The synthesis and photophysical properties of peripherally and non-peripherally substituted ball-type Mg (II) and Zn (II) phthalocyanines
- Canlica, Mevlude, Nyokong, Tebello
- Authors: Canlica, Mevlude , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/248417 , vital:51684 , xlink:href="https://doi.org/10.1039/C0DT00920B"
- Description: Newly synthesized ball-type Zn(II) and Mg(II) phthalocyanines containing four 1,1′-binaphthol substituents at peripheral and non-peripheral positions are presented. The structures of the synthesized compounds were characterized by using elemental analysis, UV-vis, FT-IR, 1H-NMR and mass spectroscopies. The ΦF values were 0.33, 0.08, 0.20 and 0.08 for 6–9, respectively. The ΦT values were 0.56, 0.85, 0.64 and 0.88 for 6–9, respectively. All the complexes showed reasonably large triplet lifetimes with τT values of 710 (6), 170 (7), 1490 (8) and 380 μs (9) in DMSO. These complexes offer potential as photosensitizers in photodynamic therapy.
- Full Text:
- Date Issued: 2011
- Authors: Canlica, Mevlude , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/248417 , vital:51684 , xlink:href="https://doi.org/10.1039/C0DT00920B"
- Description: Newly synthesized ball-type Zn(II) and Mg(II) phthalocyanines containing four 1,1′-binaphthol substituents at peripheral and non-peripheral positions are presented. The structures of the synthesized compounds were characterized by using elemental analysis, UV-vis, FT-IR, 1H-NMR and mass spectroscopies. The ΦF values were 0.33, 0.08, 0.20 and 0.08 for 6–9, respectively. The ΦT values were 0.56, 0.85, 0.64 and 0.88 for 6–9, respectively. All the complexes showed reasonably large triplet lifetimes with τT values of 710 (6), 170 (7), 1490 (8) and 380 μs (9) in DMSO. These complexes offer potential as photosensitizers in photodynamic therapy.
- Full Text:
- Date Issued: 2011
The use of experimental design in the development of an HPLC–ECD method for the analysis of captopril
- Khamanga, Sandile M, Walker, Roderick B
- Authors: Khamanga, Sandile M , Walker, Roderick B
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184056 , vital:44163 , xlink:href="https://doi.org/10.1016/j.talanta.2010.11.025"
- Description: An accurate, sensitive and specific high performance liquid chromatography–electrochemical detection (HPLC–ECD) method that was developed and validated for captopril (CPT) is presented. Separation was achieved using a Phenomenex® Luna 5 μm (C18) column and a mobile phase comprised of phosphate buffer (adjusted to pH 3.0): acetonitrile in a ratio of 70:30 (v/v). Detection was accomplished using a full scan multi channel ESA Coulometric detector in the “oxidative-screen” mode with the upstream electrode (E1) set at +600 mV and the downstream (analytical) electrode (E2) set at +950 mV, while the potential of the guard cell was maintained at +1050 mV. The detector gain was set at 300. Experimental design using central composite design (CCD) was used to facilitate method development. Mobile phase pH, molarity and concentration of acetonitrile (ACN) were considered the critical factors to be studied to establish the retention time of CPT and cyclizine (CYC) that was used as the internal standard. Twenty experiments including centre points were undertaken and a quadratic model was derived for the retention time for CPT using the experimental data. The method was validated for linearity, accuracy, precision, limits of quantitation and detection, as per the ICH guidelines. The system was found to produce sharp and well-resolved peaks for CPT and CYC with retention times of 3.08 and 7.56 min, respectively. Linear regression analysis for the calibration curve showed a good linear relationship with a regression coefficient of 0.978 in the concentration range of 2–70 μg/mL. The linear regression equation was y = 0.0131x + 0.0275. The limits of detection (LOQ) and quantitation (LOD) were found to be 2.27 and 0.6 μg/mL, respectively. The method was used to analyze CPT in tablets. The wide range for linearity, accuracy, sensitivity, short retention time and composition of the mobile phase indicated that this method is better for the quantification of CPT than the pharmacopoeial methods.
- Full Text:
- Date Issued: 2011
- Authors: Khamanga, Sandile M , Walker, Roderick B
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184056 , vital:44163 , xlink:href="https://doi.org/10.1016/j.talanta.2010.11.025"
- Description: An accurate, sensitive and specific high performance liquid chromatography–electrochemical detection (HPLC–ECD) method that was developed and validated for captopril (CPT) is presented. Separation was achieved using a Phenomenex® Luna 5 μm (C18) column and a mobile phase comprised of phosphate buffer (adjusted to pH 3.0): acetonitrile in a ratio of 70:30 (v/v). Detection was accomplished using a full scan multi channel ESA Coulometric detector in the “oxidative-screen” mode with the upstream electrode (E1) set at +600 mV and the downstream (analytical) electrode (E2) set at +950 mV, while the potential of the guard cell was maintained at +1050 mV. The detector gain was set at 300. Experimental design using central composite design (CCD) was used to facilitate method development. Mobile phase pH, molarity and concentration of acetonitrile (ACN) were considered the critical factors to be studied to establish the retention time of CPT and cyclizine (CYC) that was used as the internal standard. Twenty experiments including centre points were undertaken and a quadratic model was derived for the retention time for CPT using the experimental data. The method was validated for linearity, accuracy, precision, limits of quantitation and detection, as per the ICH guidelines. The system was found to produce sharp and well-resolved peaks for CPT and CYC with retention times of 3.08 and 7.56 min, respectively. Linear regression analysis for the calibration curve showed a good linear relationship with a regression coefficient of 0.978 in the concentration range of 2–70 μg/mL. The linear regression equation was y = 0.0131x + 0.0275. The limits of detection (LOQ) and quantitation (LOD) were found to be 2.27 and 0.6 μg/mL, respectively. The method was used to analyze CPT in tablets. The wide range for linearity, accuracy, sensitivity, short retention time and composition of the mobile phase indicated that this method is better for the quantification of CPT than the pharmacopoeial methods.
