Integrated Algae Pond Systems for the Treatment of Municipal Wastewater
- Authors: Mambo, Mutsa Prudence
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5960 , http://hdl.handle.net/10962/d1021258
- Description: Integrated algae pond systems are a derivation of the Oswald designed advanced integrated wastewater ponding system, and combine the use of anaerobic and aerobic bioprocesses to effect wastewater treatment. Integrated algae pond system technology was introduced to South Africa in 1996 and a pilot plant was designed and commissioned at the Belmont Valley wastewater treatment works in Grahamstown. Previous studies showed that this system delivered a final effluent superior to most pond systems deployed in South Africa but that it was unable to meet the general standard for nutrient removal and effluent discharge. This study was initiated to re-appraise integrated algae pond systems and to assess the potential of the technology as an effective municipal sewage treatment system. And more...
- Full Text:
- Date Issued: 2016
- Authors: Mambo, Mutsa Prudence
- Date: 2016
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5960 , http://hdl.handle.net/10962/d1021258
- Description: Integrated algae pond systems are a derivation of the Oswald designed advanced integrated wastewater ponding system, and combine the use of anaerobic and aerobic bioprocesses to effect wastewater treatment. Integrated algae pond system technology was introduced to South Africa in 1996 and a pilot plant was designed and commissioned at the Belmont Valley wastewater treatment works in Grahamstown. Previous studies showed that this system delivered a final effluent superior to most pond systems deployed in South Africa but that it was unable to meet the general standard for nutrient removal and effluent discharge. This study was initiated to re-appraise integrated algae pond systems and to assess the potential of the technology as an effective municipal sewage treatment system. And more...
- Full Text:
- Date Issued: 2016
Contextual factors influencing the use of learner-centred approaches in the teaching of home economics : a case of two universities in Zimbabwe
- Authors: Motsi, Emily
- Date: 2017
- Subjects: Home economics -- Study and teaching (Higher) -- Zimbabwe Student-centered learning -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/8463 , vital:32834
- Description: This study examined contextual factors influencing the use of learner-centred approaches in the teaching of Home Economics in two universities in Zimbabwe. The sample consisted of eight students and four lecturers who were purposively sampled. The study was anchored in the interpretivist paradigm and it adopted a qualitative approach and case-study design. Data collection instruments consisted of structured in-depth interviews, observations and documents. Interviews were conducted with students and lecturers at their respective universities with observations and document analysis inter-spaced in between. Data analysis consisted of a thematic approach where common themes were identified in participants’ responses and analysed and discussed accordingly, with data from observed and documented analysis being used to buttress/refute observations made from the interviews. A number of findings emanated from the study. Students had varied conceptions of learner-centred approaches. Some viewed learner-centred approaches as methods of teaching that were participatory, while others viewed them as learning situations in which learners were actively engaged and developed specific capabilities such as problem-solving. Lecturers conceptualised learner-centred approaches as methods that led to active learner participation with the lecturer playing more of a facilitative role. The study revealed that contextual factors such as time available in each course, flexibility of content, the use of teaching methods characterised by active learner participation, the use of constructive and interactive learning activities, had facilitative as well as inhibiting influences on the use of learner-centred approaches. Social factors such as cooperativeness within the peer group, lecturer availability for consultations, technical staff support as well as structural factors such as the availability of textbooks and e-resources, provision of materials and tools, and access to the internet had a facilitative influence on use of learner-centred approaches. The main inhibitive structural factors were the absence of purpose-built facilities and limited space that caused overcrowding. University administration support for integration of learner-centred approaches was fairly evident in the two universities. To sustain the use of learner-centred approaches, lecturers required support through professional development. The study recommended that universities have well-articulated commitments to use learner-centred approaches through a Teaching and Learning Policy. Home Economics course designers should consider contextual factors in course design and course delivery to ensure effective implementation of learner-centred approaches in the teaching of the subject. Seminars and workshops should be organised by the University Teaching and Learning Centres to enhance the teacher educators’ knowledge on interactive teaching methodologies and strategies for creating student-centred learning environments.
- Full Text:
- Date Issued: 2017
- Authors: Motsi, Emily
- Date: 2017
- Subjects: Home economics -- Study and teaching (Higher) -- Zimbabwe Student-centered learning -- Zimbabwe
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/8463 , vital:32834
- Description: This study examined contextual factors influencing the use of learner-centred approaches in the teaching of Home Economics in two universities in Zimbabwe. The sample consisted of eight students and four lecturers who were purposively sampled. The study was anchored in the interpretivist paradigm and it adopted a qualitative approach and case-study design. Data collection instruments consisted of structured in-depth interviews, observations and documents. Interviews were conducted with students and lecturers at their respective universities with observations and document analysis inter-spaced in between. Data analysis consisted of a thematic approach where common themes were identified in participants’ responses and analysed and discussed accordingly, with data from observed and documented analysis being used to buttress/refute observations made from the interviews. A number of findings emanated from the study. Students had varied conceptions of learner-centred approaches. Some viewed learner-centred approaches as methods of teaching that were participatory, while others viewed them as learning situations in which learners were actively engaged and developed specific capabilities such as problem-solving. Lecturers conceptualised learner-centred approaches as methods that led to active learner participation with the lecturer playing more of a facilitative role. The study revealed that contextual factors such as time available in each course, flexibility of content, the use of teaching methods characterised by active learner participation, the use of constructive and interactive learning activities, had facilitative as well as inhibiting influences on the use of learner-centred approaches. Social factors such as cooperativeness within the peer group, lecturer availability for consultations, technical staff support as well as structural factors such as the availability of textbooks and e-resources, provision of materials and tools, and access to the internet had a facilitative influence on use of learner-centred approaches. The main inhibitive structural factors were the absence of purpose-built facilities and limited space that caused overcrowding. University administration support for integration of learner-centred approaches was fairly evident in the two universities. To sustain the use of learner-centred approaches, lecturers required support through professional development. The study recommended that universities have well-articulated commitments to use learner-centred approaches through a Teaching and Learning Policy. Home Economics course designers should consider contextual factors in course design and course delivery to ensure effective implementation of learner-centred approaches in the teaching of the subject. Seminars and workshops should be organised by the University Teaching and Learning Centres to enhance the teacher educators’ knowledge on interactive teaching methodologies and strategies for creating student-centred learning environments.
- Full Text:
- Date Issued: 2017
Aquatic invasions of the Nseleni River system: causes, consequences and control
- Authors: Jones, Roy William
- Date: 2015
- Subjects: Gastropoda -- South Africa , Introduced snails -- South Africa , Introduced mollusks -- South Africa , Loricariidae , Introduced fishes -- South Africa , Water hyacinth , Alien plants -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5928 , http://hdl.handle.net/10962/d1017806
- Description: Globalization has seen an unprecedented dispersal of exotic and alien species worldwide resulting in worldwide homogenization and sometimes extinction of indigenous or endemic taxa. When an exotic species becomes established in a new habitat the invasive organisms are capable of having an impact on indigenous community dynamics and the overall structure and function of ecosystems. Furthermore, the impact of invasion is determined by the geographical range, abundance and the per-capita or per-biomass effect of the invader. However, the success of the introduced organisms is reliant on their ability to acclimate to the physiochemical conditions of the newly invaded environment.Freshwater ecosystems are especially vulnerable to invasions because there are numerous potential routes of introduction including intentional pathways such as stocking, and unintentional pathways such as the release of ballast water and aquarium releases. Efforts to limit the introduction of invasive species or to manage established exotic populations are often hindered by insufficient understanding of the natural history of problematic species. Relatively little is known regarding the physiological tolerances of many taxa. Knowledge about specific species ecophysiological constraints allows for the prediction of future patterns of invasion more accurately, including where an introduced organism would probably survive, thrive and disperse. Furthermore, data on the physiological tolerances of an introduced exotic organism may provide data necessary for effective management and control. This studyinvestigated three invasive species in the Nseleni River system in a protected area in KwaZulu-Natal. The species studied were, Tarebia granifera (Quilted melania – Lamarck, 1822), Pterygoplichthys disjunctivus (Suckermouth armoured catfish - Weber, 1991) and Eichhornia crassipes (water hyacinth – (Martius) Solms-Laubach,). The Nseleni River flows into Lake Nsezi which is responsible for providing potable water to the surrounding towns and industry, as well as the surrounding rural communities. The Enseleni Nature reserve has become the centre for biodiversity dispersal in the immediate area, due to the change in landscape surrounding the protected area.An important step in developing alien invasive species management strategies in protected areas is determining their extent and invasive traits. Tarebia granifera is a prosobranch gastropod originally from South-East Asia that has become invasive in several countries around the world including South Africa. Snail populations were sampled at nine sites throughout the Nseleni/Mposa river system every six weeks over a twelve month period. The snail was abundant throughout the system, especially in shallow waters of less than 1m in depth.The first positive identification the loricariid catfish Pterygoplichthys disjunctivus for the Nseleni River was in 2006. The original introduction is believed to have been via the aquarium trade. The aim of the study was to assess the usefulness of the unified framework with regard to management of fish invasions by assessing the invasion stage of the loricariid population and identifying appropriate management actions using the Blackburn et al. (2011) framework. The fish were sampled at nine different sites and three different depths over a period of twelve months, as well as when two ichthyological surveys were carried out on the Nseleni River system. This invasive fish has been located throughout the system and both male and female fish were collected. The smallest fish sampled was a fingerling of a day or two old and the smallest pregnant female was a mere 270mm TL. This is a clear indication that this fish is breeding in the river system.Although T. granifera and P. disjunctivus were abundant in the Nseleni/Mposa river system, it was not clear what their role in the system was, and in particular if they were competing with any of the indigenous species. Therefore, isotope samples were collected from numerous taxa over a two week period, with the exception of Pterygoplichthys disjunctivus samples, which were collected over 12 months. The δ13C and δ15N signatures of all samples were determined. The niche overlap between the invasive and indigenous snails was effectively zero (1.02E-13%), indicating no shared food resources. The medium ranges of dNRb (7.14) and dCRb (9.07) for the invasive fish indicate that it utilizes a wider range of food resources and trophic levels than the majority of indigenous fish. A medium CDb value (2.34) for the invasive fish species, P. disjunctivus, describes medium trophic diversity, with three indigenous species possessing higher diversity and three possessing lower diversity. Furtherresults indicated that there was no direct dietary competition between P. disjunctivus and indigenous species. Eichhornia crassipes was first recorded on the Nseleni River in 1978, and has been shown to have a significant negative impact on the biodiversity of the Nseleni/Mposa River system and therefore required a control intervention. Although biological control using the two weevil species Neochetina eichhornia (Warner) and N. bruchi (Hustache) has been credited with affecting a good level of control, the lack of a manipulated post-release evaluation experiments has undermined this statement. Five experimental plots of water hyacinth of 20m2 were sprayed with an insecticide to control weevils. After ten months the plants in the sprayed plots were significantly bigger and heavier than those in the control plots that had natural populations of the biological control agents. This study has shown unequivocally that biological control has contributed significantly to the control of water hyacinth on the Nseleni/Mposa River system.The management plan for the Enseleni Nature Reserve identifies the need to control invasive and/or exotic organisms within the boundary of the protected area. In addition, set guidelines have been implemented on how to control these organisms, so that indigenous organisms are least affected. Lack of control of exotic organisms can have serious consequences for indigenous species. It is therefore of utmost importance that the population dynamics of the invading organism be understood, what the potential impact could be and how to control them. Furthermore, it has also acknowledged the threat of possible exotic species invasions from outside of the protected area that might result in threats to the protected area and that these must be investigated, researched and managed.This thesis has identified Tarebia granifera, Pterygoplichthys disjunctivus and Eichhornia crassipes as being a threat to indigenous biodiversity within the protected area, as well as in adjacent areas to the protected area. The thesis will therefore investigate the hypothesis that both Tarebia granifera and Pterygoplichthys disjunctivus are having a direct negative effect on available food resources for indigenous species of organisms. In addition, this thesis will investigate if theNeochetina species that have previously been introduced onto E. crassipes are having any negative effect on this invasive alien aquatic plant.
