Bioremediation of trace organic compounds found in precious metals refineries wastewaters: A review of potential options
- Barbosa, V L, Tandlich, Roman, Burgess, Jo E
- Authors: Barbosa, V L , Tandlich, Roman , Burgess, Jo E
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6469 , http://hdl.handle.net/10962/d1005798 , http://dx.doi.org/10.1016/j.chemosphere.2007.01.018 , http://www.sciencedirect.com/science/article/pii/S0045653507001026
- Description: Platinum group metal (PGM) refining processes produce large quantities of wastewater, which is contaminated with the compounds that make up the solvents/extractants mixtures used in the process. These compounds often include solvesso, β-hydroxyxime, amines, amides and methyl isobutyl ketone. A process to clean up PGM refinery wastewaters so that they could be re-used in the refining process would greatly contribute to continual water storage problems and to cost reduction for the industry. Based on the concept that organic compounds that are produced biologically can be destroyed biologically, the use of biological processes for the treatment of organic compounds in other types of waste stream has been favoured in recent years, owing to their low cost and environmental acceptability. This review examines the available biotechnologies and their effectiveness for treating compounds likely to be contained in precious metal extraction process wastewaters. The processes examined include: biofilters, fluidized bed reactors, trickle-bed bioreactors, bioscrubbers, two-phase partitioning bioreactors, membrane bioreactors and activated sludge. Although all processes examined showed adequate to excellent removal of organic compounds from various gaseous and fewer liquid waste streams, there was a variation in their effectiveness. Variations in performance of laboratory-scale biological processes are probably due to the inherent change in the microbial population composition due to selection pressure, environmental conditions and the time allowed for adaptation to the organic compounds. However, if these factors are disregarded, it can be established that activated sludge and membrane bioreactors are the most promising processes for use in the treatment of PGM refinery wastewaters.
- Full Text:
- Date Issued: 2007
- Authors: Barbosa, V L , Tandlich, Roman , Burgess, Jo E
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6469 , http://hdl.handle.net/10962/d1005798 , http://dx.doi.org/10.1016/j.chemosphere.2007.01.018 , http://www.sciencedirect.com/science/article/pii/S0045653507001026
- Description: Platinum group metal (PGM) refining processes produce large quantities of wastewater, which is contaminated with the compounds that make up the solvents/extractants mixtures used in the process. These compounds often include solvesso, β-hydroxyxime, amines, amides and methyl isobutyl ketone. A process to clean up PGM refinery wastewaters so that they could be re-used in the refining process would greatly contribute to continual water storage problems and to cost reduction for the industry. Based on the concept that organic compounds that are produced biologically can be destroyed biologically, the use of biological processes for the treatment of organic compounds in other types of waste stream has been favoured in recent years, owing to their low cost and environmental acceptability. This review examines the available biotechnologies and their effectiveness for treating compounds likely to be contained in precious metal extraction process wastewaters. The processes examined include: biofilters, fluidized bed reactors, trickle-bed bioreactors, bioscrubbers, two-phase partitioning bioreactors, membrane bioreactors and activated sludge. Although all processes examined showed adequate to excellent removal of organic compounds from various gaseous and fewer liquid waste streams, there was a variation in their effectiveness. Variations in performance of laboratory-scale biological processes are probably due to the inherent change in the microbial population composition due to selection pressure, environmental conditions and the time allowed for adaptation to the organic compounds. However, if these factors are disregarded, it can be established that activated sludge and membrane bioreactors are the most promising processes for use in the treatment of PGM refinery wastewaters.
- Full Text:
- Date Issued: 2007
Creative misreadings: allegory in Tracey Rose's Ciao Bella
- Authors: Bateman, Genevieve
- Date: 2007
- Subjects: Rose, Tracey, 1974- Artists -- South Africa Women artists -- South Africa Performance artists -- South Africa Women in art
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2473 , http://hdl.handle.net/10962/d1009506
- Description: This thesis will aim to investigate the extent to which Tracey Rose's Ciao Bella can be said to allegorically perform a dialectical enfolding of the dichotomous categories of meaning/nonmeaning; image/text; past/present and original/translation. The dual concepts of performance and performativity will be utilized as a means to explore the notion of interpretation as a meaning-making process and as an engagement between artist, artwork and viewer that is necessarily open-ended and in a state of constant change and flux. Rose's performance of Ciao Bella will be read as one that questions the illusion of unmediated representation by parodying and creatively misreading a multiplicity of visual, textual and musical representations so as to foreground the politics of representation. The representational figure of allegory, as one that defines itself in opposition to the Romantic conception of the unified symbol, will be put to work so as to reveal the ways in which Rose's performance works to critically undermine various positivistic attitudes toward self-identity, gender, race, politics, history, authorial intention and interpretation.
- Full Text:
- Date Issued: 2007
- Authors: Bateman, Genevieve
- Date: 2007
- Subjects: Rose, Tracey, 1974- Artists -- South Africa Women artists -- South Africa Performance artists -- South Africa Women in art
- Language: English
- Type: Thesis , Masters , MFA
- Identifier: vital:2473 , http://hdl.handle.net/10962/d1009506
- Description: This thesis will aim to investigate the extent to which Tracey Rose's Ciao Bella can be said to allegorically perform a dialectical enfolding of the dichotomous categories of meaning/nonmeaning; image/text; past/present and original/translation. The dual concepts of performance and performativity will be utilized as a means to explore the notion of interpretation as a meaning-making process and as an engagement between artist, artwork and viewer that is necessarily open-ended and in a state of constant change and flux. Rose's performance of Ciao Bella will be read as one that questions the illusion of unmediated representation by parodying and creatively misreading a multiplicity of visual, textual and musical representations so as to foreground the politics of representation. The representational figure of allegory, as one that defines itself in opposition to the Romantic conception of the unified symbol, will be put to work so as to reveal the ways in which Rose's performance works to critically undermine various positivistic attitudes toward self-identity, gender, race, politics, history, authorial intention and interpretation.
- Full Text:
- Date Issued: 2007
'She travels alone and unattended’: the visit to the Eastern Cape of the botanical artist, Marianne North
- Authors: Beard, Margot
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147759 , vital:38668 , https://doi.org/10.1080/00043389.2007.11877077
- Description: The visit of the botanical artist, Marianne North, to South Africa during 1882 to 1883, although frequently referred to, has not received much close attention; nor has her account of the visit, in her ‘Recollections of a happy’ life, been set against the actual conditions she would have encountered. This paper attempts to flesh out at least part of that visit, specifically the weeks she spent in the Eastern Cape Colony and, more particularly, her visits to Port Elizabeth, Grahamstown and Port Alfred. What were these three centres like at the time? Who were the people she mentions? Where did she stay? How do her observations tally with other accounts of the period?.
- Full Text:
- Date Issued: 2017
- Authors: Beard, Margot
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147759 , vital:38668 , https://doi.org/10.1080/00043389.2007.11877077
- Description: The visit of the botanical artist, Marianne North, to South Africa during 1882 to 1883, although frequently referred to, has not received much close attention; nor has her account of the visit, in her ‘Recollections of a happy’ life, been set against the actual conditions she would have encountered. This paper attempts to flesh out at least part of that visit, specifically the weeks she spent in the Eastern Cape Colony and, more particularly, her visits to Port Elizabeth, Grahamstown and Port Alfred. What were these three centres like at the time? Who were the people she mentions? Where did she stay? How do her observations tally with other accounts of the period?.
- Full Text:
- Date Issued: 2017
Dog Latin, Norman Morrissey : book review
- Authors: Beard, Margot
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6115 , http://hdl.handle.net/10962/d1003828
- Description: I have only seen one earlier collection of Morrissey's - his slim volume Seasons (1999). Therein he revealed his enjoyment and interest in haiku. Even the two longer poems in that volume were haiku-like, being brief self-contained stanzas grouped under a single title. His new volume, Dog Latin, consists of sixty short poems primarily concerned with man and nature. A number of these are haiku-like in their brevity ("Edgar on Inclusive Fitness," "Setting Ratbane," "Adam Again"), although they too often do not amount to more than post-it like notes. ("This habit / of holding habits to the wind / -me" is the sum total of the poem "Adam Again.") The epigraph to the whole collection is the final stanza of Robert Frost's "The Need of Being Versed in Country Things," which suggests both Morrissey's interest in the apparently unconsidered minutiae of natural objects and beings, and, it would seem, an admiration of Frost's deceptively plain, unmannered style.
