Addressing the idiosyncrasies of contemporary notation in recorder compositions, with specific references to unconventional symbols in Music for a bird by Hans-Martin Linde and Sieben Stucke fur altblokflote by Markus Zahnhausen
- Authors: Bartle, Lynne
- Date: 2009
- Subjects: Musical notation , Musical notation -- Study and teaching , Musical notation -- History , Music -- 20th century
- Language: English
- Type: Thesis , Masters , MMus
- Identifier: vital:8516 , http://hdl.handle.net/10948/920 , http://hdl.handle.net/10948/d1012065 , Musical notation , Musical notation -- Study and teaching , Musical notation -- History , Music -- 20th century
- Description: This treatise provides recorder performers and teachers with a guide to understanding the unconventional notation symbols encountered in Music for a Bird by Hans-Martin Linde and Sieben Stücke Für Altblockflöte by Markus Zahnhausen. Given the context of the overall history of notation, it argues that the idiosyncrasies of the unconventional notation symbols encountered in the recorder repertoire of contemporary composers such as Linde and Zahnhausen are by no means an anomaly. Throughout history, notated scores have functioned merely as incomplete guides to the reconstruction and the realization of musical works. Along with the decoding of these instructions, a host of acculturated meanings have always been taken for granted on the part of the writers of such guidelines. In the light of the modernist crisis and the resultant exacerbation of the gulf between composers and their audience, however, it would seem that the need for such acculturated intervention is greater then ever before. This treatise serves to bridge the gulf between the works of Linde and Zahnhausen on the one hand, and the average performer and teacher of the recorder on the other, by offering an analysis both of the meaning of the unconventional symbols these works contain as well as of the method according to which they should be executed on the recorder.
- Full Text:
- Date Issued: 2009
- Authors: Bartle, Lynne
- Date: 2009
- Subjects: Musical notation , Musical notation -- Study and teaching , Musical notation -- History , Music -- 20th century
- Language: English
- Type: Thesis , Masters , MMus
- Identifier: vital:8516 , http://hdl.handle.net/10948/920 , http://hdl.handle.net/10948/d1012065 , Musical notation , Musical notation -- Study and teaching , Musical notation -- History , Music -- 20th century
- Description: This treatise provides recorder performers and teachers with a guide to understanding the unconventional notation symbols encountered in Music for a Bird by Hans-Martin Linde and Sieben Stücke Für Altblockflöte by Markus Zahnhausen. Given the context of the overall history of notation, it argues that the idiosyncrasies of the unconventional notation symbols encountered in the recorder repertoire of contemporary composers such as Linde and Zahnhausen are by no means an anomaly. Throughout history, notated scores have functioned merely as incomplete guides to the reconstruction and the realization of musical works. Along with the decoding of these instructions, a host of acculturated meanings have always been taken for granted on the part of the writers of such guidelines. In the light of the modernist crisis and the resultant exacerbation of the gulf between composers and their audience, however, it would seem that the need for such acculturated intervention is greater then ever before. This treatise serves to bridge the gulf between the works of Linde and Zahnhausen on the one hand, and the average performer and teacher of the recorder on the other, by offering an analysis both of the meaning of the unconventional symbols these works contain as well as of the method according to which they should be executed on the recorder.
- Full Text:
- Date Issued: 2009
The link between economic development programmes (RDP & GEAR) and poverty reduction : (Airport Valley as an illustrative case)
- Authors: Bayti, Thelma Thokozile
- Date: 2009
- Subjects: Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Government policy -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa , Poverty -- Social aspects -- South Africa
- Language: English
- Type: Thesis , Masters , MPhil
- Identifier: vital:8225 , http://hdl.handle.net/10948/921 , Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Government policy -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa , Poverty -- Social aspects -- South Africa
- Description: The key debates after apartheid have been on the successes and shortcomings of the social and economic policies that were adopted after apartheid. The ANC government decided to approach poverty reduction by closing the inequality gap between racial groups in the country. It planned to provide services that would improve the poor people’s lives and also create employment to sustain development. To provide the necessary services, the government formulated two broad, but linked macroeconomic policies namely: the RDP and GEAR which focused on the demand and supply side respectively (Venter and Landsberg (2006). This indicated the importance with which the people’s welfare and growth were regarded by the South African government. It indicated that the government believed in pro-poor growth. The purpose of this study was to gain better and deeper understanding about poverty reduction since the 1994 political transition, from the poor people of Airport Valley (in the Nelson Mandela Metropolital Municipality), who experience poverty from the real world. The study attempted to find out from these people if there was improvement in their lives since democratisation. This qualitative and quantitative study used three methods of collecting data namely: a questionnaire, interviews and observation. The results of the study suggest that there has been lack of commitment by RDP and GEAR, as the conditions under which the people live and therefore their standard of living have not improved. The study recommends that the government should speed up the process of service delivery at Airport Valley and also include the people in decision making about the future of Airport Valley.
- Full Text:
- Date Issued: 2009
- Authors: Bayti, Thelma Thokozile
- Date: 2009
- Subjects: Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Government policy -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa , Poverty -- Social aspects -- South Africa
- Language: English
- Type: Thesis , Masters , MPhil
- Identifier: vital:8225 , http://hdl.handle.net/10948/921 , Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Government policy -- South Africa -- Eastern Cape , Economic development projects -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa , Poverty -- Social aspects -- South Africa
- Description: The key debates after apartheid have been on the successes and shortcomings of the social and economic policies that were adopted after apartheid. The ANC government decided to approach poverty reduction by closing the inequality gap between racial groups in the country. It planned to provide services that would improve the poor people’s lives and also create employment to sustain development. To provide the necessary services, the government formulated two broad, but linked macroeconomic policies namely: the RDP and GEAR which focused on the demand and supply side respectively (Venter and Landsberg (2006). This indicated the importance with which the people’s welfare and growth were regarded by the South African government. It indicated that the government believed in pro-poor growth. The purpose of this study was to gain better and deeper understanding about poverty reduction since the 1994 political transition, from the poor people of Airport Valley (in the Nelson Mandela Metropolital Municipality), who experience poverty from the real world. The study attempted to find out from these people if there was improvement in their lives since democratisation. This qualitative and quantitative study used three methods of collecting data namely: a questionnaire, interviews and observation. The results of the study suggest that there has been lack of commitment by RDP and GEAR, as the conditions under which the people live and therefore their standard of living have not improved. The study recommends that the government should speed up the process of service delivery at Airport Valley and also include the people in decision making about the future of Airport Valley.
- Full Text:
- Date Issued: 2009
An investigation of the implementation of integrated development planning (IDP) as a mechanism to alleviate poverty in Port Elizabeth in the Nelson Mandela Bay Metropolitan Municipality
- Authors: Befile, Temibsa
- Date: 2009
- Subjects: Poverty -- South Africa -- Port Elizabeth , Economic development projects -- South Africa -- Port Elizabeth , Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa -- Eastern Cape , Social planning -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9076 , http://hdl.handle.net/10948/1268 , Poverty -- South Africa -- Port Elizabeth , Economic development projects -- South Africa -- Port Elizabeth , Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa -- Eastern Cape , Social planning -- South Africa -- Eastern Cape
- Description: South Africa is characterised by inequitable growth and development, a high degree of poverty, increasing demands and limited resources and the challenge of integration. The need for improved standards of living and access to better infrastructure which are seen as crucial issues in addressing poverty have necessitated the introduction of Integrated Development Planning (IDP). The IDP looks at the economic and social development of the area as a whole. It aims to coordinate the work of the local government in a coherent plan to improve the quality of life for all the people living in an area. In view of the above there is a need for proper planning and implementation of projects, as well as monitoring and assessment of success on the part of local government in order to help to eliminate poverty in the community. In this study I investigated the implementation of IDP as a mechanism to alleviate poverty in Port Elizabeth in the Nelson Mandela Bay Metropolitan Municipality. Due to the vastness of the problem and the extensive nature of the geographical area of Port Elizabeth, this study focused exclusively on Motherwell and KwaZakhele. For the purposes of this study, a mixed methods research approach was employed. This means that the study followed both the qualitative and quantitative approaches for in-depth understanding and verification. The data collection tools/techniques and instruments used in this study were mainly closed-ended questionnaire and structured interview questions. Data was collected from residents by conducting surveys, making use of questionnaires. Structured interviews were conducted with municipality officials and councillors in order to understand the situation better. The findings of the study revealed that there is a lack of adequate public consultation. It is indicated that people are left in the dark and projects are implemented without proper consultation with the community.
- Full Text:
- Date Issued: 2009
- Authors: Befile, Temibsa
- Date: 2009
- Subjects: Poverty -- South Africa -- Port Elizabeth , Economic development projects -- South Africa -- Port Elizabeth , Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa -- Eastern Cape , Social planning -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:9076 , http://hdl.handle.net/10948/1268 , Poverty -- South Africa -- Port Elizabeth , Economic development projects -- South Africa -- Port Elizabeth , Economic assistance, Domestic -- South Africa -- Eastern Cape , Poverty -- Economic aspects -- South Africa -- Eastern Cape , Social planning -- South Africa -- Eastern Cape
- Description: South Africa is characterised by inequitable growth and development, a high degree of poverty, increasing demands and limited resources and the challenge of integration. The need for improved standards of living and access to better infrastructure which are seen as crucial issues in addressing poverty have necessitated the introduction of Integrated Development Planning (IDP). The IDP looks at the economic and social development of the area as a whole. It aims to coordinate the work of the local government in a coherent plan to improve the quality of life for all the people living in an area. In view of the above there is a need for proper planning and implementation of projects, as well as monitoring and assessment of success on the part of local government in order to help to eliminate poverty in the community. In this study I investigated the implementation of IDP as a mechanism to alleviate poverty in Port Elizabeth in the Nelson Mandela Bay Metropolitan Municipality. Due to the vastness of the problem and the extensive nature of the geographical area of Port Elizabeth, this study focused exclusively on Motherwell and KwaZakhele. For the purposes of this study, a mixed methods research approach was employed. This means that the study followed both the qualitative and quantitative approaches for in-depth understanding and verification. The data collection tools/techniques and instruments used in this study were mainly closed-ended questionnaire and structured interview questions. Data was collected from residents by conducting surveys, making use of questionnaires. Structured interviews were conducted with municipality officials and councillors in order to understand the situation better. The findings of the study revealed that there is a lack of adequate public consultation. It is indicated that people are left in the dark and projects are implemented without proper consultation with the community.
- Full Text:
- Date Issued: 2009
The effect of tulbaghia violacea plant extract on the growth of aspergillus species
- Authors: Belewa, Xoliswa Vuyokazi
- Date: 2009
- Subjects: Plant products , Plant extracts , Traditional medicine
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10315 , http://hdl.handle.net/10948/d1008186 , Plant products , Plant extracts , Traditional medicine
- Description: Traditional medicine has become an important part of healthcare worldwide. It is estimated that about 25 percent of prescribed medicines contain plant products or active compounds derived from plants. In South Africa, traditional medicine forms part of the culture and tradition of most communities. Garlic compounds have been shown to have a variety of antimicrobial properties. Amongst these are antifungal, antibacterial, antiviral and anti protozoal activities. Allicin and its breakdown products have been shown to be the main active compounds which possess these properties. Tulbaghia violacea has been used for the treatment of a variety of illnesses including asthma, fever, oesophageal cancer, constipation and hypertension. This study investigated the antifungal nature of T.violacea on the morphology, spore germination and lipid synthesis of Aspergillus flavus and Aspergillus parasiticus. The results of this study showed that the plant extract inhibited A. flavus growth at a minimal inhibitory concentration of 15mg/ml and was fungicidal at 20mg/ml and above. A. parasiticus was not inhibited at 25mg/ml indicating resistance to the inhibitory component of the plant extract. A measure of metabolic activity using the XTT assay showed reduced metabolic activity in the presence of increasing concentrations of the plant extract. Higher extract concentrations resulted in higher percentage inhibition of fungal growth for both fungal species with up to 98 percent inhibition being observed for the highest extract concentrations for both fungi. Germination was also delayed in the presence of 15mg/ml plant extract concentration by up to 60hr for A. flavus and 48hr for A. parasititcus. The TEM results showed increased thickening of the cell wall with higher extract concentrations. The thickening was greater for A. flavus than for A. parasiticus. Cell wall thickening may be the reason for the delay in germination in both species. Lipid production was reduced in the presence of plant extracts when compared to the control. The plant extracts inhibited triglyceride production at 15mg/ml for both A. flavus and A. parasiticus. The results therefore indicate that T. violacea extracts are antifungal and probably affect germination through interactions with the cell wall. It is possible that the extract affects lipid production in Aspergillus species.
