Management education and training
- Authors: Amos, Trevor L , Quinn, Lynn
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270902 , vital:54490 , xlink:href="https://hdl.handle.net/10520/AJA10113487_559"
- Description: The paper outlines the role of language in leaming and cognitive development and argues that management education and training needs to be integrated with language development to enable students to cope with the demands made of them at university as well as with those of careers in the business world. An integrated language developmEint project developed by the Depanment of Management and academic language practitioners at Rhodes Uhlvetsity is descriptionbed and suggestions are outlined as to how university Management departments can integrate language development in their mainstream teaching.
- Full Text:
- Date Issued: 1997
- Authors: Amos, Trevor L , Quinn, Lynn
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270902 , vital:54490 , xlink:href="https://hdl.handle.net/10520/AJA10113487_559"
- Description: The paper outlines the role of language in leaming and cognitive development and argues that management education and training needs to be integrated with language development to enable students to cope with the demands made of them at university as well as with those of careers in the business world. An integrated language developmEint project developed by the Depanment of Management and academic language practitioners at Rhodes Uhlvetsity is descriptionbed and suggestions are outlined as to how university Management departments can integrate language development in their mainstream teaching.
- Full Text:
- Date Issued: 1997
Metallophthalocyanine catalysed electroreduction of nitrate and nitrite ions in alkaline media
- Chebotareva, Natalia, Nyokong, Tebello
- Authors: Chebotareva, Natalia , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293301 , vital:57073 , xlink:href="https://doi.org/10.1023/A:1018466021838"
- Description: Copper, cadmium, lead and bismuth (> 5 μg ml−1) are determined by adsorptive cathodic stripping voltammetry (AdCSV) on a mercury film glassy carbon electrode, using catechol, 4-methylcatechol, 4-t-butylcatechol and resorcinol as complexing ligands. Complexes of lead, copper and bismuth with resorcinol showed the largest increase in current with increase in metal concentration, whereas complexes of these metals with 4-t-butylcatechol showed the lowest current response. Cadmium showed a different behaviour from the other three metals in that the highest current response was observed with 4-methylcatechol. The four metals could be determined simultaneously in the presence of resorcinol, although considerable interference was observed between bismuth and copper.
- Full Text: false
- Date Issued: 1997
- Authors: Chebotareva, Natalia , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293301 , vital:57073 , xlink:href="https://doi.org/10.1023/A:1018466021838"
- Description: Copper, cadmium, lead and bismuth (> 5 μg ml−1) are determined by adsorptive cathodic stripping voltammetry (AdCSV) on a mercury film glassy carbon electrode, using catechol, 4-methylcatechol, 4-t-butylcatechol and resorcinol as complexing ligands. Complexes of lead, copper and bismuth with resorcinol showed the largest increase in current with increase in metal concentration, whereas complexes of these metals with 4-t-butylcatechol showed the lowest current response. Cadmium showed a different behaviour from the other three metals in that the highest current response was observed with 4-methylcatechol. The four metals could be determined simultaneously in the presence of resorcinol, although considerable interference was observed between bismuth and copper.
- Full Text: false
- Date Issued: 1997
Photosensitization reactions of neodymium, dysprosium and lutetium diphthalocyanine
- Nensala, Ngudiankama, Nyokong, Tebello
- Authors: Nensala, Ngudiankama , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:57084 , xlink:href="https://doi.org/10.1016/S0277-5387(97)00045-4"
- Description: Photolysis, using a visible radiation, of diphthalocyanine complexes of NdIII, DyIII and LuIII ([Pc(−2)NdIIIPc(−2)]−, [Pc(−2)DyIIIPc(−2)]− and [Pc(−2)LuIIIPc(−2)]−, respectively) in the presence of pentachlorophenol (PCP) or SO2 results in the one-electron oxidation of the diphthalocyanine species to Pc(−1)NdIIIPc(−2), Pc(−1)DyIIIPc(−2) and Pc(−2)LuIIIPc(−2), respectively. The PCP is reductively dechlorinated to tetra- and trichlorophenols. The quantum yields for the photosensitization reactions are of the order 10−4.
