challenge that most countries currently face, is to bring their economies out of indebtedness. In this study, the impact of public debt on the economic growth of Greece, Italy, and South Africa, and any similarities between them, was analysed. Two models were adopted for this purpose, the ARDL model and the VEC model. The ARDL was used to conduct a co-integration relationship between public debts, economic growth, with four controlled variables: inflation, government spending, net export, and investment. The results showed a negative co-integrating relationship for all three countries. In addition, the VEC model was adopted to determine whether there was causation between public debt and economic growth in each of the three countries. It was found that a unidirectional causality between public debt and economic growth exists for all three countries. For Greece, a long-run causality was found moving from economic growth to public debt. For Italy, short-run and long-run causalities were found, moving from economic growth to public debt. For South Africa, both a long-run and a short-run causality were found moving from public debt to economic growth. The economic growth and development policies for reducing the public debt of these countries, are recommended in accordance with the findings of the research results.
- Full Text:
- Date Issued: 2019
Determining the hydrological functioning of the palmiet wetlands in the Eastern and Western Cape South Africa
- Authors: Smith, Caitlin
- Date: 2019
- Subjects: Wetlands -- South Africa -- Eastern Cape , Wetland ecology -- South Africa -- Eastern Cape , Wetland management -- South Africa -- Eastern Cape , Prioniaceae -- South Africa -- Eastern Cape , Prionium serratum -- South Africa -- Eastern Cape
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/95956 , vital:31218
- Description: Wetlands provide a range of supporting, regulating and provisioning ecosystem services, including hydrological benefits such as flood attenuation and sustaining base flows. Despite their value, wetlands are one of the most vulnerable ecosystems in South Africa. Palmiet wetlands in the Eastern and Western Cape are particularly threatened. Palmiet (Prionium serratum) is a robust perennial plant that is endemic to wetlands and rivers located in the sandstones and quartzites of the Table Mountain Group (TMG), in the Eastern and Western Cape as well as the Natal Group sandstones in KwaZulu-Natal. Palmiet is described as an ecosystem engineer because of its ability to alter its environment and create large valley-bottom wetlands. The Krom River is an important water source for the city of Port Elizabeth and there has been a decline in palmiet wetlands along the Krom River as a result of alien vegetation invasion, agricultural activity, and gully erosion. Working for Water has been clearing alien vegetation and Working for Wetlands has been installing rehabilitation structures in the Krom River catchment for a number of years. There are, however, serious knowledge gaps in the understanding of palmiet wetland structure and function, particularly in respect of the hydrological functioning of these wetland systems. The aim of this study was to investigate the hydrology (surface and groundwater) behind these wetland systems. The investigation focussed on small-scale dynamics of the palmiet wetland system in order to increase general understanding of the surface water and groundwater processes of these wetland systems. Field work was concentrated on the Kompanjiesdrif and Krugersland palmiet wetlands in the upper K90A Krom River catchment. The investigation involved the installation of piezometers, water quality and stable isotope sampling and analysis, an Electrical Resistivity Tomography survey, and hydrological and mixing cell modelling. The results of the investigation indicate that the hydrological functioning of palmiet wetlands is closely linked with high sub-surface discharges typically associated with TMG aquifers. It is proposed that the palmiet wetlands are sustained by significant amounts of sub-surface water (both groundwater and interflow) moving through preferential flow paths in the alluvial fans and tributaries, which are in turn sustained by groundwater discharge from the surrounding sandstones and quartzites of the Nardouw Sub-group and Peninsula Formation. The palmiet wetlands clearly retain a significant amount of water, leading to the maintenance of prolonged flows, and a larger baseflow. However, it is hypothesised that the occurrence of palmiet as the dominant species in these wetlands is due to the sustained low flows related to catchment geology and high hydrological connectivity between the catchment and the wetland that is enabled by flow paths that allow the free flow of water from the catchment to the wetland. It is further proposed that palmiet is possibly more reliant on a consistent water supply for its existence and survival than it is on acidic nutrient-poor water and soils as stated by other authors.
