Exploring Learner Participation in Waste-Management Activities in a Rural Botswana Primary School
- Authors: Silo, Nthalivi
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386509 , vital:68148 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122820"
- Description: In Botswana, participation in environmental learning activities has been perceived as a central component of environmental education in formal education. Driven by the need to implement the objective of making the participatory approach part of the infusion of environmental education in the school curriculum as prescribed by the infusion policy, Botswana schools have come up with initiatives to involve learners in environmental education activities that seem to have ‘a direct, perceived benefit to the learners’ (NEESAP, 2007:9). Within this approach it is expected that learners should participate in these activities. However, Ketlhoilwe (2007) revealed that there has been a normalisation of environmental education into existing school culture through equating waste-management activities with environmental education. This generally entails cleaning activities by learners to maintain ‘clean schools’, which is directly associated with environmental education. Drawing from detailed case study data in one rural primary school with Standard 6 learners, I used Cultural Historical Activity Theory to investigate and explain how learners participate in these waste-management activities. Findings from this study revealed that attempts by teachers to meet the policy imperative through prescription of rules, and ascribing roles to learners in waste-management activities, create tensions. This gave rise to an elusive object of learner participation, as the purpose for their participation in these activities is not clear.
- Full Text:
- Date Issued: 2009
- Authors: Silo, Nthalivi
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/386509 , vital:68148 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122820"
- Description: In Botswana, participation in environmental learning activities has been perceived as a central component of environmental education in formal education. Driven by the need to implement the objective of making the participatory approach part of the infusion of environmental education in the school curriculum as prescribed by the infusion policy, Botswana schools have come up with initiatives to involve learners in environmental education activities that seem to have ‘a direct, perceived benefit to the learners’ (NEESAP, 2007:9). Within this approach it is expected that learners should participate in these activities. However, Ketlhoilwe (2007) revealed that there has been a normalisation of environmental education into existing school culture through equating waste-management activities with environmental education. This generally entails cleaning activities by learners to maintain ‘clean schools’, which is directly associated with environmental education. Drawing from detailed case study data in one rural primary school with Standard 6 learners, I used Cultural Historical Activity Theory to investigate and explain how learners participate in these waste-management activities. Findings from this study revealed that attempts by teachers to meet the policy imperative through prescription of rules, and ascribing roles to learners in waste-management activities, create tensions. This gave rise to an elusive object of learner participation, as the purpose for their participation in these activities is not clear.
- Full Text:
- Date Issued: 2009
Film Review: Hollywood on Safari
- Authors: Amner, Roderick J
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142680 , vital:38101 , https://doi.org/10.1386/jams.1.2.335_4
- Description: Film Review: Hollywood on Safari.
- Full Text:
- Date Issued: 2009
- Authors: Amner, Roderick J
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142680 , vital:38101 , https://doi.org/10.1386/jams.1.2.335_4
- Description: Film Review: Hollywood on Safari.
- Full Text:
- Date Issued: 2009
Foreign policy ambiguity on the part of an emergent middle power: South African foreign policy through other lenses
- Serrão, Olivier, Bischoff, Paul, 1954-
- Authors: Serrão, Olivier , Bischoff, Paul, 1954-
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/161464 , vital:40629 , DOI: 10.1080/02589341003600189
- Description: This paper attempts to address the ambiguity so frequently highlighted in South Africa's post-apartheid foreign policy. Three central arguments are put forward. Firstly, it is argued that traditional accounts of South Africa's foreign policy, utilizing rationalist or ‘mainstream’ theories of International Relations, are insufficient in themselves to explain the complexities inherent in the country's foreign policy. In this regard, constructivist IR theory offers several key insights into studies of South Africa's foreign policy. Secondly, although it is argued that constructivism, particularly its focus on identity, is crucial to understanding South African foreign policy, it alone cannot sufficiently explain its reception or results on the world stage. Finally, it is argued that in order to fully appreciate both the nature and effects of South Africa's foreign policy, a mixed focus, incorporating insights from both constructivist and materialist-based theories of IR, is necessary.
