Tuning the redox properties of Co-N4 macrocyclic complexes for the catalytic electrooxidation of glucose
- Villagra, Evelyn, Bedioui, Fethi, Nyokong, Tebello, Canales, J Carlos, Sancy, Mamie, Páez, Maritza A, Costamagna, Juan, Zagal, Jose H
- Authors: Villagra, Evelyn , Bedioui, Fethi , Nyokong, Tebello , Canales, J Carlos , Sancy, Mamie , Páez, Maritza A , Costamagna, Juan , Zagal, Jose H
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268675 , vital:54221 , xlink:href="https://doi.org/10.1016/j.electacta.2008.02.006"
- Description: Graphite electrodes modified with four different cobalt N4 macrocyclics, namely Co tetrapentapyridinophthalocyanine, (CoTPenPyrPc), Co tetrapyridinoporphyrazine (CoTPyPz), Co octa(hydroxyethylthio)phthalocyanine (CoOEHTPc) and Co tetranitrophthalocyanine (CoTNPc) exhibit catalytic activity for the oxidation of glucose in alkaline media. The purpose of this work is to establish correlations between the catalytic activity of these complexes and their redox potential. The activity of the different modified electrodes was tested by linear voltammetry under hydrodynamic conditions using the rotating disk technique. Tafel plots constructed from mass-transport corrected currents give slopes ranging from 0.080 to 0.160 V/decade for the different catalysts which suggests that a first one-electron step is rate controlling with the symmetry of the energy barrier depending on the nature of the ligand of the Co complex. A plot of log I versus the Co(II)/(I) formal potential gives a volcano curve that also includes catalysts studied previously. This illustrates the concept that the formal potential of the catalyst needs to be tuned to a certain value for achieving maximum activity. A theoretical interpretation of these results is given in terms of Langmuir isotherms for the adsorption of glucose on the Co sites of the surface-confined metal complexes.
- Full Text:
- Date Issued: 2008
- Authors: Villagra, Evelyn , Bedioui, Fethi , Nyokong, Tebello , Canales, J Carlos , Sancy, Mamie , Páez, Maritza A , Costamagna, Juan , Zagal, Jose H
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268675 , vital:54221 , xlink:href="https://doi.org/10.1016/j.electacta.2008.02.006"
- Description: Graphite electrodes modified with four different cobalt N4 macrocyclics, namely Co tetrapentapyridinophthalocyanine, (CoTPenPyrPc), Co tetrapyridinoporphyrazine (CoTPyPz), Co octa(hydroxyethylthio)phthalocyanine (CoOEHTPc) and Co tetranitrophthalocyanine (CoTNPc) exhibit catalytic activity for the oxidation of glucose in alkaline media. The purpose of this work is to establish correlations between the catalytic activity of these complexes and their redox potential. The activity of the different modified electrodes was tested by linear voltammetry under hydrodynamic conditions using the rotating disk technique. Tafel plots constructed from mass-transport corrected currents give slopes ranging from 0.080 to 0.160 V/decade for the different catalysts which suggests that a first one-electron step is rate controlling with the symmetry of the energy barrier depending on the nature of the ligand of the Co complex. A plot of log I versus the Co(II)/(I) formal potential gives a volcano curve that also includes catalysts studied previously. This illustrates the concept that the formal potential of the catalyst needs to be tuned to a certain value for achieving maximum activity. A theoretical interpretation of these results is given in terms of Langmuir isotherms for the adsorption of glucose on the Co sites of the surface-confined metal complexes.
- Full Text:
- Date Issued: 2008
Underlying mechanisms affecting institutionalisation of environmental education courses in Southern Africa
- Authors: Lupele, Justin
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386926 , vital:68188 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122773"
- Description: This paper discusses the underlying causal mechanisms that enabled or constrained institutionalisation of environmental education in 12 institutions in eight countries in southern Africa. The study was carried out in the context of the Southern Africa Development Community Regional Environmental Education Support Programme’s Course Development Network (CDN). This paper reports on part of the author's doctoral study and draws on critical realism as the ontological lens. Data analysis was done by means of a retroductive mode of inference, as articulated by Danermark, Ekström, Jakosben and Karlsson (2002). The paper demonstrates that there are a number of underlying causal mechanisms, which may enable or constrain institutionalisation of environmental education. They include factors at play at both national and institutional level; namely, responsiveness to national and institutional needs, recognition and ownership, accreditation and certification, institutional culture and politics, short course support structure and support from colleagues. As part of the discussions of the results of the study, I have advanced some retroductive theories that suggest causal mechanisms beyond the empirical data based on the participants’ experiences and events in the CDN.
