Effects of substrate on essential fatty acids produced by phytobenthos in an austral temperate river system
- Dalu, Tatenda, Galloway, Aaron W E, Richoux, Nicole B, Froneman, P William
- Authors: Dalu, Tatenda , Galloway, Aaron W E , Richoux, Nicole B , Froneman, P William
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68002 , vital:29179 , https://doi.org/10.1086/688698
- Description: Publisher version , Aquatic and riparian habitats increasingly are affected by anthropogenic stressors, but the effects of these stressors on the nutritional quality of primary producers are often unknown. We compared essential fatty acids (EFAs) in the phytobenthos (benthic algae) growing on different substrate types (bricks, clay tiles, rocks, macrophytes, and sediments) at 2 river sites subject to differing anthropogenic stressors (using nutrient concentration as a proxy) in a temperate southern hemisphere location. We hypothesized that the fatty acid (FA) content of phytobenthos changes in response to shifts in local nutrient availability but not substrate type. EFA content (18∶2ω6, 18∶3ω3, 20∶4ω6, 20∶5ω3, and 22∶6ω3) in the phytobenthos differed overall among substrates, sites, and seasons and was generally greater in summer than in autumn and winter. EFA content was significantly greater on artificial than natural substrates and was greater at the nutrient-enriched downstream site than at the upstream site. The response of EFA content at the downstream site suggests that land use affected the synthesis of EFAs by phytobenthos and, hence, food quality for aquatic consumers. These findings indicate a potential link between physical factors, such as substrate availability and land management, and the quality of basal food resources available to primary consumers in aquatic food webs.
- Full Text: false
- Date Issued: 2016
- Authors: Dalu, Tatenda , Galloway, Aaron W E , Richoux, Nicole B , Froneman, P William
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68002 , vital:29179 , https://doi.org/10.1086/688698
- Description: Publisher version , Aquatic and riparian habitats increasingly are affected by anthropogenic stressors, but the effects of these stressors on the nutritional quality of primary producers are often unknown. We compared essential fatty acids (EFAs) in the phytobenthos (benthic algae) growing on different substrate types (bricks, clay tiles, rocks, macrophytes, and sediments) at 2 river sites subject to differing anthropogenic stressors (using nutrient concentration as a proxy) in a temperate southern hemisphere location. We hypothesized that the fatty acid (FA) content of phytobenthos changes in response to shifts in local nutrient availability but not substrate type. EFA content (18∶2ω6, 18∶3ω3, 20∶4ω6, 20∶5ω3, and 22∶6ω3) in the phytobenthos differed overall among substrates, sites, and seasons and was generally greater in summer than in autumn and winter. EFA content was significantly greater on artificial than natural substrates and was greater at the nutrient-enriched downstream site than at the upstream site. The response of EFA content at the downstream site suggests that land use affected the synthesis of EFAs by phytobenthos and, hence, food quality for aquatic consumers. These findings indicate a potential link between physical factors, such as substrate availability and land management, and the quality of basal food resources available to primary consumers in aquatic food webs.
- Full Text: false
- Date Issued: 2016
Effects of the biocontrol agent, coelocephalapion camarae kissinger, galling on petiole tissues, plant growth and stored reserves in plant parts of two lantana camara L.(verbenaceae) varieties
- Authors: Kistensamy, Yoganambal
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/3126 , vital:20372
- Description: The agent evaluated in this study, Coelocephalapion camarae Kissinger (Brentidae), a petiole galling apionid, was released against Lantana camara L. (Verbenaceae) in South Africa and has the potential to significantly contribute to the control of this noxious weed. An important aspect of evaluating the effectiveness of a biocontrol agent; include the understanding of the mechanism in which the biocontrol agent causes damage to the plant and the plant’s response to this damage. Another aspect that was considered in evaluating the effects of the apionid was the varietal differences that exist within the weedy L. camara complex. Larval feeding of C. camarae damaged the tissue in the petioles causing gall formation and this was quantified on two common South African L. camara varieties (017 and 018). Up to 100% of the vascular tissue (xylem and phloem) of effected petioles was eaten by larvae, 25 days after ovipostion in both the L. camara varieties, effectively severing the vascular connection from the leaves. The effect of feeding and galling by different population densities of C. camarae, on biomass and total soluble sugar and starch concentrations of different plant parts was measured on these two varieties during autumn, and compared to a similar study, done during summer. Relatively low galling percentages were achieved in the experiments of this study. Plant growth was less affected by apionid feeding at similar galling levels, as higher galling densities in these trials were similar to those at low exposures in trials by Baars (2002). The dry weights of all individual and combined plant parts for lantana variety 017 was less for both adult density exposures after 70 days compared to the weights of its controls, although not statistically significant at P>0.05 The opposite effect, though barely noticeable was recorded for lantana variety 018; here, the dry weights of individual plant parts and as whole plants weighed more in the plants exposed to both densities of weevil feeding and galling after 70 days, compared to its controls. Coelocephalapion camarae herbivory may thus be more effective in inflicting damage on some L. camara varieties compared to others. The effects of late season carbohydrate storage revealed that, from early- to mid-autumn starch concentrations increased significantly in stems of both L. camara varieties and L. camara var. 018 had larger starch reserves for winter. In L. camara var. 018 stems, starch increased 52 times and concentrations doubled in stems of L. camara var 017. The increase in the sugar and decrease in starch concentrations in leaves of plants of both varieties exposed to apionids in this study was attributed to a possible reduction of available nitrogen and phosphorus, due to apionid feeding, whilst starch was reallocated within the plants to stems and roots. The increase in starch concentrations in stems of plants that were exposed to apionids may have been expected, as compensation for herbivory has been associated with, increases in photosynthetic rates and the mobilization of stored resources. Herbivory by the apionid early in the growing season may be easily compensated for by L. camara as there are nutrient flushes experienced by plants that allows the maximum uptake of nutrients facilitating recovery, whereas later in the season plants suffer lower nutrient availability and don’t recover so readily. Both early and late in the season the accumulated effects of C. camarae feeding over time will undoubtedly decrease fitness of most lantana varieties.
- Full Text:
- Date Issued: 2016
- Authors: Kistensamy, Yoganambal
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/3126 , vital:20372
- Description: The agent evaluated in this study, Coelocephalapion camarae Kissinger (Brentidae), a petiole galling apionid, was released against Lantana camara L. (Verbenaceae) in South Africa and has the potential to significantly contribute to the control of this noxious weed. An important aspect of evaluating the effectiveness of a biocontrol agent; include the understanding of the mechanism in which the biocontrol agent causes damage to the plant and the plant’s response to this damage. Another aspect that was considered in evaluating the effects of the apionid was the varietal differences that exist within the weedy L. camara complex. Larval feeding of C. camarae damaged the tissue in the petioles causing gall formation and this was quantified on two common South African L. camara varieties (017 and 018). Up to 100% of the vascular tissue (xylem and phloem) of effected petioles was eaten by larvae, 25 days after ovipostion in both the L. camara varieties, effectively severing the vascular connection from the leaves. The effect of feeding and galling by different population densities of C. camarae, on biomass and total soluble sugar and starch concentrations of different plant parts was measured on these two varieties during autumn, and compared to a similar study, done during summer. Relatively low galling percentages were achieved in the experiments of this study. Plant growth was less affected by apionid feeding at similar galling levels, as higher galling densities in these trials were similar to those at low exposures in trials by Baars (2002). The dry weights of all individual and combined plant parts for lantana variety 017 was less for both adult density exposures after 70 days compared to the weights of its controls, although not statistically significant at P>0.05 The opposite effect, though barely noticeable was recorded for lantana variety 018; here, the dry weights of individual plant parts and as whole plants weighed more in the plants exposed to both densities of weevil feeding and galling after 70 days, compared to its controls. Coelocephalapion camarae herbivory may thus be more effective in inflicting damage on some L. camara varieties compared to others. The effects of late season carbohydrate storage revealed that, from early- to mid-autumn starch concentrations increased significantly in stems of both L. camara varieties and L. camara var. 018 had larger starch reserves for winter. In L. camara var. 018 stems, starch increased 52 times and concentrations doubled in stems of L. camara var 017. The increase in the sugar and decrease in starch concentrations in leaves of plants of both varieties exposed to apionids in this study was attributed to a possible reduction of available nitrogen and phosphorus, due to apionid feeding, whilst starch was reallocated within the plants to stems and roots. The increase in starch concentrations in stems of plants that were exposed to apionids may have been expected, as compensation for herbivory has been associated with, increases in photosynthetic rates and the mobilization of stored resources. Herbivory by the apionid early in the growing season may be easily compensated for by L. camara as there are nutrient flushes experienced by plants that allows the maximum uptake of nutrients facilitating recovery, whereas later in the season plants suffer lower nutrient availability and don’t recover so readily. Both early and late in the season the accumulated effects of C. camarae feeding over time will undoubtedly decrease fitness of most lantana varieties.