- Full Text:
- Date Issued: 2011
The ‘refeudalisation’ or the ‘return of the repressed’ of the public sphere?:
- Authors: Garman, Anthea
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159857 , vital:40350 , DOI: 10.1080/02560054.2011.621293
- Description: The prevalent depiction of the heyday of the public sphere and its fall from grace under present-day, publicity-ridden, highly commercialised media, with their individualised address of entertainment, is an inadequate conception of today's complex public spheres. The 18th-century bourgeois public sphere had a number of features – often repressed in practice and in theory – which were bound to have their outcomes and a/effects in the public spaces, practices and vehicles we experience today.
- Full Text:
- Date Issued: 2011
- Authors: Garman, Anthea
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159857 , vital:40350 , DOI: 10.1080/02560054.2011.621293
- Description: The prevalent depiction of the heyday of the public sphere and its fall from grace under present-day, publicity-ridden, highly commercialised media, with their individualised address of entertainment, is an inadequate conception of today's complex public spheres. The 18th-century bourgeois public sphere had a number of features – often repressed in practice and in theory – which were bound to have their outcomes and a/effects in the public spaces, practices and vehicles we experience today.
- Full Text:
- Date Issued: 2011
Theiler’s murine encephalomyelitis virus infection induces a redistribution of heat shock proteins 70 and 90 in BHK-21 cells, and is inhibited by novobiocin and geldanamycin:
- Mutsvunguma, Lorraine Z, Moetlhoa, Boitumelo, Edkins, Adrienne L, Luke, Garry A, Blatch, Gregory L, Knox, Caroline M
- Authors: Mutsvunguma, Lorraine Z , Moetlhoa, Boitumelo , Edkins, Adrienne L , Luke, Garry A , Blatch, Gregory L , Knox, Caroline M
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/165085 , vital:41207 , DOI: 10.1007/s12192-011-0262-x
- Description: Theiler’s murine encephalomyelitis virus (TMEV) is a positive-sense RNA virus belonging to the Cardiovirus genus in the family Picornaviridae. In addition to other host cellular factors and pathways, picornaviruses utilise heat shock proteins (Hsps) to facilitate their propagation in cells. This study investigated the localisation of Hsps 70 and 90 in TMEV-infected BHK-21 cells by indirect immunofluorescence and confocal microscopy. The effect of Hsp90 inhibitors novobiocin (Nov) and geldanamycin (GA) on the development of cytopathic effect (CPE) induced by infection was also examined. Hsp90 staining was uniformly distributed in the cytoplasm of uninfected cells but was found concentrated in the perinuclear region during late infection where it overlapped with the signal for non-structural protein 2C within the viral replication complex.
- Full Text:
- Date Issued: 2011
- Authors: Mutsvunguma, Lorraine Z , Moetlhoa, Boitumelo , Edkins, Adrienne L , Luke, Garry A , Blatch, Gregory L , Knox, Caroline M
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/165085 , vital:41207 , DOI: 10.1007/s12192-011-0262-x
- Description: Theiler’s murine encephalomyelitis virus (TMEV) is a positive-sense RNA virus belonging to the Cardiovirus genus in the family Picornaviridae. In addition to other host cellular factors and pathways, picornaviruses utilise heat shock proteins (Hsps) to facilitate their propagation in cells. This study investigated the localisation of Hsps 70 and 90 in TMEV-infected BHK-21 cells by indirect immunofluorescence and confocal microscopy. The effect of Hsp90 inhibitors novobiocin (Nov) and geldanamycin (GA) on the development of cytopathic effect (CPE) induced by infection was also examined. Hsp90 staining was uniformly distributed in the cytoplasm of uninfected cells but was found concentrated in the perinuclear region during late infection where it overlapped with the signal for non-structural protein 2C within the viral replication complex.