- Full Text:
- Date Issued: 2015
- Authors: Jones, Roy William
- Date: 2015
- Subjects: Gastropoda -- South Africa , Introduced snails -- South Africa , Introduced mollusks -- South Africa , Loricariidae , Introduced fishes -- South Africa , Water hyacinth , Alien plants -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5928 , http://hdl.handle.net/10962/d1017806
- Description: Globalization has seen an unprecedented dispersal of exotic and alien species worldwide resulting in worldwide homogenization and sometimes extinction of indigenous or endemic taxa. When an exotic species becomes established in a new habitat the invasive organisms are capable of having an impact on indigenous community dynamics and the overall structure and function of ecosystems. Furthermore, the impact of invasion is determined by the geographical range, abundance and the per-capita or per-biomass effect of the invader. However, the success of the introduced organisms is reliant on their ability to acclimate to the physiochemical conditions of the newly invaded environment.Freshwater ecosystems are especially vulnerable to invasions because there are numerous potential routes of introduction including intentional pathways such as stocking, and unintentional pathways such as the release of ballast water and aquarium releases. Efforts to limit the introduction of invasive species or to manage established exotic populations are often hindered by insufficient understanding of the natural history of problematic species. Relatively little is known regarding the physiological tolerances of many taxa. Knowledge about specific species ecophysiological constraints allows for the prediction of future patterns of invasion more accurately, including where an introduced organism would probably survive, thrive and disperse. Furthermore, data on the physiological tolerances of an introduced exotic organism may provide data necessary for effective management and control. This studyinvestigated three invasive species in the Nseleni River system in a protected area in KwaZulu-Natal. The species studied were, Tarebia granifera (Quilted melania – Lamarck, 1822), Pterygoplichthys disjunctivus (Suckermouth armoured catfish - Weber, 1991) and Eichhornia crassipes (water hyacinth – (Martius) Solms-Laubach,). The Nseleni River flows into Lake Nsezi which is responsible for providing potable water to the surrounding towns and industry, as well as the surrounding rural communities. The Enseleni Nature reserve has become the centre for biodiversity dispersal in the immediate area, due to the change in landscape surrounding the protected area.An important step in developing alien invasive species management strategies in protected areas is determining their extent and invasive traits. Tarebia granifera is a prosobranch gastropod originally from South-East Asia that has become invasive in several countries around the world including South Africa. Snail populations were sampled at nine sites throughout the Nseleni/Mposa river system every six weeks over a twelve month period. The snail was abundant throughout the system, especially in shallow waters of less than 1m in depth.The first positive identification the loricariid catfish Pterygoplichthys disjunctivus for the Nseleni River was in 2006. The original introduction is believed to have been via the aquarium trade. The aim of the study was to assess the usefulness of the unified framework with regard to management of fish invasions by assessing the invasion stage of the loricariid population and identifying appropriate management actions using the Blackburn et al. (2011) framework. The fish were sampled at nine different sites and three different depths over a period of twelve months, as well as when two ichthyological surveys were carried out on the Nseleni River system. This invasive fish has been located throughout the system and both male and female fish were collected. The smallest fish sampled was a fingerling of a day or two old and the smallest pregnant female was a mere 270mm TL. This is a clear indication that this fish is breeding in the river system.Although T. granifera and P. disjunctivus were abundant in the Nseleni/Mposa river system, it was not clear what their role in the system was, and in particular if they were competing with any of the indigenous species. Therefore, isotope samples were collected from numerous taxa over a two week period, with the exception of Pterygoplichthys disjunctivus samples, which were collected over 12 months. The δ13C and δ15N signatures of all samples were determined. The niche overlap between the invasive and indigenous snails was effectively zero (1.02E-13%), indicating no shared food resources. The medium ranges of dNRb (7.14) and dCRb (9.07) for the invasive fish indicate that it utilizes a wider range of food resources and trophic levels than the majority of indigenous fish. A medium CDb value (2.34) for the invasive fish species, P. disjunctivus, describes medium trophic diversity, with three indigenous species possessing higher diversity and three possessing lower diversity. Furtherresults indicated that there was no direct dietary competition between P. disjunctivus and indigenous species. Eichhornia crassipes was first recorded on the Nseleni River in 1978, and has been shown to have a significant negative impact on the biodiversity of the Nseleni/Mposa River system and therefore required a control intervention. Although biological control using the two weevil species Neochetina eichhornia (Warner) and N. bruchi (Hustache) has been credited with affecting a good level of control, the lack of a manipulated post-release evaluation experiments has undermined this statement. Five experimental plots of water hyacinth of 20m2 were sprayed with an insecticide to control weevils. After ten months the plants in the sprayed plots were significantly bigger and heavier than those in the control plots that had natural populations of the biological control agents. This study has shown unequivocally that biological control has contributed significantly to the control of water hyacinth on the Nseleni/Mposa River system.The management plan for the Enseleni Nature Reserve identifies the need to control invasive and/or exotic organisms within the boundary of the protected area. In addition, set guidelines have been implemented on how to control these organisms, so that indigenous organisms are least affected. Lack of control of exotic organisms can have serious consequences for indigenous species. It is therefore of utmost importance that the population dynamics of the invading organism be understood, what the potential impact could be and how to control them. Furthermore, it has also acknowledged the threat of possible exotic species invasions from outside of the protected area that might result in threats to the protected area and that these must be investigated, researched and managed.This thesis has identified Tarebia granifera, Pterygoplichthys disjunctivus and Eichhornia crassipes as being a threat to indigenous biodiversity within the protected area, as well as in adjacent areas to the protected area. The thesis will therefore investigate the hypothesis that both Tarebia granifera and Pterygoplichthys disjunctivus are having a direct negative effect on available food resources for indigenous species of organisms. In addition, this thesis will investigate if theNeochetina species that have previously been introduced onto E. crassipes are having any negative effect on this invasive alien aquatic plant.
- Full Text:
- Date Issued: 2015
The executive government of the Cape of Good Hope, 1825-54
- Authors: Fryer, Alan Kenneth
- Date: 1959
- Subjects: Cape of Good Hope (South Africa) -- History -- 1795-1872
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2604 , http://hdl.handle.net/10962/d1011896
- Description: The study of administrative processes is a relaltively new one both in the field of history and sociology. In both disciplines what is required is study of the sructure and growth of adminstrative systems and of the impact of administrative action on the community it seeks to serve and which it often provokes. In the field of history, Professor F. Tout in his chapters on administrative history ... gave new vitality and understanding to medieval studies. In the main, South African history, though probably not more so than other Commonwealth countries, has been less fortunate. Preface, p. 1.
- Full Text:
- Date Issued: 1959
- Authors: Fryer, Alan Kenneth
- Date: 1959
- Subjects: Cape of Good Hope (South Africa) -- History -- 1795-1872
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2604 , http://hdl.handle.net/10962/d1011896
- Description: The study of administrative processes is a relaltively new one both in the field of history and sociology. In both disciplines what is required is study of the sructure and growth of adminstrative systems and of the impact of administrative action on the community it seeks to serve and which it often provokes. In the field of history, Professor F. Tout in his chapters on administrative history ... gave new vitality and understanding to medieval studies. In the main, South African history, though probably not more so than other Commonwealth countries, has been less fortunate. Preface, p. 1.
- Full Text:
- Date Issued: 1959
Environmental water quality management of glyphosate-based herbicides in South Africa
- Authors: Mensah, Paul Kojo
- Date: 2013
- Subjects: Water quality management -- South Africa Water quality management -- Environmental Aspects -- South Africa Herbicides -- Environmental aspects -- South Africa Herbicides -- Toxicology -- South Africa Water -- Glyphosate content -- South Africa Water -- Pollution -- South Africa Water quality -- Measurement -- South Africa Water -- Analysis -- South Africa Freshwater ecology -- South Africa Integrated water development -- South Africa Caridina -- Effect of pollution on -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:6023 , http://hdl.handle.net/10962/d1001987
- Description: Although the use of pesticides is necessary to meet the socio-economic needs of many developing countries, especially in Africa, side effects of these bio-active chemicals have contributed to contaminating aquatic and terrestrial ecosystems. Environmental water quality degradation by pesticides interferes with ecosystem health and poses numerous risks to aquatic life. In South Africa, glyphosate-based herbicides are frequently used to control weeds and invading alien plants, but ultimately end up in freshwater ecosystems. However, there are no South African-based environmental water quality management strategies to regulate these bio-active chemicals. Therefore, this study sought to provide a sound scientific background for the environmental water quality management of glyphosate-based herbicides in South Africa, by conducting both laboratory and field investigations. In the laboratory investigations, aquatic ecotoxicological methods were used to evaluate responses of the freshwater aquatic shrimp Caridina nilotica exposed to Roundup® at different biological system scales, and the responses of multiple South African aquatic species exposed to Roundup® through species sensitivity distribution (SSD). In the field investigations, the effect of Kilo Max WSG on the physicochemical and biological conditions of three selected sites in the Swartkops River before and after a spray episode by Working for Water were evaluated through biomonitoring, using the South African Scoring System version 5 (SASS5) as a sampling protocol. Both Roundup® and Kilo Max WSG are glyphosate-based herbicides. All the data were subjected to relevant statistical analyses. Findings of this study revealed that Roundup® elicited responses at different biological system scales in C. nilotica, while SSD estimates were used to derive proposed water quality guidelines for glyphosate-based herbicides in South Africa. The biomonitoring revealed that using glyphosate-based herbicides to control water hyacinth within the Swartkops River had a negligible impact on the physicochemical and biological conditions. Based on these findings, a conceptual framework that can be used for the integrated environmental water quality management of glyphosate-based herbicides in South Africa was developed as part of integrated water resource management (IWRM). The combined data sets contribute to a sound scientific basis for the environmental water quality management of glyphosate-based herbicides in South Africa.
- Full Text:
- Date Issued: 2013
- Authors: Mensah, Paul Kojo
- Date: 2013
- Subjects: Water quality management -- South Africa Water quality management -- Environmental Aspects -- South Africa Herbicides -- Environmental aspects -- South Africa Herbicides -- Toxicology -- South Africa Water -- Glyphosate content -- South Africa Water -- Pollution -- South Africa Water quality -- Measurement -- South Africa Water -- Analysis -- South Africa Freshwater ecology -- South Africa Integrated water development -- South Africa Caridina -- Effect of pollution on -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:6023 , http://hdl.handle.net/10962/d1001987
- Description: Although the use of pesticides is necessary to meet the socio-economic needs of many developing countries, especially in Africa, side effects of these bio-active chemicals have contributed to contaminating aquatic and terrestrial ecosystems. Environmental water quality degradation by pesticides interferes with ecosystem health and poses numerous risks to aquatic life. In South Africa, glyphosate-based herbicides are frequently used to control weeds and invading alien plants, but ultimately end up in freshwater ecosystems. However, there are no South African-based environmental water quality management strategies to regulate these bio-active chemicals. Therefore, this study sought to provide a sound scientific background for the environmental water quality management of glyphosate-based herbicides in South Africa, by conducting both laboratory and field investigations. In the laboratory investigations, aquatic ecotoxicological methods were used to evaluate responses of the freshwater aquatic shrimp Caridina nilotica exposed to Roundup® at different biological system scales, and the responses of multiple South African aquatic species exposed to Roundup® through species sensitivity distribution (SSD). In the field investigations, the effect of Kilo Max WSG on the physicochemical and biological conditions of three selected sites in the Swartkops River before and after a spray episode by Working for Water were evaluated through biomonitoring, using the South African Scoring System version 5 (SASS5) as a sampling protocol. Both Roundup® and Kilo Max WSG are glyphosate-based herbicides. All the data were subjected to relevant statistical analyses. Findings of this study revealed that Roundup® elicited responses at different biological system scales in C. nilotica, while SSD estimates were used to derive proposed water quality guidelines for glyphosate-based herbicides in South Africa. The biomonitoring revealed that using glyphosate-based herbicides to control water hyacinth within the Swartkops River had a negligible impact on the physicochemical and biological conditions. Based on these findings, a conceptual framework that can be used for the integrated environmental water quality management of glyphosate-based herbicides in South Africa was developed as part of integrated water resource management (IWRM). The combined data sets contribute to a sound scientific basis for the environmental water quality management of glyphosate-based herbicides in South Africa.
