Photodynamic inactivation of Staphylococcus aureus using low symmetrically substituted phthalocyanines supported on a polystyrene polymer fiber
- Masilela, Nkosiphile, Kleyi, Phumelele, Tshentu, Zenixole R, Priniotakis, Georgios, Westbroek, Philippe, Nyokong, Tebello
- Authors: Masilela, Nkosiphile , Kleyi, Phumelele , Tshentu, Zenixole R , Priniotakis, Georgios , Westbroek, Philippe , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7330 , http://hdl.handle.net/10962/d1020591
- Description: This work reports on the antimicrobial photo-activities of a series of low symmetrically substituted phthalocyanine complexes in solution and in a fiber matrix. Phthalocyanine complexes were successfully electrospun into a polystyrene polymer. The fiber diameter ranged from 240 nm to 390 nm in average. The modified polymer fiber showed successful singlet oxygen production with the Ge monocarboxy phthalocyanine modified fiber giving the highest singlet oxygen quantum yield value of 0.46 due to lack of aggregation when in the polymer. All the unsymmetrically substituted complexes showed antimicrobial activity towards S. Aureus under illumination with visible light. The symmetrical ZnPc and ZnTPCPc showed no activity under illumination with light in the fiber matrix due to low singlet oxygen production. , Original publication is available at http://dx.doi.org/10.1016/j.dyepig.2012.10.001
- Full Text: false
- Authors: Masilela, Nkosiphile , Kleyi, Phumelele , Tshentu, Zenixole R , Priniotakis, Georgios , Westbroek, Philippe , Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7330 , http://hdl.handle.net/10962/d1020591
- Description: This work reports on the antimicrobial photo-activities of a series of low symmetrically substituted phthalocyanine complexes in solution and in a fiber matrix. Phthalocyanine complexes were successfully electrospun into a polystyrene polymer. The fiber diameter ranged from 240 nm to 390 nm in average. The modified polymer fiber showed successful singlet oxygen production with the Ge monocarboxy phthalocyanine modified fiber giving the highest singlet oxygen quantum yield value of 0.46 due to lack of aggregation when in the polymer. All the unsymmetrically substituted complexes showed antimicrobial activity towards S. Aureus under illumination with visible light. The symmetrical ZnPc and ZnTPCPc showed no activity under illumination with light in the fiber matrix due to low singlet oxygen production. , Original publication is available at http://dx.doi.org/10.1016/j.dyepig.2012.10.001
- Full Text: false
A study on the morphology of thin copper films on para-aramid yarns and their influence on the yarn’s electro-conductive and mechanical properties
- Schwarz, Anne, Hakuzimana, Jean, Westbroek, Philippe, Mey, Gilbert De, Priniotakis, Georgios, Nyokong, Tebello, Langenhove, Lieva Van
- Authors: Schwarz, Anne , Hakuzimana, Jean , Westbroek, Philippe , Mey, Gilbert De , Priniotakis, Georgios , Nyokong, Tebello , Langenhove, Lieva Van
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/243487 , vital:51157 , xlink:href="https://doi.org/10.1177/0040517511431291"
- Description: The latest technological advances in new materials and devices enabled wearable systems to be created by utilizing textile solutions. These solutions require electro-conductive yarns as a basic component. Although the production of electroconductive yarn is widely reported, research is still necessary to characterize them to advance their electro-conductive and mechanical properties. Hence, we served this need and characterized copper-coated para-aramid yarns produced by an in-house developed electroless deposition method. In this paper we present our investigation on the yarn’s copper layer characteristics after deposition. Furthermore, we looked, in depth, at the yarn’s electro-conductive properties before and after washing as well as their mechanical properties before and after copper deposition. We found a dependency of the copper layer morphology on its deposition time. This is directly correlated to the resulting layer thickness and hence to the yarn’s electro-conductive properties, demonstrating the autocatalytic nature of the coating process. Above that, the electro-conductive properties of the coated yarn linearly decrease with washing cycles. Furthermore, the copper coating impairs the yarn’s mechanical properties decreasing its specific stress at break by 30%.
- Full Text:
- Date Issued: 2012
- Authors: Schwarz, Anne , Hakuzimana, Jean , Westbroek, Philippe , Mey, Gilbert De , Priniotakis, Georgios , Nyokong, Tebello , Langenhove, Lieva Van
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/243487 , vital:51157 , xlink:href="https://doi.org/10.1177/0040517511431291"
- Description: The latest technological advances in new materials and devices enabled wearable systems to be created by utilizing textile solutions. These solutions require electro-conductive yarns as a basic component. Although the production of electroconductive yarn is widely reported, research is still necessary to characterize them to advance their electro-conductive and mechanical properties. Hence, we served this need and characterized copper-coated para-aramid yarns produced by an in-house developed electroless deposition method. In this paper we present our investigation on the yarn’s copper layer characteristics after deposition. Furthermore, we looked, in depth, at the yarn’s electro-conductive properties before and after washing as well as their mechanical properties before and after copper deposition. We found a dependency of the copper layer morphology on its deposition time. This is directly correlated to the resulting layer thickness and hence to the yarn’s electro-conductive properties, demonstrating the autocatalytic nature of the coating process. Above that, the electro-conductive properties of the coated yarn linearly decrease with washing cycles. Furthermore, the copper coating impairs the yarn’s mechanical properties decreasing its specific stress at break by 30%.
- Full Text:
- Date Issued: 2012
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