Modelling payment systems for environmental services in the Mt Elgon ecosystem of Kenya
- Authors: Kisaka, Lily
- Date: 2014
- Subjects: Ecological disturbances -- Kenya , Freshwater ecology -- Kenya , Water quality biological assessment -- Kenya , Land degradation -- Kenya , Ecosystem health -- Kenya
- Language: English
- Type: Thesis , Doctoral , PhD (Agricultural Economics)
- Identifier: vital:11206 , http://hdl.handle.net/10353/d1013123 , Ecological disturbances -- Kenya , Freshwater ecology -- Kenya , Water quality biological assessment -- Kenya , Land degradation -- Kenya , Ecosystem health -- Kenya
- Description: Unsustainable patterns of consumption by humankind have increased the rate of change in the natural ecosystems and consequently the levels of stress experienced within the environment. Access to sufficient good quality water is essential and a requirement to meet a number of the Millennium Development Goals (MDGs). However, poor land management and untenable agricultural practices have become the main drivers of the declining watershed services. Upstream farmers often have little or no incentives to take these impacts into account in their decision-making process. Therefore, without investment in ensuring proper land management, the trend in watersheds degradation will continue. Payment for Environmental Services (PES) has emerged as an incentive–based tool that is expected to motivate farmers to improve their agricultural practices. PES is set up to facilitate the process whereby the beneficiaries of environmental services pay compensation to providers of environmental services for conserving the ecosystem. This tool has received increasing attention as a means of creating incentive measures for managing the ecosystem, addressing livelihood issues for the rural poor, and providing sustainable financing for protected areas. The Government of Kenya, as part of its efforts to improve water resource management, is considering use of economic incentive. However, there is insufficient information to guide policy making in that direction. Little is known about the farmers’ preferences for management schemes that will affect land use patterns, their willingness to accept compensation and the willingness of potential buyers to pay for the services. This study evaluates the willingness to accept and the willingness to pay for environmental services with a view to assessing the viability of a PES scheme for the Kuywa Watershed in particular, as well as the Mt. Elgon Ecosystem and other areas with similar conditions. The objectives of the study are threefold (i) to examine respondents preferences for management options for the provision of environmental services in the watershed of River Kuywa of Mt. Elgon Ecosystem; (ii) to evaluate households’ willingness to pay (WTP) and willingness to accept (WTA) payment for improved environmental services from the River Kuywa watershed; and (iii) to propose viable PES approaches for the management of the natural resource of the Kuywa watershed and the Mt. Elgon ecosystem in general. Using six land management attributes relevant to the local situation, the study applied the conjoint method to evaluate farmers’ preferences for management options for the provision of environmental service and assess farmers’ willingness to pay and willingness to accept payment for environmental services. To enable assessment of viability, an analysis was done of the institutional and legal framework within which the PES scheme would operate. Data were collected using literature review and document analysis, questionnaires, focus group discussions and key informant interviews. Results indicate that poor water quality was the most acute problem, followed by deforestation. Results from the conjoint models show that the length of commitment period and land size that is 40% or more of the total land holding influence the farmers’ rating of the management scenarios. The study found that a management contract that requires use of 20% of land holding for a period of 5 years, combined with a cash incentive, harvesting partially permitted, administered by a local NGO and requiring contribution of free labour for two days had the highest likelihood of being selected. The conjoint valuation exercise also came up with a WTA by farmers upstream of KSh. 7,080/= per year. The corresponding value downstream was KSh. 43/= per month over and above their regular water bill. In terms of the institutional and regulatory framework, Kenya has a wide range of policies, laws and regulation on water and other natural resources which provide an enabling environment for PES. With the decentralized institutional setup implemented in both the water sector and the agricultural sector, the institutional setting also provides an enabling environment for PES. With a positive WTA and WTP coupled with an enabling legal and institutional environment, the study concludes that PES is a viable environmental management tool for the Kuywa water shed and similar watersheds.
- Full Text:
- Authors: Kisaka, Lily
- Date: 2014
- Subjects: Ecological disturbances -- Kenya , Freshwater ecology -- Kenya , Water quality biological assessment -- Kenya , Land degradation -- Kenya , Ecosystem health -- Kenya
- Language: English
- Type: Thesis , Doctoral , PhD (Agricultural Economics)
- Identifier: vital:11206 , http://hdl.handle.net/10353/d1013123 , Ecological disturbances -- Kenya , Freshwater ecology -- Kenya , Water quality biological assessment -- Kenya , Land degradation -- Kenya , Ecosystem health -- Kenya
- Description: Unsustainable patterns of consumption by humankind have increased the rate of change in the natural ecosystems and consequently the levels of stress experienced within the environment. Access to sufficient good quality water is essential and a requirement to meet a number of the Millennium Development Goals (MDGs). However, poor land management and untenable agricultural practices have become the main drivers of the declining watershed services. Upstream farmers often have little or no incentives to take these impacts into account in their decision-making process. Therefore, without investment in ensuring proper land management, the trend in watersheds degradation will continue. Payment for Environmental Services (PES) has emerged as an incentive–based tool that is expected to motivate farmers to improve their agricultural practices. PES is set up to facilitate the process whereby the beneficiaries of environmental services pay compensation to providers of environmental services for conserving the ecosystem. This tool has received increasing attention as a means of creating incentive measures for managing the ecosystem, addressing livelihood issues for the rural poor, and providing sustainable financing for protected areas. The Government of Kenya, as part of its efforts to improve water resource management, is considering use of economic incentive. However, there is insufficient information to guide policy making in that direction. Little is known about the farmers’ preferences for management schemes that will affect land use patterns, their willingness to accept compensation and the willingness of potential buyers to pay for the services. This study evaluates the willingness to accept and the willingness to pay for environmental services with a view to assessing the viability of a PES scheme for the Kuywa Watershed in particular, as well as the Mt. Elgon Ecosystem and other areas with similar conditions. The objectives of the study are threefold (i) to examine respondents preferences for management options for the provision of environmental services in the watershed of River Kuywa of Mt. Elgon Ecosystem; (ii) to evaluate households’ willingness to pay (WTP) and willingness to accept (WTA) payment for improved environmental services from the River Kuywa watershed; and (iii) to propose viable PES approaches for the management of the natural resource of the Kuywa watershed and the Mt. Elgon ecosystem in general. Using six land management attributes relevant to the local situation, the study applied the conjoint method to evaluate farmers’ preferences for management options for the provision of environmental service and assess farmers’ willingness to pay and willingness to accept payment for environmental services. To enable assessment of viability, an analysis was done of the institutional and legal framework within which the PES scheme would operate. Data were collected using literature review and document analysis, questionnaires, focus group discussions and key informant interviews. Results indicate that poor water quality was the most acute problem, followed by deforestation. Results from the conjoint models show that the length of commitment period and land size that is 40% or more of the total land holding influence the farmers’ rating of the management scenarios. The study found that a management contract that requires use of 20% of land holding for a period of 5 years, combined with a cash incentive, harvesting partially permitted, administered by a local NGO and requiring contribution of free labour for two days had the highest likelihood of being selected. The conjoint valuation exercise also came up with a WTA by farmers upstream of KSh. 7,080/= per year. The corresponding value downstream was KSh. 43/= per month over and above their regular water bill. In terms of the institutional and regulatory framework, Kenya has a wide range of policies, laws and regulation on water and other natural resources which provide an enabling environment for PES. With the decentralized institutional setup implemented in both the water sector and the agricultural sector, the institutional setting also provides an enabling environment for PES. With a positive WTA and WTP coupled with an enabling legal and institutional environment, the study concludes that PES is a viable environmental management tool for the Kuywa water shed and similar watersheds.