- Full Text:
- Date Issued: 2009
- Authors: Serrão, Olivier , Bischoff, Paul, 1954-
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/161464 , vital:40629 , DOI: 10.1080/02589341003600189
- Description: This paper attempts to address the ambiguity so frequently highlighted in South Africa's post-apartheid foreign policy. Three central arguments are put forward. Firstly, it is argued that traditional accounts of South Africa's foreign policy, utilizing rationalist or ‘mainstream’ theories of International Relations, are insufficient in themselves to explain the complexities inherent in the country's foreign policy. In this regard, constructivist IR theory offers several key insights into studies of South Africa's foreign policy. Secondly, although it is argued that constructivism, particularly its focus on identity, is crucial to understanding South African foreign policy, it alone cannot sufficiently explain its reception or results on the world stage. Finally, it is argued that in order to fully appreciate both the nature and effects of South Africa's foreign policy, a mixed focus, incorporating insights from both constructivist and materialist-based theories of IR, is necessary.
- Full Text:
- Date Issued: 2009
Glumlazi
- Authors: Krueger, Anton
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229829 , vital:49715 , xlink:href="https://hdl.handle.net/10520/EJC47808"
- Full Text:
- Date Issued: 2009
- Authors: Krueger, Anton
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229829 , vital:49715 , xlink:href="https://hdl.handle.net/10520/EJC47808"
- Full Text:
- Date Issued: 2009
Grade-appropriate literacy and South African grade seven learners' classroom writing in English
- Authors: Hendricks, Monica
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:7019 , http://hdl.handle.net/10962/d1007173 , https://doi.org/10.1080/03004430600989593
- Description: preprint , This paper reports on the writing of grade 7 learners in English as an additional language at four differently-resourced schools in the Eastern Cape Province, South Africa. Because grade 7 is the start of the senior phase of schooling, it is vital that learners achieve grade-level competence in the language used as medium of instruction. Learning outcome five which states that ‘the learner will be able to use language to think and reason, as well as access, process and use information for learning’ (Department of Education 2002) is particularly relevant. The primary research question asked what the writing practices in grade 7 additional languages were, and how these contribute to the development of learners’ writing. The findings were that literacy practices at all four schools privilege grammar exercises and personal, expressive writing. In terms of Cummins’s (1984) constructs of BICS (Basic Interpersonal Communicative Skill) and CALP (Cognitive Academic Language Proficiency), learners’ written competencies are mainly conversational (BICS). The personal expressive texts which predominate in learners’ writing have done little to develop a formal, impersonal academic register (CALP). Learners need to become familiar with the more abstract impersonal factual genres associated with disciplinary-based knowledge.
- Full Text:
- Date Issued: 2009
- Authors: Hendricks, Monica
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:7019 , http://hdl.handle.net/10962/d1007173 , https://doi.org/10.1080/03004430600989593
- Description: preprint , This paper reports on the writing of grade 7 learners in English as an additional language at four differently-resourced schools in the Eastern Cape Province, South Africa. Because grade 7 is the start of the senior phase of schooling, it is vital that learners achieve grade-level competence in the language used as medium of instruction. Learning outcome five which states that ‘the learner will be able to use language to think and reason, as well as access, process and use information for learning’ (Department of Education 2002) is particularly relevant. The primary research question asked what the writing practices in grade 7 additional languages were, and how these contribute to the development of learners’ writing. The findings were that literacy practices at all four schools privilege grammar exercises and personal, expressive writing. In terms of Cummins’s (1984) constructs of BICS (Basic Interpersonal Communicative Skill) and CALP (Cognitive Academic Language Proficiency), learners’ written competencies are mainly conversational (BICS). The personal expressive texts which predominate in learners’ writing have done little to develop a formal, impersonal academic register (CALP). Learners need to become familiar with the more abstract impersonal factual genres associated with disciplinary-based knowledge.
- Full Text:
- Date Issued: 2009
Growing of trees in home-gardens by rural households in the Eastern Cape and Limpopo Provinces, South Africa:
- Shackleton, Charlie M, Paumgarten, Fiona, Cocks, Michelle L
- Authors: Shackleton, Charlie M , Paumgarten, Fiona , Cocks, Michelle L
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141360 , vital:37965 , DOI: 10.1080/13504500509469647
- Description: Trees provide a wide range of goods and services to rural households which, when incorporated into their livelihood strategies, help reduce their vulnerability to adversity. Governments and policy makers often ignore the contribution made by trees and consequently resources are focussed on cash crops and livestock. Villagers in the Eastern Cape and Limpopo Province, South Africa utilise a range of trees from home-gardens for various purposes, although predominantly for fruit and shade. Trees are either planted or actively retained in households' home-gardens. There were noticeable differences between the villages in the Eastern Cape and those in Limpopo Province, particularly with respect to the overall density of trees per hectare and the number of species per household, both being significantly greater in Limpopo Province. The five most preferred species were listed for each village, revealing a preference for exotic fruit trees in Limpopo Province and a mix of exotic fruit trees and shade trees in the Eastern Cape. Households also retained useful indigenous species, predominantly fruit-bearing species. A range of factors constrain tree growing in home-gardens and households engage in practices to grow and maintain their trees. Not all of these constraints and practices were significantly different between the various localities.
