"I want to kill myself!": identity documents and mental health in the South African Daily Sun tabloid
- Authors: Boshoff, Priscilla A
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/143549 , vital:38256 , ISBN , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: An Identity Document (ID) is needed by South Africans to study, apply for a pension or get married. However, Home Affairs, the state department responsible for issuing them, is poorly managed. The popular Daily Sun tabloid newspaper mediates for its five million working class readers the frustration caused by this incompetency in its “Horror Affairs” column. Readers tell their stories about (not) getting their IDs, stories often of suicide, depression and “giving up” on life. Using a Lacanian frame, and through a close reading of “Horror Affairs” texts, I argue that this tabloid plays a therapeutic role for its socially marginalised readers by mediating the “invisibility” engendered by the modernising state and its administrative technologies. Given the concern about high rates of mental health illness in South Africa, the research also demonstrates how popular culture forms can alert health care practitioners to issues which may otherwise go unnoticed.
- Full Text:
- Date Issued: 2015
- Authors: Boshoff, Priscilla A
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/143549 , vital:38256 , ISBN , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: An Identity Document (ID) is needed by South Africans to study, apply for a pension or get married. However, Home Affairs, the state department responsible for issuing them, is poorly managed. The popular Daily Sun tabloid newspaper mediates for its five million working class readers the frustration caused by this incompetency in its “Horror Affairs” column. Readers tell their stories about (not) getting their IDs, stories often of suicide, depression and “giving up” on life. Using a Lacanian frame, and through a close reading of “Horror Affairs” texts, I argue that this tabloid plays a therapeutic role for its socially marginalised readers by mediating the “invisibility” engendered by the modernising state and its administrative technologies. Given the concern about high rates of mental health illness in South Africa, the research also demonstrates how popular culture forms can alert health care practitioners to issues which may otherwise go unnoticed.
- Full Text:
- Date Issued: 2015
'Committed, motivated and joyful?'Job satisfaction and organisational commitment of managers at a South African public utility
- Mayer, Claude-Hélène, Louw, Lynette, Baxter, Jeremy
- Authors: Mayer, Claude-Hélène , Louw, Lynette , Baxter, Jeremy
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123320 , vital:35427 , https://doi.org/10.4102/acom.v15i1.291
- Description: During the past decade, publications and conferences on management in African organisations (Kamoche 2011a; 2011b) and in global contexts (Mangaliso 2001; Jackson 2004)1 have increased steadily. In various African contexts and organisations, job satisfaction (JS) (Walumbwa et al. 2005) and organisational commitment (OC) (Gbadamosi 2003; Wasti 2003; Nyengane 2007; Pillay 2008) have been researched. Most of the previous research is quantitative in nature. Although quantititative research provides insights into the relationships between variables, it does not necessarily provide in-depth meaningful conclusions on micro-psychological levels (e.g. Sempane, Rieger & Roodt 2002; Buitendach & De Witte 2005).
- Full Text:
- Date Issued: 2015
- Authors: Mayer, Claude-Hélène , Louw, Lynette , Baxter, Jeremy
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123320 , vital:35427 , https://doi.org/10.4102/acom.v15i1.291
- Description: During the past decade, publications and conferences on management in African organisations (Kamoche 2011a; 2011b) and in global contexts (Mangaliso 2001; Jackson 2004)1 have increased steadily. In various African contexts and organisations, job satisfaction (JS) (Walumbwa et al. 2005) and organisational commitment (OC) (Gbadamosi 2003; Wasti 2003; Nyengane 2007; Pillay 2008) have been researched. Most of the previous research is quantitative in nature. Although quantititative research provides insights into the relationships between variables, it does not necessarily provide in-depth meaningful conclusions on micro-psychological levels (e.g. Sempane, Rieger & Roodt 2002; Buitendach & De Witte 2005).
- Full Text:
- Date Issued: 2015
'Feeling at home': institutional culture and the idea of a university
- Authors: Vice, Samantha
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/142072 , vital:38047 , ISBN 9781869142902 , https://books.google.co.za/books?id=49o8rgEACAAJanddq=Being+at+home:+Race,+institutional+culture+and+transformation+at+South+African+higher+education+institutionandhl=enandsa=Xandved=0ahUKEwiPgsa6mpjjAhXNN8AKHbNwAtoQ6AEIKDAA
- Description: This edited work has gathered together contributions on how to transform universities in South Africa; as many are struggling to shift their institutional culture. In a South African context, transformation means to attempt to change higher education institutions such that they no longer reflect the values promoted by apartheid but rather reflect the values embodied in South Africa's 1996 Constitution. Institutional culture is the main subject for discussion in this book. In order to transform South Africa's universities, the contributors begin by analyzing the idea of what a university is, and relatedly, what its ideal aims are. A second theme is to understand what institutional culture is and how it functions. Moreover, transformation cannot occur without transforming the broader cultures of which they are a part. Related to this theme is a general concern about how contemporary moves towards the instrumentalization of higher education affect the ability to transform institutions. These institutions are being pushed to conform to goals that are outside the traditional idea of a university, such as concerns that universities are being 'bureaucratized' and becoming corporations, instead of a place of learning open to all. In conclusion it can be said that the contemporary South African academic community has an opportunity to recreate itself as the end of apartheid created space for engaging in transformative epistemic projects. The transformation of the tertiary sector entails a transformation of institutional cultures.
