Development of a community pharmacy experiential learning programme in a South African context: a design research approach
- Kritiotis, Lia Costas, Thesis Advisor
- Authors: Kritiotis, Lia Costas , Thesis Advisor
- Date: 2018
- Subjects: Pharmacists -- Training of , Experintial training , Community development -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/17481 , vital:28353
- Description: Application of the design research approach to devise, develop and optimise an experiential learning programme and adaptation of the Volunteer Functions Inventory (VFI) to understand community pharmacists’ motives, are unique contributions to the global pharmacy education setting. This study generated new theory, in the form of substantive and procedural claims (design principles) regarding experiential learning programmes and preceptor and student motivation in a South African pharmacy educational context, which can be added to the existing international landscape and more importantly, plant the foundational seeds of insight that can be utilised as guiding tools by other South African pharmacy faculties.
- Full Text:
- Date Issued: 2018
- Authors: Kritiotis, Lia Costas , Thesis Advisor
- Date: 2018
- Subjects: Pharmacists -- Training of , Experintial training , Community development -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/17481 , vital:28353
- Description: Application of the design research approach to devise, develop and optimise an experiential learning programme and adaptation of the Volunteer Functions Inventory (VFI) to understand community pharmacists’ motives, are unique contributions to the global pharmacy education setting. This study generated new theory, in the form of substantive and procedural claims (design principles) regarding experiential learning programmes and preceptor and student motivation in a South African pharmacy educational context, which can be added to the existing international landscape and more importantly, plant the foundational seeds of insight that can be utilised as guiding tools by other South African pharmacy faculties.
- Full Text:
- Date Issued: 2018
Development of a computational chemistry scheme for testing the utility of synthetic bacteriochlorin in dye-sensitized solar cells
- Authors: Kota, Ntsika
- Date: 2018
- Subjects: Dye-sensitized solar cells , Computational chemistry , Density functionals , Electronic excitation , Molecular orbitals , Oscillator strengths , Bacteriochlorin
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/62327 , vital:28155
- Description: A computational chemistry scheme, based on density functional theory, was developed for in silico testing of a few bacteriochlorin properties relevant to dye-sensitized solar cells. These properties included electronic excitation wavelengths, molecular orbital energy levels, and oscillator strengths among others. Comparisons were made among four species, using computational proxies for electron injection quantum yield and photo-induced current production. The proxy measures for current production (frontier orbital energy level and short circuit current) made consistent, though qualitative, predictions about the ranking of the four dyes. The proxy measures for electron injection quantum yield (change in planar dipole moment and density of states) made less categorical predictions about the ranking. Overall, the scheme singled out one dye as the worst, but made no conclusive predictions about the relative ranking of the other three. There was insufficient data for comparison of the ranking predictions with experiment.
- Full Text:
- Date Issued: 2018
- Authors: Kota, Ntsika
- Date: 2018
- Subjects: Dye-sensitized solar cells , Computational chemistry , Density functionals , Electronic excitation , Molecular orbitals , Oscillator strengths , Bacteriochlorin
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/62327 , vital:28155
- Description: A computational chemistry scheme, based on density functional theory, was developed for in silico testing of a few bacteriochlorin properties relevant to dye-sensitized solar cells. These properties included electronic excitation wavelengths, molecular orbital energy levels, and oscillator strengths among others. Comparisons were made among four species, using computational proxies for electron injection quantum yield and photo-induced current production. The proxy measures for current production (frontier orbital energy level and short circuit current) made consistent, though qualitative, predictions about the ranking of the four dyes. The proxy measures for electron injection quantum yield (change in planar dipole moment and density of states) made less categorical predictions about the ranking. Overall, the scheme singled out one dye as the worst, but made no conclusive predictions about the relative ranking of the other three. There was insufficient data for comparison of the ranking predictions with experiment.
- Full Text:
- Date Issued: 2018
Development of a low-cost bioprinting system for the fabrication of cell-laden sodium alginate hydrogels
- Authors: Honiball, John Robert
- Date: 2018
- Subjects: Regenerative medicine , Tissue engineering , Alginates , Colloids , Three-dimensional printing
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/59204 , vital:27470
- Description: Bioprinting is a rapidly expanding technology with the ability to fabricate in vitro 3D tissues in a layer-by-layer manner to ultimately produce a living tissue which physiologically resembles native in vivo tissue functionality. Unfortunately, large costs associated with commercially available bioprinters severely limit the amount of people/research groups with access to the technology. Here, we investigated the potential for modifying a commercially available RepRap Prusa iteration 3 (i3) three-dimensional (3D) printer, by replacing the traditional plastic-based print-head with various open-source syringe-housed microextrusion print-head units, such that deposition of composite bioinks consisting of cells, biopolymer scaffolds and/or biomolecules may be achieved at a relatively low cost. Using adipose-derived human mesenchymal stromal stem cells (ad-HMSC) induced for adipogenic differentiation, as well as human umbilical vein endothelial cells (HUVEC), the potential for fabricating vascularised adipose tissue was investigated. The non-toxic, inexpensive algal polysaccharide, sodium alginate, was used to test the printability of the system, as well as for investigating the functionality unmodified sodium alginate has for use as a potential bioink in adipose tissue engineering. Cell viability assays, namely WST-1 and fluorescein diacetate (FDA)/propidium iodide (PI) live/dead cell staining, revealed that ad-HMSC were viable after 7 days of culture. However, viability of HUVEC encapsulated hydrogels revealed significantly lower cell viability. Live/dead cell staining revealed that the modified printing system was able to print ad-HMSC/HUVEC co-cocultures with a large degree of cell viability after 1 day of culture. However, after 7 days of culture, the majority of cells were revealed to be dead. Furthermore, due to the lack of mechanical integrity possessed by alginate in a liquid-like state, printing sodium alginate hydrogels in air consistently resulted in deformation of printed constructs. The newly developed 3D printing technique termed freeform reversible embedding of suspended hydrogels (FRESH) was therefore investigated as a means for achieving 3D spatial control of printed hydrogels using the modified system. Printing cell-free sodium alginate hydrogels within gelatin sacrificial support baths allowed for fabricating constructs in a spatially defined manner. However, overprinting and swelling of alginate hydrogels negatively affected the overall printing accuracy. The present study aimed to pave the way for further system modifications and refinements, such that the ultimate goal of low-cost bioprinting may be achieved. Further optimisation of printing parameters, hydrogel characteristics and sterilisation techniques may allow for fabricating viable, physiologically relevant tissues using the modified system developed.
- Full Text:
- Date Issued: 2018
- Authors: Honiball, John Robert
- Date: 2018
- Subjects: Regenerative medicine , Tissue engineering , Alginates , Colloids , Three-dimensional printing
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/59204 , vital:27470
- Description: Bioprinting is a rapidly expanding technology with the ability to fabricate in vitro 3D tissues in a layer-by-layer manner to ultimately produce a living tissue which physiologically resembles native in vivo tissue functionality. Unfortunately, large costs associated with commercially available bioprinters severely limit the amount of people/research groups with access to the technology. Here, we investigated the potential for modifying a commercially available RepRap Prusa iteration 3 (i3) three-dimensional (3D) printer, by replacing the traditional plastic-based print-head with various open-source syringe-housed microextrusion print-head units, such that deposition of composite bioinks consisting of cells, biopolymer scaffolds and/or biomolecules may be achieved at a relatively low cost. Using adipose-derived human mesenchymal stromal stem cells (ad-HMSC) induced for adipogenic differentiation, as well as human umbilical vein endothelial cells (HUVEC), the potential for fabricating vascularised adipose tissue was investigated. The non-toxic, inexpensive algal polysaccharide, sodium alginate, was used to test the printability of the system, as well as for investigating the functionality unmodified sodium alginate has for use as a potential bioink in adipose tissue engineering. Cell viability assays, namely WST-1 and fluorescein diacetate (FDA)/propidium iodide (PI) live/dead cell staining, revealed that ad-HMSC were viable after 7 days of culture. However, viability of HUVEC encapsulated hydrogels revealed significantly lower cell viability. Live/dead cell staining revealed that the modified printing system was able to print ad-HMSC/HUVEC co-cocultures with a large degree of cell viability after 1 day of culture. However, after 7 days of culture, the majority of cells were revealed to be dead. Furthermore, due to the lack of mechanical integrity possessed by alginate in a liquid-like state, printing sodium alginate hydrogels in air consistently resulted in deformation of printed constructs. The newly developed 3D printing technique termed freeform reversible embedding of suspended hydrogels (FRESH) was therefore investigated as a means for achieving 3D spatial control of printed hydrogels using the modified system. Printing cell-free sodium alginate hydrogels within gelatin sacrificial support baths allowed for fabricating constructs in a spatially defined manner. However, overprinting and swelling of alginate hydrogels negatively affected the overall printing accuracy. The present study aimed to pave the way for further system modifications and refinements, such that the ultimate goal of low-cost bioprinting may be achieved. Further optimisation of printing parameters, hydrogel characteristics and sterilisation techniques may allow for fabricating viable, physiologically relevant tissues using the modified system developed.
- Full Text:
- Date Issued: 2018
Development of a paediatric-friendly formulation intended for the treatment of multi-drug resistant tuberculosis
- Authors: Nkomo, Jethro
- Date: 2018
- Subjects: Drugs -- Dosage , Pediatrics -- Formulae, receipts, prescriptions Multidrug-resistant tuberculosis -- South Africa Primary health care -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/33660 , vital:32962
- Description: Children suffering from multidrug-resistant tuberculosis (MDR-TB) are treated with at least four drugs a day for at least twenty-four months. Approximately 25 000 - 32 000 children worldwide become infected with MDR-TB each year, yet there is a lack of adequate paediatric MDR-TB options for child-friendly dosage forms for the treatment of the condition. The available options are limited to manipulating different dosage forms intended for adults by means of breaking the tablets or otherwise, to deliver the drugs to children. This challenge that is faced by both health care professionals and caregivers subsequently poses drug quality, efficacy, and safety concerns to children being treated for MDR-TB. The objective of this study was to formulate a paediatric-friendly dosage form for the treatment of MDR-TB in children below the age of eight years. A fixed-dose combination (FDC) in form of a dispersible-tablet that contains two core drugs used in treatment of MDR-TB; levofloxacin and pyrazinamide, was developed. Quality by design principles was employed in developing the product. The systematic procedure ensures that quality is built into the product throughout the manufacturing process. It allows for identification of the critical quality attributes and modification of critical process parameters to lie within desired ranges. Preformulation studies were conducted on the active ingredients to investigate potential interactions and compatibility. Some of the analytical techniques employed in the process included an HPLC assay method that was developed to simultaneously separate levofloxacin and pyrazinamide, differential scanning calorimetry (DSC), infrared spectroscopy (IR), thermogravimetric analysis (TGA), and powder density studies. A direct compression tableting process was selected as the method of choice for product formulation. Active ingredients were blended with the excipients and compressed using tableting equipment to successfully produce FDC fast-disintegrating tablets containing 150 mg of levofloxacin and 300 mg pyrazinamide. The product quality was analysed and optimised using mathematical and statistical techniques such as response surface methodology (RSM) and ANOVA, to meet the required standards recommended by the United States Pharmacopoeia. The FDC dispersible tablet containing levofloxacin and pyrazinamide in the potential treatment of MDR-TB in children was successfully formulated, manufactured and evaluated. The tablet dosage form passed all the relevant quality criteria that governed the scope of this study and disintegrate in approximately 37 seconds when placed in water. It is generally a sizeable challenge to manufacture fixed-dose combination drug products due to physicochemical differences of various drugs, however, with adequate resources researchers may still find a way to formulate more child-friendly dosage forms for MDR-TB. This may lead to improved drug efficacy, reduced safety risks and decreased burden on caregivers and healthcare workers who must administer the treatment.
