Synthesis and characterization of binary and ternary palladium alloys for use as alternative counter electrode catalysts in dye sensitized solar cells
- Authors: Zingwe, Nyengerai Hillary
- Date: 2020
- Subjects: Electrocatalysis Chemistry
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: http://hdl.handle.net/10353/18513 , vital:42580
- Description: The dye sensitized solar cell counter electrode facilitates the regeneration of the dye molecules thereby ensuring the provision of higher sunlight to electricity conversion efficiency. The standard platinum electrode suffers from low efficiency due to corrosion by the redox mediator as well as being extremely expensive due to high demand. As an alternative this research study illustrates the efforts undertaken to replace the standard platinum counter electrode with palladium alloy counter electrodes. Application of palladium alloys ensures sustenance of high catalytic activity by palladium which is as effective as platinum. Although palladium is equally as expensive as platinum, its application in the form of alloys minimizes the amount required to produce an effective counter electrode to 0.001-0.004 moles thereby ensuring the provision of high efficiency at a lower cost. Furthermore, charge transfer from the other alloyed elements to the palladium atom increases active sites leading to higher catalytic activity than platinum. Additionally, changes in crystal structure due to alloying enhances resistance to corrosion thus enabling the longevity of the alloy counter electrode in the electrolyte ___________________________________________________________________________ Electrochemical analysis was conducted to determine the catalytic functionality of the developed alloys in cobalt, ferrocene and iodine redox mediators. The binary (PdNi-reduced graphene oxide (rGO) and PdCo-rGO) and ternary (PdNiCo-rGO) palladium alloys were fabricated via a hydrothermal method. In order to determine the composition which could provide the maximum activity, optimization was conducted through variation of the molar ratios of the precursor solutions. The properties of the synthesized palladium alloys were determined using various techniques including x-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The developed alloys were observed to comprise of palladium, nickel, cobalt, and carbon atoms. The particles were spherical in nature for all the unsupported alloys with the carbon supported alloys exhibiting spherical particle wholly surrounded by graphene sheets. Cyclic voltammetry and electrochemical impedance spectroscopy analysis showed that the carbon supported alloys PdNi-rGO, PdCo-rGO and PdNiCo-rGO produced the highest catalytic activities due to the synergy between their respective alloys and the incorporated reduced graphene oxide. The high catalytic effectiveness of these alloys yielded power conversion efficiency in the order PdNiCo-rGO (9.01) > PdNi-rGO (8.4.%) > PdCo-rGO (6.56%) > Pt (5.7%) which were better than the platinum efficiency in the cobalt redox mediator. The higher efficiency in the cobalt redox mediator relative to the iodine electrolyte illustrates that they are viable alternatives to the, corrosive and volatile iodine. Obtained results show that, the high recombination rates between the photogenerated electrons and the oxidized dye molecule which have been reported to reduce power conversion efficiency in one electron redox mediators did not affect the performance of the cell. However, these higher recombination rates affected the ferrocene electrolyte leading to extremely poor efficiency metrics. The obtained results indicated that reduced graphene oxide supported PdNi-rGO, PdNiCo-rGO as well as the unsupported PdNi3 alloys could successfully be implemented as substitutes to the platinum counter electrode in dye sensitized solar cells. The application of the palladium alloys is vital for improving stability and power conversion efficiency, as well as reducing cost.
- Full Text:
- Date Issued: 2020
- Authors: Zingwe, Nyengerai Hillary
- Date: 2020
- Subjects: Electrocatalysis Chemistry
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: http://hdl.handle.net/10353/18513 , vital:42580
- Description: The dye sensitized solar cell counter electrode facilitates the regeneration of the dye molecules thereby ensuring the provision of higher sunlight to electricity conversion efficiency. The standard platinum electrode suffers from low efficiency due to corrosion by the redox mediator as well as being extremely expensive due to high demand. As an alternative this research study illustrates the efforts undertaken to replace the standard platinum counter electrode with palladium alloy counter electrodes. Application of palladium alloys ensures sustenance of high catalytic activity by palladium which is as effective as platinum. Although palladium is equally as expensive as platinum, its application in the form of alloys minimizes the amount required to produce an effective counter electrode to 0.001-0.004 moles thereby ensuring the provision of high efficiency at a lower cost. Furthermore, charge transfer from the other alloyed elements to the palladium atom increases active sites leading to higher catalytic activity than platinum. Additionally, changes in crystal structure due to alloying enhances resistance to corrosion thus enabling the longevity of the alloy counter electrode in the electrolyte ___________________________________________________________________________ Electrochemical analysis was conducted to determine the catalytic functionality of the developed alloys in cobalt, ferrocene and iodine redox mediators. The binary (PdNi-reduced graphene oxide (rGO) and PdCo-rGO) and ternary (PdNiCo-rGO) palladium alloys were fabricated via a hydrothermal method. In order to determine the composition which could provide the maximum activity, optimization was conducted through variation of the molar ratios of the precursor solutions. The properties of the synthesized palladium alloys were determined using various techniques including x-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The developed alloys were observed to comprise of palladium, nickel, cobalt, and carbon atoms. The particles were spherical in nature for all the unsupported alloys with the carbon supported alloys exhibiting spherical particle wholly surrounded by graphene sheets. Cyclic voltammetry and electrochemical impedance spectroscopy analysis showed that the carbon supported alloys PdNi-rGO, PdCo-rGO and PdNiCo-rGO produced the highest catalytic activities due to the synergy between their respective alloys and the incorporated reduced graphene oxide. The high catalytic effectiveness of these alloys yielded power conversion efficiency in the order PdNiCo-rGO (9.01) > PdNi-rGO (8.4.%) > PdCo-rGO (6.56%) > Pt (5.7%) which were better than the platinum efficiency in the cobalt redox mediator. The higher efficiency in the cobalt redox mediator relative to the iodine electrolyte illustrates that they are viable alternatives to the, corrosive and volatile iodine. Obtained results show that, the high recombination rates between the photogenerated electrons and the oxidized dye molecule which have been reported to reduce power conversion efficiency in one electron redox mediators did not affect the performance of the cell. However, these higher recombination rates affected the ferrocene electrolyte leading to extremely poor efficiency metrics. The obtained results indicated that reduced graphene oxide supported PdNi-rGO, PdNiCo-rGO as well as the unsupported PdNi3 alloys could successfully be implemented as substitutes to the platinum counter electrode in dye sensitized solar cells. The application of the palladium alloys is vital for improving stability and power conversion efficiency, as well as reducing cost.
- Full Text:
- Date Issued: 2020
Navigating Blackness in the African Diaspora
- Authors: Yates, Sarah
- Date: 2020
- Subjects: Ellison, Ralph. Invisible man , Everett, Percival. Erasure , Wicomb, Zoe. Playing in the light , Bulawayo, NoViolet. We need new names , Africans in literature , Race in literature , African fiction (English) -- History and criticism
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/145720 , vital:38461
- Description: This thesis offers a comparative reading of Ralph Ellison’s Invisible Man, Percival Everett’s Erasure, Zoë Wicomb’s Playing in the Light and NoViolet Bulawayo’s We Need New Names in order to explore the diversity of subjectivities included within the terms ‘African’ and ‘black’ and to argue for the necessity of renewed definitions of Africa(nness) and blackness which allow for diverse and fluid representations. The diverse historical and political contexts in which these novels are published, as well as the critical and theoretical discussions which surround them demonstrate an evolution in literary portrayals of identity politics. As the categories of race and nation become more fluid, so too do narrative forms. In particular, this thesis is interested in the textual strategies authors use to navigate the various ways in which depictions of blackness continue to be restricted by racism, stereotypes, and the dynamics of a global literary market. As portrayals and discussions of identity politics proliferate in popular culture, they become increasingly commodified, and therefore increasingly restricted by the market.
- Full Text:
- Date Issued: 2020
- Authors: Yates, Sarah
- Date: 2020
- Subjects: Ellison, Ralph. Invisible man , Everett, Percival. Erasure , Wicomb, Zoe. Playing in the light , Bulawayo, NoViolet. We need new names , Africans in literature , Race in literature , African fiction (English) -- History and criticism
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/145720 , vital:38461
- Description: This thesis offers a comparative reading of Ralph Ellison’s Invisible Man, Percival Everett’s Erasure, Zoë Wicomb’s Playing in the Light and NoViolet Bulawayo’s We Need New Names in order to explore the diversity of subjectivities included within the terms ‘African’ and ‘black’ and to argue for the necessity of renewed definitions of Africa(nness) and blackness which allow for diverse and fluid representations. The diverse historical and political contexts in which these novels are published, as well as the critical and theoretical discussions which surround them demonstrate an evolution in literary portrayals of identity politics. As the categories of race and nation become more fluid, so too do narrative forms. In particular, this thesis is interested in the textual strategies authors use to navigate the various ways in which depictions of blackness continue to be restricted by racism, stereotypes, and the dynamics of a global literary market. As portrayals and discussions of identity politics proliferate in popular culture, they become increasingly commodified, and therefore increasingly restricted by the market.
- Full Text:
- Date Issued: 2020
The archival turn: rereading the Guy Butler Collection in the National English Literary Museum
- Authors: Wyrill, Beth
- Date: 2020
- Subjects: National English Literary Museum (South Africa) , Butler, Guy, 1918-2001 , Archives -- South Africa , Archives -- Philosophy , Memory (Philosophy)
- Language: English
- Type: Thesis , Doctoral , PHD
- Identifier: http://hdl.handle.net/10962/145746 , vital:38463
- Description: This thesis takes as its theoretical springboard the ‘archival turn’ in South African historical studies, a moment that arguably reached its culmination in 2002 with the publication of Refiguring the Archive. The archival turn posits that, rather than using it as an unproblematic source of original material, scholars might begin to investigate the archive itself, including its processes of construction and organisation. This theoretical model also proposes that the archive might reflect the cultural beliefs and epistemologies common to the era in which it was set up. It seems that the time is ripe for a reconsideration of the insights gleaned from this academic moment in South Africa, given the recent contestation over the meanings of history and our cultural markers of heritage in the public domain, largely grouped under the term ‘Fallism.’ As such, a fresh look at South African museums, which in this country are often rooted in colonial practices of knowledge production, seems apt. This work uses the case of Guy Butler, founder of many South African English cultural institutes and arts bodies, as a conduit and lens for thinking through these problematics. One of Butler’s institutional ‘offspring,’ born from his overarching work on behalf of the English cultural and literary cause in South Africa in the twentieth century, is the National English Literary Museum (NELM). Investigating the founding context and practices of NELM is a useful way of exploring the impact of Butler’s life’s work on literary heritage in South Africa. Issues such as the way in which NELM and Grahamstown continue to signify as loci of thought and practice in the contemporary South African literary landscape will be addressed. The study draws extensively on the Butler collection at NELM, and spends much time investigating Butler’s positioning in a South African literary historical context in the twentieth century, to better understand the forces at work during the time of NELM’s coming-into-being. Derrida’s seminal work on the function of archives, in Archive Fever, is mined for a theoretical basis for the study, as is Deleuze and Guattari’s thought on how bodies (taking the NELM institution here to represent a ‘body’) form, change, and interact, explicated in the work A Thousand Plateaus. The study offers some insights into how the NELM archive was formed, and which forces continue to shape its work in the South African spheres of English literature and heritage.
- Full Text:
- Date Issued: 2020
- Authors: Wyrill, Beth
- Date: 2020
- Subjects: National English Literary Museum (South Africa) , Butler, Guy, 1918-2001 , Archives -- South Africa , Archives -- Philosophy , Memory (Philosophy)
- Language: English
- Type: Thesis , Doctoral , PHD
- Identifier: http://hdl.handle.net/10962/145746 , vital:38463
- Description: This thesis takes as its theoretical springboard the ‘archival turn’ in South African historical studies, a moment that arguably reached its culmination in 2002 with the publication of Refiguring the Archive. The archival turn posits that, rather than using it as an unproblematic source of original material, scholars might begin to investigate the archive itself, including its processes of construction and organisation. This theoretical model also proposes that the archive might reflect the cultural beliefs and epistemologies common to the era in which it was set up. It seems that the time is ripe for a reconsideration of the insights gleaned from this academic moment in South Africa, given the recent contestation over the meanings of history and our cultural markers of heritage in the public domain, largely grouped under the term ‘Fallism.’ As such, a fresh look at South African museums, which in this country are often rooted in colonial practices of knowledge production, seems apt. This work uses the case of Guy Butler, founder of many South African English cultural institutes and arts bodies, as a conduit and lens for thinking through these problematics. One of Butler’s institutional ‘offspring,’ born from his overarching work on behalf of the English cultural and literary cause in South Africa in the twentieth century, is the National English Literary Museum (NELM). Investigating the founding context and practices of NELM is a useful way of exploring the impact of Butler’s life’s work on literary heritage in South Africa. Issues such as the way in which NELM and Grahamstown continue to signify as loci of thought and practice in the contemporary South African literary landscape will be addressed. The study draws extensively on the Butler collection at NELM, and spends much time investigating Butler’s positioning in a South African literary historical context in the twentieth century, to better understand the forces at work during the time of NELM’s coming-into-being. Derrida’s seminal work on the function of archives, in Archive Fever, is mined for a theoretical basis for the study, as is Deleuze and Guattari’s thought on how bodies (taking the NELM institution here to represent a ‘body’) form, change, and interact, explicated in the work A Thousand Plateaus. The study offers some insights into how the NELM archive was formed, and which forces continue to shape its work in the South African spheres of English literature and heritage.