- Full Text:
- Date Issued: 2019
- Authors: Smith, Caitlin
- Date: 2019
- Subjects: Wetlands -- South Africa -- Eastern Cape , Wetland ecology -- South Africa -- Eastern Cape , Wetland management -- South Africa -- Eastern Cape , Prioniaceae -- South Africa -- Eastern Cape , Prionium serratum -- South Africa -- Eastern Cape
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/95956 , vital:31218
- Description: Wetlands provide a range of supporting, regulating and provisioning ecosystem services, including hydrological benefits such as flood attenuation and sustaining base flows. Despite their value, wetlands are one of the most vulnerable ecosystems in South Africa. Palmiet wetlands in the Eastern and Western Cape are particularly threatened. Palmiet (Prionium serratum) is a robust perennial plant that is endemic to wetlands and rivers located in the sandstones and quartzites of the Table Mountain Group (TMG), in the Eastern and Western Cape as well as the Natal Group sandstones in KwaZulu-Natal. Palmiet is described as an ecosystem engineer because of its ability to alter its environment and create large valley-bottom wetlands. The Krom River is an important water source for the city of Port Elizabeth and there has been a decline in palmiet wetlands along the Krom River as a result of alien vegetation invasion, agricultural activity, and gully erosion. Working for Water has been clearing alien vegetation and Working for Wetlands has been installing rehabilitation structures in the Krom River catchment for a number of years. There are, however, serious knowledge gaps in the understanding of palmiet wetland structure and function, particularly in respect of the hydrological functioning of these wetland systems. The aim of this study was to investigate the hydrology (surface and groundwater) behind these wetland systems. The investigation focussed on small-scale dynamics of the palmiet wetland system in order to increase general understanding of the surface water and groundwater processes of these wetland systems. Field work was concentrated on the Kompanjiesdrif and Krugersland palmiet wetlands in the upper K90A Krom River catchment. The investigation involved the installation of piezometers, water quality and stable isotope sampling and analysis, an Electrical Resistivity Tomography survey, and hydrological and mixing cell modelling. The results of the investigation indicate that the hydrological functioning of palmiet wetlands is closely linked with high sub-surface discharges typically associated with TMG aquifers. It is proposed that the palmiet wetlands are sustained by significant amounts of sub-surface water (both groundwater and interflow) moving through preferential flow paths in the alluvial fans and tributaries, which are in turn sustained by groundwater discharge from the surrounding sandstones and quartzites of the Nardouw Sub-group and Peninsula Formation. The palmiet wetlands clearly retain a significant amount of water, leading to the maintenance of prolonged flows, and a larger baseflow. However, it is hypothesised that the occurrence of palmiet as the dominant species in these wetlands is due to the sustained low flows related to catchment geology and high hydrological connectivity between the catchment and the wetland that is enabled by flow paths that allow the free flow of water from the catchment to the wetland. It is further proposed that palmiet is possibly more reliant on a consistent water supply for its existence and survival than it is on acidic nutrient-poor water and soils as stated by other authors.