- Full Text:
Optimization of the vermidegradation of cow dung – waste paper mixtures
- Authors: Unuofin, Frank Oshioname
- Date: 2014
- Subjects: Biodegradation , Vermicomposting , Waste paper , Earthworm culture , Phosphatic fertilizers
- Language: English
- Type: Thesis , Doctoral , PhD (Soil Science)
- Identifier: vital:11966 , http://hdl.handle.net/10353/d1021276 , Biodegradation , Vermicomposting , Waste paper , Earthworm culture , Phosphatic fertilizers
- Description: Vermicomposting is an eco-friendly waste management strategy. Its successful performance necessitate that key functioning parameters like earthworm stocking density, nutrient enrichment be established for each target waste/waste mixture. One main target waste mixture in South Africa, and in the University of Fort Hare in particular is waste paper mixed with cow dung and rock phosphate (RP) for phosphorus (P) enrichment. This study was carried out to address the following specific objectives, to determine (i) the effect of Eisenia fetida stocking density on the bioconversion of cow dung waste paper mixtures enriched with rock phosphate, (ii) an optimum application rate of low grade South African Rock Phosphate and time required for efficient vermicomposting of cow dung-waste paper mixtures, and (iii) to determine if the phosphorus in RP is responsible for improved biodegradation during the vermicomposting of cow dung-waste paper mixtures. Results of this study revealed that bioconversion of cow dung waste paper mixtures enriched with RP was highly dependent on E. fetida stocking density and time. The stocking density of 12.5 g-worms kg-1 feedstock of the mixtures resulted in highest earthworm growth rate and humification of the waste mixture as reflected by a C: N ratio of < 12, polymerization index (PI) or humic acid/fulvic acid ratio of > 1.9, and a humification index of >13 for the cow dung waste paper mixtures. A germination test carried out also revealed that the resultant vermicompost had no inhibitory effect on the germination of tomato, carrot, and radish. Extractable P increased with stocking density up to 22.5 g-worm kg-1 feedstock, suggesting that for maximum P release from RP enriched wastes, a high stocking density should be considered. Informed by an earlier study which demonstrated that RP improved vermidegration, a follow up study was done to determine the optimum amount of rock phosphate necessary for efficient vermidegradation of cow dung waste paper mixtures while ensuring a phosphorus rich vermicompost. The results showed that addition of RP at rates ≤ 1% P as RP efficiently enhanced the bioconversion of cow dung waste paper mixtures as reflected by low C: N ratio, high polymerization index (PI), HI and HR used as maturity indicators for matured compost. Final vermicompost products obtained at minimum amounts of RP application rates resulted highly humified vermicompost with finer morphological structure, with no inhibitory effect on the germination of tomato, carrot, and radish similar to the ones obtained at higher RP rates. The findings suggest that 1%P as RP application rate is optimum for efficient vermidegradation of cow dung waste paper mixtures. Since P or Ca happen to be the most prevalent elements in most rock phosphate used for compost enrichment, a study was carried out to determine if P or Ca in RP is predominantly responsible for the improved biodegradation of cow-dung waste paper mixture observed during vermicomposting. Phosphorus sources in form of triple superphosphate (TSP), phosphoric acid (PHA) and Ca in form of calcium chloride (CaCl2) salt were compared with rock phosphate. The results from the study indicated that TSP, a water soluble P source, resulted in greater and faster degradation of the waste mixtures than RP while the Ca source had the least effect. With TSP incorporation the compost maturity C: N ratio of 12 was reached within 28 days while RP, PHA and CaCl2 needed 42, 56 and more than 56 days, respectively. The results indicated that P was largely responsible for the enhanced bioconversion of the waste mixtures. This appeared linked to the effect of P to stimulate microbial growth as reflected by higher microbial biomass carbon levels where water soluble P sources were applied. The C: N ratios of the final vermicomposts at day 56 were 10, 11.5, 13, 14, and 23 for TSP, RP,PHA, Control (No P added) and CaCl2 treatments, respectively. Although TSP gave superior superior performance, RP may still be the preferred additive in the vermicomposting of cow dung waste paper mixtures as it is cheaper and produces mature compost in a shorter period of 8 weeks. Generally, the results of this study have shown that the vemidegradation of cow dung waste paper mixtures can be optimized through adoption of an E. fetida stocking density of 12.5g- worm kg-1 and an RP incorporation rate of 1% P as RP. However, higher rates of RPincorporation may be adopted where final vermicomposts with higher P fertilizer value are desired. Phosphorus appears to be the RP constituent responsible for its ability to enhance the vermidegradation of cow dung waste paper mixtures. Future studies should explore the effectiveness of other P-bearing minerals for their effectiveness in enhancing vemidegradation.
- Full Text:
- Authors: Unuofin, Frank Oshioname
- Date: 2014
- Subjects: Biodegradation , Vermicomposting , Waste paper , Earthworm culture , Phosphatic fertilizers
- Language: English
- Type: Thesis , Doctoral , PhD (Soil Science)
- Identifier: vital:11966 , http://hdl.handle.net/10353/d1021276 , Biodegradation , Vermicomposting , Waste paper , Earthworm culture , Phosphatic fertilizers
- Description: Vermicomposting is an eco-friendly waste management strategy. Its successful performance necessitate that key functioning parameters like earthworm stocking density, nutrient enrichment be established for each target waste/waste mixture. One main target waste mixture in South Africa, and in the University of Fort Hare in particular is waste paper mixed with cow dung and rock phosphate (RP) for phosphorus (P) enrichment. This study was carried out to address the following specific objectives, to determine (i) the effect of Eisenia fetida stocking density on the bioconversion of cow dung waste paper mixtures enriched with rock phosphate, (ii) an optimum application rate of low grade South African Rock Phosphate and time required for efficient vermicomposting of cow dung-waste paper mixtures, and (iii) to determine if the phosphorus in RP is responsible for improved biodegradation during the vermicomposting of cow dung-waste paper mixtures. Results of this study revealed that bioconversion of cow dung waste paper mixtures enriched with RP was highly dependent on E. fetida stocking density and time. The stocking density of 12.5 g-worms kg-1 feedstock of the mixtures resulted in highest earthworm growth rate and humification of the waste mixture as reflected by a C: N ratio of < 12, polymerization index (PI) or humic acid/fulvic acid ratio of > 1.9, and a humification index of >13 for the cow dung waste paper mixtures. A germination test carried out also revealed that the resultant vermicompost had no inhibitory effect on the germination of tomato, carrot, and radish. Extractable P increased with stocking density up to 22.5 g-worm kg-1 feedstock, suggesting that for maximum P release from RP enriched wastes, a high stocking density should be considered. Informed by an earlier study which demonstrated that RP improved vermidegration, a follow up study was done to determine the optimum amount of rock phosphate necessary for efficient vermidegradation of cow dung waste paper mixtures while ensuring a phosphorus rich vermicompost. The results showed that addition of RP at rates ≤ 1% P as RP efficiently enhanced the bioconversion of cow dung waste paper mixtures as reflected by low C: N ratio, high polymerization index (PI), HI and HR used as maturity indicators for matured compost. Final vermicompost products obtained at minimum amounts of RP application rates resulted highly humified vermicompost with finer morphological structure, with no inhibitory effect on the germination of tomato, carrot, and radish similar to the ones obtained at higher RP rates. The findings suggest that 1%P as RP application rate is optimum for efficient vermidegradation of cow dung waste paper mixtures. Since P or Ca happen to be the most prevalent elements in most rock phosphate used for compost enrichment, a study was carried out to determine if P or Ca in RP is predominantly responsible for the improved biodegradation of cow-dung waste paper mixture observed during vermicomposting. Phosphorus sources in form of triple superphosphate (TSP), phosphoric acid (PHA) and Ca in form of calcium chloride (CaCl2) salt were compared with rock phosphate. The results from the study indicated that TSP, a water soluble P source, resulted in greater and faster degradation of the waste mixtures than RP while the Ca source had the least effect. With TSP incorporation the compost maturity C: N ratio of 12 was reached within 28 days while RP, PHA and CaCl2 needed 42, 56 and more than 56 days, respectively. The results indicated that P was largely responsible for the enhanced bioconversion of the waste mixtures. This appeared linked to the effect of P to stimulate microbial growth as reflected by higher microbial biomass carbon levels where water soluble P sources were applied. The C: N ratios of the final vermicomposts at day 56 were 10, 11.5, 13, 14, and 23 for TSP, RP,PHA, Control (No P added) and CaCl2 treatments, respectively. Although TSP gave superior superior performance, RP may still be the preferred additive in the vermicomposting of cow dung waste paper mixtures as it is cheaper and produces mature compost in a shorter period of 8 weeks. Generally, the results of this study have shown that the vemidegradation of cow dung waste paper mixtures can be optimized through adoption of an E. fetida stocking density of 12.5g- worm kg-1 and an RP incorporation rate of 1% P as RP. However, higher rates of RPincorporation may be adopted where final vermicomposts with higher P fertilizer value are desired. Phosphorus appears to be the RP constituent responsible for its ability to enhance the vermidegradation of cow dung waste paper mixtures. Future studies should explore the effectiveness of other P-bearing minerals for their effectiveness in enhancing vemidegradation.
