Strike comparison of the compositional variations of the lower group and middle group chromitite seams of the critical zone, Western Bushveld complex
- Authors: Doig, Heather Leslie
- Date: 2000
- Subjects: Chromite -- South Africa , Geology -- South Africa , Mineralogy -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5005 , http://hdl.handle.net/10962/d1005618
- Description: The variations in the composition, specifically the Cr20 S content and the Cr:Fe ratio, and the morphology of the Lower Group (LG) and Middle Group (MG) chromitite seams of the Critical Zone (CZ) across the western Bushveld Complex, including the Ruighoek and Brits sections, is investigated by means of whole-rock chemical data, both major and trace elements analysis, XRD and electron microprobe data. As a result ofthe paucity of exposed or developed LG1 - LG5 chromitite seams in the western Bushveld Complex, this study is confined to the investigation of the compositional variations of the LG6 to MG4 chromitite seams. In only one section, the Ruighoek section, was the entire succession of chromitite seams, from the LG1 - MG4, exposed. The silicate host rocks from the LG6 pyroxenite footwall to the collar of the CC2 drillcore (lower uCZ) in the Rustenburg section were sampled. This study reviews the compositional trends of the silicate host rocks, as the compositional variations of the chromitite seams reflect the chemical evolution of the host cumulate environment and, to a lesser degree, the composition onhe interstitial mineral phases in the chromitite seams. The compositional variations of the LG and MG chromitite seams are attributed to the compositional contrast between the replenishing magma and the resident magma. The chemical trends of the LG and MG chromitite layers and the host cumUlate rOCKS do not support the existence of two compositionalfy dissimilar magmas in the CZ, rather the cyclic layering of the CZ and the chemical variations of the chromitite seams are attributed to the mixing of primitive magma with the resident magma, both of which have essentially similar compositions. The compositional variations of the LG and MG chromitite seams along strike away from the supposed feeder site (Union section) to the distal facies (Brits section) are attributed to the advanced compositional contrast between the resident magma and the replenishing primitive magma pulses. The CZ is characterized by reversals in fractionation trends and this is attributed to the compositional evolution of the parental magma and not to the replenishment of the resident magma by influxes of grossly dissimilar magma compositions. The Cr20 S content and the Cr:Fe ratio of the MG chromitite layers increase from the Ruighoek (near proximal) section to the Brits section (distal facies). This is attributed to the advanced compositional contrasts between the resident magma and the replenishing primitive magma. In contrast, the Cr20 3 content and Cr:Fe ratios ofthe LG6 and LG8a chromitite seams decreases eastwards from the Ruighoek section. The average Cr:Fe ratio for the western Bushveld Complex is between 1.5 and\2.0, nonetheless, a progressively lower Cr:Fe ratio is noted from the LG1 chromitite up through to the MG4 chromitite seam in the Ruighoek section. tn the LG2 - LG4 chromitite interval a deviation to higher.lratios is encountered. A progressive substitution of Cr by AT and Fe in the Cr-spinel crystal lattice characterizes the chromitite succession from the LG1 seam up through the chromitite succession to MG4. The petrogeneSiS of the chromitite seams of the CZ is attributed to magma mixing and fractional crystallization of a single magma type.
- Full Text:
- Date Issued: 2000
- Authors: Doig, Heather Leslie
- Date: 2000
- Subjects: Chromite -- South Africa , Geology -- South Africa , Mineralogy -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5005 , http://hdl.handle.net/10962/d1005618
- Description: The variations in the composition, specifically the Cr20 S content and the Cr:Fe ratio, and the morphology of the Lower Group (LG) and Middle Group (MG) chromitite seams of the Critical Zone (CZ) across the western Bushveld Complex, including the Ruighoek and Brits sections, is investigated by means of whole-rock chemical data, both major and trace elements analysis, XRD and electron microprobe data. As a result ofthe paucity of exposed or developed LG1 - LG5 chromitite seams in the western Bushveld Complex, this study is confined to the investigation of the compositional variations of the LG6 to MG4 chromitite seams. In only one section, the Ruighoek section, was the entire succession of chromitite seams, from the LG1 - MG4, exposed. The silicate host rocks from the LG6 pyroxenite footwall to the collar of the CC2 drillcore (lower uCZ) in the Rustenburg section were sampled. This study reviews the compositional trends of the silicate host rocks, as the compositional variations of the chromitite seams reflect the chemical evolution of the host cumulate environment and, to a lesser degree, the composition onhe interstitial mineral phases in the chromitite seams. The compositional variations of the LG and MG chromitite seams are attributed to the compositional contrast between the replenishing magma and the resident magma. The chemical trends of the LG and MG chromitite layers and the host cumUlate rOCKS do not support the existence of two compositionalfy dissimilar magmas in the CZ, rather the cyclic layering of the CZ and the chemical variations of the chromitite seams are attributed to the mixing of primitive magma with the resident magma, both of which have essentially similar compositions. The compositional variations of the LG and MG chromitite seams along strike away from the supposed feeder site (Union section) to the distal facies (Brits section) are attributed to the advanced compositional contrast between the resident magma and the replenishing primitive magma pulses. The CZ is characterized by reversals in fractionation trends and this is attributed to the compositional evolution of the parental magma and not to the replenishment of the resident magma by influxes of grossly dissimilar magma compositions. The Cr20 S content and the Cr:Fe ratio of the MG chromitite layers increase from the Ruighoek (near proximal) section to the Brits section (distal facies). This is attributed to the advanced compositional contrasts between the resident magma and the replenishing primitive magma. In contrast, the Cr20 3 content and Cr:Fe ratios ofthe LG6 and LG8a chromitite seams decreases eastwards from the Ruighoek section. The average Cr:Fe ratio for the western Bushveld Complex is between 1.5 and\2.0, nonetheless, a progressively lower Cr:Fe ratio is noted from the LG1 chromitite up through to the MG4 chromitite seam in the Ruighoek section. tn the LG2 - LG4 chromitite interval a deviation to higher.lratios is encountered. A progressive substitution of Cr by AT and Fe in the Cr-spinel crystal lattice characterizes the chromitite succession from the LG1 seam up through the chromitite succession to MG4. The petrogeneSiS of the chromitite seams of the CZ is attributed to magma mixing and fractional crystallization of a single magma type.
- Full Text:
- Date Issued: 2000
Structural and synthetic investigations of South African marine natural products
- Authors: Beukes, Denzil Ronwynne
- Date: 2000
- Subjects: Natural products -- South Africa Marine invertebrates -- South Africa Marine metabolites -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4350 , http://hdl.handle.net/10962/d1005015
- Description: A chemical investigation of six different marine invertebrates, collected along the South African coastline, resulted in the isolation and structural elucidation of fifteen previously undescribed secondary metabolites along with seven known compounds. The structures of the new metabolites were determined by a combination of spectroscopic and chemical methods. The endemic false limpet Siphonaria capensis was shown to contain two unusual polypropionate metabolites capensinone (162) and capensifuranone (163) as well as 2,4,6,8-tetramethyl-2-undecenoic acid (164) and the known polypropionates (E)- and (Z)siphonarienfuranone (149 and 161). Capensinone is the first example of a marine polypropionate containing a cyc1opentenone moiety. An investigation of the endemic South African soft coral Pieterfaurea unilobata yielded six new, highly oxygenated, pregnadiene sterols (180-185) and the known metabolite (169). Compounds 180-185 are the first pregnadienes obtained from the marine environment containing a C-7 substituent. An alternative procedure for the quick assignment of the absolute configuration at C-3 in this series of compounds was proposed. A companson of the pyrroloiminoquinone alkaloids of three undescribed l'}trunculid sponges resulted in the isolation of 3-dih¥drodiscorhabdin C (243), 3-dihydrodiscorhabdin B (244), discorhabdin H (197) and the previously reported alkaloids discorhabdin A (189) and discorhabdin D (192). While all three sponges were found to be morphologically different they all contained discorhabdin A as the major metabolite and discorhabdin H as one of their minor metabolites. It was found that a feature common to most of the South African latrunculid sponges is the reduction of the C-3 carbonyl gr,o up in some of the minor metabolites. The indole alkaloids, dilemmaones A-C (261-263), containing an unusual cyc1opentanone-indole skeleton, were isolated in trace amounts by bioassay guided fractionation of an extract obtained from a mixed collection of sponges collected near Cape Town. In an attempt to acquire more of these novel compounds for further investigation of their biological activity, several synthetic strategies towards their total synthesis were explored. A key feature of these approaches was the exploitation of the regioselective Gassman's artha-alkylation procedure for the introduction of an aromatic methyl substituent.