- Full Text:
- Date Issued: 2013
KwaZakele: the politics of transition in South Africa: an Eastern Cape case study
- Authors: Cherry, Janet Mary
- Date: 2001
- Subjects: South Africa -- Transition to democracy Democracy -- South Africa -- Eastern Cape Eastern Cape (South Africa) -- Politics and government Port Elizabeth region (South Africa) -- Political aspects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2766 , http://hdl.handle.net/10962/d1002976
- Description: This thesis examines the transition to democracy in South Africa through the use of case study methodology. The nature of political participation and the form of democracy to emerge at the end of the transition process are the central subjects of inquiry. They are examined through an in-depth study of the African community of Kwazakele, a township in the Nelson Mandela metropolitan area in the Eastern Cape province of South Africa. The study covers the period from 1993 to 2000, and uses as a primary data source five surveys conducted among residents of Kwazakele during that period. The emphasis of the study lies on the experience of political participation of ‘ordinary people’ – in particular, the African urban working-class in South Africa who make up the core support base for the governing African National Congress. The primary findings of the thesis are as follows: * Representative democracy has been successfully consolidated in the community under study. * Levels of political participation by urban Africans in the Eastern Cape are consistently high, both in formal political institutions (primarily elections) and in institutions of civil society. * As politics has normalised at the end of the transition period, forms of direct democratic participation have declined. * Despite the structural constraints on development, there is still potential for a high level of participation by citizens in effecting change at local level. * Drawing on the experience of ordinary people in structures of direct democracy, this level of participation can result in a deeper and stronger form of democracy than exists in many established representative democracies.
- Full Text:
- Date Issued: 2001
- Authors: Cherry, Janet Mary
- Date: 2001
- Subjects: South Africa -- Transition to democracy Democracy -- South Africa -- Eastern Cape Eastern Cape (South Africa) -- Politics and government Port Elizabeth region (South Africa) -- Political aspects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2766 , http://hdl.handle.net/10962/d1002976
- Description: This thesis examines the transition to democracy in South Africa through the use of case study methodology. The nature of political participation and the form of democracy to emerge at the end of the transition process are the central subjects of inquiry. They are examined through an in-depth study of the African community of Kwazakele, a township in the Nelson Mandela metropolitan area in the Eastern Cape province of South Africa. The study covers the period from 1993 to 2000, and uses as a primary data source five surveys conducted among residents of Kwazakele during that period. The emphasis of the study lies on the experience of political participation of ‘ordinary people’ – in particular, the African urban working-class in South Africa who make up the core support base for the governing African National Congress. The primary findings of the thesis are as follows: * Representative democracy has been successfully consolidated in the community under study. * Levels of political participation by urban Africans in the Eastern Cape are consistently high, both in formal political institutions (primarily elections) and in institutions of civil society. * As politics has normalised at the end of the transition period, forms of direct democratic participation have declined. * Despite the structural constraints on development, there is still potential for a high level of participation by citizens in effecting change at local level. * Drawing on the experience of ordinary people in structures of direct democracy, this level of participation can result in a deeper and stronger form of democracy than exists in many established representative democracies.
- Full Text:
- Date Issued: 2001
Racism and law : implementing the right to equality in selected South African equality courts
- Authors: Krüger, Rósaan
- Date: 2009
- Subjects: South Africa Promotion of Equality and Prevention of Unfair Discrimination Act, 2000 , Equality -- South Africa , Discrimination -- Law and legislation -- South Africa , Racism -- Law and legislation -- South Africa , Apartheid -- Law and legislation -- South Africa , Constitutional law -- South Africa , South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3677 , http://hdl.handle.net/10962/d1003192 , South Africa Promotion of Equality and Prevention of Unfair Discrimination Act, 2000 , Equality -- South Africa , Discrimination -- Law and legislation -- South Africa , Racism -- Law and legislation -- South Africa , Apartheid -- Law and legislation -- South Africa , Constitutional law -- South Africa , South Africa -- Politics and government -- 1994-
- Description: Racism has informed South African society since colonial times. Racist beliefs found expression in the laws of colonial and apartheid South Africa and shaped both state and society. The constitutional state that South Africa has become since 1994, is based on the values of ‘human dignity’, ‘the achievement of equality’ and ‘nonracialism’, among others. Law formed the basis of the racist state prior to 1994, and now law has a fundamental role to play in the transformation of the state and society in an egalitarian direction by addressing socio-economic inequalities on the one hand, and by changing patterns of behaviour based on racist beliefs forged in the past, on the other. This thesis examines one of the legal instruments that is intended to contribute to transformation in the latter sense, namely the Promotion of Equality and Prevention of Unfair Discrimination Act 4 of 2000 (the Equality Act), with specific reference to the issue of racism. The provisions of this Act and the framework for its operation against the background of South Africa’s racist past, and within the broader framework of international and constitutional law, are examined. These two legal frameworks are analysed for the purpose of determining the standards set by international and constitutional law regarding racial equality in order to determine whether the Equality Act measures up. This thesis also incorporates an analysis of the practical application of the provisions of the Equality Act to complaints of racism in selected equality courts. The theoretical analysis of the Act’s provisions and their application in the equality courts point to various problematic formulations and obstacles which negatively affect the application of the provisions and thus hamper social change. The thesis concludes with recommendations for refining the Act’s provisions and its application.
- Full Text:
- Date Issued: 2009
- Authors: Krüger, Rósaan
- Date: 2009
- Subjects: South Africa Promotion of Equality and Prevention of Unfair Discrimination Act, 2000 , Equality -- South Africa , Discrimination -- Law and legislation -- South Africa , Racism -- Law and legislation -- South Africa , Apartheid -- Law and legislation -- South Africa , Constitutional law -- South Africa , South Africa -- Politics and government -- 1994-
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3677 , http://hdl.handle.net/10962/d1003192 , South Africa Promotion of Equality and Prevention of Unfair Discrimination Act, 2000 , Equality -- South Africa , Discrimination -- Law and legislation -- South Africa , Racism -- Law and legislation -- South Africa , Apartheid -- Law and legislation -- South Africa , Constitutional law -- South Africa , South Africa -- Politics and government -- 1994-
- Description: Racism has informed South African society since colonial times. Racist beliefs found expression in the laws of colonial and apartheid South Africa and shaped both state and society. The constitutional state that South Africa has become since 1994, is based on the values of ‘human dignity’, ‘the achievement of equality’ and ‘nonracialism’, among others. Law formed the basis of the racist state prior to 1994, and now law has a fundamental role to play in the transformation of the state and society in an egalitarian direction by addressing socio-economic inequalities on the one hand, and by changing patterns of behaviour based on racist beliefs forged in the past, on the other. This thesis examines one of the legal instruments that is intended to contribute to transformation in the latter sense, namely the Promotion of Equality and Prevention of Unfair Discrimination Act 4 of 2000 (the Equality Act), with specific reference to the issue of racism. The provisions of this Act and the framework for its operation against the background of South Africa’s racist past, and within the broader framework of international and constitutional law, are examined. These two legal frameworks are analysed for the purpose of determining the standards set by international and constitutional law regarding racial equality in order to determine whether the Equality Act measures up. This thesis also incorporates an analysis of the practical application of the provisions of the Equality Act to complaints of racism in selected equality courts. The theoretical analysis of the Act’s provisions and their application in the equality courts point to various problematic formulations and obstacles which negatively affect the application of the provisions and thus hamper social change. The thesis concludes with recommendations for refining the Act’s provisions and its application.
- Full Text:
- Date Issued: 2009
Understanding biotic interactions in invaded pond communities in the Sundays River irrigation network, South Africa
- Authors: Mofu, Lubabalo
- Date: 2020
- Subjects: Mozambique tilapia -- South Africa -- Sundays River (Eastern Cape) , Western mosquitofish -- South Africa -- Sundays River (Eastern Cape) , Gobiidae -- South Africa -- Sundays River (Eastern Cape) , Clupeidae -- South Africa -- Sundays River (Eastern Cape) , Reservoirs -- South Africa -- Sundays River (Eastern Cape) , Zooplankton -- South Africa -- Sundays River (Eastern Cape) , Freshwater ecology -- South Africa -- Sundays River (Eastern Cape) , Biotic communities -- South Africa -- Sundays River (Eastern Cape) , Fishes -- Effect of temperature on -- South Africa -- Sundays River (Eastern Cape) , Stable isotopes , Relative Impact Potential
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/167089 , vital:41436
- Description: The Sundays River valley irrigation ponds provide a unique opportunity to investigate biotic interactions within a biological invasions context, as they contain both native and non-native fish species. This study focusses on two native species (Glossogobius callidus and Gilchristella aestuaria) and two non-native species (Oreochromis mossambicus and Gambusia affinis). The ecology of the ponds was driven by physico-chemical variables, mainly temperature, but the interactions between fishes were a complex interplay between temperature, pond community ecology and food web structure. Seasonal changes in temperature and subsequent fluctuations in water levels resulted in changes in zooplankton community. Chlorophyll-a, temperature, G. callidus and G. affinis were the drivers of the seasonal changes in macroinvertebrate composition. Stable isotope analysis identified substantial ontogenetic dietary shifts in all species, corresponding to changes in body size. Stable isotope analysis revealed that the niche space occupied by G. affinis was broad and overlapped with that of the other three focal species. Stable isotope metrics showed that G. affinis and O. mossambicus utilised a wide range of resources compared to G. callidus and G. aestuaria. Stomach content analysis showed that G. callidus, O. mossambicus and G. affinis fed predominantly on benthic resources, while G. aestuaria fed mainly plankton resources. Functional response experiments revealed that G. callidus and G. affinis both displayed Type II functional responses. In single fish trials, G. affinis had significantly higher functional responses than G. callidus. In heterospecific G. callidus-G. affinis combinations the functional response of G. callidus was reduced by the presence of G. affinis, whereas, this combination greatly enhanced G. affinis functional response magnitudes. The functional response of G. callidus, O. mossambicus and G. affinis under two temperature treatments along with fish abundance data was used to determine temporal differences in the ecological impacts of each fish species between seasons. The relative impact potential of O. mossambicus was consistently higher than that of G. callidus and G. affinis. This study demonstrates how seasonal temperature fluctuations affect the relative impact capacities of introduced species. Overall, this thesis showed that high temperature along with life-history traits contributes to the biotic interactions between native and non-native species in novel environments.