- Full Text:
- Date Issued: 2019
Developing ocean particle tracking tools for cross-disciplinary oceanic research with applications in the Agulhas current region
- Hart-Davis, Michael Geofrey, Backeberg, Björn C
- Authors: Hart-Davis, Michael Geofrey , Backeberg, Björn C
- Date: 2019
- Subjects: Ocean currents , Ocean currents -- Measurement Oceanography Oceanography -- Research -- South Atlantic Ocean
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/42308 , vital:36644
- Description: Lagrangian ocean analysis is a powerful way to study ocean processes from in-situ observations and numerical model simulations. As numerical modelling capabilities develop and physical mechanisms of the ocean are better understood, the importance of particle trajectory modelling continues to increase. Therefore, developing cross-disciplinary particle trajectory model applications for the Greater Agulhas System is highly relevant due to its potential contribution to scientific studies and operational applications. This thesis presents the results of developing particle trajectory model applications in the Greater Agulhas System towards better understanding the physical mechanisms that drive ocean processes in the region. The model is used in three applications that demonstrate their cross-disciplinary potential. These applications include a search and rescue scenario, the study of ocean dynamics and the study of the fate of juvenile turtles. Introducing spatially and temporally varying stochastic motion to account for the processes not resolved in the ocean surface current products, as well as including more appropriate boundary conditions, were shown to improve the accuracy of virtual drifters in representing the trajectory of a real surface drifter. Next, implementing the spatially and temporally varying stochastic motion in the particle trajectory model and applying it to a search and rescue scenario of a capsized catamaran revealed that including both winds and surface ocean currents in the particle trajectory model allowed for an improved prediction of the capsized vessel’s trajectory. By comparing a pair of real surface drifters with the particle trajectory model and analysing high resolution sea surface temperature (SST) fields it was shown that the formation of an eddy on the Agulhas Plateau combined with the weakening of the core current velocity resulted in enhanced eddycurrent interactions facilitating the separation of the real surface drifter-pair as they passed through this region. Lastly, the particle trajectory model was used to study the importance of including active swimming characteristic when studying the fate of juvenile turtles. It was found that including active swimming resulted in a change in the distribution of juvenile turtles and, therefore, needs to be included to provide a proper understanding of the fate of juvenile turtles in the ocean. With further development and refinement of the particle trajectory model, Lagrangian ocean analysis has the potential to provide valuable information towards improving our understanding of physical and biological ocean processes at a range of spatial and temporal scales with potential operational oceanography applications.
- Full Text:
- Date Issued: 2019
- Authors: Hart-Davis, Michael Geofrey , Backeberg, Björn C
- Date: 2019
- Subjects: Ocean currents , Ocean currents -- Measurement Oceanography Oceanography -- Research -- South Atlantic Ocean
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/42308 , vital:36644
- Description: Lagrangian ocean analysis is a powerful way to study ocean processes from in-situ observations and numerical model simulations. As numerical modelling capabilities develop and physical mechanisms of the ocean are better understood, the importance of particle trajectory modelling continues to increase. Therefore, developing cross-disciplinary particle trajectory model applications for the Greater Agulhas System is highly relevant due to its potential contribution to scientific studies and operational applications. This thesis presents the results of developing particle trajectory model applications in the Greater Agulhas System towards better understanding the physical mechanisms that drive ocean processes in the region. The model is used in three applications that demonstrate their cross-disciplinary potential. These applications include a search and rescue scenario, the study of ocean dynamics and the study of the fate of juvenile turtles. Introducing spatially and temporally varying stochastic motion to account for the processes not resolved in the ocean surface current products, as well as including more appropriate boundary conditions, were shown to improve the accuracy of virtual drifters in representing the trajectory of a real surface drifter. Next, implementing the spatially and temporally varying stochastic motion in the particle trajectory model and applying it to a search and rescue scenario of a capsized catamaran revealed that including both winds and surface ocean currents in the particle trajectory model allowed for an improved prediction of the capsized vessel’s trajectory. By comparing a pair of real surface drifters with the particle trajectory model and analysing high resolution sea surface temperature (SST) fields it was shown that the formation of an eddy on the Agulhas Plateau combined with the weakening of the core current velocity resulted in enhanced eddycurrent interactions facilitating the separation of the real surface drifter-pair as they passed through this region. Lastly, the particle trajectory model was used to study the importance of including active swimming characteristic when studying the fate of juvenile turtles. It was found that including active swimming resulted in a change in the distribution of juvenile turtles and, therefore, needs to be included to provide a proper understanding of the fate of juvenile turtles in the ocean. With further development and refinement of the particle trajectory model, Lagrangian ocean analysis has the potential to provide valuable information towards improving our understanding of physical and biological ocean processes at a range of spatial and temporal scales with potential operational oceanography applications.