- Full Text:
- Date Issued: 2015
- Authors: Vice, Samantha
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/142072 , vital:38047 , ISBN 9781869142902 , https://books.google.co.za/books?id=49o8rgEACAAJanddq=Being+at+home:+Race,+institutional+culture+and+transformation+at+South+African+higher+education+institutionandhl=enandsa=Xandved=0ahUKEwiPgsa6mpjjAhXNN8AKHbNwAtoQ6AEIKDAA
- Description: This edited work has gathered together contributions on how to transform universities in South Africa; as many are struggling to shift their institutional culture. In a South African context, transformation means to attempt to change higher education institutions such that they no longer reflect the values promoted by apartheid but rather reflect the values embodied in South Africa's 1996 Constitution. Institutional culture is the main subject for discussion in this book. In order to transform South Africa's universities, the contributors begin by analyzing the idea of what a university is, and relatedly, what its ideal aims are. A second theme is to understand what institutional culture is and how it functions. Moreover, transformation cannot occur without transforming the broader cultures of which they are a part. Related to this theme is a general concern about how contemporary moves towards the instrumentalization of higher education affect the ability to transform institutions. These institutions are being pushed to conform to goals that are outside the traditional idea of a university, such as concerns that universities are being 'bureaucratized' and becoming corporations, instead of a place of learning open to all. In conclusion it can be said that the contemporary South African academic community has an opportunity to recreate itself as the end of apartheid created space for engaging in transformative epistemic projects. The transformation of the tertiary sector entails a transformation of institutional cultures.
- Full Text:
- Date Issued: 2015
'I always knew I would go to university': a social realist account of student agency: part 1
- Authors: Ellery, Karen , Baxen, Jean
- Date: 2015
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/61207 , vital:27990
- Description: Academic development programmes at higher education institutions (HEIs) in South Africa are often underpinned by discourses that view students as deficit. Archer's social realist ontology offers a means of understanding reflexivities and agency of students in the higher education context. Using narrative data and drawing on Archer's (2003) theory of mediation between structure and agency through internal conversations, this study examined the socio-economic background of one particular student, Thando, and his agential journey to arrive at the academy. The analysis reveals Thando has a deliberate and determined stance towards achieving his project of obtaining a tertiary education in order to realise a better life for himself and his family. Despite what could be perceived as constraining socio-cultural conditions, Thando strategically circumvents such restrictions and acts in ways that help him pursue his project. It is argued that student agency needs to take a more central place within academic development programmes in higher education.
- Full Text:
- Date Issued: 2015
- Authors: Ellery, Karen , Baxen, Jean
- Date: 2015
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/61207 , vital:27990
- Description: Academic development programmes at higher education institutions (HEIs) in South Africa are often underpinned by discourses that view students as deficit. Archer's social realist ontology offers a means of understanding reflexivities and agency of students in the higher education context. Using narrative data and drawing on Archer's (2003) theory of mediation between structure and agency through internal conversations, this study examined the socio-economic background of one particular student, Thando, and his agential journey to arrive at the academy. The analysis reveals Thando has a deliberate and determined stance towards achieving his project of obtaining a tertiary education in order to realise a better life for himself and his family. Despite what could be perceived as constraining socio-cultural conditions, Thando strategically circumvents such restrictions and acts in ways that help him pursue his project. It is argued that student agency needs to take a more central place within academic development programmes in higher education.
- Full Text:
- Date Issued: 2015
'Meaningful engagement’: Towards a language rights paradigm for effective language policy implementation
- Docrat, Zakeera, Kaschula, Russell H
- Authors: Docrat, Zakeera , Kaschula, Russell H
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/174812 , vital:42512 , https://doi.org/10.1080/02572117.2015.1056455
- Description: This article aims to develop the concept of ‘meaningful engagement’ in terms of the contemporary language policy implementation framework in South Africa. By exploring the current language policies, implementation and the current lack of effectiveness, the authors offer a new implementation focus drawn from the legal concept of ‘meaningful engagement’. ‘Meaningful engagement’ is a concept within the socio-economic rights sphere. This article expands and advances the concept within a language policy framework. Against the enabling legislative environment created by the Use of Official Languages Act 12 of 2012 and the overarching Constitutional framework which embeds the rights of all official languages, ‘meaningful engagement’ is developed and applied to selected language policies and practices.
- Full Text:
- Date Issued: 2015
- Authors: Docrat, Zakeera , Kaschula, Russell H
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/174812 , vital:42512 , https://doi.org/10.1080/02572117.2015.1056455
- Description: This article aims to develop the concept of ‘meaningful engagement’ in terms of the contemporary language policy implementation framework in South Africa. By exploring the current language policies, implementation and the current lack of effectiveness, the authors offer a new implementation focus drawn from the legal concept of ‘meaningful engagement’. ‘Meaningful engagement’ is a concept within the socio-economic rights sphere. This article expands and advances the concept within a language policy framework. Against the enabling legislative environment created by the Use of Official Languages Act 12 of 2012 and the overarching Constitutional framework which embeds the rights of all official languages, ‘meaningful engagement’ is developed and applied to selected language policies and practices.
- Full Text:
- Date Issued: 2015
'Tell us a new story': a proposal for the transformatory potential of collective memory projects
- Authors: Vincent, Louise
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/${Handle} , vital:38046 , ISBN 9781869142902 , https://books.google.co.za/books?id=49o8rgEACAAJanddq=Being+at+home:+Race,+institutional+culture+and+transformation+at+South+African+higher+education+institutionandhl=enandsa=Xandved=0ahUKEwiPgsa6mpjjAhXNN8AKHbNwAtoQ6AEIKDAA
- Description: This edited work has gathered together contributions on how to transform universities in South Africa; as many are struggling to shift their institutional culture. In a South African context, transformation means to attempt to change higher education institutions such that they no longer reflect the values promoted by apartheid but rather reflect the values embodied in South Africa's 1996 Constitution. Institutional culture is the main subject for discussion in this book. In order to transform South Africa's universities, the contributors begin by analyzing the idea of what a university is, and relatedly, what its ideal aims are. A second theme is to understand what institutional culture is and how it functions. Moreover, transformation cannot occur without transforming the broader cultures of which they are a part. Related to this theme is a general concern about how contemporary moves towards the instrumentalization of higher education affect the ability to transform institutions. These institutions are being pushed to conform to goals that are outside the traditional idea of a university, such as concerns that universities are being 'bureaucratized' and becoming corporations, instead of a place of learning open to all. In conclusion it can be said that the contemporary South African academic community has an opportunity to recreate itself as the end of apartheid created space for engaging in transformative epistemic projects. The transformation of the tertiary sector entails a transformation of institutional cultures.