- Full Text:
- Date Issued: 2008
- Authors: Lupele, Justin
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386926 , vital:68188 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122773"
- Description: This paper discusses the underlying causal mechanisms that enabled or constrained institutionalisation of environmental education in 12 institutions in eight countries in southern Africa. The study was carried out in the context of the Southern Africa Development Community Regional Environmental Education Support Programme’s Course Development Network (CDN). This paper reports on part of the author's doctoral study and draws on critical realism as the ontological lens. Data analysis was done by means of a retroductive mode of inference, as articulated by Danermark, Ekström, Jakosben and Karlsson (2002). The paper demonstrates that there are a number of underlying causal mechanisms, which may enable or constrain institutionalisation of environmental education. They include factors at play at both national and institutional level; namely, responsiveness to national and institutional needs, recognition and ownership, accreditation and certification, institutional culture and politics, short course support structure and support from colleagues. As part of the discussions of the results of the study, I have advanced some retroductive theories that suggest causal mechanisms beyond the empirical data based on the participants’ experiences and events in the CDN.
- Full Text:
- Date Issued: 2008
Viewpoint: reading conference recommendations in a wider context of social change
- Authors: Lotz-Sisitka, Heila
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67411 , vital:29085 , https://www.ajol.info/index.php/sajee/article/view/122783
- Description: publisher version , This short Viewpoint paper considers the role and value of conference recommendations in shaping the field of environmental education. It explores the social politics, and often contested nature, of conference recommendations and their institutional histories, arguing that the act of producing conference recommendations forms part of the practices of new social movements. The paper recommends historicising conference recommendations and OEcross readings‚ to consider changing discourses and new developments in the field. Accompanying the short Viewpoint paper, are two sets of recently produced conference recommendations, one from the 4th International Environmental Education Conference held in Ahmedabad, India, and the other from the 1st International Conference on Mainstreaming Environment and Sustainability in African Universities held in Nairobi, Kenya.
- Full Text:
- Date Issued: 2008
- Authors: Lotz-Sisitka, Heila
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67411 , vital:29085 , https://www.ajol.info/index.php/sajee/article/view/122783
- Description: publisher version , This short Viewpoint paper considers the role and value of conference recommendations in shaping the field of environmental education. It explores the social politics, and often contested nature, of conference recommendations and their institutional histories, arguing that the act of producing conference recommendations forms part of the practices of new social movements. The paper recommends historicising conference recommendations and OEcross readings‚ to consider changing discourses and new developments in the field. Accompanying the short Viewpoint paper, are two sets of recently produced conference recommendations, one from the 4th International Environmental Education Conference held in Ahmedabad, India, and the other from the 1st International Conference on Mainstreaming Environment and Sustainability in African Universities held in Nairobi, Kenya.
- Full Text:
- Date Issued: 2008
Volcano correlations for the reactivity of surface-confined cobalt N4-macrocyclics for the electrocatalytic oxidation of 2-mercaptoacetate
- Claußen, Jan A, Ochoa, Gonzalo, Páez, Maritza, Costamagno, Juan, Gulppi, Miguel, Nyokong, Tebello, Bedioui, Fethi, Zagal, José H
- Authors: Claußen, Jan A , Ochoa, Gonzalo , Páez, Maritza , Costamagno, Juan , Gulppi, Miguel , Nyokong, Tebello , Bedioui, Fethi , Zagal, José H
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268688 , vital:54222 , xlink:href="https://doi.org/10.1007/s10008-007-0336-y"
- Description: We have investigated the electrocatalytic activity of several substituted and unsubstituted cobalt–phthalocyanines of substituted tetraphenyl porphyrins and of vitamin B12, for the electro-oxidation of 2-mercaptoacetate, with the complexes pre-adsorbed on a pyrolytic graphite electrode. Several N4-macrocyclic were used to have a wide variety of Co(II)/(I) formal potentials. The electrocatalytic activity, measured as current at constant potential, increases with the Co(II)/(I) redox potential for porphyrins as Co–pentafluorotetraphenylporphyrin larger than Co–tetrasulfonatotetraphenylporphyrin larger than Co-2,2′,2″,2‴tetra-aminotetraphenylporphyrin and decreases for cobalt phthalocyanines as Co-3,4-octaethylhexyloxyphthalocyanine > Co–octamethoxyphthalocyanine > Co–tetranitrophthalocyanine Co–tetraaminophthalocyanine > Co–unsubstituted phthalocyanine > Co–tetrasulfonatophthalocyanine > Co–perfluorinated phthalocyanine. Vitamin B12 exhibits the maximum activity. A correlation of log I (at constant potential) versus the Co(II)/(I) formal potential of the catalysts gives a volcano curve. This clearly shows that the search for better catalysts for this reaction point to those N4-macrocyclic complexes with Co(II)/(I) formal potentials close to −0.84 V versus SCE, which correspond to an optimum situation for the interaction of the thiol with the active site.