- Full Text:
- Date Issued: 2016
Effects of the invasive shrub, Lantana camara, on soil properties in the Eastern Cape, South Africa
- Ruwanza, Sheunesu, Shackleton, Charlie M
- Authors: Ruwanza, Sheunesu , Shackleton, Charlie M
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180459 , vital:43391 , xlink:href="https://doi.org/10.1111/wbm.12094"
- Description: Lantana camara L. is an invasive alien shrub of worldwide significance due to its impacts on biodiversity. It can alter the soil properties of invaded ecosystems and, as a result, affect management outcomes. However, knowledge on the impacts of L. camara on soil properties is scanty, especially in South Africa, despite the pervasive presence of the plant in the country. In this comparative study, the soils underneath L. camara were assessed in order to determine if they had different properties (soil physico-chemical properties, penetration resistance, infiltration, hydraulic conductivity and water repellency) in comparison to the soils in adjacent natural sites in the Eastern Cape, South Africa. Soil samples were collected from the top soil beneath the canopy of both L. camara-invaded and adjacent natural sites in five different locations over three summer months. The soils that were collected from underneath L. camara had a significantly higher total C, total P, gravimetric soil moisture (in November and December) and were repellent, compared to the soils in the adjacent natural sites. Soil penetration resistance was significantly higher in the natural sites than in the L. camara-invaded sites. The soil hydraulic conductivity, soil infiltration rate, soil pH, exchangeable cations and total N showed no significant difference between the invaded and the natural sites. It appears that the soils underneath L. camara have a high total C and total P, soil moisture and are repellent, thus influencing nutrient cycling, potentially making the soil properties underneath it ideal for its own growth. This could contribute to the success of L. camara as an invasive species.
- Full Text:
- Date Issued: 2016
- Authors: Ruwanza, Sheunesu , Shackleton, Charlie M
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180459 , vital:43391 , xlink:href="https://doi.org/10.1111/wbm.12094"
- Description: Lantana camara L. is an invasive alien shrub of worldwide significance due to its impacts on biodiversity. It can alter the soil properties of invaded ecosystems and, as a result, affect management outcomes. However, knowledge on the impacts of L. camara on soil properties is scanty, especially in South Africa, despite the pervasive presence of the plant in the country. In this comparative study, the soils underneath L. camara were assessed in order to determine if they had different properties (soil physico-chemical properties, penetration resistance, infiltration, hydraulic conductivity and water repellency) in comparison to the soils in adjacent natural sites in the Eastern Cape, South Africa. Soil samples were collected from the top soil beneath the canopy of both L. camara-invaded and adjacent natural sites in five different locations over three summer months. The soils that were collected from underneath L. camara had a significantly higher total C, total P, gravimetric soil moisture (in November and December) and were repellent, compared to the soils in the adjacent natural sites. Soil penetration resistance was significantly higher in the natural sites than in the L. camara-invaded sites. The soil hydraulic conductivity, soil infiltration rate, soil pH, exchangeable cations and total N showed no significant difference between the invaded and the natural sites. It appears that the soils underneath L. camara have a high total C and total P, soil moisture and are repellent, thus influencing nutrient cycling, potentially making the soil properties underneath it ideal for its own growth. This could contribute to the success of L. camara as an invasive species.
- Full Text:
- Date Issued: 2016
Efficiency analysis of electricity distribution by South African Municipalities: a cost frontier approach
- Gqwaka, Aviwe Phelele Sebatian
- Authors: Gqwaka, Aviwe Phelele Sebatian
- Date: 2016
- Subjects: Electric power distribution -- South Africa Public utilities -- South Africa Local government -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/10299 , vital:26650
- Description: Efficiency analysis in the public sector assesses the performance of municipal and government entities in their provision of services to the public. South Africa, in particular, has experienced a large degree of negative feedback with respect to the ability of the government and its municipal departments to provide basic services to citizens. This has led to a number of service delivery protests throughout the country. To remedy this, the ability of the municipality to provide basic services needs to be assessed in order for improvements to be made. A first step in this process would be to determine the efficiency with which municipalities are providing these services. This study focuses on a particular municipal service, namely electricity distribution. Primarily, the efficiency with which municipalities provide electricity to consumers is determined. This is achieved using the parametric cost frontier approach, which is appropriate since municipalities aim to reduce the costs incurred in distributing electricity. The municipalities are compared to a frontier (theoretical best practice) from which inferences on their performances can be made. Those municipalities whose performances are not optimal, deviate from the frontier. The deviations (errors) are then assumed to be caused by two factors, namely stochastic random noise and inefficiency. This composition accounts for effects for which municipalities cannot control (stochastic random noise) and those for which it can (inefficiency). The parametric nature of the cost frontier approach allows for distributional assumptions to be made on these factors. Stochastic random noise is always assumed to be normally distributed, while inefficiency is assumed to be one-sided and positively skewed.
- Full Text:
- Date Issued: 2016
- Authors: Gqwaka, Aviwe Phelele Sebatian
- Date: 2016
- Subjects: Electric power distribution -- South Africa Public utilities -- South Africa Local government -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/10299 , vital:26650
- Description: Efficiency analysis in the public sector assesses the performance of municipal and government entities in their provision of services to the public. South Africa, in particular, has experienced a large degree of negative feedback with respect to the ability of the government and its municipal departments to provide basic services to citizens. This has led to a number of service delivery protests throughout the country. To remedy this, the ability of the municipality to provide basic services needs to be assessed in order for improvements to be made. A first step in this process would be to determine the efficiency with which municipalities are providing these services. This study focuses on a particular municipal service, namely electricity distribution. Primarily, the efficiency with which municipalities provide electricity to consumers is determined. This is achieved using the parametric cost frontier approach, which is appropriate since municipalities aim to reduce the costs incurred in distributing electricity. The municipalities are compared to a frontier (theoretical best practice) from which inferences on their performances can be made. Those municipalities whose performances are not optimal, deviate from the frontier. The deviations (errors) are then assumed to be caused by two factors, namely stochastic random noise and inefficiency. This composition accounts for effects for which municipalities cannot control (stochastic random noise) and those for which it can (inefficiency). The parametric nature of the cost frontier approach allows for distributional assumptions to be made on these factors. Stochastic random noise is always assumed to be normally distributed, while inefficiency is assumed to be one-sided and positively skewed.
- Full Text:
- Date Issued: 2016
Efficient energy transfer in ethynyl bridged corrole–BODIPY dyads
- Yan, Yu, Wu, Fan, Qin, Jiawei, Xu, Haijun, Shi, Maohu, Zhou, Jingfeng, Mack, John, Fomo, Gertrude, Nyokong, Tebello, Shen, Zhen
- Authors: Yan, Yu , Wu, Fan , Qin, Jiawei , Xu, Haijun , Shi, Maohu , Zhou, Jingfeng , Mack, John , Fomo, Gertrude , Nyokong, Tebello , Shen, Zhen
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240899 , vital:50883 , xlink:href="https://doi.org/10.1039/C6RA12271J"
- Description: A series of new corrole–BODIPY dyads bridged by ethynyl linker moieties have been synthesized in high yields and fully characterized. The direction of energy transfer upon electronic excitation has been explored, and was found to be dependent on the number of corrole rings and their connection position on the BODIPY core. Intense bands in the absorption spectrum cover most of the visible region, which is potentially advantageous for capturing solar energy. Studies on the excitation spectra and lifetimes suggest that the energy transfer efficiency between the BODIPY and corrole moieties reaches almost 85%, which appears to be efficient in the context of energy transfer within the singlet manifold.
- Full Text:
- Date Issued: 2016
- Authors: Yan, Yu , Wu, Fan , Qin, Jiawei , Xu, Haijun , Shi, Maohu , Zhou, Jingfeng , Mack, John , Fomo, Gertrude , Nyokong, Tebello , Shen, Zhen
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240899 , vital:50883 , xlink:href="https://doi.org/10.1039/C6RA12271J"
- Description: A series of new corrole–BODIPY dyads bridged by ethynyl linker moieties have been synthesized in high yields and fully characterized. The direction of energy transfer upon electronic excitation has been explored, and was found to be dependent on the number of corrole rings and their connection position on the BODIPY core. Intense bands in the absorption spectrum cover most of the visible region, which is potentially advantageous for capturing solar energy. Studies on the excitation spectra and lifetimes suggest that the energy transfer efficiency between the BODIPY and corrole moieties reaches almost 85%, which appears to be efficient in the context of energy transfer within the singlet manifold.