- Full Text:
- Date Issued: 2015
- Authors: Vincent, Louise
- Date: 2015
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/${Handle} , vital:38046 , ISBN 9781869142902 , https://books.google.co.za/books?id=49o8rgEACAAJanddq=Being+at+home:+Race,+institutional+culture+and+transformation+at+South+African+higher+education+institutionandhl=enandsa=Xandved=0ahUKEwiPgsa6mpjjAhXNN8AKHbNwAtoQ6AEIKDAA
- Description: This edited work has gathered together contributions on how to transform universities in South Africa; as many are struggling to shift their institutional culture. In a South African context, transformation means to attempt to change higher education institutions such that they no longer reflect the values promoted by apartheid but rather reflect the values embodied in South Africa's 1996 Constitution. Institutional culture is the main subject for discussion in this book. In order to transform South Africa's universities, the contributors begin by analyzing the idea of what a university is, and relatedly, what its ideal aims are. A second theme is to understand what institutional culture is and how it functions. Moreover, transformation cannot occur without transforming the broader cultures of which they are a part. Related to this theme is a general concern about how contemporary moves towards the instrumentalization of higher education affect the ability to transform institutions. These institutions are being pushed to conform to goals that are outside the traditional idea of a university, such as concerns that universities are being 'bureaucratized' and becoming corporations, instead of a place of learning open to all. In conclusion it can be said that the contemporary South African academic community has an opportunity to recreate itself as the end of apartheid created space for engaging in transformative epistemic projects. The transformation of the tertiary sector entails a transformation of institutional cultures.
- Full Text:
- Date Issued: 2015
(Ferrocenylpyrazolyl) zinc (II) benzoates as catalysts for the ring opening polymerization of ε-caprolactone
- Obuah, Collins, Lochee, Yemanlall, Jordaan, Johan H L, Otto, Daniel P, Nyokong, Tebello, Darkwa, James
- Authors: Obuah, Collins , Lochee, Yemanlall , Jordaan, Johan H L , Otto, Daniel P , Nyokong, Tebello , Darkwa, James
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189515 , vital:44853 , xlink:href="https://doi.org/10.1016/j.poly.2015.02.007"
- Description: The reaction of Zn(OAc)2 and C6H5COOH or 3,5-NO2-C6H3COOH with 3-ferrocenylpyrazolyl-methylenepyridine (L1), 3-ferrocenyl-5-methylpyrazolyl-methylenepyridine (L2), 3-ferrocenylpyrazolyl-ethylamine (L3) and 3-ferrocenyl-5-pyrazolyl-ethylamine (L4) afford the corresponding complexes [Zn(C6H5COO)2(L1)] (1), [Zn(C6H5COO)2(L2)] (2), [Zn(3,5-NO2-C6H3COO)2(L1)] (3), [Zn(3,5-NO2-C6H3 COO)2(L2)] (4), [Zn(C6H5COO)2(L3)] (5), [Zn(C6H5COO)2(L4)] (6), [Zn(3,5-NO2-C6H3COO)2(L3)] (7) and [Zn(3,5-NO2-C6H3COO)2(L4)] (8). These complexes behave as catalysts for the ring opening polymerization of e-caprolactone to produce polymers with molecular weight that range from 1480 to 7080 g mol1 and exhibited moderate to broad PDIs. Evidence of these complexes acting as catalysts was obtained from both the polymerization data and kinetic studies. The polymerization data show that variation of the [CL]/[C] from 100 to 800 produced PCL with relatively the same molecular weight indicative of a catalyst behavior. The appearance of induction period in kinetic plots strengthens the fact that these complexes are catalysts rather than initiators. MALDI-TOF MS and 1 H NMR data show di-hydroxy end groups, which support the coordination mechanism rather than insertion mechanism. To understand the broad PDIs obtained for some of the polymer, the electronic properties of the zinc complexes were investigated using cyclic voltammetry. The results show that the zinc complexes containing amine based ligands are highly electrophilic therefore making them unstable, hence the broad PDIs observed for zinc complexes containing amine based ligands. Among the eight complexes investigated, complex 7 is the most active catalyst with kp value of 1.18 107 h1 mol1 at 110 C.