- Full Text:
- Date Issued: 2008
- Authors: Claußen, Jan A , Ochoa, Gonzalo , Páez, Maritza , Costamagno, Juan , Gulppi, Miguel , Nyokong, Tebello , Bedioui, Fethi , Zagal, José H
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/268688 , vital:54222 , xlink:href="https://doi.org/10.1007/s10008-007-0336-y"
- Description: We have investigated the electrocatalytic activity of several substituted and unsubstituted cobalt–phthalocyanines of substituted tetraphenyl porphyrins and of vitamin B12, for the electro-oxidation of 2-mercaptoacetate, with the complexes pre-adsorbed on a pyrolytic graphite electrode. Several N4-macrocyclic were used to have a wide variety of Co(II)/(I) formal potentials. The electrocatalytic activity, measured as current at constant potential, increases with the Co(II)/(I) redox potential for porphyrins as Co–pentafluorotetraphenylporphyrin larger than Co–tetrasulfonatotetraphenylporphyrin larger than Co-2,2′,2″,2‴tetra-aminotetraphenylporphyrin and decreases for cobalt phthalocyanines as Co-3,4-octaethylhexyloxyphthalocyanine > Co–octamethoxyphthalocyanine > Co–tetranitrophthalocyanine Co–tetraaminophthalocyanine > Co–unsubstituted phthalocyanine > Co–tetrasulfonatophthalocyanine > Co–perfluorinated phthalocyanine. Vitamin B12 exhibits the maximum activity. A correlation of log I (at constant potential) versus the Co(II)/(I) formal potential of the catalysts gives a volcano curve. This clearly shows that the search for better catalysts for this reaction point to those N4-macrocyclic complexes with Co(II)/(I) formal potentials close to −0.84 V versus SCE, which correspond to an optimum situation for the interaction of the thiol with the active site.
- Full Text:
- Date Issued: 2008
WET-Origins: controls on the distribution and dynamics of wetlands in South Africa
- Ellery, William F N, Grenfell, Michael C, Grenfell, Suzanne E, Kotze, Donovan C, McCarthy, Terence, Tooth, Stephen, Grundling, Piet-Louis, Beckedahl, Heinz, Le Maitre, David C, Ramsay, Lisa F
- Authors: Ellery, William F N , Grenfell, Michael C , Grenfell, Suzanne E , Kotze, Donovan C , McCarthy, Terence , Tooth, Stephen , Grundling, Piet-Louis , Beckedahl, Heinz , Le Maitre, David C , Ramsay, Lisa F
- Date: 2008
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/176598 , vital:40091 , ISBN 978-77005-633-6 , https://www.wrc.org.za/mdocs-posts/wetland-management-series-wet-origins-controls-on-the-distribution-and-dynamics-of-wetlands-in-south-africa/
- Description: The need for wetland rehabilitation in South Africa is compelling: loss and degradation of wetlands have been great and national policy and legislation provide clear direction and support for rehabilitation. However, rehabilitating wetlands is often complex because wetlands and their links with people are complex (e.g. through the ways that people use wetlands and the different benefits that people receive from the ecosystem services that wetlands supply).
- Full Text:
- Date Issued: 2008
- Authors: Ellery, William F N , Grenfell, Michael C , Grenfell, Suzanne E , Kotze, Donovan C , McCarthy, Terence , Tooth, Stephen , Grundling, Piet-Louis , Beckedahl, Heinz , Le Maitre, David C , Ramsay, Lisa F
- Date: 2008
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/176598 , vital:40091 , ISBN 978-77005-633-6 , https://www.wrc.org.za/mdocs-posts/wetland-management-series-wet-origins-controls-on-the-distribution-and-dynamics-of-wetlands-in-south-africa/
- Description: The need for wetland rehabilitation in South Africa is compelling: loss and degradation of wetlands have been great and national policy and legislation provide clear direction and support for rehabilitation. However, rehabilitating wetlands is often complex because wetlands and their links with people are complex (e.g. through the ways that people use wetlands and the different benefits that people receive from the ecosystem services that wetlands supply).
