Book Review: From the Outside In
- Authors: Magadla, Siphokazi
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298628 , vital:57722 , xlink:href="https://doi.org/10.1080/10220461.2019.1610042"
- Description: From the Outside In: Domestic Actors and South Africa’s Foreign Policy presents an exciting collection of chapters that explore various and often-ignored domestic actors and their relationships within the state, including government departments and local government; and non-governmental organisations such as labour unions, big business and social movements. The editors evoke the imagery of the ‘chess game of foreign policy’, used by scholars such as Joseph Nye,1 to argue that power in international relations is distributed like a ‘three-dimensional chessboard’ consisting of military power, economic power and transnational relations.
- Full Text:
- Date Issued: 2019
- Authors: Magadla, Siphokazi
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298628 , vital:57722 , xlink:href="https://doi.org/10.1080/10220461.2019.1610042"
- Description: From the Outside In: Domestic Actors and South Africa’s Foreign Policy presents an exciting collection of chapters that explore various and often-ignored domestic actors and their relationships within the state, including government departments and local government; and non-governmental organisations such as labour unions, big business and social movements. The editors evoke the imagery of the ‘chess game of foreign policy’, used by scholars such as Joseph Nye,1 to argue that power in international relations is distributed like a ‘three-dimensional chessboard’ consisting of military power, economic power and transnational relations.
- Full Text:
- Date Issued: 2019
Cost-effectiveness of public policy for the long‐term conservation of private lands: What is the deal?
- Nolte, Christopher, de Vos, Alta, Schöttker, Olivier
- Authors: Nolte, Christopher , de Vos, Alta , Schöttker, Olivier
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/415837 , vital:71293 , xlink:href="https://www.proquest.com/scholarly-journals/cost-effectiveness-public-policy-long-term/docview/2326874018/se-2"
- Description: Long-term strategies for private-land conservation are experiencing a surge in scholarly attention. This interest is timely and justified. Globally, many important biodiversity values occur on private lands and are therefore subject to private land use decisions that can threaten their persistence in the absence of protection. Public and private actors spend billions of dollars annually to ensure the long-term protection and enhancement of public ecosystem services on private lands. Many governments recognize and strengthen “privately protected areas” (PPAs) as part of long-term protection obligations under the Aichi Biodiversity Targets (Stolton, Redford, and Dudley, 2014). As public policy makers deliberate over the best strategies to enhance private-land protection, they need to understand how cost-effective these different policy options are, and how they compare to each other.
- Full Text:
- Date Issued: 2019
- Authors: Nolte, Christopher , de Vos, Alta , Schöttker, Olivier
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/415837 , vital:71293 , xlink:href="https://www.proquest.com/scholarly-journals/cost-effectiveness-public-policy-long-term/docview/2326874018/se-2"
- Description: Long-term strategies for private-land conservation are experiencing a surge in scholarly attention. This interest is timely and justified. Globally, many important biodiversity values occur on private lands and are therefore subject to private land use decisions that can threaten their persistence in the absence of protection. Public and private actors spend billions of dollars annually to ensure the long-term protection and enhancement of public ecosystem services on private lands. Many governments recognize and strengthen “privately protected areas” (PPAs) as part of long-term protection obligations under the Aichi Biodiversity Targets (Stolton, Redford, and Dudley, 2014). As public policy makers deliberate over the best strategies to enhance private-land protection, they need to understand how cost-effective these different policy options are, and how they compare to each other.
- Full Text:
- Date Issued: 2019
Engagement in local social-ecological knowledge practices in a seasonal cycles approach for transitioning to future sustainability
- Authors: O'Donoghue, Rob
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/387971 , vital:68294 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/186419"
- Description: This paper explores climate as variable natural forces driving seasonal cycles1 that many African cultures had adjusted themselves to within intergenerational knowledge practices of longue durée. The study points to the need to re-orientate and expand climate science education so that it is centred on the seasonal cycles and intergenerational learning to better align transitioning to future sustainability with these in our southern African contexts of climate change today. The narrative touches upon historical accounts of knowledge practices amongst the Krobo, Bemba, Shona, Zulu and Xhosa, briefly pointing to how each, as an African culture, is situated as a social-ecological entity within the climatic tapestries of our African landscapes. It takes note of how cultural articulation within the seasonal cycles of regional climate have a long history with adaptive change in some contexts in more recent times. The review suggests that our learning in relation to emerging climate change should be informed by these histories of intergenerational knowledge practice. It notes how a better grasp of these could be important drivers of a widening cultural response to the changing dynamics in our climatic surroundings today. The brief study suggests that southern Africa is a special place with many unique and interesting climatic processes and associated socio-ecological systems and practices. These can provide engaging perspectives for informing education to mitigate or adapt to climate change. Here, a situated exploration of seasonal cycles can draw on both the latest in modern climate science and the rich social-ecological heritage of Africa briefly touched upon in the study. A model of process is offered for how both can be used in a seasonal cycles approach climate change education. This better situated and more inclusive approach can enable us to contemplate how we might best adjust our social-ecological dispositions and practices in the changing world that we all share.
- Full Text:
- Date Issued: 2019
- Authors: O'Donoghue, Rob
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/387971 , vital:68294 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/186419"
- Description: This paper explores climate as variable natural forces driving seasonal cycles1 that many African cultures had adjusted themselves to within intergenerational knowledge practices of longue durée. The study points to the need to re-orientate and expand climate science education so that it is centred on the seasonal cycles and intergenerational learning to better align transitioning to future sustainability with these in our southern African contexts of climate change today. The narrative touches upon historical accounts of knowledge practices amongst the Krobo, Bemba, Shona, Zulu and Xhosa, briefly pointing to how each, as an African culture, is situated as a social-ecological entity within the climatic tapestries of our African landscapes. It takes note of how cultural articulation within the seasonal cycles of regional climate have a long history with adaptive change in some contexts in more recent times. The review suggests that our learning in relation to emerging climate change should be informed by these histories of intergenerational knowledge practice. It notes how a better grasp of these could be important drivers of a widening cultural response to the changing dynamics in our climatic surroundings today. The brief study suggests that southern Africa is a special place with many unique and interesting climatic processes and associated socio-ecological systems and practices. These can provide engaging perspectives for informing education to mitigate or adapt to climate change. Here, a situated exploration of seasonal cycles can draw on both the latest in modern climate science and the rich social-ecological heritage of Africa briefly touched upon in the study. A model of process is offered for how both can be used in a seasonal cycles approach climate change education. This better situated and more inclusive approach can enable us to contemplate how we might best adjust our social-ecological dispositions and practices in the changing world that we all share.
- Full Text:
- Date Issued: 2019
Tracking the decline of the world’s largest seabream against policy adjustments
- Kerwath, Sven E, Parker, Denham, Winker, A Henning, Potts, Warren M, Mann, Bruce, Wilke, Christopher, Attwood, Colin G
- Authors: Kerwath, Sven E , Parker, Denham , Winker, A Henning , Potts, Warren M , Mann, Bruce , Wilke, Christopher , Attwood, Colin G
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/131433 , vital:36571 , https://doi.org/10.3354/meps12853
- Description: For most rare marine species, abundance trends are poorly estimated. This uncertainty often translates into disagreement on management regulations, impeding conservation efforts when they are most urgently required. The world’s largest sea bream, the red steenbras Petrus rupestris, has undergone a substantial and widely acknowledged decline during the 20th century. Standardised probability of encounter over the last 3 decades was used to track red steenbras abundance trajectories in 2 regions, which together represent the species’ distribution. The results predicted a reduction in abundance of 44% in the East region and 96% in the South-West region, from what was already considered to be a collapsed population at the start of the time series. The species is now largely confined to areas in the centre of its historical abundance. Content analysis of a recreational angling magazine revealed a concurrent 50% decrease in reported size between 1984 and 2012. Shore-based observer data (2009-2010) indicate that the impact of recreational fishers on this species far exceeded that of commercial fishers at the time. Regulations in the form of progressively more stringent catch and effort restrictions appear to have been largely ineffective, too lenient, implemented too late or were unsuitable to control fishing mortality for this species. This study highlights 2 fundamental challenges in management of rare marine fish species: (1) providing decision makers with a credible measure of abundance for species whose rarity limits data availability and (2) implementing effective policy changes before the specific measures become ineffective and obsolete.