- Full Text:
- Date Issued: 2000
- Authors: Beukes, Denzil Ronwynne
- Date: 2000
- Subjects: Natural products -- South Africa Marine invertebrates -- South Africa Marine metabolites -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4350 , http://hdl.handle.net/10962/d1005015
- Description: A chemical investigation of six different marine invertebrates, collected along the South African coastline, resulted in the isolation and structural elucidation of fifteen previously undescribed secondary metabolites along with seven known compounds. The structures of the new metabolites were determined by a combination of spectroscopic and chemical methods. The endemic false limpet Siphonaria capensis was shown to contain two unusual polypropionate metabolites capensinone (162) and capensifuranone (163) as well as 2,4,6,8-tetramethyl-2-undecenoic acid (164) and the known polypropionates (E)- and (Z)siphonarienfuranone (149 and 161). Capensinone is the first example of a marine polypropionate containing a cyc1opentenone moiety. An investigation of the endemic South African soft coral Pieterfaurea unilobata yielded six new, highly oxygenated, pregnadiene sterols (180-185) and the known metabolite (169). Compounds 180-185 are the first pregnadienes obtained from the marine environment containing a C-7 substituent. An alternative procedure for the quick assignment of the absolute configuration at C-3 in this series of compounds was proposed. A companson of the pyrroloiminoquinone alkaloids of three undescribed l'}trunculid sponges resulted in the isolation of 3-dih¥drodiscorhabdin C (243), 3-dihydrodiscorhabdin B (244), discorhabdin H (197) and the previously reported alkaloids discorhabdin A (189) and discorhabdin D (192). While all three sponges were found to be morphologically different they all contained discorhabdin A as the major metabolite and discorhabdin H as one of their minor metabolites. It was found that a feature common to most of the South African latrunculid sponges is the reduction of the C-3 carbonyl gr,o up in some of the minor metabolites. The indole alkaloids, dilemmaones A-C (261-263), containing an unusual cyc1opentanone-indole skeleton, were isolated in trace amounts by bioassay guided fractionation of an extract obtained from a mixed collection of sponges collected near Cape Town. In an attempt to acquire more of these novel compounds for further investigation of their biological activity, several synthetic strategies towards their total synthesis were explored. A key feature of these approaches was the exploitation of the regioselective Gassman's artha-alkylation procedure for the introduction of an aromatic methyl substituent.
- Full Text:
- Date Issued: 2000
Studies of the population structure and generic diversity of domesticated and "wild" ostriches (Struthio camelus)
- Bezuidenhout, Cornelius Carlos
- Authors: Bezuidenhout, Cornelius Carlos
- Date: 2000
- Subjects: Ostriches Ostriches -- Genetics Ostriches -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3907 , http://hdl.handle.net/10962/d1003966
- Description: DNA sequencing and restriction fragment length polymorphism analysis (RFLP) of polymerase chain reaction (PCR) amplified mitochondrial DNA fragments, and random amplified polymorphic DNA sequence (RAPD) analysis were techniques evaluated in this study for applicability in the investigation various aspects of genetic diversity within the ostrich (Struthio camelus). The genetic aspects that were investigated were (i) relationships between ostrich subspecies, (ii) genetic variability between and within domesticated populations of southern African ostriches (Struthio camelus australis), (iii) linking egg production in domesticated ostriches to RAPD profiles, and (iv) determining the zygosity of twin ostriches. In the first part of this study DNA sequencing and the polymerase chain reaction - restriction fragment length polymorphism (PCR-RFLP) methods were evaluated for resolving genetic differences in the small mtDNA fragments ofthe ostrich. DNA sequencing ofPCR amplified 450 bp 12S rRNA gene fragments of representatives from the southern African population ostrich (S.c. australis) did not reveal any differences between the populatiohs from different geographical areas, representing ostrich lineages with different breeding histories. The PCRRFLP analysis ofmtDNA fragments (450 bp 12S rRNA gene fragment and 550 bp D-loop region) also did not reveal any genetic variability between the domesticated s.,c. australis populations included in this study. PCR-RFLP analysis of a 450 bp 12S rRNA gene fragment, however, showed differences between the subspecies s.c. australis and s.c. molybdophanes. The proportion of shared fragments (F) between these two subspecies was 0.286 and nucleotide sequence divergence estimated at 8.9 %. Divergence time between these two subspecies was estimated at 4.5 million years ago. The data presented from this study are comparable to the data from a previous study in which the entire mitochondrial genome and a larger number of restriction enzymes were used. The PCR-RFLP method thus demonstrated its usefulness for genetic studies of ostriches at thesubspecies level. The sequences used in this study could not reveal any markers that were useful for genetic studies of ostriches at the population level. In the second part of the study the RAPD method was evaluated for application in the genetic studies of ostriches. RAPD profiles, based on three RAPD primers, revealed differences between three subspecies of ostriches and indicated relationships between these subspecies that are consistent with observations from other studies. The numerical analysis of pooled and individual primer data demonstrated that the subspecies s.c. australis is more closely related to s.c. massaicus than to s.c. molybdophanes. RAPD marker differences between s.c. molybdophanes on the one hand, and s.c. massaicus and s.c. australis on the other is also consistent with observations from studies that proposed separate specie~ status for s.c. molybdophanes. RAPD analysis by five primers revealed geographic variation between s.c. australis populations. The clustering patterns observed in the dendrograms and Neighbour Joining Trees generated by computer programs showed trends of separating ostric1;t populations into geographical groups, possibly reflecting their different breeding histories. In the RAPD profiles of the inbred population, band-sharing was generally greater than in the outbreeding group. RAPD analysis thus showed that it may be a useful method in the population studies of domesticated S. c. australis. RAPDs also generated data that grouped ostriches according to trends in egg production capabilities. Analysis ofRAPD profiles by computer software showed a Neighbour Joining Tree and a dendrogram that predominantly grouped ostriches into clusters associated with either good or poor egg production. Evidence supporting the suitability of RAPDs as a tool in breeding programmes of ostriches was thus provided by this study. RAPDs also provided data, demonstrating that two sets of ostrich twins were non-identical twins. It was demonstrated by this study that RAPDs analysis may be a useful technique for applying to (1) systematic (2) population (3) breeding and (4) twin studies of ostriches (Struthio camelus).