- Full Text:
- Date Issued: 2009
- Authors: Belewa, Xoliswa Vuyokazi
- Date: 2009
- Subjects: Plant products , Plant extracts , Traditional medicine
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10315 , http://hdl.handle.net/10948/d1008186 , Plant products , Plant extracts , Traditional medicine
- Description: Traditional medicine has become an important part of healthcare worldwide. It is estimated that about 25 percent of prescribed medicines contain plant products or active compounds derived from plants. In South Africa, traditional medicine forms part of the culture and tradition of most communities. Garlic compounds have been shown to have a variety of antimicrobial properties. Amongst these are antifungal, antibacterial, antiviral and anti protozoal activities. Allicin and its breakdown products have been shown to be the main active compounds which possess these properties. Tulbaghia violacea has been used for the treatment of a variety of illnesses including asthma, fever, oesophageal cancer, constipation and hypertension. This study investigated the antifungal nature of T.violacea on the morphology, spore germination and lipid synthesis of Aspergillus flavus and Aspergillus parasiticus. The results of this study showed that the plant extract inhibited A. flavus growth at a minimal inhibitory concentration of 15mg/ml and was fungicidal at 20mg/ml and above. A. parasiticus was not inhibited at 25mg/ml indicating resistance to the inhibitory component of the plant extract. A measure of metabolic activity using the XTT assay showed reduced metabolic activity in the presence of increasing concentrations of the plant extract. Higher extract concentrations resulted in higher percentage inhibition of fungal growth for both fungal species with up to 98 percent inhibition being observed for the highest extract concentrations for both fungi. Germination was also delayed in the presence of 15mg/ml plant extract concentration by up to 60hr for A. flavus and 48hr for A. parasititcus. The TEM results showed increased thickening of the cell wall with higher extract concentrations. The thickening was greater for A. flavus than for A. parasiticus. Cell wall thickening may be the reason for the delay in germination in both species. Lipid production was reduced in the presence of plant extracts when compared to the control. The plant extracts inhibited triglyceride production at 15mg/ml for both A. flavus and A. parasiticus. The results therefore indicate that T. violacea extracts are antifungal and probably affect germination through interactions with the cell wall. It is possible that the extract affects lipid production in Aspergillus species.
- Full Text:
- Date Issued: 2009
The effect of load and technique on biomechanical and psychophysical responses to level dynamic pushing and pulling
- Authors: Bennett, Anthea Iona
- Date: 2009
- Subjects: Work -- Physiological aspects , Human engineering -- Case studies , Lifting and carrying -- Case studies , Biomechanics -- Case studies , Musculoskeletal system -- Wounds and injuries
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5110 , http://hdl.handle.net/10962/d1005188 , Work -- Physiological aspects , Human engineering -- Case studies , Lifting and carrying -- Case studies , Biomechanics -- Case studies , Musculoskeletal system -- Wounds and injuries
- Description: Pushing and pulling research has yet to fully elucidate the demands placed on manual workers despite established epidemiological links to musculoskeletal disorders. The current study therefore aimed to quantify biomechanical and perceptual responses of male operators to dynamic pushing and pulling tasks. Three common push/pull techniques (pushing, one handed and two handed pulling) were performed at loads of 250kg and 500kg using an industrial pallet jack in a laboratory environment. Thirty six healthy male subjects (age: 21 ±2 years, stature: 1791 ±43 mm and body mass: 77 ±10 kg) were required to perform six loaded experimental and two unloaded control conditions. Hand force exertion, muscle activity and gait pattern responses were collected during 10m push/pull trials on a coefficient controlled walkway; body discomfort was assessed on completion of the condition. Horizontal hand force responses were significantly (p<0.05) affected by load, with a linear relationship existing between the two. This relationship is determined by specific environmental and trolley factors and is context specific, depending on factors such as trolley maintenance and type of flooring. Hand force exertion responses were tenuously affected by technique at higher loads in the initial and sustained phases, with pushing inducing the greatest hand forces. Comparison of the motion phases revealed significant differences between all three phases, with the initial phase evidencing the greatest hand forces. Muscle activity responses demonstrated that unloaded backward walking evoked significantly higher muscle activation than did unloaded forward walking whilst increased muscular activity during load movement compared to unloaded walking was observed. However increasing load from 250kg to 500kg did not significantly impact the majority of muscle activity responses. When considering technique effects on muscle activity, of the significant differences found, all indicated that pushing imposed the least demand on the musculoskeletal system. Gait pattern responses were not significantly affected by load/technique combinations and were similar to those elicited during normal, unloaded walking. Perceptually, increased load led to increased perception of discomfort while pushing resulted in the least discomfort at both loads. From these psychophysical responses, the calves, shoulders and biceps were identified as areas of potential musculoskeletal injury, particularly during one and two handed pulling. Pushing elicited the highest hand forces and the lowest muscle activity responses in the majority of the conditions whilst psychophysical responses identified this technique as most satisfactory. Current results advocate the use of pushing when moving a load using a wheeled device. Suitability of one and two handed pulling remains contradictory, however results suggest that one handed pulling be employed at lower loads and two handed pulling at higher loads.
- Full Text:
- Date Issued: 2009
- Authors: Bennett, Anthea Iona
- Date: 2009
- Subjects: Work -- Physiological aspects , Human engineering -- Case studies , Lifting and carrying -- Case studies , Biomechanics -- Case studies , Musculoskeletal system -- Wounds and injuries
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5110 , http://hdl.handle.net/10962/d1005188 , Work -- Physiological aspects , Human engineering -- Case studies , Lifting and carrying -- Case studies , Biomechanics -- Case studies , Musculoskeletal system -- Wounds and injuries
- Description: Pushing and pulling research has yet to fully elucidate the demands placed on manual workers despite established epidemiological links to musculoskeletal disorders. The current study therefore aimed to quantify biomechanical and perceptual responses of male operators to dynamic pushing and pulling tasks. Three common push/pull techniques (pushing, one handed and two handed pulling) were performed at loads of 250kg and 500kg using an industrial pallet jack in a laboratory environment. Thirty six healthy male subjects (age: 21 ±2 years, stature: 1791 ±43 mm and body mass: 77 ±10 kg) were required to perform six loaded experimental and two unloaded control conditions. Hand force exertion, muscle activity and gait pattern responses were collected during 10m push/pull trials on a coefficient controlled walkway; body discomfort was assessed on completion of the condition. Horizontal hand force responses were significantly (p<0.05) affected by load, with a linear relationship existing between the two. This relationship is determined by specific environmental and trolley factors and is context specific, depending on factors such as trolley maintenance and type of flooring. Hand force exertion responses were tenuously affected by technique at higher loads in the initial and sustained phases, with pushing inducing the greatest hand forces. Comparison of the motion phases revealed significant differences between all three phases, with the initial phase evidencing the greatest hand forces. Muscle activity responses demonstrated that unloaded backward walking evoked significantly higher muscle activation than did unloaded forward walking whilst increased muscular activity during load movement compared to unloaded walking was observed. However increasing load from 250kg to 500kg did not significantly impact the majority of muscle activity responses. When considering technique effects on muscle activity, of the significant differences found, all indicated that pushing imposed the least demand on the musculoskeletal system. Gait pattern responses were not significantly affected by load/technique combinations and were similar to those elicited during normal, unloaded walking. Perceptually, increased load led to increased perception of discomfort while pushing resulted in the least discomfort at both loads. From these psychophysical responses, the calves, shoulders and biceps were identified as areas of potential musculoskeletal injury, particularly during one and two handed pulling. Pushing elicited the highest hand forces and the lowest muscle activity responses in the majority of the conditions whilst psychophysical responses identified this technique as most satisfactory. Current results advocate the use of pushing when moving a load using a wheeled device. Suitability of one and two handed pulling remains contradictory, however results suggest that one handed pulling be employed at lower loads and two handed pulling at higher loads.
- Full Text:
- Date Issued: 2009
Salinity induced physiological responses in juvenile dusky kob, Argyrosomus japonicus (Sciaenidae)
- Authors: Bernatzeder, Andrea Katinka
- Date: 2009
- Subjects: Osmoregulation , Argyrosomus -- Effects of salt on -- South Africa , Sciaenidae -- Effects of salt on -- South Africa , Argyrosomus -- Physiology , Sciaenidae -- Physiology , Fishes -- Physiology , Biological control systems , Marine ecology -- South Africa , Fishery management -- South Africa , Mariculture -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5318 , http://hdl.handle.net/10962/d1005163 , Osmoregulation , Argyrosomus -- Effects of salt on -- South Africa , Sciaenidae -- Effects of salt on -- South Africa , Argyrosomus -- Physiology , Sciaenidae -- Physiology , Fishes -- Physiology , Biological control systems , Marine ecology -- South Africa , Fishery management -- South Africa , Mariculture -- South Africa
- Description: Fisheries management regulations for dusky kob Argyrosomus japonicus, an important commercial and recreational fisheries species, have failed and the stock is considered collapsed. It is important to take an ecosystems approach to management which includes understanding the effect of environmental factors on recruitment, abundance and distribution. The distribution of early juveniles (20-150 mm TL) in the wild appears to be restricted to the upper reaches of estuaries at salinities below 5 psu. Food availability could not explain the distribution of early juveniles. The aim of this study was to investigate the role of salinity on the distribution of early juvenile dusky kob (<150 mm TL) by examining physiological responses of juveniles exposed to a range of salinities under laboratory conditions. The hypothesis was that the physiological functioning of early juveniles would be optimised at the reduced salinities which they naturally occur at. The objectives of this study were to investigate the effect of salinity on: i) plasma osmolality; ii) growth, food conversion ratio and condition factor; and iii) gill histology with emphasis on chloride cell size and number. A preliminary study was undertaken to determine whether the use of 2-phenoxyethanol had an effect on plasma osmolality. Juveniles pithed prior to blood sampling were used as the control. Plasma osmolality was not affected by exposure or duration of exposure (2, 4, 6, 8, 10 min) to 2-phenoxyethanol. The ability of teleosts to regulate plasma osmolality over a wide range of salinities indicates their degree of ‘physiological euryhalinity’. Plasma osmolality of juveniles exposed to 5, 12 and 35 psu was measured every two weeks over a total of six weeks. Although juveniles were able to regulate plasma osmolality over the duration of the experiment, plasma osmolality at 5 and 12 psu was significantly lower than in fish maintained at 35 psu. Growth is used as an indicator of the relative energy used for osmoregulation at different salinities, as the energy used for osmoregulation becomes unavailable for growth. A nineweek growth experiment was conducted on juveniles exposed to 5, 12 and 35 psu. Juveniles grew and survived at all three salinities. However, growth of juveniles at 5 psu was significantly lower than at 12 and 35 psu. Other than a significantly greater weight gain at 35 psu relative to 12 psu, there was no significant difference in specific growth and length gain between juveniles at 12 and 35 psu. Food conversion ratio and condition factor at 12 and 35 psu were not significantly different, but food conversion ratio and condition factor at 5 psu was significantly greater and lower than at 35 psu respectively. In fish, gills are considered the major organ involved in osmoregulation. Within the gills, chloride cells are the predominant site of ion exchange which is driven by the Na⁺, K⁺- ATPase enzyme. Gill samples of juveniles exposed to 5, 12 and 35 psu for six weeks were examined histologically using light microscopy. Chloride cells of juveniles maintained at 5 psu were significantly more abundant than in juveniles at 12 and 35 psu. Chloride cells of juveniles at 5 psu were significantly larger than in juveniles kept at 12 psu, but not significantly different to those of juveniles kept at 35 psu. The ability of the juvenile fish to regulate plasma osmolality indicates that they are 'physiologically euryhaline', but the reduced growth and proliferation of chloride cells at 5 psu suggests that energy expenditure for osmoregulation is increased at hypoosmotic salinities. Salinity induced physiological responses could therefore not explain the natural distribution of early juvenile dusky kob and it is proposed that other environmental factors (e.g. temperature) are also important. It is also hypothesised that the high conductivity of an estuary in South Africa, to which our understanding is limited, may negate the effect of reduced salinity. Although freshwater input into estuaries is an important factor, further investigations to explain the distribution and abundance of early juveniles is required to make management recommendations. Dusky kob is also becoming an increasingly popular aquaculture species in South Africa. In this regard, early juvenile dusky kob can be grown at salinities as low as 12 psu without negatively affecting growth and production.
