'She travels alone and unattended’: the visit to the Eastern Cape of the botanical artist, Marianne North
- Authors: Beard, Margot
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147759 , vital:38668 , https://doi.org/10.1080/00043389.2007.11877077
- Description: The visit of the botanical artist, Marianne North, to South Africa during 1882 to 1883, although frequently referred to, has not received much close attention; nor has her account of the visit, in her ‘Recollections of a happy’ life, been set against the actual conditions she would have encountered. This paper attempts to flesh out at least part of that visit, specifically the weeks she spent in the Eastern Cape Colony and, more particularly, her visits to Port Elizabeth, Grahamstown and Port Alfred. What were these three centres like at the time? Who were the people she mentions? Where did she stay? How do her observations tally with other accounts of the period?.
- Full Text:
- Date Issued: 2017
- Authors: Beard, Margot
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147759 , vital:38668 , https://doi.org/10.1080/00043389.2007.11877077
- Description: The visit of the botanical artist, Marianne North, to South Africa during 1882 to 1883, although frequently referred to, has not received much close attention; nor has her account of the visit, in her ‘Recollections of a happy’ life, been set against the actual conditions she would have encountered. This paper attempts to flesh out at least part of that visit, specifically the weeks she spent in the Eastern Cape Colony and, more particularly, her visits to Port Elizabeth, Grahamstown and Port Alfred. What were these three centres like at the time? Who were the people she mentions? Where did she stay? How do her observations tally with other accounts of the period?.
- Full Text:
- Date Issued: 2017
'The Area of a Triangle is 1800C’: an analysis of Learners' Idiosyncratic Geometry Responses through the Lenses of Vygotsky's Theory of Concept Formation
- Mhlolo, Michael K, Schäfer, Marc
- Authors: Mhlolo, Michael K , Schäfer, Marc
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141127 , vital:37946 , DOI: 10.1080/10288457.2013.826973
- Description: In this paper, we focus specifically on Vygotsky's theory of concept formation to gain initial insights into seemingly garbled and incoherent connections we observed in learners' responses to a geometry task. While acknowledging research that is supportive of the van Hiele model as being useful when analysing concept formation in geometry, in this paper we use empirical evidence to argue that today's geometry requires learners to reason with many tools which the van Hiele model does not seem to accommodate. Working with 470 written responses of 12–14-year-old learners to a geometry task, we then explored the potential of Vygotsky's theory of concept formation as an alternative framework. We conclude by discussing the paper's contribution both to theory and to classroom practice.
- Full Text:
- Date Issued: 2013
- Authors: Mhlolo, Michael K , Schäfer, Marc
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141127 , vital:37946 , DOI: 10.1080/10288457.2013.826973
- Description: In this paper, we focus specifically on Vygotsky's theory of concept formation to gain initial insights into seemingly garbled and incoherent connections we observed in learners' responses to a geometry task. While acknowledging research that is supportive of the van Hiele model as being useful when analysing concept formation in geometry, in this paper we use empirical evidence to argue that today's geometry requires learners to reason with many tools which the van Hiele model does not seem to accommodate. Working with 470 written responses of 12–14-year-old learners to a geometry task, we then explored the potential of Vygotsky's theory of concept formation as an alternative framework. We conclude by discussing the paper's contribution both to theory and to classroom practice.
- Full Text:
- Date Issued: 2013
'We pledge to improve the health of our entire community'
- Grant, Carolyn, Nawal, Dipty, Guntur, Sai Mala, Kumar, Manish, Chaudhuri, Indrajit, Galavotti, Christine, Mahapatra, Tanmay, Ranjan, Kunal, Kumar, Gangesh, Mohanty, Sunil, Alam, Mohammed Aftab, Das, Aritra, Jiwani, Safia
- Authors: Grant, Carolyn , Nawal, Dipty , Guntur, Sai Mala , Kumar, Manish , Chaudhuri, Indrajit , Galavotti, Christine , Mahapatra, Tanmay , Ranjan, Kunal , Kumar, Gangesh , Mohanty, Sunil , Alam, Mohammed Aftab , Das, Aritra , Jiwani, Safia
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281179 , vital:55699 , xlink:href="https://doi.org/10.1371/journal.pone.0203265"
- Description: Background: Motivation is critical to health worker performance and work quality. In Bihar, India, frontline health workers provide essential health services for the state’s poorest citizens. Yet, there is a shortfall of motivated and skilled providers and a lack of coordination between two cadres of frontline health workers and their supervisors. CARE India developed an approach aimed at improving health workers’ performance by shifting work culture and strengthening teamwork and motivation. The intervention—“Team-Based Goals and Incentives”—supported health workers to work as teams towards collective goals and rewarded success with public recognition and non-financial incentives. Methods: Thirty months after initiating the intervention, 885 health workers and 98 supervisors completed an interviewer-administered questionnaire in 38 intervention and 38 control health sub-centers in one district. The questionnaire included measures of social cohesion, teamwork attitudes, self-efficacy, job satisfaction, teamwork behaviors, equitable service delivery, taking initiative, and supervisory support. We conducted bivariate analyses to examine the impact of the intervention on these psychosocial and behavioral outcomes. Results: Results show statistically significant differences across several measures between intervention and control frontline health workers, including improved teamwork (mean = 8.8 vs. 7.3), empowerment (8.5 vs. 7.4), job satisfaction (7.1 vs. 5.99) and equitable service delivery (6.7 vs. 4.99). While fewer significant differences were found for supervisors, they reported improved teamwork (8.4 vs. 5.3), and frontline health workers reported improved fulfillment of supervisory duties by their supervisors (8.9 vs. 7.6). Both frontline health workers and supervisors found public recognition and enhanced teamwork more motivating than the non-financial incentives. Conclusions: The Team-Based Goals and Incentives model reinforces intrinsic motivation and supports improvements in the teamwork, motivation, and performance of health workers. It offers an approach to practitioners and governments for improving the work environment in a resource-constrained setting and where there are multiple cadres of health workers.