- Full Text:
- Date Issued: 2008
What future subordinates will value in their leaders
- Cox, A, Amos, Trevor L, Baxter, Jeremy
- Authors: Cox, A , Amos, Trevor L , Baxter, Jeremy
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270992 , vital:54499 , xlink:href="https://hdl.handle.net/10520/EJC51031"
- Description: Leaders should not randomly choose a leadership style. To be effective, leaders need to ensure that their leadership style is congruent with what subordinates value. The focus of this study is on what the future South African graduate workforce will value in a leader. The female and male respondents in this study emphasise similar leadership values, indicating that there is no distinct set of competencies that will be valued separately by males and females. The same was found for respondents of different cultures, namely African, Coloured, Indian, White and other. With respect to both gender and culture, the respondents emphasise a mixture of African and Western leadership values. This supports the idea that to be effective in South Africa, leaders need to understand the prevailing national cultural values before simply applying ''foreign'' leadership models and theories based upon cultural values found in the West. This research finds that irrespective of gender and culture in the South African workplace, to be effective, leaders need to be loyal and inspirational, have vision and integrity and must be open and honest with their subordinates. Leaders should avoid being autocratic, strict, religious, ritualistic and traditional. They should also avoid using consensus and perceived external control.
- Full Text:
- Date Issued: 2008
- Authors: Cox, A , Amos, Trevor L , Baxter, Jeremy
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270992 , vital:54499 , xlink:href="https://hdl.handle.net/10520/EJC51031"
- Description: Leaders should not randomly choose a leadership style. To be effective, leaders need to ensure that their leadership style is congruent with what subordinates value. The focus of this study is on what the future South African graduate workforce will value in a leader. The female and male respondents in this study emphasise similar leadership values, indicating that there is no distinct set of competencies that will be valued separately by males and females. The same was found for respondents of different cultures, namely African, Coloured, Indian, White and other. With respect to both gender and culture, the respondents emphasise a mixture of African and Western leadership values. This supports the idea that to be effective in South Africa, leaders need to understand the prevailing national cultural values before simply applying ''foreign'' leadership models and theories based upon cultural values found in the West. This research finds that irrespective of gender and culture in the South African workplace, to be effective, leaders need to be loyal and inspirational, have vision and integrity and must be open and honest with their subordinates. Leaders should avoid being autocratic, strict, religious, ritualistic and traditional. They should also avoid using consensus and perceived external control.
- Full Text:
- Date Issued: 2008
When commercial can also be community:
- Authors: du Toit, Peter , Rau, Asta
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159322 , vital:40287 , https://hdl.handle.net/10520/EJC140094
- Description: Questions of ownership, control and profit distribution are widely used to distinguish between commercial and community media ventures, but an over-reliance on such distinctions may eclipse other important considerations in a way that impacts negatively on media diversity.
- Full Text:
- Date Issued: 2008
- Authors: du Toit, Peter , Rau, Asta
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159322 , vital:40287 , https://hdl.handle.net/10520/EJC140094
- Description: Questions of ownership, control and profit distribution are widely used to distinguish between commercial and community media ventures, but an over-reliance on such distinctions may eclipse other important considerations in a way that impacts negatively on media diversity.
- Full Text:
- Date Issued: 2008
Winds of change in teachers’ classroom assessment practice: a self-critical reflection on the teaching and learning of visual literacy in a rural Eastern Cape High School
- Authors: Mbelani, Madeyandile
- Date: 2008
- Language: English
- Type: text , Article
- Identifier: vital:7021 , http://hdl.handle.net/10962/d1007201
- Description: The year 2006 saw the implementation of a new curriculum for teaching English First Additional Language (FAL) in grades 10-12 in South African high schools. The curriculum includes the teaching and assessment of visual literacy – a challenge for teachers whose apartheid-era teacher education did not address visual literacy at all. The article is a self-critical reflection on my attempts to teach and assess a unit on visual literacy in a Grade 10 class in a rural high school in the Eastern Cape province of South Africa.
- Full Text:
- Date Issued: 2008
- Authors: Mbelani, Madeyandile
- Date: 2008
- Language: English
- Type: text , Article
- Identifier: vital:7021 , http://hdl.handle.net/10962/d1007201
- Description: The year 2006 saw the implementation of a new curriculum for teaching English First Additional Language (FAL) in grades 10-12 in South African high schools. The curriculum includes the teaching and assessment of visual literacy – a challenge for teachers whose apartheid-era teacher education did not address visual literacy at all. The article is a self-critical reflection on my attempts to teach and assess a unit on visual literacy in a Grade 10 class in a rural high school in the Eastern Cape province of South Africa.