- Full Text:
- Date Issued: 2009
- Authors: Shackleton, Charlie M , Paumgarten, Fiona , Cocks, Michelle L
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141360 , vital:37965 , DOI: 10.1080/13504500509469647
- Description: Trees provide a wide range of goods and services to rural households which, when incorporated into their livelihood strategies, help reduce their vulnerability to adversity. Governments and policy makers often ignore the contribution made by trees and consequently resources are focussed on cash crops and livestock. Villagers in the Eastern Cape and Limpopo Province, South Africa utilise a range of trees from home-gardens for various purposes, although predominantly for fruit and shade. Trees are either planted or actively retained in households' home-gardens. There were noticeable differences between the villages in the Eastern Cape and those in Limpopo Province, particularly with respect to the overall density of trees per hectare and the number of species per household, both being significantly greater in Limpopo Province. The five most preferred species were listed for each village, revealing a preference for exotic fruit trees in Limpopo Province and a mix of exotic fruit trees and shade trees in the Eastern Cape. Households also retained useful indigenous species, predominantly fruit-bearing species. A range of factors constrain tree growing in home-gardens and households engage in practices to grow and maintain their trees. Not all of these constraints and practices were significantly different between the various localities.
- Full Text:
- Date Issued: 2009
Hard choices ahead
- Authors: Pithouse, Richard, 1970-
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:6204 , http://hdl.handle.net/10962/d1008573 , http://sacsis.org.za/site/article/334.1
- Description: preprint , From Introduction: In recent weeks people have been willing to risk arrest, violence and in some cases death at the hands of our habitually brutal police force to assert a whole range of demands. These demands have included an insistence on the right to the cities, the right to an income, the right to a decent education and the right to a living wage.
- Full Text:
- Date Issued: 2009
- Authors: Pithouse, Richard, 1970-
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:6204 , http://hdl.handle.net/10962/d1008573 , http://sacsis.org.za/site/article/334.1
- Description: preprint , From Introduction: In recent weeks people have been willing to risk arrest, violence and in some cases death at the hands of our habitually brutal police force to assert a whole range of demands. These demands have included an insistence on the right to the cities, the right to an income, the right to a decent education and the right to a living wage.
- Full Text:
- Date Issued: 2009
Health literacy assessment: relexicalising a US test for a South African population
- Hunt, Sally, Dowse, Roslind, La Rose, Christopher M
- Authors: Hunt, Sally , Dowse, Roslind , La Rose, Christopher M
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/139131 , vital:37708 , DOI: 10.2989/SALALS.2008.26.2.7.571
- Description: The problems of illiteracy in health contexts have been well documented in the literature and include such serious repercussions as medication non-compliance and failure to seek medical help during the course of an illness. The Rapid Estimate of Adult Literacy in Medicine (REALM) is a standardised health literacy test developed in the United States that has been previously administered and researched in South Africa (Lecoko, 2000). It is an objective vocabulary test, designed as a screening instrument to identify the health literacy levels of patients in clinics, which uses item recognition of 66 health-related words. Lecoko found that, in a South African setting, only 8 out of the 66 words in the US-developed test could be deemed acceptable. Therefore, the current study focused on the principled relexicalisation of the REALM, using words gathered from health information and promotional texts in local clinics, hypothesising that this would improve its applicability. After administration to a statistically similar group of respondents, the number of acceptable words on the test increased from eight to 38. Thus it is concluded that principled relexicalisation may be one way of improving the applicability of standardised health literacy tests to local populations and settings. However, the limitations of standardised tests may prove to be a significant barrier overshadowing the value of relexicalisation.