- Full Text:
- Date Issued: 2020
A holistic approach in understanding the effects of dietary protein sources on the growth and reproductive development of farmed abalone, Haliotis midae
- Wu, Yu
- Authors: Wu, Yu
- Date: 2020
- Subjects: Abalones -- Nutrition , Abalones -- Reproduction , Abalones -- Growth , Abalone culture , Haliotis midae -- Nutrition , Haliotis midae -- Reproduction , Haliotis midae -- Growth , Haliotis midae fisheries
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/167719 , vital:41506
- Description: The combination of fishmeal and soya in the formulated feed of farmed South African abalone, Haliotis midae, not only improved abalone growth, but also the sustainability of the compound diets by reducing the reliance on fishmeal. However, the presence of soya produced larger gonads compared to those of abalone fed kelp or single-source protein diets. There is an increasing drive to control sexual maturation and reduce undesirable spawning events in farmed abalone. However, the reasons for the reported effects of soya inclusion on the reproductive development of farmed H. midae remain unresolved. The aim of this research was to use a combination of techniques to contribute to the understanding of the relationship between growth, reproductive and nutritional physiology of farmed H. midae fed diets of varying protein sources. These techniques included stable isotope analysis (SIA), fatty acid analysis, gonad histological assessments and haemolymph sexsteroid hormone analysis. The objectives were to examine the allocation of protein and nutritional components to somatic and reproductive tissues. This study also included the first attempt to investigate the role that sex steroid hormones play during gametogenesis. Abalone (40 – 50 g abalone-1) were fed one of four diets: either a single-source protein-based diet, i.e., (1) fishmeal-only (FM) or (2) soya-only (S), or a combination diet of (3) fishmeal-soya (FM S) or (4) fishmeal-sunflower meal (FM SM). Sampling occurred in 45-day intervals over one year. Dietary protein source had an effect on the growth of abalone, with enhancements in growth linked to the combination of fishmeal and a plant-protein source. The fishmeal ingredient was the most utilised protein source throughout the temporal changes in protein allocation into somatic and reproductive tissue, followed by soya and then sunflower meal. The mean whole- body mass of abalone was significantly influenced by an interaction between time and dietary treatment, with average whole-body mass changing differently over time between treatments (RM-ANOVA, F(24, 96) = 2.13, p = 0.005). Overall, abalone that were fed FM S had higher mean whole-body mass values than abalone that were fed the single-protein based diets, while abalone that were fed FM SM were similar to animals from all dietary treatments (RMANOVA, F(3, 12) = 5.75, p = 0.01). Male abalone had significantly higher gonad bulk index (GBI) values compared to females (RM-ANOVA, F(1, 24) = 49.03, p < 0.001) and this was independent of dietary treatment. Within each sex, female abalone fed the FM S diet (15.92 ± 1.88 mm3 g-1) had significantly higher GBI values than abalone fed S (9.76 ± 1.08 mm3 g-1), while abalone fed FM (11.96 ± 1.71 mm3 g-1) and FM SM (11.90 ± 0.80 mm3 g-1) were similar to abalone from all other dietary treatments (Tukey’s HSD, p < 0.05). Male abalone fed the FM S (21.59 ± 2.10 mm3 g-1) and FM SM diet (19.30 ± 2.63 mm3 g-1) had similar GBI values and they were significantly higher than in abalone fed the S diet (14.74 ± 1.27 mm3 g-1), while abalone fed FM S had significantly higher GBI values than abalone that consumed the FM diet (15.08 ±1.63mm3 g-1) ( Tukey’s HSD, p < 0.05). Although sunflower meal was poorly utilised, it produced similar overall growth to abalone that were fed the FM S diets. Yet, feed conversion ratio values were significantly lower for abalone fed FM S (1.30 ± 0.13) compared to those in the other three treatments, with ratios ranging from 1.65 – 1.72 over the one-year. The fatty acid compositions of the somatic and gonadal tissues were similar between treatments (PERMANOVA, p = 0.21), while fatty acid composition was influenced by sampling day, tissue type and abalone sex (PERMANOVA, p < 0.05). The essential fatty acids (EFAs) eicosadienoic acid and a-linolenic acid were present in abalone tissue, but they were not detected in the diets, suggesting the important role that an alternate food source (e.g. farmed abalone also had access to diatoms) may have played and the ability that H. midae may have in converting long-chain polyunsaturated fatty acids from C18 precursors. A change in the abundance of EFAs in the gonad tissue during highest and lowest GBI values suggested that arachidonic, eicosapentaenoic, g-linolenic and linoleic acid were important in females, while eicosapentaenoic, eicosadienoic and a-linolenic acid were important for male reproductive development. Dietary protein sources had an effect on the frequency distribution of maturity stages, where females that were fed FM S produced more ripe gonads and more males that were fed FM SM contained testes that showed signs of ripeness over the one-year study. Although dietary protein influenced the sex steroid concentrations in females and males, exhibiting fluctuations throughout the one-year period, no distinct pattern linked to gametogenesis were observed. The results from this study illustrate: (1) the importance of conducting laboratory studies when implementing SIA and mixing models in aquaculture nutrition; (2) conducting nutritional studies on mature, grow-out abalone; and (3) assessing the importance of naturally occurring diatoms in their diet and their contribution to growth and reproduction. The novel contribution of this research towards abalone nutritional physiology, the implications of these findings to industry as well as potential considerations for future studies were addressed.
- Full Text:
- Date Issued: 2020
- Authors: Wu, Yu
- Date: 2020
- Subjects: Abalones -- Nutrition , Abalones -- Reproduction , Abalones -- Growth , Abalone culture , Haliotis midae -- Nutrition , Haliotis midae -- Reproduction , Haliotis midae -- Growth , Haliotis midae fisheries
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/167719 , vital:41506
- Description: The combination of fishmeal and soya in the formulated feed of farmed South African abalone, Haliotis midae, not only improved abalone growth, but also the sustainability of the compound diets by reducing the reliance on fishmeal. However, the presence of soya produced larger gonads compared to those of abalone fed kelp or single-source protein diets. There is an increasing drive to control sexual maturation and reduce undesirable spawning events in farmed abalone. However, the reasons for the reported effects of soya inclusion on the reproductive development of farmed H. midae remain unresolved. The aim of this research was to use a combination of techniques to contribute to the understanding of the relationship between growth, reproductive and nutritional physiology of farmed H. midae fed diets of varying protein sources. These techniques included stable isotope analysis (SIA), fatty acid analysis, gonad histological assessments and haemolymph sexsteroid hormone analysis. The objectives were to examine the allocation of protein and nutritional components to somatic and reproductive tissues. This study also included the first attempt to investigate the role that sex steroid hormones play during gametogenesis. Abalone (40 – 50 g abalone-1) were fed one of four diets: either a single-source protein-based diet, i.e., (1) fishmeal-only (FM) or (2) soya-only (S), or a combination diet of (3) fishmeal-soya (FM S) or (4) fishmeal-sunflower meal (FM SM). Sampling occurred in 45-day intervals over one year. Dietary protein source had an effect on the growth of abalone, with enhancements in growth linked to the combination of fishmeal and a plant-protein source. The fishmeal ingredient was the most utilised protein source throughout the temporal changes in protein allocation into somatic and reproductive tissue, followed by soya and then sunflower meal. The mean whole- body mass of abalone was significantly influenced by an interaction between time and dietary treatment, with average whole-body mass changing differently over time between treatments (RM-ANOVA, F(24, 96) = 2.13, p = 0.005). Overall, abalone that were fed FM S had higher mean whole-body mass values than abalone that were fed the single-protein based diets, while abalone that were fed FM SM were similar to animals from all dietary treatments (RMANOVA, F(3, 12) = 5.75, p = 0.01). Male abalone had significantly higher gonad bulk index (GBI) values compared to females (RM-ANOVA, F(1, 24) = 49.03, p < 0.001) and this was independent of dietary treatment. Within each sex, female abalone fed the FM S diet (15.92 ± 1.88 mm3 g-1) had significantly higher GBI values than abalone fed S (9.76 ± 1.08 mm3 g-1), while abalone fed FM (11.96 ± 1.71 mm3 g-1) and FM SM (11.90 ± 0.80 mm3 g-1) were similar to abalone from all other dietary treatments (Tukey’s HSD, p < 0.05). Male abalone fed the FM S (21.59 ± 2.10 mm3 g-1) and FM SM diet (19.30 ± 2.63 mm3 g-1) had similar GBI values and they were significantly higher than in abalone fed the S diet (14.74 ± 1.27 mm3 g-1), while abalone fed FM S had significantly higher GBI values than abalone that consumed the FM diet (15.08 ±1.63mm3 g-1) ( Tukey’s HSD, p < 0.05). Although sunflower meal was poorly utilised, it produced similar overall growth to abalone that were fed the FM S diets. Yet, feed conversion ratio values were significantly lower for abalone fed FM S (1.30 ± 0.13) compared to those in the other three treatments, with ratios ranging from 1.65 – 1.72 over the one-year. The fatty acid compositions of the somatic and gonadal tissues were similar between treatments (PERMANOVA, p = 0.21), while fatty acid composition was influenced by sampling day, tissue type and abalone sex (PERMANOVA, p < 0.05). The essential fatty acids (EFAs) eicosadienoic acid and a-linolenic acid were present in abalone tissue, but they were not detected in the diets, suggesting the important role that an alternate food source (e.g. farmed abalone also had access to diatoms) may have played and the ability that H. midae may have in converting long-chain polyunsaturated fatty acids from C18 precursors. A change in the abundance of EFAs in the gonad tissue during highest and lowest GBI values suggested that arachidonic, eicosapentaenoic, g-linolenic and linoleic acid were important in females, while eicosapentaenoic, eicosadienoic and a-linolenic acid were important for male reproductive development. Dietary protein sources had an effect on the frequency distribution of maturity stages, where females that were fed FM S produced more ripe gonads and more males that were fed FM SM contained testes that showed signs of ripeness over the one-year study. Although dietary protein influenced the sex steroid concentrations in females and males, exhibiting fluctuations throughout the one-year period, no distinct pattern linked to gametogenesis were observed. The results from this study illustrate: (1) the importance of conducting laboratory studies when implementing SIA and mixing models in aquaculture nutrition; (2) conducting nutritional studies on mature, grow-out abalone; and (3) assessing the importance of naturally occurring diatoms in their diet and their contribution to growth and reproduction. The novel contribution of this research towards abalone nutritional physiology, the implications of these findings to industry as well as potential considerations for future studies were addressed.
- Full Text:
- Date Issued: 2020
Formulation development, manufacture and evaluation of a lamivudine-zidovudine nano co-crystal thermo-responsive suspension
- Authors: Witika, Bwalya Angel
- Date: 2020
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/140546 , vital:37897 , http://dx.doi.org/10.21504/10962/140546
- Description: Expected release date-April 2021
- Full Text:
- Date Issued: 2020
- Authors: Witika, Bwalya Angel
- Date: 2020
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/140546 , vital:37897 , http://dx.doi.org/10.21504/10962/140546
- Description: Expected release date-April 2021
- Full Text:
- Date Issued: 2020
Designing a parental involvement programme to enhance parental engagement in the educational support programme at a disadvantaged primary school in the Nelson Mandela Bay Metropole, South Africa through participatory action research
- WIlliams, Pearl Juanita Cherrol
- Authors: WIlliams, Pearl Juanita Cherrol
- Date: 2020
- Subjects: Education -- Parent participation -- South Africa -- Nelson Mandela Bay Municipality
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/47303 , vital:39841
- Description: Over the past decades parental involvement in education has increased rapidly within disadvantaged schools in South Africa. This transformation is evident in the legislation of the country which celebrates a spirit of Ubuntu in a democratised society, and, education at large. The ideal of effective school-home partnership across racial boundaries are, for example, emphasised and strengthened via parental involvement at all public schools. Parents, according to the Department of Education (DoE, 1996b:11; 2000c:29; 2001b:29; 2008:23; 2009:17; 2014b:27; n.d.:6), are considered key role-players in school governance and encouraged to support equal educational opportunities for all learners. It implies that the praxis of parental involvement – especially at disadvantaged schools – is a huge benefit to learners with existing backlogs in education. In relation to this view, Stofile and Green (2007:63) emphasise the significance of parental involvement in school life as it can assist greatly in addressing the divere needs of disadvantaged learners. The dynamics associated with parental involvement are investigated in this study through two cycles of participatory action research. Initially ten parents from one of the disadvantaged primary schools within the Nelson Mandela Bay Metropole were purposively selected to participate in an in-depth qualitative research study pertaining to the design of a suitable parental involvement programme for disadvantaged learners. All the relevant information was gathered during action learning sets, individual interviews, and observations to triangulate the data and fill in possible gaps. This data was coded and categorised throughout the cyclical process via inductive participatory data analysis, as described by Patton (2015:216 & 551). Three main themes with sub-themes emerged from the study, namely (1) deficits of the academic programme: remedial education, teacher-assistants, homeworksupport, technical abilities; (2) the neglect of social wellness programmes: need for parental guidance, necessary professional assistance, upgrading of safety measures, availability of clothing bank, sustainability of a nutritional programme; and (3) voids in communication and relationships: the home environment, community, school environment. These themes and sub-themes successfully answered all the research questions. An increasing number of learners at disadvataged primary schools are neglected and/or leave school at a very young age. This scenario is often linked to poor communication and/or a lack of adequate educational support programmes to enhance better learning outcomes. The design of a PIP aimed to address the diverse needs of learners at a specific disadvantaged primary school with the full cooperation of their parents. Nested within the Ecological Model of Bronfenbrenner, the participating parents were engaged in comprehensive discussions about educational support programmes that the school could embark on with them. Numerous programmes were identified as fundamental to transforming the quality of education for many disadvantaged learners. This research therefore encouraged greater parental involvement at disadvantaged primary schools in order to sustain better learning outcomes.