- Full Text:
- Date Issued: 2018
- Authors: Nkomo, Jethro
- Date: 2018
- Subjects: Drugs -- Dosage , Pediatrics -- Formulae, receipts, prescriptions Multidrug-resistant tuberculosis -- South Africa Primary health care -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/33660 , vital:32962
- Description: Children suffering from multidrug-resistant tuberculosis (MDR-TB) are treated with at least four drugs a day for at least twenty-four months. Approximately 25 000 - 32 000 children worldwide become infected with MDR-TB each year, yet there is a lack of adequate paediatric MDR-TB options for child-friendly dosage forms for the treatment of the condition. The available options are limited to manipulating different dosage forms intended for adults by means of breaking the tablets or otherwise, to deliver the drugs to children. This challenge that is faced by both health care professionals and caregivers subsequently poses drug quality, efficacy, and safety concerns to children being treated for MDR-TB. The objective of this study was to formulate a paediatric-friendly dosage form for the treatment of MDR-TB in children below the age of eight years. A fixed-dose combination (FDC) in form of a dispersible-tablet that contains two core drugs used in treatment of MDR-TB; levofloxacin and pyrazinamide, was developed. Quality by design principles was employed in developing the product. The systematic procedure ensures that quality is built into the product throughout the manufacturing process. It allows for identification of the critical quality attributes and modification of critical process parameters to lie within desired ranges. Preformulation studies were conducted on the active ingredients to investigate potential interactions and compatibility. Some of the analytical techniques employed in the process included an HPLC assay method that was developed to simultaneously separate levofloxacin and pyrazinamide, differential scanning calorimetry (DSC), infrared spectroscopy (IR), thermogravimetric analysis (TGA), and powder density studies. A direct compression tableting process was selected as the method of choice for product formulation. Active ingredients were blended with the excipients and compressed using tableting equipment to successfully produce FDC fast-disintegrating tablets containing 150 mg of levofloxacin and 300 mg pyrazinamide. The product quality was analysed and optimised using mathematical and statistical techniques such as response surface methodology (RSM) and ANOVA, to meet the required standards recommended by the United States Pharmacopoeia. The FDC dispersible tablet containing levofloxacin and pyrazinamide in the potential treatment of MDR-TB in children was successfully formulated, manufactured and evaluated. The tablet dosage form passed all the relevant quality criteria that governed the scope of this study and disintegrate in approximately 37 seconds when placed in water. It is generally a sizeable challenge to manufacture fixed-dose combination drug products due to physicochemical differences of various drugs, however, with adequate resources researchers may still find a way to formulate more child-friendly dosage forms for MDR-TB. This may lead to improved drug efficacy, reduced safety risks and decreased burden on caregivers and healthcare workers who must administer the treatment.
- Full Text:
- Date Issued: 2018
Development of a Postharvest Cold Treatment for Cryptophlebia peltastica (Lepidoptera: Tortricidae) for Export of Litchis From South Africa
- Moore, Sean D, Kirkman, Wayne, Peyper, Mellissa, Thackeray, Sean R, Marsberg, Tamryn, Albertyn, Sonnica, Hill, Martin P
- Authors: Moore, Sean D , Kirkman, Wayne , Peyper, Mellissa , Thackeray, Sean R , Marsberg, Tamryn , Albertyn, Sonnica , Hill, Martin P
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/423729 , vital:72089 , xlink:href="https://doi.org/10.1093/jee/toy287"
- Description: The litchi moth, Cryptophlebia peltastica (Meyrick) (Lepidoptera: Tortricidae), is endemic to sub-Saharan Africa and certain Indian Ocean islands. It is an important pest of litchis and to a lesser extent macadamias. Litchis are exported to certain markets that consider C. peltastica as a phytosanitary pest. Consequently, an effective postharvest phytosanitary treatment is required. This study sought to develop a cold disinfestation treatment for this purpose. First, it was established that the fifth instar was the most cold-tolerant larval stage, as it was the only instar for which there was still some survival after 12 d at 1°C. It was then determined that cold treatment trials could be conducted in artificial diet, as there was no survival of fifth instar C. peltastica in litchis after only 9 d at 1°C, whereas it took 15 d at this temperature before no survival of fifth instar C. peltastica was recorded in artificial diet. Consequently, cold susceptibility of fifth instar C. peltastica and the most cold-tolerant larval stages (fourth and fifth instar) of false codling moth, Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae), were compared in artificial diet. There was no survival of C. peltastica after 13 d at 1°C, whereas this was only so for T. leucotreta after 16 d. Consequently, it can be concluded that any cold treatment that has been proven effective against T. leucotreta would be as effective against C. peltastica. Finally, it was confirmed that the cold susceptibility of T. leucotreta in artificial diet did not overestimate the effect of cold on T. leucotreta larvae in litchis.
- Full Text:
- Date Issued: 2018
- Authors: Moore, Sean D , Kirkman, Wayne , Peyper, Mellissa , Thackeray, Sean R , Marsberg, Tamryn , Albertyn, Sonnica , Hill, Martin P
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/423729 , vital:72089 , xlink:href="https://doi.org/10.1093/jee/toy287"
- Description: The litchi moth, Cryptophlebia peltastica (Meyrick) (Lepidoptera: Tortricidae), is endemic to sub-Saharan Africa and certain Indian Ocean islands. It is an important pest of litchis and to a lesser extent macadamias. Litchis are exported to certain markets that consider C. peltastica as a phytosanitary pest. Consequently, an effective postharvest phytosanitary treatment is required. This study sought to develop a cold disinfestation treatment for this purpose. First, it was established that the fifth instar was the most cold-tolerant larval stage, as it was the only instar for which there was still some survival after 12 d at 1°C. It was then determined that cold treatment trials could be conducted in artificial diet, as there was no survival of fifth instar C. peltastica in litchis after only 9 d at 1°C, whereas it took 15 d at this temperature before no survival of fifth instar C. peltastica was recorded in artificial diet. Consequently, cold susceptibility of fifth instar C. peltastica and the most cold-tolerant larval stages (fourth and fifth instar) of false codling moth, Thaumatotibia leucotreta (Meyrick) (Lepidoptera: Tortricidae), were compared in artificial diet. There was no survival of C. peltastica after 13 d at 1°C, whereas this was only so for T. leucotreta after 16 d. Consequently, it can be concluded that any cold treatment that has been proven effective against T. leucotreta would be as effective against C. peltastica. Finally, it was confirmed that the cold susceptibility of T. leucotreta in artificial diet did not overestimate the effect of cold on T. leucotreta larvae in litchis.
- Full Text:
- Date Issued: 2018
Development of an LCT-Based MOOC Taxonomy
- Authors: Motara, Yusuf, M
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428972 , vital:72550 , https://doi.org/10.1145/3289406.3289411
- Description: Codecademy is an example of a successful and disruptive player in the online education space. This work describes the structure, content, and experience of working through a Codecademy Pro Intensive module and compares it to the offline approach in a similar domain. Existing taxonomies are insufficiently general to explain its success, and a new taxonomy based on Legitimation Code Theory is developed to compensate. This taxonomy is arguably more meaningful and more general than those presently in use.
- Full Text:
- Date Issued: 2018
- Authors: Motara, Yusuf, M
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/428972 , vital:72550 , https://doi.org/10.1145/3289406.3289411
- Description: Codecademy is an example of a successful and disruptive player in the online education space. This work describes the structure, content, and experience of working through a Codecademy Pro Intensive module and compares it to the offline approach in a similar domain. Existing taxonomies are insufficiently general to explain its success, and a new taxonomy based on Legitimation Code Theory is developed to compensate. This taxonomy is arguably more meaningful and more general than those presently in use.
- Full Text:
- Date Issued: 2018
Development of health promotion guidelines for weight management among primary health care nurses in the Eastern Cape Province, South Africa
- Authors: Monakali, Sizeka
- Date: 2018
- Subjects: Health promotion Body weight -- Regulation Obesity -- prevention and control
- Language: English
- Type: Thesis , Doctoral , Nursing
- Identifier: http://hdl.handle.net/10353/10006 , vital:35285
- Description: Overweight and obesity have become significant public health threats both globally and in South Africa. PHC professional nurses are first contact to patients and the community as well as key stakeholders in the management and education of obese patients. However, anecdotal evidence seems to question their suitability as good models of the advocated healthy lifestyle behaviours and weight management, as overweight and obesity is also prevalent among the professional nurses. This study examines the prevalence and determinants of overweight and obesity among PHC professional nurses in the Eastern Cape (EC) Province of South Africa. This was a workplace, cross-sectional study involving 203 PHC professional nurses conveniently selected across 41 PHC facilities in EC, South Africa. A WHO STEP wise questionnaire was used to collect demographic and behavioural data. Anthropometric (weight, height and waist circumference [WC]) measurements were taken following a standard protocol. Overweight and obesity was defined as a BMI of 25-29.9kgm-2, and BMI ≥ 30kgm-2, respectively. Seventy six percent of the nurses were obese. An additional 18 percent were overweight. Age, gender, marital status, duration of practice, alcohol use and smoking were significantly associated with obesity. There was no association between physical activity and obesity. After adjusting for confounders, only age more than 30 years (OR=5.2, 95 percentCI=1.6-16.4) and not using alcohol (OR= 4.0 95 percentCI= 1.7-9.1) were significant and independent predictors of obesity among the nurses. In conclusion is an alarmingly high prevalence of obesity among primary healthcare professional nurses in Eastern Cape, South Africa. This shows that PHC professional nurses in EC are not good models of the healthy behaviours, judge be BMI indicator, if they do advocates for healthy weight management to patients. This constitutes a future risk for an increased prevalence of chronic diseases and a handicapped healthcare workforce. There is a need to implement measures to promote healthy lifestyle behaviour and weight management among professional nurses in this setting.
- Full Text:
- Date Issued: 2018
- Authors: Monakali, Sizeka
- Date: 2018
- Subjects: Health promotion Body weight -- Regulation Obesity -- prevention and control
- Language: English
- Type: Thesis , Doctoral , Nursing
- Identifier: http://hdl.handle.net/10353/10006 , vital:35285
- Description: Overweight and obesity have become significant public health threats both globally and in South Africa. PHC professional nurses are first contact to patients and the community as well as key stakeholders in the management and education of obese patients. However, anecdotal evidence seems to question their suitability as good models of the advocated healthy lifestyle behaviours and weight management, as overweight and obesity is also prevalent among the professional nurses. This study examines the prevalence and determinants of overweight and obesity among PHC professional nurses in the Eastern Cape (EC) Province of South Africa. This was a workplace, cross-sectional study involving 203 PHC professional nurses conveniently selected across 41 PHC facilities in EC, South Africa. A WHO STEP wise questionnaire was used to collect demographic and behavioural data. Anthropometric (weight, height and waist circumference [WC]) measurements were taken following a standard protocol. Overweight and obesity was defined as a BMI of 25-29.9kgm-2, and BMI ≥ 30kgm-2, respectively. Seventy six percent of the nurses were obese. An additional 18 percent were overweight. Age, gender, marital status, duration of practice, alcohol use and smoking were significantly associated with obesity. There was no association between physical activity and obesity. After adjusting for confounders, only age more than 30 years (OR=5.2, 95 percentCI=1.6-16.4) and not using alcohol (OR= 4.0 95 percentCI= 1.7-9.1) were significant and independent predictors of obesity among the nurses. In conclusion is an alarmingly high prevalence of obesity among primary healthcare professional nurses in Eastern Cape, South Africa. This shows that PHC professional nurses in EC are not good models of the healthy behaviours, judge be BMI indicator, if they do advocates for healthy weight management to patients. This constitutes a future risk for an increased prevalence of chronic diseases and a handicapped healthcare workforce. There is a need to implement measures to promote healthy lifestyle behaviour and weight management among professional nurses in this setting.
