“Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
- Shumba, Munyaradzi, Mashazi, Philani N, Nyokong, Tebello
- Authors: Shumba, Munyaradzi , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240875 , vital:50881 , xlink:href="https://doi.org/10.1016/j.jlumin.2015.11.001"
- Description: Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
- Full Text:
- Date Issued: 2016
- Authors: Shumba, Munyaradzi , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240875 , vital:50881 , xlink:href="https://doi.org/10.1016/j.jlumin.2015.11.001"
- Description: Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
- Full Text:
- Date Issued: 2016
“Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
- Shumba, Munyaradzi, Mashazi, Philani N, Nyokong, Tebello
- Authors: Shumba, Munyaradzi , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190438 , vital:44994 , xlink:href="https://doi.org/10.1016/j.jlumin.2015.11.001"
- Description: Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyaninereduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
- Full Text:
- Date Issued: 2016
- Authors: Shumba, Munyaradzi , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190438 , vital:44994 , xlink:href="https://doi.org/10.1016/j.jlumin.2015.11.001"
- Description: Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyaninereduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
- Full Text:
- Date Issued: 2016
“It is a thing that depends on God”
- Samandari, Ghazaleh, Grant, Carolyn, Brent, Lily, Gullo, Sara
- Authors: Samandari, Ghazaleh , Grant, Carolyn , Brent, Lily , Gullo, Sara
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281091 , vital:55691 , xlink:href="https://doi.org/10.1186/s12978-019-0757-y"
- Description: Background: Pregnancy among adolescent girls in Niger contributes to 34% of all deaths among females ages 15–19, but there is a dearth of research as to the specific contextual causes. In Zinder region, an area that is especially impoverished and where girls are at heightened risk, there is very little information on the main obstacles to improving adolescents’ health and well-being. This qualitative study examines the underlying social, individual and structural factors influencing married girls’ early first birth and participation in alternative opportunities (such as education or economic pursuits) in Niger. Methodology: In July of 2017, researchers conducted in-depth interviews with a non-probability sample of community members in three communes of Zinder Region, Niger. Participants (n = 107) included adolescent girls, husbands of adolescent girls, influential adults, community leaders, health providers, and positive deviants. All interviews were transcribed, coded and analyzed using Dedoose software. Results: Participants recognize the health benefits of delaying first birth, but stigma around infertility and contraceptive use, desire for children, and belief that childbirth is “God’s will” interfere with a girl’s ability to delay. Girls’ social isolation, lack of mobility or autonomy, and inability to envision alternatives to early motherhood compound the issue. Participants favor adolescents’ pursuit of increased economic opportunities or education, but would not support delaying birth to do so. Conclusions: Findings indicate the need for a holistic approach to delaying early birth and stimulating girls’ participation in economic and educational pursuits. Potential interventions include mitigating barriers to reproductive health care; training adolescent girls on viable economic activities; and providing educational opportunities for girls. Effective programs should also include or target immediate members of the girls’ families (husbands, parents, in-laws), influential local leaders and members of the community at large.
- Full Text:
- Date Issued: 2019
- Authors: Samandari, Ghazaleh , Grant, Carolyn , Brent, Lily , Gullo, Sara
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281091 , vital:55691 , xlink:href="https://doi.org/10.1186/s12978-019-0757-y"
- Description: Background: Pregnancy among adolescent girls in Niger contributes to 34% of all deaths among females ages 15–19, but there is a dearth of research as to the specific contextual causes. In Zinder region, an area that is especially impoverished and where girls are at heightened risk, there is very little information on the main obstacles to improving adolescents’ health and well-being. This qualitative study examines the underlying social, individual and structural factors influencing married girls’ early first birth and participation in alternative opportunities (such as education or economic pursuits) in Niger. Methodology: In July of 2017, researchers conducted in-depth interviews with a non-probability sample of community members in three communes of Zinder Region, Niger. Participants (n = 107) included adolescent girls, husbands of adolescent girls, influential adults, community leaders, health providers, and positive deviants. All interviews were transcribed, coded and analyzed using Dedoose software. Results: Participants recognize the health benefits of delaying first birth, but stigma around infertility and contraceptive use, desire for children, and belief that childbirth is “God’s will” interfere with a girl’s ability to delay. Girls’ social isolation, lack of mobility or autonomy, and inability to envision alternatives to early motherhood compound the issue. Participants favor adolescents’ pursuit of increased economic opportunities or education, but would not support delaying birth to do so. Conclusions: Findings indicate the need for a holistic approach to delaying early birth and stimulating girls’ participation in economic and educational pursuits. Potential interventions include mitigating barriers to reproductive health care; training adolescent girls on viable economic activities; and providing educational opportunities for girls. Effective programs should also include or target immediate members of the girls’ families (husbands, parents, in-laws), influential local leaders and members of the community at large.
- Full Text:
- Date Issued: 2019
“Ha! Relationships? I only shout at them!”: Strategic management of discordant rapport in an African small business context
- Lauriks, Sanne, Siebörger, Ian, de Vos, Mark
- Authors: Lauriks, Sanne , Siebörger, Ian , de Vos, Mark
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/385338 , vital:68009 , xlink:href="https://doi.org/10.1515/pr-2015-0002"
- Description: This study demonstrates how and why interactants at a tyre fitment centre in Grahamstown, South Africa, manage discordant interpersonal relationships in strategic ways. Individuals in a post-apartheid small business respond to their social and economic context and exercise agency to their advantage in doing so. This study draws on linguistic ethnography (Rampton 2007) and the Rapport Management Framework (RMF, Spencer-Oatey 2000b, 2011), itself a development of politeness theory (Brown and Levinson 1987). An initial RMF analysis ran into difficulties around interactions that at first glance appeared to be oriented toward Rapport Challenge and Neglect. Upon closer examination, it appeared that discordant rapport was being actively maintained in this business. This led us to address underdeveloped areas of RMF that were not responsive enough to describe naturally occurring small business interactions, and propose an Enhanced Rapport Management Framework to overcome its inadequacies. We conclude that people may deliberately maintain discordant relationships when it is in their best interests to do so. Thus, contrary to a common-sense belief that harmonious social relations are an intrinsic good, we found that promoting discordant social relations can be understood as a rational response to individuals’ social and economic contexts, particularly in conditions such as those in many postcolonial African societies.