- Full Text:
- Date Issued: 2019
- Authors: Kerwath, Sven E , Parker, Denham , Winker, A Henning , Potts, Warren M , Mann, Bruce , Wilke, Christopher , Attwood, Colin G
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/131433 , vital:36571 , https://doi.org/10.3354/meps12853
- Description: For most rare marine species, abundance trends are poorly estimated. This uncertainty often translates into disagreement on management regulations, impeding conservation efforts when they are most urgently required. The world’s largest sea bream, the red steenbras Petrus rupestris, has undergone a substantial and widely acknowledged decline during the 20th century. Standardised probability of encounter over the last 3 decades was used to track red steenbras abundance trajectories in 2 regions, which together represent the species’ distribution. The results predicted a reduction in abundance of 44% in the East region and 96% in the South-West region, from what was already considered to be a collapsed population at the start of the time series. The species is now largely confined to areas in the centre of its historical abundance. Content analysis of a recreational angling magazine revealed a concurrent 50% decrease in reported size between 1984 and 2012. Shore-based observer data (2009-2010) indicate that the impact of recreational fishers on this species far exceeded that of commercial fishers at the time. Regulations in the form of progressively more stringent catch and effort restrictions appear to have been largely ineffective, too lenient, implemented too late or were unsuitable to control fishing mortality for this species. This study highlights 2 fundamental challenges in management of rare marine fish species: (1) providing decision makers with a credible measure of abundance for species whose rarity limits data availability and (2) implementing effective policy changes before the specific measures become ineffective and obsolete.
- Full Text:
- Date Issued: 2019
Between drones and al-Shabaab: United States extra-judicial killings in Somalia, sovereignty and the future of liberal intervention
- Authors: Koloko, Mojalefa
- Date: 2019
- Subjects: Somalia -- Politics and government -- 1991- , Somalia -- History -- 1991- , Somalia -- Foreign relations -- United States , Somalia -- Foreign relations -- 1991- , Military assistance, American -- Somalia , Extrajudicial exeutions -- Somalia , Shabaab (Organization)
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/67657 , vital:29125
- Description: This study examines the nature of the United States intervention in Somalia, specifically the use of drone strikes that first targeted the militant Sunni Islamist transnational group, al-Qaeda, which claimed responsibility for the 11 September 2001 attacks on the United States, and now target the Somali organisation, Harakat al-Shabaab al-Mujahidin, commonly known as al-Shabaab. The use of drone strikes in the US led war on terror has raised concerns about sovereignty as the extra-judicial killings are conducted without the consent of the concerned states. Furthermore, drone strikes also raise questions about the processes of liberal intervention as the US conducts them without the approval of the United Nations Security Council. It is argued in this study that what is understood to be the “golden era” of liberal interventionism is a legacy of the post-Cold War unipolar dominance of the United States in global governance and security. It is argued that US unipolarity was accompanied by a shifting perception regarding the security position of weak states, whose weakness becomes understood as a source of global insecurity. This perception that so called “weak” and “fragile” states are sources of threats is a departure in International Relations theory, because the discipline is historically preoccupied with studying the actions of powerful states and their consequence for the global order. It is argued that the discourse on the war on terror, and its focus on “failed states” as breeding grounds for alleged terrorists, represents the height of the repositioning of less powerful states from a peripheral status in IR analysis and practice, to their current position that are now being represented as core sources of threat to international peace and security. Through life history interviews with Somali nationals in Grahamstown, Port Elizabeth and Uitenhage, South Africa, the study examines the consequences of US actions from the eyes of Somali people. The findings of this study show that despite all the controversy surrounding the legitimacy of the war on terror, the manner in which it is conducted, as well as the tactics that it employs, the majority of Somali participants showed an overwhelming support for the US intervention. Participants expressed support for the US extra-judicial killings because they are understood to undermine al-Shabaab strength which is a major source of insecurity. The study also shows that the lack of necessary collaboration between the US intelligence and the Somali ground forces has resulted in high numbers of civilian deaths, which participants fear can be used by al-Shabaab to recruit and radicalise more Somalis. The study also shows that most Somalis resent the presence of the African Union Mission in Somalia because Kenya and Ethiopia are seen as 10 pursuing national interests that are not invested in Somali peace and stability. The study concludes that US extra-judicial killings have failed to constrain the actions of al-Shabaab. Somalis expressed that the leadership of current president, Mohamed Abdullahi Mohamed Farmaajo, holds the unique possibilities of creating national unity that rises above clan divisions and the radical Jihadist ideology of al-Shabaab.
- Full Text:
- Date Issued: 2019
- Authors: Koloko, Mojalefa
- Date: 2019
- Subjects: Somalia -- Politics and government -- 1991- , Somalia -- History -- 1991- , Somalia -- Foreign relations -- United States , Somalia -- Foreign relations -- 1991- , Military assistance, American -- Somalia , Extrajudicial exeutions -- Somalia , Shabaab (Organization)
- Language: English
- Type: text , Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/67657 , vital:29125
- Description: This study examines the nature of the United States intervention in Somalia, specifically the use of drone strikes that first targeted the militant Sunni Islamist transnational group, al-Qaeda, which claimed responsibility for the 11 September 2001 attacks on the United States, and now target the Somali organisation, Harakat al-Shabaab al-Mujahidin, commonly known as al-Shabaab. The use of drone strikes in the US led war on terror has raised concerns about sovereignty as the extra-judicial killings are conducted without the consent of the concerned states. Furthermore, drone strikes also raise questions about the processes of liberal intervention as the US conducts them without the approval of the United Nations Security Council. It is argued in this study that what is understood to be the “golden era” of liberal interventionism is a legacy of the post-Cold War unipolar dominance of the United States in global governance and security. It is argued that US unipolarity was accompanied by a shifting perception regarding the security position of weak states, whose weakness becomes understood as a source of global insecurity. This perception that so called “weak” and “fragile” states are sources of threats is a departure in International Relations theory, because the discipline is historically preoccupied with studying the actions of powerful states and their consequence for the global order. It is argued that the discourse on the war on terror, and its focus on “failed states” as breeding grounds for alleged terrorists, represents the height of the repositioning of less powerful states from a peripheral status in IR analysis and practice, to their current position that are now being represented as core sources of threat to international peace and security. Through life history interviews with Somali nationals in Grahamstown, Port Elizabeth and Uitenhage, South Africa, the study examines the consequences of US actions from the eyes of Somali people. The findings of this study show that despite all the controversy surrounding the legitimacy of the war on terror, the manner in which it is conducted, as well as the tactics that it employs, the majority of Somali participants showed an overwhelming support for the US intervention. Participants expressed support for the US extra-judicial killings because they are understood to undermine al-Shabaab strength which is a major source of insecurity. The study also shows that the lack of necessary collaboration between the US intelligence and the Somali ground forces has resulted in high numbers of civilian deaths, which participants fear can be used by al-Shabaab to recruit and radicalise more Somalis. The study also shows that most Somalis resent the presence of the African Union Mission in Somalia because Kenya and Ethiopia are seen as 10 pursuing national interests that are not invested in Somali peace and stability. The study concludes that US extra-judicial killings have failed to constrain the actions of al-Shabaab. Somalis expressed that the leadership of current president, Mohamed Abdullahi Mohamed Farmaajo, holds the unique possibilities of creating national unity that rises above clan divisions and the radical Jihadist ideology of al-Shabaab.