- Full Text:
- Date Issued: 2018
Development of high capacity lithium-manganese-rich cathode materials xLi2MnO3•(1-x)LiMn0.5Ni0.5O2 for lithium ion batteries
- Authors: Rapulenyane, Nomasonto
- Date: 2018
- Subjects: Lithium ion batteries , Electrochemistry Lithium cells
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/34766 , vital:33442
- Description: In this study, a facile synthesis method was developed to produce layered-layered cathode materials with the formula xLi2MnO3•(1-x)LiMO2 (M= Ni and Mn) referred to as lithium-manganese-rich materials for lithium ion batteries. The prepared materials displayed high capacity ≥200 mAh/g at a current density of 20 mA/g in the voltage range of 2.0 V to 4.8 V. In particular the cathode material prepared at pH 10.0 delivered a high initial discharge capacity of 266 mAh/g at 20 mA/g current density and maintained a discharge capacity ≥220 mAh/g at 50 mA/g after 50 cycles. The synthesis method was used to further investigate the effect of lithium ratio in the layered-layered material. Li1+xMn0.6Ni0.2O2, x= 0.2, 0.25, 0.3 and 0.4 cathode materials were produced respectively. The BET surface area analysis results showed that Li1.3Mn0.6Ni0.2O2 material had comparatively higher surface area to the other cathode materials and also delivered good electrochemical results. XPS showed that the cation distribution is affected by the increase in lithium ratio, the Mn4+ percentages decreased significantly with an increase in lithium ratio. All materials peaks deconvoluted into two peaks namely Mn4+ and Mn3+, Li1.3Mn0.6Ni0.2O2 had the highest percentages of the stable Mn4+ 70.8%. Further investigation focused on the effect of the sintering temperature on the structure and the electrochemical performance of Li1+xMn0.6Ni0.2O2, x= 0.25, 0.3 and 0.4 cathode materials. X-ray diffraction showed the same patterns for all cathode materials sintered at 700˚C, 800˚C and 900˚C. Rietveld refined results however, showed that the increase in the sintering temperature, results in a decrease in the Li2MnO3 component percentage in the layered structures. Scanning electron microscopy images further proved that the particle size increases with increasing temperature. The charge–discharge tests of coin cells demonstrated that the materials sintered at 800˚C delivered higher discharge capacities above 200 mAh/g at 20 mA/g current density when compared to the materials made at the lower temperatures. Lastly the cathode material prepared at pH 10.0 was further evaluated in a cell using lithium titanate oxide Li4Ti5O12 as anode material. The cells delivered an initial discharge capacity of 213 mAh/g at 20 mA/g within a voltage range 3.3V-0.5V. The coin cells developed in this work delivered good cycling performance.
- Full Text:
- Date Issued: 2018
- Authors: Rapulenyane, Nomasonto
- Date: 2018
- Subjects: Lithium ion batteries , Electrochemistry Lithium cells
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/34766 , vital:33442
- Description: In this study, a facile synthesis method was developed to produce layered-layered cathode materials with the formula xLi2MnO3•(1-x)LiMO2 (M= Ni and Mn) referred to as lithium-manganese-rich materials for lithium ion batteries. The prepared materials displayed high capacity ≥200 mAh/g at a current density of 20 mA/g in the voltage range of 2.0 V to 4.8 V. In particular the cathode material prepared at pH 10.0 delivered a high initial discharge capacity of 266 mAh/g at 20 mA/g current density and maintained a discharge capacity ≥220 mAh/g at 50 mA/g after 50 cycles. The synthesis method was used to further investigate the effect of lithium ratio in the layered-layered material. Li1+xMn0.6Ni0.2O2, x= 0.2, 0.25, 0.3 and 0.4 cathode materials were produced respectively. The BET surface area analysis results showed that Li1.3Mn0.6Ni0.2O2 material had comparatively higher surface area to the other cathode materials and also delivered good electrochemical results. XPS showed that the cation distribution is affected by the increase in lithium ratio, the Mn4+ percentages decreased significantly with an increase in lithium ratio. All materials peaks deconvoluted into two peaks namely Mn4+ and Mn3+, Li1.3Mn0.6Ni0.2O2 had the highest percentages of the stable Mn4+ 70.8%. Further investigation focused on the effect of the sintering temperature on the structure and the electrochemical performance of Li1+xMn0.6Ni0.2O2, x= 0.25, 0.3 and 0.4 cathode materials. X-ray diffraction showed the same patterns for all cathode materials sintered at 700˚C, 800˚C and 900˚C. Rietveld refined results however, showed that the increase in the sintering temperature, results in a decrease in the Li2MnO3 component percentage in the layered structures. Scanning electron microscopy images further proved that the particle size increases with increasing temperature. The charge–discharge tests of coin cells demonstrated that the materials sintered at 800˚C delivered higher discharge capacities above 200 mAh/g at 20 mA/g current density when compared to the materials made at the lower temperatures. Lastly the cathode material prepared at pH 10.0 was further evaluated in a cell using lithium titanate oxide Li4Ti5O12 as anode material. The cells delivered an initial discharge capacity of 213 mAh/g at 20 mA/g within a voltage range 3.3V-0.5V. The coin cells developed in this work delivered good cycling performance.
- Full Text:
- Date Issued: 2018
Development of InSb/GaSb quantum dots by MOVPE
- Authors: Ahia, Chinedu Christian
- Date: 2018
- Subjects: Semiconductors , Quantum electronics Organometallic compounds
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/23382 , vital:30537
- Description: There has been an increasing interest in the modification of semiconductor band structures through the reduction of their dimensions, which simultaneously increases the band gap energy of the material and gives rise to flexibility in device properties. Advances in III-V antimony (Sb) based semiconductor fabrication have triggered the quest for extension of the emission/absorption wavelength range of this family of compounds for optoelectronic devices operating in the mid-infrared region of the electromagnetic spectrum. An interesting material system for mid-infrared (MIR) applications is indium antimonide (InSb) quantum dots (QDs) within a gallium antimonide (GaSb) matrix. However, its band alignment and emission wavelength has been the subject of some interest and controversy over the years. This study focuses on the development of InSb/GaSb QDs by metal organic vapour phase epitaxy (MOVPE). The samples were grown on different substrates using various growth parameters in order to vary the size, density and aspect ratio of the dots. Interfacial growth interruptions while flowing various source precursors through the reactor were investigated in order to influence the chemical termination of the surface, and hence the resulting strain in the structures. The samples were characterized using photoluminescence spectroscopy, scanning probe microscopy, scanning electron microscopy, X-ray diffraction and transmission electron microscopy. Likewise, the band alignment, energy levels, and carrier wave functions of the samples in this work were modelled theoretically using the nextnanomat software (version 3.1.0.0). A comparison of growth on two different GaSb substrates [(100) 2° off towards <111>B ± 0.1ᵒ and (111) ± 0.1ᵒ] using similar growth conditions yielded a higher dot density on the (100) substrate compared to the (111) substrate. This was attributed to the presence of terraces/atomic steps induced by the misorientation on the (100) substrate, which invariably gives rise to increased adsorption and an enhanced sticking coefficient of adatoms. Studies on the influence of a buffer layer on the morphology of uncapped dots showed that the shape and size of the dots are sensitive to the thickness of the buffer layer. In some case a corrugated buffer surface resulted, which introduced order in the arrangement of the dots, which formed preferentially inside the troughs. An increase in the V/III ratio from 1.0 to 3.0 was found to reduce the areal density of the QDs, while an analysis of the diameter histograms showed a narrowing of the size distribution with an increase in V/III ratio. The larger size distribution at low V/III was ascribed to the increase in indium species and the increased indium adatom migration length. This leads to increased dot density and nucleation sites, and thus triggers an increase in the conversion of tiny QDs into thermodynamically more suitable larger dots via coalescence. However, as the V/III ratio increased, the number of indium adatoms available for growth on the surface reduced, which automatically led to a decrease in the migration length of indium species which is unfavourable for the production of nucleation sites and to a decrease in dot density. Low growth rates were found to be beneficial for the growth of a high density (~5×1010cm-2) of QDs. Photoluminescence (PL) analysis of the capped samples at low temperature (~10 K), using an excitation power of 2 mW, showed a PL peak at ∼732 meV. Upon an increase in laser power to 120 mW, a blue shift of ∼ 8 meV was noticed. This emission typically persisted up to 60–70 K. An increase in the number of InSb QD-layers, was observed to cause an increase in the luminescence spectral line width and a long-wavelength shift of the PL lines, together with an enhancement in the strength of the PL emission. However, high resolution transmission electron microscopy (HRTEM) of the capped dots revealed the formation of an InGaSb quantum well-like structure, ∼10 nm thick, which was responsible for the PL signal mentioned above. The absence of QDs in the capped sample was attributed to inter-diffusion of Ga and In during the deposition of the cap layer, giving rise to a quantum well (QW) instead of the intended QDs. The presence of threading dislocations and stacking faults were also observed in the TEM micrographs of the samples containing multilayers, which can account for the fast quenching of the PL emission with increasing temperature from these samples. Theoretical simulations of the band alignment, wave functions and energy levels were in good agreement with the data collected from the PL spectra of the samples.
- Full Text:
- Date Issued: 2018
- Authors: Ahia, Chinedu Christian
- Date: 2018
- Subjects: Semiconductors , Quantum electronics Organometallic compounds
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/23382 , vital:30537
- Description: There has been an increasing interest in the modification of semiconductor band structures through the reduction of their dimensions, which simultaneously increases the band gap energy of the material and gives rise to flexibility in device properties. Advances in III-V antimony (Sb) based semiconductor fabrication have triggered the quest for extension of the emission/absorption wavelength range of this family of compounds for optoelectronic devices operating in the mid-infrared region of the electromagnetic spectrum. An interesting material system for mid-infrared (MIR) applications is indium antimonide (InSb) quantum dots (QDs) within a gallium antimonide (GaSb) matrix. However, its band alignment and emission wavelength has been the subject of some interest and controversy over the years. This study focuses on the development of InSb/GaSb QDs by metal organic vapour phase epitaxy (MOVPE). The samples were grown on different substrates using various growth parameters in order to vary the size, density and aspect ratio of the dots. Interfacial growth interruptions while flowing various source precursors through the reactor were investigated in order to influence the chemical termination of the surface, and hence the resulting strain in the structures. The samples were characterized using photoluminescence spectroscopy, scanning probe microscopy, scanning electron microscopy, X-ray diffraction and transmission electron microscopy. Likewise, the band alignment, energy levels, and carrier wave functions of the samples in this work were modelled theoretically using the nextnanomat software (version 3.1.0.0). A comparison of growth on two different GaSb substrates [(100) 2° off towards <111>B ± 0.1ᵒ and (111) ± 0.1ᵒ] using similar growth conditions yielded a higher dot density on the (100) substrate compared to the (111) substrate. This was attributed to the presence of terraces/atomic steps induced by the misorientation on the (100) substrate, which invariably gives rise to increased adsorption and an enhanced sticking coefficient of adatoms. Studies on the influence of a buffer layer on the morphology of uncapped dots showed that the shape and size of the dots are sensitive to the thickness of the buffer layer. In some case a corrugated buffer surface resulted, which introduced order in the arrangement of the dots, which formed preferentially inside the troughs. An increase in the V/III ratio from 1.0 to 3.0 was found to reduce the areal density of the QDs, while an analysis of the diameter histograms showed a narrowing of the size distribution with an increase in V/III ratio. The larger size distribution at low V/III was ascribed to the increase in indium species and the increased indium adatom migration length. This leads to increased dot density and nucleation sites, and thus triggers an increase in the conversion of tiny QDs into thermodynamically more suitable larger dots via coalescence. However, as the V/III ratio increased, the number of indium adatoms available for growth on the surface reduced, which automatically led to a decrease in the migration length of indium species which is unfavourable for the production of nucleation sites and to a decrease in dot density. Low growth rates were found to be beneficial for the growth of a high density (~5×1010cm-2) of QDs. Photoluminescence (PL) analysis of the capped samples at low temperature (~10 K), using an excitation power of 2 mW, showed a PL peak at ∼732 meV. Upon an increase in laser power to 120 mW, a blue shift of ∼ 8 meV was noticed. This emission typically persisted up to 60–70 K. An increase in the number of InSb QD-layers, was observed to cause an increase in the luminescence spectral line width and a long-wavelength shift of the PL lines, together with an enhancement in the strength of the PL emission. However, high resolution transmission electron microscopy (HRTEM) of the capped dots revealed the formation of an InGaSb quantum well-like structure, ∼10 nm thick, which was responsible for the PL signal mentioned above. The absence of QDs in the capped sample was attributed to inter-diffusion of Ga and In during the deposition of the cap layer, giving rise to a quantum well (QW) instead of the intended QDs. The presence of threading dislocations and stacking faults were also observed in the TEM micrographs of the samples containing multilayers, which can account for the fast quenching of the PL emission with increasing temperature from these samples. Theoretical simulations of the band alignment, wave functions and energy levels were in good agreement with the data collected from the PL spectra of the samples.