- Full Text:
- Date Issued: 2019
Development and characterisation of miconazole nitrate loaded solid lipid nanoparticles for incorporation into a vaginal mucoadhesive system
- Authors: Gwimo, Wimana Alexis
- Date: 2019
- Subjects: Vaginitis , Vagina -- Diseases Sexually transmitted diseases -- Diagnosis Sexually transmitted diseases -- Treatment
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/39632 , vital:35335
- Description: Vulvovaginal candidiasis (VVC) is the second most common cause of vaginitis, affecting 75% of women of sexual maturity. The prescribed first line treatment involves the use of locally-acting imidazole creams. These conventional dosage forms possess limitations, such as leakage, messiness and low residence time at the site of application; all which promote poor patient adherence to pharmacotherapy. Poor adherence is then attributed to increased incidence of VVC reoccurrence and the emergence of Candida strains. It was, therefore, speculated that through the use of novel drug delivery systems (NDDS), the pharmacokinetic and antimicrobial characteristics of a model antifungal drug (miconazole nitrate [MNZ]) could be improved. Primary aim: To develop, optimise and characterise a mucoadhesive hydrogel incorporated with MNZ loaded solid lipid nanoparticles (MNZ-SLNs) for the intended treatment of VVC. This study was conducted in three phases, viz. pre-formulation studies, development, optimisation and characterisation of MNZ-SLNs, and the development and characterisation of MNZ-SLN-loaded thermoresponsive hydrogel. An alternative method for the quantification of MNZ was developed through the use of an octyl stationary phase. The method was deemed suitable for its intended use with a linear equation of y = 811214x + 67958 and a respective limit of quantitation (LoQ) and detection of 0.015 mg/ml and 0.052 mg/ml. Differential scanning calorimetry (DSC) studies suggested that cholesterol showed great promise of facilitating high drug entrapment efficiency (EE). MNZ-SLNs were prepared by means of a novel melt- emulsification sonication and low temperature solidification method and optimised statistically by a 13-run-two-factor central composite rotatable design (CCRD). The predicted optimisation parameters were 4% m/v lipid concentration and 260.94 sonication time. Optimal MNZ-SLN formulations were prepared and characterised by means of photon correlation spectroscopy (PCS), transmission electron microscopy (TEM) and centrifugation. PCS revealed uniform particles with a narrow polydispersity index (PDI) and a mean hydrodynamic diameter (z-avg.) of 73.03 nm and zeta potential (ZP) of 38.43 mV. Percent EE was calculated via an indirect method as 75.24%. Furthermore, the MNZ -SLNs were incorporated into a mucoadhesive thermo-responsive hydrogel with a sol-gel transition temperature of 33.33 ± 2.82 °C. In vitro drug release testing (IVDRT) was undertaken with the aid of a Franz diffusion vertical cell (FDVC) apparatus. A % cumulative drug release of 27.94% and 15.87% was obtained for MNZ- SLNs and MNZ-SLN hydrogels, respectively, after eight hours. The resultant data was fitted into various kinetic models with the aid of DDSolverTM (Microsoft Excel® add-ins, 2016) to evaluate which model attained the highest correlation co-efficient (r2). Both formulations attained high r2 of 0.9941 and 0.9945, respectively, with the Korsmeyer- Peppas mathematical model. A high diffusional exponent (n) of >1 was observed, suggesting a super case II drug release mechanism. Finally, a modified Kirby-Bauer disc diffusion assay was used for ascertaining Candida albicans susceptibility to the developed formulations. Controls in the form of unloaded preparations and a commercially available cream were used. MNZ-SLNs and MNZ-hydrogel demonstrated superior antifungal activity to the commercially available cream. These results indicate that the developed MNZ-SLNloaded hydrogel formulation with localised thermo-responsive effect may be a promising carrier for intravaginal delivery of MNZ in the treatment of VVC.