- Full Text:
- Date Issued: 2011
Triggers and barriers to youth entrepreneurship in the Eastern Cape South Africa
- Authors: Chindoga, Lynety
- Date: 2011
- Subjects: Youth development -- South Africa , Entrepreneurship -- South Africa -- Eastern Cape , Young adults -- Employment -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25948 , vital:64636
- Description: To realise the dream of the African Renaissance and a better life for all South Africans, the entrepreneurial energies of all people, including children, should be harnessed to contribute towards economic development, job creation and poverty alleviation. Entrepreneurship creates wealth and results in economic prosperity for a country. However, in South Africa, entrepreneurship still remains a dream yet to be realised. This is supported by the findings of Maas and Herrington (2006), who identified entrepreneurial activity in South Africa to be very weak as evidenced by a low Total Entrepreneurial Activity (TEA) rate. Youths are not engaging in entrepreneurial activity and are making the bulk of the unemployed in South Africa. The primary objective of this study was to investigate the perceived triggers and barriers to youth entrepreneurship in South Africa. Two sets of questionnaires were self- administered to high school students and university students. The respondents which consisted of three hundred and twenty three university students and two hundred and fifty six high school students, were selected using simple random sampling method. Five point Likert scale was used to measure the responses. Descriptive as well as inferential statistics were used to analyse the data. The results indicated that youth entrepreneurial intention is low in South Africa. The results also indicated that students perceived mainly extrinsic rewards, market opportunities as well as intrinsic rewards as the three top triggers towards entrepreneurial intention. Independence/autonomy and capital were also regarded as triggers to entrepreneurial intentions. The barriers to youth entrepreneurship included lack of capital, skill and support as well as lack of market opportunities and risk. The study recommends that in order to encourage youth entrepreneurial intentions, government and all stakeholders should ensure that all the perceived triggers are made available. In addition, the barriers to youth entrepreneurship should be minimised. , Thesis (MCom) -- Faculty of Management and Commerce, 2011
- Full Text:
- Date Issued: 2011
- Authors: Chindoga, Lynety
- Date: 2011
- Subjects: Youth development -- South Africa , Entrepreneurship -- South Africa -- Eastern Cape , Young adults -- Employment -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25948 , vital:64636
- Description: To realise the dream of the African Renaissance and a better life for all South Africans, the entrepreneurial energies of all people, including children, should be harnessed to contribute towards economic development, job creation and poverty alleviation. Entrepreneurship creates wealth and results in economic prosperity for a country. However, in South Africa, entrepreneurship still remains a dream yet to be realised. This is supported by the findings of Maas and Herrington (2006), who identified entrepreneurial activity in South Africa to be very weak as evidenced by a low Total Entrepreneurial Activity (TEA) rate. Youths are not engaging in entrepreneurial activity and are making the bulk of the unemployed in South Africa. The primary objective of this study was to investigate the perceived triggers and barriers to youth entrepreneurship in South Africa. Two sets of questionnaires were self- administered to high school students and university students. The respondents which consisted of three hundred and twenty three university students and two hundred and fifty six high school students, were selected using simple random sampling method. Five point Likert scale was used to measure the responses. Descriptive as well as inferential statistics were used to analyse the data. The results indicated that youth entrepreneurial intention is low in South Africa. The results also indicated that students perceived mainly extrinsic rewards, market opportunities as well as intrinsic rewards as the three top triggers towards entrepreneurial intention. Independence/autonomy and capital were also regarded as triggers to entrepreneurial intentions. The barriers to youth entrepreneurship included lack of capital, skill and support as well as lack of market opportunities and risk. The study recommends that in order to encourage youth entrepreneurial intentions, government and all stakeholders should ensure that all the perceived triggers are made available. In addition, the barriers to youth entrepreneurship should be minimised. , Thesis (MCom) -- Faculty of Management and Commerce, 2011
- Full Text:
- Date Issued: 2011
Unitarity constraints on the ratio of shear viscosity to entropy density in higher derivative gravity
- Authors: Brustein, R , Medved, A J M
- Date: 2011
- Language: English
- Type: text , Article
- Identifier: vital:6815 , http://hdl.handle.net/10962/d1004325
- Description: We discuss corrections to the ratio of shear viscosity to entropy density η/s in higher-derivative gravity theories. Generically, these theories contain ghost modes with Planck-scale masses. Motivated by general considerations about unitarity, we propose new boundary conditions for the equations of motion of the graviton perturbations that force the amplitude of the ghosts modes to vanish. We analyze explicitly four-derivative perturbative corrections to Einstein gravity which generically lead to four-derivative equations of motion, compare our choice of boundary conditions to previous proposals and show that, with our new prescription, the ratio η/s remains at the Einstein-gravity value of 1/4π to leading order in the corrections. It is argued that, when the new boundary conditions are imposed on six and higher-derivative equations of motion, η/s can only increase from the Einstein-gravity value. We also recall some general arguments that support the validity of our results to all orders in the strength of the corrections to Einstein gravity. We then discuss the particular case of Gauss-Bonnet gravity, for which the equations of motion are only of two-derivative order and the value of η/s can decrease below 1/4π when treated in a nonperturbative way. Our findings provide further evidence for the validity of the KSS bound for theories that can be viewed as perturbative corrections to Einstein gravity.
- Full Text:
- Date Issued: 2011
- Authors: Brustein, R , Medved, A J M
- Date: 2011
- Language: English
- Type: text , Article
- Identifier: vital:6815 , http://hdl.handle.net/10962/d1004325
- Description: We discuss corrections to the ratio of shear viscosity to entropy density η/s in higher-derivative gravity theories. Generically, these theories contain ghost modes with Planck-scale masses. Motivated by general considerations about unitarity, we propose new boundary conditions for the equations of motion of the graviton perturbations that force the amplitude of the ghosts modes to vanish. We analyze explicitly four-derivative perturbative corrections to Einstein gravity which generically lead to four-derivative equations of motion, compare our choice of boundary conditions to previous proposals and show that, with our new prescription, the ratio η/s remains at the Einstein-gravity value of 1/4π to leading order in the corrections. It is argued that, when the new boundary conditions are imposed on six and higher-derivative equations of motion, η/s can only increase from the Einstein-gravity value. We also recall some general arguments that support the validity of our results to all orders in the strength of the corrections to Einstein gravity. We then discuss the particular case of Gauss-Bonnet gravity, for which the equations of motion are only of two-derivative order and the value of η/s can decrease below 1/4π when treated in a nonperturbative way. Our findings provide further evidence for the validity of the KSS bound for theories that can be viewed as perturbative corrections to Einstein gravity.