- Full Text:
- Date Issued: 2015
- Authors: Obuah, Collins , Lochee, Yemanlall , Jordaan, Johan H L , Otto, Daniel P , Nyokong, Tebello , Darkwa, James
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189515 , vital:44853 , xlink:href="https://doi.org/10.1016/j.poly.2015.02.007"
- Description: The reaction of Zn(OAc)2 and C6H5COOH or 3,5-NO2-C6H3COOH with 3-ferrocenylpyrazolyl-methylenepyridine (L1), 3-ferrocenyl-5-methylpyrazolyl-methylenepyridine (L2), 3-ferrocenylpyrazolyl-ethylamine (L3) and 3-ferrocenyl-5-pyrazolyl-ethylamine (L4) afford the corresponding complexes [Zn(C6H5COO)2(L1)] (1), [Zn(C6H5COO)2(L2)] (2), [Zn(3,5-NO2-C6H3COO)2(L1)] (3), [Zn(3,5-NO2-C6H3 COO)2(L2)] (4), [Zn(C6H5COO)2(L3)] (5), [Zn(C6H5COO)2(L4)] (6), [Zn(3,5-NO2-C6H3COO)2(L3)] (7) and [Zn(3,5-NO2-C6H3COO)2(L4)] (8). These complexes behave as catalysts for the ring opening polymerization of e-caprolactone to produce polymers with molecular weight that range from 1480 to 7080 g mol1 and exhibited moderate to broad PDIs. Evidence of these complexes acting as catalysts was obtained from both the polymerization data and kinetic studies. The polymerization data show that variation of the [CL]/[C] from 100 to 800 produced PCL with relatively the same molecular weight indicative of a catalyst behavior. The appearance of induction period in kinetic plots strengthens the fact that these complexes are catalysts rather than initiators. MALDI-TOF MS and 1 H NMR data show di-hydroxy end groups, which support the coordination mechanism rather than insertion mechanism. To understand the broad PDIs obtained for some of the polymer, the electronic properties of the zinc complexes were investigated using cyclic voltammetry. The results show that the zinc complexes containing amine based ligands are highly electrophilic therefore making them unstable, hence the broad PDIs observed for zinc complexes containing amine based ligands. Among the eight complexes investigated, complex 7 is the most active catalyst with kp value of 1.18 107 h1 mol1 at 110 C.
- Full Text:
- Date Issued: 2015
A colorimetric probe for dopamine based on gold nanoparticles-electrospun nanofibre composite
- Ngomane, Nokuthula, Torto, Nelson, Krause, Rui W M, Vilakazi, Sibulelo
- Authors: Ngomane, Nokuthula , Torto, Nelson , Krause, Rui W M , Vilakazi, Sibulelo
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/195407 , vital:45562 , xlink:href="https://doi.org/10.1016/j.matpr.2015.08.036"
- Description: An easily prepared solid state colorimetric probe for detecting the neurotransmitter dopamine (DA) was developed. The probe, in the form of an electrospun Nylon−6 (N6) nanofibre with embedded un−functionalized gold nanoparticles (UF−AuNPs) produces a clear colour change in the presence of a DA that is detectable by the naked eye. Characterisation of the nanofibre using UV/vis spectroscopy and electron microscopy (TEM) confirmed the formation of the AuNPs in the polymer solution, and that the AuNPs were completely encapsulated within the composite nanofibres before exposure to the analytes. The probe exhibited very high sensitivity towards DA resulting in colour change of the composite fibres from purple to navy blue/black even under low concentrations of DA. The probe was also selective to DA since the colour remained unchanged in the presence of commonly encountered interfering species such as ascorbic acid, uric acid, catechol, epinephrine and norepinephrine. Moreover, the colour change was observed rapid, occurring either immediately on contact with higher concentrations (5 x10−4 M) or within about 3−5 min for the lower concentrations (e.g. 5 x10−7 M). Since this probe does not require the use of any instruments, and is both rapid and stable over time, it can be applied in the field by an inexperienced person.
- Full Text:
- Date Issued: 2015
- Authors: Ngomane, Nokuthula , Torto, Nelson , Krause, Rui W M , Vilakazi, Sibulelo
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/195407 , vital:45562 , xlink:href="https://doi.org/10.1016/j.matpr.2015.08.036"
- Description: An easily prepared solid state colorimetric probe for detecting the neurotransmitter dopamine (DA) was developed. The probe, in the form of an electrospun Nylon−6 (N6) nanofibre with embedded un−functionalized gold nanoparticles (UF−AuNPs) produces a clear colour change in the presence of a DA that is detectable by the naked eye. Characterisation of the nanofibre using UV/vis spectroscopy and electron microscopy (TEM) confirmed the formation of the AuNPs in the polymer solution, and that the AuNPs were completely encapsulated within the composite nanofibres before exposure to the analytes. The probe exhibited very high sensitivity towards DA resulting in colour change of the composite fibres from purple to navy blue/black even under low concentrations of DA. The probe was also selective to DA since the colour remained unchanged in the presence of commonly encountered interfering species such as ascorbic acid, uric acid, catechol, epinephrine and norepinephrine. Moreover, the colour change was observed rapid, occurring either immediately on contact with higher concentrations (5 x10−4 M) or within about 3−5 min for the lower concentrations (e.g. 5 x10−7 M). Since this probe does not require the use of any instruments, and is both rapid and stable over time, it can be applied in the field by an inexperienced person.
- Full Text:
- Date Issued: 2015
A comparative photophysicochemical study of phthalocyanines encapsulated in core–shell silica nanoparticles
- Fashina, Adedayo, Amuhaya, Edith K, Nyokong, Tebello
- Authors: Fashina, Adedayo , Amuhaya, Edith K , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189708 , vital:44924 , xlink:href="https://doi.org/10.1016/j.saa.2014.08.062"
- Description: This work presents the synthesis and characterization of a new zinc phthalocyanine complex tetrasubstituted with 3-carboxyphenoxy in the peripheral position. The photophysical properties of the new complex are compared with those of phthalocyanines tetra substituted with 3-carboxyphenoxy or 4- carboxyphenoxy at non-peripheral positions. Three phthalocyanine complexes were encapsulated within silica matrix to form a core shell and the hybrid nanoparticles particles obtained were spherical and mono dispersed. When encapsulated within the silica shell nanoparticles, phthalocyanines showed improved triplet quantum yields and singlet oxygen quantum yields than surface grafted derivatives. The improvements observed could be attributed to the protection provided for the phthalocyanine complexes by the silica matrix.