- Full Text:
- Date Issued: 2020
- Authors: WIlliams, Pearl Juanita Cherrol
- Date: 2020
- Subjects: Education -- Parent participation -- South Africa -- Nelson Mandela Bay Municipality
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/47303 , vital:39841
- Description: Over the past decades parental involvement in education has increased rapidly within disadvantaged schools in South Africa. This transformation is evident in the legislation of the country which celebrates a spirit of Ubuntu in a democratised society, and, education at large. The ideal of effective school-home partnership across racial boundaries are, for example, emphasised and strengthened via parental involvement at all public schools. Parents, according to the Department of Education (DoE, 1996b:11; 2000c:29; 2001b:29; 2008:23; 2009:17; 2014b:27; n.d.:6), are considered key role-players in school governance and encouraged to support equal educational opportunities for all learners. It implies that the praxis of parental involvement – especially at disadvantaged schools – is a huge benefit to learners with existing backlogs in education. In relation to this view, Stofile and Green (2007:63) emphasise the significance of parental involvement in school life as it can assist greatly in addressing the divere needs of disadvantaged learners. The dynamics associated with parental involvement are investigated in this study through two cycles of participatory action research. Initially ten parents from one of the disadvantaged primary schools within the Nelson Mandela Bay Metropole were purposively selected to participate in an in-depth qualitative research study pertaining to the design of a suitable parental involvement programme for disadvantaged learners. All the relevant information was gathered during action learning sets, individual interviews, and observations to triangulate the data and fill in possible gaps. This data was coded and categorised throughout the cyclical process via inductive participatory data analysis, as described by Patton (2015:216 & 551). Three main themes with sub-themes emerged from the study, namely (1) deficits of the academic programme: remedial education, teacher-assistants, homeworksupport, technical abilities; (2) the neglect of social wellness programmes: need for parental guidance, necessary professional assistance, upgrading of safety measures, availability of clothing bank, sustainability of a nutritional programme; and (3) voids in communication and relationships: the home environment, community, school environment. These themes and sub-themes successfully answered all the research questions. An increasing number of learners at disadvataged primary schools are neglected and/or leave school at a very young age. This scenario is often linked to poor communication and/or a lack of adequate educational support programmes to enhance better learning outcomes. The design of a PIP aimed to address the diverse needs of learners at a specific disadvantaged primary school with the full cooperation of their parents. Nested within the Ecological Model of Bronfenbrenner, the participating parents were engaged in comprehensive discussions about educational support programmes that the school could embark on with them. Numerous programmes were identified as fundamental to transforming the quality of education for many disadvantaged learners. This research therefore encouraged greater parental involvement at disadvantaged primary schools in order to sustain better learning outcomes.
- Full Text:
- Date Issued: 2020
Identifying a Successful Accounting Student: Profiling of Postgraduate Accounting Students in the Eastern Cape
- Authors: Weldon, Lana Joy
- Date: 2020
- Subjects: Personality -- South Africa -- Eastern Cape , Accounting -- Study and teaching (Higher) -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/50699 , vital:42343
- Description: Throughput rates and transformation have long been considered major challenges to accounting departments in South Africa. While much research has been done on various aspects of study techniques in an attempt to assist students to succeed, little attention has been paid to profiling students to ascertain whether there are common traits in terms of personality, aptitude, values and motives, which distinguish successful students from others. This study looks at these factors and uses sub-tests of the Differential Aptitude Test (DAT), selected with reference to the South African Institute of Chartered Accountants (SAICA) Competency Framework, to determine the correlation between these aptitudes and the success of accounting students. In addition, the impact of biographical data, including gender, race and type of school attended, is considered on the success of the students and the individual sub-tests of aptitude. The study then considers the impact of various personality types, personality traits and values on the success or failure of accounting students, and finally seeks to ascertain whether there is a holistic profile of a student who has a statistically significant chance of succeeding in accounting studies. Results indicate that the sub-tests of aptitude for verbal reasoning and reading comprehension have the most significance in predicting student success and that gender and race have a medium effect. Furthermore, personality types, personality traits and values do not have a significant impact on student success. The only biographical factor to have an impact on success was race. Despite the findings in the individual factors considered, no distinct personality profile of a successful Results indicate that the sub-tests of aptitude for verbal reasoning and reading comprehension have the most significance in predicting student success and that gender and race have a medium effect. Furthermore, personality types, personality traits and values do not have a significant impact on student success. The only biographical factor to have an impact on success was race. Despite the findings in the individual factors considered, no distinct personality profile of a successful accounting student emerged. Future research on the use of literacy competency assessments in the admission requirements for chartered accounting programmes, or to inform student academic support initiatives is recommended. accounting student emerged. Future research on the use of literacy competency assessments in the admission requirements for chartered accounting programmes, or to inform student academic support initiatives is recommended.
- Full Text:
- Date Issued: 2020
- Authors: Weldon, Lana Joy
- Date: 2020
- Subjects: Personality -- South Africa -- Eastern Cape , Accounting -- Study and teaching (Higher) -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/50699 , vital:42343
- Description: Throughput rates and transformation have long been considered major challenges to accounting departments in South Africa. While much research has been done on various aspects of study techniques in an attempt to assist students to succeed, little attention has been paid to profiling students to ascertain whether there are common traits in terms of personality, aptitude, values and motives, which distinguish successful students from others. This study looks at these factors and uses sub-tests of the Differential Aptitude Test (DAT), selected with reference to the South African Institute of Chartered Accountants (SAICA) Competency Framework, to determine the correlation between these aptitudes and the success of accounting students. In addition, the impact of biographical data, including gender, race and type of school attended, is considered on the success of the students and the individual sub-tests of aptitude. The study then considers the impact of various personality types, personality traits and values on the success or failure of accounting students, and finally seeks to ascertain whether there is a holistic profile of a student who has a statistically significant chance of succeeding in accounting studies. Results indicate that the sub-tests of aptitude for verbal reasoning and reading comprehension have the most significance in predicting student success and that gender and race have a medium effect. Furthermore, personality types, personality traits and values do not have a significant impact on student success. The only biographical factor to have an impact on success was race. Despite the findings in the individual factors considered, no distinct personality profile of a successful Results indicate that the sub-tests of aptitude for verbal reasoning and reading comprehension have the most significance in predicting student success and that gender and race have a medium effect. Furthermore, personality types, personality traits and values do not have a significant impact on student success. The only biographical factor to have an impact on success was race. Despite the findings in the individual factors considered, no distinct personality profile of a successful accounting student emerged. Future research on the use of literacy competency assessments in the admission requirements for chartered accounting programmes, or to inform student academic support initiatives is recommended. accounting student emerged. Future research on the use of literacy competency assessments in the admission requirements for chartered accounting programmes, or to inform student academic support initiatives is recommended.
- Full Text:
- Date Issued: 2020
The role of microhabitats within mangroves: an invertebrate and fish larval perspective
- Authors: Vorsatz, Lyle Dennis
- Date: 2020
- Subjects: Mangrove ecology -- South Africa , Mangrove forests -- South Africa , Niche (Ecology) , Rhizophora mucronata , Acanthaceae , Rhizophoraceae , Fishes -- Larvae -- South Africa , Aquatic ecology -- South Africa
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/167644 , vital:41499
- Description: Microhabitats provided through structural complexity are central for the diversity, productivity, connectivity and niche differentiation within and among ecosystems. Mangrove forests afford juvenile fish and invertebrates with nursery and recruitment habitats, facilitated by the fine scale configuration of their specialised root systems. Although the importance of mangroves for resident and transient juveniles is well recognised, the roles that mangrove microhabitats play for larvae is not yet comprehensively understood. This study aimed to determine how microhabitats with varying degrees of complexity influence the composition, abundance and distribution of larval communities that inhabit mangrove forests and the physiological responses of larvae to acute temperature variations in relation to ontogenetic stage and microenvironment exposure. Two relatively pristine study sites were selected to represent a warm temperate and subtropical mangrove system in the Eastern Cape and KwaZulu-Natal on the east coast of South Africa, respectively. The differences in complexity among the root systems of Rhizophora mucronata, Avicennia marina and Bruguiera gymnorhiza were assessed using 3D scanning and the computed 3D models were then analysed using four complexity metrics. Results indicated that A. marina is the most complex in terms of surface-volume ratio, R. mucronata has the most interstitial space among its roots and B. gymnorhiza and R. mucronata differ in their fractal dimensions. Larvae collected in each microhabitat at each site using light traps showed that, despite temperature and salinity homogeneity across microenvironments, spatio-temporal differences occurred in both fish and invertebrate assemblages. This trend suggests that microhabitat structural complexity exerts an influence on larval community composition by acting as a microscape of available habitat, which ensures ecological linkages within and among the mangrove forest and adjacent ecosystems. In addition, the oxygen consumption rates of mangrove-associated brachyuran larvae varied according to mangrove microhabitat, whereby larvae collected at less complex environments had the highest metabolic rates at increased temperatures. Moreover, ontogenetic shifts in physiology were prevalent as older brachyuran larvae were more eurythermal than earlier stages, suggesting that thermally stressful events will have a greater impact on recently spawned larvae. Overall, the interstitial spaces within individual root systems are the most important complexity measure, as utilisation of these mangrove microhabitats is scale-dependent, and larvae will most likely occupy spaces inaccessible to large predators. Likewise, microscale variation in the environmental conditions and ontogenetic stage of brachyuran larvae within the mangrove microscape, can amplify the physiological responses to rapid temperature variations. Results suggest that early stage larvae are the most vulnerable to mass-mortality, and if thermally stressful events increase in frequency, duration and magnitude, the larval supply for the successful recruitment into adult populations could be under threat. Through linking how mangrove microhabitat complexity influences larvae in terms of community metrics and physiology, this study paves the way for further advancement of our understanding of how microscale processes emerge into meso- and macroscale patterns and influence the stability and functioning of highly productive ecosystems.
- Full Text:
- Date Issued: 2020
- Authors: Vorsatz, Lyle Dennis
- Date: 2020
- Subjects: Mangrove ecology -- South Africa , Mangrove forests -- South Africa , Niche (Ecology) , Rhizophora mucronata , Acanthaceae , Rhizophoraceae , Fishes -- Larvae -- South Africa , Aquatic ecology -- South Africa
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/167644 , vital:41499
- Description: Microhabitats provided through structural complexity are central for the diversity, productivity, connectivity and niche differentiation within and among ecosystems. Mangrove forests afford juvenile fish and invertebrates with nursery and recruitment habitats, facilitated by the fine scale configuration of their specialised root systems. Although the importance of mangroves for resident and transient juveniles is well recognised, the roles that mangrove microhabitats play for larvae is not yet comprehensively understood. This study aimed to determine how microhabitats with varying degrees of complexity influence the composition, abundance and distribution of larval communities that inhabit mangrove forests and the physiological responses of larvae to acute temperature variations in relation to ontogenetic stage and microenvironment exposure. Two relatively pristine study sites were selected to represent a warm temperate and subtropical mangrove system in the Eastern Cape and KwaZulu-Natal on the east coast of South Africa, respectively. The differences in complexity among the root systems of Rhizophora mucronata, Avicennia marina and Bruguiera gymnorhiza were assessed using 3D scanning and the computed 3D models were then analysed using four complexity metrics. Results indicated that A. marina is the most complex in terms of surface-volume ratio, R. mucronata has the most interstitial space among its roots and B. gymnorhiza and R. mucronata differ in their fractal dimensions. Larvae collected in each microhabitat at each site using light traps showed that, despite temperature and salinity homogeneity across microenvironments, spatio-temporal differences occurred in both fish and invertebrate assemblages. This trend suggests that microhabitat structural complexity exerts an influence on larval community composition by acting as a microscape of available habitat, which ensures ecological linkages within and among the mangrove forest and adjacent ecosystems. In addition, the oxygen consumption rates of mangrove-associated brachyuran larvae varied according to mangrove microhabitat, whereby larvae collected at less complex environments had the highest metabolic rates at increased temperatures. Moreover, ontogenetic shifts in physiology were prevalent as older brachyuran larvae were more eurythermal than earlier stages, suggesting that thermally stressful events will have a greater impact on recently spawned larvae. Overall, the interstitial spaces within individual root systems are the most important complexity measure, as utilisation of these mangrove microhabitats is scale-dependent, and larvae will most likely occupy spaces inaccessible to large predators. Likewise, microscale variation in the environmental conditions and ontogenetic stage of brachyuran larvae within the mangrove microscape, can amplify the physiological responses to rapid temperature variations. Results suggest that early stage larvae are the most vulnerable to mass-mortality, and if thermally stressful events increase in frequency, duration and magnitude, the larval supply for the successful recruitment into adult populations could be under threat. Through linking how mangrove microhabitat complexity influences larvae in terms of community metrics and physiology, this study paves the way for further advancement of our understanding of how microscale processes emerge into meso- and macroscale patterns and influence the stability and functioning of highly productive ecosystems.