- Full Text:
- Date Issued: 2018
- Authors: Grant, Carolyn , Nawal, Dipty , Guntur, Sai Mala , Kumar, Manish , Chaudhuri, Indrajit , Galavotti, Christine , Mahapatra, Tanmay , Ranjan, Kunal , Kumar, Gangesh , Mohanty, Sunil , Alam, Mohammed Aftab , Das, Aritra , Jiwani, Safia
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281179 , vital:55699 , xlink:href="https://doi.org/10.1371/journal.pone.0203265"
- Description: Background: Motivation is critical to health worker performance and work quality. In Bihar, India, frontline health workers provide essential health services for the state’s poorest citizens. Yet, there is a shortfall of motivated and skilled providers and a lack of coordination between two cadres of frontline health workers and their supervisors. CARE India developed an approach aimed at improving health workers’ performance by shifting work culture and strengthening teamwork and motivation. The intervention—“Team-Based Goals and Incentives”—supported health workers to work as teams towards collective goals and rewarded success with public recognition and non-financial incentives. Methods: Thirty months after initiating the intervention, 885 health workers and 98 supervisors completed an interviewer-administered questionnaire in 38 intervention and 38 control health sub-centers in one district. The questionnaire included measures of social cohesion, teamwork attitudes, self-efficacy, job satisfaction, teamwork behaviors, equitable service delivery, taking initiative, and supervisory support. We conducted bivariate analyses to examine the impact of the intervention on these psychosocial and behavioral outcomes. Results: Results show statistically significant differences across several measures between intervention and control frontline health workers, including improved teamwork (mean = 8.8 vs. 7.3), empowerment (8.5 vs. 7.4), job satisfaction (7.1 vs. 5.99) and equitable service delivery (6.7 vs. 4.99). While fewer significant differences were found for supervisors, they reported improved teamwork (8.4 vs. 5.3), and frontline health workers reported improved fulfillment of supervisory duties by their supervisors (8.9 vs. 7.6). Both frontline health workers and supervisors found public recognition and enhanced teamwork more motivating than the non-financial incentives. Conclusions: The Team-Based Goals and Incentives model reinforces intrinsic motivation and supports improvements in the teamwork, motivation, and performance of health workers. It offers an approach to practitioners and governments for improving the work environment in a resource-constrained setting and where there are multiple cadres of health workers.
- Full Text:
- Date Issued: 2018
'We throw away our books': Students’ reading practices and identities
- O'Shea, Cathy, McKenna, Sioux, Thomson, Carol
- Authors: O'Shea, Cathy , McKenna, Sioux , Thomson, Carol
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187128 , vital:44570 , xlink:href="https://doi.org/10.1016/j.linged.2018.11.001"
- Description: The aim of this research was to understand university students’ self-reported reading practices. The students attended the University of Fort Hare in South Africa, a historically black institution in a rural and under-resourced setting. A framework of New Literacy Studies (NLS) was used to understand students’ self-reported reading practices and the links between these and their identities. Tools provided by Gee, 2005, Gee, 2011 were applied to conduct a CDA of focus group discussions. In the ‘We Blacks’ Discourse, interviewees ‘othered’ the idea of reading as not being culturally valued. It was closely allied to the ‘Resistance to Reading’ Discourse, as participants explained that they tended to disregard books and did not enjoy leisure reading. The ‘Better Than Us’ discourse was drawn upon to suggest that reading was associated with attitudes of superiority. These discourses tended to homogenise class and other differences between black students and indicated the ways in which their experiences made adopting academic identities difficult. The analysis suggests that the racism of the past continues to impact students’ reading identities. The article concludes that the effects of these and related discourses require a response across the education sector, and transformative pedagogies might be needed in higher education.
- Full Text:
- Date Issued: 2019
- Authors: O'Shea, Cathy , McKenna, Sioux , Thomson, Carol
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187128 , vital:44570 , xlink:href="https://doi.org/10.1016/j.linged.2018.11.001"
- Description: The aim of this research was to understand university students’ self-reported reading practices. The students attended the University of Fort Hare in South Africa, a historically black institution in a rural and under-resourced setting. A framework of New Literacy Studies (NLS) was used to understand students’ self-reported reading practices and the links between these and their identities. Tools provided by Gee, 2005, Gee, 2011 were applied to conduct a CDA of focus group discussions. In the ‘We Blacks’ Discourse, interviewees ‘othered’ the idea of reading as not being culturally valued. It was closely allied to the ‘Resistance to Reading’ Discourse, as participants explained that they tended to disregard books and did not enjoy leisure reading. The ‘Better Than Us’ discourse was drawn upon to suggest that reading was associated with attitudes of superiority. These discourses tended to homogenise class and other differences between black students and indicated the ways in which their experiences made adopting academic identities difficult. The analysis suggests that the racism of the past continues to impact students’ reading identities. The article concludes that the effects of these and related discourses require a response across the education sector, and transformative pedagogies might be needed in higher education.
- Full Text:
- Date Issued: 2019
(Ferrocenylpyrazolyl) zinc (II) benzoates as catalysts for the ring opening polymerization of ε-caprolactone
- Obuah, Collins, Lochee, Yemanlall, Jordaan, Johan H L, Otto, Daniel P, Nyokong, Tebello, Darkwa, James
- Authors: Obuah, Collins , Lochee, Yemanlall , Jordaan, Johan H L , Otto, Daniel P , Nyokong, Tebello , Darkwa, James
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189515 , vital:44853 , xlink:href="https://doi.org/10.1016/j.poly.2015.02.007"
- Description: The reaction of Zn(OAc)2 and C6H5COOH or 3,5-NO2-C6H3COOH with 3-ferrocenylpyrazolyl-methylenepyridine (L1), 3-ferrocenyl-5-methylpyrazolyl-methylenepyridine (L2), 3-ferrocenylpyrazolyl-ethylamine (L3) and 3-ferrocenyl-5-pyrazolyl-ethylamine (L4) afford the corresponding complexes [Zn(C6H5COO)2(L1)] (1), [Zn(C6H5COO)2(L2)] (2), [Zn(3,5-NO2-C6H3COO)2(L1)] (3), [Zn(3,5-NO2-C6H3 COO)2(L2)] (4), [Zn(C6H5COO)2(L3)] (5), [Zn(C6H5COO)2(L4)] (6), [Zn(3,5-NO2-C6H3COO)2(L3)] (7) and [Zn(3,5-NO2-C6H3COO)2(L4)] (8). These complexes behave as catalysts for the ring opening polymerization of e-caprolactone to produce polymers with molecular weight that range from 1480 to 7080 g mol1 and exhibited moderate to broad PDIs. Evidence of these complexes acting as catalysts was obtained from both the polymerization data and kinetic studies. The polymerization data show that variation of the [CL]/[C] from 100 to 800 produced PCL with relatively the same molecular weight indicative of a catalyst behavior. The appearance of induction period in kinetic plots strengthens the fact that these complexes are catalysts rather than initiators. MALDI-TOF MS and 1 H NMR data show di-hydroxy end groups, which support the coordination mechanism rather than insertion mechanism. To understand the broad PDIs obtained for some of the polymer, the electronic properties of the zinc complexes were investigated using cyclic voltammetry. The results show that the zinc complexes containing amine based ligands are highly electrophilic therefore making them unstable, hence the broad PDIs observed for zinc complexes containing amine based ligands. Among the eight complexes investigated, complex 7 is the most active catalyst with kp value of 1.18 107 h1 mol1 at 110 C.
