Identifying the need for the development of an instrument to determine senior phase teachers' science-assessment competence
- Authors: Lombard, Elsa Helena
- Date: 2002
- Subjects: Science -- Ability testing -- South Africa , Science -- Study and teaching -- South Africa -- Port Elizabeth -- Evaluation , Educational tests and measurements -- South Africa , Competency-based education -- South Africa
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10786 , http://hdl.handle.net/10948/100 , Science -- Ability testing -- South Africa , Science -- Study and teaching -- South Africa -- Port Elizabeth -- Evaluation , Educational tests and measurements -- South Africa , Competency-based education -- South Africa
- Description: The focus of this study is the competences expected of teachers in the senior phase to assess the Natural Sciences learning area. In order to be in line with the new developments, the South African science teacher will need relevant assessment training in order to utilise appropriate techniques that are in line with the new educational philosophy. The question arises: What competences do teachers need for assessing science in the senior phase? An ethnographic case study was implemented as research methodology in the descriptive research paradigm. The investigation comprised observing the classroom practices of a sample of three senior phase science teachers in two primary schools and in one secondary school in the Port Elizabeth region. The data obtained from the observations were triangulated with related artefacts produced by both the teachers and the learners in each case. In order to establish these expected competences a document analysis was done from a selection of South African documents. The descriptions of the real life assessment practices of the sample of science teachers were then compared with the competences expected by the South African education system. The comparison between the real-life assessment practices and the expected practices concurred with Shepard’s (2000, p.12) belief that the abilities needed to implement classroom assessment “are daunting”. The classroom-based assessment practices of the sample of teachers revealed a variety of assessment beliefs, practices and competence. The needs of these teachers are so diversified and intense that individualised professional development is needed if sustained implementation of the new curriculum and accompanying assessment competences is to be facilitated. The research established the need to develop an instrument that the science teachers can use to assess their own competence. There should be training modules drawn up in line with this instrument. Teachers should be able to choose the professional development modules that would address their own unique needs
- Full Text:
- Date Issued: 2002
- Authors: Lombard, Elsa Helena
- Date: 2002
- Subjects: Science -- Ability testing -- South Africa , Science -- Study and teaching -- South Africa -- Port Elizabeth -- Evaluation , Educational tests and measurements -- South Africa , Competency-based education -- South Africa
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10786 , http://hdl.handle.net/10948/100 , Science -- Ability testing -- South Africa , Science -- Study and teaching -- South Africa -- Port Elizabeth -- Evaluation , Educational tests and measurements -- South Africa , Competency-based education -- South Africa
- Description: The focus of this study is the competences expected of teachers in the senior phase to assess the Natural Sciences learning area. In order to be in line with the new developments, the South African science teacher will need relevant assessment training in order to utilise appropriate techniques that are in line with the new educational philosophy. The question arises: What competences do teachers need for assessing science in the senior phase? An ethnographic case study was implemented as research methodology in the descriptive research paradigm. The investigation comprised observing the classroom practices of a sample of three senior phase science teachers in two primary schools and in one secondary school in the Port Elizabeth region. The data obtained from the observations were triangulated with related artefacts produced by both the teachers and the learners in each case. In order to establish these expected competences a document analysis was done from a selection of South African documents. The descriptions of the real life assessment practices of the sample of science teachers were then compared with the competences expected by the South African education system. The comparison between the real-life assessment practices and the expected practices concurred with Shepard’s (2000, p.12) belief that the abilities needed to implement classroom assessment “are daunting”. The classroom-based assessment practices of the sample of teachers revealed a variety of assessment beliefs, practices and competence. The needs of these teachers are so diversified and intense that individualised professional development is needed if sustained implementation of the new curriculum and accompanying assessment competences is to be facilitated. The research established the need to develop an instrument that the science teachers can use to assess their own competence. There should be training modules drawn up in line with this instrument. Teachers should be able to choose the professional development modules that would address their own unique needs
- Full Text:
- Date Issued: 2002
Weaving cloths: Research design in contexts of transformation
- Authors: Lotz-Sisitka, Heila
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184745 , vital:44268 , xlink:href="https://cjee.lakeheadu.ca/article/viewFile/259/136"
- Description: Through storytelling, I apply methodological and epistemological reflexivity to ask questions about the way in which environmental education research is framed in transformational settings. I ask questions about the role of research teachers/supervisors in the “weaving enterprise” or the research process. Do we have the dual task of developing contextually relevant frameworks, and of making sure that these frameworks are not adopted on an “industrial scale”—in other words, as new paradigms which have the potential to narrow research possibilities? The paper concerns itself with a broader question, notably the potentially debilitating effects of mass production of research, or the globalizing of knowledge production. The story I use to raise these, and other questions for consideration by teachers/supervisors of research is a research workers story (my own), constructed between 1992 and 1996, in a context of rapid socio-political and educational transformation in South Africa (Lotz, 1996). In addition to the above, the paper opens a debate about reflexivity as research methodological rigour.
- Full Text:
- Date Issued: 2002
- Authors: Lotz-Sisitka, Heila
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184745 , vital:44268 , xlink:href="https://cjee.lakeheadu.ca/article/viewFile/259/136"
- Description: Through storytelling, I apply methodological and epistemological reflexivity to ask questions about the way in which environmental education research is framed in transformational settings. I ask questions about the role of research teachers/supervisors in the “weaving enterprise” or the research process. Do we have the dual task of developing contextually relevant frameworks, and of making sure that these frameworks are not adopted on an “industrial scale”—in other words, as new paradigms which have the potential to narrow research possibilities? The paper concerns itself with a broader question, notably the potentially debilitating effects of mass production of research, or the globalizing of knowledge production. The story I use to raise these, and other questions for consideration by teachers/supervisors of research is a research workers story (my own), constructed between 1992 and 1996, in a context of rapid socio-political and educational transformation in South Africa (Lotz, 1996). In addition to the above, the paper opens a debate about reflexivity as research methodological rigour.
- Full Text:
- Date Issued: 2002
Being Brave: Writing Environmental Education Research
- Lotz-Sisitka, Heila, Burt, Jane C
- Authors: Lotz-Sisitka, Heila , Burt, Jane C
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184734 , vital:44267 , xlink:href="https://eric.ed.gov/?id=EJ654591"
- Description: The heroine came back from her very important quest and sat down to write a thesis . . . While mythical journeys do not always end this way, the stories have to be told. The work of telling the story in the hero’s journey is often left untold. This paper explores some of the headwork that goes into textwork (Van Manen, 1995) in environmental education research. We argue that writing is an integral part of the research process, and should not be viewed as an “add on” or a silent, untold part of the adventure. We reflect on some of the institutional and epistemological issues associated with writing social science (in our case environmental education) research texts. Writing research is never an easy enterprise, it is bound by history and tradition, convention, institutional habit, and regulation. It is also constrained by the uncertainty of the process of writing itself, by problems of power relations in research, and the difficulty of writing to represent experience rigorously and authentically while recognizing that all writing is a constructed symbolic representation of experience. The paper reflexively reviews our attempts at “being brave” in the construction of our research texts.