- Full Text:
- Date Issued: 2000
- Authors: Bezuidenhout, Cornelius Carlos
- Date: 2000
- Subjects: Ostriches Ostriches -- Genetics Ostriches -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3907 , http://hdl.handle.net/10962/d1003966
- Description: DNA sequencing and restriction fragment length polymorphism analysis (RFLP) of polymerase chain reaction (PCR) amplified mitochondrial DNA fragments, and random amplified polymorphic DNA sequence (RAPD) analysis were techniques evaluated in this study for applicability in the investigation various aspects of genetic diversity within the ostrich (Struthio camelus). The genetic aspects that were investigated were (i) relationships between ostrich subspecies, (ii) genetic variability between and within domesticated populations of southern African ostriches (Struthio camelus australis), (iii) linking egg production in domesticated ostriches to RAPD profiles, and (iv) determining the zygosity of twin ostriches. In the first part of this study DNA sequencing and the polymerase chain reaction - restriction fragment length polymorphism (PCR-RFLP) methods were evaluated for resolving genetic differences in the small mtDNA fragments ofthe ostrich. DNA sequencing ofPCR amplified 450 bp 12S rRNA gene fragments of representatives from the southern African population ostrich (S.c. australis) did not reveal any differences between the populatiohs from different geographical areas, representing ostrich lineages with different breeding histories. The PCRRFLP analysis ofmtDNA fragments (450 bp 12S rRNA gene fragment and 550 bp D-loop region) also did not reveal any genetic variability between the domesticated s.,c. australis populations included in this study. PCR-RFLP analysis of a 450 bp 12S rRNA gene fragment, however, showed differences between the subspecies s.c. australis and s.c. molybdophanes. The proportion of shared fragments (F) between these two subspecies was 0.286 and nucleotide sequence divergence estimated at 8.9 %. Divergence time between these two subspecies was estimated at 4.5 million years ago. The data presented from this study are comparable to the data from a previous study in which the entire mitochondrial genome and a larger number of restriction enzymes were used. The PCR-RFLP method thus demonstrated its usefulness for genetic studies of ostriches at thesubspecies level. The sequences used in this study could not reveal any markers that were useful for genetic studies of ostriches at the population level. In the second part of the study the RAPD method was evaluated for application in the genetic studies of ostriches. RAPD profiles, based on three RAPD primers, revealed differences between three subspecies of ostriches and indicated relationships between these subspecies that are consistent with observations from other studies. The numerical analysis of pooled and individual primer data demonstrated that the subspecies s.c. australis is more closely related to s.c. massaicus than to s.c. molybdophanes. RAPD marker differences between s.c. molybdophanes on the one hand, and s.c. massaicus and s.c. australis on the other is also consistent with observations from studies that proposed separate specie~ status for s.c. molybdophanes. RAPD analysis by five primers revealed geographic variation between s.c. australis populations. The clustering patterns observed in the dendrograms and Neighbour Joining Trees generated by computer programs showed trends of separating ostric1;t populations into geographical groups, possibly reflecting their different breeding histories. In the RAPD profiles of the inbred population, band-sharing was generally greater than in the outbreeding group. RAPD analysis thus showed that it may be a useful method in the population studies of domesticated S. c. australis. RAPDs also generated data that grouped ostriches according to trends in egg production capabilities. Analysis ofRAPD profiles by computer software showed a Neighbour Joining Tree and a dendrogram that predominantly grouped ostriches into clusters associated with either good or poor egg production. Evidence supporting the suitability of RAPDs as a tool in breeding programmes of ostriches was thus provided by this study. RAPDs also provided data, demonstrating that two sets of ostrich twins were non-identical twins. It was demonstrated by this study that RAPDs analysis may be a useful technique for applying to (1) systematic (2) population (3) breeding and (4) twin studies of ostriches (Struthio camelus).
- Full Text:
- Date Issued: 2000
Stuffed birds on trees: an historical review of avian systematics in southern Africa
- Authors: Craig, Adrian J F K
- Date: 2000
- Language: English
- Type: Article
- Identifier: vital:6931 , http://hdl.handle.net/10962/d1011949
- Description: Avian systematics in southern Africa has been heavily dependent on a small number of museum-based specialists. They produced bird checklists which prescribed the names to be used by other scientists. After an initial phase of cataloguing the avifauna, a major preoccupation was the description of geographical variation, which was documented in an extensive subspecific nomenclature. Until recent years, few African ornithologists have been involved in systematics as a biological discipline. This historical overview considers the contribution of particular individuals from Andrew Smith to Phillip Clancey.
- Full Text: false
- Date Issued: 2000
- Authors: Craig, Adrian J F K
- Date: 2000
- Language: English
- Type: Article
- Identifier: vital:6931 , http://hdl.handle.net/10962/d1011949
- Description: Avian systematics in southern Africa has been heavily dependent on a small number of museum-based specialists. They produced bird checklists which prescribed the names to be used by other scientists. After an initial phase of cataloguing the avifauna, a major preoccupation was the description of geographical variation, which was documented in an extensive subspecific nomenclature. Until recent years, few African ornithologists have been involved in systematics as a biological discipline. This historical overview considers the contribution of particular individuals from Andrew Smith to Phillip Clancey.
- Full Text: false
- Date Issued: 2000
Stump size and the number of coppice shoots for selected savanna tree species
- Authors: Shackleton, Charlie M
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181896 , vital:43778 , xlink:href="https://doi.org/10.1016/S0254-6299(15)31074-7"
- Description: Management of coppice dynamics of indigenous savanna trees could assist in increasing the regrowth rates or number of coppice shoots produced. This would be useful in natural resource management programmes to promote sustainable resource management. This study examined the influence of cutting height, stem size and surface area on the number of coppice shoots produced for twelve savanna species from a communal land in the Bushbuckndge lowveld. All species exhibited a strong coppicing ability following cutting. The number of shoots per stump was most frequently related to cutting height, although this was not always the most significant predictor. There were clear differences between species with respect to the number of shoots per unit surface area, the highest being for Albizia harveyii and the least Piliostlgma thonningii. The taller the potential height of a species, the fewer were the coppice shoots per stump surface area.
- Full Text:
- Date Issued: 2000
- Authors: Shackleton, Charlie M
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181896 , vital:43778 , xlink:href="https://doi.org/10.1016/S0254-6299(15)31074-7"
- Description: Management of coppice dynamics of indigenous savanna trees could assist in increasing the regrowth rates or number of coppice shoots produced. This would be useful in natural resource management programmes to promote sustainable resource management. This study examined the influence of cutting height, stem size and surface area on the number of coppice shoots produced for twelve savanna species from a communal land in the Bushbuckndge lowveld. All species exhibited a strong coppicing ability following cutting. The number of shoots per stump was most frequently related to cutting height, although this was not always the most significant predictor. There were clear differences between species with respect to the number of shoots per unit surface area, the highest being for Albizia harveyii and the least Piliostlgma thonningii. The taller the potential height of a species, the fewer were the coppice shoots per stump surface area.