- Full Text:
- Date Issued: 2009
- Authors: Bernatzeder, Andrea Katinka
- Date: 2009
- Subjects: Osmoregulation , Argyrosomus -- Effects of salt on -- South Africa , Sciaenidae -- Effects of salt on -- South Africa , Argyrosomus -- Physiology , Sciaenidae -- Physiology , Fishes -- Physiology , Biological control systems , Marine ecology -- South Africa , Fishery management -- South Africa , Mariculture -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5318 , http://hdl.handle.net/10962/d1005163 , Osmoregulation , Argyrosomus -- Effects of salt on -- South Africa , Sciaenidae -- Effects of salt on -- South Africa , Argyrosomus -- Physiology , Sciaenidae -- Physiology , Fishes -- Physiology , Biological control systems , Marine ecology -- South Africa , Fishery management -- South Africa , Mariculture -- South Africa
- Description: Fisheries management regulations for dusky kob Argyrosomus japonicus, an important commercial and recreational fisheries species, have failed and the stock is considered collapsed. It is important to take an ecosystems approach to management which includes understanding the effect of environmental factors on recruitment, abundance and distribution. The distribution of early juveniles (20-150 mm TL) in the wild appears to be restricted to the upper reaches of estuaries at salinities below 5 psu. Food availability could not explain the distribution of early juveniles. The aim of this study was to investigate the role of salinity on the distribution of early juvenile dusky kob (<150 mm TL) by examining physiological responses of juveniles exposed to a range of salinities under laboratory conditions. The hypothesis was that the physiological functioning of early juveniles would be optimised at the reduced salinities which they naturally occur at. The objectives of this study were to investigate the effect of salinity on: i) plasma osmolality; ii) growth, food conversion ratio and condition factor; and iii) gill histology with emphasis on chloride cell size and number. A preliminary study was undertaken to determine whether the use of 2-phenoxyethanol had an effect on plasma osmolality. Juveniles pithed prior to blood sampling were used as the control. Plasma osmolality was not affected by exposure or duration of exposure (2, 4, 6, 8, 10 min) to 2-phenoxyethanol. The ability of teleosts to regulate plasma osmolality over a wide range of salinities indicates their degree of ‘physiological euryhalinity’. Plasma osmolality of juveniles exposed to 5, 12 and 35 psu was measured every two weeks over a total of six weeks. Although juveniles were able to regulate plasma osmolality over the duration of the experiment, plasma osmolality at 5 and 12 psu was significantly lower than in fish maintained at 35 psu. Growth is used as an indicator of the relative energy used for osmoregulation at different salinities, as the energy used for osmoregulation becomes unavailable for growth. A nineweek growth experiment was conducted on juveniles exposed to 5, 12 and 35 psu. Juveniles grew and survived at all three salinities. However, growth of juveniles at 5 psu was significantly lower than at 12 and 35 psu. Other than a significantly greater weight gain at 35 psu relative to 12 psu, there was no significant difference in specific growth and length gain between juveniles at 12 and 35 psu. Food conversion ratio and condition factor at 12 and 35 psu were not significantly different, but food conversion ratio and condition factor at 5 psu was significantly greater and lower than at 35 psu respectively. In fish, gills are considered the major organ involved in osmoregulation. Within the gills, chloride cells are the predominant site of ion exchange which is driven by the Na⁺, K⁺- ATPase enzyme. Gill samples of juveniles exposed to 5, 12 and 35 psu for six weeks were examined histologically using light microscopy. Chloride cells of juveniles maintained at 5 psu were significantly more abundant than in juveniles at 12 and 35 psu. Chloride cells of juveniles at 5 psu were significantly larger than in juveniles kept at 12 psu, but not significantly different to those of juveniles kept at 35 psu. The ability of the juvenile fish to regulate plasma osmolality indicates that they are 'physiologically euryhaline', but the reduced growth and proliferation of chloride cells at 5 psu suggests that energy expenditure for osmoregulation is increased at hypoosmotic salinities. Salinity induced physiological responses could therefore not explain the natural distribution of early juvenile dusky kob and it is proposed that other environmental factors (e.g. temperature) are also important. It is also hypothesised that the high conductivity of an estuary in South Africa, to which our understanding is limited, may negate the effect of reduced salinity. Although freshwater input into estuaries is an important factor, further investigations to explain the distribution and abundance of early juveniles is required to make management recommendations. Dusky kob is also becoming an increasingly popular aquaculture species in South Africa. In this regard, early juvenile dusky kob can be grown at salinities as low as 12 psu without negatively affecting growth and production.
- Full Text:
- Date Issued: 2009
Curiosity first, applications later
- Berold, Robert, Limson, Janice L
- Authors: Berold, Robert , Limson, Janice L
- Date: 2009
- Subjects: Nyokong, Tebello
- Language: English
- Type: Article , text
- Identifier: vital:7188 , http://hdl.handle.net/10962/d1006281 , http://www.sajs.co.za/sites/default/files/publications/pdf/1-4-1-PB.pdf , Nyokong, Tebello
- Description: Tebello Nyokong speaks to Robert Berold and Janice Limson about her career as a chemist. Tebello Nyokong, who holds a research chair in medicinal chemistry and nanotechnology at Rhodes University, has become the first South African scientist to win the L’Oreal-UNESCO award for women in science, in the physical sciences. Only one laureate is selected from each of five world regions, and Nyokong is the 2009 laureate for Africa and the Arab states. She and the winners from the other four regions travel to Paris in March to each accept the award and a generous prize of close to R1 million. Nyokong now heads the new Nanotechnology Innovation Centre for medical sensors: the biggest single research investment in the history of Rhodes. Linked to other nanotechnology centres in the country, it is designed to bridge the gap between research and the market.
- Full Text:
- Date Issued: 2009
- Authors: Berold, Robert , Limson, Janice L
- Date: 2009
- Subjects: Nyokong, Tebello
- Language: English
- Type: Article , text
- Identifier: vital:7188 , http://hdl.handle.net/10962/d1006281 , http://www.sajs.co.za/sites/default/files/publications/pdf/1-4-1-PB.pdf , Nyokong, Tebello
- Description: Tebello Nyokong speaks to Robert Berold and Janice Limson about her career as a chemist. Tebello Nyokong, who holds a research chair in medicinal chemistry and nanotechnology at Rhodes University, has become the first South African scientist to win the L’Oreal-UNESCO award for women in science, in the physical sciences. Only one laureate is selected from each of five world regions, and Nyokong is the 2009 laureate for Africa and the Arab states. She and the winners from the other four regions travel to Paris in March to each accept the award and a generous prize of close to R1 million. Nyokong now heads the new Nanotechnology Innovation Centre for medical sensors: the biggest single research investment in the history of Rhodes. Linked to other nanotechnology centres in the country, it is designed to bridge the gap between research and the market.
- Full Text:
- Date Issued: 2009
The feasibility of starting a dating company in South Africa
- Bezuidenhout, Jacques Du Mont
- Authors: Bezuidenhout, Jacques Du Mont
- Date: 2009
- Subjects: Online dating -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8686 , http://hdl.handle.net/10948/1114 , Online dating -- South Africa
- Description: The purpose of the research is to determine the feasibility of starting a dating company, which focuses specifically on the South African market. Further sub problems were defined as follow: • Which South Africans would use a dating service, that is, who will be the main customers? • Is there specifically identifiable information that can help to recognise customers? Or can a profile be created for to identify customers? • How much are the customers willing to pay? • Does or can technology play a role in in courtship? The role of technology was investigated, in which it was found that globalisation affects everyone. One of the core factors that caused many other technologies to evolve from it, is the Internet. The intranet was a natural evolution from the Internet, which is normally specific to a company. A further literature survey was conducted to gain an understanding of dating companies globally and locally, to gain an understanding of the subject, which was used to create a questionnaire. The questionnaire reached a 120 participants, with 52 participants responding, which relates to a response rate of 43.3 percent. The questionnaire produces 37 variables, which were correlated, and as a result it was recommended that it is feasible to start a dating company in South Africa.
- Full Text:
- Date Issued: 2009
- Authors: Bezuidenhout, Jacques Du Mont
- Date: 2009
- Subjects: Online dating -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8686 , http://hdl.handle.net/10948/1114 , Online dating -- South Africa
- Description: The purpose of the research is to determine the feasibility of starting a dating company, which focuses specifically on the South African market. Further sub problems were defined as follow: • Which South Africans would use a dating service, that is, who will be the main customers? • Is there specifically identifiable information that can help to recognise customers? Or can a profile be created for to identify customers? • How much are the customers willing to pay? • Does or can technology play a role in in courtship? The role of technology was investigated, in which it was found that globalisation affects everyone. One of the core factors that caused many other technologies to evolve from it, is the Internet. The intranet was a natural evolution from the Internet, which is normally specific to a company. A further literature survey was conducted to gain an understanding of dating companies globally and locally, to gain an understanding of the subject, which was used to create a questionnaire. The questionnaire reached a 120 participants, with 52 participants responding, which relates to a response rate of 43.3 percent. The questionnaire produces 37 variables, which were correlated, and as a result it was recommended that it is feasible to start a dating company in South Africa.
- Full Text:
- Date Issued: 2009
Creating a virtual classroom: evaluating the use of online discussion forums to increase teaching and learning activities
- Authors: Bezuidenhout, L Peta
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: Conference paper
- Identifier: vital:6070 , http://hdl.handle.net/10962/d1004635
- Description: In teaching large classes, the educationally beneficial informal interaction between students and between lecturer and students is generally reduced, while effective use of both students’ and lecturer’s time is often a challenge. During student consultations, especially over the already stressful test and examination periods, many of the questions asked by the students are the same or similar. The lecturer needs to respond to each query by providing the same detailed explanation for the problem, resulting in ineffective use of time for the lecturer, while students waste time waiting for an appointment, or more often, simply don’t bother to follow up on any queries they may have. Having a social presence is important for students’ cognitive development, but in a large class posing questions or interrogating issues during a lecture appears to be challenging for many students. It is often not easy for students to initiate discussions or establish relationships with peers or the lecturer due to feelings of vulnerability and due to the size and impersonal atmosphere of the lecture theatre. This paper deals with the introduction of online discussion forums in an introductory accounting course and the benefits and problems experienced by the students, tutors and lecturer as a result thereof. Feedback received from these participants is discussed. The introduction and use of these forums resulted in a virtual classroom being created, where significantly more teaching and learning activities took place, to the benefit of all participants. Participation could have been peripheral -in the form of simply reading discussions; or active – through posting questions, or responding to questions.
- Full Text:
- Date Issued: 2009
- Authors: Bezuidenhout, L Peta
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: Conference paper
- Identifier: vital:6070 , http://hdl.handle.net/10962/d1004635
- Description: In teaching large classes, the educationally beneficial informal interaction between students and between lecturer and students is generally reduced, while effective use of both students’ and lecturer’s time is often a challenge. During student consultations, especially over the already stressful test and examination periods, many of the questions asked by the students are the same or similar. The lecturer needs to respond to each query by providing the same detailed explanation for the problem, resulting in ineffective use of time for the lecturer, while students waste time waiting for an appointment, or more often, simply don’t bother to follow up on any queries they may have. Having a social presence is important for students’ cognitive development, but in a large class posing questions or interrogating issues during a lecture appears to be challenging for many students. It is often not easy for students to initiate discussions or establish relationships with peers or the lecturer due to feelings of vulnerability and due to the size and impersonal atmosphere of the lecture theatre. This paper deals with the introduction of online discussion forums in an introductory accounting course and the benefits and problems experienced by the students, tutors and lecturer as a result thereof. Feedback received from these participants is discussed. The introduction and use of these forums resulted in a virtual classroom being created, where significantly more teaching and learning activities took place, to the benefit of all participants. Participation could have been peripheral -in the form of simply reading discussions; or active – through posting questions, or responding to questions.