- Full Text:
- Date Issued: 2007
- Authors: Beard, Margot
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6115 , http://hdl.handle.net/10962/d1003828
- Description: I have only seen one earlier collection of Morrissey's - his slim volume Seasons (1999). Therein he revealed his enjoyment and interest in haiku. Even the two longer poems in that volume were haiku-like, being brief self-contained stanzas grouped under a single title. His new volume, Dog Latin, consists of sixty short poems primarily concerned with man and nature. A number of these are haiku-like in their brevity ("Edgar on Inclusive Fitness," "Setting Ratbane," "Adam Again"), although they too often do not amount to more than post-it like notes. ("This habit / of holding habits to the wind / -me" is the sum total of the poem "Adam Again.") The epigraph to the whole collection is the final stanza of Robert Frost's "The Need of Being Versed in Country Things," which suggests both Morrissey's interest in the apparently unconsidered minutiae of natural objects and beings, and, it would seem, an admiration of Frost's deceptively plain, unmannered style.
- Full Text:
- Date Issued: 2007
Lessons from the dead masters: Wordsworth and Byron in J. M. Coetzee's Disgrace
- Authors: Beard, Margot
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6114 , http://hdl.handle.net/10962/d1003827
- Description: As one whose research interests lie in the field of Romanticism, most specifically Wordsworth and Byron, I was obviously intrigued by J. M. Coetzee's use of these poets in Disgrace. Subsequent readings of the work have convinced me that more attention needs to be paid to the deeper implications of their presence in the text. Certainly many scholars have explored the significance of David Lurie's professional interest in the Romantic poets and the novel's imbeddedness in what Jane Taylor has referred to as "the European Enlightenment's legacy of the autonomy of the individual" as well as a specifically "eighteenth century model of philosophical sympathy" (1999, 25). Yet I feel that insufficient attention has been paid to the significance of Romanticism, the Wordsworthian and the Byronic in the novel. Generally, the commentary ranges from seeing Lurie's academic interests as symptomatic of his white colonialist mentality to a more nuanced but insufficiently developed focus on the possibilities lying behind Coetzee's startling juxtaposition of two of the most famed and yet most overtly antagonistic of the Romantic poets. Zoë Wicomb is representative of the first approach. In her estimation, Lurie may be rejected since he "looks to Europe as the centre of reference" and "our feelings and experiences of nature need not be structured by poetic discourses from the metropolis".
- Full Text:
- Date Issued: 2007
- Authors: Beard, Margot
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6114 , http://hdl.handle.net/10962/d1003827
- Description: As one whose research interests lie in the field of Romanticism, most specifically Wordsworth and Byron, I was obviously intrigued by J. M. Coetzee's use of these poets in Disgrace. Subsequent readings of the work have convinced me that more attention needs to be paid to the deeper implications of their presence in the text. Certainly many scholars have explored the significance of David Lurie's professional interest in the Romantic poets and the novel's imbeddedness in what Jane Taylor has referred to as "the European Enlightenment's legacy of the autonomy of the individual" as well as a specifically "eighteenth century model of philosophical sympathy" (1999, 25). Yet I feel that insufficient attention has been paid to the significance of Romanticism, the Wordsworthian and the Byronic in the novel. Generally, the commentary ranges from seeing Lurie's academic interests as symptomatic of his white colonialist mentality to a more nuanced but insufficiently developed focus on the possibilities lying behind Coetzee's startling juxtaposition of two of the most famed and yet most overtly antagonistic of the Romantic poets. Zoë Wicomb is representative of the first approach. In her estimation, Lurie may be rejected since he "looks to Europe as the centre of reference" and "our feelings and experiences of nature need not be structured by poetic discourses from the metropolis".
- Full Text:
- Date Issued: 2007
Tuning the redox properties of metalloporphyrin-and metallophthalocyanine-based molecular electrodes for the highest electrocatalytic activity in the oxidation of thiols
- Bedioui, Fethi, Griveau, Sophie, Nyokong, Tebello, Appleby, A John, Caro, Claudia A, Gulppi, Miguel, Ochoa, Gonzalo, Zagal, José H
- Authors: Bedioui, Fethi , Griveau, Sophie , Nyokong, Tebello , Appleby, A John , Caro, Claudia A , Gulppi, Miguel , Ochoa, Gonzalo , Zagal, José H
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283988 , vital:56009 , xlink:href="https://doi.org/10.1039/B618767F"
- Description: In this work we discuss different approaches for achieving electrodes modified with N4 macrocyclic complexes for the catalysis of the electrochemical oxidation of thiols. These approaches involve adsorption, electropolymerization and molecular anchoring using self assembled monolayers. We also discuss the parameters that determine the reactivity of these complexes. Catalytic activity is associated with the nature of the central metal, redox potentials and Hammett parameters of substituents on the ligand. Correlations between catalytic activity (log i at constant E) and the redox potential of catalysts for complexes of Cr, Mn, Fe, Co, Ni and Cu are linear with an increase of activity for more positive redox potentials. For a great variety complexes bearing the same metal center (Co) correlations between log i and Eo′ of the Co(II)/Co(I) couple have the shape of an unsymmetric volcano. This indicates that the potential of the Co(II)/Co(I) couple can be tuned using the appropiate ligand to achieve maximum catalytic activity. Maximum activity probably corresponds to a ΔG of adsorption of the thiol on the Co center equal to zero, and to a coverage of active sites by the thiol equal to 0.5.
- Full Text:
- Date Issued: 2007
- Authors: Bedioui, Fethi , Griveau, Sophie , Nyokong, Tebello , Appleby, A John , Caro, Claudia A , Gulppi, Miguel , Ochoa, Gonzalo , Zagal, José H
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283988 , vital:56009 , xlink:href="https://doi.org/10.1039/B618767F"
- Description: In this work we discuss different approaches for achieving electrodes modified with N4 macrocyclic complexes for the catalysis of the electrochemical oxidation of thiols. These approaches involve adsorption, electropolymerization and molecular anchoring using self assembled monolayers. We also discuss the parameters that determine the reactivity of these complexes. Catalytic activity is associated with the nature of the central metal, redox potentials and Hammett parameters of substituents on the ligand. Correlations between catalytic activity (log i at constant E) and the redox potential of catalysts for complexes of Cr, Mn, Fe, Co, Ni and Cu are linear with an increase of activity for more positive redox potentials. For a great variety complexes bearing the same metal center (Co) correlations between log i and Eo′ of the Co(II)/Co(I) couple have the shape of an unsymmetric volcano. This indicates that the potential of the Co(II)/Co(I) couple can be tuned using the appropiate ligand to achieve maximum catalytic activity. Maximum activity probably corresponds to a ΔG of adsorption of the thiol on the Co center equal to zero, and to a coverage of active sites by the thiol equal to 0.5.
- Full Text:
- Date Issued: 2007
Improving the service quality of a civil consulting engineering firm through benchmarking
- Authors: Bellingan, Werner
- Date: 2007
- Subjects: Performance -- Measurement , Quality assurance -- Measurement
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8746 , http://hdl.handle.net/10948/743 , Performance -- Measurement , Quality assurance -- Measurement
- Description: The civil engineering industry in South Africa has seen a steady decline in the number of professionals during the last few decades, however it is expected that the government and private sectors are to spend over R200 billion on infrastructure in the next few years. This increases the demand on civil consulting engineering firms to achieve greater productivity, with reduced time and human resources, which has had a profound effect on the quality of service delivered to clients. These firms need to gain a competitive advantage by consistently providing Service Excellence, which is superior to their competitors. One way of achieving this is by benchmarking firms against their competitors. In this research paper the Service Quality and Service Recovery procedures of Company X in Port Elizabeth were benchmarked against its competitors using a customised form of the recognised SERVQUAL research instrument - the SERVPERF questionnaire. The results proved to be invaluable because the survey revealed insightful information which can be used to their strategic benefit. Civil consulting engineering firms need to be aware that Service Excellence is an imperative in the service industry, but do not necessarily have to be perfect. Firms simply need to outperform their competitors to be rated as market leaders. Strategies to improve the Service Quality and Service Recovery of the firm under review are suggested and this work concludes with suggestions for future research projects, which may be beneficial to the researcher, the civil engineering industry and the economy of South Africa.