- Full Text:
- Date Issued: 2020
“A position of great trust and responsibility”: a social history of the Grahamstown Asylum, 1875 – c. 1905
- Authors: Van Zyl, Kylie
- Date: 2020
- Subjects: Mental health services -- South Africa -- Cape of Good Hope , Psychiatric hospitals -- South Africa -- History , South Africa -- Race relations -- Social aspects , Mentally ill -- Commitment and detention -- South Africa , Mentally ill -- Abuse of -- South Africa , Mental health policy -- South Africa , Asylums -- South Africa -- Grahamstown , Discrimination in mental health services -- South Africa , Health and race -- South Africa -- History
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/151031 , vital:39025
- Description: Much has been written about the inequalities inherent in the psychiatric care provided to mentally ill individuals in the Cape Colony, but to date few works have been produced that describe in detail the processes and care regimes at particular institutions. This thesis examines the history of care and custody provided by the Grahamstown Asylum in the Cape between the years of 1875 and 1905. The intention is to determine the means and methods by which the Asylum’s authorities developed, almost unchallenged, a system of unequal treatment and favouritism within that facility, and what this meant for the men and women committed to the Asylum’s custody. To this end, contemporaneous official reports from Asylum staff and Colonial authorities were consulted, in conjunction with the Asylum’s internal records such as registers and individual patient files. This thesis concludes that the evolution of the Colony’s psychiatric community’s beliefs around mental illness, philosophies of protective custody and moral treatment within the psychiatric community at the time, the region’s laws governing psychiatric institutionalisation, and the larger context of the Cape’s socio-political environment at the time converged to create an institution that practiced discrimination on both a macro- and micro-level. This discriminatory framework affected who was admitted, the diagnosis that each person received, the asylum facilities to which they had access, and further, to the odds against their recovery. The implications of this study are relevant in the present day, as the modern South African system of psychiatric institutionalisation, though embedded within a socio-political context of equality and non-discrimination nevertheless appears to suffer from a similarly undemocratic framework of operation.
- Full Text:
- Date Issued: 2020
- Authors: Van Zyl, Kylie
- Date: 2020
- Subjects: Mental health services -- South Africa -- Cape of Good Hope , Psychiatric hospitals -- South Africa -- History , South Africa -- Race relations -- Social aspects , Mentally ill -- Commitment and detention -- South Africa , Mentally ill -- Abuse of -- South Africa , Mental health policy -- South Africa , Asylums -- South Africa -- Grahamstown , Discrimination in mental health services -- South Africa , Health and race -- South Africa -- History
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/151031 , vital:39025
- Description: Much has been written about the inequalities inherent in the psychiatric care provided to mentally ill individuals in the Cape Colony, but to date few works have been produced that describe in detail the processes and care regimes at particular institutions. This thesis examines the history of care and custody provided by the Grahamstown Asylum in the Cape between the years of 1875 and 1905. The intention is to determine the means and methods by which the Asylum’s authorities developed, almost unchallenged, a system of unequal treatment and favouritism within that facility, and what this meant for the men and women committed to the Asylum’s custody. To this end, contemporaneous official reports from Asylum staff and Colonial authorities were consulted, in conjunction with the Asylum’s internal records such as registers and individual patient files. This thesis concludes that the evolution of the Colony’s psychiatric community’s beliefs around mental illness, philosophies of protective custody and moral treatment within the psychiatric community at the time, the region’s laws governing psychiatric institutionalisation, and the larger context of the Cape’s socio-political environment at the time converged to create an institution that practiced discrimination on both a macro- and micro-level. This discriminatory framework affected who was admitted, the diagnosis that each person received, the asylum facilities to which they had access, and further, to the odds against their recovery. The implications of this study are relevant in the present day, as the modern South African system of psychiatric institutionalisation, though embedded within a socio-political context of equality and non-discrimination nevertheless appears to suffer from a similarly undemocratic framework of operation.
- Full Text:
- Date Issued: 2020
Thermal tolerance and the potential effects of climate change on coastal intertidal and estuarine organisms in the Kariega Estuary and adjacent intertitdal coastline, Eastern Cape, South Africa
- Authors: Van der Walt, Kerry-Ann
- Date: 2020
- Subjects: Ectotherms -- Climatic factors , Ectotherms -- Effect of temperature on , Fishes -- Climatic factors , Fishes -- Effect of temperature on , Climatic changes -- South Africa -- Eastern Cape
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/148459 , vital:38741
- Description: Temperature changes due to the effects of climate change are evident on all continents and oceans. As a result, there is a growing concern over how marine ectotherms will respond to extreme or fluctuating environmental temperatures. Temperature changes have strong direct and indirect effects on individual, population, and ecosystem functioning traits. A multi-scale approach determining the thermal tolerance and performance of several marine ectotherms belonging to different coastal habitats is rarely considered in thermal physiology studies but is effective for an integrated ecosystem assessment. As such, for this thesis, I aimed to quantify and compare the thermal tolerance and performance of a range of coastal marine ectotherms (fish and macro-invertebrates) with different biogeographical distributions from estuarine, subtidal and rocky intertidal habitats to available and projected in situ temperature data. This was also undertaken to gauge the local vulnerability of each species across summer and winter in a warm-temperate region of South Africa. This was done using a multi-method physiological approach, which included the dynamic method (CTmax and CTmin), static respirometry and maximum heart rate fHmax). Results of the dynamic method on several fish and macro-invertebrate species indicated that there are differences in thermal tolerance according to taxonomy, biogeography and habitat for both summer and winter. Macro-invertebrate species generally had higher CTmax endpoints, lower CTmin endpoints, higher upper and lower breadths in tolerance, higher upper and lower thermal safety margins and higher thermal scopes than the fish species. This could be a result of the macro-invertebrate species studied being less mobile compared with fish species (which are able to move to more favourable conditions) as well as having broader geographical distributions. In addition, macro-invertebrates from the intertidal rock pool habitat (Palaemon peringueyi; Pernaperna) were more tolerant of high and low temperatures compared with the macro-invertebrates from the estuarine habitat (Clibanarius virescens; Parasesarma catenatum; Upogebia africana). Overall, macro-invertebrates, with the exception of Parechinus angulosus, investigated in this study indicated that current temperatures and projected climate change scenarios across seasons would not have a significant impact on them and that they are highly adaptable to changing temperature regimes. This sign of high tolerance was further supported by the heart rates of P. perna and P. catenatum under an acute increase in temperature (1.0 °C.h-1) which showed individuals of each species physiologically depressing their metabolism until a final Arrhenius breakpoint temperature was reached (TAB). Among the fish species investigated in this study, tropical species (Chaetodon marleyi; Kuhlia mugil) had the highest CTmax and CTmin endpoints when compared with the temperate (Diplodus capensis; Sarpa salpa), warm-water endemic (Chelon dumerili; Rhabdosargus holubi) and cool-water endemic (Chelon richardsonii) fishes. This suggests that due to their lower breadths in tolerance and thermal safety margins being small, tropical species may be less tolerant of cold temperatures and thermal variability, especially in the form of summer upwelling events which are expected to increase in intensity and frequency in this region as a result of anthropogenic climate change effects. On the other hand, however, if a temperature increase of 2.0 - 4.0 °C takes place at the end of the century as predicted by the Intergovernmental Panel on Climate Change (IPCC), it is likely that tropical species such as C. marleyi will become more common. Temperate species such as D. capensis and S. salpa were able to tolerate a wide range of temperatures (wide thermal scope) compared with the other fish species. These findings may suggest that D. capensis and S. salpa are thermally resilient and may be the least vulnerable to climate change effects and temperature variability. When evaluating the different life stages of D. capensis, however, using the dynamic method (juveniles and adults), static respirometry (juveniles) and maximum heart rate (adults), results suggested that juveniles of this temperate species will be more resilient to increases in ocean temperatures compared with the adults because they have a higher thermal tolerance (CTmax/TCRIT) and a greater metabolic scope (TOPT) at higher temperatures. For both juveniles and adults, temperatures beyond 28.0 °C (upper Tpej; Tarr) will have a significant impact on their physiology. Using a multi-scale and multi-method approach thus helped to identify which species or community may be vulnerable to the effects of climate change within shallow coastal environments in this warm-temperate climate change hotspot. Adopting this type of approach will assist policy makers in developing comprehensive climate change management frameworks for coastal ecosystems globally and around South Africa.
- Full Text:
- Date Issued: 2020
- Authors: Van der Walt, Kerry-Ann
- Date: 2020
- Subjects: Ectotherms -- Climatic factors , Ectotherms -- Effect of temperature on , Fishes -- Climatic factors , Fishes -- Effect of temperature on , Climatic changes -- South Africa -- Eastern Cape
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/148459 , vital:38741
- Description: Temperature changes due to the effects of climate change are evident on all continents and oceans. As a result, there is a growing concern over how marine ectotherms will respond to extreme or fluctuating environmental temperatures. Temperature changes have strong direct and indirect effects on individual, population, and ecosystem functioning traits. A multi-scale approach determining the thermal tolerance and performance of several marine ectotherms belonging to different coastal habitats is rarely considered in thermal physiology studies but is effective for an integrated ecosystem assessment. As such, for this thesis, I aimed to quantify and compare the thermal tolerance and performance of a range of coastal marine ectotherms (fish and macro-invertebrates) with different biogeographical distributions from estuarine, subtidal and rocky intertidal habitats to available and projected in situ temperature data. This was also undertaken to gauge the local vulnerability of each species across summer and winter in a warm-temperate region of South Africa. This was done using a multi-method physiological approach, which included the dynamic method (CTmax and CTmin), static respirometry and maximum heart rate fHmax). Results of the dynamic method on several fish and macro-invertebrate species indicated that there are differences in thermal tolerance according to taxonomy, biogeography and habitat for both summer and winter. Macro-invertebrate species generally had higher CTmax endpoints, lower CTmin endpoints, higher upper and lower breadths in tolerance, higher upper and lower thermal safety margins and higher thermal scopes than the fish species. This could be a result of the macro-invertebrate species studied being less mobile compared with fish species (which are able to move to more favourable conditions) as well as having broader geographical distributions. In addition, macro-invertebrates from the intertidal rock pool habitat (Palaemon peringueyi; Pernaperna) were more tolerant of high and low temperatures compared with the macro-invertebrates from the estuarine habitat (Clibanarius virescens; Parasesarma catenatum; Upogebia africana). Overall, macro-invertebrates, with the exception of Parechinus angulosus, investigated in this study indicated that current temperatures and projected climate change scenarios across seasons would not have a significant impact on them and that they are highly adaptable to changing temperature regimes. This sign of high tolerance was further supported by the heart rates of P. perna and P. catenatum under an acute increase in temperature (1.0 °C.h-1) which showed individuals of each species physiologically depressing their metabolism until a final Arrhenius breakpoint temperature was reached (TAB). Among the fish species investigated in this study, tropical species (Chaetodon marleyi; Kuhlia mugil) had the highest CTmax and CTmin endpoints when compared with the temperate (Diplodus capensis; Sarpa salpa), warm-water endemic (Chelon dumerili; Rhabdosargus holubi) and cool-water endemic (Chelon richardsonii) fishes. This suggests that due to their lower breadths in tolerance and thermal safety margins being small, tropical species may be less tolerant of cold temperatures and thermal variability, especially in the form of summer upwelling events which are expected to increase in intensity and frequency in this region as a result of anthropogenic climate change effects. On the other hand, however, if a temperature increase of 2.0 - 4.0 °C takes place at the end of the century as predicted by the Intergovernmental Panel on Climate Change (IPCC), it is likely that tropical species such as C. marleyi will become more common. Temperate species such as D. capensis and S. salpa were able to tolerate a wide range of temperatures (wide thermal scope) compared with the other fish species. These findings may suggest that D. capensis and S. salpa are thermally resilient and may be the least vulnerable to climate change effects and temperature variability. When evaluating the different life stages of D. capensis, however, using the dynamic method (juveniles and adults), static respirometry (juveniles) and maximum heart rate (adults), results suggested that juveniles of this temperate species will be more resilient to increases in ocean temperatures compared with the adults because they have a higher thermal tolerance (CTmax/TCRIT) and a greater metabolic scope (TOPT) at higher temperatures. For both juveniles and adults, temperatures beyond 28.0 °C (upper Tpej; Tarr) will have a significant impact on their physiology. Using a multi-scale and multi-method approach thus helped to identify which species or community may be vulnerable to the effects of climate change within shallow coastal environments in this warm-temperate climate change hotspot. Adopting this type of approach will assist policy makers in developing comprehensive climate change management frameworks for coastal ecosystems globally and around South Africa.