- Full Text:
- Date Issued: 2015
- Authors: Fashina, Adedayo , Amuhaya, Edith K , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189708 , vital:44924 , xlink:href="https://doi.org/10.1016/j.saa.2014.08.062"
- Description: This work presents the synthesis and characterization of a new zinc phthalocyanine complex tetrasubstituted with 3-carboxyphenoxy in the peripheral position. The photophysical properties of the new complex are compared with those of phthalocyanines tetra substituted with 3-carboxyphenoxy or 4- carboxyphenoxy at non-peripheral positions. Three phthalocyanine complexes were encapsulated within silica matrix to form a core shell and the hybrid nanoparticles particles obtained were spherical and mono dispersed. When encapsulated within the silica shell nanoparticles, phthalocyanines showed improved triplet quantum yields and singlet oxygen quantum yields than surface grafted derivatives. The improvements observed could be attributed to the protection provided for the phthalocyanine complexes by the silica matrix.
- Full Text:
- Date Issued: 2015
A Comparison of Four End-User Devices as Thin Clients for Public Access to the Internet in Poor Communities
- Duff, Kevin, Siebörger, Ingrid, Terzoli, Alfredo
- Authors: Duff, Kevin , Siebörger, Ingrid , Terzoli, Alfredo
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430892 , vital:72725 , https://doi.org/10.1007/978-3-319-16886-9_24
- Description: In poor areas, where ICT infrastructure is being deployed with devel-opmental aims, there is a need to provide appropriate, sustainable technologies that meet the needs of the local community. Current trends for ICT interventions favour the use of mobile user equipment, such as tablets and cellphones, but we think that they are inappropriate to allow production as opposed to mainly consumption of digital con-tent, at least for the foreseeable future. Thus our objective is to reduce the cost of deployment of traditional communal Internet Access Points using PCs. In this paper we compare four candidate computers to be used as thin clients in such settings, according to seven different cate-gories. Our study identifies the strengths, weaknesses and problems of each device, and concludes with recommendations for anybody wish-ing to deploy such devices as Linux Terminal Server Project (LTSP) thin clients in a public Internet Access Point.
- Full Text:
- Date Issued: 2015
- Authors: Duff, Kevin , Siebörger, Ingrid , Terzoli, Alfredo
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430892 , vital:72725 , https://doi.org/10.1007/978-3-319-16886-9_24
- Description: In poor areas, where ICT infrastructure is being deployed with devel-opmental aims, there is a need to provide appropriate, sustainable technologies that meet the needs of the local community. Current trends for ICT interventions favour the use of mobile user equipment, such as tablets and cellphones, but we think that they are inappropriate to allow production as opposed to mainly consumption of digital con-tent, at least for the foreseeable future. Thus our objective is to reduce the cost of deployment of traditional communal Internet Access Points using PCs. In this paper we compare four candidate computers to be used as thin clients in such settings, according to seven different cate-gories. Our study identifies the strengths, weaknesses and problems of each device, and concludes with recommendations for anybody wish-ing to deploy such devices as Linux Terminal Server Project (LTSP) thin clients in a public Internet Access Point.
- Full Text:
- Date Issued: 2015
A comparison of genetic structure in two low-dispersal crabs from the Wild Coast, South Africa
- Qhaji, Y, Jansen van Vuuren, Bettine, Papadopoulos, Isabelle, McQuaid, Christopher D, Teske, Peter R
- Authors: Qhaji, Y , Jansen van Vuuren, Bettine , Papadopoulos, Isabelle , McQuaid, Christopher D , Teske, Peter R
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/444770 , vital:74297 , https://doi.org/10.2989/1814232X.2015.1077474
- Description: The Wild Coast in south-eastern South Africa is strongly influenced by the warm, southward-flowing Agulhas Current. This current has a significant impact on dispersal in the coastal biota of the region, and facilitates high levels of connectivity among populations. However, it is not known how the region's high-velocity hydrology affects genetic population structure in endemic estuarine species, populations of which are frequently isolated from the sea. Here, we compared genetic structure in two estuarine crabs of the family Hymenosomatidae. Both are presumed to have low dispersal potential, but they differ in terms of their life histories. Hymenosoma longicrure has abbreviated larval development and can complete its entire life cycle within estuaries, whereas Neorhynchoplax bovis is a direct developer that lacks planktonic larvae.
- Full Text:
- Date Issued: 2015
- Authors: Qhaji, Y , Jansen van Vuuren, Bettine , Papadopoulos, Isabelle , McQuaid, Christopher D , Teske, Peter R
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/444770 , vital:74297 , https://doi.org/10.2989/1814232X.2015.1077474
- Description: The Wild Coast in south-eastern South Africa is strongly influenced by the warm, southward-flowing Agulhas Current. This current has a significant impact on dispersal in the coastal biota of the region, and facilitates high levels of connectivity among populations. However, it is not known how the region's high-velocity hydrology affects genetic population structure in endemic estuarine species, populations of which are frequently isolated from the sea. Here, we compared genetic structure in two estuarine crabs of the family Hymenosomatidae. Both are presumed to have low dispersal potential, but they differ in terms of their life histories. Hymenosoma longicrure has abbreviated larval development and can complete its entire life cycle within estuaries, whereas Neorhynchoplax bovis is a direct developer that lacks planktonic larvae.
- Full Text:
- Date Issued: 2015
A Connection Management System to Enable the Wireless Transmission of MIDI Messages
- Authors: Shaw, Brent , Foss, Richard
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426829 , vital:72394 , https://www.aes.org/e-lib/browse.cfm?elib=18030
- Description: This paper examines the design and implementation of a wireless system for the distribution of MIDI messages for show control and studio environments. The system makes use of the MIDI and MIDINet protocols, creating wireless nodes that will enable the transmission of MIDI between devices on a wireless network with connection management capabilities through the use of embedded web servers. The paper describes the current state of the art, configuration of the system, hardware architectures, software design, and implementation.