- Full Text:
- Date Issued: 2019
In-betweenness: a postcolonial exploration of sociocultural intergenerational learning through cattle as a medium of cultural expression in Mpembeni, KwaZulu-Natal
- Authors: Masuku, Lynette Sibongile
- Date: 2019
- Subjects: Postcolonialism , Environmental education -- South Africa , Community education -- South Africa -- KwaZulu Natal , Non-formal education -- South Africa -- KwaZulu Natal , Agricultural education -- South Africa -- KwaZulu Natal , Livestock -- Handling -- South Africa -- KwaZulu Natal , Cattle -- Handling -- South Africa -- KwaZulu Natal , Cattle herding -- South Africa -- KwaZulu Natal , Life skills -- Study and teaching -- South Africa
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/68181 , vital:29213
- Description: This case study was conducted in a small rural community called Mpembeni, in South Africa’s KwaZulu-Natal province. It was motivated by my observation of high levels of competence in ‘cattle knowledge’ amongst children coupled with a simultaneous failure at school. I view schools as integral parts of the community and consider them as being influenced by the community, which they in turn influence. This study set out to understand that which embodied informal learning in home/pasture-based contexts as well as formalised learning processes in schools. I used Sociocultural theory as the most congruent of educational theories to surface and illuminate the intergenerational learning processes that were taking place in the area. This warranted my use of research investigation methods that could, in non-intrusive ways, expose the everyday community practices that related to cattle as a particular medium of cultural expression. Ethnography, sourced from anthropology, aided by ethnomethods, was not only compatible with my study and the way in which I wanted to write out the research report, but also with my educational theory and its counterhegemonic intents. To understand the colonialities that framed the discord that embodied home and school as learning contexts, I used postcolonial theory, not only as a lens but as a counterhegemonic response. This theory also informed my research methodology as well as afforded me the reflexivity tools for an examination of my own intergenerational learning and the relational identities of myself as ‘Other’ in the lives of the research participants. It further facilitated the exploration of the potential for potential hybrid third spaces within the bubbling meeting nodes of the socio-cultural context of school and home/pasture based settings of learning. I observed cattle herding related practices, interviewed children, their parents and/or carers, dipping tank managers, livestock inspectors, community elders and members. I also analysed some of the written and unwritten content that made up the formal and informal based learning processes and reviewed some of the most recent South African Curriculum Statements and related texts on the representations of cattle. I sought views from teachers on their interactions with the people of Mpembeni, whose children they taught. I also explored axes of tension, silences and presences on anything related to cattle in schools. I argue and make a case for the development of thought by African scholars to advance Africa’s education rather than aid mimicry and the importation of theories of little congruence and relevance to the African context and Africa’s future. The study has made some contributions to new knowledge. This is in its exploration of sociocultural intergenerational methods and techniques that are employed for learning in community contexts, highlighting the importance of surfacing and understanding of children’s knowledge and experiences. The study has gone further to deliberate the in-betweenness of school and home learning environments, highlighting and unsilencing silenced, peripherised, new, old, considered irrelevant in the past, context and time congruent and liberatory knowledges. I propose that the knowledges located in these cleavages of difference be utilised to transform and create learning bridges between home and school environments. I propose that those ways of knowing that see others as nothings, be exposed and unlearned. Methods of learning that naturally unfold at home could be replicated at school with a recognition of the intergenerational methods, techniques, practices and the learning values in a critically constructive manner that narrows difference and othering.
- Full Text:
- Date Issued: 2019
- Authors: Masuku, Lynette Sibongile
- Date: 2019
- Subjects: Postcolonialism , Environmental education -- South Africa , Community education -- South Africa -- KwaZulu Natal , Non-formal education -- South Africa -- KwaZulu Natal , Agricultural education -- South Africa -- KwaZulu Natal , Livestock -- Handling -- South Africa -- KwaZulu Natal , Cattle -- Handling -- South Africa -- KwaZulu Natal , Cattle herding -- South Africa -- KwaZulu Natal , Life skills -- Study and teaching -- South Africa
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/68181 , vital:29213
- Description: This case study was conducted in a small rural community called Mpembeni, in South Africa’s KwaZulu-Natal province. It was motivated by my observation of high levels of competence in ‘cattle knowledge’ amongst children coupled with a simultaneous failure at school. I view schools as integral parts of the community and consider them as being influenced by the community, which they in turn influence. This study set out to understand that which embodied informal learning in home/pasture-based contexts as well as formalised learning processes in schools. I used Sociocultural theory as the most congruent of educational theories to surface and illuminate the intergenerational learning processes that were taking place in the area. This warranted my use of research investigation methods that could, in non-intrusive ways, expose the everyday community practices that related to cattle as a particular medium of cultural expression. Ethnography, sourced from anthropology, aided by ethnomethods, was not only compatible with my study and the way in which I wanted to write out the research report, but also with my educational theory and its counterhegemonic intents. To understand the colonialities that framed the discord that embodied home and school as learning contexts, I used postcolonial theory, not only as a lens but as a counterhegemonic response. This theory also informed my research methodology as well as afforded me the reflexivity tools for an examination of my own intergenerational learning and the relational identities of myself as ‘Other’ in the lives of the research participants. It further facilitated the exploration of the potential for potential hybrid third spaces within the bubbling meeting nodes of the socio-cultural context of school and home/pasture based settings of learning. I observed cattle herding related practices, interviewed children, their parents and/or carers, dipping tank managers, livestock inspectors, community elders and members. I also analysed some of the written and unwritten content that made up the formal and informal based learning processes and reviewed some of the most recent South African Curriculum Statements and related texts on the representations of cattle. I sought views from teachers on their interactions with the people of Mpembeni, whose children they taught. I also explored axes of tension, silences and presences on anything related to cattle in schools. I argue and make a case for the development of thought by African scholars to advance Africa’s education rather than aid mimicry and the importation of theories of little congruence and relevance to the African context and Africa’s future. The study has made some contributions to new knowledge. This is in its exploration of sociocultural intergenerational methods and techniques that are employed for learning in community contexts, highlighting the importance of surfacing and understanding of children’s knowledge and experiences. The study has gone further to deliberate the in-betweenness of school and home learning environments, highlighting and unsilencing silenced, peripherised, new, old, considered irrelevant in the past, context and time congruent and liberatory knowledges. I propose that the knowledges located in these cleavages of difference be utilised to transform and create learning bridges between home and school environments. I propose that those ways of knowing that see others as nothings, be exposed and unlearned. Methods of learning that naturally unfold at home could be replicated at school with a recognition of the intergenerational methods, techniques, practices and the learning values in a critically constructive manner that narrows difference and othering.
- Full Text:
- Date Issued: 2019
On-site evaluation of smoking, alcohol consumption and physical inactivity among commercial taxi drivers in Buffalo City Metropolitan Municipality, South Africa
- Adedokun, Aanuoluwa Odunayo, Ter Goon, Daniel, Owolabi, Eyitayo Omolara, Adeniyi, Oladele Vincent, Ajayi, Anthony Idowu
- Authors: Adedokun, Aanuoluwa Odunayo , Ter Goon, Daniel , Owolabi, Eyitayo Omolara , Adeniyi, Oladele Vincent , Ajayi, Anthony Idowu
- Date: 2019
- Subjects: Alcohol use , Substance use , Commercial drivers
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/11260/5086 , vital:44345 , https://doi.org/10.5539/gjhs.v11n2p110
- Description: Commercial drivers have been identified as eliciting behaviours that promote non- communicable diseases and road traffic accidents. The aim of the study is to determine the prevalence and pattern of alcohol use, smoking and physical inactivity among commercial taxi drivers in Buffalo City Metropolitan Municipality, South Africa. A cross-sectional study was conducted among 403 commercial drivers using the face-to-face interviews method. The WHO STEPwise questionnaire was used to obtain the demographic data, self-reported rate of alcohol consumption, tobacco use and physical inactivity. The participants’ mean age was 43.3 ± 12.5 years. About 30% of the participants were daily smokers, 37% consumed alcohol regularly and only 18% were physically active, whilst 82% were physically inactive. The prevalence of alcohol use, smoking and physical inactivity is high among commercial drivers in East London. Workplace health education on the health effects of these lifestyles’ risky behaviours on individuals and the general public should be given to the drivers.
- Full Text:
- Date Issued: 2019
- Authors: Adedokun, Aanuoluwa Odunayo , Ter Goon, Daniel , Owolabi, Eyitayo Omolara , Adeniyi, Oladele Vincent , Ajayi, Anthony Idowu
- Date: 2019
- Subjects: Alcohol use , Substance use , Commercial drivers
- Language: English
- Type: article , text
- Identifier: http://hdl.handle.net/11260/5086 , vital:44345 , https://doi.org/10.5539/gjhs.v11n2p110
- Description: Commercial drivers have been identified as eliciting behaviours that promote non- communicable diseases and road traffic accidents. The aim of the study is to determine the prevalence and pattern of alcohol use, smoking and physical inactivity among commercial taxi drivers in Buffalo City Metropolitan Municipality, South Africa. A cross-sectional study was conducted among 403 commercial drivers using the face-to-face interviews method. The WHO STEPwise questionnaire was used to obtain the demographic data, self-reported rate of alcohol consumption, tobacco use and physical inactivity. The participants’ mean age was 43.3 ± 12.5 years. About 30% of the participants were daily smokers, 37% consumed alcohol regularly and only 18% were physically active, whilst 82% were physically inactive. The prevalence of alcohol use, smoking and physical inactivity is high among commercial drivers in East London. Workplace health education on the health effects of these lifestyles’ risky behaviours on individuals and the general public should be given to the drivers.