- Full Text:
- Date Issued: 1997
- Authors: Nensala, Ngudiankama , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:57084 , xlink:href="https://doi.org/10.1016/S0277-5387(97)00045-4"
- Description: Photolysis, using a visible radiation, of diphthalocyanine complexes of NdIII, DyIII and LuIII ([Pc(−2)NdIIIPc(−2)]−, [Pc(−2)DyIIIPc(−2)]− and [Pc(−2)LuIIIPc(−2)]−, respectively) in the presence of pentachlorophenol (PCP) or SO2 results in the one-electron oxidation of the diphthalocyanine species to Pc(−1)NdIIIPc(−2), Pc(−1)DyIIIPc(−2) and Pc(−2)LuIIIPc(−2), respectively. The PCP is reductively dechlorinated to tetra- and trichlorophenols. The quantum yields for the photosensitization reactions are of the order 10−4.
- Full Text:
- Date Issued: 1997
Reflecting on socially transformative environmental literacy for Lesotho
- Mokuku, Tsepo, Lotz-Sisitka, Heila
- Authors: Mokuku, Tsepo , Lotz-Sisitka, Heila
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438769 , vital:73498 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137444"
- Description: This paper is an attempt to clarify the concept of environmental literacy from a socially transformative orientation. It resulted from our ongoing reflection on a conceptual framework in and for a three-year research project on education for environmental literacy within the integrated science curriculum in Lesotho.
- Full Text:
- Date Issued: 1997
- Authors: Mokuku, Tsepo , Lotz-Sisitka, Heila
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/438769 , vital:73498 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137444"
- Description: This paper is an attempt to clarify the concept of environmental literacy from a socially transformative orientation. It resulted from our ongoing reflection on a conceptual framework in and for a three-year research project on education for environmental literacy within the integrated science curriculum in Lesotho.
- Full Text:
- Date Issued: 1997
Substituted catechols as complexing agents for the determination of bismuth, lead, copper and cadmium by adsorptive stripping voltammetry
- Limson, Janice L, Nyokong, Tebello
- Authors: Limson, Janice L , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293311 , vital:57074 , xlink:href="https://doi.org/10.1016/S0003-2670(96)00585-5"
- Description: Copper, cadmium, lead and bismuth (> 5 μg ml−1) are determined by adsorptive cathodic stripping voltammetry (AdCSV) on a mercury film glassy carbon electrode, using catechol, 4-methylcatechol, 4-t-butylcatechol and resorcinol as complexing ligands. Complexes of lead, copper and bismuth with resorcinol showed the largest increase in current with increase in metal concentration, whereas complexes of these metals with 4-t-butylcatechol showed the lowest current response. Cadmium showed a different behaviour from the other three metals in that the highest current response was observed with 4-methylcatechol. The four metals could be determined simultaneously in the presence of resorcinol, although considerable interference was observed between bismuth and copper.
- Full Text:
- Date Issued: 1997
- Authors: Limson, Janice L , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293311 , vital:57074 , xlink:href="https://doi.org/10.1016/S0003-2670(96)00585-5"
- Description: Copper, cadmium, lead and bismuth (> 5 μg ml−1) are determined by adsorptive cathodic stripping voltammetry (AdCSV) on a mercury film glassy carbon electrode, using catechol, 4-methylcatechol, 4-t-butylcatechol and resorcinol as complexing ligands. Complexes of lead, copper and bismuth with resorcinol showed the largest increase in current with increase in metal concentration, whereas complexes of these metals with 4-t-butylcatechol showed the lowest current response. Cadmium showed a different behaviour from the other three metals in that the highest current response was observed with 4-methylcatechol. The four metals could be determined simultaneously in the presence of resorcinol, although considerable interference was observed between bismuth and copper.
- Full Text:
- Date Issued: 1997
The study of the interactions of cobalt (II) tetrasulfophthalocyanine with cysteine and histidine
- Sekota, Mantoa, Nyokong, Tebello
- Authors: Sekota, Mantoa , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293458 , vital:57087 , xlink:href="https://doi.org/10.1016/S0277-5387(97)00096-X"
- Description: Kinetics for the interaction of cobalt(II) tetrasulfophthalocyanine ([CoIITSPc]4−, Pc(−2) = phthalocyanine dianion) with the amino acids, histidine and cysteine, in pH 7.2 phosphate buffer were studied. The rates were found to be first order in both the [CoIITSPc]4− and the amino acid. The formation of the [CoIIITSPc]3− species in the presence of histidine occurred with a rate constant of 0.16 dm3 mol−s−1, whereas the formation of the [CoITSPc]5− species in the presence of cysteine gave a rate constant of 2.2 dm3 mol−1.