- Full Text:
- Date Issued: 2009
- Authors: Hunt, Sally , Dowse, Roslind , La Rose, Christopher M
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/139131 , vital:37708 , DOI: 10.2989/SALALS.2008.26.2.7.571
- Description: The problems of illiteracy in health contexts have been well documented in the literature and include such serious repercussions as medication non-compliance and failure to seek medical help during the course of an illness. The Rapid Estimate of Adult Literacy in Medicine (REALM) is a standardised health literacy test developed in the United States that has been previously administered and researched in South Africa (Lecoko, 2000). It is an objective vocabulary test, designed as a screening instrument to identify the health literacy levels of patients in clinics, which uses item recognition of 66 health-related words. Lecoko found that, in a South African setting, only 8 out of the 66 words in the US-developed test could be deemed acceptable. Therefore, the current study focused on the principled relexicalisation of the REALM, using words gathered from health information and promotional texts in local clinics, hypothesising that this would improve its applicability. After administration to a statistically similar group of respondents, the number of acceptable words on the test increased from eight to 38. Thus it is concluded that principled relexicalisation may be one way of improving the applicability of standardised health literacy tests to local populations and settings. However, the limitations of standardised tests may prove to be a significant barrier overshadowing the value of relexicalisation.
- Full Text:
- Date Issued: 2009
How many declarations do we need?: Inside the drafting of the Bonn Declaration on education for sustainable development
- Authors: Lotz-Sisitka, Heila
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182522 , vital:43837 , xlink:href="https://doi.org/10.1177/097340820900300217"
- Description: The Bonn Declaration, approved by the 900 participants at the UNESCO World Conference on Sustainable Development, differs from other conference declarations in that it is the first declaration to deal exclusively with education for sustainable development. It received input from official State representatives and, perhaps because of that, it is somewhat less provocative than some nongovernmental or university-sponsored declarations. Also, it actually sets out, with some authority, an agenda for UNESCO, the manager of the UN Decade of Education for Sustainable Development. Though some may question the usefulness of conference declarations, history shows that such declarations do have at least some guiding power in that they provide common starting points for deliberation on possible changes at national and international levels.
- Full Text:
- Date Issued: 2009
- Authors: Lotz-Sisitka, Heila
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182522 , vital:43837 , xlink:href="https://doi.org/10.1177/097340820900300217"
- Description: The Bonn Declaration, approved by the 900 participants at the UNESCO World Conference on Sustainable Development, differs from other conference declarations in that it is the first declaration to deal exclusively with education for sustainable development. It received input from official State representatives and, perhaps because of that, it is somewhat less provocative than some nongovernmental or university-sponsored declarations. Also, it actually sets out, with some authority, an agenda for UNESCO, the manager of the UN Decade of Education for Sustainable Development. Though some may question the usefulness of conference declarations, history shows that such declarations do have at least some guiding power in that they provide common starting points for deliberation on possible changes at national and international levels.
- Full Text:
- Date Issued: 2009
Interaction of water-soluble CdTe quantum dots with octacarboxy metallophthalocyanines
- Idowu, Mopelola, Nyokong, Tebello
- Authors: Idowu, Mopelola , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264197 , vital:53708 , xlink:href="https://doi.org/10.1016/j.jlumin.2008.11.005"
- Description: Water-soluble CdTe quantum dots capped with L-cysteine (QD-CYS) were found to improve the photophysical and photochemical properties of octacarboxy metallophthalocyanine (MOCPc, M=Zn(II), Al(III)(OH), Ge(IV)(OH)2 and Si(IV)(OH)2) complexes. Increased diffusional interactions between the molecules and the ground-state molecular oxygen were established resulting from the increase in the triplet-state quantum yield and lifetimes of the MOCPcs in the presence of QD-CYS. Energy transfer occurred from QD-CYS to the MOCPcs upon excitation of QD-CYS. It was found that an efficient energy transfer process, which is not directly related to the amount of spectral overlap between the donor (QD-CYS) and the acceptor (MOCPc) can occur. Singlet oxygen via fluorescence resonance energy transfer (FRET) mechanism was produced in the QD-MPc mixture.
- Full Text:
- Date Issued: 2009
- Authors: Idowu, Mopelola , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/264197 , vital:53708 , xlink:href="https://doi.org/10.1016/j.jlumin.2008.11.005"
- Description: Water-soluble CdTe quantum dots capped with L-cysteine (QD-CYS) were found to improve the photophysical and photochemical properties of octacarboxy metallophthalocyanine (MOCPc, M=Zn(II), Al(III)(OH), Ge(IV)(OH)2 and Si(IV)(OH)2) complexes. Increased diffusional interactions between the molecules and the ground-state molecular oxygen were established resulting from the increase in the triplet-state quantum yield and lifetimes of the MOCPcs in the presence of QD-CYS. Energy transfer occurred from QD-CYS to the MOCPcs upon excitation of QD-CYS. It was found that an efficient energy transfer process, which is not directly related to the amount of spectral overlap between the donor (QD-CYS) and the acceptor (MOCPc) can occur. Singlet oxygen via fluorescence resonance energy transfer (FRET) mechanism was produced in the QD-MPc mixture.