- Full Text:
- Date Issued: 2015
- Authors: Shaw, Brent , Foss, Richard
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/426829 , vital:72394 , https://www.aes.org/e-lib/browse.cfm?elib=18030
- Description: This paper examines the design and implementation of a wireless system for the distribution of MIDI messages for show control and studio environments. The system makes use of the MIDI and MIDINet protocols, creating wireless nodes that will enable the transmission of MIDI between devices on a wireless network with connection management capabilities through the use of embedded web servers. The paper describes the current state of the art, configuration of the system, hardware architectures, software design, and implementation.
- Full Text:
- Date Issued: 2015
A constructivist deconstruction of post-apartheid South Africa’s trade negotiation strategies: the politics of development and global value chains
- Authors: Pillay, Morgenie
- Date: 2015
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/64731 , vital:28596
- Description: Expected release date-May 2020
- Full Text:
- Date Issued: 2015
- Authors: Pillay, Morgenie
- Date: 2015
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/64731 , vital:28596
- Description: Expected release date-May 2020
- Full Text:
- Date Issued: 2015
A critical assessment of economic policies and their impact on entrepreneurship development in South Africa: a case of Khayelitsha Township in Cape Town
- Oduwole, Olusola https://orcid.org/0000-0002-1563-7392
- Authors: Oduwole, Olusola https://orcid.org/0000-0002-1563-7392
- Date: 2015
- Subjects: Entrepreneurship , Economic policy , Economic development -- South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/26302 , vital:65236
- Description: The complexity of the South African society due to past systematic exclusion of some communities from economic activities resulted in the triple challenge of poverty, inequality and unemployment. Although various economic policies had been developed since the advent of the democratic dispensation in 1994, these policies focused on levelling the economic environment, poverty alleviation and massive social security system. However, despite all the interventions, South Africa remains one of the most unequal societies in the world. This is profiled by the mushrooming of informal settlements around cities with job seekers and frequent protests by people who are impatient to experience improvement in their quality of life and who feel cheated out of their social contract. Advocacy from the governing party’s tripartite alliance towards a developmental state had placed more obligations on the government. This requires deliberate interventions through policies implementation to improve or at best alleviate the well-being of the citizenry. A survey conducted in the township of Khayelitsha to assess the impact of such economic policies on the development of entrepreneurship. Khayelitsha is one of South Africa’s largest townships, an informal settlement profiled by unemployment, poor infrastructure and unavailability of basic services. The study explored the entrepreneurial perception, start-up barriers, entrepreneurship climate, and general cultural factors relating to the environment of entrepreneurship development. The results reveal that despite the various economic policies, high level of unwillingness of citizens towards entrepreneurial activity and business venture is rife notwithstanding the high level of unemployment and poverty. The antidote to these challenges would be a rapid entrepreneurship drive among people most affected that would cause them to mind their own business” and become “masters of their own destinies. Given the complexity and massiveness of the challenges, the conclusion shows that a pragmatic solution is required. Therefore, the emancipation of entrepreneurship development in South Africa townships needs attention. The recommended solution is a pragmatic and innovative strategy based on the acronyms NEEDS HELP which stand for Neighbourhood Enhancement and Environmental Development Strategy and Holistic Entrepreneurial Lifestyle Programme. , Thesis (PhD) -- Faculty of Management and Commerce, 2015
- Full Text:
- Date Issued: 2015
- Authors: Oduwole, Olusola https://orcid.org/0000-0002-1563-7392
- Date: 2015
- Subjects: Entrepreneurship , Economic policy , Economic development -- South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/26302 , vital:65236
- Description: The complexity of the South African society due to past systematic exclusion of some communities from economic activities resulted in the triple challenge of poverty, inequality and unemployment. Although various economic policies had been developed since the advent of the democratic dispensation in 1994, these policies focused on levelling the economic environment, poverty alleviation and massive social security system. However, despite all the interventions, South Africa remains one of the most unequal societies in the world. This is profiled by the mushrooming of informal settlements around cities with job seekers and frequent protests by people who are impatient to experience improvement in their quality of life and who feel cheated out of their social contract. Advocacy from the governing party’s tripartite alliance towards a developmental state had placed more obligations on the government. This requires deliberate interventions through policies implementation to improve or at best alleviate the well-being of the citizenry. A survey conducted in the township of Khayelitsha to assess the impact of such economic policies on the development of entrepreneurship. Khayelitsha is one of South Africa’s largest townships, an informal settlement profiled by unemployment, poor infrastructure and unavailability of basic services. The study explored the entrepreneurial perception, start-up barriers, entrepreneurship climate, and general cultural factors relating to the environment of entrepreneurship development. The results reveal that despite the various economic policies, high level of unwillingness of citizens towards entrepreneurial activity and business venture is rife notwithstanding the high level of unemployment and poverty. The antidote to these challenges would be a rapid entrepreneurship drive among people most affected that would cause them to mind their own business” and become “masters of their own destinies. Given the complexity and massiveness of the challenges, the conclusion shows that a pragmatic solution is required. Therefore, the emancipation of entrepreneurship development in South Africa townships needs attention. The recommended solution is a pragmatic and innovative strategy based on the acronyms NEEDS HELP which stand for Neighbourhood Enhancement and Environmental Development Strategy and Holistic Entrepreneurial Lifestyle Programme. , Thesis (PhD) -- Faculty of Management and Commerce, 2015
- Full Text:
- Date Issued: 2015
A description of gametogenesis in the panga Pterogymnus laniarius (Pisces: Sparidae) with comments on changes in maturity patterns over the past two decades
- Booth, Anthony J, Hecht, Thomas
- Authors: Booth, Anthony J , Hecht, Thomas
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123542 , vital:35452 , https://doi.org/10.1080/02541858.1997.11448428
- Description: A description of gametogenesis in the panga Pferogymnus laniarius, a common endemic seabream species inhabiting the Agulhas Bank, South Africa, is presented. After sexual maturity, oogenesis and spermatogenesis continued throughout the year and were found to be similar to these processes in other seabream species and teleosts in general. Analysis of maturity data over the past two decades revealed a significant change in both age and size-at-maturity, a response to fishing pressure.