- Full Text:
- Date Issued: 2018
Developmental and reproductive performance of a specialist herbivore depend on seasonality of, and light conditions experienced by, the host plant
- Zachariades, Uyi O O,, Heshula, Lelethu U P, Hill, Martin P
- Authors: Zachariades, Uyi O O, , Heshula, Lelethu U P , Hill, Martin P
- Date: 2018
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59845 , vital:27667 , https://doi.org/10.1371/journal.pone.0190700
- Description: Host plant phenology (as influenced by seasonality) and light-mediated changes in the phenotypic and phytochemical properties of leaves have been hypothesised to equivocally influence insect herbivore performance. Here, we examined the effects of seasonality, through host plant phenology (late growth-season = autumn vs flowering-season = winter) and light environment (shade vs full-sun habitat) on the leaf characteristics of the invasive alien plant, Chromolaena odorata. In addition, the performance of a specialist folivore, Pareuchaetes insulata, feeding on leaves obtained from both shaded and full-sun habitats during autumn and winter, was evaluated over two generations. Foliar nitrogen and magnesium contents were generally higher in shaded plants with much higher levels during winter. Leaf water content was higher in shaded and in autumn plants. Total non-structural carbohydrate (TNC) and phosphorus contents did not differ as a function of season, but were higher in shaded foliage compared to full-sun leaves. Leaf toughness was noticeably higher on plants growing in full-sun during winter. With the exception of shaded leaves in autumn that supported the best performance [fastest development, heaviest pupal mass, and highest growth rate and Host Suitability Index (HSI) score], full-sun foliage in autumn surprisingly also supported an improved performance of the moth compared to shaded or full-sun leaves in winter. Our findings suggest that shaded and autumn foliage are nutritionally more suitable for the growth and reproduction of P. insulata. However, the heavier pupal mass, increased number of eggs and higher HSI score in individuals that fed on full-sun foliage in autumn compared to their counterparts that fed on shaded or full-sun foliage in winter suggest that full-sun foliage during autumn is also a suitable food source for larvae of the moth. In sum, our study demonstrates that seasonal and light-modulated changes in leaf characteristics can affect insect folivore performance in ways that are not linear.
- Full Text:
- Date Issued: 2018
- Authors: Zachariades, Uyi O O, , Heshula, Lelethu U P , Hill, Martin P
- Date: 2018
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59845 , vital:27667 , https://doi.org/10.1371/journal.pone.0190700
- Description: Host plant phenology (as influenced by seasonality) and light-mediated changes in the phenotypic and phytochemical properties of leaves have been hypothesised to equivocally influence insect herbivore performance. Here, we examined the effects of seasonality, through host plant phenology (late growth-season = autumn vs flowering-season = winter) and light environment (shade vs full-sun habitat) on the leaf characteristics of the invasive alien plant, Chromolaena odorata. In addition, the performance of a specialist folivore, Pareuchaetes insulata, feeding on leaves obtained from both shaded and full-sun habitats during autumn and winter, was evaluated over two generations. Foliar nitrogen and magnesium contents were generally higher in shaded plants with much higher levels during winter. Leaf water content was higher in shaded and in autumn plants. Total non-structural carbohydrate (TNC) and phosphorus contents did not differ as a function of season, but were higher in shaded foliage compared to full-sun leaves. Leaf toughness was noticeably higher on plants growing in full-sun during winter. With the exception of shaded leaves in autumn that supported the best performance [fastest development, heaviest pupal mass, and highest growth rate and Host Suitability Index (HSI) score], full-sun foliage in autumn surprisingly also supported an improved performance of the moth compared to shaded or full-sun leaves in winter. Our findings suggest that shaded and autumn foliage are nutritionally more suitable for the growth and reproduction of P. insulata. However, the heavier pupal mass, increased number of eggs and higher HSI score in individuals that fed on full-sun foliage in autumn compared to their counterparts that fed on shaded or full-sun foliage in winter suggest that full-sun foliage during autumn is also a suitable food source for larvae of the moth. In sum, our study demonstrates that seasonal and light-modulated changes in leaf characteristics can affect insect folivore performance in ways that are not linear.
- Full Text:
- Date Issued: 2018
Digital Inclusion: A model for e-Infrastructure and e-Services in Developing Countries
- Terzoli, Alfredo, Siebörger, Ingrid, Tsietsi, Mosiuoa, Gumbo, Sibukelo
- Authors: Terzoli, Alfredo , Siebörger, Ingrid , Tsietsi, Mosiuoa , Gumbo, Sibukelo
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430973 , vital:72733 , https://doi.org/10.1007/978-3-319-98827-6_7
- Description: A large portion of the South African population is still not connected in a productive manner to the Internet, despite the existence of a govern-ment plan for public broadband, ‘SA Connect’. One reason for this could be the lack of an appropriate model, through which connectivity can be diffused in a meaningful way through all areas of South Africa. This paper presents the model developed over more than a decade of experimentation in real life settings in the Siyakhula Living Lab, a joint venture between the universities of Rhodes and Fort Hare, South Afri-ca. The model proposes the ‘Broadband Island’ as basic e-infrastructure unit, which clusters nearby points-of-presence hosted in schools. In each Broadband Island is located an applications integra-tion platform, TeleWeaver, which monetizes channels of access to the local community, to support the e-infrastructure while providing useful services to the population and the Government.
- Full Text:
- Date Issued: 2018
- Authors: Terzoli, Alfredo , Siebörger, Ingrid , Tsietsi, Mosiuoa , Gumbo, Sibukelo
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430973 , vital:72733 , https://doi.org/10.1007/978-3-319-98827-6_7
- Description: A large portion of the South African population is still not connected in a productive manner to the Internet, despite the existence of a govern-ment plan for public broadband, ‘SA Connect’. One reason for this could be the lack of an appropriate model, through which connectivity can be diffused in a meaningful way through all areas of South Africa. This paper presents the model developed over more than a decade of experimentation in real life settings in the Siyakhula Living Lab, a joint venture between the universities of Rhodes and Fort Hare, South Afri-ca. The model proposes the ‘Broadband Island’ as basic e-infrastructure unit, which clusters nearby points-of-presence hosted in schools. In each Broadband Island is located an applications integra-tion platform, TeleWeaver, which monetizes channels of access to the local community, to support the e-infrastructure while providing useful services to the population and the Government.
- Full Text:
- Date Issued: 2018
Digital storytelling as a teaching and learning strategy: experiences of student nurses
- Authors: Espach, Juanita
- Date: 2018
- Subjects: Nursing -- Study and teaching -- South Africa , Nursing students -- South Africa Storytelling -- South Africa -- Computer network resources College teaching -- South Africa Competency-based education
- Language: English
- Type: Thesis , Masters , MCur
- Identifier: http://hdl.handle.net/10948/21549 , vital:29552
- Description: The ever changing landscape of technology influences every aspect of modern society, also education. Within recent years, technological advancements and inventive educators have transformed traditional teaching and learning strategies to innovative technology infused strategies. These strategies could potentially meet the learning style of the millennial student. One such strategy is described as digital storytelling, during which student groups create a three to five minute multimedia video, utilizing a combination of digital elements such as a narrative voice recording, music, pictures, video and animation. After creating the digital story, the end product is shared with peers. Paucity in research regarding the use of digital storytelling in the context of nursing education in the Republic of South Africa was found. Thus the aim of the study was to explore and describe the experiences of student nurses during the use of digital storytelling as a teaching and learning strategy at a private Nursing Education Institution in Port Elizabeth. The researcher conducted an exploratory, descriptive, contextual and qualitative study which utilized a connectivism framework as the paradigm. Digital storytelling was used as a teaching and learning strategy in the researcher’s own class. A convenience sampling method was therefore employed to select participants. Data was gathered through documenting observational notes during the process of utilizing digital storytelling in the classroom. After the student nurses had utilized digital storytelling, five focus group interviews with twenty four research participants were conducted, which provided data saturation. The data was transcribed and analysed utilizing Tesch’s thematic analysis method and three themes emerged from the data. The benefits of digital storytelling were voiced by the participants since digital storytelling gave them a means to express themselves and they gained new skills while collaborating with others and improving their learning. There was a negative side to it as well, during which research participants experienced negative emotions, lacked the necessary technological skills and found peer teaching an obstacle to their own learning. The participants also provided suggestions to improve the use of digital storytelling during teaching and learning. A thick description of the data with a literature control was provided. The researcher utilized the findings of this study to develop guidelines for Nurse Educators in order to optimize the use of digital storytelling as a teaching and learning strategy. Rigour and trustworthiness were ensured by utilizing Guba and Lincoln’s four criteria. In this study the researcher adhered to the ethical principles as described by the Belmont Report and paid specific attention to the application of these ethical principles in the context of conducting research on one’s own teaching practices. The limitations of this study were that data was collected from only one group of student nurses at one private NEI, after the student nurses’ utilized digital storytelling for the first time in their training. The findings of this study can be used by Nurse Educators to optimize the use of digital storytelling as a teaching and learning strategy. The recommendations of this study include the implementation of the guidelines developed for Nurse Educators.