- Full Text:
- Date Issued: 1997
- Authors: Sekota, Mantoa , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293458 , vital:57087 , xlink:href="https://doi.org/10.1016/S0277-5387(97)00096-X"
- Description: Kinetics for the interaction of cobalt(II) tetrasulfophthalocyanine ([CoIITSPc]4−, Pc(−2) = phthalocyanine dianion) with the amino acids, histidine and cysteine, in pH 7.2 phosphate buffer were studied. The rates were found to be first order in both the [CoIITSPc]4− and the amino acid. The formation of the [CoIIITSPc]3− species in the presence of histidine occurred with a rate constant of 0.16 dm3 mol−s−1, whereas the formation of the [CoITSPc]5− species in the presence of cysteine gave a rate constant of 2.2 dm3 mol−1.
- Full Text:
- Date Issued: 1997
Towards sustainable conversation: Developing environmental education processes
- Authors: Le Roux, Kim
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/389884 , vital:68492 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137446"
- Description: This paper highlights the importance of seeing environmental education as a process and considers the value of conversation and storytelling in environmental education processes. These processes are explored from a post-structural perspective within the context of the writer's own involvement in supporting environmental education processes.
- Full Text:
- Date Issued: 1997
- Authors: Le Roux, Kim
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/389884 , vital:68492 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/137446"
- Description: This paper highlights the importance of seeing environmental education as a process and considers the value of conversation and storytelling in environmental education processes. These processes are explored from a post-structural perspective within the context of the writer's own involvement in supporting environmental education processes.
- Full Text:
- Date Issued: 1997
Troubled waters in south-western New Georgia, Solomon Islands: Is codification of the commons a viable avenue for resource use regularisation
- Authors: Shankar, Aswani
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/440061 , vital:73732
- Description: In recent decades there has been a growing interest in indigenous sea tenure institutions and their possible role in establishing a framework for sustainable resource use and conservation. Yet the feasibility of these institutions to cope with social and economic changes have been seldom explored. In this paper a case study is presented where internal deregularisation of the ‘commons’ is the result of existing socio-cultural principles combined with outside influences. Two territorial models are compared to elucidate emerging internal instabilities of sea tenure institutions and possible ways to correct existing problems. The codification of the commons is suggested here as a possible measure to strengthen indigenous common property regimes.
- Full Text:
- Date Issued: 1997
- Authors: Shankar, Aswani
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/440061 , vital:73732
- Description: In recent decades there has been a growing interest in indigenous sea tenure institutions and their possible role in establishing a framework for sustainable resource use and conservation. Yet the feasibility of these institutions to cope with social and economic changes have been seldom explored. In this paper a case study is presented where internal deregularisation of the ‘commons’ is the result of existing socio-cultural principles combined with outside influences. Two territorial models are compared to elucidate emerging internal instabilities of sea tenure institutions and possible ways to correct existing problems. The codification of the commons is suggested here as a possible measure to strengthen indigenous common property regimes.
- Full Text:
- Date Issued: 1997
Use of cobalt (II) phthalocyanine to improve the sensitivity and stability of glassy carbon electrodes for the detection of cresols, chlorophenols and phenol
- Mafatle, Tsukutlane J, Nyokong, Tebello
- Authors: Mafatle, Tsukutlane J , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293335 , vital:57076 , xlink:href="https://doi.org/10.1016/S0003-2670(97)00464-9"
- Description: A cobalt(II) phthalocyanine-modified glassy carbon electrode (CoPc-GCE) was used for the detection of o-, m- and p-cresols, and of 2-chlorophenol, 4-chlorophenol and phenol. Modification of the glassy carbon electrode with CoPc increases the oxidation currents of these species and increases the stability of the electrode. CoPc-GCE showed less fouling by the oxidation products of these compounds than the unmodified GCE. Comparison of some first row transition metal phthalocyanines showed the following trend for the enhancement of the currents for the oxidation of cresols and phenols: Co(II)Pc > Mn(II)Pc > Fe(II)Pc > Ni(II)Pc > Cu(II)Pc > H2Pc > Zn(II)Pc > GCE. When [Co(II)TSPc]4− (TSPc=tetrasulfo Pc) was added to aqueous solutions containing the cresols and phenols, an enhancement of the oxidation currents was also observed.