- Full Text:
- Date Issued: 2007
- Authors: Bellingan, Werner
- Date: 2007
- Subjects: Performance -- Measurement , Quality assurance -- Measurement
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8746 , http://hdl.handle.net/10948/743 , Performance -- Measurement , Quality assurance -- Measurement
- Description: The civil engineering industry in South Africa has seen a steady decline in the number of professionals during the last few decades, however it is expected that the government and private sectors are to spend over R200 billion on infrastructure in the next few years. This increases the demand on civil consulting engineering firms to achieve greater productivity, with reduced time and human resources, which has had a profound effect on the quality of service delivered to clients. These firms need to gain a competitive advantage by consistently providing Service Excellence, which is superior to their competitors. One way of achieving this is by benchmarking firms against their competitors. In this research paper the Service Quality and Service Recovery procedures of Company X in Port Elizabeth were benchmarked against its competitors using a customised form of the recognised SERVQUAL research instrument - the SERVPERF questionnaire. The results proved to be invaluable because the survey revealed insightful information which can be used to their strategic benefit. Civil consulting engineering firms need to be aware that Service Excellence is an imperative in the service industry, but do not necessarily have to be perfect. Firms simply need to outperform their competitors to be rated as market leaders. Strategies to improve the Service Quality and Service Recovery of the firm under review are suggested and this work concludes with suggestions for future research projects, which may be beneficial to the researcher, the civil engineering industry and the economy of South Africa.
- Full Text:
- Date Issued: 2007
More media for Southern Africa?: the place of politics, economics and convergence in developing media density
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147825 , vital:38676 , https://0-doi.org.wam.seals.ac.za/10.1080/02560240485310041
- Description: In line with global trends, media in Southern Africa in the past decade has been moving slowly towards mergers, partnerships and multi-platform publishing. Driven by politics and facilitated by technology, the process has had to confront the difficulty of establishing viable economic models, the lack of regional integration within Southern African countries, and what is sometimes a difficult political environment. Markets remain largely national or local and economically weak. Print media faces huge hurdles. Broadcast media density is improving, partly through noncommercial mechanisms. News websites are understaffed, lacking in viable survival strategies and skills, and are incompletely integrated with parent media platforms. Economic pressures, however, are likely to force Southern African media operations into greater synergies in search of survival. The various convergences entailed may increase media density.
- Full Text:
- Date Issued: 2007
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147825 , vital:38676 , https://0-doi.org.wam.seals.ac.za/10.1080/02560240485310041
- Description: In line with global trends, media in Southern Africa in the past decade has been moving slowly towards mergers, partnerships and multi-platform publishing. Driven by politics and facilitated by technology, the process has had to confront the difficulty of establishing viable economic models, the lack of regional integration within Southern African countries, and what is sometimes a difficult political environment. Markets remain largely national or local and economically weak. Print media faces huge hurdles. Broadcast media density is improving, partly through noncommercial mechanisms. News websites are understaffed, lacking in viable survival strategies and skills, and are incompletely integrated with parent media platforms. Economic pressures, however, are likely to force Southern African media operations into greater synergies in search of survival. The various convergences entailed may increase media density.
- Full Text:
- Date Issued: 2007
Education is a spring … it bubbles:
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159288 , vital:40284 , https://hdl.handle.net/10520/EJC144678
- Description: Asians, Americans, Australians. A handful of Africans and a couple of Arabs. A sprinkling of Canadians, Mexicans, Finns. An Israeli, a Chilean and quite a few others. In total, 450 people from some 50 countries. In common: they're all lecturers and trainers. Busy swopping notes in Singapore at the first-ever World Journalism Education Congress (WJEC) in July. It's a resource-rich pool of ideas and experiences.
- Full Text:
- Date Issued: 2007
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159288 , vital:40284 , https://hdl.handle.net/10520/EJC144678
- Description: Asians, Americans, Australians. A handful of Africans and a couple of Arabs. A sprinkling of Canadians, Mexicans, Finns. An Israeli, a Chilean and quite a few others. In total, 450 people from some 50 countries. In common: they're all lecturers and trainers. Busy swopping notes in Singapore at the first-ever World Journalism Education Congress (WJEC) in July. It's a resource-rich pool of ideas and experiences.
- Full Text:
- Date Issued: 2007
Problematising race for journalists: critical reflections on the South African Human Rights Commission Inquiry into media racism
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147913 , vital:38684 , DOI: 10.1080/02560240185310081
- Description: How journalists report race and racism was at the centre of the South African Human Rights Commission (SAHRC) Inquiry into racism in the media. A critical analysis of the conceptual assumptions in the Inquiry's Final Report, however, reveals serious limitations to the enterprise. In particular the flawed conceptualisations, plus the generalised character of the findings are of little help in assisting the momentum of eradicating racism in South African media, and for linking race transformation to issues of class, gender, sexual orientation and xenophobia. This article identifies the problems as race essentialism and a relativism about what constitutes racism. It argues instead that journalists need the concept of racialisation in order to change their reporting. The argument upholds the desired role of the South African media as one that contributes to a non-racial, as opposed to a multi-racial, society.
- Full Text:
- Date Issued: 2007
- Authors: Berger, Guy
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147913 , vital:38684 , DOI: 10.1080/02560240185310081
- Description: How journalists report race and racism was at the centre of the South African Human Rights Commission (SAHRC) Inquiry into racism in the media. A critical analysis of the conceptual assumptions in the Inquiry's Final Report, however, reveals serious limitations to the enterprise. In particular the flawed conceptualisations, plus the generalised character of the findings are of little help in assisting the momentum of eradicating racism in South African media, and for linking race transformation to issues of class, gender, sexual orientation and xenophobia. This article identifies the problems as race essentialism and a relativism about what constitutes racism. It argues instead that journalists need the concept of racialisation in order to change their reporting. The argument upholds the desired role of the South African media as one that contributes to a non-racial, as opposed to a multi-racial, society.