- Full Text:
Stakeholders' participation in curriculum development in four secondary schools in Fort Beaufort education district, Eastern cape province: towards a participatory curriculum model
- Authors: Obi, Uloma Nkpurunma
- Date: 2014
- Subjects: Curriculum planning Educational planning -- South Africa -- Eastern Cape Education -- Curricula -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5840 , vital:29401
- Description: The new democratic government came to power in 1994 and one of its major missions was to change the system of education inherited from the apartheid regime by laying a foundation for a single national core syllabus to replace the erstwhile multi-tier system, which discriminated among racial groups. Under the apartheid regime, the curriculum was flawed by ‘racially, offensive and outdated content’ and the government embarked on a bold programme to cleanse it of these elements. The democratic government went about this through curriculum reforms. In 1997, it introduced Curriculum 2005 fondly called “C2005”, with the Outcome-based Education (OBE) principles. Despite the initial overwhelming support for C2005, it soon ran into trouble. In 2000, the Minister appointed a committee that reviewed the curriculum and in 2002, the Revised National Curriculum Statement (RNCS) was born. These curriculum reforms have been met with a lot of criticism and the government felt it was not serving its purpose. Some key stakeholders still felt that their non-involvement, non-participation and the lack of proper consultation in the curriculum process were partly responsible for teachers and subject advisers misinterpreting the curriculum and implementing it from their own perspectives. Subsequently, another review was done and the National Curriculum Statement (NCS) was launched in 2002. But the complaints did not cease, probably due to continuing poor performance at the Matric Examination which continues to feature low pass rates for many provinces, especially the Eastern Cape. Against this backdrop, the government streamlined the NCS curriculum yield, and an amended Curriculum and Assessment Policy Statement (CAPS) emerged. The key issue raised by critics is the lack of sufficient involvement of stakeholders in the curriculum review processes. At the same time, government continues to insist that it has been consulting adequately with all relevant stakeholders. There are iii obviously different interpretations of stakeholder involvement and participation and there is urgent need to reconcile whatever differences of opinion and definition exist, in order to gain common understanding, which is the first step in reaching a solution. For instance, how are the stakeholders involved? More importantly, what is meant by “involvement”? Even if there is no disagreement about the meaning of “involvement”, is the stage in the process at which the stakeholders are involved an important element in whether or not the process is an inclusive and participatory one?.
- Full Text:
- Authors: Obi, Uloma Nkpurunma
- Date: 2014
- Subjects: Curriculum planning Educational planning -- South Africa -- Eastern Cape Education -- Curricula -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5840 , vital:29401
- Description: The new democratic government came to power in 1994 and one of its major missions was to change the system of education inherited from the apartheid regime by laying a foundation for a single national core syllabus to replace the erstwhile multi-tier system, which discriminated among racial groups. Under the apartheid regime, the curriculum was flawed by ‘racially, offensive and outdated content’ and the government embarked on a bold programme to cleanse it of these elements. The democratic government went about this through curriculum reforms. In 1997, it introduced Curriculum 2005 fondly called “C2005”, with the Outcome-based Education (OBE) principles. Despite the initial overwhelming support for C2005, it soon ran into trouble. In 2000, the Minister appointed a committee that reviewed the curriculum and in 2002, the Revised National Curriculum Statement (RNCS) was born. These curriculum reforms have been met with a lot of criticism and the government felt it was not serving its purpose. Some key stakeholders still felt that their non-involvement, non-participation and the lack of proper consultation in the curriculum process were partly responsible for teachers and subject advisers misinterpreting the curriculum and implementing it from their own perspectives. Subsequently, another review was done and the National Curriculum Statement (NCS) was launched in 2002. But the complaints did not cease, probably due to continuing poor performance at the Matric Examination which continues to feature low pass rates for many provinces, especially the Eastern Cape. Against this backdrop, the government streamlined the NCS curriculum yield, and an amended Curriculum and Assessment Policy Statement (CAPS) emerged. The key issue raised by critics is the lack of sufficient involvement of stakeholders in the curriculum review processes. At the same time, government continues to insist that it has been consulting adequately with all relevant stakeholders. There are iii obviously different interpretations of stakeholder involvement and participation and there is urgent need to reconcile whatever differences of opinion and definition exist, in order to gain common understanding, which is the first step in reaching a solution. For instance, how are the stakeholders involved? More importantly, what is meant by “involvement”? Even if there is no disagreement about the meaning of “involvement”, is the stage in the process at which the stakeholders are involved an important element in whether or not the process is an inclusive and participatory one?.
- Full Text:
Structural, optical and electrical characterization of nano-sized c-tio2 quamtum dots synthesized by spray pyrolysis
- Authors: Taziwa, Raymond Tichaona
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11342 , http://hdl.handle.net/10353/d1016089
- Description: In the 21st century, scientific communities face challenges and opportunities concerning future development, where innovations must be a key driver over the past, evolution of African societies were based on incomplete models, only taking into account economical growth and not paying attention to environmental deterioration as a consequence of anthropogenic activity and environmental pollution. We have to learn from our past mistakes in order not to repeat them. Education and research of today as the embryonic stages of the development models of tomorrow should be directed toward a sustainable mentality. In this sense, solar energy technologies have emerged as key instruments for minimizing environmental impact as well as reducing economic cost in the field of renewable energies. Titanium dioxide is a fascinating low cost material exhibiting unique properties of stability and photo catalytic activities, leading to clean technologies in water purification and energy conversion of sunlight. However, conventional techniques (high temperature, high vacuum, high pressures) of processing titanium dioxide are a technological limitation due to excessive energy consumption. This poses a handicap for practical applications in areas such as preparation of hybrid organic/Titanium dioxide materials or devices on thermo flexible substrates such as plastic material. It is for this reason that the investigation presented in this Ph.D thesis deals with the development of spray pyrolysis techniques for preparation of carbon doped titanium dioxide nano powders for solar cell applications. This thesis is therefore structured as follows: Chapter 1 gives a general overview of the work done in this thesis. This work relies greatly on the excellent structural optical and electrical properties of TiO2 thin films, as well as its chemical resistance and insulating properties. A summary of the physical, optical, electrical and chemical properties reported in the literature, with an emphasis on those relevant to solar cell fabrication, is presented in Chapter 2. Chapter 3 gives a concise literature review on models governing droplet formation in ultrasonic spray pyrolysis (USP) techniques, the limitations of these models have been exposed and a new relation model for estimating the final particle size given a set of initial reaction conditions has been proposed. The presently derived model is quite advantageous in that it does not require the investigator to look up values of surface tension and density for every precursor solution. Chapter 4 presents in detail the designed and constructed spray pyrolysis system capable of realizing desired nano structures for photovoltaic applications. The first system employed an ultrasonic atomization spray nozzle in order to create an aerosol of the TiO2 precursor. The reasons for choosing ultrasonic spray deposition (USP) and the TiO2 precursors, titanium iso propoxide and titanium tetra butoxide are discussed. Chapter 5 outlines experimental methodologies used in synthesis and characterization of the materials used in this study. Chapter 5 further provides experimental methodologies used in fabrication of a new type of photo electrochemical solar cells (PECs). Chapter 6 reveals the opto-electrical results of PECs solar cells fabricated. There are numerous properties that are affected by the size but emphasis will be placed on nano-size and confinement effects. Chapter 7 presents a confirmation of the phonon confinement effects in C-TiO2 QDs for the first time. In addition Chapter 7 also presents a new phonon confinement model. Chapter 8 reveals the optical, structural and electronic properties of C-TiO2 QDs synthesized by USP and PSP techniques. In addition the electrical properties of C-TiO2 QDs PEC solar cells devices are reported in Chapter 8. Concluding remarks, with potential future research projects are presented in Chapter 9. Through these 9 chapters, all research questions have been answered satisfactorily and all objectives met. Most of the work contained in this thesis has been subjected to external reviews through publication of these peer reviewed articles.