- Full Text:
- Date Issued: 2009
Critical analysis of the 2007 public service strike and its impact on the evolution of formalised collective bargaining in South Africa
- Authors: Bhe, Vuyisile
- Date: 2009
- Subjects: Collective bargaining -- South Africa , Dispute resolution (Law) -- South Africa , Strikes and lockouts -- Law and legislation -- South Africa , Labor laws and legislation -- South Africa , Industrial relations -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:10192 , http://hdl.handle.net/10948/1043 , Collective bargaining -- South Africa , Dispute resolution (Law) -- South Africa , Strikes and lockouts -- Law and legislation -- South Africa , Labor laws and legislation -- South Africa , Industrial relations -- South Africa
- Description: Section 213 of the Labour Relations Act defines ’strike’ as the partial or complete concerted refusal to work, or the retardation or obstruction of work, by persons who are or have been employed by the same employer or by different employers, for the purpose of remedying a grievance or resolving a dispute in respect of any matter of mutual interest between the employer and employee, and any reference to “work” this definition includes overtime work, whether it is voluntary or compulsory. According to Mcllroy: “As long as our society is divided between those who own and control the means of production and those who only have the ability to work, strikes will be inevitable because they are the ultimate means workers have of protecting themselves.” 1 The Constitutional Court justified the exclusion of a constitutional right to lock out and the inclusion of a constitutional right to strike by indicating that the right to strike is not equivalent to a right to lock out and is essential for workplace democracy. 2 The right to strike is essential to bolster collective bargaining and thereby to give employees the power to bargain effectively with employers. The employers on the According to the Constitutional Court employers enjoy greater social and economic power compared to individual workers and may exercise a wide range of power against workers through a range of weapons, such as dismissal, the employment of alternative or replacement labour, the unilateral implementation of new terms and conditions of employment, and the exclusion of workers from the workplace. To combat this and have a say in the workplace, the Constitutional Court held that “employees need to act in concert to provide them collectively with sufficient power to bargain effectively with employers and exercise collective power primarily through the mechanism of strike action”. The importance of the right to strike in creating workplace democracy is also reflected in a number of Labour Court and Labour Appeal Court judgments. other hand have economic strength that is used to bargain effectively. That is why the strike enjoys constitutional protection, whereas the lock-out does not. , Abstract
- Full Text:
- Date Issued: 2009
- Authors: Bhe, Vuyisile
- Date: 2009
- Subjects: Collective bargaining -- South Africa , Dispute resolution (Law) -- South Africa , Strikes and lockouts -- Law and legislation -- South Africa , Labor laws and legislation -- South Africa , Industrial relations -- South Africa
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: vital:10192 , http://hdl.handle.net/10948/1043 , Collective bargaining -- South Africa , Dispute resolution (Law) -- South Africa , Strikes and lockouts -- Law and legislation -- South Africa , Labor laws and legislation -- South Africa , Industrial relations -- South Africa
- Description: Section 213 of the Labour Relations Act defines ’strike’ as the partial or complete concerted refusal to work, or the retardation or obstruction of work, by persons who are or have been employed by the same employer or by different employers, for the purpose of remedying a grievance or resolving a dispute in respect of any matter of mutual interest between the employer and employee, and any reference to “work” this definition includes overtime work, whether it is voluntary or compulsory. According to Mcllroy: “As long as our society is divided between those who own and control the means of production and those who only have the ability to work, strikes will be inevitable because they are the ultimate means workers have of protecting themselves.” 1 The Constitutional Court justified the exclusion of a constitutional right to lock out and the inclusion of a constitutional right to strike by indicating that the right to strike is not equivalent to a right to lock out and is essential for workplace democracy. 2 The right to strike is essential to bolster collective bargaining and thereby to give employees the power to bargain effectively with employers. The employers on the According to the Constitutional Court employers enjoy greater social and economic power compared to individual workers and may exercise a wide range of power against workers through a range of weapons, such as dismissal, the employment of alternative or replacement labour, the unilateral implementation of new terms and conditions of employment, and the exclusion of workers from the workplace. To combat this and have a say in the workplace, the Constitutional Court held that “employees need to act in concert to provide them collectively with sufficient power to bargain effectively with employers and exercise collective power primarily through the mechanism of strike action”. The importance of the right to strike in creating workplace democracy is also reflected in a number of Labour Court and Labour Appeal Court judgments. other hand have economic strength that is used to bargain effectively. That is why the strike enjoys constitutional protection, whereas the lock-out does not. , Abstract
- Full Text:
- Date Issued: 2009
A public-private partnership model for the improvemnet of local economic development in South African metropolitan government
- Binza, Mzikayise Shakespeare
- Authors: Binza, Mzikayise Shakespeare
- Date: 2009
- Subjects: Economic development -- South Africa , Public-private sector cooperation -- South Africa , South Africa -- Economic conditions
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: vital:8159 , http://hdl.handle.net/10948/923 , Economic development -- South Africa , Public-private sector cooperation -- South Africa , South Africa -- Economic conditions
- Description: The post-apartheid developmental state of South Africa had a challenge of turning around an economy that was on deficit which it inherited in 1994, to a positive growth that will be sustainable and shared. The process followed in creating a sustainable economic development was first establishing a constitutional democratic government which was constituted in terms of the provisions of the Constitution of the Republic of South Africa, 1996, as three equal spheres of government, viz: the national, provincial and local spheres of government. Initiatives on innovative economic development become a reconstruction programme not only of the national and provincial spheres of government, but also of the local sphere of government which is closest to the people it governs and deliver municipal goods and services to. For an example, section 152 (1) (c) of the Constitution of the Republic of South Africa, 1996, provides that the local sphere of government which is constituted by 283 wall-to-wall municipalities must “improve social and economic development” of the people. Out of the 283 municipalities, 6 are metropolitan municipalities, and are the: City of Cape Town, City of Johannesburg, City of Tshwane, Ekurhuleni, Ethekwini, and Nelson Mandela Bay Municipality. This research project is limited to the City of Cape Town (CCT) and the Nelson Mandela Bay Municipalities (NMBM). In the second process, a number of legislations and policies providing for external mechanisms to be used to improve local economic development (LED) in an inclusive, shared and equitable manner were introduced. Policies that were introduced by the democratic government and serve as policy directive for economic development are: the Reconstruction and Development Programme (RDP) of 1994; the Growth, Employment and Redistribution (GEAR) of 1996; and the Accelerated and Shared Growth Initiative of South Africa (ASGISA) of 2006. The relevant legislations to the local sphere of government which were introduced and provided for the appropriate mechanism for enabling sustainable growth of local economies by developmental local government in partnerships with other stakeholders such as private sector and civil society movements are: the Local Government: Municipal Systems Act, 2000 (Act 32 of 2000); Municipal Service Policy of 2000; Guidelines on Municipal Service Partnerships of 2006-2010; and the National Framework for Local Economic Development in South Africa (NFLED) of 2006-2010. The above xviii legislations provide the following external mechanisms to improve local economic development in municipal areas, viz: public-private partnerships; public-public partnerships, and public-community partnerships. This research project is about the first external mechanism which is the public-private partnerships (PPPs) to enable municipalities to improve local economies that provide for job creations and employment for the local inhabitants. According to the National Treasury Regulation 16 (2004:1), PPP means a “commercial transaction between an institution, for example a metropolitan government, and a private party in terms of which: 1. The private party either performs an institutional function on behalf of the institution [in this regard a metropolitan government] for a specified or indefinite period or acquires the use of a state property for its own commercial purposes for a specified or indefinite period. 2. The private party receives a benefit for performing the function or by utilising state property, either by way of compensation from a revenue fund, or by charges or fees collected by the private party from users or customers of a service provided for them; or a combination of such compensation and such fees”. The first goal of this research project is to develop the most appropriate public-private partnership model for South African metropolitan government with special reference to the City of Cape Town (CCT) and the Nelson Mandela Bay Municipality (NMBM) in enabling and guiding them to improve and sustain local economic development (LED) in their respective areas of jurisdiction. The application of public-private partnerships (PPPs) as a policy strategy to achieve local economic development (LED) in CCT and NMBM was investigated, in order to determine whether these activities can be improved. Followed is the development of a conceptual framework for optimal PPP implementation in order to improve local economic development in the CCT and NMBM and other metropolitan and municipal areas in South Africa. A more appropriate PPP model called the Participatory Development Systems Model (PDSM) has been constructed for this purpose from a number of sources and proven good practices both locally in South Africa and internationally. The PDSM model uses the strategic prioritisation and management by a municipality of the integrated development of physical, economic, human and social capital in its region in a more participatory way, as a point of departure for PPPs. The PDSM model for PPPs also emphasises consistent systematic assessment of these strategies against the strategic LED goals of the municipality concerned in order to ensure that lessons are learnt from these experiences and used to refine or revise future LED and PPP strategies accordingly. This thesis makes an original contribution to the existing body of knowledge about the promotion of LED through PPPs in metropolitan municipalities in South Africa and elsewhere, by conceptualising PPPs in a clear and coherent way as an integrated dimension of strategic management processes in municipalities that need to be implemented in a more participatory way in order to achieve the overall strategic goal of sustainable LED.
- Full Text:
- Date Issued: 2009
- Authors: Binza, Mzikayise Shakespeare
- Date: 2009
- Subjects: Economic development -- South Africa , Public-private sector cooperation -- South Africa , South Africa -- Economic conditions
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: vital:8159 , http://hdl.handle.net/10948/923 , Economic development -- South Africa , Public-private sector cooperation -- South Africa , South Africa -- Economic conditions
- Description: The post-apartheid developmental state of South Africa had a challenge of turning around an economy that was on deficit which it inherited in 1994, to a positive growth that will be sustainable and shared. The process followed in creating a sustainable economic development was first establishing a constitutional democratic government which was constituted in terms of the provisions of the Constitution of the Republic of South Africa, 1996, as three equal spheres of government, viz: the national, provincial and local spheres of government. Initiatives on innovative economic development become a reconstruction programme not only of the national and provincial spheres of government, but also of the local sphere of government which is closest to the people it governs and deliver municipal goods and services to. For an example, section 152 (1) (c) of the Constitution of the Republic of South Africa, 1996, provides that the local sphere of government which is constituted by 283 wall-to-wall municipalities must “improve social and economic development” of the people. Out of the 283 municipalities, 6 are metropolitan municipalities, and are the: City of Cape Town, City of Johannesburg, City of Tshwane, Ekurhuleni, Ethekwini, and Nelson Mandela Bay Municipality. This research project is limited to the City of Cape Town (CCT) and the Nelson Mandela Bay Municipalities (NMBM). In the second process, a number of legislations and policies providing for external mechanisms to be used to improve local economic development (LED) in an inclusive, shared and equitable manner were introduced. Policies that were introduced by the democratic government and serve as policy directive for economic development are: the Reconstruction and Development Programme (RDP) of 1994; the Growth, Employment and Redistribution (GEAR) of 1996; and the Accelerated and Shared Growth Initiative of South Africa (ASGISA) of 2006. The relevant legislations to the local sphere of government which were introduced and provided for the appropriate mechanism for enabling sustainable growth of local economies by developmental local government in partnerships with other stakeholders such as private sector and civil society movements are: the Local Government: Municipal Systems Act, 2000 (Act 32 of 2000); Municipal Service Policy of 2000; Guidelines on Municipal Service Partnerships of 2006-2010; and the National Framework for Local Economic Development in South Africa (NFLED) of 2006-2010. The above xviii legislations provide the following external mechanisms to improve local economic development in municipal areas, viz: public-private partnerships; public-public partnerships, and public-community partnerships. This research project is about the first external mechanism which is the public-private partnerships (PPPs) to enable municipalities to improve local economies that provide for job creations and employment for the local inhabitants. According to the National Treasury Regulation 16 (2004:1), PPP means a “commercial transaction between an institution, for example a metropolitan government, and a private party in terms of which: 1. The private party either performs an institutional function on behalf of the institution [in this regard a metropolitan government] for a specified or indefinite period or acquires the use of a state property for its own commercial purposes for a specified or indefinite period. 2. The private party receives a benefit for performing the function or by utilising state property, either by way of compensation from a revenue fund, or by charges or fees collected by the private party from users or customers of a service provided for them; or a combination of such compensation and such fees”. The first goal of this research project is to develop the most appropriate public-private partnership model for South African metropolitan government with special reference to the City of Cape Town (CCT) and the Nelson Mandela Bay Municipality (NMBM) in enabling and guiding them to improve and sustain local economic development (LED) in their respective areas of jurisdiction. The application of public-private partnerships (PPPs) as a policy strategy to achieve local economic development (LED) in CCT and NMBM was investigated, in order to determine whether these activities can be improved. Followed is the development of a conceptual framework for optimal PPP implementation in order to improve local economic development in the CCT and NMBM and other metropolitan and municipal areas in South Africa. A more appropriate PPP model called the Participatory Development Systems Model (PDSM) has been constructed for this purpose from a number of sources and proven good practices both locally in South Africa and internationally. The PDSM model uses the strategic prioritisation and management by a municipality of the integrated development of physical, economic, human and social capital in its region in a more participatory way, as a point of departure for PPPs. The PDSM model for PPPs also emphasises consistent systematic assessment of these strategies against the strategic LED goals of the municipality concerned in order to ensure that lessons are learnt from these experiences and used to refine or revise future LED and PPP strategies accordingly. This thesis makes an original contribution to the existing body of knowledge about the promotion of LED through PPPs in metropolitan municipalities in South Africa and elsewhere, by conceptualising PPPs in a clear and coherent way as an integrated dimension of strategic management processes in municipalities that need to be implemented in a more participatory way in order to achieve the overall strategic goal of sustainable LED.
- Full Text:
- Date Issued: 2009
Human-river relationships in the Kat River catchment and the implications for integrated water resource management (IWRM) : an exploraratory study
- Authors: Birkholz, Sharon Alice
- Date: 2009
- Subjects: Aquatic ecology -- South Africa -- Kat River , Rivers -- South Africa -- Kat River -- Sociological aspects , Rivers -- South Africa -- Kat River , Water supply -- South Africa -- Kat River -- Management , Human ecology -- South Africa -- Kat River , Stream ecology -- South Africa -- Kat River
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: vital:4838 , http://hdl.handle.net/10962/d1005514
- Description: Through out this study ‘relational scenarios’ were seen as the possible outcomes of the expression of human-river relationships in a catchment. Working within Inglis’s (2008, pg. 10) comment that ‘the Human World Relationship is expressed through a person’s views and behaviour towards the natural world, which can be either constructive or destructive’, two relational scenarios were selected to represent these two predicted outcomes of human-environment (or in the case of this thesis human-river) relationships: IWRM, seen as constructive and mutually beneficial to both the social and ecological system, and the Tragedy of the Commons, seen as destructive and parasitic in nature. In respect to this assertion, a conceptual framework or model was developed and used to guide the inductive process of this research. Through a social survey (administered via semi-structured interviews) of stakeholders (water-users) in the Kat River Catchment, Eastern Cape, South Africa, social attitudes towards the Kat River were explored. These attitudes were considered as variables that relate to the expression of ‘Human World Relationships’ namely ‘values and behaviour’ (Inglis, 2008, pg. 10). The findings of this thesis confirm that attitudes are influential components of human-river relationships in the Kat River Catchment. It was observed from the findings that the attitudes individuals have towards the Kat River have the potential to influence the ways people interact with the River and its associated resources, and are in turn influenced by the condition of the River and connections people have or make with the River within their daily lives. Such relationships in turn affect the management of the River and its water resources and influence how individuals approach water-related issues and undertake the associated activities. Given this understanding it was then proposed that attitudes could provide information that enables the prediction of likely ‘relational scenarios’ (IWRM or the Tragedy of the Commons) in a catchment. The findings appear to support this proposal, and three main attitude groups (utilitarian, associative and dissociative) were identified and used to further the discussion into how this knowledge could be used in predicting possible relational scenarios based on human-river relationships. Further exploration of the identified attitude groups suggested that these variables are significantly influenced by environmental ethics and place attachment (present in the community) and a series of guiding frameworks were developed to facilitate the exploration of the attitude groups relative to these concepts. The frameworks were generated from the hypothesis that knowledge of attitude groups in a catchment, in connection with the relative degrees to which moral values and worldviews are expressed, could provide insight into the readiness of a catchment system for the implementation of IWRM and/or the facilitative steps needed to shift the influence of unfavourable attitude groups (i.e. dissociative attitudes). Such steps would most likely involve extensive educational, awareness and capacity building programs. Finally, given the above theoretical frameworks, inductively developed from the findings of the social survey and related literature, the conceptual model was reevaluated and extended to include the thesis findings and hypotheses. It is suggested that in a catchment where there is a balance between the expression of utilitarian and associative attitude groups, then there is a high probability of finding present evidence of mutually beneficial human-river relationships already in play, as well as ‘fertile soil’ for the promotion of IWRM and philosophies and skills that generate such relationships. Alternatively in an area with a strong expression of dissociative attitudes, it is more likely to find evidence of destructive, more parasitic-like relationships being expressed, and a lack of commitment and interest in being involved in changing the status quo. It is likely that where both associative and dissociative attitudes are present there will be an overlap of elements of both scenarios – a situation that is probable in most catchments – depending on the strength of expression of either attitude group the balance will shift (be shifting) between the two relational scenarios.