- Full Text:
- Date Issued: 2002
- Authors: Lotz-Sisitka, Heila , Burt, Jane C
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184734 , vital:44267 , xlink:href="https://eric.ed.gov/?id=EJ654591"
- Description: The heroine came back from her very important quest and sat down to write a thesis . . . While mythical journeys do not always end this way, the stories have to be told. The work of telling the story in the hero’s journey is often left untold. This paper explores some of the headwork that goes into textwork (Van Manen, 1995) in environmental education research. We argue that writing is an integral part of the research process, and should not be viewed as an “add on” or a silent, untold part of the adventure. We reflect on some of the institutional and epistemological issues associated with writing social science (in our case environmental education) research texts. Writing research is never an easy enterprise, it is bound by history and tradition, convention, institutional habit, and regulation. It is also constrained by the uncertainty of the process of writing itself, by problems of power relations in research, and the difficulty of writing to represent experience rigorously and authentically while recognizing that all writing is a constructed symbolic representation of experience. The paper reflexively reviews our attempts at “being brave” in the construction of our research texts.
- Full Text:
- Date Issued: 2002
The impact of media commercialisation on programming: a study of Radio Uganda
- Lwanga, Margaret Jjuuko Nassuna
- Authors: Lwanga, Margaret Jjuuko Nassuna
- Date: 2002
- Subjects: Radio programs -- Uganda , Radio Uganda , Public radio -- Uganda
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3453 , http://hdl.handle.net/10962/d1002907 , Radio programs -- Uganda , Radio Uganda , Public radio -- Uganda
- Description: The 1980s and 1990s saw two major changes in the political economy of the media and the world economy at large: technological advancement and transfer and privatisation. There were significant shifts in media industries: newspapers, broadcasting, cinema and telecommunications when governments begun re-regulating their air waves so as to permit private satellite transmission via both encryption and free-to-air, in addition to public service and private channels. In most societies where these changes have taken place, public service broadcasting has been threatened by the rapid rise of commercial institutions, resulting in stiff competition for audiences. This study set out to determine the extent to which commercialisation, in the era of liberalisation and commercialisation of media services in Uganda, has affected Radio Uganda’s programming. Using a combination of qualitative and quantitative methods of investigation, I have established that while Radio Uganda still maintains certain public service principles and values, programming policy has increasingly been changed by commercial considerations. This is shown by the recent rise of commercial programmes and a fall in education and developmental programmes. Limitations of finance and other resources have compromised the roles and character of public service radio programming. The majority of programmes currently on Radio Uganda are evidently geared to attract advertisers rather than serve the public interest. The study recommends, among other measures, that the licence fee be developed as a source of revenue for Radio Uganda. Secondly, government should inject more funding into public service broadcasting institutions to supplement other sources of income, before granting them autonomy. Thirdly, while advertising and sponsorship brings in a considerable amount of revenue, it should not take a central place that undermines the listener’s interest in radio programming. The Broadcasting Council should therefore map out solid policies that will systematically guide Radio Uganda in its programming in the new order.
- Full Text:
- Date Issued: 2002
- Authors: Lwanga, Margaret Jjuuko Nassuna
- Date: 2002
- Subjects: Radio programs -- Uganda , Radio Uganda , Public radio -- Uganda
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3453 , http://hdl.handle.net/10962/d1002907 , Radio programs -- Uganda , Radio Uganda , Public radio -- Uganda
- Description: The 1980s and 1990s saw two major changes in the political economy of the media and the world economy at large: technological advancement and transfer and privatisation. There were significant shifts in media industries: newspapers, broadcasting, cinema and telecommunications when governments begun re-regulating their air waves so as to permit private satellite transmission via both encryption and free-to-air, in addition to public service and private channels. In most societies where these changes have taken place, public service broadcasting has been threatened by the rapid rise of commercial institutions, resulting in stiff competition for audiences. This study set out to determine the extent to which commercialisation, in the era of liberalisation and commercialisation of media services in Uganda, has affected Radio Uganda’s programming. Using a combination of qualitative and quantitative methods of investigation, I have established that while Radio Uganda still maintains certain public service principles and values, programming policy has increasingly been changed by commercial considerations. This is shown by the recent rise of commercial programmes and a fall in education and developmental programmes. Limitations of finance and other resources have compromised the roles and character of public service radio programming. The majority of programmes currently on Radio Uganda are evidently geared to attract advertisers rather than serve the public interest. The study recommends, among other measures, that the licence fee be developed as a source of revenue for Radio Uganda. Secondly, government should inject more funding into public service broadcasting institutions to supplement other sources of income, before granting them autonomy. Thirdly, while advertising and sponsorship brings in a considerable amount of revenue, it should not take a central place that undermines the listener’s interest in radio programming. The Broadcasting Council should therefore map out solid policies that will systematically guide Radio Uganda in its programming in the new order.
- Full Text:
- Date Issued: 2002
State or public service broadcasting?: an analysis of the coverage of political issues and debates during an election campaign on television news
- Authors: Macha, Herbert
- Date: 2002
- Subjects: Public service television programs -- Zambia , Television in politics , Television broadcasting of news -- Zambia , Elections -- Zambia
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3502 , http://hdl.handle.net/10962/d1006234 , Public service television programs -- Zambia , Television in politics , Television broadcasting of news -- Zambia , Elections -- Zambia
- Description: Public Service Television remains a key institution of democratisation in the context of emerging democracies in Africa, especially with the advent of liberalisation and commercialisation of the media. The democratic changes taking place in Zambia require a genuine public service broadcasting television that will promote pluralism in the public sphere. Among the many available strategies and mechanisms for fostering a sustainable democratic and cultural environment, public service broadcasting is still the best. This study set out to examine representation of political issues and debates during election campaign on ZNBC television news to assess the extent to which it plays a role as a public broadcaster in the mediation of pluralistic politics. Election news on television, in line with the public sphere argument was found to be essential for investigating the nature of public service television from the point of view of impartiality, universality and diversity. Using both qualitative and quantitative methods the study has confirmed the hypothesis that the role of a public service television in the mediation of pluralistic politics is compromised by ZNBC's partial and unbalanced coverage of elections. As a result ZNBC, as a public service broadcaster is undermining the very democracy it is expected to promote. Public service television should take new forms if it is to be recognised and appreciated by the public as a genuine, open and democratic public sphere. I therefore recommend that a system of license fee for viewers be introduced. Secondly, government should increase funding into public service television to supplement revenue from license fee and advertising. Thirdly, I recommend the appointment of an independent board whose members will be appointed for a fixed term, by public nomination and a process of public hearing, according to publicly available criteria, which guarantees diversity of political, ethnic, social and professional background. Fourthly I suggest the formation of an Election News Coverage Committee comprising of journalists, academicians, the church and civic organisation that will formulate and implement editorial policy on election coverage and above all monitor and the coverage of elections on ZNBC television news.