- Full Text:
- Date Issued: 2015
- Authors: Booth, Anthony J , Hecht, Thomas
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/123542 , vital:35452 , https://doi.org/10.1080/02541858.1997.11448428
- Description: A description of gametogenesis in the panga Pferogymnus laniarius, a common endemic seabream species inhabiting the Agulhas Bank, South Africa, is presented. After sexual maturity, oogenesis and spermatogenesis continued throughout the year and were found to be similar to these processes in other seabream species and teleosts in general. Analysis of maturity data over the past two decades revealed a significant change in both age and size-at-maturity, a response to fishing pressure.
- Full Text:
- Date Issued: 2015
A narrative-discursive analysis of abortion decision making in Zimbabwe:
- Chiweshe, Malvern T, Macleod, Catriona I
- Authors: Chiweshe, Malvern T , Macleod, Catriona I
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143882 , vital:38291 , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: The available research on abortion-decision-making tends to focus on the ‘factors’ or ‘influences’ that are seen to affect abortion decision-making. This approach is rarely able to account for the complex, multi-faceted nature of abortion decision-making, and is often not located within a framework that can unpick the complex array of power relations that underpin the ‘process’ of abortion decision-making. Data reported on in this paper were collected from three sites in Zimbabwe. Narrative interviews were conducted with 18 women who had terminated pregnancies (six at each site) and semi-structured interviews were conducted with six service providers. The women employed discursive resources around stigma, religion, health and culture in telling stories around abortion shame, abortion as justified and the fearful, secretive act of abortion. Comparisons of the way women positioned themselves and how they were positioned by health service providers point to the availability and embeddedness of social discourses and power relations that work to enable/constrain reproductive justice.
- Full Text:
- Date Issued: 2015
- Authors: Chiweshe, Malvern T , Macleod, Catriona I
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143882 , vital:38291 , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: The available research on abortion-decision-making tends to focus on the ‘factors’ or ‘influences’ that are seen to affect abortion decision-making. This approach is rarely able to account for the complex, multi-faceted nature of abortion decision-making, and is often not located within a framework that can unpick the complex array of power relations that underpin the ‘process’ of abortion decision-making. Data reported on in this paper were collected from three sites in Zimbabwe. Narrative interviews were conducted with 18 women who had terminated pregnancies (six at each site) and semi-structured interviews were conducted with six service providers. The women employed discursive resources around stigma, religion, health and culture in telling stories around abortion shame, abortion as justified and the fearful, secretive act of abortion. Comparisons of the way women positioned themselves and how they were positioned by health service providers point to the availability and embeddedness of social discourses and power relations that work to enable/constrain reproductive justice.
- Full Text:
- Date Issued: 2015
A quantitative analysis of microplastic pollution along the south-eastern coastline of South Africa
- Nel, Holly A, Froneman, P William
- Authors: Nel, Holly A , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68032 , vital:29187 , https://doi.org/10.1016/j.marpolbul.2015.09.043
- Description: Publisher version , The extent of microplastic pollution (< 5 mm) in the southern hemisphere, particularly southern Africa, is largely unknown. This study aimed to evaluate microplastic pollution along the south-eastern coastline of South Africa, looking at whether bays are characterised by higher microplastic densities than open stretches of coastline in both beach sediment and surf-zone water. Microplastic (mean ± standard error) densities in the beach sediment ranged between 688.9 ± 348.2 and 3308 ± 1449 particles·m− 2, while those in the water column varied between 257.9 ± 53.36 and 1215 ± 276.7 particles·m− 3. With few exceptions there were no significant spatial patterns in either the sediment or water column microplastic densities; with little differences in density between bays and the open coast (P > 0.05). These data indicate that the presence of microplastics were not associated with proximity to land-based sources or population density, but rather is governed by water circulation.
- Full Text: false
- Date Issued: 2015
- Authors: Nel, Holly A , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68032 , vital:29187 , https://doi.org/10.1016/j.marpolbul.2015.09.043
- Description: Publisher version , The extent of microplastic pollution (< 5 mm) in the southern hemisphere, particularly southern Africa, is largely unknown. This study aimed to evaluate microplastic pollution along the south-eastern coastline of South Africa, looking at whether bays are characterised by higher microplastic densities than open stretches of coastline in both beach sediment and surf-zone water. Microplastic (mean ± standard error) densities in the beach sediment ranged between 688.9 ± 348.2 and 3308 ± 1449 particles·m− 2, while those in the water column varied between 257.9 ± 53.36 and 1215 ± 276.7 particles·m− 3. With few exceptions there were no significant spatial patterns in either the sediment or water column microplastic densities; with little differences in density between bays and the open coast (P > 0.05). These data indicate that the presence of microplastics were not associated with proximity to land-based sources or population density, but rather is governed by water circulation.