- Full Text:
- Date Issued: 1997
- Authors: Mafatle, Tsukutlane J , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293335 , vital:57076 , xlink:href="https://doi.org/10.1016/S0003-2670(97)00464-9"
- Description: A cobalt(II) phthalocyanine-modified glassy carbon electrode (CoPc-GCE) was used for the detection of o-, m- and p-cresols, and of 2-chlorophenol, 4-chlorophenol and phenol. Modification of the glassy carbon electrode with CoPc increases the oxidation currents of these species and increases the stability of the electrode. CoPc-GCE showed less fouling by the oxidation products of these compounds than the unmodified GCE. Comparison of some first row transition metal phthalocyanines showed the following trend for the enhancement of the currents for the oxidation of cresols and phenols: Co(II)Pc > Mn(II)Pc > Fe(II)Pc > Ni(II)Pc > Cu(II)Pc > H2Pc > Zn(II)Pc > GCE. When [Co(II)TSPc]4− (TSPc=tetrasulfo Pc) was added to aqueous solutions containing the cresols and phenols, an enhancement of the oxidation currents was also observed.
- Full Text:
- Date Issued: 1997
Voltammetric behavior of cysteine and metallothionein on cobalt (II) tetrasulfonated phthalocyanine modified glassy carbon electrodes
- Limson, Janice L, Nyokong, Tebello
- Authors: Limson, Janice L , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293346 , vital:57077 , xlink:href="https://doi.org/10.1002/elan.1140090314"
- Description: Cysteine, and rat Cd, Zn-metallothionein (Cd, Zn-MT) have been studied electrochemically at glassy carbon electrodes modified with cobalt(II) tetrasulfonated phthalocyanine, [CoIITSPc]4−, where Pc(2-) = phthalocyanine dianion. The electrode was modified by electrodeposition of [CoIITSPc]4−. The anodic currents for the oxidation of cysteine on these electrodes are observed at 0.82 V (vs. Ag/AgCl) in acidic media. The anodic currents for the oxidation of Cd, Zn-MT are observed at 0.90 V at pH 8.4 (Tris buffer).
- Full Text:
- Date Issued: 1997
- Authors: Limson, Janice L , Nyokong, Tebello
- Date: 1997
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293346 , vital:57077 , xlink:href="https://doi.org/10.1002/elan.1140090314"
- Description: Cysteine, and rat Cd, Zn-metallothionein (Cd, Zn-MT) have been studied electrochemically at glassy carbon electrodes modified with cobalt(II) tetrasulfonated phthalocyanine, [CoIITSPc]4−, where Pc(2-) = phthalocyanine dianion. The electrode was modified by electrodeposition of [CoIITSPc]4−. The anodic currents for the oxidation of cysteine on these electrodes are observed at 0.82 V (vs. Ag/AgCl) in acidic media. The anodic currents for the oxidation of Cd, Zn-MT are observed at 0.90 V at pH 8.4 (Tris buffer).
- Full Text:
- Date Issued: 1997
A pre-impoundment study of the Sabie-Sand River system, Mpumalanga with special reference to predicted impacts on the Kruger National Park (Volume 3)
- O’Keeffe, Jay H, Weeks, D C, Fourie, A, Davies, B R
- Authors: O’Keeffe, Jay H , Weeks, D C , Fourie, A , Davies, B R
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437759 , vital:73407 , ISBN 1 86845 237 9 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/294-3-96.pdf
- Description: This project was begun in January 1990 in response to a need to characterise the fauna of the Sabie-Sand River system for which plans were already advanced to build impoundments. During the cource of the project, the region was subjected to the worst drought on record. As a result the scope and duration of the project was extended. This volume is the first of three which describe the results. Volume 1 de-scribes the ecological status of the Sabie, the Sand and other major tributaries of the system, including the diversity and distribution of the fish and macro-invertebrate faunas, and their habitat requirements. The second volume describes the results of a drought monitoring programme in which three reaches of the Sabie and one in the Sand River were intensively sampled throughout the worst drought on record, from 1991 to 1992. The purpose of this volume is to assess the probable effects of proposed impoundments in the Sabie-Sand River (both positive and nega-tive) on the ecology of the downstream reaches, and to draw on the information from volumes one and two to make recommendations for the management and monitoring of the flows in the river.