- Full Text:
- Date Issued: 2007
The role of the euthecosome pteropod, limacina retroversa, in the polar frontal zone, Southern Ocean
- Authors: Bernard, Kim Sarah
- Date: 2007
- Subjects: Pteropoda Limacidae Zooplankton -- Antarctic Ocean Copepoda Phytoplankton
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5761 , http://hdl.handle.net/10962/d1005449
- Description: The aim of the present study was to assess the ecological role of the euthecosome pteropod, Limacina retroversa, in particular, and the mesozooplankton community, in general, in the pelagic ecosystem of the Polar Frontal Zone (PFZ), Southern Ocean. Data were collected from four oceanographic surveys to the Indian sector of the PFZ during austral autumn 2000, 2002, 2004 and 2005. Copepods, mainly Calanus simillimus, Oithona similis, Clausocalanus spp. and Ctenocalanus spp., typically dominated total mesozooplankton counts, accounting for, on average, between 75.5 % and 88.1 % (Mean = 77.4 %; SD = 13.4 %) of the total, during the present investigation. Results of the study indicate that L. retroversa may, at times, contribute substantially to total mesozooplankton abundances. During the study, L. retroversa contributed between 0.0 and 30.0 % (Mean = 5.3 %; SD = 7.1 %) to total mesozooplankton numbers. Significant small-scale variability in abundance and size structure of L. retroversa and abundance of copepods was minimal. Inter-annual variability, on the other hand, was significant between some years. Total pteropod numbers were greatest during April 2002 and 2004, while copepods exhibited greatest abundances during April 2004 only. Pearson’s Correlation analysis suggested that L. retroversa abundances were positively correlated to total surface chlorophyll-a (chl-a) concentrations. The significantly lower chl-a concentrations recorded during April 2005 may explain the reduced pteropod numbers observed during that survey. The size class structure of L. retroversa comprised mainly small and mediumsized individuals during all four surveys. This corresponds well with records from the northern hemisphere (sub-Arctic and Arctic waters) where Limacina spp. are reported to exhibit maximum spawning during mid to late-summer. Higher abundances of large individuals only occurred during April 2005, when chl-a concentrations were very low; possibly the result of delayed spawning, due to reduced food availability. Ingestion rates of the four most abundant copepods, determined using the gut fluorescence technique, ranged between 159.32 ng (pigm) ind⁻¹ day⁻¹ and 728.36 ng (pigm) ind⁻¹ day⁻¹ (Mean = 321.01 ng (pigm) ind⁻¹ day⁻¹; SD = 173.91 ng (pigm) ind⁻¹ day). Ingestion rates of L. retroversa were much higher, ranging from an average of 4 28.68 ng (pigm) ind⁻¹ day⁻¹ in April 2002 to 4 196.88 ng (pigm) ind⁻¹day⁻¹in April 2005 (Mean = 4157.36 ng (pigm) ind⁻¹ day⁻¹; SD = 35.37 ng (pigm) ind⁻¹day⁻¹). Average daily grazing rates for the pteropod varied between 0.39 mg (pigm) m⁻² day⁻¹ in April 2005 and 17.69 mg (pigm) m-2 day-1 in April 2004 (Mean = 6.13 mg (pigm) m⁻² day⁻¹; SD = 11.04 mg (pigm) m⁻² day⁻¹); corresponding average daily grazing impacts ranged between 8.4 % and 139.8 % of the phytoplankton standing stock in April 2005 and 2004, respectively (Mean = 48.5 %; SD = 84.5 %). Average daily grazing rates of the four copepods ranged from 4.58 mg (pigm) m⁻² day⁻¹ to 8.77 mg (pigm) m⁻² day⁻¹ -1, during April 2002 and 2004, respectively (Mean = 6.28 mg (pigm) m⁻² day⁻¹; SD = 5.94 mg (pigm) m⁻² day⁻¹). Collectively, the copepods removed an average of between 31.6 % and 89.8 % of the phytoplankton standing stock per day, during April 2002 and 2004, respectively (Mean = 70.8 %; SD = 86.7 %). The daily grazing impact of the copepods accounted for an average of between 40.4 % and 87.8 % of the total zooplankton grazing impact, during April 2004 and 2005, respectively (Mean = 75.0 %; SD = 65.5 %). L. retroversa was responsible for an average of 52.4 % and 59.5 % of the total zooplankton grazing impact, during April 2002 and 2004, respectively. However, during April 2005, when L. retroversa numbers were significantly lower than previous years, the pteropod contributed an average of only 7.5 % to the total zooplankton grazing impact. Thus, during the present investigation,the pteropod was responsible for removing a mean of 48.9 % of the available phytoplankton (SD = 74.9 %). The predation impact of the dominant carnivorous macrozooplankton and micronekton in the PFZ was determined during April 2004 and 2005 using daily ration estimates obtained from the literature. Additionally, gut content analysis was used to determine the contribution of L. retroversa to the diet of the dominant predators. Average predation impact ranged from 1.1 % and 5.7 % of the total mesozooplankton standing stock during April 2004 and 2005, respectively (Mean = 3.8 %; SD = 12.3 %). Chaetognaths and euphausiids dominated total carnivore numbers and made the greatest contributions to total predation impact during both years. Copepods appeared to be the main prey item of the dominant carnivorous macrozooplankton-micronekton in the region. L. retroversa was only detected in the gut contents of the amphipod, Themisto gaudichaudi, but not in either of the chaetognath species (Eukrohnia hamata and Sagitta gazellae) or the myctophid fish (Electrona spp.). The pteropod was found in 19 % of amphipod guts dissected. Pearson’s Correlation analyses showed that the four major predatory zooplankton groups found in the PFZ (chaetognaths, euphausiids, amphipods and myctophid fish) were positively correlated to abundances of L. retroversa, suggesting that the pteropod might be an important prey item for many of the carnivorous macrozooplankton/micronekton in the PFZ. To conclude, L. retroversa may play an important role in the pelagic ecosystem of the PFZ, in austral autumn. However, ocean acidification and calcium carbonate undersaturation (as a result of increased anthropogenic carbon dioxide emissions), that is predicted to occur within the next 50 – 100 years, will most likely have significant implications for the Sub-Antarctic pelagic ecosystem if L. retroversa cannot adapt quickly enough to the changes.
- Full Text:
- Date Issued: 2007
The role of the euthecosome pteropod, limacina retroversa, in the polar frontal zone, Southern Ocean
- Authors: Bernard, Kim Sarah
- Date: 2007
- Subjects: Pteropoda Limacidae Zooplankton -- Antarctic Ocean Copepoda Phytoplankton
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5761 , http://hdl.handle.net/10962/d1005449
- Description: The aim of the present study was to assess the ecological role of the euthecosome pteropod, Limacina retroversa, in particular, and the mesozooplankton community, in general, in the pelagic ecosystem of the Polar Frontal Zone (PFZ), Southern Ocean. Data were collected from four oceanographic surveys to the Indian sector of the PFZ during austral autumn 2000, 2002, 2004 and 2005. Copepods, mainly Calanus simillimus, Oithona similis, Clausocalanus spp. and Ctenocalanus spp., typically dominated total mesozooplankton counts, accounting for, on average, between 75.5 % and 88.1 % (Mean = 77.4 %; SD = 13.4 %) of the total, during the present investigation. Results of the study indicate that L. retroversa may, at times, contribute substantially to total mesozooplankton abundances. During the study, L. retroversa contributed between 0.0 and 30.0 % (Mean = 5.3 %; SD = 7.1 %) to total mesozooplankton numbers. Significant small-scale variability in abundance and size structure of L. retroversa and abundance of copepods was minimal. Inter-annual variability, on the other hand, was significant between some years. Total pteropod numbers were greatest during April 2002 and 2004, while copepods exhibited greatest abundances during April 2004 only. Pearson’s Correlation analysis suggested that L. retroversa abundances were positively correlated to total surface chlorophyll-a (chl-a) concentrations. The significantly lower chl-a concentrations recorded during April 2005 may explain the reduced pteropod numbers observed during that survey. The size class structure of L. retroversa comprised mainly small and mediumsized individuals during all four surveys. This corresponds well with records from the northern hemisphere (sub-Arctic and Arctic waters) where Limacina spp. are reported to exhibit maximum spawning during mid to late-summer. Higher abundances of large individuals only occurred during April 2005, when chl-a concentrations were very low; possibly the result of delayed spawning, due to reduced food availability. Ingestion rates of the four most abundant copepods, determined using the gut fluorescence technique, ranged between 159.32 ng (pigm) ind⁻¹ day⁻¹ and 728.36 ng (pigm) ind⁻¹ day⁻¹ (Mean = 321.01 ng (pigm) ind⁻¹ day⁻¹; SD = 173.91 ng (pigm) ind⁻¹ day). Ingestion rates of L. retroversa were much higher, ranging from an average of 4 28.68 ng (pigm) ind⁻¹ day⁻¹ in April 2002 to 4 196.88 ng (pigm) ind⁻¹day⁻¹in April 2005 (Mean = 4157.36 ng (pigm) ind⁻¹ day⁻¹; SD = 35.37 ng (pigm) ind⁻¹day⁻¹). Average daily grazing rates for the pteropod varied between 0.39 mg (pigm) m⁻² day⁻¹ in April 2005 and 17.69 mg (pigm) m-2 day-1 in April 2004 (Mean = 6.13 mg (pigm) m⁻² day⁻¹; SD = 11.04 mg (pigm) m⁻² day⁻¹); corresponding average daily grazing impacts ranged between 8.4 % and 139.8 % of the phytoplankton standing stock in April 2005 and 2004, respectively (Mean = 48.5 %; SD = 84.5 %). Average daily grazing rates of the four copepods ranged from 4.58 mg (pigm) m⁻² day⁻¹ to 8.77 mg (pigm) m⁻² day⁻¹ -1, during April 2002 and 2004, respectively (Mean = 6.28 mg (pigm) m⁻² day⁻¹; SD = 5.94 mg (pigm) m⁻² day⁻¹). Collectively, the copepods removed an average of between 31.6 % and 89.8 % of the phytoplankton standing stock per day, during April 2002 and 2004, respectively (Mean = 70.8 %; SD = 86.7 %). The daily grazing impact of the copepods accounted for an average of between 40.4 % and 87.8 % of the total zooplankton grazing impact, during April 2004 and 2005, respectively (Mean = 75.0 %; SD = 65.5 %). L. retroversa was responsible for an average of 52.4 % and 59.5 % of the total zooplankton grazing impact, during April 2002 and 2004, respectively. However, during April 2005, when L. retroversa numbers were significantly lower than previous years, the pteropod contributed an average of only 7.5 % to the total zooplankton grazing impact. Thus, during the present investigation,the pteropod was responsible for removing a mean of 48.9 % of the available phytoplankton (SD = 74.9 %). The predation impact of the dominant carnivorous macrozooplankton and micronekton in the PFZ was determined during April 2004 and 2005 using daily ration estimates obtained from the literature. Additionally, gut content analysis was used to determine the contribution of L. retroversa to the diet of the dominant predators. Average predation impact ranged from 1.1 % and 5.7 % of the total mesozooplankton standing stock during April 2004 and 2005, respectively (Mean = 3.8 %; SD = 12.3 %). Chaetognaths and euphausiids dominated total carnivore numbers and made the greatest contributions to total predation impact during both years. Copepods appeared to be the main prey item of the dominant carnivorous macrozooplankton-micronekton in the region. L. retroversa was only detected in the gut contents of the amphipod, Themisto gaudichaudi, but not in either of the chaetognath species (Eukrohnia hamata and Sagitta gazellae) or the myctophid fish (Electrona spp.). The pteropod was found in 19 % of amphipod guts dissected. Pearson’s Correlation analyses showed that the four major predatory zooplankton groups found in the PFZ (chaetognaths, euphausiids, amphipods and myctophid fish) were positively correlated to abundances of L. retroversa, suggesting that the pteropod might be an important prey item for many of the carnivorous macrozooplankton/micronekton in the PFZ. To conclude, L. retroversa may play an important role in the pelagic ecosystem of the PFZ, in austral autumn. However, ocean acidification and calcium carbonate undersaturation (as a result of increased anthropogenic carbon dioxide emissions), that is predicted to occur within the next 50 – 100 years, will most likely have significant implications for the Sub-Antarctic pelagic ecosystem if L. retroversa cannot adapt quickly enough to the changes.