- Full Text:
- Date Issued: 2011
Use and users of municipal commonage around three small towns in the Eastern Cape, South Africa
- Davenport, Nicholas A, Shackleton, Charlie M, Gambiza, James
- Authors: Davenport, Nicholas A , Shackleton, Charlie M , Gambiza, James
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181116 , vital:43700 , xlink:href="https://doi.org/10.1016/j.jenvman.2010.11.003"
- Description: Municipal commonages surround many small towns throughout South Africa, and are an integral component of the national land reform programme. But little is known about their extent, use or value, and most appear to have limited or no management or investment. This paper reports on a survey of randomly selected households in three small towns in the Eastern Cape to ascertain the extent and purpose of use of municipal commonages. Between 27% and 70% of urban households used commonage depending on site. Key resources used were fuelwood, medicinal plants, and grazing of livestock. Typically, commonage using households were poorer and less educated than other urban residents, although the profile of users is unique for each town. Given the extensive use of commonage resources, and their contribution to the livelihoods of the poor, local municipalities need to develop and implement sound management strategies that account for all users of commonages, rather than the oft encountered focus on livestock owners and production.
- Full Text:
- Date Issued: 2011
- Authors: Davenport, Nicholas A , Shackleton, Charlie M , Gambiza, James
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181116 , vital:43700 , xlink:href="https://doi.org/10.1016/j.jenvman.2010.11.003"
- Description: Municipal commonages surround many small towns throughout South Africa, and are an integral component of the national land reform programme. But little is known about their extent, use or value, and most appear to have limited or no management or investment. This paper reports on a survey of randomly selected households in three small towns in the Eastern Cape to ascertain the extent and purpose of use of municipal commonages. Between 27% and 70% of urban households used commonage depending on site. Key resources used were fuelwood, medicinal plants, and grazing of livestock. Typically, commonage using households were poorer and less educated than other urban residents, although the profile of users is unique for each town. Given the extensive use of commonage resources, and their contribution to the livelihoods of the poor, local municipalities need to develop and implement sound management strategies that account for all users of commonages, rather than the oft encountered focus on livestock owners and production.
- Full Text:
- Date Issued: 2011
VC’s tapestry unveiling address
- Authors: Badat, Saleem
- Date: 2011
- Language: English
- Type: text
- Identifier: vital:7589 , http://hdl.handle.net/10962/d1006580
- Description: From introduction: This afternoon we publicly launch an exquisite tapestry commissioned from the Keiskamma Arts Project based in Hamburg on the coast. It is intended to express the social purposes that are the rationale for our existence; the geography and environment of Rhodes University; the economic, political, historical and social forces that have shaped it over 107 years and the complexity, antinomies, paradoxes and ambiguities of Rhodes’ history. It is also intended to express our origins, where we have come from the road we have travelled and where we are today; the continuities and discontinuities that characterise Rhodes; the inexcusable and shameful actions of our past in which we can take no pride, as well as the courageous actions, successes and achievements in which we can take pride, and that we can and must celebrate. The launch of the tapestry is an important moment in our continuing journey as Rhodes University of critical reflection, ‘critical appreciation of where we come from,’ and ‘dialogical and analytic engagement with where we are now’ and where we seek to be in future. I have indicated that the launch of the tapestry is a moment in our continuing journey – a journey of the remaking, renewal, modernisation, transformation and further development of Rhodes University.
- Full Text:
- Date Issued: 2011
- Authors: Badat, Saleem
- Date: 2011
- Language: English
- Type: text
- Identifier: vital:7589 , http://hdl.handle.net/10962/d1006580
- Description: From introduction: This afternoon we publicly launch an exquisite tapestry commissioned from the Keiskamma Arts Project based in Hamburg on the coast. It is intended to express the social purposes that are the rationale for our existence; the geography and environment of Rhodes University; the economic, political, historical and social forces that have shaped it over 107 years and the complexity, antinomies, paradoxes and ambiguities of Rhodes’ history. It is also intended to express our origins, where we have come from the road we have travelled and where we are today; the continuities and discontinuities that characterise Rhodes; the inexcusable and shameful actions of our past in which we can take no pride, as well as the courageous actions, successes and achievements in which we can take pride, and that we can and must celebrate. The launch of the tapestry is an important moment in our continuing journey as Rhodes University of critical reflection, ‘critical appreciation of where we come from,’ and ‘dialogical and analytic engagement with where we are now’ and where we seek to be in future. I have indicated that the launch of the tapestry is a moment in our continuing journey – a journey of the remaking, renewal, modernisation, transformation and further development of Rhodes University.