- Full Text:
- Date Issued: 2009
- Authors: Birkholz, Sharon Alice
- Date: 2009
- Subjects: Aquatic ecology -- South Africa -- Kat River , Rivers -- South Africa -- Kat River -- Sociological aspects , Rivers -- South Africa -- Kat River , Water supply -- South Africa -- Kat River -- Management , Human ecology -- South Africa -- Kat River , Stream ecology -- South Africa -- Kat River
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: vital:4838 , http://hdl.handle.net/10962/d1005514
- Description: Through out this study ‘relational scenarios’ were seen as the possible outcomes of the expression of human-river relationships in a catchment. Working within Inglis’s (2008, pg. 10) comment that ‘the Human World Relationship is expressed through a person’s views and behaviour towards the natural world, which can be either constructive or destructive’, two relational scenarios were selected to represent these two predicted outcomes of human-environment (or in the case of this thesis human-river) relationships: IWRM, seen as constructive and mutually beneficial to both the social and ecological system, and the Tragedy of the Commons, seen as destructive and parasitic in nature. In respect to this assertion, a conceptual framework or model was developed and used to guide the inductive process of this research. Through a social survey (administered via semi-structured interviews) of stakeholders (water-users) in the Kat River Catchment, Eastern Cape, South Africa, social attitudes towards the Kat River were explored. These attitudes were considered as variables that relate to the expression of ‘Human World Relationships’ namely ‘values and behaviour’ (Inglis, 2008, pg. 10). The findings of this thesis confirm that attitudes are influential components of human-river relationships in the Kat River Catchment. It was observed from the findings that the attitudes individuals have towards the Kat River have the potential to influence the ways people interact with the River and its associated resources, and are in turn influenced by the condition of the River and connections people have or make with the River within their daily lives. Such relationships in turn affect the management of the River and its water resources and influence how individuals approach water-related issues and undertake the associated activities. Given this understanding it was then proposed that attitudes could provide information that enables the prediction of likely ‘relational scenarios’ (IWRM or the Tragedy of the Commons) in a catchment. The findings appear to support this proposal, and three main attitude groups (utilitarian, associative and dissociative) were identified and used to further the discussion into how this knowledge could be used in predicting possible relational scenarios based on human-river relationships. Further exploration of the identified attitude groups suggested that these variables are significantly influenced by environmental ethics and place attachment (present in the community) and a series of guiding frameworks were developed to facilitate the exploration of the attitude groups relative to these concepts. The frameworks were generated from the hypothesis that knowledge of attitude groups in a catchment, in connection with the relative degrees to which moral values and worldviews are expressed, could provide insight into the readiness of a catchment system for the implementation of IWRM and/or the facilitative steps needed to shift the influence of unfavourable attitude groups (i.e. dissociative attitudes). Such steps would most likely involve extensive educational, awareness and capacity building programs. Finally, given the above theoretical frameworks, inductively developed from the findings of the social survey and related literature, the conceptual model was reevaluated and extended to include the thesis findings and hypotheses. It is suggested that in a catchment where there is a balance between the expression of utilitarian and associative attitude groups, then there is a high probability of finding present evidence of mutually beneficial human-river relationships already in play, as well as ‘fertile soil’ for the promotion of IWRM and philosophies and skills that generate such relationships. Alternatively in an area with a strong expression of dissociative attitudes, it is more likely to find evidence of destructive, more parasitic-like relationships being expressed, and a lack of commitment and interest in being involved in changing the status quo. It is likely that where both associative and dissociative attitudes are present there will be an overlap of elements of both scenarios – a situation that is probable in most catchments – depending on the strength of expression of either attitude group the balance will shift (be shifting) between the two relational scenarios.
- Full Text:
- Date Issued: 2009
Reform in defence of sovereignty: South Africa in the UN Security Council, 2007–2008
- Authors: Bischoff, Paul, 1954-
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/161431 , vital:40626 , https://0-doi.org.wam.seals.ac.za/10.1177/000203970904400205
- Description: After 1994, South Africa became the sine qua non of an internationalist state, willing to promote cooperation amongst a plurality of actors, believing common interests to be more important than their differences. This raised the hopes of constitutionalists, and those who believed in the expansion of a liberal democratic peace. South Africa has acted out two seemingly contradictory roles: those of a reformer and those of a conserver. By 2007–2008 she had shifted towards the latter, conservative-reformist position. Thus, South Africa's voting record at the General Assembly expressed her overriding concern to regionalise African issues and minimise the US and the West shaping political events. This brought her foreign policy into sharper relief. But while in some sense successful, it came at a price: a controversy about her surrendering her internationalism and principles on human rights for African unity and traditional sovereignty. But it also marked the arrival of South Africa in the world of international Realpolitik.
- Full Text:
- Date Issued: 2009
- Authors: Bischoff, Paul, 1954-
- Date: 2009
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/161431 , vital:40626 , https://0-doi.org.wam.seals.ac.za/10.1177/000203970904400205
- Description: After 1994, South Africa became the sine qua non of an internationalist state, willing to promote cooperation amongst a plurality of actors, believing common interests to be more important than their differences. This raised the hopes of constitutionalists, and those who believed in the expansion of a liberal democratic peace. South Africa has acted out two seemingly contradictory roles: those of a reformer and those of a conserver. By 2007–2008 she had shifted towards the latter, conservative-reformist position. Thus, South Africa's voting record at the General Assembly expressed her overriding concern to regionalise African issues and minimise the US and the West shaping political events. This brought her foreign policy into sharper relief. But while in some sense successful, it came at a price: a controversy about her surrendering her internationalism and principles on human rights for African unity and traditional sovereignty. But it also marked the arrival of South Africa in the world of international Realpolitik.
- Full Text:
- Date Issued: 2009
The green revolution and poverty alleviation challenges faced by women in small-scale agriculture: an investigation into the Siyazondla Homestead Food Production Programme, Mbhashe local municipality Eastern Cape
- Authors: Blaai-Mdolo, Bulelwa
- Date: 2009
- Subjects: Women in agriculture -- South Africa -- Eastern Cape , Rural poor -- South Africa , Poverty -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Soc Sc (Rural Development)
- Identifier: vital:11935 , http://hdl.handle.net/10353/133 , Women in agriculture -- South Africa -- Eastern Cape , Rural poor -- South Africa , Poverty -- South Africa -- Eastern Cape
- Description: The researcher is perturbed by the escalating levels of poverty and unemployment in Mbhashe Local Municipality (Integrated Development Plan, 2008/9) despite the poverty alleviation programmes that have been established since 1994. The main objective of this study is to identify the underlying factors and challenges faced by women of the Impumelelo Isezandleni Community Garden and Poultry Project in meeting the set objectives of the programme such as improving food security and job creation through sustainable agricultural development. This project falls under the Siyazondla Homestead Food Production Programme (SHFPP), which is one of the programmes developed under the Green Revolution strategy of the Department of Agriculture. SHFPP is proclaimed to be running successfully in improving food security in the Mbhashe Local Municipality (MECDoA: 2008/9). 7 ABSTRACT The researcher is perturbed by the escalating levels of poverty and unemployment in Mbhashe Local Municipality (Integrated Development Plan, 2008/9) despite the poverty alleviation programmes that have been established since 1994. The main objective of this study is to identify the underlying factors and challenges faced by women of the Impumelelo Isezandleni Community Garden and Poultry Project in meeting the set objectives of the programme such as improving food security and job creation through sustainable agricultural development. This project falls under the Siyazondla Homestead Food Production Programme (SHFPP), which is one of the programmes developed under the Green Revolution strategy of the Department of Agriculture. SHFPP is proclaimed to be running successfully in improving food security in the Mbhashe Local Municipality (MECDoA: 2008/9). The dissertation argues that women, the beneficiaries of the project, are faced with a variety of challenges which make it impossible to meet the set objectives. Using a qualitative research methodology where semi-structured interviews gather data from 15 respondents who are beneficiaries in the project, findings indicate that there are a number of challenges and constraints that are experienced by women in the project. These challenges amongst others range from gender equity, culture and tradition; lack of provisions for diverse women population in the project; violation of the people-centered approach; limited women empowerment; insufficient support and lack of capacity from the Department of Agriculture (DoA) officials, the non-existent Land Reform Programme etc. While women seem committed and want the project to grow to sustain them, this is not complemented with enough support by the DoA. The study anticipates that should these women find viable alternatives, they will soon abandon the project. To avoid a total anticipated collapse of the project in future, the study recommends that a serious intervention by the state should occur coupled with the revitalization of the programme and a paradigm shift towards an effective food security programme which emphasizes women and their important role in agriculture.
- Full Text:
- Date Issued: 2009
- Authors: Blaai-Mdolo, Bulelwa
- Date: 2009
- Subjects: Women in agriculture -- South Africa -- Eastern Cape , Rural poor -- South Africa , Poverty -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Soc Sc (Rural Development)
- Identifier: vital:11935 , http://hdl.handle.net/10353/133 , Women in agriculture -- South Africa -- Eastern Cape , Rural poor -- South Africa , Poverty -- South Africa -- Eastern Cape
- Description: The researcher is perturbed by the escalating levels of poverty and unemployment in Mbhashe Local Municipality (Integrated Development Plan, 2008/9) despite the poverty alleviation programmes that have been established since 1994. The main objective of this study is to identify the underlying factors and challenges faced by women of the Impumelelo Isezandleni Community Garden and Poultry Project in meeting the set objectives of the programme such as improving food security and job creation through sustainable agricultural development. This project falls under the Siyazondla Homestead Food Production Programme (SHFPP), which is one of the programmes developed under the Green Revolution strategy of the Department of Agriculture. SHFPP is proclaimed to be running successfully in improving food security in the Mbhashe Local Municipality (MECDoA: 2008/9). 7 ABSTRACT The researcher is perturbed by the escalating levels of poverty and unemployment in Mbhashe Local Municipality (Integrated Development Plan, 2008/9) despite the poverty alleviation programmes that have been established since 1994. The main objective of this study is to identify the underlying factors and challenges faced by women of the Impumelelo Isezandleni Community Garden and Poultry Project in meeting the set objectives of the programme such as improving food security and job creation through sustainable agricultural development. This project falls under the Siyazondla Homestead Food Production Programme (SHFPP), which is one of the programmes developed under the Green Revolution strategy of the Department of Agriculture. SHFPP is proclaimed to be running successfully in improving food security in the Mbhashe Local Municipality (MECDoA: 2008/9). The dissertation argues that women, the beneficiaries of the project, are faced with a variety of challenges which make it impossible to meet the set objectives. Using a qualitative research methodology where semi-structured interviews gather data from 15 respondents who are beneficiaries in the project, findings indicate that there are a number of challenges and constraints that are experienced by women in the project. These challenges amongst others range from gender equity, culture and tradition; lack of provisions for diverse women population in the project; violation of the people-centered approach; limited women empowerment; insufficient support and lack of capacity from the Department of Agriculture (DoA) officials, the non-existent Land Reform Programme etc. While women seem committed and want the project to grow to sustain them, this is not complemented with enough support by the DoA. The study anticipates that should these women find viable alternatives, they will soon abandon the project. To avoid a total anticipated collapse of the project in future, the study recommends that a serious intervention by the state should occur coupled with the revitalization of the programme and a paradigm shift towards an effective food security programme which emphasizes women and their important role in agriculture.