- Full Text:
- Date Issued: 2016
Elder man traditional beer
- Unknown family members and Dr. McConnachie
- Authors: Unknown family members and Dr. McConnachie
- Date: 2016
- Subjects: UNCATALOGUED
- Type: Image
- Identifier: http://hdl.handle.net/10962/219808 , vital:48559 , KHP-189
- Description: Elder man crouching to mix traditional beer in a tin , Use of this resource is governed by the terms and conditions of the Creative Commons "Attribution-NonCommercial-ShareAlike" License (http://creativecommons.org/licenses/by-nc-sa/2.0/) (NEVER CAHNGE THIS FIELD)
- Full Text: false
- Date Issued: 2016
- Authors: Unknown family members and Dr. McConnachie
- Date: 2016
- Subjects: UNCATALOGUED
- Type: Image
- Identifier: http://hdl.handle.net/10962/219808 , vital:48559 , KHP-189
- Description: Elder man crouching to mix traditional beer in a tin , Use of this resource is governed by the terms and conditions of the Creative Commons "Attribution-NonCommercial-ShareAlike" License (http://creativecommons.org/licenses/by-nc-sa/2.0/) (NEVER CAHNGE THIS FIELD)
- Full Text: false
- Date Issued: 2016
Electrical power output estimation model for a conical diffuser augmented wind turbine
- Authors: Masukume, Peace-Maker
- Date: 2016
- Subjects: Wind power , Wind turbines , Renewable energy sources
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/1517 , vital:27404
- Description: Energy is integral to the quality of life of any society. However, meeting the demand for energy sustainably is the main challenge facing humanity. In general, non-renewable energy resources are used to supply the ever increasing energy demand. However, the extraction and processing of these resources is accompanied by the production of wastes which are a health hazard and impact negatively on climate change. Considering the finite nature of non-renewable sources, the environmental concerns which are associated with their usage and ensuring energy security, renewable energy sources have been brought in the energy supply chain. Wind energy is one of the renewable energy sources which has been supplying electrical energy to the ever increasing energy demand of humanity. Wind energy technology is a mature technology which over and above the bare (conventional) wind turbine technology has seen the development of duct augmented wind turbines. Ducts are used to encase wind turbine rotors to augment the power output of wind turbines especially in low wind speed areas. Though the technology has been under study for decades now, research indicates that there is no known model to estimate the power output of a diffuser augmented wind turbine. This thesis presents the development of the conical Diffuser Augmented Wind Turbine (DAWT) power output estimation model and its validation.
- Full Text:
- Date Issued: 2016
- Authors: Masukume, Peace-Maker
- Date: 2016
- Subjects: Wind power , Wind turbines , Renewable energy sources
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/1517 , vital:27404
- Description: Energy is integral to the quality of life of any society. However, meeting the demand for energy sustainably is the main challenge facing humanity. In general, non-renewable energy resources are used to supply the ever increasing energy demand. However, the extraction and processing of these resources is accompanied by the production of wastes which are a health hazard and impact negatively on climate change. Considering the finite nature of non-renewable sources, the environmental concerns which are associated with their usage and ensuring energy security, renewable energy sources have been brought in the energy supply chain. Wind energy is one of the renewable energy sources which has been supplying electrical energy to the ever increasing energy demand of humanity. Wind energy technology is a mature technology which over and above the bare (conventional) wind turbine technology has seen the development of duct augmented wind turbines. Ducts are used to encase wind turbine rotors to augment the power output of wind turbines especially in low wind speed areas. Though the technology has been under study for decades now, research indicates that there is no known model to estimate the power output of a diffuser augmented wind turbine. This thesis presents the development of the conical Diffuser Augmented Wind Turbine (DAWT) power output estimation model and its validation.
- Full Text:
- Date Issued: 2016
Electrocatalytic activity of nanocomposites of sulphur doped graphene oxide and nanosized cobalt phthalocyanines
- Shumba, Munyaradzi, Nyokong, Tebello
- Authors: Shumba, Munyaradzi , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188530 , vital:44762 , xlink:href="https://doi.org/10.1002/elan.201600226"
- Description: In this work we explore the electrocatalytic activity of nanocomposites of reduced sulphur doped graphene oxide nanosheets (rSDGONS) and cobalt phthalocyanine (CoPc) or cobalt tetra amino phthalocyanine (CoTAPc) towards hydrogen peroxide. Transmission electron microscopy, scanning electron microscopy, X-ray photon spectroscopy, X-ray diffraction, chronoamperometry, linear scan voltammetry and cyclic voltammetry were used to characterize the nanocomposites. Nanosized CoPc showed superior (in terms of currents) electrocatalytic oxidation and reduction of hydrogen peroxide compared to CoTAPc nanoparticles (CoTAPcNP). The lowest detection limit was obtained for hydrogen peroxide oxidation on electrodes modified with CoPcNP-rSDGONS at 1.49 µM. The same electrode gave a high adsorption equilibrium constant of 1.27×103 mol−1 and a Gibbs free energy of −17.71 kJ/mol, indicative of a spontaneous reaction on the electrode surface.
- Full Text:
- Date Issued: 2016
- Authors: Shumba, Munyaradzi , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188530 , vital:44762 , xlink:href="https://doi.org/10.1002/elan.201600226"
- Description: In this work we explore the electrocatalytic activity of nanocomposites of reduced sulphur doped graphene oxide nanosheets (rSDGONS) and cobalt phthalocyanine (CoPc) or cobalt tetra amino phthalocyanine (CoTAPc) towards hydrogen peroxide. Transmission electron microscopy, scanning electron microscopy, X-ray photon spectroscopy, X-ray diffraction, chronoamperometry, linear scan voltammetry and cyclic voltammetry were used to characterize the nanocomposites. Nanosized CoPc showed superior (in terms of currents) electrocatalytic oxidation and reduction of hydrogen peroxide compared to CoTAPc nanoparticles (CoTAPcNP). The lowest detection limit was obtained for hydrogen peroxide oxidation on electrodes modified with CoPcNP-rSDGONS at 1.49 µM. The same electrode gave a high adsorption equilibrium constant of 1.27×103 mol−1 and a Gibbs free energy of −17.71 kJ/mol, indicative of a spontaneous reaction on the electrode surface.
- Full Text:
- Date Issued: 2016
Electrode modification using alkyne manganese phthalocyanine and click chemistry for electrocatalysis
- O'Donoghue, Charles St John Nqwabuko, Fomo, Gertrude, Nyokong, Tebello
- Authors: O'Donoghue, Charles St John Nqwabuko , Fomo, Gertrude , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188541 , vital:44763 , xlink:href="https://doi.org/10.1002/elan.201600379"
- Description: In this work, azidobenzene diazonium salt is grafted onto a glassy carbon electrode (GCE) followed by clicking of manganese tetrahexynyl phthalocyanine for the electrocatalysis of hydrazine. The GCE was first grafted via the in situ diazotization of a diazonium salt, rendering the GCE surface layered with azide groups. From this point, the 1,3-dipolar cycloaddition reaction, catalyzed by a copper catalyst was utilized to ‘click’ the manganese tetrahexynyl phthalocyanine to the surface of the grafted GCE. This new platform was then characterized using cyclic voltammetry (CV), scanning electrochemical microscopy (SECM) and X-ray photoelectron spectroscopy (XPS). Based on the cyclic voltammetry calibration curve of electrocatalysis for hydrazine, the clicked Mn phthalocyanine electrode proved to be an effective sensor with a sensitivity of 27.38 µA mM−1 and the limit of detection (LoD) of 15.4 pM which is a great improvement compared to other reported sensors for this analyte.
- Full Text:
- Date Issued: 2016
- Authors: O'Donoghue, Charles St John Nqwabuko , Fomo, Gertrude , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188541 , vital:44763 , xlink:href="https://doi.org/10.1002/elan.201600379"
- Description: In this work, azidobenzene diazonium salt is grafted onto a glassy carbon electrode (GCE) followed by clicking of manganese tetrahexynyl phthalocyanine for the electrocatalysis of hydrazine. The GCE was first grafted via the in situ diazotization of a diazonium salt, rendering the GCE surface layered with azide groups. From this point, the 1,3-dipolar cycloaddition reaction, catalyzed by a copper catalyst was utilized to ‘click’ the manganese tetrahexynyl phthalocyanine to the surface of the grafted GCE. This new platform was then characterized using cyclic voltammetry (CV), scanning electrochemical microscopy (SECM) and X-ray photoelectron spectroscopy (XPS). Based on the cyclic voltammetry calibration curve of electrocatalysis for hydrazine, the clicked Mn phthalocyanine electrode proved to be an effective sensor with a sensitivity of 27.38 µA mM−1 and the limit of detection (LoD) of 15.4 pM which is a great improvement compared to other reported sensors for this analyte.