- Full Text:
- Authors: Taziwa, Raymond Tichaona
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11342 , http://hdl.handle.net/10353/d1016089
- Description: In the 21st century, scientific communities face challenges and opportunities concerning future development, where innovations must be a key driver over the past, evolution of African societies were based on incomplete models, only taking into account economical growth and not paying attention to environmental deterioration as a consequence of anthropogenic activity and environmental pollution. We have to learn from our past mistakes in order not to repeat them. Education and research of today as the embryonic stages of the development models of tomorrow should be directed toward a sustainable mentality. In this sense, solar energy technologies have emerged as key instruments for minimizing environmental impact as well as reducing economic cost in the field of renewable energies. Titanium dioxide is a fascinating low cost material exhibiting unique properties of stability and photo catalytic activities, leading to clean technologies in water purification and energy conversion of sunlight. However, conventional techniques (high temperature, high vacuum, high pressures) of processing titanium dioxide are a technological limitation due to excessive energy consumption. This poses a handicap for practical applications in areas such as preparation of hybrid organic/Titanium dioxide materials or devices on thermo flexible substrates such as plastic material. It is for this reason that the investigation presented in this Ph.D thesis deals with the development of spray pyrolysis techniques for preparation of carbon doped titanium dioxide nano powders for solar cell applications. This thesis is therefore structured as follows: Chapter 1 gives a general overview of the work done in this thesis. This work relies greatly on the excellent structural optical and electrical properties of TiO2 thin films, as well as its chemical resistance and insulating properties. A summary of the physical, optical, electrical and chemical properties reported in the literature, with an emphasis on those relevant to solar cell fabrication, is presented in Chapter 2. Chapter 3 gives a concise literature review on models governing droplet formation in ultrasonic spray pyrolysis (USP) techniques, the limitations of these models have been exposed and a new relation model for estimating the final particle size given a set of initial reaction conditions has been proposed. The presently derived model is quite advantageous in that it does not require the investigator to look up values of surface tension and density for every precursor solution. Chapter 4 presents in detail the designed and constructed spray pyrolysis system capable of realizing desired nano structures for photovoltaic applications. The first system employed an ultrasonic atomization spray nozzle in order to create an aerosol of the TiO2 precursor. The reasons for choosing ultrasonic spray deposition (USP) and the TiO2 precursors, titanium iso propoxide and titanium tetra butoxide are discussed. Chapter 5 outlines experimental methodologies used in synthesis and characterization of the materials used in this study. Chapter 5 further provides experimental methodologies used in fabrication of a new type of photo electrochemical solar cells (PECs). Chapter 6 reveals the opto-electrical results of PECs solar cells fabricated. There are numerous properties that are affected by the size but emphasis will be placed on nano-size and confinement effects. Chapter 7 presents a confirmation of the phonon confinement effects in C-TiO2 QDs for the first time. In addition Chapter 7 also presents a new phonon confinement model. Chapter 8 reveals the optical, structural and electronic properties of C-TiO2 QDs synthesized by USP and PSP techniques. In addition the electrical properties of C-TiO2 QDs PEC solar cells devices are reported in Chapter 8. Concluding remarks, with potential future research projects are presented in Chapter 9. Through these 9 chapters, all research questions have been answered satisfactorily and all objectives met. Most of the work contained in this thesis has been subjected to external reviews through publication of these peer reviewed articles.
- Full Text:
Synthesis, characterization, and biological studies of pyrazolone Schiff bases and their transition metal complexes
- Authors: Idemudia, Omoruyi Gold
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11340 , http://hdl.handle.net/10353/d1016068
- Description: Some new acylpyrazolone Schiff bases have been synthesized from the condensation reaction of two acylpyrazolone diketone precursors with phenylhydrazine, 2,4-dinitrophenylhydrazine and sulfanilamide. They have been fully characterized by elemental analysis and spectroscopic techniques (IR,1H and 13C NMR, and mass-spectra). The single crystal structure of the benzoyl derivative acylpyrazolone Schiff bases have been obtained and analyzed by X-ray crystallography technique. Solid state X-ray diffraction revealed a keto tautomer Schiff base in solid state. Mn(II), Co(II), Ni(II) and Cu(II) complexes with the Schiff bases have been synthesized and characterized by elemental analysis, IR and UV-VIS spectroscopy, magnetic susceptibility measurements, and thermal studies (TGA and DTG). An octahedral geometry around the transition metal ion, consisting of two bidentate Schiff base ligands bonding through the azometine nitrogen and ketonic oxygen have been proposed based on careful interpretation of available analytical and spectroscopic characterization results. Two water molecules as ligands complete the octahedral geometry in all cases. Using the invitro disc diffusion method for screening synthesized compounds against selected gram positive and gram negative bacterial at 40 mg/mL, and the DPPH free radical scavenging methods at 0.50, 0.25 and 0.13 mg/mL, the synthesized Schiff base and metal complexes showed varying biological activities. 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one sul29 fanilamide showed more activity generally, exhibiting a broad spectrum activity against all selected bacterial in some cases. Mn(II), Co(II) and Ni(II) complexes of sulfanilamide Schiff base with the acetylpyrazolone derivative 4-acetyl-3-methyl-1-phenyl-2-pyrazolin-5-one sulfanilamide, exhibited a stronger and very good DPPH radical scavenging activity as good as ascorbic acid on comparing, but not with Cu(II). As such they could be important antitumour candidates.
- Full Text:
- Authors: Idemudia, Omoruyi Gold
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11340 , http://hdl.handle.net/10353/d1016068
- Description: Some new acylpyrazolone Schiff bases have been synthesized from the condensation reaction of two acylpyrazolone diketone precursors with phenylhydrazine, 2,4-dinitrophenylhydrazine and sulfanilamide. They have been fully characterized by elemental analysis and spectroscopic techniques (IR,1H and 13C NMR, and mass-spectra). The single crystal structure of the benzoyl derivative acylpyrazolone Schiff bases have been obtained and analyzed by X-ray crystallography technique. Solid state X-ray diffraction revealed a keto tautomer Schiff base in solid state. Mn(II), Co(II), Ni(II) and Cu(II) complexes with the Schiff bases have been synthesized and characterized by elemental analysis, IR and UV-VIS spectroscopy, magnetic susceptibility measurements, and thermal studies (TGA and DTG). An octahedral geometry around the transition metal ion, consisting of two bidentate Schiff base ligands bonding through the azometine nitrogen and ketonic oxygen have been proposed based on careful interpretation of available analytical and spectroscopic characterization results. Two water molecules as ligands complete the octahedral geometry in all cases. Using the invitro disc diffusion method for screening synthesized compounds against selected gram positive and gram negative bacterial at 40 mg/mL, and the DPPH free radical scavenging methods at 0.50, 0.25 and 0.13 mg/mL, the synthesized Schiff base and metal complexes showed varying biological activities. 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one sul29 fanilamide showed more activity generally, exhibiting a broad spectrum activity against all selected bacterial in some cases. Mn(II), Co(II) and Ni(II) complexes of sulfanilamide Schiff base with the acetylpyrazolone derivative 4-acetyl-3-methyl-1-phenyl-2-pyrazolin-5-one sulfanilamide, exhibited a stronger and very good DPPH radical scavenging activity as good as ascorbic acid on comparing, but not with Cu(II). As such they could be important antitumour candidates.