- Full Text:
- Date Issued: 2018
- Authors: Espach, Juanita
- Date: 2018
- Subjects: Nursing -- Study and teaching -- South Africa , Nursing students -- South Africa Storytelling -- South Africa -- Computer network resources College teaching -- South Africa Competency-based education
- Language: English
- Type: Thesis , Masters , MCur
- Identifier: http://hdl.handle.net/10948/21549 , vital:29552
- Description: The ever changing landscape of technology influences every aspect of modern society, also education. Within recent years, technological advancements and inventive educators have transformed traditional teaching and learning strategies to innovative technology infused strategies. These strategies could potentially meet the learning style of the millennial student. One such strategy is described as digital storytelling, during which student groups create a three to five minute multimedia video, utilizing a combination of digital elements such as a narrative voice recording, music, pictures, video and animation. After creating the digital story, the end product is shared with peers. Paucity in research regarding the use of digital storytelling in the context of nursing education in the Republic of South Africa was found. Thus the aim of the study was to explore and describe the experiences of student nurses during the use of digital storytelling as a teaching and learning strategy at a private Nursing Education Institution in Port Elizabeth. The researcher conducted an exploratory, descriptive, contextual and qualitative study which utilized a connectivism framework as the paradigm. Digital storytelling was used as a teaching and learning strategy in the researcher’s own class. A convenience sampling method was therefore employed to select participants. Data was gathered through documenting observational notes during the process of utilizing digital storytelling in the classroom. After the student nurses had utilized digital storytelling, five focus group interviews with twenty four research participants were conducted, which provided data saturation. The data was transcribed and analysed utilizing Tesch’s thematic analysis method and three themes emerged from the data. The benefits of digital storytelling were voiced by the participants since digital storytelling gave them a means to express themselves and they gained new skills while collaborating with others and improving their learning. There was a negative side to it as well, during which research participants experienced negative emotions, lacked the necessary technological skills and found peer teaching an obstacle to their own learning. The participants also provided suggestions to improve the use of digital storytelling during teaching and learning. A thick description of the data with a literature control was provided. The researcher utilized the findings of this study to develop guidelines for Nurse Educators in order to optimize the use of digital storytelling as a teaching and learning strategy. Rigour and trustworthiness were ensured by utilizing Guba and Lincoln’s four criteria. In this study the researcher adhered to the ethical principles as described by the Belmont Report and paid specific attention to the application of these ethical principles in the context of conducting research on one’s own teaching practices. The limitations of this study were that data was collected from only one group of student nurses at one private NEI, after the student nurses’ utilized digital storytelling for the first time in their training. The findings of this study can be used by Nurse Educators to optimize the use of digital storytelling as a teaching and learning strategy. The recommendations of this study include the implementation of the guidelines developed for Nurse Educators.
- Full Text:
- Date Issued: 2018
Dimensions of a memorable experience within a marine tourism context
- Authors: Jonas, Altouise Glowdean
- Date: 2018
- Subjects: Customer relations -- Management , Customer relations Relationship marketing Tourism -- Environmental aspects Coastal zone management -- Environmental aspects
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/30540 , vital:30958
- Description: Worldwide, businesses are operating in an environment which is continuously changing, forcing them to adapt their strategies in order to remain competitive. Two changes were of particular importance to this study. Firstly, businesses are faced with an increasing demand from consumers for experiences as opposed to products and services. Secondly, consumers are demanding experiences that are not just ordinary, but are unique and memorable. As one of the largest and most diverse industries globally, tourism offers a multitude of tourist activities. Marine tourism is one of the oldest, most popular and fastest developing types of tourism globally. Marine tourism has also become popular in South Africa. This popularity might be attributed to the country’s expansive coastline and to it being home to one of the most diverse marine systems in the world. Marine tourism makes significant contributions to South Africa’s economy. More benefits can be derived from this lucrative type of tourism if attention is given to the design and provision of marine tourism experiences that go beyond average experiences, and become memorable experiences. The reason for conducting this research was to provide the South African tourism industry, and marine tourism operators in particular, with information which might assist them in designing and staging memorable experiences. Such memorable experiences could result in a competitive advantage and enable the operators to attract more customers, which in turn, will benefit the individual operators, the industry as a whole, and ultimately, the South African economy. The study focused on three marine tourism activities, namely; shark-diving, visits to marine protected areas and whale-watching. Eight dimensions, namely; Delight, Hedonism, Involvement, Knowledge, Meaningfulness, Novelty, Refreshment and Social-Interaction were identified as prospective dimensions of a memorable experience within a marine tourism context. v The study employed purposive, convenience and snowball sampling to identify potential respondents. Primary data was collected by means of an online survey and paper-based self-administered questionnaires. Four hundred and forty-four useable responses were received. The results of the empirical study showed a positive correlation between all the dimensions and memorable experience for each of the three activities and for all the activities combined. A second order factor analysis showed that the eight dimensions loaded onto two factors. The resulting factors were named as the Affective Domain (consisting of Hedonism, Refreshment, Delight and Involvement) and the Cognitive Domain (consisting of Knowledge, Social- Interaction, Meaningfulness and Novelty). A positive relationship was found between the Affective Domain and Memorable Experience and also between the Cognitive Domain and Memorable Experience. The Cognitive domain showed a stronger relationship with Memorable Experience than what the Affective Domain did, for all the activities combined. The memorability of an experience in the case of all three activities combined can, firstly, be improved by Involvement. This is closely followed by the following dimensions in the Affective Domain; Delight, Hedonism and Refreshment. Under the Cognitive Domain the factor which is most important for improving memorability of all the activities combined is Meaningfulness, followed by Knowledge, Novelty and Social-Interaction. Finally, structural equation modelling confirmed a model representing the eight experience dimensions (Delight, Hedonism, Involvement, Knowledge, Meaningfulness, Novelty, Refreshment and Social-Interaction) and identified the relationships between the dimensions and Memorable Experience. This study makes four important contributions. Firstly, it contributes to the under-researched topic of marine tourism in South Africa. Secondly, it adds to the literature on memorable tourism experiences, specifically memorable marine tourism experiences and provides a measurement instrument and framework for further research. Thirdly, the study identifies and confirms that ‘delight’ is an important dimension of a memorable marine tourism experience. vi Lastly, a model was developed which can be used by marine tourism operators to enhance their strategies, operations and facilities which will enable operators to achieve a sustainable competitive advantage.
- Full Text:
- Date Issued: 2018
- Authors: Jonas, Altouise Glowdean
- Date: 2018
- Subjects: Customer relations -- Management , Customer relations Relationship marketing Tourism -- Environmental aspects Coastal zone management -- Environmental aspects
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/30540 , vital:30958
- Description: Worldwide, businesses are operating in an environment which is continuously changing, forcing them to adapt their strategies in order to remain competitive. Two changes were of particular importance to this study. Firstly, businesses are faced with an increasing demand from consumers for experiences as opposed to products and services. Secondly, consumers are demanding experiences that are not just ordinary, but are unique and memorable. As one of the largest and most diverse industries globally, tourism offers a multitude of tourist activities. Marine tourism is one of the oldest, most popular and fastest developing types of tourism globally. Marine tourism has also become popular in South Africa. This popularity might be attributed to the country’s expansive coastline and to it being home to one of the most diverse marine systems in the world. Marine tourism makes significant contributions to South Africa’s economy. More benefits can be derived from this lucrative type of tourism if attention is given to the design and provision of marine tourism experiences that go beyond average experiences, and become memorable experiences. The reason for conducting this research was to provide the South African tourism industry, and marine tourism operators in particular, with information which might assist them in designing and staging memorable experiences. Such memorable experiences could result in a competitive advantage and enable the operators to attract more customers, which in turn, will benefit the individual operators, the industry as a whole, and ultimately, the South African economy. The study focused on three marine tourism activities, namely; shark-diving, visits to marine protected areas and whale-watching. Eight dimensions, namely; Delight, Hedonism, Involvement, Knowledge, Meaningfulness, Novelty, Refreshment and Social-Interaction were identified as prospective dimensions of a memorable experience within a marine tourism context. v The study employed purposive, convenience and snowball sampling to identify potential respondents. Primary data was collected by means of an online survey and paper-based self-administered questionnaires. Four hundred and forty-four useable responses were received. The results of the empirical study showed a positive correlation between all the dimensions and memorable experience for each of the three activities and for all the activities combined. A second order factor analysis showed that the eight dimensions loaded onto two factors. The resulting factors were named as the Affective Domain (consisting of Hedonism, Refreshment, Delight and Involvement) and the Cognitive Domain (consisting of Knowledge, Social- Interaction, Meaningfulness and Novelty). A positive relationship was found between the Affective Domain and Memorable Experience and also between the Cognitive Domain and Memorable Experience. The Cognitive domain showed a stronger relationship with Memorable Experience than what the Affective Domain did, for all the activities combined. The memorability of an experience in the case of all three activities combined can, firstly, be improved by Involvement. This is closely followed by the following dimensions in the Affective Domain; Delight, Hedonism and Refreshment. Under the Cognitive Domain the factor which is most important for improving memorability of all the activities combined is Meaningfulness, followed by Knowledge, Novelty and Social-Interaction. Finally, structural equation modelling confirmed a model representing the eight experience dimensions (Delight, Hedonism, Involvement, Knowledge, Meaningfulness, Novelty, Refreshment and Social-Interaction) and identified the relationships between the dimensions and Memorable Experience. This study makes four important contributions. Firstly, it contributes to the under-researched topic of marine tourism in South Africa. Secondly, it adds to the literature on memorable tourism experiences, specifically memorable marine tourism experiences and provides a measurement instrument and framework for further research. Thirdly, the study identifies and confirms that ‘delight’ is an important dimension of a memorable marine tourism experience. vi Lastly, a model was developed which can be used by marine tourism operators to enhance their strategies, operations and facilities which will enable operators to achieve a sustainable competitive advantage.
- Full Text:
- Date Issued: 2018
Discontinuous gully erosion as a mechanism of wetland formation: a case study of the Kompanjiesdrif basin, Kromrivier, Eastern Cape, South Africa
- Authors: Lagesse, Juliette V
- Date: 2018
- Subjects: Arroyos -- South Africa -- Kromme River (Eastern Cape) , Arroyos -- Erosion -- South Africa -- Kromme River (Eastern Cape) , Climatic geomorphology -- South Africa -- Kromme River (Eastern Cape) , Sedimentation and deposition -- South Africa -- Kromme River (Eastern Cape) , Alluvial fans -- South Africa -- Kromme River (Eastern Cape) , Wetland ecology -- South Africa -- Kromme River (Eastern Cape) , Rhizophoraceae , Palmiet (Prionium serratum)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/60540 , vital:27791
- Description: The Kompanjiesdrif basin is an unchannelled valley bottom palmiet wetland located near the headwaters of the Kromrivier in the Eastern Cape of South Africa. The wetland itself is underlain by Bokkeveld shales with the bordering mountain ranges comprising more resistant Table Mountain Group quarzitic sandstones. The valley is relatively planar and broad in form over a width of approximately 200 m. None of the existing controls that are considered to lead to valley widening and longitudinal slope reduction are immediately apparent. The basin lies on the Post Africa II erosion surface; with no evidence of a resistant lithology which might act as a local base level, limiting rates of vertical erosion and inducing lateral planing in upstream reaches via a meandering channel. The possible role of sagging of the basin due to long term deep chemical weathering of bedrock is discounted as the lithologies in the basin are sedimentary in origin and thus not susceptible to chemical weathering. The degree to which climate and sea level changes affected rates of incision and subsequent slope reduction is unclear, although their potential influence should be acknowledged. This study examined the geomorphic dynamics as discerned from the sedimentary record and morphology of the wetland basin, which provide a snapshot into the long-term processes which lowered the longitudinal slope and widened this valley. Coring within the wetland to depths of 1 - 3.3 m revealed that the sedimentary fill generally comprised an upward fining sequence, with sand or fine sand at the base, grading into silt and clay and organic material in the upper sections of cores. Occasional instances of multiple fine sand layers were observed in a few of the cores. An increase in the organic content of material from the north to the south side of the wetland and the occurrence of multiple thin layers of sand in the stratigraphy, highlighted the role of the northern tributary alluvial fans in influencing valley form. Sediment from north bank alluvial fans seem to periodically, partially impound the wetland basin. Surveyed transects across the wetland basin along with subsurface coring to the depth to refusal, illustrated a localised increase in longitudinal slope downstream of the nodes of tributary alluvial fan deposits, which impinge on the trunk stream basin. Coupled with the presence of deep, drowned, trench-like features (up to 8 m deep) beneath floating mats of palmiet, which were predominantly free of sedimentary fill and found opposite tributary alluvial fans; confirmed that the northern tributaries play a major role in the structure and geomorphic dynamics of the basin. The trench-like features appeared to be remnants of deep, narrow, discontinuous gullies. Dating of sediment from the base of these features (460-7040 BP) confirmed that they were formed prior to European settlement in the area. Therefore, it is suggested that the localised increase in longitudinal slope, caused by sediment deposition on the alluvial fans, transgresses a geomorphic threshold slope and that gully erosion is thus initiated. The process of repeated gully erosion leads to planing of bedrock and longitudinal slope reduction. Gully erosion forms an integral component of a cycle of deposition and incision referred to as “cut-and-fill”. During each iteration of the cycle of cutting and filling, gullies form in novel locations leading to gradual valley widening. Over geological time scales, the planing of bedrock and resultant valley widening creates a broad planar valley with a very low longitudinal slope; producing conditions suitable for unchannelled valley bottom wetland formation.