- Full Text:
- Date Issued: 2016
Electrode modification using nanocomposites of boron or nitrogen doped graphene oxide and cobalt (II) tetra aminophenoxy phthalocyanine nanoparticles
- Shumba, Munyaradzi, Nyokong, Tebello
- Authors: Shumba, Munyaradzi , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188699 , vital:44777 , xlink:href="https://doi.org/10.1016/j.electacta.2016.02.166"
- Description: Reduced graphene oxide nanosheets (rGONS), reduced boron doped graphene oxide nanosheets (rBDGONS) and reduced nitrogen doped graphene oxide nanosheets (rNDGONS) and their composites with cobalt tetra aminophenoxy phthalocyanine nanoparticles (CoTAPhPcNP) were employed towards the detection of hydrogen peroxide. The nanomaterials were characterized by absorption spectroscopy, transmission electron microscopy, scanning electron microscopy, Raman spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, linear sweep voltammetry and cyclic voltammetry. rNDGONS showed excellent electrooxidation and electroreduction of hydrogen peroxide supported by superior surface coverage values. The inclusion of nanosized Pc significantly lowered the reduction overpotential. CoTAPhPcNP-rNDGONS-GCE gave a sensitivity of 39.30 mA/M, catalytic rate constant of 1 × 103 M−1 s−1 and a detection limit of 8.2 nM. An adsorption equilibrium constant and Gibbs free energy of 1.26 × 103 M−1 and −17.69 kJ mol−1 respectively were observed.
- Full Text:
- Date Issued: 2016
- Authors: Shumba, Munyaradzi , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188699 , vital:44777 , xlink:href="https://doi.org/10.1016/j.electacta.2016.02.166"
- Description: Reduced graphene oxide nanosheets (rGONS), reduced boron doped graphene oxide nanosheets (rBDGONS) and reduced nitrogen doped graphene oxide nanosheets (rNDGONS) and their composites with cobalt tetra aminophenoxy phthalocyanine nanoparticles (CoTAPhPcNP) were employed towards the detection of hydrogen peroxide. The nanomaterials were characterized by absorption spectroscopy, transmission electron microscopy, scanning electron microscopy, Raman spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, linear sweep voltammetry and cyclic voltammetry. rNDGONS showed excellent electrooxidation and electroreduction of hydrogen peroxide supported by superior surface coverage values. The inclusion of nanosized Pc significantly lowered the reduction overpotential. CoTAPhPcNP-rNDGONS-GCE gave a sensitivity of 39.30 mA/M, catalytic rate constant of 1 × 103 M−1 s−1 and a detection limit of 8.2 nM. An adsorption equilibrium constant and Gibbs free energy of 1.26 × 103 M−1 and −17.69 kJ mol−1 respectively were observed.
- Full Text:
- Date Issued: 2016
Electrode modification using nanocomposites of electropolymerised cobalt phthalocyanines supported on multiwalled carbon nanotubes
- Nyoni, Stephen, Mashazi, Philani N, Nyokong, Tebello
- Authors: Nyoni, Stephen , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188730 , vital:44780 , xlink:href="https://doi.org/10.1007/s10008-015-2985-6"
- Description: A polymer of tetra(4)-(4,6-diaminopyrimidin-2-ylthio) phthalocyaninatocobalt(II) (CoPyPc) has been deposited over a multiwalled carbon nanotube (MWCNT) platform and its electrocatalytic properties investigated side by side with polymerized cobalt tetraamino phthalocyanine (CoTAPc). X-ray photoelectron spectroscopy, scanning electron microscopy and cyclic voltammetry studies were used for characterization of the prepared polymers of cobalt phthalocyanine derivatives and their nanocomposites. L-Cysteine was used as a test analyte for the electrocatalytic activity of the nanocomposites of polymerized cobalt phthalocyanines and multiwalled carbon nanotubes. The electrocatalytic activity of both polymerized cobalt phthalocyanines was found to be superior when polymerization was done on top of MWCNTs compared to bare glassy carbon electrode. A higher sensitivity for L-cysteine detection was obtained on CoTAPc compared to CoPyPc.
- Full Text:
- Date Issued: 2016
- Authors: Nyoni, Stephen , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188730 , vital:44780 , xlink:href="https://doi.org/10.1007/s10008-015-2985-6"
- Description: A polymer of tetra(4)-(4,6-diaminopyrimidin-2-ylthio) phthalocyaninatocobalt(II) (CoPyPc) has been deposited over a multiwalled carbon nanotube (MWCNT) platform and its electrocatalytic properties investigated side by side with polymerized cobalt tetraamino phthalocyanine (CoTAPc). X-ray photoelectron spectroscopy, scanning electron microscopy and cyclic voltammetry studies were used for characterization of the prepared polymers of cobalt phthalocyanine derivatives and their nanocomposites. L-Cysteine was used as a test analyte for the electrocatalytic activity of the nanocomposites of polymerized cobalt phthalocyanines and multiwalled carbon nanotubes. The electrocatalytic activity of both polymerized cobalt phthalocyanines was found to be superior when polymerization was done on top of MWCNTs compared to bare glassy carbon electrode. A higher sensitivity for L-cysteine detection was obtained on CoTAPc compared to CoPyPc.
- Full Text:
- Date Issued: 2016
Electrode surface modification using iron(II) phthalocyanine immobilized via electrografting and click chemistry and clicked onto azide-functionalized quantum dots: applications in electrocatalysis
- Authors: Nxele, Siphesihle Robin
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/3464 , vital:20501
- Description: Tetrakis(5-hexynoxy)Fe(II) phthalocyanine was used alone and in combination with quantum dots (QDs) in order to test the electrocatalytic ability with hydrazine and paraquat as the analytes of interest. This novel phthalocaynine was successfully synthesised and characterized using various characterisation techniques. The QDs used were the well-known core-shell CdSe/ZnS nanostructures. The fabrication of glassy carbon electrodes involved covalent attachment by electrochemical grafting and click chemistry for the first part of the work and the second part involved the conjugation of the synthesised QDs and the phthalocyanine by click chemistry. This approach of conjugating these nanostructures introduced another aspect of novelty to the work reported in this thesis. The immobilisation of this conjugate on a glassy carbon electrode (GCE) was achieved by adsorption. Characterisation techniques such as infrared spectroscopy, x-ray diffractometry, UV/vis spectroscopy, transmission electron microscopy and x-ray photoelectron spectroscopy were used to characterise the molecules and conjugates of interest. With respect to the electrocatalytic part of the work, electrode surface characterisation involved scanning electrochemical microscopy and cyclic voltammetry to determine changes in the nature of the surface as well as reactivity of the surface at different modification steps. Detection limits and the sensitivity determined for the electrocatalysts fabricated here proved to be an improvement compared to other reported work involving phthalocyanines and the test analytes chosen for application. With respect to the conjugate, the electrocatalytic ability was improved when the QDs and phthalocyanine were combined using click chemistry compared to using the phthalocyanine alone.
- Full Text:
- Date Issued: 2016
- Authors: Nxele, Siphesihle Robin
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/3464 , vital:20501
- Description: Tetrakis(5-hexynoxy)Fe(II) phthalocyanine was used alone and in combination with quantum dots (QDs) in order to test the electrocatalytic ability with hydrazine and paraquat as the analytes of interest. This novel phthalocaynine was successfully synthesised and characterized using various characterisation techniques. The QDs used were the well-known core-shell CdSe/ZnS nanostructures. The fabrication of glassy carbon electrodes involved covalent attachment by electrochemical grafting and click chemistry for the first part of the work and the second part involved the conjugation of the synthesised QDs and the phthalocyanine by click chemistry. This approach of conjugating these nanostructures introduced another aspect of novelty to the work reported in this thesis. The immobilisation of this conjugate on a glassy carbon electrode (GCE) was achieved by adsorption. Characterisation techniques such as infrared spectroscopy, x-ray diffractometry, UV/vis spectroscopy, transmission electron microscopy and x-ray photoelectron spectroscopy were used to characterise the molecules and conjugates of interest. With respect to the electrocatalytic part of the work, electrode surface characterisation involved scanning electrochemical microscopy and cyclic voltammetry to determine changes in the nature of the surface as well as reactivity of the surface at different modification steps. Detection limits and the sensitivity determined for the electrocatalysts fabricated here proved to be an improvement compared to other reported work involving phthalocyanines and the test analytes chosen for application. With respect to the conjugate, the electrocatalytic ability was improved when the QDs and phthalocyanine were combined using click chemistry compared to using the phthalocyanine alone.