- Full Text:
- Date Issued: 2020
- Authors: Mofu, Lubabalo
- Date: 2020
- Subjects: Mozambique tilapia -- South Africa -- Sundays River (Eastern Cape) , Western mosquitofish -- South Africa -- Sundays River (Eastern Cape) , Gobiidae -- South Africa -- Sundays River (Eastern Cape) , Clupeidae -- South Africa -- Sundays River (Eastern Cape) , Reservoirs -- South Africa -- Sundays River (Eastern Cape) , Zooplankton -- South Africa -- Sundays River (Eastern Cape) , Freshwater ecology -- South Africa -- Sundays River (Eastern Cape) , Biotic communities -- South Africa -- Sundays River (Eastern Cape) , Fishes -- Effect of temperature on -- South Africa -- Sundays River (Eastern Cape) , Stable isotopes , Relative Impact Potential
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/167089 , vital:41436
- Description: The Sundays River valley irrigation ponds provide a unique opportunity to investigate biotic interactions within a biological invasions context, as they contain both native and non-native fish species. This study focusses on two native species (Glossogobius callidus and Gilchristella aestuaria) and two non-native species (Oreochromis mossambicus and Gambusia affinis). The ecology of the ponds was driven by physico-chemical variables, mainly temperature, but the interactions between fishes were a complex interplay between temperature, pond community ecology and food web structure. Seasonal changes in temperature and subsequent fluctuations in water levels resulted in changes in zooplankton community. Chlorophyll-a, temperature, G. callidus and G. affinis were the drivers of the seasonal changes in macroinvertebrate composition. Stable isotope analysis identified substantial ontogenetic dietary shifts in all species, corresponding to changes in body size. Stable isotope analysis revealed that the niche space occupied by G. affinis was broad and overlapped with that of the other three focal species. Stable isotope metrics showed that G. affinis and O. mossambicus utilised a wide range of resources compared to G. callidus and G. aestuaria. Stomach content analysis showed that G. callidus, O. mossambicus and G. affinis fed predominantly on benthic resources, while G. aestuaria fed mainly plankton resources. Functional response experiments revealed that G. callidus and G. affinis both displayed Type II functional responses. In single fish trials, G. affinis had significantly higher functional responses than G. callidus. In heterospecific G. callidus-G. affinis combinations the functional response of G. callidus was reduced by the presence of G. affinis, whereas, this combination greatly enhanced G. affinis functional response magnitudes. The functional response of G. callidus, O. mossambicus and G. affinis under two temperature treatments along with fish abundance data was used to determine temporal differences in the ecological impacts of each fish species between seasons. The relative impact potential of O. mossambicus was consistently higher than that of G. callidus and G. affinis. This study demonstrates how seasonal temperature fluctuations affect the relative impact capacities of introduced species. Overall, this thesis showed that high temperature along with life-history traits contributes to the biotic interactions between native and non-native species in novel environments.
- Full Text:
- Date Issued: 2020
The development of a concept of psychological well-being
- Authors: Bar-On, Reuven
- Date: 1988
- Subjects: Mental health -- Psychological aspects Personality
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2928 , http://hdl.handle.net/10962/d1002437
- Description: This thesis focuses on the development of an operational and theoretically eclectic concept of psychological well-being. A comprehensive research strategy was employed to examine various personality factors thought to be components of psychological health (i.e., the basis of the proposed concept). The general approach involved four major phases: (1) the clustering of various variables and identification of underlying key factors purported to be related to psychological health based on the writer's clinical experience and review of the mental health literature, (2) the formulation of an ~ priori concept of psychological well-being based on the operational definition of those factors, (3) the construction of an inventory designed to examine the proposed concept, and (4) the interpretation of the results and their implications for the development of the overall concept based on the examination of the factorial structure, validity and reliability of the inventory. The"a posteriori concept" evolved out of this process. The results of the present study indicate that the most valid and reliable factorial components of psychological well-being are self regard,interpersonal relationship, independence, problem-solving, assertiveness,reality testing, stress tolerance, self-actualization and happiness; social responsibility and flexibility emerged as questionable components of the a posteriori concept. The inventory which was designed to study the concept was successful in significantly differentiating various levels of psychological health. This way of conceptualizing and assessing psychological well-being has potential applicability for mental health practitioners and researchers.
- Full Text:
- Date Issued: 1988
- Authors: Bar-On, Reuven
- Date: 1988
- Subjects: Mental health -- Psychological aspects Personality
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:2928 , http://hdl.handle.net/10962/d1002437
- Description: This thesis focuses on the development of an operational and theoretically eclectic concept of psychological well-being. A comprehensive research strategy was employed to examine various personality factors thought to be components of psychological health (i.e., the basis of the proposed concept). The general approach involved four major phases: (1) the clustering of various variables and identification of underlying key factors purported to be related to psychological health based on the writer's clinical experience and review of the mental health literature, (2) the formulation of an ~ priori concept of psychological well-being based on the operational definition of those factors, (3) the construction of an inventory designed to examine the proposed concept, and (4) the interpretation of the results and their implications for the development of the overall concept based on the examination of the factorial structure, validity and reliability of the inventory. The"a posteriori concept" evolved out of this process. The results of the present study indicate that the most valid and reliable factorial components of psychological well-being are self regard,interpersonal relationship, independence, problem-solving, assertiveness,reality testing, stress tolerance, self-actualization and happiness; social responsibility and flexibility emerged as questionable components of the a posteriori concept. The inventory which was designed to study the concept was successful in significantly differentiating various levels of psychological health. This way of conceptualizing and assessing psychological well-being has potential applicability for mental health practitioners and researchers.
- Full Text:
- Date Issued: 1988
Aspekte van die Judaïes-Christelike en die Boeddhistiese in die poësie van Breyten Breytenbach
- Authors: Ferreira, Jeanette
- Date: 1988
- Subjects: Breytenbach, Breyten Afrikaans poetry -- History and criticism , Breytenbach, Breyten -- Criticism and interpretation
- Language: Afrikaans
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3574 , http://hdl.handle.net/10962/d1002097
- Description: Concepts of life and death, time and self-denial are investigated in the poetry of Breyten Breytenbach, with specific reference to the similarities and differences between the Judeo-Christian and the Buddhist traditions. Biblical references in the poetry are examined, and their underlying concepts compared to related concepts in Tantric Buddhism and Zen-Buddhism. The conclusion is drawn that the biblical concepts are transposed in the poetry in order to create Buddhist concepts of life and death, time and a form of self-denial. De-sacralisation of the Christian. concepts is inevitable in this creative process. However, the primary intention of the author is not de-sacralisation, but the implementation 'of the Buddhist philosophy of life in which everything is experienced as "totally one". A comparison between the reconstructed intended reader of Breytenbach's poetry and elements of the Afrikaans reading public suggests that political comment on segregated South African society is intended. Breytenbach's poetry is compared to canonized Afrikaans poetry with respect to Buddhist influence, national protest, aspiration to holiness and transposed biblical concepts. The conclusion is that his poetry is highly innovative in these respects. In the broader spectrum of South African literature his poetry is compared, with reference to transposed biblical concepts and national protest, to the poetry of Black poets writing in English, and (where material is available) to those writing in Afrikaans. The conclusion is that Breytenbach's poetry is strongly linked to this poetry. However, the complexity of Breytenbach's poetry, and the advanced aesthetic level and linguistic code required of the intended reader determine his placing within the canon of Afrikaans poetry.
- Full Text:
- Date Issued: 1988
- Authors: Ferreira, Jeanette
- Date: 1988
- Subjects: Breytenbach, Breyten Afrikaans poetry -- History and criticism , Breytenbach, Breyten -- Criticism and interpretation
- Language: Afrikaans
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3574 , http://hdl.handle.net/10962/d1002097
- Description: Concepts of life and death, time and self-denial are investigated in the poetry of Breyten Breytenbach, with specific reference to the similarities and differences between the Judeo-Christian and the Buddhist traditions. Biblical references in the poetry are examined, and their underlying concepts compared to related concepts in Tantric Buddhism and Zen-Buddhism. The conclusion is drawn that the biblical concepts are transposed in the poetry in order to create Buddhist concepts of life and death, time and a form of self-denial. De-sacralisation of the Christian. concepts is inevitable in this creative process. However, the primary intention of the author is not de-sacralisation, but the implementation 'of the Buddhist philosophy of life in which everything is experienced as "totally one". A comparison between the reconstructed intended reader of Breytenbach's poetry and elements of the Afrikaans reading public suggests that political comment on segregated South African society is intended. Breytenbach's poetry is compared to canonized Afrikaans poetry with respect to Buddhist influence, national protest, aspiration to holiness and transposed biblical concepts. The conclusion is that his poetry is highly innovative in these respects. In the broader spectrum of South African literature his poetry is compared, with reference to transposed biblical concepts and national protest, to the poetry of Black poets writing in English, and (where material is available) to those writing in Afrikaans. The conclusion is that Breytenbach's poetry is strongly linked to this poetry. However, the complexity of Breytenbach's poetry, and the advanced aesthetic level and linguistic code required of the intended reader determine his placing within the canon of Afrikaans poetry.
- Full Text:
- Date Issued: 1988
Synthetic and physical organic studies of chromone derivatives
- Ramaite, Ipfani David Isaiah
- Authors: Ramaite, Ipfani David Isaiah
- Date: 1997
- Subjects: Benzopyrans Heterocyclic compounds -- Derivatives Coumarins
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4380 , http://hdl.handle.net/10962/d1005045
- Description: A range of chromone-2-carboxylic acids has been prepared by condensing suitably substituted 2-hydroxyacetophenones with diethyl oxalate. pK₂ Studies of these acids revealed that 6- or 7-methoxy substituents decreased acidity while the 6-nitro group enhanced acidity; the strongest acid was the 3-chloro derivative, the increase in acidity being attributed to steric inhibition of acid-weakening delocalisation between the carboxyl group and the chromone system. Various chromone-2-carboxamides, derived from acid chloride precursors, were converted to polysubstituted acrylamides by nucleophilic ring-opening with selected amine nucleophiles. The main fragmentation patterns exhibited by these acrylamides were elucidated using a combination of low resolution, high resolution and meta-stable peak analysis, while the effect of substituents on the simultaneous internal rotation involving the carboxamide and enamine moieties were studied using dynamic NMR spectroscopy. Rotational barriers of ca. 67.1 kJmol ̄¹ and ca. 102 kJmol ̄¹ were found for the enamine and amide rotors, respectively. Several synthetic pathways were followed to prepare a series of 2-(N,N-dialkylamino)chromones which were subjected to detailed mass spectral analysis. In addition to substituent-specific fragmentations , the 2-aminochromones appear to fragment via 3 major pathways. The effect of substituents on the internal rotation of the amino moeity was investigated by variable temperature ¹H NMR spectroscopy and the resulting DNMR data was used to calculate the rotational barriers. Examination of the data reveals that the electron-releasing 6- and 7- substituents reduce the C-NMe₂ rotational barrier to ca. 43.5 kJmol ̄¹ , while the nitro analogue has the largest rotational barrier (ca. 46.1 kJmol ̄¹) because of the electron-withdrawing effect of this substituent.
- Full Text:
- Date Issued: 1997
- Authors: Ramaite, Ipfani David Isaiah
- Date: 1997
- Subjects: Benzopyrans Heterocyclic compounds -- Derivatives Coumarins
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4380 , http://hdl.handle.net/10962/d1005045
- Description: A range of chromone-2-carboxylic acids has been prepared by condensing suitably substituted 2-hydroxyacetophenones with diethyl oxalate. pK₂ Studies of these acids revealed that 6- or 7-methoxy substituents decreased acidity while the 6-nitro group enhanced acidity; the strongest acid was the 3-chloro derivative, the increase in acidity being attributed to steric inhibition of acid-weakening delocalisation between the carboxyl group and the chromone system. Various chromone-2-carboxamides, derived from acid chloride precursors, were converted to polysubstituted acrylamides by nucleophilic ring-opening with selected amine nucleophiles. The main fragmentation patterns exhibited by these acrylamides were elucidated using a combination of low resolution, high resolution and meta-stable peak analysis, while the effect of substituents on the simultaneous internal rotation involving the carboxamide and enamine moieties were studied using dynamic NMR spectroscopy. Rotational barriers of ca. 67.1 kJmol ̄¹ and ca. 102 kJmol ̄¹ were found for the enamine and amide rotors, respectively. Several synthetic pathways were followed to prepare a series of 2-(N,N-dialkylamino)chromones which were subjected to detailed mass spectral analysis. In addition to substituent-specific fragmentations , the 2-aminochromones appear to fragment via 3 major pathways. The effect of substituents on the internal rotation of the amino moeity was investigated by variable temperature ¹H NMR spectroscopy and the resulting DNMR data was used to calculate the rotational barriers. Examination of the data reveals that the electron-releasing 6- and 7- substituents reduce the C-NMe₂ rotational barrier to ca. 43.5 kJmol ̄¹ , while the nitro analogue has the largest rotational barrier (ca. 46.1 kJmol ̄¹) because of the electron-withdrawing effect of this substituent.