- Full Text:
- Date Issued: 2020
A personality-based surveillance model for Facebook apps
- Authors: Van der Schyff, Karl Izak
- Date: 2020
- Subjects: Facebook (Electronic resource) , Electronic surveillance -- Psychological aspects , Online social networks -- Psychological aspects , Social media -- Psychological aspects , Personality
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/145534 , vital:38447
- Description: The surveillance of data through the use of Facebook Apps is an ongoing and persistent problem that impacts millions of users. Nonetheless, limited research has been conducted investigating to what extent a Facebook user’s personality influences their awareness of such surveillance practices. Thus, to understand this situation better, the current study inductively developed four propositions from secondary data sources as part of a detailed content analysis. Spanning three search and analysis phases the content analysis led to the development of the research model. Guided by the propositions and research questions, a questionnaire was developed based on the relevant constructs prescribed by the Theory of Planned Behaviour. This questionnaire was used, and a total of 651 responses were collected from Facebook users over the age of 18 years old and residing in the United States of America. Primary data took place at both a univariate and multivariate level with a specific focus on the development of a structural model. Interpretation of the structural model revealed that out of all the Big Five personality traits, Conscientiousness exhibited the strongest relationship with information security awareness followed by Openness to Experience and Neuroticism, respectively. The results further indicated that the model constructs based on attitude, social norms and awareness significantly influenced the intended use of Facebook Apps. The study also contributes by indicating which personality traits are most vulnerable to Facebook App surveillance. For example, it was found that individuals high in Conscientiousness are the least vulnerable with individuals high in Extraversion being the most vulnerable. Since the results indicate that not all the personality traits are significantly related to the model constructs, additional factors may contribute to App surveillance in this context. Concerning this, factors such as user apathy, information privacy, privacy concerns, control and Facebook dependency are discussed as a means to argue why this might be the case.
- Full Text:
- Date Issued: 2020
- Authors: Van der Schyff, Karl Izak
- Date: 2020
- Subjects: Facebook (Electronic resource) , Electronic surveillance -- Psychological aspects , Online social networks -- Psychological aspects , Social media -- Psychological aspects , Personality
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/145534 , vital:38447
- Description: The surveillance of data through the use of Facebook Apps is an ongoing and persistent problem that impacts millions of users. Nonetheless, limited research has been conducted investigating to what extent a Facebook user’s personality influences their awareness of such surveillance practices. Thus, to understand this situation better, the current study inductively developed four propositions from secondary data sources as part of a detailed content analysis. Spanning three search and analysis phases the content analysis led to the development of the research model. Guided by the propositions and research questions, a questionnaire was developed based on the relevant constructs prescribed by the Theory of Planned Behaviour. This questionnaire was used, and a total of 651 responses were collected from Facebook users over the age of 18 years old and residing in the United States of America. Primary data took place at both a univariate and multivariate level with a specific focus on the development of a structural model. Interpretation of the structural model revealed that out of all the Big Five personality traits, Conscientiousness exhibited the strongest relationship with information security awareness followed by Openness to Experience and Neuroticism, respectively. The results further indicated that the model constructs based on attitude, social norms and awareness significantly influenced the intended use of Facebook Apps. The study also contributes by indicating which personality traits are most vulnerable to Facebook App surveillance. For example, it was found that individuals high in Conscientiousness are the least vulnerable with individuals high in Extraversion being the most vulnerable. Since the results indicate that not all the personality traits are significantly related to the model constructs, additional factors may contribute to App surveillance in this context. Concerning this, factors such as user apathy, information privacy, privacy concerns, control and Facebook dependency are discussed as a means to argue why this might be the case.
- Full Text:
- Date Issued: 2020
“Don’t be alarmed. It’s to do with sex.” Sherlock Holmes fanfiction and freedom of the imaginary domain
- Authors: van der Nest, Megan
- Date: 2020
- Subjects: Fan fiction , Fans (Persons) -- Fiction , Holmes, Sherlock , Literature and the internet , Sex in literature
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/124208 , vital:35576
- Description: In this thesis I argue that, for the individual fan, reading and writing fanfiction texts, and engaging with the online fandom communities within which these texts are produced, is a potentially valuable experience. This is because the kind of social and creative spaces found in these communities allow for, and celebrate, the free imaginative play with romantic and sexual desires, identities, and relationships. To articulate the importance of these spaces, I draw on Drucilla Cornell’s concept of the imaginary domain, defined as the psychic space each individual uses to explore different sexual desires and personae, which exploration is necessary for the development of full personhood. I also argue that the growing visibility and influence of fandom in modern society means that it could serve as a mechanism for social change, particularly in the acceptance and support of multiple sexual identities and forms of love. Selected texts, drawn from the Sherlock fandom, are discussed as representative of the approach taken within fanfiction communities towards various aspects of sexuality and sexual ethics. This approach combines the enthusiastic exploration of sexual desires without shame or fear of judgment with an ongoing, critical interrogation of sexual ethics.
- Full Text:
- Date Issued: 2020
- Authors: van der Nest, Megan
- Date: 2020
- Subjects: Fan fiction , Fans (Persons) -- Fiction , Holmes, Sherlock , Literature and the internet , Sex in literature
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/124208 , vital:35576
- Description: In this thesis I argue that, for the individual fan, reading and writing fanfiction texts, and engaging with the online fandom communities within which these texts are produced, is a potentially valuable experience. This is because the kind of social and creative spaces found in these communities allow for, and celebrate, the free imaginative play with romantic and sexual desires, identities, and relationships. To articulate the importance of these spaces, I draw on Drucilla Cornell’s concept of the imaginary domain, defined as the psychic space each individual uses to explore different sexual desires and personae, which exploration is necessary for the development of full personhood. I also argue that the growing visibility and influence of fandom in modern society means that it could serve as a mechanism for social change, particularly in the acceptance and support of multiple sexual identities and forms of love. Selected texts, drawn from the Sherlock fandom, are discussed as representative of the approach taken within fanfiction communities towards various aspects of sexuality and sexual ethics. This approach combines the enthusiastic exploration of sexual desires without shame or fear of judgment with an ongoing, critical interrogation of sexual ethics.
- Full Text:
- Date Issued: 2020
Resource Allocation Framework in Fog Computing for the Internet of Things Environments
- Authors: Vambe, William Tichaona
- Date: 2020
- Subjects: Internet of things Cloud computing
- Language: English
- Type: Thesis , Doctoral , PhD (Computer Science)
- Identifier: http://hdl.handle.net/10353/18498 , vital:42575
- Description: Fog computing plays a pivotal role in the Internet of Things (IoT) ecosystem because of its ability to support delay-sensitive tasks, bringing resources from cloud servers closer to the “ground” and support IoT devices that are resource-constrained. Although fog computing offers some benefits such as quick response to requests, geo-distributed data processing and data processing in the proximity of the IoT devices, the exponential increase of IoT devices and large volumes of data being generated has led to a new set of challenges. One such problem is the allocation of resources to IoT tasks to match their computational needs and quality of service (QoS) requirements, whilst meeting both task deadlines and user expectations. Most proposed solutions in existing works suggest task offloading mechanisms where IoT devices would offload their tasks randomly to the fog layer or cloud layer. This helps in minimizing the communication delay; however, most tasks would end up missing their deadlines as many delays are experienced during offloading. This study proposes and introduces a Resource Allocation Scheduler (RAS) at the IoT-Fog gateway, whose goal is to decide where and when a task is to be offloaded, either to the fog layer, or the cloud layer based on their priority needs, computational needs and QoS requirements. The aim directly places work within the communication networks domain, in the transport layer of the Open Systems Interconnection (OSI) model. As such, this study follows the four phases of the top-down approach because of its reusability characteristics. To validate and test the efficiency and effectiveness of the RAS, the fog framework was implemented and evaluated in a simulated smart home setup. The essential metrics that were used to check if round-trip time was minimized are the queuing time, offloading time and throughput for QoS. The results showed that the RAS helps to reduce the round-trip time, increases throughput and leads to improved QoS. Furthermore, the approach addressed the starvation problem, a phenomenon that tends to affect low priority tasks. Most importantly, the results provides evidence that if resource allocation and assignment are appropriately done, round-trip time can be reduced and QoS can be improved in fog computing. The significant contribution of this research is the novel framework which minimizes round-trip time, addresses the starvation problem and improves QoS. Moreover, a literature reviewed paper which was regarded by reviewers as the first, as far as QoS in fog computing is concerned was produced.
- Full Text:
- Date Issued: 2020
- Authors: Vambe, William Tichaona
- Date: 2020
- Subjects: Internet of things Cloud computing
- Language: English
- Type: Thesis , Doctoral , PhD (Computer Science)
- Identifier: http://hdl.handle.net/10353/18498 , vital:42575
- Description: Fog computing plays a pivotal role in the Internet of Things (IoT) ecosystem because of its ability to support delay-sensitive tasks, bringing resources from cloud servers closer to the “ground” and support IoT devices that are resource-constrained. Although fog computing offers some benefits such as quick response to requests, geo-distributed data processing and data processing in the proximity of the IoT devices, the exponential increase of IoT devices and large volumes of data being generated has led to a new set of challenges. One such problem is the allocation of resources to IoT tasks to match their computational needs and quality of service (QoS) requirements, whilst meeting both task deadlines and user expectations. Most proposed solutions in existing works suggest task offloading mechanisms where IoT devices would offload their tasks randomly to the fog layer or cloud layer. This helps in minimizing the communication delay; however, most tasks would end up missing their deadlines as many delays are experienced during offloading. This study proposes and introduces a Resource Allocation Scheduler (RAS) at the IoT-Fog gateway, whose goal is to decide where and when a task is to be offloaded, either to the fog layer, or the cloud layer based on their priority needs, computational needs and QoS requirements. The aim directly places work within the communication networks domain, in the transport layer of the Open Systems Interconnection (OSI) model. As such, this study follows the four phases of the top-down approach because of its reusability characteristics. To validate and test the efficiency and effectiveness of the RAS, the fog framework was implemented and evaluated in a simulated smart home setup. The essential metrics that were used to check if round-trip time was minimized are the queuing time, offloading time and throughput for QoS. The results showed that the RAS helps to reduce the round-trip time, increases throughput and leads to improved QoS. Furthermore, the approach addressed the starvation problem, a phenomenon that tends to affect low priority tasks. Most importantly, the results provides evidence that if resource allocation and assignment are appropriately done, round-trip time can be reduced and QoS can be improved in fog computing. The significant contribution of this research is the novel framework which minimizes round-trip time, addresses the starvation problem and improves QoS. Moreover, a literature reviewed paper which was regarded by reviewers as the first, as far as QoS in fog computing is concerned was produced.