- Full Text:
- Date Issued: 2011
Vice-Chancellor's welcoming address 2011
- Authors: Badat, Saleem
- Date: 2011
- Language: English
- Type: text
- Identifier: vital:7591 , http://hdl.handle.net/10962/d1006582
- Description: From introduction: The Purposes of a University. So permit me to spend a few minutes on the meaning of a university and the three purposes. Rhodes University exists to serve. The first purpose is to produce knowledge, so that we can advance understanding of our natural and social worlds and enrich our scientific and cultural heritage. This means that we ‘test the inherited knowledge of earlier generations’, we dismantle the mumbo jumbo that masquerades for knowledge, we ‘reinvigorate’ knowledge, and we share our findings with others. As a university, our second purpose is to disseminate knowledge and to develop your minds. Our goal is to ensure that you can think imaginatively, ‘effectively and critically’; that you ‘achieve depth in some field of knowledge’; that you can critique ideas and views and construct alternatives, and that you can communicate cogently, orally and in writing. Our final purpose as a university is to undertake community engagement, whether this is as part of academic courses or your voluntary participation in community projects organized by our Community Engagement Office.
- Full Text:
- Date Issued: 2011
- Authors: Badat, Saleem
- Date: 2011
- Language: English
- Type: text
- Identifier: vital:7591 , http://hdl.handle.net/10962/d1006582
- Description: From introduction: The Purposes of a University. So permit me to spend a few minutes on the meaning of a university and the three purposes. Rhodes University exists to serve. The first purpose is to produce knowledge, so that we can advance understanding of our natural and social worlds and enrich our scientific and cultural heritage. This means that we ‘test the inherited knowledge of earlier generations’, we dismantle the mumbo jumbo that masquerades for knowledge, we ‘reinvigorate’ knowledge, and we share our findings with others. As a university, our second purpose is to disseminate knowledge and to develop your minds. Our goal is to ensure that you can think imaginatively, ‘effectively and critically’; that you ‘achieve depth in some field of knowledge’; that you can critique ideas and views and construct alternatives, and that you can communicate cogently, orally and in writing. Our final purpose as a university is to undertake community engagement, whether this is as part of academic courses or your voluntary participation in community projects organized by our Community Engagement Office.
- Full Text:
- Date Issued: 2011
Violence, postcolonial fiction, and the limits of sympathy:
- Authors: Marais, Mike
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143993 , vital:38301 , DOI: 10.1353/sdn.2011.0034
- Description: In this article, I consider the implications for fiction of Slavo Zizek’s argument that the violence of individual subjects is informed by ‘symbolic violence’ (1-2), that is, the distortions concomitant on languages’s constitutive, rather than merely referential, relation to the world.
- Full Text:
- Date Issued: 2011
- Authors: Marais, Mike
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143993 , vital:38301 , DOI: 10.1353/sdn.2011.0034
- Description: In this article, I consider the implications for fiction of Slavo Zizek’s argument that the violence of individual subjects is informed by ‘symbolic violence’ (1-2), that is, the distortions concomitant on languages’s constitutive, rather than merely referential, relation to the world.
- Full Text:
- Date Issued: 2011
Voltammetry and electrochemical impedance spectroscopy of gold electrodes modified with CdTe quantum dots and their conjugates with nickel tetraamino phthalocyanine
- Khene, Samson, Moeno, Sharon, Nyokong, Tebello
- Authors: Khene, Samson , Moeno, Sharon , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/247187 , vital:51554 , xlink:href="https://doi.org/10.1016/j.poly.2011.06.002"
- Description: This work reports on the synthesis of conjugates of cadmium telluride quantum dots (CdTe-QDs) caped with thioglycolic acid and peripherally substituted nickel tetraamino phthalocyanine (NiTAPc) complex. The conjugates are characterized using cyclic (CV) and differential pulse (DPV) voltammetries, electrochemical impedance spectroscopy, X-ray powder diffraction, infrared spectroscopy, Raman spectroscopy, atomic force microscopy and time correlated single photon counting. CV and DPV show that NiTAPc stabilizes the CdTe QDs against oxidation to metallic products.
- Full Text:
- Date Issued: 2011
- Authors: Khene, Samson , Moeno, Sharon , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/247187 , vital:51554 , xlink:href="https://doi.org/10.1016/j.poly.2011.06.002"
- Description: This work reports on the synthesis of conjugates of cadmium telluride quantum dots (CdTe-QDs) caped with thioglycolic acid and peripherally substituted nickel tetraamino phthalocyanine (NiTAPc) complex. The conjugates are characterized using cyclic (CV) and differential pulse (DPV) voltammetries, electrochemical impedance spectroscopy, X-ray powder diffraction, infrared spectroscopy, Raman spectroscopy, atomic force microscopy and time correlated single photon counting. CV and DPV show that NiTAPc stabilizes the CdTe QDs against oxidation to metallic products.
- Full Text:
- Date Issued: 2011
Water chemistry and effect of evapotranspiration on chemical sedimentation on the Mkuze River floodplain, South Africa:
- Humphries, M S, Kindness, A, Ellery, William F N, Hughes, J C
- Authors: Humphries, M S , Kindness, A , Ellery, William F N , Hughes, J C
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144376 , vital:38340 , https://doi.org/10.1016/j.jaridenv.2011.01.013
- Description: The Mkuze Wetland System, forming part of the iSimangaliso World Heritage Site, is South Africa’s largest freshwater wetland area and is known to act as a sink for naturally occurring solutes within the landscape. The chemistry of groundwater and porewater samples, collected from two transects on the Mkuze River floodplain, was investigated to identify processes involved in the control of solute concentrations. Results show that solutes in the groundwater become increasingly concentrated under the influence of evapotranspiration, resulting in the saturation, precipitation, and accumulation of less soluble compounds.