- Full Text:
- Date Issued: 2015
- Authors: Obuah, Collins , Lochee, Yemanlall , Jordaan, Johan H L , Otto, Daniel P , Nyokong, Tebello , Darkwa, James
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189515 , vital:44853 , xlink:href="https://doi.org/10.1016/j.poly.2015.02.007"
- Description: The reaction of Zn(OAc)2 and C6H5COOH or 3,5-NO2-C6H3COOH with 3-ferrocenylpyrazolyl-methylenepyridine (L1), 3-ferrocenyl-5-methylpyrazolyl-methylenepyridine (L2), 3-ferrocenylpyrazolyl-ethylamine (L3) and 3-ferrocenyl-5-pyrazolyl-ethylamine (L4) afford the corresponding complexes [Zn(C6H5COO)2(L1)] (1), [Zn(C6H5COO)2(L2)] (2), [Zn(3,5-NO2-C6H3COO)2(L1)] (3), [Zn(3,5-NO2-C6H3 COO)2(L2)] (4), [Zn(C6H5COO)2(L3)] (5), [Zn(C6H5COO)2(L4)] (6), [Zn(3,5-NO2-C6H3COO)2(L3)] (7) and [Zn(3,5-NO2-C6H3COO)2(L4)] (8). These complexes behave as catalysts for the ring opening polymerization of e-caprolactone to produce polymers with molecular weight that range from 1480 to 7080 g mol1 and exhibited moderate to broad PDIs. Evidence of these complexes acting as catalysts was obtained from both the polymerization data and kinetic studies. The polymerization data show that variation of the [CL]/[C] from 100 to 800 produced PCL with relatively the same molecular weight indicative of a catalyst behavior. The appearance of induction period in kinetic plots strengthens the fact that these complexes are catalysts rather than initiators. MALDI-TOF MS and 1 H NMR data show di-hydroxy end groups, which support the coordination mechanism rather than insertion mechanism. To understand the broad PDIs obtained for some of the polymer, the electronic properties of the zinc complexes were investigated using cyclic voltammetry. The results show that the zinc complexes containing amine based ligands are highly electrophilic therefore making them unstable, hence the broad PDIs observed for zinc complexes containing amine based ligands. Among the eight complexes investigated, complex 7 is the most active catalyst with kp value of 1.18 107 h1 mol1 at 110 C.
- Full Text:
- Date Issued: 2015
(Unused) potentials of educators’ covert language policies at public schools in Limpopo, South Africa:
- Kretzer, Michael M, Kaschula, Russell H
- Authors: Kretzer, Michael M , Kaschula, Russell H
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/174679 , vital:42500 , DOI: 10.1039/D0PP00075B
- Description: Language policy is an influencing factor of the educational outcome for pupils in Africa. Colonial languages have been largely used and African Languages are neglected. Despite this, the South African Constitution (1996) declares eleven official languages. However, curricular developments favour Afrikaans and English. To analyse the implementation of the official language policy, we focus on Limpopo Province. Over 1000 questionnaires were answered by teachers. This approach aimed to analyse the language practices and language attitudes of teachers. Schools in Limpopo showed significant differences between the official language policy and the daily language practices. Some teachers implement the official language policy; others use one or more African languages in their oral communications during the lessons in the form of Code Switching.
- Full Text:
- Date Issued: 2020
- Authors: Kretzer, Michael M , Kaschula, Russell H
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/174679 , vital:42500 , DOI: 10.1039/D0PP00075B
- Description: Language policy is an influencing factor of the educational outcome for pupils in Africa. Colonial languages have been largely used and African Languages are neglected. Despite this, the South African Constitution (1996) declares eleven official languages. However, curricular developments favour Afrikaans and English. To analyse the implementation of the official language policy, we focus on Limpopo Province. Over 1000 questionnaires were answered by teachers. This approach aimed to analyse the language practices and language attitudes of teachers. Schools in Limpopo showed significant differences between the official language policy and the daily language practices. Some teachers implement the official language policy; others use one or more African languages in their oral communications during the lessons in the form of Code Switching.
- Full Text:
- Date Issued: 2020
13C pulse-chase labeling comparative assessment of the active methanogenic archaeal community composition in the transgenic and nontransgenic parental rice rhizospheres
- Zhu, Weijing, Lu, Haohao, Hill, Jaclyn M, Wang, Hailong, Wu, Weixiang
- Authors: Zhu, Weijing , Lu, Haohao , Hill, Jaclyn M , Wang, Hailong , Wu, Weixiang
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/122993 , vital:35389 , https://doi.org/10.1111/1574-6941.12261
- Description: Rhabdosargus holubi (Steindachner, 1881) is a small (maximum size = 450 mm total length; Heemstra and Heemstra 2004) sparid that is distributed along the south-east coast of Africa from St Helena Bay, South Africa, to Maputo, Mozambique (Götz and Cowley 2013). Spawning occurs in the nearshore marine environment primarily during winter, specifically May–August in KwaZulu-Natal (KZN) (Wallace 1975) and July–February in the South-Eastern Cape (Whitfield 1998). Individuals reach 50% sexual maturity at approximately 150 mm standard length (SL) in the Eastern Cape (Whitfield 1998). The early life stages are transported by the south-westward-flowing Agulhas Current, and recruit as post-flexion larvae and early juveniles into estuaries during late winter and early summer (Blaber 1974). The warm temperatures and high nutrient levels in estuaries favour fast growth (Blaber 1973a), and fish spend their first year of life in these environments, migrating back out to sea after reaching approximately 120 mm SL. Some individuals remain trapped in closed estuaries, where they may reach sizes greater than 200 mm SL (James et al. 2007a). Rhabdosargus holubi is the dominant estuarine-dependent marine teleost species recorded in permanently open and temporarily open/closed estuaries in the warm-temperate region, which spans the south, south-east and east coast of South Africa (Harrison 2005). The species is also an important component of the linefishery in many SouthAfrican estuaries (10–15.6% by number) (Pradervand and Baird 2002), particularly in Eastern Cape estuaries (Cowley et al. 2003). These figures underestimate the presence of R. holubi, as most individuals making use of estuaries are young, feeding predominately on filamentous macroalgae and diatom flora, and are generally too small to be caught with hook and line (De Wet and Marais 1990). James et al. (2007b) showed that R. holubi made up 34–92% of the annual seine-net catch in the East Kleinemonde Estuary. Rhabdosargus holubi is also important in the KZN shorebased linefishery, representing 4.6% of the total landed catch (Dunlop and Mann 2012)More and more investigations indicate that genetic modification has no significant or persistent effects on microbial community composition in the rice rhizosphere. Very few studies, however, have focused on its impact on functional microorganisms. This study completed a 13C-CO2 pulse-chase labeling experiment comparing the potential effects of cry1Ab gene transformation on 13C tissue distribution and rhizosphere methanogenic archaeal community composition with its parental rice variety (Ck) and a distant parental rice variety (Dp). Results showed that 13C partitioning in aboveground biomass (mainly in stems) and roots of Dp was significantly lower than that of Ck. However, there were no significant differences in 13C partitioning between the Bt transgenic rice line (Bt) and Ck. RNA-stable isotope probing combined with clone library analyses inferred that the group Methanosaetaceae was the predominant methanogenic Archaea in all three rice rhizospheres. The active methanogenic archaeal community in the Bt rhizosphere was dominated by Methanosarcinaceae, Methanosaetaceae, and Methanomicrobiaceae, while there were only two main methanogenic clusters (Methanosaetaceae and Methanomicrobiaceae) in the Ck and Dp rhizospheres. These results indicate that the insertion of cry1Ab gene into the rice genome has the potential to result in the modification of methanogenic community composition in its rhizosphere.