- Full Text:
Targeting and characterizing potentially high yield aquifers in the neotectonic zones in the Eastern Cape Province in South Africa
- Authors: Madi, Kakaba
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Geology)
- Identifier: vital:11530 , http://hdl.handle.net/10353/d1021270
- Description: The Eastern Cape Province has, besides the three known neotectonic belts (southern, eastern and northern) a fourth zone, which is inactive. This inactive zone is located almost in its central part north of the southern neotectonic zone, and south of the northern neotectonic belt. The three above mentioned neotectonic belts (southern, eastern and northern) were chosen for this study, each one with its own characteristics. This study aims at characterizing and targeting potentially high yield aquifers in the neotectonic zones in the Eastern Cape Province. The methods used in this study include: 1) A comprehensive literature review on neotectonics in South Africa in general and in the Eastern Cape Province in particular; 2) Extraction of lineaments through remote sensing and examination of digital elevation models; 3) Examination of seismic data for the subsurface visualization onshore and offshore; 4) Study on the genesis of the Grahamstown kaolin deposits through the structural component; and 5) Acquisition and interpretation of magnetic, electromagnetic and radiometric data from three of the hot springs in the northern neotectonic belt. The results indicate the following: 1) Old map of seismic epicentres in South Africa need to be reviewed continually. The Eastern Cape was regarded as quiescent in terms of seismicity. However, the investigation from recent seismic epicenters downloadable from the IRIS website has shown that recent seismic events occurred in the Eastern Cape Province especially in the northern and southern neotectonic belts. The central part located north of the southern neotectonic belt and south of the northern neotectonic belt is inactive. This inactive zone can be considered for the storage of nuclear wastes. 2) The eastern neotectonic belt has, like the northern neotectonic belt, a higher density of lineaments oriented northwest-southeast, which makes it the second important neotectonic belt. These lineaments correlate with the normalized difference vegetation index indicative of a good circulation of groundwater. In the south, the Eastern Cape great lineament oriented east-west is now considered a neotectonic domain because many seismic epicentres occur therein. Its geomorphologic shape in graben type form is a favourable structure for groundwater catchment. The surface topography is not uniform and high elevations in the east are related to the uplift that took place in the Quaternary. Most vector gradients are oriented east-west, a fact to be reckon with in the study of surface water flow and aquifers characterization. 3) Offshore along the east coast, the subsurface is affected by neotectonic faults, which are probably splays of the Agulhas Falkland Fractured Zone (AFFZ). The folds that occur are related to the regional compressional stress known as the Wegener Stress Anomaly (WSM). On land, straight lines from seismic profiles indicate that weathering occurs in consolidated materials probably along faults or fractures, unconsolidated sediments always have wavy profiles. On the other hand, field observations in King Williams Town have clearly shown that a tectonic uplift took place on a dolerite sill overlain by mudstones and sandstones. The uplift is possibly related to the Amatole-Swaziland event that occurred in the last five millions years. The escarpment along this dolerite sill overlain by sedimentary rocks is a meso-scale fault with a dip-slip component. Healthy vegetation and a river flowing parallel to the cliff indicate groundwater flow in the zone of weakness. 4) In the southern neotectonic belt there is a clear northwest-southeast horizontal compression and a southwest-northeast vertical to sub-vertical extension. Enrichment of granitic breccias and feldspar in the Grahamstown Dwyka tillite is the source for the formation of kaolin deposits. The weathering starts in the granitic breccias through their extensional fractures and then extends in the matrix, which has micro-fractures that are only visible with the transmitted microscope. Combined extensional strike-slip and dip-slip faulting is responsible for the earthquakes in the region of Grahamstown where the kaolin is formed. There is also an unreported thermal (quartz veins) and neotectonic event identified in this region. 5) The hot springs in the northern neotectonic belt are connected by a regional neotectonic fault. The use of magnetic and electromagnetic methods helped to decipher the occurrence of faults, fractures, dolerite dykes, and variable degree of weathering. Uranium/potassium ratios derived from radiometric surveys show that areas around some hot springs are characterized by enrichment in uranium. High concentrations of thorium are related to its low capacity of being easily dissolved in water. It can be concluded that seismicity, hot springs and accordingly deep groundwater circulation, high density of lineaments, quaternary tectonic uplift, are the predominate characteristics of the three neotectonic zones. Furthermore, on the environmental point of view, thorium concentration is higher than that of either uranium or potassium. Although it is nonetheless below the world average threshold of 7.4 ppm according to United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR), it may be a source of radiation hazard to humans and animals if they are subjected to prolonged exposure. All the neotectonic zones in the Eastern Cape Province present potentials to host good and important aquifers. It is suggested that the Eastern Cape great lineament in the southern neotectonic belt and the Kokstad-Koffiefontein seismic belt in the northern neotectonic belt, be monitored for future research regarding, neotectonics, seismic risk assessment and hydrogeology.
- Full Text:
- Authors: Madi, Kakaba
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Geology)
- Identifier: vital:11530 , http://hdl.handle.net/10353/d1021270
- Description: The Eastern Cape Province has, besides the three known neotectonic belts (southern, eastern and northern) a fourth zone, which is inactive. This inactive zone is located almost in its central part north of the southern neotectonic zone, and south of the northern neotectonic belt. The three above mentioned neotectonic belts (southern, eastern and northern) were chosen for this study, each one with its own characteristics. This study aims at characterizing and targeting potentially high yield aquifers in the neotectonic zones in the Eastern Cape Province. The methods used in this study include: 1) A comprehensive literature review on neotectonics in South Africa in general and in the Eastern Cape Province in particular; 2) Extraction of lineaments through remote sensing and examination of digital elevation models; 3) Examination of seismic data for the subsurface visualization onshore and offshore; 4) Study on the genesis of the Grahamstown kaolin deposits through the structural component; and 5) Acquisition and interpretation of magnetic, electromagnetic and radiometric data from three of the hot springs in the northern neotectonic belt. The results indicate the following: 1) Old map of seismic epicentres in South Africa need to be reviewed continually. The Eastern Cape was regarded as quiescent in terms of seismicity. However, the investigation from recent seismic epicenters downloadable from the IRIS website has shown that recent seismic events occurred in the Eastern Cape Province especially in the northern and southern neotectonic belts. The central part located north of the southern neotectonic belt and south of the northern neotectonic belt is inactive. This inactive zone can be considered for the storage of nuclear wastes. 2) The eastern neotectonic belt has, like the northern neotectonic belt, a higher density of lineaments oriented northwest-southeast, which makes it the second important neotectonic belt. These lineaments correlate with the normalized difference vegetation index indicative of a good circulation of groundwater. In the south, the Eastern Cape great lineament oriented east-west is now considered a neotectonic domain because many seismic epicentres occur therein. Its geomorphologic shape in graben type form is a favourable structure for groundwater catchment. The surface topography is not uniform and high elevations in the east are related to the uplift that took place in the Quaternary. Most vector gradients are oriented east-west, a fact to be reckon with in the study of surface water flow and aquifers characterization. 3) Offshore along the east coast, the subsurface is affected by neotectonic faults, which are probably splays of the Agulhas Falkland Fractured Zone (AFFZ). The folds that occur are related to the regional compressional stress known as the Wegener Stress Anomaly (WSM). On land, straight lines from seismic profiles indicate that weathering occurs in consolidated materials probably along faults or fractures, unconsolidated sediments always have wavy profiles. On the other hand, field observations in King Williams Town have clearly shown that a tectonic uplift took place on a dolerite sill overlain by mudstones and sandstones. The uplift is possibly related to the Amatole-Swaziland event that occurred in the last five millions years. The escarpment along this dolerite sill overlain by sedimentary rocks is a meso-scale fault with a dip-slip component. Healthy vegetation and a river flowing parallel to the cliff indicate groundwater flow in the zone of weakness. 4) In the southern neotectonic belt there is a clear northwest-southeast horizontal compression and a southwest-northeast vertical to sub-vertical extension. Enrichment of granitic breccias and feldspar in the Grahamstown Dwyka tillite is the source for the formation of kaolin deposits. The weathering starts in the granitic breccias through their extensional fractures and then extends in the matrix, which has micro-fractures that are only visible with the transmitted microscope. Combined extensional strike-slip and dip-slip faulting is responsible for the earthquakes in the region of Grahamstown where the kaolin is formed. There is also an unreported thermal (quartz veins) and neotectonic event identified in this region. 5) The hot springs in the northern neotectonic belt are connected by a regional neotectonic fault. The use of magnetic and electromagnetic methods helped to decipher the occurrence of faults, fractures, dolerite dykes, and variable degree of weathering. Uranium/potassium ratios derived from radiometric surveys show that areas around some hot springs are characterized by enrichment in uranium. High concentrations of thorium are related to its low capacity of being easily dissolved in water. It can be concluded that seismicity, hot springs and accordingly deep groundwater circulation, high density of lineaments, quaternary tectonic uplift, are the predominate characteristics of the three neotectonic zones. Furthermore, on the environmental point of view, thorium concentration is higher than that of either uranium or potassium. Although it is nonetheless below the world average threshold of 7.4 ppm according to United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR), it may be a source of radiation hazard to humans and animals if they are subjected to prolonged exposure. All the neotectonic zones in the Eastern Cape Province present potentials to host good and important aquifers. It is suggested that the Eastern Cape great lineament in the southern neotectonic belt and the Kokstad-Koffiefontein seismic belt in the northern neotectonic belt, be monitored for future research regarding, neotectonics, seismic risk assessment and hydrogeology.