- Full Text:
- Date Issued: 2016
Embassy of the Federal Republic of Germany Pretoria
- Smith, Jan-Willem Christiaan
- Authors: Smith, Jan-Willem Christiaan
- Date: 2016
- Subjects: Embassy buildings -- South Africa -- Pretoria -- Design Architecture, Modern -- 21st century , Historic buildings -- South Africa --Pretoria
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/15400 , vital:28239
- Description: This treatise aims to demonstrate an understanding of the complexities involved in the design of a German Embassy in Pretoria, in terms of technicality and identity. Programmatic requirements will be considered, with an emphasis on creating the maximum level of security against any reasonable threat. The identity of the embassy will also be considered through the lens of a symbolic aesthetic that must be reconciled with the embassy’s physical and symbolic context. At a time of increasing cultural homogenisation and growing sameness within an ever more interconnected world, this treatise will explore the problem of creating a unique physical expression of German cultural and political identity. This aim exists in tension with the growing fluidity and porosity of cultural identity at the present moment, and the research herein therefore seeks to articulate a new vision of cultural identity that can coexist with globalisation without losing its own specificity. In essence, an attempt will be made to give a concrete expression to cultural identity and move beyond preconceptions of this idea.
- Full Text:
- Date Issued: 2016
- Authors: Smith, Jan-Willem Christiaan
- Date: 2016
- Subjects: Embassy buildings -- South Africa -- Pretoria -- Design Architecture, Modern -- 21st century , Historic buildings -- South Africa --Pretoria
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/15400 , vital:28239
- Description: This treatise aims to demonstrate an understanding of the complexities involved in the design of a German Embassy in Pretoria, in terms of technicality and identity. Programmatic requirements will be considered, with an emphasis on creating the maximum level of security against any reasonable threat. The identity of the embassy will also be considered through the lens of a symbolic aesthetic that must be reconciled with the embassy’s physical and symbolic context. At a time of increasing cultural homogenisation and growing sameness within an ever more interconnected world, this treatise will explore the problem of creating a unique physical expression of German cultural and political identity. This aim exists in tension with the growing fluidity and porosity of cultural identity at the present moment, and the research herein therefore seeks to articulate a new vision of cultural identity that can coexist with globalisation without losing its own specificity. In essence, an attempt will be made to give a concrete expression to cultural identity and move beyond preconceptions of this idea.
- Full Text:
- Date Issued: 2016
Emergence of Environment and Sustainability Education (ESE) in teacher education contexts in Southern Africa : a common good concern
- Mandikonza, Caleb, Lotz-Sisitka, Heila
- Authors: Mandikonza, Caleb , Lotz-Sisitka, Heila
- Date: 2016
- Subjects: Sustainable development -- Study and teaching -- South Africa , Environmental education -- South Africa , SADC Regional Environmental Education Programme
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59624 , vital:27632 , http://dx.doi.org/10.17159/2221-4070/2016/v5i1a7
- Description: Environmental and sustainability issues prevail in modern society. Southern Africa, where this study is based, is one of the regions most at risk from intersecting issues of climate health risk, and poverty-related ills. Education has the potential to facilitate catalytic transformation of society through development of understandings of these intersecting environment and sustainability concerns, and to support engagements in more sustainable social practices oriented towards the common good. This requires a rethinking of education within a wider common good frame. It also has implications for how quality education is considered. However, little is said of how this could be done, especially in teacher education. The paper shares two cases of teacher educators’ change project experiences, as they emerged via professional development support and the mediatory processes applied in courses conducted by the Southern African Development Community Regional Environmental Education Programme (SADC REEP) aimed at enhancing professional capacity of teacher educators and other environmental educators for mainstreaming environment and sustainability education (ESE)1. These courses are framed using a change project approach, and involve teacher educators as main participants. In-depth data were generated from interviews with two teacher educators, their assignment write-ups, and observations of their teacher education practice. Realist social theory, particularly the principle of emergence, was used to trace the emergence of change in teacher education practice. Sociocultural learning theory was used to explain mediation of learning-oriented changes in teacher education practice. We illustrate how the change project model and approach contributed to mediating change in practice, showing emergent attributes of capacity for mainstreaming ESE and elements of a concept of quality education among course participants oriented towards the common good. In conclusion, we argue that ESE seems to be a sensitising construct for initiating and sustaining change for ESE in teacher education. In addition, the change project has proved to be a potential vehicle for mainstreaming the notion and practice of ESE into social systems and teacher education practices. We argue that reflexive ESE praxis provides a sensitising focus, initiating quality education with humanising properties necessary for the common good.
- Full Text:
- Date Issued: 2016
- Authors: Mandikonza, Caleb , Lotz-Sisitka, Heila
- Date: 2016
- Subjects: Sustainable development -- Study and teaching -- South Africa , Environmental education -- South Africa , SADC Regional Environmental Education Programme
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/10962/59624 , vital:27632 , http://dx.doi.org/10.17159/2221-4070/2016/v5i1a7
- Description: Environmental and sustainability issues prevail in modern society. Southern Africa, where this study is based, is one of the regions most at risk from intersecting issues of climate health risk, and poverty-related ills. Education has the potential to facilitate catalytic transformation of society through development of understandings of these intersecting environment and sustainability concerns, and to support engagements in more sustainable social practices oriented towards the common good. This requires a rethinking of education within a wider common good frame. It also has implications for how quality education is considered. However, little is said of how this could be done, especially in teacher education. The paper shares two cases of teacher educators’ change project experiences, as they emerged via professional development support and the mediatory processes applied in courses conducted by the Southern African Development Community Regional Environmental Education Programme (SADC REEP) aimed at enhancing professional capacity of teacher educators and other environmental educators for mainstreaming environment and sustainability education (ESE)1. These courses are framed using a change project approach, and involve teacher educators as main participants. In-depth data were generated from interviews with two teacher educators, their assignment write-ups, and observations of their teacher education practice. Realist social theory, particularly the principle of emergence, was used to trace the emergence of change in teacher education practice. Sociocultural learning theory was used to explain mediation of learning-oriented changes in teacher education practice. We illustrate how the change project model and approach contributed to mediating change in practice, showing emergent attributes of capacity for mainstreaming ESE and elements of a concept of quality education among course participants oriented towards the common good. In conclusion, we argue that ESE seems to be a sensitising construct for initiating and sustaining change for ESE in teacher education. In addition, the change project has proved to be a potential vehicle for mainstreaming the notion and practice of ESE into social systems and teacher education practices. We argue that reflexive ESE praxis provides a sensitising focus, initiating quality education with humanising properties necessary for the common good.
- Full Text:
- Date Issued: 2016
Emergent effects of structural complexity and temperature on predator–prey interactions
- Wasserman, Ryan J, Alexander, Mhairi E, Weyl, Olaf L F, Barrios‐O'Neill, Daniel, Froneman, P William, Dalu, Tatenda
- Authors: Wasserman, Ryan J , Alexander, Mhairi E , Weyl, Olaf L F , Barrios‐O'Neill, Daniel , Froneman, P William , Dalu, Tatenda
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69190 , vital:29444 , https://doi.org/10.1002/ecs2.1239
- Description: Ephemeral aquatic environments are important habitats for a variety of species. They are highly variable with regards to vegetation structure and physico‐chemical features that potentially mediate outcomes of biotic interactions. Multiple environmental variables and their emergent impacts on the relationship between prey consumption rate by a predator and prey density (functional response), however, are rarely assessed. Here, we investigated the combined effects of temperature and habitat complexity on the functional response of the freshwater predatory notonectid Enithares sobria on the cladoceran prey organism Daphnia longispina. A Type II functional response was observed for E. sobria predating on D. longispina and while temperature and habitat complexity had no effect on the response type, these environmental variables interacted with consequences for the magnitude of the functional responses. Overall, structural complexity favored the predator as greater consumption was observed in the most complex habitat treatment. Temperature effects were also evident although these effects were not unidirectional with regard to treatment factor gradients as predators were the most successful at intermediary temperatures. Furthermore, there was a complex interplay between habitat complexity and temperature, with attack rates being greatest at low and high complexities within intermediate temperatures, while at zero complexity attack rates were greatest at the lowest temperature. The effect of habitat on handling times was only evident in the low temperature treatments which decreased steadily with each increase in complexity. Through the application of functional responses the synergistic effects of multiple environmental drivers on predator–prey interaction outcomes have been highlighted, adding insight into how interactions among species may be affected by natural or artificially induced environmental variability.