- Full Text:
- Date Issued: 2011
- Authors: Humphries, M S , Kindness, A , Ellery, William F N , Hughes, J C
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144376 , vital:38340 , https://doi.org/10.1016/j.jaridenv.2011.01.013
- Description: The Mkuze Wetland System, forming part of the iSimangaliso World Heritage Site, is South Africa’s largest freshwater wetland area and is known to act as a sink for naturally occurring solutes within the landscape. The chemistry of groundwater and porewater samples, collected from two transects on the Mkuze River floodplain, was investigated to identify processes involved in the control of solute concentrations. Results show that solutes in the groundwater become increasingly concentrated under the influence of evapotranspiration, resulting in the saturation, precipitation, and accumulation of less soluble compounds.
- Full Text:
- Date Issued: 2011
Water-soluble quaternized mercaptopyridine-substituted zinc-phthalocyanines
- Durmuş, Mahmut, Yaman, Hanif, Göl, Cem, Ahsen, Vefa, Nyokong, Tebello
- Authors: Durmuş, Mahmut , Yaman, Hanif , Göl, Cem , Ahsen, Vefa , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/247133 , vital:51549 , xlink:href="https://doi.org/10.1016/j.dyepig.2011.02.007"
- Description: The synthesis and characterization of the new zinc phthalocyanine derivatives, tetra- (non-peripheral, 5) and octa-(peripheral, 6) substituted with 2-mercaptopyridine and their respective quaternized derivatives (8 and 9) are reported. Photochemical and photophysical properties of the new complexes are compared with those of the previously reported peripherally tetra-substituted complexes 7 and 10. The quaternized compounds exhibit excellent solubility in water, making them potential photosensitizers for use in photodynamic therapy (PDT) of cancer. Spectroscopic, aggregation, photophysical and photochemical properties of these complexes are also investigated and compared. Photophysical (fluorescence quantum yields and lifetimes) and photochemical (singlet oxygen and photodegradation quantum yield) properties of these phthalocyanine photosensitizers are very important for the assessment of these complexes as PDT agents. In this study, the effects of the position of the substituents and quaternization of the substituents on the photophysical and photochemical parameters of the zinc phthalocyanines are also reported. This study also showed that the water-soluble quaternized zinc phthalocyanines strongly bind to blood plasma proteins such as bovine serum albumin (BSA).
- Full Text:
- Date Issued: 2011
- Authors: Durmuş, Mahmut , Yaman, Hanif , Göl, Cem , Ahsen, Vefa , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/247133 , vital:51549 , xlink:href="https://doi.org/10.1016/j.dyepig.2011.02.007"
- Description: The synthesis and characterization of the new zinc phthalocyanine derivatives, tetra- (non-peripheral, 5) and octa-(peripheral, 6) substituted with 2-mercaptopyridine and their respective quaternized derivatives (8 and 9) are reported. Photochemical and photophysical properties of the new complexes are compared with those of the previously reported peripherally tetra-substituted complexes 7 and 10. The quaternized compounds exhibit excellent solubility in water, making them potential photosensitizers for use in photodynamic therapy (PDT) of cancer. Spectroscopic, aggregation, photophysical and photochemical properties of these complexes are also investigated and compared. Photophysical (fluorescence quantum yields and lifetimes) and photochemical (singlet oxygen and photodegradation quantum yield) properties of these phthalocyanine photosensitizers are very important for the assessment of these complexes as PDT agents. In this study, the effects of the position of the substituents and quaternization of the substituents on the photophysical and photochemical parameters of the zinc phthalocyanines are also reported. This study also showed that the water-soluble quaternized zinc phthalocyanines strongly bind to blood plasma proteins such as bovine serum albumin (BSA).
- Full Text:
- Date Issued: 2011
Well-nourished women in a Solomon Islands society with a biased sex ratio
- Furusawa, Takuro, Shankar, Aswani
- Authors: Furusawa, Takuro , Shankar, Aswani
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/422173 , vital:71917
- Description: This study reports on the growth and nutritional status of females in Roviana (population 12 235), Solomon Islands, where there are fewer surviving females than males in all age groups (male/female= 1.10; Solomon Islands Government 2000). Anthropometric measurements were performed for 1243 voluntary participants from seven villages. The results showed that females were better nourished than males; weight-forage z-scores, for instance, were better for females than those for males throughout all age groups, with statistical significance in the following age groups: younger than 5 years, 10–14 years and 15–19 years. The same pattern was also observed for adults. Results suggest that gender inequality might not be caused by social discrimination.
- Full Text:
- Date Issued: 2011
- Authors: Furusawa, Takuro , Shankar, Aswani
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/422173 , vital:71917
- Description: This study reports on the growth and nutritional status of females in Roviana (population 12 235), Solomon Islands, where there are fewer surviving females than males in all age groups (male/female= 1.10; Solomon Islands Government 2000). Anthropometric measurements were performed for 1243 voluntary participants from seven villages. The results showed that females were better nourished than males; weight-forage z-scores, for instance, were better for females than those for males throughout all age groups, with statistical significance in the following age groups: younger than 5 years, 10–14 years and 15–19 years. The same pattern was also observed for adults. Results suggest that gender inequality might not be caused by social discrimination.