- Full Text:
- Date Issued: 2015
- Authors: Lauriks, Sanne , Siebörger, Ian , de Vos, Mark
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/385338 , vital:68009 , xlink:href="https://doi.org/10.1515/pr-2015-0002"
- Description: This study demonstrates how and why interactants at a tyre fitment centre in Grahamstown, South Africa, manage discordant interpersonal relationships in strategic ways. Individuals in a post-apartheid small business respond to their social and economic context and exercise agency to their advantage in doing so. This study draws on linguistic ethnography (Rampton 2007) and the Rapport Management Framework (RMF, Spencer-Oatey 2000b, 2011), itself a development of politeness theory (Brown and Levinson 1987). An initial RMF analysis ran into difficulties around interactions that at first glance appeared to be oriented toward Rapport Challenge and Neglect. Upon closer examination, it appeared that discordant rapport was being actively maintained in this business. This led us to address underdeveloped areas of RMF that were not responsive enough to describe naturally occurring small business interactions, and propose an Enhanced Rapport Management Framework to overcome its inadequacies. We conclude that people may deliberately maintain discordant relationships when it is in their best interests to do so. Thus, contrary to a common-sense belief that harmonious social relations are an intrinsic good, we found that promoting discordant social relations can be understood as a rational response to individuals’ social and economic contexts, particularly in conditions such as those in many postcolonial African societies.
- Full Text:
- Date Issued: 2015
“Eye on the big prize!”: Iconizing the Democratic Alliance in the Daily Sun
- Siebörger, Ian, Adendorff, Ralph D
- Authors: Siebörger, Ian , Adendorff, Ralph D
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/385324 , vital:68007 , xlink:href="https://www.ajol.info/index.php/splp/article/view/253996"
- Description: This article gives a snapshot view of how Mmusi Maimane’s rise to leadership in the Democratic Alliance (DA) in 2015 was reported on in the Daily Sun, South Africa’s biggest-selling national daily newspaper (South African Audience Research Foundation, 2016). Through analysis of a Daily Sun news article exemplifying trends in the positioning of the DA in the tabloid over the first half of 2015, the present study demonstrates how Maimane tried to align the DA around a new iconography (Tann 2010, 2013), centred on the values of “freedom”, “fairness” and “opportunity”. Moreover, the present study also shows how this purported transformation in the DA was treated with scepticism by the news article’s author, who iconizes the DA as incapable of transformation and effective governance. Fine-grained complementary Legitimation Code Theory (LCT) and Systemic Functional Linguistics (SFL) analyses were conducted on this news article. The LCT analysis shows how multiple voices in the news article create conflicting binary constellations, axiologically charged through various linguistic resources, including intertextual references. The analysis, using SFL’s Appraisal system (Martin and White 2005), shows how iconization is accomplished in the news article through evaluative language, coupled with intertextual references, grammatical metaphor andtechnicality to produce syndromes of meaning in the news article. Such iconization works, in this case, to reproduce an attitude of cynicism toward party politics in post-apartheid South Africa. This cynicism foreshadows Maimane’s ultimate lack of success in transforming the discourses of the DA.
- Full Text:
- Date Issued: 2022
- Authors: Siebörger, Ian , Adendorff, Ralph D
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/385324 , vital:68007 , xlink:href="https://www.ajol.info/index.php/splp/article/view/253996"
- Description: This article gives a snapshot view of how Mmusi Maimane’s rise to leadership in the Democratic Alliance (DA) in 2015 was reported on in the Daily Sun, South Africa’s biggest-selling national daily newspaper (South African Audience Research Foundation, 2016). Through analysis of a Daily Sun news article exemplifying trends in the positioning of the DA in the tabloid over the first half of 2015, the present study demonstrates how Maimane tried to align the DA around a new iconography (Tann 2010, 2013), centred on the values of “freedom”, “fairness” and “opportunity”. Moreover, the present study also shows how this purported transformation in the DA was treated with scepticism by the news article’s author, who iconizes the DA as incapable of transformation and effective governance. Fine-grained complementary Legitimation Code Theory (LCT) and Systemic Functional Linguistics (SFL) analyses were conducted on this news article. The LCT analysis shows how multiple voices in the news article create conflicting binary constellations, axiologically charged through various linguistic resources, including intertextual references. The analysis, using SFL’s Appraisal system (Martin and White 2005), shows how iconization is accomplished in the news article through evaluative language, coupled with intertextual references, grammatical metaphor andtechnicality to produce syndromes of meaning in the news article. Such iconization works, in this case, to reproduce an attitude of cynicism toward party politics in post-apartheid South Africa. This cynicism foreshadows Maimane’s ultimate lack of success in transforming the discourses of the DA.
- Full Text:
- Date Issued: 2022
‘We do not cook, we only assist them’
- Ratele, Kopano, Shefer, Tamara, Strebel, Anna, Fouten, Elron
- Authors: Ratele, Kopano , Shefer, Tamara , Strebel, Anna , Fouten, Elron
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/277945 , vital:55334 , xlink:href="https://doi.org/10.1080/14330237.2010.10820414"
- Description: This article discusses how the gendering of activity by boys coincides with, contests or recreates constructions of hegemonic masculinity in the context of South Africa. The study used a qualitative methodology including a series of three focus groups with 14–16 year-old boys across six different schools in the Western Cape, South Africa. A discursive analysis in which particular attention was paid to how participants construct their masculinity in relation to what they may or may not do as boys/men was conducted. The findings foreground how articulations of masculinity by boys are characterised by efforts to gender activity in the process of, amongst other things, counter blushing—meaning not to be regarded as girl-like or a moffie, or other derogatory notions that do not fit with hegemonic masculinity in a particular context. However, resistances and alternative views on what boys/men can and cannot do also emerged, highlighting the contested nature of current constructions of masculinity among young people in South Africa.