- Full Text:
- Date Issued: 1996
- Authors: O’Keeffe, Jay H , Weeks, D C , Fourie, A , Davies, B R
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437759 , vital:73407 , ISBN 1 86845 237 9 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/294-3-96.pdf
- Description: This project was begun in January 1990 in response to a need to characterise the fauna of the Sabie-Sand River system for which plans were already advanced to build impoundments. During the cource of the project, the region was subjected to the worst drought on record. As a result the scope and duration of the project was extended. This volume is the first of three which describe the results. Volume 1 de-scribes the ecological status of the Sabie, the Sand and other major tributaries of the system, including the diversity and distribution of the fish and macro-invertebrate faunas, and their habitat requirements. The second volume describes the results of a drought monitoring programme in which three reaches of the Sabie and one in the Sand River were intensively sampled throughout the worst drought on record, from 1991 to 1992. The purpose of this volume is to assess the probable effects of proposed impoundments in the Sabie-Sand River (both positive and nega-tive) on the ecology of the downstream reaches, and to draw on the information from volumes one and two to make recommendations for the management and monitoring of the flows in the river.
- Full Text:
- Date Issued: 1996
An extended version of Linda for Transputer systems
- Wells, George C, Clayton, Peter G, Chalmer, A G
- Authors: Wells, George C , Clayton, Peter G , Chalmer, A G
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430512 , vital:72696 , https://dl.acm.org/doi/abs/10.5555/270088.270117
- Description: This paper discusses the associative matching mechanism used in the Linda coordination language for the retrieval of data. There are a number of problems with this mechanism which are discussed in the light of the requirements of applications using Linda. A number of solutions to these problems have been proposed. These are discussed and compared with a new approach to solving these problems. The benefits and the limitations of the new approach are considered, showing how it provides a considerable improvement in this area.
- Full Text:
- Date Issued: 1996
- Authors: Wells, George C , Clayton, Peter G , Chalmer, A G
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430512 , vital:72696 , https://dl.acm.org/doi/abs/10.5555/270088.270117
- Description: This paper discusses the associative matching mechanism used in the Linda coordination language for the retrieval of data. There are a number of problems with this mechanism which are discussed in the light of the requirements of applications using Linda. A number of solutions to these problems have been proposed. These are discussed and compared with a new approach to solving these problems. The benefits and the limitations of the new approach are considered, showing how it provides a considerable improvement in this area.
- Full Text:
- Date Issued: 1996
Cyclic voltammetry and spectroelectrochemistry of osmium phthalocyanines in aqueous and non-aqueous solvents
- Sekota, Mantoa, Nyokong, Tebello
- Authors: Sekota, Mantoa , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293358 , vital:57078 , xlink:href="https://doi.org/10.1016/0277-5387(95)00581-1"
- Description: Cyclic voltammetry of osmium phthalocyanine complexes, [(CN)2OsIIPc]2− and (py)2OSIIPc (PC = phthalocyanine dianion), show two oxidation couples and two reduction couples in acetonitrile and dimethy1formamide. Oxidation and reduction in these complexes occur at the ring to form cation and anion radical species, respectively. The [(CN)2OsIIPC]2− complexes show a remarkable ease of ring oxidation with oxidation potentials that are much lower than is typical for metallophthalocyanines. Half-wave potentials of 0.25 and 0.67 V (versus saturated calomel electrode, SCE) were obtained for the first and second ring oxidations, respectively. The [(CN)2OSIIPc]2− complex is soluble in water at pHs greater than 4. This complex shows one oxidation couple in pH 9 buffer at −0.11 V versus SCE.
- Full Text:
- Date Issued: 1996
- Authors: Sekota, Mantoa , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293358 , vital:57078 , xlink:href="https://doi.org/10.1016/0277-5387(95)00581-1"
- Description: Cyclic voltammetry of osmium phthalocyanine complexes, [(CN)2OsIIPc]2− and (py)2OSIIPc (PC = phthalocyanine dianion), show two oxidation couples and two reduction couples in acetonitrile and dimethy1formamide. Oxidation and reduction in these complexes occur at the ring to form cation and anion radical species, respectively. The [(CN)2OsIIPC]2− complexes show a remarkable ease of ring oxidation with oxidation potentials that are much lower than is typical for metallophthalocyanines. Half-wave potentials of 0.25 and 0.67 V (versus saturated calomel electrode, SCE) were obtained for the first and second ring oxidations, respectively. The [(CN)2OSIIPc]2− complex is soluble in water at pHs greater than 4. This complex shows one oxidation couple in pH 9 buffer at −0.11 V versus SCE.