- Full Text:
- Date Issued: 2009
Language shift in Grahamstown: A case study of selected Xhosa-speakers
- Authors: De Klerk, Vivian A
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158106 , vital:40149 , https://0-doi.org.wam.seals.ac.za/10.1515/ijsl.2000.146.87
- Description: A number of scholars (Fasold 1984; Aitchison 1991; Denison 1977; Dorian 1980; Gal 1979) have examined the issue of language maintenance and shift, trying to discover why certain languages (or language variants) sometimes replace each other among some Speakers, particularly in certain domains of linguistic behaviour under some conditions or intergroup contact. This article provides an overview of the main factors that have been identified as playing an important role in influencing language shift and then reports on the relative importance of these factors in a survey that examined the experiences and attitudes of Xhosa-speaking parents who have recently chosen to send their children to English-medium schools in Grahamstown (Eastern Cape, South Africa). The research was carried out during 1998, and the project was a multifaceted quantitative and qualitative longitudinal study involving responses to a postal questionnaire sent to all non-English parents at English-medium schools in the town, and follow-up Interviews with 26 parents.
- Full Text:
- Date Issued: 2009
- Authors: De Klerk, Vivian A
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158106 , vital:40149 , https://0-doi.org.wam.seals.ac.za/10.1515/ijsl.2000.146.87
- Description: A number of scholars (Fasold 1984; Aitchison 1991; Denison 1977; Dorian 1980; Gal 1979) have examined the issue of language maintenance and shift, trying to discover why certain languages (or language variants) sometimes replace each other among some Speakers, particularly in certain domains of linguistic behaviour under some conditions or intergroup contact. This article provides an overview of the main factors that have been identified as playing an important role in influencing language shift and then reports on the relative importance of these factors in a survey that examined the experiences and attitudes of Xhosa-speaking parents who have recently chosen to send their children to English-medium schools in Grahamstown (Eastern Cape, South Africa). The research was carried out during 1998, and the project was a multifaceted quantitative and qualitative longitudinal study involving responses to a postal questionnaire sent to all non-English parents at English-medium schools in the town, and follow-up Interviews with 26 parents.
- Full Text:
- Date Issued: 2009
Meeting democracy’s challenge developments:
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159389 , vital:40293 , https://hdl.handle.net/10520/EJC139935
- Description: In a context of declining public participation, can mobile phone technology and 'new media' be used to involve more people in local decision-making, asks Harry Dug more in this exploration of the implications of mobile communication on journalism in the developing world.
- Full Text:
- Date Issued: 2009
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159389 , vital:40293 , https://hdl.handle.net/10520/EJC139935
- Description: In a context of declining public participation, can mobile phone technology and 'new media' be used to involve more people in local decision-making, asks Harry Dug more in this exploration of the implications of mobile communication on journalism in the developing world.
- Full Text:
- Date Issued: 2009
Metal (Co, Fe) tribenzotetraazachlorin–fullerene conjugates
- Ozoemena, Kenneth I, Mamuru, Solomon A, Fukuda, Takamitsu, Kobayashi, Nagao, Nyokong, Tebello
- Authors: Ozoemena, Kenneth I , Mamuru, Solomon A , Fukuda, Takamitsu , Kobayashi, Nagao , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263464 , vital:53630 , xlink:href="https://doi.org/10.1016/j.elecom.2009.04.011"
- Description: Novel hexabutylsulphonyltribenzotetraazachlorin–fullerene (C60) complexes of iron (FeHBSTBTAC–C60) and cobalt (CoHBSTBTAC–C60) have been synthesized and their electrochemistry and oxygen reduction reaction (ORR) compared with their octabutylsulphonylphthalocyanine analogues (FeOBSPc and CoOBSPc). It is proved that electron-withdrawing substituents (–SO2Bu and C60) on phthalocyanine macrocycle exhibit distinct impact on the solution electrochemistry of these metallophthalocyanine (MPc) complexes. The more electron-withdrawing C60 substituent suppressed ORR compared to the –SO2Bu in alkaline medium. FeOBSPc showed the best ORR activity involving a direct 4-electron mechanism, a rate constant of ∼1 × 108 cm3 mol−1 s−1 and a Tafel slope of −171 mV dec−1.