- Full Text:
- Date Issued: 2019
Phototransferred thermoluminescence and thermally-assisted optically stimulated luminescence dosimetry using α-Al2O3:C,Mg annealed at 1200°C
- Kalita, Jitumani M, Chithambo, Makaiko L
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105422 , vital:32511 , https://doi.org/10.1016/j.jlumin.2018.08.085
- Description: We report phototransferred thermoluminescence (PTTL) and thermally-assisted optically stimulated luminescence (TA-OSL) of α-Al2O3:C,Mg annealed at 1200 °C. PTTL is TL measured from an irradiated phosphor after its exposure to light. The other theme of this study, TA-OSL is the additional amount of luminescence optically stimulated from a sample over and above the amount that would be measured at room temperature. A sample irradiated to 10 Gy and preheated to 230 °C at 1 °C/s followed by illumination by 470 nm blue light produced four PTTL peaks at 53, 80, 102 and 173 °C. The PTTL peaks occur at the same positions as the corresponding conventional TL peaks. Their kinetic parameters are also similar. The intensity of the PTTL peaks increased with duration of illumination to a maximum within 200 s for doses between 1 Gy and 10 Gy. The dose response of each of the PTTL peaks at 80, 102 and 173 °C is linear within 1–15 Gy. The rate of fading is low and the peaks are reproducible. When the irradiated sample is optically stimulated at temperatures between 30 °C and 300 °C, after preheating to 500 °C, the intensity of its TA-OSL goes through a peak with temperature at 200 °C. Using the rising edge of the plot, activation energy of thermal assistance for a deep electron trap was estimated as (0.21 ± 0.02) eV. The TA-OSL dose response is sublinear from 10–250 Gy and saturates thereafter. The PTTL and TA-OSL analyses signify that the concentration of deep traps in α-Al2O3:C,Mg increased after annealing at 1200 °C. As a result, the sample produced better PTTL and TA-OSL response than when annealed at lower temperature.
- Full Text: false
- Date Issued: 2018
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105422 , vital:32511 , https://doi.org/10.1016/j.jlumin.2018.08.085
- Description: We report phototransferred thermoluminescence (PTTL) and thermally-assisted optically stimulated luminescence (TA-OSL) of α-Al2O3:C,Mg annealed at 1200 °C. PTTL is TL measured from an irradiated phosphor after its exposure to light. The other theme of this study, TA-OSL is the additional amount of luminescence optically stimulated from a sample over and above the amount that would be measured at room temperature. A sample irradiated to 10 Gy and preheated to 230 °C at 1 °C/s followed by illumination by 470 nm blue light produced four PTTL peaks at 53, 80, 102 and 173 °C. The PTTL peaks occur at the same positions as the corresponding conventional TL peaks. Their kinetic parameters are also similar. The intensity of the PTTL peaks increased with duration of illumination to a maximum within 200 s for doses between 1 Gy and 10 Gy. The dose response of each of the PTTL peaks at 80, 102 and 173 °C is linear within 1–15 Gy. The rate of fading is low and the peaks are reproducible. When the irradiated sample is optically stimulated at temperatures between 30 °C and 300 °C, after preheating to 500 °C, the intensity of its TA-OSL goes through a peak with temperature at 200 °C. Using the rising edge of the plot, activation energy of thermal assistance for a deep electron trap was estimated as (0.21 ± 0.02) eV. The TA-OSL dose response is sublinear from 10–250 Gy and saturates thereafter. The PTTL and TA-OSL analyses signify that the concentration of deep traps in α-Al2O3:C,Mg increased after annealing at 1200 °C. As a result, the sample produced better PTTL and TA-OSL response than when annealed at lower temperature.
- Full Text: false
- Date Issued: 2018
Effect of bromination on the optical limiting properties at 532 nm of BODIPY dyes with p-benzyloxystyryl groups at the 3, 5-positions
- Ngoy, Bokolombe P, May, Aviwe K, Mack, John, Nyokong, Tebello
- Authors: Ngoy, Bokolombe P , May, Aviwe K , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187507 , vital:44665 , xlink:href="https://doi.org/10.1016/j.molstruc.2018.08.012"
- Description: The optical limiting (OL) properties of 3,5-di-p-benzyloxystyrylBODIPY dyes that contain both protons and bromine atoms at the 2,6-positions have been investigated by using the Z-scan technique at 532 nm on the nanosecond timescale. There is relatively weak absorbance at 532 nm under ambient light conditions, because the incorporation of p-benzyloxystyryl groups at the 3,5-positions results in a ca. 140 nm red shift of the main BODIPY spectral band to the 640–670 nm range. Reverse saturable absorbance (RSA) profiles that are consistent with an excited state absorption (ESA) mechanism involving the T1 and/or S1 states are observed in CH2Cl2 solution. Second order hyperpolarizability values of ca. 8 × 10−30 esu are obtained and this demonstrates that the dyes are potentially suitable for use in OL applications at 532 nm. There is a slight enhancement of the OL properties upon bromination, due to increased intersystem crossing to the triplet manifold, but the enhancement of the OL properties is less significant than has been observed with metal phthalocyanine complexes.
- Full Text:
- Date Issued: 2019
- Authors: Ngoy, Bokolombe P , May, Aviwe K , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187507 , vital:44665 , xlink:href="https://doi.org/10.1016/j.molstruc.2018.08.012"
- Description: The optical limiting (OL) properties of 3,5-di-p-benzyloxystyrylBODIPY dyes that contain both protons and bromine atoms at the 2,6-positions have been investigated by using the Z-scan technique at 532 nm on the nanosecond timescale. There is relatively weak absorbance at 532 nm under ambient light conditions, because the incorporation of p-benzyloxystyryl groups at the 3,5-positions results in a ca. 140 nm red shift of the main BODIPY spectral band to the 640–670 nm range. Reverse saturable absorbance (RSA) profiles that are consistent with an excited state absorption (ESA) mechanism involving the T1 and/or S1 states are observed in CH2Cl2 solution. Second order hyperpolarizability values of ca. 8 × 10−30 esu are obtained and this demonstrates that the dyes are potentially suitable for use in OL applications at 532 nm. There is a slight enhancement of the OL properties upon bromination, due to increased intersystem crossing to the triplet manifold, but the enhancement of the OL properties is less significant than has been observed with metal phthalocyanine complexes.
- Full Text:
- Date Issued: 2019
Incentive effects: assessing effort and heterogeneity in professional tennis
- Authors: Chadwick, Byron James Rhett
- Date: 2019
- Subjects: Professional sports -- Economic aspects , Tennis players -- Wages , Tennis -- Tournaments , Achievement motivation , Incentive awards
- Language: English
- Type: text , Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/69467 , vital:29541
- Description: This study explores the impact incentive effects have on the level of effort exerted by professional men and women tennis players. Understanding what impact incentives have on tennis players can allow for greater understanding of the impact incentives have in the workplace and how employees react to different incentive schemes. The study makes use of data from both the ATP and WTA tour of every tournament played during the 2016 season. This includes player statistics, tournament statistics and in-game statistics from the quarter-finals, semi-finals and finals of each tournament in an attempt to account for initial seeding effects. This provides a total of 440 ATP matches and 389 WTA matches for an overall sample size of 829 professional tennis matches. The findings from this study illustrate in the last three rounds of all the tournaments played, for both male and females, money is not considered to be a key motivator for players. The ATP and WTA results suggest that competitors do not alter their effort levels depending on the level of the tournament. This illustrates that players exert similar effort levels regardless of the amount of money or ranking points available. The outcome of the findings supports that of the capability effect of heterogeneity on players’ performance. This means that the outcome of a match is linked more to the abilities of the competitors involved as opposed to the incentives available. Thus, players will adjust their effort levels according to their opponent and not because there are more money or ranking points available. This suggests that both the ATP and WTA should aim to reduce the differences in abilities amongst the players in an attempt to raise the attractiveness of the sport. Overall, the findings from this study illustrate that the capability effect outweighs that of the incentive effect.
- Full Text:
- Date Issued: 2019
- Authors: Chadwick, Byron James Rhett
- Date: 2019
- Subjects: Professional sports -- Economic aspects , Tennis players -- Wages , Tennis -- Tournaments , Achievement motivation , Incentive awards
- Language: English
- Type: text , Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/69467 , vital:29541
- Description: This study explores the impact incentive effects have on the level of effort exerted by professional men and women tennis players. Understanding what impact incentives have on tennis players can allow for greater understanding of the impact incentives have in the workplace and how employees react to different incentive schemes. The study makes use of data from both the ATP and WTA tour of every tournament played during the 2016 season. This includes player statistics, tournament statistics and in-game statistics from the quarter-finals, semi-finals and finals of each tournament in an attempt to account for initial seeding effects. This provides a total of 440 ATP matches and 389 WTA matches for an overall sample size of 829 professional tennis matches. The findings from this study illustrate in the last three rounds of all the tournaments played, for both male and females, money is not considered to be a key motivator for players. The ATP and WTA results suggest that competitors do not alter their effort levels depending on the level of the tournament. This illustrates that players exert similar effort levels regardless of the amount of money or ranking points available. The outcome of the findings supports that of the capability effect of heterogeneity on players’ performance. This means that the outcome of a match is linked more to the abilities of the competitors involved as opposed to the incentives available. Thus, players will adjust their effort levels according to their opponent and not because there are more money or ranking points available. This suggests that both the ATP and WTA should aim to reduce the differences in abilities amongst the players in an attempt to raise the attractiveness of the sport. Overall, the findings from this study illustrate that the capability effect outweighs that of the incentive effect.