- Full Text:
The establishment of a mobile phone information security culture: linking student awareness and behavioural intent
- Authors: Bukelwa, Ngoqo
- Date: 2014
- Subjects: Information security awareness -- Mobile phone security , Information safety
- Language: English
- Type: Thesis , Doctoral , PhD (Information Systems)
- Identifier: http://hdl.handle.net/10353/657 , vital:26485 , Information security awareness -- Mobile phone security , Information safety
- Description: The information security behaviour of technology users has become an increasingly popular research area as security experts have come to recognise that while securing technology by means of firewalls, passwords and offsite backups is important, such security may be rendered ineffective if the technology users themselves are not information security conscious. The mobile phone has become a necessity for many students but, at the same time, it exposes them to security threats that may result in a loss of information. Students in developing countries are at a disadvantage because they have limited access to information relating to information security threats, unlike their counterparts in more developed societies who can readily access this information from sources like the Internet. The developmental environment is plagued with challenges like access to the Internet or limited access to computers. The poor security behaviour exhibited by student mobile phone users, which was confirmed by the findings of this study, is of particular interest in the university context as most undergraduate students are offered a computer-related course which covers certain information security-related principles. During the restructuring of the South African higher education system, smaller universities and technikons (polytechnics) were merged to form comprehensive universities. Thus, the resultant South African university landscape is made up of traditional and comprehensive universities as well as universities of technology. Ordinarily, one would expect university students to have similar profiles. However in the case of this study, the environment was a unique factor which had a direct impact on students’ learning experiences and learning outcomes. Mbeki (2004) refers to two economies within South Africa the first one is financially sound and globally integrated, and the other found in urban and rural areas consists of unemployed and unemployable people who do not benefit from progress in the first economy. Action research was the methodological approach which was chosen for the purposes of this study to collect the requisite data among a population of university students from the ‘second economy’. The study focuses on the relationship between awareness and behavioural intention in understanding mobile phone user information security behaviour. The study concludes by proposing a behaviour profile forecasting framework based on predefined security behavioural profiles. A key finding of this study is that the security behaviour exhibited by mobile phone users is influenced by a combination of information security awareness and information security behavioural intention, and not just information security awareness.
- Full Text:
- Authors: Bukelwa, Ngoqo
- Date: 2014
- Subjects: Information security awareness -- Mobile phone security , Information safety
- Language: English
- Type: Thesis , Doctoral , PhD (Information Systems)
- Identifier: http://hdl.handle.net/10353/657 , vital:26485 , Information security awareness -- Mobile phone security , Information safety
- Description: The information security behaviour of technology users has become an increasingly popular research area as security experts have come to recognise that while securing technology by means of firewalls, passwords and offsite backups is important, such security may be rendered ineffective if the technology users themselves are not information security conscious. The mobile phone has become a necessity for many students but, at the same time, it exposes them to security threats that may result in a loss of information. Students in developing countries are at a disadvantage because they have limited access to information relating to information security threats, unlike their counterparts in more developed societies who can readily access this information from sources like the Internet. The developmental environment is plagued with challenges like access to the Internet or limited access to computers. The poor security behaviour exhibited by student mobile phone users, which was confirmed by the findings of this study, is of particular interest in the university context as most undergraduate students are offered a computer-related course which covers certain information security-related principles. During the restructuring of the South African higher education system, smaller universities and technikons (polytechnics) were merged to form comprehensive universities. Thus, the resultant South African university landscape is made up of traditional and comprehensive universities as well as universities of technology. Ordinarily, one would expect university students to have similar profiles. However in the case of this study, the environment was a unique factor which had a direct impact on students’ learning experiences and learning outcomes. Mbeki (2004) refers to two economies within South Africa the first one is financially sound and globally integrated, and the other found in urban and rural areas consists of unemployed and unemployable people who do not benefit from progress in the first economy. Action research was the methodological approach which was chosen for the purposes of this study to collect the requisite data among a population of university students from the ‘second economy’. The study focuses on the relationship between awareness and behavioural intention in understanding mobile phone user information security behaviour. The study concludes by proposing a behaviour profile forecasting framework based on predefined security behavioural profiles. A key finding of this study is that the security behaviour exhibited by mobile phone users is influenced by a combination of information security awareness and information security behavioural intention, and not just information security awareness.
- Full Text:
The impact of export diversification on economic performance in South Africa: 1980-2012
- Authors: Choga, Ireen
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , Doctor of Commerce (in Economics)
- Identifier: vital:11489 , http://hdl.handle.net/10353/d1018223
- Description: A widely held view is that export diversification constitutes an important component of export led growth, and poses a major challenge for many developing countries. Given this, the role of export diversification on economic growth warrants a fresh analysis in South Africa. The primary objective of this study is to determine the impact of export diversification on economic growth in South Africa. In this context, the study seeks to establish the relationship between export diversification, export stability and export growth. Initially, the study examines the extent and structure of export diversification in South Africa; it then empirically establishes the link between export diversification, export stability and export growth. Finally, it develops a model and investigates the effects of export diversification on economic growth in South Africa. As an attempt to fulfill the proposed objectives, this study uses quarterly data for the period 1980 to 2012 as well as data for 28 selected groups of commodities to investigate the effects of export diversification on economic growth in South Africa. Measures of export diversification and structural changes in exports in the context of South Africa were discussed. The findings of this study are that the Commodity Specific Cumulative Experience function showed that plots for manufactured commodities are shifted to the right indicating that the commodities are non-traditional in nature whereas, plots for primary commodities are shifted to the left. Results also indicated that South Africa relies more on traditional exports than manufactured exports. Various measures of export instability were used to calculate the export instability index in South Africa. The results of the study reveal that the South African export basket is slightly diversified, and the less diversified or primary commodities are associated with high instability VECM approach was used to allow us to establish the extent of influence of export diversification and other explanatory variables on economic growth. Consistent with other researchers, the study found that export diversification plays significant roles to economic growth in South Africa. A number of diagnostic checks were employed to validate the parameter evaluation of the outcomes achieved by the model. The model passed all the diagnostic checks. On the whole, the results to a larger extent painted a pictured that export diversification is important or drives economic growth in South Africa. Corroborating our findings with work of other scholars, we conclude that our results are complementary.
- Full Text:
- Authors: Choga, Ireen
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , Doctor of Commerce (in Economics)
- Identifier: vital:11489 , http://hdl.handle.net/10353/d1018223
- Description: A widely held view is that export diversification constitutes an important component of export led growth, and poses a major challenge for many developing countries. Given this, the role of export diversification on economic growth warrants a fresh analysis in South Africa. The primary objective of this study is to determine the impact of export diversification on economic growth in South Africa. In this context, the study seeks to establish the relationship between export diversification, export stability and export growth. Initially, the study examines the extent and structure of export diversification in South Africa; it then empirically establishes the link between export diversification, export stability and export growth. Finally, it develops a model and investigates the effects of export diversification on economic growth in South Africa. As an attempt to fulfill the proposed objectives, this study uses quarterly data for the period 1980 to 2012 as well as data for 28 selected groups of commodities to investigate the effects of export diversification on economic growth in South Africa. Measures of export diversification and structural changes in exports in the context of South Africa were discussed. The findings of this study are that the Commodity Specific Cumulative Experience function showed that plots for manufactured commodities are shifted to the right indicating that the commodities are non-traditional in nature whereas, plots for primary commodities are shifted to the left. Results also indicated that South Africa relies more on traditional exports than manufactured exports. Various measures of export instability were used to calculate the export instability index in South Africa. The results of the study reveal that the South African export basket is slightly diversified, and the less diversified or primary commodities are associated with high instability VECM approach was used to allow us to establish the extent of influence of export diversification and other explanatory variables on economic growth. Consistent with other researchers, the study found that export diversification plays significant roles to economic growth in South Africa. A number of diagnostic checks were employed to validate the parameter evaluation of the outcomes achieved by the model. The model passed all the diagnostic checks. On the whole, the results to a larger extent painted a pictured that export diversification is important or drives economic growth in South Africa. Corroborating our findings with work of other scholars, we conclude that our results are complementary.
- Full Text:
The implementation of inclusion policy for learners with special education needs in primary schools in Fort beafort district :Towards a rights based approach to education
- Authors: Adewumi, Toyin Mary
- Date: 2014
- Subjects: Inclusive education Education and state -- South Africa -- Eastern Cape Children with disabilities -- Education -- South Africa -- Eastern Cape Special education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5873 , vital:29413
- Description: The implementation of inclusion policy for learners with special education needs as stipulated in the Education White Paper 2001has been an issue of concern for South African schools. This study sheds light on the implementation of inclusion policy for learners with special education needs in the selected primary schools in the Fort Beaufort District in the Eastern Cape Province in South Africa. The aim of the study is to examine the implementation of inclusion policy for learners with special education needs. The study was placed within the post-positivism paradigm and used a mixed method research approach that integrated concurrent procedures in the collection, analysis and interpretation of the data. Questionnaires were used to collect quantitative data while qualitative data were collected through interviews, and document analysis. A total number of 30 teachers completed the questionnaires. The researcher conducted interviews with ten principals and eight teachers. She also held interviews with four education district officials and one provincial official. Data were analysed by statistical and non-statistical procedures. The study revealed that the inclusion policy is being implemented in the selected schools. However, there are challenges that are being encountered. Firstly, some teachers have not received adequate training with regards to inclusive education policy. Staff development workshops put in place to address this challenge are minimal, and there is not enough joint effort being established by the different stakeholders with regards to support and monitoring the implementation process. Despite the challenges that accompany implementation of inclusion of learners with special education needs, as well as the difficult working conditions, this study reveals that there are pockets of good practice of inclusion policy in some of the selected schools in the Fort Beaufort District. For instance, it was found that teachers implement inclusion of learners with special education needs, even though the majority of them do not have qualifications in special education. It was also revealed that teachers used learner-centred teaching methods to accommodate all learners, which include group and individual teaching, group demonstration, discussions, question-and-answer sessions, and practical activities.