- Full Text:
- Date Issued: 2013
- Authors: Zhu, Weijing , Lu, Haohao , Hill, Jaclyn M , Wang, Hailong , Wu, Weixiang
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/122993 , vital:35389 , https://doi.org/10.1111/1574-6941.12261
- Description: Rhabdosargus holubi (Steindachner, 1881) is a small (maximum size = 450 mm total length; Heemstra and Heemstra 2004) sparid that is distributed along the south-east coast of Africa from St Helena Bay, South Africa, to Maputo, Mozambique (Götz and Cowley 2013). Spawning occurs in the nearshore marine environment primarily during winter, specifically May–August in KwaZulu-Natal (KZN) (Wallace 1975) and July–February in the South-Eastern Cape (Whitfield 1998). Individuals reach 50% sexual maturity at approximately 150 mm standard length (SL) in the Eastern Cape (Whitfield 1998). The early life stages are transported by the south-westward-flowing Agulhas Current, and recruit as post-flexion larvae and early juveniles into estuaries during late winter and early summer (Blaber 1974). The warm temperatures and high nutrient levels in estuaries favour fast growth (Blaber 1973a), and fish spend their first year of life in these environments, migrating back out to sea after reaching approximately 120 mm SL. Some individuals remain trapped in closed estuaries, where they may reach sizes greater than 200 mm SL (James et al. 2007a). Rhabdosargus holubi is the dominant estuarine-dependent marine teleost species recorded in permanently open and temporarily open/closed estuaries in the warm-temperate region, which spans the south, south-east and east coast of South Africa (Harrison 2005). The species is also an important component of the linefishery in many SouthAfrican estuaries (10–15.6% by number) (Pradervand and Baird 2002), particularly in Eastern Cape estuaries (Cowley et al. 2003). These figures underestimate the presence of R. holubi, as most individuals making use of estuaries are young, feeding predominately on filamentous macroalgae and diatom flora, and are generally too small to be caught with hook and line (De Wet and Marais 1990). James et al. (2007b) showed that R. holubi made up 34–92% of the annual seine-net catch in the East Kleinemonde Estuary. Rhabdosargus holubi is also important in the KZN shorebased linefishery, representing 4.6% of the total landed catch (Dunlop and Mann 2012)More and more investigations indicate that genetic modification has no significant or persistent effects on microbial community composition in the rice rhizosphere. Very few studies, however, have focused on its impact on functional microorganisms. This study completed a 13C-CO2 pulse-chase labeling experiment comparing the potential effects of cry1Ab gene transformation on 13C tissue distribution and rhizosphere methanogenic archaeal community composition with its parental rice variety (Ck) and a distant parental rice variety (Dp). Results showed that 13C partitioning in aboveground biomass (mainly in stems) and roots of Dp was significantly lower than that of Ck. However, there were no significant differences in 13C partitioning between the Bt transgenic rice line (Bt) and Ck. RNA-stable isotope probing combined with clone library analyses inferred that the group Methanosaetaceae was the predominant methanogenic Archaea in all three rice rhizospheres. The active methanogenic archaeal community in the Bt rhizosphere was dominated by Methanosarcinaceae, Methanosaetaceae, and Methanomicrobiaceae, while there were only two main methanogenic clusters (Methanosaetaceae and Methanomicrobiaceae) in the Ck and Dp rhizospheres. These results indicate that the insertion of cry1Ab gene into the rice genome has the potential to result in the modification of methanogenic community composition in its rhizosphere.
- Full Text:
- Date Issued: 2013
4-Azidoaniline-based electropolymer as a building block for functionalisation of conductive surfaces
- Coates, Megan, Elamari, Hichem, Girard, Christian, Griveau, Sophie, Nyokong, Tebello, Bedioui, Fethi
- Authors: Coates, Megan , Elamari, Hichem , Girard, Christian , Griveau, Sophie , Nyokong, Tebello , Bedioui, Fethi
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/244404 , vital:51254 , xlink:href="https://doi.org/10.1016/j.jelechem.2012.01.001"
- Description: We propose in this work to compare three approaches using 4-azidoaniline combined with “click” chemistry and electrochemistry to anchor ferrocene moieties at glassy carbon surfaces. The immobilisation of a newly synthesised molecule, 4-(4-ferrocenyl-1H-1,2,3-triazol-1-yl)aniline, through direct electropolymerisation or via in situ diazotization followed by electrografting is studied by analysing the samples by XPS and electrochemistry.
- Full Text:
- Date Issued: 2012
4-Azidoaniline-based electropolymer as a building block for functionalisation of conductive surfaces
- Authors: Coates, Megan , Elamari, Hichem , Girard, Christian , Griveau, Sophie , Nyokong, Tebello , Bedioui, Fethi
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/244404 , vital:51254 , xlink:href="https://doi.org/10.1016/j.jelechem.2012.01.001"
- Description: We propose in this work to compare three approaches using 4-azidoaniline combined with “click” chemistry and electrochemistry to anchor ferrocene moieties at glassy carbon surfaces. The immobilisation of a newly synthesised molecule, 4-(4-ferrocenyl-1H-1,2,3-triazol-1-yl)aniline, through direct electropolymerisation or via in situ diazotization followed by electrografting is studied by analysing the samples by XPS and electrochemistry.