- Full Text:
- Date Issued: 2019
Perspectives on land and water politics at Mushandike Irrigation Scheme, Masvingo, Zimbabwe
- Authors: Mafukidze, Jonathan
- Date: 2019
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/76479 , vital:30573
- Description: Access to, control and ownership of land and water, amongst other natural resources in Zimbabwe, shape and affect rural lives, livelihoods, social relations and social organisation. Rural poverty has been entrenched and exacerbated by, amongst other factors, highly restricted access to these scarce resources. Historically, Zimbabwe’s rural areas (such as communal areas, smallholder irrigation schemes and resettlement areas) have existed as sites of struggles where contestations and negotiations over access to, control or ownership of these resources have taken place. Resultantly, multifaceted and dynamic social relations have been weaved and contested social spaces carved out. In rural Zimbabwe, contestations have tended to be complex, nuanced and intricate, working themselves out in different ways across time and space. In their heightened and more visible state, they have been characterised by violent physical expressions which, in the history of the country, involved two wars of liberation, the First Chimurenga (1896-1897) and the Second Chimurenga (1960s to 1980). The most recent violent manifestation was through nation-wide land invasions, politically christened the Third Chimurenga, which peaked in 2000 and continued sporadically to this day. Few studies on smallholder irrigation schemes in Zimbabwe have focused on understanding how contestations for access to scarce land and water resources are framed and negotiated at the local level. Cognisant of this lacuna, this thesis uses social constructionism in examining, as a case study, Mushandike Smallholder Irrigation Scheme in Masvingo Province in order to understand and analyse how land and water politics occur at the local level. The study deploys a qualitative research methodology approach in examining local water and land politics, which involved original irrigation beneficiaries and more recent land invaders. Findings of the thesis indicate that land and water shortages have increased considerably in the past two decades at the irrigation scheme due to the influx of land invaders into the scheme. This influx has had a negative impact on agricultural production and other livelihood strategies. Both scheme members and land invaders lay claim to land and water at Mushandike. These claims are intricately constructed and contested, and they are linked to broader issues such as partisan party-politics, policy developments, and tradition, origin, indigeneity and belonging. Though the struggles over land and water at Mushandike are firmly rooted in the concrete conditions of existence and experiences of beneficiaries and land invaders, external actors such as political leaders, state bureaucrats and traditional chiefs tend to complicate and intensify the contestations.
- Full Text:
- Date Issued: 2019
- Authors: Mafukidze, Jonathan
- Date: 2019
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/76479 , vital:30573
- Description: Access to, control and ownership of land and water, amongst other natural resources in Zimbabwe, shape and affect rural lives, livelihoods, social relations and social organisation. Rural poverty has been entrenched and exacerbated by, amongst other factors, highly restricted access to these scarce resources. Historically, Zimbabwe’s rural areas (such as communal areas, smallholder irrigation schemes and resettlement areas) have existed as sites of struggles where contestations and negotiations over access to, control or ownership of these resources have taken place. Resultantly, multifaceted and dynamic social relations have been weaved and contested social spaces carved out. In rural Zimbabwe, contestations have tended to be complex, nuanced and intricate, working themselves out in different ways across time and space. In their heightened and more visible state, they have been characterised by violent physical expressions which, in the history of the country, involved two wars of liberation, the First Chimurenga (1896-1897) and the Second Chimurenga (1960s to 1980). The most recent violent manifestation was through nation-wide land invasions, politically christened the Third Chimurenga, which peaked in 2000 and continued sporadically to this day. Few studies on smallholder irrigation schemes in Zimbabwe have focused on understanding how contestations for access to scarce land and water resources are framed and negotiated at the local level. Cognisant of this lacuna, this thesis uses social constructionism in examining, as a case study, Mushandike Smallholder Irrigation Scheme in Masvingo Province in order to understand and analyse how land and water politics occur at the local level. The study deploys a qualitative research methodology approach in examining local water and land politics, which involved original irrigation beneficiaries and more recent land invaders. Findings of the thesis indicate that land and water shortages have increased considerably in the past two decades at the irrigation scheme due to the influx of land invaders into the scheme. This influx has had a negative impact on agricultural production and other livelihood strategies. Both scheme members and land invaders lay claim to land and water at Mushandike. These claims are intricately constructed and contested, and they are linked to broader issues such as partisan party-politics, policy developments, and tradition, origin, indigeneity and belonging. Though the struggles over land and water at Mushandike are firmly rooted in the concrete conditions of existence and experiences of beneficiaries and land invaders, external actors such as political leaders, state bureaucrats and traditional chiefs tend to complicate and intensify the contestations.
- Full Text:
- Date Issued: 2019
Intersectionality and complexity in the representation of ‘queer’ sexualities and genders in African women’s short fiction
- Authors: Du Preez, Jenny Boźena
- Date: 2019
- Subjects: Sexual minority culture , Sexual minorities' writings , African fiction -- Women authors -- History and criticism , Gender identity in literature , Short stories, South African , Feminism in literature , Political poetry , Eroticism in literature , Lesbianism in literature
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/119047 , vital:34697
- Description: This thesis sets out to contribute to the growing body of knowledge about queer sexualities and genders in Africa by examining their depiction in selected post-2000 African women’s short fiction written in English. Post-2000, the short story form has become the primary vehicle for queer representations by African women writers, and is thus an important development in the burgeoning body of queer literature by African writers. Broadly speaking, this literary formation can be defined as anti-homophobic, feminist and politically pragmatic. Using an intersectional lens, this thesis sets out to examine four significant strands in the political work these stories engage in. The chapters are structured around four main points of contention that have particular significance at the intersection of ‘queer’, ‘women’ and ‘Africa’. Firstly, I examine South African short stories that perform what I call queer conversations with history: imaginatively asserting a queer South African history, writing back against a male-dominated and heterosexist literary canon and, in doing so, contributing to the reimagination of the contemporary South African nation. Secondly, I analyse short stories from Africa that foreground the family, both as social formation and ideology. I examine how these stories ‘fracture’ this powerful and naturalised heterosexist concept by depicting the tensions and contradictions that queer characters experience in relation to family. Thirdly, I consider short stories from various African contexts that work to reconceptualise queer sexuality in relation to religious discourse in order to challenge homophobic and patriarchal religious authority. Finally, I examine queer, feminist erotic short stories by African women writers that challenges various colonialist, racist, sexist and lesbophobic discourses that have historically stifled the portrayal of sex and erotic experience between women.
- Full Text:
- Date Issued: 2019
- Authors: Du Preez, Jenny Boźena
- Date: 2019
- Subjects: Sexual minority culture , Sexual minorities' writings , African fiction -- Women authors -- History and criticism , Gender identity in literature , Short stories, South African , Feminism in literature , Political poetry , Eroticism in literature , Lesbianism in literature
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/119047 , vital:34697
- Description: This thesis sets out to contribute to the growing body of knowledge about queer sexualities and genders in Africa by examining their depiction in selected post-2000 African women’s short fiction written in English. Post-2000, the short story form has become the primary vehicle for queer representations by African women writers, and is thus an important development in the burgeoning body of queer literature by African writers. Broadly speaking, this literary formation can be defined as anti-homophobic, feminist and politically pragmatic. Using an intersectional lens, this thesis sets out to examine four significant strands in the political work these stories engage in. The chapters are structured around four main points of contention that have particular significance at the intersection of ‘queer’, ‘women’ and ‘Africa’. Firstly, I examine South African short stories that perform what I call queer conversations with history: imaginatively asserting a queer South African history, writing back against a male-dominated and heterosexist literary canon and, in doing so, contributing to the reimagination of the contemporary South African nation. Secondly, I analyse short stories from Africa that foreground the family, both as social formation and ideology. I examine how these stories ‘fracture’ this powerful and naturalised heterosexist concept by depicting the tensions and contradictions that queer characters experience in relation to family. Thirdly, I consider short stories from various African contexts that work to reconceptualise queer sexuality in relation to religious discourse in order to challenge homophobic and patriarchal religious authority. Finally, I examine queer, feminist erotic short stories by African women writers that challenges various colonialist, racist, sexist and lesbophobic discourses that have historically stifled the portrayal of sex and erotic experience between women.