- Full Text:
- Date Issued: 2020
A narrative study of students’ and staff’s experiences of living with HIV and AIDS at Rhodes University
- Authors: Tsope, Lindiwe
- Date: 2021-04
- Subjects: AIDS (Disease) South Africa Makhanda , HIV infections South Africa Makhanda , College students Health and hygiene South Africa Makhanda , Universities and colleges South Africa Makhanda Employees Health and hygiene , Stigma (Social psychology) , AIDS (Disease) Social aspects South Africa Makhanda , HIV infections Social aspects South Africa Makhanda , AIDS (Disease) Psychological aspects , HIV infections Psychological aspects , Health counseling South Africa Makhanda , Discourse analysis, Narrative
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/176894 , vital:42769 , 10.21504/10962/176894
- Description: A narrative study of students’ and staff’s experiences of living with HIV and AIDS at Rhodes University Research on HIV and AIDS in university settings, especially research exploring the experience of living with the disease, has been minimal. As a response to the knowledge and research gaps, this thesis is a qualitative study involving students and staff living with HIV (LWH) and accessing treatment (ART) at the Rhodes University Health Care Centre. This study explored the personal and social symbolisms as well as meanings attached to living with HIV, through in-depth interviews with ten students and staff living with HIV, all purposively sampled and recruited through the Rhodes University Health Care Centre. Using social constructionism, symbolic interactionism and the theory of biographical disruption, the narratives revealed a positive and inspirational side of living with HIV and AIDS – especially emphasizing that PLWHA do not have to surrender to the deadly narrative of the disease. It became evident that stigma, both internal and external, largely influences illness narratives. Furthermore, the study revealed the social reconstruction of life narratives both in order to understand the illness in terms of past social experiences and to reaffirm the impression that life has a course and the self has a purpose. All participants found that accessing treatment from the Rhodes University Health Care Centre positively influenced their experiences of adherence and reconstruction of narratives. The study indicates that HIV-related interventions in place at the university need to pay more attention to the psychosocial needs of PLWH, involvement of PWLH, as well as keeping up with the continuously changing global HIV narrative. The study argues for more attention to in-depth experiences and personal narratives in HIV and AIDS, and PLWHA education at Rhodes University. , Thesis (PhD) -- Humanities, Department of Sociology, 2021
- Full Text:
- Date Issued: 2021-04
- Authors: Tsope, Lindiwe
- Date: 2021-04
- Subjects: AIDS (Disease) South Africa Makhanda , HIV infections South Africa Makhanda , College students Health and hygiene South Africa Makhanda , Universities and colleges South Africa Makhanda Employees Health and hygiene , Stigma (Social psychology) , AIDS (Disease) Social aspects South Africa Makhanda , HIV infections Social aspects South Africa Makhanda , AIDS (Disease) Psychological aspects , HIV infections Psychological aspects , Health counseling South Africa Makhanda , Discourse analysis, Narrative
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/176894 , vital:42769 , 10.21504/10962/176894
- Description: A narrative study of students’ and staff’s experiences of living with HIV and AIDS at Rhodes University Research on HIV and AIDS in university settings, especially research exploring the experience of living with the disease, has been minimal. As a response to the knowledge and research gaps, this thesis is a qualitative study involving students and staff living with HIV (LWH) and accessing treatment (ART) at the Rhodes University Health Care Centre. This study explored the personal and social symbolisms as well as meanings attached to living with HIV, through in-depth interviews with ten students and staff living with HIV, all purposively sampled and recruited through the Rhodes University Health Care Centre. Using social constructionism, symbolic interactionism and the theory of biographical disruption, the narratives revealed a positive and inspirational side of living with HIV and AIDS – especially emphasizing that PLWHA do not have to surrender to the deadly narrative of the disease. It became evident that stigma, both internal and external, largely influences illness narratives. Furthermore, the study revealed the social reconstruction of life narratives both in order to understand the illness in terms of past social experiences and to reaffirm the impression that life has a course and the self has a purpose. All participants found that accessing treatment from the Rhodes University Health Care Centre positively influenced their experiences of adherence and reconstruction of narratives. The study indicates that HIV-related interventions in place at the university need to pay more attention to the psychosocial needs of PLWH, involvement of PWLH, as well as keeping up with the continuously changing global HIV narrative. The study argues for more attention to in-depth experiences and personal narratives in HIV and AIDS, and PLWHA education at Rhodes University. , Thesis (PhD) -- Humanities, Department of Sociology, 2021
- Full Text:
- Date Issued: 2021-04
Resource recovery options in brewery effluent treatment using activated sludge and high rate algal ponds: assessing environmental impacts
- Authors: Taylor, Richard Peter
- Date: 2020
- Subjects: Sewage -- Purification -- Activated sludge process , Sewage disposal plants , Sewage -- Purification -- Biological treatament , Sewage -- Purification -- Nitrogen removal , Brewery waste , Breweries -- Waste disposal , Microalgae -- Biotechnology , Algal biofuels
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/153746 , vital:39507
- Description: Wastewater treatment plants (WWTPs) are designed to clean effluents, but they also consume resources and produce waste. Various treatment technologies allow for the recovery of energy, nutrients and water from effluents turning this waste into products, which increases their sustainability and decreases the impact of WWTPs on the environment. There is a lack of literature which comprehensively compares the treatment performances, environmental impacts and beneficial downstream uses of the biomass generated by high rate algal pond (HRAP) and activated sludge (AS) treatment systems. This thesis aimed to compare (1) effluent treatment performance, (2) emissions and (3) downstream use of algae cultured in HRAP to sludge produced in AS and to obtain data to conduct a life cycle analysis (LCA) to compare the systems. The focus was on adding value to the effluent treatment process, while identifying the associated environmental impacts and contributing to the first ever zero-waste brewery effluent treatment system. Furthermore, these data were used to provide a basis to critically review and contribute to improving the methods used in the LCA of effluent treatment systems; particularly since this was the first wastewater treatment LCA that compared AS and HRAP using data collected from the same temporal and geographic location and from a single effluent stream. The electrical consumption water emission and land application of waste biomass caused the major environmental impacts of both treatment systems. The HRAP had less than 50 % of the electrical energy consumption (0.11±0.01 kW/m3 of effluent treated) compared to the AS system (0.29±0.11 kW/m3) which resulted in the technology having a lower climate change, photochemical oxidant formation, freshwater and marine ecotoxicity and fossil fuel depletion impact. It is imperative to understand the method of electrical energy (fossil fuel vs renewable) generation when conducting a LCA and deciding which technologies to use, since they have a major influence on the aforementioned impacts. The biogas yield of algal and sludge substrates was similar with an average gas production of 241 ml/g volatile solids fed. Biogas from algae fed digesters had a significantly higher methane content (64.73±0.81 %) and lower carbon dioxide content (22.94±0.24 %) when compared to WAS fed digesters (60.08±0.18 % and 27.37±0.43 %) respectively due to it being a less oxidised substrate. Swiss chard plants (Beta vulgaris) fertilised with anaerobically digested (AD) algae or sludge had a significantly higher mean biweekly yield (5.08±0.73 kg/m2) when compared to the inorganic-fertiliser control (3.45±0.89 kg/m2; p<0.0001). No difference was observed in the soil’s physical fertility when algae or sludge were applied to the soil (p>0.05). The HRAP produced more biomass (317.18±27.76 g/m3) than the AS (83.12±64.91 g/m3), which resulted in a significantly greater downstream production of biogas and fertiliser per volume of effluent treated. According to the LCA, this also resulted in the HRAP system having a higher terrestrial ecotoxicity, due to the greater volume of solids and thus heavy metals applied to the soil. This interpretation can be misleading, because the mass of heavy metals released into the environment is the same for both systems, with a greater portion being applied to the land in the HRAP scenario and discharged into fresh water in the case of AS. Future LCA models should clarify if these biomasses are going to be applied to a single piece of land or multiple sites as this will influence the risk of contamination via pollutant build up in the soil. The application of sludge or algae on soil increased the soil’s sodium concentration and sodium absorption ratio from 774.80±13.66 mg/kg to 952.17±34.89 mg/kg and 2.91±0.04 to 3.53±0.13, respectively. Regulations on the application of algae or sludge on agricultural soils should be altered to consider the limit values for sodium and future LCA’s associated with effluent treatment facilities should incorporate the possibility of soil contamination through sodium build-up. This work also conceptualised the importance of reporting water emissions in wastewater treatment LCA in as much detail as possible, because this had a significant influence on the eutrophication impacts on water systems. Reporting water emissions as total nitrogen underestimated downstream eutrophication impacts compared with those using nitrogen-species concentration (ammonia, nitrite, nitrate etc). A marine eutrophication sensitivity co-efficient should be included in future LCA models which accounts for the probability of nitrogen and phosphorus emissions entering the coastal environment as well as the vulnerability of the marine environment to eutrophication. Activated sludge systems are favourable for situations where space is limited, were there are inadequate options for biomass disposal (biomass not be used in agriculture or AD) and were electricity is generated from a renewable source; whereas, HRAP are more suitable under circumstances where electricity production relies on fossil fuel that carries a high environmental impact and where options are available to use the biomass for economic gain such as biogas and fertiliser production. This thesis contributes towards a zero-waste brewery effluent treated process. The HRAP and AS treated effluent for reuse in the brewery or in agricultural irrigation. The solids were anaerobically digested, and the carbon was recovered as a biogas, while the digestate was applied as an agricultural fertiliser. This allowed for the recovery of water, nutrients and carbon.
- Full Text:
- Date Issued: 2020
- Authors: Taylor, Richard Peter
- Date: 2020
- Subjects: Sewage -- Purification -- Activated sludge process , Sewage disposal plants , Sewage -- Purification -- Biological treatament , Sewage -- Purification -- Nitrogen removal , Brewery waste , Breweries -- Waste disposal , Microalgae -- Biotechnology , Algal biofuels
- Language: English
- Type: text , Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/153746 , vital:39507
- Description: Wastewater treatment plants (WWTPs) are designed to clean effluents, but they also consume resources and produce waste. Various treatment technologies allow for the recovery of energy, nutrients and water from effluents turning this waste into products, which increases their sustainability and decreases the impact of WWTPs on the environment. There is a lack of literature which comprehensively compares the treatment performances, environmental impacts and beneficial downstream uses of the biomass generated by high rate algal pond (HRAP) and activated sludge (AS) treatment systems. This thesis aimed to compare (1) effluent treatment performance, (2) emissions and (3) downstream use of algae cultured in HRAP to sludge produced in AS and to obtain data to conduct a life cycle analysis (LCA) to compare the systems. The focus was on adding value to the effluent treatment process, while identifying the associated environmental impacts and contributing to the first ever zero-waste brewery effluent treatment system. Furthermore, these data were used to provide a basis to critically review and contribute to improving the methods used in the LCA of effluent treatment systems; particularly since this was the first wastewater treatment LCA that compared AS and HRAP using data collected from the same temporal and geographic location and from a single effluent stream. The electrical consumption water emission and land application of waste biomass caused the major environmental impacts of both treatment systems. The HRAP had less than 50 % of the electrical energy consumption (0.11±0.01 kW/m3 of effluent treated) compared to the AS system (0.29±0.11 kW/m3) which resulted in the technology having a lower climate change, photochemical oxidant formation, freshwater and marine ecotoxicity and fossil fuel depletion impact. It is imperative to understand the method of electrical energy (fossil fuel vs renewable) generation when conducting a LCA and deciding which technologies to use, since they have a major influence on the aforementioned impacts. The biogas yield of algal and sludge substrates was similar with an average gas production of 241 ml/g volatile solids fed. Biogas from algae fed digesters had a significantly higher methane content (64.73±0.81 %) and lower carbon dioxide content (22.94±0.24 %) when compared to WAS fed digesters (60.08±0.18 % and 27.37±0.43 %) respectively due to it being a less oxidised substrate. Swiss chard plants (Beta vulgaris) fertilised with anaerobically digested (AD) algae or sludge had a significantly higher mean biweekly yield (5.08±0.73 kg/m2) when compared to the inorganic-fertiliser control (3.45±0.89 kg/m2; p<0.0001). No difference was observed in the soil’s physical fertility when algae or sludge were applied to the soil (p>0.05). The HRAP produced more biomass (317.18±27.76 g/m3) than the AS (83.12±64.91 g/m3), which resulted in a significantly greater downstream production of biogas and fertiliser per volume of effluent treated. According to the LCA, this also resulted in the HRAP system having a higher terrestrial ecotoxicity, due to the greater volume of solids and thus heavy metals applied to the soil. This interpretation can be misleading, because the mass of heavy metals released into the environment is the same for both systems, with a greater portion being applied to the land in the HRAP scenario and discharged into fresh water in the case of AS. Future LCA models should clarify if these biomasses are going to be applied to a single piece of land or multiple sites as this will influence the risk of contamination via pollutant build up in the soil. The application of sludge or algae on soil increased the soil’s sodium concentration and sodium absorption ratio from 774.80±13.66 mg/kg to 952.17±34.89 mg/kg and 2.91±0.04 to 3.53±0.13, respectively. Regulations on the application of algae or sludge on agricultural soils should be altered to consider the limit values for sodium and future LCA’s associated with effluent treatment facilities should incorporate the possibility of soil contamination through sodium build-up. This work also conceptualised the importance of reporting water emissions in wastewater treatment LCA in as much detail as possible, because this had a significant influence on the eutrophication impacts on water systems. Reporting water emissions as total nitrogen underestimated downstream eutrophication impacts compared with those using nitrogen-species concentration (ammonia, nitrite, nitrate etc). A marine eutrophication sensitivity co-efficient should be included in future LCA models which accounts for the probability of nitrogen and phosphorus emissions entering the coastal environment as well as the vulnerability of the marine environment to eutrophication. Activated sludge systems are favourable for situations where space is limited, were there are inadequate options for biomass disposal (biomass not be used in agriculture or AD) and were electricity is generated from a renewable source; whereas, HRAP are more suitable under circumstances where electricity production relies on fossil fuel that carries a high environmental impact and where options are available to use the biomass for economic gain such as biogas and fertiliser production. This thesis contributes towards a zero-waste brewery effluent treated process. The HRAP and AS treated effluent for reuse in the brewery or in agricultural irrigation. The solids were anaerobically digested, and the carbon was recovered as a biogas, while the digestate was applied as an agricultural fertiliser. This allowed for the recovery of water, nutrients and carbon.