- Full Text:
- Date Issued: 2012
4-Bis (4-aminophenoxy) phenoxy derivitized phthalocyanine conjugated to metallic nanoparticles
- Nwaji, Njemuwa, Mack, John, Nyokong, Tebello
- Authors: Nwaji, Njemuwa , Mack, John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188965 , vital:44802 , xlink:href="https://doi.org/10.1039/C7NJ02718D"
- Description: In this study, the photophysical, nonlinear absorption and nonlinear optical limiting properties of 4-(2,4-bis(4-aminophenoxy)phenoxy) phthalocyinato zinc(II) phthalocyanine (6) conjugated to metallic nanoparticles have been investigated using open aperture Z-scan techniques using 532 nm nanosecond pulses. The nonlinear optical response demonstrated that the studied complex and the nanoconjugates exhibit higher excited state absorption cross-section compared to ground state absorption. Enhanced optical limiting performance was observed when complex 6 was conjugated to nanoparticles with 6CB-AuNPs (CB = covalent bond) showing the highest optical limiting threshold of 0.36 J cm−2.
- Full Text:
- Date Issued: 2017
- Authors: Nwaji, Njemuwa , Mack, John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188965 , vital:44802 , xlink:href="https://doi.org/10.1039/C7NJ02718D"
- Description: In this study, the photophysical, nonlinear absorption and nonlinear optical limiting properties of 4-(2,4-bis(4-aminophenoxy)phenoxy) phthalocyinato zinc(II) phthalocyanine (6) conjugated to metallic nanoparticles have been investigated using open aperture Z-scan techniques using 532 nm nanosecond pulses. The nonlinear optical response demonstrated that the studied complex and the nanoconjugates exhibit higher excited state absorption cross-section compared to ground state absorption. Enhanced optical limiting performance was observed when complex 6 was conjugated to nanoparticles with 6CB-AuNPs (CB = covalent bond) showing the highest optical limiting threshold of 0.36 J cm−2.
- Full Text:
- Date Issued: 2017
5-Fu inclusion complex capped gold nanoparticles for breast cancer therapy
- Lakkakula, Jaya R, Krause, Rui W M, Divakaran, Deepika, Barage, Sagar, Srivastava, Rohit
- Authors: Lakkakula, Jaya R , Krause, Rui W M , Divakaran, Deepika , Barage, Sagar , Srivastava, Rohit
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/191713 , vital:45150 , xlink:href="https://doi.org/10.1016/j.molliq.2021.117262"
- Description: We have attempted to prolong the circulation time and increase the solubility of 5-Fluorouracil by complexing it with cyclodextrin and then further conjugating onto the gold nanoparticle to form 5Fu ICAu. The 1H NMR and molecular docking studies suggested that 5-Fu was included within the 2HP-β-CD cavity and H-5 proton probably serves as the binding site for stabilization of the inclusion complex. The 5Fu-ICAu showed higher cell inhibition rate when studied on MDA-MB-231 and MCF-7 breast cancer cell lines due to the enhanced permeability and retention (EPR) effect by allowing the selective accumulation of nanoparticles at tumor site. This unique system can serve as a novel nanocarrier for delivery of hydrophobic drugs.
- Full Text:
- Date Issued: 2021
- Authors: Lakkakula, Jaya R , Krause, Rui W M , Divakaran, Deepika , Barage, Sagar , Srivastava, Rohit
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/191713 , vital:45150 , xlink:href="https://doi.org/10.1016/j.molliq.2021.117262"
- Description: We have attempted to prolong the circulation time and increase the solubility of 5-Fluorouracil by complexing it with cyclodextrin and then further conjugating onto the gold nanoparticle to form 5Fu ICAu. The 1H NMR and molecular docking studies suggested that 5-Fu was included within the 2HP-β-CD cavity and H-5 proton probably serves as the binding site for stabilization of the inclusion complex. The 5Fu-ICAu showed higher cell inhibition rate when studied on MDA-MB-231 and MCF-7 breast cancer cell lines due to the enhanced permeability and retention (EPR) effect by allowing the selective accumulation of nanoparticles at tumor site. This unique system can serve as a novel nanocarrier for delivery of hydrophobic drugs.
- Full Text:
- Date Issued: 2021
[Post] Colonial Histories: Trauma, Memory and Reconciliation in the Context of the Angolan Civil War
- Authors: Baines, Gary F
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125752 , vital:35814 , https://doi.10.1080/03612759.2019.1587342
- Description: In 2007, a former South African Defence Force (SADF) paratrooper, Marius van Niekerk, embarked on a journey to confront his shameful memories relating to his role in the Angolan Civil War. From Sweden (where he had gone into exile), Van Niekerk returned to Angola, where he had been deployed during the mid-1980s, and recruited three other veterans of the war to join his party: Patrick Johannes, who had been coerced to fight for the Popular Armed Forces for the Liberation of Angola (FAPLA); Samuel Machado Amaru, who was forcefully enlisted by the National Union for the Total Independence of Angola (UNITA); and Mario Mahonga, who had fought for the Portuguese colonial army before he was recruited by the SADF to fight against the Popular Movement for the Liberation of Angola (MPLA) regime. Van Niekerk had been conscripted at the age of seventeen, and the others had been coerced into their respective militias at more tender ages. It is not clear how the three Angolans were induced to participate in the project, whose objectives they evidently did not share.
- Full Text:
- Date Issued: 2019
[Post] Colonial Histories: Trauma, Memory and Reconciliation in the Context of the Angolan Civil War
- Authors: Baines, Gary F
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125752 , vital:35814 , https://doi.10.1080/03612759.2019.1587342
- Description: In 2007, a former South African Defence Force (SADF) paratrooper, Marius van Niekerk, embarked on a journey to confront his shameful memories relating to his role in the Angolan Civil War. From Sweden (where he had gone into exile), Van Niekerk returned to Angola, where he had been deployed during the mid-1980s, and recruited three other veterans of the war to join his party: Patrick Johannes, who had been coerced to fight for the Popular Armed Forces for the Liberation of Angola (FAPLA); Samuel Machado Amaru, who was forcefully enlisted by the National Union for the Total Independence of Angola (UNITA); and Mario Mahonga, who had fought for the Portuguese colonial army before he was recruited by the SADF to fight against the Popular Movement for the Liberation of Angola (MPLA) regime. Van Niekerk had been conscripted at the age of seventeen, and the others had been coerced into their respective militias at more tender ages. It is not clear how the three Angolans were induced to participate in the project, whose objectives they evidently did not share.
- Full Text:
- Date Issued: 2019
A 1394-based Architecture for professional audio production
- Moses, Bob, Laubscher, Rob, Foss, Richard
- Authors: Moses, Bob , Laubscher, Rob , Foss, Richard
- Date: 2000
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427318 , vital:72430 , https://www.aes.org/e-lib/browse.cfm?elib=9092
- Description: With the advent of the IEEE 1394 standard, many audio device manufacturers have anticipated its employment within audio production systems, with the hope that future audio production systems will utilize this single connection type for the transmission of all audio and control data. This paper outlines extensive work that has been performed on the design and implementation of 1394 audio production components and, in the process, describes the resolution of the problems that arise when audio and audio device control data pass across 1394.