- Full Text:
- Date Issued: 2009
The ichthyofauna associated with Taylor's salt marsh, Kariega estuary (Eastern Cape), South Africa
- Authors: Booth, Tara Loren
- Date: 2009
- Subjects: Fishes -- South Africa -- Eastern Cape , Estuaries -- South Africa -- Eastern Cape , Fish communities -- South Africa -- Eastern Cape , Salt marsh animals -- South Africa -- Eastern Cape , Eelgrass -- South Africa -- Eastern Cape , Gray mullets -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5710 , http://hdl.handle.net/10962/d1005396 , Fishes -- South Africa -- Eastern Cape , Estuaries -- South Africa -- Eastern Cape , Fish communities -- South Africa -- Eastern Cape , Salt marsh animals -- South Africa -- Eastern Cape , Eelgrass -- South Africa -- Eastern Cape , Gray mullets -- South Africa -- Eastern Cape
- Description: The spatial and temporal patterns in the ichthyofaunal community composition and structure in Taylor’s salt marsh and adjacent eelgrass beds (Zostera capensis) in the Kariega Estuary, was investigated every two months between May 2006 and March 2007. Total ichthyofaunal abundances and biomass in the salt marsh ranged between 0.55 and 21.7 ind.10m-2 and between 0.03 and 1.9 g.wwt.10m⁻², respectively. There were no significant spatial patterns in the values evident (P > 0.05 in all cases) although seasonal trends were marked, with highest values consistently recorded during the warmer summer months. Investigations into the community structure showed that the ichthyofaunal community within salt marsh was composed almost exclusively of juveniles of estuarine dependant (category II) species, mainly juvenile Mugilidae (<20mm SL) that comprised up to 83% of all fish sampled. Hierarchical cluster analysis and multidimensional scaling did not identify any distinct spatial patterns in the ichthyofaunal community within the salt marsh. The absence of any spatial patterns in the community structure could be related to the absence of any significant spatial patterns in the physico-chemical (temperature, salinity and dissolved oxygen concentrations) and biological (water column and microphytobenthic algal concentrations) variables within the salt marsh (P > 0.05 in all cases). Temporal shifts in the ichthyofaunal community structure within the salt marsh were, however, evident largely reflecting the breeding cycles of individual species within the sub-region. Within the adjacent eelgrass beds, total ichthyofaunal abundances and biomass ranged between 8.4 and 49.4 ind.10m⁻² and between 2.9 and 94.5 g.wwt.10m⁻², respectively. Once again there were no distinct spatial patterns in the abundance and biomass values evident although seasonal patterns were marked. In contrast to the salt marsh, within the in the eelgrass community, there were a large number of adult individuals recorded. Again category II species, the estuarine dependent species, were numerically and gravimetrically dominant. The dominance of category II species reflects the marine dominance of Kariega Estuary. The remaining estuarine utilisation categories did not contribute significantly to abundance or standing stock totals. Hierarchical cluster analysis showed that the salt marsh and eelgrass beds represented two distinct habitats within the Kariega Estuary. Within the salt marsh, the family Mugilidae were numerically dominant contributing 83% of the total catch. Within the eelgrass beds, the sparid, Rhabdosargus holubi and representatives of the family Gobidae contributed 36.3% and 33.9% respectively to the total catch. Estuaries with a wide range of microhabitats have been demonstrated to support a more diverse ichthyofaunal community. Shallow water habitats in general are important areas for juvenile fish within estuaries. Taylor’s salt marsh provides an alternative shallow water habitat, occupied by a distinct ichthyofaunal community composition, with increased food availability and decreased predation pressure, for a wide range of fish species.
- Full Text:
- Date Issued: 2009
- Authors: Booth, Tara Loren
- Date: 2009
- Subjects: Fishes -- South Africa -- Eastern Cape , Estuaries -- South Africa -- Eastern Cape , Fish communities -- South Africa -- Eastern Cape , Salt marsh animals -- South Africa -- Eastern Cape , Eelgrass -- South Africa -- Eastern Cape , Gray mullets -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5710 , http://hdl.handle.net/10962/d1005396 , Fishes -- South Africa -- Eastern Cape , Estuaries -- South Africa -- Eastern Cape , Fish communities -- South Africa -- Eastern Cape , Salt marsh animals -- South Africa -- Eastern Cape , Eelgrass -- South Africa -- Eastern Cape , Gray mullets -- South Africa -- Eastern Cape
- Description: The spatial and temporal patterns in the ichthyofaunal community composition and structure in Taylor’s salt marsh and adjacent eelgrass beds (Zostera capensis) in the Kariega Estuary, was investigated every two months between May 2006 and March 2007. Total ichthyofaunal abundances and biomass in the salt marsh ranged between 0.55 and 21.7 ind.10m-2 and between 0.03 and 1.9 g.wwt.10m⁻², respectively. There were no significant spatial patterns in the values evident (P > 0.05 in all cases) although seasonal trends were marked, with highest values consistently recorded during the warmer summer months. Investigations into the community structure showed that the ichthyofaunal community within salt marsh was composed almost exclusively of juveniles of estuarine dependant (category II) species, mainly juvenile Mugilidae (<20mm SL) that comprised up to 83% of all fish sampled. Hierarchical cluster analysis and multidimensional scaling did not identify any distinct spatial patterns in the ichthyofaunal community within the salt marsh. The absence of any spatial patterns in the community structure could be related to the absence of any significant spatial patterns in the physico-chemical (temperature, salinity and dissolved oxygen concentrations) and biological (water column and microphytobenthic algal concentrations) variables within the salt marsh (P > 0.05 in all cases). Temporal shifts in the ichthyofaunal community structure within the salt marsh were, however, evident largely reflecting the breeding cycles of individual species within the sub-region. Within the adjacent eelgrass beds, total ichthyofaunal abundances and biomass ranged between 8.4 and 49.4 ind.10m⁻² and between 2.9 and 94.5 g.wwt.10m⁻², respectively. Once again there were no distinct spatial patterns in the abundance and biomass values evident although seasonal patterns were marked. In contrast to the salt marsh, within the in the eelgrass community, there were a large number of adult individuals recorded. Again category II species, the estuarine dependent species, were numerically and gravimetrically dominant. The dominance of category II species reflects the marine dominance of Kariega Estuary. The remaining estuarine utilisation categories did not contribute significantly to abundance or standing stock totals. Hierarchical cluster analysis showed that the salt marsh and eelgrass beds represented two distinct habitats within the Kariega Estuary. Within the salt marsh, the family Mugilidae were numerically dominant contributing 83% of the total catch. Within the eelgrass beds, the sparid, Rhabdosargus holubi and representatives of the family Gobidae contributed 36.3% and 33.9% respectively to the total catch. Estuaries with a wide range of microhabitats have been demonstrated to support a more diverse ichthyofaunal community. Shallow water habitats in general are important areas for juvenile fish within estuaries. Taylor’s salt marsh provides an alternative shallow water habitat, occupied by a distinct ichthyofaunal community composition, with increased food availability and decreased predation pressure, for a wide range of fish species.
- Full Text:
- Date Issued: 2009
Rhenium (I) and (V) complexes with potentially mulidentate ligands containing the Amino group
- Authors: Booysen, Irvin Noel
- Date: 2009
- Subjects: Rhenium , Ligands
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10386 , http://hdl.handle.net/10948/1270 , Rhenium , Ligands
- Description: The complex trans-[Re(dab)Cl3(PPh3)2] (H2dab = 1,2-diaminobenzene) was prepared from the reaction of trans-[ReOCl3(PPh3)2] with H2dab in ethanol. The ligand dab is coordinated to the rhenium(V) centre through a dianionic imido nitrogen only in a distorted octahedral coordination geometry around the metal ion. The complex trans- [Re(ada)Cl3(PPh3)2] (H2ada = 2-aminodiphenylamine) was prepared from the reaction of trans-[ReOCl3(PPh3)2] with H2ada in acetonitrile. The ligand ada is coordinated to the rhenium(V) centre through a dianionic imido nitrogen only, in a distorted octahedral coordination geometry around the metal ion. The ‘2 + 1’ complex fac- [Re(CO)3(Hamp)(amp)] (Hamp = 2-aminophenol) was isolated from the reaction of a two molar ratio of Hamp with [Re(CO)5Br] in toluene. The reaction of a 1:1 molar ratio of [Re(CO)5Br] and H2ada led to the isolation of the Re(I) complex, fac- [Re(CO)3Br(H2ada)]. The reaction of equimolar quantities of cis-[ReO2I(PPh3)2] with 5,6-diamino-1,3- dimethyluracil (H2ddd) in acetonitrile led to the formation of [Re(ddd)(Hddd)I(PPh3)2](ReO4). The X-ray crystal structure shows that the ligand ddd is coordinated monodentately through the doubly deprotonated amino nitrogen and is therefore present as an imide. The chelate Hddd is coordinated bidentately via the neutral amino nitrogen, which is coordinated trans to the imido nitrogen, and the singly deprotonated amido nitrogen, trans to the iodide. The reaction of trans-[ReOCl3(PPh3)2] with N-(2-aminobenzylidene)-5-amino-1,3-dimethyl uracil (H3dua) in ethanol gave a mixed crystal which contains both the neutral oxorhenium(V) complex [ReOCl(Hdua)] and the imido rhenium(V) [Re(dua)Cl2(PPh3)] in an equimolar ratio in the asymmetric unit. The reaction of equimolar quantities of [NH4(ReO4)] with H2ddd in methanol under reflux led to the isolation of [C12H12N6O4] as only product. The [ReO4]- anion is therefore instrumental in the formation of [C12H12N6O4], and since the product contains no rhenium in any oxidation state, the conclusion is that [ReO4]- catalyses the oxidative deamination Abstract I.N. Booysen Nelson Mandela Metropolitan University vii of H2ddd. The X-ray crystal structure consists of two centrosymmetric, tricyclic rings, comprising a central pyrazine ring and two terminal pyrimidine rings. The reaction of 2-(2-aminophenyl)benzothiazole (Habt) with [Re(CO)5Br] led to the isolation of the rhenium(I) complex fac-[Re(Habt)(CO)3Br]. With trans-[ReOCl3(PPh3)2], the ligand Habt decomposed to form the oxofree rhenium(V) complex [Re(itp)2Cl(PPh3)] (itp = 2-amidophenylthiolate). From the reaction of trans-[ReOBr3(PPh3)2] with 2-(2- hydroxyphenyl)benzothiazole (Hhpd) the complex [ReVOBr2(hpd)(PPh3)] was obtained. The reaction of a twofold molar excess of H2apb (2-(2-aminophenyl)-1-benzimidazole) with trans-[ReO2(py)4]Cl in ethanol gave the green product of formulation [ReO(Hapb)(apb)] in good yield. The rhenium atom lies in a distorted trigonalbipyramidal environment. The two imidazole N(2) atoms lie in the apical positions trans to each other, with the oxo-oxygen and two amido N(1) atoms in the trigonal plane. A new nitrosylrhenium(II) complex salt, [Re(NO)BrL2(PPh3)2](ReO4) (H2L2 = 2-amino-5- (triphenylphosphino)phenol), is the first example of a complex containing the triphenylphosphonium-amidophenolate ligand L2, formed by the nucleophilic attack of a PPh3 on a coordinated amidophenolate ring. The complex salt trans-[Re(mps)Cl(PPh3)2](ReO4) (H3mps = N-(2-amino-3- methylphenyl)salicylideneimine) was prepared by the reaction of trans-[ReOCl3(PPh3)2] with a twofold molar excess of H3mps. The X-ray crystal structure shows that the trianionic ligand mps acts as a tridentate chelate via the doubly deprotonated amino nitrogen (an imide), the neutral imino nitrogen and the deprotonated phenolic oxygen. The six-coordinated complex cis-[Re(mps)Cl2(PPh3)2] was prepared by the reaction of trans-[ReOCl3(PPh3)2] with a twofold molar excess of H3mps in benzene. The X-ray crystal structure show that the mps ligand coordinates as a tridentate chelate via the doubly deprotonated 2-amino nitrogen, the neutral imino nitrogen and the phenolate oxygen. The imide and phenolate oxygen coordinate trans to each other in a distorted octahedral geometry, around the rhenium(V) centre, with the two chlorides in cis positions. A new oxofree rhenium(V) complex salt, [Re(bbd)2](ReO4) ( H2bbd = N-(2- Abstract I.N. Booysen Nelson Mandela Metropolitan University viii aminobenzylidene)benzene-1,2-diamine), has been synthesized and the chelates bbd are coordinated as dianionic tridentate N,N,N-donor diamidoimines. The rhenium(V) ion is centered in a distorted trigonal prism. The rhenium(I) compound fac-[Re(CO)3(daa)].Hpab.H2O (Hpab = N1,N2-(1,2- phenylene)bis(2-aminobenzamide); Hdaa = 2-amino-N-(2-aminophenyl)benzamide) was synthesized from the reaction of [Re(CO)5Br] with a two equivalents of Hpab in toluene. The monoanionic tridentate ligand daa was formed by the rhenium-mediated cleavage of an amido N-C bond of the potentially tetradentate ligand Hpab. Daa is coordinated as a diaminoamide via three nitrogen-donor atoms. The reaction of a twofold molar excess of H2amben (H2amben = N1,N2-bis(2-aminobenzylidene)ethane-1,2-diamine) with trans- [ReOBr3(PPh3)2] gave the oxorhenium(V) cationic complex [ReO(amben)]X (X = Br-, PF6 -). The Re(V) oxo-bridged compound, {μ-O}[ReO(omben)]2.H2O (H2omben = N1,N2- bis(2-hydroxybenzylidene)ethane-1,2-diamine) was isolated from the reaction of a 2:1 molar ratio of H2omben and trans-[ReO2(py)4]Cl in methanol. The seven-coordinate rhenium(III) complex cation [ReIII(dhp)(PPh3)2]+ was isolated as the [ReO4]- salt from the reaction of cis-[ReVO2I(PPh3)2] with 2,6-bis(2- hydroxyphenyliminomethyl)pyridine (H2dhp) in ethanol. In the complex fac- [Re(CO)3(H2dhp)Br], prepared from [Re(CO)5Br] and H2dhp in toluene, the H2dhp ligand acts as a neutral bidentate N,N-donor chelate. An equimolar ratio reaction of 2-aminobenzaldehyde and 2-(2-aminophenyl)-1- benzimidazole in methanol led to 2-(5,6-dihydrobenzimidazolo[1,2-c]-quinazolin-6- yl)aniline. In an attempt to explore the template formation of this class of ligand with rhenium, the reaction of salicylaldehyde and 2-(2-aminophenyl)-1-benzimidazole in ethanol which was followed by the addition of trans-[ReOBr3(PPh3)2] led to the formation of the salt, 6-(2-hydroxyphenyl)-5,6-dihydrobenzimidazolo[1,2-c]quinazolin- 12-ium bromide. The compound 6-(2-methylthiophenyl)-5,6-dihydrobenzimidazolo[1,2- c]quinazolin-12-ium was synthesized via the reaction of 2-aminobenzaldehyde and 2- methylthiobenzaldehyde in methanol.