- Full Text:
- Date Issued: 2018
- Authors: Lagesse, Juliette V
- Date: 2018
- Subjects: Arroyos -- South Africa -- Kromme River (Eastern Cape) , Arroyos -- Erosion -- South Africa -- Kromme River (Eastern Cape) , Climatic geomorphology -- South Africa -- Kromme River (Eastern Cape) , Sedimentation and deposition -- South Africa -- Kromme River (Eastern Cape) , Alluvial fans -- South Africa -- Kromme River (Eastern Cape) , Wetland ecology -- South Africa -- Kromme River (Eastern Cape) , Rhizophoraceae , Palmiet (Prionium serratum)
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/60540 , vital:27791
- Description: The Kompanjiesdrif basin is an unchannelled valley bottom palmiet wetland located near the headwaters of the Kromrivier in the Eastern Cape of South Africa. The wetland itself is underlain by Bokkeveld shales with the bordering mountain ranges comprising more resistant Table Mountain Group quarzitic sandstones. The valley is relatively planar and broad in form over a width of approximately 200 m. None of the existing controls that are considered to lead to valley widening and longitudinal slope reduction are immediately apparent. The basin lies on the Post Africa II erosion surface; with no evidence of a resistant lithology which might act as a local base level, limiting rates of vertical erosion and inducing lateral planing in upstream reaches via a meandering channel. The possible role of sagging of the basin due to long term deep chemical weathering of bedrock is discounted as the lithologies in the basin are sedimentary in origin and thus not susceptible to chemical weathering. The degree to which climate and sea level changes affected rates of incision and subsequent slope reduction is unclear, although their potential influence should be acknowledged. This study examined the geomorphic dynamics as discerned from the sedimentary record and morphology of the wetland basin, which provide a snapshot into the long-term processes which lowered the longitudinal slope and widened this valley. Coring within the wetland to depths of 1 - 3.3 m revealed that the sedimentary fill generally comprised an upward fining sequence, with sand or fine sand at the base, grading into silt and clay and organic material in the upper sections of cores. Occasional instances of multiple fine sand layers were observed in a few of the cores. An increase in the organic content of material from the north to the south side of the wetland and the occurrence of multiple thin layers of sand in the stratigraphy, highlighted the role of the northern tributary alluvial fans in influencing valley form. Sediment from north bank alluvial fans seem to periodically, partially impound the wetland basin. Surveyed transects across the wetland basin along with subsurface coring to the depth to refusal, illustrated a localised increase in longitudinal slope downstream of the nodes of tributary alluvial fan deposits, which impinge on the trunk stream basin. Coupled with the presence of deep, drowned, trench-like features (up to 8 m deep) beneath floating mats of palmiet, which were predominantly free of sedimentary fill and found opposite tributary alluvial fans; confirmed that the northern tributaries play a major role in the structure and geomorphic dynamics of the basin. The trench-like features appeared to be remnants of deep, narrow, discontinuous gullies. Dating of sediment from the base of these features (460-7040 BP) confirmed that they were formed prior to European settlement in the area. Therefore, it is suggested that the localised increase in longitudinal slope, caused by sediment deposition on the alluvial fans, transgresses a geomorphic threshold slope and that gully erosion is thus initiated. The process of repeated gully erosion leads to planing of bedrock and longitudinal slope reduction. Gully erosion forms an integral component of a cycle of deposition and incision referred to as “cut-and-fill”. During each iteration of the cycle of cutting and filling, gullies form in novel locations leading to gradual valley widening. Over geological time scales, the planing of bedrock and resultant valley widening creates a broad planar valley with a very low longitudinal slope; producing conditions suitable for unchannelled valley bottom wetland formation.
- Full Text:
- Date Issued: 2018
Discovery and validation of a CD4 binding aptamer through Crossover SELEX towards the preliminary development of a point-of-care aptasensor for rapid CD4+ T-cell counting
- Authors: Fellows, Tamika
- Date: 2018
- Subjects: Uncatalogued
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/63527 , vital:28431
- Description: Expected release date-April 2020
- Full Text:
- Date Issued: 2018
- Authors: Fellows, Tamika
- Date: 2018
- Subjects: Uncatalogued
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/63527 , vital:28431
- Description: Expected release date-April 2020
- Full Text:
- Date Issued: 2018
Discrepancy in conventional microscopic manual differential counts of band neutrophils among microscopists
- Godson-Katchew, Chesna Terry-Lee
- Authors: Godson-Katchew, Chesna Terry-Lee
- Date: 2018
- Subjects: Neutrophils , Hematology Medical statistics -- Research
- Language: English
- Type: Thesis , Masters , MHSc
- Identifier: http://hdl.handle.net/10948/30127 , vital:30830
- Description: The interpretation of the band neutrophil count on manual differential counts performed amongst microscopists can vary greatly. The band neutrophil is an immature granulocyte, maturing towards a segmented neutrophil. There are varying degrees of misconception of the band neutrophil identification, as the band neutrophil closely resembles the maturing segmented neutrophil. Although there are guidelines for the identification of band neutrophils, many laboratories incorporate their own “standard” as to what a band neutrophil should look like. Even when a standard exists for the identification of band neutrophils, many microscopists still have difficulty identifying these cells, making it difficult to accurately perform, interpret and report a manual differential count. Due to the controversy it is thus necessary to identify whether the problem lies with the identification of the band neutrophil itself, or the individual microscopist’s perception of differentiation between the band neutrophil and a maturing segmented neutrophil. The purpose of this study was to establish the accuracy by which microscopists distinguish band neutrophils from mature segmented neutrophils, the extent of discrepancies in the band neutrophil count amongst microscopists, to establish whether microscopists required re-training and to establish meaningful recommendations for microscopists to aid in the accurate identification of band neutrophils. The researcher thus made use of a self-administered picture diagram, distributed among microscopists to assess the accuracy of the band neutrophil counts prior to training. Participants counted an average of 61.47% neutrophils and 38.53% band neutrophils. Coefficient of variation (CV) for neutrophils and band neutrophils were calculated and yielded a CV of 22.48 and 35.87 respectively. Due to the high CV calculated, suggesting a greater level of dispersion around the mean, the researcher investigated individual responses from the picture-diagram. With the findings of the individual picture-diagram results, the researcher developed an impression that there was a large variation in counts for both neutrophils and band cells. Training was then given to participants arranged by the researcher, for accurate band neutrophil identification. Following training a second survey was conducted in order to assess the variation in counts among microscopists. 1 The peripheral blood smear was then provided and used to perform a manual differential count by conventional light microscopy, in order to compare results. Similarly, results obtained by the microscopists was compared to the verified manual differential count performed by a Haematologist; to improve the accuracy of results reported routinely. With the findings of the individual manual differential count results the researcher observed, that there was indeed a discrepancy in the manual differential counts performed by microscopists.
- Full Text:
- Date Issued: 2018
- Authors: Godson-Katchew, Chesna Terry-Lee
- Date: 2018
- Subjects: Neutrophils , Hematology Medical statistics -- Research
- Language: English
- Type: Thesis , Masters , MHSc
- Identifier: http://hdl.handle.net/10948/30127 , vital:30830
- Description: The interpretation of the band neutrophil count on manual differential counts performed amongst microscopists can vary greatly. The band neutrophil is an immature granulocyte, maturing towards a segmented neutrophil. There are varying degrees of misconception of the band neutrophil identification, as the band neutrophil closely resembles the maturing segmented neutrophil. Although there are guidelines for the identification of band neutrophils, many laboratories incorporate their own “standard” as to what a band neutrophil should look like. Even when a standard exists for the identification of band neutrophils, many microscopists still have difficulty identifying these cells, making it difficult to accurately perform, interpret and report a manual differential count. Due to the controversy it is thus necessary to identify whether the problem lies with the identification of the band neutrophil itself, or the individual microscopist’s perception of differentiation between the band neutrophil and a maturing segmented neutrophil. The purpose of this study was to establish the accuracy by which microscopists distinguish band neutrophils from mature segmented neutrophils, the extent of discrepancies in the band neutrophil count amongst microscopists, to establish whether microscopists required re-training and to establish meaningful recommendations for microscopists to aid in the accurate identification of band neutrophils. The researcher thus made use of a self-administered picture diagram, distributed among microscopists to assess the accuracy of the band neutrophil counts prior to training. Participants counted an average of 61.47% neutrophils and 38.53% band neutrophils. Coefficient of variation (CV) for neutrophils and band neutrophils were calculated and yielded a CV of 22.48 and 35.87 respectively. Due to the high CV calculated, suggesting a greater level of dispersion around the mean, the researcher investigated individual responses from the picture-diagram. With the findings of the individual picture-diagram results, the researcher developed an impression that there was a large variation in counts for both neutrophils and band cells. Training was then given to participants arranged by the researcher, for accurate band neutrophil identification. Following training a second survey was conducted in order to assess the variation in counts among microscopists. 1 The peripheral blood smear was then provided and used to perform a manual differential count by conventional light microscopy, in order to compare results. Similarly, results obtained by the microscopists was compared to the verified manual differential count performed by a Haematologist; to improve the accuracy of results reported routinely. With the findings of the individual manual differential count results the researcher observed, that there was indeed a discrepancy in the manual differential counts performed by microscopists.
- Full Text:
- Date Issued: 2018
Discrimination and dismissal based on age
- Authors: Hlohlolo, Sephiri
- Date: 2018
- Subjects: Age discrimination in employment -- South Africa , Employees -- Dismissal of -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: http://hdl.handle.net/10948/30309 , vital:30929
- Description: The purpose of this treatise is to discuss discrimination and dismissal based on age in the workplace. When doing this, specific focus will be on the provisions of section 187(2)(b) of the Labour Relations Act and its fairness when it comes to normal or agreed retirement age for persons employed. Section 187(2)(b) sets out certain justifications on which an employer can rely when it comes to dismissals based on age. South Africa (SA) is a constitutional state and the Constitution is the supreme law. What this means is that any national legislation promulgated must not be in conflict with the Constitution. On the contrary, national legislation must enable the constitutional imperatives. Reference to the Constitution of SA will be made, more so, the equality and fairness provisions. In the process of doing so, a probe into whether section 187(2)(b) as a constitutional enabler, will pass the constitutional muster, will also be looked into. Not all discrimination is unfair when it comes to the SA Labour Law. Provision for fair discrimination has been provided for and as a result, the treatise will also look at the concept of unfair discrimination and how it has been tested by the Courts. A further discussion will outline what is meant by discrimination and dismissal based on age, and whether such a dismissal is in fact a dismissal, and whether within the requirements of the LRA, such a dismissal or termination of employment contract, is in fact, fair. The history of the development of the concept of discrimination in SA will be addressed, and so is a comparative study on foreign law. While foreign jurisprudence is cardinal, a focus on the current SA case law will be done in order to evaluate how discrimination and dismissal based on age are dealt with. Lastly, a critical analysis of sub section 187(2)(b) of the LRA in relation to subsection 187(2)(a) will be looked at, as well.