- Full Text:
- Date Issued: 2008
Women writers of the South Asian diaspora : towards a transnational feminist Aesthetic?
- Authors: Naidu, Samantha
- Date: 2008
- Language: English
- Type: Article , text
- Identifier: vital:26375 , http://hdl.handle.net/10962/54027 , https://orcid.org/0000-0001-9456-8657
- Description: Women writers of the South Asian diaspora have, in recent decades, found prominence in the international literary arena. These writers may be new immigrants to their diasporic homes, migrants who divide their lives between far-flung homes (for example, Anita Desai, who lives in India, the United Kingdom [UK] and Germany), or descended from nineteenth-century immigrants, as is the case of South African authors like Farida Karodia and Agnes Sam.
- Full Text: false
- Date Issued: 2008
- Authors: Naidu, Samantha
- Date: 2008
- Language: English
- Type: Article , text
- Identifier: vital:26375 , http://hdl.handle.net/10962/54027 , https://orcid.org/0000-0001-9456-8657
- Description: Women writers of the South Asian diaspora have, in recent decades, found prominence in the international literary arena. These writers may be new immigrants to their diasporic homes, migrants who divide their lives between far-flung homes (for example, Anita Desai, who lives in India, the United Kingdom [UK] and Germany), or descended from nineteenth-century immigrants, as is the case of South African authors like Farida Karodia and Agnes Sam.
- Full Text: false
- Date Issued: 2008
Women’s rights get a dressing down: mini skirt attacks in South Africa
- Authors: Vincent, Louise
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141888 , vital:38013 , DOI: 10.18848/1447-9508/cgp/v06i06/42462
- Description: On Sunday the 17th of February 2008 25-year old Nwabisa Ngcukana was stripped, paraded naked while more than 100 onlookers jeered and laughed, doused in alcohol and sexually assaulted by taxi drivers and hawkers at the Noord Street taxi rank in Johannesburg1 (The Star 2008: 2). She was the fourth woman to be assaulted in this way at the rank on that evening. Three other women were stripped and sexually assaulted at the same taxi rank on the previous day. In each of these cases the fact that the women were wearing mini skirts was cited as the reason for the attack.
- Full Text:
- Date Issued: 2008
- Authors: Vincent, Louise
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141888 , vital:38013 , DOI: 10.18848/1447-9508/cgp/v06i06/42462
- Description: On Sunday the 17th of February 2008 25-year old Nwabisa Ngcukana was stripped, paraded naked while more than 100 onlookers jeered and laughed, doused in alcohol and sexually assaulted by taxi drivers and hawkers at the Noord Street taxi rank in Johannesburg1 (The Star 2008: 2). She was the fourth woman to be assaulted in this way at the rank on that evening. Three other women were stripped and sexually assaulted at the same taxi rank on the previous day. In each of these cases the fact that the women were wearing mini skirts was cited as the reason for the attack.
- Full Text:
- Date Issued: 2008
‘Boys will be boys’: traditional Xhosa male circumcision, HIV and sexual socialisation in contemporary South Africa
- Authors: Vincent, Louise
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141500 , vital:37980 , DOI: 10.1080/13691050701861447
- Description: Ritual male circumcision is among the most secretive and sacred of rites practiced by the Xhosa of South Africa. Recently, the alarming rate of death and injury among initiates has led to the spotlight of media attention and government regulation being focused on traditional circumcision. While many of the physical components of the ritual have been little altered by the centuries, its cultural and social meanings have not remained unchanged. This paper attempts to understand how some of these cultural and social meanings have shifted, particularly with respect to attitudes towards sex and the role that circumcision schools traditionally played in the sexual.
- Full Text:
- Date Issued: 2008
- Authors: Vincent, Louise
- Date: 2008
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141500 , vital:37980 , DOI: 10.1080/13691050701861447
- Description: Ritual male circumcision is among the most secretive and sacred of rites practiced by the Xhosa of South Africa. Recently, the alarming rate of death and injury among initiates has led to the spotlight of media attention and government regulation being focused on traditional circumcision. While many of the physical components of the ritual have been little altered by the centuries, its cultural and social meanings have not remained unchanged. This paper attempts to understand how some of these cultural and social meanings have shifted, particularly with respect to attitudes towards sex and the role that circumcision schools traditionally played in the sexual.