- Full Text:
- Date Issued: 2000
- Authors: Moses, Bob , Laubscher, Rob , Foss, Richard
- Date: 2000
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427318 , vital:72430 , https://www.aes.org/e-lib/browse.cfm?elib=9092
- Description: With the advent of the IEEE 1394 standard, many audio device manufacturers have anticipated its employment within audio production systems, with the hope that future audio production systems will utilize this single connection type for the transmission of all audio and control data. This paper outlines extensive work that has been performed on the design and implementation of 1394 audio production components and, in the process, describes the resolution of the problems that arise when audio and audio device control data pass across 1394.
- Full Text:
- Date Issued: 2000
A 3, 5-DistyrylBODIPY Dye Functionalized with Boronic Acid Groups for Direct Electrochemical Glucose Sensing
- Ndebele, Nobuhle, Mack, John, Nyokong, Tebello
- Authors: Ndebele, Nobuhle , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187556 , vital:44671 , xlink:href="https://doi.org/10.1002/elan.201800651"
- Description: The synthesis and characterization of a novel BODIPY dye functionalized with bis-boronic acid groups to enable direct glucose sensing through selective recognition of carbohydrates is reported. Styrylation with boronic acid groups at the 3,5-positions of the BODIPY core results in an extension of the π-conjugation system of the dye and in a red-shift of the main absorption band from 500 to 637 nm. The functionalized BODIPY dye was adsorbed on a glassy carbon electrode using the drop and dry method. Modified and bare electrodes were characterized using cyclic voltammetry and scanning electrochemical microscopy, while glucose detection was carried out by using differential pulse voltammetry and chronoamperometry. The detection limit was determined to be 1.42 μM. The dye was found to be selective and sensitive towards glucose, since likely interferences have only minor effects on the glucose detection.
- Full Text:
- Date Issued: 2019
- Authors: Ndebele, Nobuhle , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187556 , vital:44671 , xlink:href="https://doi.org/10.1002/elan.201800651"
- Description: The synthesis and characterization of a novel BODIPY dye functionalized with bis-boronic acid groups to enable direct glucose sensing through selective recognition of carbohydrates is reported. Styrylation with boronic acid groups at the 3,5-positions of the BODIPY core results in an extension of the π-conjugation system of the dye and in a red-shift of the main absorption band from 500 to 637 nm. The functionalized BODIPY dye was adsorbed on a glassy carbon electrode using the drop and dry method. Modified and bare electrodes were characterized using cyclic voltammetry and scanning electrochemical microscopy, while glucose detection was carried out by using differential pulse voltammetry and chronoamperometry. The detection limit was determined to be 1.42 μM. The dye was found to be selective and sensitive towards glucose, since likely interferences have only minor effects on the glucose detection.
- Full Text:
- Date Issued: 2019
A Baseline Numeric Analysis of Network Telescope Data for Network Incident Discovery
- Cowie, Bradley, Irwin, Barry V W
- Authors: Cowie, Bradley , Irwin, Barry V W
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427971 , vital:72477 , https://www.researchgate.net/profile/Barry-Ir-win/publication/326225071_An_Evaluation_of_Trading_Bands_as_Indicators_for_Network_Telescope_Datasets/links/5b3f231a4585150d2309e1c0/An-Evaluation-of-Trading-Bands-as-Indicators-for-Network-Telescope-Datasets.pdf
- Description: This paper investigates the value of Network Telescope data as a mechanism for network incident discovery by considering data summa-rization, simple heuristic identification and deviations from previously observed traffic distributions. It is important to note that the traffic ob-served is obtained from a Network Telescope and thus does not expe-rience the same fluctuations or vagaries experienced by normal traffic. The datasets used for this analysis were obtained from a Network Tele-scope for the time period August 2005 to September 2009 which had been allocated a Class-C network address block at Rhodes University. The nature of the datasets were considered in terms of simple statistical measures obtained through data summarization which greatly reduced the processing and observation required to determine whether an inci-dent had occurred. However, this raised issues relating to the time in-terval used for identification of an incident. A brief discussion into statis-tical summaries of Network Telescope data as" good" security metrics is provided. The summaries derived were then used to seek for signs of anomalous network activity. Anomalous activity detected was then rec-onciled by considering incidents that had occurred in the same or simi-lar time interval. Incidents identified included Conficker, Win32. RinBot, DDoS and Norton Netware vulnerabilities. Detection techniques includ-ed identification of rapid growth in packet count, packet size deviations, changes in the composition of the traffic expressed as a ratio of its constituents and changes in the modality of the data. Discussion into the appropriateness of this sort of manual analysis is provided and suggestions towards an automated solution are discussed.
- Full Text:
- Date Issued: 2011
- Authors: Cowie, Bradley , Irwin, Barry V W
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/427971 , vital:72477 , https://www.researchgate.net/profile/Barry-Ir-win/publication/326225071_An_Evaluation_of_Trading_Bands_as_Indicators_for_Network_Telescope_Datasets/links/5b3f231a4585150d2309e1c0/An-Evaluation-of-Trading-Bands-as-Indicators-for-Network-Telescope-Datasets.pdf
- Description: This paper investigates the value of Network Telescope data as a mechanism for network incident discovery by considering data summa-rization, simple heuristic identification and deviations from previously observed traffic distributions. It is important to note that the traffic ob-served is obtained from a Network Telescope and thus does not expe-rience the same fluctuations or vagaries experienced by normal traffic. The datasets used for this analysis were obtained from a Network Tele-scope for the time period August 2005 to September 2009 which had been allocated a Class-C network address block at Rhodes University. The nature of the datasets were considered in terms of simple statistical measures obtained through data summarization which greatly reduced the processing and observation required to determine whether an inci-dent had occurred. However, this raised issues relating to the time in-terval used for identification of an incident. A brief discussion into statis-tical summaries of Network Telescope data as" good" security metrics is provided. The summaries derived were then used to seek for signs of anomalous network activity. Anomalous activity detected was then rec-onciled by considering incidents that had occurred in the same or simi-lar time interval. Incidents identified included Conficker, Win32. RinBot, DDoS and Norton Netware vulnerabilities. Detection techniques includ-ed identification of rapid growth in packet count, packet size deviations, changes in the composition of the traffic expressed as a ratio of its constituents and changes in the modality of the data. Discussion into the appropriateness of this sort of manual analysis is provided and suggestions towards an automated solution are discussed.