- Full Text:
- Date Issued: 2019
- Authors: Gwimo, Wimana Alexis
- Date: 2019
- Subjects: Vaginitis , Vagina -- Diseases Sexually transmitted diseases -- Diagnosis Sexually transmitted diseases -- Treatment
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/39632 , vital:35335
- Description: Vulvovaginal candidiasis (VVC) is the second most common cause of vaginitis, affecting 75% of women of sexual maturity. The prescribed first line treatment involves the use of locally-acting imidazole creams. These conventional dosage forms possess limitations, such as leakage, messiness and low residence time at the site of application; all which promote poor patient adherence to pharmacotherapy. Poor adherence is then attributed to increased incidence of VVC reoccurrence and the emergence of Candida strains. It was, therefore, speculated that through the use of novel drug delivery systems (NDDS), the pharmacokinetic and antimicrobial characteristics of a model antifungal drug (miconazole nitrate [MNZ]) could be improved. Primary aim: To develop, optimise and characterise a mucoadhesive hydrogel incorporated with MNZ loaded solid lipid nanoparticles (MNZ-SLNs) for the intended treatment of VVC. This study was conducted in three phases, viz. pre-formulation studies, development, optimisation and characterisation of MNZ-SLNs, and the development and characterisation of MNZ-SLN-loaded thermoresponsive hydrogel. An alternative method for the quantification of MNZ was developed through the use of an octyl stationary phase. The method was deemed suitable for its intended use with a linear equation of y = 811214x + 67958 and a respective limit of quantitation (LoQ) and detection of 0.015 mg/ml and 0.052 mg/ml. Differential scanning calorimetry (DSC) studies suggested that cholesterol showed great promise of facilitating high drug entrapment efficiency (EE). MNZ-SLNs were prepared by means of a novel melt- emulsification sonication and low temperature solidification method and optimised statistically by a 13-run-two-factor central composite rotatable design (CCRD). The predicted optimisation parameters were 4% m/v lipid concentration and 260.94 sonication time. Optimal MNZ-SLN formulations were prepared and characterised by means of photon correlation spectroscopy (PCS), transmission electron microscopy (TEM) and centrifugation. PCS revealed uniform particles with a narrow polydispersity index (PDI) and a mean hydrodynamic diameter (z-avg.) of 73.03 nm and zeta potential (ZP) of 38.43 mV. Percent EE was calculated via an indirect method as 75.24%. Furthermore, the MNZ -SLNs were incorporated into a mucoadhesive thermo-responsive hydrogel with a sol-gel transition temperature of 33.33 ± 2.82 °C. In vitro drug release testing (IVDRT) was undertaken with the aid of a Franz diffusion vertical cell (FDVC) apparatus. A % cumulative drug release of 27.94% and 15.87% was obtained for MNZ- SLNs and MNZ-SLN hydrogels, respectively, after eight hours. The resultant data was fitted into various kinetic models with the aid of DDSolverTM (Microsoft Excel® add-ins, 2016) to evaluate which model attained the highest correlation co-efficient (r2). Both formulations attained high r2 of 0.9941 and 0.9945, respectively, with the Korsmeyer- Peppas mathematical model. A high diffusional exponent (n) of >1 was observed, suggesting a super case II drug release mechanism. Finally, a modified Kirby-Bauer disc diffusion assay was used for ascertaining Candida albicans susceptibility to the developed formulations. Controls in the form of unloaded preparations and a commercially available cream were used. MNZ-SLNs and MNZ-hydrogel demonstrated superior antifungal activity to the commercially available cream. These results indicate that the developed MNZ-SLNloaded hydrogel formulation with localised thermo-responsive effect may be a promising carrier for intravaginal delivery of MNZ in the treatment of VVC.