- Full Text:
- Date Issued: 2007
An investigation into the popularity of Zimbabwe's first health communication soap opera, Studio 263 : a qualitative reception study of Bulawayo students aged between 15 and 20 years
- Authors: Bhebhe-Mpofu, Adilaid
- Date: 2007 , 2014-08-18
- Subjects: Studio 263 (Television program) , Television soap operas -- Zimbabwe , Television viewers -- Zimbabwe , Mass media and children -- Zimbabwe , Television and children -- Zimbabwe , AIDS (Disease) -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3531 , http://hdl.handle.net/10962/d1013310
- Description: Within the context of debates concerning the reception and interpretation of media texts by television audiences, this qualitative reception study explores how a sample of Bulawayo students negotiate meanings from Zimbabwe's first health communication soap opera, Studio 263. The study thus examines the reasons behind the popularity of this programme with this target audience. The findings of the study reveal that meaning making is a complex process that is dependent on a variety of factors which include, among others, the socio-cultural context of media consumption, gender, economic disposition and age. It particularly maintains that gender and lived realities influence the interpretation and negotiation of meanings in this particular study. , Adobe Acrobat Pro 11.0.0 Paper Capture Plug-in
- Full Text:
- Date Issued: 2007
- Authors: Bhebhe-Mpofu, Adilaid
- Date: 2007 , 2014-08-18
- Subjects: Studio 263 (Television program) , Television soap operas -- Zimbabwe , Television viewers -- Zimbabwe , Mass media and children -- Zimbabwe , Television and children -- Zimbabwe , AIDS (Disease) -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3531 , http://hdl.handle.net/10962/d1013310
- Description: Within the context of debates concerning the reception and interpretation of media texts by television audiences, this qualitative reception study explores how a sample of Bulawayo students negotiate meanings from Zimbabwe's first health communication soap opera, Studio 263. The study thus examines the reasons behind the popularity of this programme with this target audience. The findings of the study reveal that meaning making is a complex process that is dependent on a variety of factors which include, among others, the socio-cultural context of media consumption, gender, economic disposition and age. It particularly maintains that gender and lived realities influence the interpretation and negotiation of meanings in this particular study. , Adobe Acrobat Pro 11.0.0 Paper Capture Plug-in
- Full Text:
- Date Issued: 2007
Towards continental transformation: understanding sustainable peace agreements in Africa
- Authors: Bischoff, Paul, 1954-
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/161409 , vital:40624 , https://0-hdl.handle.net.wam.seals.ac.za/10520/EJC15983
- Description: There are social and political questions to be asked about the new continent-wide institutions in and around what is still a young African Union (AU). These include questions such as whether the AU and its institutions can be built in ways that will allow this body to transform Africa's international relations, and how this is to be done. What are the norms and values that will inform this change and the African renewal promoted by the AU? Is the multilateral architecture of the AU able to encourage democracy and people-centredness, for instance? Will it, in the end, be able to deliver on the hoped-for "pan-African transnational democratic revolution"?.
- Full Text:
- Date Issued: 2007
- Authors: Bischoff, Paul, 1954-
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/161409 , vital:40624 , https://0-hdl.handle.net.wam.seals.ac.za/10520/EJC15983
- Description: There are social and political questions to be asked about the new continent-wide institutions in and around what is still a young African Union (AU). These include questions such as whether the AU and its institutions can be built in ways that will allow this body to transform Africa's international relations, and how this is to be done. What are the norms and values that will inform this change and the African renewal promoted by the AU? Is the multilateral architecture of the AU able to encourage democracy and people-centredness, for instance? Will it, in the end, be able to deliver on the hoped-for "pan-African transnational democratic revolution"?.
- Full Text:
- Date Issued: 2007
Transcending state-centrism: new regionalism and the future of Southern African regional integration
- Authors: Blaauw, Lesley
- Date: 2007
- Subjects: Southern African Development Community Southern African Customs Union Southern African Development Coordination Conference Regionalism -- Africa, Southern Africa, Southern -- Economic integration
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2761 , http://hdl.handle.net/10962/d1002971
- Description: This dissertation argues that in the 1990s and beyond, the character and functions of regions and regionalism have experienced a major transformation. This requires a reconceptualisation of regions and regionalism that transcends state-centrism. The argument here is that the definition of regions and regionalism needs to recognise that other actors also participate in the construction of regions and the practise of regionalism. Up to now, however, theories of integration incompletely deal with outcomes appropriate to developing countries, states and regions. In the context where people remain vulnerable to top-down forms of regionalism driven by the forces of globalisation, this calls for a new approach in the analytical study of regionalism in a transnational context. The contention is that new regionalism, and its variant, developmental regionalism pay attention to the role those organised civil society actors and those marginalised by both globalisation and regionalisation play in promoting regionalism in a transnational context. Historically, state-centric regionalism in southern Africa was not aimed at achieving developmental objectives. In the case of SACU, the argument is that South Africa used its economic strength in a hegemonial way. To counter-act apartheid South Africa’s economic hegemony, SADCC was formed. SADCC achieved limited success in the fields of infrastructural development and in attracting donor aid. The end of the Cold War and the downfall of apartheid compelled these organisations to recast their objectives and purpose. For SACU this meant changing from an organisation dominated by South Africa to a fully-fledged inter-state one. Disconcertedly, however, about the reforms undertook by SACU, is that the disposition of member states remain important in determining the content and scope of regionalism. SADC, on the other hand, has also not sufficiently reform itself to achieve the ambitious goals it set-out for itself. Moreover, while SADC has since its inception in 1992 set-out to involve non-state actors in its regional integration efforts, limited institutional reform in 2000 and beyond, and elites at the forefront of institutional restructuring make it difficult for non-state actors to contribute to sustainable regional integration. In conclusion, this dissertation maintains that sustainable regionalist orders are best built by recognising that beyond the geometry of state-sovereignty, civil society organisations with a regional focus and the ordinary people of the region also contribute to regioness and as such to the re-conceptualisation of regional community in southern Africa.