- Full Text:
- Date Issued: 2019
Discorhabdin N, a South African Natural Compound, for Hsp72 and Hsc70 Allosteric Modulation: combined study of molecular modeling and dynamic residue network analysis
- Amusengeri, Arnold, Tastan Bishop, Özlem
- Authors: Amusengeri, Arnold , Tastan Bishop, Özlem
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/162949 , vital:40999 , https://doi.org/10.3390/molecules24010188
- Description: The human heat shock proteins (Hsps), predominantly Hsp72 and Hsp90, have been strongly implicated in various critical stages of oncogenesis and progression of human cancers. While drug development has extensively focused on Hsp90 as a potential anticancer target, much less effort has been put against Hsp72. This work investigated the therapeutic potential of Hsp72 and its constitutive isoform, Hsc70, via in silico-based screening against the South African Natural Compounds Database (SANCDB). A comparative modeling approach was used to obtain nearly full-length 3D structures of the closed conformation of Hsp72 and Hsc70 proteins. Molecular docking of SANCDB compounds identified one potential allosteric modulator, Discorhabdin N, binding to the allosteric β substrate binding domain (SBDβ) back pocket, with good binding affinities in both cases.
- Full Text:
- Date Issued: 2019
- Authors: Amusengeri, Arnold , Tastan Bishop, Özlem
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/162949 , vital:40999 , https://doi.org/10.3390/molecules24010188
- Description: The human heat shock proteins (Hsps), predominantly Hsp72 and Hsp90, have been strongly implicated in various critical stages of oncogenesis and progression of human cancers. While drug development has extensively focused on Hsp90 as a potential anticancer target, much less effort has been put against Hsp72. This work investigated the therapeutic potential of Hsp72 and its constitutive isoform, Hsc70, via in silico-based screening against the South African Natural Compounds Database (SANCDB). A comparative modeling approach was used to obtain nearly full-length 3D structures of the closed conformation of Hsp72 and Hsc70 proteins. Molecular docking of SANCDB compounds identified one potential allosteric modulator, Discorhabdin N, binding to the allosteric β substrate binding domain (SBDβ) back pocket, with good binding affinities in both cases.
- Full Text:
- Date Issued: 2019
Synthesis and photophysicochemical properties of novel axially di-substituted silicon (IV) phthalocyanines and their photodynamic antimicrobial chemotherapy (PACT) activity against Staphylococcus aureus
- Sen, Pinar, Sindelo, Azole, Mafukidze, Donovan M, Nyokong, Tebello
- Authors: Sen, Pinar , Sindelo, Azole , Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186757 , vital:44531 , xlink:href="https://doi.org/10.1016/j.synthmet.2019.116203"
- Description: In this study, novel silicon (IV) phthalocyanine axially di-substituted with benzimidazole moieties (3) and its quaternized derivative (4) have been synthesized and fully characterized. The photophysical and photochemical properties of both phthalocyanines such as absorption, fluorescence and, singlet oxygen quantum yields, triplet state quantum yields and exited state lifetimes were investigated in solutions. These new silicon phthalocyanines exhibited low fluorescence but produced high singlet oxygen yields in both DMSO (compound 3 and 4) and aqueous media (compound 4). The quaternization of Si(IV)Pc (3) improved the triplet state quantum yield (ΦT) 0.61 to 0.83, consequently singlet oxygen generation (ΦΔ) increased to 0.69 from 0.42. Photodynamic antimicrobial chemotherapy activities (PACT) of Si(IV)Pc photosensitizers were determined towards Staphylococcus aureus. The higher efficiency was obtained with cationic derivative (4) giving reduction percentage value of 99.75%.
- Full Text:
- Date Issued: 2019
- Authors: Sen, Pinar , Sindelo, Azole , Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186757 , vital:44531 , xlink:href="https://doi.org/10.1016/j.synthmet.2019.116203"
- Description: In this study, novel silicon (IV) phthalocyanine axially di-substituted with benzimidazole moieties (3) and its quaternized derivative (4) have been synthesized and fully characterized. The photophysical and photochemical properties of both phthalocyanines such as absorption, fluorescence and, singlet oxygen quantum yields, triplet state quantum yields and exited state lifetimes were investigated in solutions. These new silicon phthalocyanines exhibited low fluorescence but produced high singlet oxygen yields in both DMSO (compound 3 and 4) and aqueous media (compound 4). The quaternization of Si(IV)Pc (3) improved the triplet state quantum yield (ΦT) 0.61 to 0.83, consequently singlet oxygen generation (ΦΔ) increased to 0.69 from 0.42. Photodynamic antimicrobial chemotherapy activities (PACT) of Si(IV)Pc photosensitizers were determined towards Staphylococcus aureus. The higher efficiency was obtained with cationic derivative (4) giving reduction percentage value of 99.75%.
- Full Text:
- Date Issued: 2019
Teachers’ engagement with learners in inclusive foundation phase classrooms: a case study analysis
- Authors: Skae, Vera Astrid
- Date: 2019
- Subjects: Early childhood education -- South Africa -- Eastern Cape -- Case studies , Education and state -- South Africa
- Language: English
- Type: text , Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10962/92705 , vital:30722
- Description: Since 2001, South African teachers have been attempting to practise inclusive education in classrooms in ordinary, public schools. Previous research has shown the many challenges South African teachers face in our current educational environment. Strong arguments, however, have been made for more research to be done on actual teacher engagement with learners in our ordinary, public school classrooms, and the extent to which classroom practices are inclusive (Engelbrecht, Nel, Nel & Tlale, 2015, p. 3). This study sought to do an in-depth critical analysis of three foundation phase teachers and their engagement with learners in their classrooms at an Eastern Cape school. The aim was to examine how inclusive education was being enacted by the teacher with learners in real classroom settings, with particular attention paid to ways in which learners experience barriers to learning. A micro-level analysis was conducted in a single unit case study and using a qualitative research approach in an interpretive paradigm. Questionnaires, observations, and semi-structured interviews were conducted in an attempt to gather in-depth data. It was heartening to observe the extent to which inclusive education and practices were being enacted at the school and in the classrooms, and instructive in providing examples of what can work in the South African context. Key findings of this study include the generation of a framework for analysing inclusive classroom practice at the micro level. Criteria were identified as indicators of inclusive education of learners including those experiencing barriers to learning in the classroom. This study builds on and extends what has been developed at the macro and micro level of inclusive education in schools and in the classroom. It found that a number of challenges remain for enabling the implementation of an inclusive education. At the macro level, these include the provision of clear directives for implementation of inclusive education by the appropriate authorities; the provision of well-structured professional teacher training and development programmes in inclusive classroom practices, as well as in barriers to learning and how to address them; and the provision of funding for school and classroom infrastructure and resources. At the micro level, these include the successful implementation by teachers of inclusive classroom practices and the provision of the necessary support for learners experiencing barriers to learning in their classrooms, including expert personnel, resources, and assistive devices.
- Full Text:
- Date Issued: 2019
- Authors: Skae, Vera Astrid
- Date: 2019
- Subjects: Early childhood education -- South Africa -- Eastern Cape -- Case studies , Education and state -- South Africa
- Language: English
- Type: text , Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10962/92705 , vital:30722
- Description: Since 2001, South African teachers have been attempting to practise inclusive education in classrooms in ordinary, public schools. Previous research has shown the many challenges South African teachers face in our current educational environment. Strong arguments, however, have been made for more research to be done on actual teacher engagement with learners in our ordinary, public school classrooms, and the extent to which classroom practices are inclusive (Engelbrecht, Nel, Nel & Tlale, 2015, p. 3). This study sought to do an in-depth critical analysis of three foundation phase teachers and their engagement with learners in their classrooms at an Eastern Cape school. The aim was to examine how inclusive education was being enacted by the teacher with learners in real classroom settings, with particular attention paid to ways in which learners experience barriers to learning. A micro-level analysis was conducted in a single unit case study and using a qualitative research approach in an interpretive paradigm. Questionnaires, observations, and semi-structured interviews were conducted in an attempt to gather in-depth data. It was heartening to observe the extent to which inclusive education and practices were being enacted at the school and in the classrooms, and instructive in providing examples of what can work in the South African context. Key findings of this study include the generation of a framework for analysing inclusive classroom practice at the micro level. Criteria were identified as indicators of inclusive education of learners including those experiencing barriers to learning in the classroom. This study builds on and extends what has been developed at the macro and micro level of inclusive education in schools and in the classroom. It found that a number of challenges remain for enabling the implementation of an inclusive education. At the macro level, these include the provision of clear directives for implementation of inclusive education by the appropriate authorities; the provision of well-structured professional teacher training and development programmes in inclusive classroom practices, as well as in barriers to learning and how to address them; and the provision of funding for school and classroom infrastructure and resources. At the micro level, these include the successful implementation by teachers of inclusive classroom practices and the provision of the necessary support for learners experiencing barriers to learning in their classrooms, including expert personnel, resources, and assistive devices.