- Full Text:
- Date Issued: 2020
The Influence of Clientelism on the Informal Sector in Zimbabwe : a Case Study of Glen View 8 Complex, Harare
- Authors: Tandire, Justin
- Date: 2021-04
- Subjects: Patron and client -- Zimbabwe -- Harare , Informal sector (Economics) -- Zimbabwe -- Harare , Informal sector (Economics) -- Political aspects -- Zimbabwe -- Harare , Patronage, Political -- Zimbabwe -- Harare , ZANU-PF (Organization : Zimbabwe) , Zimbabwe -- Social conditions , Glen View Complex 8 (Zimbabwe)
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/177986 , vital:42896 , 10.21504/10962/177986
- Description: This study focuses on the influence of clientelism in the informal sector of Zimbabwe in Glen View 8 (Complex). The study used the case of Glen view 8 (complex) in Harare Province. The study focused on political dynamics in the informal sector; livelihood strategies employed by informal sector operators; manifestation of “Big Men”, social networks in the informal sector; and different strategies employed by operators to overcome the problems of political manipulation, clientelism and patronage. It employs a qualitative research methodology to enable a nuanced comprehension of the clientelistic relationships that take place in the informal sector of Zimbabwe. Through in-depth interviews, focus group discussions, narratives and in-depth interviews with key informants, the study explored the clientelistic nature of the informal sector. The major findings of the study are that the informal sector in Zimbabwe is influenced by political patronage. It was established that patronage influences the informal sector in Zimbabwe in general and at Glen View Complex 8 in particular. Some of the operators revealed that patronage negatively affects their business as they are sometimes forced to attend political party meetings either at the complex or at ZANU-PF star rallies in town. The operators experience a plethora of problems such as lack of security, poor sanitation, stiff competition, poor infrastructure, lack of insurance and fire outbreaks. It has been revealed that most of the problems experienced at the complex are a result of the politicisation of the informal sector particularly by the ZANU-PF party. Operators at the complex have described the politicisation of the informal sector as a major drawback to their efforts of realising maximum benefits from their work. Therefore, the thrust of this thesis is premised on the de-politicisation of the informal sector as the starting point in the transformation of the activities of the operators. , Thesis (PhD) -- Faculty of Humanities, Sociology, 2021
- Full Text:
- Date Issued: 2021-04
- Authors: Tandire, Justin
- Date: 2021-04
- Subjects: Patron and client -- Zimbabwe -- Harare , Informal sector (Economics) -- Zimbabwe -- Harare , Informal sector (Economics) -- Political aspects -- Zimbabwe -- Harare , Patronage, Political -- Zimbabwe -- Harare , ZANU-PF (Organization : Zimbabwe) , Zimbabwe -- Social conditions , Glen View Complex 8 (Zimbabwe)
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/177986 , vital:42896 , 10.21504/10962/177986
- Description: This study focuses on the influence of clientelism in the informal sector of Zimbabwe in Glen View 8 (Complex). The study used the case of Glen view 8 (complex) in Harare Province. The study focused on political dynamics in the informal sector; livelihood strategies employed by informal sector operators; manifestation of “Big Men”, social networks in the informal sector; and different strategies employed by operators to overcome the problems of political manipulation, clientelism and patronage. It employs a qualitative research methodology to enable a nuanced comprehension of the clientelistic relationships that take place in the informal sector of Zimbabwe. Through in-depth interviews, focus group discussions, narratives and in-depth interviews with key informants, the study explored the clientelistic nature of the informal sector. The major findings of the study are that the informal sector in Zimbabwe is influenced by political patronage. It was established that patronage influences the informal sector in Zimbabwe in general and at Glen View Complex 8 in particular. Some of the operators revealed that patronage negatively affects their business as they are sometimes forced to attend political party meetings either at the complex or at ZANU-PF star rallies in town. The operators experience a plethora of problems such as lack of security, poor sanitation, stiff competition, poor infrastructure, lack of insurance and fire outbreaks. It has been revealed that most of the problems experienced at the complex are a result of the politicisation of the informal sector particularly by the ZANU-PF party. Operators at the complex have described the politicisation of the informal sector as a major drawback to their efforts of realising maximum benefits from their work. Therefore, the thrust of this thesis is premised on the de-politicisation of the informal sector as the starting point in the transformation of the activities of the operators. , Thesis (PhD) -- Faculty of Humanities, Sociology, 2021
- Full Text:
- Date Issued: 2021-04
Development of Tio 2 nanostructure arrays for photonic extraction of hydrogen gas
- Authors: Suliali, Nyasha Joseph
- Date: 2020
- Subjects: Nanostructures , Nanostructured materials Hydrogen
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/49314 , vital:41620
- Description: Amid the energy crisis of the 21st century, renewable energy is a thriving field of study, light harvesting materials being a central theme due to the abundance of solar energy. Nanostructured TiO2 is the most studied photocatalysis material, since the discovery of its energy harvesting properties by Fujishima and Honda in 1972. Environmentally friendly products such as hydrogen fuel, can be produced using TiO2 due to its non-toxicity, chemical stability and photocatalytic activity. The surprising aspect of this important material is that it can be prepared using cost-effective methods such as hydrothermal synthesis, solution gelation and anodic oxidation. This research focused on the three key elements required to develop TiO2 photoelectrodes i.e. the deposition of Ti films on transparent substrates, a thorough analysis of the chemistry of the anodic oxidation process and the development of the TiO2 thin films. Glass substrates that have Ti films are the base component for TiO2 photoelectrode production. Ti films with thicknesses up to 4 μm, were developed on commercial F-doped SnO2 (FTO) glass substrates using high-power impulse magnetron sputtering (HiPIMS). The sputter deposition experiments were performed in the 1 to 8 kW range at a substrate temperature of 500 °C and Ar pressure of 400 mPa. At higher powers, thicker films were deposited, resulting in increased intensity of Xray-diffraction peaks. However, on comparing the XRD patterns, the (001) peak outgrew the rest regardless of thickness of the film. The deposition process therefore favoured orientation of most of the α-Ti phase crystallites with the [001] axis perpendicular to the substrate surface. Surface roughness results were interesting, showing a non-linear dependence of the surface roughness on HiPIMS pulse energy in the 1 to 8 kW range. The surface roughness is highest at the starting deposition power of 1450 W and reduces to a minimum at 4500 W. From this minimum, it increases to its second highest value at 7900 W. From this data, the parameters required to produce Ti films of lowest surface roughness, for deposition on commercial Technistro® FTO glass, were deduced at the inflection point, where the deposition power was 4500 W. The surface roughness obtained is a critical result for the anodic production of quality TiO2 photoelectrodes, which if high, leads to uneven etching, thus irregular and inefficient photoelectrodes. Direct current magnetron sputtering was also carried out in the 1 to 5 kW range to obtain ratios of power-normalised growth rates of the Ti films. This investigation provided the Ti films on FTO glass, the transparent, conductive substrates which were used to develop TiO2 photoelectrodes. To elucidate the chemistry of anodic oxidation of Ti, a mathematical model of the anodic current density, which had not been reported at the time of its publication, was developed. The technique, a highlight of this research, is a predictive numerical computation of the instantaneous quantities of species that participate in the anodization process. From eleven chemical reactions, 14 first order ordinary differential equations were compiled using the principles of chemical reaction kinetics. The pattern, transient behaviour and response to anodization parameters of the current density signal, were successfully predicted. Strong agreement between the model and measurements was demonstrated in seven experiments. The results confirm that the current density signal is a numerical integral of the kinetics of redox reactions of water. The bulk of this research was on the development of TiO2 nanotubular arrays on Ti foil substrates and Ti films on FTO glass. TiO2 films with well-defined tubular structures were synthesised. The films were developed in anhydrous, polar organic hosts with water and etching agents in the range of 10 V to 70 V. The control of geometrical properties of the tubes such as the length, pore diameter, wall thickness, tube separation and number of nanotubes per unit area was demonstrated. Anatase only and mixed anatase-rutile phase compositions were obtained at different annealing temperatures. Nanotubes with diameters as small as 20 nm and thickness as high as 29 μm were produced. Apart from an increase in nanotube thickness, a decrease in distance between nanotubes grown in diethylene glycol was observed at longer anodization times. Studies of the effects of anodization parameters on the current density measured, morphological and crystallographic properties of the nanotube films were conducted in three main investigations. The first was the study of the effect of anodization parameters on current density. Besides the obvious increase of current density with anodic voltage, the first steady state of the growth process was found to depend on the NH4F concentration. The second investigation focused on the effect of accelerated growth of TiO2 nanotubular films. In the study, 9 μm-thick nanotube films were synthesised at twice the growth rate of a 9 μm-thick control sample. The array obtained by accelerated growth had distinguishable nanotubes, however, the morphological quality was reduced. The third investigation demonstrates the control of the number of nanotubes per unit area. By varying the etchant content, the anodic voltage and the viscosity of the electrolyte host, various distributions were obtained. The research ends with a photoelectrochemical application: measurement on photocurrents generated in a two-electrode setup. The photocurrent densities measured in the off and on conditions were 30 nA/cm2 and 2.57 μA/cm2, respectively, demonstrating photoactivity of the developed films.
- Full Text:
- Date Issued: 2020
- Authors: Suliali, Nyasha Joseph
- Date: 2020
- Subjects: Nanostructures , Nanostructured materials Hydrogen
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10948/49314 , vital:41620
- Description: Amid the energy crisis of the 21st century, renewable energy is a thriving field of study, light harvesting materials being a central theme due to the abundance of solar energy. Nanostructured TiO2 is the most studied photocatalysis material, since the discovery of its energy harvesting properties by Fujishima and Honda in 1972. Environmentally friendly products such as hydrogen fuel, can be produced using TiO2 due to its non-toxicity, chemical stability and photocatalytic activity. The surprising aspect of this important material is that it can be prepared using cost-effective methods such as hydrothermal synthesis, solution gelation and anodic oxidation. This research focused on the three key elements required to develop TiO2 photoelectrodes i.e. the deposition of Ti films on transparent substrates, a thorough analysis of the chemistry of the anodic oxidation process and the development of the TiO2 thin films. Glass substrates that have Ti films are the base component for TiO2 photoelectrode production. Ti films with thicknesses up to 4 μm, were developed on commercial F-doped SnO2 (FTO) glass substrates using high-power impulse magnetron sputtering (HiPIMS). The sputter deposition experiments were performed in the 1 to 8 kW range at a substrate temperature of 500 °C and Ar pressure of 400 mPa. At higher powers, thicker films were deposited, resulting in increased intensity of Xray-diffraction peaks. However, on comparing the XRD patterns, the (001) peak outgrew the rest regardless of thickness of the film. The deposition process therefore favoured orientation of most of the α-Ti phase crystallites with the [001] axis perpendicular to the substrate surface. Surface roughness results were interesting, showing a non-linear dependence of the surface roughness on HiPIMS pulse energy in the 1 to 8 kW range. The surface roughness is highest at the starting deposition power of 1450 W and reduces to a minimum at 4500 W. From this minimum, it increases to its second highest value at 7900 W. From this data, the parameters required to produce Ti films of lowest surface roughness, for deposition on commercial Technistro® FTO glass, were deduced at the inflection point, where the deposition power was 4500 W. The surface roughness obtained is a critical result for the anodic production of quality TiO2 photoelectrodes, which if high, leads to uneven etching, thus irregular and inefficient photoelectrodes. Direct current magnetron sputtering was also carried out in the 1 to 5 kW range to obtain ratios of power-normalised growth rates of the Ti films. This investigation provided the Ti films on FTO glass, the transparent, conductive substrates which were used to develop TiO2 photoelectrodes. To elucidate the chemistry of anodic oxidation of Ti, a mathematical model of the anodic current density, which had not been reported at the time of its publication, was developed. The technique, a highlight of this research, is a predictive numerical computation of the instantaneous quantities of species that participate in the anodization process. From eleven chemical reactions, 14 first order ordinary differential equations were compiled using the principles of chemical reaction kinetics. The pattern, transient behaviour and response to anodization parameters of the current density signal, were successfully predicted. Strong agreement between the model and measurements was demonstrated in seven experiments. The results confirm that the current density signal is a numerical integral of the kinetics of redox reactions of water. The bulk of this research was on the development of TiO2 nanotubular arrays on Ti foil substrates and Ti films on FTO glass. TiO2 films with well-defined tubular structures were synthesised. The films were developed in anhydrous, polar organic hosts with water and etching agents in the range of 10 V to 70 V. The control of geometrical properties of the tubes such as the length, pore diameter, wall thickness, tube separation and number of nanotubes per unit area was demonstrated. Anatase only and mixed anatase-rutile phase compositions were obtained at different annealing temperatures. Nanotubes with diameters as small as 20 nm and thickness as high as 29 μm were produced. Apart from an increase in nanotube thickness, a decrease in distance between nanotubes grown in diethylene glycol was observed at longer anodization times. Studies of the effects of anodization parameters on the current density measured, morphological and crystallographic properties of the nanotube films were conducted in three main investigations. The first was the study of the effect of anodization parameters on current density. Besides the obvious increase of current density with anodic voltage, the first steady state of the growth process was found to depend on the NH4F concentration. The second investigation focused on the effect of accelerated growth of TiO2 nanotubular films. In the study, 9 μm-thick nanotube films were synthesised at twice the growth rate of a 9 μm-thick control sample. The array obtained by accelerated growth had distinguishable nanotubes, however, the morphological quality was reduced. The third investigation demonstrates the control of the number of nanotubes per unit area. By varying the etchant content, the anodic voltage and the viscosity of the electrolyte host, various distributions were obtained. The research ends with a photoelectrochemical application: measurement on photocurrents generated in a two-electrode setup. The photocurrent densities measured in the off and on conditions were 30 nA/cm2 and 2.57 μA/cm2, respectively, demonstrating photoactivity of the developed films.