- Full Text:
- Date Issued: 2011
When breast is not best: young women and breast reduction surgery
- Lamb, Tessa, Vincent, Louise
- Authors: Lamb, Tessa , Vincent, Louise
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141832 , vital:38008 , DOI: 10.1080/10130950.2011.610978
- Description: Most cosmetic surgery patients in South Africa are younger than 21, and in this focus we examine narrative accounts from young South African women who have chosen to undergo cosmetic breast reduction surgery. Feminist debates on cosmetic surgery have focused on the question of whether to regard women who modify their bodies in this way as active agents engaged in liberatory ‘body projects’, or whether such projects are evidence of their subjection to oppressive stereotypes and beauty norms. The latter perspective is challenged here by the participants’ characterisation of breast reduction surgery as profoundly ‘freeing’. The article deals in particular with the conscious choice of participants to knowingly risk not being able to breastfeed children in future in order to achieve a body type which conforms to their understanding of youthful beauty and sexuality.
- Full Text:
- Date Issued: 2011
- Authors: Lamb, Tessa , Vincent, Louise
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141832 , vital:38008 , DOI: 10.1080/10130950.2011.610978
- Description: Most cosmetic surgery patients in South Africa are younger than 21, and in this focus we examine narrative accounts from young South African women who have chosen to undergo cosmetic breast reduction surgery. Feminist debates on cosmetic surgery have focused on the question of whether to regard women who modify their bodies in this way as active agents engaged in liberatory ‘body projects’, or whether such projects are evidence of their subjection to oppressive stereotypes and beauty norms. The latter perspective is challenged here by the participants’ characterisation of breast reduction surgery as profoundly ‘freeing’. The article deals in particular with the conscious choice of participants to knowingly risk not being able to breastfeed children in future in order to achieve a body type which conforms to their understanding of youthful beauty and sexuality.
- Full Text:
- Date Issued: 2011
Work-family conflict, stress and some demographic and occupational variables among female factory workers in East London, South Africa
- Authors: Dywili, Mtutuzeli
- Date: 2011
- Subjects: Work and family -- South Africa , Job stress -- South Africa , Women employees -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24128 , vital:62382
- Description: The study examines work-family conflict, stress, and some demographic and occupational variables among female factory workers in East London, South Africa. The participants were female factory workers in East London, South Africa. The independent variables for the study were, demographic and occupational variables, while stress is the dependent variable. Work-family conflict is dependent on demographic and occupational variables, while on the other hand is independent to stress. The demographic variables concerned are age, marital status, number of children and age of the last born child. The occupational variable on the other hand is occupational level, i.e. managerial versus non-managerial. The measuring instruments were a self-designed questionnaire to measure the demographic and occupational variables, a questionnaire developed by Stephens and Sommer (1996) to measure work-family conflict (cronbach’s alpha = 0,90) and the Effort – Reward Imbalance (ERI) questionnaire (Pikhart, Bobak, Siegrist, Pajak, Rywick, Kyshegyi, Gostaus, Skodova& Marmot, 1996) to measure stress at workplace. Cronbach’s alpha for the whole questionnaire reaches the value of 0,89. , Thesis (MCom) -- Faculty of Management and Commerce, 2011
- Full Text:
- Date Issued: 2011
- Authors: Dywili, Mtutuzeli
- Date: 2011
- Subjects: Work and family -- South Africa , Job stress -- South Africa , Women employees -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24128 , vital:62382
- Description: The study examines work-family conflict, stress, and some demographic and occupational variables among female factory workers in East London, South Africa. The participants were female factory workers in East London, South Africa. The independent variables for the study were, demographic and occupational variables, while stress is the dependent variable. Work-family conflict is dependent on demographic and occupational variables, while on the other hand is independent to stress. The demographic variables concerned are age, marital status, number of children and age of the last born child. The occupational variable on the other hand is occupational level, i.e. managerial versus non-managerial. The measuring instruments were a self-designed questionnaire to measure the demographic and occupational variables, a questionnaire developed by Stephens and Sommer (1996) to measure work-family conflict (cronbach’s alpha = 0,90) and the Effort – Reward Imbalance (ERI) questionnaire (Pikhart, Bobak, Siegrist, Pajak, Rywick, Kyshegyi, Gostaus, Skodova& Marmot, 1996) to measure stress at workplace. Cronbach’s alpha for the whole questionnaire reaches the value of 0,89. , Thesis (MCom) -- Faculty of Management and Commerce, 2011
- Full Text:
- Date Issued: 2011
Zimbabwe's Land Reform: myths and realities
- Authors: Helliker, Kirk D
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144710 , vital:38372 , DOI: 10.1080/02589001.2011.581502
- Description: Zimbabwe’s land reform is the first book on contemporary Zimbabwe that offers an empirically-rich and detailed account of redistributed farms that arose from ‘fasttrack’ land reform 10 years ago. In order to fully appreciate the significance of this book, it is necessary to outline briefly recent intellectual debates on Zimbabwe. Two main positions exist on Zimbabwean politics and society. The first position argues that the radical restructuring of agrarian relations (including undermining white agricultural capital and breaking up large commercial farms into smaller units) is a progressive tendency that has opened up opportunities for black small-scale farmers. Simultaneously, this position often underplays the existence of state restructuring of an authoritarian kind. The second position argues that land redistribution has dramatically undercut agricultural production thereby severely compromising food security for all Zimbabweans. It brings to the fore violent state action in instigating land occupations and in thwarting political opposition to ‘fast-track’.