- Full Text:
- Date Issued: 2016
- Authors: Wasserman, Ryan J , Alexander, Mhairi E , Weyl, Olaf L F , Barrios‐O'Neill, Daniel , Froneman, P William , Dalu, Tatenda
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/69190 , vital:29444 , https://doi.org/10.1002/ecs2.1239
- Description: Ephemeral aquatic environments are important habitats for a variety of species. They are highly variable with regards to vegetation structure and physico‐chemical features that potentially mediate outcomes of biotic interactions. Multiple environmental variables and their emergent impacts on the relationship between prey consumption rate by a predator and prey density (functional response), however, are rarely assessed. Here, we investigated the combined effects of temperature and habitat complexity on the functional response of the freshwater predatory notonectid Enithares sobria on the cladoceran prey organism Daphnia longispina. A Type II functional response was observed for E. sobria predating on D. longispina and while temperature and habitat complexity had no effect on the response type, these environmental variables interacted with consequences for the magnitude of the functional responses. Overall, structural complexity favored the predator as greater consumption was observed in the most complex habitat treatment. Temperature effects were also evident although these effects were not unidirectional with regard to treatment factor gradients as predators were the most successful at intermediary temperatures. Furthermore, there was a complex interplay between habitat complexity and temperature, with attack rates being greatest at low and high complexities within intermediate temperatures, while at zero complexity attack rates were greatest at the lowest temperature. The effect of habitat on handling times was only evident in the low temperature treatments which decreased steadily with each increase in complexity. Through the application of functional responses the synergistic effects of multiple environmental drivers on predator–prey interaction outcomes have been highlighted, adding insight into how interactions among species may be affected by natural or artificially induced environmental variability.
- Full Text:
- Date Issued: 2016
Emergent governance practices in the University of Malawi following reform implementation from 1997 to 2013
- Authors: Nampota, Tarsizius
- Date: 2016
- Subjects: Education, Higher -- Malawi , Universities and colleges -- Malawi , University of Malawi , Educational change -- Malawi
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1330 , http://hdl.handle.net/10962/d1019933
- Description: Higher education reform is an international phenomenon and one that greatly impacts on the form and function of Universities in society. I set out in this study to investigate the University of Malawi’s (UNIMA) experiences with governance reforms after observing that no comprehensive study of this process had been undertaken following the implementation of these reforms from 1997. I used Bhaskar’s Critical Realist Theory as my main theoretical framework because my intention was to understand the mechanisms from which such reforms emerged: the emergent governance practices and properties enabling or constraining governance reforms in UNIMA. I employed Archer’s Social Realist Theory in my research design and interpretation of the results, which entailed that I focus on issues of structure, culture and agency in UNIMA governance. I have established that the governance context in UNIMA in 1995 at the time the reforms were being considered was one that promoted the continuation of the status quo because the Malawi Government’s vested interest then was to exercise great control over UNIMA at system, institutional and disciplinary level of governance due to the political imperatives of the time in Malawi. However, this situation was frustrating to many in the University as it greatly impeded academic freedom. Furthermore, in 1995 the University relied heavily on Government’s financial structures. When these were subjected to structural reforms under the influence of the World Bank and the International Monetary Fund in the early nineties the impact seriously undermined the University’s revenue base and threatened to challenge further the realization of the University’s objectives. This prompted changes in the administrative and academic governance structures and culture intended to improve utilisation of the available limited resources as well as to broaden the University’s revenue base. The governance reform measures that were introduced were mainly influenced by New Public Management (NPM) ideologies. Most of the reforms intended to transform the administrative structures and culture were successfully implemented. The study revealed that this was enabled by the interests of those operating at disciplinary levels who were frustrated by the previous constraining governance context and who viewed such reforms as bringing about the self-governance they lacked. However, the majority of the reforms that were mainly targeted at academic restructuring were resisted because they were construed as contradictory to the interests of those in the academy particularly those concerned with matters of academic freedom. The study further revealed that the academic reforms were constrained by a lack of agency for change management and weak leadership at the top senior level of the University. In addition, there have been delays in amending the UNIMA Act, which should have catalysed some of the reforms, a scenario that has perpetuated many aspects of the institutional level of governance. Consequently, compared to the situation before the reforms were introduced, governance in UNIMA at the time of reporting manifested two scenarios: (a) an elaboration in governance practices at systems level where Government machinery exercises control and at enterprise (college) level where faculties and academic departments operate promoting cultural morphogenesis, or changes at the level of ideas, beliefs and values, which in turn is exerting pressure on governance practices at institutional level; and (b) morphostasis, or lack of change, at institutional levels of the governance exacerbated by the lack of amendment of the UNIMA Act and weak leadership. The findings have also led to uncertainty regarding the unitary nature of the University. There are fears that once the UNIMA Act is amended the four colleges forming UNIMA might break away to become separate universities.
- Full Text:
- Date Issued: 2016
- Authors: Nampota, Tarsizius
- Date: 2016
- Subjects: Education, Higher -- Malawi , Universities and colleges -- Malawi , University of Malawi , Educational change -- Malawi
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1330 , http://hdl.handle.net/10962/d1019933
- Description: Higher education reform is an international phenomenon and one that greatly impacts on the form and function of Universities in society. I set out in this study to investigate the University of Malawi’s (UNIMA) experiences with governance reforms after observing that no comprehensive study of this process had been undertaken following the implementation of these reforms from 1997. I used Bhaskar’s Critical Realist Theory as my main theoretical framework because my intention was to understand the mechanisms from which such reforms emerged: the emergent governance practices and properties enabling or constraining governance reforms in UNIMA. I employed Archer’s Social Realist Theory in my research design and interpretation of the results, which entailed that I focus on issues of structure, culture and agency in UNIMA governance. I have established that the governance context in UNIMA in 1995 at the time the reforms were being considered was one that promoted the continuation of the status quo because the Malawi Government’s vested interest then was to exercise great control over UNIMA at system, institutional and disciplinary level of governance due to the political imperatives of the time in Malawi. However, this situation was frustrating to many in the University as it greatly impeded academic freedom. Furthermore, in 1995 the University relied heavily on Government’s financial structures. When these were subjected to structural reforms under the influence of the World Bank and the International Monetary Fund in the early nineties the impact seriously undermined the University’s revenue base and threatened to challenge further the realization of the University’s objectives. This prompted changes in the administrative and academic governance structures and culture intended to improve utilisation of the available limited resources as well as to broaden the University’s revenue base. The governance reform measures that were introduced were mainly influenced by New Public Management (NPM) ideologies. Most of the reforms intended to transform the administrative structures and culture were successfully implemented. The study revealed that this was enabled by the interests of those operating at disciplinary levels who were frustrated by the previous constraining governance context and who viewed such reforms as bringing about the self-governance they lacked. However, the majority of the reforms that were mainly targeted at academic restructuring were resisted because they were construed as contradictory to the interests of those in the academy particularly those concerned with matters of academic freedom. The study further revealed that the academic reforms were constrained by a lack of agency for change management and weak leadership at the top senior level of the University. In addition, there have been delays in amending the UNIMA Act, which should have catalysed some of the reforms, a scenario that has perpetuated many aspects of the institutional level of governance. Consequently, compared to the situation before the reforms were introduced, governance in UNIMA at the time of reporting manifested two scenarios: (a) an elaboration in governance practices at systems level where Government machinery exercises control and at enterprise (college) level where faculties and academic departments operate promoting cultural morphogenesis, or changes at the level of ideas, beliefs and values, which in turn is exerting pressure on governance practices at institutional level; and (b) morphostasis, or lack of change, at institutional levels of the governance exacerbated by the lack of amendment of the UNIMA Act and weak leadership. The findings have also led to uncertainty regarding the unitary nature of the University. There are fears that once the UNIMA Act is amended the four colleges forming UNIMA might break away to become separate universities.