- Full Text:
- Date Issued: 2002
- Authors: Macha, Herbert
- Date: 2002
- Subjects: Public service television programs -- Zambia , Television in politics , Television broadcasting of news -- Zambia , Elections -- Zambia
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3502 , http://hdl.handle.net/10962/d1006234 , Public service television programs -- Zambia , Television in politics , Television broadcasting of news -- Zambia , Elections -- Zambia
- Description: Public Service Television remains a key institution of democratisation in the context of emerging democracies in Africa, especially with the advent of liberalisation and commercialisation of the media. The democratic changes taking place in Zambia require a genuine public service broadcasting television that will promote pluralism in the public sphere. Among the many available strategies and mechanisms for fostering a sustainable democratic and cultural environment, public service broadcasting is still the best. This study set out to examine representation of political issues and debates during election campaign on ZNBC television news to assess the extent to which it plays a role as a public broadcaster in the mediation of pluralistic politics. Election news on television, in line with the public sphere argument was found to be essential for investigating the nature of public service television from the point of view of impartiality, universality and diversity. Using both qualitative and quantitative methods the study has confirmed the hypothesis that the role of a public service television in the mediation of pluralistic politics is compromised by ZNBC's partial and unbalanced coverage of elections. As a result ZNBC, as a public service broadcaster is undermining the very democracy it is expected to promote. Public service television should take new forms if it is to be recognised and appreciated by the public as a genuine, open and democratic public sphere. I therefore recommend that a system of license fee for viewers be introduced. Secondly, government should increase funding into public service television to supplement revenue from license fee and advertising. Thirdly, I recommend the appointment of an independent board whose members will be appointed for a fixed term, by public nomination and a process of public hearing, according to publicly available criteria, which guarantees diversity of political, ethnic, social and professional background. Fourthly I suggest the formation of an Election News Coverage Committee comprising of journalists, academicians, the church and civic organisation that will formulate and implement editorial policy on election coverage and above all monitor and the coverage of elections on ZNBC television news.
- Full Text:
- Date Issued: 2002
Deconstructive discourse analysis: extending the methodological conversation
- Authors: Macleod, Catriona I
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6259 , http://hdl.handle.net/10962/d1007877 , http://journals.sagepub.com/doi/abs/10.1177/008124630203200103
- Description: Discourse analysis is increasingly becoming a methodology of preference amongst qualitative researchers. There is a danger, however, of it being viewed as a bounded and uncontested domain of research practice. As discourse analysis is inextricably linked with theoretical issues, it is a dynamic practice that is constantly in a process of revision. In this paper I reflect on some of the conceptualisations undergirding the notion of discourse – conceptualisations that have important implications in terms of how the practice of discourse analysis proceeds. I highlight some of the dualisms that may plague discourse analysis, and offer some solutions to these. Finally, I outline the deconstructive discourse analysis that I utilised in my doctoral work. The purpose of the latter is not to provide a recipe of methodology, but to illustrate how elements of various theorists’ work (in this case Foucault, Derrida and Parker) may be profitably drawn together to perform specific discourse analytic work. , Rhodes University
- Full Text:
- Date Issued: 2002
- Authors: Macleod, Catriona I
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6259 , http://hdl.handle.net/10962/d1007877 , http://journals.sagepub.com/doi/abs/10.1177/008124630203200103
- Description: Discourse analysis is increasingly becoming a methodology of preference amongst qualitative researchers. There is a danger, however, of it being viewed as a bounded and uncontested domain of research practice. As discourse analysis is inextricably linked with theoretical issues, it is a dynamic practice that is constantly in a process of revision. In this paper I reflect on some of the conceptualisations undergirding the notion of discourse – conceptualisations that have important implications in terms of how the practice of discourse analysis proceeds. I highlight some of the dualisms that may plague discourse analysis, and offer some solutions to these. Finally, I outline the deconstructive discourse analysis that I utilised in my doctoral work. The purpose of the latter is not to provide a recipe of methodology, but to illustrate how elements of various theorists’ work (in this case Foucault, Derrida and Parker) may be profitably drawn together to perform specific discourse analytic work. , Rhodes University
- Full Text:
- Date Issued: 2002
Foucauldian feminism: the implications of governmentality
- Macleod, Catriona I, Durrheim, Kevin
- Authors: Macleod, Catriona I , Durrheim, Kevin
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6261 , http://hdl.handle.net/10962/d1007879
- Description: Foucauldian discourse has been received with varying degrees of enthusiasm within feminist circles. Some authors (e.g. Balbus, 1988; Di Leonardo, 1991; Hartsock, 1990) see a Foucauldian stance as incompatible with feminist theory, while others (e.g. Grimshaw, 1993; Hoy, 1988; McNay, 1992; Sawicki, 1988) advocate a positive relationship between Foucauldian discourse and feminism. And then there are those theorists (e.g. Burman, 1990) who stand between these two positions, stating that while Foucault offers useful insights and methods to feminists, it can also be dangerous.
- Full Text:
- Date Issued: 2002
- Authors: Macleod, Catriona I , Durrheim, Kevin
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6261 , http://hdl.handle.net/10962/d1007879
- Description: Foucauldian discourse has been received with varying degrees of enthusiasm within feminist circles. Some authors (e.g. Balbus, 1988; Di Leonardo, 1991; Hartsock, 1990) see a Foucauldian stance as incompatible with feminist theory, while others (e.g. Grimshaw, 1993; Hoy, 1988; McNay, 1992; Sawicki, 1988) advocate a positive relationship between Foucauldian discourse and feminism. And then there are those theorists (e.g. Burman, 1990) who stand between these two positions, stating that while Foucault offers useful insights and methods to feminists, it can also be dangerous.