- Full Text:
- Date Issued: 2010
- Authors: Ratele, Kopano , Shefer, Tamara , Strebel, Anna , Fouten, Elron
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/277945 , vital:55334 , xlink:href="https://doi.org/10.1080/14330237.2010.10820414"
- Description: This article discusses how the gendering of activity by boys coincides with, contests or recreates constructions of hegemonic masculinity in the context of South Africa. The study used a qualitative methodology including a series of three focus groups with 14–16 year-old boys across six different schools in the Western Cape, South Africa. A discursive analysis in which particular attention was paid to how participants construct their masculinity in relation to what they may or may not do as boys/men was conducted. The findings foreground how articulations of masculinity by boys are characterised by efforts to gender activity in the process of, amongst other things, counter blushing—meaning not to be regarded as girl-like or a moffie, or other derogatory notions that do not fit with hegemonic masculinity in a particular context. However, resistances and alternative views on what boys/men can and cannot do also emerged, highlighting the contested nature of current constructions of masculinity among young people in South Africa.
- Full Text:
- Date Issued: 2010
‘Exploring the practical adequacy of the human rights, social justice, inclusivity and healthy environment policy discourse in South Africa’s National Curriculum Statement’
- Schudel, Ingrid, Lotz-Sisitka, Heila
- Authors: Schudel, Ingrid , Lotz-Sisitka, Heila
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/391180 , vital:68629 , xlink:href="https://www.tandfonline.com/doi/full/10.1080/13504620701284860"
- Description: This article examines the practical adequacy of the recent defining of a normative framework for the South African National Curriculum Statement that focuses on the relationship between human rights, social justice and a healthy environment. This politically framed and socially critical normative framework has developed in response to socio-political and socio-ecological histories in postapartheid curriculum transformation processes. The article critically considers the process of working with a normative framework in the defining of environmental education teaching and learning interactions, and seeks not only to explore the policy discourse critically, but also to explore what it is about the world that makes it work in different ways. Drawing on Sayer’s perspectives on the possibilities of enabling ‘situated universalism’ as a form of normative theory, and case-based data from a teacher professional development programme in the Makana District (where the authors live and work), the article probes the relationship between the establishment of a ‘universalising’ normative framework to guide national curriculum, and situated engagements with this framework in/as democratic process. In this process it questions whether educators should adopt the ‘norms’ as presented by society and simply universalize and implement them as prescribed by curriculum statements, or whether educators should adopt the strategies of postmodernists and reduce normative frameworks to relations of power situated in particular contexts.
- Full Text:
- Date Issued: 2006
- Authors: Schudel, Ingrid , Lotz-Sisitka, Heila
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/391180 , vital:68629 , xlink:href="https://www.tandfonline.com/doi/full/10.1080/13504620701284860"
- Description: This article examines the practical adequacy of the recent defining of a normative framework for the South African National Curriculum Statement that focuses on the relationship between human rights, social justice and a healthy environment. This politically framed and socially critical normative framework has developed in response to socio-political and socio-ecological histories in postapartheid curriculum transformation processes. The article critically considers the process of working with a normative framework in the defining of environmental education teaching and learning interactions, and seeks not only to explore the policy discourse critically, but also to explore what it is about the world that makes it work in different ways. Drawing on Sayer’s perspectives on the possibilities of enabling ‘situated universalism’ as a form of normative theory, and case-based data from a teacher professional development programme in the Makana District (where the authors live and work), the article probes the relationship between the establishment of a ‘universalising’ normative framework to guide national curriculum, and situated engagements with this framework in/as democratic process. In this process it questions whether educators should adopt the ‘norms’ as presented by society and simply universalize and implement them as prescribed by curriculum statements, or whether educators should adopt the strategies of postmodernists and reduce normative frameworks to relations of power situated in particular contexts.
- Full Text:
- Date Issued: 2006
‘Don't educate them out of educating themselves’
- Krueger, Anton, Wunder, Albert
- Authors: Krueger, Anton , Wunder, Albert
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/225481 , vital:49226 , xlink:href="https://doi.org/10.5920/pam.1005"
- Description: Al Wunder's biography, in his own words: I had four lucky breaks that precipitated my becoming a teacher of improvised movement theatre. Between the ages of eight and fourteen I broke my right leg four different times. In 1962, I began modern dance classes with Alwin Nikolais as a physical therapy. His choreography and improvisation sections of class inspired me to teach and perform professionally. I spent eight years studying, teaching, choreographing, and performing with Nikolais. 1970 saw me move to the San Francisco Bay area where I opened a dance studio teaching Nikolais dance technique and improvisation. In 1971, I joined forces with Terry Sendgraff and Ruth Zaporah creating The Berkeley Dance Theater and Gymnasium. My focus was to create a way to teach dance technique through improvisation. I met my Australian wife, Lynden Nicholls, in 1981 when she came to study Motivity at Terry’s studio in Berkeley. In 1982, I moved to Melbourne, Australia where Lynden and I set up a dance studio. My focus changed from teaching dance technique improvisationally to teaching improvised movement theatre performance
- Full Text:
- Date Issued: 2021
- Authors: Krueger, Anton , Wunder, Albert
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/225481 , vital:49226 , xlink:href="https://doi.org/10.5920/pam.1005"
- Description: Al Wunder's biography, in his own words: I had four lucky breaks that precipitated my becoming a teacher of improvised movement theatre. Between the ages of eight and fourteen I broke my right leg four different times. In 1962, I began modern dance classes with Alwin Nikolais as a physical therapy. His choreography and improvisation sections of class inspired me to teach and perform professionally. I spent eight years studying, teaching, choreographing, and performing with Nikolais. 1970 saw me move to the San Francisco Bay area where I opened a dance studio teaching Nikolais dance technique and improvisation. In 1971, I joined forces with Terry Sendgraff and Ruth Zaporah creating The Berkeley Dance Theater and Gymnasium. My focus was to create a way to teach dance technique through improvisation. I met my Australian wife, Lynden Nicholls, in 1981 when she came to study Motivity at Terry’s studio in Berkeley. In 1982, I moved to Melbourne, Australia where Lynden and I set up a dance studio. My focus changed from teaching dance technique improvisationally to teaching improvised movement theatre performance
- Full Text:
- Date Issued: 2021
Zinc phthalocyanine photocatalyzed oxidation of cyclohexene
- Sehlotho, Nthapo, Nyokong, Tebello
- Authors: Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289399 , vital:56629 , xlink:href="https://doi.org/10.1016/j.molcata.2004.05.010"
- Description: Cyclohexene photooxidation catalyzed by zinc phthalocyanine (ZnPc) using either red or white light results in the formation of cyclohexenone, cyclohexenol, trans-cyclohexanediol, cyclohexene oxide and cyclohexene hydroperoxide. The product yield increased as follows: cyclohexenone > cyclohexenol > trans-cyclohexanediol > cyclohexene oxide > cyclohexene hydroperoxide. The mechanism for the formation of these products involves both singlet oxygen and radicals (Type II and Type I mechanisms, respectively). The catalyst degraded slowly when low light intensities were employed. The product yields were found to depend on the light intensity, the nature of solvent, irradiation time and the rate of photodegradation of the catalyst.