- Full Text:
- Authors: Adewumi, Toyin Mary
- Date: 2014
- Subjects: Inclusive education Education and state -- South Africa -- Eastern Cape Children with disabilities -- Education -- South Africa -- Eastern Cape Special education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5873 , vital:29413
- Description: The implementation of inclusion policy for learners with special education needs as stipulated in the Education White Paper 2001has been an issue of concern for South African schools. This study sheds light on the implementation of inclusion policy for learners with special education needs in the selected primary schools in the Fort Beaufort District in the Eastern Cape Province in South Africa. The aim of the study is to examine the implementation of inclusion policy for learners with special education needs. The study was placed within the post-positivism paradigm and used a mixed method research approach that integrated concurrent procedures in the collection, analysis and interpretation of the data. Questionnaires were used to collect quantitative data while qualitative data were collected through interviews, and document analysis. A total number of 30 teachers completed the questionnaires. The researcher conducted interviews with ten principals and eight teachers. She also held interviews with four education district officials and one provincial official. Data were analysed by statistical and non-statistical procedures. The study revealed that the inclusion policy is being implemented in the selected schools. However, there are challenges that are being encountered. Firstly, some teachers have not received adequate training with regards to inclusive education policy. Staff development workshops put in place to address this challenge are minimal, and there is not enough joint effort being established by the different stakeholders with regards to support and monitoring the implementation process. Despite the challenges that accompany implementation of inclusion of learners with special education needs, as well as the difficult working conditions, this study reveals that there are pockets of good practice of inclusion policy in some of the selected schools in the Fort Beaufort District. For instance, it was found that teachers implement inclusion of learners with special education needs, even though the majority of them do not have qualifications in special education. It was also revealed that teachers used learner-centred teaching methods to accommodate all learners, which include group and individual teaching, group demonstration, discussions, question-and-answer sessions, and practical activities.
- Full Text:
Towards the modeling of indigenous poultry production in the Eastern Cape Province, South Africa: characterization and extension evaluation for poverty reduction
- Yusuf, Shehu Folaranmi Gbolahan Shehu
- Authors: Yusuf, Shehu Folaranmi Gbolahan Shehu
- Date: 2014
- Subjects: Poultry -- Breeding -- South Africa -- Eastern Cape , Chickens -- Breeding -- South Africa -- Eastern Cape , Economic development -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD (Agricultural Economics)
- Identifier: vital:11223 , http://hdl.handle.net/10353/d1019833 , Poultry -- Breeding -- South Africa -- Eastern Cape , Chickens -- Breeding -- South Africa -- Eastern Cape , Economic development -- South Africa -- Eastern Cape
- Description: Poverty remains a critical issue mostly in the rural South Africa. Various initiatives, policies and programs have been enacted by the government with attempting to reduce poverty at the national and provincial levels; poverty is yet to be abated. The target of the Millennium Development Goal 1 (MDG1) of halving poverty by the year 2015 notwithstanding, poverty remains a threat to quality livelihoods. Agriculture has continued to be one of the pillars of government efforts to address poverty. However, in livestock production interventions, efforts of government had largely been on cattle, sheep, goats, pigs and exotic poultry with little attention being given to indigenous poultry production (IPP). This study explores the option of using IPP to address rural poverty by capitalizing on its minimal inputs while recognizing its prevalence in a variety of households. The study addresses the characterization of the IPP from the perspectives of housing, feeding, healthcare management, breeding and marketing options.Skill competencies of the indigenous poultry farmers (IPFs) and the Agricultural Development Technicians (ADTs) were examined. This study reviewed poultry models in different parts of the world with special attention to Africa. The human resource development program of the department of rural development and agrarian reform was discussed. The study employed the use of multi-methods approach, the quantitative and qualitative research methodologies. Descriptive statistical analysis, frequent count, percentage, means, standard deviation, chisquare, and principal component analysis was used in the quantitative data analysis while the “open social system” was used for the qualitative methodology. Findings revealed that IPFs face some challenges among which are, the poor housing that exposed the birds to inclement weather, predator attacks and stock theft, high mortality of chicks after hatching and expensive feed for the flock. The IPFs showed competencies in nine skill items that included ability to identify chicken predators (x=3.92) and high yielding chickens (x=3.79); control of predators(x=3.77); methods of using ethno veterinary drugs to treat chicken diseases and pests (x=3.72), and identify signs of diseases (x=3.69), among others. However, the ADTs did not show any competency in any of the 32 skills items. The principal component analysis with Varimax rotation was performed to ascertain the dimensionality of the measures. Six factors with eigen value of >1, which accounted for 77.317% were extracted, with each factor loading ranging from 0.523 to 0.93. Factor loading after rotation that emerged on the same component was described; as brooding, shelter and care of the chicks; predators and healthcare; hygiene and litter management; feeds and feeding stuff; and record keeping and marketing. The findings on the human resource development revealed that staff meetings were the most common method of capacity development. This was followed by in-service-training, formal study, workshop, and on the job training. The farmers’ field school and study tours were sparingly used. However, respondents were in favor of on-site training, staff meetings, formal study and in-service training. The findings on the appropriate model suggest a theoretical indigenous poultry production model (IPPM) for the Eastern Cape Province (ECP). The “open social system” was used to develop a framework for an indigenous poultry cooperative society (to be known as Abafuyi Benkukhu Zemveli [ABZ]). This was meant to create a binding force for capacity development, a strong economic foundation through equity contributions, creation of marketing channels, and the development of a concept of ‘‘our own'' product in the market. Lastly, the study offers options for a training program that would accommodate the new initiatives, with a strong capacity development training approach. In this context, the study advocates for institutional support for the IPFs and the incorporation of indigenous poultry in the curriculum of the agricultural training programs at higher education institutions in South Africa.
- Full Text:
- Authors: Yusuf, Shehu Folaranmi Gbolahan Shehu
- Date: 2014
- Subjects: Poultry -- Breeding -- South Africa -- Eastern Cape , Chickens -- Breeding -- South Africa -- Eastern Cape , Economic development -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD (Agricultural Economics)
- Identifier: vital:11223 , http://hdl.handle.net/10353/d1019833 , Poultry -- Breeding -- South Africa -- Eastern Cape , Chickens -- Breeding -- South Africa -- Eastern Cape , Economic development -- South Africa -- Eastern Cape
- Description: Poverty remains a critical issue mostly in the rural South Africa. Various initiatives, policies and programs have been enacted by the government with attempting to reduce poverty at the national and provincial levels; poverty is yet to be abated. The target of the Millennium Development Goal 1 (MDG1) of halving poverty by the year 2015 notwithstanding, poverty remains a threat to quality livelihoods. Agriculture has continued to be one of the pillars of government efforts to address poverty. However, in livestock production interventions, efforts of government had largely been on cattle, sheep, goats, pigs and exotic poultry with little attention being given to indigenous poultry production (IPP). This study explores the option of using IPP to address rural poverty by capitalizing on its minimal inputs while recognizing its prevalence in a variety of households. The study addresses the characterization of the IPP from the perspectives of housing, feeding, healthcare management, breeding and marketing options.Skill competencies of the indigenous poultry farmers (IPFs) and the Agricultural Development Technicians (ADTs) were examined. This study reviewed poultry models in different parts of the world with special attention to Africa. The human resource development program of the department of rural development and agrarian reform was discussed. The study employed the use of multi-methods approach, the quantitative and qualitative research methodologies. Descriptive statistical analysis, frequent count, percentage, means, standard deviation, chisquare, and principal component analysis was used in the quantitative data analysis while the “open social system” was used for the qualitative methodology. Findings revealed that IPFs face some challenges among which are, the poor housing that exposed the birds to inclement weather, predator attacks and stock theft, high mortality of chicks after hatching and expensive feed for the flock. The IPFs showed competencies in nine skill items that included ability to identify chicken predators (x=3.92) and high yielding chickens (x=3.79); control of predators(x=3.77); methods of using ethno veterinary drugs to treat chicken diseases and pests (x=3.72), and identify signs of diseases (x=3.69), among others. However, the ADTs did not show any competency in any of the 32 skills items. The principal component analysis with Varimax rotation was performed to ascertain the dimensionality of the measures. Six factors with eigen value of >1, which accounted for 77.317% were extracted, with each factor loading ranging from 0.523 to 0.93. Factor loading after rotation that emerged on the same component was described; as brooding, shelter and care of the chicks; predators and healthcare; hygiene and litter management; feeds and feeding stuff; and record keeping and marketing. The findings on the human resource development revealed that staff meetings were the most common method of capacity development. This was followed by in-service-training, formal study, workshop, and on the job training. The farmers’ field school and study tours were sparingly used. However, respondents were in favor of on-site training, staff meetings, formal study and in-service training. The findings on the appropriate model suggest a theoretical indigenous poultry production model (IPPM) for the Eastern Cape Province (ECP). The “open social system” was used to develop a framework for an indigenous poultry cooperative society (to be known as Abafuyi Benkukhu Zemveli [ABZ]). This was meant to create a binding force for capacity development, a strong economic foundation through equity contributions, creation of marketing channels, and the development of a concept of ‘‘our own'' product in the market. Lastly, the study offers options for a training program that would accommodate the new initiatives, with a strong capacity development training approach. In this context, the study advocates for institutional support for the IPFs and the incorporation of indigenous poultry in the curriculum of the agricultural training programs at higher education institutions in South Africa.