- Full Text:
- Date Issued: 2011
A baseline study of youth identity, the media and the public sphere in South Africa:
- Malila, Vanessa, Duncan, Jane, Costera Meijer, Irene, Drok, Nico, Garman, Anthea, Strelitz, Larry N, Steenveld, Lynette N, Bosch, Tanja, Ndlovu, Musa
- Authors: Malila, Vanessa , Duncan, Jane , Costera Meijer, Irene , Drok, Nico , Garman, Anthea , Strelitz, Larry N , Steenveld, Lynette N , Bosch, Tanja , Ndlovu, Musa
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159780 , vital:40343 , https://research.vu.nl/ws/portalfiles/portal/3635364/Baseline+study+single+column+(1).pdf
- Description: The project on youth identity, the media and the public sphere in South Africa was led by Prof Jane Duncan, Highway Africa Chair of Media and Information Society, at Rhodes University in South Africa. The research project was funded by the South Africa Netherlands Research Programme on Alternatives in Development (SANPAD), and partnered in the Netherlands with Prof Irene Costera Meijer (of VU University of Amsterdam) and Prof Nico Drok (of Windesheim University).
- Full Text:
- Date Issued: 2013
- Authors: Malila, Vanessa , Duncan, Jane , Costera Meijer, Irene , Drok, Nico , Garman, Anthea , Strelitz, Larry N , Steenveld, Lynette N , Bosch, Tanja , Ndlovu, Musa
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159780 , vital:40343 , https://research.vu.nl/ws/portalfiles/portal/3635364/Baseline+study+single+column+(1).pdf
- Description: The project on youth identity, the media and the public sphere in South Africa was led by Prof Jane Duncan, Highway Africa Chair of Media and Information Society, at Rhodes University in South Africa. The research project was funded by the South Africa Netherlands Research Programme on Alternatives in Development (SANPAD), and partnered in the Netherlands with Prof Irene Costera Meijer (of VU University of Amsterdam) and Prof Nico Drok (of Windesheim University).
- Full Text:
- Date Issued: 2013
A Bernsteinian analysis of the integration of natural resource management in the curriculum of a rural disadvantaged school
- Authors: Nsubuga, Yvonne
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386415 , vital:68139 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122771"
- Description: Knowledge integration is one of the key principles that underpin curriculum reform in post-apartheid South Africa. One form of teacher support that has been adopted in South Africa is to provide schools throughout the country with samples of pedagogic texts such as curriculum documents and examination exemplars to act as guidelines to teachers as they implement this new curriculum requirement. In the isolated and under-resourced rural schools of South Africa, these texts are the main form of curriculum guidance to teachers. Hence the knowledge integration principles and messages conveyed within these texts are of crucial importance. One contributory factor to the lack of information on knowledge integration at rural underresourced schools is the lack of simple and effective research tools by which to analyse and compare the extent of knowledge integration within pedagogic texts and classroom practices. This article reports on a Bernstein informed analysis that was carried out on three different Grade 10 Life Sciences pedagogic texts in order to assess the extent to which they integrate natural resource management (NRM). The study involved the construction of two indicator frameworks as the research tools with which the analysis was conducted. Results from the analysis showed that although the official Grade 10 Life Sciences pedagogic texts contained very high levels of NRM integration, this was not the case for the Grade 10 Life Sciences text that was produced at the school level. The study provides useful insight into curriculum recontextualisation at a rural under-resourced school through the lens of NRM integration within the Grade 10 Life Sciences pedagogic texts. Such insight has the potential to contribute to better curriculum design and implementation strategies to service schools. This will hopefully help to narrow the gap that currently exists between the official and enacted curricula.
- Full Text:
- Date Issued: 2008
- Authors: Nsubuga, Yvonne
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386415 , vital:68139 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122771"
- Description: Knowledge integration is one of the key principles that underpin curriculum reform in post-apartheid South Africa. One form of teacher support that has been adopted in South Africa is to provide schools throughout the country with samples of pedagogic texts such as curriculum documents and examination exemplars to act as guidelines to teachers as they implement this new curriculum requirement. In the isolated and under-resourced rural schools of South Africa, these texts are the main form of curriculum guidance to teachers. Hence the knowledge integration principles and messages conveyed within these texts are of crucial importance. One contributory factor to the lack of information on knowledge integration at rural underresourced schools is the lack of simple and effective research tools by which to analyse and compare the extent of knowledge integration within pedagogic texts and classroom practices. This article reports on a Bernstein informed analysis that was carried out on three different Grade 10 Life Sciences pedagogic texts in order to assess the extent to which they integrate natural resource management (NRM). The study involved the construction of two indicator frameworks as the research tools with which the analysis was conducted. Results from the analysis showed that although the official Grade 10 Life Sciences pedagogic texts contained very high levels of NRM integration, this was not the case for the Grade 10 Life Sciences text that was produced at the school level. The study provides useful insight into curriculum recontextualisation at a rural under-resourced school through the lens of NRM integration within the Grade 10 Life Sciences pedagogic texts. Such insight has the potential to contribute to better curriculum design and implementation strategies to service schools. This will hopefully help to narrow the gap that currently exists between the official and enacted curricula.
- Full Text:
- Date Issued: 2008
A capability approach: Its potential for transformative education research focusing on education for sustainable development and gender issues in science teacher education
- Authors: Chikunda, Charles
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/387120 , vital:68208 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122266"
- Description: In this article, I use the capability approach to explore the role that the science, mathematics and technical subjects (SMTs) teacher education curriculum can play as a ‘gender conversion factor’. This comes amidst evidence that a major hindrance to the participation of girls in these disciplines is a lack of gender responsiveness in the pedagogy applied in schools. Seven teacher educators, who were purposively sampled at a Technical Teachers’ College in Zimbabwe, were the research participants. I adopted a case study design in which I used in-depth interviews, focus-group discussions and document analysis to generate data. Data was analysed deductively using predetermined themes based on an analytical tool anchored on Sen’s two, but quite distinct, aspects of freedom, that is, the opportunity aspect and the process aspect of freedom. The findings reveal that there is a limited awareness of gender issues among teacher educators, and that these issues are not being transformed into curriculum practice. All in all, it is evident that curriculum practices of SMTs teacher educators are riddled with gender blindness and so trainee teachers graduate from college without the necessary agency to deal with personal, social and environmental conversion factors that can play a role in girls converting the curriculum into functionings (beings and doings) and wider freedoms and valued beings and doings (capabilities).