- Full Text:
- Date Issued: 2007
Transcending state-centrism: new regionalism and the future of Southern African regional integration
- Authors: Blaauw, Lesley
- Date: 2007
- Subjects: Southern African Development Community Southern African Customs Union Southern African Development Coordination Conference Regionalism -- Africa, Southern Africa, Southern -- Economic integration
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2761 , http://hdl.handle.net/10962/d1002971
- Description: This dissertation argues that in the 1990s and beyond, the character and functions of regions and regionalism have experienced a major transformation. This requires a reconceptualisation of regions and regionalism that transcends state-centrism. The argument here is that the definition of regions and regionalism needs to recognise that other actors also participate in the construction of regions and the practise of regionalism. Up to now, however, theories of integration incompletely deal with outcomes appropriate to developing countries, states and regions. In the context where people remain vulnerable to top-down forms of regionalism driven by the forces of globalisation, this calls for a new approach in the analytical study of regionalism in a transnational context. The contention is that new regionalism, and its variant, developmental regionalism pay attention to the role those organised civil society actors and those marginalised by both globalisation and regionalisation play in promoting regionalism in a transnational context. Historically, state-centric regionalism in southern Africa was not aimed at achieving developmental objectives. In the case of SACU, the argument is that South Africa used its economic strength in a hegemonial way. To counter-act apartheid South Africa’s economic hegemony, SADCC was formed. SADCC achieved limited success in the fields of infrastructural development and in attracting donor aid. The end of the Cold War and the downfall of apartheid compelled these organisations to recast their objectives and purpose. For SACU this meant changing from an organisation dominated by South Africa to a fully-fledged inter-state one. Disconcertedly, however, about the reforms undertook by SACU, is that the disposition of member states remain important in determining the content and scope of regionalism. SADC, on the other hand, has also not sufficiently reform itself to achieve the ambitious goals it set-out for itself. Moreover, while SADC has since its inception in 1992 set-out to involve non-state actors in its regional integration efforts, limited institutional reform in 2000 and beyond, and elites at the forefront of institutional restructuring make it difficult for non-state actors to contribute to sustainable regional integration. In conclusion, this dissertation maintains that sustainable regionalist orders are best built by recognising that beyond the geometry of state-sovereignty, civil society organisations with a regional focus and the ordinary people of the region also contribute to regioness and as such to the re-conceptualisation of regional community in southern Africa.
- Full Text:
- Date Issued: 2007
Report of the multidisciplinary investigation of differentiation and potential hybridisation between two Yellowfish species Labeobarbus Kimberleyensis and L. Aeneus from the Orange-Vaal system
- Bloomer, Paulette, Villet, Martin H, Bills, Ian R, Van der Bank, F Herman, Jones, Nick, Walsh, Gina
- Authors: Bloomer, Paulette , Villet, Martin H , Bills, Ian R , Van der Bank, F Herman , Jones, Nick , Walsh, Gina
- Date: 2007
- Language: English
- Type: Report
- Identifier: vital:7162 , http://hdl.handle.net/10962/d1011937
- Description: From the executive summary]: The relationships within and between two yellowfish species, Labeobarbus aeneus (smallmouth yellowfish) and L. kimberleyensis (largemouth yellowfish) from the Orange-Vaal system were investigated through three independently conducted studies of the same material collected from the Sak River (the type locality of L. aeneus), the upper Orange River at Aliwal North and the lower Orange River at Pella and Onseepkans.
- Full Text:
- Date Issued: 2007
- Authors: Bloomer, Paulette , Villet, Martin H , Bills, Ian R , Van der Bank, F Herman , Jones, Nick , Walsh, Gina
- Date: 2007
- Language: English
- Type: Report
- Identifier: vital:7162 , http://hdl.handle.net/10962/d1011937
- Description: From the executive summary]: The relationships within and between two yellowfish species, Labeobarbus aeneus (smallmouth yellowfish) and L. kimberleyensis (largemouth yellowfish) from the Orange-Vaal system were investigated through three independently conducted studies of the same material collected from the Sak River (the type locality of L. aeneus), the upper Orange River at Aliwal North and the lower Orange River at Pella and Onseepkans.
- Full Text:
- Date Issued: 2007
Continuous auditing technologies and models
- Authors: Blundell, Adrian Wesley
- Date: 2007
- Subjects: Auditing , Auditing -- Data processing
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9798 , http://hdl.handle.net/10948/476 , http://hdl.handle.net/10948/d1011922 , Auditing , Auditing -- Data processing
- Description: Continuous auditing is not a totally new concept, but it has not been widely implemented, and has existed mostly as a point of debate amongst the auditing fraternity. This may soon change, as continuous auditing has become a topic of great interest, especially in the last decade. This may be due to a combination of reasons. In the last decade, much of the confidence in auditors’ reports was lost due to corporate governance scandals. This also brought about a greater desire for faster, more reliable reporting on which to base decisions. This desire has been transposed into regulations such as the Sarbanes-Oxley act in the United States, which encourages real-time auditing activities, which would benefit from continuous auditing. A second, possible contributing factor to the heightened interest in continuous auditing is that much of the requisite technology has matured to a point where it can be successfully used to implement continuous auditing. It is the technologies which form the focus of this research. It is therefore, the primary objective of this research to investigate and identify the essential technologies, and identify and define their roles within a continuous auditing solution. To explore this area, three models of continuous auditing are compared according to the roles of the technologies within them. The roots of some auditing technologies which can be adapted to the paradigm of continuous auditing are explored, as well as new technologies, such as XML-based reporting languages. In order to fully explore these technologies, the concepts of data integrity and data quality are first defined and discussed, and some security measures which contribute to integrity are identified. An obstacle to implementing a continuous model is that even with the newly available technologies, the multitudes of systems which are used in organisations, produce data in a plethora of data formats. In performing an audit the continuous auditing system needs to first gather this data and then needs to be able to compare “apples with apples”. Therefore, the technologies which can be used to acquire and standardise the data are identified.
- Full Text:
- Date Issued: 2007
- Authors: Blundell, Adrian Wesley
- Date: 2007
- Subjects: Auditing , Auditing -- Data processing
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9798 , http://hdl.handle.net/10948/476 , http://hdl.handle.net/10948/d1011922 , Auditing , Auditing -- Data processing
- Description: Continuous auditing is not a totally new concept, but it has not been widely implemented, and has existed mostly as a point of debate amongst the auditing fraternity. This may soon change, as continuous auditing has become a topic of great interest, especially in the last decade. This may be due to a combination of reasons. In the last decade, much of the confidence in auditors’ reports was lost due to corporate governance scandals. This also brought about a greater desire for faster, more reliable reporting on which to base decisions. This desire has been transposed into regulations such as the Sarbanes-Oxley act in the United States, which encourages real-time auditing activities, which would benefit from continuous auditing. A second, possible contributing factor to the heightened interest in continuous auditing is that much of the requisite technology has matured to a point where it can be successfully used to implement continuous auditing. It is the technologies which form the focus of this research. It is therefore, the primary objective of this research to investigate and identify the essential technologies, and identify and define their roles within a continuous auditing solution. To explore this area, three models of continuous auditing are compared according to the roles of the technologies within them. The roots of some auditing technologies which can be adapted to the paradigm of continuous auditing are explored, as well as new technologies, such as XML-based reporting languages. In order to fully explore these technologies, the concepts of data integrity and data quality are first defined and discussed, and some security measures which contribute to integrity are identified. An obstacle to implementing a continuous model is that even with the newly available technologies, the multitudes of systems which are used in organisations, produce data in a plethora of data formats. In performing an audit the continuous auditing system needs to first gather this data and then needs to be able to compare “apples with apples”. Therefore, the technologies which can be used to acquire and standardise the data are identified.