- Full Text:
- Date Issued: 2000
Suba
- Rokia Traore (author, composer, arranger, interpreter, lead singer, guitar), Coco Mbassi, Rokia Traore (chorus), Andra Kouyate (N'Goni Ba), Label Bleu
- Authors: Rokia Traore (author, composer, arranger, interpreter, lead singer, guitar) , Coco Mbassi, Rokia Traore (chorus) , Andra Kouyate (N'Goni Ba) , Label Bleu
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Cameroon Yaounde f-cm
- Language: Bambara
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/131028 , vital:36516 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC49-03
- Description: Non-Malian vocal style and multilayered singing accompanied by traditional Malian instuments played with a modern edge
- Full Text: false
- Date Issued: 2000
- Authors: Rokia Traore (author, composer, arranger, interpreter, lead singer, guitar) , Coco Mbassi, Rokia Traore (chorus) , Andra Kouyate (N'Goni Ba) , Label Bleu
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Cameroon Yaounde f-cm
- Language: Bambara
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/131028 , vital:36516 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC49-03
- Description: Non-Malian vocal style and multilayered singing accompanied by traditional Malian instuments played with a modern edge
- Full Text: false
- Date Issued: 2000
Sulphide-enhanced hydrolysis of primary sewage sludge : implications for the bioremediation of sulphate-enriched wastewaters
- Whittington-Jones, Kevin John
- Authors: Whittington-Jones, Kevin John
- Date: 2000
- Subjects: Bioremediation Sewage sludge Hydrolysis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3910 , http://hdl.handle.net/10962/d1003969
- Description: The potential application of sulphate reducing bacteria for the bioremediation of acid mine drainage has already been recognised, and offers significant financial advantages over conventional chemical treatment approaches. Although the technology has been demonstrated successfully on both small- and large-scale, it’s extensive implementation has been constrained by the provision of suitable and cost effective electron donor and carbon sources. Primary sewage sludge is readily available in large quantities, but the slow rate of solubilization and low yield of soluble products do not apparently favour its use for this application. A number of pre-treatment steps have been introduced in an attempt to improve the yield and rates under methanogenic conditions. However, although early work suggested that degradation of lignocellulose and proteins may be more rapid under sulphate reducing conditions, the fate of primary sewage sludge under these conditions has been ignored. It was proposed that by combining the hydrolysis of primary sewage sludge and biological sulphate reduction, in a settling sludge bed, both processes would be enhanced. The aim of this study was to test this hypothesis on laboratory- and pilot-scale, and attempt to elucidate the underlying mechanism involved. The solubilization of primary sewage sludge was enhanced in the presence of sulphate reduction in continuous laboratory-scale reactors. Particulate matter accumulated in the bed of non-sulphidogenic systems, but not in sulphidogenic ones. This was attributed to increased solubilization and the smaller average floc size in the latter. Solubilization occurred within the settling sludge bed of the reactors, and offered a possible explanation for the better performance of the multiple- over single-stage reactor. A pilot-scale Falling Sludge Bed Reactor was constructed at Grootvlei Gold Mine, Springs, South Africa, and resulted in the solubilization of more than 70% of the influent primary sewage sludge. The system was also found to be highly resilient to severe perturbations, and returned rapidly to steady-state. Flask studies revealed that the hydrolysis of both proteins and complex carbohydrates was accelerated in the presence of biological sulphate reduction or sulphide. A study of the enzymology of sludge digestion revealed that sulphate reduction had little direct effect on the activity of the hydrolytic enzymes, but that reactor design was critical in the prevention of washout of these enzymes. Finally, a descriptive model was developed to explain the enhanced hydrolysis of primary sewage sludge. The model incorporated the effect of sulphidogenesis on floc fracture and reflocculation, and likely implications for mass transfer limitations.
- Full Text:
- Date Issued: 2000
- Authors: Whittington-Jones, Kevin John
- Date: 2000
- Subjects: Bioremediation Sewage sludge Hydrolysis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3910 , http://hdl.handle.net/10962/d1003969
- Description: The potential application of sulphate reducing bacteria for the bioremediation of acid mine drainage has already been recognised, and offers significant financial advantages over conventional chemical treatment approaches. Although the technology has been demonstrated successfully on both small- and large-scale, it’s extensive implementation has been constrained by the provision of suitable and cost effective electron donor and carbon sources. Primary sewage sludge is readily available in large quantities, but the slow rate of solubilization and low yield of soluble products do not apparently favour its use for this application. A number of pre-treatment steps have been introduced in an attempt to improve the yield and rates under methanogenic conditions. However, although early work suggested that degradation of lignocellulose and proteins may be more rapid under sulphate reducing conditions, the fate of primary sewage sludge under these conditions has been ignored. It was proposed that by combining the hydrolysis of primary sewage sludge and biological sulphate reduction, in a settling sludge bed, both processes would be enhanced. The aim of this study was to test this hypothesis on laboratory- and pilot-scale, and attempt to elucidate the underlying mechanism involved. The solubilization of primary sewage sludge was enhanced in the presence of sulphate reduction in continuous laboratory-scale reactors. Particulate matter accumulated in the bed of non-sulphidogenic systems, but not in sulphidogenic ones. This was attributed to increased solubilization and the smaller average floc size in the latter. Solubilization occurred within the settling sludge bed of the reactors, and offered a possible explanation for the better performance of the multiple- over single-stage reactor. A pilot-scale Falling Sludge Bed Reactor was constructed at Grootvlei Gold Mine, Springs, South Africa, and resulted in the solubilization of more than 70% of the influent primary sewage sludge. The system was also found to be highly resilient to severe perturbations, and returned rapidly to steady-state. Flask studies revealed that the hydrolysis of both proteins and complex carbohydrates was accelerated in the presence of biological sulphate reduction or sulphide. A study of the enzymology of sludge digestion revealed that sulphate reduction had little direct effect on the activity of the hydrolytic enzymes, but that reactor design was critical in the prevention of washout of these enzymes. Finally, a descriptive model was developed to explain the enhanced hydrolysis of primary sewage sludge. The model incorporated the effect of sulphidogenesis on floc fracture and reflocculation, and likely implications for mass transfer limitations.
- Full Text:
- Date Issued: 2000
Sumbera
- Ma Sane, Do Sagna, Yade (vocals), Toto (guitar), Race, Magx Thiam (keyboards), Galass, Mbaye Joola (percussion), Beuz (drums), Studio 2000
- Authors: Ma Sane, Do Sagna, Yade (vocals) , Toto (guitar) , Race, Magx Thiam (keyboards) , Galass, Mbaye Joola (percussion) , Beuz (drums) , Studio 2000
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Senegal Thies f-sg
- Language: Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/128108 , vital:36076 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC10-01
- Description: Senegalese band featuring singing accompanied by keyboard, guitar and percussion
- Full Text: false
- Date Issued: 2000
- Authors: Ma Sane, Do Sagna, Yade (vocals) , Toto (guitar) , Race, Magx Thiam (keyboards) , Galass, Mbaye Joola (percussion) , Beuz (drums) , Studio 2000
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Senegal Thies f-sg
- Language: Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/128108 , vital:36076 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC10-01
- Description: Senegalese band featuring singing accompanied by keyboard, guitar and percussion
- Full Text: false
- Date Issued: 2000
Sutura
- Ajah Sy ( lead vocals, author, composer, chorus), Biram Ndeck Ndiaye, El Hadji Niang (arrangement), Lamine Faye (guitar), El Hadji Niang (bass), Bakane Seck (percussion), Marie Codou Pouye, Ajah Sy, Abdourahmane Diallo,Missala man, Aly Hachem, Mame Gor Mboup (chorus), El Hadji Niang, Aly Hachem, Ousmane Wade (keyboards), Studio 2000
- Authors: Ajah Sy ( lead vocals, author, composer, chorus) , Biram Ndeck Ndiaye , El Hadji Niang (arrangement) , Lamine Faye (guitar) , El Hadji Niang (bass) , Bakane Seck (percussion) , Marie Codou Pouye, Ajah Sy, Abdourahmane Diallo,Missala man, Aly Hachem, Mame Gor Mboup (chorus) , El Hadji Niang, Aly Hachem, Ousmane Wade (keyboards) , Studio 2000
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Senegal Dakar f-sg
- Language: Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129350 , vital:36264 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC27-02
- Description: A homage to women in general and rural women in particular, for courageously and stoically facing their arduous socetal burden
- Full Text: false
- Date Issued: 2000
- Authors: Ajah Sy ( lead vocals, author, composer, chorus) , Biram Ndeck Ndiaye , El Hadji Niang (arrangement) , Lamine Faye (guitar) , El Hadji Niang (bass) , Bakane Seck (percussion) , Marie Codou Pouye, Ajah Sy, Abdourahmane Diallo,Missala man, Aly Hachem, Mame Gor Mboup (chorus) , El Hadji Niang, Aly Hachem, Ousmane Wade (keyboards) , Studio 2000
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Senegal Dakar f-sg
- Language: Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129350 , vital:36264 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC27-02
- Description: A homage to women in general and rural women in particular, for courageously and stoically facing their arduous socetal burden
- Full Text: false
- Date Issued: 2000
Synthetic and analytical studies of biomimetic metal complexes
- Authors: Wellington, Kevin Wayne
- Date: 2000
- Subjects: Biomimetics Metal complexes Metalloenzymes Metal ions Ligands
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4377 , http://hdl.handle.net/10962/d1005042
- Description: Several series of novel diamido, diamino and diimino ligands containing different spacers and heterocyclic donors have been synthesised. The spacers include the flexible biphenyl, the rigid 1,1 O-phenanthroline and various acyclic moieties, while the heterocyclic donors comprise pyridine, imidazole or benzimidazole groups. These ligands have been designed to complex copper and act as biomimetic models of the active site of the enzyme, tyrosinase, and their complexes with copper, cobalt, nickel and platinum have been analysed using microanalytical, IR, UV-Visible and cyclic voltammetric techniques. Attempted reduction of the biphenyl-based diimino ligands resulted in an unexpected intramolecular cyclisation affording azepine derivatives, the structures of which were elucidated with the aid of single crystal X-ray analysis of cobalt and nickel complexes. Computer modelling methods have been used to explore the conformational options of the copper complexes, and to assess the accessibility of the dinuclear copper site to substrate molecules. Computer modelling has also been used, in conjunction with the available analytical data, to visualise the possible structures of selected ligands and complexes. The copper complexes, although predominantly polymeric, were evaluated as biomimetic catalysts using 3,5-di-t-butylphenol and 3,5-di-t-butylcatechol as substrates. Some of the complexes clearly displayed biomimetic potential, exhibiting both phenolase and catecholase activity.