- Full Text:
- Date Issued: 2011
- Authors: Helliker, Kirk D
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144710 , vital:38372 , DOI: 10.1080/02589001.2011.581502
- Description: Zimbabwe’s land reform is the first book on contemporary Zimbabwe that offers an empirically-rich and detailed account of redistributed farms that arose from ‘fasttrack’ land reform 10 years ago. In order to fully appreciate the significance of this book, it is necessary to outline briefly recent intellectual debates on Zimbabwe. Two main positions exist on Zimbabwean politics and society. The first position argues that the radical restructuring of agrarian relations (including undermining white agricultural capital and breaking up large commercial farms into smaller units) is a progressive tendency that has opened up opportunities for black small-scale farmers. Simultaneously, this position often underplays the existence of state restructuring of an authoritarian kind. The second position argues that land redistribution has dramatically undercut agricultural production thereby severely compromising food security for all Zimbabweans. It brings to the fore violent state action in instigating land occupations and in thwarting political opposition to ‘fast-track’.
- Full Text:
- Date Issued: 2011
Innovation through education: rediscovering the lost generation
- Authors: Pieterse, Koot
- Subjects: Business incubators , Entrepreneurship , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/20889 , vital:29411
- Description: Innovation implies the generation as well as the practical implementation of new ideas. These ideas could appear as new product opportunities, new markets or new management systems and business schools are ideally situated to promote their exploitation and implementation. This study emphasises the need for business schools to elevate innovation to one of the core values in their mission. The need for innovation in the local business environment is explored along with reasons why these opportunities have not always been pursued with the required vigour. The results of a literature study are represented, that demonstrate what initiatives on the incorporation of innovation into their activities have been taken by a selection of business schools around the world and the study is concluded by exploring similar opportunities open to the Business School of the Nelson Mandela Metropolitan University.
- Full Text:
- Authors: Pieterse, Koot
- Subjects: Business incubators , Entrepreneurship , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/20889 , vital:29411
- Description: Innovation implies the generation as well as the practical implementation of new ideas. These ideas could appear as new product opportunities, new markets or new management systems and business schools are ideally situated to promote their exploitation and implementation. This study emphasises the need for business schools to elevate innovation to one of the core values in their mission. The need for innovation in the local business environment is explored along with reasons why these opportunities have not always been pursued with the required vigour. The results of a literature study are represented, that demonstrate what initiatives on the incorporation of innovation into their activities have been taken by a selection of business schools around the world and the study is concluded by exploring similar opportunities open to the Business School of the Nelson Mandela Metropolitan University.
- Full Text:
Relationship marketing in retail banks: superannuated concept?
- Authors: Tait, Madele
- Subjects: Relationship marketing , Banks and banking , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/20923 , vital:29418
- Description: All business is based on relationships. The firm only has to make them meaningful for its customers – provided that the customers want this (Grönroos 1994). Relationship marketing concerns the facilitation and managing of the relationships between the business and its customers and was developed as a response to the realisation that businesses were spending vast resources in time and money to attract new customers but very little on retaining existing ones. Relationship marketing is particularly relevant when a customer has alternative service providers to choose from, when the customer makes the selection decision and when there is an ongoing desire or need for a product or service, such as in the banking industry (Morgan & Hunt 1999).
- Full Text:
- Authors: Tait, Madele
- Subjects: Relationship marketing , Banks and banking , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/20923 , vital:29418
- Description: All business is based on relationships. The firm only has to make them meaningful for its customers – provided that the customers want this (Grönroos 1994). Relationship marketing concerns the facilitation and managing of the relationships between the business and its customers and was developed as a response to the realisation that businesses were spending vast resources in time and money to attract new customers but very little on retaining existing ones. Relationship marketing is particularly relevant when a customer has alternative service providers to choose from, when the customer makes the selection decision and when there is an ongoing desire or need for a product or service, such as in the banking industry (Morgan & Hunt 1999).
- Full Text:
The reward preference/motivation paradox and implications for performance and education
- Authors: Snelgar, Robin
- Subjects: Employee motivation , Incentive (Psychology) , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/21897 , vital:29799
- Description: The focus on reward preference has emerged essentially as a result of the need to identify what really motivates productive behaviour within the workplace, despite the fact that other variables such as retention and attraction have also been taken into consideratin. Motivation has always been an issue of great interest to both reserachers as well as practitioners within the organizational setting, the intention being to find ways to improve performance and, more specifically, particular types of performance within the world of work. Ultimately, the issue has always been how to understand, predict, shape and control human behaviour.
- Full Text: false
- Authors: Snelgar, Robin
- Subjects: Employee motivation , Incentive (Psychology) , f-sa
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/10948/21897 , vital:29799
- Description: The focus on reward preference has emerged essentially as a result of the need to identify what really motivates productive behaviour within the workplace, despite the fact that other variables such as retention and attraction have also been taken into consideratin. Motivation has always been an issue of great interest to both reserachers as well as practitioners within the organizational setting, the intention being to find ways to improve performance and, more specifically, particular types of performance within the world of work. Ultimately, the issue has always been how to understand, predict, shape and control human behaviour.
- Full Text: false