- Full Text:
- Date Issued: 2016
Emotional intelligence training model for executive leadership in South Africa
- Authors: Els, Deon André
- Date: 2016
- Subjects: Development leadership -- South Africa , Executives -- Training of -- South Africa , Emotional intelligence -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/7398 , vital:21350
- Description: Global leadership crises and increasing executive leadership failures necessitate a new approach to executive leadership development. Globalisation results in new leadership challenges that affect people, the planet and peace across the world. Critical issues include increasing extremism and terrorism, displaced migrants fleeing to stable countries, earth warming and economic decline. The role of the individual executive leader cannot be isolated from human development challenges. Various executive leadership failures and examples of unethical leadership practises, both internationally and in South Africa, place the focus on ethical governance and emotionally matured leadership development. This study follows a nexus, based on a three-stranded cordial link between human development, emotional intelligence and executive leadership. The central themes of the United Nations Human Development’s (UNDP) reports of 1990 to 2009 as well as the Post-United Nations Human Development Report of 2015 form a framework for evaluating the relationship between human development and executive leadership. Although economic growth is central to human development, the development of people through building human capabilities and active participation to improve their lives, are the main goals of the UNDP-2015. The role of executive leadership, leadership derailment and required executive proficiencies and attributes are investigated by evaluating traditional leadership theories and approaches as a lens for investigating leadership development. The positive effect of globalisation is that it affords new approaches and opportunities for executive leadership development. Emotional intelligence-based leadership, including the role of neuro-leadership, is evaluated and an integrative approach that involves the new paradigm of leadership as a response to human development challenges and globalisation is presented. The new paradigm of integrative leadership approaches includes empirical-based authentic leadership, shared leadership and gender-based leadership. The integrative leadership models of Hatala and Passmore are selected as a framework to propose a theoretical emotional intelligence leadership model for this study. New opportunities to develop emotionally intelligent executive leaders include technology-based training, iLeadership and eLeadership in an environment without boundaries. Time constraints are identified as a key obstacle for leadership development. Various training and executive coaching strategies are evaluated and proposed to accelerate leadership development. The link between human development and executive leadership development is proposed by collective leadership approaches towards Corporate Social Responsibilities (CSR) above entrepreneurial acumen and stakeholder involvement. A positivist approach based on quantitative research using Structural Equation Modelling (SEM) is used. The primary research problem is formulated to investigate the multidimensional and complex nature of factors that influence the success of developing emotionally intelligent executive leaders in South Africa. A conceptual theoretical model comprising of factors that influence Human Development and the perceived success of Emotional Intelligence Training is developed. A total of ten independent variables that influence the two mentioned dependent variables are identified. The proposed model and envisaged hypotheses are empirically tested. The study consists of a 73-itemed questionnaire with 360 participants. The sourced data are statically analysed by means of the exploratory factor analysis (EFA) to assess the discriminate validity of the research instrument and to confirm underlying dimensions of the constructs. Cronbach-alpha coefficients are calculated for each of the identified factors by using SEM. The significance of the hypothesised relationships in the revised model is tested. The value of this study’s contribution to the body of knowledge lies within the findings, the proposed Integrative Emotional Intelligence Leadership Model and recommendations for future research. The proposed model identifies practical training approaches to accelerate executive leadership against a background of serious leadership failures in South Africa.
- Full Text:
- Date Issued: 2016
- Authors: Els, Deon André
- Date: 2016
- Subjects: Development leadership -- South Africa , Executives -- Training of -- South Africa , Emotional intelligence -- South Africa
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/7398 , vital:21350
- Description: Global leadership crises and increasing executive leadership failures necessitate a new approach to executive leadership development. Globalisation results in new leadership challenges that affect people, the planet and peace across the world. Critical issues include increasing extremism and terrorism, displaced migrants fleeing to stable countries, earth warming and economic decline. The role of the individual executive leader cannot be isolated from human development challenges. Various executive leadership failures and examples of unethical leadership practises, both internationally and in South Africa, place the focus on ethical governance and emotionally matured leadership development. This study follows a nexus, based on a three-stranded cordial link between human development, emotional intelligence and executive leadership. The central themes of the United Nations Human Development’s (UNDP) reports of 1990 to 2009 as well as the Post-United Nations Human Development Report of 2015 form a framework for evaluating the relationship between human development and executive leadership. Although economic growth is central to human development, the development of people through building human capabilities and active participation to improve their lives, are the main goals of the UNDP-2015. The role of executive leadership, leadership derailment and required executive proficiencies and attributes are investigated by evaluating traditional leadership theories and approaches as a lens for investigating leadership development. The positive effect of globalisation is that it affords new approaches and opportunities for executive leadership development. Emotional intelligence-based leadership, including the role of neuro-leadership, is evaluated and an integrative approach that involves the new paradigm of leadership as a response to human development challenges and globalisation is presented. The new paradigm of integrative leadership approaches includes empirical-based authentic leadership, shared leadership and gender-based leadership. The integrative leadership models of Hatala and Passmore are selected as a framework to propose a theoretical emotional intelligence leadership model for this study. New opportunities to develop emotionally intelligent executive leaders include technology-based training, iLeadership and eLeadership in an environment without boundaries. Time constraints are identified as a key obstacle for leadership development. Various training and executive coaching strategies are evaluated and proposed to accelerate leadership development. The link between human development and executive leadership development is proposed by collective leadership approaches towards Corporate Social Responsibilities (CSR) above entrepreneurial acumen and stakeholder involvement. A positivist approach based on quantitative research using Structural Equation Modelling (SEM) is used. The primary research problem is formulated to investigate the multidimensional and complex nature of factors that influence the success of developing emotionally intelligent executive leaders in South Africa. A conceptual theoretical model comprising of factors that influence Human Development and the perceived success of Emotional Intelligence Training is developed. A total of ten independent variables that influence the two mentioned dependent variables are identified. The proposed model and envisaged hypotheses are empirically tested. The study consists of a 73-itemed questionnaire with 360 participants. The sourced data are statically analysed by means of the exploratory factor analysis (EFA) to assess the discriminate validity of the research instrument and to confirm underlying dimensions of the constructs. Cronbach-alpha coefficients are calculated for each of the identified factors by using SEM. The significance of the hypothesised relationships in the revised model is tested. The value of this study’s contribution to the body of knowledge lies within the findings, the proposed Integrative Emotional Intelligence Leadership Model and recommendations for future research. The proposed model identifies practical training approaches to accelerate executive leadership against a background of serious leadership failures in South Africa.
- Full Text:
- Date Issued: 2016
Employee engagement and staff retention in a motor manufacturing company in the Eastern Cape
- Authors: Sekalo,Siviwe
- Date: 2016
- Subjects: Employee retention -- South Africa -- Eastern Cape Motor industry -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/12757 , vital:27118
- Description: There is an overwhelming body of literature that exist in the subject of employee engagement. More and more studies are still conducted in this phenomenon as it had proved to produce high returns for organisations when mastered.The universal definition of this concept has not been found, various scholars continue to provide different views on how it should be defined. These definitions however bear common themes such as energy, taking initiative, going an extra mile, being grossly involved in the task, organisational citizenship, involvement, satisfaction, connection and enthusiasm which are caused by a feeling of being taken care of by the employer. It is clear from these that there is a reciprocal relationship between employer and employee which is claimed to have a link to profits and staff retention; as a result employers are increasingly devising strategies to engage the employees in order to reap the said benefits. The purpose of this study is to facilitate employee engagement and staff retention a motor manufacturing company in the Eastern Cape. In order to archive that the study assessed the level of engagement of artisans by means of a questionnaire focusing on factors such as meaningful work, organisational culture, social relationships, rewards and recognition and career development as these are repeatedly identified in the literature as key drivers of employee engagement. An imperial study was done on these drivers as well as on the existing company engagement programs to identify the employee’s perception of their effectiveness. The result of the study proves that artisans of this company are engaged and that all the drivers above were confirmed to have influence employee engagement and staff retention. The study however the study found that there is a split on the effectiveness of the existing engagement programs in the company with only less than 50% saying they were effective. A strong relationship was found to exist between all the factors that were studied and employee engagement and staff retention.
- Full Text:
- Date Issued: 2016
- Authors: Sekalo,Siviwe
- Date: 2016
- Subjects: Employee retention -- South Africa -- Eastern Cape Motor industry -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/12757 , vital:27118
- Description: There is an overwhelming body of literature that exist in the subject of employee engagement. More and more studies are still conducted in this phenomenon as it had proved to produce high returns for organisations when mastered.The universal definition of this concept has not been found, various scholars continue to provide different views on how it should be defined. These definitions however bear common themes such as energy, taking initiative, going an extra mile, being grossly involved in the task, organisational citizenship, involvement, satisfaction, connection and enthusiasm which are caused by a feeling of being taken care of by the employer. It is clear from these that there is a reciprocal relationship between employer and employee which is claimed to have a link to profits and staff retention; as a result employers are increasingly devising strategies to engage the employees in order to reap the said benefits. The purpose of this study is to facilitate employee engagement and staff retention a motor manufacturing company in the Eastern Cape. In order to archive that the study assessed the level of engagement of artisans by means of a questionnaire focusing on factors such as meaningful work, organisational culture, social relationships, rewards and recognition and career development as these are repeatedly identified in the literature as key drivers of employee engagement. An imperial study was done on these drivers as well as on the existing company engagement programs to identify the employee’s perception of their effectiveness. The result of the study proves that artisans of this company are engaged and that all the drivers above were confirmed to have influence employee engagement and staff retention. The study however the study found that there is a split on the effectiveness of the existing engagement programs in the company with only less than 50% saying they were effective. A strong relationship was found to exist between all the factors that were studied and employee engagement and staff retention.