- Full Text:
- Date Issued: 2000
- Authors: Wellington, Kevin Wayne
- Date: 2000
- Subjects: Biomimetics Metal complexes Metalloenzymes Metal ions Ligands
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4377 , http://hdl.handle.net/10962/d1005042
- Description: Several series of novel diamido, diamino and diimino ligands containing different spacers and heterocyclic donors have been synthesised. The spacers include the flexible biphenyl, the rigid 1,1 O-phenanthroline and various acyclic moieties, while the heterocyclic donors comprise pyridine, imidazole or benzimidazole groups. These ligands have been designed to complex copper and act as biomimetic models of the active site of the enzyme, tyrosinase, and their complexes with copper, cobalt, nickel and platinum have been analysed using microanalytical, IR, UV-Visible and cyclic voltammetric techniques. Attempted reduction of the biphenyl-based diimino ligands resulted in an unexpected intramolecular cyclisation affording azepine derivatives, the structures of which were elucidated with the aid of single crystal X-ray analysis of cobalt and nickel complexes. Computer modelling methods have been used to explore the conformational options of the copper complexes, and to assess the accessibility of the dinuclear copper site to substrate molecules. Computer modelling has also been used, in conjunction with the available analytical data, to visualise the possible structures of selected ligands and complexes. The copper complexes, although predominantly polymeric, were evaluated as biomimetic catalysts using 3,5-di-t-butylphenol and 3,5-di-t-butylcatechol as substrates. Some of the complexes clearly displayed biomimetic potential, exhibiting both phenolase and catecholase activity.
- Full Text:
- Date Issued: 2000
Taara
- Didier Sourou Awadi aka DJ Awadi (performer), Amadou Barry aka Doug E Tee or Duggy-Tee (performer), Positive Black Soul (band name aka PBS), MALI K7 S.A. Ali Furka Toure Associe, Bamako
- Authors: Didier Sourou Awadi aka DJ Awadi (performer) , Amadou Barry aka Doug E Tee or Duggy-Tee (performer) , Positive Black Soul (band name aka PBS) , MALI K7 S.A. Ali Furka Toure Associe, Bamako
- Date: 2000
- Subjects: Rap (Music) , Folk music , Africa Senegal Dakar f-sg
- Language: Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129785 , vital:36331 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC33-03
- Description: Senegalese hip hop song accompanied by traditional Senegalese instruments
- Full Text: false
- Date Issued: 2000
- Authors: Didier Sourou Awadi aka DJ Awadi (performer) , Amadou Barry aka Doug E Tee or Duggy-Tee (performer) , Positive Black Soul (band name aka PBS) , MALI K7 S.A. Ali Furka Toure Associe, Bamako
- Date: 2000
- Subjects: Rap (Music) , Folk music , Africa Senegal Dakar f-sg
- Language: Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129785 , vital:36331 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC33-03
- Description: Senegalese hip hop song accompanied by traditional Senegalese instruments
- Full Text: false
- Date Issued: 2000
Tama
- Adama Drame (performer, arranger, composer, djembe, tama, doumdoum, chekere, voice, harmonica), Yacouba Kone (djembe), Bakari Doumbia (zin-zin), Mamadou Diabate ( balafon), Djesou Mory Kante (accoustic and electric guitar), Adjara Cisse (lead vocal), Oulare, Mariame Sylla, Tagaly (chorus), Adama Troare (accoustic guitar), Augustin Lompo (bass), Bassirou Sanou (flute), Tinminu Adio (tama), Brass: Andre Laourou, Dadie, Franck Desamin, Dramane Kienou (djembe accompaniment), Lamine Soumano (kora), Seydoni Production B.F.
- Authors: Adama Drame (performer, arranger, composer, djembe, tama, doumdoum, chekere, voice, harmonica) , Yacouba Kone (djembe) , Bakari Doumbia (zin-zin) , Mamadou Diabate ( balafon) , Djesou Mory Kante (accoustic and electric guitar) , Adjara Cisse (lead vocal) , Oulare, Mariame Sylla, Tagaly (chorus) , Adama Troare (accoustic guitar) , Augustin Lompo (bass) , Bassirou Sanou (flute) , Tinminu Adio (tama) , Brass: Andre Laourou, Dadie, Franck Desamin , Dramane Kienou (djembe accompaniment) , Lamine Soumano (kora) , Seydoni Production B.F.
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Burkina Faso Ouagadougou f-uv
- Language: French
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/128725 , vital:36145 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC14-03
- Description: Music from Burkino Faso played and sung in the griot style commenting on historical and contemporary events
- Full Text: false
- Date Issued: 2000
- Authors: Adama Drame (performer, arranger, composer, djembe, tama, doumdoum, chekere, voice, harmonica) , Yacouba Kone (djembe) , Bakari Doumbia (zin-zin) , Mamadou Diabate ( balafon) , Djesou Mory Kante (accoustic and electric guitar) , Adjara Cisse (lead vocal) , Oulare, Mariame Sylla, Tagaly (chorus) , Adama Troare (accoustic guitar) , Augustin Lompo (bass) , Bassirou Sanou (flute) , Tinminu Adio (tama) , Brass: Andre Laourou, Dadie, Franck Desamin , Dramane Kienou (djembe accompaniment) , Lamine Soumano (kora) , Seydoni Production B.F.