- Full Text:
Training of teachers in multigrade teaching: integration of vertical and horizontal knowledge in post -training
- Authors: Ganqa, Ncumisa Hazel
- Date: 2014
- Subjects: Combination of grades -- Cross-cultural studies Teachers -- In-service training Teachers
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: http://hdl.handle.net/10353/6158 , vital:29496
- Description: The purpose of this study was to examine the training and development of teachers in multi-grade teaching in selected Eastern Cape primary schools with a particular focus on the integration of vertical and horizontal knowledge in post-training. Multigrade teaching is the combining of learners of different grade levels in one classroom taught by one teacher. To gain better understanding of the construct of vertical and horizontal integration of knowledge within post-training environment, this qualitative case study design sampled eight teachers, four school principals and three trainers, purposively. In order to evaluate the training and development provided for teachers in multi-grade classrooms the researcher examined the training programmes, the training curriculum and transfer of training inputs. The results of the study indicate that post-training is the determinant of the extent of the effectiveness of the transfer of training skills, knowledge and attitudes gained in multi-grade teaching training. The study found a massive gap that currently exists between training in multi-grade teaching and the actual transferability of such training in multi-grade contexts. Positive transfer of training in multi-grade teaching strategies was found to be skills related to teaching strategies, lesson management, curriculum integration and social components of multi-grade teaching. Negative transfer of training included classroom organisation, lesson planning, timetabling, curriculum adaptation and assessment. Although multi-grade teacher training programme is assumed to change behaviours, attitudes, impart knowledge and improve teaching skills, the results of the study indicate that training inputs might not necessarily transform into classroom practice. In order to facilitate and ensure vertical and horizontal integration of knowledge and skills and transfer of training to classroombased teaching, recurrent training in multi-grade teaching is therefore, suggested.
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- Authors: Ganqa, Ncumisa Hazel
- Date: 2014
- Subjects: Combination of grades -- Cross-cultural studies Teachers -- In-service training Teachers
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: http://hdl.handle.net/10353/6158 , vital:29496
- Description: The purpose of this study was to examine the training and development of teachers in multi-grade teaching in selected Eastern Cape primary schools with a particular focus on the integration of vertical and horizontal knowledge in post-training. Multigrade teaching is the combining of learners of different grade levels in one classroom taught by one teacher. To gain better understanding of the construct of vertical and horizontal integration of knowledge within post-training environment, this qualitative case study design sampled eight teachers, four school principals and three trainers, purposively. In order to evaluate the training and development provided for teachers in multi-grade classrooms the researcher examined the training programmes, the training curriculum and transfer of training inputs. The results of the study indicate that post-training is the determinant of the extent of the effectiveness of the transfer of training skills, knowledge and attitudes gained in multi-grade teaching training. The study found a massive gap that currently exists between training in multi-grade teaching and the actual transferability of such training in multi-grade contexts. Positive transfer of training in multi-grade teaching strategies was found to be skills related to teaching strategies, lesson management, curriculum integration and social components of multi-grade teaching. Negative transfer of training included classroom organisation, lesson planning, timetabling, curriculum adaptation and assessment. Although multi-grade teacher training programme is assumed to change behaviours, attitudes, impart knowledge and improve teaching skills, the results of the study indicate that training inputs might not necessarily transform into classroom practice. In order to facilitate and ensure vertical and horizontal integration of knowledge and skills and transfer of training to classroombased teaching, recurrent training in multi-grade teaching is therefore, suggested.
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Wild vegetables of the Eastern Cape of South Africa: the nutritional value and domestication of solanum nigrum l
- Authors: Bvenura, Callistus
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Ethnobotany)
- Identifier: vital:11885 , http://hdl.handle.net/10353/d1015514
- Description: An ethnobotanical survey was conducted in Alice and Willowvale in the Nkonkobe and Mbashe municipalities of the Eastern Cape Province, South Africa to identify and document wild vegetables growing in the areas. The survey documented 22 vegetable species belonging to 12 different families. The Amaryllidaceae, Amaranthaceae, Apiaceae, Asteraceae, Caryophyllaceae, Chenopodiaceae, Convolvulaceae, Cruciferae, Cucurbitaceaea, Euphorbiaceae, Tiliaceae, Solanaceae, Polygonaceae and Urticaceae were the families that were recorded. The species were Tulbaghia violacea Harv., Amaranthus blitoides S., Amaranthus blitum L., Amaranthus hybridus L., Centella coriacea Nannfd., Bidens pilosa L, Cotula heterocarpa DC., Sonchus oleraceus L., Galinsoga parviflora Cav., Taraxacum officinale Weber, Hypochaeris radicata L., Stellaria media L., Chenopodium album L., Chenopodium murale L., Ipomoea batatas L., Sisymbrium thellungii O. Schulz, Cucurbita pepo L., Rumex crispus L., Acalypha virginica L., Nicandra physalodes L., Physalis peruviana L., Solanum nigrum L., Urtica urens L. and Corchorus olitorius L. About 27 % of the wild vegetables were native to South Africa and about 45 % were also used as medicinal plants in the areas. Sun drying was the most common method of preserving the wild vegetables for the off season months. This study also revealed that, men and the younger generation knew less about wild vegetables than the women. The study also revealed a loss of knowledge of wild vegetables and their use by the rural dwellers who are more in favour of the exotic types such as spinach and cabbage.
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- Authors: Bvenura, Callistus
- Date: 2014
- Language: English
- Type: Thesis , Doctoral , PhD (Ethnobotany)
- Identifier: vital:11885 , http://hdl.handle.net/10353/d1015514
- Description: An ethnobotanical survey was conducted in Alice and Willowvale in the Nkonkobe and Mbashe municipalities of the Eastern Cape Province, South Africa to identify and document wild vegetables growing in the areas. The survey documented 22 vegetable species belonging to 12 different families. The Amaryllidaceae, Amaranthaceae, Apiaceae, Asteraceae, Caryophyllaceae, Chenopodiaceae, Convolvulaceae, Cruciferae, Cucurbitaceaea, Euphorbiaceae, Tiliaceae, Solanaceae, Polygonaceae and Urticaceae were the families that were recorded. The species were Tulbaghia violacea Harv., Amaranthus blitoides S., Amaranthus blitum L., Amaranthus hybridus L., Centella coriacea Nannfd., Bidens pilosa L, Cotula heterocarpa DC., Sonchus oleraceus L., Galinsoga parviflora Cav., Taraxacum officinale Weber, Hypochaeris radicata L., Stellaria media L., Chenopodium album L., Chenopodium murale L., Ipomoea batatas L., Sisymbrium thellungii O. Schulz, Cucurbita pepo L., Rumex crispus L., Acalypha virginica L., Nicandra physalodes L., Physalis peruviana L., Solanum nigrum L., Urtica urens L. and Corchorus olitorius L. About 27 % of the wild vegetables were native to South Africa and about 45 % were also used as medicinal plants in the areas. Sun drying was the most common method of preserving the wild vegetables for the off season months. This study also revealed that, men and the younger generation knew less about wild vegetables than the women. The study also revealed a loss of knowledge of wild vegetables and their use by the rural dwellers who are more in favour of the exotic types such as spinach and cabbage.
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