- Full Text:
- Date Issued: 2004
- Authors: Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2004
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289399 , vital:56629 , xlink:href="https://doi.org/10.1016/j.molcata.2004.05.010"
- Description: Cyclohexene photooxidation catalyzed by zinc phthalocyanine (ZnPc) using either red or white light results in the formation of cyclohexenone, cyclohexenol, trans-cyclohexanediol, cyclohexene oxide and cyclohexene hydroperoxide. The product yield increased as follows: cyclohexenone > cyclohexenol > trans-cyclohexanediol > cyclohexene oxide > cyclohexene hydroperoxide. The mechanism for the formation of these products involves both singlet oxygen and radicals (Type II and Type I mechanisms, respectively). The catalyst degraded slowly when low light intensities were employed. The product yields were found to depend on the light intensity, the nature of solvent, irradiation time and the rate of photodegradation of the catalyst.
- Full Text:
- Date Issued: 2004
Zinc (II) 2, 9, 16, 23-tetrakis [4-(N-methylpyridyloxy)]-phthalocyanine anchored on an electrospun polysulfone polymer fiber: Application for photosensitized conversion of methyl orange
- Zugle, Ruphino, Nyokong, Tebello
- Authors: Zugle, Ruphino , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232741 , vital:50020 , xlink:href="https://doi.org/10.1016/j.molcata.2012.10.001"
- Description: In this work, a comparative study of photodegradation of methyl orange, an azo dye, in homogeneous aqueous solution of a quarternized cationic zinc phthalocyanine and a heterogeneous catalytic system based on the same phthalocyanine anchored on polysulfone polymer fiber is presented. In both cases, conversion involved the azo bond of the dye with no detectable opening up of the aromatic benzene rings. The reaction kinetics in both cases were consistent with first order with the conversion occurring in the homogeneous system being faster than when the functionalized polymer fiber was used. The reaction products consisted of a coupling product as well as a series of oligopolymeric products.
- Full Text:
- Date Issued: 2013
- Authors: Zugle, Ruphino , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/232741 , vital:50020 , xlink:href="https://doi.org/10.1016/j.molcata.2012.10.001"
- Description: In this work, a comparative study of photodegradation of methyl orange, an azo dye, in homogeneous aqueous solution of a quarternized cationic zinc phthalocyanine and a heterogeneous catalytic system based on the same phthalocyanine anchored on polysulfone polymer fiber is presented. In both cases, conversion involved the azo bond of the dye with no detectable opening up of the aromatic benzene rings. The reaction kinetics in both cases were consistent with first order with the conversion occurring in the homogeneous system being faster than when the functionalized polymer fiber was used. The reaction products consisted of a coupling product as well as a series of oligopolymeric products.
- Full Text:
- Date Issued: 2013
Youth Attitudes and Participation in Climate Protest
- Prendergast, Kate, Hayward, Bronwyn, Aoyagi, Midori, Burningham, Kate, Hasan, Mehedi, Jackson, Tim, Jha, Vimlendu, Kuroki, Larissa, Lukianov, Anastasia, Mattar, Helio, Schudel, Ingrid J, Venn, Sue, Yoshida, Aya
- Authors: Prendergast, Kate , Hayward, Bronwyn , Aoyagi, Midori , Burningham, Kate , Hasan, Mehedi , Jackson, Tim , Jha, Vimlendu , Kuroki, Larissa , Lukianov, Anastasia , Mattar, Helio , Schudel, Ingrid J , Venn, Sue , Yoshida, Aya
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/294471 , vital:57224 , xlink:href="https://doi.org/10.3389/fpos.2021.696105"
- Description: This article examines youth participation the school climate strikes of 2018 and 2019 (also known as #Fridays4Future), through an exploratory study conducted in seven diverse cities. Despite the international nature of the climate strikes, we know little about the factors that influenced youth participation in these protests beyond the global North. This matters because youth of the global South are disproportionately impacted by climate change and there is growing concern that the climate movement is dominated by narratives that marginalize the voices and priorities of Indigenous communities and people of color. In this context, the exploratory research reported here aimed to compare the attitudes of climate protesters (n = 314) and their non-protester peers (n = 1,217), in diverse city samples drawn from a wider study of children and youth aged 12–24 years, living in Christchurch (New Zealand); Dhaka (Bangladesh); Lambeth, London (United Kingdom); Makhanda (South Africa); New Delhi (India); São Paulo (Brazil); and Yokohama (Japan). Using cross-sectional data (N = 1,531) and binary logistic regression models, researchers examined three common explanations for youth participation in protest: availability (biographical and structural), political engagement (reported individual and collective efficacy of strikers and non-strikers), and self-reported biospheric values amongst participants. Results indicate that even in diverse city samples, structural availability (civic skills and organizational membership) predicted strike participation across city samples, but not political engagement (self-efficacy and collective efficacy). Youth who reported that ‘living in harmony with nature and animals’ was important for their wellbeing, were also more likely to strike than their peers. Descriptive statistics indicated that the majority (85 percent) of all protestors in this study agreed climate change was a serious issue and a startling 65 percent said that they think about climate change “all the time”. Reported rates of youth climate protest participation varied across city samples as did the extent to which participants reported having friends take part or expecting climate change to have a personal impact. While the study is exploratory, it points to the need for more extensive research to understand the diversity of youth participation in ‘global climate strikes’.