- Full Text:
- Date Issued: 1997
An examination of the extractives of Leonotis species
- Authors: Kaplan, Errol R
- Date: 1966
- Subjects: Leonotis -- Analysis Botanical chemistry Chemistry, Analytic Chemistry, Organic
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4481 , http://hdl.handle.net/10962/d1012628
- Description: Marrubiin and the other two diterpenoids, compounds X and Y, which had previously been isolated from Leonotus leonurus have been reinvestigated. Although the structure for marrubiin is well known its stereochemistry has been the subject of protracted discussion and is by no means secure except at C₅ and C₁₀ . N.M.R. spectral evidence showed that the lactone ring was cis-fused and β-orientated. Dehydration experiments carried out by previous workers were repeated, in order to resolve the residual uncertainty regarding the stereochemistry at C₉, an attempt was made to prepare iodoacetyl marrubic acid for X-ray crystallographic studies. Compound Y, C₂₀H₂₈0₃, a triply-unsaturated compound was shown by spectral studies to contain a furan ring and an α,β- unsaturated keto-group. It possesses a hydroxyl group incapable of acetylation, but readily removed by alkali and dehydrating agents to yield a tetraunsaturated compound, anhydro~Y; the hydroxyl is thus tertiary, Isolation of 1:2:5-trimethylnaphthalene on dehydrogenation indicated a relationship with the labdane diterpene group and supported the C₂₀ formula, The position of the α,β-unsaturated keto-group was resolved by interpretation of the ultraviolet spectra of degradation products and also by isolation of 1:2:3:5- trimethylnaphthalene on dehydrogenation of a suitable grignard product, The presence of a β-substituted furan was further indicated by colour reactions and confirmed by mass and n.m.r. spectra. The skeleton of compound Y is correlated with marrubiin via "iso-ambreinolide " and its stereochemistry is discussed. Further stereochemical assignments are postulated from the study of the n.m.r. spectra. Compound X, C₂₀H₂₈0₅, was shown by spectral and chemical evidence to be a diterpenoid dilactone containing an ether bridge between C₉ and C₁₃ Isolation of 1:2:5 trimethylnaphthal ene on dehydrogenation showed it to be closely related to marrubiin, This was supported by n.m.r. spectral results. A structure for compound X is proposed and the stereochemistry discussed. The aerial portions of Leonotis leonitis were also extracted and shown to contain a new compound, compound R. Preliminary investigation showed that it was a dilactone containing a furan ring, The n.m.r. spectrum of the compound is discussed.
- Full Text:
- Date Issued: 1966
- Authors: Kaplan, Errol R
- Date: 1966
- Subjects: Leonotis -- Analysis Botanical chemistry Chemistry, Analytic Chemistry, Organic
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4481 , http://hdl.handle.net/10962/d1012628
- Description: Marrubiin and the other two diterpenoids, compounds X and Y, which had previously been isolated from Leonotus leonurus have been reinvestigated. Although the structure for marrubiin is well known its stereochemistry has been the subject of protracted discussion and is by no means secure except at C₅ and C₁₀ . N.M.R. spectral evidence showed that the lactone ring was cis-fused and β-orientated. Dehydration experiments carried out by previous workers were repeated, in order to resolve the residual uncertainty regarding the stereochemistry at C₉, an attempt was made to prepare iodoacetyl marrubic acid for X-ray crystallographic studies. Compound Y, C₂₀H₂₈0₃, a triply-unsaturated compound was shown by spectral studies to contain a furan ring and an α,β- unsaturated keto-group. It possesses a hydroxyl group incapable of acetylation, but readily removed by alkali and dehydrating agents to yield a tetraunsaturated compound, anhydro~Y; the hydroxyl is thus tertiary, Isolation of 1:2:5-trimethylnaphthalene on dehydrogenation indicated a relationship with the labdane diterpene group and supported the C₂₀ formula, The position of the α,β-unsaturated keto-group was resolved by interpretation of the ultraviolet spectra of degradation products and also by isolation of 1:2:3:5- trimethylnaphthalene on dehydrogenation of a suitable grignard product, The presence of a β-substituted furan was further indicated by colour reactions and confirmed by mass and n.m.r. spectra. The skeleton of compound Y is correlated with marrubiin via "iso-ambreinolide " and its stereochemistry is discussed. Further stereochemical assignments are postulated from the study of the n.m.r. spectra. Compound X, C₂₀H₂₈0₅, was shown by spectral and chemical evidence to be a diterpenoid dilactone containing an ether bridge between C₉ and C₁₃ Isolation of 1:2:5 trimethylnaphthal ene on dehydrogenation showed it to be closely related to marrubiin, This was supported by n.m.r. spectral results. A structure for compound X is proposed and the stereochemistry discussed. The aerial portions of Leonotis leonitis were also extracted and shown to contain a new compound, compound R. Preliminary investigation showed that it was a dilactone containing a furan ring, The n.m.r. spectrum of the compound is discussed.
- Full Text:
- Date Issued: 1966
A contribution to the limnology of Swartvlei: the effect of physico-chemical factors upon primary and secondary production in the pelagic zone
- Authors: Robarts, R D (Richard D)
- Date: 1974
- Subjects: Limnology -- South Africa -- Swartvlei
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5822 , http://hdl.handle.net/10962/d1007474
- Description: From Resumé: The effect of physico-chemical factors on the biology of the upper reaches of Swartvlei has been investigated during 1971-1972. Physico-chemical data have shown that Swartvlei was characterized by an extremely labile ectogenic meromixis. This instability was due to three factors : (1) the inflow of freshwater, (2) the inflow of sea water, and (3) wind stress. The magnitude of the effects of these factors upon the physics, chemistry and biology of the upper reaches was dependent upon whether or not the estuary mouth was open or closed. The phytoplankton of the pelagic zone of Swartvlei was dominated by nannoplankton. Three major categories were recorded: dinoflagellates, flagellates and diatoms. The major factor regulating their productivity in the upper reaches was light. As a result of humate staining and suspended detrital matter light conditions in Swartvlei were comparable to those in extremely eutrophic northern hemisphere lakes. A maximum integral primary productivity of 39.66 mg C m⁻² h⁻¹ was recorded in November 1972. The aerobic heterotrophic bacterial population in Swartvlei was usually less than 300 col. ml⁻¹ (plate counts). The activity of the total microbial population was measured with ¹⁴C techniques. Uptake of acetate was dominated by flagellates and one species of dinoflagellate when they were present. Glucose uptake was due to bacteria as was acetate uptake in the absence of heterotrophic phytoplankton. Glucose uptake was usually greatest in the anaerobic zone. This, and the presence of H₂S, suggested that a large active photosynthetic and chemosynthetic bacterial population may have been present in the monimolimnion. The possible importance of these bacterial processes in the total productivity of the pelagic zone of Swartvlei was discussed. Daytime zooplankton population size was statistically correlated with the size of the flagellate population. The zooplankton was dominated by Acartia and Halicyclops. These two animals were found in the anaerobic bottom of Swartvlei after October 1971. This corresponded to the disappearance of the flagellate population from the water column. The dominance of these animals in the zooplankton population may have been related to their ability to live in anaerobic water where the bacterial population appeared to be considerably more abundant than in the aerobic zone. Further implications of the results are discussed in reference to phytoplankton cell size and heterotrophy indicating a possible adaptive significance of these factors in Swartvlei.
- Full Text:
- Date Issued: 1974
- Authors: Robarts, R D (Richard D)
- Date: 1974
- Subjects: Limnology -- South Africa -- Swartvlei
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5822 , http://hdl.handle.net/10962/d1007474
- Description: From Resumé: The effect of physico-chemical factors on the biology of the upper reaches of Swartvlei has been investigated during 1971-1972. Physico-chemical data have shown that Swartvlei was characterized by an extremely labile ectogenic meromixis. This instability was due to three factors : (1) the inflow of freshwater, (2) the inflow of sea water, and (3) wind stress. The magnitude of the effects of these factors upon the physics, chemistry and biology of the upper reaches was dependent upon whether or not the estuary mouth was open or closed. The phytoplankton of the pelagic zone of Swartvlei was dominated by nannoplankton. Three major categories were recorded: dinoflagellates, flagellates and diatoms. The major factor regulating their productivity in the upper reaches was light. As a result of humate staining and suspended detrital matter light conditions in Swartvlei were comparable to those in extremely eutrophic northern hemisphere lakes. A maximum integral primary productivity of 39.66 mg C m⁻² h⁻¹ was recorded in November 1972. The aerobic heterotrophic bacterial population in Swartvlei was usually less than 300 col. ml⁻¹ (plate counts). The activity of the total microbial population was measured with ¹⁴C techniques. Uptake of acetate was dominated by flagellates and one species of dinoflagellate when they were present. Glucose uptake was due to bacteria as was acetate uptake in the absence of heterotrophic phytoplankton. Glucose uptake was usually greatest in the anaerobic zone. This, and the presence of H₂S, suggested that a large active photosynthetic and chemosynthetic bacterial population may have been present in the monimolimnion. The possible importance of these bacterial processes in the total productivity of the pelagic zone of Swartvlei was discussed. Daytime zooplankton population size was statistically correlated with the size of the flagellate population. The zooplankton was dominated by Acartia and Halicyclops. These two animals were found in the anaerobic bottom of Swartvlei after October 1971. This corresponded to the disappearance of the flagellate population from the water column. The dominance of these animals in the zooplankton population may have been related to their ability to live in anaerobic water where the bacterial population appeared to be considerably more abundant than in the aerobic zone. Further implications of the results are discussed in reference to phytoplankton cell size and heterotrophy indicating a possible adaptive significance of these factors in Swartvlei.