- Full Text:
- Date Issued: 2020
Phytoplankton of the Southern Agulhas Large Marine Ecosystem (sACLME)
- Authors: Sonnekus, Martinus Jakobus
- Date: 2020
- Subjects: Botanical chemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/47646 , vital:40261
- Description: The southern Agulhas Large Marine Ecosystem (sACLME) consists of the greater Agulhas Current system, including the areas influenced by the Agulhas Current, the Agulhas Shelf, Agulhas Bank, Agulhas Retroflection as well as the Agulhas Return Current. Four biogeographical regions were identified within the sACLME and the composition of the phytoplankton communities and the associated physico-chemical variables in each were investigated. Water temperature and nitrate concentration were found to be the main drivers of the sACLME phytoplankton community. A total of 215 phytoplankton taxa were identified that were separated into two groups: the Agulhas Current group and the Southwest Indian Ocean Ridge group. The structure of the phytoplankton community was consistently homogeneous throughout the sACLME. Nutrient concentrations of the water varied, but nitrate was the most abundant source of nitrogen, especially in regions that were subjected to the upwelling of cold nutrient-rich water. The phytoplankton communities were significantly influenced by the availability and stoichiometry of the macronutrients nitrogen; phosphorus and silicon. The low mean N:P ratio of 5.5 is an indication that the waters of the sACLME are generally nitrogen limited, as is typical of oceanic systems. There is a change in phytoplankton cell size and functional groups within in the various water masses that are specific to certain biogeographical regions within the Agulhas Current system. It is clear that frontal systems may form barriers between phytoplankton communities.
- Full Text:
- Date Issued: 2020
- Authors: Sonnekus, Martinus Jakobus
- Date: 2020
- Subjects: Botanical chemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/47646 , vital:40261
- Description: The southern Agulhas Large Marine Ecosystem (sACLME) consists of the greater Agulhas Current system, including the areas influenced by the Agulhas Current, the Agulhas Shelf, Agulhas Bank, Agulhas Retroflection as well as the Agulhas Return Current. Four biogeographical regions were identified within the sACLME and the composition of the phytoplankton communities and the associated physico-chemical variables in each were investigated. Water temperature and nitrate concentration were found to be the main drivers of the sACLME phytoplankton community. A total of 215 phytoplankton taxa were identified that were separated into two groups: the Agulhas Current group and the Southwest Indian Ocean Ridge group. The structure of the phytoplankton community was consistently homogeneous throughout the sACLME. Nutrient concentrations of the water varied, but nitrate was the most abundant source of nitrogen, especially in regions that were subjected to the upwelling of cold nutrient-rich water. The phytoplankton communities were significantly influenced by the availability and stoichiometry of the macronutrients nitrogen; phosphorus and silicon. The low mean N:P ratio of 5.5 is an indication that the waters of the sACLME are generally nitrogen limited, as is typical of oceanic systems. There is a change in phytoplankton cell size and functional groups within in the various water masses that are specific to certain biogeographical regions within the Agulhas Current system. It is clear that frontal systems may form barriers between phytoplankton communities.
- Full Text:
- Date Issued: 2020
A theory-based approach to evaluating a Continuing Teacher Professional Development Programme aimed at strengthening environment and sustainability education
- Authors: Songqwaru, Nonyameko Zintle
- Date: 2020
- Subjects: Fundisa for Change , Environmental education -- South Africa , Teachers -- Training of -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/145267 , vital:38423
- Description: This study uses a theory-based approach to evaluate the Fundisa for Change training programme, a continuing teacher professional development programme aimed at strengthening environment and sustainability education. The aim of the study was to surface assumptions that underpin the design and implementation of the Fundisa for Change training programme. The Fundisa for Change Teacher Education programme is a national collaborative programme that is implemented in all the nine provinces of South Africa. The study reports on the implementation of the programme in five provinces. The study aimed to surface the Fundisa for Change training programme’s implementation theory and programme theory as these affect programme delivery. The Fundisa for Change training programme was implemented in diverse contexts by different facilitators to different participants. To determine how training programme outcomes were achieved, use was made of context-mechanism-outcome (CMO) configurations for each site where the programme was implemented. Data used to construct CMO configurations was generated through document analysis of Fundisa for Change documents, interviews with stakeholders and participants, as well as observations of programme implementation at five sites. There were three phases to data analysis: content analysis of Fundisa for Change documents, content analysis of observation transcripts and use of the CMO configuration, an analytical tool used in realist evaluation. An initial CMO configuration was constructed prior to observing implementation of the programme and a refined CMO configuration for the Fundisa for Change training programme was constructed based on similarities between the CMO configurations constructed for each of the five sites under study. The partnership model of the Fundisa for Change training programme brought diverse expertise and resources (material, cognitive, social and emotional) which were conducive to the achievement of programme outcomes. The programme’s action context (structure, culture, agency and relations) contributed to the achievement of programme outcomes by participants. Participants’ subject content knowledge, teaching practice and assessment practice was enhanced through attending the Fundisa for Change training. On-course tasks were mediated during training and this created opportunities for participants to discuss and reflect on current practice in ways that could lead to a change in practice. In evaluating professional development programmes, an elaborated definition of context in terms of structure, culture, agency and relations enables a comprehensive exploration of potential programme mechanisms that can be activated when programmes are implemented. It is also important to disaggregate resources and reasons when identifying mechanisms as this assists with differentiating between context and mechanisms. The study offers insights into the professional learning of teachers grappling with new content and pedagogical content knowledges related to environment in the context of recent curriculum changes where the South African national school curriculum has come into focus. Environmental education programmes in South Africa have implicitly used a realist approach. This study offers the first substantive professional learning evaluation that develops this approach explicitly using Theory of Change and Realist Evaluation in combination.
- Full Text:
- Date Issued: 2020
- Authors: Songqwaru, Nonyameko Zintle
- Date: 2020
- Subjects: Fundisa for Change , Environmental education -- South Africa , Teachers -- Training of -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/145267 , vital:38423
- Description: This study uses a theory-based approach to evaluate the Fundisa for Change training programme, a continuing teacher professional development programme aimed at strengthening environment and sustainability education. The aim of the study was to surface assumptions that underpin the design and implementation of the Fundisa for Change training programme. The Fundisa for Change Teacher Education programme is a national collaborative programme that is implemented in all the nine provinces of South Africa. The study reports on the implementation of the programme in five provinces. The study aimed to surface the Fundisa for Change training programme’s implementation theory and programme theory as these affect programme delivery. The Fundisa for Change training programme was implemented in diverse contexts by different facilitators to different participants. To determine how training programme outcomes were achieved, use was made of context-mechanism-outcome (CMO) configurations for each site where the programme was implemented. Data used to construct CMO configurations was generated through document analysis of Fundisa for Change documents, interviews with stakeholders and participants, as well as observations of programme implementation at five sites. There were three phases to data analysis: content analysis of Fundisa for Change documents, content analysis of observation transcripts and use of the CMO configuration, an analytical tool used in realist evaluation. An initial CMO configuration was constructed prior to observing implementation of the programme and a refined CMO configuration for the Fundisa for Change training programme was constructed based on similarities between the CMO configurations constructed for each of the five sites under study. The partnership model of the Fundisa for Change training programme brought diverse expertise and resources (material, cognitive, social and emotional) which were conducive to the achievement of programme outcomes. The programme’s action context (structure, culture, agency and relations) contributed to the achievement of programme outcomes by participants. Participants’ subject content knowledge, teaching practice and assessment practice was enhanced through attending the Fundisa for Change training. On-course tasks were mediated during training and this created opportunities for participants to discuss and reflect on current practice in ways that could lead to a change in practice. In evaluating professional development programmes, an elaborated definition of context in terms of structure, culture, agency and relations enables a comprehensive exploration of potential programme mechanisms that can be activated when programmes are implemented. It is also important to disaggregate resources and reasons when identifying mechanisms as this assists with differentiating between context and mechanisms. The study offers insights into the professional learning of teachers grappling with new content and pedagogical content knowledges related to environment in the context of recent curriculum changes where the South African national school curriculum has come into focus. Environmental education programmes in South Africa have implicitly used a realist approach. This study offers the first substantive professional learning evaluation that develops this approach explicitly using Theory of Change and Realist Evaluation in combination.
- Full Text:
- Date Issued: 2020
Addressing flux suppression, radio frequency interference, and selection of optimal solution intervals during radio interferometric calibration
- Authors: Sob, Ulrich Armel Mbou
- Date: 2020
- Subjects: CubiCal (Software) , Radio -- Interference , Imaging systems in astronomy , Algorithms , Astronomical instruments -- Calibration , Astronomy -- Data processing
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/147714 , vital:38663
- Description: The forthcoming Square Kilometre Array is expected to provide answers to some of the most intriguing questions about our Universe. However, as it is already noticeable from MeerKAT and other precursors, the amounts of data produced by these new instruments are significantly challenging to calibrate and image. Calibration of radio interferometric data is usually biased by incomplete sky models and radio frequency interference (RFI) resulting in calibration artefacts that limit the dynamic range and image fidelity of the resulting images. One of the most noticeable of these artefacts is the formation of spurious sources which causes suppression of real emissions. Fortunately, it has been shown that calibration algorithms employing heavy-tailed likelihood functions are less susceptible to this due to their robustness against outliers. Leveraging on recent developments in the field of complex optimisation, we implement a robust calibration algorithm using a Student’s t likelihood function and Wirtinger derivatives. The new algorithm, dubbed the robust solver, is incorporated as a subroutine into the newly released calibration software package CubiCal. We perform statistical analysis on the distribution of visibilities and provide an insight into the functioning of the robust solver and describe different scenarios where it will improve calibration. We use simulations to show that the robust solver effectively reduces the amount of flux suppressed from unmodelled sources both in direction independent and direction dependent calibration. Furthermore, the robust solver is shown to successfully mitigate the effects of low-level RFI when applied to a simulated and a real VLA dataset. Finally, we demonstrate that there are close links between the amount of flux suppressed from sources, the effects of the RFI and the employed solution interval during radio interferometric calibration. Hence, we investigate the effects of solution intervals and the different factors to consider in order to select adequate solution intervals. Furthermore, we propose a practical brute force method for selecting optimal solution intervals. The proposed method is successfully applied to a VLA dataset.
- Full Text:
- Date Issued: 2020
- Authors: Sob, Ulrich Armel Mbou
- Date: 2020
- Subjects: CubiCal (Software) , Radio -- Interference , Imaging systems in astronomy , Algorithms , Astronomical instruments -- Calibration , Astronomy -- Data processing
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/147714 , vital:38663
- Description: The forthcoming Square Kilometre Array is expected to provide answers to some of the most intriguing questions about our Universe. However, as it is already noticeable from MeerKAT and other precursors, the amounts of data produced by these new instruments are significantly challenging to calibrate and image. Calibration of radio interferometric data is usually biased by incomplete sky models and radio frequency interference (RFI) resulting in calibration artefacts that limit the dynamic range and image fidelity of the resulting images. One of the most noticeable of these artefacts is the formation of spurious sources which causes suppression of real emissions. Fortunately, it has been shown that calibration algorithms employing heavy-tailed likelihood functions are less susceptible to this due to their robustness against outliers. Leveraging on recent developments in the field of complex optimisation, we implement a robust calibration algorithm using a Student’s t likelihood function and Wirtinger derivatives. The new algorithm, dubbed the robust solver, is incorporated as a subroutine into the newly released calibration software package CubiCal. We perform statistical analysis on the distribution of visibilities and provide an insight into the functioning of the robust solver and describe different scenarios where it will improve calibration. We use simulations to show that the robust solver effectively reduces the amount of flux suppressed from unmodelled sources both in direction independent and direction dependent calibration. Furthermore, the robust solver is shown to successfully mitigate the effects of low-level RFI when applied to a simulated and a real VLA dataset. Finally, we demonstrate that there are close links between the amount of flux suppressed from sources, the effects of the RFI and the employed solution interval during radio interferometric calibration. Hence, we investigate the effects of solution intervals and the different factors to consider in order to select adequate solution intervals. Furthermore, we propose a practical brute force method for selecting optimal solution intervals. The proposed method is successfully applied to a VLA dataset.
- Full Text:
- Date Issued: 2020