- Full Text:
- Date Issued: 2021
- Authors: Prendergast, Kate , Hayward, Bronwyn , Aoyagi, Midori , Burningham, Kate , Hasan, Mehedi , Jackson, Tim , Jha, Vimlendu , Kuroki, Larissa , Lukianov, Anastasia , Mattar, Helio , Schudel, Ingrid J , Venn, Sue , Yoshida, Aya
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/294471 , vital:57224 , xlink:href="https://doi.org/10.3389/fpos.2021.696105"
- Description: This article examines youth participation the school climate strikes of 2018 and 2019 (also known as #Fridays4Future), through an exploratory study conducted in seven diverse cities. Despite the international nature of the climate strikes, we know little about the factors that influenced youth participation in these protests beyond the global North. This matters because youth of the global South are disproportionately impacted by climate change and there is growing concern that the climate movement is dominated by narratives that marginalize the voices and priorities of Indigenous communities and people of color. In this context, the exploratory research reported here aimed to compare the attitudes of climate protesters (n = 314) and their non-protester peers (n = 1,217), in diverse city samples drawn from a wider study of children and youth aged 12–24 years, living in Christchurch (New Zealand); Dhaka (Bangladesh); Lambeth, London (United Kingdom); Makhanda (South Africa); New Delhi (India); São Paulo (Brazil); and Yokohama (Japan). Using cross-sectional data (N = 1,531) and binary logistic regression models, researchers examined three common explanations for youth participation in protest: availability (biographical and structural), political engagement (reported individual and collective efficacy of strikers and non-strikers), and self-reported biospheric values amongst participants. Results indicate that even in diverse city samples, structural availability (civic skills and organizational membership) predicted strike participation across city samples, but not political engagement (self-efficacy and collective efficacy). Youth who reported that ‘living in harmony with nature and animals’ was important for their wellbeing, were also more likely to strike than their peers. Descriptive statistics indicated that the majority (85 percent) of all protestors in this study agreed climate change was a serious issue and a startling 65 percent said that they think about climate change “all the time”. Reported rates of youth climate protest participation varied across city samples as did the extent to which participants reported having friends take part or expecting climate change to have a personal impact. While the study is exploratory, it points to the need for more extensive research to understand the diversity of youth participation in ‘global climate strikes’.
- Full Text:
- Date Issued: 2021
Young pregnant women and public health
- Macleod, Catriona I, Feltham-King, Tracey
- Authors: Macleod, Catriona I , Feltham-King, Tracey
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298572 , vital:57717 , xlink:href="https://doi.org/10.1080/09581596.2019.1573313"
- Description: In this paper, we outline a critical reparative justice/care approach to adolescent reproductive health as an alternative to the standard public health response to ‘teenage pregnancy’. Joining an increasing body of critical scholarship that calls for nuance in understanding reproduction amongst young people, we draw, in this paper, on data generated from an ethnographic study conducted in antenatal care units in an Eastern Cape township in South Africa. To illustrate the approach we propose, we home in on five case studies that highlight the variability of young women’s lives, the multiple injustices they experience, and the agency they demonstrate in negotiating their way through pregnancy and birth. Injustices evident in these cases centre on sexual violence, rape myths, education system failures, health system failures, shaming and stigmatising practices, socio-economic precariousness, absent male partners, and denial of services. We outline how the reparative justice approach that highlights repair and support for social and health injustices at the individual and collective level as well as at the material and symbolic level may be taken up to ensure reproductive justice for young pregnant women.
- Full Text:
- Date Issued: 2020
- Authors: Macleod, Catriona I , Feltham-King, Tracey
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298572 , vital:57717 , xlink:href="https://doi.org/10.1080/09581596.2019.1573313"
- Description: In this paper, we outline a critical reparative justice/care approach to adolescent reproductive health as an alternative to the standard public health response to ‘teenage pregnancy’. Joining an increasing body of critical scholarship that calls for nuance in understanding reproduction amongst young people, we draw, in this paper, on data generated from an ethnographic study conducted in antenatal care units in an Eastern Cape township in South Africa. To illustrate the approach we propose, we home in on five case studies that highlight the variability of young women’s lives, the multiple injustices they experience, and the agency they demonstrate in negotiating their way through pregnancy and birth. Injustices evident in these cases centre on sexual violence, rape myths, education system failures, health system failures, shaming and stigmatising practices, socio-economic precariousness, absent male partners, and denial of services. We outline how the reparative justice approach that highlights repair and support for social and health injustices at the individual and collective level as well as at the material and symbolic level may be taken up to ensure reproductive justice for young pregnant women.