- Full Text:
- Date Issued: 1974
Implementation of gender equality policies to enhance female leadership in Zimbabwean universities : towards a comprehensive framework
- Chitsamatanga, Bellita Banda
- Authors: Chitsamatanga, Bellita Banda
- Date: 2016
- Subjects: Sex differences in education Discrimination in education Women executives
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/13571 , vital:39680
- Description: This study critically examined the implementation of gender equality policies to enhance female leadership in Zimbabwean universities. Three theoretical frameworks were adopted for this study which were: The feminist critical policy analysis, top-down and bottom-up policy implementation theories. Within this study an interpretive paradigm which aligned with the qualitative approach and the case study design to better understand the phenomena were adopted. The study covered two state universities in Zimbabwe which were purposively selected. The participants who comprised Pro Vice Chancellors, Deputy Registrars Human Resources, Faculty Deans, Director of Gender Schools, Senior Administrative Registrars, Chairpersons of Departments and males and female academics were also purposively selected. Semi structured interviews, focus group discussion and document analysis were used as data collection instruments. Data were analysed using content analysis and the emerging results were organised into different themes reflective of the participant’s responses. The findings of the study presuppose that the state universities Zimbabwe were implementing gender sensitive organisational culture through open door policy and this promoted transformational leadership in both universities. The study revealed that both universities consulted internal and external gender experts and top-down and bottom-up consultations were made during policy formulation. It was discovered from the study that both universities had also utilised gender mainstreaming and affirmative action as strategies for promoting female leadership and gender equality. Despite teaching and learning, community engagement, research, recruitment and promotions which were used to promote the gender agenda, there were indications that these were being implemented in a haphazard manner. This adversely influenced active participation of females in decision making processes. The collected data also showed that both universities had enacted gender structures which were in line with international, regional and national gender policies and conventions and were being used to irradiate the importance of having gender parity in top positions. The findings of the study further illuminated that monitoring and evaluation of the gender equality policy and programs in place to advance females to leadership positions had not been done, leading to major impediments to achievement of gender balance. There also emerged a number of challenges which were uniform in both universities namely; lack of gender knowledge; commitment, lack of gender training and workshops, lack of consultation using bottom-up approach, gender budgeting and inadequate resources. Though the above mentioned were identified as encumbering features in both universities there was a substantiation of pockets of good practices. These were; implementation of gender equality policy, involvement of internal and external gender experts to policy formulation; promotion of shared power and authentic leadership through transparent selection of chairperson of departments; gender workshop and training; staff development programmes; enactment of gender structures, enhanced community engagement and liaison with NGOs to promote gender agenda at all levels. Regardless of the number of hurdles that indicate that universities continue to be fraught with challenges in promoting female leadership, the pockets of good practices are evidence that both universities are making positive strides through the implementation of gender equality policies to enhance female leadership. Therefore, to benchmark changes in universities, the study recommends that transformational leadership must permeate in all university structures to promote an organisational culture that is gender sensitive. There must be adequate resources, gender training and workshops; focal persons and points; commitment and political will, gender experts from governmental to ministerial levels and satellite gender structures. Monitoring and evaluation should be carried out in both universities and this should be guided by a framework so as to assist universities to tap into female empowerment and gender equality that will promote the interests of both genders, while retaining the quality and excellence in universities. Lastly, the findings of the study and the extant literature are indicative that enhancement of female leadership in universities is currently affected by a number of challenges. Therefore, as part of redress, the researcher recommends a comprehensive framework which illuminates pockets of good practices in implementing gender equality policies to enhance female leadership in universities.
- Full Text:
- Date Issued: 2016
- Authors: Chitsamatanga, Bellita Banda
- Date: 2016
- Subjects: Sex differences in education Discrimination in education Women executives
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/13571 , vital:39680
- Description: This study critically examined the implementation of gender equality policies to enhance female leadership in Zimbabwean universities. Three theoretical frameworks were adopted for this study which were: The feminist critical policy analysis, top-down and bottom-up policy implementation theories. Within this study an interpretive paradigm which aligned with the qualitative approach and the case study design to better understand the phenomena were adopted. The study covered two state universities in Zimbabwe which were purposively selected. The participants who comprised Pro Vice Chancellors, Deputy Registrars Human Resources, Faculty Deans, Director of Gender Schools, Senior Administrative Registrars, Chairpersons of Departments and males and female academics were also purposively selected. Semi structured interviews, focus group discussion and document analysis were used as data collection instruments. Data were analysed using content analysis and the emerging results were organised into different themes reflective of the participant’s responses. The findings of the study presuppose that the state universities Zimbabwe were implementing gender sensitive organisational culture through open door policy and this promoted transformational leadership in both universities. The study revealed that both universities consulted internal and external gender experts and top-down and bottom-up consultations were made during policy formulation. It was discovered from the study that both universities had also utilised gender mainstreaming and affirmative action as strategies for promoting female leadership and gender equality. Despite teaching and learning, community engagement, research, recruitment and promotions which were used to promote the gender agenda, there were indications that these were being implemented in a haphazard manner. This adversely influenced active participation of females in decision making processes. The collected data also showed that both universities had enacted gender structures which were in line with international, regional and national gender policies and conventions and were being used to irradiate the importance of having gender parity in top positions. The findings of the study further illuminated that monitoring and evaluation of the gender equality policy and programs in place to advance females to leadership positions had not been done, leading to major impediments to achievement of gender balance. There also emerged a number of challenges which were uniform in both universities namely; lack of gender knowledge; commitment, lack of gender training and workshops, lack of consultation using bottom-up approach, gender budgeting and inadequate resources. Though the above mentioned were identified as encumbering features in both universities there was a substantiation of pockets of good practices. These were; implementation of gender equality policy, involvement of internal and external gender experts to policy formulation; promotion of shared power and authentic leadership through transparent selection of chairperson of departments; gender workshop and training; staff development programmes; enactment of gender structures, enhanced community engagement and liaison with NGOs to promote gender agenda at all levels. Regardless of the number of hurdles that indicate that universities continue to be fraught with challenges in promoting female leadership, the pockets of good practices are evidence that both universities are making positive strides through the implementation of gender equality policies to enhance female leadership. Therefore, to benchmark changes in universities, the study recommends that transformational leadership must permeate in all university structures to promote an organisational culture that is gender sensitive. There must be adequate resources, gender training and workshops; focal persons and points; commitment and political will, gender experts from governmental to ministerial levels and satellite gender structures. Monitoring and evaluation should be carried out in both universities and this should be guided by a framework so as to assist universities to tap into female empowerment and gender equality that will promote the interests of both genders, while retaining the quality and excellence in universities. Lastly, the findings of the study and the extant literature are indicative that enhancement of female leadership in universities is currently affected by a number of challenges. Therefore, as part of redress, the researcher recommends a comprehensive framework which illuminates pockets of good practices in implementing gender equality policies to enhance female leadership in universities.
- Full Text:
- Date Issued: 2016
Physiological and mechanistic characteristics of all-out running using the critical speed concept
- Authors: Kramer, Mark
- Date: 2019
- Subjects: Aerobic exercises , Physical fitness Running Exercise
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/40511 , vital:36178
- Description: The studies described in this thesis, as far as could be ascertained, were the first to investigate the physiological and mechanistic characteristics of all-out running using the critical speed concept specifically applied to field-sport athletes. In the first study the oxygen uptake (𝑉̇𝑂2) kinetics of linear and shuttle all-out running were investigated. The 𝑉̇𝑂2 kinetic parameters were also related to parameters derived from a graded exercise test. No differences were observed in all 𝑉̇ 𝑂2 kinetic parameters between all-out linear and shuttle running, even though differences in all-out testing parameters were evident. The study was novel in that it was, as far as could be ascertained, the first to implement and investigate differences in 𝑉̇𝑂2 kinetics applied to all-out running. The second study investigated whether the parameters derived from all-out linear and shuttle running were representative of aerobic fitness, and the extent to which the all-out test (AOT) related to already established evaluations of aerobic fitness (e.g., graded exercise test [GXT] and the Yo-Yo intermittent recovery test [YYIR1]). It was also investigated whether the parameters from the AOTs could be used to predict the time to completion (tLIM) of shuttle-based performances. The outcomes of this study showed that both the linear and 50-m AOTs were indeed valid for the aerobic assessment of fitness by showing high correlations with maximal pulmonary oxygen uptake (𝑉̇𝑂2𝑚𝑎𝑥). Both the linear and 50-m AOT could therefore be used as surrogates for the evaluation of aerobic fitness. Interestingly, in terms of the tLIM prediction, the 25-m AOT showed the greatest utility. This study was novel on several fronts in that it was the first to: (1) investigate the physiological link between linear and shuttle AOTs and the GXT, (2) investigate the difference between AOTs and the YYIR1, and (3) investigate the application of the AOT methodology to field-based athletes such as rugby players. The third study investigated the energetic cost (EC) of locomotion as well as the metabolic power (𝑃̇) required to run at given speeds. The energetic approach provides a more robust evaluation of the differences between linear and shuttle running due to the all-out nature of the tests. Conventional methods of energy assessment often fall short due to the preclusion of a physiological steady-state, hence requiring more robust mathematical models to evaluate all-out running performance. The results of this study showed that differences between linear and shuttle AOTs are more likely neuromuscular as opposed to physiological. Peak EC and 𝑃̇ were significantly greater for shuttle running compared to linear running, showing clear non-linear increases with each successive increase in running speed. However, the mean EC and 𝑃̇ were not different, showing that all-out shuttle running ‘balances’ the lower running speeds (implying a lower physiological load compared to linear running) with the higher metabolic load imposed by the intense directional changes. This study was novel as it was, as far as could be ascertained, the first to apply the energetic approach to all-out running as well as investigate the differences in energetics between linear and shuttle AOTs. The fourth study provided a means by which the speed-time characteristics of all-out running could be objectively quantified. A novel bi-exponential model was applied to both the linear and shuttle speed-time curves and allowed various mechanistic aspects of the speed-time curve to be characterized. Conventional assessment of the AOT allows for the derivation of only two key parameters, namely critical speed (CS) and the finite distance achievable at speeds exceeding CS (D’). The application of the bi-exponential model expands the number of useful parameters that can be derived from an AOT to seven. The additional useful parameters include: maximum speed [𝑆𝑚𝑎𝑥], time to maximum speed [𝑡𝑐], amplitude of the difference between 𝑆𝑚𝑎𝑥 and CS [𝐴𝑑], curvature constant of the exponential decay [𝜏𝑑] and the asymptote of the exponential decay function [𝑆0], fatigue index showing the percent decline between 𝑆𝑚𝑎𝑥 and CS [FI%], and the finite capacity for running at speeds exceeding CS [D’; representing the area under the curve that is above CS]. The CS and D’ parameters derived from the bi-exponential model were not different to the CS and D’ parameters derived using the conventional method of analysis, thereby showing that the bi-exponential model is a valid means of assessing the curvature characteristics of the AOT, as well as providing additional information that cannot be gleaned from the traditional approach.
- Full Text:
- Date Issued: 2019
- Authors: Kramer, Mark
- Date: 2019
- Subjects: Aerobic exercises , Physical fitness Running Exercise
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/40511 , vital:36178
- Description: The studies described in this thesis, as far as could be ascertained, were the first to investigate the physiological and mechanistic characteristics of all-out running using the critical speed concept specifically applied to field-sport athletes. In the first study the oxygen uptake (𝑉̇𝑂2) kinetics of linear and shuttle all-out running were investigated. The 𝑉̇𝑂2 kinetic parameters were also related to parameters derived from a graded exercise test. No differences were observed in all 𝑉̇ 𝑂2 kinetic parameters between all-out linear and shuttle running, even though differences in all-out testing parameters were evident. The study was novel in that it was, as far as could be ascertained, the first to implement and investigate differences in 𝑉̇𝑂2 kinetics applied to all-out running. The second study investigated whether the parameters derived from all-out linear and shuttle running were representative of aerobic fitness, and the extent to which the all-out test (AOT) related to already established evaluations of aerobic fitness (e.g., graded exercise test [GXT] and the Yo-Yo intermittent recovery test [YYIR1]). It was also investigated whether the parameters from the AOTs could be used to predict the time to completion (tLIM) of shuttle-based performances. The outcomes of this study showed that both the linear and 50-m AOTs were indeed valid for the aerobic assessment of fitness by showing high correlations with maximal pulmonary oxygen uptake (𝑉̇𝑂2𝑚𝑎𝑥). Both the linear and 50-m AOT could therefore be used as surrogates for the evaluation of aerobic fitness. Interestingly, in terms of the tLIM prediction, the 25-m AOT showed the greatest utility. This study was novel on several fronts in that it was the first to: (1) investigate the physiological link between linear and shuttle AOTs and the GXT, (2) investigate the difference between AOTs and the YYIR1, and (3) investigate the application of the AOT methodology to field-based athletes such as rugby players. The third study investigated the energetic cost (EC) of locomotion as well as the metabolic power (𝑃̇) required to run at given speeds. The energetic approach provides a more robust evaluation of the differences between linear and shuttle running due to the all-out nature of the tests. Conventional methods of energy assessment often fall short due to the preclusion of a physiological steady-state, hence requiring more robust mathematical models to evaluate all-out running performance. The results of this study showed that differences between linear and shuttle AOTs are more likely neuromuscular as opposed to physiological. Peak EC and 𝑃̇ were significantly greater for shuttle running compared to linear running, showing clear non-linear increases with each successive increase in running speed. However, the mean EC and 𝑃̇ were not different, showing that all-out shuttle running ‘balances’ the lower running speeds (implying a lower physiological load compared to linear running) with the higher metabolic load imposed by the intense directional changes. This study was novel as it was, as far as could be ascertained, the first to apply the energetic approach to all-out running as well as investigate the differences in energetics between linear and shuttle AOTs. The fourth study provided a means by which the speed-time characteristics of all-out running could be objectively quantified. A novel bi-exponential model was applied to both the linear and shuttle speed-time curves and allowed various mechanistic aspects of the speed-time curve to be characterized. Conventional assessment of the AOT allows for the derivation of only two key parameters, namely critical speed (CS) and the finite distance achievable at speeds exceeding CS (D’). The application of the bi-exponential model expands the number of useful parameters that can be derived from an AOT to seven. The additional useful parameters include: maximum speed [𝑆𝑚𝑎𝑥], time to maximum speed [𝑡𝑐], amplitude of the difference between 𝑆𝑚𝑎𝑥 and CS [𝐴𝑑], curvature constant of the exponential decay [𝜏𝑑] and the asymptote of the exponential decay function [𝑆0], fatigue index showing the percent decline between 𝑆𝑚𝑎𝑥 and CS [FI%], and the finite capacity for running at speeds exceeding CS [D’; representing the area under the curve that is above CS]. The CS and D’ parameters derived from the bi-exponential model were not different to the CS and D’ parameters derived using the conventional method of analysis, thereby showing that the bi-exponential model is a valid means of assessing the curvature characteristics of the AOT, as well as providing additional information that cannot be gleaned from the traditional approach.