- Full Text:
- Date Issued: 2002
Racializing teenage pregnancy : ‘culture’ and ‘tradition’ in the South African scientific literature
- Macleod, Catriona I, Durrheim, Kevin
- Authors: Macleod, Catriona I , Durrheim, Kevin
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6260 , http://hdl.handle.net/10962/d1007878
- Description: The signifiers, ‘race’, ‘culture’ or ‘ethnicity’ are utilized in the teenage pregnancy literature (1) to highlight ‘differences’ in adolescent sexual and reproductive behaviour and (2) as explanatory tools. When ‘white’ teenagers are the focus of research, psychological explanations are usually invoked, while for ‘black’ teenagers, explanations are socio-cultural in nature. In this paper, we explore how, through a process of racialization, the psycho-medical literature on teenage pregnancy in South Africa contributes to the entrenchment of ‘race’, ‘culture’ and ‘ethnicity’ as fixed, ‘natural’ signifiers. We utilize Derrida’s notion of différance, together with Phoenix and Woollett’s adaptation – ‘normalized absence/pathologized presence’ – to indicate how ‘black’ people are cast as the Other, the pathologized presence which relies on the normalized absent trace, ‘whiteness’, for definition. We analyse how the notions of ‘tradition’ and ‘culture’ are deployed to sanitize or disguise the underlying racializing project. ‘Black’ is exoticized and rendered strange and thus open to scrutiny, monitoring and intervention. ‘Culture’ and ‘tradition’ appeal to the myth of origin, thus providing pseudo-historical explanations which essentialize and naturalize racialized collectivities. , Rhodes University
- Full Text:
- Date Issued: 2002
Racializing teenage pregnancy : ‘culture’ and ‘tradition’ in the South African scientific literature
- Authors: Macleod, Catriona I , Durrheim, Kevin
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6260 , http://hdl.handle.net/10962/d1007878
- Description: The signifiers, ‘race’, ‘culture’ or ‘ethnicity’ are utilized in the teenage pregnancy literature (1) to highlight ‘differences’ in adolescent sexual and reproductive behaviour and (2) as explanatory tools. When ‘white’ teenagers are the focus of research, psychological explanations are usually invoked, while for ‘black’ teenagers, explanations are socio-cultural in nature. In this paper, we explore how, through a process of racialization, the psycho-medical literature on teenage pregnancy in South Africa contributes to the entrenchment of ‘race’, ‘culture’ and ‘ethnicity’ as fixed, ‘natural’ signifiers. We utilize Derrida’s notion of différance, together with Phoenix and Woollett’s adaptation – ‘normalized absence/pathologized presence’ – to indicate how ‘black’ people are cast as the Other, the pathologized presence which relies on the normalized absent trace, ‘whiteness’, for definition. We analyse how the notions of ‘tradition’ and ‘culture’ are deployed to sanitize or disguise the underlying racializing project. ‘Black’ is exoticized and rendered strange and thus open to scrutiny, monitoring and intervention. ‘Culture’ and ‘tradition’ appeal to the myth of origin, thus providing pseudo-historical explanations which essentialize and naturalize racialized collectivities. , Rhodes University
- Full Text:
- Date Issued: 2002
Economic security and the social science literature on teenage pregnancy in South Africa
- Authors: Macleod, Catriona I
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6253 , http://hdl.handle.net/10962/d1007871
- Description: Feminists have argued that the association made between teenage childbearing and long-term lower socioeconomic status hides a multitude of socially constructed inequalities. I extend this position by analysing how the association is linked in the South African literature on teenage pregnancy to economic security. I utilise Foucault’s conceptualization of the method of security. Security refers to institutions and practices that defend and maintain a national population as well as secure the economic, demographic, and social processes of that population. I analyse how the traits of the method of security are deployed with regard to teenage pregnancy; how reproductive adolescents are viewed as disrupting the production of the economic self and fracturing population control, thereby threatening economic security; and how the invocation of economic security allows for the legitimation of various regulatory practices. , Rhodes University
- Full Text:
- Date Issued: 2002
- Authors: Macleod, Catriona I
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6253 , http://hdl.handle.net/10962/d1007871
- Description: Feminists have argued that the association made between teenage childbearing and long-term lower socioeconomic status hides a multitude of socially constructed inequalities. I extend this position by analysing how the association is linked in the South African literature on teenage pregnancy to economic security. I utilise Foucault’s conceptualization of the method of security. Security refers to institutions and practices that defend and maintain a national population as well as secure the economic, demographic, and social processes of that population. I analyse how the traits of the method of security are deployed with regard to teenage pregnancy; how reproductive adolescents are viewed as disrupting the production of the economic self and fracturing population control, thereby threatening economic security; and how the invocation of economic security allows for the legitimation of various regulatory practices. , Rhodes University
- Full Text:
- Date Issued: 2002
A critical review of literature on the expected roles of principals in schools
- Authors: Madaza, Simbongile Simphiwe
- Date: 2002
- Subjects: School principals -- South Africa School management and organization -- South Africa Educational change -- South Africa Educational leadership -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1914 , http://hdl.handle.net/10962/d1007243
- Description: Schools, like all organizations, are undergoing radical changes in the way that their business is conducted. "One of the most significant of these is that leadership, rather than management, needs to be seen as the most crucial focus for institutional development and growth in the years ahead," (Whitaker, 1993). In these projects I focus on three dimensions of leadership. First, a critical review of literature on the expected roles of principals in schools. Second, a case study of change management at a South African senior secondary school; and finally, a situational analysis of my organization with regard to organizational structure, leadership, decision making, communication and interpersonal relationships.
- Full Text:
- Date Issued: 2002
- Authors: Madaza, Simbongile Simphiwe
- Date: 2002
- Subjects: School principals -- South Africa School management and organization -- South Africa Educational change -- South Africa Educational leadership -- South Africa
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1914 , http://hdl.handle.net/10962/d1007243
- Description: Schools, like all organizations, are undergoing radical changes in the way that their business is conducted. "One of the most significant of these is that leadership, rather than management, needs to be seen as the most crucial focus for institutional development and growth in the years ahead," (Whitaker, 1993). In these projects I focus on three dimensions of leadership. First, a critical review of literature on the expected roles of principals in schools. Second, a case study of change management at a South African senior secondary school; and finally, a situational analysis of my organization with regard to organizational structure, leadership, decision making, communication and interpersonal relationships.
- Full Text:
- Date Issued: 2002
Biosulphidogenic hydrolysis of lignin and lignin model compounds
- Authors: Madikane, Mzekelo
- Date: 2002
- Subjects: Lignin Lignin -- Biodegradation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3917 , http://hdl.handle.net/10962/d1003976
- Description: Lignin degradation under biosulphidogenic conditions has not been extensively reported in the literature. Although aerobic degradation of lignin is well documented, anaerobic biodegradation has focused mainly on methanogenic systems with biosulphidogenic systems receiving less attention. Sulphate reducing bacteria are known to generate moderately high levels of both sulphide and alkalinity at room temperatures, and these conditions draw some comparison with the Kraft pulping process. In the Kraft pulping process, lignin is degraded chemically at ±170°C under high sulphide and alkaline conditions and may provide a model for understanding biosulphidogenic lignin degrading activity. The aim of this study was to investigate the biosulphidogenic hydrolysis of lignin within the context of the chemical and biological conditions generated by a mixed sulphate reducing bacteria consortia. Bioreactor studies with a mixed sulphate reducing consortia and pine wood powder (both untreated and depectinated) resulted in the generation of comparable levels of sulphide and alkalinity used in the chemical hydrolysis studies. Aromatic compound yields were between 20 to 50% of the chemical hydrolysis studies. This fluctuation may have been due to the utilization of these aromatic compounds as electron donors by the sulphate reducing consortia as evidenced by the high rate of sulphate reduction in both the untreated and depectinated wood bioreactors. Biodegradation of lignin model compounds was investigated in order to elucidate lignin degradation mechanisms. Both mono-aromatic and dimeric lignin model compounds were used as electron donors and carbon sources for the mixed sulphate reducing consortia. Biodegradation and mass spectrometer analysis of mono-aromatic compounds, ferulic acid and ferulic acid ethyl ester resulted in the production of intermediates such as catechol, cyclohexane carboxylic acid and adipic acid. These intermediates were also observed in the degradation of dimeric ferulic acid. Biodegradation of salicin resulted in the production of salicyl alcohol, ortho-cresol and acetate. Biodegradation of benzylic ether resulted in the production of vanillin and acetate as end products. The results of these studies provide evidence for a biosulphidogenic hydrolysis of lignin, and also the utilisation of lignin-derived aromatic compounds as electron donor sources, by a mixed sulphate reducing consortia.