- Full Text:
- Date Issued: 2019
Optical limiting and femtosecond pump-probe transient absorbance properties of a 3, 5-distyrylBODIPY dye
- Ngoy, Bokolombe P, May, Aviwe K, Mack, John, Nyokong, Tebello
- Authors: Ngoy, Bokolombe P , May, Aviwe K , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186835 , vital:44538 , xlink:href="https://doi.org/10.3389/fchem.2019.00740"
- Description: The optical limiting (OL) properties of a 3,5-di-p-benzyloxystyrylBODIPY dye with an p-acetamidophenyl moiety at the meso-position have been investigated by using the open-aperture Z-scan technique at 532 nm with 10 ns laser pulses. There is a ca. 140 nm red shift of the main spectral band to 644 nm relative to the corresponding BODIPY core dye, due to the incorporation of p-benzyloxystyryl groups at the 3,5-positions. As a result, there is relatively weak absorbance across most of the visible region under ambient light conditions. Analysis of the observed reverse saturable absorbance (RSA) profiles demonstrates that the dye is potentially suitable for use in optical limiting applications as has been reported previously for other 3,5-distyrylBODIPY dyes. Time-resolved transient absorption spectroscopy and kinetic studies with femtosecond and nanosecond scale laser pulses provide the first direct spectral evidence that excited state absorption (ESA) from the S1 state is responsible for the observed OL properties.
- Full Text:
- Date Issued: 2019
- Authors: Ngoy, Bokolombe P , May, Aviwe K , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186835 , vital:44538 , xlink:href="https://doi.org/10.3389/fchem.2019.00740"
- Description: The optical limiting (OL) properties of a 3,5-di-p-benzyloxystyrylBODIPY dye with an p-acetamidophenyl moiety at the meso-position have been investigated by using the open-aperture Z-scan technique at 532 nm with 10 ns laser pulses. There is a ca. 140 nm red shift of the main spectral band to 644 nm relative to the corresponding BODIPY core dye, due to the incorporation of p-benzyloxystyryl groups at the 3,5-positions. As a result, there is relatively weak absorbance across most of the visible region under ambient light conditions. Analysis of the observed reverse saturable absorbance (RSA) profiles demonstrates that the dye is potentially suitable for use in optical limiting applications as has been reported previously for other 3,5-distyrylBODIPY dyes. Time-resolved transient absorption spectroscopy and kinetic studies with femtosecond and nanosecond scale laser pulses provide the first direct spectral evidence that excited state absorption (ESA) from the S1 state is responsible for the observed OL properties.
- Full Text:
- Date Issued: 2019
An analysis of the use of DNS for malicious payload distribution
- Authors: Dube, Ishmael
- Date: 2019
- Subjects: Internet domain names , Computer networks -- Security measures , Computer security , Computer network protocols , Data protection
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/97531 , vital:31447
- Description: The Domain Name System (DNS) protocol is a fundamental part of Internet activities that can be abused by cybercriminals to conduct malicious activities. Previous research has shown that cybercriminals use different methods, including the DNS protocol, to distribute malicious content, remain hidden and avoid detection from various technologies that are put in place to detect anomalies. This allows botnets and certain malware families to establish covert communication channels that can be used to send or receive data and also distribute malicious payloads using the DNS queries and responses. Cybercriminals use the DNS to breach highly protected networks, distribute malicious content, and exfiltrate sensitive information without being detected by security controls put in place by embedding certain strings in DNS packets. This research undertaking broadens this research field and fills in the existing research gap by extending the analysis of DNS being used as a payload distribution channel to detection of domains that are used to distribute different malicious payloads. This research undertaking analysed the use of the DNS in detecting domains and channels that are used for distributing malicious payloads. Passive DNS data which replicate DNS queries on name servers to detect anomalies in DNS queries was evaluated and analysed in order to detect malicious payloads. The research characterises the malicious payload distribution channels by analysing passive DNS traffic and modelling the DNS query and response patterns. The research found that it is possible to detect malicious payload distribution channels through the analysis of DNS TXT resource records.
- Full Text:
- Date Issued: 2019
- Authors: Dube, Ishmael
- Date: 2019
- Subjects: Internet domain names , Computer networks -- Security measures , Computer security , Computer network protocols , Data protection
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/97531 , vital:31447
- Description: The Domain Name System (DNS) protocol is a fundamental part of Internet activities that can be abused by cybercriminals to conduct malicious activities. Previous research has shown that cybercriminals use different methods, including the DNS protocol, to distribute malicious content, remain hidden and avoid detection from various technologies that are put in place to detect anomalies. This allows botnets and certain malware families to establish covert communication channels that can be used to send or receive data and also distribute malicious payloads using the DNS queries and responses. Cybercriminals use the DNS to breach highly protected networks, distribute malicious content, and exfiltrate sensitive information without being detected by security controls put in place by embedding certain strings in DNS packets. This research undertaking broadens this research field and fills in the existing research gap by extending the analysis of DNS being used as a payload distribution channel to detection of domains that are used to distribute different malicious payloads. This research undertaking analysed the use of the DNS in detecting domains and channels that are used for distributing malicious payloads. Passive DNS data which replicate DNS queries on name servers to detect anomalies in DNS queries was evaluated and analysed in order to detect malicious payloads. The research characterises the malicious payload distribution channels by analysing passive DNS traffic and modelling the DNS query and response patterns. The research found that it is possible to detect malicious payload distribution channels through the analysis of DNS TXT resource records.
- Full Text:
- Date Issued: 2019
The impact of elephants on thicket vegetation and other mammals in the Eastern Cape Province, South Africa
- Authors: Nuttall-Smith, Gareth David
- Date: 2019
- Subjects: Albany Thicket -- Effect of browsing on , Elephants -- South Africa -- Eastern Cape , African elephant populations -- South Africa -- Eastern Cape , Woody plants -- Effect of browsing on -- South Africa -- Eastern Cape , Animal-plant relationships -- South Africa -- Eastern Cape , Vegetation monitoring -- South Africa -- Eastern Cape , African elephant populations -- Environmental aspects -- South Africa -- Eastern Cape , Biotic communities -- South Africa -- Eastern Cape , African elephant -- Food , Vegetation dynamics -- South Africa -- Eastern Cape
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/76365 , vital:30554
- Description: African elephants (Loxodonta africana) were absent from large portions of the Eastern Cape Province of South Africa for more than 100 years following widespread hunting for ivory. However, recent shifts in land use practices have resulted in the establishment of many private game reserves throughout the region. Some of these reserves have reintroduced elephants, raising management concerns because of the perceived impact that elephants can have on vegetation and the animals that rely on it for resources. My thesis aimed to assess the role of elephants in determining the structure and complexity of the locally important Thicket Biome and how medium and large mammals are affected. I quantified the woody and succulent components of Albany Thicket across nine reserves with elephants between May 2016 and November 2017 using a modified Point-Centre-Quarter method. Camera traps were deployed at each site for the duration of a calendar year to measure the relative abundances of all medium and large mammals at the sites. Across all study sites, climatic conditions (specifically rainfall and temperature) were the primary drivers of woody vegetation structure and diversity. Elephants appeared to have little influence since they were reintroduced at low densities 20 years ago. The associated mammal communities were mostly influenced by the height and basal area coverage of the thicket across the sites. I conclude that because elephant populations have been maintained at relatively low densities across my study sites, negative effects on the thicket vegetation and the associated mammal communities were not observed. In fact, the establishment of private game reserves, even with elephants, present may offer sustainable conservation for the threatened Albany Thicket. However, these elephant populations are still relatively new and changes to the vegetation are likely to be cumulative. Thus, future research should focus on how the vegetation is affected over time. To this end, I recommend the establishment of permanent sampling stations across all reserves with elephants in the Eastern Cape Province.