- Full Text:
- Date Issued: 2019
Development of a framework for a proposed antimicrobial usage reporting tool for public sector hospitals
- Authors: Ramjan, Yumna
- Date: 2019
- Subjects: Anti-infective agents
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: http://hdl.handle.net/10948/43030 , vital:36727
- Description: Background: The inappropriate and unnecessary use of antimicrobials has increased the need to monitor antimicrobial usage so as to identify inappropriate use. In order to support the antimicrobial stewardship (AMS) programme, it is important to quantify the usage of antimicrobials and this can be achieved by promoting the use of AMS utilisation metrics. They are used to measure the progress and efficacy of an AMS programme (Brotherton, 2018).Primary Aim of Research: The primary aim of the research was to develop a framework for a proposed antimicrobial usage reporting tool, which would integrate with various data sources in order to be used by AMS practitioners to optimise antimicrobial usage in the South African public sector hospital setting.Methodology: The study was divided into three phases: a preliminary phase, a developmental phase and a post-developmental phase. The preliminary phase focused on obtaining a comprehensive understanding of the type and nature of the AMS utilisation metrics and subsequently identifying the views on the usage, usefulness and clinical relevance of those AMS utilisation metrics using a quantitative questionnaire, which was conducted among infectious disease specialists, pharmacists, medical prescribers, i.e. prescribers who were not specialists and clinical pathologists employed at tertiary level, public sector hospitals in the Eastern Cape province of South Africa. Consequently, a qualitative semi-structured interview was conducted among healthcare professionals who were involved in the daily implementation of AMS in the workplace. Results obtained from the quantitative component and qualitative component were integrated in order to develop a framework for a proposed antimicrobial usage reporting tool. Results: The Defined Daily Dose (DDD), Prescribed Daily Dose (PDD) and Days of Therapy (DOT) were identified as the most common AMS metrics (Grau et al., 2013). However, the DDD was the only AMS metric currently recommended by the South African National Department of Health (South African National Department of Health, 2017a)and it was the only AMS metric currently being utilised at two of the five research sites in the Eastern Cape province of South Africa. It was identified that data pertaining to antimicrobial usage was available and was being extracted from Rx Solution®. However, the programme did not have the ability of automatically producing the reports, hence, emphasising on the need for an antimicrobial usage reporting tool for South African public sector hospitals. Therefore, the framework for the proposed antimicrobial usage reporting tool would integrate antimicrobial stock management data with the following AMS utilisation metrics: DDD, DOT and PDD, were considered for inclusion in the proposed antimicrobial usage reporting tool. Conclusion: The qualitative findings obtained during the post-developmental phase, therefore, established that although an electronic platform for the purpose of monitoring antimicrobial usage for the South African public sector hospitals was required, there would be many challenges obstructing the implementation of the proposed antimicrobial usage reporting tool.
- Full Text:
- Date Issued: 2019
- Authors: Ramjan, Yumna
- Date: 2019
- Subjects: Anti-infective agents
- Language: English
- Type: Thesis , Masters , MPharm
- Identifier: http://hdl.handle.net/10948/43030 , vital:36727
- Description: Background: The inappropriate and unnecessary use of antimicrobials has increased the need to monitor antimicrobial usage so as to identify inappropriate use. In order to support the antimicrobial stewardship (AMS) programme, it is important to quantify the usage of antimicrobials and this can be achieved by promoting the use of AMS utilisation metrics. They are used to measure the progress and efficacy of an AMS programme (Brotherton, 2018).Primary Aim of Research: The primary aim of the research was to develop a framework for a proposed antimicrobial usage reporting tool, which would integrate with various data sources in order to be used by AMS practitioners to optimise antimicrobial usage in the South African public sector hospital setting.Methodology: The study was divided into three phases: a preliminary phase, a developmental phase and a post-developmental phase. The preliminary phase focused on obtaining a comprehensive understanding of the type and nature of the AMS utilisation metrics and subsequently identifying the views on the usage, usefulness and clinical relevance of those AMS utilisation metrics using a quantitative questionnaire, which was conducted among infectious disease specialists, pharmacists, medical prescribers, i.e. prescribers who were not specialists and clinical pathologists employed at tertiary level, public sector hospitals in the Eastern Cape province of South Africa. Consequently, a qualitative semi-structured interview was conducted