- Full Text: false
- Date Issued: 2015
A re-examination of the type material of Entomoneis paludosa (W Smith) Reimer and its morphology and distribution in African waters
- Richoux, Nicole B, Taylor, J C, Dalu, Tatenda, Froneman, P William
- Authors: Richoux, Nicole B , Taylor, J C , Dalu, Tatenda , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69179 , vital:29440 , https://doi.org/10.5507/fot.2015.002
- Description: The current study aims to enhance the understanding of the distribution and morphology of the diatom Entomoneis paludosa W Smith 1853 in African waters. The type material of Entomoneis paludosa (W Smith) Reimer was examined using light and scanning electron microscopy and the morphological characters were compared with new specimens sampled from a temperate river in South Africa. The wider distribution of this taxon on the African continent is discussed, and its relationship to water quality variables.
- Full Text:
- Date Issued: 2015
- Authors: Richoux, Nicole B , Taylor, J C , Dalu, Tatenda , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69179 , vital:29440 , https://doi.org/10.5507/fot.2015.002
- Description: The current study aims to enhance the understanding of the distribution and morphology of the diatom Entomoneis paludosa W Smith 1853 in African waters. The type material of Entomoneis paludosa (W Smith) Reimer was examined using light and scanning electron microscopy and the morphological characters were compared with new specimens sampled from a temperate river in South Africa. The wider distribution of this taxon on the African continent is discussed, and its relationship to water quality variables.
- Full Text:
- Date Issued: 2015
A review of current DNS TTL practices
- Van Zyl, Ignus, Rudman, Lauren, Irwin, Barry V W
- Authors: Van Zyl, Ignus , Rudman, Lauren , Irwin, Barry V W
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427813 , vital:72464 , https://www.researchgate.net/profile/Barry-Ir-win/publication/327622760_A_review_of_current_DNS_TTL_practices/links/5b9a16e292851c4ba8181b7f/A-review-of-current-DNS-TTL-practices.pdf
- Description: This paper provides insight into legitimate DNS domain Time to Live (TTL) activity captured over two live caching servers from the period January to June 2014. DNS TTL practices are identified and compared between frequently queried domains, with respect to the caching servers. A breakdown of TTL practices by Resource Record type is also given, as well as an analysis on the TTL choices of the most frequent Top Level Domains. An analysis of anomalous TTL values with respect to the gathered data is also presented.
- Full Text:
- Date Issued: 2015
- Authors: Van Zyl, Ignus , Rudman, Lauren , Irwin, Barry V W
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427813 , vital:72464 , https://www.researchgate.net/profile/Barry-Ir-win/publication/327622760_A_review_of_current_DNS_TTL_practices/links/5b9a16e292851c4ba8181b7f/A-review-of-current-DNS-TTL-practices.pdf
- Description: This paper provides insight into legitimate DNS domain Time to Live (TTL) activity captured over two live caching servers from the period January to June 2014. DNS TTL practices are identified and compared between frequently queried domains, with respect to the caching servers. A breakdown of TTL practices by Resource Record type is also given, as well as an analysis on the TTL choices of the most frequent Top Level Domains. An analysis of anomalous TTL values with respect to the gathered data is also presented.
- Full Text:
- Date Issued: 2015
A review of three generations of critical theory: Towards conceptualising critical HESD research
- Authors: Lotz-Sisitka, Heila
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/437136 , vital:73345 , ISBN 9781315852249 , https://www.taylorfrancis.com/chapters/edit/10.4324/9781315852249-17/review-three-generations-critical-theory-heila-lotz-sisitka
- Description: To begin a review of the purpose(s) of ESD research, we must first ask the basic question of the purpose of research generally. Definitions of research normally centre on it comprising sys-tematic investigation which contributes to knowledge or under-standing of phenomena or a problem. A distinction is common-ly drawn between pure or basic research which focuses on understanding phenomena and issues, and applied research where the primary emphasis is on research which contributes to the solution of problems or some systemic improvement ra-ther than knowledge for its own sake. Some commentators see action research as a third category as it is predicated on the researcher being part of the research process which itself is committed to personal or social change. ESD research as an area of interest is perhaps unusual because it accommodates and crosses these categories. It also engages in philosophic research regarding cultural, worldview and ethical dimensions of sustainability education – critically important dimensions of ESD research, but not within the scope of this chapter. Re-search on – say – the relative effect of different pedagogies, or how a learning environ-ment affects learning, may be thought of as basic research, but at another level, ESD research is often purposeful beyond the accumulation of understanding about educational processes.
- Full Text:
- Date Issued: 2015
- Authors: Lotz-Sisitka, Heila
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , book chapter
- Identifier: http://hdl.handle.net/10962/437136 , vital:73345 , ISBN 9781315852249 , https://www.taylorfrancis.com/chapters/edit/10.4324/9781315852249-17/review-three-generations-critical-theory-heila-lotz-sisitka
- Description: To begin a review of the purpose(s) of ESD research, we must first ask the basic question of the purpose of research generally. Definitions of research normally centre on it comprising sys-tematic investigation which contributes to knowledge or under-standing of phenomena or a problem. A distinction is common-ly drawn between pure or basic research which focuses on understanding phenomena and issues, and applied research where the primary emphasis is on research which contributes to the solution of problems or some systemic improvement ra-ther than knowledge for its own sake. Some commentators see action research as a third category as it is predicated on the researcher being part of the research process which itself is committed to personal or social change. ESD research as an area of interest is perhaps unusual because it accommodates and crosses these categories. It also engages in philosophic research regarding cultural, worldview and ethical dimensions of sustainability education – critically important dimensions of ESD research, but not within the scope of this chapter. Re-search on – say – the relative effect of different pedagogies, or how a learning environ-ment affects learning, may be thought of as basic research, but at another level, ESD research is often purposeful beyond the accumulation of understanding about educational processes.
- Full Text:
- Date Issued: 2015