- Full Text:
- Date Issued: 2018
- Authors: Hlohlolo, Sephiri
- Date: 2018
- Subjects: Age discrimination in employment -- South Africa , Employees -- Dismissal of -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: http://hdl.handle.net/10948/30309 , vital:30929
- Description: The purpose of this treatise is to discuss discrimination and dismissal based on age in the workplace. When doing this, specific focus will be on the provisions of section 187(2)(b) of the Labour Relations Act and its fairness when it comes to normal or agreed retirement age for persons employed. Section 187(2)(b) sets out certain justifications on which an employer can rely when it comes to dismissals based on age. South Africa (SA) is a constitutional state and the Constitution is the supreme law. What this means is that any national legislation promulgated must not be in conflict with the Constitution. On the contrary, national legislation must enable the constitutional imperatives. Reference to the Constitution of SA will be made, more so, the equality and fairness provisions. In the process of doing so, a probe into whether section 187(2)(b) as a constitutional enabler, will pass the constitutional muster, will also be looked into. Not all discrimination is unfair when it comes to the SA Labour Law. Provision for fair discrimination has been provided for and as a result, the treatise will also look at the concept of unfair discrimination and how it has been tested by the Courts. A further discussion will outline what is meant by discrimination and dismissal based on age, and whether such a dismissal is in fact a dismissal, and whether within the requirements of the LRA, such a dismissal or termination of employment contract, is in fact, fair. The history of the development of the concept of discrimination in SA will be addressed, and so is a comparative study on foreign law. While foreign jurisprudence is cardinal, a focus on the current SA case law will be done in order to evaluate how discrimination and dismissal based on age are dealt with. Lastly, a critical analysis of sub section 187(2)(b) of the LRA in relation to subsection 187(2)(a) will be looked at, as well.
- Full Text:
- Date Issued: 2018
Disputes, relationships and identity: analysing human-human conflicts as a basis for human-wildlife conflicts in the mid-Zambezi valley, northern Zimbabwe
- Authors: Jani, Vincent
- Date: 2018
- Subjects: Environmental geography , Wildlife management Wildlife conservation Human-animal relationships
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/30364 , vital:30934
- Description: This study analysed how human-human conflicts (HHCs) underlie human-wildlife conflicts (HWCs) in Chapoto Ward in the mid-Zambezi valley, northern Zimbabwe. The analytical framework entailed the use of the Levels of Conflict Model (LCM) – a model that seeks to expose different levels of conflict. To gain a rich understanding of the conflicts under investigation, a qualitative research design was employed with triangulation at its core in order to ensure the necessary quality and rigour of the findings. In this case, four different types of data were used, namely, in-depth interviews with heads of households, key informant interviews, focus group sessions, and document analysis. Thematic and content analysis were used to analyse the data which were classified into the following conflict levels: surface level disputes; an intermediate level involving ongoing conflictual relationships; and a deeper level of conflict rooted in identity. Three key findings were generated. Firstly, a substantial number of long-standing disputes were recorded during the ten-year period (2007-2016). Most of these disputes were not resolved because they had a long and complicated history which resulted in previous disputes resurfacing whenever a current one arose. Secondly, the history of unresolved conflict resulted in mistrust and failure to find common ground between the parties involved in the conflict. Lastly, the source of the disputes and unresolved conflicts was traced back to the identity level. This means that the antagonistic relationships among the stakeholders spilled over into the labelling and stigmatisation of all the groups involved in wildlife management. Thus, conflict between people and wildlife in Chapoto Ward was demonstrated to be a complex issue and underlain by HHC. These findings support the new line of thinking that HWC should not be viewed as simply a problem between people and wildlife but as a conflict between stakeholders with divergent views over wildlife management which manifests as HHC. Furthermore, the degree of polarisation between groups is substantial. In light of these findings, four major conclusions are drawn. Firstly, is the need to shift from narrowly focusing on the proximate conflicts between people and wildlife, to fully understand the complexity of conflict in order to arrive at solutions that successfully mitigate conflict between people and wildlife, and to address the underlying and deep-rooted conflict between stakeholders with divergent wildlife management goals. Secondly, the need for concerted efforts to ensure the involvement of all stakeholders, including women, in wildlife management and conservation by developing structures that enhance active participation of the local people in decision-making, v which promotes the success of conservation initiatives. Thirdly, the need to address the underlying and deep-rooted conflicts over wildlife management by building positive relationships and trust between stakeholders through the holding of regular capacity building workshops based on a more respectful and inclusive process. Fourthly, is the need to consider the interests of both ethnic groups, namely the Doma and the Chikunda by gathering information on the preferences of the identity groups in order to increase cooperation among them. Overall, the thesis introduces a new lens through which one can clearly understand the complexity of the conflict between people and wildlife.
- Full Text:
- Date Issued: 2018
- Authors: Jani, Vincent
- Date: 2018
- Subjects: Environmental geography , Wildlife management Wildlife conservation Human-animal relationships
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/30364 , vital:30934
- Description: This study analysed how human-human conflicts (HHCs) underlie human-wildlife conflicts (HWCs) in Chapoto Ward in the mid-Zambezi valley, northern Zimbabwe. The analytical framework entailed the use of the Levels of Conflict Model (LCM) – a model that seeks to expose different levels of conflict. To gain a rich understanding of the conflicts under investigation, a qualitative research design was employed with triangulation at its core in order to ensure the necessary quality and rigour of the findings. In this case, four different types of data were used, namely, in-depth interviews with heads of households, key informant interviews, focus group sessions, and document analysis. Thematic and content analysis were used to analyse the data which were classified into the following conflict levels: surface level disputes; an intermediate level involving ongoing conflictual relationships; and a deeper level of conflict rooted in identity. Three key findings were generated. Firstly, a substantial number of long-standing disputes were recorded during the ten-year period (2007-2016). Most of these disputes were not resolved because they had a long and complicated history which resulted in previous disputes resurfacing whenever a current one arose. Secondly, the history of unresolved conflict resulted in mistrust and failure to find common ground between the parties involved in the conflict. Lastly, the source of the disputes and unresolved conflicts was traced back to the identity level. This means that the antagonistic relationships among the stakeholders spilled over into the labelling and stigmatisation of all the groups involved in wildlife management. Thus, conflict between people and wildlife in Chapoto Ward was demonstrated to be a complex issue and underlain by HHC. These findings support the new line of thinking that HWC should not be viewed as simply a problem between people and wildlife but as a conflict between stakeholders with divergent views over wildlife management which manifests as HHC. Furthermore, the degree of polarisation between groups is substantial. In light of these findings, four major conclusions are drawn. Firstly, is the need to shift from narrowly focusing on the proximate conflicts between people and wildlife, to fully understand the complexity of conflict in order to arrive at solutions that successfully mitigate conflict between people and wildlife, and to address the underlying and deep-rooted conflict between stakeholders with divergent wildlife management goals. Secondly, the need for concerted efforts to ensure the involvement of all stakeholders, including women, in wildlife management and conservation by developing structures that enhance active participation of the local people in decision-making, v which promotes the success of conservation initiatives. Thirdly, the need to address the underlying and deep-rooted conflicts over wildlife management by building positive relationships and trust between stakeholders through the holding of regular capacity building workshops based on a more respectful and inclusive process. Fourthly, is the need to consider the interests of both ethnic groups, namely the Doma and the Chikunda by gathering information on the preferences of the identity groups in order to increase cooperation among them. Overall, the thesis introduces a new lens through which one can clearly understand the complexity of the conflict between people and wildlife.
- Full Text:
- Date Issued: 2018
Distribution of virulence determinants in Plesiomonas shigelloides and Vibrio species isolated from selected hospital wastewater effluents in the Eastern Cape Province, South Africa
- Authors: Mashudu, Mavhungu
- Date: 2018
- Subjects: Vibrio
- Language: English
- Type: Thesis , Masters , MSc (Microbiology)
- Identifier: http://hdl.handle.net/10353/14505 , vital:39996
- Description: Plesiomonas shigelloides and some Vibrio species are amongst the bacteria species classified into the emerging pathogenic bacteria grouping, and they portend increasing virulence and high resistance to some of the most potent antimicrobial agents used as most important and critical lines of defence against pathogenic infectious agents. Hospital wastewater has attracted significant attention as a pool for the regurgitation of pathogens into the environment which eventually becomes a problem to public health. It has been variously reported that hospital wastewater critically serves also as a puddle for microbial genetic interaction with outcomes including the development of resistance to antimicrobial agents among other pathogenic traits. And, in the same vein, exchanges and gene recombination may have been leading to the emergence of virulence determinants not previously known owing to the capacity of hospital wastewater to encompass a vast diversity of pathogenic bacteria and antimicrobial agents at the same material time. Hence, this research aimed at the evaluation of the prevalence of virulence and antibiotic resistance in Plesiomonas shigelloides and some human pathogenic Vibrio species isolated from selected hospital wastewater in the Eastern Cape Province of South Africa. Wastewater samples were collected at two weeks intervals throughout three months sampling duration from hospital wastewater facility in the Eastern Cape Province. The wastewater samples were from the secondary hospital and, tertiary hospital along with Limbede community wastewater facilities based in the Eastern Cape Province of South Africa. The wastewater samples were aseptically screened for the presence of presumptive Plesiomonas shigelloides and selected Vibrio species using the culture-based method. The identity of the presumptive Plesiomonas shigelloides and Vibrio species (Vibrio cholerae, V. fluvialis, V. parahaemolyticus, and V. vulnificus) isolates were confirmed using species specific primers. After that, the presence 14 of virulence determinants and the antimicrobial susceptibility profiles of the positive strains as well as the antimicrobial resistance factors were all determined. The distribution of the presumptive isolates was as follows; 322 Plesiomans shigelloides and 378 Vibrio species respectively. However, upon molecular confirmation studies, 85 out of 322; 26% of the total presumptive isolates, were confirmed as positive for Plesiomans shigelloides and, on the other hand, from the 378 presumptive Vibrio species, 71% (270) was as positive to Vibrio genus, and upon speciation of the positive isolates; 27% (73) was confirmed as Vibrio cholerae, 9% (24) as Vibrio parahaemolyticus, 4% (12) as Vibrio vulnificus and 3% (8) as Vibrio fluvialis. The remaining 57% (153) which was unaccounted for may belong to other Vibrio species not included in this studies. Various virulence determinants were shown to be present in the Vibrio species identified and the degree varied in line with the species. P. shigelloides showed high levels of resistance to impregnated antibiotics (18 different types). The antibiogram characteristics showed P. shigelloides to possess 100% resistance to Ciprofloxacin, Nalidixic acid, Trimethoprim, Ampicillin, Penicillin, Tetracycline, Doxycycline, Erythromycin, and Cephalothin. These findings are of crucial importance to public health and the science of infectology as it gives insight into the role of the hospital wastewater as a puddle for the recombination of antibiotic resistance determinants and virulence emergence in bacteria. On the strength of the finding of this research, it is essential to indicate that there is a need for an immediate review of hospital wastewater disposal process. Some form of treatment or pretreatment of the hospital wastewater is required before discharge into municipal wastewater treatment facilities. And, perhaps, continuous monitoring of hospital wastewater to reduce the risk posed to public health.