- Full Text:
- Date Issued: 2019
- Authors: Nuttall-Smith, Gareth David
- Date: 2019
- Subjects: Albany Thicket -- Effect of browsing on , Elephants -- South Africa -- Eastern Cape , African elephant populations -- South Africa -- Eastern Cape , Woody plants -- Effect of browsing on -- South Africa -- Eastern Cape , Animal-plant relationships -- South Africa -- Eastern Cape , Vegetation monitoring -- South Africa -- Eastern Cape , African elephant populations -- Environmental aspects -- South Africa -- Eastern Cape , Biotic communities -- South Africa -- Eastern Cape , African elephant -- Food , Vegetation dynamics -- South Africa -- Eastern Cape
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/76365 , vital:30554
- Description: African elephants (Loxodonta africana) were absent from large portions of the Eastern Cape Province of South Africa for more than 100 years following widespread hunting for ivory. However, recent shifts in land use practices have resulted in the establishment of many private game reserves throughout the region. Some of these reserves have reintroduced elephants, raising management concerns because of the perceived impact that elephants can have on vegetation and the animals that rely on it for resources. My thesis aimed to assess the role of elephants in determining the structure and complexity of the locally important Thicket Biome and how medium and large mammals are affected. I quantified the woody and succulent components of Albany Thicket across nine reserves with elephants between May 2016 and November 2017 using a modified Point-Centre-Quarter method. Camera traps were deployed at each site for the duration of a calendar year to measure the relative abundances of all medium and large mammals at the sites. Across all study sites, climatic conditions (specifically rainfall and temperature) were the primary drivers of woody vegetation structure and diversity. Elephants appeared to have little influence since they were reintroduced at low densities 20 years ago. The associated mammal communities were mostly influenced by the height and basal area coverage of the thicket across the sites. I conclude that because elephant populations have been maintained at relatively low densities across my study sites, negative effects on the thicket vegetation and the associated mammal communities were not observed. In fact, the establishment of private game reserves, even with elephants, present may offer sustainable conservation for the threatened Albany Thicket. However, these elephant populations are still relatively new and changes to the vegetation are likely to be cumulative. Thus, future research should focus on how the vegetation is affected over time. To this end, I recommend the establishment of permanent sampling stations across all reserves with elephants in the Eastern Cape Province.
- Full Text:
- Date Issued: 2019
Reproductive isolation mechanisms of two cryptic species of Eccritotarsus (Hemiptera: Miridae), biological control agents of water hyacinth, Eichhornia crassipes (Martius) Solms-Laubach (Pontederiaceae)
- Authors: Mnguni, Sandiso
- Date: 2019
- Subjects: Eccritotarsus , Meridae , Noxious weeds -- Biological control -- South Africa , Aquatic weeds -- Biological control -- South Africa , Water hyacinth -- Biological control -- South Africa , Biological pest control agents
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/68133 , vital:29202
- Description: Water hyacinth, Eichhornia crassipes (Martius) Solms-Laubach (Pontederiaceae), is one of the world’s worst alien invasive plants. It is indigenous to the Amazon basin in South America but has become a problematic alien invasive in other parts of the world. As such, several host-specific biological control agents have been sourced from the native distributions in South America and have been released to control this plant where it has become problematic. Two of these agents include the geographically and reproductively isolated cryptic species of Eccritotarsus (Hemiptera: Miridae). One of these species was collected in the upper reaches of the Amazon River in Peru, while the other was collected over 3500km away from that site, in Florianopolis, southern Brazil. These cryptic species were thought to be a single species until recently, when DNA barcoding indicated that they were likely to be two species, and the species status has now been confirmed by interbreeding experiments and detailed morphological studies. The Brazilian population remains Eccritotarsus catarinensis (Carvalho), while the Peruvian population is now known as Eccritotarsus eichhorniae (Henry). The aim of this project was to investigate the mating behaviour and other behavioural traits of the two species that have resulted in reproductive isolation, and which could have led to speciation. In addition, investigations involving analysis of chemical compound compositions of the two species aimed to determine the extent to which the compounds played a role in the development and maintenance of reproductive isolation. To achieve the aims, behavioural-observation experiments were conducted in the form of no-choice, bi-choice and multi-choice tests in 1:1, 2:1 and 3:1 sex ratio assessments, both within and between species. Chemical compound compositions of E. catarinensis and E. eichhorniae were also assessed using Nuclear Magnetic Resonance (NMR), Solid-phase micro-extraction (SPME) and Gas-Chromatography Mass-Spectrometry (GC-MS) techniques. In no-choice experiments, the highest number of single and multiple copula incidences, and average total copula duration was found within species while copulation between species was much rarer. In bi-choice experiments, E. eichhorniae females and E. catarinensis males only chose to mate with their respective conspecifics, and within species copulations continued to have higher average total copula duration. In multi-choice experiments, the highest number of single and multiple copula incidences and average total copula duration was also found within species. GC-MS analysis suggested that E. catarinensis females and E. eichhorniae males have unique chemical compounds missing in their conspecifics and same sex of the other species. Further analysis suggested that E. catarinensis females and E. eichhorniae males have similar chemical compound compositions, whereas as E. eichhorniae females and E. catarinensis males have similar chemical compound compositions. These results suggest that there are behavioural differences that led to the development and maintenance of prezygotic reproductive isolation mechanisms, and that this is probably driven by pheromones in chemical compound compositions. These two species were geographically isolated in the native range and the populations have diverged to the point that they are now reproductively incompatible and therefore, distinct species. The main driver of the speciation is most likely mate recognition and attraction, as only reproductively important traits such as pheromones, genitalia, the scent glands and antennae have changed, while other traits, including host range and morphology, have remained remarkably stable. This provides evidence that differences in sexual selection in isolated populations may be important drivers of speciation and reproductive isolation in cryptic species.
- Full Text:
- Date Issued: 2019
- Authors: Mnguni, Sandiso
- Date: 2019
- Subjects: Eccritotarsus , Meridae , Noxious weeds -- Biological control -- South Africa , Aquatic weeds -- Biological control -- South Africa , Water hyacinth -- Biological control -- South Africa , Biological pest control agents
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/68133 , vital:29202
- Description: Water hyacinth, Eichhornia crassipes (Martius) Solms-Laubach (Pontederiaceae), is one of the world’s worst alien invasive plants. It is indigenous to the Amazon basin in South America but has become a problematic alien invasive in other parts of the world. As such, several host-specific biological control agents have been sourced from the native distributions in South America and have been released to control this plant where it has become problematic. Two of these agents include the geographically and reproductively isolated cryptic species of Eccritotarsus (Hemiptera: Miridae). One of these species was collected in the upper reaches of the Amazon River in Peru, while the other was collected over 3500km away from that site, in Florianopolis, southern Brazil. These cryptic species were thought to be a single species until recently, when DNA barcoding indicated that they were likely to be two species, and the species status has now been confirmed by interbreeding experiments and detailed morphological studies. The Brazilian population remains Eccritotarsus catarinensis (Carvalho), while the Peruvian population is now known as Eccritotarsus eichhorniae (Henry). The aim of this project was to investigate the mating behaviour and other behavioural traits of the two species that have resulted in reproductive isolation, and which could have led to speciation. In addition, investigations involving analysis of chemical compound compositions of the two species aimed to determine the extent to which the compounds played a role in the development and maintenance of reproductive isolation. To achieve the aims, behavioural-observation experiments were conducted in the form of no-choice, bi-choice and multi-choice tests in 1:1, 2:1 and 3:1 sex ratio assessments, both within and between species. Chemical compound compositions of E. catarinensis and E. eichhorniae were also assessed using Nuclear Magnetic Resonance (NMR), Solid-phase micro-extraction (SPME) and Gas-Chromatography Mass-Spectrometry (GC-MS) techniques. In no-choice experiments, the highest number of single and multiple copula incidences, and average total copula duration was found within species while copulation between species was much rarer. In bi-choice experiments, E. eichhorniae females and E. catarinensis males only chose to mate with their respective conspecifics, and within species copulations continued to have higher average total copula duration. In multi-choice experiments, the highest number of single and multiple copula incidences and average total copula duration was also found within species. GC-MS analysis suggested that E. catarinensis females and E. eichhorniae males have unique chemical compounds missing in their conspecifics and same sex of the other species. Further analysis suggested that E. catarinensis females and E. eichhorniae males have similar chemical compound compositions, whereas as E. eichhorniae females and E. catarinensis males have similar chemical compound compositions. These results suggest that there are behavioural differences that led to the development and maintenance of prezygotic reproductive isolation mechanisms, and that this is probably driven by pheromones in chemical compound compositions. These two species were geographically isolated in the native range and the populations have diverged to the point that they are now reproductively incompatible and therefore, distinct species. The main driver of the speciation is most likely mate recognition and attraction, as only reproductively important traits such as pheromones, genitalia, the scent glands and antennae have changed, while other traits, including host range and morphology, have remained remarkably stable. This provides evidence that differences in sexual selection in isolated populations may be important drivers of speciation and reproductive isolation in cryptic species.
- Full Text:
- Date Issued: 2019
Pushing against ‘China-Africa’ slowly, and with small stories:
- Authors: Simbao, Ruth K
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146778 , vital:38556 , http://www.somethingweafricansgot.com/about-1
- Description: the new focus on african arts and critical thought.
- Full Text:
- Date Issued: 2019
- Authors: Simbao, Ruth K
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/146778 , vital:38556 , http://www.somethingweafricansgot.com/about-1
- Description: the new focus on african arts and critical thought.
- Full Text:
- Date Issued: 2019