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Burkina Faso Ouagadougou f-uv
- Language: French
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/128725 , vital:36145 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC14-03
- Description: Music from Burkino Faso played and sung in the griot style commenting on historical and contemporary events
- Full Text: false
- Date Issued: 2000
Tchwa
- Rokia Traore (author, composer, arranger, interpreter, lead singer, guitar, chorus), Bouboucar Traore (singer), Abdul Wahab Berthe (bass), Andra Kouyate (N'Goni), Sidiki Camara (percussion), Label Bleu
- Authors: Rokia Traore (author, composer, arranger, interpreter, lead singer, guitar, chorus) , Bouboucar Traore (singer) , Abdul Wahab Berthe (bass) , Andra Kouyate (N'Goni) , Sidiki Camara (percussion) , Label Bleu
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Mali Bamako f-ml
- Language: Bambara
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/131136 , vital:36527 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC49-10
- Description: Non-Malian vocal style and multilayered singing accompanied by traditional Malian instuments played with a modern edge
- Full Text: false
- Date Issued: 2000
- Authors: Rokia Traore (author, composer, arranger, interpreter, lead singer, guitar, chorus) , Bouboucar Traore (singer) , Abdul Wahab Berthe (bass) , Andra Kouyate (N'Goni) , Sidiki Camara (percussion) , Label Bleu
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Mali Bamako f-ml
- Language: Bambara
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/131136 , vital:36527 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC49-10
- Description: Non-Malian vocal style and multilayered singing accompanied by traditional Malian instuments played with a modern edge
- Full Text: false
- Date Issued: 2000
Testimony
- Peter Gabriels Muonagor (written, arranged, produced and composed by), Tosia Alesh (arranged and produced by), Studio 2000
- Authors: Peter Gabriels Muonagor (written, arranged, produced and composed by) , Tosia Alesh (arranged and produced by) , Studio 2000
- Date: 2000
- Subjects: Popular music , Music--Religious aspects--Chrisitianity , Africa Nigeria Lagos f-nr
- Language: English , Yoruba
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129549 , vital:36305 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC29-03
- Description: Solo and chorus singers singing Christian gospel songs accompanied by Nigerian band using traditional Nigerian rhythms and instruments
- Full Text: false
- Date Issued: 2000
- Authors: Peter Gabriels Muonagor (written, arranged, produced and composed by) , Tosia Alesh (arranged and produced by) , Studio 2000
- Date: 2000
- Subjects: Popular music , Music--Religious aspects--Chrisitianity , Africa Nigeria Lagos f-nr
- Language: English , Yoruba
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129549 , vital:36305 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC29-03
- Description: Solo and chorus singers singing Christian gospel songs accompanied by Nigerian band using traditional Nigerian rhythms and instruments
- Full Text: false
- Date Issued: 2000
Tete
- Selle Diop (comoser, performer), Souleymane Faye (arranged by), Lay Diagne (keyboards), Robson (accoustic guitar, percussion), Nagirou Dia, Selle Diop (chorus), Studio 2000
- Authors: Selle Diop (comoser, performer) , Souleymane Faye (arranged by) , Lay Diagne (keyboards) , Robson (accoustic guitar, percussion) , Nagirou Dia, Selle Diop (chorus) , Studio 2000
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Reggae music , Africa Senegal Dakar f-sg
- Language: Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/128503 , vital:36117 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC11-05
- Description: Senegalese band featuring singing accompanied by keyboard, guitar and percussion
- Full Text: false
- Date Issued: 2000
- Authors: Selle Diop (comoser, performer) , Souleymane Faye (arranged by) , Lay Diagne (keyboards) , Robson (accoustic guitar, percussion) , Nagirou Dia, Selle Diop (chorus) , Studio 2000
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Reggae music , Africa Senegal Dakar f-sg
- Language: Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/128503 , vital:36117 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC11-05
- Description: Senegalese band featuring singing accompanied by keyboard, guitar and percussion
- Full Text: false
- Date Issued: 2000
Tette
- Ajah Sy ( lead vocals, author, composer, chorus), Biram Ndeck Ndiaye, Ousmane Wade (arrangement), Lamine Faye (guitar), Samba Laobe Ndiaye (bass), Moussa Traore (percussion), Marie Codou Pouye, Ajah Sy, Abdourahmane Diallo,Missala man, Aly Hachem, Mame Gor Mboup (chorus), Studio 2000
- Authors: Ajah Sy ( lead vocals, author, composer, chorus) , Biram Ndeck Ndiaye , Ousmane Wade (arrangement) , Lamine Faye (guitar) , Samba Laobe Ndiaye (bass) , Moussa Traore (percussion) , Marie Codou Pouye, Ajah Sy, Abdourahmane Diallo,Missala man, Aly Hachem, Mame Gor Mboup (chorus) , Studio 2000
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Senegal Dakar f-sg
- Language: Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129395 , vital:36273 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC27-07
- Description: Lyrical songs with solo and chorus accompanied by keyboard, percussion and guitars, in traditional Senegalese music style mixed with international influences
- Full Text: false
- Date Issued: 2000
- Authors: Ajah Sy ( lead vocals, author, composer, chorus) , Biram Ndeck Ndiaye , Ousmane Wade (arrangement) , Lamine Faye (guitar) , Samba Laobe Ndiaye (bass) , Moussa Traore (percussion) , Marie Codou Pouye, Ajah Sy, Abdourahmane Diallo,Missala man, Aly Hachem, Mame Gor Mboup (chorus) , Studio 2000
- Date: 2000
- Subjects: Popular music , Popular music--Africa, West , Africa Senegal Dakar f-sg
- Language: Wolof
- Type: sound recordings , field recordings , sound recording-musical
- Identifier: http://hdl.handle.net/10962/129395 , vital:36273 , International Library of African Music, Rhodes University, Grahamstown, South Africa , SDC27-07
- Description: Lyrical songs with solo and chorus accompanied by keyboard, percussion and guitars, in traditional Senegalese music style mixed with international influences
- Full Text: false
- Date Issued: 2000
The analysis of trace gas emissions from landfills
- Authors: Rubidge, Gletwyn Robert
- Date: 2000
- Subjects: Gases, Asphyxiating and poisonnous , Gases -- Analysis , Sanitation -- Environmental engineering
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10983 , http://hdl.handle.net/10948/d1006341 , Gases, Asphyxiating and poisonnous , Gases -- Analysis , Sanitation -- Environmental engineering
- Description: Numerous informal houses have been built on and adjacent to a landfill in iBayi, Port Elizabeth, South Africa, which accepted domestic and industrial waste. Formal housing surrounds most of the site at a greater distance - some 60 m, or further, from the landfill. Both formal and informally housed residents complain of odours, burning eyes, sore throats and headaches - symptoms which they believed were caused by the landfill. The landfill gas and ambient air were analyzed to classify and quantify the VOCs (volatile organic compounds) emitted and then to compare the quantitative data with recognised standards to establish if the residents are at risk. Eighteen target (potentially hazardous) VOCs were quantified. A wide variety of compounds were detected in both the ambient air and landfill gas. The results of the VOC analyses were similar to those of other workers in both the qualitative and quantitative studies. The concentrations of the VOCs were mostly lower than the TLV (threshold limit values) values, but exceeded the MRLs (minimum recommended levels). The combined concentrations of the VOC’s in the ambient air either approached or exceeded the limit values for combined exposure thus indicating that a potential health hazard exists. One third of the VOCs were detected in both the ambient air and the subsurface gas, however, external pollution sources also appear to contribute to the VOC concentrations ambient air. Dangerously high methane concentrations were repeatedly detected in the landfill gas amongst the informal houses. There was a vast improvement in the aesthetic qualities of the landfill since the disposal restriction to accept only domestic refuse and building rubble in July 1997. The ambient air was less odorous and landfill site littered. Fewer informal recyclers were present and their concomitant squabbling over valuables had almost vanished. The management of the iBayi landfill holds much room for improvement. There is potential for serious injury or even death if no action is taken to remedy the problems at the iBayi landfill. A holistic solution will have to be found to make the landfill a safe neighbour. Some complementary analyses (such as pH, heavy metal concentrations in the water and sediments etc.) were performed on the leachate and water surrounding the landfill.