- Full Text:
- Date Issued: 2002
- Authors: Madikane, Mzekelo
- Date: 2002
- Subjects: Lignin Lignin -- Biodegradation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:3917 , http://hdl.handle.net/10962/d1003976
- Description: Lignin degradation under biosulphidogenic conditions has not been extensively reported in the literature. Although aerobic degradation of lignin is well documented, anaerobic biodegradation has focused mainly on methanogenic systems with biosulphidogenic systems receiving less attention. Sulphate reducing bacteria are known to generate moderately high levels of both sulphide and alkalinity at room temperatures, and these conditions draw some comparison with the Kraft pulping process. In the Kraft pulping process, lignin is degraded chemically at ±170°C under high sulphide and alkaline conditions and may provide a model for understanding biosulphidogenic lignin degrading activity. The aim of this study was to investigate the biosulphidogenic hydrolysis of lignin within the context of the chemical and biological conditions generated by a mixed sulphate reducing bacteria consortia. Bioreactor studies with a mixed sulphate reducing consortia and pine wood powder (both untreated and depectinated) resulted in the generation of comparable levels of sulphide and alkalinity used in the chemical hydrolysis studies. Aromatic compound yields were between 20 to 50% of the chemical hydrolysis studies. This fluctuation may have been due to the utilization of these aromatic compounds as electron donors by the sulphate reducing consortia as evidenced by the high rate of sulphate reduction in both the untreated and depectinated wood bioreactors. Biodegradation of lignin model compounds was investigated in order to elucidate lignin degradation mechanisms. Both mono-aromatic and dimeric lignin model compounds were used as electron donors and carbon sources for the mixed sulphate reducing consortia. Biodegradation and mass spectrometer analysis of mono-aromatic compounds, ferulic acid and ferulic acid ethyl ester resulted in the production of intermediates such as catechol, cyclohexane carboxylic acid and adipic acid. These intermediates were also observed in the degradation of dimeric ferulic acid. Biodegradation of salicin resulted in the production of salicyl alcohol, ortho-cresol and acetate. Biodegradation of benzylic ether resulted in the production of vanillin and acetate as end products. The results of these studies provide evidence for a biosulphidogenic hydrolysis of lignin, and also the utilisation of lignin-derived aromatic compounds as electron donor sources, by a mixed sulphate reducing consortia.
- Full Text:
- Date Issued: 2002
The identification of the UV degradants of melatonin and their ability to scavenge free radicals
- Maharaj, Deepa S, Anoopkumar-Dukie, Shailendra, Glass, Beverley D, Antunes, Edith M, Lack, Barbara A, Walker, Roderick B, Daya, Santylal
- Authors: Maharaj, Deepa S , Anoopkumar-Dukie, Shailendra , Glass, Beverley D , Antunes, Edith M , Lack, Barbara A , Walker, Roderick B , Daya, Santylal
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184303 , vital:44198 , xlink:href="https://doi.org/10.1034/j.1600-079X.2002.01866.x"
- Description: Ultraviolet (UV) light is known to induce the generation of free radicals in biological tissues such as skin. Of these free radicals, the O2–· and particularly the ·OH radical can induce cellular damage including lipid peroxidation. Thus, the use of antioxidants to prevent such damage induced by UV irradiation has received much attention recently. One such antioxidant, which has the potential to be incorporated into sunscreens, is the pineal secretory product melatonin. One of the concerns of using melatonin in sunscreens is its photostability. In the present study, we investigated the photostability of melatonin subjected to UV irradiation. In addition, we used liquid chromatography mass spectrometry (LC-MS) to identify the degradants and we also assessed the ability of the degradants to inhibit O2–· generation as well as lipid peroxidation in rat brain homogenate. The results show that UV irradiation of melatonin (0.1 mg/mL) using a 400-W lamp for 2 hr caused a significant decline of melatonin to 18% of its original concentration after 20 min, with the decline continuing until the melatonin concentration reaches zero at 120 min. The LC-MS results show that the degradants of melatonin are 6-hydroxymelatonin and N1-acetyl-N2-formyl-5-methoxykynurenamine (AFMK). These degradants were able to provide equipotent activity against potassium cyanide (KCN)-induced superoxide generation compared to non-irradiated melatonin. Thus, the study shows that although melatonin is rapidly degraded by UV irradiation, the degradants retain antioxidant activity, making melatonin a likely candidate for inclusion in sunscreens.
- Full Text:
- Date Issued: 2002
- Authors: Maharaj, Deepa S , Anoopkumar-Dukie, Shailendra , Glass, Beverley D , Antunes, Edith M , Lack, Barbara A , Walker, Roderick B , Daya, Santylal
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184303 , vital:44198 , xlink:href="https://doi.org/10.1034/j.1600-079X.2002.01866.x"
- Description: Ultraviolet (UV) light is known to induce the generation of free radicals in biological tissues such as skin. Of these free radicals, the O2–· and particularly the ·OH radical can induce cellular damage including lipid peroxidation. Thus, the use of antioxidants to prevent such damage induced by UV irradiation has received much attention recently. One such antioxidant, which has the potential to be incorporated into sunscreens, is the pineal secretory product melatonin. One of the concerns of using melatonin in sunscreens is its photostability. In the present study, we investigated the photostability of melatonin subjected to UV irradiation. In addition, we used liquid chromatography mass spectrometry (LC-MS) to identify the degradants and we also assessed the ability of the degradants to inhibit O2–· generation as well as lipid peroxidation in rat brain homogenate. The results show that UV irradiation of melatonin (0.1 mg/mL) using a 400-W lamp for 2 hr caused a significant decline of melatonin to 18% of its original concentration after 20 min, with the decline continuing until the melatonin concentration reaches zero at 120 min. The LC-MS results show that the degradants of melatonin are 6-hydroxymelatonin and N1-acetyl-N2-formyl-5-methoxykynurenamine (AFMK). These degradants were able to provide equipotent activity against potassium cyanide (KCN)-induced superoxide generation compared to non-irradiated melatonin. Thus, the study shows that although melatonin is rapidly degraded by UV irradiation, the degradants retain antioxidant activity, making melatonin a likely candidate for inclusion in sunscreens.
- Full Text:
- Date Issued: 2002
The distribution of platinum group elements in the Insizwa lobe, Mount Ayliff Complex, South Africa: implications for Ni-Cu-PGE sulfide exploration in the Karoo igneous province
- Maier, W D, Marsh, Julian S, Barnes, Sarah-Jane, Dodd, D C
- Authors: Maier, W D , Marsh, Julian S , Barnes, Sarah-Jane , Dodd, D C
- Date: 2002
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150353 , vital:38969 , https://0-doi.org.wam.seals.ac.za/10.2113/gsecongeo.97.6.1293
- Description: The Mount Ayliff Complex of the Eastern Cape province of South Africa is a layered intrusion of some 800 km2 surface area and up to 1,200 m thickness. On the basis of compositional similarities and spatial association, it is generally interpreted to form part of the Karoo igneous province. Similarities between the Mount Ayliff Complex and the staging chambers and feeder conduits to flood basalts that host magmatic sulfide ores elsewhere in the world suggest that the Mount Ayliff Complex may have an enhanced potential for Noril’sk-Talnakh–type massive Ni-Cu sulfide ores, an idea that is supported by the well-known sulfide occurrence at Waterfall Gorge.