among healthcare professionals who were involved in the daily implementation of AMS in the workplace. Results obtained from the quantitative component and qualitative component were integrated in order to develop a framework for a proposed antimicrobial usage reporting tool. Results: The Defined Daily Dose (DDD), Prescribed Daily Dose (PDD) and Days of Therapy (DOT) were identified as the most common AMS metrics (Grau et al., 2013). However, the DDD was the only AMS metric currently recommended by the South African National Department of Health (South African National Department of Health, 2017a)and it was the only AMS metric currently being utilised at two of the five research sites in the Eastern Cape province of South Africa. It was identified that data pertaining to antimicrobial usage was available and was being extracted from Rx Solution®. However, the programme did not have the ability of automatically producing the reports, hence, emphasising on the need for an antimicrobial usage reporting tool for South African public sector hospitals. Therefore, the framework for the proposed antimicrobial usage reporting tool would integrate antimicrobial stock management data with the following AMS utilisation metrics: DDD, DOT and PDD, were considered for inclusion in the proposed antimicrobial usage reporting tool. Conclusion: The qualitative findings obtained during the post-developmental phase, therefore, established that although an electronic platform for the purpose of monitoring antimicrobial usage for the South African public sector hospitals was required, there would be many challenges obstructing the implementation of the proposed antimicrobial usage reporting tool.
- Full Text:
- Date Issued: 2019
Development of a manual to train food handlers of the national school nutrition programme
- Authors: Barkhuizen, Kirsten Lyn
- Date: 2019
- Subjects: Food -- Safety measures
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/36559 , vital:33974
- Description: The study was conducted in order to develop a hygiene and food safety manual that can be used to train the food handlers of the National School Nutrition Programme. The co-operation of the Institute for International Medicine, Partnerships with Children, as part of the Health in Action Programme in this study, is appreciated. Food handlers of the National School Nutrition Programme in low socio-economic schools, in the Nelson Mandela Bay, in the Eastern Cape, were the population of the study. With many South Africans experiencing poverty and food insecurity, the National School Nutrition Programme aims to provide a social safety net and address short term hunger in children. However, challenges are faced regarding the implementation thereof, such as a lack of training of food handlers. This results in poor hygiene and food safety knowledge and behaviour. Subsequently, the risk of transmission of foodborne pathogens and the contamination of food rises. Foodborne illnesses are a major cause of morbidity and mortality, specifically in children, due to weak immune systems. Therefore, the study was conducted in order to develop and test a hygiene and food safety manual so that it can be made available to the South African Department of Education to be used by teachers in order to train the food handlers of the National School Nutrition Programme. The manual can then be used to train all newly recruited food handlers, and therefore ensure that school meals are safe to consume by learners.
- Full Text:
- Date Issued: 2019
- Authors: Barkhuizen, Kirsten Lyn
- Date: 2019
- Subjects: Food -- Safety measures
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/36559 , vital:33974
- Description: The study was conducted in order to develop a hygiene and food safety manual that can be used to train the food handlers of the National School Nutrition Programme. The co-operation of the Institute for International Medicine, Partnerships with Children, as part of the Health in Action Programme in this study, is appreciated. Food handlers of the National School Nutrition Programme in low socio-economic schools, in the Nelson Mandela Bay, in the Eastern Cape, were the population of the study. With many South Africans experiencing poverty and food insecurity, the National School Nutrition Programme aims to provide a social safety net and address short term hunger in children. However, challenges are faced regarding the implementation thereof, such as a lack of training of food handlers. This results in poor hygiene and food safety knowledge and behaviour. Subsequently, the risk of transmission of foodborne pathogens and the contamination of food rises. Foodborne illnesses are a major cause of morbidity and mortality, specifically in children, due to weak immune systems. Therefore, the study was conducted in order to develop and test a hygiene and food safety manual so that it can be made available to the South African Department of Education to be used by teachers in order to train the food handlers of the National School Nutrition Programme. The manual can then be used to train all newly recruited food handlers, and therefore ensure that school meals are safe to consume by learners.
- Full Text:
- Date Issued: 2019