- Full Text:
- Date Issued: 2009
- Authors: Booysen, Irvin Noel
- Date: 2009
- Subjects: Rhenium , Ligands
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10386 , http://hdl.handle.net/10948/1270 , Rhenium , Ligands
- Description: The complex trans-[Re(dab)Cl3(PPh3)2] (H2dab = 1,2-diaminobenzene) was prepared from the reaction of trans-[ReOCl3(PPh3)2] with H2dab in ethanol. The ligand dab is coordinated to the rhenium(V) centre through a dianionic imido nitrogen only in a distorted octahedral coordination geometry around the metal ion. The complex trans- [Re(ada)Cl3(PPh3)2] (H2ada = 2-aminodiphenylamine) was prepared from the reaction of trans-[ReOCl3(PPh3)2] with H2ada in acetonitrile. The ligand ada is coordinated to the rhenium(V) centre through a dianionic imido nitrogen only, in a distorted octahedral coordination geometry around the metal ion. The ‘2 + 1’ complex fac- [Re(CO)3(Hamp)(amp)] (Hamp = 2-aminophenol) was isolated from the reaction of a two molar ratio of Hamp with [Re(CO)5Br] in toluene. The reaction of a 1:1 molar ratio of [Re(CO)5Br] and H2ada led to the isolation of the Re(I) complex, fac- [Re(CO)3Br(H2ada)]. The reaction of equimolar quantities of cis-[ReO2I(PPh3)2] with 5,6-diamino-1,3- dimethyluracil (H2ddd) in acetonitrile led to the formation of [Re(ddd)(Hddd)I(PPh3)2](ReO4). The X-ray crystal structure shows that the ligand ddd is coordinated monodentately through the doubly deprotonated amino nitrogen and is therefore present as an imide. The chelate Hddd is coordinated bidentately via the neutral amino nitrogen, which is coordinated trans to the imido nitrogen, and the singly deprotonated amido nitrogen, trans to the iodide. The reaction of trans-[ReOCl3(PPh3)2] with N-(2-aminobenzylidene)-5-amino-1,3-dimethyl uracil (H3dua) in ethanol gave a mixed crystal which contains both the neutral oxorhenium(V) complex [ReOCl(Hdua)] and the imido rhenium(V) [Re(dua)Cl2(PPh3)] in an equimolar ratio in the asymmetric unit. The reaction of equimolar quantities of [NH4(ReO4)] with H2ddd in methanol under reflux led to the isolation of [C12H12N6O4] as only product. The [ReO4]- anion is therefore instrumental in the formation of [C12H12N6O4], and since the product contains no rhenium in any oxidation state, the conclusion is that [ReO4]- catalyses the oxidative deamination Abstract I.N. Booysen Nelson Mandela Metropolitan University vii of H2ddd. The X-ray crystal structure consists of two centrosymmetric, tricyclic rings, comprising a central pyrazine ring and two terminal pyrimidine rings. The reaction of 2-(2-aminophenyl)benzothiazole (Habt) with [Re(CO)5Br] led to the isolation of the rhenium(I) complex fac-[Re(Habt)(CO)3Br]. With trans-[ReOCl3(PPh3)2], the ligand Habt decomposed to form the oxofree rhenium(V) complex [Re(itp)2Cl(PPh3)] (itp = 2-amidophenylthiolate). From the reaction of trans-[ReOBr3(PPh3)2] with 2-(2- hydroxyphenyl)benzothiazole (Hhpd) the complex [ReVOBr2(hpd)(PPh3)] was obtained. The reaction of a twofold molar excess of H2apb (2-(2-aminophenyl)-1-benzimidazole) with trans-[ReO2(py)4]Cl in ethanol gave the green product of formulation [ReO(Hapb)(apb)] in good yield. The rhenium atom lies in a distorted trigonalbipyramidal environment. The two imidazole N(2) atoms lie in the apical positions trans to each other, with the oxo-oxygen and two amido N(1) atoms in the trigonal plane. A new nitrosylrhenium(II) complex salt, [Re(NO)BrL2(PPh3)2](ReO4) (H2L2 = 2-amino-5- (triphenylphosphino)phenol), is the first example of a complex containing the triphenylphosphonium-amidophenolate ligand L2, formed by the nucleophilic attack of a PPh3 on a coordinated amidophenolate ring. The complex salt trans-[Re(mps)Cl(PPh3)2](ReO4) (H3mps = N-(2-amino-3- methylphenyl)salicylideneimine) was prepared by the reaction of trans-[ReOCl3(PPh3)2] with a twofold molar excess of H3mps. The X-ray crystal structure shows that the trianionic ligand mps acts as a tridentate chelate via the doubly deprotonated amino nitrogen (an imide), the neutral imino nitrogen and the deprotonated phenolic oxygen. The six-coordinated complex cis-[Re(mps)Cl2(PPh3)2] was prepared by the reaction of trans-[ReOCl3(PPh3)2] with a twofold molar excess of H3mps in benzene. The X-ray crystal structure show that the mps ligand coordinates as a tridentate chelate via the doubly deprotonated 2-amino nitrogen, the neutral imino nitrogen and the phenolate oxygen. The imide and phenolate oxygen coordinate trans to each other in a distorted octahedral geometry, around the rhenium(V) centre, with the two chlorides in cis positions. A new oxofree rhenium(V) complex salt, [Re(bbd)2](ReO4) ( H2bbd = N-(2- Abstract I.N. Booysen Nelson Mandela Metropolitan University viii aminobenzylidene)benzene-1,2-diamine), has been synthesized and the chelates bbd are coordinated as dianionic tridentate N,N,N-donor diamidoimines. The rhenium(V) ion is centered in a distorted trigonal prism. The rhenium(I) compound fac-[Re(CO)3(daa)].Hpab.H2O (Hpab = N1,N2-(1,2- phenylene)bis(2-aminobenzamide); Hdaa = 2-amino-N-(2-aminophenyl)benzamide) was synthesized from the reaction of [Re(CO)5Br] with a two equivalents of Hpab in toluene. The monoanionic tridentate ligand daa was formed by the rhenium-mediated cleavage of an amido N-C bond of the potentially tetradentate ligand Hpab. Daa is coordinated as a diaminoamide via three nitrogen-donor atoms. The reaction of a twofold molar excess of H2amben (H2amben = N1,N2-bis(2-aminobenzylidene)ethane-1,2-diamine) with trans- [ReOBr3(PPh3)2] gave the oxorhenium(V) cationic complex [ReO(amben)]X (X = Br-, PF6 -). The Re(V) oxo-bridged compound, {μ-O}[ReO(omben)]2.H2O (H2omben = N1,N2- bis(2-hydroxybenzylidene)ethane-1,2-diamine) was isolated from the reaction of a 2:1 molar ratio of H2omben and trans-[ReO2(py)4]Cl in methanol. The seven-coordinate rhenium(III) complex cation [ReIII(dhp)(PPh3)2]+ was isolated as the [ReO4]- salt from the reaction of cis-[ReVO2I(PPh3)2] with 2,6-bis(2- hydroxyphenyliminomethyl)pyridine (H2dhp) in ethanol. In the complex fac- [Re(CO)3(H2dhp)Br], prepared from [Re(CO)5Br] and H2dhp in toluene, the H2dhp ligand acts as a neutral bidentate N,N-donor chelate. An equimolar ratio reaction of 2-aminobenzaldehyde and 2-(2-aminophenyl)-1- benzimidazole in methanol led to 2-(5,6-dihydrobenzimidazolo[1,2-c]-quinazolin-6- yl)aniline. In an attempt to explore the template formation of this class of ligand with rhenium, the reaction of salicylaldehyde and 2-(2-aminophenyl)-1-benzimidazole in ethanol which was followed by the addition of trans-[ReOBr3(PPh3)2] led to the formation of the salt, 6-(2-hydroxyphenyl)-5,6-dihydrobenzimidazolo[1,2-c]quinazolin- 12-ium bromide. The compound 6-(2-methylthiophenyl)-5,6-dihydrobenzimidazolo[1,2- c]quinazolin-12-ium was synthesized via the reaction of 2-aminobenzaldehyde and 2- methylthiobenzaldehyde in methanol.
- Full Text:
- Date Issued: 2009
An assessment of the computer literacy status of nurse managers in a private hospital group in the Nelson Mandela metropolitan area
- Authors: Booysen, Mary Kathleen
- Date: 2009
- Subjects: Nursing informatics , Nursing -- Data processing -- South Africa - Nelson Mandela Metropolitan Area , Information storage and retrieval systems -- Hospitals , Hospital care -- Data processing -- South Africa - Nelson Mandela Metropolitan Area
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:10035 , http://hdl.handle.net/10948/924 , Nursing informatics , Nursing -- Data processing -- South Africa - Nelson Mandela Metropolitan Area , Information storage and retrieval systems -- Hospitals , Hospital care -- Data processing -- South Africa - Nelson Mandela Metropolitan Area
- Description: There has been an increase in the use of information technology in the hospital environment over the past decade and the use of computers by Nursing Managers is rapidly increasing. The latter poses a challenge to Nurse Managers, as their computer literacy status is unknown. This is evident from the fact that prior to 1996 there was only four computers at one of the private hospitals used in this study. Computer skills were never a requirement when applying for the position of Nurse Manager; and there is still currently no formal computer training provided for Nurse Managers or Acting Nurse Managers. Resources are however available in the hospitals to assist the managers with various computer problems but it is not known if these resources equip managers with the appropriate tools to become efficient in their role. The lack of formal training and lack of assessment of resources to determine whether the computer needs of Nurse Managers are met results in a lot of time being wasted and many frustrations experienced among Nurse Managers. The researcher was therefore motivated by the latter problem to explore and describe the computer literacy status of Nurse Managers in order to make recommendations to management regarding the research findings. The researcher selected a quantitative, explorative, contextual and descriptive survey design. The research population was made up of all Nurse Managers and Acting Nurse Managers at the time of the study. A 100 percent sample was utilised and comprised thirty-four respondents who made up the entire group of Nurse Managers and Acting Nurse Managers at the time of the study. A structured, self-administered questionnaire was used in Phase One of the research and in Phase Two a data observation sheet was used to test the respondents and to collect the necessary data. This data was manually processed and analysed by the iii researcher. All ethical considerations were honoured throughout the research process. The main findings of the research study reflected that the respondents had a below average ability to use various software packages such as Microsoft Word, EXCEL and Power Point. Findings further revealed that the respondent’s literacy levels were average with regard to the use of peripheral components of the computer such as the use of the mouse and keyboard. The respondents rated their competency level as average with regard to using a computer. Due to the limitations and small sample size used in the study the researcher recommends that further research using a larger sample by expanding the research into the other private hospitals in the group through out South Africa should take place in order to produce more constructive results than this study.
- Full Text:
- Date Issued: 2009
- Authors: Booysen, Mary Kathleen
- Date: 2009
- Subjects: Nursing informatics , Nursing -- Data processing -- South Africa - Nelson Mandela Metropolitan Area , Information storage and retrieval systems -- Hospitals , Hospital care -- Data processing -- South Africa - Nelson Mandela Metropolitan Area
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:10035 , http://hdl.handle.net/10948/924 , Nursing informatics , Nursing -- Data processing -- South Africa - Nelson Mandela Metropolitan Area , Information storage and retrieval systems -- Hospitals , Hospital care -- Data processing -- South Africa - Nelson Mandela Metropolitan Area
- Description: There has been an increase in the use of information technology in the hospital environment over the past decade and the use of computers by Nursing Managers is rapidly increasing. The latter poses a challenge to Nurse Managers, as their computer literacy status is unknown. This is evident from the fact that prior to 1996 there was only four computers at one of the private hospitals used in this study. Computer skills were never a requirement when applying for the position of Nurse Manager; and there is still currently no formal computer training provided for Nurse Managers or Acting Nurse Managers. Resources are however available in the hospitals to assist the managers with various computer problems but it is not known if these resources equip managers with the appropriate tools to become efficient in their role. The lack of formal training and lack of assessment of resources to determine whether the computer needs of Nurse Managers are met results in a lot of time being wasted and many frustrations experienced among Nurse Managers. The researcher was therefore motivated by the latter problem to explore and describe the computer literacy status of Nurse Managers in order to make recommendations to management regarding the research findings. The researcher selected a quantitative, explorative, contextual and descriptive survey design. The research population was made up of all Nurse Managers and Acting Nurse Managers at the time of the study. A 100 percent sample was utilised and comprised thirty-four respondents who made up the entire group of Nurse Managers and Acting Nurse Managers at the time of the study. A structured, self-administered questionnaire was used in Phase One of the research and in Phase Two a data observation sheet was used to test the respondents and to collect the necessary data. This data was manually processed and analysed by the iii researcher. All ethical considerations were honoured throughout the research process. The main findings of the research study reflected that the respondents had a below average ability to use various software packages such as Microsoft Word, EXCEL and Power Point. Findings further revealed that the respondent’s literacy levels were average with regard to the use of peripheral components of the computer such as the use of the mouse and keyboard. The respondents rated their competency level as average with regard to using a computer. Due to the limitations and small sample size used in the study the researcher recommends that further research using a larger sample by expanding the research into the other private hospitals in the group through out South Africa should take place in order to produce more constructive results than this study.