- Full Text:
- Date Issued: 2018
- Authors: Mashudu, Mavhungu
- Date: 2018
- Subjects: Vibrio
- Language: English
- Type: Thesis , Masters , MSc (Microbiology)
- Identifier: http://hdl.handle.net/10353/14505 , vital:39996
- Description: Plesiomonas shigelloides and some Vibrio species are amongst the bacteria species classified into the emerging pathogenic bacteria grouping, and they portend increasing virulence and high resistance to some of the most potent antimicrobial agents used as most important and critical lines of defence against pathogenic infectious agents. Hospital wastewater has attracted significant attention as a pool for the regurgitation of pathogens into the environment which eventually becomes a problem to public health. It has been variously reported that hospital wastewater critically serves also as a puddle for microbial genetic interaction with outcomes including the development of resistance to antimicrobial agents among other pathogenic traits. And, in the same vein, exchanges and gene recombination may have been leading to the emergence of virulence determinants not previously known owing to the capacity of hospital wastewater to encompass a vast diversity of pathogenic bacteria and antimicrobial agents at the same material time. Hence, this research aimed at the evaluation of the prevalence of virulence and antibiotic resistance in Plesiomonas shigelloides and some human pathogenic Vibrio species isolated from selected hospital wastewater in the Eastern Cape Province of South Africa. Wastewater samples were collected at two weeks intervals throughout three months sampling duration from hospital wastewater facility in the Eastern Cape Province. The wastewater samples were from the secondary hospital and, tertiary hospital along with Limbede community wastewater facilities based in the Eastern Cape Province of South Africa. The wastewater samples were aseptically screened for the presence of presumptive Plesiomonas shigelloides and selected Vibrio species using the culture-based method. The identity of the presumptive Plesiomonas shigelloides and Vibrio species (Vibrio cholerae, V. fluvialis, V. parahaemolyticus, and V. vulnificus) isolates were confirmed using species specific primers. After that, the presence 14 of virulence determinants and the antimicrobial susceptibility profiles of the positive strains as well as the antimicrobial resistance factors were all determined. The distribution of the presumptive isolates was as follows; 322 Plesiomans shigelloides and 378 Vibrio species respectively. However, upon molecular confirmation studies, 85 out of 322; 26% of the total presumptive isolates, were confirmed as positive for Plesiomans shigelloides and, on the other hand, from the 378 presumptive Vibrio species, 71% (270) was as positive to Vibrio genus, and upon speciation of the positive isolates; 27% (73) was confirmed as Vibrio cholerae, 9% (24) as Vibrio parahaemolyticus, 4% (12) as Vibrio vulnificus and 3% (8) as Vibrio fluvialis. The remaining 57% (153) which was unaccounted for may belong to other Vibrio species not included in this studies. Various virulence determinants were shown to be present in the Vibrio species identified and the degree varied in line with the species. P. shigelloides showed high levels of resistance to impregnated antibiotics (18 different types). The antibiogram characteristics showed P. shigelloides to possess 100% resistance to Ciprofloxacin, Nalidixic acid, Trimethoprim, Ampicillin, Penicillin, Tetracycline, Doxycycline, Erythromycin, and Cephalothin. These findings are of crucial importance to public health and the science of infectology as it gives insight into the role of the hospital wastewater as a puddle for the recombination of antibiotic resistance determinants and virulence emergence in bacteria. On the strength of the finding of this research, it is essential to indicate that there is a need for an immediate review of hospital wastewater disposal process. Some form of treatment or pretreatment of the hospital wastewater is required before discharge into municipal wastewater treatment facilities. And, perhaps, continuous monitoring of hospital wastewater to reduce the risk posed to public health.
- Full Text:
- Date Issued: 2018
Donor support, electoral dynamics and democratisation in South Africa :the case of the Buffalo City Metropolitan Municipality, Eastern Cape
- Authors: Bosompem, Henry Kofi
- Date: 2018
- Subjects: Democratization -- South Africa Elections -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD(Sociology)
- Identifier: http://hdl.handle.net/10353/11243 , vital:37612
- Description: This thesis is on Donor Support, Electoral Dynamics and Democratisation in South Africa with particular focus on the Buffalo City Municipality of the Eastern Cape. The main aim of the thesis is to investigate and highlight the global outlook of donor support perspectives and conditionalities and to examine the basic tenets of democratisation and link them to the interplay of the electoral dynamics that influence grassroots political participation. Furthermore, the study attempts to ascertain the involvement and perceptions of local communities with regard to the role of donor support in democratic governance, development and electoral dynamics. In this era and dispensation of democracy, the fledging democratic institutions require substantial donor support to perform their constitutional mandatory obligations. Most of this support had traditionally come from government. Given the weight and pressure on the government budget, the widening unemployment and inequality in South African communities, there is the need to solicit assistance from development partners for electoral administration and development. The current study, therefore, investigated community voters, political parties and the Elected or Nominated Councillors’ perceptions of donor support and democratisation. This thesis further investigated the roles and functions of the Donor Agency, the Independent Electoral Commission (IEC) and Buffalo City Metropolitan Municipality (BCMM) in donor support, electoral administration and democratisation. The study utilized a mixed method approach where 384 structured questionnaires were administered and 52 in-depth interviews conducted with the respondents. The study made use of a systematic empirical inquiry and literature review to understand its subject matter. It did not only scrutinise data previously collected by other researchers but also utilised information from other sources such as tabloid surveys, brochures, bulletins and the internet. Thus, this strategy is ideal for the present study which seeks to capture the views, experiences and feelings and understanding of party officials. This study utilized the Development aid theory, political party and democratisation theories, Gouldner’s theory of Moral Norm of Reciprocity and Social Support in combination with Larzasfeld’s Voters’ behaviour theory and the social justice and equity perspective as elements of the theoretical framework.The purpose of achieving electoral confidence among the citizens is to demonstrate the value of electoral dynamics and perspectives of democratization that forms an expressed vi indicator of the relationship between politics and development. The electoral dynamics that shape political institutions, governance and its discourses in any democratic enterprise include: party affiliation, party and donor support mobilisation, voting patterns, government and the state agency’s performance. In addition, it includes economic policies towards poverty alleviation, service delivery, ethnic politics and all the state democratization policies which are pursued to bring greater relief to its citizens. Correspondingly, it is geared towards creating a balanced relationship on the donor-recipient equation and to ensure socio-economic well-being to the citizens guided by reciprocity, good governance, transparency, accountability and social justice.The emerging findings indicate that most political parties and elected councillors in the municipality receive donor support beside the traditional sources that we know such as membership dues, party subscriptions, levies, state sponsorship,fundraising for special projects and sale of souvenirs. Some of the sources were from international community and Non-Governmental Organisations (NGOs). The study found that donors require huge returns on their support and investments. The IEC and BCMM were largely funded by Treasury for their projects and programmes. However, the BCMM also gets substantial support from sister-city relations with other municipalities abroad. Some community voters hold the view that political party funding opens the doors for the hijacking of democracy. Others hold the opinion that dishonest donors corrupt weak governments, undiscerning officials and immoral leaders. Nevertheless, some political party officials felt that donors were not all that evil. They hold the view that genuine donors help to build the capacity of officials and strengthen party structures, thereby deepening democratic ethics and culture. They were of the view that good donors promote transparency, accountability and good governance to strengthen the pillars and the threshold of democracy and the democratisation processes in emerging states in sub-Saharan Africa. On the basis of these findings, the core argument of this study is that donor support induces democratisation which mainly benefit donor communities and municipal elites at the expense of local communities. Nevertheless, the perception that development projects funded by donor agencies are meant for donor poverty alleviation, despite the absence of visible effects of trickle down, account for community members’ participation in the electoral system.
- Full Text:
- Date Issued: 2018
- Authors: Bosompem, Henry Kofi
- Date: 2018
- Subjects: Democratization -- South Africa Elections -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD(Sociology)
- Identifier: http://hdl.handle.net/10353/11243 , vital:37612
- Description: This thesis is on Donor Support, Electoral Dynamics and Democratisation in South Africa with particular focus on the Buffalo City Municipality of the Eastern Cape. The main aim of the thesis is to investigate and highlight the global outlook of donor support perspectives and conditionalities and to examine the basic tenets of democratisation and link them to the interplay of the electoral dynamics that influence grassroots political participation. Furthermore, the study attempts to ascertain the involvement and perceptions of local communities with regard to the role of donor support in democratic governance, development and electoral dynamics. In this era and dispensation of democracy, the fledging democratic institutions require substantial donor support to perform their constitutional mandatory obligations. Most of this support had traditionally come from government. Given the weight and pressure on the government budget, the widening unemployment and inequality in South African communities, there is the need to solicit assistance from development partners for electoral administration and development. The current study, therefore, investigated community voters, political parties and the Elected or Nominated Councillors’ perceptions of donor support and democratisation. This thesis further investigated the roles and functions of the Donor Agency, the Independent Electoral Commission (IEC) and Buffalo City Metropolitan Municipality (BCMM) in donor support, electoral administration and democratisation. The study utilized a mixed method approach where 384 structured questionnaires were administered and 52 in-depth interviews conducted with the respondents. The study made use of a systematic empirical inquiry and literature review to understand its subject matter. It did not only scrutinise data previously collected by other researchers but also utilised information from other sources such as tabloid surveys, brochures, bulletins and the internet. Thus, this strategy is ideal for the present study which seeks to capture the views, experiences and feelings and understanding of party officials. This study utilized the Development aid theory, political party and democratisation theories, Gouldner’s theory of Moral Norm of Reciprocity and Social Support in combination with Larzasfeld’s Voters’ behaviour theory and the social justice and equity perspective as elements of the theoretical framework.The purpose of achieving electoral confidence among the citizens is to demonstrate the value of electoral dynamics and perspectives of democratization that forms an expressed vi indicator of the relationship between politics and development. The electoral dynamics that shape political institutions, governance and its discourses in any democratic enterprise include: party affiliation, party and donor support mobilisation, voting patterns, government and the state agency’s performance. In addition, it includes economic policies towards poverty alleviation, service delivery, ethnic politics and all the state democratization policies which are pursued to bring greater relief to its citizens. Correspondingly, it is geared towards creating a balanced relationship on the donor-recipient equation and to ensure socio-economic well-being to the citizens guided by reciprocity, good governance, transparency, accountability and social justice.The emerging findings indicate that most political parties and elected councillors in the municipality receive donor support beside the traditional sources that we know such as membership dues, party subscriptions, levies, state sponsorship,fundraising for special projects and sale of souvenirs. Some of the sources were from international community and Non-Governmental Organisations (NGOs). The study found that donors require huge returns on their support and investments. The IEC and BCMM were largely funded by Treasury for their projects and programmes. However, the BCMM also gets substantial support from sister-city relations with other municipalities abroad. Some community voters hold the view that political party funding opens the doors for the hijacking of democracy. Others hold the opinion that dishonest donors corrupt weak governments, undiscerning officials and immoral leaders. Nevertheless, some political party officials felt that donors were not all that evil. They hold the view that genuine donors help to build the capacity of officials and strengthen party structures, thereby deepening democratic ethics and culture. They were of the view that good donors promote transparency, accountability and good governance to strengthen the pillars and the threshold of democracy and the democratisation processes in emerging states in sub-Saharan Africa. On the basis of these findings, the core argument of this study is that donor support induces democratisation which mainly benefit donor communities and municipal elites at the expense of local communities. Nevertheless, the perception that development projects funded by donor agencies are meant for donor poverty alleviation, despite the absence of visible effects of trickle down, account for community members’ participation in the electoral system.
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- Date Issued: 2018