- Full Text:
- Date Issued: 2019
Simulation of the visuo-motor processes in the tracking and interception of a tennis ball in play
- Authors: Pappo, Harry A
- Date: 1985
- Subjects: Tennis -- Psychological aspects Motor ability -- Physiological aspects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1365 , http://hdl.handle.net/10962/d1001431
- Description: In sports, one might wish to test new ideas regarding player movement, tactics, or strategy without subjecting the athletes to possibly wasteful or even harmful habit formations. If a method of simulation of the athlete can be devised, experiments might reasonably be conducted to evaluate the ideas independently of actual training or trial in the field. Simulation of a complex system generally begins with a long period of analysis. During this time there may be mathematical and programming explorations and constructions to sharpen and examine different approaches. Meetings are usually held by the participants to try to define the task and explore alternatives. Ideas are amplified, possibly discarded as not feasible, or incorporated into the system package. Gradually there evolves a tighter and more acceptable formulation using logical and mathematical expressions (Preface, p. vii)
- Full Text:
- Date Issued: 1985
- Authors: Pappo, Harry A
- Date: 1985
- Subjects: Tennis -- Psychological aspects Motor ability -- Physiological aspects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:1365 , http://hdl.handle.net/10962/d1001431
- Description: In sports, one might wish to test new ideas regarding player movement, tactics, or strategy without subjecting the athletes to possibly wasteful or even harmful habit formations. If a method of simulation of the athlete can be devised, experiments might reasonably be conducted to evaluate the ideas independently of actual training or trial in the field. Simulation of a complex system generally begins with a long period of analysis. During this time there may be mathematical and programming explorations and constructions to sharpen and examine different approaches. Meetings are usually held by the participants to try to define the task and explore alternatives. Ideas are amplified, possibly discarded as not feasible, or incorporated into the system package. Gradually there evolves a tighter and more acceptable formulation using logical and mathematical expressions (Preface, p. vii)
- Full Text:
- Date Issued: 1985
On the growth and characterisation of AIGaN alloys for optoelectronic applications
- Authors: James, Grant Robert
- Date: 2005
- Subjects: Gallium nitride -- Electric properties , Photoluminescence
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/8824 , vital:26433
- Description: In this study the growth and characterisation of undoped and Si-doped AlxGa1-xN has been performed. The layers were grown using low-pressure metalorganic vapour phase deposition (MOCVD) on sapphire substrates. The optical and electrical properties of the AlxGa1-xN layers were studied using variable temperature Hall effect and photoluminescence measurements. AlxGa1-xN layers were grown over the entire composition range. Room temperature ultraviolet (UV) transmission measurements showed that the material quality was very good for layers with an Al content, x, of 0 _ x _ 0.5. However, the quality of layers of higher composition was seen to rapidly decrease with increasing x. The electrical and optical properties of AlxGa1-xN with x < 0.5 were also good, comparable to those reported on in literature. The study of the Si-doping of AlxGa1-xN was performed in two parts; firstly a series of Al0.23Ga0.77N samples was grown in which the doping level was increased from zero to n _ 3 × 1018 cm-3. A similar, albeit a less rigorous, study was performed for Al0.41Ga0.59N and Al0.5Ga0.5N. A second series of samples was then grown in which the doping level was kept constant, while the Al content was incrementally increased. Room temperature Hall effect measurements performed on Si-doped Al0.23Ga0.77N showed that the electron concentration did not scale linearly with the silane flow, as was the case in GaN. It was also seen that the electron mobility of the layers increased with slight Si-doping, possibly due to an improvement in the crystalline quality and/or a change in the conduction mechanism. It was also found that at higher compositions (x = 0.41 and 0.50) an increase in the doping level resulted in an increase in the mobility. Variable temperature Hall effect and photoluminescence measurements, performed on the Al0.23Ga0.77N samples, revealed a good correlation between the first PL activation energy E1 and the donor activation energy ED, prompting the conclusion that the first PL recombination channel in AlxGa1-xN is due to the delocalisation of excitons bound at neutral Si donors. Furthermore, E1 and ED were seen to decrease with n1/3, as is the case for GaN and other semiconductor materials. It was also observed that strong exciton localisation occurs in slightly Si-doped material, with the amount of localization becoming less at higher doping levels. Possible mechanisms responsible for the second PL recombination channel of activation energy E2 were also proposed. The electrical and optical properties of the second set of AlxGa1-xN samples was then studied. The PL properties of undoped AlxGa1-xN were typical of a homogeneous alloy system, with the increase in the PL FWHM and exciton localisation energies with x following the trend predicted by alloy disorder theory. The variation of the band gap energy with the Al content could not, however, be fitted over the entire composition range using a single bowing parameter. It was proposed that this was due either to an effect of the 9 7 valence band crossover, or due to exciton localisation at alloy disorder and/or impurities. As was the case for GaN and Al0.23Ga0.77N, all undoped material was highly resistive. As was mentioned earlier, the exciton localisation energies increased according to alloy disorder theory in undoped AlxGa1-xN. In the doped samples, however, a large increase in the donor localisation energy was measured for x > 0.3. The possibility that Si could become a DX-centre in AlxGa1-xN was then investigated. However, Hall effect measurements showed that the Si activation energy increased in good agreement with the model of a shallow effective mass state donor, with no sudden increase in ED being observed up to x = 0.4. It was then suggested that the increase in the E1 and E2 activation energies, as well as the exciton localisation energies, could be due to the 9 7 valence band crossover, which occurs at roughly the same composition. However, due to the scarcity of reports on the valence band structure in AlxGa1-xN no conclusions could be made at this stage as to the effect of the 9 7 valence band crossover on the PL properties of AlxGa1-xN.
- Full Text:
- Date Issued: 2005
- Authors: James, Grant Robert
- Date: 2005
- Subjects: Gallium nitride -- Electric properties , Photoluminescence
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/8824 , vital:26433
- Description: In this study the growth and characterisation of undoped and Si-doped AlxGa1-xN has been performed. The layers were grown using low-pressure metalorganic vapour phase deposition (MOCVD) on sapphire substrates. The optical and electrical properties of the AlxGa1-xN layers were studied using variable temperature Hall effect and photoluminescence measurements. AlxGa1-xN layers were grown over the entire composition range. Room temperature ultraviolet (UV) transmission measurements showed that the material quality was very good for layers with an Al content, x, of 0 _ x _ 0.5. However, the quality of layers of higher composition was seen to rapidly decrease with increasing x. The electrical and optical properties of AlxGa1-xN with x < 0.5 were also good, comparable to those reported on in literature. The study of the Si-doping of AlxGa1-xN was performed in two parts; firstly a series of Al0.23Ga0.77N samples was grown in which the doping level was increased from zero to n _ 3 × 1018 cm-3. A similar, albeit a less rigorous, study was performed for Al0.41Ga0.59N and Al0.5Ga0.5N. A second series of samples was then grown in which the doping level was kept constant, while the Al content was incrementally increased. Room temperature Hall effect measurements performed on Si-doped Al0.23Ga0.77N showed that the electron concentration did not scale linearly with the silane flow, as was the case in GaN. It was also seen that the electron mobility of the layers increased with slight Si-doping, possibly due to an improvement in the crystalline quality and/or a change in the conduction mechanism. It was also found that at higher compositions (x = 0.41 and 0.50) an increase in the doping level resulted in an increase in the mobility. Variable temperature Hall effect and photoluminescence measurements, performed on the Al0.23Ga0.77N samples, revealed a good correlation between the first PL activation energy E1 and the donor activation energy ED, prompting the conclusion that the first PL recombination channel in AlxGa1-xN is due to the delocalisation of excitons bound at neutral Si donors. Furthermore, E1 and ED were seen to decrease with n1/3, as is the case for GaN and other semiconductor materials. It was also observed that strong exciton localisation occurs in slightly Si-doped material, with the amount of localization becoming less at higher doping levels. Possible mechanisms responsible for the second PL recombination channel of activation energy E2 were also proposed. The electrical and optical properties of the second set of AlxGa1-xN samples was then studied. The PL properties of undoped AlxGa1-xN were typical of a homogeneous alloy system, with the increase in the PL FWHM and exciton localisation energies with x following the trend predicted by alloy disorder theory. The variation of the band gap energy with the Al content could not, however, be fitted over the entire composition range using a single bowing parameter. It was proposed that this was due either to an effect of the 9 7 valence band crossover, or due to exciton localisation at alloy disorder and/or impurities. As was the case for GaN and Al0.23Ga0.77N, all undoped material was highly resistive. As was mentioned earlier, the exciton localisation energies increased according to alloy disorder theory in undoped AlxGa1-xN. In the doped samples, however, a large increase in the donor localisation energy was measured for x > 0.3. The possibility that Si could become a DX-centre in AlxGa1-xN was then investigated. However, Hall effect measurements showed that the Si activation energy increased in good agreement with the model of a shallow effective mass state donor, with no sudden increase in ED being observed up to x = 0.4. It was then suggested that the increase in the E1 and E2 activation energies, as well as the exciton localisation energies, could be due to the 9 7 valence band crossover, which occurs at roughly the same composition. However, due to the scarcity of reports on the valence band structure in AlxGa1-xN no conclusions could be made at this stage as to the effect of the 9 7 valence band crossover on the PL properties of AlxGa1-xN.