- Full Text: false
- Date Issued: 2002
- Authors: Maier, W D , Marsh, Julian S , Barnes, Sarah-Jane , Dodd, D C
- Date: 2002
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150353 , vital:38969 , https://0-doi.org.wam.seals.ac.za/10.2113/gsecongeo.97.6.1293
- Description: The Mount Ayliff Complex of the Eastern Cape province of South Africa is a layered intrusion of some 800 km2 surface area and up to 1,200 m thickness. On the basis of compositional similarities and spatial association, it is generally interpreted to form part of the Karoo igneous province. Similarities between the Mount Ayliff Complex and the staging chambers and feeder conduits to flood basalts that host magmatic sulfide ores elsewhere in the world suggest that the Mount Ayliff Complex may have an enhanced potential for Noril’sk-Talnakh–type massive Ni-Cu sulfide ores, an idea that is supported by the well-known sulfide occurrence at Waterfall Gorge.
- Full Text: false
- Date Issued: 2002
A comparative study of atmospheric dynamics in the mesosphere and lower thermosphere (MLT) near Grahamstown (South Africa) and Adelaide (Australia)
- Authors: Malinga, Sandile Bethuel
- Date: 2002
- Subjects: Atmospheric physics Atmospheric physics -- South Africa -- Eastern Cape Atmospheric physics -- Australia Dynamic meteorology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5506 , http://hdl.handle.net/10962/d1007307
- Description: The observations made near Grahamstown (33 .3°S, 26.5°E), South Africa and Adelaide (34.5°S, 138.5°E), Australia over the years 1987 to 1994 are used to study the dynamics of the mesosphere and lower thermosphere (ML T) region with a focus on ∼ 90 km altitude. In particular this thesis deals with on the atmospheric mean flow and the solar diurnal and semi diurnal oscillations with a view to (i) deducing their patterns at the two sites, (ii) comparing the dynamic structures observed at the two sites with special emphases on longitudinal variations, and (iii) putting these observations in a global context by comparing with other ground-based observations, satellite observations and numerical simulations. The main findings are summarised below. The mean flow and the tides at Grahamstown and Adelaide are characteristically variable at planetary time scales. Wavelet spectral and multiresolution analyses reveal that the dominant planetary oscillation is the quasi-16-day oscillation. However, no apparent correlation in the 16-day waves of the mean flow, the diurnal tide and the semidiurnal tide was found. The short-term fluctuations were also investigated using complex demodulation and bispectral techniques and it was found that some of the observed variations in tides could be due to non-linear wave-wave interactions. The long-term trends of the mean flow and tides show patterns that are in broad agreement with theory, results from elsewhere (ground-based and satellite) and the results of the Global-Scale Wave Model and various models by Portnyagin and others. In general the mean flow, the amplitudes and phases of both tides were found to exhibit seasonal and interannual variations which are thought to be related to various factors including (i) changes in the atmospheric mean environment, (ii) thermotidal forcing (iii) gravity wave effects, (iv) planetary scale influence, (v) long-term (e.g. quasi-biennial oscillation) modulation, and (vi) solar activity. There are significant longitudinal differences in the dynamic structure between Grahamstown and Adelaide. More especially, Grahamstown tends to have stronger mean flow and tidal activity than Adelaide. For tides, these differences are thought to be partly due to nonmigrating tidal modes but, in general, migrating modes were found to be dominant.
- Full Text:
- Date Issued: 2002
- Authors: Malinga, Sandile Bethuel
- Date: 2002
- Subjects: Atmospheric physics Atmospheric physics -- South Africa -- Eastern Cape Atmospheric physics -- Australia Dynamic meteorology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:5506 , http://hdl.handle.net/10962/d1007307
- Description: The observations made near Grahamstown (33 .3°S, 26.5°E), South Africa and Adelaide (34.5°S, 138.5°E), Australia over the years 1987 to 1994 are used to study the dynamics of the mesosphere and lower thermosphere (ML T) region with a focus on ∼ 90 km altitude. In particular this thesis deals with on the atmospheric mean flow and the solar diurnal and semi diurnal oscillations with a view to (i) deducing their patterns at the two sites, (ii) comparing the dynamic structures observed at the two sites with special emphases on longitudinal variations, and (iii) putting these observations in a global context by comparing with other ground-based observations, satellite observations and numerical simulations. The main findings are summarised below. The mean flow and the tides at Grahamstown and Adelaide are characteristically variable at planetary time scales. Wavelet spectral and multiresolution analyses reveal that the dominant planetary oscillation is the quasi-16-day oscillation. However, no apparent correlation in the 16-day waves of the mean flow, the diurnal tide and the semidiurnal tide was found. The short-term fluctuations were also investigated using complex demodulation and bispectral techniques and it was found that some of the observed variations in tides could be due to non-linear wave-wave interactions. The long-term trends of the mean flow and tides show patterns that are in broad agreement with theory, results from elsewhere (ground-based and satellite) and the results of the Global-Scale Wave Model and various models by Portnyagin and others. In general the mean flow, the amplitudes and phases of both tides were found to exhibit seasonal and interannual variations which are thought to be related to various factors including (i) changes in the atmospheric mean environment, (ii) thermotidal forcing (iii) gravity wave effects, (iv) planetary scale influence, (v) long-term (e.g. quasi-biennial oscillation) modulation, and (vi) solar activity. There are significant longitudinal differences in the dynamic structure between Grahamstown and Adelaide. More especially, Grahamstown tends to have stronger mean flow and tidal activity than Adelaide. For tides, these differences are thought to be partly due to nonmigrating tidal modes but, in general, migrating modes were found to be dominant.
- Full Text:
- Date Issued: 2002
Gender discourse and Malawian rural communities: a study of the meaning the people of traditional authority Likoswe of Chiradzulo make from human rights and gender messages
- Authors: Manda, Levi Zeleza
- Date: 2002
- Subjects: Human rights -- Malawi , Mass media in community development -- Malawi , Communication in community development -- Malawi , Mass media -- Social aspects -- Malawi , Mass media criticism -- Malawi , Women's rights -- Malawi , Sex role -- Malawi
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3456 , http://hdl.handle.net/10962/d1002910 , Human rights -- Malawi , Mass media in community development -- Malawi , Communication in community development -- Malawi , Mass media -- Social aspects -- Malawi , Mass media criticism -- Malawi , Women's rights -- Malawi , Sex role -- Malawi
- Description: Contrary to earlier beliefs and media theories such as the hypodermic needle or magic bullet, the audience of public communication is not a passive homogenous mass that easily succumbs to media influence. The audience is active, that is, it makes an effort to interpret media content. Depending on predisposing cultural, political, religious, or economic factors the audience makes different meanings from media texts. Media messages are not wholly controlled by producers, although the producers have their preferred and expected readings. Using qualitative research techniques associated with ethnographic and cultural studies (notably focus group discussions), this study sought to explore the meanings rural people in Malawi make out of human rights and gender messages broadcast on radio and through music. Interpreted against Stuart Hall's (1974b) Encoding and Decoding model, the study concludes that while rural communities understand and appreciate the new sociopolitical discourse, they take a negotiated stance because they have their own doubts and fears. They fear losing their cultural identity. Additionally, men, in particular, negotiate the messages because they fear losing their social power over land, property and family.