- Full Text:
- Date Issued: 2009
- Authors: Ozoemena, Kenneth I , Mamuru, Solomon A , Fukuda, Takamitsu , Kobayashi, Nagao , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263464 , vital:53630 , xlink:href="https://doi.org/10.1016/j.elecom.2009.04.011"
- Description: Novel hexabutylsulphonyltribenzotetraazachlorin–fullerene (C60) complexes of iron (FeHBSTBTAC–C60) and cobalt (CoHBSTBTAC–C60) have been synthesized and their electrochemistry and oxygen reduction reaction (ORR) compared with their octabutylsulphonylphthalocyanine analogues (FeOBSPc and CoOBSPc). It is proved that electron-withdrawing substituents (–SO2Bu and C60) on phthalocyanine macrocycle exhibit distinct impact on the solution electrochemistry of these metallophthalocyanine (MPc) complexes. The more electron-withdrawing C60 substituent suppressed ORR compared to the –SO2Bu in alkaline medium. FeOBSPc showed the best ORR activity involving a direct 4-electron mechanism, a rate constant of ∼1 × 108 cm3 mol−1 s−1 and a Tafel slope of −171 mV dec−1.
- Full Text:
- Date Issued: 2009
Metallophthalocyanine Based Carbon Paste Electrodes for the Determination of 2′, 3′‐Dideoxyinosine
- Ozoemena, Kenneth I, Stefan-van Staden, Raluca-Ioana, Nyokong, Tebello
- Authors: Ozoemena, Kenneth I , Stefan-van Staden, Raluca-Ioana , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263430 , vital:53627 , xlink:href="https://doi.org/10.1002/elan.200904581"
- Description: Novel electrochemical sensors based on carbon paste impregnated with metallopthalocyanine (MPc, M=Co, Fe) complexes, have been constructed for the assay of anti-HIV drug 2′,3′-dideoxyinosine (didanosine, DDI). Both modified electrodes showed electrocatalytic activity towards the oxidation of dideoxyinosine in phosphate buffer pH 7.4 with a working concentration range of 10−6–10−4 mol/L and a detection limit of 10−7 mol/L magnitude order. The sensor proved to be highly reliable for the assay of the purity of DDI - raw material as well as for the uniformity content test of Videx tablets.
- Full Text:
- Date Issued: 2009
- Authors: Ozoemena, Kenneth I , Stefan-van Staden, Raluca-Ioana , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263430 , vital:53627 , xlink:href="https://doi.org/10.1002/elan.200904581"
- Description: Novel electrochemical sensors based on carbon paste impregnated with metallopthalocyanine (MPc, M=Co, Fe) complexes, have been constructed for the assay of anti-HIV drug 2′,3′-dideoxyinosine (didanosine, DDI). Both modified electrodes showed electrocatalytic activity towards the oxidation of dideoxyinosine in phosphate buffer pH 7.4 with a working concentration range of 10−6–10−4 mol/L and a detection limit of 10−7 mol/L magnitude order. The sensor proved to be highly reliable for the assay of the purity of DDI - raw material as well as for the uniformity content test of Videx tablets.
- Full Text:
- Date Issued: 2009
Mobile monitors: protecting the will of the people
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159377 , vital:40292 , https://hdl.handle.net/10520/EJC139912
- Description: The use of mobile phone technology in recent African elections has empowered citizens, allowing them to put in place the checks and balances needed to make elections freer and fairer in Africa - and elsewhere in the world, writes Harry Dugmore.
- Full Text:
- Date Issued: 2009
- Authors: Dugmore, Harry
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159377 , vital:40292 , https://hdl.handle.net/10520/EJC139912
- Description: The use of mobile phone technology in recent African elections has empowered citizens, allowing them to put in place the checks and balances needed to make elections freer and fairer in Africa - and elsewhere in the world, writes Harry Dugmore.