- Full Text:
- Date Issued: 2009
Possible trace fossils of putative termite origin in the Lower Jurassic (Karoo Supergroup) of South Africa and Lesotho
- Bordy, Emese M, Bumby, A J, Catuneanu, O, Eriksson, P G
- Authors: Bordy, Emese M , Bumby, A J , Catuneanu, O , Eriksson, P G
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6732 , http://hdl.handle.net/10962/d1007541
- Description: Complex structures in the sandstones of the Lower Jurassic aeolian Clarens Formation (Karoo Supergroup) are found at numerous localities throughout southern Africa, and can be assigned to five distinct architectural groups: (1) up to 3.3-m high, free-standing, slab-shaped forms of bioturbated sandstones with elliptical bases, orientated buttresses and an interconnecting large burrow system; (2) up to 1.2-m high, free-standing, irregular forms of bioturbated sandstones with 2-cm to 4-cm thick, massive walls, empty chambers and vertical shafts; (3) about 0.15-m to 0.25-m high, mainly bulbous, multiple forms with thin walls (<2 cm), hollow chambers with internal pillars and bridges; (4) about 0.15-m to 0.2-m (maximum 1-m) high, free-standing forms of aggregated solitary spheres associated with massive horizontal, orientated capsules or tubes, and meniscate tubes; and (5) about 5 cmin diameter, ovoid forms with weak internal shelving in a close-fitting cavity. Based on size, wall thickness, orientation and the presence of internal chambers, these complex structures are tentatively interpreted as ichnofossils of an Early Jurassic social organism; the different architectures are reflective of the different behaviours of more than one species, the history of structural change in architectural forms (ontogenetic series) or an architectural adaptation to local palaeoclimatic variability. While exact modern equivalents are unknown, some of these ichnofossils are comparable to nests (or parts of nests) constructed by extant termites, and thus these Jurassic structures are very tentatively interpreted here as having been made by a soil-dwelling social organism, probably of termite origin. This southern African discovery, along with reported Triassic and Jurassic termite ichnofossils from North America, supports previous hypotheses that sociality in insects, particularity in termites, likely evolved prior to the Pangea breakup in the Early Mesozoic.
- Full Text:
- Date Issued: 2009
- Authors: Bordy, Emese M , Bumby, A J , Catuneanu, O , Eriksson, P G
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6732 , http://hdl.handle.net/10962/d1007541
- Description: Complex structures in the sandstones of the Lower Jurassic aeolian Clarens Formation (Karoo Supergroup) are found at numerous localities throughout southern Africa, and can be assigned to five distinct architectural groups: (1) up to 3.3-m high, free-standing, slab-shaped forms of bioturbated sandstones with elliptical bases, orientated buttresses and an interconnecting large burrow system; (2) up to 1.2-m high, free-standing, irregular forms of bioturbated sandstones with 2-cm to 4-cm thick, massive walls, empty chambers and vertical shafts; (3) about 0.15-m to 0.25-m high, mainly bulbous, multiple forms with thin walls (<2 cm), hollow chambers with internal pillars and bridges; (4) about 0.15-m to 0.2-m (maximum 1-m) high, free-standing forms of aggregated solitary spheres associated with massive horizontal, orientated capsules or tubes, and meniscate tubes; and (5) about 5 cmin diameter, ovoid forms with weak internal shelving in a close-fitting cavity. Based on size, wall thickness, orientation and the presence of internal chambers, these complex structures are tentatively interpreted as ichnofossils of an Early Jurassic social organism; the different architectures are reflective of the different behaviours of more than one species, the history of structural change in architectural forms (ontogenetic series) or an architectural adaptation to local palaeoclimatic variability. While exact modern equivalents are unknown, some of these ichnofossils are comparable to nests (or parts of nests) constructed by extant termites, and thus these Jurassic structures are very tentatively interpreted here as having been made by a soil-dwelling social organism, probably of termite origin. This southern African discovery, along with reported Triassic and Jurassic termite ichnofossils from North America, supports previous hypotheses that sociality in insects, particularity in termites, likely evolved prior to the Pangea breakup in the Early Mesozoic.
- Full Text:
- Date Issued: 2009
An evaluation of the quality of customer service delivery offered by the East London public transport commuter rail service provider (operated by Metrorail)
- Authors: Bosch, Colin
- Date: 2009
- Subjects: Railroads -- Customer services -- South Africa -- Eastern Cape Transportation -- Customer services -- South Africa -- Eastern Cape Railroads -- Quality control -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:744 , http://hdl.handle.net/10962/d1003865
- Description: The aim of this survey is to evaluate the quality of customer service delivery offered by the East London public transport commuter rail service provider Metrorail, a division of the state owned enterprise (SOE) PRASA. The former tolerant rail commuter has become increasingly frustrated at the ever-decreasing quality of rail service delivery. This is evidenced by increasing incidents of commuter arson to failed rail assets and the practice is considered to be a strategy to enforce the replacement of unreliable infrastructure and ineffective/reactive management controls. The objectives of the research are guided by three fundamental service quality indicators. In order to evaluate these indicators, the research focuses on whether the quality of customer services provided by Metrorail meets commuter expectations, whether commuters rank five dimensions of service quality differently and whether the level of service quality provided is perceived differently amongst the various demographic commuter segments. Service organizations which are highly interactive, labour-intensive, reliant on a number of service providers, required to perform at various locations and have high intensity/volume operations, will be susceptible to failure; Metrorail services fall into this category. The legacy of the apartheid era regime and strategy resulted in poor rail planning and underfunding. Commuter rail operations in South Africa are fraught with a myriad of inadequacies of the past that only now manifest. As a consequence, their ability to operate effectively and efficiently is impaired. The situation is further exacerbated by the global economic crisis of 2008 and the impact of constricted budget allocations by the State to all SOE's which could further impede the interventions and innovation required to improve service quality. The in-depth literature review provided sufficient information relating to a wide array of service organizations similar in nature to Metrorail. This information is translated into useable knowledge and recommendations from which Metrorail can benefit. The research methodology is clearly articulated and the data analysis ensures distinct findings which are discussed in the final chapter. The research undertaken identifies and prioritises the service quality attributes and dimensions that will require redress to improve overall service quality. The findings are clearly defined from which a set of recommendations are suggested.
- Full Text:
- Date Issued: 2009
- Authors: Bosch, Colin
- Date: 2009
- Subjects: Railroads -- Customer services -- South Africa -- Eastern Cape Transportation -- Customer services -- South Africa -- Eastern Cape Railroads -- Quality control -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:744 , http://hdl.handle.net/10962/d1003865
- Description: The aim of this survey is to evaluate the quality of customer service delivery offered by the East London public transport commuter rail service provider Metrorail, a division of the state owned enterprise (SOE) PRASA. The former tolerant rail commuter has become increasingly frustrated at the ever-decreasing quality of rail service delivery. This is evidenced by increasing incidents of commuter arson to failed rail assets and the practice is considered to be a strategy to enforce the replacement of unreliable infrastructure and ineffective/reactive management controls. The objectives of the research are guided by three fundamental service quality indicators. In order to evaluate these indicators, the research focuses on whether the quality of customer services provided by Metrorail meets commuter expectations, whether commuters rank five dimensions of service quality differently and whether the level of service quality provided is perceived differently amongst the various demographic commuter segments. Service organizations which are highly interactive, labour-intensive, reliant on a number of service providers, required to perform at various locations and have high intensity/volume operations, will be susceptible to failure; Metrorail services fall into this category. The legacy of the apartheid era regime and strategy resulted in poor rail planning and underfunding. Commuter rail operations in South Africa are fraught with a myriad of inadequacies of the past that only now manifest. As a consequence, their ability to operate effectively and efficiently is impaired. The situation is further exacerbated by the global economic crisis of 2008 and the impact of constricted budget allocations by the State to all SOE's which could further impede the interventions and innovation required to improve service quality. The in-depth literature review provided sufficient information relating to a wide array of service organizations similar in nature to Metrorail. This information is translated into useable knowledge and recommendations from which Metrorail can benefit. The research methodology is clearly articulated and the data analysis ensures distinct findings which are discussed in the final chapter. The research undertaken identifies and prioritises the service quality attributes and dimensions that will require redress to improve overall service quality. The findings are clearly defined from which a set of recommendations are suggested.
- Full Text:
- Date Issued: 2009
Production of biologically active recombinant HIV-1 protease and intehrase for the purpose of screening medicianl plant extracts
- Authors: Bosch, Janine
- Date: 2009
- Subjects: Medicinal plants -- South Africa , HIV infections -- Alternative treatment -- South Africa , Materia medica, Vegetable -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10325 , http://hdl.handle.net/10948/1056 , Medicinal plants -- South Africa , HIV infections -- Alternative treatment -- South Africa , Materia medica, Vegetable -- South Africa
- Description: Human immunodeficiency virus (HIV) and its gradual weakening of the immune system is an ever growing threat. Acquired immune deficiency syndrome (AIDS), the final stage of HIV, renders a person vulnerable to various opportunistic infections, which in the end lead to death. Apart from intensive vaccine studies, treatment research mainly focuses on preventing the individual HIV enzymes (reverse transcriptase, integrase and protease) from performing their functions. Entry inhibitors, however, block viral entry into the cell, while antisense drugs lock onto the viral genome to keep it from functioning. In this study production of active recombinant HIV-1 protease and integrase was attempted for future drug screening programs. HIV-1 protease was cloned into a pET28b(+) vector and expressed in ROSETTA(DE3)pLysS cells. The protein was purified using a nickel-affinity column utilizing the hexa-histidine tag encoded by the vector. Gel filtration chromatography was attempted after refolding of the protease, but protease yield seemed to decrease with the additional purification step. Partially purified protease was characterized with kinetic studies. Kinetic parameters of HIV-1 protease were determined to be Km = 592 μM, Vmax = 0.59 μM/min and kcat = 31 s-1. HIV-1 integrase, which was cloned into a pET15b vector, was expressed in E. coli BL21(DE3) cells. The coding sequence had been mutated to introduce the amino acid substitutions F185K and C280S, increasing solubility of the protein. The first step in purification of this protein was nickel-affinity chromatography, after which cation exchange chromatography was attempted. HIV-1 integrase concentration was low throughout experiments and no clear elution from the cation exchange column could be observed. A non-radioactive enzyme linked HIV-1 integrase assay failed to detect integrase activity. Modifications to future studies of the integrase are suggested in the chapter involved.
- Full Text:
- Date Issued: 2009
- Authors: Bosch, Janine
- Date: 2009
- Subjects: Medicinal plants -- South Africa , HIV infections -- Alternative treatment -- South Africa , Materia medica, Vegetable -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10325 , http://hdl.handle.net/10948/1056 , Medicinal plants -- South Africa , HIV infections -- Alternative treatment -- South Africa , Materia medica, Vegetable -- South Africa
- Description: Human immunodeficiency virus (HIV) and its gradual weakening of the immune system is an ever growing threat. Acquired immune deficiency syndrome (AIDS), the final stage of HIV, renders a person vulnerable to various opportunistic infections, which in the end lead to death. Apart from intensive vaccine studies, treatment research mainly focuses on preventing the individual HIV enzymes (reverse transcriptase, integrase and protease) from performing their functions. Entry inhibitors, however, block viral entry into the cell, while antisense drugs lock onto the viral genome to keep it from functioning. In this study production of active recombinant HIV-1 protease and integrase was attempted for future drug screening programs. HIV-1 protease was cloned into a pET28b(+) vector and expressed in ROSETTA(DE3)pLysS cells. The protein was purified using a nickel-affinity column utilizing the hexa-histidine tag encoded by the vector. Gel filtration chromatography was attempted after refolding of the protease, but protease yield seemed to decrease with the additional purification step. Partially purified protease was characterized with kinetic studies. Kinetic parameters of HIV-1 protease were determined to be Km = 592 μM, Vmax = 0.59 μM/min and kcat = 31 s-1. HIV-1 integrase, which was cloned into a pET15b vector, was expressed in E. coli BL21(DE3) cells. The coding sequence had been mutated to introduce the amino acid substitutions F185K and C280S, increasing solubility of the protein. The first step in purification of this protein was nickel-affinity chromatography, after which cation exchange chromatography was attempted. HIV-1 integrase concentration was low throughout experiments and no clear elution from the cation exchange column could be observed. A non-radioactive enzyme linked HIV-1 integrase assay failed to detect integrase activity. Modifications to future studies of the integrase are suggested in the chapter involved.
- Full Text:
- Date Issued: 2009