- Full Text:
- Date Issued: 2013
- Authors: Chikunda, Charles
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/387120 , vital:68208 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122266"
- Description: In this article, I use the capability approach to explore the role that the science, mathematics and technical subjects (SMTs) teacher education curriculum can play as a ‘gender conversion factor’. This comes amidst evidence that a major hindrance to the participation of girls in these disciplines is a lack of gender responsiveness in the pedagogy applied in schools. Seven teacher educators, who were purposively sampled at a Technical Teachers’ College in Zimbabwe, were the research participants. I adopted a case study design in which I used in-depth interviews, focus-group discussions and document analysis to generate data. Data was analysed deductively using predetermined themes based on an analytical tool anchored on Sen’s two, but quite distinct, aspects of freedom, that is, the opportunity aspect and the process aspect of freedom. The findings reveal that there is a limited awareness of gender issues among teacher educators, and that these issues are not being transformed into curriculum practice. All in all, it is evident that curriculum practices of SMTs teacher educators are riddled with gender blindness and so trainee teachers graduate from college without the necessary agency to deal with personal, social and environmental conversion factors that can play a role in girls converting the curriculum into functionings (beings and doings) and wider freedoms and valued beings and doings (capabilities).
- Full Text:
- Date Issued: 2013
A career in photophysicochemical and electrochemical properties of phthalocyanine: A Linstead Career Award paper
- Authors: Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186045 , vital:44458 , xlink:href="https://doi.org/10.1142/S1088424620300037"
- Description: This manuscript highlights the author’s contributions to phthalocyanine chemistry, especially the applications based on their electrochemistry and photophysicochemistry. In particular, the use of phthalocyanines as electrocatalysts and photocatalysts is presented. For photocatalysis, photodynamic antimicrobial chemotherapy and pollution control using green technologies are highlighted. For electrocatalysis the phthalocyanines are employed for the detection of pollutants and environmentally important molecules. Phthalocyanines are combined with nanomaterials for improved photocatalysis and electrocatalysis.
- Full Text:
- Date Issued: 2020
- Authors: Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186045 , vital:44458 , xlink:href="https://doi.org/10.1142/S1088424620300037"
- Description: This manuscript highlights the author’s contributions to phthalocyanine chemistry, especially the applications based on their electrochemistry and photophysicochemistry. In particular, the use of phthalocyanines as electrocatalysts and photocatalysts is presented. For photocatalysis, photodynamic antimicrobial chemotherapy and pollution control using green technologies are highlighted. For electrocatalysis the phthalocyanines are employed for the detection of pollutants and environmentally important molecules. Phthalocyanines are combined with nanomaterials for improved photocatalysis and electrocatalysis.
- Full Text:
- Date Issued: 2020
A case for ethical frameworks to enhance mobile government implementation at South African municipalities
- Makwembere, Sandra, Garidzira, Rufaro
- Authors: Makwembere, Sandra , Garidzira, Rufaro
- Date: 2021
- Subjects: Government Ethics Technology and state Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7170 , vital:53081 , xlink:href="https://doi.org/10.4102/td.v17i1.826"
- Description: Interest in mobile government (m-government) is growing globally. Mobile government refers to the use of wireless and mobile technologies to deliver services to citizens, businesses, employees and other government entities. Presently, technological advancements take place despite questions on whether the existing policy and regulatory frameworks are suitable to regulate the effects of m-government. With m-government, municipal operations take place in virtual spaces where the consequences of such operations are still largely unknown and the frameworks that are apt to minimise any long-term effects on society are yet to be defined. This conceptual article suggests that ethical frameworks should be encouraged as part of mobile government implementation in municipalities to encourage reflective municipal practices and to improve judgement and behaviour in m-government decision-making. It contributes to debates on approaches to comprehensively support and guide mobile government towards positive municipal service delivery outcomes. Keywords: m-government; ethics; ethical frameworks; municipal service delivery; e-government; mobile technology
- Full Text:
- Date Issued: 2021
- Authors: Makwembere, Sandra , Garidzira, Rufaro
- Date: 2021
- Subjects: Government Ethics Technology and state Article
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7170 , vital:53081 , xlink:href="https://doi.org/10.4102/td.v17i1.826"
- Description: Interest in mobile government (m-government) is growing globally. Mobile government refers to the use of wireless and mobile technologies to deliver services to citizens, businesses, employees and other government entities. Presently, technological advancements take place despite questions on whether the existing policy and regulatory frameworks are suitable to regulate the effects of m-government. With m-government, municipal operations take place in virtual spaces where the consequences of such operations are still largely unknown and the frameworks that are apt to minimise any long-term effects on society are yet to be defined. This conceptual article suggests that ethical frameworks should be encouraged as part of mobile government implementation in municipalities to encourage reflective municipal practices and to improve judgement and behaviour in m-government decision-making. It contributes to debates on approaches to comprehensively support and guide mobile government towards positive municipal service delivery outcomes. Keywords: m-government; ethics; ethical frameworks; municipal service delivery; e-government; mobile technology
- Full Text:
- Date Issued: 2021
A case for the adoption of Swahili as a language of early school literacy instruction in Ekegusii-speaking areas of western Kenya:
- Mose, Peter, Kaschula, Russell H
- Authors: Mose, Peter , Kaschula, Russell H
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/174645 , vital:42497 , https://www.njas.fi/njas/article/view/433
- Description: Swahili, a national and official language in Kenya, is in wide use in the country as an inter-ethnic medium of communication and, generally, as a lingua franca. The operative language policy for lower primary–up to grade three–provides for the use of languages of the catchment as languages of instruction. The languages of the catchment refer to the more than 42 indigenous languages spoken in the country. The purpose of this study was to determine and discuss institutional and extra-institutional factors that might favour adoption of Swahili as the best medium–in the current sociolinguistic realities–in the ‘language-of-the-catchment-based’ literacy learning in Ekegusii-speaking areas of western Kenya. Data were obtained through classroom observations, teacher and church leaders’ interviews, observation and analysis of language trends at church worship services, and critical literature review.
- Full Text:
- Date Issued: 2019
- Authors: Mose, Peter , Kaschula, Russell H
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/174645 , vital:42497 , https://www.njas.fi/njas/article/view/433
- Description: Swahili, a national and official language in Kenya, is in wide use in the country as an inter-ethnic medium of communication and, generally, as a lingua franca. The operative language policy for lower primary–up to grade three–provides for the use of languages of the catchment as languages of instruction. The languages of the catchment refer to the more than 42 indigenous languages spoken in the country. The purpose of this study was to determine and discuss institutional and extra-institutional factors that might favour adoption of Swahili as the best medium–in the current sociolinguistic realities–in the ‘language-of-the-catchment-based’ literacy learning in Ekegusii-speaking areas of western Kenya. Data were obtained through classroom observations, teacher and church leaders’ interviews, observation and analysis of language trends at church worship services, and critical literature review.
- Full Text:
- Date Issued: 2019