- Full Text:
- Date Issued: 2002
- Authors: Manda, Levi Zeleza
- Date: 2002
- Subjects: Human rights -- Malawi , Mass media in community development -- Malawi , Communication in community development -- Malawi , Mass media -- Social aspects -- Malawi , Mass media criticism -- Malawi , Women's rights -- Malawi , Sex role -- Malawi
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:3456 , http://hdl.handle.net/10962/d1002910 , Human rights -- Malawi , Mass media in community development -- Malawi , Communication in community development -- Malawi , Mass media -- Social aspects -- Malawi , Mass media criticism -- Malawi , Women's rights -- Malawi , Sex role -- Malawi
- Description: Contrary to earlier beliefs and media theories such as the hypodermic needle or magic bullet, the audience of public communication is not a passive homogenous mass that easily succumbs to media influence. The audience is active, that is, it makes an effort to interpret media content. Depending on predisposing cultural, political, religious, or economic factors the audience makes different meanings from media texts. Media messages are not wholly controlled by producers, although the producers have their preferred and expected readings. Using qualitative research techniques associated with ethnographic and cultural studies (notably focus group discussions), this study sought to explore the meanings rural people in Malawi make out of human rights and gender messages broadcast on radio and through music. Interpreted against Stuart Hall's (1974b) Encoding and Decoding model, the study concludes that while rural communities understand and appreciate the new sociopolitical discourse, they take a negotiated stance because they have their own doubts and fears. They fear losing their cultural identity. Additionally, men, in particular, negotiate the messages because they fear losing their social power over land, property and family.
- Full Text:
- Date Issued: 2002
The identification of factors that contribute to the competitive advantage of the catalytic converter industry cluster in the Eastern Cape
- Authors: Manlee, Tamaryn
- Date: 2002
- Subjects: Competition , Industrial management , Automobiles -- Catalytic converters
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:10892 , http://hdl.handle.net/10948/99 , Competition , Industrial management , Automobiles -- Catalytic converters
- Description: The research problem addressed in this study was to determine what the main factors are that contribute to the competitive advantage of the catalytic converter industry cluster in the Eastern Cape. To achieve this objective theoretical models of competitive advantage and literature of industry clustering were identified. For the models on competitive advantage, Porter’s diamond was used for national competitive advantage and Porter’s model on the competitive environment, which affects the competitive advantage of a region. Other theories on competitive advantage of cities and regions were identified, leading up to the theory on the cluster approach. The literature mentioned was broken down and analysed using literature, from knowledgeable people in the automotive industry in the Eastern Cape, identified during the study. A questionnaire was developed to test the degree to which the catalytic converter industry cluster in the Eastern Cape is in agreement with the literature study. The empirical study obtained a strong concurrence with the literature study on national competitive advantage and the theory of clusters. This resulted in a strategy for the catalytic converter industry cluster to sustain competitive advantage and remain globally competitive.
- Full Text:
- Date Issued: 2002
- Authors: Manlee, Tamaryn
- Date: 2002
- Subjects: Competition , Industrial management , Automobiles -- Catalytic converters
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:10892 , http://hdl.handle.net/10948/99 , Competition , Industrial management , Automobiles -- Catalytic converters
- Description: The research problem addressed in this study was to determine what the main factors are that contribute to the competitive advantage of the catalytic converter industry cluster in the Eastern Cape. To achieve this objective theoretical models of competitive advantage and literature of industry clustering were identified. For the models on competitive advantage, Porter’s diamond was used for national competitive advantage and Porter’s model on the competitive environment, which affects the competitive advantage of a region. Other theories on competitive advantage of cities and regions were identified, leading up to the theory on the cluster approach. The literature mentioned was broken down and analysed using literature, from knowledgeable people in the automotive industry in the Eastern Cape, identified during the study. A questionnaire was developed to test the degree to which the catalytic converter industry cluster in the Eastern Cape is in agreement with the literature study. The empirical study obtained a strong concurrence with the literature study on national competitive advantage and the theory of clusters. This resulted in a strategy for the catalytic converter industry cluster to sustain competitive advantage and remain globally competitive.
- Full Text:
- Date Issued: 2002
Women in paid domestic work and their children : an exploratory study
- Authors: Maqungu, Nomzamo Florence
- Date: 2002 , 2013-05-16
- Subjects: Household employees -- South Africa , Women, Black -- Employment -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:711 , http://hdl.handle.net/10962/d1007476 , Household employees -- South Africa , Women, Black -- Employment -- South Africa
- Description: This study explores the views and experiences of domestic workers with regard to service conditions of their occupation, the arrangements they make for the care of their own children and the frequency of contact they make with their children. Data was obtained through use of pre - coded self administered questionnaires which were employed to 50 domestic women who are working in East London and its suburbs and have children under the age of 16 years. Semi-structured interviews were tape recorded and transcribed and the analysis process looked at general trends where qualitative data was obtained. Quantitative data was tabulated in frequency tables and interpreted by means of graphs. The study is pioneering efforts in the Eastern Cape and South Africa in general as well as setting a way forward for further exploration of this subject. It is hoped that the study will make a worthwhile contribution and bring upfront valuable information that could be used when addressing issues of domestic workers. The study also indirectly challenges those professions and disciplines who have been advocating on behalf of domestic workers to mobilize these workers towards taking part in the uplifting of their standards and to fInish up the good work they had already started until their aims have been achieved. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2002
- Authors: Maqungu, Nomzamo Florence
- Date: 2002 , 2013-05-16
- Subjects: Household employees -- South Africa , Women, Black -- Employment -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: vital:711 , http://hdl.handle.net/10962/d1007476 , Household employees -- South Africa , Women, Black -- Employment -- South Africa
- Description: This study explores the views and experiences of domestic workers with regard to service conditions of their occupation, the arrangements they make for the care of their own children and the frequency of contact they make with their children. Data was obtained through use of pre - coded self administered questionnaires which were employed to 50 domestic women who are working in East London and its suburbs and have children under the age of 16 years. Semi-structured interviews were tape recorded and transcribed and the analysis process looked at general trends where qualitative data was obtained. Quantitative data was tabulated in frequency tables and interpreted by means of graphs. The study is pioneering efforts in the Eastern Cape and South Africa in general as well as setting a way forward for further exploration of this subject. It is hoped that the study will make a worthwhile contribution and bring upfront valuable information that could be used when addressing issues of domestic workers. The study also indirectly challenges those professions and disciplines who have been advocating on behalf of domestic workers to mobilize these workers towards taking part in the uplifting of their standards and to fInish up the good work they had already started until their aims have been achieved. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2002
Valuation of intellectual capital in South African companies: a comparative study of three valuation methods
- Authors: Maree, Kevin W
- Date: 2002
- Subjects: Accounting
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:877 , http://hdl.handle.net/10962/d1001631
- Description: This study discusses three valuation methods for intellectual capital and considers two of these (Tobin’s “q” and CIV) as suitable valuation methods.