- Full Text:
- Date Issued: 2000
- Authors: Rubidge, Gletwyn Robert
- Date: 2000
- Subjects: Gases, Asphyxiating and poisonnous , Gases -- Analysis , Sanitation -- Environmental engineering
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10983 , http://hdl.handle.net/10948/d1006341 , Gases, Asphyxiating and poisonnous , Gases -- Analysis , Sanitation -- Environmental engineering
- Description: Numerous informal houses have been built on and adjacent to a landfill in iBayi, Port Elizabeth, South Africa, which accepted domestic and industrial waste. Formal housing surrounds most of the site at a greater distance - some 60 m, or further, from the landfill. Both formal and informally housed residents complain of odours, burning eyes, sore throats and headaches - symptoms which they believed were caused by the landfill. The landfill gas and ambient air were analyzed to classify and quantify the VOCs (volatile organic compounds) emitted and then to compare the quantitative data with recognised standards to establish if the residents are at risk. Eighteen target (potentially hazardous) VOCs were quantified. A wide variety of compounds were detected in both the ambient air and landfill gas. The results of the VOC analyses were similar to those of other workers in both the qualitative and quantitative studies. The concentrations of the VOCs were mostly lower than the TLV (threshold limit values) values, but exceeded the MRLs (minimum recommended levels). The combined concentrations of the VOC’s in the ambient air either approached or exceeded the limit values for combined exposure thus indicating that a potential health hazard exists. One third of the VOCs were detected in both the ambient air and the subsurface gas, however, external pollution sources also appear to contribute to the VOC concentrations ambient air. Dangerously high methane concentrations were repeatedly detected in the landfill gas amongst the informal houses. There was a vast improvement in the aesthetic qualities of the landfill since the disposal restriction to accept only domestic refuse and building rubble in July 1997. The ambient air was less odorous and landfill site littered. Fewer informal recyclers were present and their concomitant squabbling over valuables had almost vanished. The management of the iBayi landfill holds much room for improvement. There is potential for serious injury or even death if no action is taken to remedy the problems at the iBayi landfill. A holistic solution will have to be found to make the landfill a safe neighbour. Some complementary analyses (such as pH, heavy metal concentrations in the water and sediments etc.) were performed on the leachate and water surrounding the landfill.
- Full Text:
- Date Issued: 2000
The biology of commercially important fish species and a preliminary assessment of the fisheries potential of Katse Dam, Lesotho
- Authors: Nthimo, Mokitinyane Francis
- Date: 2000
- Subjects: Fishes -- Lesotho -- Katse dam , Fishes -- Physiology , Rainbow trout , Barbus aeneus , Labeo , Katse dam (Lesotho) , Fisheries -- Lesotho -- Katse dam , Fishery management -- Lesotho
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5238 , http://hdl.handle.net/10962/d1005081 , Fishes -- Lesotho -- Katse dam , Fishes -- Physiology , Rainbow trout , Barbus aeneus , Labeo , Katse dam (Lesotho) , Fisheries -- Lesotho -- Katse dam , Fishery management -- Lesotho
- Description: The construction of the Katse dam was completed in 1996. The dam started filling in 1995 and reached full capacity in early 1998. It forms part of Phase 1A of the Lesotho Highlands Water Project (LHWP). The main aim of the project is to provide revenue to Lesotho, by transferring water from the catchment of the Senqu (Orange) River in Lesotho to South Africa’s major industrial and population centres. During the implementation of the project, an estimated 130 people were displaced. However, the most serious impact has been the loss of the traditional way of life in the form of arable and grazing land as a consequence of inundation. One of the obligations of the project is to ensure that the standard of living of those affected by the project is not impaired. The Lesotho Highlands Development Authority identified a number of rural development projects, which included fisheries development. This study is an integral part of fisheries development in Lesotho. The aim of this study was to gain an understanding of the biology and the demographics of the fish species in the lake. This information would serve as the basis for the development of a management plan for the sustainable utilisation of the fisheries resources. To achieve this aim, the following specific objectives were addressed: 1. Investigation of the biology of the three principal species. 2. Description of the key population parameters (growth, mortality & recruitment). 3. Investigation of the distribution and relative abundance of the three species. The three principal species in the Katse dam are rainbow trout, Oncorhynchus mykiss, and the two cyprinids, Barbus aeneus and Labeo capensis. Sectioned otoliths were used to age O. mykiss while both otoliths and scales were used to age B. aeneus and L. capensis. Marginal zone analysis revealed that slow growth was experienced in winter for the three species. The maximum-recorded age for both B. aeneus and L. capensis was 12 years while O. mykiss reached 4 years. There was no significant difference in growth rates of the different sexes and growth was best described by the 3 parameter Von-Bertalanfy growth model as Lt = 603[1-e⁻°·¹⁵⁽t ⁺ °·°³⁾] for B. aeneus, Lt = 526[1-e⁻°·²¹⁽t ⁺ °·⁹⁾] for O. mykiss and Lt = 521[1-e⁻°·¹⁷⁽t ⁺ °·²¹⁾] for L.capensis. Male and female O. mykiss attained 50% sexual maturity (Lm₅₀) at 235 and 275mm FL, respectively. There was no difference in Lm₅₀ for male and female B. aeneus and L. capensis. B. aeneus reached sexual maturity at 285mm FL while L. capensis reached sexual maturity at 244mm. Both cyprinid species spawned in summer (November to January) while O. mykiss spawned in winter (May to August). The mean total mortality rate (Z) estimated from catch curves and Butterworth et al (1989) equation was 0.72 yr⁻¹ for B. aeneus, 0.62 yr⁻¹ for L. capensis and 1.32 yr⁻¹ for O. mykiss. The estimate of natural mortality was 0.41 yr⁻¹ for both B. aeneus and L. capensis and 0.81yr⁻¹ for O. mykiss.
- Full Text:
- Date Issued: 2000
- Authors: Nthimo, Mokitinyane Francis
- Date: 2000
- Subjects: Fishes -- Lesotho -- Katse dam , Fishes -- Physiology , Rainbow trout , Barbus aeneus , Labeo , Katse dam (Lesotho) , Fisheries -- Lesotho -- Katse dam , Fishery management -- Lesotho
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5238 , http://hdl.handle.net/10962/d1005081 , Fishes -- Lesotho -- Katse dam , Fishes -- Physiology , Rainbow trout , Barbus aeneus , Labeo , Katse dam (Lesotho) , Fisheries -- Lesotho -- Katse dam , Fishery management -- Lesotho
- Description: The construction of the Katse dam was completed in 1996. The dam started filling in 1995 and reached full capacity in early 1998. It forms part of Phase 1A of the Lesotho Highlands Water Project (LHWP). The main aim of the project is to provide revenue to Lesotho, by transferring water from the catchment of the Senqu (Orange) River in Lesotho to South Africa’s major industrial and population centres. During the implementation of the project, an estimated 130 people were displaced. However, the most serious impact has been the loss of the traditional way of life in the form of arable and grazing land as a consequence of inundation. One of the obligations of the project is to ensure that the standard of living of those affected by the project is not impaired. The Lesotho Highlands Development Authority identified a number of rural development projects, which included fisheries development. This study is an integral part of fisheries development in Lesotho. The aim of this study was to gain an understanding of the biology and the demographics of the fish species in the lake. This information would serve as the basis for the development of a management plan for the sustainable utilisation of the fisheries resources. To achieve this aim, the following specific objectives were addressed: 1. Investigation of the biology of the three principal species. 2. Description of the key population parameters (growth, mortality & recruitment). 3. Investigation of the distribution and relative abundance of the three species. The three principal species in the Katse dam are rainbow trout, Oncorhynchus mykiss, and the two cyprinids, Barbus aeneus and Labeo capensis. Sectioned otoliths were used to age O. mykiss while both otoliths and scales were used to age B. aeneus and L. capensis. Marginal zone analysis revealed that slow growth was experienced in winter for the three species. The maximum-recorded age for both B. aeneus and L. capensis was 12 years while O. mykiss reached 4 years. There was no significant difference in growth rates of the different sexes and growth was best described by the 3 parameter Von-Bertalanfy growth model as Lt = 603[1-e⁻°·¹⁵⁽t ⁺ °·°³⁾] for B. aeneus, Lt = 526[1-e⁻°·²¹⁽t ⁺ °·⁹⁾] for O. mykiss and Lt = 521[1-e⁻°·¹⁷⁽t ⁺ °·²¹⁾] for L.capensis. Male and female O. mykiss attained 50% sexual maturity (Lm₅₀) at 235 and 275mm FL, respectively. There was no difference in Lm₅₀ for male and female B. aeneus and L. capensis. B. aeneus reached sexual maturity at 285mm FL while L. capensis reached sexual maturity at 244mm. Both cyprinid species spawned in summer (November to January) while O. mykiss spawned in winter (May to August). The mean total mortality rate (Z) estimated from catch curves and Butterworth et al (1989) equation was 0.72 yr⁻¹ for B. aeneus, 0.62 yr⁻¹ for L. capensis and 1.32 yr⁻¹ for O. mykiss. The estimate of natural mortality was 0.41 yr⁻¹ for both B. aeneus and L. capensis and 0.81yr⁻¹ for O. mykiss.