- Full Text:
- Date Issued: 1996
Electrocatalytic oxidation of cysteine by molybdenum (V) phthalocyanine complexes
- Mafatle, Tsukutlane J, Nyokong, Tebello
- Authors: Mafatle, Tsukutlane J , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293369 , vital:57079 , xlink:href="https://doi.org/10.1016/0022-0728(95)04519-8"
- Description: Chemically modified electrodes, constructed by incorporating oxomolybdenum(V) phthalocyanine (OMo(V)(OH)Pc, Pc = phthalocyanine dianion) into graphite powder were used to catalyse the oxidation of cysteine. Solution catalysis of cysteine by oxomolybdenum(V) tetrasulfophthalocyanine, [OMo(V)(OH)TSPc]4−, was also investigated. A considerable reduction in overpotential for cysteine oxidation was observed. Cysteine oxidation occurred at 0.26 and 0.28 V vs. Ag/vbAgCl for catalysis by Omo(V)(OH)Pc and [OMo(V)(OH)TSPc]4− respectively as opposed to 0.77 V vs. Ag/vbAgCl observed on CoPc chemically modified electrodes. The anodic peak currents vary linearly with cysteine concentration in the range 0.02 to 0.08 mol dm−3 and 0.008 to 0.02 mol dm−3 for [OMo(V)(OH)TSPc]4− and OMo(V)Pc respectively.
- Full Text:
- Date Issued: 1996
- Authors: Mafatle, Tsukutlane J , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293369 , vital:57079 , xlink:href="https://doi.org/10.1016/0022-0728(95)04519-8"
- Description: Chemically modified electrodes, constructed by incorporating oxomolybdenum(V) phthalocyanine (OMo(V)(OH)Pc, Pc = phthalocyanine dianion) into graphite powder were used to catalyse the oxidation of cysteine. Solution catalysis of cysteine by oxomolybdenum(V) tetrasulfophthalocyanine, [OMo(V)(OH)TSPc]4−, was also investigated. A considerable reduction in overpotential for cysteine oxidation was observed. Cysteine oxidation occurred at 0.26 and 0.28 V vs. Ag/vbAgCl for catalysis by Omo(V)(OH)Pc and [OMo(V)(OH)TSPc]4− respectively as opposed to 0.77 V vs. Ag/vbAgCl observed on CoPc chemically modified electrodes. The anodic peak currents vary linearly with cysteine concentration in the range 0.02 to 0.08 mol dm−3 and 0.008 to 0.02 mol dm−3 for [OMo(V)(OH)TSPc]4− and OMo(V)Pc respectively.
- Full Text:
- Date Issued: 1996
Perceptions of affirmative action
- Scott, Judith, Amos, Trevor L, Richard Scott, W
- Authors: Scott, Judith , Amos, Trevor L , Richard Scott, W
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270914 , vital:54491 , xlink:href="https://hdl.handle.net/10520/EJC-67e7bffd2"
- Description: Private and public South African employers have instituted affirmative action policies meant to provide employment opportunities to Black South Africans. A body of literature suggests that because of affirmative action policies Black hopes have been raised while Whites view such policies as having a negative impact on their opportunities. However, no extant literature details an empirical investigation of these suggestions. Therefore, this study focusses on the affirmative action perceptions held by 350 South African university commerce students.
- Full Text:
- Date Issued: 1996
- Authors: Scott, Judith , Amos, Trevor L , Richard Scott, W
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270914 , vital:54491 , xlink:href="https://hdl.handle.net/10520/EJC-67e7bffd2"
- Description: Private and public South African employers have instituted affirmative action policies meant to provide employment opportunities to Black South Africans. A body of literature suggests that because of affirmative action policies Black hopes have been raised while Whites view such policies as having a negative impact on their opportunities. However, no extant literature details an empirical investigation of these suggestions. Therefore, this study focusses on the affirmative action perceptions held by 350 South African university commerce students.
- Full Text:
- Date Issued: 1996
Pharmacokinetics of cyclizine following intravenous administration to human volunteers
- Kanfer, Isadore, Walker, Roderick B
- Authors: Kanfer, Isadore , Walker, Roderick B
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184389 , vital:44214 , xlink:href="https://doi.org/10.1016/0928-0987(96)00177-7"
- Description: The pharmacokinetics of cyclizine, a piperazine derivative useful in the prevention and treatment of nausea and vomiting, was investigated in six healthy male volunteers following an intravenous bolus dose. The drug is extensively distributed with a mean volume of distribution of 16.50 ± 3.33 l/kg and a mean total clearance of 0.870 ± 0.105 l/h per kg. Urinary excretion data showed that less than one percent of the dose was excreted up to 36 h as unchanged drug in the urine. The extremely low mean renal clearance (0.005 ± 0.002 l/h per kg) for the parent drug comprised only a small proportion of total clearance indicating that urinary excretion of parent drug is not a major route of elimination for cyclizine. The drug appears to exhibit biexponential pharmacokinetics and has a terminal elimination half-life of approximately 13 h.