- Full Text:
- Date Issued: 2020
Young people and environmental affordances in urban sustainable development
- Nissen, Sylvia, Prendergast, Kate, Aoyagi, Midori, Burningham, Kate, Hasan, Mohammed Mehedi, Hayward, Bronwyn, Jackson, Tim, Jha, Vimlendu, Mattar, Helio, Schudel, Ingrid J, Venn, Sue, Yoshida, Aya
- Authors: Nissen, Sylvia , Prendergast, Kate , Aoyagi, Midori , Burningham, Kate , Hasan, Mohammed Mehedi , Hayward, Bronwyn , Jackson, Tim , Jha, Vimlendu , Mattar, Helio , Schudel, Ingrid J , Venn, Sue , Yoshida, Aya
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/294460 , vital:57223 , xlink:href="https://doi.org/10.1186/s42055-020-00039-w"
- Description: Background: Cities are at the fore of sustainability challenges of the twenty-first century, and many, particularly in Asia and Africa, are predominantly youthful spaces. Understanding young people's experiences in urban environments is therefore important as we strive to achieve both the Sustainable Development Goals and the Paris Agreement. Two amenities identified in the urban Sustainable Development Goal 11, transport and public and green space, are specifically recognised as applying to youth. Yet, there is little analysis that explicitly considers how youth experience these amenities across the Global North and South, and no current measures for understanding progress in youth experiences of green space and transport. Results: This paper provides a comparative analysis of young people's experiences with local transport and green space in seven diverse urban communities (Christchurch, New Zealand; Dhaka, Bangladesh; Lambeth/London, UK; Makhanda, South Africa; New Delhi, India; São Paulo, Brazil; and Yokohama, Japan). Our study contributes to a growing body of literature that seeks to listen to child and youth perspectives to understand their environmental experiences. We examine the 'affordances' young residents aged 12 to 24 years currently associate with green space and transport amenities. Affordances are defined here as the inter-relationships between what a local environment offers young people and their perceptions and actions. Drawing on focus groups and interviews conducted with 332 young people, we identify five affordances young people associate in relation to transport and public space across these diverse urban settings: (1) social inclusion and belonging; (2) autonomy; (3) physical comfort and security; (4) relaxation and reflection; and (5) health and fitness. Conclusions The paper contributes to growing interdisciplinary research interest in measuring affordances as a way to advance the Sustainable Development Goals in an urban context. In providing a comparative account of young people's experiences across diverse contexts, our discussion highlights how affordances in relation to transport or public and green space can help understand the multiple interconnections between the well-being of young people and sustainability. In particular, we argue that it is not merely the provision of transport or public and green space that matters, but the nuanced meaning of places and experiences as understood by local communities that needs to be recognised if we are to better support urban youth wellbeing and advance sustainable development goals.
- Full Text:
- Date Issued: 2020
- Authors: Nissen, Sylvia , Prendergast, Kate , Aoyagi, Midori , Burningham, Kate , Hasan, Mohammed Mehedi , Hayward, Bronwyn , Jackson, Tim , Jha, Vimlendu , Mattar, Helio , Schudel, Ingrid J , Venn, Sue , Yoshida, Aya
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/294460 , vital:57223 , xlink:href="https://doi.org/10.1186/s42055-020-00039-w"
- Description: Background: Cities are at the fore of sustainability challenges of the twenty-first century, and many, particularly in Asia and Africa, are predominantly youthful spaces. Understanding young people's experiences in urban environments is therefore important as we strive to achieve both the Sustainable Development Goals and the Paris Agreement. Two amenities identified in the urban Sustainable Development Goal 11, transport and public and green space, are specifically recognised as applying to youth. Yet, there is little analysis that explicitly considers how youth experience these amenities across the Global North and South, and no current measures for understanding progress in youth experiences of green space and transport. Results: This paper provides a comparative analysis of young people's experiences with local transport and green space in seven diverse urban communities (Christchurch, New Zealand; Dhaka, Bangladesh; Lambeth/London, UK; Makhanda, South Africa; New Delhi, India; São Paulo, Brazil; and Yokohama, Japan). Our study contributes to a growing body of literature that seeks to listen to child and youth perspectives to understand their environmental experiences. We examine the 'affordances' young residents aged 12 to 24 years currently associate with green space and transport amenities. Affordances are defined here as the inter-relationships between what a local environment offers young people and their perceptions and actions. Drawing on focus groups and interviews conducted with 332 young people, we identify five affordances young people associate in relation to transport and public space across these diverse urban settings: (1) social inclusion and belonging; (2) autonomy; (3) physical comfort and security; (4) relaxation and reflection; and (5) health and fitness. Conclusions The paper contributes to growing interdisciplinary research interest in measuring affordances as a way to advance the Sustainable Development Goals in an urban context. In providing a comparative account of young people's experiences across diverse contexts, our discussion highlights how affordances in relation to transport or public and green space can help understand the multiple interconnections between the well-being of young people and sustainability. In particular, we argue that it is not merely the provision of transport or public and green space that matters, but the nuanced meaning of places and experiences as understood by local communities that needs to be recognised if we are to better support urban youth wellbeing and advance sustainable development goals.
- Full Text:
- Date Issued: 2020
X-ray photoelectron spectroscopy analysis of the effect of alkyl-and arylthio substituents on manganese phthalocyanines for self-assembled monolayer formation on gold
- Coates, Megan, Nyokong, Tebello
- Authors: Coates, Megan , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190490 , vital:44999 , xlink:href="https://doi.org/10.1016/j.elecom.2013.03.019"
- Description: Self-assembled monolayers of an octa-substituted alkylthio and arylthio manganese phthalocyanines were formed on gold. X-ray photoelectron spectroscopy was used to analyse both of the phthalocyanine layers on gold. Approximately 60% of the sulphur groups in the aryl substituted-SAM surface were bound to gold through the cleavage of the C S bond, as opposed to only 37% for the alkyl substituted-SAM.
- Full Text:
- Date Issued: 2013
- Authors: Coates, Megan , Nyokong, Tebello
- Date: 2013
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/190490 , vital:44999 , xlink:href="https://doi.org/10.1016/j.elecom.2013.03.019"
- Description: Self-assembled monolayers of an octa-substituted alkylthio and arylthio manganese phthalocyanines were formed on gold. X-ray photoelectron spectroscopy was used to analyse both of the phthalocyanine layers on gold. Approximately 60% of the sulphur groups in the aryl substituted-SAM surface were bound to gold through the cleavage of the C S bond, as opposed to only 37% for the alkyl substituted-SAM.