- Full Text:
- Date Issued: 2005
Applications of the Baylis-Hillman reaction in the synthesis of coumarin derivatives
- Authors: Musa, Musiliyu Ayodele
- Date: 2003
- Subjects: Coumarins Heterocyclic compounds -- Derivatives
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4403 , http://hdl.handle.net/10962/d1006705
- Description: The reaction of specially prepared salicylaldehyde benzyl ethers with the activated alkenes, methyl acrylate or acrylonitrile, in the presence of the catalyst, DABCO, has afforded Baylis-Hillman products, which have been subjected to conjugate addition with either piperidine or benzylamine. Hydrogenolysis of these conjugate addition products in the presence of a palladium-on-carbon catalyst has been shown to afford the corresponding 3-substituted coumarins, while treatment of O-benzylated Baylis-Hillman adducts with HCl or HI afforded the corresponding 3-(halomethyl)coumarins directly, in up to 94%. The 3-(halomethyl)coumarins have also been obtained in excellent yields (up to 98%) and even more conveniently, by treating the unprotected Baylis-Hillman products with HCl in a mixture of AcOH and Ac₂O, obtained from tert-butyl acrylate and various salicylaldehydes. The generality of an established route to the synthesis of coumarins via an intramolecular Baylis-Hillman reaction, involving the use of salicylaldehyde acrylate esters in the presence of DABCO, has also been demonstrated. Reactions between the 3-(halomethyl)coumarins and various nitrogen and carbon nucleophiles have been shown to proceed with a high degree of regioselectivity at the exocyclic allylic centre to afford 3-substituted coumarin products. The electronimpact mass spectra of selected coumarin derivatives have been investigated using high-resolution and B/E linked scan data. Fragmentation pathways have been proposed and fragmentation modes associated with different coumarin-containing analogues have been compared. A series of coumarin-containing analogues of ritonavir (a clinically useful HIV-1 protease inhibitor) have been prepared and characterized. The synthetic approach has involved the coupling of coumarin derivatives with a hydroxyethylene dipeptide isostere to afford ritonavir analogues containing coumarin termini. An interactive docking procedure has been used to explore the docking of ritonavir and a coumarincontaining analogue into the enzyme active site.
- Full Text:
- Date Issued: 2003
- Authors: Musa, Musiliyu Ayodele
- Date: 2003
- Subjects: Coumarins Heterocyclic compounds -- Derivatives
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4403 , http://hdl.handle.net/10962/d1006705
- Description: The reaction of specially prepared salicylaldehyde benzyl ethers with the activated alkenes, methyl acrylate or acrylonitrile, in the presence of the catalyst, DABCO, has afforded Baylis-Hillman products, which have been subjected to conjugate addition with either piperidine or benzylamine. Hydrogenolysis of these conjugate addition products in the presence of a palladium-on-carbon catalyst has been shown to afford the corresponding 3-substituted coumarins, while treatment of O-benzylated Baylis-Hillman adducts with HCl or HI afforded the corresponding 3-(halomethyl)coumarins directly, in up to 94%. The 3-(halomethyl)coumarins have also been obtained in excellent yields (up to 98%) and even more conveniently, by treating the unprotected Baylis-Hillman products with HCl in a mixture of AcOH and Ac₂O, obtained from tert-butyl acrylate and various salicylaldehydes. The generality of an established route to the synthesis of coumarins via an intramolecular Baylis-Hillman reaction, involving the use of salicylaldehyde acrylate esters in the presence of DABCO, has also been demonstrated. Reactions between the 3-(halomethyl)coumarins and various nitrogen and carbon nucleophiles have been shown to proceed with a high degree of regioselectivity at the exocyclic allylic centre to afford 3-substituted coumarin products. The electronimpact mass spectra of selected coumarin derivatives have been investigated using high-resolution and B/E linked scan data. Fragmentation pathways have been proposed and fragmentation modes associated with different coumarin-containing analogues have been compared. A series of coumarin-containing analogues of ritonavir (a clinically useful HIV-1 protease inhibitor) have been prepared and characterized. The synthetic approach has involved the coupling of coumarin derivatives with a hydroxyethylene dipeptide isostere to afford ritonavir analogues containing coumarin termini. An interactive docking procedure has been used to explore the docking of ritonavir and a coumarincontaining analogue into the enzyme active site.
- Full Text:
- Date Issued: 2003
Some aspects of the ecology of the citrus red mite, Panonychus citri (McGregor), in the Eastern Cape Province
- Authors: Keetch, D P
- Date: 1969
- Subjects: Citrus -- Diseases and pests -- South Africa -- Eastern Cape Plant mites -- Ecology -- South Africa Citrus red mite Citrus red mite -- Ecology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5860 , http://hdl.handle.net/10962/d1012630
- Description: The citrus red mite, Panonychus citri (McGregor), is a relatively new pest to South African citriculture, the first recorded injury to citrus trees was from Rustenberg, Transvaal in 1950 (Smith 1953). In the U.S.A. the biology of this mite has been studied by Quayle (1938), Prendergast (1938), English and Turnipseed (1941), DeBach (1947), DeBach et al. (1950), Ebeling (1959) and Jeppson et al. (1957,1961). However, in South Africa little information is available concerning the ecolopy of the citrus red mite. The majority of the literature pertaining to P. citri in Republic, (Smith (1953), Mentz (1954), Stofberg (1959), Schwartz (1965) and Brodrick (1965) is of a descriptive nature, and mainly concerned with the chemical control of the mite. The only biological investigation on the development of P.citri, and the effect of insecticides and insect predators on its biology, under South African conditions, was made by van Rooyen (1966) at Zebediela, Transvaal. In the control of citrus pests, such as the citrus red mite, that need for a better understanding of their ecology has been well emphasised by DeBach (1951) and Griffiths (1951). DeBach (1951) in particular, stressed the danger of the continued reliance on insecticidal treatment as the only method of nest control, and has pointed out that persistent chemical applications may only serve to intensify the pest problem. He has suggested that a closer study of the environment of the pest species could provide a solution to the problems now encountered as a result of insecticidal control measures. Intro., p. 1-2.
- Full Text:
- Date Issued: 1969
- Authors: Keetch, D P
- Date: 1969
- Subjects: Citrus -- Diseases and pests -- South Africa -- Eastern Cape Plant mites -- Ecology -- South Africa Citrus red mite Citrus red mite -- Ecology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5860 , http://hdl.handle.net/10962/d1012630
- Description: The citrus red mite, Panonychus citri (McGregor), is a relatively new pest to South African citriculture, the first recorded injury to citrus trees was from Rustenberg, Transvaal in 1950 (Smith 1953). In the U.S.A. the biology of this mite has been studied by Quayle (1938), Prendergast (1938), English and Turnipseed (1941), DeBach (1947), DeBach et al. (1950), Ebeling (1959) and Jeppson et al. (1957,1961). However, in South Africa little information is available concerning the ecolopy of the citrus red mite. The majority of the literature pertaining to P. citri in Republic, (Smith (1953), Mentz (1954), Stofberg (1959), Schwartz (1965) and Brodrick (1965) is of a descriptive nature, and mainly concerned with the chemical control of the mite. The only biological investigation on the development of P.citri, and the effect of insecticides and insect predators on its biology, under South African conditions, was made by van Rooyen (1966) at Zebediela, Transvaal. In the control of citrus pests, such as the citrus red mite, that need for a better understanding of their ecology has been well emphasised by DeBach (1951) and Griffiths (1951). DeBach (1951) in particular, stressed the danger of the continued reliance on insecticidal treatment as the only method of nest control, and has pointed out that persistent chemical applications may only serve to intensify the pest problem. He has suggested that a closer study of the environment of the pest species could provide a solution to the problems now encountered as a result of insecticidal control measures. Intro., p. 1-2.
- Full Text:
- Date Issued: 1969
Ellipsis in the vP domain in Mandarin and Xhosa
- Authors: Ma, Xiujie
- Date: 2017
- Subjects: Grammar, Comparative and general -- Ellipsis , Chinese lanaguage -- Ellipsis , Chinese lanaguage -- Grammar, Comparative -- Xhosa , Xhosa lanaguage -- Ellipsis , Xhosa lanaguage -- Grammar, Comparative -- Chinese
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/43105 , vital:25266
- Description: This thesis provides a unified analysis of ellipsis in the vP domain in two typologically different languages, Mandarin and Xhosa from a generative perspective. It starts with the V-stranding Verb Phrase Ellipsis (VPE) assumption and shows that Mandarin and Xhosa do not have V-stranding VPE. The evidence for this is that in both languages, the constituents that remain in vP obligatorily are not allowed to be deleted, whereas the ones that can/must move out of vP can be deleted. The deleted constituents display the characteristics of PF-deletion, i.e. they have an internal syntactic structure. Based on the parallel between movement and ellipsis of the vP-internal constituents, I propose the Ellipsis EPP Hypothesis to account for ellipsis in the vP domain. The Hypothesis predicts that there is an Ellipsis Phrase at the left periphery of vP. The EP bears an Ellipsis-EPP (EEPP) feature, which must be satisfied. Maximal phrases in the c-command domain of EP are all potential candidates for satisfying the EEPP feature by moving to [Spec, EP]. However, only the phrases that are allowed to move out of vP can move to [Spec, EP] as EP is located above vP. Moreover, the movement to [Spec, EP] is subject to the syntactic and semantic restrictions in structure-building in that ellipsis is one operation in the course of structure-building and the derivation will continue after ellipsis takes place. The EEPP feature renders an XP in the specifier phonetically empty and syntactically frozen; therefore, a constituent will be deleted as soon as it moves to [Spec, EP]. The Hypothesis is schematically represented below. The Ellipsis EPP Hypothesis adequately accounts for the ellipsis of various vP-internal constituents - NPs, DPs, infinitive complements and CP complements - in both Mandarin and Xhosa. At the same time, it reveals the reasons why vP is precluded from being elided in these two languages. In Mandarin vP moves to [Spec, AspPi] to check the uninterpretable [asp] feature and in Xhosa vP moves to [Spec, FocP] to realize the focus; consequently, vP may not move to [Spec, EP] for ellipsis.
- Full Text:
- Date Issued: 2017
- Authors: Ma, Xiujie
- Date: 2017
- Subjects: Grammar, Comparative and general -- Ellipsis , Chinese lanaguage -- Ellipsis , Chinese lanaguage -- Grammar, Comparative -- Xhosa , Xhosa lanaguage -- Ellipsis , Xhosa lanaguage -- Grammar, Comparative -- Chinese
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/43105 , vital:25266
- Description: This thesis provides a unified analysis of ellipsis in the vP domain in two typologically different languages, Mandarin and Xhosa from a generative perspective. It starts with the V-stranding Verb Phrase Ellipsis (VPE) assumption and shows that Mandarin and Xhosa do not have V-stranding VPE. The evidence for this is that in both languages, the constituents that remain in vP obligatorily are not allowed to be deleted, whereas the ones that can/must move out of vP can be deleted. The deleted constituents display the characteristics of PF-deletion, i.e. they have an internal syntactic structure. Based on the parallel between movement and ellipsis of the vP-internal constituents, I propose the Ellipsis EPP Hypothesis to account for ellipsis in the vP domain. The Hypothesis predicts that there is an Ellipsis Phrase at the left periphery of vP. The EP bears an Ellipsis-EPP (EEPP) feature, which must be satisfied. Maximal phrases in the c-command domain of EP are all potential candidates for satisfying the EEPP feature by moving to [Spec, EP]. However, only the phrases that are allowed to move out of vP can move to [Spec, EP] as EP is located above vP. Moreover, the movement to [Spec, EP] is subject to the syntactic and semantic restrictions in structure-building in that ellipsis is one operation in the course of structure-building and the derivation will continue after ellipsis takes place. The EEPP feature renders an XP in the specifier phonetically empty and syntactically frozen; therefore, a constituent will be deleted as soon as it moves to [Spec, EP]. The Hypothesis is schematically represented below. The Ellipsis EPP Hypothesis adequately accounts for the ellipsis of various vP-internal constituents - NPs, DPs, infinitive complements and CP complements - in both Mandarin and Xhosa. At the same time, it reveals the reasons why vP is precluded from being elided in these two languages. In Mandarin vP moves to [Spec, AspPi] to check the uninterpretable [asp] feature and in Xhosa vP moves to [Spec, FocP] to realize the focus; consequently, vP may not move to [Spec, EP] for ellipsis.
- Full Text:
- Date Issued: 2017