- Full Text:
- Date Issued: 2009
Mulch tower treatment system for greywater reuse Part II: destructive testing and effluent treatment
- Tandlich, Roman, Zuma, Bongumusa M, Whittington-Jones, Kevin J, Burgess, Jo E
- Authors: Tandlich, Roman , Zuma, Bongumusa M , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71547 , vital:29863 , https://doi.org/10.1016/j.desal.2008.03.031
- Description: The mulch tower (MT) system described in Part I was tested to failure to determine its range of operating conditions. An increase in the influent temperature led to a statistically significant release of components of the chemical oxygen demand (COD) and the five day biochemical oxygen demand (BOD5), as well as phosphates from the MT system. Heterotrophic plate count (HPC) of the mulch layer dropped from 1.2 (± 0.6) × 106/g dry weight to 1.5 (± 0.3) × 105/g dry weight of the mulch layer with increases of the influent temperature. This indicates that the increase in influent temperature killed off some of the active biomass in the MT biofilm. After a five day drying period under active aeration, the MT system retained the ability to remove COD, total suspended solids (TSS), and nitrates. Greywater treatment by the MT system became impossible after a 48 day drying period under active aeration. Chlorination of the simulated MT effluent with a mixture of sodium dichloroisocyanurate and trichloroisocyanuric acid decreased the faecal coliform concentrations (FC) and the total coliform concentrations (TC) below 800 CFUs/100 ml within 65 h. Beyond 65 h, the pH of the effluent became highly acidic. To maintain optimum performance influent should be fed into the MT system at least once every 5 days, sufficient aeration should be guaranteed, and the MT effluent should be chlorinated for 65 h to eliminate all pathogens before any reuse.
- Full Text: false
- Date Issued: 2009
Mulch tower treatment system for greywater reuse Part II: destructive testing and effluent treatment
- Authors: Tandlich, Roman , Zuma, Bongumusa M , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71547 , vital:29863 , https://doi.org/10.1016/j.desal.2008.03.031
- Description: The mulch tower (MT) system described in Part I was tested to failure to determine its range of operating conditions. An increase in the influent temperature led to a statistically significant release of components of the chemical oxygen demand (COD) and the five day biochemical oxygen demand (BOD5), as well as phosphates from the MT system. Heterotrophic plate count (HPC) of the mulch layer dropped from 1.2 (± 0.6) × 106/g dry weight to 1.5 (± 0.3) × 105/g dry weight of the mulch layer with increases of the influent temperature. This indicates that the increase in influent temperature killed off some of the active biomass in the MT biofilm. After a five day drying period under active aeration, the MT system retained the ability to remove COD, total suspended solids (TSS), and nitrates. Greywater treatment by the MT system became impossible after a 48 day drying period under active aeration. Chlorination of the simulated MT effluent with a mixture of sodium dichloroisocyanurate and trichloroisocyanuric acid decreased the faecal coliform concentrations (FC) and the total coliform concentrations (TC) below 800 CFUs/100 ml within 65 h. Beyond 65 h, the pH of the effluent became highly acidic. To maintain optimum performance influent should be fed into the MT system at least once every 5 days, sufficient aeration should be guaranteed, and the MT effluent should be chlorinated for 65 h to eliminate all pathogens before any reuse.
- Full Text: false
- Date Issued: 2009
Mulch tower treatment system Part I: Overall performance in greywater treatment
- Zuma, Bongumusa M, Tandlich, Roman, Whittington-Jones, Kevin J, Burgess, Jo E
- Authors: Zuma, Bongumusa M , Tandlich, Roman , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71537 , vital:29862 , https://doi.org/10.1016/j.desal.2008.03.030
- Description: A mulch tower (MT) system for greywater treatment is introduced in this paper. Materials used to assemble the MT system included mulch, coarse sand, fine and coarse gravel. Limited removal efficiency of the MT system was demonstrated for alkalinity, total hardness, pH, Cl–, PO43–, NH4+, and SO42–, with the estimated cumulative removals ranging from 7 to 12%. Intermediate removal efficiency was observed for chemical oxygen demand (COD), NO3–, and S2– with the estimated cumulative removals ranging from 24 to 28%. The highest removal efficiency was observed for the total suspended solids (TSS) with the estimated cumulative removal equal to 52%. Given the minute residence time in the MT system, the results obtained were promising and justify scale-up studies for potential on-site applications. The MT effluent did not meet hygienic norms with respect to the faecal coliform concentration (FC) and the total coliform concentration (TC), and further effluent treatment is required before any discharge or reuse of the treated greywater. Further research should focus on characterisation of the microbial community of the MT, and the fate of Cl–, PO43–, NH4+, and SO42–.