- Full Text:
- Date Issued: 1996
- Authors: Kanfer, Isadore , Walker, Roderick B
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184389 , vital:44214 , xlink:href="https://doi.org/10.1016/0928-0987(96)00177-7"
- Description: The pharmacokinetics of cyclizine, a piperazine derivative useful in the prevention and treatment of nausea and vomiting, was investigated in six healthy male volunteers following an intravenous bolus dose. The drug is extensively distributed with a mean volume of distribution of 16.50 ± 3.33 l/kg and a mean total clearance of 0.870 ± 0.105 l/h per kg. Urinary excretion data showed that less than one percent of the dose was excreted up to 36 h as unchanged drug in the urine. The extremely low mean renal clearance (0.005 ± 0.002 l/h per kg) for the parent drug comprised only a small proportion of total clearance indicating that urinary excretion of parent drug is not a major route of elimination for cyclizine. The drug appears to exhibit biexponential pharmacokinetics and has a terminal elimination half-life of approximately 13 h.
- Full Text:
- Date Issued: 1996
Photochemically induced electron transfer between sulfur dioxide and tin (IV) mono-and di-phthalocyanines
- Nensala, Ngudiankama, Nzimande, Ayanda, Nyokong, Tebello
- Authors: Nensala, Ngudiankama , Nzimande, Ayanda , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293402 , vital:57082 , xlink:href="https://doi.org/10.1016/1010-6030(96)04344-4"
- Description: Photolysis, using radiation from a tungsten lamp, of tin diphthalocyanine (Pc2Sn(IV)) in dichloromethane containing SO2 results in the one-electron oxidation of this species to [Pc(−2)Sn(IV)Pc(−1)]+. The relative quantum yields for the formation of the oxidized species were in the order of 10−3. The one-electron oxidized complex was also formed when Pc2Sn was photolysed in an acetonitrile/dichloromethane solvent mixture. Photolysis of the monomeric (L)2Sn(IV)Pc(LOH−, Cl−, Br− and F−) in pyridine and in the presence of SO2 resulted in the reduction of these species to (L)2Sn(IV)Pc(−3)]− with quantum yields in the order of 10−2.
- Full Text:
- Date Issued: 1996
- Authors: Nensala, Ngudiankama , Nzimande, Ayanda , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293402 , vital:57082 , xlink:href="https://doi.org/10.1016/1010-6030(96)04344-4"
- Description: Photolysis, using radiation from a tungsten lamp, of tin diphthalocyanine (Pc2Sn(IV)) in dichloromethane containing SO2 results in the one-electron oxidation of this species to [Pc(−2)Sn(IV)Pc(−1)]+. The relative quantum yields for the formation of the oxidized species were in the order of 10−3. The one-electron oxidized complex was also formed when Pc2Sn was photolysed in an acetonitrile/dichloromethane solvent mixture. Photolysis of the monomeric (L)2Sn(IV)Pc(LOH−, Cl−, Br− and F−) in pyridine and in the presence of SO2 resulted in the reduction of these species to (L)2Sn(IV)Pc(−3)]− with quantum yields in the order of 10−2.
- Full Text:
- Date Issued: 1996
Spectroelectrochemical studies of tin (IV) diphthalocyanine
- Nensala, Ngudiankama, Nyokong, Tebello
- Authors: Nensala, Ngudiankama , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293436 , vital:57085 , xlink:href="https://doi.org/10.1016/0277-5387(95)00325-1"
- Description: Cyclic voltammetry of tin(IV) diphthalocyanine (Pc2Sn) in dichloromethane containing TEAP shows two reduction couples at −0.56 and −0.89 versus saturated calomel electrode (SCE) and one oxidation couple at 0.35 V versus SCE; all were quasireversible one-electron couples. The oxidation couple corresponds to [Pc(−1)SnIVPc(−2)+/Pc(−2)SnIVPc(−2) and the reduction couples to Pc(−2)SnIVPc(−2)/[Pc(−3)SnIVPc(−2)]− and [Pc(−3)SnIVPc(−2)]−/[Pc(−3)SnIVPc(−3)]2−, respectively. The electronic absorption spectra of the various reduced or oxidized tin(IV) diphthalocyanine species are reported.