- Full Text:
- Date Issued: 2000
The comparative value of wild and domestic plants in home gardens of a South African rural village
- High, Christopher, Shackleton, Charlie M
- Authors: High, Christopher , Shackleton, Charlie M
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181907 , vital:43779 , xlink:href="https://doi.org/10.1023/A:1006247614579"
- Description: Rural inhabitants make considerable use of wild resources from communal areas around their settlements, as well as from arable and residential plots. These wild resources compete with the main crops planted in arable plots and home gardens, but play a significant economic and nutritional role in rural livelihoods. This paper reports upon a conservative financial evaluation of the wild plant resources harvested from home gardens and arable plots by inhabitants of rural village in the Bushbuckridge lowveld (South Africa), and examines their importance relative to other domesticated crops. On average, each household made use of four to five species of wild plants growing on their residential plot, whereas the mean number of crop plants was 3.4. The total value of all plants was R1694 (US$ 269) per household per year, or approximately R4200 (US$ 667) per hectare of home garden per year. Wild plants represented 31% of the value of all plants grown on residential plots, relative to the 69% for domesticated crops (including fruit trees). Approximately 72% of the total value of all plant products was consumed by the household, and the remaining 28% was sold.
- Full Text:
- Date Issued: 2000
- Authors: High, Christopher , Shackleton, Charlie M
- Date: 2000
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181907 , vital:43779 , xlink:href="https://doi.org/10.1023/A:1006247614579"
- Description: Rural inhabitants make considerable use of wild resources from communal areas around their settlements, as well as from arable and residential plots. These wild resources compete with the main crops planted in arable plots and home gardens, but play a significant economic and nutritional role in rural livelihoods. This paper reports upon a conservative financial evaluation of the wild plant resources harvested from home gardens and arable plots by inhabitants of rural village in the Bushbuckridge lowveld (South Africa), and examines their importance relative to other domesticated crops. On average, each household made use of four to five species of wild plants growing on their residential plot, whereas the mean number of crop plants was 3.4. The total value of all plants was R1694 (US$ 269) per household per year, or approximately R4200 (US$ 667) per hectare of home garden per year. Wild plants represented 31% of the value of all plants grown on residential plots, relative to the 69% for domesticated crops (including fruit trees). Approximately 72% of the total value of all plant products was consumed by the household, and the remaining 28% was sold.
- Full Text:
- Date Issued: 2000
The development of a geographic information systems based atlas of southern African freshwater fish, and its application to biogeographic analysis
- Scott, Lucy Elizabeth Powell
- Authors: Scott, Lucy Elizabeth Powell
- Date: 2000
- Subjects: Freshwater fishes -- Africa, Southern , Freshwater fishes -- Geographical distribution -- Atlases , Freshwater fishes -- Africa, Southern -- Geographical distribution -- Atlases , Geographic information systems
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5256 , http://hdl.handle.net/10962/d1005099 , Freshwater fishes -- Africa, Southern , Freshwater fishes -- Geographical distribution -- Atlases , Freshwater fishes -- Africa, Southern -- Geographical distribution -- Atlases , Geographic information systems
- Description: A Geographic Information Systems (GIS) atlas of southern African freshwater fish was developed for the SADC countries from natural history collection specimens, hydrological, topographical and climatological data. The primary purpose of the development of the atlas of freshwater fish was the construction of a practical framework to transform vast amounts of existing biological data for use in research and management of aquatic resources. The database of freshwater fish collection specimens that was incorporated into the atlas, was developed in association with ALCOM (Aquatic Resources Management for Local Community Development Programme). The development of advanced computing and GIS technology has increased the scope of biological atlas projects by facilitating the integration of large amounts of spatial data to produce derived databases for specific applications. The atlas of freshwater fish was constructed using TNTmips GIS software as the most practical system available for managing and analysing biological data with a spatial component. The atlas contains 35 180 comprehensive distribution records of 735 species of fish. It has many applications as an inventory of ichthyofaunal spatial biodiversity, including those of conservation planning, environmental assessment and biogeographic research. Biogeographic studies have traditionally been subjective due to the logistical problems of working with large amounts of distribution data, although some small-scale quantitative research has been carried out in the past. The content of the atlas of freshwater fish is tested with respect to these previous studies, on known patterns of freshwater fish distributions, and the analytical capability of the atlas is tested and demonstrated with some new preliminary approaches to the analysis of freshwater fish distributions in southern Africa.
- Full Text:
- Date Issued: 2000
- Authors: Scott, Lucy Elizabeth Powell
- Date: 2000
- Subjects: Freshwater fishes -- Africa, Southern , Freshwater fishes -- Geographical distribution -- Atlases , Freshwater fishes -- Africa, Southern -- Geographical distribution -- Atlases , Geographic information systems
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5256 , http://hdl.handle.net/10962/d1005099 , Freshwater fishes -- Africa, Southern , Freshwater fishes -- Geographical distribution -- Atlases , Freshwater fishes -- Africa, Southern -- Geographical distribution -- Atlases , Geographic information systems
- Description: A Geographic Information Systems (GIS) atlas of southern African freshwater fish was developed for the SADC countries from natural history collection specimens, hydrological, topographical and climatological data. The primary purpose of the development of the atlas of freshwater fish was the construction of a practical framework to transform vast amounts of existing biological data for use in research and management of aquatic resources. The database of freshwater fish collection specimens that was incorporated into the atlas, was developed in association with ALCOM (Aquatic Resources Management for Local Community Development Programme). The development of advanced computing and GIS technology has increased the scope of biological atlas projects by facilitating the integration of large amounts of spatial data to produce derived databases for specific applications. The atlas of freshwater fish was constructed using TNTmips GIS software as the most practical system available for managing and analysing biological data with a spatial component. The atlas contains 35 180 comprehensive distribution records of 735 species of fish. It has many applications as an inventory of ichthyofaunal spatial biodiversity, including those of conservation planning, environmental assessment and biogeographic research. Biogeographic studies have traditionally been subjective due to the logistical problems of working with large amounts of distribution data, although some small-scale quantitative research has been carried out in the past. The content of the atlas of freshwater fish is tested with respect to these previous studies, on known patterns of freshwater fish distributions, and the analytical capability of the atlas is tested and demonstrated with some new preliminary approaches to the analysis of freshwater fish distributions in southern Africa.
- Full Text:
- Date Issued: 2000