- Full Text:
- Date Issued: 2013
Writing groups as transformative spaces
- Wilmot, Kirstin, McKenna, Sioux
- Authors: Wilmot, Kirstin , McKenna, Sioux
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:44576 , xlink:href="https://doi.org/10.1080/07294360.2018.1450361"
- Description: Curriculum transformation is a central concern for higher education in response to rapidly expanding technologies, globalisation and the widening diversity of the student and staff body. This is particularly true for South Africa, which is still grappling with inequalities and pressure for social redress in its universities. Early responses to supporting students took the form of add-on, ‘deficit-model’ approaches which understood poor student retention and success rates as emerging from students’ lack of neutral literacy ‘skills’. Recent initiatives have begun to adopt more socio-cultural understandings of literacy that seek to challenge traditional power structures and cultivate horizontal peer-orientated spaces for learning with a focus on practice rather than on product. Writing groups, as spaces for academic writing development, embrace this orientation and are argued to provide a transformative framework that foregrounds proactive student learning and experience, while still accommodating disciplinary learning through peer engagement. Drawing on the successful implementation of such forms of support at a research-intensive university, this paper argues that writing groups can play a critical role in both personal (student) transformation and broader curriculum transformation. Data include anonymous questionnaires and surveys with participants and coordinators of the writing groups. An inductive, constant comparative analysis indicated that students feel empowered in this space to develop not only their writing practices but also their transforming identities as scholars. Writing groups were found to provide ‘safe spaces’ where academic practices can be made explicit and where they can be challenged. The paper therefore argues that writing groups can play a small but key role in broader transformation efforts.
- Full Text:
- Date Issued: 2018
- Authors: Wilmot, Kirstin , McKenna, Sioux
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/${Handle} , vital:44576 , xlink:href="https://doi.org/10.1080/07294360.2018.1450361"
- Description: Curriculum transformation is a central concern for higher education in response to rapidly expanding technologies, globalisation and the widening diversity of the student and staff body. This is particularly true for South Africa, which is still grappling with inequalities and pressure for social redress in its universities. Early responses to supporting students took the form of add-on, ‘deficit-model’ approaches which understood poor student retention and success rates as emerging from students’ lack of neutral literacy ‘skills’. Recent initiatives have begun to adopt more socio-cultural understandings of literacy that seek to challenge traditional power structures and cultivate horizontal peer-orientated spaces for learning with a focus on practice rather than on product. Writing groups, as spaces for academic writing development, embrace this orientation and are argued to provide a transformative framework that foregrounds proactive student learning and experience, while still accommodating disciplinary learning through peer engagement. Drawing on the successful implementation of such forms of support at a research-intensive university, this paper argues that writing groups can play a critical role in both personal (student) transformation and broader curriculum transformation. Data include anonymous questionnaires and surveys with participants and coordinators of the writing groups. An inductive, constant comparative analysis indicated that students feel empowered in this space to develop not only their writing practices but also their transforming identities as scholars. Writing groups were found to provide ‘safe spaces’ where academic practices can be made explicit and where they can be challenged. The paper therefore argues that writing groups can play a small but key role in broader transformation efforts.
- Full Text:
- Date Issued: 2018
Woza Albert! (Student Editions)
- Authors: Krueger, Anton
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229598 , vital:49691 , xlink:href="https://doi.org/10.1080/10137548.2018.1560975"
- Description: Publishing Woza Albert! back in 1983 was a smart move by Methuen Publishing, since it went on to become South Africa’s most canonical dramatic text. As Temple Hauptfleisch points out in his introduction to this new edition, the play has become one of the most anthologized and produced of all South African plays, a regular prescribed work…particularly so in the new curricula introduced since 1994…a major work in the South African literary canon, one of the most studied and produced of the plays from the turbulent 1980s.
- Full Text:
- Date Issued: 2019
- Authors: Krueger, Anton
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229598 , vital:49691 , xlink:href="https://doi.org/10.1080/10137548.2018.1560975"
- Description: Publishing Woza Albert! back in 1983 was a smart move by Methuen Publishing, since it went on to become South Africa’s most canonical dramatic text. As Temple Hauptfleisch points out in his introduction to this new edition, the play has become one of the most anthologized and produced of all South African plays, a regular prescribed work…particularly so in the new curricula introduced since 1994…a major work in the South African literary canon, one of the most studied and produced of the plays from the turbulent 1980s.
- Full Text:
- Date Issued: 2019
Working with cultural-historical activity theory and critical realism to investigate and expand farmer learning in Southern Africa
- Mukute, Mutizwa, Lotz-Sisitka, Heila
- Authors: Mukute, Mutizwa , Lotz-Sisitka, Heila
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182494 , vital:43835 , xlink:href="https://doi.org/10.1080/10749039.2012.656173"
- Description: This article uses the theoretical and methodological tools of cultural historical activity theory and critical realism to examine three case studies of the introduction and expansion of sustainable agricultural practices in southern Africa. The article addresses relevant issues in the field of agricultural extension, which lacks a theoretical “bridge” between top-down knowledge transfer and bottom-up participatory approaches to learning. Further, the article considers the learning environments necessary for sustainable agriculture. Such environments provided research participants with encounters with “postnormal” scientific practices that recognise and engage plural ways of knowing. Our research explored why farmers learn and practise sustainable agriculture, how they learn and practise it, the contradictions they are facing, and how these contradictions can be overcome in a context of change-oriented learning.
- Full Text:
- Date Issued: 2012
- Authors: Mukute, Mutizwa , Lotz-Sisitka, Heila
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182494 , vital:43835 , xlink:href="https://doi.org/10.1080/10749039.2012.656173"
- Description: This article uses the theoretical and methodological tools of cultural historical activity theory and critical realism to examine three case studies of the introduction and expansion of sustainable agricultural practices in southern Africa. The article addresses relevant issues in the field of agricultural extension, which lacks a theoretical “bridge” between top-down knowledge transfer and bottom-up participatory approaches to learning. Further, the article considers the learning environments necessary for sustainable agriculture. Such environments provided research participants with encounters with “postnormal” scientific practices that recognise and engage plural ways of knowing. Our research explored why farmers learn and practise sustainable agriculture, how they learn and practise it, the contradictions they are facing, and how these contradictions can be overcome in a context of change-oriented learning.
- Full Text:
- Date Issued: 2012
Working with cultural-historical activity theory and critical realism to investigate and expand farmer learning in Southern Africa
- Mukute, Mutizwa, Lotz-Sisitka, Heila
- Authors: Mukute, Mutizwa , Lotz-Sisitka, Heila
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/391236 , vital:68633 , xlink:href="https://doi.org/10.1080/10749039.2012.656173"
- Description: This article uses the theoretical and methodological tools of cultural historical activity theory and critical realism to examine three case studies of the introduction and expansion of sustainable agricultural practices in southern Africa. The article addresses relevant issues in the field of agricultural extension, which lacks a theoretical “bridge” between top-down knowledge transfer and bottom-up participatory approaches to learning. Further, the article considers the learning environments necessary for sustainable agriculture. Such environments provided research participants with encounters with “postnormal” scientific practices that recognise and engage plural ways of knowing. Our research explored why farmers learn and practise sustainable agriculture, how they learn and practise it, the contradictions they are facing, and how these contradictions can be overcome in a context of change-oriented learning.