- Full Text:
- Date Issued: 2007
Cultural values and leadership styles of middle level managers in a private sector hospitals in the Eastern Cape
- Authors: Boguslavsky, Marianna
- Date: 2007
- Subjects: Hospitals, Proprietary -- South Africa -- Eastern Cape , Leadership -- South Africa -- Eastern Cape , Middle managers -- South Africa -- Eastern Cape , Corporate culture -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:10080 , http://hdl.handle.net/10948/478 , http://hdl.handle.net/10948/d1011927 , Hospitals, Proprietary -- South Africa -- Eastern Cape , Leadership -- South Africa -- Eastern Cape , Middle managers -- South Africa -- Eastern Cape , Corporate culture -- South Africa -- Eastern Cape
- Description: In recent years, South Africa has seen increasing cultural diversification with regard to the appointment of managers in private healthcare facilities. However, research conducted in this area remains extremely limited. The aim of the present study was to explore and describe cultural values and leadership styles of middle managers at a private sector hospital in the Eastern Cape. Hofstede’s (1980, a ) model of cultural values served as a theoretical framework to conceptualise this study. The study was qualitative in nature and made use of in-depth research interviews conducted with a diverse sample of middle managers. The researcher made use of homogeneous and convenience sampling and utilised five participants. The qualitative data was analysed using Tesch’s (1990, in De Vos, 2002) method of analysis. Results revealed that despite the differences in personal culture, most of the managers are similar in their leadership styles and are also affected by the organizational culture. The results of the study contribute to a better understanding of the influence of cultural values and leadership styles in South Africa and will thereby benefit health institutions in their dealings with their modern day multi-cultural management staff.
- Full Text:
- Date Issued: 2007
- Authors: Boguslavsky, Marianna
- Date: 2007
- Subjects: Hospitals, Proprietary -- South Africa -- Eastern Cape , Leadership -- South Africa -- Eastern Cape , Middle managers -- South Africa -- Eastern Cape , Corporate culture -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:10080 , http://hdl.handle.net/10948/478 , http://hdl.handle.net/10948/d1011927 , Hospitals, Proprietary -- South Africa -- Eastern Cape , Leadership -- South Africa -- Eastern Cape , Middle managers -- South Africa -- Eastern Cape , Corporate culture -- South Africa -- Eastern Cape
- Description: In recent years, South Africa has seen increasing cultural diversification with regard to the appointment of managers in private healthcare facilities. However, research conducted in this area remains extremely limited. The aim of the present study was to explore and describe cultural values and leadership styles of middle managers at a private sector hospital in the Eastern Cape. Hofstede’s (1980, a ) model of cultural values served as a theoretical framework to conceptualise this study. The study was qualitative in nature and made use of in-depth research interviews conducted with a diverse sample of middle managers. The researcher made use of homogeneous and convenience sampling and utilised five participants. The qualitative data was analysed using Tesch’s (1990, in De Vos, 2002) method of analysis. Results revealed that despite the differences in personal culture, most of the managers are similar in their leadership styles and are also affected by the organizational culture. The results of the study contribute to a better understanding of the influence of cultural values and leadership styles in South Africa and will thereby benefit health institutions in their dealings with their modern day multi-cultural management staff.
- Full Text:
- Date Issued: 2007
Nesting success and survival rates of suburban Olive Thrushes (Turdus olivaceus olivaceus).
- Authors: Bonnevie, Bo T
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/448299 , vital:74720 , https://doi.org/10.2989/OSTRICH.2007.78.2.19.99
- Description: Adult survival rates of suburban Olive Thrushes (Turdus olivaceus) were estimated from the proportion of adults and juveniles in mist-net samples from the Eastern Cape and Western Cape provinces of South Africa. These survival rates were compared to an estimate from recovery data. Reproductive rate, clutch size, nesting success and survival rate of dependent fledglings were estimated from breeding records in the Eastern Cape. These data were used to estimate survival rate of independent fledglings. The estimated adult survival rate in this region was high and the clutch size was small, compared to those of the Blackbird (Turdus merula) in Europe. Dispersal patterns from recapture and recovery data, and the relatively low survival rates of juvenile birds, suggest that fledglings are most vulnerable when they reach independence and leave their natal territories.
- Full Text:
- Date Issued: 2007
- Authors: Bonnevie, Bo T
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/448299 , vital:74720 , https://doi.org/10.2989/OSTRICH.2007.78.2.19.99
- Description: Adult survival rates of suburban Olive Thrushes (Turdus olivaceus) were estimated from the proportion of adults and juveniles in mist-net samples from the Eastern Cape and Western Cape provinces of South Africa. These survival rates were compared to an estimate from recovery data. Reproductive rate, clutch size, nesting success and survival rate of dependent fledglings were estimated from breeding records in the Eastern Cape. These data were used to estimate survival rate of independent fledglings. The estimated adult survival rate in this region was high and the clutch size was small, compared to those of the Blackbird (Turdus merula) in Europe. Dispersal patterns from recapture and recovery data, and the relatively low survival rates of juvenile birds, suggest that fledglings are most vulnerable when they reach independence and leave their natal territories.
- Full Text:
- Date Issued: 2007
Rhenium(V)-Imido complexes with potentially multidentate ligands containing the amino group
- Authors: Booysen, Irvin Noel
- Date: 2007
- Subjects: Rhenium , Ligands
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10385 , http://hdl.handle.net/10948/479 , Rhenium , Ligands
- Description: The complex trans-[Re(dab)Cl3(PPh3)2] (H2dab=1,2-diaminobenzene) was prepared from the reaction of trans-[ReOCl3(PPh3)2] with H2dab in ethanol. The ligand dab is coordinated to the rhenium(V) centre through a dianionic imido nitrogen only, in a distorted octahedral coordination geometry around the metal ion. The complex trans-[Re(ada)Cl3(PPh3)2] (H2ada=2-aminodiphenylamine) was prepared from the reaction of trans-[ReOCl3(PPh3)2] with H2ada in acetonitrile. The ligand ada is coordinated to the rhenium(V) centre through a dianionic imido nitrogen only, in a distorted octahedral coordination geometry around the metal ion. Surprisingly, the Re-Cl bond length trans to the Re=N bond is shorter than the two equatorial Re-Cl bond lengths. The reaction of equimolar quantities of cis-[ReO2I(PPh3)2] with 5,6-diamino-1,3- dimethyluracil (H2ddd) in acetonitrile led to the formation of [Re(ddd)(Hddd)I(PPh3)2](ReO4). The X-ray crystal structure shows that the ligand ddd is coordinated monodentately through the doubly deprotonated amino nitrogen and is therefore present as an imide. The chelate Hddd is coordinated bidentately via the neutral amino nitrogen, which is coordinated trans to the imido nitrogen, and the singly deprotonated amido nitrogen, trans to the iodide. The reaction of equimolar quantities of [NH4(ReO4)] with H2ddd in methanol under reflux conditions led to the isolation of [C12H12N6O4] as only product. The [ReO4]- ion is therefore instrumental in the formation of [C12H12N6O4], and since the product contains no rhenium in any oxidation state, the conclusion is that [ReO4]- catalyses the oxidative deamination of H2ddd. The X-ray crystal structure consists of two centrosymmetric, tricyclic rings, comprising a central pyrazine ring and two terminal pyrimidine rings. The reaction of a twofold molar excess of H2apb (H2apb=2-(2-aminophenyl)-1Hbenzimidazole) with trans-[ReO2(py)4]Cl in ethanol gave the green product of the formulation [ReO(Hapb)(apb)] in good yield. The rhenium atom lies in a distorted trigonal-bipyramidal environment. The two imidazole N(2) atoms lie in the apical positions trans to each other, with the oxo-oxygen and two amido N(1) atoms in the trigonal plane. The complex has C2-symmetry. The two amino groups are singly deprotonated and provide a negative charge each, so that they are coordinated as amides. The oxo group provides two negative charges. In order to obtain electroneutrality for the rhenium(V) complex, the two coordinated imidazole nitrogens provide one negative charge. The complex salt trans-[Re(mps)Cl(PPh3)2](ReO4) (H3mps=N-(2-amino-3- methylphenyl)salicylideneimine) was prepared by the reaction of trans- [ReOCl3(PPh3)2] with a twofold molar excess of H3mps. The X-ray crystal structure shows that the trianionic ligand mps acts as a tridentate chelate via the doubly deprotonated amino nitrogen (which is present in trans- [Re(mps)Cl(PPh3)2](ReO4) as an imide), the neutral imino nitrogen and the deprotonated phenolic oxygen. The [ReO4]- anion has approximately regular tetrahedral geometry. Two significant hydrogen bonds are formed between two of the perrhenyl oxygens and the water of crystallization. The six-coordinated complex cis-[Re(mps)Cl2(PPh3)2] was prepared by the reaction of trans-[ReOCl3(PPh3)2] with a twofold molar excess of H3mps in benzene. The Xray crystal structure shows that the mps ligand coordinates as a tridentate chelate via the doubly deprotonated 2-amino nitrogen, the neutral imino nitrogen and the phenolate oxygen. The imide and phenolate oxygen coordinate trans to each other in a distorted octahedral geometry around the rhenium(V) centre, with the two chlorides in cis positions.