- Full Text:
- Date Issued: 2002
- Authors: Maree, Kevin W
- Date: 2002
- Subjects: Accounting
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:877 , http://hdl.handle.net/10962/d1001631
- Description: This study discusses three valuation methods for intellectual capital and considers two of these (Tobin’s “q” and CIV) as suitable valuation methods.
- Full Text:
- Date Issued: 2002
Effects of axial ligands on the photophysical properties of silicon octaphenoxyphthalocyanine
- Maree, M David, Nyokong, Tebello, Suhling, Klaus, Phillips, David
- Authors: Maree, M David , Nyokong, Tebello , Suhling, Klaus , Phillips, David
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289582 , vital:56651 , xlink:href="https://doi.org/10.1142/S1088424602000452"
- Description: The photochemistry and photophysics of six axially substituted silicon phthalocyanines are reported and show the importance of the axial groups in the photochemistry of these compounds. The fluorescence quantum yields are especially affected by the axial ligand. A very good correlation was found for the experimentally determined fluorescence lifetimes and the theoretically determined lifetimes using the Strickler-Berg equation for the unaggregated molecules.
- Full Text:
- Date Issued: 2002
- Authors: Maree, M David , Nyokong, Tebello , Suhling, Klaus , Phillips, David
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289582 , vital:56651 , xlink:href="https://doi.org/10.1142/S1088424602000452"
- Description: The photochemistry and photophysics of six axially substituted silicon phthalocyanines are reported and show the importance of the axial groups in the photochemistry of these compounds. The fluorescence quantum yields are especially affected by the axial ligand. A very good correlation was found for the experimentally determined fluorescence lifetimes and the theoretically determined lifetimes using the Strickler-Berg equation for the unaggregated molecules.
- Full Text:
- Date Issued: 2002
Effects of Axial Ligands on the Photosensitising Properties of Silicon Octaphenoxyphthalocyanines
- Authors: Maree, Machiel David
- Date: 2002
- Subjects: Ligands , Photochemotherapy , Phthalocyanines
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4553 , http://hdl.handle.net/10962/d1018246
- Description: Various axially substituted Silicon octaphenoxyphthalocyanines were synthesised as potential photosensitisers in the photodynamic therapy of cancer. Conventional reflux reactions were used for synthesis as well as new microwave irradiation reactions, wherein the reaction times were decreased tenfold with a marginal increase in reaction yield and product purity. An interesting series of oligomeric (dimer to a nonamer) silicon octaphenoxyphthalocyanines were also successfully synthesised in a reaction similar to polymerisation reactions. These compounds were found to undergo an axial ligand transformation upon irradiation with red light (> 600 nm) in dimethylsulphoxide solution. All the ligands were transformed into the dihydroxy silicon octaphenoxyphthalocyanine with varying degrees of phototransformation quantum yields ranging in order from 10⁻³ to 10⁻⁵ depending on the axial ligand involved. During and after axial ligand transformations a photodegredation of the dihydroxy silicon octaphenoxy phthalocyanine was observed upon continued irradiation. The oligomers were found to undergo the same axial ligand transformation process with a phototransformation quantum yield of 10⁻⁵ The singlet oxygen quantum yields of the unaggregated monomeric silicon octaphenoxy phthalocyanines were all found to be approximately 0.2 with the exception of a compound with two (trihexyl)siloxy axial substituents that had a singlet oxygen quantum yield of approximately 0.4 in dimethylsulphoxide solutions. The oligomers showed a surprising trend of an increase in singlet oxygen quantum yield with an increase in phthalocyanine ring number up to the pentamer and then a dramatic decrease to the nonamer. The triplet quantum yield and triplet lifetime were determined by laser flash photolysis for selected compounds and no correlation was observed with any of these properties and the singlet oxygen quantum yields. These selected compounds all fluoresce and a very good correlation was found between the fluorescence lifetimes determined experimentally by laser photolysis and the Strickler-Berg equation for the non-aggregated compounds. Electrochemical measurements also indicate the importance of the axial ligands upon the behaviour of the phthalocyanines as cyclic voltammetric behaviour was determined by the nature of the axial ligand.
- Full Text:
- Date Issued: 2002
- Authors: Maree, Machiel David
- Date: 2002
- Subjects: Ligands , Photochemotherapy , Phthalocyanines
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4553 , http://hdl.handle.net/10962/d1018246
- Description: Various axially substituted Silicon octaphenoxyphthalocyanines were synthesised as potential photosensitisers in the photodynamic therapy of cancer. Conventional reflux reactions were used for synthesis as well as new microwave irradiation reactions, wherein the reaction times were decreased tenfold with a marginal increase in reaction yield and product purity. An interesting series of oligomeric (dimer to a nonamer) silicon octaphenoxyphthalocyanines were also successfully synthesised in a reaction similar to polymerisation reactions. These compounds were found to undergo an axial ligand transformation upon irradiation with red light (> 600 nm) in dimethylsulphoxide solution. All the ligands were transformed into the dihydroxy silicon octaphenoxyphthalocyanine with varying degrees of phototransformation quantum yields ranging in order from 10⁻³ to 10⁻⁵ depending on the axial ligand involved. During and after axial ligand transformations a photodegredation of the dihydroxy silicon octaphenoxy phthalocyanine was observed upon continued irradiation. The oligomers were found to undergo the same axial ligand transformation process with a phototransformation quantum yield of 10⁻⁵ The singlet oxygen quantum yields of the unaggregated monomeric silicon octaphenoxy phthalocyanines were all found to be approximately 0.2 with the exception of a compound with two (trihexyl)siloxy axial substituents that had a singlet oxygen quantum yield of approximately 0.4 in dimethylsulphoxide solutions. The oligomers showed a surprising trend of an increase in singlet oxygen quantum yield with an increase in phthalocyanine ring number up to the pentamer and then a dramatic decrease to the nonamer. The triplet quantum yield and triplet lifetime were determined by laser flash photolysis for selected compounds and no correlation was observed with any of these properties and the singlet oxygen quantum yields. These selected compounds all fluoresce and a very good correlation was found between the fluorescence lifetimes determined experimentally by laser photolysis and the Strickler-Berg equation for the non-aggregated compounds. Electrochemical measurements also indicate the importance of the axial ligands upon the behaviour of the phthalocyanines as cyclic voltammetric behaviour was determined by the nature of the axial ligand.
- Full Text:
- Date Issued: 2002