- Full Text:
- Date Issued: 2012
- Authors: Mukute, Mutizwa , Lotz-Sisitka, Heila
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/391236 , vital:68633 , xlink:href="https://doi.org/10.1080/10749039.2012.656173"
- Description: This article uses the theoretical and methodological tools of cultural historical activity theory and critical realism to examine three case studies of the introduction and expansion of sustainable agricultural practices in southern Africa. The article addresses relevant issues in the field of agricultural extension, which lacks a theoretical “bridge” between top-down knowledge transfer and bottom-up participatory approaches to learning. Further, the article considers the learning environments necessary for sustainable agriculture. Such environments provided research participants with encounters with “postnormal” scientific practices that recognise and engage plural ways of knowing. Our research explored why farmers learn and practise sustainable agriculture, how they learn and practise it, the contradictions they are facing, and how these contradictions can be overcome in a context of change-oriented learning.
- Full Text:
- Date Issued: 2012
Working in poverty: Informal employment of household gardeners in Eastern Cape towns, South Africa
- King, A, Shackleton, Charlie M
- Authors: King, A , Shackleton, Charlie M
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/401398 , vital:69731 , xlink:href="https://doi.org/10.1080/0376835X.2021.1940867"
- Description: In South Africa there has been relatively little consideration of the informal employment offered to domestic household workers and gardeners. Here we report on the number and profile of gardeners employed by private households and the wage and satisfaction rates in 12 towns of the Eastern Cape. Over 98% of the informal gardeners were male, middle-aged and with limited formal schooling. Approximately 58% of middle and upper income households employed a gardener, at a mean daily rate of R112.20 in 2019. This equated to 13 170 gardeners earning a total wage bill of R139 million p.a. across the 12 towns, which scales up to 0.7–1 million informal gardeners nationally earning approximately R10–14 billion per year. However, daily remuneration was insufficient to cover basic needs, and slightly more than half of the gardeners would prefer a different job, indicating the survivalist nature of the sector.
- Full Text:
- Date Issued: 2022
- Authors: King, A , Shackleton, Charlie M
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/401398 , vital:69731 , xlink:href="https://doi.org/10.1080/0376835X.2021.1940867"
- Description: In South Africa there has been relatively little consideration of the informal employment offered to domestic household workers and gardeners. Here we report on the number and profile of gardeners employed by private households and the wage and satisfaction rates in 12 towns of the Eastern Cape. Over 98% of the informal gardeners were male, middle-aged and with limited formal schooling. Approximately 58% of middle and upper income households employed a gardener, at a mean daily rate of R112.20 in 2019. This equated to 13 170 gardeners earning a total wage bill of R139 million p.a. across the 12 towns, which scales up to 0.7–1 million informal gardeners nationally earning approximately R10–14 billion per year. However, daily remuneration was insufficient to cover basic needs, and slightly more than half of the gardeners would prefer a different job, indicating the survivalist nature of the sector.
- Full Text:
- Date Issued: 2022
Woody plant species richness, composition and structure in urban sacred sites, Grahamstown, South Africa
- De Lacy, Peter J G, Shackleton, Charlie M
- Authors: De Lacy, Peter J G , Shackleton, Charlie M
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180079 , vital:43307 , xlink:href="https://doi.org/10.1007/s11252-017-0669-y"
- Description: Sacred sites are important not only for their traditional, spiritual or religious significance, but may also potentially be valuable for biodiversity conservation in human transformed landscapes. Yet, there has been little consideration of sacred sites in urban areas in this respect. Consequently, to better understand the ecosystem service and conservation value of urban sacred sites, inventories of their floral communities are needed. We examined the richness, composition and structure of the trees and shrubs in 35 urban churchyards and cemeteries in the City of Saints (Grahamstown). The combined area of urban sacred sites (38.7 ha) represented 2.2% of the city area and 13.6% of the public green space area. Species richness of woody plants was high, albeit dominated by non-native species. Levels of similarity among sites were low, indicating the effects of individual management regimens. There was no relationship between age of the site and measured attributes of the vegetation, nor were there any significant differences in vegetation among different religious denominations. However, the basal area and number of woody plants was significantly related to site size. These results indicate the significant heterogeneity of urban sacred sites as green spaces within the urban matrix. The significance of this heterogeneity in providing ecosystem services to users of sacred sites and the broader urban communities requires further investigation.
- Full Text:
- Date Issued: 2017
- Authors: De Lacy, Peter J G , Shackleton, Charlie M
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180079 , vital:43307 , xlink:href="https://doi.org/10.1007/s11252-017-0669-y"
- Description: Sacred sites are important not only for their traditional, spiritual or religious significance, but may also potentially be valuable for biodiversity conservation in human transformed landscapes. Yet, there has been little consideration of sacred sites in urban areas in this respect. Consequently, to better understand the ecosystem service and conservation value of urban sacred sites, inventories of their floral communities are needed. We examined the richness, composition and structure of the trees and shrubs in 35 urban churchyards and cemeteries in the City of Saints (Grahamstown). The combined area of urban sacred sites (38.7 ha) represented 2.2% of the city area and 13.6% of the public green space area. Species richness of woody plants was high, albeit dominated by non-native species. Levels of similarity among sites were low, indicating the effects of individual management regimens. There was no relationship between age of the site and measured attributes of the vegetation, nor were there any significant differences in vegetation among different religious denominations. However, the basal area and number of woody plants was significantly related to site size. These results indicate the significant heterogeneity of urban sacred sites as green spaces within the urban matrix. The significance of this heterogeneity in providing ecosystem services to users of sacred sites and the broader urban communities requires further investigation.
- Full Text:
- Date Issued: 2017