- Full Text:
- Date Issued: 2016
Employee happiness in general motors
- Authors: Cooper, Julian
- Date: 2016
- Subjects: Job satisfaction -- South Africa , Corporate culture -- South Africa , Happiness -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/4365 , vital:20590
- Description: Happiness is essentially the degree to which you find and judge your existence as favourable, in addition to an enduring, psychological feeling of contentment. In the hedonic view, happiness is pleasant feelings and favourable judgements, while the contrasting eudaimonic view describes it as doing what is morally right, what is righteous, that will enhance growth and that is meaningful to an individual. Both these views contribute to the overall happiness of an individual. People that are pleased with their lives usually experience greater satisfaction in their jobs. This is in line with the literature as happiness is positively correlated with job satisfaction, which suggests that a happy employee will most likely result in one that is satisfied with his/her job. In addition, happiness is correlated with evidence of success in the workplace and can increase an employee’s effectiveness at work. It is, therefore, essential that organisations identify the factors which influence employee happiness in order to enhance its cultural value-offering for employees and, in turn, increase their levels of job satisfaction. Job satisfaction is essentially the degree to which a person enjoys his/her job. It is the positive emotional state resulting from the evaluation of one’s work experience. This has profitable outcomes such as improved work performance. Furthermore, people who experience satisfaction in their jobs are better ambassadors for their organisation, demonstrate greater commitment, are more engaged and perform better within the organisation than their unhappy peers. Job satisfaction can be deemed an attitude. It is therefore important to understand the dimensions of the job, which are complex and interrelated in nature, in order to understand job attitudes. Organisational culture has been shown to influence the attitude and behaviour of employees through shared values and beliefs in the organisation. It is for this reason that there is a significant need to determine the factors in organisational culture that influence employee happiness and, in turn, job satisfaction. An organisation’s employees, through their participation and commitment, can be regarded as the most important source of success for the organisation. Organisational culture can therefore, greatly influence the efficiency and effectiveness of an organisation through its employees. Moreover, the culture of an organisation has a significant influence on the commitment and satisfaction of its employees. It inspires employees not only to feel committed to the organisation but also to perform well. The correlation between organisational culture and job satisfaction have been examined by various authors in the literature. All of these authors found a positive relationship between the two concepts. These conclusions show that the culture of an organisation can actually influence an employee’s job satisfaction and therefore his/her happiness. This research investigates the cultural value-offering of General Motors South Africa (GMSA) and its alignment to the needs of its employees. Until the end of 2012, an employee needs-analysis regarding employee happiness and his/her job satisfaction, was non-existent in the organisation. Towards the end of 2012 the organisation introduced a “Workplace of Choice” survey to perform an employee needs-analysis in order to investigate if there was a difference between employee needs and the organisation’s cultural value-offering. Another “Workplace of Choice” survey followed in 2014. This, however, was performed with the staff employees only and not with the hourly employees. Many organisations neglect to analyse the workplace needs of their employees to ensure that the organisation fully understands and is able to satisfy or accommodate these needs. Understanding employee needs is crucial to an organisation’s success. It is therefore important that the organisation investigates the employee needs to be able to align them with the cultural value-offering of the organisation. The purpose of this study is to advance the current understanding of Employee Happiness in the workplace by conducting a systematic analysis of the factors in Organisational Culture that influence Employee Happiness and, in turn, their Job Satisfaction in GMSA.
- Full Text:
- Date Issued: 2016
- Authors: Cooper, Julian
- Date: 2016
- Subjects: Job satisfaction -- South Africa , Corporate culture -- South Africa , Happiness -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/4365 , vital:20590
- Description: Happiness is essentially the degree to which you find and judge your existence as favourable, in addition to an enduring, psychological feeling of contentment. In the hedonic view, happiness is pleasant feelings and favourable judgements, while the contrasting eudaimonic view describes it as doing what is morally right, what is righteous, that will enhance growth and that is meaningful to an individual. Both these views contribute to the overall happiness of an individual. People that are pleased with their lives usually experience greater satisfaction in their jobs. This is in line with the literature as happiness is positively correlated with job satisfaction, which suggests that a happy employee will most likely result in one that is satisfied with his/her job. In addition, happiness is correlated with evidence of success in the workplace and can increase an employee’s effectiveness at work. It is, therefore, essential that organisations identify the factors which influence employee happiness in order to enhance its cultural value-offering for employees and, in turn, increase their levels of job satisfaction. Job satisfaction is essentially the degree to which a person enjoys his/her job. It is the positive emotional state resulting from the evaluation of one’s work experience. This has profitable outcomes such as improved work performance. Furthermore, people who experience satisfaction in their jobs are better ambassadors for their organisation, demonstrate greater commitment, are more engaged and perform better within the organisation than their unhappy peers. Job satisfaction can be deemed an attitude. It is therefore important to understand the dimensions of the job, which are complex and interrelated in nature, in order to understand job attitudes. Organisational culture has been shown to influence the attitude and behaviour of employees through shared values and beliefs in the organisation. It is for this reason that there is a significant need to determine the factors in organisational culture that influence employee happiness and, in turn, job satisfaction. An organisation’s employees, through their participation and commitment, can be regarded as the most important source of success for the organisation. Organisational culture can therefore, greatly influence the efficiency and effectiveness of an organisation through its employees. Moreover, the culture of an organisation has a significant influence on the commitment and satisfaction of its employees. It inspires employees not only to feel committed to the organisation but also to perform well. The correlation between organisational culture and job satisfaction have been examined by various authors in the literature. All of these authors found a positive relationship between the two concepts. These conclusions show that the culture of an organisation can actually influence an employee’s job satisfaction and therefore his/her happiness. This research investigates the cultural value-offering of General Motors South Africa (GMSA) and its alignment to the needs of its employees. Until the end of 2012, an employee needs-analysis regarding employee happiness and his/her job satisfaction, was non-existent in the organisation. Towards the end of 2012 the organisation introduced a “Workplace of Choice” survey to perform an employee needs-analysis in order to investigate if there was a difference between employee needs and the organisation’s cultural value-offering. Another “Workplace of Choice” survey followed in 2014. This, however, was performed with the staff employees only and not with the hourly employees. Many organisations neglect to analyse the workplace needs of their employees to ensure that the organisation fully understands and is able to satisfy or accommodate these needs. Understanding employee needs is crucial to an organisation’s success. It is therefore important that the organisation investigates the employee needs to be able to align them with the cultural value-offering of the organisation. The purpose of this study is to advance the current understanding of Employee Happiness in the workplace by conducting a systematic analysis of the factors in Organisational Culture that influence Employee Happiness and, in turn, their Job Satisfaction in GMSA.
- Full Text:
- Date Issued: 2016
Employment and diversity in the cultural and creative industries in South Africa: research note
- Authors: Snowball, Jeanette D
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71493 , vital:29858 , https://hdl.handle.net/10520/EJC188591
- Description: The publication of Richard Florida's (2002) The Rise of the Creative Class marked a growing international interest in the creative economy. There are several ways of understanding the creative economy, often divided into the cultural and creative industries. Cultural industries are those whose major outputs have some symbolic value, such as fine arts, film and craft, jewelry design, publishing and fashion. Creative industries are defined more broadly as those that have knowledge as their major input. In addition to cultural goods and services, these include things like software design and internet services. UNESCO (2009) provides guidelines for defining the cultural and creative industries and the ways in which they can be measured, but there is currently no international consensus. Nor is there likely to be, since different countries will have very different levels of involvement and focus that may shape what information is useful, for example, for shaping policy.
- Full Text: false
- Date Issued: 2016
- Authors: Snowball, Jeanette D
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71493 , vital:29858 , https://hdl.handle.net/10520/EJC188591
- Description: The publication of Richard Florida's (2002) The Rise of the Creative Class marked a growing international interest in the creative economy. There are several ways of understanding the creative economy, often divided into the cultural and creative industries. Cultural industries are those whose major outputs have some symbolic value, such as fine arts, film and craft, jewelry design, publishing and fashion. Creative industries are defined more broadly as those that have knowledge as their major input. In addition to cultural goods and services, these include things like software design and internet services. UNESCO (2009) provides guidelines for defining the cultural and creative industries and the ways in which they can be measured, but there is currently no international consensus. Nor is there likely to be, since different countries will have very different levels of involvement and focus that may shape what information is useful, for example, for shaping policy.
- Full Text: false
- Date Issued: 2016