- Full Text:
- Date Issued: 1996
- Authors: Nensala, Ngudiankama , Nyokong, Tebello
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293436 , vital:57085 , xlink:href="https://doi.org/10.1016/0277-5387(95)00325-1"
- Description: Cyclic voltammetry of tin(IV) diphthalocyanine (Pc2Sn) in dichloromethane containing TEAP shows two reduction couples at −0.56 and −0.89 versus saturated calomel electrode (SCE) and one oxidation couple at 0.35 V versus SCE; all were quasireversible one-electron couples. The oxidation couple corresponds to [Pc(−1)SnIVPc(−2)+/Pc(−2)SnIVPc(−2) and the reduction couples to Pc(−2)SnIVPc(−2)/[Pc(−3)SnIVPc(−2)]− and [Pc(−3)SnIVPc(−2)]−/[Pc(−3)SnIVPc(−3)]2−, respectively. The electronic absorption spectra of the various reduced or oxidized tin(IV) diphthalocyanine species are reported.
- Full Text:
- Date Issued: 1996
Status report on the Kruger National Park Rivers Research Programme: A synthesis of results and assessment of progress to January 1996
- O'Keeffe, Jay H, Coetzee, Yvette
- Authors: O'Keeffe, Jay H , Coetzee, Yvette
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437715 , vital:73404 , ISBN 1 86845 242 5 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/711-1-96.pdf
- Description: In August 1995, the Programme Development and Management Committee of the Kruger National Park Rivers Research Programme (KNPRRP) recommended to the Water Research Commission (WRC) that an information synthesis and status report of the Programme be undertaken. The main purpose of the report is to inform all the interested parties (including researchers, managers, and funding agencies) of the achievements and capabilities of the Programme; to assess these in relation to the stated goals and tasks of the "Second Phase: Programme description"; and to identify gaps and priorities for further work.
- Full Text:
- Date Issued: 1996
- Authors: O'Keeffe, Jay H , Coetzee, Yvette
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , report
- Identifier: http://hdl.handle.net/10962/437715 , vital:73404 , ISBN 1 86845 242 5 , https://wrcwebsite.azurewebsites.net/wp-content/uploads/mdocs/711-1-96.pdf
- Description: In August 1995, the Programme Development and Management Committee of the Kruger National Park Rivers Research Programme (KNPRRP) recommended to the Water Research Commission (WRC) that an information synthesis and status report of the Programme be undertaken. The main purpose of the report is to inform all the interested parties (including researchers, managers, and funding agencies) of the achievements and capabilities of the Programme; to assess these in relation to the stated goals and tasks of the "Second Phase: Programme description"; and to identify gaps and priorities for further work.
- Full Text:
- Date Issued: 1996
Suppositories: An underutilized dosage form
- Webster, Jessica A, Dowse, Roslind, Walker, Roderick B
- Authors: Webster, Jessica A , Dowse, Roslind , Walker, Roderick B
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184697 , vital:44264 , xlink:href="https://hdl.handle.net/10520/AJA16836707_911"
- Description: The rectal route is useful for the delivery of both local acting and systemic drugs. In certain cases suppositories are the best form of therapy, or else they are an effective alternative when oral therapy is not possible. However; doctors rarely prescribe them and patients are often reluctant to use them. Understanding how suppositories work, and their numerous uses, can overcome the aversion to this particular dosage form. Pharmacists are in an ideal position to educate doctors, other health care providers, and patients, on the benefits of using suppositories and their correct use, and to offer advice on any problems associated with their use.
- Full Text:
- Date Issued: 1996
- Authors: Webster, Jessica A , Dowse, Roslind , Walker, Roderick B
- Date: 1996
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184697 , vital:44264 , xlink:href="https://hdl.handle.net/10520/AJA16836707_911"
- Description: The rectal route is useful for the delivery of both local acting and systemic drugs. In certain cases suppositories are the best form of therapy, or else they are an effective alternative when oral therapy is not possible. However; doctors rarely prescribe them and patients are often reluctant to use them. Understanding how suppositories work, and their numerous uses, can overcome the aversion to this particular dosage form. Pharmacists are in an ideal position to educate doctors, other health care providers, and patients, on the benefits of using suppositories and their correct use, and to offer advice on any problems associated with their use.
- Full Text:
- Date Issued: 1996