- Full Text:
- Date Issued: 2008
Applications of thermal spray technology for surface protection
- Authors: Gorlach, I A
- Subjects: Metal spraying , Surfaces (Technology)
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/21866 , vital:29795
- Description: With the rapid development of modern industry, the quality of surfaces of structures, products and components is important in terms of many aspects such as efficiency, reliability, appearance, maintenance costs and economy. A local failure on the surface usually causes the entire component to be rejected or it may lead to a failure of a machine or structure. It is estimated that in developed countries, the loss caused by corrosion is up to 2-4% of gross national product [1]. Thus, many countries have made great efforts to improve the surface performance of parts in order to enhance the reliability of mechanical equipment and prolong their service life.
- Full Text: false
- Authors: Gorlach, I A
- Subjects: Metal spraying , Surfaces (Technology)
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/21866 , vital:29795
- Description: With the rapid development of modern industry, the quality of surfaces of structures, products and components is important in terms of many aspects such as efficiency, reliability, appearance, maintenance costs and economy. A local failure on the surface usually causes the entire component to be rejected or it may lead to a failure of a machine or structure. It is estimated that in developed countries, the loss caused by corrosion is up to 2-4% of gross national product [1]. Thus, many countries have made great efforts to improve the surface performance of parts in order to enhance the reliability of mechanical equipment and prolong their service life.
- Full Text: false
Perspectives on leadership
- Authors: Arnolds, Cecil Ashleigh
- Subjects: Leadership , Industrial management , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/21857 , vital:29794
- Description: My fields of study are business management and organizational behaviour (OB). In business management we study how to manage businesses effectively by executing various functions (marketing, finance, human resources management, general and strategic management, purchasing and logistics, public relations management, production and opertaions, information technology management) and management tasks (planning, organising, leading and control) (Bosch, Tait and Venter, 2006).
- Full Text: false
- Authors: Arnolds, Cecil Ashleigh
- Subjects: Leadership , Industrial management , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/21857 , vital:29794
- Description: My fields of study are business management and organizational behaviour (OB). In business management we study how to manage businesses effectively by executing various functions (marketing, finance, human resources management, general and strategic management, purchasing and logistics, public relations management, production and opertaions, information technology management) and management tasks (planning, organising, leading and control) (Bosch, Tait and Venter, 2006).
- Full Text: false
Social cohesion: is it possible in a diverse society?
- Authors: Pauw, H C
- Subjects: Social interaction -- South Africa , South Africa -- Social conditions , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/21914 , vital:29801
- Description: The Faculty of Arts has been requested to drive one of the NMMU research themes, namely "Social cohesion". Being a memeber of the Faculty of Arts and from the School of Governance and Social Sciences I have decided to provide some input regarding this theme. South Africa experienced violent xenophobic attacks on non-South African Africans during May 2008. In a report in The Times (17 June 2008) under the title Mandela calls for 'Social cohesion', former president Nelson Mandela urged the youth of South Africa to work for social cohesion in the country. "The struggle for democracy has never been a matter pursued by one race, class, religious community or gender among South Africans. As future leaders of this country, your challenge is to foster a nation in which all people, irrespective of race, colour, sex, religion or creed, can ascertain a social cohesion fully," (http://www.TheTimes-Mandela calls for 'social cohesion'.htm). My perspective regarding humans is, to paraphrase the late Clyde Kluckhohn, that: Every human is like all other humans, some other humans and no other human.
- Full Text: false
- Authors: Pauw, H C
- Subjects: Social interaction -- South Africa , South Africa -- Social conditions , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/21914 , vital:29801
- Description: The Faculty of Arts has been requested to drive one of the NMMU research themes, namely "Social cohesion". Being a memeber of the Faculty of Arts and from the School of Governance and Social Sciences I have decided to provide some input regarding this theme. South Africa experienced violent xenophobic attacks on non-South African Africans during May 2008. In a report in The Times (17 June 2008) under the title Mandela calls for 'Social cohesion', former president Nelson Mandela urged the youth of South Africa to work for social cohesion in the country. "The struggle for democracy has never been a matter pursued by one race, class, religious community or gender among South Africans. As future leaders of this country, your challenge is to foster a nation in which all people, irrespective of race, colour, sex, religion or creed, can ascertain a social cohesion fully," (http://www.TheTimes-Mandela calls for 'social cohesion'.htm). My perspective regarding humans is, to paraphrase the late Clyde Kluckhohn, that: Every human is like all other humans, some other humans and no other human.
- Full Text: false