- Full Text: false
- Date Issued: 2009
- Authors: Zuma, Bongumusa M , Tandlich, Roman , Whittington-Jones, Kevin J , Burgess, Jo E
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71537 , vital:29862 , https://doi.org/10.1016/j.desal.2008.03.030
- Description: A mulch tower (MT) system for greywater treatment is introduced in this paper. Materials used to assemble the MT system included mulch, coarse sand, fine and coarse gravel. Limited removal efficiency of the MT system was demonstrated for alkalinity, total hardness, pH, Cl–, PO43–, NH4+, and SO42–, with the estimated cumulative removals ranging from 7 to 12%. Intermediate removal efficiency was observed for chemical oxygen demand (COD), NO3–, and S2– with the estimated cumulative removals ranging from 24 to 28%. The highest removal efficiency was observed for the total suspended solids (TSS) with the estimated cumulative removal equal to 52%. Given the minute residence time in the MT system, the results obtained were promising and justify scale-up studies for potential on-site applications. The MT effluent did not meet hygienic norms with respect to the faecal coliform concentration (FC) and the total coliform concentration (TC), and further effluent treatment is required before any discharge or reuse of the treated greywater. Further research should focus on characterisation of the microbial community of the MT, and the fate of Cl–, PO43–, NH4+, and SO42–.
- Full Text: false
- Date Issued: 2009
Nathaniel Merriman’s lecture: “Shakspeare, as Bearing on English History”
- Authors: Wright, Laurence
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:7060 , http://hdl.handle.net/10962/d1007424 , http://hdl.handle.net/10520/EJC48132
- Description: preprint , “Shakspeare, as Bearing on English History” is the second of two lectures on Shakespeare given by Archdeacon Nathaniel Merriman in Grahamstown in 1857. The first was delivered in the Court House on the 2nd September 1857, and the second two months later, on Friday 6th November that same year, again in the Court House. The lecture was published in 1858. An article placing the lectures in their local context appeared in Shakespeare in Southern Africa 20 (2008): 25-37, accompanying an annotated edition of the first lecture, “On the Study of Shakspeare”. Readers desiring details of the editorial principles adopted in producing annotated editions of the two lectures are referred to the introductory material prefacing the first lecture.
- Full Text:
- Date Issued: 2009
- Authors: Wright, Laurence
- Date: 2009
- Language: English
- Type: text , article
- Identifier: vital:7060 , http://hdl.handle.net/10962/d1007424 , http://hdl.handle.net/10520/EJC48132
- Description: preprint , “Shakspeare, as Bearing on English History” is the second of two lectures on Shakespeare given by Archdeacon Nathaniel Merriman in Grahamstown in 1857. The first was delivered in the Court House on the 2nd September 1857, and the second two months later, on Friday 6th November that same year, again in the Court House. The lecture was published in 1858. An article placing the lectures in their local context appeared in Shakespeare in Southern Africa 20 (2008): 25-37, accompanying an annotated edition of the first lecture, “On the Study of Shakspeare”. Readers desiring details of the editorial principles adopted in producing annotated editions of the two lectures are referred to the introductory material prefacing the first lecture.
- Full Text:
- Date Issued: 2009
NGOs and rural movements in contemporary South Africa
- Authors: Helliker, Kirk D
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71252 , vital:29823 , https://doi.org/10.1080/02533952.2013.806415
- Description: This article provides a critical examination of relationships between non-governmental organisations (NGOs) and rural movements in post-apartheid South Africa, particularly with regard to the possible subordination of movements to NGOs. In discussing NGOs as a particular organisational form, and in reviewing some arguments pertaining to NGOs and rural movements globally, I explore whether NGOs in South Africa have a progressive role to play in agrarian transformation.
- Full Text:
- Date Issued: 2009
- Authors: Helliker, Kirk D
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71252 , vital:29823 , https://doi.org/10.1080/02533952.2013.806415
- Description: This article provides a critical examination of relationships between non-governmental organisations (NGOs) and rural movements in post-apartheid South Africa, particularly with regard to the possible subordination of movements to NGOs. In discussing NGOs as a particular organisational form, and in reviewing some arguments pertaining to NGOs and rural movements globally, I explore whether NGOs in South Africa have a progressive role to play in agrarian transformation.
- Full Text:
- Date Issued: 2009
Nine Notes on Lisbon
- Authors: Krueger, Anton
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229807 , vital:49712 , xlink:href="https://hdl.handle.net/10520/EJC47812"
- Full Text:
- Date Issued: 2009
- Authors: Krueger, Anton
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229807 , vital:49712 , xlink:href="https://hdl.handle.net/10520/EJC47812"
- Full Text:
- Date Issued: 2009