- Full Text:
- Date Issued: 2007
- Authors: Booysen, Irvin Noel
- Date: 2007
- Subjects: Rhenium , Ligands
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10385 , http://hdl.handle.net/10948/479 , Rhenium , Ligands
- Description: The complex trans-[Re(dab)Cl3(PPh3)2] (H2dab=1,2-diaminobenzene) was prepared from the reaction of trans-[ReOCl3(PPh3)2] with H2dab in ethanol. The ligand dab is coordinated to the rhenium(V) centre through a dianionic imido nitrogen only, in a distorted octahedral coordination geometry around the metal ion. The complex trans-[Re(ada)Cl3(PPh3)2] (H2ada=2-aminodiphenylamine) was prepared from the reaction of trans-[ReOCl3(PPh3)2] with H2ada in acetonitrile. The ligand ada is coordinated to the rhenium(V) centre through a dianionic imido nitrogen only, in a distorted octahedral coordination geometry around the metal ion. Surprisingly, the Re-Cl bond length trans to the Re=N bond is shorter than the two equatorial Re-Cl bond lengths. The reaction of equimolar quantities of cis-[ReO2I(PPh3)2] with 5,6-diamino-1,3- dimethyluracil (H2ddd) in acetonitrile led to the formation of [Re(ddd)(Hddd)I(PPh3)2](ReO4). The X-ray crystal structure shows that the ligand ddd is coordinated monodentately through the doubly deprotonated amino nitrogen and is therefore present as an imide. The chelate Hddd is coordinated bidentately via the neutral amino nitrogen, which is coordinated trans to the imido nitrogen, and the singly deprotonated amido nitrogen, trans to the iodide. The reaction of equimolar quantities of [NH4(ReO4)] with H2ddd in methanol under reflux conditions led to the isolation of [C12H12N6O4] as only product. The [ReO4]- ion is therefore instrumental in the formation of [C12H12N6O4], and since the product contains no rhenium in any oxidation state, the conclusion is that [ReO4]- catalyses the oxidative deamination of H2ddd. The X-ray crystal structure consists of two centrosymmetric, tricyclic rings, comprising a central pyrazine ring and two terminal pyrimidine rings. The reaction of a twofold molar excess of H2apb (H2apb=2-(2-aminophenyl)-1Hbenzimidazole) with trans-[ReO2(py)4]Cl in ethanol gave the green product of the formulation [ReO(Hapb)(apb)] in good yield. The rhenium atom lies in a distorted trigonal-bipyramidal environment. The two imidazole N(2) atoms lie in the apical positions trans to each other, with the oxo-oxygen and two amido N(1) atoms in the trigonal plane. The complex has C2-symmetry. The two amino groups are singly deprotonated and provide a negative charge each, so that they are coordinated as amides. The oxo group provides two negative charges. In order to obtain electroneutrality for the rhenium(V) complex, the two coordinated imidazole nitrogens provide one negative charge. The complex salt trans-[Re(mps)Cl(PPh3)2](ReO4) (H3mps=N-(2-amino-3- methylphenyl)salicylideneimine) was prepared by the reaction of trans- [ReOCl3(PPh3)2] with a twofold molar excess of H3mps. The X-ray crystal structure shows that the trianionic ligand mps acts as a tridentate chelate via the doubly deprotonated amino nitrogen (which is present in trans- [Re(mps)Cl(PPh3)2](ReO4) as an imide), the neutral imino nitrogen and the deprotonated phenolic oxygen. The [ReO4]- anion has approximately regular tetrahedral geometry. Two significant hydrogen bonds are formed between two of the perrhenyl oxygens and the water of crystallization. The six-coordinated complex cis-[Re(mps)Cl2(PPh3)2] was prepared by the reaction of trans-[ReOCl3(PPh3)2] with a twofold molar excess of H3mps in benzene. The Xray crystal structure shows that the mps ligand coordinates as a tridentate chelate via the doubly deprotonated 2-amino nitrogen, the neutral imino nitrogen and the phenolate oxygen. The imide and phenolate oxygen coordinate trans to each other in a distorted octahedral geometry around the rhenium(V) centre, with the two chlorides in cis positions.
- Full Text:
- Date Issued: 2007
Reproductive co-existence among five sympatric single-stemmed aloes in the Gamtoos River Valley, Eastern Cape
- Authors: Botes, Christo
- Date: 2007
- Subjects: Aloe -- South Africa -- Gamtoos River Valley , Aloe -- South Africa -- Identification
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10628 , http://hdl.handle.net/10948/481 , Aloe -- South Africa -- Gamtoos River Valley , Aloe -- South Africa -- Identification
- Description: In this study I documented the convergence of five congeneric bird-pollinated plants (Aloe pluridens, A. lineata var. muirii, A. speciosa, A. africana, and A. ferox) into three functional groups based on size, shape, and the arrangements of flowers on the inflorescence, but also nectar rewards, pollen deposition sites on the bird-pollinators, and the degree to which bees play a role in their pollination. Individuals of similar functional groups were divergent in their peak flowering times and limited their degree of flowering overlap further by spatial aggregation and niche separation, within the Thicket of the Gamtoos River Valley. The nectar properties were especially useful in structuring the bird pollinator community, which resulted in greater ethological isolation and hence, greater reproductive assurance in the mixed co-flowering plant communities. Choice array experiments revealed that it was the fine scale aggregation of flowering individuals that ensured that bird-pollinators feed selectively, since when equal choice was available, interspecific visitation increased significantly compared to natural scenarios. Bird behaviour and the ecological intermediateness of one to the species explained its prominence in hybrid combinations. The spatial occurrence of hybrid individuals can be traced back to the energetics of foraging and its influence on bird floral constancy. The pollination ecology of similar South African Aloe species were extrapolated from these and recent findings by various authors, but emphasises the need for a robust natural phylogeny of the Aloaceae in order to draw comprehensive conclusions on the evolutionary radiation of this highly charismatic group.
- Full Text:
- Date Issued: 2007
- Authors: Botes, Christo
- Date: 2007
- Subjects: Aloe -- South Africa -- Gamtoos River Valley , Aloe -- South Africa -- Identification
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10628 , http://hdl.handle.net/10948/481 , Aloe -- South Africa -- Gamtoos River Valley , Aloe -- South Africa -- Identification
- Description: In this study I documented the convergence of five congeneric bird-pollinated plants (Aloe pluridens, A. lineata var. muirii, A. speciosa, A. africana, and A. ferox) into three functional groups based on size, shape, and the arrangements of flowers on the inflorescence, but also nectar rewards, pollen deposition sites on the bird-pollinators, and the degree to which bees play a role in their pollination. Individuals of similar functional groups were divergent in their peak flowering times and limited their degree of flowering overlap further by spatial aggregation and niche separation, within the Thicket of the Gamtoos River Valley. The nectar properties were especially useful in structuring the bird pollinator community, which resulted in greater ethological isolation and hence, greater reproductive assurance in the mixed co-flowering plant communities. Choice array experiments revealed that it was the fine scale aggregation of flowering individuals that ensured that bird-pollinators feed selectively, since when equal choice was available, interspecific visitation increased significantly compared to natural scenarios. Bird behaviour and the ecological intermediateness of one to the species explained its prominence in hybrid combinations. The spatial occurrence of hybrid individuals can be traced back to the energetics of foraging and its influence on bird floral constancy. The pollination ecology of similar South African Aloe species were extrapolated from these and recent findings by various authors, but emphasises the need for a robust natural phylogeny of the Aloaceae in order to draw comprehensive conclusions on the evolutionary radiation of this highly charismatic group.
- Full Text:
- Date Issued: 2007